SCIENTIFIC ABSTRACT SKRIPNIK, YU.A. - SKRIPOV, V.P.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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y, SjI.- SKRIIII'lK, Yu.A. t u 11 E V S11 (I , - j - . -* 1;3 j Measuring phase sh-I f t between -ti,;o d; s ~ c r t d ro" ~-agl~s a Z"r - * u,:!h,-b. mv-3' prib. 7 no.U-02-27 t64' (% -1, 1 --- R -4 19 S. I ) i. : ; - pojiteklm,4,:~h~2~'F,-' -inst t'a7~-- - 1. ~,:iy,-vskiy ordana ien - ~ - - -Y I w m dovzma kafeclroy izmcri-tp-l'nykh uat:-o75-h- SKRiHiti" L bridgtj ,.ilth a (!,'fferetifi, i rid L no. 5:14-111 164. 3.7.12.) 3. Kly~-.vskly izinei-ILeliny'r-h USU-Qy~;tt,. 47 ACC NRo twj~ I 60-10024 SOURCE CODE: Ult/0119/66/000/003/0014/0015 AUTHOR:,. Skripnik, Yu. A. lCandidate of technical sciences); Yaremchuk, N. A. (Engineer) ORG: none TITLE: An automatic single-channel electronic logometer SOURCE: Priborostroyeaiye, no. 3, 1965, 1445 TOPIC TAOS: electronic device, logometer, circuit design ABSTRACT: Recording circuits operating with electric parametric sensors (qppacitative, Inductive sensors) must be designed so'ab to exclude the Influence of the power source on the results of measurements. This problem can be easily solved by utilizing 16gometers as Indicating and registering devices. However, existing electromechanical, rectifier, and con- V.Frter logometers require a considerable amq~nt of power. Consequently, the authors designej &,bd successfully tested an automatic electronic logometer shown in Fig. 1. 000 Card 1/2 UDC: 621.317.61:621.376.2 't'tTBj'j IDATT- T 79M Y,ADUT.j BOGq Sr-PIMaRp YU*Av Maasurawnt of =all coaffiaients of non2inear distortiono in a wido rv,-43a of I!roquancivaw T--v.-vyo.uchab.%av.; radlotekho 8 no.4486-4M Jl-Aa 165, On 18sn) 1. Submitted Januar7 13,p 1965. 1, 02428-67 EWT(d) GD -COVZ---UR[000'0-/6-6-/OOO/000/0047-/0052-' ACC NR, AT6031907 SOURCE ,I ~71 AUTHOR; �kripnik Yu. A. technical sciencesi Docent); (Candidate of 3 Skripnik, V. 1. (Aspirant) I ~ORG: (Skripnik Yu. A.] Institute of ElectrodXnamics, AN UkrSSR (Insti- , ki N Uk-r-9-SM; ~_tkripnik, V. 1. tut elektrodinami A lInstitute (Kiyevskiy politekhnichaskiy institut) ITITLEi A single-channel quadrature phase meter with phase switching SOURCE: Lvov. Politekhnicheskiy institut. Kontroltno-izmeritellnaya tekhnika (Control and measurement techniques) no. 2. Lvov, Izd-vo L'vov. univ., 1966, 47-52 TOPIC TAGS% phase shif t, phase recording, phase meter 10 ABSTRACT: A portable quadrature phase meter with phase switching is described. The input voltages V1 and V2 are applied to blocks 1 and 2 (see Fig. 1) which provide a high-impedance and low-capacitance input to the meter. One of the voltages (V2) goes through a 180* phase switcher whose switching frequency is controlled by a square wave generator (10). The two voltages are then added in-transformer Tp. The resultant output is an amplitude-modulated signal with the index of modulation proportional to the duration from quadrature, i.e., the phase difference of the two applied voltages. The resultant signal is amplified, applied to a square-law detector (5), amplified by a low- Card I / 2 L 02428-67 AT6031907 ~CC NRt V1. V2 2 WW~M't: Fig. 1. Block diagram of quadratun phase meter. AO . J-1I- frequency amplifier (6), applied to a detector (7), synchronized to the switching frequency, and fed through an integrator (8) to a highly sensitive indicator (9). The characteristics of the meter are: input frequency range, I to 1.5 Mc; input voltage, 3-30 v; fine and coarse ~ iscales of 1 30' and 5*; quadrature indication error (with maximum nonlinear distortion of 2%), 6', 30' and 90' for frequencies of 1-200 kc, 200-500 kc, and 500 kc to 1.5 Mc, respectively; minimum iinput; impedance. 0.5 Mohm; threshold sensitivity, not less than 1'. IThe weight of the meter does not exceed 6 kg. 6rig. art. has: 3 figures iand 1 table. [IV) UB CODE11-7,01 SUBM DATE., 25May66/ ORIG REF: 009/ OTH REF: 002 S1 Card 2 2 ACC NR: AT6034601 'A (Uj= L7 U, (1) where U(t) is the signal analyzed, Ug UoeJIOc is the signal of a tunable generator whose frequency determines the analysis frequ6ncy,,and A (Uw) is the signal at I;orchogonal converter output. Specific cases are discussed. Orig. art. has: 22 :formulas and 5_figures- 1SUB CODE: 09, . 1.4/ SUBM DATE: none/ ORIG REF: 006 C.id 2/2 ACC iN3; AI'6034662 SOURCE CODE: UR/3232/66/000/003/0022/0'027 V. I.; Slkripnik, Yu. A. 0-IRG: none -17---': T*-,2 cf-:,~ct ol a-miplitude oa tile accuracy of anLiphase zero L ' vov. Polite',,~hnicheskiy instituz. '.,ortrol'-,io-i--veritel'-,iaya tekhai~a, no. 3, 1966, 22-27 n~ TOPIC TAGS phase measurement, phase shift, phase -meter axzzhod o-: comparinc, amplitude unstable voltages does not provide -.2 c;a ssa of the 180' phase shift. T~e article d-scusses --,ii measurement accuracy of oDeration and describes an accurate antiphase measur-ing device ir, -.-'racision measurer-nents of the 180' phase shift in the relatively broad frequency :.-z-aZe ~s reached using the phase sensitive circuit with periodic co=uta- cions of cG;7.Dar-ed voicages. The equipment has the E llowing paramneters: 1) the - 0. 'o Zr~-,:U2111CY rC-n--2 Is rrOM I kc to I mc. 2) The effective values of input voltages zr,).-. to 20 v, 3) the maximum reading error when the coefficient of nonlinear ~s not hi-her Chan 2/1. is 0.1* for frequencies of 1-100.kc, 0.2* for Zr,ac-,;encies of lOG-300 kc and 0.3* for frequencies of 300kc-I mc. Orig. art. s and 13 f or-mul as. S ZT3 CODE'- 09/ SU31V DATE: nc.-.-.e/ OIRIG REF: 007 w d I SKRIPHIK, Tyacheslav Tasillyevich [Skrypnyk, Y.), kand.sellskokhoz.nauk; PANCOMO, Y., red.; LUC M T, K., tekhred. [Planting of vineyards] Posadke vynahradnyka. Uzhhorod. Zakarpatelke obl.vyd-vo, 1958. 24 p. (MM 13:3) (Viticulture) SKRIPNIK,.,-Vyachealev Tanil'yevich,[Skrypnyk, Y.I. kand.sel'skokhos.riauk; GaimTjT, Y. [Hrymut, V ..1, 1- spetarad.; PANCMMO, T., red.; LUCHKIT, M., takhred. (Cultivation-practices for good yields] Agrotakhniks vysokykh urozhaiv. Uzhhorod, Zaknrpatelke obl.vyd-vo, 1958. 33 P. I (MIFIA 13:3) (Vitimilture) SOV-21-58-8-13/27 'MRS: Skrivnik, Z.D., Cbervyatsova, L.L., and Yankovskaya, G.F. TITLE: Hydrolysis of Acetic Ethyl Ester in the Presence of Oxieized Carbon (Gidroliz uksusnoetilovogo efira v prisutstvii okis- lennogo uglya) PERIODICAI.: Dopovidi Akademii nauk Ukrains1koi RSR, 1958, Nr 8, PP 853-856 (USSR) ABSTRACT: The authors show that oxidized carbon, in comparison with the considerably more bulky carboxylic cation-exchange resin of the KB-4 type, is a good catalyst for the hydrolysis re- action of acetic ethyl ester. On the basis of the results of their investigation and previous studies conducted by I.A. Tarkovskaya (Ref. 16), D.N. Strazhesko (Ref. 1), con- clusion was drawn that the catalytic activity of oxidized carbon, as well as its capacity for cation exchange in an acid medium, is due to hydrogen ions. Their connection with the adsorbent surface, according to the concepts of Verwey and de Boer (Ref. 17), and A. Frumkin (Ref. 18), is of electro- chemical nature. The authors express an assumption that oxidized carbon can apparently serve as a sufficiently Card 1/2 effective catalyst for other reactions of the acid type, SOV-21-5F-8-13/27 of Acetic Ethyl Ester in the Presence of Oxidized Carbon usually accelerated by dissolved strong acids or cationites of the sulfoacid type. This investigation was carried out under the guidance of Professor D.N. Strezhesko. Thorc is I graph and 19 references, 7 of which are Soviet, 4 German, 2 English, 3 American, 1 Australian, and 2 Dutch. ASSOCIATION: Institut fizicheskoy khimii AN UkrSSR im. L.V. Pisarzhevskogo (Institute of Physical Chemistry of the AS UkrSSR imeni L.V. Pisarzhevskiy); Kiyevskiy meditsinskiy institut im. 0.0. Bo- gomolltsa (Kiyev Medical Institute imeni 0.0. Bogomolets) PRESENTED: By Member of the AS UkrSSR, A.I. Brodskiy SUBMITTED: March 6, 1958 NOTE: Russian title and Russian names of individuals and institutions appearing in this article have been used in the transliteration. 