SCIENTIFIC ABSTRACT SHVACHKIN, YU. P. - SHVALBE, K.P.
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CIA-RDP86-00513R001550320013-1
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
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August 31, 2001
Sequence Number:
13
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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Body:
L 10882-66 EWT W
-;CC NR, AP5028259
RM
SOURCE CODE: UR/0189/65/000/004/009
AUTHOR: Shvachkin, Yu. P. ;- Berestenko, M. K.;~ Boltyanskaya, 9.~ I.
ORG: Department of Organic Chemistry, Moscow State University (Kafedra organicheskoy
khimii--Mo-s-kovskogo universiteta)
TITLE: New pyrimidine analog of phenylalanine
SOURCE: Moscow. Universitet. Vestnik. Seriya 2. Xhimiy0no 4 1965, 92-93
TOPIC TAGS: alanine, amino acid, pyrimidine
ABSTRACT: The following synthetic paths are given:
A
1.4 00. 1'. -OH
Card
VOM-2-66-
ACC NRs AP5028259
f -COWN
The starting material used was ethyl~O -(2-pyrimidyl)pyruvate (11), which reacted
with hydroxylamine to form ethyl 4_ -oximino-.t*-(2-pyrimidyl)propionate (III). The
latter is then reacted with stannous chloride in an acid medium; this-single step
accomplishes the reduction of the ketoxime fragment and the saponification of the
ester gr -oup, and yieldsA -(2-pyrimidyl)alarhne (1). This new pyrimidyl amino acid
has very definite amphoteric properties. Authors thank Prof. M. A.-Prokof,ye!~ for-.
his interebt and attention to this wbrk, and are also deeply grateful to A. P.1,710 ~
Skoldinov for the tetraethoxypropane which he kindly supplied. Orig. art. has:k.,-r
SUB CODE: 07 SUBM DATE:' llJan65 ORIG REF,. 001 OM REF: 004
jw
Card 2/2
BELINKINq A.A.; BUKANOV, V.A.; ZOTIKOVq S.L.1 KATULIN, V.A.; SHVACHKI-Nk
A.F. ",.--- z.'a"Zop-
Substitution of plastic materials for metals. Mod. prom. 15 no.l:
54,55 Jai '61. (HIRA 14: 1)
1. Leningradskiy ordena Lenina mediko-instrumentalln" sayod
*Krasnogvardeyets.1 (DRUG INDUSTRY)
SHVACW,O, I., inzh.
Let's mechanize operations in quarries 7erving several collective
farms. Sil'.bud. 10 no.1:16-17 Ja 60. (MIRA 13:5)
(Ukraine--Quarries and quarrying--Zquipment and supplies)
BELOV, V.Te.; BILENKO, A.I.; SliVACHKO, M.S.; BRAILOVSKII, N.G.. inzhener,
redaktor; KHITROV, P.A.. TIMMMnkly redaktor
[Unit method of repairing freight cars] Uzlovoi metod, remonta
gruzovykh vagonov; opyt vagonnogo, depo, stantsii Likhobor7-Noskovsko-
Okruzhnoi dorogi. Moskva, Gos. transp. zliel-dor. izd-vo, 1954. 54 p.
(Railroads-Fraight-cars) (KUU 8:6)
I .. . I F - ~ 1 , -,I'. ;
,-7,1 * :.,, --,:nn"ivif- rtirport onert?tinn. Grs7hd.nv. 'If an.7:3-t
. . I . (KWIA
11 !1 .: -,I, otdeln aeroport.-.
. . (Aimorts)
--, SHVACHKO, P.
This is vital and useful. Izobr.i rats. no-12:32-33 D l6o.
(MIRA 13:22)
1. Sekretarl Ukrainskogo reepublikanskogo soveta Vsesoyuznogo
ob8hchestva izobretateley i ratsionalizatorov, Kiyev.
(Ukraine--Coal minse and mining--Technological innovations)
SHVAGHKOJ, P.P.
