SCIENTIFIC ABSTRACT SHOSTAKOVSKIY, M.F. - SHOSTENKO, YU.V.

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CIA-RDP86-00513R001549920005-6
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December 31, 1967
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SCIENTIFIC ABSTRACT
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P U STAY v A.S.; MIRSKOVA, Ac-N'. 5H0, and transformations of polyhydric alcohols Part 1i ,vr-he~-,s ~lnd trarisfonmati=s of some esters Cl- pr'yhydn- alcohol.--,. Zhur. ob. kh~m~ 15 no.5;804-807 Mv 165. ~~vn~he~,Is and transfcrmatiofs of pclyhydric~ al::~!-hols. Part 2, ,31r-~.hes4s r,-,; Trip Uhy! ole tbane and ite, derf";zatives. Zl-~ur. ob. khim. 35 nn.5A07-809 T,~v 165. (M-IRA ig-,6), I. '--',~,atskiy Irs"ILut oraanioheskoy Khimii Sibir3kogo otdeleniva. AN AW-v`-K-7.~ M,F~~ A-S.; YEGOROV, N.V. Synt,heslls cf prfmary and accetyle-nic -1-col!-ols. Zhur. ob, W-P. 35 no.5:8M-311 MY '65. (MTRA 18:6) L S*birskogo otdel-3n-tya rkut63k -y institut organicheskly k-h!T- AN S-13 S R ~ 1,~ , i I _i SHOSTAF,OVSKIY,, M~7,, mTTf"y,(JV4 R.~J. S-,rnthes-s of crasinot'-n ac=tvlenic ethers. Zhur. ob. khLr. 35 c no.6:1121 je 16-5. (MIRA 18:6) 1. Irkutsk-fy institut organicheskoy khiniii S,..b.-rskogo ctdeleniya AN SSSR. _':'PICX~T AV, Tt'-' ERG TNA , N I. IN 4ARCR v r~4!'Ccl SDeCtra of some dlacetvlene orcancailicon comov.-w-ds. Zlhair. :b. Khlm. 35 no.9,,165C,-1654 ': 165. k4ap-A 18~101 --,r'l(.utskiy institut crganicheslicy I~nlmii Sibir3kogo otdeleniya SHOSTAKOV IM ---~.3K -E,? ATOPT, '.S.~ LAVROV, VI,- 'ROFIMOV, B.A. Reaction of vinyl ethers containing a dialkylaminomethoxy group with ethyl mercaptan. Zhur. org. khim. I no.6sll69-1170 Je 165. (MIRA 18-.7) 1. Irk-atskiy institut organicheskoy khimii Sibirskogo otdeleniya AN S99R. VASIL'YEV, G.S,; PR.ELT-'ZHAYEVA, Ye.N.; BYSTPOV, V-F,; SHOSTAKOVSKIY,-B.-F. Structure of products of the react-,on of (alkoxy a lkylthi abut -3rynr--.;:, with phosphorus pentachloride. 7hur. 0r),. khim, no.8:1350- 1357 Ag 165. (MIRA lgz8), 1. Institut organicheskoy khimii imeni D. Zeinskogo AN SSSR. II- L 00266-66 ETEF (C)/F--JT (M) IaTf(j) /T RPL F14AA-1. ~ACCESSION NR; APS013446 UR/0020/65/162/001/01S~0126 4 !AUTHOR.- Shostakovskiy, M. F. (Corresgonding member AN SSSR); Skvortsova, G. G zapunnaya.T. G. ozyrev, ~155 :TITLE-. Concerning the structure of copolymersl~f acrolein%ith v~~r ~lesterA ISOURCE: AN SSSR. Doklady, v. 162, no. 1, 1965, 124-126 ~TOPIC TAGS: copolymer, polymer structure, IR spectrum, acrolein, vinylaryl ester ;ABSTFACT: In order to determine the structure of the copolymers of acrolein with Ivinylaryl esters, assumed to be 2-phenoxy-3,4-dihydropirane, the IR spectra shown :in fig. I of the Enclosure were examined. There is a good agreement between spec- 1tra 1 and 2, a,.-id the literature data on IR absorption for 2-phenoxy-3,4-dihydropi- Irane. There also is a good agreement between spectra 3 and 4. Similarly confirm- ;ed were the structures of copolymers of acrolein with ortho-, metha-, and para- 'cresyl and vinyl esters of thymol. "The authors thank N. I. Sher in,and N. 1. i - 9 as., f 'Golovava for their assistance in making the IR spectra." Orig. art g- ure, I fofl~a. +1 I Card 1/3 L oo266-.66 ACCESSION RR: APS013446 ENCLOSURE: 01 Fig. 1. 