SCIENTIFIC ABSTRACT SHILOV, V.N. - SHILOV, E.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549430002-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SHILOV, V.K.; BELIKOVA,-N.M.; YERSHOVA. Z.P.
'
Fusion method for aDDroximnting the chemicnl composition of Cenozo
igneous rocks in South Sakhalin. Dokl. AN SSSR 119 no.2:326-329 Mr
158. (MIELA 11:5)
1. Sakhalinskiy kompleksnyy nauchno-iseledovatellskiy institut AN
SSSR. Predstavleno akademil-om D.S. Korshinskim.
(Sakhalin--Rocks, Igneous)

SOV/20-122-zi-43/5'
T i,,* 0, ii 3h 1. 1 ov, V. N. . Ka I Ishr-v-ich, 01. K.
`.-In-@ rrob.'Iem. oi' zi-@t- '.uill@@-V-ratonhyre (K voprosu
ob -,,.kh obrp_z.-)Vaniya poro,j zpilito-ker@tofirovoy
I OD 1 C; L: D o k I aKa d (- ri - i na uR. 3 i
Vc, 12' N PP 902-904
The soilate-keratophyre t'ormatian (the zeienokamennaya green-
M' poo@5ynolinez;. --'uch 'rocks usually
or,-imire -,,n me bE:,i,,,-in!-,in e P(.-, -I e (Ref 2).
R C rh g . m;.,-nclJ ial cyci
..'ecording to nresent ideas Ref 1), the spilitic formationsy
although occurring -.-.i-tn diftering acidities, are bailt over a
re-@;-_d .-)f time under saomarin;- _-.@ndkt4Lons. -it is just
r-onda,.ions and not t@ie or-_Iginal compositions that are
held reouozisible -I'or the peculiar end-composition (markedly
aizfering from zhe usual cal-c-alkaii series) of the spilite
Th-3 r I
aleogeorraphy of iaklia-lin -'ur-inz th.e Tertiary was
04" @n
fz;r t:.t, ff'ormL@t7on al spilite-k@_raton_-Yre "Ear@
Ret' 3, La-Le Neogen,@, '@arly Pliocene). An
@,:I a i, in these formatiors ailows not only

C. 11 '@:c
actlv:.tv, buz,
A .%z-
r! SJ 11.qle orti,_)t ions urk I P. C e Mrs
C 1-1 ,h(- b@ oi' tn,2 t'o:i-
rt! I L ns i. I a8soc'ntions and
@n@; 1 1 fnolo@:,y c-'mcil,irlt.d Oias thez p,,111ow lavaR and ball lavas
Viv-'-r _,t:id Onoo- , ar;.t,@kogo) erupted at a depth
;uns -f salinity
ti@. nand znt- analogoug lavas on the
-')i* 2"@"00: ;IIIILIanon evn:-'T@ed in rche !2.uterai zone, at
of le-s r.,ian m. the rauld cool--ng the
s ;q t@ i t & 1 a s sy ,-. i -, h a mr i c r opor phy r t i c -:?x t u k1thou8h
i@i a L -re I
nder ,@.e water h-as nroduced a special texture
tO S0131-2 @_XteDt influenced the m-inerai composition, the
is in no ,.ay albitized - 'the particular character-
AS71C 0: 3I)il.,te-.'-eratcp!,yre. This study has shown that sub-
OTI*I'n.,i!'-.!-, -alone, at least up tc depths of 100 m, is not
uznduce. soil@te lavas. There are 11 table and 6 ref-
0 1, C' III C eS , 4 CIL which ar@ Soviet.
n,;,
0 C T IC, NN '--ikhall k-Q., ,a,~.ictin-a-i-sleiovateltsl-iy institut
7-,11 .' n, a I: al I.-, ': o i e n z i c R e s ea r c ,I I nS 4 t
f
a 0

SHILCV. V@N@; ZADLIROVA, IIA.A.; IL'YFV, A.Ta.,- PODZOPOV, A.V,
Eruption of the Yuzhno-Sakhalinsk Mfud VoIc-ano ir '.hc- ap-r-ing of 19519.
Trudy Sakh.koinpl. much. -issl. inst. .10 SSSR no.10--83-99 161.
(IMIR-k 115:6)
(Sakhalin-Volca--Des)

FEDORCHENKO, V.I.; SHILOV. V.N.
Volcano (pa-rarmishir Island) in 1961-
Er-uptlon of -.he Chikurachkii 0
Biull. Vulk. sta. no.34.-36-43 1063. (1EPA 16:10)

KIRSANOVY I.T.; SERAFIMOVA, Ye.K.; SIDOROV, S.S.; TRUBENKO, V.F.;
FARBEROV, A.I.; FEDORCHENKO, V.A.- SHILOV V.N.
@1-1-,,,
EruDtion of the Ebeko Volcano from March to April, 1963.
Bid. vulk. sta. no.36:66-72 164. (MIRA 17:9)

SHILOV, V.N.; ILIYEV, A.Ya.; PODZOROV, A.V.
Eruption in Sakhalin. Priroda 54 no.8:95-96 Ag 165. (MIRA 18:8)
1. Sakhalinskiy kompleksnyy nauchno-isEl.3dovateliskiy institut
Sibirskogo otdeleniya AN SSSR, poselok Novo-Aleksandrovsk.

15-57-4-4306
Study of the Paleolithic in the Lower Don Region (Cont.)
regions, where discoveries of Neanderthal culture are already well
1. known. The lower Don region is apparently also a promising region
for searching for lower Paleolithic sites.
Card 2/2

ATMORN 3. T.. 3OV/30-59-2-45/60
Doctor of Technical Sciencoa
TITLX& The IMTS-tigotiOn Of Vitreous S-1-C-duat-
(Isuchaniy* stokloobrazaykh poluprovadnikov)
FMODICA.Ls T*.taik Akd.odl nak sssz, 1959, Nr 2, Pp 103-104 (USSR)
ABSTRACT. From December I to 2f 1950 a conference took place on this
problem at the Tisiko.takhalchaakly lastitat Lkadoxii nauk
SSn chni.&I Institute of the Academy of Science..
U)!ftyaioot*
MM It dealtwith the discussion of the experiment. carried
cut# mutual information on the course of experiments and their
general coordination. Representatives from 11 scientific
institutions attended the conference. The follceing 1-turod
wre board. V. V. Tars.ov, NOsko,.kiy kh1aLkc-t.kh-lcgioh..kIy
InatItut (Moscow Chemicot*chao logical Institute) spoke of
experimental results connected i%h the investigation Of beat
oapacity at low temperatures of As 233 and A.13. 3 - His ...Oad
port dealt with the polymeric ooncept of glass formation &&A
:,loond.t.ro In general.
GoludarstreWV7 optlabookly Inotitut
.State Optical Institute) omphssiaad the deoi.LY* "Is played
by the covalent bond In glass formation.
Aa_Aa__T_&Zko.l1n, Institut khl-ti Ilikato, kk&d-.ii -k 33SR
(Institut-e-o-T Silicate Cheal.try of the AS USSR) described the
investigation of the structure of the Yet.. As 2543-L42 T-3
by X-ray method..
Institut kri.tallagTafll Akadealt cook SM
(Cr7.tallographloal Institute of the AS USSR) "parted an the
structural Invontigation of some chaloogprAda by olvatros-
diffraction.
A. 1. Cubanov and T T,- rhert-4,-x, Ylsiko-toithalob.skiy
Institute) "ported an theoretical
problems of %be semiconductor properties of glass types.
.T-j..MLLjp.dIscuo&od working results in the determination of
boundaries In glass formation in the As233and As 23.3system..
J6_As-Q2Mawvm compared the boundaries of vitreous state In
Man systems with the criteria of glass formation obtained by
Z&kbarl&@.U &M4 V12tor-lasya &A4 found that there exist.
Gorrelation between the..
_Tt_F@1&xarcv& I"g-tigatod the electric properties of
Potalcond.ator-glass type. 1. the y1a. - As2Se 3 system'
4%. 2. Waxiy.t.,spok. of research work in the field of Inner
7KFG_47-Q_VrrV-wff.Gt done by T. 11. Momantova.
D.A. P&Y1 T dl-aua..4 experimental "suit. of the position of
-the absorption boundary so de,@Adeat on the ahanSo of
so.p.olti.n of glass typos.
V. P Food;;, "ported on material he obtained in the
roll 'I.Goally of class type a in the
As2be 3 -An2T.3 system.
I
.j.T,1K 1::l rized the working results obtained by
PhY:L t::hL=11nst1tut* and fcun4 that in the material.
trm.:tizutod the short-range ordor 1. act changed in the
it!.*,n from the vitreous Into the crystalline state.
,,@ A. uningradskiX kh1.Lko-tokhnaIogich.&kiy Inatitat
ngroA Chest co technical Institute) d-4rited the
investigation of the semiconductor properties of silicate
1soroollic.to gloom types with the addition of iro-ob.1t .d
ti t"Lum aside&.
_K. T, Zalvarpkh- Xa.kovokly 1-tit,t :iokt-tk
at
,,:kla (Xosoov institute of Mqotmt* hG h.Lch:.akcg.
I& .. )tILoad
and inwTig.tio. r..ults of the bounUrio. of glass f.rou,%jon
ty,.:h,., lootric Properties of ccutiguous sdaicoa4uotor class
the composition V205 - P205 - H.0y (R- ale'"ts Of the
It Ilv IlIo IV AM T groups of the periodic system).
Th.tas's t conference On fool-oond-ot.r glass type. .111
pro ably be hold in 1959.

