SCIENTIFIC ABSTRACT SHOKOL, A.A. - SHOL, O.A.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

18-3100 65692
SOV/136-59-10-9/18
AUTHORS: Shokol, A.A., lakhomova, A.D. and Kozin, L.F.
TITLE: Production of High Purity Metallic Thallium by the
Amalgamation Method
PERIODICAL:Tsvetnyye metally, 1959, Nr 10, PP 52-57 (USSR)
ABSTRACT: The object of the investigation described in the present
paper was to explore the possibilities of using the
amalgamation method for the preparation of high purity
thallium. The amalgam process, when used for extracting
thallium from solutions obtained by decomposition of
thallium concentrates, makes it possible to simplify the
existing technique, while the high 1~urlty of the metal is
ensured by the application of anodic oxidation of the
obtained amalgams. In the experiments carried out by the
present authors, a 20% Cd amalgam was obtained by
cementation of a solution resultant from leaching and
industrial hydrated concentrate containing (g/1):
1.0 Tl, 0.6 As and 50 H2SO4. The recovery of thallium
in the amalgam amounted to 90%, decreasing to 701; when the
process was repeated. The thallium content in the amalgam
obtained after double cementation did not exceed 21iD. No
Card 1/10 satisfactory results were obtained when the acidity of the

65692
SOV/136-59-10-9/18
Production of High Furity Metallic Thallium by the Amalgamation
Method
cemented solution was reduced to 5 g/1 of free sulphuric
acid; high proportion of arsenic, iron and other
impurities present in the solution resulted in rapid
conversion of mercury to slag. This showed that cadmium
amalgam can be used for cementation of thallium from
purified solutions only. Better results were obtained
when solutions, resultant from decomposition of bichromate
concentrate, were used. In cementation of thallium with
cadmium amalgams from solutions obtained by decomposition
of a solution of pure thallium bichromate, recovery of
95 to 97% can be attained, the degree of utilization of
cadmium being 8094. The results of experiments in which
the effect of the acidity of the solution on cementation
of thallium with a 576 Cd amalgam was studied (volume of
the solution - 100 ml; duration of the treatment - 6 hr)
are reproduced in Table 1 under the following headings:
Tl, Cd and H2SO4 content (g/1) in the starting solution;
quantity (g and %) of Tl, transferred into the amalgam;
quantity (g) of Cd (a) spent on thallium and (b) gone into
Card 2/10 the solution; useful consumption (5o') of cadmium;

65692
SOV/136-59-1c)-9/18
Production of High Purity Metallic Thallium by the Amalgamation
Method
application of the amalgam (first time, second time, etc).
It will be seen that, on average, 955' thallium was extracted
in the amalgam; when the free 142S04 content in the solution
was reduced from 13.1 to 3.9 9/1, the degree of
utilization of cadmium increased from 57 to 93%. In the
experiments in which the amalgam was re-used five times,
the thallium content in the amalgam reaclied 7'/~, the degree
of utilization of cadmium amounting to 850%. In the next
series of experiments, decomposition of the obtained
amalgam (containing 2% Tl, 0.5% Cd) with solutions of
various oxidizing agents, was studied; in each experiment
2 ml of the amalgam was treated with 10 ml of the solution
and the results are reproduced in Table 2 under the
following headings: the oxidizing agent (5% Hg2(NO 3)29
0.1 mol Fe2(SO4) ditto, 0.1 mol FeCl 3 , ditto);
duration of the ~rleatment,minutes; quantity (g) of Tl
and Cd found in the solution after cementation; the
potential, E, (v) of the amalgam (after cementation)
referred to normal hydrogen electrode. (In the experiment
Card 3/10 marked with an asterisk, the amalgam was converted into

.L Ij
656~2
SOV/136-59-ic-c,/18
Production of High Purity Metallic Thallium by the Arnalgantation
Method
paste.) All the investigated substances, wit'a tiie
exception of ferric chloride, secured full decomposition
of the amalgam; for practical reasons, it is expedient
to use for this purpose the ir-on sulphate solution. The
anodic oxidation of the amalgam was carried out in ail
electrolyte containing 60 g/l NH40H and 90 g/l Nk14C1,
pure mercury being used as the cathode. The results of
the electrolysis of 56.25 g of a 5% thallium amalgam are
reproduced in Table 3 under the following headings:
duration of the treatment, minutes; voltage, v;
current density, amp/dm2; the anode potential, Es (v) in
respect to normal hydrogen electrode. The change of the
anode potential with time was gradual; the electrolysis
was terminated when a white deposit (thallj-um chloride)
appeared on the anode surface. The products of
electrolysis contained: thallium amalgam (anode) -
4-975% Tl (corresponding to 99-5*Y6 of the thallium content)
and 0.025% Cd; cadmium anialgam (cathode) - 0.451j~ Cd and
0.011111) Tl; electrolyte - less than 0.001% Tl and
Card 4/10 0. 02550' Cd. Thus, it was shown that practically all

65692
SOV/136-59-10-9/18
Production of High Purity Metallic Thallium by the Amalgamation
Method
cadmium can be extracted from thallium amalgam by
electrolysis in an ammonia-chloride electrolyte. The
flow sheet of the process used in the large-scale
experiments on the extraction of thallium from bichromate
concentrate is reproduced in Fig 1. The bichromate
concentrate was obtained from the solution after
decomposition of 5.7 kg of industrial hydrated cake.
From the resultant solution, containing 6 g/1 Tl and
4 9/1 H2SO4, thallium was extracted by room teraFerature
cementation with a 5'/'Q Cd amalgam; 1 kg of the amalgam
(re-used five times) was used for 10.5 1 of the 5olution.
The typical results obtained are reproduced in Table 4
tinder the following headings: application of the
amalgam (first, second time etc); duration (hr) of the
cementation; proportion of Tl ('jQ' of the initial content)
remaining in the solution after cementation. The obtained
amalgam contained 8.44c0' Tl, 2.6c~,. Cd, lead, tin, bismuth,
copper and other impurities. For the preparation of high
purity metal it is advisable to use a more concentrated
Card 5/10 amalgam. If electrolysis is used for tllii3 purpo~~5e and if

65692
SOV/136-59-10-9/18
Production of High furity Metallic Thallium by the Anialgamation
Method
an electrolyte is employed in which the potential of
cadmium is more negative, a cadmIum-free amalgam will
be obtained; the more I~ositive metallic impurities vrill
remain in the "primary" amalgain. Curves plotted in Fig 2
illustrate the relationship between potential of the
cadmium and thallium amalgams and the metal content
(at -%) in the electrolytes for the following cases:
1 - cadmium ainalgam in an electrolyte containing
2 mol NH40H and I mol (NH4)2504; 2 - cadmium amalgam in
an electrolyte containing 0.5 mol NHIOH and
I mol (NH4)2SO4; 3 - thallium awalgam in an electrolyte
containing 0-5 mol NH40H and 1 mol (NH4)2SO4. Itwi'Ll be
seen that increasing concentration of ammonia in the
electrolyte, the potential of the cadmium ainalgam is
shifted towards the more positive values. Fig 3 shows
the polarization curves of anodic decomposition of:
1 - an amalgam containing 7 at-1,6 thallium in an
electrolyte containing 0.5 mol NH40H, 1 mol (NH4))SO4
and 0.01 mol T12SO4; 2 - an amalgam containing
Card 6/10 5 at-','o cadmium in an electrolyte containing 0.5 mol 'N"40H,

65692
SOV/136-59-10-9/18
Production of High Purity Metallic Thallium by the Amalgamation
Method
1 mol (NH4)2SO4, and 0.01 mol CdSO4; 3 - an aral-am
containing 5 at-$G' cadmium in an electrolyte containing
2 mol NH40H, 1 mol (NH4)2SO4, and 0.01 mol CdSO4. These
curves show that dissolution of cadmium takes place mainly
in the initial stages of the process; in the electrolyte
containing 2 mol NHiOH, the polarization curve of the
anodic decomposition of the cadmium amalgam is shifted
towards the more negative values of the potential.
Fig 4 shows the polarization curves of cathodic
deposition for the following cases: 1 - thallium on
mercury from an electrolyte containing 0.5 mol "NH40HI
I mol (NH4)2SO4, and 0.1 mol T12SO4; 2 - thallium on
anialgani containing 7 at-% thallium froj-.i an electrolyte of
the same composition; 3 - thallium on amalgam containing
40 at-% thallium from the same electrolyte; 4 - cadmium
on amalgam containing 40 a-t-To thallium from an
electrolyte containing 0.5 mol NH40H, 1 mol (NH4)qSO4,
and 0.1 mol CdSO4; 5 - cadmium on mercury from a~i
electrolyte containing 2 mol NH40H, 1 mol (NHOIS04, and
0.1 mol CdS04; 6 - cadmium on amaigam cantainin-g
Card 7/10 40 at-56 thallium from the same electrolyte. It will be

