SCIENTIFIC ABSTRACT SHOSTAKOVSKIY, M.F. - SHOSTAKOVSKIY, M.F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549920002-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

85659
Z 2_ o 5 1 11 12. 1~6 S/079/60/030/009/016/022/XX
BOO1/BO66
AUTHORS: Shostakovpkiv., M, F-, Guseynov, I. I,, Shmonina, L.
Vasillyev, G. S., and Lopatin, B, V~
TITLE., Synthesis of Compounds of the Type of 11-Alkoxy-2-
oxy-chlorophosphine-3-chlorobutadienes-1,3 I
PERIODICAL: Zhurnal obshchey khimii, 1960, vol. 30, No, 9.
pp~ 2836 - 2838
TEXT: The present paper deals with the reaction of ethinyl-vinyl
alkzl ethers1with PC1 (a reaction that has not been described as
yet), They suggest th2 following scheme:
ROCH~CH - 0 CH + 2PC1 5-------)IROCHC1 CHPC1 4- C -~CH I PC1 5]
OCH ==-CPC1 CC1===CH ROCH
R 4- 2 PC151 + S02 --7 CPOC12
I
- M ~ CH 2+ 2SOC1 2 + POC1 3
Card 1/3

Synth-esis of Compounds of "he Typ,-l 079/60/030/009/01 6/022/XY
~ -1 -,orophosphlne--~-
Alkoxy-2-oxi-ch- BOOl/B066
,j
chlr,robutadienes-',
~SSOCIATIONi Ins~lut or-anicheskoy kh-imil Akad.emi-l nauk SSSR
(Institute of GrFamc Cherp--istri,, of' the Academy of
Sciences USSR)
SUBI,TI TITED. August ~5, 1:959
Carl 5/3

S "G3G- ~009/022/022 -X-~-
BOO,1/BO66
AUTHORS: -Shostakovskiz. All Fel, FrileZilayaVaro Ye. N, Tsymoal:
and Stolyarova-1-17-G .
TITLE: Stereochemistrylof Addition React'.ors to the Triple Bond
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol, 30, No. 9.
pp~ 3143 - 3144
TEXT; There are no data available in publications on the stereo-
chemistry of addition reactions of any reagents to the triple bonds of
diacetylenelor vine' ! acetylene systems, nor on the stereochemistry ~Df
fh-~ r--actions of homolytic addition of thiols e(to acetylenes, The
authors indicate that the stereochemistry OT reactions of diacetylenn
(I) with alkyl thiols (II) giving 1-alkyl-thiobuten-1--4nes-3 (III)~
investigated previously by them, as well as of reactions of compounds
(III) with (II) giving the '~,4-dialkyl-thiobutadienes-!,'; (IV), take
C, .1
place according to the scheme given here. The geometric structure (IV)
follows from the sulfone structure (V) which was confirmed by means of
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Stereochemistry of Addition Reactions S,/079/60/030/009/022/022/XX
to the Triple Bond B001//BO 6
dipole moments; ultraviolet and infrared spect:?a,. as well as by
quantitative isomerization of the cis-cis and cis-trans compounds (V)
into the trans-trans compounds M, under the action of iodine, Thus,
the thiols add stereospecifically in nucleophilic reactions with the
C_~z~_C bonds, both in diacetylene and vin 1 acetylene systems, according
to the rule of "trans-addition" (Ref., 2~, Under free radical conditions;
the reaction does not proceed quite stereoselectively, so that mix--
tures of cis-cis and trans-trans isomers (IV) are formed at low
temperatures., The predominance of (IV) indicatE!s a high specific
gravity of the cis addition of the radicals. At. elevated temperatures,
isomerization to the trans-trans compound (IV) occurs, It was also
found thac the reaction of ethanethiol with ethyl-thio ethine (VI)
(Ref. 3) proceeds stereospecifically both under free radical and ionic
conditions, and obeys the rule of "trans-addition", since (VII-Cis)
is the main product yielding the sulfone (VIII-cis). Under free radical
conditions., thiols may react with various acetylene compounds stereo-
chemi.cally in different ways, This is always due to the stability of
one of the geometrinal foT7rs of the radi.--a', Rg(.'H.-=,-CX which appears
Cazd 2/3

84866
S/079/60/030/010/002//030
B000075
AUTHORS: Chekulayeva, I. A., and Kondrat'-
yeva, L. V.
TITLE: Reaction of Diacetylene~with Amino Alcohols and Amines.
II. Synthesis of 11-Alkyldiaiiino-1,4-butadienes-1,3 and
N,N-Dialkylamino-l-buten-1-:Lnes-3 7
PERIODICAL: Zhurnal obahchey khimii, 19150, vol. 30, No. 10,
pp, 3179-3183
TEXT: The authors had shown in Ref. 4 that the reactions of diacetylene
with ali-ohatic amines and P-(dialkylamino) ethanols start at room tem-
perature and proceed exothermically withou-. a catalyst. This paper gives
a detailed description of these reactions in which the nature of the ini
tial amine plays an essential Dart. Thus, primary amines react with
diacetylene to form IT-alkyldiamino-1,4-buttidienes-1,3 M (80% yield)
according to the following formula:
2RNH2 + CH=-C-C=-CH ~o RNHCH=CH-CH=CHNHR (I) (I a): R = n-C 4H9;
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84866
Reaction of Diacetylene With Amino Alcohols S/079/60/030/010/002/030
and Amines. II.. Synthesis of N-Alkyldiamino- B001/B075
1,4-butadienes-1,3 and N,N-Dialkylamino-1--
buten-l-ines-3
(I b): n-C 5H11 ; (I v): iso-C 5Hil . Secondary amines react under analogolus
conditions, forming N,iN-dialkylamino-l-bui;er-l-ines-3 (II) (60~. yield)
according to the following formula:
R2NH + CITI=_C-C~_CH ), R2NCH=CH-C~_CH (I-E) (II a).- R = C2H5
(II b): n-C4H9; (!I v): n- C5 H11. The addition of the amines to com-
pound (II) requires harder conditions. The diene structure of the reaction
products was proved by spectral analysis and by diene synthesis with
ethyl vinyl sulfone. The structure of the products obtained by reacting
diacetylene with secondary amines was proved by hydrolysis. The synthe-
sized Droducts are unstable liquids which are only stable when kept in
0 0
sealed ampoules between -50 and -70 .Dienes M and (III) absorb car-
bon dioxide from the air and form solid, stable carbonates. The spectral
analysis carried out by B. V. Lopatin confirmed the presence of the
group - C-1'_O in the dienes obtain There are 1 table and 6 referencesi
~0_
3 Soviet, 2 German, and 1 US.
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8h866
Reaction of Diacetylene With Amino Alcohcls S/,079/"0/030/010/002/030
and Amines. II. Synthesis of N-Alkyldiamino _ B001/B075
1,4-butadienes-1,3 and N,N-Dialkylamino-l-buten-
1-ines-3
ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry of the Academy of Sciences
U LR)
SUBMITTED- August A, 1959
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84867
(a-~ Z2 ocs, 12 73
E_.U00
S/079/60/030/010/003/030
BOO1/BO75
AUTHORS: Shostakovskiy, M. F., K.ondratlyev, Kh. I., and Gorban', A.K.
TITLE: Investigation in the Field of Synthesis and Conversions
of Oxygen-containing Organosilicon Compounds. IX. Synthesis
of Organosilicon and Naphthyl-containing Acetals
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol. 30, No. 10,
PPo 3183-3186 q
TEXT: In Ref. 1 the authors showed that -the reaction of vinyl alkyl ether
with silanols led to the formation of mixed trialkyl silvl alkyl acetals:
CH 2~ CHOAlk + HOSiR3 CH3 CH____~ OAlk
~'-OSiR 3
The subject of the present paper is the reaction of vinylethyl, vinyliso-
propyl, and vinyl-n-butyl ethers with a-Tiaphthyl dimethyl silanol W.
Compound (I) was obtained by hydrolyzing the acetic acid ester of
a-naphthyl dimethyl silanol. Shostakovskiy and his collaborators (Ref. 1)
have found that,due to an ionic mechanism, vinyl alkyl ether reacted
Card 112