VASHKO, A.; PROKOPOVA, G.; KOLOMIYETS, B.T.; FAVLOV, B.V.; SHILOV, V.P.
Absorption spectra of glass of the system As2S3--As2 Se3jMIRA.
Opt. i spektr. 12 no.2:275-277-F 162. 15:2)
(Arsenic sulfide--Spectra)
(Arsenic selenide--Spectra)

Effect of disturbance of short-range order on the electrical properties
of so) id solutions with tetrahedral structure of distribution of atoms.
D. 1. Tret'yakov.
Some electrical properties of solid solutions in the system
AgInTe2-2lnSb. S. M. Mamayev, V. 0. Prochukhan.
(Presented by 0. 1. Tretlyakov--15 minutes).
(Paper not presented).)
Investigation of thermalry.stimulated current in vitreous Tl2Se-As2Tie3'
A. M. Andriyash, B. T. Kol6miyets.
Measurement of the mobility of current carriers in vitreous chalcogenide
se.T.iconductors. I. B. Ivkin, B. T. Kol(milyets, E. A. Lebedev.
Oxychalcogenide Glasses. B. T. Kolomiyets, V. P. Shilo.
(?resented by 8. T. Ko)on.I-*yets--20
@Icnoz-t iorascnted at the 1rd National Conference on Semiconductor Compounds,
ris*,-;n,:,,v, 16-21 Sopt 19,63

PHASE I BOOK EXPLOITATIuN 540
Shilov, V.S.
Ratsionallnyye konstruktsiJ. shtampov kholodnoy shtampovki; opyt Lenin-
gradskogo zavoda "Krasnaya zarya" (Efficient Die Design for Cold
Working; Practices of the "Krasnaya Zarya" Plant in Leningrad)
Leningrad, 1955. 14 p. (Leningradskiy dom nauchno-tekhnicheskoy
propagandy. Informatsionno-tekhnicheskiy listok, no. 88 /.,776/)
7,000 copies printed.
Sponsoring Agencies: Leningradskiy dom nauchno-teldinicheskoy propa-
gandy, and Vsesoyuznoye obzhchestvo, po ra3prostraneniyu politi-
cheskikh i nauchnykh znaniy.
Ed.: Chuloshnikova, Ye.P., Engineer; Tech. Ed.: Freger, D.P.
PURPOSE: This pamphlet contains a brief description of various dies
and of the elements of die design. It may be of interest to die-
makers and to apprentices in this trade.
Card 1/3

.Efficient Die Design (Cont.)
540
3. Progressive Pierce, Blank, and Form Die Using Strip Stock 6
Die Construction and Operation 6
4. Die for Piercing Holes in Material Where the Thickness
Exceeds the Diameter of the Hole 8
Quality and accuracy of the pierced holes 9
Die construction 9
Die operation 10
5. Progressive Piercing, Blanking and Forming Die for Tubular
Shapes Using Strip Stock 12
Die construction and operation
Wasteless pressing of thick stock 13
Die construction and operation 15
AVAILABLE: Library of Congress
Card 3/3 GO/ad
8-25/58

GOROKI[OVSKIY, A.I.; i"INYU, II.N.; SiWW,UOV. S-V-; SHIMY, V-S-
Semi-autoruitic distribution conveyer. Kozh.-obilv.prom.
no.10:9-12@. 0 '59. OURA 13:2)
(Assembly-line methods) (Shoe manufacture)

VAYNTRA'UB., David Abramovich; KUMETSOV, Dr:itriy Petrovich; FILINA,
Irina Stepanovna- SHILOV, Viktor Stepanovich; TSUKM, G.Ye.,
red.; FREGF-q, D.P., r-eY.--32ZWv-a
[Cold extrusion] Kholodnoe vydav-livanie; obzor. Lenipgrad.
So.l. 1961. 62 p. WIFLA 15:4)
(Extrusion (Metals))

VAYNTRAUBI David Abramovich; KUZNETSOV, Dmitriy Petrovich; FILINA,
Irina Stepanovna; SBILGV, Viktor Stepanov--.ch; TSUIMR, G.Ye.,
red.; FREGER, D.P.,-red.izd-va - -:
[Gold extrustion; a review] Kholodnoe vydavlivanie; obaor. Le-
ningrad.(Leningradskii dom nauchno-tekhnicheskoi propagandy.
Seriia: Goriachaia i kholodnaia obrabotka metallov davleniem)
No.2. 1961, 47 p. (MIRA 15:6)
(Extrustion (Metals))

ZIPIEV, A.B.; PIPOYOU'VIGH, A.V.; SHILOV, V.V.
Equl pment for automatic tempers. ture regulation of die-cas ting molds.
Mashinostroitell no.10t6-7 0 165. (MIRA 18:10)

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meth(m] I-% dr4cribed. Th, following modifications of the method are suggeted, (1)
69 I-Ilillyirne t1ibromide can be easily obtained dirtetly from tech. grade bivinyl (butz-
1
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(2) TtirtmofN.Nfciin,.tradof,14IBfeinthrreacik)n
di,tir) I,v the Tin,
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I1rCII
0 ,
WAi found more -atkfurtorv. *rhe diltronthle I% next shaken with water and ppiol.
Ag,O to f.rin 110%f,!,N'Citiltll:CIICII,N%fe.OH which ii then distd., drop by drop.
-.ind the CIf,-CIIC: CII rFrovert4l In a linuid-air condenser. jamcs@orrel@
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:
0*0

4 1 A I 1 0 is 11 tj 11 4 it m it Is a :1 a a id is a 2x it x If 1: U 34 a h v is it x as a 11 'm a r
A 11- L- . is % W, M41- I
A
Do JO .01111
Condensation of scatoldehyde to aldefl.
Do butadlems from IS-butyleae glycol.) ..H. A. Shilov and
C-- L Y&kimc'F- SAW. Kaw"ah 1934, %fo'4, 7-12@ -0 0
Condensation was carried out by the addo. of N&OH (0.4
cc. of 10% NsOH Pff 20 9. of AM as standard), The -0
0 Speed of reaction increasm with the proportion of catalyst Do
and witlo an inerfeast: in temp. The Presence of ether
go retards the reviction. J'he reaction stopa upon reaching &
C m1ain limit. Water ant! aics. do not chanle the limit ot
condensation. A th-.WT .00
00
00 0
00 zso
'. @64091t'i
W
pig I'D*
Dip
jk I RI LAIfALtj;RrKAf, LITIM41449 CLASSIFICATION I i
00 Si I ..
to 10#3 - C'. -I aw-e@@ -it,
-V
- ) I IF
0 11 11 01 K K tt 19 9 It It It It cc K43 n I&(Ido 9 4131'"S"13
0 0 0 0 O'o 0 0 46 0 a 0 0 0 0 0 0 0 a 0 a 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0.
Ol

A
St
A
00
go r
00 A':1
00
00
09
U 13 1
Y
@100-1 I
ASA-ILA RIETALLURrICAL LITFRAT
:7 7
%,.ago -, 1 1. Na')
U st AT )a Ill;
IV it Ir SO 4C Or
000 000000
@O 0 : : : : 1: : 0 0 0 o 0 o

1
8
0
0 00 i i lip i!#
1
.
U
1
1
2
1 Ill it a h 9 is j
V a
@ 41 61 Al Ad G
'a

.
-1 T u V-
V z &A
k
@ .
two
is ..ts 41@ _Ot-s
Le
PDOCiSSIS A-D 1`110"11111 -4011
a the additflas of hypechtattillis add to a doubt*
d -
K
A
dd
k
d
.
.
.
a
Clotoo
an
1.
15!rdid - ad
R
Clitesti
S
S
(11
Pk
)
:
J
.
.
.
.
.
Yj.
raev.
.
X
And JC
6U_-j2(Ig34)._In the absence of other substancini
-00
addn. of IIOCI to h1eCII:CIICOjII Ia aq. *olni. front
d
it) 0011, M proceeds acs-oftlinx to the tritnt.4. ellitAtiou

03
.0
l
a04
Idt - k1lICWIjIjC&IIAj. The prr%encr or C
talytically and Witten lite order of the reiwli-ii I., lite
taly
d: - diHOCII/di - kjK X kJ11100110-1. where
nd:
K X Ill is the total concti. or mot. and ionic crotonic
X
At 0', k - 33.3 X 101. The value of k inctrAse,
th H-lim conen. and the complete kinetic cipiati-m is
t
j moo
d(ttOCII/di - kiHOCIIIKIIIICII + k,IHOCIllkl

hI
'
'
to2f)
HCIJ. 'Me energy of activatlist is 7570 cal. frornO
n
I
C
@H
@
x In". PH" [foci Join.
nd the action const. a b 4.8
tj
nd
prepd- by treating Cl water with AUM, till free from

was
.p
isdor, and Shen filtering. Thiss,sciln. had a mol.cond.of

Cl is
Ci d
:
* 0
1.11) at 0". F. If. Rittlintann
.40 at diln.
0 Z
.
So
coo

ties

CLASAWKITIC. Uz-
1:111111, 0
0
1

. I
1*0
1*0
VOtt Ct J., is,
0
A
I is A I ZA
a K It 1 a t" 0 1 N It 5 a
o
I it it cc KLo a i m An 1
1
;
-1

"

0000 000*00
so 96906004000
0
'so 00
0000000-0-00100:40900000000,06 0:,9 0
i

0-0 0
It jC 0
a - I A WZV 0 U f, 't, Ut -AOL .11 h, I Jye
A
0 A if" G.vl#t
go - -- -efK(twc% '-Ut i -00
00 A
Of
The rate of hydrolysis of chlortme F. A Sluiny and
rill
oo VRUpinska Compt. rr"d. drad. -.T. S. 00
- ( M@ 2114 eseti.dt
so a .14 %n The rale.4 the r .00
. ,.,i)n 1 1110CI + H # 4 CI- was measured toy drig.
elve. tviud. i,f Cl solist. The hydrolysis of Cl ptusveds - 410
00 A:'@ y ralildly even at 0'. When u coned, voln. fit Cl was
I., the Lond. fe-Ached its find value in 2 min., but
of x ments made in the IM min. give values soniewhat
go x 0 the final value. The rate is therefore rapid but
R. R. Rushton 600
00 13 1, zoo
oo') coo
=00
00 -w
oo
are*
zoo
x0e
!:Nei
go,
A i I A ETALLIjRGKAL LITFRATLA CLASSIFKATICN tto 0
0 to,, 14-1 j.'- wee
Able 's,
W UP D 11 OF K K xcr n a Kw n xa ena,
100"410 0 0 0 0 0 0 00 0 000 0 0 a * 0 0 a 0 6@6 0 0 00 0 0 0 a C f 000
0 0 0 0 0 Sio a 0 0 & Goo 0so 0 0 0 * 0 0 ejo 0 q a 0 090009 see
4