6 '-" 6 9 2
SOV/136-59-lo-9/18
Production of High Purity Metallic Thallium by the Amal.-arilation
Method
seen that in the case of the electrolyte containing
0.5 mol NH40H, the shift of the cadmium potential in-
relation to thallium is riot sufficiently large; the
current density permissible in this electrolyte (stirred
at the rate of 60 rev/min) decreased from 1.2 to 0-5 amp/dm2
as the thallium concentration in the amalgam increased;
when an electrolyte containing 2 mol NH40H is used, the
shift of the potential is larger, which makes it possible
to use higher current density (1.2 amp/dm2). The
diluted thallium amalgam was concentrated by
electrolysis in which mercury cathode arid ammonia-sulphate
electrolyte (0-5 mol NH40H, 1 mol (NH4)2SO4) were usedt
the resultant amalgam contained 32,81j'0' thallium.,
5.6% cadmium and other impurities, the thallium content
in the electrolyte being 0.27 9/1. The results of the
potential measurements carried out during this operation
are given in Table 5 under the following headings:
quantity of electricity, amp-hr; cathode and anode
potentials (v) relative to normal hydrogen electrode,
Card 8/10 The impurities were removed from t1he concentrated amalgam

65692
SOV/136-59-lo-9/18
Production of High Purity Metallic Thallium by the Amalgamation
Method
by anodic polarization in an electrolyte consisting of
0.1 mol trilon B in 1~0 N solution of NaOH, at the current
density of 0-5 amp/dm2., The bulk of the impurities was
removed at room temperature unLiI thallium ions appeared
in the electrolyte; the process was then continued for
3 to 4 hr at 60 to 700C, the electrolyte being stirred at
the rate of 200 rev/min,, the quantity of thailium passing
into the solution during this operation amounted to 10 to
20 g/1. The purified amalgam was then subjected to anodic
dissolution carried out under the following conditions:
cathode - platinum; electrolyte - 40 to 70 g/I TlC'049
60 to 120 g/1 NaC'041 1% N2H4.H2SO4I 0.04 to 0~1% sodium
salt of carboxyniethyl-cellulosei pH equal 2 - 3; speed
of stirrer - 60 rev/min. The most dense deposits were
obtained at the cathode current density of 0.3 to o.6 amp/dm
To reduce the quantity of inercury in the cathodic deposit,
hydroxylamine was added to the electrolyte to reduce the
dissolved oxygen which, by oxidizing mercury, promotes its
Card 9/10 transfer into the electrolyte., The process was carried

S/073/62/028/006/002/002
D202/ "307
10THORS: Sholcol, A.A. and Kozin, L.F.
TITLE.: The purification of gallium, indium, and thallIUM
from admixtures of mercury, cadmium and zinc by
high temperatt.-ure distillation in vacuum
PERIODICAL: Uhrainskiy khirAcheskiy zhurn~Ll, v. 28, no.- 6, 1962,1
699-702 i
T EXT: The authors purified 10-12 g samples of Ga, In aind
TI or their alloys from the above adiftixtures,-by heating the metals
i-a a quartz tube, at a pressure of I mm 11g; over a period of 4 h-rs,
at temperatures ranging from 500 to 12000C, It was found that when
the distillations were carried out at 1000 - 12000C no 1-1g; Od or Zn i
could be detected in the original metals, either colorimetrically
or spectroscopically, the mercury being practically eliminated by a
t-reatment at 8000G. The success of this method is ascribed to the
great differences in the partial pressures of the metals concerned.
There are 1 figure and 2 tables.
Card, 112

3/073/62/028/006/002/002
The purif i cation' of,.. gal Hum, D202/D307
,NSSOCIATION: Institut obshchey i neorganicheskoy khimii m USSIt
(The Institute of General and-Inorganic Chemistr
y
AS U1.rSSR)
SUBMITTED: May 15, 1961
Card 2/2

S/O-,1/6Zi/o-,O,/009/00!//O'~.1I
AC,51~A126
A U'17 10 RS) Shokol, A. A., Andrusenko, L. P.
TITIZE: Investigation of the conditions of germanium precipitation with
magnesium and iron
PMIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 28, no. 9, 1962, 1009-- 1013
TID,T; Optimal conditions (concentration df Ge, pH. and the consumption
factor of precipitants) for the precipitation of'germanium by magnesium and/or
iron were studied at the Institut obshchey i neorganicheskoy khimii AN USSR
(Institute of General and Inorganic Chemistry AS UkrSSR). The precipitated Ge
was filtered off and in the filtrate the non-precipitated Ge was colorimetrically
determined with phenylfluoron. The following results were obtained: The maximum
precipitation (98.4,c./) of Ge by a magnesia mixture at a concentration of
1-32.5 mg Ge/1 occurs at pH = 12.0. In the absence of ammonium salts the maximum
is lower (89.2 - 91.81%) and lies at pH 9.6 - 11.6. Varying-the ratio Mg : Ge J,
from 0.1 to 50, an almost complete (99.8%) precipitation of Ge was achieved at a
pH of about' 10 and a 15fold excess of rig. A surplus of sodium hydroxyde does
Card 1/3

S/073/62/028/00,9/00 1/0 11
of the condi t! ons of, A05~)A 1 -06
'kCa&,Te -eg7e,.7_7,V117
f Onw~~ ana T~~ of Ge on ma~_-aestuar hydroxyde accurs. Zxper2ment,5 w-2ty)
genvai7im.-we pr&c!p_24',?tJon bZ iron hydroxyde (as collector) at a pH of about 8, by
varying the Re/Ge ratio kO.1 - 50) showed a complete precipitation of Ge 0.25
mg Ge,1100 n1) in the presence of a 2_5fold excess of iron. In this case a zurplus
of sodium hydroxyde showed a negative effect upon the Ge precipitation, apparent-
ly due to adsorption processes. Germanium precipitation by magnezium in the pre-
serice of iron hydroxyde (1.25 mg Ge + 6.25 mg Mg in 100 ml solution) at a pH of
about, 8 showed a 99.9% precipitation of Ge, if at a 5fold. M9 excez~ a 1G - 15fold
excess of iron ;-.,as present or a 10QZ precipitation of' Ge if at a 15fold iron ex- o/
cess a 2fold excess of f-1g was present. The pH should not drop below 8. Experi-
ments at a constant ratio Mg : Ge = 5 : I shavied that with. an increasing amount
of Ge the quantity of' iron necessary for a complete precipitation of Ge de-
creases, but only at a concentration of more than. 10 mg Ge/1 a complete precipi-
tation of Ge can be attained, because in diluted solutions Ge remains partly dis-
solved as magnesium orthogermanate. A complete precipitation, even at low Ge
concentrations (0.1 mg1l) is effected at a ratio Ge : Fe = 1 : 25 (or more), or
in*the presence oif a 2fold surplus of f~g at only a 10 - 15fold excess of iron at
Card 213

S/073/62/026/009/001/011-
Investigation of the conditions of... A057/A!26
pH > 8. 'M(-rc arc Clgure,; and 0' tables.
ASSO'C'IATION; Institut ob5hchey I neorganicheskoy khimll AN USSR (Institute of'
General and Inorganic Chemistry, AS UkrSSR)
SUBMI=: July 21, 1961
V
Card 3/3

Ni , rA
K f- -)
USSR/CrE,anic Ch,2rrdstry - S~nthetic Crgand-c Chemistry E - 2
".ts jol.ir ReDarat Zhur - Khllmi~,-a, No 2, 195'fy 4330
Mthor Babictev, F,S,, Shokod., V-,A.
Ti tie Reaction of Beta -7-d-n-c-c-Ty7mercaptan with Anhydrides of
Dibasic Pcids
Orig Pub Ukr~ khiia. zh~, 1956, 22, No 2, 20-2141
libstract Study of the reaction of beta-aminoethylmercantan M
with the anh:ydrides of dibasic acids, It is shown that
I gives w-ith succinic anhydride (I!) 14-f" beta-mercaptoe-
Thyl)-succinirride (111), with gilitaric the mono-bata-,
mercaptoothylamide of &lLitaric acid (IV), end with phtha-
lie an1hydride the N-(batv.-i,,it-,rc,)I;toethyl~.',,ph.'.haliride.
The expoct~2d formfition u,' (thiazolin),l-'~l-alkylcprboxyll-c
acids (see Mlly-him, 1956, 68371) dies not take place,
2 g I and 2,6 g I! in 10 ID-1 C61'6 (in a sealed tifoe,
120-1300, 16 hours) give III, yield 6qj,,4', ',-T 500 (fron,
alcohol), From III and 15% H 202 is obtained ihe
Card 1/2 ~'e 49 -

USSR/Organic Chemistry Synthetic Organic Chwial.-ry, E-2
Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 942
Author: Babichev, F, S.~ and Shokol, V. A.
Institution: None
Title- Synthesis of 3-keto-1,4-thiazapes
Original
Periodical: Ukr. Min. zh., 1956, Vol 2'2, No 2, 215-216
Abstract: A number of 3-keto-l,k-thiazanes of the type SCHRCONHC112 H~ M have
been prepared. Dry toluene, one gram-atom Na., ana 1.1 Males -
aminoetbylmercaptan (prepared by saturating alcoholic ethylamine with
H2S at 10-150; yield 72.5%, mp 980) are heated at,-jlOOO until all thi;
Na dissolves; one mole of the ester of the ex-brominated acid (II) is
added dropwise with constant cooling, follcrred by heating for 2-2.5
hours at -1000. The NaBr is separated and the toluene distilled off,
leaving I. The amount of initial II., R, the yield of I in percent,
and the mp in 0 C are given: CH2BrCOOC2H5, H, 65.3, 89 (from alcohol
or benzene) (a molecular compound is formed with AgN03 in aqueous
Card 1/2