84867
Investigation in the Field of Synthesis S/079/60/030/010/003/030
and Conversions of Oxygen-containing Organo- BOOI/BO75
silicon Compounds. IX. Synthesis of
Organosilicon and Naphthyl-containing Acetals
easily with silanols in the presence of traces of mineral acids. However,
organosilicon acetals were found to be formed even without a catalyst.
In this case, the yield is very high, whereas in the presence of acids
(Refs. 1, 2) side reactions take place, such as hydrolysis, dimerization
of the silanols, and polymerization of the initial vinyl ether. The struc-
ture of the acetals obtained was proved by hydrolyzing them with 2~6 sul-
furic acid under the formation of a-naphthyl dimethyl silanol, acetalde-
hyde, and the corresponding alcohol. The a-naphthyl dimethyl silyl alkyl
acetals (II) are colorless, very mobile liquids which are soluble in
ordinary organic solvents but insoluble in water. There are I table and
2 Soviet references.
ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry of the Academy of Sciences
USFR)
SUBMITTED: December 14, 1959
Card 2/2

is oLq
87539
S/079/60/030/012/027/027
BOO1/BO64
AUTHORS: Shostakovskiy, M. F., Sidellkovskaya, F. P., and
Ko 1 on-i
TITLE; Sulfides Containing Lactam Cycles
PERIODICAL; Zhurnal obshchey khimii, 1960, Vol. 30, No. 12, PP-4108-4109
TEXT: Independently of recent.publications (Ref.1), the authors
synthesized the following compounds by reacting the sodium salts of
lactams with allyl halides: N-allyl-a-pyrrolidone (I), N-allyl-F--capro-
lactam (II), and N-allyl-a.-piperidone (III) which had hitherto not been
described, Their polymerization and the copolymerization of compound W
with methyl methacrylate a-nd methyl acrylate were studied (Ref.2). The
hitherto unknown addition reaction of the mercaptans to the compounds M
and (II), and to N-vinyl lactams was studied. When these two compounds
were heated with equimolar amounts of ethyl mercaptan (IV), n-butyl
mercaptan and the ethyl ester of thioglycolic acid (V) in the presence of
the dinitrile of azoisobutyric acid (0.5% of the total weight), in the
ampoule at 70 - 80 0 C, compounds of the general formula
Card 1/2

