SCIENTIFIC ABSTRACT SIPYAGIN, A.S. - STRAKOV, L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001550820007-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 24, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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A A:,TCA~; j, C7,' C,
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T ""I E
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Tek.hnoloviy2 Frakhmnlopatochnogo Prcizvcdstva. (Technolci-y of Starch-
-1,1n:r nroduction). 1~ockva, Pishchepromizdat, 195C-
L,~3 p. Illus., Tables, DiaErs.
P-11 Head of Title: A. S. Sipyagin, etc.
"Literaturall- u. L-,:~o-(L21)
So:
722-31
.Se.

KRAVCHENKO, S.F.; THnHAC.UVA, A.A.; SIPYAGIN, iL .S , professor, retsenzent;
o- -, -~-M 4
BURM.iUl, M.Te. , inzhener, retsenz-alr13 PRITTKINA, L.A., mdaktor; MEDVE-
IDEVA, L.A., tekhnicheakiy redaktor.
[Technochemical-control and calculation of the prod-action of corn-
starch products, Tekhno-khimicneskii kontroll i uchet proizvodstva
kral-,hmaloproduktov iz kukuruzy, Moskva, Pishchepromizdat, 1954.
162 p. (MIU 8:1)
(Cornstarch)

- SIPYAGIN.--A.S.. Prof.; SIDOROVA, Ye.K., kand-tekhn.nauk
On the theoretical yield of sirup. Trudy TSNIIM no-3:283-291
'5 9- (MIU 13:9)
(Sirupe)

9/02 60/000/009/005/006
B01 5YB058
AUTHOR: Sipyagin,, L. A
TITLE: The Plants of the Stalinskiy sovnarkhoz (Stalino
sovnarkhoz) Do Not Comply With the VOCT (GOST Standards)
PERIODICAL: Standartizatsiya~ 19609 No. 91 PP- 51 - 52
TEXT: After the 21st Congress of the CPSU. many changes were made in
the plants of the Stalino Economic Rayon for the purpose of increasing
produn,tion and raising the quality. The biggest installation in the
world for continuous steel casting was put into operation at the
Stalinskiy metallurgichaskiy zavod (Stalino Metallurgical Plant 9 a
calcining process in quaeiliquid charge was introduced at the Nikitov-
skiy rtutnyy kombinat (Nikitovka Mercury Kombinat), production of heavy
automatic lathes of the type K)K-36 (KZh-,36) and KA-37 (M-37) as
well as K >R-,25 (M-25) was started at the Kramatorskiy zavod
tyazhelogo atankostroyeniya (Kramatorsk Plant for Heavy Machine Con-
struction and the production of a new rotary excavator with an hour
output of looo m3 was started at the Stalinskiy mashinostroytellnyy
Card 1/4

The Plants of the Stalinskiy sovnarkhoz 5/026/60/000/009/005/006
(Stalino sovnarkhoz) Do Not Comply With B015/BO58
the POCT (GOST Standards)
zavod im. 15--letiya LKSKU (Stalino MachLne Construction Plant imeni
15th Anniversary LKSUU). It was however2 established that some plants
of the Stalino sovnarkhoz do not pay enough attention to quality-qAand
the activity of thes4 plants was therefore investigated by the Stalin-
skaya gosudarstvennaya kontrolinaya laboratoriya po izmeritellnoy
tekhnike (Stalino State Control Laboratory for Measuring Technology).
The deficiencies established thereby are mentioned in the present paper)
and it -is stated that a deviation from the standards laid down is "main-
ly the reason for a deterioration of quality. The following plants are
mentioned and criticized: Konstantinovskiy zavod ogneupornykh izdeliy
"Krasnyy Oktyabr" (Konstantinovka Plant for Refractories "Krasnyy
Oktyabrl"), YasinovJ-s-klyzavod gornoprokhodcheskogo oborudovaniya
(Yasinovataya Plant for Mine Sinking Equipment), Slavyanskiy armaturno-
izolyatornyy zavod im. Ar+iim-a--(~ra-v-j~in,-sE--Pl-t-ti-ngs- and Insulator Plant
imeni Artem), Khartsyzakiy trubnyy zavod (Khartayzk Tube Plant)9
Zhdanovskiy zavod "Tyazhmash" Zhdanov "Tyashmash" Plant) and Chasov-
Yarskiy kombina".- ogneupcrnykh izdeliy (Chasov Yar Kombinat for Refrac-
tories),. The plants neglaot the following standards in the specification
Card 2/4