*ego 0 4 0 0 0 Wo a
1 3 4 1 ? I f 10 10 11 11 14 is 14 ly 13 2 0 jivilmadlem" ape
A@l C_1 L 9. L -L- I It
00 Iri
Tim RON 01 die endowed" of scolawArds so
,qhftv j AMW Choi". (U. S. IL 6, m
01"tion was mard outlaith 9.3%
Itimewladed that tbecondf tWuX
.00
of AM to aMd Is cimed mot by cumfiflam of - eqW
b be formation of a comvpd. d the WM md the
mvb&W bas t1a ATWtuft of a cr&
see
MecH.O.cHme-MCK(OH).0. Twd- reemom.
A. A. liarhilingit
ass
r
coo
'004
goo
010 z
00 2 Zoe
e @192.
00
.OIL j: Joe 0
0
*0
zoo
Ole
o A I aS L A mtTALLURWAL LITFRAIL41 CLASSIFKATICk so
0
W., .0. 1 M 00
040 tj .1--j-
7r
T IA An L S I Od 0 N a I V N 2 a 0 2 1 T
U tt AV Ll! A
0 0 o 0 4
Its
0 * 0:0 00 0* 00 00 00 0* 0 0 4 0 0 0 4 0 4 4 0 0 0 0 0 0 0 0
*TOG I I I

a L a L_j A
A
0 Al
oe
of
fig
v
I
00
-t1-LLUi`1k.L LiffitAlt
3 it
%

it U IS
1_ AA a IM 0 OL11 it
:00

Thee vielmity 0 h?"jak at ckkd" H A-Shlovand
ff1w, stod--w.- (I R, j.4,
-1
Ifit
ll
h)
1 ! 0
a
.
t t
a
9,
031---41w title W thee rm-thm Cie t Not) .-!-
HOCI +
C4, Imalk fullamerl4i by "Wititwinx Ow ivw. 11.'r
"ItELIO) Of friw1ken twiwrvn phroul 111161 llml Ibi-
0
[WAS 1wirimalrul ut phenol Evr"j, 'iful J% tired. 11V the
:w "elvik"t .4 Or fi*1114114,11 14 C1 fl."Is 1100 '411.1 11VI
01%1'4 111r,611% 14 -61A. 11w 4 to,
0
Arthur A. V,,jition

;we

ago

tic.
C k '%I'F OC

IF *1TL AA 1 4 s aw 0 it a I w 64 it I
I
00 00 00

17 4 A if a a is a xA it 11 2 0 m 15 is v a x 4 41 a u bia
I M Eff b A , I
9- vA I I M -L-A-,- k __p -_,_ a , ,
110 --0 4" 900-
0 A "P L
PSOCM11 &me Vneptay, -01.
of .-Oo
KINUICS --F i.DDITII-v F :-r:--'"1H,LC`1':7 A 11) 7@, 1-00
D ilb-LE i ONDS. H@P3CHLOK'7z AND --!:YL
and 1,.7. o"te.,mAkovh. J
Of -.A.. Shilov, N.P. Funyuev
PTi 8, %9-2B(1936).- For the for
o 0 mation of 2--chloroeth&nol the velocitv is @lrmort; ntil
X'I i I . '. see
00 to the conen. f iinhydrolviod CI.1, i. e., to thn mte
00.3 of hydrolysis of the C1. The kinctics )f th, rouct, - n
00 j between HOCI and allre at O'ard at 0.(C?Ql t@- C.C.1
00 '.n-1 . PL r 1. Is t@iven by the e.,unti-m- d(".:") '@t
coo
-f th-z eth y re a**
males oer 1. cr min. In -On@e f rl`@) t"ere COO
id a catalytic effect that follows the d(C.;--' 1@ 'dt roe
(ECCI )2- where Y -,,i s -imLx. at 201,` 0--" or is@*
1h nvid d ify) At I 0@,' I
(I-L-) Ythere 1 0.6 x lc@ mol. o-r 1 . r in . 2 7i v 9
17 Now
%a" - ann
S . S L A ACTALLUNGKAL LITERAIURE CLASWKAtIC" tjo
ap
%*JC*13 k. 04, C-C 411117dwe. 4#1J31 avc Kp-, Lit
C . . an L I I ad 0 K 0 1 Ar rx 5 a a 3 1 v
u s% &V so U at In 11, i. '. 11-4
44b* 0 0 *if 0 0 0 0 Of 0"'0 0 a 0 0 0 Olp 0 9 0 0 00 0 o a 0 0
0
0010 000 0 0 0 0 0 6 0 0 0 0 0 *1# so a 0 0 0909000

Wr9*010000*6*900 0 0 0 0 0 9004-969t over-
*a,: I $ I a 1 6 1 1 1 TO $I U U It is WeV 0 TV IT TM 10
A &CO&I All ILLjL_S_-p_g Is 41 a a a a
ILI I L A
It! L!0e (-V- 0914t
00
into Parpuft are Wt tlarlz
A NOW tbltwids im tbt C1611=11trY W ChAtwim bteadlizz. -99
F-A"'P*Yr- rpw. 1937. No. 1.
JUV M; XA;'W- Rl!".11. Zk-,. 1. Nw 3. JiLtz l!Ql_ The 00
0
00 Author a new throu of Cl l4raching avtwlllnjt 0
00 1 lo which this pracm is a tkrsteucji,@n -4 tltc ""ed
.1,triptis, The Oil and NHj %Tmpri activate the cutraawj 1:60
00 A!' Cl into the tool. of the aniniatic runigki. ()thcT 1.90
I Not, Coot 1. SAM 1. etc.) air tir,activAtittg. Nvii,jrimps -00
Ate 0"It"ilu"I in the Ituil. W diff"vilt dyes. fluting the
Iractiorl firnt the chlotination of the (15ac takes plae- 5*0
so J.il@ then its disintegration into the o- and the P-lormls. The =00
addn. of increasing amts. of HOS06 increases thic speed of
90 the reaction. while the adifix. of a Igm first increa".
later decreases it. Thernals."vdo(sractiontakesplacr
in a ba:4c soln. The cause ill the decrease in the bleach-
Ing speed is the wJective ad-r-ptill. ,( the ba-w n,t .f
1100 by the fiber, as a result of which a greater Nac)H/ =00
1100 ratio is formed an the surface than in the quill.
00 Intermediate complements are formed during the addn. 900
fit HC10 to the aromatic ring which are staWiwd into Z940
likmbirdrilas in aliphatic complis. and as substitution
products in arutnatic comp(ts. The caralytic action of 600
Acids and bases is the rrsult@of,tbc: formation of inter- '00
inediatc comptis. more active, 1100. Only one
practical conclusion is madle-CIrchitur must be dme be*
in alLaci-i *00 P tkon
t'*
BETALLU*GKAL LITERATURE CLAWFKATWit -"T z
-4 ZOE *14411 *-t filial. ant a.. lit
U A it
791 a A, Ao Ili .1 .1 Or a, IT 119 19 0. a a a a 3 1
Ell .19

Is 16 ly Is On DMISUVA29 Alil I? U Id A it U 11 P W JI It Al a ago
C I L
A ZL--I- JL--L a. it P 9 it L.L J-1-1 1 h 6
[

:-99
*0
06 ir KW*tka of t1ke adtlifiomi ad hyp"Alorom add at doubt*
,bmds. IV. R"oakrom add md 2-butesm-1,4-dial.
'
'W
E
1
d N
P 00
.
A.-
ilov sol
. P. Kanysev. J.
Ays. C". (1.
. S.
S. R.) 10. 123-31(1937); cf. C. A. 31. 21ro 51.-Tbe
kinetics of the reaction HOC[ + HOCH,---CH@Cil-
CHOH - HE)CH.-CHOH-010-01,011 in aq,
Soln. at 0' obeys the 3rd-order eclivatiou All C- Cj!dt 00
00. kall-10011IC-C) where k, - W ma"ll, min. at low

3 concus. while at higher cloncits. the exponents 2 and I are
09 replaced by 1.9 and 0.7. rt-sp. HCI acts as a pos. "taly@t
00 and the order of reaction is given by the eqtiwtk,n J1 U- coo
Ci Idl - 1.1 limit it *1 Ict-1 wbm 1, - 4 X 10-of Iteatly
coo
the value fur the tmff. of rrhydrolysis of 0,, iadirminx
that Ch mots. play a deciding Me in the mcchanimn of the
reaction. In alk. win. the kinetics is exprewd by J1 C-
a so
oo a Cilds - qJ1,1001100-11C-Cl where 9 - W.WO up
to 15 auAe % 14*011. and decreases at higher coneas. of Z go*

:0:0: j1d either N&OH or of HOCI. The complete reaction rua-
'
1
400
t
415 s Of consecutive stages of which the butme-1
-diol-1.4
ion is oar. F. If. Rathiuman ]1

A I a I L A AttAiLLMICAL. LITIRAT01 CLASSIFICATION 1
S :
4.11 q.-. 's,
I&L"ONt,
- - - - -
-'
-
- -
-

U AV -0 11
009 Kit Ra Plan It 19
,
4
J T All A i 0 1W of 01 ji
lii
i
HAD (I I
n ,
0 0 0 0 0 0 0 0 0 0 0 I
0 0 a 0 0 0 0 0 0
.
0 0
0 iA
0 00 99,9 0 0000000000000 0 41;* 0 00 0 0 0000 0000 0 * 0 00

Ill It It It it to 14 It to " v U b )o A A V 111 It @ x 11 V
;1
A a Al-I 'A 'A 1,1 @ I.-I AA 81 CC 0 U@l 1 0 d t
A A A. A x r 9 4 1 1

Preparation and control of hypobfumous acid. K A.
S
5111k)v awl N. 11. xanyaurv. J. Gtn. Ck*,M. it'. 8@-3. It, I
'
IftX11ah
447(lU311)).-Bromise matcr wwK.
00 0.01-0.05 mal. Rr per 1. is abakru with an ext-tse, of AIIII't ?.%
410 until the Word Dr disappea". 11m win, isdistd. inmis
all-simillstjI.app. ThedistiOstristestrtiff)rfrmitri.y
00 mewts ot AKNO,. S. L. MadorAy
04
1MOC641sm of balosenstlogi of phands.
Gin. Moro. (U. S. S. R.) 8, sl9--"3(I9Mq cf. C. A. see
So 0 j 32,67714-A fxAmic with lAklambetstoysud Arkhangel'.
zoo
Akaya, C. A. 32, 51DI. Chat. Plant:
oo
00 z
00 j,
zoo
zoo
!.se,

