SCIENTIFIC ABSTRACT SLADKOV, A.M. - SLADKOV, A.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001651220019-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 24, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

01 0 7
1 .2.2 j 0
AUTHORS:
TITLE-
PERIODICALi
0 9 0 1-1
B 0 '-,:'B 2'ct
Kcrshak, V,, V, Ccrresponding r A' S 7,SS.:i Kas-i
?y,_ NI., K ud -r y a V T S C- V, P, . a d Ut~v
Synthesis and properti.es of
Dok.lady Akademii nauk. 8SSRj v, '156, no. 6, 1,961, '542 13414
TEXT: The al.tthOrS prodliced polyacetyle;-ne (PA") and studied Its
structure arid physical propertLeS. The.-'r that PA formed it-, J~
-t~: ty' .deo e G Fic,fl-.-C
oxidation o" bis-acetylerie ac ~ en, Cf typ
-hich are said to be among the polymerise prcd)-;zts not y,~t They
had already suggested a formaLion mec-nanism c" PA in Ref, 5, 1% prt~ser,~-
.Lnvestigatiori, they produced tl,,,e requ-ired acetylt~fiidi~ ''Y
through the ammoniacal 30111tion f:,f a salt oi bi,~,alenL
the acetylenide was oxidized by an aqu,-o,-;a3 scluti~,,n o." potazsiIL~
cyanide at boiling temperature. The authors assullied tha' t~ie
black powder (containing 981i0' of C) was a atixturt~ oi poly-mar homolcqn~ of
polyacetylene, On the basis of the tempera t tire -depend~-n z vei ht Ir. ,,i
Card 1/5

S/ 023"'61 36!0'0~".;
Synthesis and properties of., BI03/ B203
(Fig. 1 ) and tho ele,,: tror. paramagnetic resonance, they conciLid, th"is
product is a polymer vith cumulene structure, probably
PA showed hig-111 )-eat. -resistance, being transformed into graph~_te -.niy at
23000C, Below 23000C, the carbon. in PA remains in the form of poly'a(;C-Lyiene.
Graphite is also formed by long boiling o-f annea2ed PA samples in c,,,n-
centrated HCI_ The authors Daint to the readiriess of tran~formazi'~t-~ 0-f
carbon atom chains of PA into graphite monolayers, and the zc~rrasp.-;ndarg
transformation of valerjc_~ forms under the ajtior. of HC!, The elec~r~_'
resistivity f measured by the zero method on an MT8(MTV) tridl-e dr~)pped
witK rising temperature. This is explained hy she concentrat-Ion oi
line copper due to thermal dissrx~--tion and the separat~lor, of termina
copper atoms from PA, p continued llroj~ping a~ higher-
copper had already evaporated and no graphite whs for-med, T;-ii_s
synthesis w-nic"r, -:oc-ie. p-A-:e
an extension o" PA chains daring the pyrot-enetic
due to thermal dissociation and copper sapararirsns as well a3 SL'Ilc~-~~i_~rlt
recombination of the resulting free polymeric radicalF. The emr' _t vvEs
measured by the compensation method on a [IF)T(3(PPTV) high-resistan,-..~_
uotentiometer, On the basis of the values ~,,bt~,Aned fcr P ani
Card 2

.20638
3102016111361006101479
;Synthesis and properties of... B103/B203
2~D
.conclude that the PA sample investigated is an n-type semiconductor. The
:1 conDer atoms imbedded in the molecular carbon chain with polyallene struo.
~ture play the role of the electron donor. This is confirmed by the fact
Vthat the a of PA samples which,were produced with the use of stronger
icopper-free oxidizers (nitrate ion, H202) is equal to zero. -The change of
the sign of a (near zero at 1300 and 1500 OC + above 1500 uP to 23000C
corresponds to the transition of the PA sampYe to a p-type semiconductor.
The authors think that this is coupled with the thermal dissociation and
the seDaration of copper- and hydrogen atoms from the carbon chain, and
is certainly connected with the acceptor properties of the terminal C
atoms. There are 3 figures, 1 table, and 3 references: 1 Soviet-bloc
and 1 non-Soviet-bloc.
ASSOCIATIONt Institut goryuchikh iskopayemykh Akademii nat* SSSR
(Institute of Mineral Fuels of the Academy of Sciences USSR)
Institut elementoorganicheskikh soyedineniy Akademii nauk
SSSR (Institute of Elemental-organic Compounds of the
Academy of Sciences USSR)
Card 3/5
.3 0

AUTHORS:
01-
B I C; G
TITLE-
PERIODICAL:
~,crshak, V, V., , Corr~,jponding hller2'c~r AS !,S5,9,
"I.adrkov, A., !.",, Kudryavlloev. P,, nd U5je.,.-
Synthesis and properties of po""facetyl--ta
Dok.lady Ak-ademii nauk SSSR, v.. 130", no. C., 1,961. 1542
TEXT: The aLlLhors produced polyacet,,71ene (PA') and studied its Chemical
structure and physicai properLLe9, They aa:-umed that P.A. form-ed in t-11P
oxidation of bis-acetylerje ar-t~,ty,,ende-,A of tile type HC1=5C -- (Cu,~
fr, r. r: Y
,,hich are said to be among the poly-meric products not yeT. stl,di,~d.
had already suggested a formatiQn mechacism of FA an Ref, 5. in ,he pr&4en~
investigation, they produced tine required a4-etylenide lby pass-ing a:~etylene
through the ammoni-acal sol~jtjcn of a salt ol biialelit cDpper.
the acetylenide was oxidized by an aquao;ls sr,-' ,~ ti ,,n of po ta3s i um ferri. -
cyanide at boiling tempe-Tature The authors assumed tha, -l.qe resul ~1-r;8
black powder (contalnin-- 9810' C) vas a mixt,,~rtz ci po!3,-wer of
polyacetylene, On the basis of the temperature-depend~-nz weight lcz~seo
Card 1/5

Synthesis and properties of...
,Legend to Fig. 3: p and a;
e
ordinate on the leftz -4v/degree,
ordinate on the righti ohm-cm.
217)
IBM
800
-~'400
loop mop mou #00-c
Card 5/5
.30

S/062/62/000/004/012/013
B110/B101
AUTHORSt Korshak, V. V., Sladkov, A. Vt., and Luneva, L. K.
TITLE: Synthesis of elemental organic polymers with acetylene
bonds in their chain
PERIODICALt Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nank, no. 4, 1962, 728
TEXT: New polymers were obtained by polycondensation of halides of elements
organic compounds, R]AeCl 2' with Na acetylenides of bis-acetylenes in polar
solvents (tetrahydrofuran, dimethyl ether, diethylene glycol, ethyl etherp
etc.). The acetylenide was obtained from finely distributed sodium or
sodium amide and bis-acetylene in the solvent. Elemental organic compounds
in the same solvent were added at room temperature, heated to 60-IOOOCY
filtered off, and the polymer was separated from the filtrate. Thus, the
acetylenide was obtained from p-di-ethinyl benzene and sodium. After the
addition of dimethy-l- dichloro silane, the substance was boiled for 7 hret
cooled, and diluted with water. A light-yellow polymer not melting at
Card-1/2

S/062/62/000/004/Oi2/013
Synthesis of elemental organic ... B110/B101
3000C and slightly darkening at 240 0C (C 66-45, 11 - 7-74, Si - 20.92~)
-1 40
precipitated. The infrared spectra showed C~-C (2250 cm
) and Si-CH
3
stretching vibrations (1250 cm The range of elastic deformation was
thermodynamically determined at 150-3000C. Similarly, an acetylenide wa's
obtained from phenyl acetylene and sodium. Addition of dimethyl dichloro
45
silane at room temperature and subsequent boiling for 4 hrs yielded
di-p-phenyl ethinyl dimethyl silane (b. p. 180-185 OC at 4 mm Hg)- In an
analogous manner, polymers can also be obtained from other compounds of
elements of Group IV. The resulting monomers Were used for producing
polymers and copolymers.
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk
SSSR (Institute of Elemental Organic Compounds of the
Academy of Sciences USSR)
SUBMITTEDs December 25, 1961

Card 2/2

KORSHAK, V. V.; SLADKOV A. M - LUNEVA., L. K.
_,,o -0
Elementoorganic polymers. Izv. AN SSSR Otd. khim. n& k 120012.'
2251-2253 D 162j, (MIRA 16:1Y
1. Inatitut elementoorganichesldlih soyedineniy AN SSSRO
(Polymers) (Organometallic compounds)

SLADKOV, A.M.: KRON,.;AUZ, Ye.S.
Chemistry of organometallic compounds. Priroda 51 no.3-35-39
Mr 162. (MIRA 15:3)
1. Institut elementoorganicheskikh soyedineniy AN SSSR, Moskva.
(Organometallic compounds)

