SCIENTIFIC ABSTRACT SHOSTAKOVSKIY, M.F. - SHOSTAKOVSKIY, M.F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549910018-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

-
M
g ~va 7 V _
1; ~l
'~ v
LS
v
RICV~ Akud.
) J
'.
J
5
3
~
C.A Ila, I vvm-n polyawl ketl y
ment with a ttac.2 d 50~j,', 1kc]-fiff 0 ill IWO11 (vigurow; m-
UPtioll ). The ~"Ilpnjjs' wiliell 5,31. in tim. ust lat org'i
sulvei1s, had tfic d,-, al's'
-
'91123'
A tr'ol. wt., given)': (R cis, 0
1.461~j, 2545; Ell* 71), b.-)570, 1.4320, a~.34; Pr~ 90, Olt)wsl
isa-olr, 61, (h(J26'L 1.46-'0i 45W; Bu, 921"
1 A570, -17;JS: 0.9"G5,. 1 ~ 1 5,, 4 [83;
4'o-A: it, OAJ t ti , 1A60"% 40,18; CA), 815, 0.9 126, Mei,
1545;
1.4067, 4'182-
CA., 87.~
U'D-Ti2' 1"IGS2, 5ISS,
IAM A~ WW. L.FH

VDW174fives Orundfurated tertia" ate GIs L nffe-
dis of acetylenic acetals bas,nd on vinyt others anTacetylenic
:alcohols. M. F. Shostako-.skiT and I. A. Shilchiev (Just.
ACad. bm Akad -
a; ChT.10 _. -
uk, 1953, INI-7.-To 42
R., Oldel. Khiin. Na
MeC(OH)C,.. CH and 72 S. R tOCII -. CHt (which failed to
react alone) was added 0,02 nil, 30% RCI and the mixt.
allovmd to stand overnight: distn. after drying with KtCOz
gave 79.5% ArecHpa WesCiCH, bit.-it 42-30, dia
0.8701, ts"DO 1.4162, readIly, hydrolyzing In 2% H:SO4 to
AcH, EtOC;H:CH,, and a moderate yield of MeCII(OC-,
MejOCHN (1), L4 70~-82% d:4 0,6970i xT 1.4468. , Simi-
larly- 1,.;o-PrOCH:CH3 gave 70.5% J1eC11(OC1[,I[e,)O~
~CA ICIC11, b-,O 153-51, bit-ji 47--V, di-4 O.SMS, tjl~
fe
1.4150. Healing thii amal (42.6 %.) with 42 S. WIC.
(OH)C I CH In a at-iled tube 5-9 firs. At 170-180" rave a lit Oz
fiso-PrOH, 20.7 j. ),fe%C(OlI)C,'CH aria 46.4 k.crude(32%
pure)l,b,,74-6 d!1oO.80G7,n'DQI.44I2. iso-BuOMCH,
simiJarly gave 79,t te,Cl C11,
7, M,'C1I(OCHfC11Aff3)OCJ
dmO.M7 n'."1.4170. BuOCH-CH
3imilarly gav 531.0% 3fdCH(OA11)OC,1frjC,: CH. b:,
TheBuwdi--]Bu
derivs.,Nvere Most stable thermally in respect to r por-

2 'w I "Via" -, 'P. D
. "1105TAROV3M, V. F. DID- -- ~~Iml ) I I .
1
2. U-A)V (600~
4.. La c tam s
?. ketivation of vinylcaprolactan in the presence of hydrogen peroxide. Irv.
AN -3-31R. Otd. khim. naiA. no. 1, 1953
9. Monthly List of Russian Accessions, Library of Congress, June 195""'. Unclassified.

ye. -
~'l4 n,
L Uj: No
5 3
List of Accesoion-s. LLb""'41-Y, Of Gorilgress) Jurie Unci.

11 -;-T
on of the "Hon of metalllexlaad&.Z~t -Vol~-Mi liji:-7
qAz= of pqjZMLrkgticn of gyrene by ferric and stannic
eblorfdes. M. RShostakov-sk-if and 5. M ' Tnd&hevakp3jlvesIia,
.6 -~ rene
1953. No. the presence oT cC .6 C, st
does not polymerise in N, and I- lystyreuke and benzaldehyde
In airs wherew in presence of Sao, it Alymeris.,z in both N. d
Mu
PL C.

GHOST,,ROVSK.IIY, PRIIZZHAYFGVA, Ye..N.; &UPIRO. Ye.S.
Synthesis of sulfur compounds based on vinyl ethers and acetylen.3. Part
6. Reaction of merca-Dtans with vinyl ethers. Izv. AN SSSR. Otd.khim.
nauk. no.2:357-367 Mr-Ap '53. (MLU, 6:5)
1. Institut organicheskoy khimii Akademii nauk SSSR.
(Mercaptans) (Vinyl ethers)

SHOSTAKOVSKIY, M.F.; OBEKUIAYEVA, I.A.
Synthesis and transformations of vinyl ethers of ethanolamines. Part 3.
Nature of the double bond of vinyl ethers of ethanolamines. Izv. AN SSSR.
Otd.khim.nauk. no.2:368-373 Mr-Ap 153. (KLRA 6:5)
1. Institut organicheskoy khimii Akademii nauk SSSR. (Vinyl ethanolamine)

--�ynthe-,tIs of.mix Ipnd polyethers of y, nn"
alcohols. A. 11. )6
and F. V. %1114C A U.S.3114
nornik Statel ObjAcliel Khim. 2, - W-Ilf-311
-Y1 vinyl ethers over W- tAl-
(195.3).-Hydrogemition of alL
Ni alloy catalyst (cf. C-A. 31. RXV) mAily yields the cor.
respow ling mixed ethers. The caudyst ii prejul. by Ueat-
ment of 150 g. 60% Al-Mi alloy with.hM ml. .1% N%tOfl, then'
with a similurnint. ofNuOll after subsidence of t1u: reaction,
and 2 more similarmuts. after 3-4 lirs. Thecatalystretuins
appreciublearnts. ofAl, thustliffLringfroin thLcouventional
RuneyNi. The hydroge-antions were run at W-140atm. It
und gave about j5% yields of the satd. ethers. Thwi,
BuOCH:CIlj gave &OBu;' (CH.-OCH-Cif )2 ga Cli
-- - gave 11 t. b
01,03, and (CH,CJhOCH:CFf:). - LZ o~
G .1.
r
':J~
JAM.
D