The Plants of the Stalinskiy sovnarkhoz 3/028160/000/009/005/006
(Stalino sovnarkhoz) Do Not Comply With B015/BO58
the POCT (COST Standards)
of drawings: "System of Administration of Drawings" and "Drawings in
Machine Construction". A change of the OCT(OST) 10210-40 standard takes
place at the "Krasnyy Oktyabr"I Plant and there is no OST NKTP 5853/140
standard "Methods of Measuring the Blunting of Angles and Ribs in Re-
fractories" at that plant. There are various inaccuracies in the tech-
nical documentation of the Yasinovatays, Plant, with reference to
GOST 977-53, GOST 1284-45, BH-46-51 (VN-46-~-51); in some a.;:awings, for
example, the weight of individual parts is not mentioned OK1-13-0101
(DKI-13-0101), AK4-148 (DK4-148)),,some drawings of bushes of the type
ARI-0212 (DK1-0212) and lids of the type AKI-0206 (DKI,-0206) are used
without introducing the essential modification; technical references
for the crusher of the type AA ~-lM (DDZ-lM) are missing. At the Plant
imeni Artem) articles are produced according to a modified GOST 2634-44
standard, instead of the valid GOST 2634--59 standard, and certain notes
are missing in the drawings for suspension insulators of the type
M-4-5 (PM-4-5)- Furthermore, technological discipline is not kept up
in the plants being criticized, i.e.2 the production process is modified
arbitrarily, and the quality of production is thus impaired. At the
Card 3/4

SH M FAYNt F.I.; SIPYAGINq L.A.
Cooperation of a state testing laboratory and basic organisations.
Standartizataila 25 no.3.-38-39 Mr 161. (MIRA 3.4:3)
(Standardization) (Testing laboratory)

sci -
-1
5
D

SIPTAGIN, Vladimir Aleksandrovieb,; SACHKOV, Aleksandr Fedorovich,,
HMM. 7-H.. red. izd-va.; ISLENTITEVA.
BARON, L.I., red-.; S
F.G., tekhn. red.
[Dust elimination in mines; a practical handbook] Obeepylivenie
atmoofery rudnikov; praktichaskoe rukovodstvo. Moskva. Goo.
uauchno-takha. izd-vo lit-ry po chernot i tsvetnoi metall4rgli,
1958. 4oo p. (MIRA 11-12)
(Niw dust)

SrOGNIY, Nikolay Ivanovich;- SMAQI~,_ Vk., otv. red. j YKROKHIN, G.M. p
red. izd-va,- IWINSWA, G.M.,, tekhn. red.; SABITOV, A., tekhn,.
red.
[Analysis of mine air] Analiz rudaichnogo vozdukha. Moikva, Goo.
nauchno-tekhn. lzd-vb lit-ry po gornomu delu, 1961. 226 p.
(miu 14: n)
(mine gases) (Air-Analysis)

--'-'777777777-
L 17p~~-6~ E`NP(j)/BPF(C)/EWT(m)/13DS s/o62/63/000/004/009/022
~~-sY- Pc-4/--'Pr-4 Wwvj
AUTHOR: M409-Y4j-9?, I-# Khananashvili, L. Mo. and
Simagina. M. A*
TITLE! On the condensation ofo( .40 -dih ox eth iloxanes th 1,
ydr.q
~ _yj s
3-diaceto-1, 3-dimethyl-1, 3-dip-fieiijddii1A'6~a-ne"
PERIODICAL: Akademiya nauk SSSR. lzvestiya. Otdeleniye kbimicheskikh nauk.
no. 4, 1963, 651-654
TEXT: The synthesis of 3-inear pqjy!~ers by the reaction of polycondensa-
tion of oligomers of the dimethylsiloxane type with the hydroxyl groups at the
and of chains with oligomers containing the acetate groups. for example. 1. 3-
diacetoxy-1. 3-dimetbyl-1. 3-dipheyqldisiloxane was of interest to the authors.
The reaction of alpha, omega-dichloromethylphenylsiloxanes with acetic anhy-
dride was studied and several alpha, omaga-diacetoxymothylphorqlsiloxELnes were
synthesized. The condensation between alpha, omega-dihydro.Voctamethyltetrasi-
loxane and 1.3-diaceto.V-1, 3-diphenyldisiloxane was conducted. The polymer
formed has a higher vitrification temperature (-530) than the polymer based on
Card 1/2