S/020/62/144/001/016/024
B119/B144
11 V Corresponding Ifember AS USSR, Sladkov,
i(' ',,udryavtsev, Yu. P.
-3,5-'iethinyl
G-.--idutive dehydropolycondensation of 2,6-diraethyl
-:-,y-.idinb and 9,10-diethinyl-9,10-dihydroxy-9,10-dihydro-
anthracene
'~.kademiya nz-~'C SSSP- Dokl--dy, v. 144, no. 1, 1962, 115 - 117
authors checked their assumption that the reaction
02
C ~~C - R - C
_C=
[C C _ R -Cir must lead to soluble products
if i-. 'olace in the presence of compounds containing only one H. CC
=-Gu-") (lower molecular weight by early chain rupture; (2) if it proceeds
coll-Dounds where R is a large hydrocarbon group, or (3) if R represents
-)c)l:,.r (;--our- The compounds mentioned in the title rere condensed alone,
U I U
also in the presence of acetylene, p-diethinyl benzene, phenyl --cetylEne,
:--,D-par6yl alcohol, and 2-methyl-5-ethinyl pyridine. The structure of the
Card 1/2

,/62/144/001/016/rj24
S/020
Oxidative dehydropolycondensation... B119/3144
I -
condons-tion products wa3 determined from their infrared spectra. Products
of a soluble and an insoluble fraction of identical atructure
obtained in all cases. The epr spectra taken for some condensation
-ee U
s
rlo.. , ea a! concentration of individual electrons in the soluble
Insoluble fractions. The highest number of individual electrons
9.2- C)17 -- a sirnal aidth of 7.2 oe) was found in the condensation
----cduc- of 9,10-d-Jet-hinyl dihydroxy dihydroanthracene with acetylene. TI-Ore
S U-b-le. The most important Eng-lish-language reference is: A.
Chem., 25, 1275 (19,0).
.:::C'7: 7-Sti+Ut ;anicheskilch soyedineniy Akademii nau'- SSSR
elementoorE
(Institute of 'Elemental Organic Compounds of 'the Ac~7.demy of
Sciences USSP),
7 1) January 106, 1962

019/024
B
-ill. ?.I
tse,41 .t) e'r
av ' 1'4'e 6A
reSIP011cli'llp
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0
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1~ Tiloo 0.116L '~ e renj ctor VTO .4. 144, Erola t1le lab uIeTs
. 0114U J)dy-latly I ,tea, . tj-4e 'Poll Stal'
o_j3eM'c re'P 0 S e jlS'.L labor
phot 5551L. a-re 'hoto & J.11 the !A
lla'131C '41,11 on 'Q se t.Lj e
r ch a ens
6 nes -1 thesl
-resea e
JcNbt 'Xa atile Vhere 'V eT -,er-j -photo
0 'Polla" -~ -a OXIII&S V -r e
Y tvie 'L el: ell - 0 o lul) .11
for 11. The _%. qora
I)ata b ?. eaLin cv.C-O' ]~
cteaL
torl .i-re been V Tocc 0-rS S.
lolls
has te& b-j W CIPA.
6i-rec
C
ON
COC r.0c
mod
a ent cloc
Was
-_Vnd~ctivity
___Vr_e_re_ examined more
reduc photo-emf showed a
excit( _,__;fI_fh a narrow selective peak of
case of
for I and a wide peak in -this range
--zamination of II for 2 hr in ultraviolet light,
from an - ------ -1--,O-y mercury lamp increased its photo-emf by*one orde
of magn long-wave threshold of activation is at 366 m~uand the
405 mr. 11-ii-e is inactive. (3) Preliminary illumination is more effective
in vacuo than in air. The photo-emf of I increases during the first
Card 2,13

S/020/62/144/004/019/024
rhoto-apmiconductor properties ... B101/B138
3 - 5 min ligflitin6, then slowly decreases, but after approx. 1hr regains
its initial value. After 1 - 2 hr storage in -the dark this process is
repeatable. (4) 11' 11 is activated by UV IiUht in vacua the admission of
air im:neditely reduces its photo-emf to 1/2 - 1/3. This effect is also
repeatable. These results a~e explained by the UV light ionizing the con-
jugated molecules so that positively charged local centers are formed
~,.,.,hich act as electron traps. The photoelectron is retained in the polymer
structure according to E. C. Lim, G. 71. Swenson (J. Chem. Phys., 36, no. 11
118 (1962))). The absorption of light permits the origination 6-f an exciton
which migrates between the molecules and disintegrates on a defeat pro-
duced by the UV light to form a mobile hole and an electron trapped by the*,
defeat. Accordingly it should be possible to synthesize photosensitive
polymers. There are 3 figures.
SUNMITTED: April 20, 1962
Card 3/3

KORSAK, V.V., VTNOGUWVA, S.V., SOSIN, S.L., SLADKDV, A.M.
Synthesis and slactrophysical properties of the polymers vi h the
conjugated sy3tem of bonds and the po3,vcoordination polymers.
Report submitted for the International Symposium of Macrowlecular chemistry
Paris -1-6 juiy 63

SLADROV, A.M.; EOPSFJK, V.V.; MAKHSUMOV, A.G.
Synthesis of polyesters with acetylenic bonds in their chain. Izv.
AN SSSR. Ser.khim. no.7:134j-1345 Jl 163. (,?.a:?-A 16:9)
1. Inatitut elementoorganichoskikh seyedineniy All SSSR.
(Esters) (Polymers) (Acetylone compounds)

KASATOCHKINY V.I.; SLADKO"Pl.; KUDRYAVTSEV, Yu.P.; SMUTKINA, Z.S.;
-r-*iO-RSftA' V.v.
KHRENKOVA, M.-, y
Properties of polyacetylenes. Izv. AN SSSR Ser.khim. no,10:174J,1771
0 163. (HIRA 17T. 3)
1. Inatitut elementoorganicheskikh soyedineniy AN SSSR i Institut
goryuchikh iskopayeqrkh.

KORSHAK, V.V.; SLADKOV, A.M.; KUDRYAVTISEV, Yu.P.; MAKHSUMOV, A.G.
--~
Synthesis of polyesters containing acetylenic bonds in the chain.
Izv. All SSSR Ser.khim. no.10:1852-1853 0 163. (MIRA 170)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

SLADKOV, A.M.; UKHIN, L.Yu.; KORSHAK, V.V.
Reaction of copper acetylideB with halogen compounds.
Izv. AN SSSR. Ser. khim. no.12:2213-2215 D '63.
(MIRA 17:1)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

E J) /EP1rtc)/LW (w~/BDS, ASD - Pc-4/Pr-4 Rx/ww/mr
L 18o44~63 WP
ACCESSION XR: A?3001145 S/0190/63/005/006/0793/0798

JTHORS- Korshak, V. V.; Sladkov, A. M.; Kudryavtsev, Yu. P.
I.Ab
lbenz
-diethin
- d
f
ondensation
id
bi
d
O
h
TITLE
ly
v-
c
x
a
e
ropo
:
y
1!
y

*ye soyedineniya, v. 5, no. 6, 1963, 793-798,
SOURCE: Vysokom.)lekulyarny
TOPIC TAGS: oxilative condensation, copolycondensation, dehydropolycondensation,
diethinylbenzene, acetylene
ABSTRACT: Earli,!r studies by,the authors on dehydiopolycondeiisation of
'
fercicyanide in the pre ence of
p-diethinylbenzeae by oxidation with potassium
S
cuprous chloride induced the present investigation, where oxygen of the air,
hydrogen peroxida, a~d ammonium persulfate were added to the list of oxidizers.
r
I For copolymeryzation'istudies, acetylene,
pheny lace ty lene, qand ethylacetylene
l
were-used in conjunction with p-diethinyl benzene.~ The oxidative dehydropoly-
condensation of p-diethinylbenzene by air was conducted in a pyridine solution
in the presence of cuprous chloride, through which air was bubbled for 1.5 hours,
resulting in the formation of a yellow precipitate. The obtained substance uas
subjected to elenientary analysis and to infrared spectroscopy, which showed

i Card
.:W

IL 18o44-63
ACCESSION NR:' AP3001145
absorption bands in the 3300 and 1250 cm1i regions, which are characteristic
for =-C-H bonds, while the 2200 cm-l-band-is,indicative of the CeC bond. The
appearance of other characteristic bands indicated the presence of phenyl nuc'lei-~
along the polymeric chain. The oxidative copolymerization of diethinylbenzene,
with acetylene, phenylacetylene. and ethylacetylene yielded low.molecular ether-
soluble compounds with the first two instances, and an insoluble, product with
ethylacetylene. Orig. art. has: 4 formulas and 5 charts.
ASSOCIATION: Institut elementoorganicheskikh soedineniy AN SSSR (Institute Of,
Elementoorganic Compounds, Academy of Sziences, SSSR)
SUBMITTED: 140ct6l DATE ACQ: OlJul63 ENCL: 00
SUB CODE: CH NO REF SOV: 003 OTHER: M2
Card 2/2_