1--2-phenoxy-3,4-diiiydropirane obtained by thermal diene synthesis; 2--2-pbenoxy-3,4-diliydropyrane obtained in: a 60-70% yield from the product of copo- lymerization of acrolein with vinylophenyl ester; 3--a polymer of 2-phenoxy-3,4- i dihydropirane; and 4--a copolymer of acro';_ lein with vinylphenyl ester. .,I so 0 40 40 700 900_11OL7 JJW 1500 cjy-I Card -3h SHOST AKCA; ~')K I f , M ~ F. j KEYIKO , N . A . ~Iylltll(-,Iis ")1, ['14.1, AIN ",)SSH 162 nc;.~~-J62-363 My 16, 5 . (MIRA 18:5) 1. irkutskiy institut organi0-,qkov kh-L,,rdi Sibirskogo otdeleniva AN SSSR~ 2. I,hlen-korrez3pcjr,!-l(,nt N "STR (f.-.~r Shostakovskiy). -6269,4-65 AccEssm NR: AP5018748 The reaction is autocatalytic., Iul addition, --thexeaction. cAn.be ca.used to take the following. coiwse In the presence of excess acet~lenlc component- CRI + U10. P,3SnOSnR,, + 2R'C CH 2%&C The associated side reactions are described. The mechanism of the reaction studied;,.~ involves an electrophilic proton attack of the oxygen atom and interaction with the acetylenic aniow. G R* B + BasnoH.- +'R#SnOSnR# H-0 xsu The pbysicocheinical constants, of thesynthesized compounds are tahwhb6d.- The procedurbs; followed in the preparation of trimethylethynylstannage. bis (tri-p-propY14"Y1)ace-. j tylene, triethyLitanny1diacetylenei and triethylatannylethynylvinyldiethylamine, and in the reaction of hexaethy1distannoxane with triethyleftaylatannane and of the latter with triethylstannancd are described. Orig. art. hast. I table and 10 formulas. 2/3 I~rd -If ~w SHOSTAKOVSK"i"t, 114,6~i ATAVIN, A-';.~ 'FR0FVVVq B.A., VYALYKII, Yed. 7 ome ccnvers-,ors of alkoy-ysJ111nes, anal alkrx,,ac Y.-Y San e s L , eto ,-Orit,aining acefal vings. Zhur. ob. kh4lr,. 35 no.10-i,"q-1763 (MIRA 18:10) v-sk"y ~nst' '---t or~araicheskoy- kii-4mj--' SJbirskogo o-Ael~naya AN SSISR. bI.F.; ATAVIN9 K,;netir--s of hydrolyF-Is ~-dioxoiaries . izv. SO AN SSS:R~. ir'Futsk--'Y inatitut crgan"cl-leskoy kh--'n- L b. ot.Aelcniya Ali SSSR. ? -* N. V. - i I L I - - -- .. I Kil i 114F 'I'TAV V IIS L V f E.- r a t on ny FL!,ho, o :)l zv `:0 AN F-SSR no. F, 8 7'SH. II.A.; 1AVROV, (3,-.Llt~~r!LLM 1r, f,~-e Illydroly0i:3 ~; U ethers '163 '65. Sibirskogo otdp-len-'L",a Ih, J 7 AN S C. j (for Shostakovsk4y). Mt I 'i A FOON't, 7D17L IF - .1 V- nq,IF~rf-rol fj-. none co- ~!.T~m-ers tl~, ally-'- derne d ace ta-te . Izv. A:T SSSR.Ser.'ihim. no.l0.-1eS`-1SA2 (?.TPA 18: 10) i T,, s k- o y k h Urn m, D Z (-- 1, i ris k o c- o SS -1! R. -,iL crirarnl'ne L - S,HQSTAKOVSKIYJ, M.F.; VLASOV, V.M.; KUZNETSOVA, T.S. Dis~roportionation of acetala of acetylete glycols. Izv.AN SSSR.Ser.khim. no.12.-2198-2199 165. (MIRA :L8:121 1. Irkutskiy institut organicheskoy kbimii Sibirskogo otdeleniya AN SSSR. Submitted April 5, 1965. SHO-SITAKHOVSKIY,. M.F.; ATAVIN, A.S.; PROKOPIYEV, B.V.; TROFIMOV,"'*P~,~-; IAVROV., V.I.; DERIGLASOV, N.M. Kinetics of hydrolysis of monovinyl ethers of ethylene glycol, di-, and triethylene glycols. Izv. AN SSSR. Ser. khim. no.8: 14-85-1487 165. (MIRA 18:9) 1. Irkutskiy institut organicheskoy khimii Sibirskogo otdeleniya AN SSSR. S110STAKCJVSKIY.pA,,F,; ATAVIN, A.S.; RIKITIN, V.M.; TROFDtGV, B.A.; VYK-6,- V.V.; LAVROV, V.I. Synthesis and some transformations of vinyl silyl ethers of gl7cols. 1zv. AN SSSR. Ser. khim. no.11:2049-2051 165. (MIRA 18.