40 o

1., .11,11 C., all
K it q( so It to It if NW(I 1 @14
g
o o 0 mo

6-10- 1W . . - - - - - A .
$'go :Fxqra@.= a 0 a W a - -
its I I I hillulliIII5116.11 0 " 1111112 Ilion 17 WI. 1 11 it 13 J4 a Is 9 a 0 0 41 4 a * a
A-L-A A F_ I 1_11 IM-LU or a fi-L-L go
fIL ..a
&to rsurfll,@t11..14-%
Transmitting mechanisms of organic reactions. P.
Shil(IT, N 1; 1111,t-I
Its-Nl(ut litilthithi, S litttl@ A
i'al tirK. tracllolti %ifil"ill ull-Iiintillit jil'.4 11"Ill ClOwl
it kini-tii- %i-1h.itil I Ili- li- 1wit,
lilt! fMillatit'll 1.141 4 fit) vtilt-.
11", lifiritycivs, kctip-cu.if lailto"IM/ation, loriiiiinl3iiii:i if
an criol, t lie CanniZzarij react ion. 4 lie 11,1wherik" rc.lef i....
the ClAien Evildru'llimi, .."JuIC11,111"ll I,, loyin bull I.,
CYCHV 'llitim And 'Illistitlill.,11 all Ow I'llilrow ring, Or-
xoo
ell"'14"lly "ItIf'"t-Itt"tl '"Ill
S J:-iik. Flillid-CtAl M.1 till
,Alicyliv acid. Thus, addii. at till joilhic 1-10
M-Cil" w, it silliple hilill.f. teactioll. I'll% it
lit Ow twitt
.3
'I'vi.triltAlIv ji- W.
lie %all l4, ItL,- wa. I I'm A C-L 09
AtTALLUSICKAL LITIENA!tOt CLASUPICATION a.Z'- ts
1,1083 Wip 0.- Glit II*A a., lit
7
11 A, to Ij
1) u cc it It
: 'Oro .0 0-0 0 00 0 00
;0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0
04 Is U it is is 1. a Ij If A A V Is A. m It U a J4 is is U 0
L__r GL -n- I - L - L_ A - It r & A 11 1 - Q - rX M [Z i A.- 1@ 1 4, -A
00
I tt- )-il CODIRS -
-00
a Di. find polvarylethanes, 1. Di-p'ttenyletbanome and
' I,
Vudin
Gm
i I K
Shil
J
d
i
ti
A

go
.
.
.
ves
.
.
er
va
is
, ant
v
The tctn "xrn" of
(ftkilo
.
mittyl, prol-,"t by Hale @ C. .4. 27. 76) 4,; a 1,444 (" the 'ViS-5' 1from PhNiglir anti 111, rlvc@ a cri .nl.,nz .4n. in
'
(
; -00
o AtOll it gavr P.W.-
h! anti ill dcri".. is ti@cd in this vcm@. concd. ffr@X)., Wilh JFCI or IM
,
" Ifficticlaturc of I
00 P-Veffoliff, I'lic.11,01,01I)COC.H.Ph (11), was prelld. 1fgC11:C!CJfXhjPA, to. fC411,). This in -00
Ir,"it p-PlIC.H.C110 W. fley, C. A. 26, 4421 by conden- C.% with fir virlded an .-broinidr, m. 212 33 . prrmwlly :_*O
@tittn %fill KC.N in If). a1c. by the nielhod of Ct)nil--rg 7 1-j.-Xjpktkyi@-1,:4t-p, I !

of
and Vall Nalla @ C, .4. 23.3!Ch. The aildn. of 24) It. Zn xrx?Mh,1xO1. If'. I from -CJlt.Nlgfir andni
give, i-00
,
thl't if) the 0-11M. 421 3 hm into builing41 g. I in I L 4 an intvnwiv Irtri-ji st)ln. if, lfl:@434. changing on standing tw -00
JfKl",Q AcOII and the revrymn. of the pill. from boiling heatmil fit vrimvo. The ethene detir., fit. '-VJ- W. 11.

06
Nviror vielded 34r"O di-p-rmyletha none, PhCJ1&C113COG- Synthesis of 1,2,3,4 -tetra -p-zenylbutane- 1.4 -dione and 2Ito

00 13' Ili, fit. :iij% it is practically in-A. in cold tetra -p-lenytiuran. F. K. I'milin. Aid. Ph -

'
-
1
i
k- C
i
d
l
h
l
i
h
A
CHC
=00
ar
. w
.v v.)
ot org. v
verft
t
a strong
.
and patolg
n
O(V1.1
A
41, (111), In. Zj
, 3m_5
, was oblai-3ed

Of 0:
cence. Its orime m. 173Z-4'. 11 is but little I I j from 11 in Cill&.N fly midizing with Vice- of Cu(N(h),
ld.@ 'Jo zoo

00 r
cooilm . it d-s mn rcact with FcO., AcyO and AcCl. on a water hath (cf. Onninerg and Van Natta, foc@ cli-). =00
- t21
With I and 2 mol-. Hr in CIICI, and hc3ting. U gavr E2 [-outing into ILO and rccrystg@ the ppt. irmi xyle

go
fit. (C.114). anti the irmn the Pitt-Hr anti mit-d dvriv,_ of 11 by cunde lux%
ae 0
ro

Of
dibmmidr. fit. ISI -3 % resp. Thc attempt4 to obtain fir with Nattirkupfer C in lJh.Nfc. Unlike 11-hur like trian,
: ,@a
400

! derim ,f 11 fmin I with If fir at 130--44Y and with Pill. it) throne, U
soln4. do not fluoresce. indicating the a
Itsencr
;
142'
t1
di
f
li
l di
i
b
i
d
00 X . o
mime
one, m.
eno
um
-p-rrn*
zat
1,4) on Frillix
on,
1
nx pro
ul an Ihr addli. Ill H'SO, give a slmn,

0 0=0 nit,] Grojon f Her. 30. 21Y_1VISAf7)) observed analo- bluelluorecen,,, Ill with rzmss A@Cl in .,,ch:d hcon
1
I and PBr
I Ili @ f
ivs
heati
d its d
f b
i
1 l
o
di
.
or .
er
minitation o
enzo
n an
j
ng at
us
im or at IM for 2
br.%- gave
g
futuird If. A in%twosion of M g. I in tM nit. of hot CfICIv 101% of Ill. 2,81-IJi" sparingly o]. in
retul, Willi SOCI, to give 4:11"o /'hCJ1j(71C7COC411&Ph. mg. v-)lvrntt will% inieum: fluorrswtntr. Cf
Itl if.-
zoo
00 Ili, W. It feacts witW arvi magnesium brornid"
00 to give which Willi IICI in C.114 are fie- @411111 0

00 corupd. to brn the cmtc-lumflint ellwge d-i- 1-1'keprW-
00
00- L lib. 6 AA. 4AAU. T".
00 1
L -11 C.WAL Liff AT62E CLASSIFICAtIGN f z
of
0.
0 j __I
- r -1 - --f-i n-

0 qX
j t I
to TZO
D 1. 64 K Cf it U it it It Ox, 0 @@114 12
0 0 0 0 0 0 0 a o * o 0 0 : :1 4 0 0 0 0 0 q 0 0 0 0 0,
1
T
@A
IS
: 00 ,0 0 f 41 0 0 6006600000
00*.00000000000000 0 0 0!

I *@l
it
&2-da v a ,
F-k-4 bi W-M -W1 at it u j4
M. 0- a- d a I 1 41, A --AAL-
MQ -0 .10 vi@#

Unklimp. N.

- "Wonat OW hypockhtione sm a add
'
!
09 a ceamtisdamis. - 11. A. Shwv. S.
!S-W
N
4nd
so A.N.Kurskin.
-
O
I
f
el
(
C. A U 414
.-Is sq. RCI C#11. w
M
1
and 1101
tufan@(CUPi
olf(u
I
(B W CI rftct
f
l
lic
i
.
,
s
),
M l.
t
ic
coacm Is wt
cr tha
I
n O@ M tDA mt. all
S I facuted 6
3.4 Mol.-% that of U
=
A slmflw mllatka In true -. himllependerl of The HCl cown.
for the tonnadmat of the chlocome.
&W dkW*rkk In the ramcdaia of Cl idth " ak. It 4

00 -3 Infefired that ibm Is a wo& of furmalka of I from 11
eAd C1 wbLkh do" not Involve the partkim6aii, Zat",
lam at the dk=t. notimtslyzed uWua of C1 to the double
bond. D. C. P. A.