1. Acetic ethyl ester--Hydrolysis 2. Carbon--App-licazions Card 2/2 SKRIPNIKJ, Z.D. [Skrypnyk, A.D.] Catalytic oxidation of ascorbic acid in the presence of aftive carbon. Dop. AN URSR no.5:609-613 '64. (MIRA .17:6) 1. Institut fizicheskoy khimii AN UkrSSR. Pr~stavelno akademikom AN UkrSSR A.I.Brodskim [Brodslkyi, 0.1.]. STRAZHESKO, D.N.; SKRIPNIK, Z.D.; CIIERVYATSOVA, L.L.; YANKOVSKAYA, G.F. Acid catalysis in solutions in the presence of oxidized carbon. Dokl. AN SSSR 155 no.1:168-170 Mr 164. (14IRA 17:4) 1. Institut fizicheskoy khimii im. L.V.Pisarzhevskogo AN UkrSSR i Kiyevskiy meditsinskiy institut im. A.A.Bogomolltsa. Predstavleno, akademikom A.N.Frumkinym. c,OL'DSHTEYN, D.L.; RYSAIU)V, M-V-- SKRIPNIK, Z.L-L.- ROGOV, S.P. ,~-- , Production of transformer and turbine oils by bydrogenation of sulfur-bearinp, petroleum products. T--udy VNII NP no.7-245-253 15,9. (MIRA 12:10) (Petroletim products) (Hydrogenation) SKFIPNIKOV, G. K. "Organizational and Technical Aid to Stakhttno-,Iy Brigodes b.,- Comrades Batalov and 1,11trakov During Forced Drpft Sinkinp, of Forizontal Cvos.~-Cut Tunnel,)." (BK) by G. X. Skripulkov. Rcvlowcd by A. BAnkotov. Tsvet. Mat., 14, No. 4-14, 1939. Ronort U-1506, 4 Oct. 1951. ACC NRt AP6035204 SOURCE CODE: UR/0066/66/0001009/0030/0032 AUTHOR: Ivanov, S. K. ; Skripnikov, V. B. ORG: Dongiprouglemash TITLE: KPSh40P movable mine air conditioner with pneumatic drive SOURCE: Miolodillnaya teldinika, no. 0, 1066, 30-32 Tr)PTC TAGS: air conditioning equipment/KPSh40P air conditioner ABSTRACT: Dongiprouglemash has designed a KPSh40P movable air conditioning unit with a pneumatic drive to be used in mines. The Odessa Refrigeration Equipi-nent Plant has produced the experimental model. The unit (Fig. 1) is mounted on a special lorry on 600- to 900-mm wide gage rails. In the summer of 1965, the air conditioner was successfully tested at the "Kochegarka" mine of the Gorlovskugoll Trust of Artemugoll Complex. . Serial production of the new air conditioner is planned for 1967 at the Odessa Refrigeration Equipment Plant. Orig. art. has: 4 figures. [GC] Card 1 / 2 UDC: 628.83 o' Con"ress ll~ t a. t I -.1347 'fu.G. Ins-'-u Ti U, T'. Ori,,- Dub 1~1-5" 10 cstra--~ -',;rnuln for D "f t'~- C. -jollov-r of th~ c,---ll cqu:~.l D is tI!,j ravcra;.,~ -f t',c frui of rr- I ~L Clos,: result.-. V.S. AU''THOR: Skripriikov, Yu.G. 2b-58-5-40/57 TITLE: An Interesting Case of Frolific Fruiting of a 1`um7:1-in (Interesny sluchay mnoLo,,lodiya tikvy) PERIGDI~AL: iriroda, 1958, 1 Nr 5, P 113 033H) A -~- 31'1%ACT lin instance is L;iven, where a -umpkin plant 7~ror!uced 13 pumpkins as compared with the usual 1-3 pumpkins per plant. There is one photo. A330CIATION: Flodoovoshchnoy institut imeni I.V. Michurina, Llichurinsk (Fruit and Vegetable Institute imeni I.V. Michurin, !,1ichurinsk) AVAILABLE: Library of Congress Card 1/1 1. Pumpkins - USSR SKRIPNIKOV, Yu.G. A new pumpkin hybrid. Agrobiclogiia ne.6:137-138 N-D '58. (YIU 12: 1) l.Plodovo-ovoshchn07 institut imerii I.V. Michurina, g. Michurinsk. (Pucapkin-Varisties) - RUBTSOV, M.I., dots.; YEINILOVA, A.A., dots.; CHEREPOVA, O.M., kand. sellkhoz.nauk; SKMPNIKOV, Yu.G., dots.; DOROKHOV, A.A., kand. sellkhoz.nauk; LITUNDVA, M.K., W-ssistent; MUSTAFIN, A.M., pre- podavatell; PESHKOV, V.P., red.; PO-%V, V.N., tekhn. red. (Growing vegetables in the Central Chernozem Region of the U.S.S.R.]Vyrashchivanie ovoshchei v TSentrallnoi chernozemnoi zone SSSR. Tambov, Tambovskoe knizhnoe izd-vo, 1962. 110 p. (MIRA 16:2) 1. Sotrudniki kafedry ovoshchevodstva Michurinskogo plodoovoshch- nogo instituta im.I.V.Michurina (for all except Peshkov, Popov). (Central Chernozem. Region--Vegetable gardening) SKRIPNIKOV, Yu.G-. Squash breeding and seed production. Nacuh. dokl vys. shkoly; biol. nauki no.4t170-173 163 NiRA 16ai) 1. Rekornenclovana kafedroy ovoshchevodstva Hichurinskogo plodo- ovoshchnogo instituta. kJ794-66 EWT(m)/EWP(t)/EWP(b) IJP(c) JD ACC NR: APS027631 SOURCE CODE: UR/0109/65/010/011/2074/2077 AUTHOR: Avaklyants, G. M.; Alimova, L. I.; Murvain. -YI. L.~, Skripnikov, Yu. S.; Togrias, R. A. ORG: none TITLE: Selective properties of silicon diodes with gold- oped base SOURCE: Radiotekhrxika i elektronika, v. 10, no. 11. 1965, Z074-ZO77 TOPIC TAGS: silicon diode, semiconductor diode ABSTRACT: Results are reported of an experimental investigation of an Au- doped-base silicon diode used as a parallel oscillatory circuit thanks to the falling-off branch of its I-V characteristic (N. Holonyak, Proc. IRE, 1962, 50, 12, 2421). Biased to the negative -resistance region, the diode behaved like a high-Q oscillatory circuit; biased to the edge of the positive -resistance region, it Card I UDC:' 621. 382, Z: 546. Z8 *. 6Z1. 39 1. 8 L 7794-66 ;ACC NR: AP5027631 exhibited the characteristics of a low-Q oscillatory circuit. In addition to the jundamental resonance curve, a number of resonance peaks at various multiple i frequencies were observed; higher applied voltages resulted in distorted (asymmetrical) resonance curves. A compound peaked high-Q resonance curve was exhibited by some specimens. As a rule, the resonance frequency increased with the bias current. As a parametric amplifier the silicon diode developed a i voltage gain of 15-25. A transistor circuit, in which the resonant silicon diode was connected in lieu of the collector load, could be operated as an amplifier from a 9-12-v supply-voltage source. Orig. art. has: T figures. SUB CODE: 09 / SUBM DATE: 05Jun64 / ORIG REF: 004 / OTH REF: 001 L 7793-66 E1dT(m)/FWP(t)/EWP(b) NP(c) JD ACC NR: APS027632 SOURCE CODE: UR/0109/65/010/011/2077/2081 AUTHOR: Avak'yants, G. M.; Z!!y,2v, A. V.; M ~jkriEBjhov,. Yu. S.; Surov, V. P.; Tserfas, R. A. ORG: none TITLE: Amplifying and oscillating properties of silicon diodes with 121d-doped base POURCE: Radiotekhnika i elektronika,, v. 10, no. 11, 1965, 2077-2081 J, TOPIC TAGS: silicon diode, semiconductor diode ABSTRACT: The results of an experimental investigation of the operation of a silicon diode as a voltage amplifier and as an oscillator are reported. A simple amplifier circuit consisting of a capacitor in series with the diode developed a voltage gain of 18-20 and a power gain of 200-300; its resonance frequency and Card 112 UDC. 621.382.2:546.z8:621.3 7s+62i. 373 L 7793-66 ACC NR: AP5027632 0 passband depended on the bias current; its maximum sensitivity was 5-10 mv, and in some specimens, 200-300 mv. The noise in such a circuit was incoherent, sinusoidal, and had a maximum coinciding with the resonant frequency. As an oscillator, the silicone diode developed a practically sinusoldal, waveshape; both its frequency and amplitude depended largely on the bias current and external capacitance. Orig. art. has: 7 figures. SUB CODE: 09 SUBM DATE: 05Jun64 ORIG REF: 004 OTH REF: 001 UW Card., .5" 30344 3/19 62/004/008/002/016 B117YB144 AUTHORSt Matsoyan, S. G., Pogosyan, G. Skripnikova, R. K. TITLE;. Study of cyclic polymerization and copolymer~zation. IX. Cyclic polymerization of 4-substituted.hepta-1, 6-dienes in the'presence of radical initiators PERIODICAL: Vysokomolekulyarnyye soyedineniya, V. 4, no. 8, 1962, 1142 - 1144 T.EXT. The authors studied the cyclic polymerization of diallyl malonic a-d diallyl acetoacetic esters, diallyl acetic acid, and a,a-diallyi acetone heated in the presence of benzoyl peroxide and azoisobutyric dinitrile. '.Vith benzoyl peroxide, the polymer yield.; were higher than with azoisobutyric dinitrile. An increase in polymerization tempera .ture above 800C (diallyl malonic ester up to 1600C) reduced the yields. Polymers of diallyl malonic and diallyl acetic esters, and diallyl acetic acid, are fusible white powders easily solWole in acetic acid, benzene, carbon tetrachloride, and hot alcohol, having a molecular weight of 12000 ~ 15000 (determined ebullioscopically). Poly-a,a-diallyl acetone is Card 1/2 5/190/62/004/00a/002/010' Study of cyclic polymerization ... B117/B144 a glasslike mass soluble in organic solvents. It was shown that in the course of radical polymerization two vinyl groups of the initial monomers react without cross-linking. Cyclic polymers containing cyclohexane rings in the principal chain, are formed. Finally it was observed that de- carboxylation takes place when polydiallyl acetic acid is heated to 30OCIG, with formation of polyhexahydrobenzyl, a polymer soluble in benzene. There is 1 table. ASSOCIATIONs Institut organicheskoy khimii AN ArmSSR (Institute of Organic Chemistry AS ArSSR) SUBMITTED; April 24, 1961 Card 212 s/i7i.i /62/01.s/oo6/oo5/oo6 E071/E492 Auvloi~s: Matsoyan, S.G., Pogosyant G.M.1 Nilcogoayan, L.L. TITLE: Investigations in the field of cyclic polymerisation and copolymerisation. Communication 19. A study of radical polymerisation of certain substituted. hoptadienes-1,6 PERIODICAL: Alcademiya nauk Armyanskoy SSR. Izvestiya, Khimicheakiye nauki, v.15, no.6, 1962, 541-551 TEXT: The work is a continuation of previous investigations on --the ability of some substituted heptadiones-1,6 to cyclic* polymerisation and properties of the polymers formed. A number of heptadienes-1,6 were synthesized namely: diallylacetic acid, ethyl and phenyl esters, amide, dimethylamide and phenylamide df diallylacetic acid, diallylearbinol, acetate and benzoate.of diallylcarbinol, 4-chloroheptadlene-1,6, 2,6-dichloro-4-acetyl-k- carbethoxyheptadiene-1,6 and their ability to cyclic polymerisation was investigated. It was shown that on polymerisation of the above monomers in the presence of radical Card 1/2 S/19 63/005/002/004/024.' Bi 01 %102 AUTHORS, Matsoyan, S. G., Fogoayan, G. M., Skripnikova, R. K., h1ushegyan, A. V. TITLE: Studiee in cyclic polymerizatioa and copolymerization@ XI;f Polymerization of substituted hepta-1,6-dienes in, th 1presence of radical initiators PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 5,' no. 2, 19631 163-187 TEXT: Studies were made of 414-dfacetyl-hepta-1,6-diene M, 4-cyano-4- carbethoxy-hepta-1,6-diene (II), 4-eyano-4-carboxy-hepta-1)6-diene (II I) 4-cyano-hepta-1,6-diene (IV)$ 2,6-dictiloro-4,4-,Iicarbothoxy-hopta-1,6- diene (V), and 2t6-dichloro-4-carboxy-iiep'la-1,0'-diene (VI) as to their suitability for cyclic polymerization in the preaence of 2 mole;6 benzoyl peroxide or azoisobutyric dinitrile. When using benzoyl peroxide, the yields (~) and m.p. (OC) of the polymers were: 1, 22.7,,65-67; 11, 34, 76-84; 111, 40-0, 270-300; IV, 9.4, 65-67; V, 79-6~,.th 'iok daqej VI, 47-39 crosBlinking at 2800C. YJith azoisobutyric dinitrile, the yields were Card 1/2 ,-/igo/63/005/002/004/024 Studies in cyclic polyi).e).ization ... B101/B102 lovier.. The molecular weight was 7000 to 20,000, the intrinsic viscosity 0.05-0-15. All polymers were soluble in orEanic solvents, except that of V. Introduction of electron-acceptor groups into the hepta-1,6-diene in 2, 4, or 6 position makes thus the radical polymerization of hepta-1,6- diene possible, which was not achieved without substitution according to C. S. Marvel, J. K. Stille (J. Amer. Chem. soc., 80, 1740, 1956). The IR spectra of the polymers revealed the almost complete absence of double bonds and showed the bands characteristic ol~' substituted oydlohexane rings* Cyclization between C 2 and C7 and linear cyclic polymerization are assumed. In the 2,6-dichloro derivatives, BC1 is split-off. When H01 vias completely separated from the polymer of V! by aqueous alkali solution, a dark brown p?lymer formed, m.p. 202-2050C. The IR spectrum ahowed 'that oyclohexa-1,4-,'. aiene links formed in this reaction. Ther-e are 2 figures and 1 table. ASSOCIATION: Institut organicheokoy klhimii AN AinSSR (Institute of Organic Chemistry AS ArSSR) SUBMITTED: July 25, 196, Card 2/2 ISKRIFNIFOVA, Ye. There can not be two opinions. NTO 3 no.80J_34 Ag 161. (MIRA 14:9) 1. Uchenyy sekretarl soveta Nauchno-tokhnicheskogo obshchestva Krasnodarskago maslozhirovogo kombinata. (Krasnodar--Oils and fats, Edible) SKRIPNIKOVA, Ye, We should work together and not replace each other. NTO 5 no.5: 52 My 163. (WRA. 16:7) I.-Uchen7y sekretart soveta nauehno-takhnicheskogo obshchestva Krasnodarskogo zhirovogo kombinata. - (Technological innovations) SKRIPIIIKUwFA, Ye.P. Materinls!"oi~~ the biolog:r of f ruit mites of the Alma-Ata orshprd rej,ion. Trudy Rpsp.Btn,znshch.rast.2:l64-l7 3 '55 a' (FMA 10:1) (Alma-Ata Provinf-.e--Red snider) (Fruit--Dispases nnd Des's) KHRULEV V. M. ; (',IJPJ,,NKO, A. B. , doktor tokhn. nauk, reteenzent; FREYDIN, A.S., kand. tekhn. nauk, retsenzent- S41UPOV, I - B.S., kand. tekhn.nauk, retsenzent; S(IVOGHKIN, F.P., -dots., retsenzent; ZAYCHIKOVA, E.A., red.; KASWV, D.Ya., tekhn. red. [Improving the durability of glued wooden structures and building elements I Povyshenie d6lgovechnosti kleenykh de- reviannykh konstruktsii i stroitellnykh detalei. Moskva, Gosstroiizdat, 1963. 113 P. (Plywood) (MIRA 16:8) I'd SKRIPOVI F.I. DECEASED -1 --- --- -1962/5 - --- I-- ig6i SEE ILC PHroics ~,,C; . ; -: I Q;~ - ", ic Z: --of'. red., Ot. ral".CIr~n. 'LA course of 2ectures on rp-*Lc,.-rjwa,.,e -j~ectroscol,,,~'lj Kurs lekt.gli po radlospektroskopii. nIngrad, Izd-vo Leningr univ. , 1964. 211 p. (MIiLA 18:2) r I ; Sj~aTPOV, F, T. rdeceas -d AIEKSAITIROV , I . - - - L - - ,-r - - Ir. of nuclear c.-:, +,-e e of crystals by 'e z ethod resonance. Analele inat 11") no.4:!C-!--154 C-D 162. i,agiiet-i c c 1. L-mupo.l. I. V. ?-. lms-'q (oo) 4. Siberia - Turnips 7. Turnips-in the steppe zone of Siberia, Korm. baza. 3. No. 12, 1952. 9. Monthly List of Russian Accessions, Library of Congress, February 1953. Unclassified. K k) ..,"Brazing with heatresistant bramf. M.I.Skr* VC410A. Affolliflos.r 35, NO. 7, 47-5 1 "I 11-11t, used Ivere C11-1.1e lljoyt; Ill, IOIU-. 1100' aud 960-1(M*; the third had a Ni lxwe wid m.p. of 1200-1225'. Their corm,ii. Nvas not given. The flux tin- ployed consisted of 80(,~; 11~1304, 1.1% boriN. 5.3% C~il-*-, and *0.5%Al-Cu-Mg alloy. Specimensuf ValTstvelaodof Kit- N78T alloy ivere lap brazed with tin oxyacetylem-- torch, those of steel being licated at WO' for 4-22W lirs. and those of the alloy at 7001 for2-14 tin. Results of metallographic study, of intercryst. carrosiou dcto.. creep strength Measure- _T~at,.L"dtLati5u~~strengt~i detu. are given. J. D. Gat SKRIPOV, n. I. 20?83. Shchelkunov., V. V., Krivonogov, N. I. i Skripov, N. 1. 0 tipe ekipazha loko- motiva dlya dekovilInykh Dorog. Sbornik nauch. -issled. Rabot (Arkhang. lesotekhn. in-T im Kuybysheva), X11, 1949y S. 5-31. -Bibliogr. 8 nn v. SO: LETOPIS ZHURNAL STATEY - Vol. 28, Moskva, 1949. S,K:--T~ C V. V. i SIFT-it-cv, T- C ~c-j~c-*-.rle:ii di.74zhentyli 7Cd.'--71-nc-c ed. ra-bot 3c-t!-ju~~ uz'-o'rIc-yn-,kh -hf-'ezryih dor-,. S'-Ornlk mluoh.-isSl ---- -- TI, jl)f-,, S. I esotf~lk~ n. 'In-t-. Yuybysiif.%:a' , nr,7v. L;'V4~'J- y SKRIPOV.-.-Njkn1A-..Iy.wwvich; STRASHINSKIY, B.A., red.; KALININA, L.M., red.izd-va; KARWVA, G.L., tekha. red. (Precast reinforced concrete pavement on logging roada]Sbornoe zhelezobetonnoe pokrytie na lesovoznykh dorogakh. Moskva, Gos- lesbumizdat, 1962. 132 p. (MIRA 16:2) (Pavements, Goncrete) (Forest roads) SHCHELKUNOV, 1.,alentin Vasillyevich; SKRIFOV, k.li*oizfy lvnnovich; S%IRNOV, A.I., red. [Effectiveness of the use of various ty-pes of logging roads] 0 Effekti-vnost' primeneniia razlichnykh tipov lesovoznykh do- rog. Moskva, Goslesbumizdat, 1963. 