L M84-63 EWP(j)/EPF(c)/ZWT-(m)/BDS - --ASD Pe__4/Pr,_4 RM/MAyiwW
1C -CE S_�_I 67N NR: AP3006746 S/0190/63/005/009/1284/1287
AUTHOR: Korshak V. V.; Sladkov, A. M.; Luneva, L. K.; Girshovich'
A. S.
TITLE: Synthesis and.study of polymers containing allyloxytitano-
cene
Card
SOURCE: Vy*sokomolekulyarny*ye soyedineniya, v. 5, no. 9, 1963,
1284-1287
TOPIC TAGS: titanium compounds, titanocene, dicyclopentadienyl-
titanium(IV) dichloride, allyl alcohol, allyloxytitanocene,
allyloxydicyclopentadienyltitanium(IV) chloride, -synthesis, polym-
er.i zation, polymer, dicyclopentadienyltitanium(IV) dichloride.
trimer, styrene, methyl methacrylate, copolymerization7 COPO'YMerf
allyloxydicyclopentadienyltitanium(IV). polymer with styrene,
styrene. polymer with allyloxydicyclopentadienyltitanium, allyloxy-
dicyclopentadienyltitanium(IV). polymer with methyl methacrylate
methyl methacrylate. polymer with allyloxydicyclopentadienyltita-
nium, copolymer structure, copolymer property
1 3

L 18184-63
ACCESSION NR: AP3006746
ABSTRACT: The synthesis of allyloxytitanocen Eallyloxydicyclo-
pentadienyltitanium chloride] (1) and its polymerization and co-
ty.Lene 1~r methyl methacrylate have been
synthesize
s
bis allyloxy-
studied..-Af-te+ an unsuccessful attempt to
titanocene [bis(allyloxy)dicyclopentadienyltitaniumI from I mol
titanocene [dicyclopentadienyltitanium dichloride] and 2 mols allyl
alcohol, I was prepared from stoichiometric amounts of the starting
materials in the presence of ammonia to bind HCl. The structure'
of I was determined by IR spectroscopic analysis. Polymerization
of I in toluene solution at 100C for 10 hr in the presence of 0.1%
benzoyl peroxide yielded the trimer of 1, as shown by molecu-1ar-
weight measurements and IR and elemental analysis data. Copolymers.
of IV together with polystyrene or poly(methyl methacrylate~, were
produced by heating 10% 1 solutions in styrene or methyl meth-.
acrylate at 120C for 3 hr in the presence of 0.5% benzoyl peroxide.
The copolymers are orange transparent solids with molecular weights
of 22,100 and 70,000. IR spectroscopic analysis of the conolymers
showed that the titanocene groups (sic] are located in the side
chains and that the backbones of the copolymers differ from those
Card 2 / 3
J
ii

FA
L i8184_63
ACCESSION NR: AP3006746
of polystyrene and poly(methyl methacrylate). The softening poilit
of the copolymer with styrene (120C) is higher than that of poly-
styrene (100C). Orig. art. has: 2 figures.
ASSOCIATIONt Institut elementoorganicheskikh soyedineniy AN SSSR:
(Institute of Organoelemental Compounds, AN SSSR)
SUBMITTED: 23Dec6l DATE ACQ: 30Sep63 ENCL: 00
SUB CODE: CH NO REF SOV: 003 OTHER: 002
Card 3/3

L 19444-63 E~1F(c)/EWP(j)/EWT(m)/BDS ASD/ESD-3 Pc-4/Pr-4- M/W'd/MAY
ACCESSION NR: AP3006747 S/0190/63/005/OD9/1288/1291
AUTHOR: Korshak'. V. V.; Sladkov, A. M.; Luneva, L. K.;
Bu I gakova , I . A.1,
TITLE: Study in. the field of coordination volvmers~ 16. Synthesis'
of poly.Rprr. base'd on orthotitanatas and bis-(Bata-diketanoa)i
SOURCE: Vy*sokomolekulyarny*ye soyedineniya, v. 5, no. 9,'1~63,'
1288-1291
TOPIC TAGS: polymers, coordination.polymers, soluble: coordination,i
polymers, soluble coordination polymer synthesis, synthesis,
acecoaccric acid. 2.2'-terephthaloyldi-. ethyl aster, copper
acetate, acetic acid. copper salt, copper,.,nickel,- cobalt mag-
nesium, mercury,.1.3-butanedione. 1-phenyldi-, 2-propanedione.
l-terephchaloyld'--q % 114TiO4. alkyl ester, H4T'04, tetraethyl ester
"1. 3 TiO
2.4-pentanediong, -butanedione.-l-phenyl-, complex, H 4 4-
cc cra-te rc-bu ty; aster, hydrolysis, coordination polymer property,
property
1/4-

L 19444-63
ACCESSION NR: AP3006747
ABSTRACT: Soluble coordination polymers have been prepared by the
methods: 1) Use of.addenda with polar substituents.
Hc;icing of a 5% alcohol solution of ethyl 2,21-terephthaloyldi-
acetoacetate with an excess of a saturated alcohol solution of
ate yielded a coordination polymer in the form of a
copper acet
green precipitate. The polymer withstands heating to 200C, is
readily soluble in diethy1formamide, and is' slightly soluble in
alcohol, benzene, and acetic acid. Similar prdducts were pro-
pared using Ni, Co, Mg, and 11g. 2) Synthesis of complexes of
diketones-with metals having the coordination number 6. Heating
te etone with tetraethyl or tetra-tert-butyl,
OZ rephthaloyldiac
orthot1tanate in dry xylene, with stripping off of the theoretical I
amount of alcohol, yielded-products fully soluble in xylene and
having the general formula (as confirmed by elemental analysis)
on C113
O=~ LO OR
1 _V
C11 11C Ti +2nO11
OR O=C_C,114r-,C-0 OR

L 19444-63
ACCESSION NR-: AP3006747
By addition of petroleum ether, these products can be precipitated'
Cro-ft xylene solution as a yellow fine crystalline substance partly
soluble in benzene and dimethylformamide. The molecular we*ight of~l
the product prappLrad with- tert-butyl titanate was determined by
thd cryoscopic method to be 800, cor-responding to that of the dimei.
3) Syathesis of acetyla.cetonate or benzoylacetonate complexes with,
catra-cert-bucyl ticanate.and their hydrolysis with the cheoreti-
cal amount of water:
11"G CIII C113 11,C CII, C113 113C C1112. C11,
C CIL G CIL C CIL
0 0 0 0 0 0
RO Ti - OR Ti -0-71-
0. 0 0 0 0 0
if
I G CILC ell ,C
C,
112C C113- C113 112C C., 1,3
Card 3/4

L 19444-63
ACCESSION NR: AP3006747
The acetvlacetonate complex yielded a polymer with molecular
weight 1i.000 which melts at about 120C and is hydrolyzed in air
to form a brittle insoluble product. Thetbanzoylacetonate com-
plex yielded a polymer with molecular weight 900 which is soluble
in methyl alcohol, benzene, acetone, and dimethylformamide. Orig-1
art. has: 4 formulas.
ASSOCIATION: In b,.t t'u'-t'--r`e'1emen too rgan L che akikh 'soyedineniy AN SSSR
(Institute of Or-gan 0elemental Compounds,-AN SSS~R)
SUBIMITTED: .23Dec6l DATE.ACQ:... -30Sep63 ENCL: 00.
SUB CODE: CH NO REF SdV: 003 OTHER: 000

L EWP(J)/EPF(C)AW(M)/BDS/ES(s)-2--AFnC/ASD/ESD-3/SSD--Pc-h/
ACCESSION NR: AP3001448 S/0074/63/032/005/0509/0538
AUTHOR: Sladkov, A. M-L Kudryavtsev, Yu. P.
7%0
TITLE: Polyacetylenes
v- 32 5,19630 -55-09-538
SOURCE: Uspekhi khimii, no.
TOPIC TAGS: synthesis of polyacetylenes, properties of polyacetylenes, macro-
cyclic compounds, dehydrocondensation
ABSTRACT: The original article gives a summary of the systhesis and properties of,.
polyace~tylenes, macrocycile c ' ounds with conjugated acetylenie bonds.7and the
OMP
synthesis of polyacetylenes by an oxidizing dehydropolycondensation of bis-acety~
lenes. The polyacetylenes presently synthesized have as many as 10 conjugated
triple bond molecules. The natural polyacetylenic compounds are not discussed.
The basic methods which make the synthesis of a largevariety of polyacetfLenic
hydrocarbons were developedby K. Glaser, P. Cadiot and W. Chodkiewiez, and E. R.
H. Jones. These methods are Tepresented as shown in the enclosure. Dat'idiene-1,3
(diacetylene), one of the simplest compounds, was first prepared thr!,~d-g-h-oo-dfi-f1`on
of acetylenide with CuCl, and later with MnO sub 4. it was found that water SOT.
lutions of Ca(OH) sub 2 and K sub 2 CO sub 3 when used in the reaction~give yields
as high as 60 percent. Diacetylene is quite unstable and can be stored only at
Card
- - - - - - - - - - - - - - - - -- - - - - - - - -

