SCIENTIFIC ABSTRACT SHPITALNIKOV, K.F. - SHPITSBERG, A.L.

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CIA-RDP86-00513R001549930004-6
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December 31, 1967
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SCIENTIFIC ABSTRACT
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24531 The maximum output of a centrifugal.... S/147/61/000/002/010/015 E194/Ei84 U rDn ~Oa (6) Cos (7) The results of an experimental study of the flow capacity of the inlet section of compressor impellers is then given and it is found that the theoretical flow parameters give much higher outputs than the experimental values. The stage intake could be increased by some 20% if the rest of the impeller could handle it. The through- put can be improved by having an appropriate value of inlet swirl, or for a given output the compressor may be made smaller. A numerical example is then given of determination ot optimum flow parameters in the inlet section of an impeller and the relationship between the optimum flow parameters and the relative radius at the inlet to the impeller are plotted in Fig.9. The maximum flow density is obtained by use of stationary guide vanes at inlet to the impeller. A brief.discussion of the advantages of a correct inlet Card 3/4 24531 The maximum output of a centrifugal.... S/147/61/000/002/o.lo/ol5 E194/EI84 swirl is given. There are 9 figures and 6 Soviet references. SUBMITTED: March 22, 196o XW;/IM; LL Fig. 9 Card 4/4 0,6 0,4 0,2 1~ 6 80 -110 --- 60 so 27-536 s/oq6/6i/ooo/oo6/003/do6 0 E-194/-E155 AUTHOR: Shpitalln~~~ Candidate of Technical Sciences TITLE: Selection of the.peripheral speed of the runner of a centrifugal compress.or stage PERIODICAL: Teplocnergetika, 1961, No.6, pp. 42-47 TEXT: The peripheral speed u2 of a centrifugal stage runner is usually found by a fo rmu la due to B. Ekkert. (Ref.1): r U 71--A9 -0 Ul= I/ H, where 0 PO out/pO in is the compression ratio of the stage; 77 "~ad is the adiabatic head coefficient of the stage; Had is the adiabatic head of the st,~ge; is the 9r,avitational constant; :Z is the gas constant; k is the adiabati6 index of the process; ~.Cl is the temperature of the.adiabatically-retarded flow at iniet to the runner. FrPvided that data are available for an existing stage which does not differ too much from that being Card 1/6 22536 5/oq6/61/ooo/oo6/003/oo6 Selection of the peripheral spe6d ... E194/E155 designed., the aAiabatic head coefficient may be selected reliably on the!'basis of prototype data. 'Thd problem is much more difficult if the'design stage differs substantially from existing stages in the meridianal section of the flow path and in the.~ype of blades on the runner. In this case correct select ' ion of Had and calculation of u2 are very difficult. Therefore, the peripheral speed of the runner must be selected on the basis-of analvsis of the aerodynamics of air flow in the runners of several variants. The relative merits of runners with*blades bent forward (in the direction of rotation) which are termed 'active', or bent back,,which are termed 'reactive', are 'then discussed. The problem of the rational selection of peripheral speed of