SCIENTIFIC ABSTRACT SHOSTENKO, YU.V. - SHOTS, G.B.

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CIA-RDP86-00513R001549920006-5
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December 31, 1967
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SCIENTIFIC ABSTRACT
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USSR/Chcmistry - Alkp1oids Aug 52 "A Study of the Desc.-ption of Molecularly Idsorbed Substances by a Stream of Solvent," N. A. Izmaylov, Yu. V. Shostenko, Khar1kov Sci Res Chem-Phar Inst "Zhur 11rik nim" Vol 25, 140 8, pp 876-883 Using chloroform and activated carbon, the depend- ence of the kinetic coeff of the desorption of caf- feine on the rate of the flow of solvent was detd. Examn of the rates of flow of the desorbing solvent shmed that 75~ - 80~ of the aasorbpd substance w4s desorbed relatively rapidly, and that the ant of caffeine desorbed was directly proportional tc the vOl Of sOlvent_passing through the column. The remaining 20% 25% Of adsorbed substance was desorbed relatively more slowly. During this Stage, the quantity of substance desorbed by that vOl of solvent dininished on transition to In- creased rates of solvent fjow. There was an es- sential difference between the curve of distribu- tion of caffeine on carbon obtained under dynamic c'Onditions of desorption by chloroform, and the curve calcd on the basis of the isotherm of ad- sorption from chloroform under static corditions. 228T19 TROPP, M.Ya.; SHOSTENKO, Yu.V.; KOLMNIKOV, D.G. Spectrographic investigation of cardiac glycosides from the hellebore. ZbiLr. ob.khim. 23 no.8:1421-1425 Ag '53. MRA 6-8) 1. Kharlkovskiy nauchno-issledovatellskiy khimiko-farmatsevticheakiy institut. (CA 4? no.22:12759 '53) (Glycoaides) (Hellebore) H 05 -r I- N Ko YO J,o--besorptlon of molecularly absorbed subfftancoa with Soxhlet- a SPPAratUX. VU. V. ShCkgttnkO (SCI. Research Chem.-AiTaprm. Inst. Kli-arKovi. MR. '7 am. S.S.S.R. JADIOSS, No. 2, 35-8; cf. C.A. 48, 0151O.-Dtiorption of caffeWe by CHC4 and CH,CIC11,CI from activated C in a Soxhlet app. Is studied by varying the flow velocity of solvent and packing ratio of C In the Soxhlet app. , No equilibrated conditions were observed. Complete desorption can be ob, tained; hence for laboratory purposes this continuous method is to be preferred over a column. CHC4 appears to be the AID P - 2758 Subject USSR/Chemistry Card 1/1 Pub. 119 - 6/6 Authors Izmaylov, N. A., Yu. V. Shostenko, and S. Kh. Mushin8kaya (Kharl MV) Title Principles of adsorption techniques for isolation of substances from solutions Periodical Usp. khim. 24, 3, 346-376, 1955 Literature on the adsorption from solutions used in industry and the advantages of this method over extraction from solutions is reviewed. Selection of adsorbents and solvents is discussed. One table, 12 diagrams; 71 references (59 Russian: 1929-1955) Institution : None Submitted : No date !~y,m~-m;ZITrPeju~. V SHOE =-TIKO, Yu. V., Candidate of Chem Sci (diss) -- "T"he P-yr,-mics of molecular and ion-exchariSe adSorpt4 on and desorption of organic stfostances as the I u I basis of the technolog7 of their adsorption isolation from soluzions". Kiev, 19~9- 19 pp (Acad Sci Tr1w SSR, Tnst of Phys Chem Im L. V. Pisarzhevskly), 220 copler, (n, IT(-, 20, 1959, 1019) SHOSTENKO, Yu.V.; SIMON, I.S. Quantitative determination of santonin in extracts of Artemisia cina and in eluates. Apt.delo 9 no.1:59-60 Ta-F 160. (miRA 13:6) 1. Iz laboratorii fizicheskoy khimil Kharlkovskogo nauchno- Issledovatellskogo khimiko-farmateevtichaskogo instituta. (SANTONIN) IZVAYIDVY M.Z. [deceased); SHOSTEIIITKO, Yu.V.- MqILI, V.D. Use of polymeric materials in partition chromatography with inverted phases. Dop. AN URSR no.2:201-205 162. (MIRA 15-.2) 1. Kharikovskiy nauchno-issledovatellskiy khimiko-farmdt5evti- cheskiy institut. 2. Chlen-korrespondent AN USSR (for Izmaylov). (Chromatographic analysis)(Polymers) ve SIMON, I.S.; SHOSTENKO, Yu.V. Study of alkaloids extracted from lobelia (Lobelia urens). Zhur.ob.khim. 32 no-31lOO2-1004 Mr 162. 04IRA 15:3) (Alkaloids) ORLOV, Yu.Ye. (Orlov, JU.IE.); DZYUBA, N.P.; SHOSTENKOP YU.V. Quantitative determination of Ichellin in combined medicinal preparations with the use of the polarographic method. Farmatsev. zhur, 18 no.5:36-39 163. NIRA 17:8) 1. Kharskovskiy nauchno-issledovateliskiy khimiko-farmatsev- ticheskiy institut. C At-PRA/Enc _Pr I*Vu j3p(c) R*Atf/ !'ACCESSION NR: AP5015695 UR/0076/65/0391096/1536A53~ 543.~544 AUTHOR: Igna~qy., Yu, Shostenko, Yu. V. Gubina,. T. NO TITLE: !Effect of deep cooling on the properties of ion-- exchangers SOURCE: Zhurnal fizicheskoy kWmii,'v.' 39, no..- 6, 1965, 15.116-1537 TOPIC TAGS: ion resin exchanger, ion exchange, morphine adsorption, resin cooling go calcium adsorption, adsorptive capacity ABSTRACT: The effect of low temDeratures on the properties of KU-1,, KU-2, and KFU ion exchange resins was studied by immersing the latter in liquidnitrogen. for .10 hr,' then keeping -them in air at room ternperaturefor h.r. No changes in adsorptive capacity (determined by adsorption of calcium ions) or, in. external: appearance were obs erved. The swelling increas ed by 15- 20176.. B ecaus e of , this 'increase, it was.expected :t that the ion exchangers would perferentially adsorb organic Ions as compared to untreated exchangers. Static experiments with morphine hydrochloride confirmed this hypothesis. -J~ It is concluded that the thermal treatment of condensation cation-exchangers may be used to alter their selectivity, particularly in the adsorption of large organic ions. Pre- liminary exposure of ion exchangers to low temperatures is preferred to treatment at high C-rd 1/2 i I i i i . I I I N I- I I i I I - "I I I I I I I i II I f ra t In -rlhYdr Ou s croqttantities by a (1~11111L 18:3) 3-i~r -farmatsavticheslrdy B.-, x~imiko 5110~,.TEIIKO, Yu.V.; R-A.-CHINSKIY, V.V. Nikolai Arl-adievIch Izmallov and I'Jar.11a Se=en-Ovna Shraiber, creators of thin-layer chrorutography. Zhux.fiz.1--him. 30 no.7,1802-1803 JI 1015. 18:8) t f~ ~Yc)