SHWTAKOVSKIY, M.F.; MIKHANTIYZV, B.I.; OVCHINNIKOVA, N.N.
Indirect vinylation of monocarbonic acids and oxvacids. Izv.AT SSSR Otd.
)dlim.nauk. no-3:556-561 My-Je '53. (YURA 6:8)
1. Institut organialieskoy k-himii Akademii nauk =R. (Esters)

SHOSTAKOVSKIY, M.F.; GEMHTEYN, N.A.
Conversions of vinyl ethers. Chemical properties of alkyl-P -chloroethyl-
acetals. Izv.AN SSSR. Otd.khim.nwik no.4:7i6-720 J1-Ag '53. (MLRA 6:8)
1. Institilt organicheskoy khimii Akademii nauk SSSR. (ViVl compounds)

SHOSTAKOVSKIY, M.F.; MIEHiLNTIYJIV, B.I.; OVCHINNIKOVA, H.N.
Ionic copolymerization of vinyl ethers. Izv.All SSSR. Otd.khiw.nauk no.4:
721-725 Tl-Ag '53. (KTT?A 6:8)
1. Institut orgarxicheskoy khimii Akademii nauk SSSR.
(Polymers and polymerization) (Vinyl ethers)

o v
V M Chemistry - Synthesis
Card 1/1 Pub. 40 - 20/22
Authors Shosta o~s M.-S.; Shikfiiev, I. A.; and Kochkin) D. A.
TMA Synthesis and:conversions of oxygen-containing silicon-organic can-
pounds. Part 1.- Synthesis of silicon-organic acetals
Perlodical Izv. AN SSSR. Otd. khim. nauk 5. 941-944, Sep-Oct 1953
Abstract A new,synthesis of O-containing silicon-organic compowiids, based on the-
reaction of vinyl ethers and silanols, is discussed. It was established~
for the first time that triethylailanol condenses with vinylbutyl and
vinylisobutyl ethers in conditions analogous to corresponding syntheses
with organic alcohols. The synthesis of hitherto unknown nonsymetri-
cal butyl- and..,isobutyltriethylsilaiieacetals, is described., A new
method for the derivation of Various silicon-organic acetals, is pr4-
sented. Three USSR references (1933-1952).
Institution Academy of Sciences, Institute of Organic Chemistry
Submitted December 23, 1952

SHOSTAKOVSKIY, M.F.; SHIKHI)rBV, I.A.; KOCHKIN, D.A.
Investigation in the field of synthesis and conversions of silicon organic
compounds containing oxygen. Report no.l: Synthesis of silicon-organic
acetals. Izv.AN SSSR Otd.khim.nauk no.5:941-944 S-0 153. (KT-RA 6:10)
1. Inatitut organicheskoy khimii, Akademii, nauk SSSR.
(Acetals) (Silicon organic compounds)

SHOSTAKOVISKIY, M.F.; XHOMUTOV, A.M.
Research in the field of chemical conversions of unsaturated and high
molecular weight compounds. Report no.l. Copolymerization of metha-
cr7lic acid and vinylalkyl ether's. Izv.AN SSSR Otdkhim.nauk no.6:
1048-1055 N-D '53. Off-RA 6:12 )
1. Institut organicheakoy khimii Akademii nauk SSSR.
(High molecular weight compounds) (Methacrylic acid) (Sthers)

SHOSTAKOVSKIT. M.F.; MIKHANTIYEV, B.I.; GTCRINNIKOV~~, N.H.
Ionic polymerization of virql others. Izv.AN MR. Otd.khim.nauk no.6.,
1056-1060 H-D '53. (KLU 6:12)
1. Institut organicheskoy khimii, Akademii nauk SSSIR
(Vinyl others) (Polymers and polymerization)

SHOSTAKOVSKIY, H.F.; SHIKHIYBV, I.A.
Research in the field of the derivatives of tertiary unsaturated alco-
hols. Report no.l. Synthesis of acetylene acetals based on vinyl
ethers and acetylene alcohols. Izv.AN SSSIL Otd.khim.nank. no.6.-1061-
1067 K-D 153. (MLBA 6:12)
1. Institut organicheskoy khimii Akademii nauk SSSR.
(Acetals) (Acetylene derivatives) (Ithers)

SaOSTAKOVSKY, M. F.
301;. Methods of aualysi-s- of' halogenated,
1. Anab-sis of a-hrlogen-dIR&A and e TYI

AnalytiCal Abst. ethers. IAL F. lhastal ny5ky and A. V. Rq annya
S53, 8 141. 23)-234).--

Vol. 1 No. 2 Compounds of the type TCCFIICFfXOR' where
R = H or Cli,, X = CI or Br, and R' = AlkyI or
Feb. 1954 Aryl are hydrolysed instantaneously at mom temp.