KIRSAITOV, A.V.; SHOKOL, V.A.
Diesters of thioacylamidophosphoric acids. Zhur. ob. khim. 30
no.9:3031-3037 S 160. (MIRA 13-9)
1. Institut organicheskoy khimii Akademii nuak %=ainskoy SSR.
(Ilaosphoric acid)

DERKACH, G.I.; SHOKOL, V.A.; KIRSANOV, A.V.
Diesters of acylamidophosphoric acids. Zhur.ob.khim. 30 no.10:
3393-3397 0 161. (KIRA 14:4)
1. Institut organicheskoy khimii Akademii nauk Ukrainskoy SSR.
(Phosp'noramidic acid)
IF-,

AUTHORS:
TITLE
895-19
B/079/61/031/002/012/019
B118/B208
Kirsanov, A. V. and Shokol, V. A.
Aryl esters of N-diaroxy-phosphinylimino-thiocarboxylic acids
of the aromatic series
PERIODICAL: Zhurnal obshchey khimii, v - 31 , no. 2, 1961 , 582-593
TEXT: ThedLesters of thioacyl-phosphamic acids ArC(=S)NHPO(OR )2 synthesized
by the authors in Ref. 1 are tautomeric with N-diaroxy-phosphinylimino-thio-
carboxylic acids M ArC [= NPO(OR)21SH. The aromatic esters of the latter
he chlorides of N-diaroxy-phosphinylimino- X
were obtained by reacting t v
carboxylic acids (Ref. 2) with sodium thiophenolates, or (with particular
ease) with thiophenols in the presence of tertiary amines:
+ HSAR" + (C N
ArC NPO(OAr') 01 - 05 3 -~ ArC NPO(OAr' )2 SAr". The esters
Im I or NaSAr" 1= I
are insoluble in water, alkali lyes, and acids. p-Nitrophenyl esters of N-
diaroxy-phosphinylimino-thiocarboxylic acids are gradually decomposed on
Card 1/3

Aryl esters of N-diaroxy-
89519
S/079,/61/031/002/012/019
B118/B208
heating (250-3000C) in high vacuum to give nitriles, and also considerably
carbonized. As far as the chemical properties are concerned, the esters M
much resemble the aryl esters of N-diaroxy-phosphinylimino-carboxylic acids
(Ref- 3). Esters (I) are easily saponified with aqueous-alcoholic solutions
of strong mineral aciday and with 9Wb acetic acid. When treating the esters
(I) with NH or amineB, the corresponding amidines and thiophenols are
. 3
obtained.
ArC I =NPO(OArl),] SAr" + RNH2 Ar"SH + ArC 1= NPO(OArl)2]NHR.
In alcoholic solutions, the esters (I) react with NE very easily and with
nearly quantitative yields. The reaction of the esters (I) with amines is
much more difficult, and requires prolonged heating (UP to 35 hr). To com-
pare the properties of the esters (I) with the aryl esters of N-diaroxy-
phosphinylimino-carboxylic acids (Ref. 3), the reaction of the latter with
NH3 and amines was studied. The aroxy0group of these aromatic esters, which
is combined with the carbon atom, wa~ found to be also substituted by the
amino group, on the action of NH3 or amines, giving the corresponding
amidines and phenols:
Card 2/3

Aryl esters of N-diaroxy-
ArC I =NPO(OArl)2]OAr" + RNH2 :0 Ar" OH +
8953,9
S/079/61/031/002/01 2/010
B118/B208
ArC 1= NPO(OArt)21 NHR.
Concentrated HNO 3 hydrolyzes the esters (I) to diesters. When heating the
esters (I) with dimethyl sulfate at 1000C, without solvent, no alkylation
occurs at the sulfur atom; the initial product gradually changes to form
nitriles, thiophenols, diesters of acyl-phosphamic acids, and other
products of unknown structure. The sulfur in the esters W thus has not
the properties of sulfide sulfur. There are 4 tables and 7 references:
5 Soviet-bloc and 1 non-Soviet-bloc.
ASSOCIATION: Institut organicheskoy khimii Akademii nauk Ukrainskoy SSR
(Institute of Organic Chemistry of the Academy of Sciences
Ukrainskaya SSR)
SUBT-JITTED: March 7, 1960
Card 3/3

-DERKACH,"O.I.; SHOKOL, V.A.; KIRSANOV, A.V.
lll-diAroxyphosphinyl-112(N3-arylthiocarbaminyl) arenamidines
(NI-ar.vl-N2(N3-diaroxyphcfsphinylimi-n'oaroyl),thioureal. Zhur.
ob.khim. 31 no.712275-2282 Jl 61. (flW 14:7)
i
1. Institut organicheskoy khimii AN Ukrainskoy SSR.
(Urea) (Amidines)

DERKAGII) G.I.; SHOKOL, V.A.; SAMARAY, L.I.; KIRSAN(W, A.V.
New method of preparing trichlorophosphazoacyls. Zhur. ob. khim.
32 no.1:159-160 Ja 162. (MJPA 15-~)
1. Institut organicheskoy kbimii AN Ukrainskoy SSR.
(Phosphazo, compoimds)

SHOKOL, V.A.; DEW(ACH, G.I.; KIRSANOV, A.V.
Phenyleichloro- and diphenylehlorophosphazo-dichloro-and
trichloroacetyls and their derivatives. Zhur.' ob. khim. 32 no.l:
166-171 Ja 162. (MIRA 15:2)
1. Institut organicheskoy khimii AN Ukrainskoy SSR.
(Phosphazo compounds)

DERKACH, G.I.; GUBNITSKAYA, Ye.S.;-SHOKO
,L -Y.A.-;-KIRSANOV, A.V.
Triaroxyphosphazoacyls. Part 2. Zhur.ob.khim. 32 no.4:1201-
1207 Ap '62. (MIRA 15-4)
1. Institut organicheskoy khimii AN Ukrainskoy SSR.
(Phosphorus organic compounds) (Esters)

DERKACH. G.I.; GUBNITSKAY-k, Ye.S.; SHOKOL, V.A.; KIRSAITOV, A.V.
Pheny2dichloro-, diphenylehloro-, and triphenylphosphazo acyls.
Zhur.ob.khim. 32 no.6:1874-1878 Je 162. OMIRA 15:6)
1. Institut organicheskoy khimii Akadpmii naWc UkraJnskoy SSR.
(Phosphazo compounds)

DFJWtCll.t G. I.; SX11,111AY') L. I. ;._SIIOKOL, V.A.
Trichlorophosphazo acyls. Znur.ob.khim. 32 no.6:2059 Je 162.
(MIRA 15:6)
1. Institut organicheskoy)ddmii Akademi.-*L nauk Ukrainskoy SSR.
(Phosphazo compounds)

DERK&CH, G.I.; SIfOKOL, Y.&,; GUBNITSKAYA, Ye.S.
Aryldichlorophosphazoacyls and their derivatives. Zhur.ob,
khim. 33 no.22553-557 F 163. (NIRA 16:2)
1. Institut organicheskoy khimii AN UkrSSR.
(Phosphorus organic compounds)

DERKAGH, G.I.; GUBNITSKAYA9 Ye.S.; SAMARAY, L.I.~ SHOKOL,_V.A-
w
Diaroxychloro- and triaroxyphosphazoacyls. Zhu--.ob.khim. 33
no.2.,557-562 F 163. (MIRA 16:2)
(Phosphorus organic compounds)

SHOKOL. V.A.. DERKACH, G.I.; KISILENKO, A.A.
y
Ultraviolet and infrared spectra of diesters of acylthioamidoDhosphoric
and acylimidophosphoric acids and their derivatives. Zhur. o~.
khim. 33 no.8:2660-2667 Ag 163. (MM~ 16:11)
1. Institut organicheskoy khimii All UkrSSR.

DFRKACH, G.I.; GUBNITSKAYA, Ye.S.; SHOKOL, V.A.; KISILENKO, A.A.
Infrared spectra of trichlo-ophosphazoar-yin and "heir derivativeq.
Zhur.ob.khim .34 no.1:82-88 Ja 164. 04IRA 17:3)
1. Institut organicheskoy khimii ARN UkrSSR.

sfiuwl., v . t,L . ; ~ E'. L , T ~ -, FRC, OVI, , " J41 . ; K -1 4,- 1 f- lr r V
. ZL. 'f~ IU4 ~
Higher dialkyl eaters of acils.
Zhur . ob. k~--' in . -35 no. 3 -, 5,7 1 -544~ Mr ' 6J'- ~ ~ M :Pj~- 18 - i "I
1. institut organ3.c-hss'r-.cy khairrt,~f AN 'tTkr-S`R,

DER~-,Cll, Ya.-E_ SHOYCIL, V~A,
DerfvatAves of acylamidoarylphosphoril-,, anids. Zhur. ob. kh-'n,.
'35 ~e ( M Ir F ;. 18 -, 6 i-
1, Institut organi.-heskoy khlm5i AN UkrSSR,.