Gor;ference nP inventors and efficiency promoters. Tekst.prom. 20
no~3:90-92 Yx '60~, (MIRA 14:5)
1. Sekretarl Ukrainskogo reepul)likanskogo soveta Voesoyuznogo
obshchestva-izobretateley i rat6ionalizatorov.
(Textile industry-Technological innovatiofis)
ACC NR- AR-100,1107 souncE CODE: UR/016,9/66/000/0121VO25/VO25
AUTTIOR: Shvachko, R. F.
TIT LE: Fluctuations in sound and random inhomogenities in the ocean
SOURCE: Ref. zh. Geofizika, Abs. 12VI47
REF SOURCE: Sb. 2-y Mezhdunar. okeanogr. kongress, 1966. Tezisy dokl. M..
Nauka, 1966, 420-421
TOPIC TAGS: refractive index, ocean acoustics, acoustics, oceanography,
turbulent mixing, sound signal fluctuation, two thirds law, random inhomogeneity
ABSTRACT: One possible application of acoustics in oceanography rests on the
relationship between fluctuations in sound and random variations in sound velocity,
which are usually caused by temperature fluctuations in the ocean. These
temperature fluctuations, in turn, are due to turbulent processes in the ocean.
Thus, a relationship is established between the turbulence parameters and the
i statistical characteristics of an acoustical signal passing through a turbulent
medium with random inhomogeneities in sound velocity c (refraction index n-efc).
Card 1/4 UDC: 551. 463._?2
ACC N
': AR7004107
A study of this relationship in the Atlantic Ocean was made in 1961-1964 by the
scientific research vessels of the Soviet Academy of Sciences, "Sergey Vavilov"
and "Petr Lebedev". As a rule, recordings of the fluctuations in the amplitude of
a pulsed sound signal (which had been reflected from the ocean surface) were made
at the same time as direct measurements of fluctuations of the index of refraction.
These measurements were made using a practically inertialess instrument which.
measured small deviations (up to 10-1) of the index of refraction from the mean
value (equal to one), using a microphasometric method of measuring the sound
velocity of 2-mc frequency over a base several centimeters long. Slower fluctua-
tions of the index of refraction were measured with a velocity meter based on the
if sing-around" principle. Its sensitivity for a measurement time of one sec is
5 - 10-6. In order to make the transition from fluctuations of the index of refrac-
tion to temperature fluctuations, sensitivity values expressed in units of the
refraction index should be multiplied by 500% Both'the direct and indirect
measurements which were made (based on the statistical characteristics of
amplitude fluctuations in the acoustical signal) showed that Kolmogorov-
Obukhov's "law of two-thirds" for local isotropic turbulence, D.(P).-[n(P1)-n(_,*)j3-Cn'P'1',
Ps
is true for the structural function 'D.(P) of fluctuations in the coefficient of
refraction. Here, Cn is the so-called structural constant, and ~ P-1P1_P31 is
the distance between measurement points; the arrows in the equation indicate
Card 214
ACC N~:
This law is true within a scale range from
averaged va'ues of the set (o-- in time).