Organio Analysis tn RCHXI-10, HX awl R'011 by excess n( water.
Detect on of the coinpounds can be based on tests
for aldehy(lc, hal id,,-, or acid. They can be det6r,
ininerl by h.ydrolysj4 followtA by titration withi
0-1 N NaOll. titraticti with 0-1 A' AgNO,
titration of tile ald'!hyd' with biquipbite..
nurnher of diffcrrnt C-impounds. x4re deterMinid-
in this way with excO Icut results. G. S. smllrl'i

Dec LIOU of benzoyl peroxide in the ialiciiii-r-4-017.
some compounds. M. F. Shostakov!,kif, E. P.
Gracheya, and V. A. Neterman. Zht:r. 06.4hefXhim. 23,
(12 g.) in 72A g. Cif2:CHOAc a.id-
'
34-7-5' in N atm. over 5 hrs.
120 g. petr. ether licatcd to
and 0.0366 g. 1120
with
-Iivc Q
0
CO;
015111
""C ,
,
,
,
,
~
94.337D decomini. leadli~g to 0 foiniation. The !,ccondary
source of COI appears to be destructive oxidation of CH
-Il
CM J
th
f CJJ
l
i
O
i
C
n
e presence o
ar react
on
H
Ac. S
u
j:
COIMe gavA: 0.4043 g. 0. 0.0171 g. CO~, and 0.05421
Tl-.O: whilo. tht reaction in the presence of PhCH:C112 gave
0.073-13 g. COI. The reaction in the'prespuce of CHj:-
ClIOAc gave sonie DiOH, poly-Onyl acetate, AcOH, aju:!L~
AcH. With Cfl_-:CNIFtCO;NIe the by-products included
poly-niethyl methitcrylate, while the reaction in the presence
of PhCH:Clf2 run similarly at 86' gave only 3.38% de- -
compn. of the peroxide to CGI. Heating 100 g. BuOCff:-
Cil,and 12g. BL;0,38 firs. gave 07.7 g. unchanged BuOCl-j-- 0
CH. and 4.7 Lr. product, b1, 74-5*, n'o' 1.4040, dia 0.8--60,
and 33.1 g. vi5cmjs solid, beziides 3.75 g. BzOIJ. Thedistd.
product "nalyxcd as CjWtA. Thus peroxides like DzOj
'4- serv: as supply of both free radicals and 0, the latter beiny
able to serve as a chain i-iittatcr in polymerization reactions
of vinyl deriv. pre;ient; in the system. Vinyl ethers are not
gilyrierlired by the--e tueLns as they are not polymerized
'
M
K
s
l
ff
Z.
o
o
apo
y atm. 0. C
,

SHOSTAKOVSKIY, M.F.; GRACBEVA, Ye.P.
Investigation in the field of synthesis and conversions of substituted
vinyl others. Part 1. Synthesis ofalt-substituted vinyl thters. Zhur.ob.
k.him. 23 no.7:1153-1158 Jl '53. (mLRA 6:7)
1. Institut organichaskoy khimii Akademii Hauk SSSR. Laboratoriya vini-
lovykh efiroy. (Ethers) (Vinyl derivatives)

SHOSTAKOVSKIY, M.F.; MIKIWITIYEV, B.I.; OVCHINNIKOVA, N.N.; NICTFJ04AN, V.A.
Synthesis of incomplete acylals of lactic acid. Zhur.ob.khim. 23 n0-7:
1167-1173 J-1 '53. NIJU 6:7)
1. Institut organicheskoy khimii Akademii Hauk =R.
(lactic acid) (Ethers)

I I b
ith 2 drops coacd. IICI reacted exothermically and distn.
0 the mEtture gave 81% Me,C(OBu)j, bs',O*, WR 1.4150.
dia 0.8303. This is completely hydrolyzed by ths-king I hr.
with 1% HrS04, yielding Nfelco. G. M. KosoLapoff

SHOSTAKOVSKIY, M.F.; FRILEMAYINA, Ye.N.; UVAROVA, N.I.
--- ~e- 7. r,-., --.
Azeotropic mixtures of vinylalkyl ethers and alcohols. Zhur.prikl.khim. 26
no.10:1074-1079 0 '53. (MI-7A 6:10)
1. Institut organicheskoy khimii Akademii nauk SSSR. Laboratoriya vinilovykh
soyedeneniy. (Azeotropy) (Vinyl ethers) (Alc,)hols)

Til

D. Matve,,va.
and A.

RkWdy 51
R
99
.
Raman spectra of runticutinyl eth(:rsbf glycol, CITACH-01G,
'
~
w
l
h

1954
10 aug-
k
ow, a
ave dlsvh
mment
a the Oil frequeney vjith_
.1 -1
1. ic
4114-
-band -at
*WL600 c
3
1
APT. r
_
.
m.
vyo- o,
,
i

GrgardO Obami trY ?-c6ple m6l. wts.-, als
o show amocn. I g with in&wsed
nmamn
f
h
th
In
11
e
:
W

Comen. o
e e
t
us
the bwrntric cyclic U
r
9 of
1
4
,;
gi5col
CH CfftGHh,,and (CH.CILO1I):, which cannot
t
i
form
d
zon
also b
pt. and lower: vi. coaltits'
than aro shown by t -omers:, vinyl glycol ethers - The-
heit. Is
latter'shbw isomtrizatiffll~ Into thincetali fit s6ln�- it, t0i','

this does not occur In Ciii, m. apa
Two] ff
F
7Z

F
SHOSTAY,.GVSKlY, M. F. - BATIUW, 11. 1. - TPIPAEV, P. V. - -XAVIEMIA, A. D.
Oxonium
Oxonium t',eory and its optical substantiation on simple vinyl. ethers.
Dokl. All SSSR 89 no. 1, 1953
9. Monthly List of Russian Accessions, Library of Congress, May 1953. Unclassified.

5w - s -ems%w
Stl OSTA K c)V 5 K ly

-S th I d tions:-- 6u bxygeii
-qn jran~fQrma -iontum
yu eslu
S.
an

c compoun Ihesis w inothy ethyl;
at y
v tri, " -, , - 11, : -
-sl , A
ISOM DO thylsilmo a
ceil, M. F. 164, kovskly. K.
Y, I~A 'Slilkbic~ An -D.A.- -Kochkill.,* Doklady
Mad. Nauk' S.S.*S.R. 93; 14(19.13); cf.-trecedingabstr. j
--fleating 33 9. MOW, 19 g~::AlcOCII:CFfj and -0.02 iid.
M% MCI in-scaled tubeAJ! Ing-at. (15' jivii .1% 9(",D -j
:Clf(OA1C)OSiMi, IJ6 74-11% it" %Wosn~ '33
Ets-siotl nad Etocllckl~ 1~ia,5 ailditrom." IfiL, 710--

Hlfflzindtlte*iiiixt,'%va'she4tedI lin1wWalid Idt live I
mtg it
a fter dqIng It j~dvd 45.1 % Ale CH(OFi)QSiF_6-,- b 78_9"