- - I ~ . . . ! ,,:- : :'. :- , , -- ~ : - , - , t~: . -~ ll~ ~ ..r; .
. , - I : -, - - ~- ;2
- , I~: , , I - - ; I -
. , --- I ., - - I t . . I. - -, I .,

5-66__ EWP(J)4WT;'(M) flm
ACC ..NRi AP6018835 SOURCE COM UR/ 976570351003705 W 0544
AUTHOR:_Shokol, V, A*'; Fedotova, Le I*; Frolova, As No; Kirsanov, A, Ve
ORG:
~n Of
~~_qEganie Chemistry, AN UkrSSR Institut organichookoy kh4=14 AN UkrS
TITIE: Higher dialkyl esters of =71sulforWlanddophosphoric acids 7
SOURCE: Zhurnal obshchey mi'mii, v. 35, no- 3, 1965, 334-344
TOPIC TAGSi organic synthetic process, ester, phosphoric acid, organic sulfur
compound, organic nitrogen compound, organic salt
ABSTRACT: Dialkyl esters of a -isulfo'nylamidophosphorio- a'oids--
ry
with highek aldyl radicals were synthesized and investigated as
complex formers and extraction reagents for various metals. Dial-
kyl esters of arylsulfonylamidophosphorio acids# possessing the
-properties of monobasic, acids$ were synthesized by the action of
,'trlohlorophosphazosulfonylaryls on higher aliphatic alcohols or
!by the action of dichlorides of arylsulfonylamldophospho~io acids J
on higher sodium alcoholates. The solubility of the sodium salts..*
.of higher alkyl esters of arylsulfonylamidophosphorie acids in
water deorpasest while that In organic solvents inereases-with
:Increasing molecular weight-of the alkyls. Sodluta salts of the.-..'.
'higher dialkyl esters of arylsulfonylamidophosphorio acids are
Card TMC!
546,1850 542,541,521-1

L 28875-66
ACC NRs AP6018835
,extriot~d-' m aqueous solutions by organic solventso-'- Extraction
takes plao2ronlY from neutral or alkaline solutions. 14nder the
'action of sodium iiilts of higher dialkyl - est-e-rs -6-fliylsulf onyla- --I
midophosphoric acids on metal chlorides, sulfates, or nitrates in
aqueous solutionsl dluminuml barium berylliumg ferrous and ferric,
Icadmiumg calciumi magnesiumt manganese) copper, nickel, strontium,.
land chromium salts of higher dialkyl esters of arylsulfonylamido-
phosphoric acids are produced; they are very sparingly soluble
In water and readily soluble in organic solvents. In the synthesisl'-.
,of dialkyl esters of arylsulfonylamidophosphorio acids from tri-
:chlorophosphazosulfonylaryls and higher alcoholsi-higher monoalkyl
esters of the arylsulfonylamidophotphoric acids /'ArSO2NHPO(OH)(,Oa)/:
are formed and are'isolated in the'-foiz of,the disodium. saltsb-i
Orid. art
has 1 6 tables* rJPRS7
SUB 07 -SUB-1 DATE: 18~a:
.~QDE n64 IG RE F 002
Card 212

L 29276-66 -EWP(j)/EWT(M)/T RM
-AC C N R. AP6019322 SOURCE CODE: UR/007976-57035700871468714M
AUTHOR: Shokol, V. A.; Derkach, G. I.
ORG-. Institute of Organic, Cherdstry AN UkrSSR (Institut organicheskuy WAmii
AN UkrSSR)
TITM: I)ialkyl eaters of aoylamidophosphoric acids
SOURCE: ftmal obahcheY WAMii, V-35, no- 8, 1965, 1468-1471
TOPIC TAGS: phosphate ester, organic synthetic process, alcohol
ABSTRACT: By ihteradtli-ig-tr.Cohlorophddphazoacyls or dichlorides
of aeylamidophosphorio, acids with alcohols in benzene solutions
:in the presence of triethylamine, dialkyl esters of acylamidophos-
phoric, aoids RCONHFO(OAlk)~ (I) were prepared. The following new
compounds of this type were synthesized by these methods:
.1 (R--CH C1, Alk=Me); I R--CH Alk=Bt); I (R=CH C19 Alk = Iso-Pr);
2 2C1 2
1 (R--Ccl Alk=iso-P.r); ..I (P,,--Phg Alk '= iso-Pr); I (RwPh, Alk = hexyl);
31
(R-Ph, Alk=heptyl); I (R--Phs Alk = ootyl); I (R--Ph, Alk =nonyl);.
(R--Ph, Alk=deoyl); I (R--p-ClC04, Alk = hexyl); I (R--P-MC64,
Alk.= heptyl); I (a k P
-P-7C1C041. A' 00tyl); I (R-- -ClC04,
Card

L 29276-66
ACC NR, AP6019322
t
Alk = deeyl). The esters with Alk
-Alk = nonyl); I (R P-Clc6H4v
'Meg Et, Iso-Pr were orystalline sol1dsq those with-Alk hexyl tp
ileoil colc~rl,~ss`,'
;Vacuo without deeomposition, Compounds I were dimerie In benzene;
solutions..- (of. M. M. Kabaohnik et 'all Xzv.-_ AN, -SSSR,_.OKM-15~9
1952); ib~ -aut-h-oir's than 47 Vi. Kir-banov for-TAs-,
6' heIP'and advi d'o Orig. art. has:
1 figure, 3 fon=las, and 1 table.
SUB COM 07 SUBM DAM 25MAr63 ORIG REF: 005
Card 2/2

L 0,
."'18~ k:"ip( i)
ACC'NR, AP7000744 SOURCE CODE: UR/0079/66/036/005/0930/0937
S110KOL,.V. A., MOLYAVKO) L. I., DEpj=Hz G. I., Institute of Organic Chemistryl
c- em3'r of Sciences Ukrainian SSR D
-Chloremides of
Reaction of Compounds of Trivalent Phosphorus with N
Acids. I. interaction of Phosphites and Triphenylphosphine with N-Chloro-N-
'!al~yjsulfanx~des"
~468cow, Zhurnal shchey Khimii, Vol 36, No 5, 1966, pp 930 937
Abstract: In the reaction of N-chloro-N-methylarylsulfamides with trialkyl-
or alkyldiarylphosphites, there is an Arbuzov rearrangement, forming diesters
of N-alkylamidophosphoric acids. The diesters are colorless viscous liquids
or low-melting crystalline substances, which yield N-alkylarylsulfamides when
boiledwith aqueous alcohol solutions of hydrochloric acid. Triphenylphosphine
reacting with N-chloro-H-methylarylsulfamider,, gives N-methylarylsulfonylamido_
tri~henylphoephonium chlorides. They are all readily hydrolyzed by atmospheric
moisture or under the action of water or alcohol, yielding complex compounds
o~ triphenylphosphine oxide with N-methylarylsulfamides ArSO~N(CH
3)H ... op(C6H5)3"
When the phosphonlum salts are heated to 90-1200., they split off an alkyl halide,'
yielding triphenylphoE;phazosulfonylaryls. The infrared spectra of the compounds
obtained are discuqjo d
Orig. art. has: 1 figure and 4 tables. IJPRS,. 37,023
TOPIC TAGS: organic amide, organic sulfur compound, organlc phosphorus compound
AUB CODE: 071 SUBM DATE: 19Apr65 / ORIG REF: Oll / OTH REF: 005
Card I ~j 1-.Tnh MCI 547 5R3 2
0~~j IYZY_~_ Z'

ACC NR, 4PCO-26-9-01
of 11-chlorourethanes with dimethyl sulfate:
ROCONIIII, cl,
IIOCONIICI IIOCON(R')Cl.
Composition and properties of the dieaters are given in the table.
Origo art. bass 1 tablo, [W.A. 503
3rd 2/3

Table 1. Olestaws of 9-alkylphosphanocarbawic Melds XOCON(X')PO(ojt")2
Ylield
I ,. I It 9,.ttp d formula ~alcld
(in 2) bit (p in me) tr 4, Foundicatc, %P
C112 c1l, c11, w 83-84' (1.51 1.2774 1.4366 40.40 40.71 16.02 c'll"Hosp 15.71
Clio C113 1.1"0 1.43fg 50.04 49.93 11.05 clil"No,p 13.76
Clio c11, Iso-,lit 63 75-1610.4) 1.00 114209 50,17 Will 13.31 coll"NoAr 12.24
c11, cill, q1t, 55 94-95(0.41 f.134A 1.4333 54.81 54,57 13.19 rif,,KO,P 12.95
c1l, C21is too-cally 50 90-91(0.3) 1 10730 1.42R5 54.12 Gj.PD 11.53 C,,IF,NO,P 11.59
c,111 c1l, c11, 50 71-72JOA) 1,2160 1.4343 45.27 45.33 14.33 C,11,t4o'l, f4.0t
COS c1l, qns V 83-84(0.5) 1.010 1.4301 54.63 54.57 13.23 c,1l,NO,p 12.95

c2lls CH, laox,311, 65 Of-92 (0.7) 1.0770 1.4277 63.61 63.80 11.51 c'.11,P40,P 11.59
L-COI C113 cil, 57 114-t 0 (3) 1.107 1.43M 49.92 49.95 13.Ga cllj,No,p 13.74
i0ox-211, clis cill, 50 IS-92 (1.5) t.1041 1.4292 59.14 59.18 12.42 qll,NO,P 12.24
J"-c3tjl cut 1.06xill, PO 100-108 (f.5) 1. f*20 1.42M 68.60 68.42 ILD4 (711111,00sp 11.01
SUB CODE1 07,4%./SUBM DATES 1OJu165/ ORIG REFS 008/ OTH REFS 004
Card 313