S/080/60/033/0,4/40/045
AUTHOFS- Shostakovskiy, M.F., Sidelikovskaya, F,,P , Ogibina, T.Ya.
TITTLE. A Refractometric Method for the Quantitative Determination of G(-
Pyrrolidone in a Mixture With a' -Butyrolactone
PERIODICAL- Zhurnal prikladnoy khimii, 1960, Vol 33, Nr 4, PP 978 - 98o
TEXr- OL -pyrrolidone is obtained by the interaction of ff-butyrolactone with
ammonia. In the final product there are admixtures of butyrolactone. In the literature
there is no method to be found for the determination of OL -pyrrolidone in the presence
of 'r -butyrolactone. For this purpose the refractometric method is proposed. Standard
mixtures of o( -pyrrolidone in the presence of r -butyrolactone were prepared and their
refractive indices were measured. The data obtained are shown in a table and a graph.
It is evident that the refractive index increases with the concentration of pyrrolidone.
On reaching a pyrrolidone content of 35 - 40% in the butyrolactone solution the average
increment of the refractive index becomes a constant value, being 5-0~-10 on the
average. The method of pyrrolidone determination has an accuracy of - 1%.
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S/080/60/033/04/40/045
A Refractometric method for the Quantitative Determination of OL -Py--rolidone in a
Mlx+ure With if-Butyrolactone
19here are: 2 tables, 1 graph and 5 references, 3 of which are Soviet and 2 German. '11-1
ASSOCI-ATIM. Institut organicheskoy khimii imeni N.R. Zelinskogo AN SSSR (Institute
of Organic Chemistry imeni N.D. Zelinslciy of the AS USSR)
SUaMITTED I August 13, 1959
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Boo66
7 00~6
S/02 60/132/01/40/064
Boll B126
AUTHORSt Shostakovskiy, M. F., Gracheva, Ye. P., Kayutenko, L. A.
TITLE: Synthesis and Conversions of Trialkylsilylethinylvinylalkyl Ethers
PERIODICAL: Doklady Akademii nauk SSSR, 196o, vol. 132, Wo. 1, pp. 153-156
TEXT: The object of the authors' work is to study the interaction of ethinyl-
vinylalkyl ethers with trialkylchlorosilanes. The ethers mentioned in the title
were synthesized via the organomagnesium derivative, which was produced, not in
tetrahydrofuran (as in Refs. 13, 14), but in sulfuric ether (2), (3). Both these
reactions take place under mild conditions. The trialkylsilylethinylvinylbutyl
ethers that were obtained remind one, because of their chemical properties, of
the ethinylvinylalkyl ethers which contain no silicon. Both are easily hydrolized
with 2% H2SO4 The former have also, however, some peculiarities. The hydrolysis
performed to detect their structure has shown that a splitting of the Si-C bond
takes place (see scheme). The butin-l-al-4 that is produced by this reaction is
isomerized to tetrolaldehyde. Unlike the silicon-free ethinylvinylalkyl ethers,
trialkylsilylethinylvinyl ethers are not hydro-enated via Pt02-H2O or via Pd
precipitated on calcium sulfate. Their hydrogenation succeeds only via a mixture
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80066
Synthesis and Conversions of Trialkylsilylethinylvinyl- S/020/60/132/01/40/064
alkyl Ethers B011/B126
of 2% Pd/CaCO 3 and 5% Pt/C. Trimethylsilylbuto3:Y-4-butadiene-1,3 was obtained by
a gradual hydrogenation. The latter is condensable with maleic anhydride and
forms the adduct (A), from which butylalcohol and trimethylsilanol are split off.
Under the conditions of the reaction the latter gives hexamethyldisiloxane. The
authors have established that the adduct is a phthalanhydride. The silicon-
rich ethinylvinylbutyl ether cannot be converted either by heating with
butanol without a catalyst or in the presence of from 1-276 of basic or acid
catalyst into trimethylsilylbutin-l-al-4-acetal. There are 1 table and
17 references, 4 of which are Soviet.
ASSOCIATION; Inatitut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk
SSSR ( hemistry imeni N. D. Zelinskiy of the
Academy of Sciences, USSR
PRESENTED: January 8, 1960, by B. A. Kazanskiy, Academician
SUBMITTED: December 24, 1959
Card 2/2

SEO-STAKOVSKI-Y, ~LF.-:--BO-GDANOVA, A.V.; MUM, T.M.; LOPATIN, B.V.
Vinyl compounds in diene synthesis. 'Stereospecific orientation
of the diene synthesis of vinyl aryl others condensed with
cyclopentadiene in relation to the temperature. Dokl.AN SSSR
132 no-5:1118-1121 Je 160. (MIRA 13:6) ---
1. Institut organicheskoy khimii im. II.D.Zelinskogo Akademii naii
SSSR. Predstavleno akademikom B.A. Kazanskim.
(Ethers) (Cyclopentadiene)

83558
S/020/60/134/001/'010/021
5^'U 10 BO16/Bo67
AUTHORS: Shostakovskiy. M. F.,_ Corresponding Member of the AS USSR,
Sidelfkovskaya, F. F., Kolodkin, F. 4,
TITLEi On the Interaction Between Lact mi and Diacetylene
2am-a-,
PERIODICAL: Doklady Akademii nauk SSSR, 1960) Vol. 134, No. 1,
pp. 102-105
TEXTt It waa th p r e of the present paper a) to produce valuable
e us;08
unsaturated compound with conjugate systems of multiple bonds in com-
bination with such heteroatoms as oxygen# nitrogen, and sulfur by-re-
acting lactams with diaoetylene; b) to compare the activity of acetylene
with that-of diao etylenein their reaction with laciams. The authors
studied the addition of laotams to diacetylene by the example of pyrroli-
done. CoWpared with acetylene, this reaction takes place much more readily
at 20-35 C at atmospheric pressure. Sodium salt of pyrrolidone served as
catalyst. In benzene medium the process takes place much more rapidly than
dioxane. The isolated crystalline main product (I) of the reaction cor-
responded to monopyrrolidonyl buteninse Besides, small amounts of an
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83558
On the Interaction Between Lactame and Diacetylene S/020/60/134/001/010/021
B016/Bo67
isomeric compound (II) were isolated. The IR epeatra (taken by T. 1.
Shkurina and B.Y. Lopatin, collaborators at the Optical Laboratory of the
authors'-inotitute) excluded the lactim, allene-, or butadiine structures.
The authors concluded from an almost complete agreement between the ab-
sorption frequencies that the stru'otures of I and II are 6quals The hydro-
genation product of I is identical with N-n-bixtyl pyrrolidone (IV). This
proves that I has the structure of I-N-(a-pyr:rolidonyl)-l-buten-3-ine.
This is proved by the formation of triaoetyl 'benzene in boiling I with
5% H2SO4. The most likely cause of the differences between I and II as to
the melting temperature, solubility, and lower stability of 11 is probably
the monotropic molecular dimorphism* By hydrolyzing I and II under less
rigid oonditionsp the carbonyl compound, formed was converted into 2,4-di-
nitraphenyl hydrazone (DNPH),by direct additiorl of 2,4-dinitrophenyl hydra-
zine (DNP) to the reaction mixture4 In,this connection, the hitherto un-
known 2A_DNPH 0 1 H N 0 (VI) was isolated. The authors proved that (VI)
in a derlyative of 1512N2(a-pyrrolidonyl)-l-tiuten-3-one (V~.,.,which is formed
as a result of the h;dration of 1-N-(a-pyrrol.idonyl)-l-buten-3-ine on the
triple bond. Ketone V was isolated under mild conditions also without the
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83558
On 'bP Interaction Between Lactams and DiAcetylene S/020/60/134/001/01-0/021
B016/Bo67
additict, of DNP. The degree of conjugation in the molecule is high, The
readine.-i; of hydration of the triple bond in N-pyrrolidonyl butenine is
probabl-.%, 7c.,nnected with the interaction between the C-0 group of the
-sctam ring and the vinyl-acetylene chain by means of the nitrogen atom.
IN (a-pyrrolidonyl)-1-buten-3-ine adds one thiophenol molecule in the
of azo-iso-butyric acid dinitrile, and forms 1-N-(cr-pyrrolidonyl)_
a -c~,t,ny~z-hio-1,5~butadiene (VIII). Analytically pure VIII, however, is a
m-.x*nre of isomers which could not be separated by crystallization. There
ar~ 1 !';gure: I table, and 10 references: 6 Soviet, 1 US, and 1 German~
A~~SOCIATION: Institut organicheskoy khimii im~ N. D. Zelinskogo
Akademii nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences, USSR)
Mny 4~ 1960
3/5