110 P. (MIRA 17:4) USSR/Chemistry - Phase Conversions Mar 51 "Phase Conversions of the Second Order and Crit- ical Phenomena: III. Heat Capacity of Liquid Binary Systems in the Critical Region of Layer- Formation," V. K. Semenchenko, V. P. Skripov) Inst Phys, Moscow State U imeni M. V. Lomonosov "Zhur Fiz Khim" Vol XXV., No 3, PP 362-368 Using specially designed calorimeter, measured heat capacity of binary mixts (triethylamine- H20 and nitrobenzene-hexane) in crit region of layer-formation by method of cooling. Resu:~ts 185_1a4___ USSR/Chemistry - Phase Conversions Mar 51 (Contd) compared with those by direct measurement. Heat capacity in crit region, rising after 1-1.50 to temp of layer-f ormation, passes through finite MA . Secondary max appears in absense of crit concn of mixt. c- n. a nal j C-I Dckl. in the c-rit-al ar;~a c" T h e Y AN SSI-IF, 35 nc. uss ar cessicnz, Library cf Congress, Decemter 10/52. Unclas s if ied. ..cnt'~lv List C-0 H SKRIPOV, V. P. Dissertation: "Heat Capacity of Liquid Binary Mixtures in the Critical Area of Layer Formation." Gand Phys Math Sci, Moscow State U, 1408cow, 1953. W-30928 SO: Referativnyy Zhurnal, No. 5, 1)ec 1953, Moscow, AN USSR (MadtpM) US-R/ Chemistry Physical chemistry Card 1/1 Pub. 147 - 23/26 Authors I Semenchenoko, V. K. and Skripov, V., P. Title Phase conversions of second order and critical phenomena. Part 6. Effect of small admixtures on the specific heat of the triethylamine- A water system in the critical separation zone. Periodical t Zhur. fiz. khim. 29/1, 194-197, Jan 1955 Abstract I In order to determine the effect Gf admixtures on the specific heat in the critical zone the authors investigated a triethylamine-water mixture of critical concentratimwith admixtures of tetraethylammonium iodide and isoamyl alcohol. The tetraethylammonium iodide acted as a surface-active substance increasing the lower critical temperature and reducing the specific heat maximum. The isoamyl alcohol acted as an inert substance thus reducing the critical temperature and the specific heat maximum. The results obtained are briefly described. Seven references: 6 USSR and 1 USA (1934-1955). Diagrams. Institution The M. V. Lomonosov State University, Moscow Submitted June 24, 1954 (/Th'i liolutions. V- p- 4;k-r-inAv M. rel4;iou W-a-s-ro-uM betweeir the sp. beats and tile conclis. of bol"~ This rcUtIon be-comes L!vi- 01" lic-lit ja the crit. layer-formation range, but is not limited to it, mild is of a gelleral Character. The relation was studied [at differer4l. tYptts of sohis. A qual. agreement was found wit), the observation oil the Rayleigh light dispe-tsion. W. M, Sternberg SKRIPOV, V.P. Distribution fuAction of a system containing a varying number of particles in a uniform external field. Zhur.fiz-kh-im. 31 no.l: 150-156 Ja 157. (MIRA 10:5) I.Urallski7 politekhnicheakir institut im. S.M. Kirova, Sverdlovsk. (Thermodynamics) (Statistical mechanics) AtaMR: ml:Awvp v0 re Tl=i of ZqdlV:cdvK N-m- the wd -6'13 Part ViVed -q Walu;am. to3bki i PlItIODIMi Zhumel Widlv .19350 WC. 32,, W 3# PF- 71-2-j16 (LTM) fts :pmmarl Msr Cxavi vVA tXe oTaImMdom -;Pf tht kmaliwit4leal vh:~dh -jrve tl~,Zamd im ol~.~I&Udhlm VL* :U ilA myrWA Uqzll - gw, tAIA-Uim (ref(mmat 1) hM pkxzm%l that Z TI? *A "~r f Woz Of MTZSP SLf" thm ewldq ="VZ- -dt=tcxo, .i~tm Tw- Saw-r-u-na t~ the. hei&t of the tzbe takes a 1=6 Uue, otkar - izv*Vdatiolm of the TawdaLl 012=bStilon of tho 4,=4,v of ffm-balm-40 -a-U.-M &'-so pwforAou tkm 2men-wima mw the twittcml 201g-t a=,.- tska lwk, ww=b a =061C. of *ftifte fazb~og SmA z& e.g. the 4%Ao ef *be grxwiuv.= votav-81 aczo::&-Izg to -~a'* k--d&z of tht tmbe. Imo t!!,,-- m-it.4tsll yAmt oc~,o 1.m v"-7 LrravWg%W7L=a Qf the eff*--ts ef grcvLtm;W-= misw ItLe twit:Ltall w,,L.4,b by Card 113 T i 6-,V-3-35/43 fte Zstabll"~,**, of Now fts c'mt,"ladIze- lkdm'. vid t~La pKr'. Vlvp~sl by 0mvitatlax A, G, (rafw*Lc,s 6)j cthw raisew-abvs gNwe viiiah w*,, hwwwo, L-- agrgsaiwb v:Llh ths -%c lb;rw (.rafamwi.* 'j'). Ax wam t7 VIV.214maw #a& 5)Vi*%Il M=as. Es&2L- Om'. !.writ :4vvltrmq of V,.,& Offest Of g-mmitel'im'. malf-, im L!T--iAs r,-;vxr tlz~a we C=ssti= levwl a O~Zlr~al i~,f Z.=~;-Wom of e.Aaz-",V &-A a t-sa4VI= 'b!*.-,7 4-42-sOM famz, I:"r,'s Y-~m &?---aaZ7 m0slu3i W (~',Ofevmalft . 10) an! rwial.-Ly tr V, Ke Ommu"Wrizko (rdft--smrz Z:--)p vbtr.*=O Is* ". O!P.,s TA) lbx). ta,-- a," Ijza- *is # ~.u af(v A.. Is wfcime~,,-* (VivL dw-iTW.-=nj :;r a gzbq~=ae In a var,*A,'.-,ml Ult- dr..-,a vlmra '.*4 im mriand- tlLe, -. re, an.7at-LI Tot la-m=Ae-A La t~!a i2!!W!- Cori 2/3 240) SOV/56-35-5-41/56 t 0 R 3VriT)ov,.Y-~.--- [;I,;: The Mi-xing Heat of Lil-, it and Heavy Water (TePlota smesheniya lflj~koy i ty'l.."holoy vody) FERIODICAL: '4hurnal eksperimentallnoy i teoret-icheskoy fiziki, 1958, Vol ITr 5, pp 1294-1295 (USSR) '.113TRACT: At the first glance it seems that the joulean effect produced b,F mixinl-I H,O and D 0 must be very small, because a mixture 6 2 a, molecules ;-,ith various isotopes may be consi!iered to be an ideal solution. H`owever, also che::ii-cal i:~teraction between t`ie molecules of initial substances muLt be taken into account: U H 0 + D 0 211DO. For 'lie constant of the equilibrium of 2 2 this reaction in the liquid r.111ase usually (Ref 1) 'the value K = 3.26 io a*sumed. Accordingly, 0.9',; -aole HDO are formed by mi-,Iinl~l I mole H20 anI I mole D 20. if the mixin.7 heat a of the li:rlit and heavy water and the equilibrium constant of t~ie reaction 11 20 + D 20 2 HDO are known, it is no~sible immediately to determine the heat of 'formation qI of HDO at the interaction of H 20 and D 20 in the condensed phase, and C~ird 1/ herefrom some conclu3ions can then be drawn as to the diversity Tlj~! 'Ji r.,,r if r,~;; L of Lij-ht ard Hea-ty Water SOV/56-35-5-41/56 of zero energies of the water molecules with different hydro- ,,ren isotopes. 'Phe i.-Axing heats of H20 and D 20 (99.7%) were determined by means of a hermetically closed tippinE-calori- meter. Durin., mi:cing (up to a molecular concentration n - 0.5 of deuterium) the system was observed to cool down (by rv 0-3~-). In the course of the e,.periment also the speci- fic lhe~at of the system was determined. By means of these ex- periments, the value q = 7-92 + 0.25 Cal/mole was obtained for n = 0.50 after taking all posel"ble errors into account. By butting the equilibrium constant of the reaction H 0 + D 0 2RDO 2 2 in the liquid phase equal to 3.26, the value q1 = 16.7 + 0-5 cal/mole is obtained for the heat of formation of 1 mole HDO (,.,jithout takinF, the influence exercised by the heavy oxygen isotope 018 into account). For the gaseous phase q' = 34 Cal/mole is obtained. The reduction of the heat of fo~-mation of HDO in the condensed phase as against the gaseous pliase may be due to the considerable nolecular interaction in the solution and to the corresponcling -variation of zero enerFies. The author thanks V. 1'. Koctin for his assistance Card 2A in carryin.- out the e:cperiments. There are 3 Soviet references. 24(8) PHASK r :Ki,Y .. P%OITAT!ON Akademlya nauk SSSR. Otdel.r-*ye nauk Tormodinamilca I stroyaniye rastvomv; triidy noveshchaniya... (Thermodynamics and Structu~ of Solutions; Trmnsactlons of the Conference Held JazuLary 27-30, 195a) M~3c0w- Izd-vO A.4 SSSH, 1959. 295 P. 3,ODO Copies Printed. Zd. : M. 1. Shakhparonov, Doctor of Chemical Sciences; Ed. of Publishing House: V. 0. Yegorov; Toch. Ed.: T. V. Polyakova. PURPOSI: This book is Intended for physicists, chamista, and chemical engineers. COVIRA01: This collection of pap*m was originally presented at the Conference on Thermodynamics and Structure of Solutions aponoomd by the Section or Chemical Sciences of the Academy of Sciences, USSR. ind the Dapartagnt of Chemistry of Moscow State University, and hold In Moscow on January 27-30, 1958. Officers of the !!AV- 11stod in the Foreword. A list of other reports ---ZV[&0"r.a&-at thii -o5ufWr;iice, but not Iniluded'in t5ra-U6o1c, are given. Among the problems treated in this work are: electrolytic solutions, ultrasonic measurement, dielectric and thermodynamic properties of various Mixtures, GP0CtrO- soopio analysis, ate. Reforv=en accompany Individual articles. h aronov b TE's-ruodynamic 17 0 u one or xcvAi~troiytez 36 Fluctuation of Energy in Solutions and Their -Cl.tt Z.- at CAP&OItY 43 Fisher I Z ad V. 1. NazImich. Molecular Theory of 48 Khazanova. CriticiLl PhanomenA 49 _jlgZdrAX_Y-Y_ Study of the CrIttlaiLl States of Individual Compounds and of Their MIxtures With the Aid of "".0sonic Methods 56 -A9z12naX--0--j9-' anQdA. Ph a Transitions In jrAUjft%1-- as SlApis Systems and '.sti.. 6T _EaLrraj%Aax--A-1L- Use of 'Mtrowonlc Measurments In the 3~udy-of Solutions T2 N-t-l 011J'U~ and 11. 