runner in the gene'ral case, without allowance for changes in the parameters of the air flow at the inlet to the wheel, was considered in a previous article by the present author in Teplocnergetika No.4, 196o (Ref-3). In the present work the peripheral speed is selected by investigation of changes in the flow parameter both at inlet to and outlet from the runner. For the sake of.simplicity the selection of runndr speed is illustrated by a numerical u-orked example, which occupies nearly all of this article. Card 2/6 22536 s/oq6/6l/ooo/oo6/003/oo6 Selection of the peripheral spe.ed ... E194/E155 The principal formulae derived are the folloiring: w D arc cos 'u (19) P2 If .1 cp (U2 + U,6)1 + SM arccos ,uD 2 D W1 CP (23) 2 2k k-1 U2 k + I gR IT.t + kR g + a, ==,lrC tg tVI CP c2u -uD (24) D sin (are cos W, CP =arc tg u, + w" _.i t!'Icse expressions the following notation is used: D wl CT) ;Nr2 Card 3/ 6 22536 /61)0 s/o96 oo/oo6/00/oo6 Selection of the peripheral speed .... E194/E155 ",'l cp is the average spewed at the,mean radius; w2 Js the outlet speed; wu = IT2'* C 0 s P 202 is the discharge angle of flow from the runner; X t.is ~L number commonly used to characterise the condition of the flow, the suffix I relating to inlet and the suffix 2 relating to discharge; a2 is the angle of flow at discharge from the runner in absolute motion. Fig.6 shows graphs Of*-.X2, P2 and a2 for the particular example iv,orked in the article, constructed by means of equations (19),- (23) and (24j. From thes~e graphs a number of conclusions are drawn about the influepceof different factors in runner design on the performance. On t*~4~'basis-of these considerations.-the optimum design of the numerical'worked example under consideration is recommended. It is concluded that in each particulAr case selection of the peripheral speed of the runner in designing a compressor stage consists not in simple selection of the head coefficient Had but in investigation of the inlet and discharge aerod-~namics of the runner. During this investigation it is usualiy possible to avoid-undesirable effect*s of supersonic flow within the stage, or at any rate to minimise-the negative influence of such effects, and so to make a rational selection of the Card 4/6 . peripheral speed of the runner. , SH"JULI-1111KOV, K.F., kand.tekhn.nauk Carrying capacity of the input cross section of a centrifugal compreosor stage. Energomashinostroenie 7 no.6:23-24 Je 161. (MIRA 14-7) (Compressors) SHPITAL'NYY, A.A. Formation of polyamide resins. Part 5. Participation of polymeri- zation and polycondensation In the conversion of E-caprolactam into polymer. Zhur.ob.khim. 26 no.2:530-534 F 156. (MLRA 9:8) 1. Leningradakiy takstillnyy institut. (Polymers and polymerization) (Hyxamethylenimine) -17-0 g g I J 4 1 S I I t so It U 14 La 14 is J A 1 V 41 .1 avo L [ A A Glut.b jo mical properties ot substantive dyestl;ft A- A, SHPITA1.1011 [SWIlIffil Ch e r*lstd Proms. J'afCopp. I No 4-4~ 77-81.-I.Awt stable sub~tAntivr dymtuffs Appear 0* l and f h d -00 rnzy y ent dine Intrvooluctitm o lkini c4 bn.. , ith natobtlahmic AM. t i .00 o na 00 to 1w cimi oulto POUPS IncirwWol Stalwility, "Xio is ILLqO the effWt Of ITICITWInt the VAI, Of (M, (Will reased toy Oil and sullo groulvi. t d i .40 s ec n. And S(hNa Mop%. Viscosity of a dye lo go G. Toorim 7 . 