84667
2 zo (3 S/Q20/60/135/001/020/030
BOf6/BO67
AUTHORS: Shostakovskiy, M. F., Correspond 'ing Member AS USSR,
Chekulayeva,--I-.--A-., Kondratlyeva, L. V., and Lopatin, B.V.
TITLE: Structure and Some Properties of the ProJucts of Interac-
tion Between Diacetylene and Alk yl Amines
PERIODICAL: Doklady Akademii nauk S R, 1960, Vol. 135, No. 1,PP-101-104
TEXT: In studying the reaction of diacetylene with primary and secondary
alkyl amines (Ref. 1) the authors observed that the N-alkyl-diamino-1,4-
butadienes,-1,3 and the N,N-dialkyl-amino-l-butenines-3, respectively, are
the main products. The authors succeeded in isolating the geometric iso-
mers of N,N-diethyl-amino-l-buten-l-ine-3 (I and II) from the reaction of V
diacetylene with diethyl amine. The chemical transformations and the data if N
of spectral analysis prove that I and II have cis- and trans-structures,
respc~ctively. On heating, isomer I passes over into II. The UV SDectrum
of II is more intensive than that of I. In the IR spectrum of I, no ab-
sorption bands were observed in the range of from 800 to 1000 cm-1, -in
the IR spectrum of II, however, an intensive absorption band is observed
at 945 cm" which is characteristic of a trans-confIguration (Table 1).
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84667
Structure and Some Properties of the Product.3 S/020/60/135/001/020/030
of Interaction Between Diacetylene and BO106/BO67
Alkyl Amines
Furthermore, an intensive absorption band is observed in the spectrum of
substance I at 692 cm-1 which is interpreted as the CH-vibrational de-
formation of the isomer. In spectrum II, no corresponding band exists in
this region. The IR spectra of the isomers I and II were taken on a spec-
L-rophotometer of the type UR-10. The pictures showed that the bands of
the double bond are split into two components. The intensities of the
components are not equal. Substance I and II may only be geometrical
or place isomers:(C-H ),)NCH=CH-.C;;--CH and CH ',N(C H - In the
-I e 5 ~ 1 2 =' 2 5)2_C ~CH'
range 885-895 cm and 3075-3095 cm of the IF, spectrum of both substan-,
ces, nc absorption bands are observed which are characteristic of a
terminal double bond. This confirms the cis--trans isomerism. On the basis
of the investigation of products of the addition of amines (III), alcohols
(IV), and mercaptans (V) to I and II, the place isomerism- seems to be
excluded (see Scheme). In the reaction of n--amyl amine with the isomers
I and 115 1,4-amino-substituted butadienes (III) were
formed under analogous conditions which
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8h667
Structure and Some Properties of the Products S/020/60/135/001/020/030
of Interaction Between Diacetylene and B016,/Bo67
Alkyl Amines
had the same phyaico-chemical constants, formed the same picrates, and
also had similar IR spectra. The IR spectra of products of the addition
of butyl alcohol (IV) and ethyl mercaptan (V) to I had no absorption bands
corresponding to theterminal. double bond. This excludes the presence of
this bond in the initial isomers. Hence, the addition with the formation
of I is the most essential Doint in the reaction of diacetylene with di-
ethyl amine. This agrees with the results obtained by the ion reaction of
the thiols with diacetylene which is stereospecific and proceeds according
to the method of the "trans-addition" rule. 11-butyl-diamino-1,4-blitadiene-
1,3 (VI) with cis-cis configuration of the substituents with respect to
the double bonds is the main product resulting from the reaction of di-
acetylene with n-butyl amine. The structure of VI was confirmed by a,diene
synthesis and by data of spectral analysis. `R spectra of butadiene VI Ix
in a polar and a non-polar solvent showed that the position of the ab-
sorption bands of >C=N and >C=CC=N (1684 cm-1 in the IR spectrum) was also present
Card 3/4

84667
Structure and Some Properties of the Products,3/02o/6o/135/001/020/030
of Interaction Between Diacetylene and 3016/B067
Alkyl Amines
in a second substance which wa s formed in a small amount in the reaction
of diacetylene with n-butyl amine. This substance will be further investi-
gated. There are I figure, 3 tables, and 3 references: 2 Soviet and 1 US.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR
(Institute! of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences, USSR)
SlJBMITTED: July 18, 1960
Card 4/4

ARBUZOV, A.Ye., akad.~ VAVILOVi s.I., akEd.;-V0L'FK0VICH, S.I., akad.;
KOCHUIA, P.Ya,,, akad.; IANI~S13ERG, G~S.v akad.; LEYBENZON, L.S.j,
akad. PORAY.-KOSHITS, A.Ye.,, akad.; SMIRNOV, V.I., akad.; FESENKOV,
V.G., akad.?, CHM1YAYEV,'V.L, ahad.; XAPUSTINSKIY, A.F.; KORSHAK,
V.V.; KRAVKbV, S.V.; NIKIFOROV, P.M.; PETROV, A.D.; PREDVODITELEV,
A.S.; FRISK, S~E.; CHETAYEV, N.G.; CII-WTOV, V.K.j_�HO5
KUZNETSOV, I.V., red.; MIKULUiSK1Y, S.R., red.; HURASHOVA, N.Ya.,
takhn.red.
[Men of Russian science; essays on prominent persons in natural
science and technology: Mathematics mee-hanics, astronomy2 physics,
chemistry] Liudi russkoi nauki; ocherki o vydaiushchikhsia deiate-
liakh estestvoznan-4ia i tekhniki: matematika, mekhanika, astronomiia,
fizika, khirnlia. Moskva, Cos. j.zd--vo firiko-matem. lit-ry, 1961.
599 P. (MIRA 14.10)
1. Chleny-korrespondenty Ali SSSR (for Kapustinskiy, Korshak, Kravkov,
Pikiforov, Petrov, Predvoditelev, Frish, Chetayev, Chmutov, Shostakovskly).
(Scientists)