I to I-,,. If the internal scale 1 is determined by minimum dimensions of the
0 0
inhornorreneities which could exist for reasons of energy dissipation (in the ocean
I cm), then the external scale Lo is determined by the characteristic dimen-
0
!j sions of the mechanism of turbulence excitation. Measurements in the upper
mixed layer of the ocean (at depths of 20-40 m) showed that an excitation mechan-
ism exists which is capable of causing inhomogeneities with an outer scale Lo
ranging from several decimeters to several meters, with the magnitude of the
-structural constant C. - 10-4 u-' 0 Results obtained in processing
amplitude fluctuations in 25 kcps signals (wavelength ~-Ccm ) showed that when
the distance L between the emitter and receiver equals several hundred meters,
with the condition I(TL->LO prevailing, the transverse radius of the correla-
tion of sound amplitude fluctuations, following from theoretical considerations,
coincides in order of magnitude with the external dimensions of inhomogeneities
Lo' and the mean square value V relative to amplitude fluctuations agrees well
with the theoretical relationship:
V_3'CX-'L616L1j2. -
I Measurements of sound fluctuations at great depths (150-250 m), as well as direct
measurements of fluctuations in the refraction index at depths up to 1500 m,
L~.rd 3 / 4
ACC NR: A117004107
showed that the "law of two-thirds" was observed to apply to dimensions up to an
order of several tens and hundreds of meters with a structural constant value of
Under these conditions, at a frequency of 3 kcps
(wavelength )6-0,5 w and distances to several kilometers, when the
condition LZ4 prevails, the transverse radius of correlation of
I sound amplitude fluctuations coincides in order of magnitude with V_!_L , and the
I mean square value of relative amplitude fluctuations follows the relationship:
V_ CAX-4J12 LI 1112. ~2)
Thus, as may be seen from expressions (1) and (2), the Cn and Lo parameters of
turbulent oceanic mixing may be calculated from the measures mean quadratic
values of relative amplitude fluctuations in the sound signal and values of the trans-
verse radius of the correlation of these fluctuations.. [Translation of abstract]
[SPI
SUB CODE: 08/
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FOGE 1. 1 )Ya.M.; NADYKTO, B.T.; SIIVAGIIKO, V.I.; RYBALKO, V.F.;
KOROBCIIANSKAYA,
Catalytic oxidation of ammonia on platinum studied by the method
of secondary ionic emission. Dokl. AN SSSR 155 no.1:171-174 Mr
164. (WRA 17r4)
1. KharIkovskly gosudarstvennyy universitet im. A.M.Gorlkogo.
Predstavleno akademikom A.N.Frumkinym.
M
FOGELI) Ya.M.; NADYK110, B.T.; RYDALKO, V.F.; SHW"MiKO, V.I.; KOROBC11ANSKAYA,
I.Ye. -
Study of the catalytic oxidation of ammonia on plat-fnum by the
secondary ion emission method. Kin. i kat. 5 no.3:496-504 IV-
Je 164. (14IRA 17: 11)
1. Kharlkovskiy gosudatstvennyy universitet imeni Gor1kogo.
L23051-65 LWGQ)/ZWT(m)/,8
PF(c)/EPR/j3WP(0/EWP(b) Pr-4/p 4 IJP(c)
JD
ACCESSION NR: AP4047980 S/0076164/038/010/239712402
v)'-, Nadykio, B. T.(Khar'kov)j Shvachko, V.: I#
AUTHOR: M.(Xharlko
29
(Kartkov); R-Ybalko. V. F. (Kharlkov)
TITLE: Secondary Ion emission Investigation of the state of o
_MAen adsorbed on
a silver surface
SOURCE: Zhurnal fizicheskoy khimii, v. 38, no. 10, 1964, 2307-2402
IV
TOPIC TAGS- secondary oxygen ion emission, oxidation mechanism, silver-oxida4_..-
tioncatalyst, negative oxygen ion, positiveox gen ion
y
ABSTRACT: In order to study the mechanism of the oxidation process 6n a me-.
tallic catalyst (silver catalyst used:in ethylene oxidation) the.s'ta-te of the oxygen
adsorbed on the surface was determined. !The mass spectra of the secondary poI
tive and negative ions. formed by bombarding a silver ribbon with a primary. beam
of argon ions in an oxygen atmosphere were-studied. The,dependence of the.
intensity of the mass spectral lines on the oxygen pressure -and the ribbon temper--_-,'.~,*~~,.
ature was determined. -In the.20-500C range the oxygen adsorbed on the silve'r.,.