L ii7o63-63
On the condensation of .....
5/062/63/000/004/009/022
heptamethylphenyloyclotetrasilw=e (400). There are 2 figures. The 2
English-language references read as follows: W. H. Davdt, J. F, Hyde q J. Amer
Chem. Soo., 74, 386 (1952); P. George, L. Sommer. F. Whitmore. J. Amer. Chem.
Soc.. 75. 1585 (1953).
ASSOCIATION: Institut tonkoy kbimichaskoy tekhnologii im. M. V. Lcmonosova
(Institute of Fine Chemical Technology, imeni M. V. Lcmonosov)
SUEMITTEDs June 15, 1962

ANDRIANOV, K.A.; SIPYAGINA, M.A.; GASHNIKOVA, N.P.; FTOLOVA, Z.M.
Synthesis of 0e, W -d i sod iumlqdro)qrme thylphenyls iloxanes and
o~,-sodiumhydroxy-6)-t,rimethyl(triphenyl)siloxymethylpenylsil-
oxanes. Izv. AN SSSR. Neorg. mat. I no.9:1441-1446 S 165.
(MIRA 18ill)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologil imeni
Lomonosova.

-~~Cc -NR.AP6019547'---(j-\-~~- -SOURCE, CODE: UR/0190/0'6/008/006/1113/1116
AUTHORS: Andrianov, K. A.; SlpXagina M. A.
A- 7
ORG: Moscow Institute of Fine Chemical Technology Im. M. V. Lonorwsw;,~
(Moskovskiy institut tonkoy kfilmicheskoy tekhnologii) -. -
TITLE:_ PolyM.grizatipri of oc tamet hy leg clotetrasi loxane'lin the preaencvjt~.~
Of CL, O'di-sodiumhydroxymethylphenylailoxaneaI
SOURCE: Vysokomolekulyarnyye soyedineniya, V. 6, no. 6, 1966, L113a-ual
TOPIC TAGS: polymerization, siloxane
ABSTRACT: Polymerization of octamethyleyelotetrasi.loxane--_Ilaaz-begn
carried out in the presence of Q. w.-disodiumhy.dr xymethylphenylsilazaneo,.-
generally described by: NaO[(CHj) (C6H.) SiO]fNg , where x - 39 6, and
and conditions for the synthesit of dimethylsiloxanea4with a high
average molecular weight have been found. It has Lt the
average molecular weight of,oolymers decreases as the distance between
the terminal groups of the catalyst a,ld-disodiumhydroxymethylphenyl-
siloxane increases. Orig. art. has: 2 figures and 1 table. (Based on
authors' abstract]
SUB CODE: 07/ SUBM DATE: llJun65/ ORIG REP: 007/ OTH REP: 009/
-A 1 /1 AAC 134.L4-70 A
4

OD
11487
S/079/61/031/001/021/025
B001/B066
AUTHORS: Andrianov, K. A., Ugarova, T. A., and-_.~iyagina, M..A.
TITLE: Some Organosilicon Liketodicarboxylic Acids
PERIODICAL: Zhurnal obshchey khimii, 1961, Vol- 31, No. 1, pp. 234 - 238
TEXT: Following the paper of Ref. 1 on the acylation of organosilicon
compounds,-the authors in the present paper studied the synthesis of
organosilicon diketodicarboxylic acids. Phthalic and maleic anhydride
were used as acylating agents, and methyl-phenyl-siloxane groups were
introduced into the molecule of diketodicarboxylic acids at the same time.
When changing the ratio of the acylation product (I) to methyl-phenyl-
dichlorosilane in the hydrolysis process, organosilicon diketodicarboxyl.ic
acids resulted, which contained X methyl-phenyl-siloxane groups (X - 1, 2, V~
3, 4, 5 or 10). These acids are well soluble in alcohol, acetone, ether,
benzene, toluene, CC14, and chloroform; in unpurified and purified state
they are viscous, transparent liquids, and do not crystallize even on
prolonged standing at room temperature. Their viscosity is related to the
number of methyl-phenyl-siloxane groups in the molecule; it incraases with
Card 1/3