LOTAICOVSTH f/ F - KVOPT30VA, C.G.; Sil!"Olf AF 17 Y!
_$ .- S L---,-S -I'. *LCVA, N.Ya.; Z UIMA L, K.1.;
KOSITSYM~ E.I.
Vinyl compouaids. Izv.Sib.ota.AJ7 SSSI, no.1!36-43 161. (-"11:.A 24Q)
1. Vostochno-Sibirskiy filicl Sibirs',:o,-o otdeicniya '.'I S401-1
(Vinyl comFolmds)

1TGDiJ*Cj'h'-, A.V..; USF~IKGW~,j T.H.; LOPATIT"y -!-~.V.
Virryl corpounds in the diere sy-nthesis. Report Yo. 4: Compamtive
characteristics of the Cien-ophilic activity of vinyl End
thiovinyl others, and optical P+~i:dy of the Ldducts obtained. Izv.
All SSSR. Otd. khim. nawk nc. 1:12G-127 Ja 161. (21-URA 14:2)
1. L:stitu'u organicherkoy kIdmii im. N.D. Zelinskogo kH SSSR.
(Ethers)

SIDELIKOVSKAYA, F.P.; ZELE1ij1,AL`Lj M.G.; SHOST~.KOVSK!Yq M.F.
Lactones and lactz~ms. Report No. 17: Dienophilic activity o--:,
u-vinyl lactams and of the vinyl ethcr of 11-(e-hydrox-jethyl)
pyrrolidone. Izv. AT SSSR. Otd. 'ehim.rauk no. 1:128-135 Ja 151.
Mr-21- 14:2)
1. Institut organicheskoy Ichimii im. I.I.D. Zelinskogo AN SSSa.
(1,actums) (Ether) (Pyrrolidinone)

.SHOSTAKOVSKIY, M.F. ; SKVORTSOVA, G.G. ; SWOYIDVAp M.Ta.; 7APUNNAYkt K.V.
tinyl compounds-. Report No.2t Copolymerimation of-vinyl esters of -
the cresol fraction of semicoking tar with acrolein in the presence
of ionic catalysts. Izv.Sib.Otd.An SSSR no. 2:50-56 1 61.
(MIRA 14:3)
1. Institut khimii Vowtocbao-4ibirskogo, filiala Sibirskogo
otdoleniya AN 330, Irkutsk. -
(Vinyl compounds)
(AcTolein)

-SHOSTAKOVSM,--M.-F-., UVAPOVA, N.I.
Synthesis and certain properties of vinyl boronyl ether. Izv.
AN SSSR. Otd. khim. nauk no.2:343-348 F 161. (KM 14:2)
1. Dallnevoptochnyy fillal Sibirskogo otdeleniya AN SSSR i instit-tt
organicheskoy khimil im.N.D.Zelinskogo AN SSSR.
(Ether)

I I
~#OSTAKOVSKIY, M.F.; SIDELIKOVSKAYA, F.P.; ZELENSKAYA, M.G.; SHKURINA, T.)T,.
- OGIBINA-,--f.-Yi-.
I,actones and lactams. Report NO.18: Reaction of vinyl lactams
with hydrogen chloride and alcohols. Izv.AN SSSR Otdakhimonauk
no.3:1+82-1+87 Mr 161. (Mm 14:10
1. Institut organicheskoy khIndi imeni N.D.Zelinskogo AU SSSR.
(IActams)

20941
2 2/062 "1 /000/003/008/013
,01-"7/B208
AUTHORS: Shostakovskiy, M, F., Khomutov, A~ M_. Baykova, R_ I., and
Kayutenko, L, A.
TITLE: Studies in the field of chemical conversions of unsaturated
and high-polymer compounds. Report 17. Synthesis of
polymers and copolymers of bis,-(metiiyl-2-buten-i-yne-3)alkyl-
silanea
PERIODICAL: Izvestiya Akademii na-ak SSSR. Otdeleniye kh1michesk1kh nauk,
no. 3, 1961, 488-49,
TEXT: The authors report on the study of polymerization and copolymeriza-
tion of: bis-(methyl-2-buten-1-yne-3)diethyl silane, bis-(methyl-2-buten-
l.-yne-3)dimethyl silane, and bis-(methyl-2-buten-1-yne-3)methyl-propyl
silane. Freshly distilled monomers were used. Copolymerization was
carried out continuously for 100 hr at 600 +_ 10C. Azoisobutyric acid
dinitrile was used as an initiator in a quantity of O~2 % of the total
weight of the monomer- Control experiments for investigating the poly-
merization of initial monomers were carried out under 'the same Conditions-
Card 1/3

20941
3/062/61/000/00AI/008/oix,
Studies in the field of chemical... B-,17/h20F,
Bis-(methyl-2-buten-1-yne-2)diethyI silane readily polymerizes at room
temperature on the air and in the presence of initiators. The polymers
are transparent, hard, and three-dimensional substances- They remain
unchanged when heated to 4000C. During copolymerizatior with methyl
methaorylate, polymers of different composition are formed, according to
the concentration of the initial monomers in the reaction m'edium- The
copolymer yields were found to decrease with increasing content of bis-
(methyl-2-buten-1-yne-3)diethyl sil&ne in the reaction medium from 10 to
25 mole%. They change little later on. The number of silane links in the
copolymer increases as its concentration in the reaction medium rises-
The resultant copolymers are hard, I light yellow substances with high di-
electric properties: ?, = 10"-10 f3 ohm-cm. Bis-(methyl-2-buten-1-yne-3)
diethyl silane was used for "cross-linking" in the polymerization of
methacrylic acid and styrene, For comparisonj the copolymerization of
methyl methacrylate with bis-(methyl-2-buten-1-yne-3)dimethyl silane and
bis-(methyl-2-buten-1-yne-3)methyl--oropyl silane was studied at equal molar
ratios. It was found that those copolymers have the highest yields and the
highest content of silane links, which contain links of bis-(methyl-2-
buten-1-yne-3)diethyl silane. There are I figure, 5 tables, and 6
Card 2/3