1. Zenborak. Transfomation of Binary Hateroaxectropes Into- azeoEropez and Homozootropts 79 _Atg=zkjj6-.A-Y-, and A. 0. MorischEyS!Oj- Applicability or Konovalow-2 and Vrovskry-s-TWw-sto Ternary Solutions ST M. -&=Lt= Relation of Themo- of V Sa urated Ter=7 dynamic Proportl -3-aturated " early t Solutions to Thel~ composition 93 4.~jjuhAak*,K-V. Thermodynamic Properties of Water In r 73oitrtiona or Electrolytes 97 -9T.AXt,10.-L-1L-~ssocj&tioo or Klectroiytes in Nonaqueous 105 Alekqwdrnv~N~V- and-U F. Ivanova. Thermodynamic Proper- ~ ; -rA tion Nonacucous 3olu 'i r -- 118 -'- 1.41 . ' N A V. L. Kr-or# L. X. Kutayna, and y~. V.Tito,. Study Or t" iiisat Of Solvents on the StrOngth of Acids by Means of Optical Methods 122 asoclation or Acids and Complex compounds Ktk III and Methods of Studying It 126 Yatalairskiy, X-11. Change In Thermodynamic Functions in of Ions In Solutions 133 Thermodynamics of "Aquacomplazes- 140 -jancmi-Awdar- stoxy of Partial PrOsmu" Of Solvent In Aqu"Us Solutions of Klectrolytes 144 MIno, Star- interactions of Proton With Molecules (Water, and Met~71 Ethyl and n-Pmpyl Alcohol@) 152 21(f), 5(4) SOV/156-59-2-6/48 AUTHORS: Kotellnikov, V. V.,_ Skripov, V. P. TITLE: The Isotopic Effect in the Mutual Solubility of Water and Triethylamine (Izotopnyy effekt vo vzaimnoy rastvoritellnosti vody i trietilamina) PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimiya i khimicheskaya tekhnologiya, 1959, Nr 2, pp 248-249 (USSR) ABSTRACT: The solubility in the systems (C 2 H5)3 It - D20 and (C2H 5)3 N_ H20 is investigated. A diagram (Fig 1) shows the experimental results. The solubility is reduced in heavy water, the 0 , critical temperatures amount to 17.86 lor H 20 and to 14-050 for D 20; thus the difference is negative. For dif- ferent deuterium content of the water the change of the critical temperature in the case of an equal concentration of weight of triethylamine is calculated in the following way: tX - t H20 -cX(tH20 - tD 20) (tH 20 , tD20 denote the temperature limit values at 100% H 20 and D20, respectively). Card 1/2 A table gives the values for a . They are in good agreement x The Isotopic Effect in the ethylamine SOV/156-59-2-6/46 Alutual Solubility of Water and Tri- with the measuring results. An isotopic exchange occurs in solutions of triethylamine and heavy water. Under experimental conditions (concentration of triethylamine 351,46 by weight) I - 1-5~ of the deuterium atoms pasoed over iato triethylamine. There are 1 figure, 1 table, and 3 references, 1 of which is Soviet. PRESEfMD BY:: Kafedra teoreticheskoy khimii Urallskogo politekhnicheskogo instituta im. S. M. Kirova (Chair of Theoretical Chemistry, Ural Polytechnic Institute imeni S. IA. Kirov) SUBMITTED: September 22, 1958 Card 2/2 21(l), 5(4) SOV/1 56-59-2-7/48 AUTHORS: Skripov, V. P., Rusinov, N. Ya. TITLE: The Distri ion of the Heavy Water Between the Liquid Phases in the Stratified3olution Triethylamine - Light Water - Heavy Water (Raspredeieniye tyazheloy vody mezhdu zhidkimi fazami v rasslaivayushchemsya rastvore trietilamin - legkaya voda - tyazhelaya voda) PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimiya i khimicheskaya tekhnologiyaq 1959, Nr 2, pp 250-252 (USSR) ABSTRACT: The distribution coefficient of heavy water between the upper and lower layer of an unmixed solution of triethylamine cool- ed below the critical temperature is given by a table and amounts to a - 1.01. The pycnometric determination of the content of heavy water and the purification of watsr from triethylamine residuals by repeated unmixing at 72 , filtra- tion through active coal and distillation repeated by q times, as well as purity test of water by measuring the electric conductivity are described in detail. Similar investigations carried out in the USA are mentioned (Ref 4). The difference between the value found by the authors (a = 1.01) and that Card 1/2 found in the USA (a - 1.04) is explained by the differant SOV/156-59-2-7/48 The Distribution of the Heavy Water Between the Liquid Phases in the Strati- fied Solution Triethylamine - Light Water - Heavy Water type of the experimental order. The result of the thermo- dynamical analysis on the basis of the generalized Clapeyron- Clausius equation amounts for a to 1-005. Taking into account the further terms of the equation with the differential quo- tient of the chemical potential of the components leads to a higher a-value; it was, however, not possible as a result of inadequate experimental data. There are I table and 4 referencear 3 of which are Soviet. PRESENTED BY: Kafedra teoreticheskoy fiziki instituta im. S. hi. Kirova (Chair of Theoretical Physics, imeni S. M. Kirov) Urallskogo politekhnicheskogo Ural Polytechnic Institute SUBMITTED: September 22, 1956 Card 2/2 29410 SIOB 1/61/000/017/005/i 66 B 1021B 138 AUTHOR: TITLE: Structural features of a substance near critical point, and transfer effects PERIODICAL: Referativilyy zhurnal~ Khimiya, no. 17, ',961i 44., abstract 176307 (Sb, "Kritich, yavleniya i flyuktuatsii v rastvorakh,, M, All SSSR, 196o; 117 - 125) TEXT: The structural peculiarities of matter near the critical points (CP) are discussed on the basis of Semenchenko's presentations (Sb. "Primeneniye ulltraakustiki k issledovaniyu veshchestva".. M., Izd-vo MOPI, 1956)_ It is shown that in a closed domain, matter is near to indifferent equilibrium as regards changes of extensive parameters (density, concentration, entropy). The extraordinary slowness with which equilibrium is established in a one-component system close to CP indicates the diffusion nature of the process. It is noted that microheterogeneity is the main structural feature of a substance near CP- Ideas concerning 'the colloidal nature of liquid mixtures above the critical temperature (RZhKhim, 19--8; Nc~ 141, 46167) are discussed, A quasicolloidal model su.-gested to explain Card 1/3 1 29410 S/081/'61/000/017/005/166 Stl'LlCtural features of a substance. . . B 1102,/3 138 Complete translation. I Car(i 11/,~ S/081/61/000/024/010/086 B138/BIO2 AUTHORS: SkriDov, V. P., Kolpakov, Yu. D. TITLE: Scattering of light in carbonic acid along sub- and trans- critical isotherms PERIODICAL: Referativnyy zhurnal. Khimiya, no. 24, 1961, 73, abstract 24B522(Sb. "Kritich. yavleniya i flyuktuatsii v rastvorakh". M., All SSSR, 196o, 126 - 136) TEXT: The sca8tering of light on carbonic acid is studied for five sub- (19-98 - 30.67 C) and five transcritical (31.20 - 49-90 0C) isotherms. Intensity of scattered I' and of transmitted light I are measured for three 0 'lines of the mercury spectrum ~5461, 4350 and 4060 t). The measurements were made with high pressures k50 - 125 at) in the system. The extremum values of I' increase on approaching critical temperature, and the difference between I' for the liquid and the vapor becomes less. On the transcritical isotherms I' peaks are observed, which also increase on approaching critical point. With variable p - t, points for the I, peaks of transcritical isotherms Dlot very well into a straight line, merging Card 1/2 AUTHORS: TITLE: PERIODICAL: 80284 S/17 60/003/04/05/027 B007Y31O2 Skripov, V.P., Kolpakov, Yu.D. An Investigation of the Interphase-region Transition in Carbonic Acid From Light Scattering Inzhenerno-fizicheakiy zhurnal, 1960, Vol. 3, No. 4, PP- 30-36 TEXT: In this paper experiments are described in which scattered as well as transmitted light was observed during isothermal change of the state of the substance. The experiments were ma "de with carbonic acid. A section through the test chamberis shown in Fig. 1. The experimental arrangement consisted of this chamber, of a system for refilling the device with carbonic acid, a thermal pressure control and an optical system. The device is briefly described. Eight isothermal curves (6 transcritical