00 Qo 06 '00 019 a* . 1 1 0 ~ 0 0 . 6 0 0 :Zoo j we Lfe 0 00 8 '0 '13 , 41, A 1 v 900 " 4 j ~ 1 rw o so sa . 2 0 tons 0 0 0 0 o 0 0 0 0 0 0 0 0 * 0 * is a 0 61 40 0 00 030 0 * 0 0 0 0 0 =7 0 00 0 0 0 0 000 4 0 0 a 0 0 0 0 0 0000 0 I to 11 1) is 14 11 11 39 C it 42 a a at* L I j) X m a CE W U 'A The ripening of vLacosZ A. S. SumTALNijIL d%. 1. Mans AmD L. 1. MutLA& J. carried out in order to dis- No. 1, 8D-060932).-Front R.) 00 ~00 oo 00 00 00 j 00 cipts. Gex, Chem. (U. S. 'k 2, cover th rucchanism of the ripening of vLvtm it is concluded that thcre am involved a chem. e n Z. In the decompn. o( zanthate and a colloidal procem cmist- F y of manthate particles. This stability is due not to the no. d s, f Lbilgit ing of a PE Of CSSN grou^ but to the presence or absence of substances which stabilite or tender -00 unstable the xanthate particles in the mdn. S. L. ht"ommy .00 150* =09 tft 'C' -ILA SITALLUACKAL LITINAILME CLASSIFICATWO La I A b U is A, 03 LS I Ov a CA It erg KnICS9 Kolt * * 0 0 OTOO: : a :is 0 0 9 0 =0 q Zoo is 0 tjo 0 A ILL11 n_-6~v Lt. L 1 4 04 0 it it Ot RM M I in 0 0 0 * 6 0 0 0 0 0 0 0 9 go 0 * 0 010 * * 4 0 * 0 0 0 0 0 0 0 0 9 0 0 0;; 116 if it it *III A-1 If x A if A. 8 1 1 0 1 v A A 1. t M w -00 .90 ^a see coil COO 60 SOO coo '00 tM44J.-I'mligninar cumauLlIkatiOu. ch.. ulam 6 00 as to J!, *0 61 ~r A S 9 S L A SITALLUItGXAL LITERATURK CLASSOPKAVON Os AT so Ast, IT ft K tr it U OTS:0 00 00 00 1001 ts a 0 42.111, use J111, 0 I a Od 0 0 9 w Im I a a 3 0 c :1 q q * G 0: :::::: G * 4 0 O 111 0 4 0 0 4 Ozi 1 11 11 It Is u Is 16 It Is a 1 17 11 J4 Is 26 17 a m I Aj A) it u m w Is 16 W AT # tj .3 A L -1 fi 1--, L . M Is a M of I ot - 00 :-so so -00 00 So so -00 Volumetric analysis of viscoses, 0 1 R S -00 . Lyashch. likussnrniso, 6 '19 7) i N 1 40 3 goo o. . . . (IIL34).-A 'fi%cuw%km of the exi,im, 06 it, Chas. 11131W zoo' coo roe z 0 00 z 21 So 0 *0 2 1 free .0 W, goo 1 g0 0 A S a . I L A AtTALLI;PGKAL LITIRATURE CLASSIFKATION 0* AT 1 3 IT D to IV ap III K it 9 It a It It at S a ad 0 0 w 14 9 93 a 3 A T 17u, 10 0 0 0 Ole 0 0 st fil * 0 * 0 0 v r 0 0 0 0 0 0 f 0'* 6 0 0 0 0 6 0 0 a 0 4 0 0 0 0 0 0 0. q 0 0 0 Ole a 0 - 0 C 0 0 0 0 0 0 0 0 0 0 I 0 0 *1* 0 0 a 0 0 0 0 0 0 0 0 0 * 0 0 I OIL - cv 11 U If 14 is 1. 11 It It AD Ill vi D ;4 Z3 h 17 J2 M11 11 ]JI 1] 14 031 It jq P Q R 1 1, a is I . IF ; It, G 0 I s 00 pfrocess of pro4faumucautilose. Y 11M , A. Mmw and Lyu3hch. IskmijAvix,4 I jjjikNt, -00 0 s:- ~A lkkiat FRAINT) S. No. 2, 41-3(19M) --A pirclitntn o a . wry Chu. Blanc 00 -00 of -90 0 =00 00 zoo Z9 0 zoo A S All - S L A E.Z- SITALLLRrICAL LITEXATUNE CLASSIFICATION -- TS AV PO I Kit 6111 nutr tim V I, If 0, 0 mion t!xa AT 00 0 0 ;0 171V MM 0 0 0 0 0 0 0 0 0 0 0 r 0.0 0 0 40 0 o 00 0 0 0 0 0 0 Ole 0 0 0 0 0 0 0 0 0 a 9 0 0 0 9 *if * & 0 0 0 0 0 0 0 6 0 * e 0 9 op 0 0 0 0 0 0 0 0 0 0 0 0 0 I 1 4 1 A I a I IQ 11 1z ii W Arl-f-t 2 - r, it I A L_A it F in Ll 00 r 00 a 00 00 of z 00 f so 4 Of AS-SLA it U AV 0 At IOT-400 0 4F 0 10 0 a 0 0 0 0 a 0 0 O~q OW ,i-Pl ~ ; .4"toolill Ott so so** 0 0 0 is 14 1? Is a it D, U )A a 26 J? Is 20]b) it 11 11 0 is A, J1 M M 0 41 Q &I M a no , A $- I AA W DO tt~ t t d 1 -1 k A I Defects of wiscose made from cellulose conts-1-sted with A. . Sh JISI*nuil. ilkniltvomos VoWma IRS R- tM, made 5 from'ccliulw coatig. over 1% lignin when treated with dil. acid omKg. five Ch bmm- d-I1-c0k)md in the process al g"pigg and rewoficing with wealc alkalies 1,,-aum of the pmaence of chlorinated lignin. 