surface was partly atomic and partly molecular, and some of the molecular oxy-
Cardl2
L 23051-65
ACCESSION NR: AP4047980
gen was in the state of a negative molecular ion 0 The.statiiW the charge. of
2
the atomic oxygen was not determined. At temperatures above-:300C the effect',-
of the oxides on the silver surface on the secondary emission of oxygen ion .-
S
was insignificant; the latter were formed only.from oxygen adsorbed on the silver.,:-'
surface. Below 300C the surface oxides could be involved in the secondary emis-,.:~,
sion of oxygen ions~ but apparently to only a small extent. Thus if the oxygen in
the surface oxides on the silver plays a significant role in catalytic oxidation
reactions, the activity of the silver catalyst will drop at temperatures above 306Ci"~.,
"In conclusion we wish to sincerely thank 1. prof. A. K.: Vallter for constant advic'e'.-,,`-7
and interest in the work. Orig. art, has: 3, figures and 3 e4uations~
0
ASSOCIATION: Khar1kovskly gosudarstvienny*y universitet Im.- X# M. Gor1kog
(Kharkov State University)
-ENCL: 00
SUBMITTED: 170ct63
SUB CODE: GC, NP NO REF.SOV: 005 OTHER: 002"
Card 2/2
L 46183-65 M1T(1)/EWT(m)/EFA( Is )_2/zP1r(0)/LVA'(d)/EPA(w)-2 Ea(t)/NWP(t)/~
-1-JP( _JDAN
EWP,(b), Pab~10/Pr-l;/Peb, /W"-
0 T
UR/0020/6S/161/004/0896/ a
ACCESSION NR: AP5010839
ire
C
Nqdyktol,B. Twi, Folzelf pjao M.-
AUTHOR: Shyacbk!p Garger, K.
Kondratlyev, V. N
TITLE: The use of secondary ion emission f-pr investigation of.corrosi sea
on proces
on the surface of steel
SOURCE: AN SSSR. Doklady, v. 161, no. 4, 1965 886-888/
TOPIC TAGS: secondary emission, steel surface oxidation, irm pentacarbonyl,
ferric oxide, ferrous hydroxide, argon ion.beam.-steel corrosion.
ABSTRACT: The article presents preliminary results of a study of the processes
occurr va. -6
iniz.on.the-surfe of- steel -during -heating. in a cuum 5 x 10 mm Hg) and
'(in
made up of Ar ions accele
secondary ions versus the LUMPOL'aLt"M WJL UAW 04--=W-L OLZ'AF CM7~ 9XV%2&2* .&&I= LULIMMIA-0-n-
L4;c!!d 1/3
46183-65
ACCESSION NR: AP5010839
of ferric o4de on the steel surface',is due to oxygen in the residual gas. How-
ever at oxygen pressMs higherthan 2-10 mm Hg there -is no increase -in the in-
tensity of the Fe203 ion'beam, and therefore no increase In the oxide coating on
the steel surface. In the 20-5000 range, the rateof decomposition of ferric
oxide increases with temperature more rapidly than the rate of oxide formation;
which reduces the oxide coating. In the.500-8000 range this situation is reversed.
6 nsidered in rela-
and the oxide coatingincreases. The formati n of F~e(002 is CO
tion to the pressur .e of water vapo r. T he coating,o f the surface with Fe(CO)5 J*Ln'-
creases monotonically above 2000. A definite part in:,,the machanism,of formation
of iron pentacarbonyl is played by the carbon presentIn the steel; the oxidation
of carbon may constitute the first stage.of formation of-the pentacarbonyl. If
such is the case, the formation and evaporation of Fe(C0)5 should lead to the de-
carburization of steel. "We consider it.our pleasant duty to.thank Prof A.-K.
for a steady interest in this,% rk Oili
Vallter w0 i g., art. has: 3 fi
gures.
(Kharkov"__~
ASSOCIATION: -Kharlkovskl~ gosudarstve'Tmyy:,,tmi,~,exisitiet~- is. -Ail- M.
Go~!kogo
:.
,
State University)
Card 2/3,
tj
L 588Z2_65 EPF(c)
/EPF FPIVLWG(J)/EPA(w)-2/EWT(1)/19WT(m)/LVP(b)/EPik(,pp~
EWPM Pr-;4/Ps-4/Pu_4/Peb IjP(c) AT/jD/j(;
ACCESSION NR: AP5017281 ti/0181/651007/007/1944/195
is. 14
AUTHOR: S I.; Na kto, B,,T&*, Fog4-It','Ya. M,;--Vasyutin6kiy
hvachko, V.