20941
S/062/61/000/003/008/013
Studies in the field of chemical... B11?/B208
references: 3 Soviet-bloc and 3 non-Sovlet-blo;_~.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademil
nauk SSSR (institute of Organic Chemistry imeni
N~ D. Zel-inakiy, Academy of Sciences USSR)
SUBMITTED: November 19, 1959
Card 3/3

BATUYEV, M.I.; SIMNINA, L.I.; MANEYM, A.D.; SHOSTAKOVSKIY, M.F.
Optical study of the structure of some 1. 2. 3z-substituted 2, 3-
butadiones. Izv.AN SSSR Otd.kh"nauk no.3.513-516 Me !61.
(MIR& 14:10
1. Institut goryuchikh iskopetyem;7kh AN SSSR i Institut organicheskoy
khImii imeai N.D.Zelinskogo AN SSSR.
(Batadiene)

20942
S1106216110001003100910!3
2
Is-'p. 05 B 17/B2O8
AUTHORS: Shostakovskiy~ M. F. and Shapiro, E.. S.
TITLE- Synthesis of phthalyl glycine vinyl ester and some of its
conversions
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimiche8kikh
nauk, no. 3, 1961, 517-519
TEXT: In this news in brief,the authors report on their method of direct
vinylation of N-substituted C~-amino acid. Phthalyl glycine was used as
standard substance. Vinylation was carried out in a rotating autoclave
with a manometer and a thermocouple vrith automatic temperature regulation.
The reaction took place at a high acetylene excess in absolute dioxane
medium, i.e., under conditions that had been repeatedly applied with
success by the authors. Anhydrous z-.Lnc acetate was used as catalyst. The
corresponding vinyl ester was thus obtained in 80-85 % yieldt
CO
0 H NCH COOCH= CH is a crystalline substance insoluble in most
6 4 CO 2 2
Card 1/3

20942
S10621611000100310091013
Synthesis of phthalyl glycine vinyl... B117/B208
organic solvents, in petroleum, and in water. This fact is used for puri-
fying the vinyl ester from the initial phthalyl glycine in those caseg in
which vinylation does not quantitatively proceed, Some conversions of the
respective vinyl ester were studied. Its hydrolysis was found to occur
under more rigorous conditions than in vinyl alkyl estersi i..e., on heating
to BOOC with 15 % sulfuric acid. Thiols are added smoothly and quantita-
tively during catalysis with a radical initiator, thus giving the
corresponding sulfides; phthalyl gl-cine-~-ethyl-thioethyl ester
C14H1504NS, boiling point 1390-1410C (0.015 mm); phthalyl glycine-p-butyl-
thioethyl ester C16H1904NS, boiling point 1500-1520C (0.008 mm). After
distillation, both sulfides become nearly colorless, viscous liquids which
crystallize on standings After recrystallization from petroleum ether,
their melting points are 430 and 370-380C, respectively. In the presence
of the dinitrile of azoisobutyric acid and benzoyl peroxide, the phthalyl
glycine vinyl ester is poljmerized. Also its copolymerization with methyl
methacrylate was shown to be possible in principle, There are 3 tables
and 6 references: 2 Soviet-bloc and 4 non-Soviet-bloc,
Card 2/3

20942
S/062~61/000/003/009/017,
Synthesis of phthalyl glycine vinyl ... B117/3208
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akadem-4i
nauk SSSR (Institute of Organic Chemistry imeni N. D . Zelinskiy,
Academy of Sciences USSR)
SUBMITTED: May 4, 1960 (initially)
October 9, 1960 (after revision)
Card 3/3

GHEKULAYEVA, I.A.; SHOSTAKOVSKIY, M.F.; GLADYSHEV..,KAYA, V.A.; LIPOVIGH, I.V.
Synthesis and transformations of vinyl ethanol-in ethers.- Part 13;
Copolymerization of some vinyl ethanolamine ethers with methacrylate.
Vy.gokom.soed. 3 no.6:901,-9CY7 Je 161. (MIRA 14:6)
1. Institut organicheskoy khjmii imeni. N.D.Zelinskogo.
(Ethanol) (Methacrylie acid) (Polymerization)

SHOSTAKOVSKIY M-F,- LASKORINY B.N.; NIKULISKAYA, G.N.; CHEKULAYKVA, I.A.;
IOANISIANI19 P,G,,
suspension polymezizatiozi of the trivinyl ether of triethanolaminat
Synthesis of a new anion exchanger. Vysokom.soed. 3 no*62908-91-1
je 161. (KERA 14:6)
1. Institut organicheskoy WWI imeni N,D.Zelinskogo AN SSSR.
(Ethanol) (Ethers) (Pol7wrization) (Ion exchanger resins)

25260 s/igo/61/003/007/004MI
B!01/B208
AUTHORS: Shostakovskiy, M. F., Sidellkovskaya,'. F. P., Ibragimov, F.
TITLE: Copolymerization of vinyl pyrrolidone and vinyl caprolactam
with dimethyl vinyl ethinyl carbinol
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v, 3, no, 7,~ 1961,'
TEXT., The purpose of the present paper was to study the fundamental.
rules governing the copolperization of vinyl. pyrrolidone (VP) and vinyl
caprolactam (VC) with dimethyl vinyl ethinyl carbinol (CARB). -It was of
interest in this connection that CARB is the raw material for the
so-called carbinol glues. The following formula is given for the
structure of the copolymers:
M12-CH . . . . . . . .
IM,
N (C112)'CO C
C
C (C H3)-- OR
Card 1/5 n 3~ 5._____

v

' 2526a S119 61/003/007/004/021
Y
Co
polymerizat ion crf-vinyl pyrrolidone B101
B208

For the links of the copolymer which consist of carbinol, also the
formation of
* cyclobutene rings is possible. copolymerization was
e
~formed in
p ampuls at 6 OC for 72 hr. 0.2%
0 azoisobutyric acid.dinitrile
was added as initiator. The results for VC + CARB are as follows:

initial mixtu
mole-;' 'yield of copolymer,C
re
"" composition of the
,
, copolyme
VC CARB VC CARB
0 76-5 100*. 0 0
90 10 18.7 65-7 34 3
75 25 19.7 38.1 61:9
50 50 33-15 87.4