'rho chlorinating effect of hypuchkwitc solos. on lignin cannot he detected by analysis. By uvating cellulose with alkalles the lignin content can only he reduc"l to a cirttain nce. of active C1, in njertyrizing alkalies degree. T'he PrM turthem a better ex1n. of fignin In crtlut-e- C. B. i-00 -00 -00 no* =00 COO ZOO Coe 0 N 4goo ;;0 0 METALLURCKAL LITtR.T601 CLASS]FKATICN tv tv to )t 6( K n it 91 K CS tt 1% 49 0 0 00 a 0 * 41 0 0 0 a 4p 0 0 00 0 0 0 0 9 0 0 e 00 =0 0 &so An L S N DA 0 1 W IM 5 AZ a 3 4 1.1 La ri 1 1. ano 00-11, 0 0 0 6,0 0 e * 0 0 4p 0 0 0 4 0 * 0 9 0 q o : 0 0 0 ejo 0 0 a 0 0 0 * lp 40 0 0 0 0 0 0 0 4p O:i 0 0 0 0 0 0 0 0 * 0 0 0 0 6 0 0 0 0 or*---O--* 0 0 0-0 0 0 0 oll 0 0 0 0 0 0 0 0 0 0.7; a A 1 0 it 11 IS " 134 1116 pilk;J121 Z114b 22 V A R-jell CIS ben hIPAIM441 41 Q a Q~Co 00 4 CrLl r US at Lahf'QR It %ly.?A TIAAM CC W Mai It I d 1_1 a h *6 00 00 1 00 Laitoormally vl"Saav 1866"a of the "Iloottleth" [a t n , Y -00 'f 0444a Sal 'Af A *ipu4J:tua 1 ' t (.0 90 z rad4); cf. C. A. 23, "U'- StudYof tile Y.No. 8.M it %N~r rayon anit nitat,faIst% vdinan'ut the (urniatimi tit Saint vi 1-00 00 . Sold lit tile influctscr s4contaluiltat"I cclitillamw &In the 11411114). .00 Of 9,,lIs`Ily.'(viimt%ww test to tile following trillative Allwrva- Iliglia: %JAI Vj1Cj)W ij IntaIr SnICTIMIalt' 11) CS-11111111tillAt"I 0 0 Withanibefilste, -04 00 dnad t ta visit arordiw1owti to large no,,)( Solicit s~ca.pic cas, it ic- ham.'l lay tile invoillpletv rtl1mvill .4 " do'd K%_"vs .04 00 ... . ...... . o'.. p-14. 1, it, tile 111m.- ill thotad I"Its-m-tuti" x 1 '00 00 j h at, ta:c% kianmllon,d sit., Kill, small.. RVOTS lly. tile 40,11-4 ,00 Vloinj- tile VIYAgUlAtIllit 1)[OfIT111CS tit 4 1)jltat. twill. 400 00 5 -^Itkql ill this raynn %hom similarity is) the pituilu, I tAi- - f S 0o ' 60' ' ~ '. ow Willi an itwica-d quantity o C lanivil films It vi. Ilse high SisisicarimbiMy of most irj%~w III Z ! tillo'bli's allm s., lu'Allialily, artAted to it. ext,clatilor mllfacr 4 1 To Oll dial 11, Sit Ilse %u n I list IS... i .00 00 1 giving highly visocoaus adshis., tuu.,t unstraps is nums, pass. Isimirmaii of Siolvalititt than the atit"Cladirs Ifiving low. 2 va-,e-liv -,hvs. At eflual vi-.1witY tit uAim, the viv,- 0 0 ilpimanv4 I Itoin contmalmnsted crIlulcrse is less hisin-sivuvans, .600 illowl'sidt'.1lovally still sit tile filtFain"I vrlqwilvl tholl tile 60 v1sivis,r obtainvil (risoll l"urt tvuuh-. stra."Ic. his Ilse t i I I l1 l ' o- alit ll" t"111 Ilialisne 'c atallillats,% o Isuplovcd ~'Sly. Sa ~ '00 A as 112, I-c. isuch as oil inc-ses" quantity of C , I I 1 es C I Ile, lluvallurn of Xtulthatiun Uor malvathall, Insist ti -06 00 Of 0 0 04 8 L.Ilit.1k.91 ad" t3 :'00 00 t _ ' . '.: O 2. Z- Is, * - - - - - - 0 " ;O 4 1 r IF F I a 1i V 7IInL INN So w b 0 A3 a I 1 0 0 0 411, da 0 0 T II rt 0 SO as 0 it It To 11 n I m a * 0 0 INS * 0 0 0 0 0 0 0 0 0 ria -1 ~ "s 44,3 0 a a 4 0 0 * 0 0 a 0 0 4 0 a a 0 4 6 0 6. 