SCIENTIFIC ABSTRACT SHVACHKIN, YU. P. - SHVALBE, K.P.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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L 10882-66 EWT W -;CC NR, AP5028259 RM SOURCE CODE: UR/0189/65/000/004/009 AUTHOR: Shvachkin, Yu. P. ;- Berestenko, M. K.;~ Boltyanskaya, 9.~ I. ORG: Department of Organic Chemistry, Moscow State University (Kafedra organicheskoy khimii--Mo-s-kovskogo universiteta) TITLE: New pyrimidine analog of phenylalanine SOURCE: Moscow. Universitet. Vestnik. Seriya 2. Xhimiy0no 4 1965, 92-93 TOPIC TAGS: alanine, amino acid, pyrimidine ABSTRACT: The following synthetic paths are given: A 1.4 00. 1'. -OH Card VOM-2-66- ACC NRs AP5028259 f -COWN The starting material used was ethyl~O -(2-pyrimidyl)pyruvate (11), which reacted with hydroxylamine to form ethyl 4_ -oximino-.t*-(2-pyrimidyl)propionate (III). The latter is then reacted with stannous chloride in an acid medium; this-single step accomplishes the reduction of the ketoxime fragment and the saponification of the ester gr -oup, and yieldsA -(2-pyrimidyl)alarhne (1). This new pyrimidyl amino acid has very definite amphoteric properties. Authors thank Prof. M. A.-Prokof,ye!~ for-. his interebt and attention to this wbrk, and are also deeply grateful to A. P.1,710 ~ Skoldinov for the tetraethoxypropane which he kindly supplied. Orig. art. has:k.,-r SUB CODE: 07 SUBM DATE:' llJan65 ORIG REF,. 001 OM REF: 004 jw Card 2/2 BELINKINq A.A.; BUKANOV, V.A.; ZOTIKOVq S.L.1 KATULIN, V.A.; SHVACHKI-Nk A.F. ",.--- z.'a"Zop- Substitution of plastic materials for metals. Mod. prom. 15 no.l: 54,55 Jai '61. (HIRA 14: 1) 1. Leningradskiy ordena Lenina mediko-instrumentalln" sayod *Krasnogvardeyets.1 (DRUG INDUSTRY) SHVACW,O, I., inzh. Let's mechanize operations in quarries 7erving several collective farms. Sil'.bud. 10 no.1:16-17 Ja 60. (MIRA 13:5) (Ukraine--Quarries and quarrying--Zquipment and supplies) BELOV, V.Te.; BILENKO, A.I.; SliVACHKO, M.S.; BRAILOVSKII, N.G.. inzhener, redaktor; KHITROV, P.A.. TIMMMnkly redaktor [Unit method of repairing freight cars] Uzlovoi metod, remonta gruzovykh vagonov; opyt vagonnogo, depo, stantsii Likhobor7-Noskovsko- Okruzhnoi dorogi. Moskva, Gos. transp. zliel-dor. izd-vo, 1954. 54 p. (Railroads-Fraight-cars) (KUU 8:6) I .. . I F - ~ 1 , -,I'. ; ,-7,1 * :.,, --,:nn"ivif- rtirport onert?tinn. Grs7hd.nv. 'If an.7:3-t . . I . (KWIA 11 !1 .: -,I, otdeln aeroport.-. . . (Aimorts) --, SHVACHKO, P. This is vital and useful. Izobr.i rats. no-12:32-33 D l6o. (MIRA 13:22) 1. Sekretarl Ukrainskogo reepublikanskogo soveta Vsesoyuznogo ob8hchestva izobretateley i ratsionalizatorov, Kiyev. (Ukraine--Coal minse and mining--Technological innovations) SHVAGHKOJ, P.P. Gor;ference nP inventors and efficiency promoters. Tekst.prom. 20 no~3:90-92 Yx '60~, (MIRA 14:5) 1. Sekretarl Ukrainskogo reepul)likanskogo soveta Voesoyuznogo obshchestva-izobretateley i rat6ionalizatorov. (Textile industry-Technological innovatiofis) ACC NR- AR-100,1107 souncE CODE: UR/016,9/66/000/0121VO25/VO25 AUTTIOR: Shvachko, R. F. TIT LE: Fluctuations in sound and random inhomogenities in the ocean SOURCE: Ref. zh. Geofizika, Abs. 12VI47 REF SOURCE: Sb. 2-y Mezhdunar. okeanogr. kongress, 1966. Tezisy dokl. M.. Nauka, 1966, 420-421 TOPIC TAGS: refractive index, ocean acoustics, acoustics, oceanography, turbulent mixing, sound signal fluctuation, two thirds law, random inhomogeneity ABSTRACT: One possible application of acoustics in oceanography rests on the relationship between fluctuations in sound and random variations in sound velocity, which are usually caused by temperature fluctuations in the ocean. These temperature fluctuations, in turn, are due to turbulent processes in the ocean. Thus, a relationship is established between the turbulence parameters and the i statistical characteristics of an acoustical signal passing through a turbulent medium with random inhomogeneities in sound velocity c (refraction index n-efc). Card 1/4 UDC: 551. 