25
75 59.1
4-8 95-1 50:
10 90 6o.7 was not determined
0 100 97-5 0 100:0
The compositi on of the copolymer was calculat ed'from its nitrogen c6ntent.;
The following was found for VP + CARB:
Card 2/ 5

Copoi,ymcrization of vinyl pyrroliap-ge6o...
initi.,rd mixture, ~,ole-,, yici(I of coj)olyn,(--,r,
U
7 -
u 7

7 -
2~ 75 'i
.1 Q0 7(,.-,"

S/190/61/003/007/0',)4/(.j2l
B101/jt206
6
4 2 5 i. a
7 .9 72.2
The conclusions 1) Thr,
CARD than the in it ial mix t urf.-1 ,vi e1 d 4.r C -rc"Le11n s 111;-
CARIB conlu-(nO .Tlie copcdymor~-, o f '..ypon vj,-r.-f, lcoaiuo ~?nl
irpollubl,~ in (Iiethy) et'll'.",
And v.-:tt()r. noti-,d -J )OOr in ljf the
he
copolymer 10" Ve and 9.0 d
copolymerp ;,or,.- -U
Cii.rd 3/5

2526o 3",
Copolymerizati,-.)n of vinyl pyrrolidenc, 13 1 L) I /D2 08
OCII 0
Cif CH CH- C,11 )-co,
1 c

,-avp
from that -j" t~Lo 1! 1: 2.-!; -P. ~i v J 1 i t v i :.C or
Vi, nf o o c; r . 2 nr -.;IP

re.;
a v
c c(-.,Yr r.o.5i t _4 on of r;O 2 t ve
mixtil-
tial ,:
o -.
a :p -I t ur i
i r i t
.
e ;. .
-
V--

VC 0
V ~A:?:;
V V-* 7

Thu co ',nlyme-t- ~i. e a, I' vt- j'4_, Im-formin~ o-ronortie!-
witil i I
ncrea2ing (;
,m.P.-,~ crtnn(nnt. -
e f.,LL,.UI:es, &n.:
3riviet-bloc
11'ard 4/ 5

,'5260 3/190 0 /003/007"n-04/021
Copolymerizaticn of v--'-nyl pyrrolidone B!01~B208
ASSOCIATION: Institut organ-icheskoy khimii im. N.D. Zplinskogo AN SSSR
T
(Tnstitute of Organic Chemi3try imeni ~.D. Zelinsl~iy,
AS USSR)
SUM"ITTED: Iujus? 7, !1)6o
Card 5/5

26290
S/190/61/003/008/003/019
B110/B220
AUTHORS: Shostakovski~M. Kotrelev, V. N., Kalinina, S. P.,
-Ku-znetsova, G. I., Layne, L. V., Borisova, A. I.
TITLE: Organotin monomers and polymers.IV. Synthesis and conversion
of tin-containing esters of acrylic and cinnamic acids
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 8, 1961,
1128-1130
TEXT: The present paper deals with the synthesis of organotin derivatives
of cinnamic and acrylic acids. Che synthesis was performed by a method
developed by the authors. The vaporous alkyl haliae was reacted in a tube
furnace or au'toclave with an Sn-Mg alloy in the presence of various solventA3
and catalysts. The alkyl-halide tin compounds formed were saponified with
lye to the corresponding hydroxy derivatives, and then the esters were ob-
tained by reaction with acrylic ar cinnamic acid. 1) Triethyl-stannyl
acrylate (C 2H 5)3 SnOCOCH=CH 21 was obtained from a 50~c aqueous solution of
acrylic acid at 5-100C by adding triethyl stannol. The white crystalline
Card 1/3

S/1902~2691~003/008/003/019
Organotin monomers and polymers ... B110/B220
precipitate (melting point 1020C) could be dissolved in organic solvents.
2) In the same way, tributyl-stannyl acrylate was obtained from hexabutyl
stannous oxide and acrylic acid. 3) The triethyl-stannyl ester of cinnamic
acid was obtained from cinnamic acid and hexaethyl stannous oxide accord-
ing to the equation (C2H5)6 Sn 20 + 2C6H5~ CHCOOH )2 (C2H5)3 SnOCOCH=CHC6H5
+ H20. The organotin compounds o~3tained-polymerize easily, and form trans-
parent solid copolymers with styrtane and methyl methacrylate. The thermo-
mechanical properties of some polymers and copolymers are shown in Fig. 2.
There are 2 figures and 3 Soviet references.
ASSOCIATION: Nauchno-issledovatellskiy institut plasticheskikh mass
(Scientific Research Institute of Plastics)
SUBMITTED: September 1, 1960
Card 2/3

2629
S/190$/003/008/004/019
B110/B220
AUMORS: Shostakovskiy, M. F., Kotrelev, V. N., Kuznetsova, G. I.,
-k-a-linina, S. P.,"Layne, L. V., Borisova, A. I.
TITLE: Studies on the sjynthesis and conversions of organotin
monomers and polymers. V. Study of the formation of
organotin polymers as a function of the polymerization con-
ditions, and some physicochemical properties of organotin
polymers
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 8, 1961,
1131-1134
TEXT: The present study deals with the yield in polymers of triethyl-
stannyl methacrylate and acrylate as a function of polymerization time,
temperature, initiation, and concentration. Benzoyl peroxide, azoisobutyric
acid dinitrile, or triethyl-,benzyl ammonium chloride served as initiators.
The results are shown in Fig. 1. The composition of the copolymer from
triethyl-stannyl methacrylate and methyl methacrylate was studied for
initial molar ratios of the components of 1:1, 1:4, and 1:12, At an initial
Card 1/5

?2517
S-,-~)7 0 0 2205 S/062/61/000/004/006/008
B118/B208
AUTHORS.- Shostakkovskiy, M. F., Komarov, N. V., Kuznetsovaj V. P., and
Ln
Igonina, I. I.
TITLE,~ Study in the 'field of synthesis and conversions of unsaturated
organosilicon compounds. 1. Esterification of primary and
tertiary psilicon-containing acetylene alcohols by adipic
acid
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
no. 4, 1961, 699-703
TEM The authors studied the esterification of primary and tertiary
Y-silicon-containing acetylene alcohols with adipic acid. This esterifica-
tion was accomplished by direct reaction of the alcohols with adipic acid,
and by reaction of these alcohols, or their magnesium derivatives, with
adipic acid chloride. The esterification of the primary F-silicon-con-
taining acetylene alcohols with adipic acid without catalysts takes place
either to form the acid adipic ester:
R3SiC-C-CH20H + HOOC(CH2)4 COOH ~,R3SiC~-C-CH2OOC(CH 2)4 COOH, where
Card 1/4