1A 0 0 0 0 0 do 0 0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 0 0 0,4 0 0 * 6 0 0 0 0 * 0 0 0 0 0 0 0 0 61 je 0 0 a 0 0 0 0 0 0 q 0 0 0 0 FM 2 1 4 5 4 1 0 n-v. 4 1 to it U U " It %a V U to a s a in 11 U U M a M V X P 4 1 "2l at a U a 410 r o-L-.L r X I K L &-x-f -a JL.A- I It it- 1 1 44- A, cc iv a 4-L t -s. t -A---L- a b j k a .,,L i L9 0 11, coot % ..0 t~ V.*!!~ 00 90 The &coon of chlorine asd hypochlorous acid cc the % i ti b i ncrusta on au stances (l gnin of pulp, and visco". A. - ' 00 ic S. Shpital rivi And F. Nfni%. Ore. Chem. Ind. (r. g- _00 0 a I S. R.) 2'*0-"q(lR1#;).-Thc accurarv of the HgAn detn. . ' 1-00 hv pptn with 72~ ,, HSO, wai %tudied by comparative 00 t of %+k-(~ and Spriwe pulp With A114 without pre- _09 00 11,11,114ty chlorinAtion. The rffivf of irmniniv matter on to, rrmulti of the drin. wai evond. hv treating %Ample% go with Cl before ano After the exto, with C.11. and ale. The rr,ults show that the degree of pulp destruction does not ff l 00 A ect essentia ly the quantity 4 lignin pptd. by HpS04. . and dnes not inflortsce at all thr anit. of Cl combined. A =0 0 0 miewhat STrater Cl content in unextd. pulp prepno. 1- l i d 0 00 exp a ne by chlorination of the te.Quous metier. The gTrater fate of lignin AlocinaG,ti explainx the retsilvely Small difference between the Cl mutents of extd. and on- 0 extd. samples. Sprutv -tawdunt k mAly chlorinated by -60 HC10. while pure cellulose remaitted unch4ntvd after 23 00 hr-. 4 contact with RM. Cha%. Plane 0 -00 lei i- ASM.SLA 00 STALLURGICAL LITERATURE CL45S tFIC41100 I Rao. tab** 4J.0. is% ' U W % 1 1 U T ' An A I n 10 1 ; O I 0 0 0 6 4 0 0 0 0 so 6 0 0 0 0 0 4 Ole 0 0iq 0 0 0 0 0 0 4 6 9 0 6 9 0 op 0 I 1 0 10 11 U If 14 Is 14 17 4 1 26 V A 20 1 M 11 32 U 14 15 It v is it 40 41 2 u U is A 11 0 0 4 L _ _ ;I_ __G_JL_J -1. a )I P rd A I- L If r T_L_AA it CC RP -L. U-I a j -1 , I k. 1, 1L % a - _2L_ ~;F 00 -a* .00 0 --Preparation of wool-like staple rayon from CS58111. Of (Ormalin in anits. of 30-M g. i1. gave a favorable effect. -00 as it A. S. Shpilal*nyi, A. 1. %'ale%hkrvich and R. S. Lyashch. The fibers should be treated with water and fognuslin i l f li i .00 0 success ve orma n y ( nctvascd the strength of fiber). 1. A )Wed Chem. W. S. S. R.) 10, 10-53-00937).- Stretching of cascin threads during spinning and stable. .1-he 4,afoslf courn in the cast-in vpinnins soln. should be S .00 00 . ahout I-I..J%: thit yields tibers that am sticky when quent treatment Induced in them an optical anizatropy i i h 0 0 ant ncrra-ed t e strength and stretch. Dry msein moist and bMile %Iwn dry. t'n,l,r certain spinning 4 mixed with %ri"s,- for 2 hrs yielded fibers limi can 00 so _ ng itiers can be prepd. DIS. a t condi Ions Off treatment, soft Ii of cellulose and ca-vin; fm better results cossein cawin in art alkali soln. togohrr with CS, caused should be olvin . 90 g 4vasiderable incrraw of viscosity (if [lie soln. and forma tirtlitninafily wetted for 2 Itrx. In halforequal wt. otwitter. 