$8437
Some Organosilicon Diketodicarboxylic S/079/61/031/001/021/025
Acids BOOI/BO66
the number of these groups. Composition and structure of the resultant
acids were confirmed by chemical and spectroscopic analysis. Diagram I
gives the infrared absorption spectrum of diketodicarboxylic acids with
X 10 in the molecule. The vibration frequencies correspond to the groups
- Si(450 cm- and (500 cm- Si-CH (815 cm- 1
3
S (855 Cm -1 OH(936 cm -1 ), Si-00036, 1072, 1088 cm- 1
4,FH 3 ) 2 1
COOH(1285, 1306 cm- C-0(1678, 1700 cm- ). In the cohydrolysis of
compound (III) with methyl-phenyl-dichlorosilane, acids were formed with
X methyl-phenyl-siloxane groups in the molecule (X = 1, 2, 3, 4, 5, or 10).
They are viscous liquid products well soluble in the above solvents. The
following structure is confirmed by ultimate analysis and their infrared
spectra: CH3 C6H CH3
1 1 1
HOOCCH= CHCC 6H 4CH25i - Isio x - bl(;ki 2u6l'4' CH=CHCOOH
0 CH3 CH3 CH3 0
Card 2/3

88487
Some Organosilicon Diketodicarboxylic Acids S/079/61/031/001/021/025
BOO1/B066
Diagram 2 gives the infrared absorption spectrum of diketodicarboxylic
acid (IV) with X - 3 in the molecule; this spectrum discloses the presence
of the following groups in the compound:
_Si(450, 1127 cm- 1) 1 CD (1155 cm-1), Si -CH 3(798 cm-1
si-(CH 3Y 842 cm-1), OH(940 cm-1), SiO(1040, 1090 cm-1), COOH(1304,1328c3n-ll
C= o(1661, 1698 cm-1). There are 2 figures and 1 Soviet reference.
ASSOCIATION: Vsesoyuznyy elektrotekhnicheskiy institut imeni V.I. Lenina
(All-Union Electrotechnical Institute imeni V. Lenin)
SUBMITTED: February 8, 1960
Card 3/3

SMYSLOV, N.I.; SIPYAGINA, M.I.; KRASNUSHKIN, V.V.; LEVIN, M.N.
[Combined contact-tower process for sulfuric acid manufacture]
Kombinirovannyi kontaktno-bashennyi protsess polucheniia ser-
noi kisloty. Moskva, 1962. 39 p. (MIRA 16:2)
1. Moscow. Nauchnyy institut po udobreniyam I insektofungisi-
dam. 2. Laboratoriya bashennoy sernoy kisloty Nauchnogo instituta
po udobreniyam i insektofungitsidam imeni prof. Ya.V.Sa ylova
(for Smyslov, Sipyagina).. 3. Gosudarstvennyy institut po proyek-
tirovaniyu zavodov osnovnoy khimicheskoy promyshlennosti (for
Krasnushkin., Levin).
(Sulfuric acid)

S/062/62/000/008/007/Oi6
B117/B180
AUTLHORS:
TITLE:
FEAIODICAL:
Andrianov, K. A.9 and 4~
Synthesis of a,w-dihydroxy-methyl-phenyl siloxanes and their,
reactions with silicon tetrachloride and tetrabutoxy titanium
kkademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 8, 1962, 1392-1395
TEXT; a,(j-dihydroxy-methyl-phenyl siloxanes were synthesized by
hydrolyzing pure a,G)-dichloro-methyl-phenyl siloxanes. At -50C, the
following were obtainea from an ethereal solution of a,&)-dichloro-methyl-
phenyl siloxanes with 4% aqueous caustic soda: -a,u-dihydroxy-1,3-dimethY1-
1,3-diphenyl diBiloxane, m-P- 770C, 84.7% yield; a,G)-dihydroxy-1,3,5-tri-
methyl-1,3,5-triphenyl trisiloxane, 76.1% yield; a,O-dihydroxy-1,3,5,7-
tetramethyl-1,3,5p7-tetraphenyl tetrasiloxane, 74-5% yield. Cross-shaped
compounds with a silicon atom at the center and hydroxyl groups at the ends
of the arms were obtained by reacting (excess) a,w-dihydroxy-methyl-phenyl
siloxanes with silicon tetrachloride at 230C in the presence of pyridine:
a,(J-dihydroxy-lt3-dimethyl-193-diphenyl disiloxane gave tetracid-(3,5i-di-
Card 1/2