SiOH-with
30';i
_HCI catalyst jiiveaft4~rsAi,hli. in 13 scaled;
.
-a~-i-42";*3feCH(OCIIA[e,IOSiEI3~ bit- 87-9o
c at OV, g
M ff
7

SK I
w,:

oz ix-mitogianat ed it
I/ walmlizallon \f;7 P. losta
korgkil and cad. Sci.
P4,
loscolv). r =vest.. au
1954 - W2-5 -&L ell
uk d4filao Sta M a tayi 'Forl.

va
I
st,vwd inimiB Or yi~tr5 of itOCI e
lluocltm~ur kattaim.1, by'-p1do, tj en 21
Fur stabllh~Ltillll at el.eval,~tl lell ul laliqa
allit. of addeff -C~'O,ulust-be allailt5
ai 1)66L ShOll I IL
uctiall. 5 1

-

7-7
777
S~iOSTAKDVSKI' 4
Z:
ARea-Wan' f' I and func-t&W CGMF=d-- t
0 -vifty. poly
-
i
l

S S R Rkictiat
of viny
slkyl atheravith gtY4araL
. M. F Shoda~
kovskil.: V. V. Zhebrovskili and M;
(lost. Org,. Chtifi. A=d; ScL U.S.S.R.; Moscow).
M ad Nauk S.'s-SpR4 Oldd. KUM. -N"k'1964,: 16442!,

41'
Sa.-- US.S.R.. Div;::Meitt.: Sa. ~lm' - -
131

(
Milliall trafislation).-4tirriail ~ 14.4'9. -, C d
4 an
HtOCH H

tkccrbl PA hr. 6LAyst gaii
aeul adding, 1 drop 114
-
V
ater which
exothermic reaction (teviii. Am~to
the mlxt. was neutralized and mi 4
EtOff and MeCEI(ORth, and 17.9 g.-- crude, prod t, biA;'-
uc
'

7."3*, wl e 4-Ved iutp- pui-,--
ilch could not U r =patients.
c
r? lid bet - (1):
BZCl in, iio4u
j-2 40 -
-
L'bi'llatle" g
- I Z- id6tifiid i
liquid be
6~tei%)
1
V
.
nz
~
s
;
'
'85*. i4 4g 7
P-thylideneglyLerol benzzaale,'ra- -thff 1121
Pthylidene isomer, b$-12 16L-2'q J-
d:d J.IM8, ~iq, 15140

rid
heated with 1001o KOH until a clear ~oln-foime F ~ r-
cooled saln satd. w" KIC01-and extd. with Ft%0 yidde& -
35% 1,3-ethylideneglycerrjl,,bl~-1166-~g*, t0.6 IAL~j,
1.45,38- H imilar- 4370- I,Z~effiylid yeerl'
1-4436.
treat;1-

with 1 male glycerol did not f o
Ihesedelivs.; theproducW
rM
were EtOH, ~Mecff(OM)'. -knd~
To-25.G4 g. BuQ-'-'H:Cffi a-ad 2j g. glycerol wavadded 3.'~ -
and the tfiixt, heated 0 bi- to W. ~t
drops HCl cataly

which Cal. eXotheiMie Ctiolt -'took. pjace;' , dt1j!-
,oiRt rea
..rlization the aiixt.- yielded 11.87 g~ BuOH and 23 1&.*!
crude product, bu-s 95-103% which, benzoYlated as above.~
60 IL
yielded 9.2 g. BuOBz and, 29.08 9- n; wai found,
-lieved th-a g formation
It is bt. t the reaction proceeds throd h
of raixed aretals with subnquent cyclization to tbennal;
.7,
products. G. M. lCosol ff-

0.

-'synthesis of fsul or compounds fia
ll
l
V P
i
f
1
9
=

anit
aetir
ecu
ar
ckla o
at 0
tho 4
1
.
n of

Natok S.S.S.
K11103, Ou 954;.292-302;~O. C.A.48,0.41i,~~Adda..oU*~-'
A 14' to 11110CH. CH% is cu SHIA ouiitunta (if, 01
!

, V ~, SM
which lemlatkicontra-Mat
m", --ler of adda4l, a
dole and *)itte itcroxidL-3 ulso give this mult.-
'
hinder the wwtfoyl thu
Ing Its radlettl natu L P
uy clialn faicaking throtilth oxidatiou of chaia-leading trudl~
limthig I 1110)e~ RUCIC11. CH" wltll~

~ -:-,
Iequimourinixt, III tie'cold yicw.
,'
4
,
l
for u
Ocii; Cl 12 fitured 1111 .
long t
e t)Vei
tIM&
N;i
'
.....
peroxide test-reacts very sluggishly, but BuOICII..
CHOtored
jareiietsvortwally,
A good eatalytic ellect'is lra~
-d hy'all(lu.. of tics In 111..
ronoral tnothod of,~Byathefiirvof
Ibid. HS aad' ROCH! Cklijn. the.,
af, tiaeet * of - 0 yieldt, cite
present;u
*k1tylaierrAptnii4 and cormspaiding wslfides,~ PrC(G4iia1IElj'
on espechilly noted jjt')A-~
111roliCtleAl Ctht(fi, tead ta tht, iiorsual- adda.'
prodocW.,
Xmpblg 15 C. MOMIXII. iind 9.Tjr.,jI.S in jr,
%euledtubaJOduys gavei&O, 1~0C1401,S11;'b. 126-81';
nV 1.4465(4 dja (MM12, awl. .5.1 g. the
yiews R51ig CJ, 111., 144.5-151. PrOMIX11, -,%Oth:
Ut
6-1
1,4478., dN 0.9227, auO a mixturt-al (Procj[~ W
PrO C11, CH:SCH(O11r) Ate'. ti,,
1 7
(if tha hitter"obtuim3thv Wrotin1j; .jtjm%~~A& the I I
;ttter,
Milo" RQVQ;'tW lourt: j0m), -~ujjaje;~J),
d-019*14; Whose 111cl.m., 60-70'. Ite4v-1.1on a

wit~-ii..~' iti-16, gave 7 0i so-IrOCIT,-
(at n"ut Imp. the yield was 6811,1~1*, b44 150.1-6.4',
lal; 4121. d~v,3.9136. ~cnd, U-89% (dep~udiug mi reagent
(4,54--p~.001,C14hs. uIld iu.PkOCIACII~-
uppreciuble uluouut!~ of the:
tici; sL-r mAxturc yi,.Wed a(tLr the abuve treatidesit
pum (js,p-,Po*CIjrCJf,~6.% t4 W~-9.V. till 4~193 dl," .,,
(14 . Reaction 'WiL., is~'-junocu:clf' al te'rup.