463._?2 ACC N ': AR7004107 A study of this relationship in the Atlantic Ocean was made in 1961-1964 by the scientific research vessels of the Soviet Academy of Sciences, "Sergey Vavilov" and "Petr Lebedev". As a rule, recordings of the fluctuations in the amplitude of a pulsed sound signal (which had been reflected from the ocean surface) were made at the same time as direct measurements of fluctuations of the index of refraction. These measurements were made using a practically inertialess instrument which. measured small deviations (up to 10-1) of the index of refraction from the mean value (equal to one), using a microphasometric method of measuring the sound velocity of 2-mc frequency over a base several centimeters long. Slower fluctua- tions of the index of refraction were measured with a velocity meter based on the if sing-around" principle. Its sensitivity for a measurement time of one sec is 5 - 10-6. In order to make the transition from fluctuations of the index of refrac- tion to temperature fluctuations, sensitivity values expressed in units of the refraction index should be multiplied by 500% Both'the direct and indirect measurements which were made (based on the statistical characteristics of amplitude fluctuations in the acoustical signal) showed that Kolmogorov- Obukhov's "law of two-thirds" for local isotropic turbulence, D.(P).-[n(P1)-n(_,*)j3-Cn'P'1', Ps is true for the structural function 'D.(P) of fluctuations in the coefficient of refraction. Here, Cn is the so-called structural constant, and ~ P-1P1_P31 is the distance between measurement points; the arrows in the equation indicate Card 214 ACC N~: This law is true within a scale range from averaged va'ues of the set (o-- in time). I to I-,,. If the internal scale 1 is determined by minimum dimensions of the 0 0 inhornorreneities which could exist for reasons of energy dissipation (in the ocean I cm), then the external scale Lo is determined by the characteristic dimen- 0 !j sions of the mechanism of turbulence excitation. Measurements in the upper mixed layer of the ocean (at depths of 20-40 m) showed that an excitation mechan- ism exists which is capable of causing inhomogeneities with an outer scale Lo ranging from several decimeters to several meters, with the magnitude of the -structural constant C. - 10-4 u-' 0 Results obtained in processing amplitude fluctuations in 25 kcps signals (wavelength ~-Ccm ) showed that when the distance L between the emitter and receiver equals several hundred meters, with the condition I(TL->LO prevailing, the transverse radius of the correla- tion of sound amplitude fluctuations, following from theoretical considerations, coincides in order of magnitude with the external dimensions of inhomogeneities Lo' and the mean square value V relative to amplitude fluctuations agrees well with the theoretical relationship: V_3'CX-'L616L1j2. - I Measurements of sound fluctuations at great depths (150-250 m), as well as direct measurements of fluctuations in the refraction index at depths up to 1500 m, L~.rd 3 / 4 ACC NR: A117004107 showed that the "law of two-thirds" was observed to apply to dimensions up to an order of several tens and hundreds of meters with a structural constant value of Under these conditions, at a frequency of 3 kcps (wavelength )6-0,5 w and distances to several kilometers, when the condition LZ4 prevails, the transverse radius of correlation of I sound amplitude fluctuations coincides in order of magnitude with V_!