a
I L A MITALLURMAL U7111,67100111 CLASSOICATION
ZOOM c1i;@111;1I
`911
.00
-00
-04110
As 0
coo
go*
v*
=60
-00
good* mollf Of 1 '14 (1 3 it T
)a As ip $10 a a 0 0 0 0 9 0 0 0
0 0 c 4 0 0 0 0 0 0

goo 0 goo o 0
7
`
9
a T
0
1 36 27
2
1 a ace
Iq r a a I I- Y Y@, 0
I-A-1-1-M.
U

64
/C/
00 Brotniat cation am & bron"atins agent. Fvgrnii -00
*0 -Widum-awl Nik-Oul Kunyucv, Compl. rex4, aftPl. w,
-00
U. H. S. S. 24, 890-2(IWU)(in Ongfish).,14nev the ve-
00 it locity of the reaction huaw"a Na AsAmdaule lullullatc anti .00
110fir variesditertly with thecumn. of buthJlODraqdR'
isla In the soln.. the l1rculson j* pro"Y the hatul brplni-
.00
nating agent. When the brovaloation was carricif odt in -#6

prestiwe of 118t or 110 (instevA of HXOj or
"
'r
2C [it And BrCl ("Med acted as iadCpctHtTnt brotainating
accuts, their activities being detd. by their tendencies to
IxAarize into Br'X-. The velocity of brornination of Nu
m-anisolesutfonatt increases in the folluvring order for the

ous brunditatiog agents: DrUff, Dr, BrCl, Dc ion.
.i
cog
of j. George @ky@rs Ice*

coo

so I

00
AS- SLA -tIALLUPM -L LITEROURE CLASVFKATIC@ C: 0 0

00 It --iW-1.7
-
-
-
-
-
i
bu n A. .0 1, V i
T
TU
1
11 o I it IM ii
Ti
69 Is K q Kan )t "@Uzn

o 0 a
T dna
0 * 0
o
0 *is 0 0 0 4 go 04 0 0 0 0 0 9 0 go i

491 1 1 f A F U TA is I - -
'A r Tv Jo
. b A
00A
Xmy., and E. A.
o a -M jWmm %. K & R.)
, R
lK
871 G
C
A
.
.
.
.
,^
*oil
us
d
e"
*s
.
r4
3.
F":
CUM
79115
i
YE
P
.
ollit Vol, Vtwqk%-
-l
Am,
om
al 4
The sp. 11W-
tired. luto it auk (wkb - kv thet-
d W of lict and
d
000 am
tuistat wm itAn
ituur.wbkh bad botacockdA0 Ov, Timsola-w"miltd,
-
e
tMa4effed to a "Od,wi* qkdmijvA electrodes In an k
000 tbenrAstst &W the ded. coad. wA*mre4 at 0*. JISMIlel
undaldealliffiL.maditloin with watcr
Frm do dmcm of the clec. cood-
SOW hy*,IyA, coust. of Bra w" found to be c*W to
go -a v v4 X 10-4@ Thit own. of Sr c&U- in mixts. of HOW
,Nth "ft. is go SMU the% it -a" be dad.
of=
mists
uil
f e
h
.
.
e -ps-o
q
T
at- ma be cakd. by a- of the con". a 1
chrm. equilibria. Nice Ida W. It. H.

MOOD %*Idea war am
D@USS A 1 00 AS
0 O'o 0 0 0 0 0 0 o * o 4 * 0:0 0, 0:0.1
e7ooo
@--* -Se 4i-g-*-C' 0 0 0 0 0 0 a 4-4 A
.00
so I
not
goo
coo
6041
600
41 aw a x a I a a 9 3 9 v
-0- 00040*00*00*0*000*
a a a a t 0 -00 0 10-6 0 0 0 0 0 0,0
Ire

's a 0 a a 0 0 0 a ts 0 0 00*10 -a

0 all I i
"u 11 0 5 is 11
14 6
o
0 a
o
, " - a V 1 0
0
'
U
1

A AL JL__L A -,X--P o A
9
n 34
11)
il
il
1)
A 20 Z At it is
36 cc
4'--L -1
J
1111
4
-
-
Pt

SO 17

A nitrift M26od for dvtWMh&6 "dye Wariatt. G.
3-4
2W-8
Kki
k fit
r
i
15
N
1
1
6
d
P

00 --
.
o.
1021
e
.
m
13
0
.
;
.
;
Rgferd. ZAw. 190 No- S. 60--APPlicAtioo Of 142N% +
to Cut-
ochlocite socurdin
Itratin
h
fo
t
HCO
l
N
00 n.
r
L
s so
g
g
yp
ti, produeed &MMIC roWL& at p1l 8.6. At PH 8.5 the
00 reatits wm high and at pH 9.5-10.0 titrackta was PrW- .00
*0 ticRily impossible. In be Kattintegn, method NaN%

In. umt be ubed without the addis. of NalICOs. The
so Joe
00 Hs1J0s ujed for reducing the alkY. Of the 310111. OLD be fe-
placed with phowhate buffer soln. (N&GHP04.21fiO 288

of it. + NaHrM 58.5 g. Per L of water). To the dil. hypo-
chlorite tioln. add 15 cc. of the buffer soln. to 40 cc. of the zoo
hyltochlorils w1n.and 111rate with NnN0, cont O.W
:*
h
i
zoo
cum.
rat
on
mot. of 3AS S. of NaN(h W 1. The t
pleted when no resction is obtained with At drup of the
soln.sudl-sttirchpaper. The amt. of buffer soln. tuust be
increased if the hypochlorite soln. is strongly alk. The
we a
owing to the use of external indi-
method is incoinvemicut
.
i
hi
h
h
c
e act
ve
t
cator. The phenol-perozide method (in w
Cl and alky. are detd. simultatteously) is the most rapid
and simple titration, method. W. R. Henn as a

as 0

see
r
SS AT 0 W ZA
Aft I 1 11 14 0

0 0 0 0 0 0 0 a 000 0 0 a
- 0:0000000000
.
T
.
ONN:100000 000000 00
00000000* I

_*_w w 0 a,
-0,@ffi@o 000*0000 *Ogg Sao

t. Ij a 6, a A a . . - . - --- _1 * *0 0 0
0 00 *a
lor IF IF IF , - :
of *so*
is 0- a TO. 4 41 a a 40 690
A If -C C of L J_A_A@
L
kt, A_ 0
nit, 's
161 AV @@EAWkf_ Mt "'t. -
bty4rOEW End
durtag arVwjc tran=10i, .. 1. 1, &m. D-kAtdy
00-4 i AAdd.tAUUA S. S. S. R. 30, prol-
'A a 'Jew Y;K- of migration Inechanisol for rcitelions inyolvinIt
"sol. rearrangements. The If atom or the radical in-
volvcd in the rearrangement, according to this theory. lee
forms an intermediate complex in the form of a 3-mem-
bered ring with The 2 adjacent C atoms which arc involved
7i
in the rearrangement. Iloth clectrophilic and nucleo-
philic agent.,
can initiate the reaction. A no. of rearrange-
'Hent j are cited aj support Ing t lie theory. Thecuntention
that the migrating group at no time becomes wpd. from Zoo
the mat. issupportrit by- lack of such by-products which
wuuld indicate the formation of free radicals- or ion3 and
00 a V lie preservation by the unigrating group of its opliad 400
000 configuration during rearrangement. The tracing of 00
these reactions by tracer atoms (D) is suggtnitcd asameans
OOJ of ;)rtx)f 4 the theory. G. At. Koollavoff 00
few cc of
fez roe
AA.! 1400
16
4
zoo
bloo
=00
a 0
:t boo
S L A METALLURGICAL LIT90ATUNE CLASSOPKATION
slow 41,141L.-
131111 Car G-V Lot of
%video W&f a%. Got 3 1 V
$&noet;
n, 0 1 a I Ir M 0 A
US AT 10 It It tr It or it K 1 0 0 0 0 966060 6
0 0 0 0 0 00 00 0 0 0 0 0 0 49 0 0 o 0 04 00
0 0 0 0 0 0 4 00 00 0

0 0 0 0 0*0* 00 00 0:4
),- '. It )V ID 11 22 33 ld A 16 9 11 4D it #2 0 A- 6,210
I C 0 L-f-fi h r , Q. A - t. I lk. S-
0
Rudko
with altriftio. U. A. Shilov.
00 J. A U-SI.R.) 17, 354@-MlMr=A@ -so
come. @Mf, ! @
if 0". w n bypoclilorits sold. of a given
comen. do IM change sppreclaWy in
41 nitrites. beamm the presence .1
INS MONS Considerable hydictlysh ovurs.
thitt itt trw WM OW10M variation Of HNO!s cancu. At'
06 a ia`@ plf'V@es the cown" " H-No- and HOCI de- -06
Cream to xt Siw-ikr extent and at PH 10 oxidation of th,,
00 nitrite is taftntkuy 3 .00
G. 11. xasolapoff
0 0 see
Oe
00 zoo
00 Cos
-XO 0
00
Mat goo
I'
A I A S I A 0jTALLUe(,KAk LiTtHATURE CLASOF 'CATICR
'S: !, ;i@ - I - ---=-:7@
t 112.11 @11 cli. JAI
bIL AV No Ls@r-- ; , 1. , *. , "-,@
K a a It 0
0 0 0 It 1
0 *1:
ZOO
SO 0
NO 0
IWO
w,, to-in;
Sim Ab
mir *J,Ajl 4AC 4-1 451
;: An I S 9 0 9 If -1 N IN 3 AS 0 7 R T
@. -, ;
000 so* a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
41 0 Ole 0 0 0 0 0 0 0 0 0 0 0 0 0 41 0 0 0 9

x x of #a ago
fit AND 2.0 aftlas 1
gem"" am 0600#91196 MORO

C Ub. I
*

me givM for a tar in 00
which the Consists of a . OW-
ated by a screw. 7U dkm. of the awtv d. by
th
l
t
k
i
e vo
. o
t l
t
quid to be drawn; a Ocm. u@mbrane
draws appros. 26 pd. of the HquM. Siz niferenus.
00 W. R. Henn

Ago
so
0:
00
V
00

NOW

ago

Mae
Ala.ILA NITALLURGICALMERAYMCLAUVICATM 1416

9103460 "At o4v aft Nou"619 NIZA31 0MV Aft
@
U SAY 00 M a v bt 0 0 0 '1 Is 01 5 As 0
9 49 as a I Is
000 0 o * 0 4 .0 0 O-wo o *4 * 4 so oo 04060-000060 00
1
0
'
Goo 0 0 * 9 40 O'gle'L" OL* 0 'o A a 00 00 0000 00 0100.0 0-0 0
6

MEMO
0,:,W IF
0 0
It a Al 66 43 11
I L r -'-t Q r-L L .4 1 q. t -AA. 00 W ti. 0
L

00
*
00 Catalytic 4pmition of mixtures of chlildne with
ethylen*

!
C and other combustible gases. H. A. Shilor (!%WwVA- -00
00
1 Chrits.-Techwil. ln%t.; Org. Client. lAh.). J. Gtn.
00 A @ - Cheo". (U.S.S.R.) IS. 135-41(194h)(husli,li suiatntary@;
99 t-f. C.A. 39. 47911-Adwixts.ofoxide,suf 11g, Ag, and 111I
i
f
i

00 Cl-ethylene tn
xts., u) that ex-
1(mer the iguit
on temp. o
Ish).mosts oLvur even at rtxmi tc:np. Mixis. of Cl with 11
"r C If. exill'Xic at m)ttt teiiip. over yciiuw I tic tt%itiv. itiv
09
09- tutalytic effort 6 ontnevtt-d with heat.% of kntnatit)n of thr
AIM 1-11111till". 01. hl. K.-lal-11