M--F
-:)kia.- vi Kov K I
.i4.

n - , , - - , '. . - -6.
. ,~' - "', -~" ~` I ~
1 1..-, - J- ;I - --,
V., 4, .
- 1 -7 - -

StA OSTA Kov S K %y,
yn
yii
0,'gLhd blitYl di.

fthyl- ~S() 10"
tsLs of gueo
lth~
l ovs
aiol
ny
c 809-12
j

gV, .
- IV. (eth y1
-Rs!. lk esis of dimi
d eth teth I(eth- A ~ T yl)-.
'
y

. - . *
F 1. A.
Yf ac F -4. .49,-
lbid 821
and V
ii hiv
,
..38903.

U)
4-
0

- ..
-
"
' ....
,
.7
7
7
V,Trars ofinations of' viiiyl ai-YI, ethers, 1. Ionic' poly-~. `S~
of vinyl aryl othei's. A. V. Bordanova and
'"k-
-itak-rivskir (N. D. Zcl;nsJ, m.,
Slip zi! Inst. Org. Club
I=sf.Akad.NauhS,S,S..R..
Oldzl. Kh6a, Natik (10 g.) and
4 -italyst (PeCig, AIC4, or YjFjXYt,O, or 1.111k,
*
i
SA F
:
eels in d
matte
%yerc.
or 0.5 ml. 10% BrIM10 in EtsO)
in amptils at 3,5-18*; inervase of viscosity br.-P~bie
nqfidly appareitt (most rapid with Dill); similar rmtilts are,
obt,.iiiedaftt!rl-'~1.5tirs.rLfiuxing. ThcremfltingpolS~nivtrs,
had low. raol. wt. (M and were very vigcous ljqW6,
"Icept for the one prelid. with AlCl, catalyst hi which ctisc~
40-2'
the
and bad taol
wt
Pre
n
of
olvi~~r m
405
.
.
.
.
.,
,
p
p
it tbe:poly*mer with BIT. catalyst at reflux iindt!r 2.5 inut. prcs-

sure gave the only collorlez polymer. Pmetionationofthe: J
dii prbd(icts resulted in isolation of- diphellyl -acetat
t s6rrd'frable product, im. 4,5-7*, corres1w)nding to
Alol. distn. gave a viscous (C,Fl.O): a
Wid
solid in,. 45-50'. p;Mc11CCl14()C1f Z CHI W th'
t :
ht-
o-4%
C1
t
e
Jo
d solid
m
7
l
92% li
re
C
4 ca
a
.
ce
.
gav
Ys
,
:.
g
Wrrv.,qx,iidlnC to (C* 11,40)t; aimillar to that obtained with
IJ1F*.a,fAklyst at rootn'texnp.' With.EF; catalyst at reflux,
undervacuuni thcre was Foctned 86.7% solid'polyiner, M.
-10-1% con-eslinriding to (Culll[i,O)j., IL Radical poly-,
merjzatian and copolyinericaliancit vinyl aryl others. ALI?
~
Shostakovskil atidA, V.~ Bogdanova. Ibid. 019-23.-Th
use of jCMct(CN)N:j% ascatalyxt ha3 iresulted In. suecemfut.
polyntaization of, ArQCJIXXII.~ as well as in their copoly..
merization. PhOCJl:C11ji in 100 tirs. with 4% catalyst at.
.75!',trave,21.6% crude polywer. which yielded nit frnctiona-

C.11jiNt and one; in. -14-~b',,corre_spniid1ng 1,t (Cj &0)&.
'
,$huilVLrlY.~ p-Me4CQ1f,GC11:Cf1, gixve 17.6%
CJ14R.
~
tvolyinxr, ra. 48-0*, corresponding to (Cj,1fmO)zCtH4NT,, A
ruixi. (I-.I)'of'PhOCH:C1-rj and -BuOCH.C1-1: wiLiv 20,1
'
1
cat:43,st-gavc 0.71,t
~,copolym&
coing. 60.57o PhOCIICII,
Intits. Witit the product
(0,370) cintaiacd 71.06% PbOCHC11- 1111its. while BUOCII:--
Cjjr;j~?t1CACCjj40C1l: CH. gave all I j yield of prWhict
cou g ArOWC1.1i units.. The products had Ic,)% tw~!.
737
jvj 1 -74.'1). 11kc iiuaf riulicul imecItaninin,with Nf.-,
530
~L.4 indital-is Proposed. G. M

it hlEh z%jlecu-
Chemical transformat one of unsaturated
Is.r weight com unds. 111. CopolymerUation of i:!cth-