_L , and the I mean square value of relative amplitude fluctuations follows the relationship: V_ CAX-4J12 LI 1112. ~2) Thus, as may be seen from expressions (1) and (2), the Cn and Lo parameters of turbulent oceanic mixing may be calculated from the measures mean quadratic values of relative amplitude fluctuations in the sound signal and values of the trans- verse radius of the correlation of these fluctuations.. [Translation of abstract] [SPI SUB CODE: 08/ Card 4/4 tit J.~CVVIVII.S~i LI Ti- J. AOCZMW Me AIP3WSUS AMMI 0 Tinas AaouUo In qWw om4c Urn arA UMV MOWUM IN redo -A ~- I $, .,:., sod" M=1 Multicbeski *mrwap ve 99 we 3p 1963# A7-360 T6PM TAGSI acow"o 92=608610no randon Ig IMMYO oosem 2qwp retreoUve corroution fawtion PUIS 'ADWRACTs Remits of an IMINCISSI InvestigstIon In somd level -EMONS Sa. upper lWwm of the ocean hm been reportede The aqwaftents mwe duo Ax MW 2961 in the nortbern Atlantic* 2W miles south of -Pomgdm Bank* Fulse frequea- cies vers at 20 ond 25 kop duration I sows and recurrence parled 4W mseco, MW :transducer Inursion dqAh uss 40 a Ln an vow IsM aO a thlelce the refractive Indez 0 was vithia Us Umike w4to 2 z 10-4. us nonaused 4efractive Indeals PUMA asslast Ir2 - r:Ll*. Ow"- PdA" I&M a [card 'ACCESSION URI AP3005625 .!good agresswit with the predicted 2/3 Im for Dn Twow v*U with the nmb=lllo !transverse radius of corr"lon faaction lmd colmides IJWJU a a 1.4 to 2.5 No an now In a Put of neity radims of the retractivs V.' mormUsed structwe of refractive badex fluGt"10110 at the 254m frwPOW far to Tul M. mollb"adw fw helps In as 41z distances. Me Mthw 19 gr&Wul I:expwimaW and "ta rsduaUmn,� Orige Wbe Me' 3 fwwal" aid 3 APM8, bAlMs AN SM) idol** m sm.amm t 00 M# DM AM, SM63 . 2;- An 0=8 We 3 ~Al T Un Cwd w FOGE 1. 1 )Ya.M.; NADYKTO, B.T.; SIIVAGIIKO, V.I.; RYBALKO, V.F.; KOROBCIIANSKAYA, Catalytic oxidation of ammonia on platinum studied by the method of secondary ionic emission. Dokl. AN SSSR 155 no.1:171-174 Mr 164. (WRA 17r4) 1. KharIkovskly gosudarstvennyy universitet im. A.M.Gorlkogo. Predstavleno akademikom A.N.Frumkinym. M FOGELI) Ya.M.; NADYK110, B.T.; RYDALKO, V.F.; SHW"MiKO, V.I.; KOROBC11ANSKAYA, I.Ye. - Study of the catalytic oxidation of ammonia on plat-fnum by the secondary ion emission method. Kin. i kat. 5 no.3:496-504 IV- Je 164. (14IRA 17: 11) 1. Kharlkovskiy gosudatstvennyy universitet imeni Gor1kogo. L23051-65 LWGQ)/ZWT(m)/,8 PF(c)/EPR/j3WP(0/EWP(b) Pr-4/p 4 IJP(c) JD ACCESSION NR: AP4047980 S/0076164/038/010/239712402 v)'-, Nadykio, B. T.(Khar'kov)j Shvachko, V.: I# AUTHOR: M.(Xharlko 29 (Kartkov); R-Ybalko. V. F. (Kharlkov) TITLE: Secondary Ion emission Investigation of the state of o _MAen adsorbed on a silver surface SOURCE: Zhurnal fizicheskoy khimii, v. 38, no. 10, 1964, 2307-2402 IV TOPIC TAGS- secondary oxygen ion emission, oxidation mechanism, silver-oxida4_..- tioncatalyst, negative oxygen ion, positiveox gen ion y ABSTRACT: In order to study the mechanism of the oxidation process 6n a me-. tallic catalyst (silver catalyst used:in ethylene oxidation) the.s'ta-te of the oxygen adsorbed on the surface was determined. !The mass spectra of the secondary poI tive and negative ions. formed by bombarding a silver ribbon with a primary. beam of argon ions in an oxygen atmosphere were-studied. The,dependence of the. intensity of the mass spectral lines on the oxygen pressure -and the ribbon temper--_-,'.