22517
Study in the field...,
S/062/61/000/004/006/008
B118/B208
R -- CH3i C2H 5Y and C6HV or to form the neutral adipic. ester:
2R3sic~c-CN20ff + HOOc(cH2)4 COOR >R 3sic - c-CH200c(CH2)4 COOCH2 C ~-CSiR 3;
where R - CH 3 and C6EY, deprrM&ng on the condItions and the quantitative
ratio of the components. This method is, however, not applicable to the
esterification of tertiary'r-silicon-containing acetylene alcohols, since
the reaction of these alcohols with adipic acid, with or without acid
catalysts (such as boric acid etc.) gives rise to dehydration of the
initial alcohols with formation of the corresponding silicon vinyl
acetylene hydrocarbons.
CH
1 3
R-Sic,---C----C--OH-----*!o.R Sic-~C--C~CH + H 0. where R = CH and G H Also
1 3 1 2 9 3 2 5*
Uti3 CH 3
the esterification of tertiary r-silicon-containing acetylene alcohols by
their reaction with adipic acid chloride in the presence of pyridine as
well as the ester interchange of these alcohols with dimethyl adipate
under the action of sodium ethylate were unsuccessful. The synthesis of
Card 214

Study -i n the f ield ...
22517
31
16/3208
*d
a
c -.nd neutral esters of -ertiary ~-silicon-contai.-Idn~- acetylere
alcohols -.,.-as accomol-ished 'by ::-eactiion of maggnesiwm alcohoiates v.--, nf~47"-,C
-IC4d chloride
R:,SiC~--C-UU,~lafir-',-k.IOC(CH..),COCI
CH,
CFI,
P"Sic =-C-COOC (CH2),COCI
u-i,
CH,
R,SiC=C-COO'\- (CH~)~CO09
~.-ard 3/4

Study in tqe field...
CH,
2[Z,SiC~--C-Coi%IgBr-~CIOC(CH.),,CO(' I
CH:,
22517
S/062/61/C00/004/CO6/CO8
B-,18/B208
CH,
R,SjC=(,-COOC(CH.,
CFI,
r,,Ie
There are 7 Soviet-blac references.
AISOC7 ' T 1 C', `:: 7rkutskiv Jnst-*t,.:,. c7-anich-~~skoy 4 c" 4 1~
~ ': -,birsogo
-j~dc',en-'Ya A', 5'--SH ln~Ftitu:te of Organic Chemistry
th e S ib e ri a n 3r a of e o 'f S c J- ences USS-L)
71-c~~-,-.--~-
Card 4/4

2253.8
S/062/61/000/004/007/008
00 12.05 B118/B208
AUTHORS; Shostakovskiy, Lt. F., Kaliberdo, L. M., and Komarov, N. V.
TITLE. Studies in the field of synthesis and conversions of un-
saturated organosilicon compounds. 2. Cyanoethylation of
tertiary T-silicon-containing acetylene alcohols
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
no. 4, 1961, 703-705
TEXT: Cyanoethylation cf secondary and tertiary silicon-containing
alcohols has as yet not been described, unlike that of the primary ones.
Thare are also no data available on the reaction of acrylonitrile with
silicon-containing acetylene alcohols, in spite of the considerable
impcrtance of the cyanoethylation of acetylene alcohols and glycols. The
authors therefore studied the cyanoethylation of tertiary r-silicon-con-
taining acetylene alcohols:
Card 1/3

2253.8
Studies in the field...
S/062/61/000/004/007/008
B118/B208
CH CH
1 3
R-Sic~--c--~--3-OH -t- CH ~CH-CN-->R CH CN, where R = CH and
6 3 CH3
C9H_ This cyanoethylation of acetylene alcohols was carried out under the
action of a 40% aqueous caustic potash solution and also of sodium
methylate. The catalytic effect of caustic potash solution gave no
P-cyanoethyl ethers. The application of sodium methylate permitted the
synthesis of A-cyanoethyl ethers of the silicon-containing acetylene
alcohols used (50-60% yields). The reaction is exothermic. Better yields
are obtained by using benzene as the solvent. The reaction of the
~-cyannethyl ether of 4-trimethyl-silyl-2,-methyl butyn-3-ol-2 with ethyl
ma.-riesium bromide gave, like several analogous cases, the corresponding
silicon acetylene ketone according to the equation
CH CH3
m
(CH ) Sic~_C-~ICH CH CN + C H MgBr-->(CH ) SiCiE~C_~___OCH CH CC H ~he
3 3 1 2 2 9 5 3 3 2 211 2 5'
tlti3 3 0
Card 2/3

2 er-~~_A
Studies in the field...
3/00'2/61/000/004/007/008
B118/B208
presence of a carbonyl group in this compound was confirmed by the forma-
tion of 2,4-dinitro-phenyl hydrazone. In addition to the formation of the
or-anosilicon ketone according to this equation also a cleavage of the
P-eyanoethyl ether takes place to give 4-trimethyl-silyl-2-methyl-butyn-
'-ol--2. Other conversions of the P-cyanoethyl ethers of tertiary
T-silicon-containing acetylene alcohols will be described in the following
report. There are 8 references: 4 Soviet-bloc and 4 non-Soviet-bloc.
The two refPrences to English-language publications read as follows:
R. Cookson, P. Mann, J. Chem. Soc. 618 (1947), 67 ~19401); S. Nozakura,
S. Konotsune, Bull. Chim. Soo. Japan 29, 322, 326 1956).
ASSOCIATION: Institut khimii Vostochno-Sibirskoge filiala Sibirskogo
otdeleniya AN SSSR (Institute of Chemistry of the Eastern
Siberian Branch of the Siberian Department, Academy of
Sciences USSR)
SUBMITTED; December 15, 1959
Card 5/5

V21-5,2,2' Zeec,--r,