L nil, 1-6,4
ACCESSION RR: AP3001448
temperatures lower than -25C. When the second..acetylenic bond is introduced into.
an acid molecule the dissociation constant Increases. A noticeable amount of dia-.
cetylene glycol was found in all the reactions. A number of explanations are given
for the mechanism of the oxidized dehydrocondensation. Klebanakiy with.'hisco-wor_
kers believe'that the formation of-diacetylenic compounds in aqueoussolutions-
proceed by an ionic radical mechani sm. Triacetylenes which are very unstable even
at -50C and diphenyltriacetylones which are quite stable in 'Comparison to aliphatic
triacetylenes were also synthesized by various methods. The synthesis of octatet~.
rayne-1,M,7 (tetraacetylene), decapentayne-1,3.5.7.9 (penta-acetylene), dodeca-
hexayne-1 3 5 7 n (hexa-acetylene), tatradecaheptayne-1,3,5.7 9 11 l3'(hePt4_
acetylenQ5,'h'ex'adecaoctatetrayme-1,3,5,7,9,:L2,13,15 (octa-acei~lene~.. and eico.sa-
docayne-1.3.5.7.9.11,13.15.17,19 (deca-acetylene)'by various methods and'authors
are given in detail. The stability.of the above acetylenes decreases with.the in-
crease or acetylenic groupp in the polyacetylens chain. Their stability increasse
with the substitution of the end hydrogen with alkjl or aryl radicals, and the
size and configuration of the radical. Due to,their specific reaction ability,,
the acetylynic hydrocarbons have a special place in organic chemistry. -The elec-
tron structure of the acetylenic bond affers fron.the ethylene bond by the fact
that Sigma bond is formed from 2 sp hybrid orbits. Nucleophylic reaction capabili-
ty of acetylenic bond and the oxidation-of acetylenic hydrogen is explained by
Card 21,61
- - - - - - --- - - - - - -

L 1111j3-63
ACCESSION NR: AP3001448
the asymmetric electronicldistribution. A detailed description of the mechanisms
and products is given coveidrig the following reactions:. hydrogen substitution; nu-
cleophylic additions with qH sub 3 OH, HCN, ROH, CH(COOR) sub 2. CH sub 3 Li and
H sub 2 0, (Alh sub 4) sup - and H sub 2 0, and. the formation of cis- and trans
isomers; electrophylic additions; radical reactions; catalytic hydratim; and
formatioil of cumulines (mesomeric structures) from poly-ynes. This pap-sr also
presents the synthesis of a series of macrocyclic compounds with conjugated acety-
lenic bonds obtained through oxidation with oxygen or Oxygen with CaCl, or other
oxidizers. The cyclic compounds are in the form of dimers, trimerstetramerst pen-
tamers, hexamers, and even higher cyclic acetylenes, It was noted that in order
to avold the formation of a linear polymer the reaction must take place in a homo-
geneous solution. One of the best solutions was found to be py~dine and methanol
mixture. The synthesis of polyacetylenes from bis-acetylenes by the oxidizing -
dehydropolycondensation was also studied. The mddent used in these reactions was
oxygen which was used in conjunction with mono- or di- valent cop er Additional
oxidation of the reaction mixture was attained with K sub 3 Fe(CN3 ;~b,6 which re-
sulted in the formation of poly-yne hydrocarbons. It must be noted that the.use
of strong oxidants such as HC10 sub 4 results in the formation of coalescent struc-
tures. Dehydropolycondensation of acetylene with 9,10-diethynyl-9,10-dioxi-9,10-
dihydroanthracene gives a soluble product. Oxidative dimerization of monopyridy-
Card 3/n
~4.1

L 11143-63
ACCESSION NR: AP3001448
lacetylenes forms dipyridylpolyaoetyidnes. It was dipcovered that spme sy nthesized
polyacetylenes have a high photoelectric sensitLvityl~~ the modulated., lig4t. This
discovery points to the approach of the possibility of synthesizing photosensitive
polymers. Orig. art. has: 4 tables, 1 graph, and 1 figure.
ASSOCIATION: Institut elementoorgardehesk:Lkh soyedineniy akademii nauk S5SR (Ins-
titute of SR)
_Organo~emental Compounds, AcadmW of Sciences SS
SUBMITTED- 00 DATE-ACQD: 12Jun63 ENCL: 01
SUB CODE: 00 NO REF SOV: 020 OTHERi 067
Card 44~

KASATOCHKIN, V.I.; SLADKOV, A.M.; ASEYEIV, Yu.G.; KUDRYAVTSEV, Yu.P.;
YEGORGVA, 0.1.; KORSHAK, V.V.
Infrared spectra of poly-Ines. Dokl. AN SSSR 153 no.2:346-349
N 163. (KIRA 16:12)
1. Institut goryuchikh iskopayenqkh AN SSSR i Institut
elementoorganicheskikh soyedineniy AN SSSR. 2. Chlen-korresuondent
AN SSSR (for Korshak).
I
't -

ACCESSION NR: AP4028153 S/0291/64/000/001/0067/0070
.AI:TIIOR: Korshak. V. V.; Sladkov, A. M.; Makhsumov, A. G.
TITLE: Synthesis and investigation of properties of polyesters containing triple
.bonds in the chain. Communication 2. Production of polyes t.ers by the
oxidative dehydropolycondensation reaction
SOURCE: Uzbekskiy khimicheskiy zhurnal, no. 1, 1964,,67-70
TOPIC TAGS: dipropargyl ester, dipropargyl polyester, acetylenic
polyester, dipropargyi isoph thalate, dipropargyl succinate, dipropargyl maleat~,
IR spectra, mnitina ooint. softening temperature, heat i4sistance, oxida-
tive hydrop olycondens at ion
ABSTRACT: Several new dipropargyl esters and polyesters were synthesized.
Dipropargyl terephthalate, oxalate, isophthalate, succinate and maleate (the
last three compounds have not been reported in the literature) were prepared by
reaction of propargyl alcohol and the appropriaie acid anhydride. The dipropar-
CovIlWyesters were then prepared by oxidative dehydropolycondensation in the
r

ACCESSION NR: AP4028153
presence of copper acetate in pyridine and methanol solutions by - re-
fluxing for 20 hours,- pouring ' the product into cold water, and filtering
the black polymer, which 'i a formed according to the reactLon:
CU+2
nHCmC- H3G-0-C-R C-0-CF12-C CH
0 0
I-Ci--C-CHj-0-C-R-C-0-CH2-~-CmCl'-
11
0- 0
IR spectra of the polymers show C- C, C-0, C=O and C-O-C groups and the
absence, of the -=C- H group. The polymers have high softening temperatures and'
high thermal stability (fipr. 1). Orig. art. has: 2 tables, I figure andIequation
ASSOCIATIONS Institut khimii polymerov AN UzSSR (Institute of Polymer Chemist
AN UzSSR) ry,
SUDIMITTEDs 24May63 DATE ACQ: 29Apr64 EKCLs 01
SUB CODES OC NO R&F SOVs 003 OrHERS 005
Card 2/3 ATD PRESSt 3044

-ACCESSI ON NRt AP4028153 BNCLOSURZi 01
10 to 4w. .590 &V -7049
Fig. 1. Synthesis and investigation of poly6.eter properties
I - Dipropargyloxalate polymer; 2 - dipropargy1maleate poly-
mer; 3 - dipropargyltorephthalate polymer;.4 - dipropargyl-
succinate polymer; 5 diptopargy1isophthalate polymov.
Card 3/3,

SIADKOV, A.M.; UKHIN, L.Yu.
Preparation of bromoacetylenes and acetylenic nitriles. Izv.AN
SSSR.Ser,khim. no,2:392-393 F 164. (MIRA 170)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

Acamsim NR: AP4033390
S/0062/&/000/004/0733/0736
AUIHOR: Makhsumov, A. G.; SIAAk v0 A. M.; Korshak, V. V.
TITLE: Acid polycoadensation of dipropargyl ethers conta:Laing wcucon.' phosphorus
and fluorine.
SOURCE: AN SSSR. Izvestiya. Seriya kbimicheskaya., no. 4, 1964, 733-736
TOPIC TAGS: acid polycondensation, dipropargyl ether, acetylenic polymer, triple
bond cont,-JnJng polymer, phosphorus containing acetylenic polymer, fluorine
containing acetylenic polymer,, silicon containing acetylenic polymer,
methylphosphonic acid dipropargyl ether, dipheno.Vsl3ane dipropargyl ether,
polydehydrocondensation *' thermal stability, hexafluorodiane diproparVl ether,
oligomer, IR spectrum
ABSTRACT: The authors continued their earlier work in preparing polymers contain-
Ing, trlple bonds in the cbaln by acid polycondenzation of dipropargyl ethers
(A.M. Sladkov, V. V. Korshak i A. G. Mak-hsumov. Izv. AN SSSR. Ser. 1drin. 1343)
1963), attempting to prepare acetylenic polymers containing phosphorus, fluorine
or silicon. These acetylenic ethers, not described previously in the literature
Card