B/062/62/000/008/007/016
Synthesis of a,G)-dihydroxy- B117/B160
methyl-3,5-diphenyl-disiloxane-5-hydroxy) silane, (49. e/o.yield); a,w-di-
hydroxy-1,3,5-trimetliyl-1,3,5-triphenyl trisiloxane gave totracid-(3,5,7-
trimethyl-3,5,7-trihydroxy-trisiloxane-7-hydroxy) silane, (44.2~j yield).
Croes-shaped compounds with a titanium atom at the center were obtained
by reacting a,o-dihydroxy-methyl-phenyl siloxaneB with tetrabutoxy
titanium at 400C in vacuo, (1 mm Hg): tetracid-(3,5-dimethyl-3,5-diphenyl-
disiloxane-5-hydroxy) titanium, 96-5% yield; tetracid-(3,5,7-trimethyl-
3,5,7-triphonyl-trisiloxane-7-hydroxy) titanium, 95.2% yield. There is
1 table.
ASSOCIATION: Institut tonkoy khimicheskoy tekhnologii im. M. V. Lomonosova
(Institute of Fine Chemical Technology imeni M. V. Lomonosov)
SUBMITTED: February 1?9 1962
Card 2/2_

ANDRIANOV, CA.;, KLIEGVA., M.I.; KHANANAUVILI, L.M.; SIFYAGINA, M.A.
Condensation of&,W-dibydroiymethy.Isi-lox'anes with 43-diacetoxy-lj3-
dimethyl-l,,3-dimetbyl-I.,3-diphanyldiadloxane. Izvo AN &WR. Otd.khim.
44uk n0-4:651-654 Ap 163., (MIRA 16:3)
3~1 Institut tonkoy khimicheskby tekhnologii im. M.V.Lomnosova.
(Silicon organic compounds) (Folymerization)

FCLONUXIY, Mikhail Iaaakovich; IX6.%CHINSKIY, Tladimir Grigorlyevich;
SIFYAGINA, Z.A., otv.red.; IMHTIYZTA, P.G., tekhn.red.;
LOMIrJU ' L.K., tekhn.red.
[Hole boring in underground mining] Buranie shpurov I akvazhin
pri podzemoi dobyche rud. Moskva. Gos.nauchno-takhn.isd-vo
lit-ry po gornomn delu, 1959. 225 p. (KIRA 13:2)
(Mining engineering)

11.
"A Sui7f 7,L.,ticr i'c r I ~~ ~ rcv, -,F th,- C-1 en-rinc of' T" C~nC.Mj',7,ej'S'I. T-,. 111 Vol. 3, No. 3,
-.-- - I-C . I z .9
I'l-rch J-1.953, Fraha, Czec*I--cSIc-,a'-.-ia,j.
SC: Ecuthly List of EaOt ~--',Ircpean Accesrdcrs, LC, Vol. 3, Nc. 555, KaY 1954, Unclassified.

STAUDY Miloslav; P2MS, Milos1wir; SR, Fmanuel,- SKARVADA, Ales
Hydro-e-natior. of Romashk2x-o crude oil. Ropa a uhl-ie 5 no.79.
205-208 J I I 'S 3 .
1. Vy-7kw-wy t:siAv- Kralovopolske strujimy, zavcdy chemickych
zarizeni, n.p., Brmo.

S~j P" i .
A further experimental road construction with a stabilized foundation.
P. 12, ( Silnice) Vol. 6, no. 7/8, JulY/Aur,. 1? 57, Praha, Czechoslovakia
SO: Monthly Index of East European Acessions (EIKAI) Vol. 6, i~io. u November 1957

y A
611 r.;.,t-xl:3t-ance ~f mye'lurra and' pulmonary
-tr.-.7t5r. Nowotwory 15 Ap.-Je 165.
1. Z I Klinlkl Chorob 1,lewnetruyeh Pomorskiej AM w Szczecinie
(Kiorownlk: doc. dr. mad. 13-regorezyk) i z 7akladu Anatornil
I
Uatalogicznej Pomor--k'e,l AM w Szczeclnie Wierownik: prof. dr.
v3d. K.

NEVAR, Jiri, inz., CSc.; SIR, Josef, inz.
Reinforcement of nondurable rDads with local material. Siln
doprava 3-1 no.7:2-5 963.
1-, Vyzkumny ustav dopravai (:t6r Posvar),
2. Silnicni vyvoj Brno (for Sir).