~,*~~,. ature was determined. -In the.20-500C range the oxygen adsorbed on the silve'r.,. surface was partly atomic and partly molecular, and some of the molecular oxy- Cardl2 L 23051-65 ACCESSION NR: AP4047980 gen was in the state of a negative molecular ion 0 The.statiiW the charge. of 2 the atomic oxygen was not determined. At temperatures above-:300C the effect',- of the oxides on the silver surface on the secondary emission of oxygen ion .- S was insignificant; the latter were formed only.from oxygen adsorbed on the silver.,:-' surface. Below 300C the surface oxides could be involved in the secondary emis-,.:~, sion of oxygen ions~ but apparently to only a small extent. Thus if the oxygen in the surface oxides on the silver plays a significant role in catalytic oxidation reactions, the activity of the silver catalyst will drop at temperatures above 306Ci"~., "In conclusion we wish to sincerely thank 1. prof. A. K.: Vallter for constant advic'e'.-,,`-7 and interest in the work. Orig. art, has: 3, figures and 3 e4uations~ 0 ASSOCIATION: Khar1kovskly gosudarstvienny*y universitet Im.- X# M. Gor1kog (Kharkov State University) -ENCL: 00 SUBMITTED: 170ct63 SUB CODE: GC, NP NO REF.SOV: 005 OTHER: 002" Card 2/2 L 46183-65 M1T(1)/EWT(m)/EFA( Is )_2/zP1r(0)/LVA'(d)/EPA(w)-2 Ea(t)/NWP(t)/~ -1-JP( _JDAN EWP,(b), Pab~10/Pr-l;/Peb, /W"- 0 T UR/0020/6S/161/004/0896/ a ACCESSION NR: AP5010839 ire C Nqdyktol,B. Twi, Folzelf pjao M.- AUTHOR: Shyacbk!p Garger, K. Kondratlyev, V. N TITLE: The use of secondary ion emission f-pr investigation of.corrosi sea on proces on the surface of steel SOURCE: AN SSSR. Doklady, v. 161, no. 4, 1965 886-888/ TOPIC TAGS: secondary emission, steel surface oxidation, irm pentacarbonyl, ferric oxide, ferrous hydroxide, argon ion.beam.-steel corrosion. ABSTRACT: The article presents preliminary results of a study of the processes occurr va. -6 iniz.on.the-surfe of- steel -during -heating. in a cuum 5 x 10 mm Hg) and '(in made up of Ar ions accele secondary ions versus the LUMPOL'aLt"M WJL UAW 04--=W-L OLZ'AF CM7~ 9XV%2&2* .&&I= LULIMMIA-0-n- L4;c!!d 1/3 46183-65 ACCESSION NR: AP5010839 of ferric o4de on the steel surface',is due to oxygen in the residual gas. How- ever at oxygen pressMs higherthan 2-10 mm Hg there -is no increase -in the in- tensity of the Fe203 ion'beam, and therefore no increase In the oxide coating on the steel surface. In the 20-5000 range, the rateof decomposition of ferric oxide increases with temperature more rapidly than the rate of oxide formation; which reduces the oxide coating. In the.500-8000 range this situation is reversed. 6 nsidered in rela- and the oxide coatingincreases. The formati n of F~e(002 is CO tion to the pressur .e of water vapo r. T he coating,o f the surface with Fe(CO)5 J*Ln'- creases monotonically above 2000. A definite part in:,,the machanism,of formation of iron pentacarbonyl is played by the carbon presentIn the steel; the oxidation of carbon may constitute the first stage.of formation of-the pentacarbonyl. If such is the case, the formation and evaporation of Fe(C0)5 should lead to the de- carburization of steel. "We consider it.our pleasant duty to.thank Prof A.