and 2 suberitical) of the intensity of scattered and of transmitted light as depending on carbonic-acid pressure were taken. The entire temperature range of the measurements was 80C. The dependence of height and position of the maxima of V (intensity of scattered light) on the magnitude of the difference 4T between testing temperature and critical Lemperature is very conspicuous in these curves (Fig. 2)~ The intensity rise of Card 113 80284 An Inveatigation of the Interphase-rQgion Transition S/170/60/003/04/05/027 in Carbonic Acid From Light Scattering B007/B102 scattered light becomes weaker with growing distance from To (critical temperature)~ Vertical lines mark the points of condensation in the below-critical isothermal lines. Fig. 3 shows the dependence of the If-maxima on 4 T for three spectral lines. The maximum of light scattering shifts towards higher pressure with rising temperature (Fig. 2). The relation between temperature and pressure at the V-maxima is, near the critical pointg a straight line with the inclina- tion of dp/dT - 1-50 at/deg or, in reduced quantities, dx/dr - 6.2. The latter value is almost equal to that obtained by M.G Kaganer (Ref. 6) for the critical isochoric curve of various nonpolar gases (dit~d-r - 6.0). In the experiments described also the intensity I of the transmitted light was measured. The minima of transmittent light were obtained in the range of the scattering maxima. The results of earlier measurements made by one of the authors (V.P. Skripov) and G.P. Nikolayev (Ref. 11) have already been given. The qualitative dependence of light scatter on wavelength is shown in table 1 and Fig. 3. The light 4. ,3catterinp, observed had the character of a Rayleigh scattering, i.e. If- I'he data of light scatter and formula (3) (Ref. 8) may be used for calculating or compressibility P -1 (dv/dp)T of the substance elasticity -(dp/clv)T v Card 2/3 80284 An Investigation of the Interphase-region Transition 5/170/60/003/04/05/027 in Carbonic Acid From Light Scattering B007/BJO2 within a narrow range of density variation. In this case elasticity of carbonic acid along the scattering maxima in the transcritical region was calculated. The results are given in table 2. The problem of structure marks in interphase- region transition of gas-like- into fluid-like phases of matter are discussed. This discussion is made from V.K. Semenchenko's aspect (Ref. 7) who connected the investigation of phase transitions with the thermodynamical oriteria of phase stability. In these transitions a continuous number of macroscopically homogeneous isothermal states contains a region with maximum microscopic inhomogeneity of fluctuating character. The existence of such regions is con- nected with the decrease in thermodynamical stability of the original phase and with the formation of "islands" of-a more stable phase. All anomalies in the transcritical region are assumed to be caused by the character of the interphase- region transition. There are 3 figures, 2 tables, and 12 references, 8 of which are Soviet. ASSOCIATION: Urallskiy politekhnicheskiy institut im. S.M. Kirova, g. Sverdlovsk (Ural Polytechnic Institute imeni S.M. Kirov, City of Sverdlovsk) Card 3/3 S/076/60/034/007/019/042/XX B004/B068 AUTHORS: Skripov, V. P, and Kostin, V. M. TITLE: --Specific Heat of Solutions of Triethyl Amine Forming Separate Layers in Light and Heavy Water PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 7, pp. 1503-1507 TEXT: Starting from a theory developed by V. K. Semenchenko (Ref. 1) on critical phenomena, the predictions of a specific-heat maximum in the neighborhood of the critical concentration in separate-layer-forming solutions made according to this theory were examined. For this purpose, the specific heats of triethyl-amine (I) solutions in heavy water (II) and in light water (III) were measured with an adiabatic rocking calorimeter which contained a thermistor and was heated electrically. Five solutions of I and II containing 19.3; 25.6; 30.5; 33.0; and 43.0 % by weight of I, and four solutions of I and III containing 20.1; 25.6; 28.B; and 31.5 % by weight of I were examined. Fig. 2 shows C p, expressed in cal/mole-degree, as a function of temperature (in OC), and Fig. 4 shows C p as a function of Card 1/A I.- Specific Heat of Solutionsof Triethyl Amine S/076/60/034/007/019/042/XX Forming Separate Layers in Light and Heavy Water B004/Bo68 the percent by weight of I. For 6.76 mole% of I, a shift of the critical cal separation temperature equal to 3.8 0 C is observed if H20 is used instead of D20. The highest C p values are near the critical temperature at which separation of the solution into two layers occurs. This is explained by the fluctuation which precedes the macroscopic layer separation and leads to microscopic latent separation dependent on concentration and temperature. A visual method developed by Alekseyev is mentioned but not described. There are 4 figures and 8 references: 7 Soviet and 1 US. ASSOCIATION: Urallskiy politekhnicheakiy institut im. S. M. Kirova, Sverdlovsk (2ral Polytechnic Institute imeni S. M. Kirov, Sverdlovsk) SUBMITTED: September 23, 1958 Text to Fig. 2: 1: Triethyl Amine and Heavy Water; 2: Triethyl Amine and Light Water. Molar Concentration of Triethyl Amine in Both Experimentsz 6.76%; a) cal/mole-degree. Card 2/~- SKRIPOV, V. P. "Thermodynamic Stability of a Liquid and Crisis of Boiling" Report presented at the Conference on Heat and Mass Transfer. Minsk, USSR, 5-10 June 61 A complete cessation of bubble boiling and the establishment of a film regime are conditioned by a critical temperature near the wall and the influence of wettability conditions on it are taken into account. SKRIPOV, V.P. Relationship *tween the dynamic stability of droplets and critical vapor supersaturation during condensation. Koll. zhur. 23 no.1:106-111 Ja-F 161. (MIRA 17:2) 1. Urallskiy politekhnicheskiy institut imeni Kirova, Sverdlovsk. SKRIPOVI, V.P,; KUKUSHYMI, V.I. (Sverdlovsk) Apparatus fnr observing the lirait superheating of liquids. Zhur.fiz.kfiim. 35 no.12:2811-2813 D 161. WIRA 14:12) 1. Ural'skiy politekhnicheskiy institut imeni S.M. Kirova. (Superheaters) (Liquids) S/862,/62/002/000/003/029 A059/A126 AUTHOR: Skripov, V.P. TITLE: Critical boiling and the thermodynamic stability of a liquid SOURCE: Teplo- i massoperenos. t. 2: Teplo- i massoperenos pri fazovykii i khimicheskikh pmvrwhcheniyakh. Ed. by AN. Lykov and B.M. Smoll~ skiy. Minsk, I,.d-vo All BSSR, 1962. 60 - 64 T=-:. The so-called first critical boiling corresponds to the onset of disturbances of nucleate boiling which is followed by a transition region with alternating nucleate and film boiling in space and time and, finally, the tran- sition to film boiling is accomplished at the point of second critical boillng ('!