16C. " A vascin coment ti III 2 h t f II k h . . o I y w cv p u w. ') ail fit 11c tion of the S defivs. of cascin, yielding saft and elast' eff-t on the vi-wotity a'P oil -2turit of viscose Add I =00 . a. Y fibers. In a mi%t. conig. NaOff 2% and US, 2%, W % 'A)% and more Of casein to viscose required an addni z00 . i coniumid in the formation of S deriva. of latter :if the I 11111t. Of alkali (3 1. of 11% NaOH per kg. of casein) i . The d l 00 e ast astrin NIF Mf anti 11,SO, aim, yield soft an . . enerated untreated cellulfmc-cuscin thread contained about 7U% from 17 in was re f th i h fi = 00 e caw ,~ o ty- %v g fibrrs- V g ofthecawinuird. Treat men t (It such fibers with by njeans of acids anti OS% it CS, was hotand 2% NaOH soln . -4d soapy tratcr -C with water. formalin and wst of cawin. Tbc spinning p Mapy CT rOccW sIdn 3 added to the alk a 0 W r . . wag the best. Fourteen references. A. A. Pindrorn was M(*t sati%factory it a bath conig. HISOa 120-4210 1 ' and NWS04 44) 240 k. 'I. of soin. was used. The addn. - 'see zoo ? as 00 S I t a -fT-LLLFrIC1L LiTIO.T1.6if CL-SSIFICAT10h _T- W U vi 11 It) S An L $ V Dd 0 4 a it 14 1 a - ff If If M '110 n I X a 4 It of If K It C K am 0 0 a 0 0 a 0 9 0 0 00 0 0 0 IS 0 0 0 a a 0 0 0 a 0 0 0 0 0 0 0 0 4P a a 0 11 JS )4 15 is It to 011 11 U it 14 n 1. ois 6; v 4j 41L L 6 13j JLL a a r liI II v I A Y I As Pill w (tj f 0 Tht deptudence of the strength of rayon on the spin nto i 00 g cond ticas and the quality Of 1119 C111ulolle. A ' . "I'llital urf anti V. A, Applird KJ Ao. Im Fri-rwis 0-SIX11" 'Wellinic uml ft"101 W 111'. Owl sit. -111, "f Ile'ZIA.Ull"11 ,, Initial fill, tAY1111 "Ile 1 . , "' hV % I~ -V J." J~t 11 ..... ... . 1 . . IV- , " &jt' InctrA,11111 Ill, 00 r Ille ."JiltItur 0 00 .I 0 s I I Ibc 'd Ific n..'t'j'stv III, I,, A: A. zoo "90 4A ti II .,I !,,vn1 1. 0 0 0 0 0 0 0 0 C. I 11C 1-6.1 I Isis$ is ."Iftfuldis 9 a 101 a is v a m a if a a As It Is a ~.oovlll all 'Sio. ".1mli C, L- k 44 M CC a k A IL- I L.. 11-A - &- L. a -.1 r , a Tbv prii-sna Its nng process of alkali cellulose..- A-I'l.- .(pf4,cd( -*fm I V. S. S. R I 1J, 44. .54 lilt C;trnta1F;-4.-4 i t I ilin.) I.- - I'lle I,, -VIII 1 IHS 1 it M, I - 00 ir erriLed rcliul~ aft" removal o cxvc~ tit alkalt. w.L& oil. -00 ~^rd. %'cly intri1xive destriwiloll tit ceffillose was OU. ~T-l dining tills lielimi, tile it-ter tile higher tile initial .00 vtsr..ity tit r0bilow. The caojw of susch il"Ifuclion 6 -00 twt known. A cwtst. CLI-ClInnflAtitin 411 avidic proilticts tit .00 of ct-11411ow was OlKelvc4l 4111(ing all the pfcw- "I i law ate tabulate,1 and Plot ted. A. A. Pixistoiny see 60 a 00 goo 00 zoo 06 0 60 00 Is! see 00 tj tso A S fil S L ASITALLURGIC&L 1.1111141LAt CLASUPICATION Z7 -Z. WOO svloaj J, aft, Opt U fa Air 00 'VA --I Ir "a- V f tT1 An I I W 0 11 1 1 It It 5 a 0 1 4 V MX-4! Six 11 ""loll ar it is of a PI a -F F '/ i-T 0 44, Structure of uits from diamines and dicarboxylic acids of the atiphatic series. A. S. F A A. 1, Kwvi~kava k$. m. Kit.v 'F,ttilc In-t . L. um - K17311'. /hu,. (INA.M Khaw. (). Gvn~ Cheru~~ 20. ,71 1; -90. -Wts ill AhAinitim anti divartuixyliv --M~ air M I'nuleti only in a dtfinite stuivincirtictric ti4tiu, e,t4bInhe,I hv tile Acid ttelixths tif the arids l1wit. of like jullut- bis no effm-t -in tile rl,'1111. The prelu" ul.Oe ill -J. F1011 virldril: 1.1 jull, of 'I'ld .1til h1r.1- MU-j"; Ju'liplir mid o'lah.p. ill. 191-2". all-I Ill, 1911 r"ll.; 1111 are vullt prulmIlly Cyt-114, in %ttljk'- lure. hi, at., -it), i civi),. -hicii ii,v, iddv dd. f J'K' value'. 