ACC NR, AP6028901 SOURCE' CODEt UR/0079/66/036/008/1442/1444
AUTHOR: Sbokol, V. A.; Mikhaylyuchenko, N. K.; Derkach,-.,G. I,
ORG: Institute of Organic Chemistry. Academy of SciencealUkrSSR
(Ins 1~~ m Akademii nauk UkrSSR)
TITLE: Reactions of compounds of trivalent phosphorus with N-chloro-
amides. 11. Reactions of phosphites with N-chloro-N-alkylurethanes
SOURCE: Zhurnal obahchey khimii, v. 36, no. 8, 1966, 1442-1444
TOPIC TAGS: insec icide, alkylphosphonocarbamic acid eater 0
WBSTtACT, N-'c!hloro-N-alkylurethanes react with trialkyl phosphiteelto
form the corresponding eater a:
ROCO,N(Ro.)CI + (R"0).,P ---i- jROCON(R')P(OR")3j4C1-
--I- ROCON(H')P0(011")2 + 11"C1.
Without solvent the reaction is very vigorous, therefore, it is con-
ducted in benzene solution with boiling. The diesters of N-alkylRhoa-
phonocarbamic acid are effective insecticides~and at the same time the
are harmless to humans and animals. The initial H-chloro-N-alkylure-
thans were obtained by chlorination of N-alkylurethanesor by methylatio
DCt 547.495.1

ACC NRi
of N-chlorourethanes with dimethyl sulfate:
IROCONIIR' c1, -, ROCON(R')CI.
. ROCONIJCI -iM01-6011
Composition and properties of the diesters, are given in the table, -
Orig. art* haul 1 table* [W.A' 50]
r
2/3

ACC NRt AP6028901
Table 1. Dle*tftws of 31-11tylphomphonocarbowLe aelds R0C0ff(X')P0(0A")2
IF
d Formula Le'd
a (in X) bp (p in ma) i vp %P
round
l ealc'd
C113 C it, Clio 60 83-44-it.5) 1.2T74 L4366 40.40 40.7( 16.02 C31"'No'p 15.71
Clio CH3 CIIIS 64 1.1880 1.4319 50.08 49,95 13.95 C~1100'p 13.76
Clio CHI to o-q'i f 62 75-75(0.6) 1. 1(W 1.4299 59.17 59.0 f2.31 C'1l'N0'p 12.24
CH, CIRS CtHS 55 V4-95 (0.4) 1.1348 1.4333 54.61 54.57 P.M rll"Nosp 12.95
CHI C.11, 1&Q-cS1l' 50 M-91 (0.3) 1.0130 1.42AS 54.12 63.90 11.53 C,,If,NO,P 11.59
r.". CHI CBS 50 71-72(0.41 1.21W L" 45.27 45.33 14.33 C'll"r(G'p 14.01
qHI Clio Clus 63 &3.-84 (0.5) 1.1310 1.4301 54.63 54.57. 13.23 GNHJSNOAF OAS
Calls CHI Immc'"' 65* Of-02(0.7) 1,0770 1.4277 63.81 53.90 11-51 C'HnN0'p 11.59.
law-CAT CHI CHI 57 114-115(3) 1.19P 1. 43M 49.99 49.95 13-68 Crillemosp 13.76
Clio CjHj 56 gs-ft(l.5) 1.1041 1.42UZ 5V. 14 59.18 12.42 C11130NOSP 12.24
j"-CjHj CBS L*bx4uv 90 f06-109 11 ~5) M620 1,4270 U. 65 W.42 11.04 Cj'H'N0'p 11.0.1
t
SUB CODE: 07P(P/SUBM DATEI 10Ju165/ ORIG RE .Ft 008/ 1 OTW REFt 004
Card 313

ACC NR: AP6031382 SOURCE CODE*: UR/0079/66/036/009/1636/1639
AUTHOR: Shokol, V. A.; Coli'r-1, G. A.; Libman, B. Ya.; Derkach, G. I.
ORG: Institute of Organic Chemistry, Academy of Sciences, UkrSSR (Institut
organicheskoy khimii Akademii nauk MrSSR)
TITLE: Monoalkylamides of alkyl methylphosphonates
SOURCE: Zhurnal obshchey khimii, v. 36, no. 9, 1966, 1636-1639
TOPIC TAGS: insecticide, Fl-;60"=t~Q oP6 I) -I C -')ImD-~
r
ABSTRAM In a search for new insecticide*s', a series of monoalkyl-amides
of alkyl methylphosphonates was obtained by the reaction of
methylphosphonic acid chloride with primary amines in the presence
of triethy;amine in an ether solution at room temperaturez
CH3P(O)(ORY~HR*
Composition and properties of the amides are given in the.table.
Card 114 UDC: 547.26'118

A
NR, T
CC- -APM-31382- ~~j-e 1. Monoalkyl=idas of alkyl methylphosphonates
-CH.-,P(O)(OR)NHR'
R
Card ~/A
CH,
CH3
CH,
c1l,
C,H,
CA
C2H5
C,H,
iso-C3H7
isO -C3H7
iso-C1117
jSO-C3H7
R'
CH,
C2145
nao-C3H7
11--C4Hg
CH,
C,H5
930-CIH7
.9--C4H9*$
CH,
C2
Hs
1130-cJR7
H.-CjHq
bp (p, mm) d,-
%

a, 37 '72-73- (0.02) 1. 1288 1.4423
a, 58 78-79 (0.02) 1.0779 1.4402
a 42 81-83.(0.03) 1.0402 1.4373
a 36 95-96(0.1) 1.0192 1.4424
6. 82 (69) 86-88(0.5) 1. 0835 1.4390
6. 72 91-93(0.4) 1.0482 1.4372
6, 78 (62) 66-67 (0.03) 0.9995 1.4347
54 (1 t) 100-101 (0. f) 0.9971 1.4400
6, 8 1(58.) 73-75 (0.06) 1.0372 1.4350
6, 79 69-7t (0.03) 1.0109 1.4338
6. 63 85-87 (0.07) 0.9863 1.4318
e, 54 (13) 1138 -139 (It) 0.9712 1 1.4376

ACC NR: APo03,-3,"i-)
Table 1. (C nt.)
3t 1?,
found, % formula calculated
found calc
28.89 29A3 N H.43 C,11,,NO,.P N It.33
33.54 33.65 CII,O 22.53. C'11"NO'p CII,O 22.59
:38A2 38.36 CH,O 2.0.65 C,H,,NO,P CII,O 20.53
42.92 42.98 CH30 18.74 COHIGIN02P CH30 18.79
33.32 33.65 IX 10.21 C41f"v(O'p N 10122
37.92 38.36 N 9.22; C,H,,NO,P N 9.27;
P 20.53 P 20.49
43.08 42.98 r 18.59 CjI"NO'p P 18.75
47.39 47.60 N 7.5~ C7HISN02P IN 7.81
-38.0.3 38.36 N 9.34 C,H,,NO,P X 9.27
42.53 42.9S X 8.43 C,H,,NO.P IN 8.48
47-11 47.60 N 7,99; C7H,SNOZP N 8.01.
P 17.34 P. 17.28
52A3 52.22 N 7.28; C'H'-'40'P N 7.25;
Card 3/4 P t6.04 p 16.05

-~610 7
3 C) V/7 3 0 -
AUTHORIS: Muslilkalo, L. K., Z. 1.
TITLE i Co-ndensat-ion of U115aturated Carbonyl Compounds and
~-Fialoi,etones With /3- Ayrilnoethylmercap tan and
~thylenediainine Derivatives. II
PERIODICAL: Zhurnal obshchey 1chlinii, 1'960, Vol 30, Nr 3, pp -102'~-
1028 (USSR)
ABSTRACT: New seven-membered heterncyclic baaes viere 3ynthesized
by the condensation of 1,2-aminothiols and 1,2-diamines
wi ti, a , /3-unsaturated lretones.
+
U11-2-IN 112
... C112-N=C-11...
Y = S.
Card 1/1~

aiid -HaLolietlotir-~-; W[Lii
Ap'llnk)(. t1ly] me t,c aptai,. ati(i EiAiyli'~rit-~Uaw'!..
derivatives. II
Gil,
Gil-NII +
I
C11 +
G112-N-G-C113
The 'o-1.1-oviing new compounds were obtained: 2,5 7, tetra-
methyltetrahydrohepta-1,1~-thiazine, obtainE by
condensation of 2-mercaptopropylamine with mes-ityl oxide
on heating the reaction mixture on a water bath for 10-12
hr, d20 0.9837, n20 1.4970; 7-inethyl-5,7-diethyltetrahy-
LL D
drohepta-1,4-thiazine, obtained (83%) by condensation of
,A-aminoethy1mercaptan with '3-methyl4epten-3-one-5, on
eating the reaction mixture in a sealed tube on a boiling
Card 2/4 water bati-i, bp 8Q-90' (3 mm), d18 o.9870, n18 1.5008;
4 D