SADEK, Jaromir; SIR, Ladislav
Effect of suture thread on wound healing. Cas. lek. cesk.
91 no.27:786-790 4 July 52.
1. Z cbirurgickeho oddeleni nemocjice OUNZ v Ostrave 1.
prednosta. doc. dr. C. Vohnout; z chirurgickabo oddeleni nemocnice
KUNZ v Ostrove-Zabrehu, prednosta. doc. dr. J. Sejhar.
(WOUBS AND INJURIES,
healing, eff. of suture thread)
(SUTURZS,
eff. on wds. healing)

SOUREK, J.; SIR, Z.
Antigenic relationships between native culture filtrate of certaW rep-
resentatives of Yqcoblateria. Cesk. epidem. mikrob. imun. 8 n0-1:33-41
Jan 59.
1. UBtav epidemiologie a mikrobiologie v Praze Vyzkumny ustav tuberkulosy
v Praze. J. S., Praha 12, Srobarova 48.
(MYCOBAGTF&RIUM. culture
antigenic relationships between native culture filtrates of
certain Mycobact. (Gz))

add a volumewo gyms at
fluminium gad
Commun.. 195.1, 90 (4), 871-875.-Alurninium
Interkus irk the indirect cornpleximetric titrattion
of Fe with 1,2-diaminacycloliexane-NNNN'-tetra-
acetic acid (Chenta reagent) (1). Aluminium. as
well as Ti. forms a stable chmplex with I in a soln,
bufferedwitt yridincorwitfiliinixtureofpyriditxe,
TINH,Cl. All three tl. can b.
Mi. Z 4 1 9
Viermined singly in weakly alkalloo pyridine soln.
by the addition of an excess of 0-05M X the
unchanged I being back-titrated with 0-05 N ZnCl.
or ZnSO, soln.; Eriochrome black T is used as the
indicator. When the ions of all three metals are
present, Fell' can be determined if Al- a6d
are complexed by the addition of a 2 per cent.
soln. of NH4F. WATON

-71
Complexometrictitniffans(chelatometry) XU. IT-Di-
&MInnerclohe etrasce 'add as a 'vWu-.
al ga-MmLnatlaa of Iran, aluminum, and tl--
We 't. 134'. 'q, 4 R4
am.
~Sla= X.8,921t P%IAl VI-Autnui ttav
em. idy 49, 679-M1935);,
tZ : I
.410 salt of 1,2-diamixocyckke=x4r-:
f
,VUE,,4,2[,fzDs- a
N. N, N'. ar;d (1) nas avd [a the Indirect.
.compitiontetric detn. of Fe, Al, and Ti based an the thra-I
-tion of the excessl In pyridinesoln. with ZnCls. Vetn.of:
Ft und Al or Fe and Ti, resp., cao be carried out after 3creen-
iuji Al or Ti with NH4F. To det. Fe, Al, or TI, add to an
acidic sample an axass of O.O5Af 1, dit. to 150-M ml., add
p)edine or a pyridlne buffer droewise to a slightly:addic
reaction, and titrate the excess of I sith 0,05M ZUC12 (with
Edoebrome Black T as indicator) until violet to tied color.;
To wxftn Al or Ti. add to the sample 15-20 ml. 2% NH4F-
to maintain the slightly acidic reaction, then excess 1. dil.
to 200-300 trI., and contiuue as described above.
Ru.#k~k