-K. for a steady interest in this,% rk Oili Vallter w0 i g., art. has: 3 fi gures. (Kharkov"__~ ASSOCIATION: -Kharlkovskl~ gosudarstve'Tmyy:,,tmi,~,exisitiet~- is. -Ail- M. Go~!kogo :. , State University) Card 2/3, tj L 588Z2_65 EPF(c) /EPF FPIVLWG(J)/EPA(w)-2/EWT(1)/19WT(m)/LVP(b)/EPik(,pp~ EWPM Pr-;4/Ps-4/Pu_4/Peb IjP(c) AT/jD/j(; ACCESSION NR: AP5017281 ti/0181/651007/007/1944/195 is. 14 AUTHOR: S I.; Na kto, B,,T&*, Fog4-It','Ya. M,;--Vasyutin6kiy hvachko, V. -Kartmazov, TITLE: Using secondary ion-ionic emissiotAfor studying the interaction of with the surface of~niobium SOURCE: Fizika tverdogo tela, 7,'no. 7, 1965, 1944-1951 TOPIC TAGS: ion emission, niobium, oxidation _M ABSTRACT: The metho4~,pf secondary,ion-ionic:emission was used to investigate the composition of pxidesy*hich form-on the surface of niobium when it interacts with -14~~`i'V oxygen. It was established.that in the temperature.range from.20 to 12000C the, tdl~w L4 lowing oxides form on the surface of nioblum which is In an oxygen atmosphere ata g -4 4; pressure of approximately"10 mm of mercury: NbO, NbO2.. Nb203, and Nb205- In the- temperature interval from 1200 to 20000C the surface of Nb*contains only NbO and NbZ03. The corrosion wear of Nb results.1mm the'formation and subsequent evapora- tion of NbO starts at 14000C and then-increases very rapidly with temperature, in., the 20- reac-~ -80010C'temperaturs range Nb02 undergoes decomposition according to the. -gaseous. phase :,"In - c6ticlIP-1... Nb02 tion. 4 NbO+ 0 with thi desorption of,~xygen into a Card 1/2 `tk ;j"l -4 4 58872-65 . 0 ....... ACCESSION MR: AP5017281 irely greteful to A. K- Vaj~tsr:for hid constant,interest'in. the sion, we are sincf ig. art. has- 4 f gurea work." Or KfiiA6V udarstvennyy uniVerbitet.14- 'Aa:~ H- Gorikog0'( ASSOCIATION. Kharlkovskiy gos tp 5 State University) UB'COD9 ' 3 S ENCL: ~00 4 SUBMITTED: 27HoV6 t SOVI 003 PIVER: '001" NO REF I -W t 7 12 2 Card - - Ya . M. r 3 n s c n o s u ra e me ,,,,I no.4- P~C7-988 (MMA 18:5) KharlIkov3kiy gosudarstv,innyy univ.-rsitn'. im. A.MGorlkor~o. i In --tcber 6, -PO"ELI, Ya.M.- NADYKTOr. B.T.5 RYBALKO, V.F.; KOROBCHANSKAYA, U I T.Ije. Use of the secondary ton emission method for investigating catalytic reactions between ammonia and nitric oxide, and the decomposition of nitric oxide on platinum. Kin. i kat. 5 no.5042--c44 S-0 164. (MIRA 17:12) 1. Kharlkovsk-'y gosudarstvennyy universitet imeni GorIkogo. ACCESSION NR: AP4009524 S/0293/63/00l/0()3/0414/0435 AUMIM: Vakhninl V. M.; Slan-idin, G. A.; Shvachunov., I. ff. TITLE: The movement of charged particles in the field of a magnetic dipole, considering enerE;y dissipation SOURCE: Kosmicheskiye issledovaniya, V. 1Y no- 3, 1963, 414-435 TOKIC TAGS: magie-tic dipole, magnetism, charged particle., charged particle motion., magnetic field., energy dissipation ABSTI-LIXT: The authors have analyzed the mavement of charged particles in a ma.r~.etic field by the phase plane method both in a conservative approximation and 'vrith considerattion of losses of their kinetic energy due to radiation, thus pro- viding a qualitative picture of the influence of Idnetie energy -..csses on the par- ticle trajectory. These losses vrere considered in the form of small dissipatioa perturbations of the conservative approximation. The authors succeeded in aemcn- strating the existence of certain critical trajectories,, at which pax-ticle seizure by t:he magnetic field occurs eu arbitrarily small energy losses. (It is obvious that at small, but finite, energy losses, seizure may also occur in the case of other trajectories,, close to critical.) The phase plane method was found to be particularly coavenient-when studying the movement of the particle in a c=plex Card POCESSIOIT IM: AP4009624 field containing a dipolar and harog Y cneous, (external) ccmpcnent. The authors considered cmservative appradz~-tions and their dissipaticx perturbatims for three idealized situations: a) magnetic dipole with no external magnetic field present; b) magnetic dipole in space with uniform magietic field parallel to the ma~-;net*izatim vector of the dipole's magnetic field and located in its equatorial plane; and c) magnetic dipole in space witli uniform magnetic field antiparallel to the magietizatim vector of the dipole's magnetic field and. located in its equatorial plane. The ana3,ysis was conducted in the ma'snetic plane of the dipole. in the first case (movement of a charged particle in the field of a magnetic di- -pole in the absence of an external magnetic field), the differential equation for the "phase trajectory" off the moticn of the charged particle was discussed. Fol- loi-ring this, "isoclines" and a "field of directicns" were ccnstracied in the phase plane in a cmservative appro.,.imation. Phase trajectory behavior-mas ccnsidered at as well as the trajectories of charged L. large =1 small values of u and w. particles in a magnetic field which correspmd to the phase trajectories,, both vita and without consideration of energy dissipation. With fev exceptims, this .5reatment was also followed in the case of the other two ideal hypotheses. Orig. art. has: 19 figures and 43 formulas. ASSMATI(XI: none Card 2/~ L 49441-6 -tWT(I)/SWG(v)/FCC/EFC-4/UC(ti/EWA(h,) Po_4/P Pq.4/Pa -Pi-4-, - GW- ACCESSION WR: APS009654 UR/0293/65/003,/002'/0336/0346~~ e v D.; Shuridint G.: A Shalim AUTHOR: Pletn Shvachunov. 1. N, TITLEs Dynamics of the-geomagnetie* trap and the origiii~ radiation.,, 0 belts ~SOURCE: Kosmicheakiye issledovaniya,, v. 3, n o.., 21 1965g 336-340 ell, ar 'windN 'd TOPIC TAGS I sol fiel ~magnetic_ geomagnatic storm, force line, proton belt, electron*belt by'jhelnter~ ABSTRACTS The boundary of the magnetoo-phere created Iaction betvaen the solar windland the geamagnatid fiel&reaches a, -radii on the d Elec- distance of 16 terrestrtal ay side o U the,',eArth, tric currento on the butAudary incre nce the tragnetic field theres the night side the magitetosphere is very artetuderl. ,A part cla may through the bonudzkry of the maqiie~osph,are because of..a drift of Lhe particla Ln art asymmet).,ic wagnatic fleld* The physical,, processes are atudlecl In a magnetic field fron parallels,470, , The' regions permitting wid lixohlbiting paiticln motioti.'..aro- determinedg.. 1-Card 1/2 T L 65296-65 ~-EIT(l)/FCO/kM(h), GW. 26 AP502D992 UR/02D3/6 550-388 0 2 ;AUTHORSt P SMIJ letnevp Ve D.; Skuridin, G q_Aq; V# Is 44155. ;TITLEt Dynamics of the geomagnetic trap and the ori gin of eart~hl ?Sr~adiation to 'SOURCEs Geomagneti= i aeronomiya, v. 5 hoi 4P 626-644 .1965-0 ;TOPIC TAGSt magnetic fieldv Van Allen beltj, magnetiolrapg.geomagnetio fieldv !charged particle concentrationg magnetic Istorm, solair burst 44) !ABSTRACT: The interaction of solar corpuscular streams41th the Reomametic field lis discussed with explanations about the formation of.the.earthla- kagnotosphere and Ithe mechanism of charged particle penetration.into,the magnotoopheree The scalar potential of the geomagnetic field inside the earthlo.magmetoophere is eivressed in ~spherical harmonicst and the solar particle atream--geomagnetic field-interaction described by the model shown in Fig* I on the Enclosureo In order to snai4ze: ;possibility of particle penetration.into the magnetosphere -the followIng equation !is solved numerically P 2y, 0