06

AS-SLA MCIALLURGICAL Lfflklt@@t CL-StIFKATICH
r
0 U '0 ty a It 01* Kit R91 K1111 It Or
0::00*!00*000000000004
OT40
9 0 6140 0 0 * 41 00 0 0 00000 -**
a
woo
Ct a.. Lft
U A V &A An I S FW 0 If a I Is In 5 a a 2 Q T
UG It I afto
00010 004-00 0 a 4D 0 6 0 6 0 0 0 0 * *I

oil
A
00
00 i
:0
00
0
06
A I a - S L AMETALLUMMAL LITIMATURE CLAHVICATM
S1104i .1. owv cat 14315i
-@b. IL U Al M-W ; .1 ' ' I
a
0
0
10, 100 00 10, 10000 000 0
6 o 0 0,64,40,04 0
JIMI'MRAIN004404
040C15696 AND PROFfOlIll, HdPtl
-J&rcethanol. 1. The p"udocatz-
lydicto=600(u. Nft In the preparation of 2 41doro-
othand E.A--%U9v, N- P-
K=yuv, and S. N. Solodusheakov (Imnov Cilisn.-TwIl.
t.). J. Gen. Chem. (U.S.S.R.) 15. 791-50940-
In
Careful rvl)ctitioll of tile tnctho& (IcKribed in the fitcra-
ture show that anyapporent catalytic effect of Cu baits on
the col"Witalims kf C,11, and Cl in 11,0 wa3 due to expli.
It. M. Leictatcr
see
=0*
coo
Coo
rob
woo
age
we
we
matill IW Mv 151
An L I a Od 0 of w -1 N of a 0
0 0 0 0 0 0 * 0 0 0
0 0 0 0 0 0 0 *@* 0 0 EA

It Ra J114 lop AN
I
L Is P.

Some data an isa pieparation of acetylaullsudlyl cW01146
1. A
Shiltiv Kkul A
Kobvnin
J. APPIW Chtm.
1
.
@
.
.
11SLO abovell that darind
60 lbe, hydrtj@&bi of ac fanityl chlotide (1) there Wv
f
d i
=ffi
l IICI
ll

*0 e acid aut'
o
owe
ll
hauled at hrWt accty
.
into% by AcOll and sullanitse acid; its a by-ptoduct there
is fowill"I about 2% (mcoy6uIfaniIyI)*uI(anifiv acitt.
llydrulymb, of Ac group is hattencil by Incresse, of 11 lon
courn., hcuce by rwiluctlAst of the Vol, J water used.
I. a hontogrtivems wittel-IsteU) m4n. the hydfolyda of
the .14-1,cl Clutip occurs Amadiul; to a W,,adet fraclikul.
*
"
being IG tuin, at Nl
with tile time of "Italf-11 olysi,
,
I vl
'
ff
f
d
00 j ect
oes not a
Ion
at 40
. I
40 ruiv. at .30% and I
the rate, bill Oil lost greatly accelerates It. Tile m4y, of
d
d

00 a el
, at
I In (CHIC04. betlarur. and their 1: 1 "kilt. wits
truips. twilaven 0* and the b.p. Ilse ptuduct truly be
itcrystd. equally well front either thy state or from 14 mulat

paste when (CHtCl), Is used f,,v solvent at 111il- with
15-21011 retention in the mother Hquor, which may be re-
used 2 3 times.

44?
MIJANage,
-4@
.00
-00
.00
.00
2.00
=00
i " Moo
00 0
z:o
I
tl
r
I A at TALLURGICAL LITERATUNE CLASSW#CATION tl* 0
8 , -- - - -- -*--- -@ --@ ;:- @ I- -
a's
2V 1 ;1 --,,1 A - -
ilk .4 1. lama I P list 0
U It AV 00 H An A I V W 0 As W I W IM D ja a a Q

x 36 a nil 33D 34536Y XWO43 Ca40420
A T 71 T-
004
PROCIlut Ale ONOP111111 ;O-IR
T:4
04
Continuous method for pr*mtion -of Cw0ioace'lons.
E. A. Shiloy and 0. V. Kupinskays. J. Applied Cktm. .00
(U-SAR-JIS, 121-6(1945).-An app. is deslzribcd for' -00
the lab. continuous chlorination of WICO in %which the
rearamix in a water-jacketrd temp. -con-trolled columnk .0 C
wit TICI removal being effected by wathing Aith so
concd. CaC4 soln. Wlcn chlorinatk)n h carTied only to
W-70% the product is 990' poire moxochhpr,@jtelone. .410
The product, after wa3hing.11ractionated, CoClj wiln.
is regenerated by marble. Yields mnge frivin 1.1 ju 1.2.5
kg. product per I kg. acetone. G. M. Kimelapoff
zoo
0
coo
'*e
AS&-SLA MITALLURGICAL LITERATME CLAStWKATION
110"I fill 311'. - 114W so"Ov
$#logo Mir (my car
silill ONE 4" ill
U aAV W3 ;P ll KI-11 its, lot Arziff I I s a (W 0 0 V I W IM 0 a a

W ' W V . 0 . - ..M

A
V.; I U."
/ -W 4p
rp
=
cytaAxJd*. V. A.
preparatim W tkiffures IMM
0 Slujav- 1. APOW CAm. (U.S.S.R.) IS ZA) 511RTT--
- C
'
l
;
A cyan-
rl
"
nglish summary).-Thiourra was prrPd.
(It
smide A4 folloWl: an Almost SAW. $01n. Of thiourea, VIMIJ.
,,me yellow Nil. .4ulfide. N11,011, and Ca h)n1rusulfide .00
A :
thi. vila. i, the mother liquor from previous runs) is
Wated with itirring with HrS and Ca cyanamide (about
I kg. of loc@, CaCN, per 2 1. soln.). When HjS 3aln. is
Oil oeripletc at 23'. wbkh takes about I hr.. tht, mist. is
hcatA to Po*, with careful temp. ctmtrol: the resulting
h
ot
naction requires 10-)5 min. for completion. Thr
a
0 u,Ix-risimi is filterrd. the PrWuct is wa.-hed with mother
. liquorand. finally. with disid. water. Coolingulthefiltrate
00 gives ZPO@ g. thiourea per Jig. Ca cyanamide. As a
c4ontrol analytival method that of Cuthill and Atkins
1
h
h
at t
e
) was used with the modification t
(C.A. 31, 3417

hlilkti-n of the A9'5 PPt- ww@ Onlittecf-
the d X! 34 ip
,
ecompn. of
thiourea Procreds quantitatively in 'Vif
Off sol
.
u.
Ko"g-dr
a**
I V.

see
woo

A ft. SLA WTA
LLUMMAL UTI[II&IL191 V-jsj@rpw
- slaw W"IMV
i goo
@ I
11931 a& GIFT 121
0 F
uu- Ski aW 0 IS 9 1 N 80 5 A 0 2 9
a at K 91 ft 9 K it a i
0 0 0 0 0 0 of 0 0 0 0 * 0 46 a 00 00 411-6 0 0 * 9 0 0 0 0 0 0 0 4 0, 41 0 00 00
l
0 0 0 0 66 9 40 0 a - a- -9 0 111 -9 0 .0 0 0 O'e

W-.4v 2k III or
58 Joel**
..j'; ? ? I I It I It 9 I'd a IS v III imp It a 93 is alto
A A _L_,Q_1[ I f R A L L -A--Jl f_. 9 9 . )_-1. -, IL. T_LXL___AL__A__L_ a- Iwo -1--t-A-1 - L-a' A 1- -4 -7
c"Of"I __ - .
00
C&IAlytic Inflammation of chlorine -ethylene mlittistes. 410
40, 0 5119VO(iii
(-Ipl. Femd. aead. .41. L*.R.S..';.
1:11 b'10. III gla- Illbor'. the ir'lliti-I IVIIII., of IIINt'. "1 -00
go a ;. V @ 0, . it Is 2.'. #171; C'I 1. 1, % it bill I lit- billil 00
L:4.0 'k1wilditig -111v%%hat m the 4 Ibr 1111%I.
Ix'Urifill rMalsti.. vffcvt@
It 1911111111-111 S-111 tvIIIII. %IIIII IIK()- 119P, 41M Ag1l)
..I It ..'J'imially 141 Vo" 'lath 111.0,
I, 11hos Ate imit-la lv,,
(Al. ev
C41AIYII" oye'.tivelav", for the 11irtal modv@ Illesiti"lo-ol
6 pt"IyAbly 'Ille I" the Cl, iWorructitig with the
IfIllif, Ill Pflillit-V C"11111106 IIS%Iul "P-_Illools- 410111K. highlY
ot-All.thh. or iiiiiiaiiiiK ftat-iiiii, oiaii,
0 Imr-lurti"ll J Cl:0 im" CII-C-11. mi%t'. .'k' 11'.1
ill reolticing Ivillp. NUIly III.I.Sk aml
'live 7*
netal vil.,!,Il, F..' C110. CII.O. NIgO, C.111). Sill 1:'
AN111(h, Will I"CIO-IrC C.03tyli-7311V illartive. J.W.Iletry
Z' zoo
Poo
A S M I L A METALLURGICAL LITERATURE CLASIIFICATICod
r
TWIG43 .41 all as[
Ajillic"ej Ast
_r -
u u A' to 'I K' 9 (W a N a I If m A3 a 'I s
It Z..
0
0 0

0 0 0 0 0 0 0 0 0 0
A-0 100 CM*tl% NO AND 41" MISS
"octs"S Aso 11,1110411111111 1"IEW lee
- -
'
'
i
timation of 2,2
-dichlorodlethyl otber in the slristhiss6
of 2-ehlorisedutool. lust.,
-h-
Z

Go Avanovo). COMPI. re
U XT
4
47, 72-4; .0
so D.Wady Akad. N4uk S.S.S.R. 47.' 400@2(1045j-
A-unting that (CH&CIC110-0 (1) formits by reaction bc-
twcc,, C111, Cis, 11,0, and CH,001,0H. 2 r t d
m-
'
m:
u
j 11:1110
x lw wt up: (A) dxIdt - k
Oix
q lee

00 1) 41 c
c
is, bkh . 6 dse conon. of 1; and (B) di C1. tOCHj-

l
'1 471110CHIONI i C611.) I Cis) -
11 - kjCj1I.I I Oil - As
'
t
00 li may
y C."tibining A atid B into a single expression. k
i

04 13 im evaluatcd fruits tile final concts. of I and the Initial and

k'1k
1
Or
i
Zoe
00 0 -
as
ve
.
final L%jncns. of CII.CiCII3011: expvi. g
c.)n,(.,jvrr wide iruiatious in the concti. of C11,00fisOlf.