-11) 1. Irkutski7 institut organicheskoy khinii Sibirskogo otdeleniya AN SSSR. SHOSTAKOVSKIY,;M.F.; SHERGINA, N.I.; GOLOVANOVA, N.I.; KOMAROV, N.V.; BRODSKAYA, E.I.; ~USYUNAS, V.K. Vibrational spectra of some organotin acetylenic compounds. Zhur. ob. khim. 35 no.10:170'8-1770 0 165. (MIRA 18:10) 1. Irk-utskiy institut organicheskoy khimii Sibirskogo otdeleniya AN SSSR. - E y F. G Ij'- G-L N 13:6 :'2 I rhitskiy ins t i r1l 3 rcrar. i olle Vn i ko~D o t, erl v i~:[ SSSR. Submittel Ac.,ril . ~z xv. IJOWYA, K.14. SffWlr&K"Cl.'l-K Y, m , , , -,'i - - 1. .)f A N S S, V S---T n'O M -RA ]l 13 A I ~'j 1. 1 S i b] rC i;h,--l.k~y kh AN SSES.F., L 7895-66 EWT(m)/EPF(c-)/EWP(J)/Ewp(t)/E~IP(b)/EWA(c) IJP(c) JDIV24 ACC NR: ILP5024967 SOURCE CQtE: UR/0286,/65/09,0/016/0032/0032 AUTHORS: Shostakovsk4,_M.__K.; Vlasov, V. M.; Mirskov,, R. G . ORG: none all TITLE: Method for obtaining organic tin compounds Ibless 12, No. 173757 SOURCE: Byulleten' izobreteniy-.i.tovarnykh znakov, no. 16, 1965, 32 TOPIC TAGSs tin compound, acetylene, VAV0--4X- ABSTRACT: This Author Certificate presents a method for oktaining_organic 'tin compounds having an Sn-C bond by the reaction of acetylene'leompounds containing free hydrogen acetylene with organic compounds of-The-Yy-pe.-\R3Sn0R' (R - alkyl, aryl; RI - R, H, SnR3 ). To broaden the selection of organic tin compounds, com- pounds of the formula CH =- CRff (Rn has various meanings, e.g., -CH2CH20CH = OH2j, -CH2qCH(4C4Hq)CH3, -CH20CH3, -CH2OSn(C2H5)31 besides -C05) are used as the ini- tial acetylene compounds. The process is carried out in an organic solvent, e0ge) benzene or toluene. SUB CODE: 07/ -SUBM DATE: 05Nov63 Card 1/1 V,~-) UDCx 547.419.6.(y7 r. 30992-66 EWT (-ri-) /9-TP RM :ACC NR.- AP600?-~!O SOURCE CODE: UR/0286/65/000/023/0017/0018' AUTHORS: Shostakovskiy, M. F.; Atavin, A. S.; Vyalykh, Ye. P.; Trofimov, B. A* IORG: none'- A method for obtaining organotin vinyl glycol eaters. Class 12, ]go. 1765 2' SOTJRCE: Byulleten' izobreteniy i tovarnykh znakov, no. 23, 1965, 17-18 TOPIC TAGS: organotin compound, organometallic compound, glycol,.ester ABSTRACT: This Author Certificate presents a preparative method for obtaining organotin vinyl glycol esters by interacting the sodium derivatives of hydroxyl- icontaining vinyl esters with alkyltin chlorides. '-SUB CODE: 07/ SUBM DATE: 1qOct64 Card ---UDC: 547 419.6.07 S-HOSTkKOVSKZY, M~F.3 VLASOV, V,M,; SKVORTSOV, Yu.M.; L'VOV, A.!, Synthesis of v-i-.iyl ethers of ace-zvlenic alcohols by indirect vi.nylation. Zhur. org. khim. 1 no.8i15141-1515 Ag 165. (MIRA 18:11) 1. Irkutskiy institut organicheskoy khijn:'1 S'-'bllr,,,kogo otdalenlya AN SSSR. L 29293-66 --EWP(j)/EWT(m)/T RM ACC NRt AP601()317 SOURCE CODE: UR/0079/65/033/008/1350/1357 AUTHOR: Vasillyev, Go So; Prilazh;Weva, Yeo N