ACCESSIM NR: AP4033390
were synthesized: the dipropargyl ethers of methylphosphonic acid, of diphenoxy
silane, and of hexafluoro-2,2-bis-(4-hydroxyphenyl)- propane. When subject to
acid polydehydrocondensatioa the first compound hydrolysed to the original
materials, methylphosphonic acid and propargyl alcohol; the second hydrolysed to
form polyphenoxysiloxane. A thermally stable oligomer of the dipropargyl ether
of hexafluorodiane., molecular weight 2730 (dark brown, boiling 95-98CJ and mole-
cular weight 1327 (yellov, boiling 160-162C), was formed from the tbixxl. A polywr~.
containing phosphorus and acetylenic bonds was obtained by the polycondensation
of methylphosphoaic acid chloranhydride with butyndiol. IR spectra Identifying
the products are shown. Orig. art. has: 4 figures.
ASSOCL4TICN: Institut ele~meatoorganicheskjkh soyedinenV Akad nauk SSSR
(Institute of Orgammeta"lle CompoundsAcademy of Sciezces,,SWR)
:SUBMITTED: OqDec63 DA32 ACQ: 1W.W& EXCL: 00
:SUB CODE: OC NO MW SOV: 003 01m: 001
Card 2/2

LARINA, L.P.; SLADKOVY A.M.; MAYISUMOV, A.G.
Ultraviolet adsorption spectra of dipropargyl ether and ester
solutions. Izv. AN SSSR Ser. khim. no.7:131+9-1352 Jl 164.
(MI!u 17:8)
1. Institut elementoorganilcheskikli soyedineniy AN SSSR.

SLADKOV, A.M.; UKHIN., L.Yu.
Interaction of silver acetylides with diazonium salts. Izv.
AN SSSR. Ser. khim. no.8:1552-1553 Ag 164. (MIRA 17:9)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

ACCESSION NR: AP4043776 S/0190/64/006/008/1398/1402
AUTHOR: Sladkov, A. M., Korshak, V. V., Makhsumov, A. G.
TITLE: Synthesis and investigation of the properties of polyesters containing triple
bonds In the chain. Polycondensation of acetylene glycols with dicarboxylic acids
SOURCE: Vy*solcomolekulyarny*ye soyedineniya, v. 6, no. 8, 1964, 1398-1402
TOPIC TAGS: polyester, acetylene, polyacetylene, acetylene glycol, dicarboxylic acid,
polycondensation, polymer physical property
ABSTRACT: Polyhexadieneisophthalate, polybutenephthalate, polybu tyneplitha.1 ate. poly-
buLyncisophtlialate, polyhexadicneterephthal ate, polybutynemaleate, polybutenemaleate,
polybutenesu--cinate, polybutynesuccinate, and polybutenefumarate were prepared by the
classical condensation of acetylene glycols with the chloroanhydrides of dicarboxylic acids,
to supplement the results of a previous study in which similar polymers were obtained by
polydehydrocondensation with oxidation. The melting point, yield, molecular weight,
solubility, empirical formula of the monomer and elemental analysis, found va calculated,
are tabulated, as well as the infrared spectra of the polymers. The synthesis of 2,4-
hexadienediol-1, 6 and the polycondensation of butynediol with succinic anhydride, butynediol
Card 1/2

ACCESSION NR: AP4043776
with lsophthalylchloride, 2,4-hexadienediol- 1, 6 with lsophthalylehloride and
butenediol- 1, 4 with fumaric acid arc described in detail. Thermomechanical curves
(relative elongation vs. temperature) of the polymers are presented and discussed.
Orig. art. has: 3 tables and I figure
ASSOCIATION: Institut elementoorganicheskikh soyedineniy AN SSSR (Institute of
Organometallic Compounds, AN SSSR).
SUBMITTED: 08Aug63
NO REF SOV: 001 OTHER: 001
SUB CODE: OC
C.rd2/2

Z:-,
-,-'-~TL 1-13306-66, f E*r(m)/EPF(,C)/EWP(j C-4 -
6 Ot 9 A
.~:-.'ACCESSIO N'NR. AP4045423 iol,90/6410 .400, A0011571!,V~
Kois,fia'k, V.. V.; Sl dk
AUTHORi~- a 0:1ri Mak tumol
d
h-;
0 Y on eft.6910~
n o
TITLEs Prep ratio lyit d'
a
ersk 7~, I ae4proc
tion of dipropargyl acetate
Mz'
?
3,~
ad
y Tien Yet- V# no
SOURCE V *sokomotekuly __y ~,ye.~ soy L L '1964
1570
TOPIC TAGS:, polyether,.dipropargyi ac-etal' oxLdative-. 00 ydefi ydrocoivrjL, gr
deneation
,,qizkt,
on; I V of ihe~ serLes -Syathes1s* nd,.1stu y -o
ABSTRACT: CommunLcatL 'a
the properti vacetyl L~_bohd An--- -the kb
es of polymers with ac, t n' a &C one,
reports.that certain new dipvopsrgy aceta 's. have--~e'en"':p tip
,
f I I. th, D
1ve:d
converted to a. new, type o ~po ye ero- i9ceta pveparAt..,0a.-.-w_j04o
c ith f orm S.-ldeh d tit sh,
the ree tion -of'. alcohol V d
,propargy y at; ace i
Atesition f
bentaldehydet o-r furfuraldehyde,,. 0 propargy 8, co
0
Raraldehyde yielded 1 acetat- f -the Atimi,
-the dLpr rgy
P7 C
tu
1/2
Card

-7- -7-_
L -11330n~5~,.
Q,
ACCHSSION NR: AP4045423
aud the monopropargyl. acetal,-;. Acid'l~ catalysts, were. ~U'8184r'- TII'' ,1.o,
structures were confirmed by' elemental. analysis', of ird 0
mo a
molecular weight do to rain& t Lon. 'and, I It -sps ctros co'py'i 6xi dali L44.1
.-dL met
polydehydrocondensation of the a - &Is L' ld' d dark.4tiso fibid~',~
T 0
or= - -Orig
pa YaAxs Icontainin :Ln complex f
I a Popper
figure and-2 formulasb.'.
V~
AS'SdCIATIOR: Initituit elementoorganichijkLih i6yed-Lij, so
.AM S
(institute of Otganaftlem6n tal - Compounds
~3 0 ?-,:
14tTTEDI, 6 -AT PRESSt
SUB Me
B CODE v Ocj HT-:~
00 OT98 R V
T
C,. 2/1
rd
E,I

KORSHAK, V.V.;,SLADKOV, A.M.; MAKIISUMOV, A.G.
Synthesis and study of the properties of polyesters with triple
bonds in the chain. Report No.2. Uzb.khim.zhur. 8 no.l,-67-70
164. (MIRA 17%4)
1. Institut khimii polimerov AN UzSSR.

ADOMAYTENE, S.V.; SLADKOV, A.M.; SHISHKOV, V.P.
Condensation of vinyl ethers with amides of substitmWearboxylie
acids. Part 1. Znur.ob.khim. 34 tio.2:432-434 F 164. (MIRA 17:3)

A DOMA Y T --EN 1E, S . 1'. ; S LA DKOV , JA - M - ; S 111 Sq KOV , V - F -
Condensation of vinyl ethers with anddes. Part 2. Zhur. ob. khim.
34 no.O.:-29-58-2960 S 10'4. (M-IRA 17: 11)

GORSHKOVA, CHIIBAFWVA~ 11,11.A.; UKHIN, L.Yu.; SLADKO',T, A.M.;
KASATOCHFIr, V. 1.
Infrared and ultravioIet absorption spectra of substituted
diphenylacetylenes. Zhur. fiz. 1&,-im. 38 no.10:2485-2487
0 164. (MJTII~ 16:2)
1. Institut goIr"ruchikh iskopayemykh All SSSR.

A
and ultralvIO-let
benzrnec: and
infrared and ultraviolet absorption spectra of substiti~ted diphenyl-
butadlypes. Ibid,:2516-2520
goryuchikh
AN, SSIS-R.

SLADKOV, A.M., kand. khim. nauk; KTDRYAVTSEV, Yu.P.
Is a third form of carbon possible? Priroda 53 n0-5:88-94
164. (MIRA 17:5)
1. Institut elementoorganicheskikh soyedineniy AN SSM,
Moskva.