.3
00 Ctli. livid Cis west passed sintultancomly at 20 rul./inin.

into tit-al tube I Fri. by IS Mut., Coutc. 3fx) na. of
a "Ir
ntil Sato
oll
f k
f C11
Cicil
am
.
nown concti. u
o
11,0 -Ims. o
'
s
wmq rVached., 6-12 ltrS. Was required. I was dctd. by
i *

we 0
n a Dina-
I differente by dista. front 50-100 mi. of sets.
Siark %pp., redistg. frorn 100 rul. H10 (to retuoye MCI- Z me
Clljol I), suldremoving r by coned. ILSO. from the inixt.
L'outg. I and (CII.C01. Orville J. Strecting

noel
AS4-SLA 114TALLURGOICAL WINATURIE CLASWXA710
11" Silva
Imi .4 L. aft. 441c
1131 &Jll 41111 ww 411
U S AV go r I ; 1 0 F -
W v At to W m ig in WIOA XG a ad a a 9 IN 9 AD 4 3 -.72"
0 0 0 * :: e 0 0 0 0 :@2 -
; 00 00 0 0 a 0 0 0 0' 0 If 0 0
iri. 1. :
OT411 0004000*0*000000:

Jit it 32 33 misidu sit a it a a a C, zo
P a,JL J 7 L, V . . . . .
I
V
-oo KPU%%t$ AND F*CPIR
Iij INCIE.
-
r
V
R
A -T-
Series of aromade k
enes: pheny
iobertylyisetene
and v-pheUYj,(j-nxphIhYI)kvfCn*. S. 1. burmistrut,
anti E. A,@hilovjlvznovsk Client. Tech. Inst.). J.tem.
s_
bi
1
6
M
h
i
l
R
).-
e 4-
env
y-
.S.
.) 16.295-1)(
94
Ckm. M
y1g
p
*
'
. in. 61-2
) reacted with llh,%Iglir to
o!ytate (b..'21fri-O
Wid pArxyl4-6ip"yWglyroUc "id, tn. 164-7'. which on
treatment with PCIA gave Ph(PhCJI,)CCICOCI (1).
*
(from fictr. ether). 1 (2 g.) was shaken with fig
sit. 70
10
0 in Ht.0 under C% in a stated tube to yivid phenyl-4-bi-
*
*
-06
. tr,-at-
, as yvllow plAt-;
phrmylylkelexe (11). in. 102-4

0 inent of 11 with PhNII, pvc n-phtmyl--("ipkenvI)4)-
' .00

0 atelandide, tit. 1740, while the ti@ of dr %v
Y NIII K-A
'
'
. I-w
W
tit. =
identification. III was also prepd. by the
'
0
AcOlf-lfiSO, of pkexyl-4-bi*pkenylvkcrt,,nitfile, tn. 1321-3'
'
'
ze 0
hCll-
by reaction 4 l
(front EtOll). which wa,; prvpd.
'
-e of ImCl,. HIC(I'l..
t
(01I)CIN with Ph. in the prcsen, a
0
0
000 t.) and I-CiXiMitfir (from 134 g. C.11,110 gave 78
ZOO
ff. phen 1-miplaky(clyrtWic aci4 (IV). tit. I ifrout
00 b kyale, in. 147-W* (from belimic)): trat-
V =0 41
wtth PC4 gave phmyl-l-mipkhyrch!ortAsravI
ment of l
cWride, tit. 151--5' (front betizene-ix-tr. eth,r). which int vo 0
prolongni shaking with fig in Etto under C(L gavL- ZOO
pktnYl4-xaphIhjdkrIexe (V), tit. yel!ow pri,im.
F go 0
The tatter gave with N11, the n,-phenW,,-(I-n,zph:hvh-
fl)rm-
which readil
oin henzene)
id
l
12W (f
am
r
"e
r, in.
.
y
*
V
E
OlD
d
5
f
dil z
-6
.
an
ront
.
t
a rejqs6hydrate, tit. 1&
(
Ph';Ift yielded tit.
H and Vren(filygavr the corre-
'-M* (from 80% AcOll).
t:6 a
sponding diarylacetic acids on treatment with watt,r.
C:O 0
_G_M_KT4
Oil A S 0 . S L A AFTALLUSIGICAL LITF4.TLH CLASSIFICATICH

U SI AT 10 LS
: of ts 14 St PC it It An I S a rw 0 x W I W 14 0 a a 3 1
i; HAD n 1 14 T Kill
0
T JOWA
*9
a : : : : 0 0
a & 0
0 0 0 0 0 0 0 * * 0 0
0 0 a 0 0 &00 0 * 0_0_0 q_"L04k_0_4@_* 0 0 0 0 -_ * 0 * 0 6 *
A

0 A
1010"
O#j
of at
se 't
so 2
0
:0
so
00 0
so-
of It
all an 1100A 11191111111004
Syntko& 0( 3-CWQMthAAG1. U. T to" ca-
effident of the rate of Gomber a to".60077,76hutiv
and N. P. Kanyaty Uvanovsfthem. Tech. 1ut'.T.-7.-
Gen. Chem. (U.S.S.R.) 16, cf. C.A. 40,
71521.-The formation of 2-chloroethand from IW,
CA, and Cis is detd. by diffusion at the gas-soln. inter-
face, and, since both the phys. factors dit1r. the reaction,
rate and the chem. process" are very fast (C.A. 23.
29W), a small temp. coeff. of reaction rate was to be ex-
pected and was confirmed by expt. A tylindrical venel
(W) cc., 4 cm. diam.. 49 em. long), with stiffer. filled with
HO, was kept in a thermostat at 3-W'; Cf. and qH. were
introduced at 25 cc./min. so that the Sams were always in
excess (at 60- absorption): test samples were withdrawn
h4nirly and tiltomted with alWi. after 4 firs., 2-chlaroetha.
not was dct(f. in the fiml "n. The v"tioas cf the rr-
uctiws ratr wcrc of randimi chanwiter &nil showal little
Irsup. tivimult-nev (after 4 his. at 3% irld 0.2,111
At Ni-, o.2111 11,@1.34 1. Av. vultivi of I-C.-full Yield% wrte.
30-a' M' 0.2*1, In 111i,
tetup. inkfvAl 111V 1@4clioll rate k h0elictident of temp,
KtWM4Apufl
so
I**
.00
111040
=00
000
P Mae
2 see
ago
woo
t1is Is
nois
100 0
0 it a U W 16
It 1. if P. A..
IIT Ago
ASS.ILA NITALLOGICAL LITINATINIC CLASMFKATW*
=_ W*41
I low II. a) IVO 13000 VOWOV
$flow WIP QMV aft NuAJI0149 1111101 CIA colt M
P I 1--r Aft I 1 8 W 0 0 0 1 V 111 91a 0 2 9 1
u u kv 00 Ls 0 Is It at At it a It It PIC a 19 it a KW I
10 1110 U640* e. 40
0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 41& 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1041 Is

00 101 0 0 0 0 0 00406660006 660141,
1) 10 It .0 Is Is $I V a 34 A Is V Is IN 4 4f a a 61 are
-A L-L A.-A P I -L-1 AA
V_ _K__Z L_Z_AA_
PAOCC&SO AV ONOVE11111 -Noll
00
00 it
0* 9
-00
GomWM's Mtheds of. 2-chloroethaniol. M. Re-
suits of the PrOMCO and @oTraidon of the CAMUS Ph"S. -
00 U. A. Shilov and N. P. Kanya-tv (Ivanov%k Che - .00
T4icb.'_Iftstj. J. Gen. Ckm IOD-16
so ms.S.R.) IT,
(1947)(in Russian) I cf. C.A. 41, 119ir.-Agawmsmixt. see
oo of Cill, and Q In contact with an aq. %oln. of the gams, =00
09 vigorously agitated, forms CIClfjC!HjOFf (1) and (CIIjCl)I
(11) in the same ratio as when the reaction takes place In a 0
homogeneous soln. The sunts. a( each formed depend on coo
the concu. a( chloride Ion in soln. The formation of 11 is a
roe
'a surface reaction and occurs only above the soln. on solid -
surfaces or liquid films. CjH4 and Cis combine very
slowly on an tee surface In the abwace of a Hquid hase
The ratio of I and 11 formed Is Independent of the CtOcl; F
ratio, The rate Of C111. Absorption increases with in- ZO 0
creasing Cf concn. in the soln. but is less than proportlorW
to it. Arild Miller 00
400
=*O
too
A IT ALL URGKAL Ll ENATUPI CLASSIFICAMN tgoo
.00
WOO
01"
'a., Get
$%Iasi
IL U AT go is t 8 A F A
0 n I S V 'M 0 0 9-7-W,
P, it 1P OP Or a It a U at
0 Mal
0:0000 00000 0 00000000*0000*0000000go so
i !@!!, !
0 0 * 0 :1;0 " : : :@.I
o 0 0 0 0 0 0 0 0 0 * 0 0 * 0 0 6 * 0 0 0 0 * 0 0 0 0 0 0 0 0 0 0