('Otl(len.~.~li' loll o1,
coninound"?. 'alld
and
Derivatives. II
5, 7, 7 -t v Line thyl -4 -phenyl te t rahydrohep ta-1, 4 -thiaz' i ne,
obtained (91%) by condensation of /3-phenylaminoethyl-
15 1.5
mer,cantan with !nc.;ityl oxide, d)j 1 .0720, nD L . c:6oi
It in unstal)le and decompose," on distilling under
vW!U1,1111. It wn~; purified by (,onver.,Aon into the pev-
C 1-110 Pi-I t 0 Gil,
CH.
111V4
The base was obtained by treatment with aqueous KOH.
7-Methyl-5,7-diethyltetrahydrohepta-l,lt-diazitie was
obtained (60%) by condensation of ethylenediamine
Card 3/11 with 3-methy1hepten-3-one-5, bp 93-950 (r~ 1"11n),

Condensation of Unsaturated (3arbonyl 78303
Compounds and fi? -1-Talolce tones With SOV/79-30-3-57/69
-fkmino,--'-h mer-riptan an(!, Ethyle-nedlamine
-1 Yl L
ivative3. II
r
ASSOCIATION:
SUBMITTED:
20
d 4 0.9298, nD 1.11850. There are 3 references, 2
German, 1 Soviet.
Kiev State University (Kiyevslciy gosudarst\rennyy
universitet )
January 19, 1959
Car([ 4/)t

MUSHKALO
I L.K.; SHOKOL, Z.I.
Cyanine dyes from seven-link heterocyclic systems. -Part 3.'
Marocyanines and thiocyanines in the series of tetrahydrohepta-
1,4-thiarilre and tetrahyfrohepta-1,4--diazine. Ukr.khim.zhur.
27 no.3072-379 161. (MIRA 14:11)
1. Kiyevskiy gosudarstvennyy universitet imeni. T.G.Shevchonko,.
kafedra organicheskoy khimii.
(Merocyanines)
(Cyanines)

llt'41-ls-
L)
'Dri J -Imcn, ,
YAY.CTrFNKC,,
Kazakh S'taE~-ffn-iversity named for S. M. KIROV, Alr-a--Ata.
M-1-crobiological investigation of Lake "Teresken". Introduction.
Sri: MIMBICLOCIA, Vol. 20, No. 6, NovlDec 51.
0 0 0 0 0 0 0 0 9 0 0 0 * 9 0 * 0 0 * 0 0 0 0 41 0 0 0

=1111SKIYY B.I.; SHOKOMOLGV, I-.
Perturbations in the system
18:44-51 158.
~ I Ursae Majoris. Uch.zap.Tadzh.un.
(MIRA 14:7)
1. Tadzhikskiy Gosudarstvennyy universitet imeni V.I.Lenina,
Stalinabad.
(Ursa Major) (Problem of three bodies) -(Perturbation)

GEROLIS-',~'CA, L.S., kand. 1.ek!Ln. nauk.; SA-RYU'Hl,'V.A-, 1',F., kand. tWkhn. nauh-;
-,:ash-.*Lriy and sc-aveno-Ing booth for locomotives.
st~-o-L~ ll~ nc.9.,30-32 S 764 (MIRIA 18.-l)

SHOKOUVA, L., kand.iokuss-tvovedcheakikh nauk
How to take care of your voice. Prof.-tel-j,.. obr. 19 no.6:28-29
Je t62. (MIRA 15:7)
(Voice-Care and hygiene)

0000
?etrolol:?~ 0'It
t C
Woo ,4eeis P
70' motie 0".t be
MAU qetTolewu as Or t &'%)'J
19561 stos oilgi, ;,ewlp
e-4
!Z
*tlae
. aleers exe
IleftVVIX te$ tusv aoe& -rov
ove I tTso &aeas Alot
eXe Tue
vat-OPT $to; vu -feetS OeTIwIll, trsAs too t SA
NO-2- ae tor 0 te& tl3s~
9 T Of -to 13jee Ts 0, a3lee-f
00- ~~.fer tralo
;;~~
bolp- a. D-110 ...,,Cll&e e w4ee
"et
StT . ~o 0)
-FLeo tjDjs Tort
IT 10 Iff eTe
8.rtsT -to ..ts
t0& th$lt Wo JbO ~lt'3~ U",Op 0&
se. VOT 11330
jell' tills V,;o"f9.)-s0-s 0 o,, su
.tle 'Afo iA
sutcoo; -ao . 110V
w ' is esoLl4f
e-Jc 'be
310
elcee
TUIS vs:ll Tio

SHOKOTIKOP L.P.
I
Processing of texbile fabrIco for the imparting of crease - and shrink-
re-4iotant-prelmrties. Leh.prom. no.3.-20-23 Je - Ag 162. (PiRA 16:2)
1. Khersonskiy khlopchatobumazhnyy kombinat.
(Textile finishing)

SHOKOTIKO, L.P.
Improving the waar resistance cif, and blended fab=-ics.
Leh. prom. no.2:30-31 Ap-Jr-164. (MIRA 17:7)

VO LC;'; IAT.'i ~'f "iI vlll.l~ iF-p~v~ -;ii0hCT'K0, .".G. (K,i-,-v)
:7 mi- fJmd r - nvris t,-' oa ",,;. r,.-! 'Che s -, re2neo; state
jurd e 1, p z -,ja- hD'o- s in cyl lndr; c al shel I Prik-2. mesh.
c
a rr
ne..- ~ 61 -6'?
1. K:Vev-=k_Jy ~;o5udar.3t-venrvy un4veroltet.

LAIN"I'l) "A" -i,f A.',HC iJENKO, A.I. (F_IYk"v); S1,101,0710) S.G. (KLyev)
inve;3tigating stre-sed :*,ate- of a cant, inuou o ,rail girder. Prikl.mekh.
1 no.7:127-131 165. (YJRA 19:8)
1. Kivevskiy avtomohilt
I -no-dorozlinyy institut i Kiyevckiy gosudarstven-
nyy univer-sitet.

S/1,";/62/000/001/006/010
0-/
D
2 ~ D308
U'-'HOR: 'o-ko-1-ov, K. , ssi stant
U
esl~ -!-.s of ex-jerimental investigations of the working
,--ocess of a coTibined en-ine
LI G D 1 C,% L.- Izvestiya vysshik, uchebny1h zavedeniy. ?.'ashino-
L U li
sturoyeniye, no. 1, 1962, 75 - 94
T',e co-bined enEJne L,.sed for the experinents
cons-isted of
-"actory nark
soction oIL' Diesel ens-ine 16~4 24/27 (i6ftN24/27),
-70 (D-70), a turbine, and a supercha.r.er. The following tests
~-,re :~.a::e and ,e results recorded in graphilcal form and analyzed:
a) ---'ffec-,. of t.-,.e bacic ~)ressure at the engine outlet on the e'L--;'-icien-
C"' of -the comb.ined nlant, b) effect of the air excess coefficient a
I -
C)n'U'lle -I'lant ef'ficiency for constant and variable supercharging -c-res-
Sures, c" ef--P--ct of the air temcerature at the engine inletoon the
-ant e-:'~ic-ency. G-neral conclusions: Analysis of the effective
0
iciency " -L the n1ant by pa2sing- from the thermodynamic cycle to
'fj",-o actual-lone, tuaking into account the experimental data and all
.r.
lactors that distinguish these two cycles, allows: 1) To investilga-
C--rd 1/2

S/14 6210001'~-01100061010
Hesults of exoe-1--i-ent.,11 i-nvestigations ... D20"2YD3 08
~e the for.-tation of 7,he effective efficiency of the installations,
.f) to obtain comparative qualitative estimates of the influence of
--.ndiv--;dual -factGrs on the efficiency of the installation, 3) to esti-
-ate 'h a
-ethods of further improvements in fuel economy. There are
~L U U
16 fiEures.
'SSCCI~TION: a-arlkovskiy politekhnicheskiy institut (Khar1kov
Polytechnic Institute)
S'L;31.* 7~""ED: Sep-ember 25, 1961
Card, 2/2

SHOKOTOV., N.K., assistent
Results of experimental investigations of the performance of a
foux-stroke combined engine. 12v.vys.ucheb.zav.; mashinostr.
no.lt75-91+ 162. (IMA 15:4)
1. Khartkovskiy politekhnicheakiy institut.
(Diesel engines-Testing)