2 1e, .4 .4, 0 1 1 Ir 'J USSR/Chemistry - Synthetic Fibers Jul 52 "The Problem of the Formation of Polyamide A'. Meos, A. StIr- Resins," A. S. Shpital'nyy, Ye kov., 4i~b_of Synthetic 1-ibers, Leningrad Textile Inst imeni'S*.--M. "Zhur Obshch Miim" Vol 22, No 7, pp 1266-1270 In the formation of polyamide structures, 7- membered rings may be converted to polymers in 2 ways: polymerization and polycondensation. States that~ contrary to published data, condi- tions could be found under which N-methylcapro- lactam forms polymers. The, resulting polymers 229T48 were f ou,nd to -be inore sensitive to heat than the 'polymers of 7-membered rings not' substituted at ,the N-atom. Products of the combination of Z-amin- ocaprolactam with adj:pic and succini f, acids -.m rx e !isolated. The addn of' E-aminocalroic acid to E -caprolactam significantly increases the relative viscosity of the polymer in the early stage of the reaction. t-4 229T48 USSJI/Chemistry - Synthetic Fibers Aug 53 "Opening the 'Ring, in E -Caprolactam Using, Dicar- boxylic Acids of the Fatty Scries and Amines,"'A. S. Shpitv.Iniy'---Ye. A. Meos and-'K. Ye. Perepelkin, Lcnin~jrad Tech Inst im S. M. Kirova, Chair of Syn- thetic Fibers Zhur Obshch Khim, Vol 23, No 8, PP 1382-1363 Treated E-caprolactam (I) with aniline, hexa-mc- thylenediaivine, and ethylenediamine an(I obtained the reaction products and the benzoyl derivs of the reaction products. Some of the products were also 270T28 isol-,tted in -the form of picrates and oxalates. Pre- sents some J.(Icas on the character of the polymeriza- tion -c ondenf;a-l-, ion processes taking place when (I) is converted -to a polymer. 27OT2B 19 US,' It/Chemistry - Macromolecular chemistry Card 1/1 Pub. 151 - 9/37 Authors Shpital'nyy,,,A. S.; PerepeUdn, K. E.; and Heos, E. A, Title Process Of'formation of polyamide resins, Part 4,- The multistage process of formation of polyamide resins and the products obtained from the re- action of E - caprolactam vdth adipic. acid Periodical Zhur. ob. khim. 24/3., 447-450, Mar 1954 Abstract i The multistage polymerization process occurring during the formation of polyamides from;-- -caprolactam vras definitely proven'by the formation of adipic acid -caprolactam reaction products uith a molar ratio of 1 : 2 and 1 : 4)o The properties of reaction products of different mole- cular ratio and the solubility of Ag-sait, a reaction product during equimolecular ratio of the basic components, were detemined* Thepre- sence of benzoic acid in the reaction mixture during its reaction with 6 _ caprolactam is explained* Ten references: 7-USSR; 2-German and 1-TJSA (1843-1953). Table. Institution: The Textile Institute, Leningrad Submitted : July 3, 1953 virocess of formati OUPOIYAlnidd reSilli_ V. Pallid, A -ti-- of p I at reac tiona Sh al'uyl (T~Yftiic In.91, urivi). zhur. Obsh- N q',"171, 6- c- 49 MD-4(T t ' , , In tile course of,tran-f6rLatim, of caprolactant, into VIC - take UM pru