ACCESS= NR: AP',u'j4542 s/oo2o/64/l53/oo5/1i4o/1i43
A70111OR: . Sladhov., A. M.; Norshak, V. V. Oorreuoiidina member); IWdryavtsev,, Yu.
P.;
TITIE: Synthesis of polyethers containin.- triple bonds in the chain.
SOURCE: AII SSSR. Doklady*, v. 155, no. 5, 1964, U40-1143
TOPIC TAGS.- polyether, synthesis, triple bond polyether, annopropargyl ether
copolymer, dipropargyl ether copolymer, diethynylbenzene copolymer, unsaturated
ether, electrophysical property, pliotoelectromotive force., conjurated polyene, IR
spectra, acid polydebydrocondensation, conjurated triple bond p acetylenee ether
polymer
ABSTRACT: Polyethers based on the acid condensation products of mono- and
dipropargyl ethers with p-diethYnylbenzene (DEB) were.synthesized and their
proparties, especially their electrophysical properties, were studied. DEB was
condensed under acid conditions with the dipropargyl ethers of 404-dihydroxytu-
phenyl, of 4,4-dibydroxvcUphenyl-ol-2-prop=e, and of hexaf1uorO-2,2-bi5-(4-
hydrox;yphenyl)-propaae., and the proparal ethers of phenol, quiniz--in -0 benzoic
Card 1/2 --

ACCEWICU SR. AP4034542
acid. These unsatumted athars were selected because their certain electro-
pbysical propertiesp such as photoolectrmotive force. The characterlstic, for
conjugated polyenes were abseat in these polymers. It was hoped that Incorporatlng
DEBinthe chain of the polyether molecule would change its electropbysical
.properties. IR spectra of the products obtained showed the characteristic of the
absorption bands for the acid polydebvdrocondensation of DEB were preserved. F=
IR data and elementary analysis it is,concluded that the generally insoluble
polymers contained conjugated triple bonds alternated with the ether Smups. "IR
spectra were obtained in the WEEOS AN SSSR laboratory by N. A. Chumay-a-Vok., whom
the authors sincerely thank." Orig. art. has: 4 figures and 2 tables*,~,
ASSOCIATICK: Institut elementoorgaaicheskikh soyedineniy Akademli nauk SSSR
(Institute of Organometallic Compounds Academy of Sciences SSSR)
SUMUTTM: 290ct63 DATE AcQ: 134,v64 ENCL-. 00
SUB CME: No M SOV: 004 OMR; 000
Card 2/2

SLADKOV, A.M.; UKHIN, L.Yu.; GORSHKOVA., G.N.; CHUBAROVA, M.A.; MAKHSUMOV, A.G.;
KASATOCHKIN., V.I.
Synthesis and spectra of iodo and bromoacel~ylene derivatives.
Zhur.org.khim. 1 no.3:415-1+21 Mr 165. WIFLA 18:4)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

b
itl- 37-?U-65 t*(c)/LPPR/VA(o R, PC
Pt4o' M(o)
IA'ACCESSION NRf-.;I--AP5006368.~, slotspomfoo? 03
0-
, - ~: , -
L. r*hak,7,vi,
K
64 V4"d PrONO-ties roorge"Ac'- pol"firs- tedu a
bous'
-614 bilk
ir4 AU -"
Ptc, TAdS e-, o-xis it, semi d~n4u c tov;~~,-s oulcondu t0c 012 a.
TO
-gdtid. -Ycopf..- ot 7
V
t Liv onj gat
InIUMIA u d polyziers
BOVIN&I jj I - , e
-EW7, ~177,
lwacaki Woudg-alAernatIng VE
-propors.d wh 1 ch:!~6cpiiti'
oto to the -,b' d 31i~ ""Tab Is:A ;'-0
a 4. L at d
t
FV"Jilecho "i a :SOL 0
virs pplymer $4 It
~P3
..~jj tit 'r f chl6vilpimi beis OYL pe iW a cats at;'
I - 4~ p 0 - . j," - " ... - v-4,
alysti ous- tite; 7
''i'vLthout thc.propst,
0
in o" a
T d 2 The therms stablfti'
abii I -an 4,00
tw1h4--prd 0~m.
'N

L 37718-65
- ------
ACCESSION NRt AP5'008368 _jL
.
i"U.maximum.vo. at e-
300~~-350 C, (temperaturea. c os .a- ectric 1
a ~~meas~.
,
urements (Table 2 'of -the -Encl-osure) thet' al' a t 1 ~_--dalta~ - - an-d" iR
abi Ity
spectr Ioscopy Isugge
a t that'. the d rbital's oV
Si,_._Gei_.and
tit var~ti~i-
pate in the chemical bondi f orma'f ion so-that 'these'~ he terlo , atoms.- o
not impair conjugat L~o .n 0 rig a r,t it a a .3 tables I' f igure' and .1~

formula, T
h USM
e .- men oorg-aitiche'ski
'ASSOCIATIONi Institut ~_el
It S S R
k soye dine n; i Y: i A]
(,institute of Orgazoe-limental- Comiiii~ d Ai 8~SO

-03-
SUBkITTEDt 6811ay64 --"--SUB -CODE4

Oc

~:~No ItEv SOV: 003: T t
97
RES

329
A D
L J,

Card 2/5'
-717-7~7-

SHABANOVAP A.G.; SLADKOV, A.M.; UVAROV, A.V.
Structure of aluminum alizarates. Zhur. fiz. khim. 39 no.6-,
1442-1445 Je 165. (MIRA D;:1,111
1. Subriuluted March 10, 1964.

L 13032-66 EWT(?W)/1WP(j)/_T - -:RM
ACC NR: AP5028581 SOURCE CODE: UR/0076/65/039/01.1/2695/270-OW
AUTHOR: Gorshkova, G. N.; Chubarova, M. Sladkovs A. M.; Luneva,"A'
.L. K.; K.asatochkin, V. I.
ORG: Moscow Institute of Mineral Fuels (Hoskovskiy institut goryuchiJch
iskopayemykh)
TITLE: Spectra of elemental-organic monomers.and 12olymers containing
double and triple bonds
SOURCE: Zhurnal fizicheskoy khimii, v. 39, no. 11, 1965, 2695-2700
TOPIC TAGS: IR spectrum, UV spectrum, polymer, organosilicon compound, organot,
compound, organogermanium compound, organomercury compound, organic phosphorus com-.
pound
ABSTRACT: IR and UV spectra were studied for monomeric silicon, go r-
manium, mercury and phosphorus organic compounds and the IR spectra of.
related polymeric silicon, germanium and tin organic compounds with C=C
and C=_C bonds. The IR spectra were-taken using an IKS-14 spectrophoto-
meter in the 4000-400 cm-1 region on specimens in the form of pellets
with KBr. The spectra of the three monomers containing phenylethynyl
groups displayed C=-C valence vibration band. The position and the in-
UDC: 543,42+547
Card 1/2

L 13032-66
ACC NR: AP5028581 C6
tensity of this band was somewhat de endent on the element: dimetb 1--
di-(Phenylethynyl)silanellat 2159 cm- was very intense; qj;hy1tr!(Rh
Othynyl)g rmanium at-2itb cm-1 was less intens a and di(phanylethynyi)
mercurytat-yii-9cl- I was of medium intensity._ Iin d-ipfi-enyXdiethyny1 si-
t e CEC bond occurs in the 2030-2040 am region. This shows the
effect of the benzene substituent on the position of the CSC bond. In
the former three compounds the shift of the band toward the higher fre-
quency region is caused by the shift of electrons from the nucleus to
the CE bond and thus strengthening of the bond. Ultraviolet spectra
were measured on an SF-4 instrument using cyclohexane as the solvents
An attempt is made to find the relationship between the position and,thi,
intensity of the principal maxima on the molecular structure and the
nature of the element. Orig. Art. has: 3 figures, 1 table.
SUB CODEt 07,20/ SUBM DATE: 22Jul62/ ORIG REr: 002/1 OTH REF: 000
Card 22