S/262/62/000/014/014/016
1007/1207
AUTHOR: Shokotov,-,N. K.
TITLE: The influence of excess-air coefficient on the basic performance of a combined (diesel-gas
turbine) unit
PERIODICAL: Referativnyy zhurnal, otdel'nyy vypusk. 42. Silovy e ustaniovk, no. 14, 1962, 61, abstract
.Y
42.14.383 jr. Khar'kovsk. in-ta inzh, zh.-d. transp, no. 43, 1961, 96-108)
TEXT: Proceeding from experimental data the author studies the dependence of the performance of a
combined (diesel-gas turbine) unit on the value of the excess-air coefficient. The excess-air coefficient was
found to affect the level and nature of variation of the combined unit; this variation leads to changes in the
indicated efficiency of the diesel engine and in the share of excess work of the turbine in the total work of
the combined unit. The exact nature of the relationship between a series of coefficients necessary for the
computation and analysis of the indicated and actual performance of a combined power set for different
values of the excess-air coefficient is established theoretically.
[Abstracter's note: Complete translation.]
Card 1/1

SHOKOTOV, N.K., inob.
Calculational and experimental detemination of reserves for in-
creasi3ng the efficiency of the l6ChNZ4/Z-7 diesel engine. Teplo-
voz.i sud.dvig. no-3:102-124 262. (MIM 16.-2)
(Diesel locomotives)

SHOKOTOV 2- NZ., J-nzh.
Coefficient of effective heat emission and relative losses in
the cooling system using load characteristics. Teplovoz i sud.
dvig. no.3:31-43 162. ?MMA 16:2)
(Gas and oil engines) (Heat-Transmission)

S/273/63/000/001/006/013
AO52/A126
AVrHORS1 Shokotov, N,,K. 'Oleynik, Md.
TITM ..Supercharge pressure selection as a reserve to raise the combined
engine economy
.PERIODICAL: '.Referativnyy zhurnal, otdellnyy vypusk,*39. Dylgateli vnutrennego
.8goraniyay no..1p 1963, 17, abstract 1.39-103 (Tr. Khar1kovsk. in-
-ta ihzh.'zh.-d. transp., no. 50, 1961, 88 98).
-TM: The problem of the effect of the excess air coefficient oL on the
'economy ofra.turboch6x;ged diesel is.considered for the case when C4 changes as a
.'the-
..reSU3:t of eharge pressure. The investigations have established that the in
crease in the. economy~.of'a combined unit with the increase of a results from an
-indicated process'of the piston engine.
I.,,-'[AbstiActer sno0d:-'Complete translation]
card

110KCTOV, N.K., kand.tekhn.nauk-,; TIYIICHFNKC.1, V.G., inzh.
Superfluous operation of a turbine and effective e-fTiciency c-'
a composite system. Energomashinostrcf:riie I-C, no,1,1.-21 Ja
,64.

KRYNANOVSKAYA, r.A. .. karid.tekh.nauk; MIRAKIYAN, V.M., inzh.j SIIOKOTOVA, B.G.,
inzh.; MIOLODIM, A6G., lazlis
Hydration of clinker alkali minerals. TSement 31 no-5:10-11 S-0 165.
(MTRA 18:10)
1. Vsesoy-uznyy institut po provektirovaniyu i nauchno-issladovatell-
skim rabotam I'Tuzhgiprotsement".

V.11.; KUKOIEV, L.G.;
ik, 10 K ()'-f'0 1"A
B, U.,
g 4t.
irc.Fertle-s cf G-,,at of nctmry and ways of U-sin
Trudy TUzhg;prctse;renta n0..4--4"--54 3.
17 -. 11)

SYRKIN, Ya.M.; GOLIDSBM=, E.M.; SHOKOTOVA B G - RYVKIND, N.D.
3
Properties of dust and ways of using it. TSemnt 27 no. 2:11-12
~Ir-Ap 161. . (WRA 1415)
(Cement plants) (Salvage (waste, etc.)) :

MCLIVANOV, I.I., inzh.; BURGER, A.I., inzh.; IVANOV, A.I., inzh.,
retsenzent; SHOKOV, Jk.L-. inzh., retsenzent; TIMOFEM, V.S.,
inzh., nauchnyy red.; LEKIbTSIND, A.M., inzh., nauchnyy red.;
KAPLAN, M.Ta., red.izd-va; FULIKINA, Ye.l., tekhn.red.
[Building machinery] StroitelInye mashiny. Leningrad, Gos.
izd-vo lit-ry po stroit., arkhit. i stroit.materialam. 1958.
310 p. (MIRA 12:6)
(Building machinery)

84651
0() cn'tj 0 S 12 S/020/60/133/005/032/034/XX
I B016/BO60
AUTHORS: Kazanskiy, B, A., Academician,-Shokova, E.,'A., Khromov, S. I.,
Aleksanyan, V. T., and Sterin, Kh. Ye~
TITLE: Contact Conversions of CyclooctanA in the Presence of
Platinized Coal
PERIODICAL: Doklady Akademii nauk SSSR, 196o, vol. 133, No- 5,
Pp~ 1090 - 1093
TEXT: The authors wanted to find out the behavior of polymethylenes of
average ring size on platinized coal at lower temperatures than those
applied by V. Prelog (Ref. 1). Moreover, they wanted to repeat the in-
complete work of N~ D. Zelinskiy and Go I. Freyman (Ref. 3). According to
the latest notions, cyclooctane can principally exist in two most stable
forms:
Card 113

84651
Contact Conversions of Cyclooctane in the S/020/60/133/005/032/034/XX
Presence of Platinized Coal B016/Bo6o
The amount of (II) in cyclooctane is probably very small. In the centro-
symmetric form (1), the four equatorial hydrogen atoms are placed higher
than the central ring plane, whereas other four of them are placed below
this plane, When any pair of these atoms in 1,5-Position separates, the
trarisannular C-C bond may form and cis-bicyclo-(093,3)-octane-(cis-penta-
lane) may result. In this work, the authors examined the conversions of
cyclooctane on platinized coal at 3100 in the presence and irl the absence
of hydrogen. A quantitative conversion of cyclooctane took place in both
cases. In tile absence of hydrogen, cis-bicyclo-(0,3s3)-octane-(cis-pen'La-
lane) developed in an amount of about 51 wt% of the catalyzate. Appreciable
amounts were also obtained of trans-l-methyl-2-ethyl cyclopentane (about
2350 and n-propyl cyclopentane (about 2051.), as well as smaller amounts
(about 6%) of 4-methyl heptane. Basing on the reaction products, the
authors set up a scheme of this reactions Apparently, the first stage is
the formation of cis-pentalane which then undergoes hydrogenolysis under
the action of the resulting hydrogen~ Trans-l-methyl-2-ethyl cyclopentane
and n-propyl cyclopentane thus results 4-methyl-l-heptane is formed by the
hydrogenolysis of the latter. The same substances were formed in the
presence of hydrogen, but the quantitative proportion was different. This
Card 213

84651
Contact Conversions of Cyclooctane in the S/020/60/133/005/032/034/XX
Presence of Platinized Coal B016/BO60
is explained by a more intense hydrogenolysis of the five-fliembered ring in
the presence of hydrogen. At the same time, the hydrogenolysis of pentalane
and n-propyl cyclopentane takes place more smoothly than that of 1-methyl-
-2-ethyl cyclopentane~ The authors were not able to detect methyl cyclohep-
tane in the reaction products (as conversely stated in Ref- 3). About 1 - 2~,,
of aromatic iiydrocarbons were obtained. toluene, ethyl benzene, and o-xy.-
lene.Tables 1 - 4 collect the results of distillation, the individual
fractions together with their constants, and the quantitative proportions
of the resulting substances. They were determined from the Raman spectra
(monograph by G~ S. Landsberg, B, A. Kazanskiy, and others, Ref, 9) of the
fractions. A paper by A, L, Liberman and others (Ref, 10) is mentioned.
There are 4 tables and 11 references: 6 Soviet, 3 US, 1 Swiss, and I French.
ASSOCIATION: Moskovs4y gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)~ Komissiya po
spektroskopii Akademii nauk SSSR (Commission for Spectro-
scopy of the-Academy of Sciences USSR)
SUBMITTED: May 11, 1960
Card 3/3

SHOKOVA., E.A.; KHROMOV, S.I.; STERIN, Kh.Ye.; KAZANSKIY, B.A.
Contact conversions of cyclo&tane in the presence of an alumina-
chromium oxide catalyst. Neftekhimlia 1 no.1:28-32 JTa-F '61.
4MIRA 15:2)
1. 14oskovskiy gosudarstvennyy universitet, kafedra kbialia nefti
i komissiya po spektroakopii AN SSSR.
(Cyclo~;ctane) (Catalysts)

SHOKOVAI E.A.; KHROMOV, S.I.; KAZPIISKIY, B.A.
Catalytic method for preparing cis-bicyclo-(Ol 3, 3)-octane.
Neftekhimia 1 no-3:353-355 MY-Je 161. (MIRA 16:11)
1. Moskovskiy gosudarstvenny universitet imeni Lamonosova,
kafedra. khimii nefti.