th
1
r
n it
ter with
l
I
li
id
l
h
h
r
t

s ma
(
e
.
c ac
a
as
v
w
acry
ay
art.
y
p
M. F. Shostakovskil and A. At. Miotnutov (N, D. Z1 1111.,kh
&-I
'Mo3cow)
Chem
Acad
S
S
R
bve~l
Inst
U
Org
.
.
.
.
.
.
.
..
.
,
,
Ahad. X4uk S.S..3.R., Otdol. Khohn. Nauk 1954, 024-4o;
cf. C.A. 49, 0961a.-Copolyinerl&alon of r1%OC1I:C11r
with CIIj:C,%TPCO~H (1) and Its Afe ester (11) wem. ruit ,.I I . I
Go* in the presence of 0.2 M Bz%Ot; a 1:1 ratio of t1ii! ether
ve a copolymer ool. In 1:1 BuOI1-PhOCMCH-.'
and 11
f:,
At 1/. of IT. and PhOCU-.CIT2 the capoly1w:r was
formed simiMy and Its soly. was shriflar to the above.
As the proportion of PhOCH:CHv In the InItU mt-;t. was
raised from 25% t-- 75V., the content *f PhOCHC143 unit
In the copolymer rose from 11.5 to,84.6 but theyleld of
T818
d
7
from
6 to
the copolymer decline
6%. The abs.,
I
21
d
li
d T
0
uct dec
ne
r
orn
viscosity of the pro
.0
to 0.0051, and
relative viscositY from 2.89 to IMi, Intereetion 0 1 and;
PhOCH.CH, In 3/1 ratio gave a 10% yield of product,

a
contg. 57.88% lunits. Atl:lprowtion ireactanta,thes
'
1
l
1
d h
. wt-2
units an
ad mo
product contained 42%
265, while
at 1:3 reactant proportion the product contained 0.5% r
units. The liquid.residue contained appreciable mts. of
CH,:CMeCOC1lMeOPh. The results. indicate thiLt 1110109
with copolymerization side reactions take ploce which re-.
,
sult in formation of acylals. G. M. Kosolap9ir-

777;'- _7 m
VIA
ir -
f
tad'tertliu7 alcaii6 11
LY Derivatives of on" Is; -S
.7n;
'thet3is of methyl, ethy Mpropyl. And btdr -astethylywil
M. F. ShostakovsIdl iind 1. A. Shuddev (N. ~Dc;
zeunsku rnst. ort. Chem., Acad. Sd- U.S.S.R ~ Moscow) 4qr~'~.
V Awl. Akqd,~Namk
-5; d. CA. 48,23Mf.-Ta 21.5
931
and 18 g. MeOCH. CHs raw added at -w)T, 0.016 ml. a0
-to., xt 63!
IlCl and the n3lxt, huted In sailed ttibe 9.5 h
n
give after w1th XsCOs 78% 'MOCRAM p
clifetcH! C111, b- h- .11o: I 'Win
0.8601. Letting
OCR: CFft stand
larly gave 82.82,
boo 146 1
79% iso-PrOCHI
nV 1.4120, d,, 0
CH,, b 182
dirmethiiethyalric
butyl acttalsi S
-1. HelOev.
0 02 ad 30% H1
at room.t
bit &S-9 keulp6J
dt,
72.5% A(clG06
nV 1.4264; 810A
OXM. s,60 1.42
bit 7M16, dm 0j
mrdatively less stj
yello* In atomse

.2

"'s

SHOSTAKOYSUT. M.P.; PRIIAZEAUVA, U.N.; SH"IRO, B.S.
Synthesis of sulfurous substances based on vinyl eaters and acety~-
lene. Report no.8. General method for the synthesis of ~-alkoxyethyl-
marcaptans. Izv. AN SSSR. Otd.khim.nauk no.2:303-313 Mr-Ap 154.
OUJI A 7: 6)
1. Institut organicheskoy khimii im. H.D.Zelinskogo Akademii nauk
SSSR.
(Mercaptans)

LYSSR/Chemistry Copolymerization
Card
Authors Shostakovskiy, M. F. , and Khor-rutov, A. M,

Title Study of chemical conversions of unsaturated and high-molecular compounds.
Part 2.- Copol~qrerlzation of mt-,thyl methacrylate ankl vinyl alkyl ethers
Periodical Izv. AN SSSR, Otd, iffiim. Hauk. , 3, 484 h90, May - itine 1954
Abstract The bopolyrierization of methyl acrylate and vinyl alkyl ethers was irivesti_'_..._
gated at different ratios under the effect of benzoyl peroxide. The
copolyr.eric products obtained are described. Benzoyl peroxide promotes'
the copolymerization of vinyl alkyl ethE!rs i-rith compounds containing
railtiple C = C - C = 0 bonds. The reas(:n for not finding methyl
methacrylate polyirers during the polymerization under the effect of
benzoy'l percoide is explained. Sixteen references: 11 USSR; 1 German,
4 USA. Tables.
Institution Acad. of Sc. USSEZ,.The N. D. Zelinskiy 1nstitute of organic Chemistry
Submitted 1--farch 20, 1953

;04"
USSR/ Ch,-,-dr, try Quantitative analysis
Card
Authors Shostakovs4y, 11. F., aW Prilezhaova E. N.
Title SyTithesis of sulfurous compounds on acetylene and vinyl etherbases,
Partu q.- 'Syiithesis and certain propertieo of beta-alkoxyethylvinyl
sulfides
Periodical Izv. Al'i SSSR ~ Ctd. Flini. Nauk. 3, 517 -525, y - June 1~54
Abstract 1. method for the synthesis of beta-alkoxyethylvinyl sulfides from beta-
alkoxy mothyl mercaqptanes is described, A newly introduced method for
quantitative deter:rd-nation of thiovinyl ethers I based on their
decom,osition macticn in the Presence of mercuric chlorideY is
analyzed. A study of the che.-i-deal properties of beta-alkoxyethylvinyl.
sulfides showed that the reactions of tbiovinyl. ethers.are much'
different than the reaction of their oxy.gen analogues. Sixteen
references: 11 USSR, 4 USA and 1 German. Tables.
The 141. D. Zelinski-y Institute- of Cag. Cherdstry
Institution Acad. of So. MISR,
Sub,ititted Feb 102 1953