~'tcr2, qcr2) where At is superheating and q the heat flow. Since it ea'n be expected, on the basis of theoretical considerations, that the second critical temperature tcr2 will be close to the. temperature ts of maximum superheating of the liquid, this assumption was verified experimentally. For this purpose, t. and tcr2 were independently determined for different substances and at different pressures. Maximum superheating was determined by the method of H. Wakeshima. Card 1/3 S/86a/62/002/c,oo/003/029 Critical boiling and the thermodynamic .... A059/A126 and K. Takata (J. Phys. Soc. Japan, v. 13, 678, 1958) which is based on the fact that small droplets of the investigated liquid flow into the vertical column of another liquid with a considerabiy higher boiling point which forms a mutually insoluble vapor. Along the height of the column, a temperature gradient is es- tablished which secures the superheating of the overflowing droplets. When these droplets reach some height, they are evaporated in an explosive way with-a characteristic crack. The apparatus used was further improved by the author and V.I. Kukushkin which will be described in another communication. Experiments i,.ere performed with n-hexane, n-heptane, ethyl ether, benzene and water. The mean coefficient of heat exchange.in. the experiments with droplets was found to be proportional to 1/% 6t., where *Z is the time of complete evaporation of the droplets, and ~It the temperature gradient. From data obtained, it is evident that the critical boiling temperature is, as a rule, lower than the maximum su- perheating temperature of the liquid. Maximum superheating of the liquid at the boundary of the solid is determined bythe effective surface tension d eff (0), where 6 is the wetting angle-and + cos 2 )ZY3 (2 cos 9). (2) 2 Card 2/3 S/86Z/6~/OOZ/000/003/029 Critical boiling and the thermodynamic .... A059/A126 The practically complete discontinuation of nucleate boiling is experimentally found to be due to the fact that the liquid along the hot wall teaches the tem- perature of maximum superheating, with the conditions of wetting being taken in- to account. Maximum superheating itself is determined irrespectively of the phenomena of heat transfer and, from its nature, it appears as the critical thermodynamic stability of t-he liquid phase at a given pressure. E.N. Gorbuno- va, M.P. Vukalovich, and I.I. Novikov are mentioned. There are 3 figures and I table. ASSOCIATIO14: Ural'skiy politekhnicheskiy institut, g. Sverdlovsk (Ural Poly- technic Institute, City of Sverdlovsk) SKRIFOV, V.F.; POTASHEV, P.I. Heat transfer to carbonic acid along surercirtical isotherms in the case of free convection. Inzh.-fiz. zhur. ', no.2:30-34 F '62. (MiRji 1j:1) 1. Ural'skiv politekhnic~e6kiy institut imeni S.M.Kirova, Sverdlovsk. (Peat~--Transmission) (Heat--Convection) (Carbonic acid) KOLPAKOV, Yu.D.; 4wmV.-V-p--t;_GORBUNOVA, E.N. Scattering of light in carbonic acid and its relation to the equation of state. Ukr.fiz.zhur. 7 no.7:787-792 J1 162. (MMA 12:15) lo Ur,-%llskiy politekbnicheski7 institut i Urallskiy filial AN SSSRp g. Sverdlovsk. (Light-Scattering) (Carbonic acid) (Equation of state) 33693 0 S/076/62/036/002/004/0001 B119/B101 i"'UTHORS SkriDov, V. P., an,-I Povyshev, L. V. (Sverdlovsk) TITLE: Excess enthalpy of solutions of liCht and heavy water .-ERIO-DIC;-.L- 7,hurnal fizicheskoy khimii, v. 36, no. 2, 19(62, 325 - 331 T F X"': The excess enthalpy, AH, of If 0 - D 0 solutiong was determined at L 2 2 25 and 450C as dependent on the deuterium concentration in the solution. , ments were conducted in a tilting calorimeter with a Pt res4stancc 1 Measur- thermometer (measuring device: nnTI3 (PPTV) potentiometer). The endo- thermic effect observed when mixing H 20 with D 20, is due to the reaction H2 0 + D20 = 2HDO (equilibrium constant of the reaction 3.80). The heat of formation, Ah, of one mole of HDO was measured to be 15.5 cal on the assumi)tion that the solutions are ideal. Theoretical calculations with the aid of the standard enthalDies of HDO, H 20, and D 20, yielded Ah = 2B cal/mole, For similar calculations it is therefore necessary 0 that these standard values be determined with greatest accuracy. At 95 C Card 1/2 33693 3/076/62/036/0021/004/009 Excess enthalov of solutions ... B119/B101 and an atomic fr.-action of the deuterium nD = 0.50, AH is 7.65 � 0.2'~ Cal/mole, at 450C, 6H is 7.55 cal/mole. For determining the heat of exchange and estimating the temperature dependence of the equilibrium V-K constants, the calorimetric method nay be applied for systems with fast isotcuic exchange. A paper by A. I. Brodskiy (Khimiya izotopov (Chemistry of isoto.nes), Izd-vo AN SSSR, M., 1957) is mentioned. There are 3 fi,T-ires, 2 tables, and 5 references: 3 Soviet and 2 non-Soviet. MSSO,-T`.TIOH; Ural'skiy politekhnicheskiy institut im. S. M. Kirovn (Ural Polytechnic Institute imeni S. M. Kirov) a STJR"JI'.Pf!1,~]D1 ADril 23, 1960 Card 212 .3 ; '.4_ EP1?(C)/FWT(m)/B ACQF-55ION MR: AP3004992 S/OOT6/63/037/008/1925/1927 AUTHORSi Skri2ov. V P. Ermakov, G. V., TITLE: Practicable superheating of liquids SOURCE: Zhurnal fiz. kh1mii, v. 37, i~o.18, 1963, 1925-1927 TOPIC TAGS: superheating, superheating of liquid ABSTRACT: Results are reported on the determination of practicable! limits of superheating hydrocarbons at atmospheric and near criti- cal pressures according to methods of H. Wakenshima-and K. Takata (J. Phys. Soc. Japan, 13, 1958, 678) and V. P. Skripov and V., I. Kukushkin (Zh. fiz. khimii, 35, 1961, 2811). Experimental tempera-, ture limits agreed with values calculated from Doering-Volmer'for- how- mula. Near the critical conditions (P :-- 0.7 Pk1 tk = 196.6C) ever,.data could not be obtained because the droplets lose their explosive character. On p - t coordinates, the line of * superheat- ing limits is almost straight for n-pentane. The values for n- hexane and n-heptane are practically on the lame line. Orig. art. -Card L -Mr3::63- ACCESSION NR-. AP3oo4992 hasi 1 table. i ASSOCIATION: Urallskiy politekhnicheskiy institut im. S. M. Kirova,~ Sverdlovsk (Ural polytechnic institute) SUBMITTED: igNov62 DATE ACQ.# 06Sep63 ENCL: 00 SUB CODE: CH NO REP SOV: oo4 OTHER: 003 ;Card , , .P S~MIYOV, V. P. N IKOLXYLli U : . ; - "Irive ~, t 4, at i(-)ri iritr) the 'ulzrn-out of --arbori dioxide, boiling witi-, natural can- vection at pressures close to criticEd." report submitted Vor 2nd Ali-Union ConC on Illeat & Mass Transfer, Rinsk, 4-12 Ma.y 19611. Ural' Pol,4techaiic Inst. S i I-,, I 1-CV, V. -. ,: i-17 -111-~TRCIV IN.'Al Ye . It . "Curlvecti%rc: fluaL ~.i diozlde in tir-e near critical reglion." report submitted for 2nd All-Union Conf on Heat & Mass Transfer, Minsk, 4-12 Play 1'~,'164. Ural' ;,ranch, Acad Sci USSR, Ural' Polytechnic Inst PAVLOV, P.A.; SKRIPOV, V.P. Boiling up of a liquid in pulse heating. Part 1: Methodology of the experiment with thin wires. Tep-lofiz. vys. temp. 3 no.1:109- 114 Ja--F 165, (MIRA 18t4) 1. Urallskiy politekhnicheskiy institut imeni Kirova. ACCESSION NR: AP4034605 S/0143/64/000/004/0066/0071 AUTHOR: Skripov, V. P. (Docent); Nikolayev, G. P. (Engineer) TITLE: Heat exchange with boiling carbon dioxide at near-critical pressures SOURCE: IVUZ. Energetika, no. 4, 1964, 66-71 TOPIC TAGS: carbon dioxide,.carbon dioxide heat exchange, heat exchange, critical boiling, critical boiling pressure ABSTRACT: An experimental investigation of the critical boiling of carbon dioxide at near-critical pressures of a liquid-vapor system under natural convec- tion conditions is reported. The heat exchange was studied with a 3. 9 / 3. 0 -mm brass tubing passing circulating water and cooled externally by boiling carbon dioxide. The tubing was mounted in a pressure chamber with thermocouples, viewing ports, etc. (drawing supplied). These pressures were maintained in the .chamber: 65.9. 68. 1, 69.9, 72. Z, 73.7. 74.2, 75. 0 kg1cm A. ; the carbon dioxide z critical pressure was 75.3 kglcm " It was found that: (1) At near-critical pressures, the pattern of liquid boiling on the tubing surface undergoes a sharp Card 112 ACCESSION NR: AP4034605 change; the wall -temperature vs. ape cifii- -ther mal -flow curve retains its normal shape; it passes through its maximum and minimum, except for p a 75.0 kg/cm where no crisis was observed; (Z) For pressure ratios p/p, .,i+. - 0.875-0.995, the variation of q,,, , q,~,,, and twr"-., was measured, the I-,cal wall temperature corresponding to the bubble -to-film-boiling transition was lower than ,,it ; (3) The line of the max -heat -transfer factor turns into the supercritical t, max -heat -transfer line at the boiling point; at supercritical pressures, boiling is impossible; however, the max th6rmal expansion and max heat capacity conditions result in the highest heat-transfer factor. Orig. art. has: 4 figures and I formula. ASSOCIATION: Ural'skiy politekhnicheakiy institut im. S. M. Kirov (Ural Polytechnic Institute) SUBMITTED: l8Mar63 DATEAGQ: 15May64 ENCL: 00 SUB CODE: PR,GG NO REF SOV: 004 OTHER: 000 Card Z/7, ACCESSION NR: AP4041051 s/olzo/64/000/003/0 15~",'61 ~5 AUTHOR: Skripov, V. P.; Cherepanov, V. N. TITLE: Instrumeni for determining the range of sensitivity of an overheated liquid to radiation SOURCE: Pribory* i tekhnika ekBperimenta, no. 3, 1964, 192-195 TOPIC TAGS: bubble. chamber, bubble chamber radiation sensitivity ABSTRACT: An instrument (see Enclosure 1) provides for floating up tiny I droplets of the test liquid in another liquid. In small flask 12, a small amount of the test liquid is emulsified in sulfuric acid by means of a magnetic stirrer 1. Via capillary Z, droplets of 0. 