-Kartmazov,
TITLE: Using secondary ion-ionic emissiotAfor studying the interaction of
with the surface of~niobium
SOURCE: Fizika tverdogo tela, 7,'no. 7, 1965, 1944-1951
TOPIC TAGS: ion emission, niobium, oxidation
_M
ABSTRACT: The metho4~,pf secondary,ion-ionic:emission was used to investigate the
composition of pxidesy*hich form-on the surface of niobium when it interacts with -14~~`i'V
oxygen. It was established.that in the temperature.range from.20 to 12000C the, tdl~w
L4
lowing oxides form on the surface of nioblum which is In an oxygen atmosphere ata g
-4 4;
pressure of approximately"10 mm of mercury: NbO, NbO2.. Nb203, and Nb205- In the-
temperature interval from 1200 to 20000C the surface of Nb*contains only NbO and
NbZ03. The corrosion wear of Nb results.1mm the'formation and subsequent evapora-
tion of NbO starts at 14000C and then-increases very rapidly with temperature, in.,
the 20- reac-~
-80010C'temperaturs range Nb02 undergoes decomposition according to the.
-gaseous. phase :,"In - c6ticlIP-1...
Nb02
tion. 4 NbO+ 0 with thi desorption of,~xygen into a
Card 1/2
`tk
;j"l -4 4
58872-65
. 0
.......
ACCESSION MR: AP5017281
irely greteful to A. K- Vaj~tsr:for hid constant,interest'in. the
sion, we are sincf
ig. art. has- 4 f gurea
work." Or
KfiiA6V
udarstvennyy uniVerbitet.14- 'Aa:~ H- Gorikog0'(
ASSOCIATION. Kharlkovskiy gos tp 5
State University)
UB'COD9
'
3
S
ENCL: ~00
4
SUBMITTED: 27HoV6
t
SOVI 003 PIVER: '001"
NO REF
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7
12
2
Card
-
-
Ya . M.
r 3 n s c n o s u ra e
me ,,,,I no.4-
P~C7-988 (MMA 18:5)
KharlIkov3kiy gosudarstv,innyy univ.-rsitn'. im. A.MGorlkor~o.
i In --tcber 6,
-PO"ELI, Ya.M.- NADYKTOr. B.T.5 RYBALKO, V.F.; KOROBCHANSKAYA,
U I
T.Ije.
Use of the secondary ton emission method for investigating
catalytic reactions between ammonia and nitric oxide, and the
decomposition of nitric oxide on platinum. Kin. i kat. 5
no.5042--c44 S-0 164. (MIRA 17:12)
1. Kharlkovsk-'y gosudarstvennyy universitet imeni GorIkogo.
ACCESSION NR: AP4009524 S/0293/63/00l/0()3/0414/0435
AUMIM: Vakhninl V. M.; Slan-idin, G. A.; Shvachunov., I. ff.
TITLE: The movement of charged particles in the field of a magnetic dipole,
considering enerE;y dissipation
SOURCE: Kosmicheskiye issledovaniya, V. 1Y no- 3, 1963, 414-435
TOKIC TAGS: magie-tic dipole, magnetism, charged particle., charged particle
motion., magnetic field., energy dissipation
ABSTI-LIXT: The authors have analyzed the mavement of charged particles in a
ma.r~.etic field by the phase plane method both in a conservative approximation and
'vrith considerattion of losses of their kinetic energy due to radiation, thus pro-
viding a qualitative picture of the influence of Idnetie energy -..csses on the par-
ticle trajectory. These losses vrere considered in the form of small dissipatioa
perturbations of the conservative approximation. The authors succeeded in aemcn-
strating the existence of certain critical trajectories,, at which pax-ticle seizure
by t:he magnetic field occurs eu arbitrarily small energy losses. (It is obvious
that at small, but finite, energy losses, seizure may also occur in the case of
other trajectories,, close to critical.) The phase plane method was found to be
particularly coavenient-when studying the movement of the particle in a c=plex
Card
POCESSIOIT IM: AP4009624
field containing a dipolar and harog
Y cneous, (external) ccmpcnent. The authors
considered cmservative appradz~-tions and their dissipaticx perturbatims for
three idealized situations: a) magnetic dipole with no external magnetic field
present; b) magnetic dipole in space with uniform magietic field parallel to the
ma~-;net*izatim vector of the dipole's magnetic field and located in its equatorial
plane; and c) magnetic dipole in space witli uniform magnetic field antiparallel to
the magietizatim vector of the dipole's magnetic field and. located in its
equatorial plane. The ana3,ysis was conducted in the ma'snetic plane of the dipole.