USSR/ Chemistry Sulfurous compounds
Card
A'athors Shostalcovskiy, M. F., Frilezhaeva, E. N., and Uvarova, N. I.
Title I Syrithesis.of sulfurous compounds on the vinyl ether and acetylene basis.
Part 10.- Synthesis and certain convercions of vinylethyl sulfide.
Periodical Izv. MVESSR, Otd. Khim. Nauk. 3, 526 - 534, i-lay - June 1954
Abotract Conditions favorable for the synthesis of vinylethyl sulfide with a yield
of 6o--1., i,--re established. The addition of mercaptan and hydrogen sulfide
to vinylethyl sulfide when exposed to air, arxl t6polyimrization of the
latter in the presence of FeCl and SnClq iork catalysts, are analyzed.
The forriation of mercurated et~ylwercap'ta_n salt was determined during the
reaction of vinyleihyl sulfide with nercuric chloride in alcohol and
water solutions. The formation of 'an unstable complex salt. decomposing
in water or alcohol, was established during the reaction in an ether
solution. 'Nenty-two references: 10 USSRI 8 Gerrmn, 4 UE E.A. Tables.
Institution Acad. of Sc. US-IR, The H. D. Zelinskiy Institute of Org. Chemistry
Submitted February 10,
1~53

USSR/Chemistry Synthesis
Card t 1A Pub. 40 15/27
Authors 1 Shostakovskiy,,_.~. F.,, and Bogdanova., A. V.
Title I Investigation of acetylene alcohole and glycols. Part 3.- Multistage
synthesis of acetals of acetylene glycols
Periodical I IMv. AN SSSR, Otd. khim. nauk 4, 677 - 682., July - August 1954
Abstract l Experimental data are presented shcwing the multistage mechanism of the
formation of diacetals of acetylene glycols. The two basic methods -' "
catalytic and thermal - by which multistage synthesis of diacetals is
realized, are described. Symmetrization, which intensifies with the
increase of molecular weights of the radicals of the basic vinyl ethers,
was observed during the derivation of mixed diacetals from hoinologous
monoacetals. It was established thit symmetrical diacetal is a product
of substitution of the low-molecular alkoxy group by a high-moleoular
group. Seventeen references: 12 USSRj 3 French; 1 USA and 1 German
(1912 - 1954). Tables.
Institution s Acad. of So. 'USSR, The N. D. Zelinskiy Institute of organic Chemistry
Submitted i September 21, 1953

-AIW
ussR/ chemistry Reaction processes
Card 1/1 Pab. 40 16/27
Authors I Shostakovskiy', M. F.., Zhebrovskiy., V. V.J. and Yedelyanovskaya, M, A.
Title investigation of reactions of vinyl and polyfunctional compounds. Part
3.- Reaction of trivinylglycerin ether with ethylenc, glycoland 1.4-
butylene glycol
periodical Izv. AN SSSR. Otd. khim. nauk 4., 683 - 688) July - August 1954-
Abstract The reaction process., in the case-when both components (irivinylglycerin,
ether - ethylene- and 1.4-butylene glycols) are polyfunational'compounds
was investigated. The ratio of the basic reaction componehts vas found
to be of great importance in the yield of reaction products,. A vinyl --
ether surplus, which has the same effectas the reverse order of adding
reagents, leads to displacement of the reaction toward cyc2-ization of
the monoacetal. The formation of cytlicl acetals of glycols and glycerin
is explained by the tautomerism.of the acetals. Eight references-.
6 TJSSR; I USA and 1 German (1890 - 1954).
Institution : Acad. of Sc. USSR, The N. D. Zelinskiy Institute of Organic Chemistry
Submitted : May 20, 1953

1-1. F
USMI Chemistr7 Hydrolysis
Card 1/1 Pub. 40 - 17/27
Autbors j Shosiakovskiy., M, F,., Sidellkovalmya,, F, P,, and Zelenakaya., M, 0,
Title 1 Ion hydro3,veis of vinyl lactams in an acid medium
Periodical. jIzv. AN SSSR. Otd. khim. nauk 4, 689 6933 July - August 1954
Abstract IIon hydrd-Lyais of vinyl caprolaotam, and viWiLpyrrolidone, was. investi-
gated under the effect of sulfuric acid. Lactame and azetaideWe,were
found to be the products of ion hydrolysis, A method of quanUtative
determination of vinyl caprolactam and vinyl pyrrolidone., is described,
The effect of acid concentration and tempe:eature on the percentage yield
of the hydrolysis products,, Is explained. Swren referenceos 6 USSR and
1 German (1900 - 1953). Tables.
Institudon .Acad. of So. USSR, The N. D. Zellpskiy Institute of Organic Che=Lstry
Submitted May 8, 1953

USSR/Organic Chemistry Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - 101imiya, No 19, 1956, 61593
Author: Shostakovoki F., Shikhiyev, I. A.
Institution: None
Title: Investigations of the Syntheses and Conversions of Organosilicon
Compounds. Communication I. Synthesis of the Vinyl Ether of 'r-
hydroxypropyltrimethylsilane
Original
Periodical: Izv. AN SS SR, otd. kh1m. n., 1954), No 4~, -(415-74,7
Abstract: Using ~--hydroxypropyj trimethylailane (I) as an example the possi-
bility has been asce?'tained of vinylating orgamosilicon alcohols.
I was prepared by passing for 2.5 hours gaseous # hylene oxide (2
mol) into a cooled to -60 Grignard reagent (f a 1 g-atom Mg in
800 ml *solute After and 1 mol oc-chloronetbyl trimetbylsilane),
yield 77.3%, BF r2-630/10 mm D20D 1.k298. d~o 0.8408. The vinyl
ether of Y-hydroxypropyl trimethyls-1.1ane CHp = CH-OCH2CH2CH2si(CH3)3
(II) obtained on heating in autoclave (8 hol-irs, 1800) a reaction
Card 1/2

USSR/Organic Chemistry - Synthetic Organic Chemistry, E-2
. Abst Journal: Referat nil - Khimiya, No 19, 1956, 61593
Abstract: mixture consisting of 20 g 1, 2 g KOH and 60 g absolute dioxane.
saturated with C2H2 (18-20 atm, 200).. yJ.eld of :11 35%, BP 600/lb
mm, D20D 1.4286, d~ 0 o.8168
Card 2/2