J
,,,;in tic
wMintitf. .1 c sfu-IAMWOE-muelma, Lan XVI..-'r)c-'
it titanium.
Uen6k Air and R" I (V Ve--tec,
YzK. ustav met
I'M); cl, A 50,
314&~Fe, At. and Ti weir delM, (I iQ, with
solos. bi:
j( pyridinewhich increa"d the stability of Ti and Alcoropfcxr~
nates and prevented the Interfering infittencr of Fe rotn-,
plexonate on the Indicator. The excess 4 (11-Na ethylene-
diatnincletroacetate (1) wai bvelt-titrated ivith O.Uf Zn('I,
itrid Critichronic T or with 0~5M CuWj iInd PyrocatLvho
Violet as indicator. Fe or Cit was Md. fit the presence tit
,At and Ti, provided these were masked with NJI,F. The
methocis dmribed were successfully applied tit the ajialy3is
Icruls, Otliermcttds,wittitlieexci:pti.11,~f
Ali ")Yd5'-"1nPa~' lis, interferfti anti had to bL remlived by
c it
PpEn.. us hydroxides. XV111. Determination of nickel
and copper in cobalt and its salts. and
Rudoff Plibil (Pharm. RcsLareh liest.. ]bid.
5:M--U.-Aftc,i- remi-ing IN "'11K 0 t-0 kup I'! F. C") by
Goldstehl's luctlTrAl C.A. 48, 9:.CKM) (tic filtrate
is made slightly acidic with HCI (pli &-6), OAMN I athkil, -
and the excess with 0.05N Nfg,'iO*, After additig 2
rul. 30% 1110t and 0.2-1),F) g, XCN the liberated I is litrated
with MgS04. The same procedure is uscil in ilvtg. total
Ni and Cit. Cu is deld. in a similar way %vid- 0.()5N 1,2-
Ii * ocy0obexandetrancetic acid (It) (C.A. 40, '~Mfl-
~,a
't,%tent (if Ni is calcti. frnm the difference between eon-
sit lotion qf I and 11. L. J. Ilrb5111;L-~1

-7-
CZECHOSLOVAKIA/ iLnalytical Chum-,.str.,, - Analysis of Organic
Substances
G-3
Abs Jour Referat Zhur - Khimiya, No 4, 1957, 12144
Author Sir Z., Komers R.
Title Oft4anosilican Compounds.
Organosilicon Compounds.
Linked to the Silicoa.
VI. Determination of Silicon in
VII. Determination of Halogen
Orig Pub Chem. listy, 1956, 50, No 1, 88-93; 162-i63(Czech); Sb.
chekhosl. khim. rabot, 1956, 21, No 4, 873-879;
ic66-1c68
Abstract VI. A simple method was worked out for quantitative de-
t~~rmiziation of Si in organosilicon compounds (OSC). mi-
neralization of analyzed substance is effected by wet pro-
cedure with a iuxture of oleum or H2S04 and fuming H'103
With most OSC minQralization occurs readily, only lower al-
kyl silanes (in particular tetramethyl silane) exhibit con-
siderable stability. To avoid losses in the case of more
Card 1/3
CZECHOSLOVAKIA/ Amlytical Chemistry - Analysis of Organic G-3
Substances
Abs Jour Referat Zhur - KhimiYai No 4, 1957, 12144
volatile halogeiiated silanes,the authors recommend to
weig~i the latter in cooled pyridine. Determination of
Si is effected by acidiinetric method based on formation of
K SiF6 in acid medium. Use is made of mixed indicator
2 In or-
(methyl red and bromcresol green at a ratio 6-5).
der to obviate hycholysis oZ K2SiF, at high pH values it
is necessary to carry out the titrktion vith a small volu-
me of liquid being titrated and in a solution saturated-
with K ions. By the above-stated method the Si content
was determined in several hut7dred samples of osC with ve-
ry good results.
VII. The authors have developed a reliable method for de-
termination of halogen in OSC of the type R SiX4 n (R --
alkyl, aryl or hydrogen, X -- halogen). Thne dete-rmination
is carried out as follows: The substance is hydrolyzed
Card 2/3
CZECHOSLOVAKIA Analytical Chem:stry - kialysis of Organic G-3
Substances

chelatometry7
XVTLl TIl.- - - I-
I ;,uc, aluminturi
Chem r ...... 195d. 21 ,7_1 -in G~rr~n,
The -fallowing inethd& ore rec,,climendcd for -the
dualvdi ui Fe - Al - Cu afit~ys. Vit,-_olvc I g of alloy
in HBr t6 mi). add- KCI (:! gi and cvapvrat~ to
drvues:~ i~n e water b-.tL Djitscl-vc the rcsidu~ in
iou m;
!;ill,: t i't md "I (--i t -1,~-l 11.~ ind
dljut~ I" ill 11tIlli'll 11~1 ijll Q t,3 .11
EDTA 13ij !:11 pyl,dm- m.1; 3,14

5
ldc ~~ rat'. a tullbotr afiquot
i, 14 -4 1 th C uSO, -~lri I'
Nff,F ioli,~ (21"1 (15 ridt'. 1A)FA W ml, 'lat
pyllblit t'.01:111. 'and "w:kutmte -th Cu