Bystrovt Voi FG; Shostakovi~~ M. F ORG: Institute of Organic Chemistry im. N D. Zelinsldy, AN SSSR (Institut organi-71." ohaskoy klhildi AN SSSR) TITIE: Structm-e of.products of the reaction of (alkoaW)al~rlthiobuter Stith phospborus pentachloride SOURCE: Zhurnal obahchoy )diimiip v. 35# no, 80 19651 1350-1357 TOPIC-TAGSt phosphorus chlor e,:chemical reacti - -pr - "1 0 8UUW #d onj, o~oh resonance, organi compound ABSIRACT: S~nthe -ais -.by-other.methods and study of proton magnetic'-.' ~resonanoe spectra Indicated that addition of PM to 1-alkylthio- *(alkoxy)butenynes takes place at the triple oarb9n-oarbon bond with the forma-tion of chlorides of 1-alkylthio(alkoxy)-3-chlorobu- ;tadiene- 1,314-phosphiao acids Tt was established for the first ~tIMG that 9LCLCLIr.10n or alooftols diaeatylene under the conditions :of a nuoleophillo reaction proceeds stereospeoifically with the formation-of ols-l-alkoxybutanynes., Thereaotion of diaoetylene ,with one moleaule of a thiol (MeSK) under nuoleophillo conditions also resulted in a produot (l-Me-th1qbut6-,qne) wit1h a ois-struc-' Itures It was shownthat In produots of the addition of P01 to Card me I IT ss"R. 1. Erkutskiy ins-titut organicheskoy kh-indii llibirskoi-o i - otdel,enlya APT SSSR. Submitted August 5, 1963). EwP(j)A,wT(m) RM SOURCE CODE: AUTHOR: Sho13 M. F. Sherginap N. I.; Kagany G. I.; Komarovp N. ve TITLE: InVestigation of the vibrational spectra of certain carborWI-containing silicoac2tylene c I I SOURCE: Refo zb. Fizika, Abs. 1ID186 REF SOURCE: Mr. Komis. po spektroskopii., AN SSS~Rj, t. 3. vyp. ii, 1964) 92-98 -TOPIC TAGS: silicon corq)ound, acetylene compoundp ir spectrump vibration spectrunp ohemical bondim ABSTRACT: The auth sr estigated the ir s ectra of 16 silicoacetylene compounds which were Bywthesl2red or the first time. The frequencies of the vibrations of the fundamental groups are classified. It, is shown that the frequency of the oscilla- tions of the acetylene bond, which contains.the silicon stom in the a. position, changes with the character of the radical R. On the basis of the values of the vibrational frequencies for the bonds r=SiCCmC- and -GaC- it is noted that these bonds do not interact. CTranslation of abstract] SUB CO1:,E: 20, 07/ Card L 36921-66 EJVT(M)/EWP(j) RM ACC NR- AP6008504 SOURCE CODE: UR/0062/66/000/001/0101/0104 AUTHOR: ShostakovskiX, M. F.; Komarov, N. V. : Yarosh, 0. G. URG: Irkkusk Institute -oL_Qrganjg Cljprni.*,~j~y, ;3~~bcrizin Dj~RpLyLnent.AN SSS~ (irkutskiy institut organicheskoy khir-nii SibirskoZ;o otdelte~i:.ya Akademl-i nauk SSSR) TITLE: Synthesis of trjpjkXlethvnv Is i lane Ind silicoacetylene al SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 1, 1966, 101-104 TOPIC TAGS: chemical synthesis, silane, alcohol -1 S141roAJ ABSTRACT: In this investigation the authors attempt to find a simpler and more convenient -nethod of synthesizing monosubstituted silicoacetylenes. The reaction of sodium acetylene with bis(trialkylsilyi) sulfates is investigated for the first time. Tile inr~3stigation showed that the reaction occurs normally and leads to the formation of triall-