SHOSTAKOVS.KIY,_M.F.; SHIKKIYU, I.A.; BELYAYEV, V.I.
- Omms
Investigation in the field of derivatives of tertiar7 unsaturated
alcohols. Report no-3- S7nthesis of dimethylacetylenyl(vinyl)-
- and methylethvlacetylenyl(vinvl)-tert-butyl acetals. Izv. AN
SSSR Otd.khim. nauk no-5:945-948 3-0 '54. (MI,'RA 8:3)
1. Institut organicheekoy khimii Akademii nauk SSSR.
(Acetals)

427. )t~
USSR/Chemistry Analytical chemistry
Card, t,3 Pub. 40 - 22/27
Authors Shostakovskiy, M'. F.; Batuyev, M. I.; Tyupayev, P. V.; and Matveyeva, A.~D.-
Title The oxonlum theory and the optical study of the I-Tdrogen bond in some
monovinyl ethers of glycols and polyglycols
Periodical t Izv. AN SSSR. Otd. Ichim. nauk 61 1103-1110, Nov-Dec 1954
Abstract I An optical study was conducted on several monovinyl ethersbf iiquid
glycols and poly glycols to determine whether the valence of the oxygen
in these compounds is variable and whether the intermolecular hydrogen--
bond is stable. The existence of the intermolecular hydrogeri bond was
also confirmed by other physico-chemical investigations.
Institution Acad. of Sc., USSH, The N. D. Zelihskiy Institute of Organ. Chemistry
Submitted September 10, 1953

76 k 0 1/'!~ i'e
'U R/ Chemistry - Synthesis
Card 1/2 Pub. 40 - 23/27
Authors I Shostakovskiy, M. F., and Chekulayeva, I. A.
Title Synthesis an"d conversions of vinyl ethers of ethanol amines. Part 5
Periodical. i
Izv. Ali SSSR. Otd. khim. nauk 6, lln-1118, Nov-Dee 1954
Abstract I The'processes occurring during the vinylation of di-and trietbanol ami-
nes were investigated. It was found that the virVlation of above men-
tioned amines leads to the synthesis of complete and incomplete vinyl
ethers. Mcperiments showed that vinyl ethers of diethanol amine and
beta-aminoethatiol do,not submit to cyclization during the synthesis.
Institution Acad. of Sc., USSR, The N. D. Zelinskiy Institute of Org. Chemistry
Submitted December 23, 1953

I

USSR/Chemistry Synthesis
Card 1/1 Pub. 40 -25/27
Authors I Shostakovskiy, M. F.; Kochkin, D. A.; and Vlasov, V. M.
Title I Synthesis and conversions of oxygen-containing silicon-organic compounds
Periodical t Izv. AN SSSR. Otd. khim. nauk 6, 1120-1123, Nov-Dee 1954
Abstract I An investigation was conducted to determine the reaction between ethylene:.
oxide and trialkyl(aryl)silane chlorides : trimethyl-, dimethylethyl-, .
tri-ethyl- and diethylphenylsilane chlorides. The derivation of 2-chloro-
ethoxy dimethyl-j methyldiethyl- triethyl- and diethylphenylsilanes and..
their chemical characteristics are described. A new method for the deri-:'
vation of oxygen-containing silicon-organic.oompounds is described. FiV e.
references: 3 U3SR and 2 USA ( 1941-1954 ). Table.
Institution Acad. of Sc., USSR, The N. D. Zalinskiy Institute of Organ. Chemistry
Submitted July 12, 1954

!~EQST,WQV�]~~Y, M.F., professor; KOHONOV, M.F.
Acetic acid manufacture. Khim.v shkole 9 no.6:15-23 N-D 154.
(Acetic acid) (MLRA 8:1)

SHOSTAKOVSKIY,M.F.; SHIKHIYKV,I.A.; VLASOV,V.M.; BELYAYIW,V.I.
Synthesis of vinylisopropyl, vinyldibutyl and vin3,ldiamyl ethers
and their conversions. Dokl. AN Azerb. SSR 10 no.7:473-482 154.
(MLRA 8: 10)
1. Predstavleno deystvitelinym chlenom Akademii nauk Azerbaydzhan-
skoy SSR Yu.G.Mamedaliyevym.
(Vinyl polymers)

SHOSTAKOVSKIY,M.F., SHIKHIYEV,I.A.: 2ELYAYEV.V.I.
Investigation in the field of synthesis of derived tertiary un-
saturated alcohols. Dokl.AN Azerb.SSR 10 no.11:759-765 '54.
(MIRA. 8: 10)
1. Predstavleno deystvitellnym chlenom Akademii nauk Azerbay-
dzhanskoy SSR Yu.G.Mamedaliyevym.
(Alcohols)

4,P
USSR/Chemistry - Physical chemistry
Card 1/1 Pub..43 50/62
Authore I Kasatoollikin, V. 1.1 5hostakovskiyj M, F#; Zillberbranid) 9i L; and,
Kochkin, D. A.
Title About hydrogen bonds in silanols
Periodical t Izv. AN SSSR. Seri fiz. 718/6j 726-:728,,Nov-Dee 1054
Abstract The infrared absorption spectra of trimethylearbinol iLnd five-different
silanols- (CH ) SiOH (C~) C H SiOH, C~(Y )SiOHJ~02H ) SiOH and
.enjtA;3of from
C6H (c2H;) 2SiOA Kre inves i9ea in a) r'a ge o~ wave 3
2 -4
.
,
.
to aeterfnine the nature of molecular association of silanols and the effect
of the Si-atom on the-hydroxyl group. Itwas establisheds among others...
that the chem. propertiea of silanols, particularly theiramphoteric pro- -
perties, are due to the strengthening of the O-H bond and strong reaction
between the oxygen and hydrogen of the neighboring molecules which takes-
place as result of increased polarity of the O-H bond.~ Graphs,
Institution Acad. of Sc., USSR, Institute of Combustible Minerals
Submitted t ..........

I -
SUOS TAKO `k;KIY, T;. F.
'lInvesyigations in the Field of Alcohol Oxides.II PreDaration and Properties of
a.,B-Alcohol oxides of the Aliphatic Series," Zhur. Obshch- Khin, ., 24, No.2. p.231, 1954
Corment E-870013 27 Jul 55