-L P11.76-M Tjp(a)
ACZ! NR: 6005391-' SOURCE CODE: uR/o4l3/66/000/001/01521'0152
INVENTOR: Levina. F. A.; B!rbalko, G. I. Sidaravi 51_D.
Sladkov, A. M. Wer-eni-n A- N.
ORG: none P,
TITLE: Preparation of electrophotographic layers. Class 57, No. 169395
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 1, 1966, 152
TOPIC TAGS: electrophotography, electrophotographic layer
ABSTRACT: An Author Certificate has been issued describing a method for making
(7
electrophotographic layers, using poly-N-vinylearbazole as binder. To increase the
sensitivity of the coating, organic photoelectric sensitive compounds such as metal- f"
polyacetylenes and acetylenides are added to the poly-N-vinylcarbazole. [LD1
SUB CODE: ll/ SUBM DATE: 27jul63/
Card 1/1

r
ACC NR: AF60263551 SOURCE CODE1 UR/023~~/66/000/005/0027/0030
~ravichm,I,; 1wrina. F.-A.; lt~jq~-Uoj_ G. Sl~adkqvi-Ai- M. i nikov,,
AUTHORt Sl~
V. S.; Kudryavtsevj Yu. F.; Ukhin, L.
ORG: none
T7MIEt Elootrophotographic layers with photoseraiconducting ac 6 poiymerij3 com-
qylereL
pounds
souRC-A52 Optlko-mokhanicheskaya promyshlennost'p no. 5, 1966., 27-3o
TOPIC TAGS I electrophotography, organic sewdcoMuctor, sem1conducting polymor, coppar",
compound, acetylene compotind
$ST%WTt The D-rtAclrj rwriews roported studiec. of now electrophotogra-plMe layera.
S~omicopducting orGande polymeric compounds contai-xing 11-riplo bonds in the Conjugation
Y and Very
q.~~tir.''Kpolyynos) hive been found to display a h'Gh
64ort timea of photooffect relacation. Tho strucElure of tbevo co-=4ouada 13
C- C- R
Card 113- --.UDCt 2.93

L ('57
ACC NR. AP6026355
pared from them. Authors are sincerely grateful to Academician A. P. Terenin for
supervising the work. Orig. art. has: I table.
SUB CODE: 141 SUBM DATEI OiNov65/ ORIG REF: 010/ OTH REF: 015
L Card 3/3

i A-
91, 1 1 - 11
ACC NR: AP6009159 6
bromide with dihalo derivatives of organometallic compounds. IR spectra of all the
compounds are interpreted. Orig. art. has: I figure, 2 tables.
SUB CODE: 07/ SUBM DATE: O8Jul64/ ORIG REF*: 005/ O`I'H REF: 007
Card 2/2 --c"'C-

ACC NN AP6018060
with 0.001* accuracy. The C p value was accurate to 0.5.Z. For the
purpose of comparison, Cp was a.lao measured in Acheson graphite, C-3
domestic graphite, and ace'tylepe black. Hpat capacity was found to
vary in the sequence:. diamond15< graphitelAk acetylene black < carbyne.
Heat capacity of all nine carbyne samples was significantly higher
thar. that of graphite, although different in each sample. This
difference in CP from on& carbyne sample to another was correlated with
the different ratio of the chain to lamellar structure, i.e., with
partiaLccross-linking of carbon chains. The samples with highest C
p
were assumed to have a low degree of cross-linking, therefore to be
nearly linear carbon polymers, since the value of n in the formula
CP - ATP was nearly I for these samples. The n value for other samples
was 1.2-1.5. Therefore, it was concluded that the products synthe-
sized as described were different from graphite and had a lamellar-
chain 4tructure, Orig. art. has: 2 figures and 2 tablets.
JJK]
SUB CODE3 07/ SUBH DATE: 280ct65/ ORIG REF: 012/ OTH REF: 007
ATD. PRESS:$_aO,5
Card2 2

SLAMOV, A. "I.
Paleobrotumy
Identifying snecies Lycatiodlim. L. and Selaginelia Spring. by spores jard rdcro-spores,
Tri.idy Inst. reor. All SSS~, 110. 50, 1951.
Monthly Q.2L o Nssian Accessions, Library of Congress, -Ttme 1952. LT.'UTA.SS=-IED.
f~ F

1. SLADKOV, A. N.
2. USSR 600
4. Pollen
7. Forms of pollen grains of Kitraria Schoberi, Dokl. AN SSSR, 88, No. 3, 1953.
9. Monthly List of Russian Accessions, Library of Congress, April 1953, Uncl.

SIAMOV, A.N.
I
Morphological description of the pollen of Pyrolace". Kc-notro-
paceas, Bricaceae, V&cciniaceae, and Impetmce" in Zurope&n
U.S.S.R. Trudy Inst.geol. 61:119-156 154. (MISA 8:2)
(Pollen. Fossil)

SLLI)KOV, A. 11.
Morphological description of the pollen of ZygophyllaceiA of
Turkmenis. Trudy Inst.geol. 61:157-167 '54. (Kutk 8: 2)
(Turk:menistan-Pollen, Fossil)

SLADKOY, A.H.
Polymorphism of spores in Pteris cretica. L. Dokl. AN SSSR 117
no-5:gnO-903 D '57. (MIRA l1:_7)
1. Vaesoyusnyy aerogeologicheakiy treat Miniaterstva geologii
okhr.qny nedr SSSR. Prodstavleno sk.Rdemikom V.N.Sukqchev3,m.
(Ferns) (SDores (Botany)

- I- " 'i , :, ";II
. ~ ", 12 ~ -- , I ..I,
SIADKOV, A.N.
....... ..I.....
Concerning the spore-pollen method. Razved. i okh. necIr 23 Mo.9:
11-16 3 157. (KIU 10:11)
(Vagt) (Palynology)

AUTHORt Sladkov, A. N. 20-117, -5.-49/54
TITLE: The Polymorphism of Spores in Fteris cretic;v. (Polimorfizm spor
u pterisa kritskogo)
PERIODICALs Doklady AN SSSR, 1957, Vol- 117, Nr 5, PP-900 - 903 (USSR)
ABSTRACT: The author met the mentioned phenomenon during the preliminry works
for the working out of a determim tion table for the spore-pollen-
-analysis.Pteris cretica occurs in the USSR only in Kolkhida and
Talysh (Kavkaz). Numerous other species of the genus Pteris occur
mainly in the tropics. The Pteris spores are easily to be distin-
guished from the spores of other ferns of the USSR (figure 1). A
dese.ription of the' typical Pteris spores follows. Besides typical
spores with a three-radiate gap also spores of bilateral construg-
tion with single-radiate and with four-radiate gap were found to.;.
gether with transition forms (figure 2). Abnormal spore forms of
ferns are known in the references (reference 1, 4-6). In all her--
bary examples of 'Pteris cretica which were at the author's dis-
posal in small quantities spores were found with single- and four-
-radiate gap. The transitionsbetween the single types of gap and
C the supposed ways of formation of these types are described. The
Card 1/2 spore polymorphism of Pteris cretica can apparently be connected

SLA.DKOV. A. 11.
Studies on the morpholo&v of pollen and spores of modern plants
for spore-pollen analysis in the U.S.S.R. Razved. i okli.nedr
24 no.10:1-4 0 '58. (MIRA 12:2)
1. Aerogeologicheakiy trest.
(Falynology)

SLADKOV, A.11.
Spores of adder's tongue species occurring in the U.S.S.R. Biul.
MOM Otd. biol. 64 no.2:97-111 Mr-Ap, 159. (MIRA 12:10)
(Adder's tongue) (Spores (Botanv))

sov/?O-- 12 ~61

:!IT LE O'n. T. pp -'l rglcal Char o Spor e- ,f R~fa
I ct, tine si..,- Faz ilk, of P,. e rir~ a c- J) of T,,aii us s a F

a F~ S-1 T-1 1. z SSSftl-
PERIODTCAL,,~ ra..k S,~FR- Vo- N~-
'T c
ssl?
ABSTRACTi T i~~ n
hor s at. oa
euf;.
x S U S SR C. f f am.' -nt,,. one,l 111
sp~,r:~z appear tma-,7
-1.11 a-Y 7h~,
Z;.ab da--?. for f
er, -a -.r PT
-~f t":e mor-
y e 5
a.' :3 :.mPortan.-e for the of ~h~.
~.pore~ of oldev iedfmexits. Tha sp-r~-, -;6-3-1 fo--71 p r 01 c 0 n
pr t-~ p a7, a o r-,-z c ~7 I g-- n a t r ~jz h ex-1c a-2 x: a. ez
r a n , L v S ~ i t " t e o f MO -i -, ow - L a-ni.ngs r a~L : B -4, t h I
an-1 of Sakbaliz~ "'y 1, 1. Kaiyagf; L. A.
a--.J. A. I. w,?re -,-a~e4 mea-ns
caxi o4f a - -e S " S , T, ~1,;~ SP ~ r n-e S 4, at 6. d,:4 C, D s 1, J r~ e t a- ah, sd r a 1