1-0. 4-mm enter a glass tube I I filled with sulfuric acid and float up. A copper shell 4 has heater 8 at the top which provides for a uniform temperature rise along the acid column. Glass jacket 6 stabilizes the heat loss conditions. Isotopes Co'60, Zn65, NaF11 , and the gamma-bremsstrah1fing from a 6-Mev betatron were used as radiation sources. Without irradiation. an droplets burst within 2 mm (temperature interval t 0. 5G) , With irradiation, part' .7-7 ACCESSION NR: AP4041051 of the droplets burst at a lower temperature. These substances were tested: n-pentane, n-heptane, pernuoroheptane, pernuoropropylpyridine. Sensitivity temperature limits for these substances are reported. "The authors wish to thank Ye. N. Sinitsy*n for his help In carrying out a few of the experiments. They are also grateful to W. B - Delone, V. I.. Lyapidevskiy, and G. S. Voronov for discussing some points, and to S. V. Sokolov for lending the fluorinated- I'liquids. " Orig. art. has: 3 figures'and I table. ASSOCIATION: Ural 'skiy pblitekhnicheskiy institut im. S. M. Kirova (Ural Polytechnic Institute) ASUB11ITTED: 02jul63 ENCL: 01 SUB CODE:. IM NO REF SOV: OOZ OTHER: 002 ACCESSION NR: AP4040376 S/0185/641009/004/0393/0400 ,AUT11OR: Skripov, V* F. ndary of its Stabilityffixth Con-; .TITLE: overheated liquid near the bou .ference on the Physics of Liquid State of Matter hold in Kiev in 19637 SOURCE: Ukrayins'ky*y fizy*chny*y zhurnal, v. 9, no. 4,-1964. 393-400 TOPIC TAGS: overheated li4uid stability, metastable state, over- -saturated vapor, thermodynamic stability, Van der Waals equation, ;11impan equation ~.ABSTRACT: The attainable overheating of liquid under pure conditions! iis associated with the kinetics of the process of forming nuclear centers of the vapor phase. However, there is a thermodynamic bound-~ !ary of the stability of liquid (spinodal), defined by the equation (DP/DV)T - 0. A method is proposed for approximating this boundary using the experimental data on the attainable overheating of liquids. This is important for making the equations of state more precise so that they can correctly describe the properties of the substance in the region.of metastable states. As an example, the Van der Waals ~Card 1/2 ACCESSION NR; AP4040376 equation was used to obtain some information about the state. It was found that since the derivative (dp/dT)sp is positive, the possible changes of molecular volume of the liquid at the boundary of stability are within limits of 1/3Vk< Vsp< Vk, where Vk is critical volume.of .substance and Vspis.the moleculw volume of liquidonthe spinodal. This range of volumes coincides with the evaluation of the region accepted :in literature in which a liquid can exist, at least for simple sub- stances. The volume-of liquid on the spinodal first increases slightly with a rise in temperature, then increases faster and faster until .the critical temperature is reached. For comparison the Himpan equa- tion of state (an equation of the Van der Waals type with more precise: coefficients) was calculated for n-pentane. Comparison of the results. obtained from this calculation and the processed experimental data for: the attainable overheating of n-pentane at different pressures showed that good agreement-was obtained. Orig. art. hast 8 formulas and 5 figures. ASSOCIATION: Ural'skiy politekhnicheskiy institut, Sverdlovsk (Ural Polytechnic Institute) :SUBMITTED: 00 DATE ACQ., .13May*64 ENCLt 00, SUB CODE: GP NO REF SOV: 004 OTHER: 002 .Cord 2/2 SKRIPOV, V.P.; YEPMAIOV, G.V. Pressure dependenl-e of ti.- j'it,-mate qupfzrheating of liquids - ~l 1. L.Illir. fiz. khirr. 39 no.2-.~96-~04 F 64. (MIRA 17-.;) flk -a--'.qkiy p,-,,2itekhnicheskJy instilut imeni Kirove. - UT ~ -1 L 23042-65 04T (m) IjP(C) ACCESSION 1JR: AP5002311 S/0053/64/084/004/0727/0M AUTHQR: Skripoy V. tf-M, Ye _-N J. f~ARL TITLE; Experiments with superheated liquid SOURCE: Uspekhi fizichoskikh nauk, v. P)~, no. 4~ 1964P 727-729 TOPIC TAGS: superheat, methane, pentane, nucleate boiling., bubD ~ec Mb-lar-1 ABSTRACT: The author indicates that the question of degree of superheat attain- able in a vapor is not discussed in textbooks, and,the very possibility of a. prolonged existence of highly superheated liquids is not well known) so th'it it would be useful to introduce appropriate laboratory experiments in the physics curriculum. Apparatus used to this end at the Physicatechnical Department of them Ural Polytechnic Institute, both for research and for student laboratory exer-. cises, is described. The apparatus is shown in Fig. I of the enclosure. It is used to superheat a saturated hydrocarbon of the methane series in the form of small droplets imbedded in sulfuric acid. Droplets of diameter 001--0.5.mm are superheated and made to float upward in sulfuric acid. When a definite tempera- tMe is reached, the superheated droplets become unstable and evaporate ex- Ccird 1/3 L 23o42-65 ACCESSIO14 VR: AP50023U plosively, with the resultant characteristic, noise clearly heard in the lecture room. By introducing a thermocouple at the position of the explosion it is pos- sible to determine with sufficient accuracy the corresponding temperature ofthe medium and consequently the temperature of the droplets. More detailed informa- tion on the attainable superheating of the liquid can be obtained by bringing the droplets to rest at a given temperature. The procedure for this is alsolde- scribed. The apparatus can also be used to determine the lifetime of droplets under the action of ganma radiation in the sensitive zone of a superheated liquid4 Experiments of this kind are similar to investigations of.the density of tracks of ionizing particles in bubble chambers. The,performance of such an experiment, is described. Orig. art, has*. 2 figures. ASSOCIATION: None SUBMITTED: 00 ENCL: 01 SUB CODE: GPI TiR RW SOV: 005 OTMM: 001 Card 2/3 L 23o42-65 ACCESSION W - rig.!: i 6rd SKRIPOV, V.P. A sup-erheated liquid near the limit of its stability. Ukr. fiz. zhur. 9 no.4:393-400 Ap 164. (MA 17:8) 1. Urallskly politekhnicheakiy inatitut, Sverdlovsk, SKRIPOV, V.P.; SDIITS)W, Ye.N. .L Experiments with superheated liquids. U-1p. fiz. nauk 84 no.4: 727-728 D 64 (MIRA 18:1) L 46104-65 E14'r(l)/EPF'(c)/EFF(n)-2/EW(m!/EPR Pr-4/Ps-4/Pu.-4 T4W ACCESSION RR.- AP5009555 9/mT/65/OW/Ml/0115 AUMORI Pubrovina, E. N (Sverdlomk); Skripovp V,P* Sverd2o"k) near i i7r_Rf~_A p4lat of carbon dimdde TrM: Convection and beat exchange SOURCE: Prikladnoy mekbaniki Les 6y fizW- p no.- I,,- 1965t 115-119 TOPIC TAGS: heat exchange, convection, carbon dioxide,, critical point, convective beat exchange ABSTRACT: Convective heat exchange of carbon dioxide with an electrically- heated platinum wire was investigated in horizontal and vertical chamels* The coeffi- cient of heat exchange and the coefficient-of convection were determined. The criterial equation determining the currents of convection vas,verified. 7fie con- nection between the conditions that.ens=e the development of convection and cW- acter of heat exchange vaa checked for a wide range of states of the aubstance. Particular attention van paid to states lying on both sides of the line of trans- critical continuous trawitions through the region of decreased thermo4mamic. phase stability. Me experimental set-up is shown in Fig. 1 of the Eaclosure* During the course of the experiments meawxr==ts vere made of the temperature# Card L 4616h-65 kPOW555 Fig. -10 sift-lup ~Ccro 3/4