in the first case (movement of a charged particle in the field of a magnetic di-
-pole in the absence of an external magnetic field), the differential equation for
the "phase trajectory" off the moticn of the charged particle was discussed. Fol-
loi-ring this, "isoclines" and a "field of directicns" were ccnstracied in the phase
plane in a cmservative appro.,.imation. Phase trajectory behavior-mas ccnsidered
at as well as the trajectories of charged
L. large =1 small values of u and w.
particles in a magnetic field which correspmd to the phase trajectories,, both
vita and without consideration of energy dissipation. With fev exceptims, this
.5reatment was also followed in the case of the other two ideal hypotheses. Orig.
art. has: 19 figures and 43 formulas.
ASSMATI(XI: none
Card 2/~
L 49441-6 -tWT(I)/SWG(v)/FCC/EFC-4/UC(ti/EWA(h,) Po_4/P Pq.4/Pa
-Pi-4-, - GW-
ACCESSION WR: APS009654 UR/0293/65/003,/002'/0336/0346~~
e v D.; Shuridint G.: A Shalim
AUTHOR: Pletn
Shvachunov. 1. N,
TITLEs Dynamics of the-geomagnetie* trap and the origiii~ radiation.,,
0
belts
~SOURCE: Kosmicheakiye issledovaniya,, v. 3, n o.., 21 1965g 336-340
ell,
ar 'windN 'd
TOPIC TAGS I sol fiel ~magnetic_
geomagnatic
storm, force line, proton belt, electron*belt
by'jhelnter~
ABSTRACTS The boundary of the magnetoo-phere created
Iaction betvaen the solar windland the geamagnatid fiel&reaches a,
-radii on the d Elec-
distance of 16 terrestrtal ay side o U the,',eArth,
tric currento on the butAudary incre nce the tragnetic field theres
the night side the magitetosphere is very artetuderl. ,A part cla may
through the bonudzkry of the maqiie~osph,are because of..a
drift of Lhe particla Ln art asymmet).,ic wagnatic fleld* The physical,,
processes are atudlecl In a magnetic field fron parallels,470, , The'
regions permitting wid lixohlbiting paiticln motioti.'..aro- determinedg..
1-Card 1/2 T
L 65296-65 ~-EIT(l)/FCO/kM(h), GW.
26
AP502D992 UR/02D3/6
550-388 0 2
;AUTHORSt P SMIJ
letnevp Ve D.; Skuridin, G
q_Aq; V# Is
44155.
;TITLEt Dynamics of the geomagnetic trap and the ori
gin of eart~hl ?Sr~adiation to
'SOURCEs Geomagneti= i aeronomiya, v. 5 hoi 4P 626-644
.1965-0
;TOPIC TAGSt magnetic fieldv Van Allen beltj, magnetiolrapg.geomagnetio fieldv
!charged particle concentrationg magnetic Istorm, solair burst
44)
!ABSTRACT: The interaction of solar corpuscular streams41th the Reomametic field
lis discussed with explanations about the formation of.the.earthla- kagnotosphere and
Ithe mechanism of charged particle penetration.into,the magnotoopheree The scalar
potential of the geomagnetic field inside the earthlo.magmetoophere is eivressed in
~spherical harmonicst and the solar particle atream--geomagnetic field-interaction
described by the model shown in Fig* I on the Enclosureo In order to snai4ze:
;possibility of particle penetration.into the magnetosphere -the followIng equation
!is solved numerically
P 2y,
0