S/020/61/136/005/019/032
B103/B208
AUTHORS: Khromov, S. 1.9 Shokova, E. A., Sterin, Kh. Ye., and
Bo Ao Kazanskiy, 'A-c-aa~emician
TITLE. Contact conversions of cyclooctane in the presence of a
nickel catalyst
PERIODICAL: Doklady Akademii nauk SSSR, v. 136, no. 5, 1961, 1112-1115
TEXT: The authors studied the conversions of cyclooctane on a catalyst
consisting of 50% nickel on kieselguhr, a) at 2500C, and b) at 2500C in
an intense hydrogen stream. In case a) - 61% of cyclooctane was con-
verted, in case b) - 81%. The composition of the fractions obtained
by distillation of the final catalyzates was studied by means of Raman
spectra (methods described previously in Ref. 7). The authors concluded
from the results that three processes take place at the rather mild
temperatures applied; 1) hydrogenolysis of the 8-membered ring giving
n-octane (in analogy to an identical process with substances with
smaller rings, Refs. 2-5), which was detected for the first time by the
Card 116

S/02o/61/136/005/019/032
Contact conversions of cyclooctane B103/B208
authors; 2 ') a transannular dehydrogenation which yields cis-pentalane,
and 3) a stepwise isomerization of cyclooctane to compounds with
7-, 6-, and 5-membered rings. At 2000C, the following compounds were
formed: n-heptane, cyclohexane, methyl cyclohexane, cyclopentane, and
cis-1,2-dimethyl cyclopentane. The latter may be formed as a result of
the afore-mentioned isomerization. About 46-5 wt% fall to the share of
the unreacted cyclooctane, Very small quantities of ois-bioyolc-(0,3,3)-
ootane-(ois-pentalane) were also found. On the basis of these results
the authors suggested the reaction scheme at 2000C.
Card 2/6

S/020/61/136/005/019/032
Contact conversions of cyclooctane ... 3103/B208
H-C?Hle
CH's
C 1;, CH,
J
CHS
U-CH,
Card-JA--

S/02 61/136/005/019/034
Contact conversions of cyclooctane 3103Y3208
The catalyzate consisted at 2500C of 8 Wt% of cis-Pentalane,
- 11~6 toluene, and - 2% benzene (apart from the unreacted cyclooctane).
Besides, the following compounds were obtained: methyl cycloh6xanef;
cyclohexane, cis-1,2-dimethyl cyclopentane, and gem-dimethyl
cyclohexane.
ii-C&HIs
CH, CHj 1--rC HI
cli. XD CH,
Ch.
7C)
CH
-Qard 41A

S10201611136100510191032
Contact conversions of cyclooctane ... BIOVB208
The reaction temperature was found to play an important part in the
quantitative interrelation of the afore-mentioned three processes at
200 and 2500C. Marked hydrogenolysis of cyclooctane occurs only at
2000C, and practically ends at 2500C. The formation of pentalane, on the
other hand, is characteristic mainly of 2500C. The ring isomerization
which is accompanied by hydrocracking takes place both at 200 and 2500C,
but is in addition complicated at 2500C by an aromatization of hexa-
methylene hydrocarbons. The authors assume that small quantities of
cis-1,2-dimethyl cyclopentene are formed at 2500C owing to competitive
processes: from methyl cyclohexane, the latter compound is formed on
the one hand, benzene and toluene on the other hand, with the
equilibrium being shifted toward the latter two. No aromatization
occurs at 2000C. The transannular dehydrogenation of cyclooctane to
cis-pentalane, and the isomerization of the hydrocarbons also take place
on platinized carbon, but at a higher temperature (3100C, Refs. 6,7).
The experiments of the authors showed that this does not apply to cyclo-
octane at 200-2500C. There are 4 tables and 8 references: 4 Soviet-bloc
and 2 non-Soviet-bloo.
Card 5/6

S/02o/61/136/005/019/'0.32-
Contact convercions of cyolooctano ... B103/B208
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V.
Lomonosova (Moscow State University imeni M. V. Lomonosov)
SUBMITTED: November 11, 1960
Card 6/6

SHOKOVA,- E. A.
Dissertation defended for the degree of Candidate of Chemical
Sciences at the Institute of Hetrochemical Synthesis: in 1962:
"Catalytic Conversions of Hydrocarbon of Moderate Cycle Size in the
Presence of Hydro-dehydrogenation Catalysts."
Vest. Akad. Nauk SSSR. No. 4, Moscow, 1963., pages 119-145

BILENKOVA, Ye.S.; KHROMOV, S.I.; SHOKOVA, E.A.; KUCHERYAVAYA, N.N.;
STERIN, Kh.Ye.; KAZANSKIY-i-B-.A:.------
Catalytic conversions of cycloheptane. Neftekhimiia 2 no-3:
275-279 My-Je 162. (MIRA 15-8)
1. Moskovskiy gosudarstvennTf universitet imeni Lomonosova i
Komissiya po spektroskopii AN SSSR.
(Cycloheptane) (Catalysis)

-SHOKOVA, E.A.; KHROMOV, S.I.; BAISNKOVA, Ye.S.; BOBROV, A.V.; SMUN,
K~.Ye.; KAZANSKIY, B.A.
Catalytic conversions of cyclononane and cyclodecane in the
presence of nickel catalyst. Neftekhimiia 2 no.3:280-287
MY-Je '62. (MIRA 15:8)
1. Yoskovskiy gosudarstvennyy universitet imeni Lomonosova i
Komissiya po spektroskopii AN SSSR.
(Cyclononane) (Cyclodecane) (Nickel catalysts)

s -.n Leaves of 9Ctm~ ID18-ntS in relat~cm t0
ar, zatJ i-ri de3ert. Tzv. AN 'Kazakh, S"2?,. biol.
f
k. ! I :-,1 17:10)
~Vly -J p~4;

SHOKUL A.A.
NT

.r_T
ur innova~cr~i of'
the Doksimk-*Lr-o -'ce-,one iiantj flashi ratsionali7atcry v
borlbe za tekYa-Licheskii progress; iz op-rta riboty Lokshukin-
..~~,)go atsetoravogo zavocita.
knizhnoe i,,d-vo, 2963. 9 P. (11-IlEii .17:110)

SHOKUN, V.,'kand.ekonom.nauk
Economical expenditure of wage funds is an important means for reducipp
production costs. Den.i kred. 19 no.6:49-52 Je 161a
(MM 1/+:6)
1, Zamestitelf upravlyayushchego Ukrainskoy respublikanskoy kontoroy
Gosbanka.
(Ukraine-Wages) (Costs, Industrial)

--- SHOKUN, Y.K. --
Some problems of further consolidation of business account-
Ing in coal mines. Ugoll Ukr. 4 no.2:38-41 F '60.
(MIU 13: 6)
(Bonus systems) (Coal mines-Accaunting)

SHOKU-d, A.A.
Case of myeloma combined with thyrotoxicosis. Vrach. delo no.9:134-
135 161. (Z-9-PA 14:12)
1. Gematologicheskoye otdeleniye (nauchnyf ~ukovoditell - prof. B.S.
Shl--lyar) klinicheskoy oblastnoy bollnitsy imeni N.I.Firogova, Vinnitsa.
(MARROW-TWRORS) (THYROID GIAND-DISEASES)

immg~'Wl - -
-SJLOKIJHPV~, A,~Etj_ BJUER, O.N.
Paleolithic site on the Belaya River. Vopt geole vosts okrs Russ
platf. i IUzh. Urals, no. 5:139-1" 160. (KIRA 14:5)
(Bashkiria--Stone age)

.. 3HO"!,Ui,OVJ polkovnilm- tel-,'.nic'ico'lloY scluzhby
Require more from your ratcd specialiSts. Vest.prc.tivovozd.obor.
no.1:47-49 Ja 161. (I.:DU 3J,:2)
(Radio, 'Lldlita-rly)

SHOKUROV, S.
Deficiencies in planning results in nonpayments to the budget. Fin.SSSR
39 no.2:73-76 F 164. (MIRA 17:2)
1. Zamestitell zaveduyushchego Smalenskim promyshlennym oblastnym fi-
nansovym otdelom.

SHOL" I?.
Connection between Muntz theorem and orthogonal expansions. DoklA
AN SSSR log no-5-.910-912 Ag. 1956. WRA 9110)
1. Predstavleno akademikom A.R. Kolmogorovym.
(Functions, Orthogonal)

I - f- - -1---
- , - z. . - .. , ..; - -.j ] . Trudy I r. S - -
, . . ~~ '~ - , - I , I - ,
I " '-' I . ..-
r .,~- -, -,
I - . -- I j-, ~r .
- -- - . ( '~ - T . ..,

~MZGIII, S.S.; SHOLI_.. 0.A.
investigating feeder cable equipment of self-propelled mining
machines. Trudy Inst. gor. dela AN Kazakh. SSR 17:93-101 165.
(MIRA 18:9)

r r W ~Sinlcr self-
I.Jup ri,
~az;ikh. 933R 17:
28:G)