Or.. -~h? Itiorphological Characteristic-- of the Sporei S07/2C- 1 2; z
of Peal Fern5 of 37-,3.'_-p_mJ ly .~f Pter--deas
of rh~~- TTSSi F_,.~7a
-,etradz, Tn-?-f !:a-.rr- spores ea,h, tnp followlrg ar's
drawri 'r, 1--ar;-Oug
d,~- il; ed T 1-~ e 6 p o r e ~ w _~ r =_ 3:~'- em -a a 1
pcsltio,r~= (.F-4g SporeS of real ferni ha-.- 2 shcti'~,. forme'.5
I. I
ty urctop as,.?. a) a
In tn= ard endospor:7-,m wh4ch get:; lost
of p-2trificatio I-
.ir fossii 9porea ani whiz~t is atta:~hel L ') t~ie f-.L-,st of 'he two
si-ell~ from, _'-ns-I;d;:.. Publ_-"cati:.)ns diverge -as to .he exis-.em"e of
p,ir!_c3p~.r- - -a thf.7,J in nd.ivid,iai ,ypes of ferns ~.alsc
I ef! z-p-D-.:~ ref T, e 3,-,~tho_r rJel 41rers
di s~--uss,_on, on .h a c I ass if on
i_ c a-,; iarl synon.,,my
of 'ch- (Re-P3 2-7, c: Th,~ investigatLor-3
h- author s~cwea Thai r ~he iase Df pter-*d_,a=--
Y
az- deals wl,.-,''r,. ~r, tji~ presen- p;.pex, i',w~ th t-h=
nf th.-, outer z~ht?1I ma-v ei-her
om-p a-thor
"andone.J., He_--;s_Forwa:rJ __ -
calls~ s.~.iells perlspores. On -the whole his otservatio-rS
agres v7,---:h refefen-.~ 4, whinh were not eno-ugh considered by
F, Han,,-.-,-,,ig iKhannJ.g, 'Ret_ a,~cordiln-g to the autlor'_-
C ~_rl 2/ tjie
p . r, . I I .. -

on T !I :-a. Char a z-t- ~Df th,~- Sp ~Y-~ z, SOV/2~ -2=.
of Real F-7- P
-h~ U
SSR.
o
and uprl9c,~I- cp,
ex-p,,7~, wtt-
-;:l T,a EL ;M:D s
'orma~.. A I OT. a x L 5
P)r f 0 1~
-j;-~
T F', F na- 1 1- r;r ot, em o n -i r J.;-,
whil. -h are SovieT-
ASSOCIA'T I'Cll V s g :!!1 .3 s e-- v7;- eM 1-n 9 B a geo., og4
y 19C
Sq
n s t T o f 0g yar,-,i
PRESENTED, V. N~ S-;Jka~--te%,
SUBMITTEDA
cari.

17(4) -
AUTHA: Sladkov, A. 11. SOV/20-125-2-50/64
TITLE: On the Morphological Similarity and Dissimilarity in the
Spores of Cryptogramma R. Br. and Botrychium Sw. Species
of the Flora of the USSR (0 morfologicheskom akhodstve i
razlichii spor vidov Cryptogramma R. Br i Botrychium Sw.
flory SSSR)
PERIODICAL: Doklady Akademii nauk SSSR, 1959t Vol 125, Nr 2, PP 414-416
(USSR)
ABSTRACT: Comparative morphological investigations of Recent material
of spores are now particularly required in view of the in---.
creasing necessity of determining the genera a-ld species of
fossil pollen grains and spores as precisely as possible. The
dissimilarities in the species within one genus often are in-
significantp while sometimes distantly allied pollen grains
and spores may be similar to one another. Such a similarity
was found by the author between the two fern species mentioned
in the title, which belong to 2 different families (Poly-
podiaceae and Ophioglossaceae). The species dIffer in ecology,
but the specied of both genera are found in the same regions.
Card 1/3 There might be a common presence~-of fossil spores.

On the Morphological Similarity and Dissimilarity in SOV/20-125-2-50/64
the Spores of Cryptogramma R. Br. and Botrychium Sw. Species of the Flora
of the USSR
The separation and separate classification of the spores of
these 2 genera is desired and depends on the determination of
constant morphological dissimilarities. In spite of considera-
ble similarity a determination of the generic classification
of these spores is possible. Table I indicates that Botry-
chium spores in general are smaller than Cryptogramma spores,
a fact that is insufficient, however, for determining the
generic classification. The size of spores may be used only
as an additional feature. The principal indicative features
are the whole character of the Exosporium on the proximal
spore side and the relative size of pominences on the sur-
face of this side (Fig 2). There are 2 figures, 1 table, and
2 Soviet references.
Card 2/3

On the Morphological Similarity and Dissimilarity in SOV/20-125-2-50/64
the Spores of Cryptogramma R. Br. and Botrychium Sw. Species of the Flora
of the USSR
ASSOCIATION: Vsesoyuznyy aerogeolo-icheskiy trest Ministerstva geologii i
okhrany nedr SSSR (All-Union Ae-_,ogrccjogica~LTrust of the Minis-
try of Geology and Protection of' Mineral Resources, USSR)
PRESENTED: October 6, 1958, by V. N. Sukachev, Academician
SUBMITTED: October 6, 1958
Card 3/3

SUkDKOV, A. N., Cand -Hol Sci (diss) -- "Tte morpl,olo.7j of pollen and spores of.
contemporary plants of the USSR in connection with methods of its practical
application". Moscow, 1q60. 20 pp (tioccow Order of Lenin and Order of Labor
RA Panner State Tj im M. V. Lomonosov, Soil-Blol Faculty), 200 copies (KL, No
11, 1960, lu)

SLADKOV, A.N.
Spores of Microlepia Presl. species in the flora of the U.S.S.R.
Nauch.dokl.vys.shkoly: biol.nauki no.4:117-120 6o. (MIR! 13:11)
1. Rekomendovana kafedroy vysshikh rasteniy Moskovskogo gosudar-
stvennogo universiteta im. M.V.Lomonosava.
(FERNS)
(SPORES (BOTANY))

ST-A OV, A. N.
Clearness of spore and pollen diagrams. Vest. Mosk. un. Ser. 6:
Biol., Pochv. 15 no.4:32-37 Jl-Ag 16o. (MIRA 13:10)
1. Kafedra vysshlkh rastenly Moskovskogo uni-wersiteta.
(Falynology)

SLADKOV. A.N.
Spores of true ferns of the subfamily Pteridae Diels in the flora
of the U.S.S.R. Report N0.3: Series Pteridae - Adiantinae and
Pteridae - Pteridinae. Nauch. dokl. vys. shkoly; biol. nauki
no.3'-112-119 '61. (MIRA 14.7)
1. Rekomendovana, kafedroy vysshikh rasteniy Moskovsko.cro gosudarstvennogo
universiteta im. M.V.Lomonosova.
(FEMIS) (SPOfM (BOTANY))

SLADKOV, A.N.
Spores of the real ferns of the subfamily Pterideae Diels of the
U.S.S.R. flora. Report No. 1. Range Pterideae -% Gymnogramminae.
Vest. Mosk. un. Ser. 6: Biol., pochv. 16 no.6:45-52 N-D '61.
(MIRA 15--l)
1. Kafedra vysshikh rasteniy Moskovskogo universiteta.
(Ferns)

SLADKOV, A.N.
Guide for the identification of the spores of true f 'no of
the subfamily Pterideae Diels in the flora of the U.I~ S. R.
Nauch. dokl. vys. shkoly; biol. nauki no.1:129-134 '-I-. (MIRA 15:3)
1. Rekomendovana kafedroy vysshikh rasteniy Moskovskogo
gosudarstvennogo universiteta im. M.V. Lomonosova.
(FERNS)
(SPORES (BOTANY))

SIADKOV P A. N.
Spores of tru? ferns of the subfamily Pterideae Diels found in
the U.S.S.R. Report No. 2. Series Fterideae-Cheilanthinae.
Vest. Mook. un. Ser. 6: Biol.s pochv. 17 no.4:48-59 J1-Ag 162.
(ILM 15:9)
1. Kafedra vysshikh rasteniy Moskovskogo universiteta.
(Spores (Botany)) (Ferns)

SLADKOV., A, N.
Spore tetrads in pteridophyUs. Doklo AN SSSR 143 no.2:1+64-
466 Mr 162o (MIRA 15:3)
1. Moskovskiy gos-adarstvennyy universitet im. M.V.Imonosova.
Predstavleno akademikom V,H.Sukachevym,
(Pteridophyta)
(Spores(Botany))

SUDKOV A. IT
--I.-----I
Polar axes of spores and the moving apart of nuclei during meiosis
in tetrads of different types in peridophytes. Dokl AN SSSR
146 no.1:225-228 S 162. (MIM 15:9)
1. Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova.
Predstavleno akademikom V.N. Sukachevym.
(Pteridophyta) (Botany6--E-mbryology)

SLADKOV, A.N.
Morphographical classification of pollen and spores (based on the
works of G. Erdtman). Nauch. dokl. vys. shkoly; biol. nauki n0-3:
104-111 163. (141RA 16:9)
(Pollen--Morphology) (Spores (Botany))

SLADKOV, A. N.
"0--, t,~e tetra-,-~s a-nd hexads of
report submitted for 10tia Intl Botanical Clong, Edinburgh, 3-12 Aug 64.
Nbscow State Univ.