A A C.2 L-r--
so
0 S' 3 Is,
2.chloroethassol. IV. Thowy of forms-
ZcWoroethyl) ether. Method of
UX.11 bles 11 0
so .1 .
ir ; the reaction mixture. A. ShIlov. Zkmr. gro. 41,
00 j Kilims. (). Gers. Client.) l7.'TIW-15O2fI947) On Rtmliall)!
g .:
'00 t et. C.A. 42. 4JL17A.- 35. 3-jtl.-'Me formation of tb@
""'c"i" 7f C'C'I'
7, (CIC11,01,1,11 in llnr G-subm, J1Y
00 XI-1 fiv the Wherne: Ctil, + C11 +
of Ol.; @ C
IltK*lI,ClIXI -ki
\.Ct
OCII,Cli,Cl; tbe imegrated tiplation for the vetaction
k kik'
rate I. V - F. In - heir R Is the
kik, . X, - "
00 0 v'"Icn. of OCII.C14011, V. 6 it. InItiAl Cotten.. X I- the
so
C'mcn. W the 4ti-cl ititec, k is the cractiall rate k0il-It.
00 . :
00 v
. jWc previous, referEtWO, Ckd. withoutd-Utingtoecther
00 larmation.,And Vi,, the reaction rate const. foir the formal Ism
00
of the di-CI r1hirr 14mv E is stnell in comparimian with
klk'. the apprim. (mm Is. Vlk - 2XAW -41). A
sernival tutv I m. lotil; and 114 nutt. In distills. ill" pmv Cd
with & %joix-twIL At the lKAtimn. Ufar which the two tittlets
1; @919
w" attached
were settled in; lwluw the cAtr&nCv Of thOw
uding tube which termimted near the toll of the
rtor (this -Arved lit it eirvilhiling till* for the tillsit.).
The alip. wL% L.-pt lit the dark and the tractinilm were
ill 1,,, ,j), 'l,lie Itilte wais cl,italls-41 with Alls
Alis.ILA tYALLtJVrKAL U11114101 CLASSIMATIC11
44
000000 0 0
a 41 0 44 if tit

nd. slt.@sl arld C1 and Cilf. 61 at 20 tsal./sitin. over 5 -10 0
bru.. with atia"ion taking place. At t In. end 4
a full the Cl th1w vt&, %WpLivd Wiser the C'oll,, Ill tmjW tit
flulb Out arlY Cisimm Cl. -rise mists. wast snAde uls tit 'AX)
-so
ml. and analyzett IL4 ItAlov" for IICI, CICIl,CII,()II, isn't
(CICIIPCII,W. IICI wat littlitni imitift wthyl orange -to
.
OC14CII.Oll N
*0 0
*14101 1.1the millple Iis 4!VV 0 cmicts. .4 1).4 "U40/1. her..1
tit W us milt
anti itchilrit-.1 liv IINO
l
hi
I
-so
.
ltr w
t
s opso-
., a
tiOn with 0-1 A IAsNOP atkl Nll..1;CV lit the perene, 01 0 -

little AmOll ills statkilize the cn.iix,lnl) Xivr, .111ficie"gil
l 00
ac%
umle results. Steam dIstsi. wait used tusep. the di-Cl 0

`tlWT Ill ill,, litv"sem, of Ilk od, c'milms-.1 "t it, =06
Owl stint WIVII01'. I- wish
Ow v%A. 1. Ineatilml and ill, ml%t, virilb I..
-
'
t
th
tl
i as
-
.
e t
wv. 111
nA A .
Oll-liOtl 1.1.0111, 4 IMA Ild. I
ll'.
-
%if
, r1pl'. H.JVC 111, aV. VAIjje,,f k'lk OAX-11; AS).
' ro a

I
linil -If a for the om,tirmit wimai-m vr
t. sea
1
lel
-
l.
00*11 siv- li,l) m", CICII'Cil'oll 41, 00
Appilil. Clinally in frietion .ills it,, Ini.
14
* Me
00
.
1114
y nf 1.
,I I. ,"I, Cl, Tbt- r"J"li"ll "Jilmon, 1,
-
flil fog milvins; tal'A 1-rold'.111-
It lions, lw
s
si

,
it
l
iart of a CICHIC11,011 1, .114- 10111 Ow CA.".
500
thm D, anti I,: X - V, X *74 x S,
1)
01t* El
if
h
-
.
t
;
e flim) CICI i.Cl i.01 I Convis. I, I Illol".
I
so
(he Ill-Cl Cther emilrall 4,111 1,v 1`@ nf till. We 2
molms./l, rimWti. will xi.v 2", M
0
Lee
#ION,
J4
U Vl &V K3 I% V
M
Oll K It Is a 11 it a It 09 141111 It
10
.T.- 0000000000000060009004
0 0 :10 0 0 a 0 0 0 * 0 0 0 0 0 0-aiLs 0-016-AU
it
I
00000000000060
tw 0 -iii 'i- I Its At it m) 11
0 0 0 0 0 St 0 1% 0 0 0 0 Vl@

fa@ A As
15 1 10
if X ft V 41 a di at at*
0 @t I --i-1.
- @ t--& -A-L-TV
A 30D Ak0_410CO01411
0110CIESSO A.0 PtCPIXtlt$ --Dt-

d Wanes and
dilorwaft. S. 1.
R. A. Shi
Ovsk). J llow Tech. Ism., lvLu.j
17
1684-7
1947
i
.
R-sI-).-PhCH%COjH ( .
n
(
)(
419.) was heated on
& st
a
,
e
m
bath I hr. with 21 g
PC4
the cooled mi
t
t
t
d
i
h
.00
.
s
.
rea
.
e
w
t
40 -- CSo. -W the iialo. gradually added with ke-coding- -00

66 s. Alai suornifed In 140 cc. CS, owtg. 48 g. t.
it, a
1
10COH1. tat 5 win. the taw. was d. with

-00
y ke and the mi. layer dirAd. with stoma. =F'
lug was

0
heated with oWs sitin. and the Injoi. matter on ctrata. .00

0
:
SM
W
ak
in
128% ThI
i
d h
p
00b
f 600

00 -
.
S
es
e
,
ro.t
w
i
140-60 irith 4.4 1. SoOp in I cc. AciO tows 80
,
Ph o

%
=Go
4-4-Y-1-OW.Waraw", m. im
(from utco$ ;
000 thh gives a quinotfifine an beating with O-CJ14(NIts)9
1!: while oxidation with 11POs In aq. pyridlue gave atoll
and 4-metbasY-1-asplithoic acid
in
230'; the latt
too
00- .
,
er
add treated with SOCh. then PhNfle. gave the 11nilitle

oo :1 in. 220'. The diketime (1.2 x.) heated 1.5 hrs. td) Iwj
with I Jr. O-C ANIII)f In 8 Cc. PyTidine and several (it
'Af "Mell. fig. gave
X
1). 17d'
ff"=Klilftoll in. Th Ortku IftOII)' OicrdJv in 107'
e rvaction of Pbcllwz, with 2
No

@ MCOCIJIF similarly
* -
gave litax.)i I- P44yi- zoo
krt~ to - 74-6
(from RtoH)' pkrou, tn. 10 (from
EtOHI
1j; k
id
i
.
etone on ox
at
on with SeO, gave ph"
:-WWAOxY-Z-W
139'
PkAY1 dibd~
m ISO*

0 .
.
j
which gives a red Mar with Na In RtOH soin., the Mar
vanishing on shaking then reap oxidation gave
2-nutboxy-l-amphtho;c add, us. 174V* Pa.). t:O 0

ts**
alTaLLURINCAL LITESIOLINE CLASSURKATION M. lCosol"Off

-if 04V cat 411.1j""If

u u &V PO is 1 5 F ZA An I I I 1W 0 is 0 1 W ad it 0
at it it It ItK Cc It it at kLo (I ZA
ty rp it it V
anir,
'0
0
g 0 0 0 0 0 0 0 0 0 0 0 0 0
;
ONON90
*
0 9 0009066-60009041liq *-*oooooooo*oo*eo*

0
0 0 0
11 11 14 Is it if n j, r I"
Z
L f 6 1 1 L L a r 0 A I 1 0 i

set MerhanLun of Chloride Hydrolysis. (in Rwodan.) F.
00
A. Shilav and S. N. Solodushenkov. Zhurptal Fizi-
go chesk,4 Khimij (Journal of Physical Chmistry), v. 00
0*0 21, Oct. 1947.1).1159-1161.
4*0 .3 The hyp-thesir that chloride hydritlysim may take 00

, place even in an acid medium with participation @j
00- of hydroxyl ion was investigated. It is shown that @06
this hyNthemis is contrary ts) kinctic data. The
mneept of direct interaction of chlorine and water

60 X1
molecules is shown to be correct- ZOO
00
00
ze 0
@O 0
00,01
L A ofTALLURCK AL LITERATUSE CLAS11FICATICN
o tr* 0
:.E
--
-
A
-
-
-
-

it
V
4
F
CP 6( K is ItaK a ff It Cc ;;
d 0 -
se
L
W1. n
43 1
0 0 0 0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 *10 0 O;o 0 0 0 0 a * 0 0 0 0 0 0 0 0 0 0 0 0
4000000,;:::ooooooooooeooo*040000000000*00000000
1

F-i
USSR/Chemistry - Argentometry Jul/Aug 48
Chemistry - Analysis, Vol:umetric
Me Use of Organic Liquids in Argentometric
Titration," Ye. A. Shilov, Inat of Org Chem,
Acad Sci Ukrainian SSR) Ivanovo Chem Eng Inst,
3 3/4 pp
-Zhur Analit Khimii" No 4
Shows that various insoluble alcohols, isoamyl,
octyl, benzyl and cyclohexanol, can be used in-
stead of nitrobenzene in volumetric determi-
nations by Follgard's method. Many other ordi-
nary liquids, which do not contain complex-
forming groups, are almost or completely
go 18/49T6-
USSR/Chemistry - Argentometry (Corltd) Jul/Aug 48
Ineffective as additives to conglomerate silver
deposits. Submitted 3 Sep 47.
18/49T6

IT C@- IyA
um/chdiletiy @ftreu'.. Mcror LA
"The lmpr&e&@'Mcroburetl of P. M. leakov," Ye. A.
Shilov, 1 p
"Zhur Obahoh Rhie Vol MI! (=), No 2
Brief article stating that P. M. Isakov's ideas con-
cerning a micrametrie screw are not at all new. Sub-
mitted 20 Jun 1947.
6&158
PA 68308

0 0 0 0 0 0 0 a 0 0 0 0 0 0 4 0 0 0 0 0 0 4 0 0 0 6 0 a-

- -a -*-a-*-
`VTO a 0 0-0 0 4-0 0-0-0-1114
I @ 1, 1 ; ., 1.
,
: 1;
, ,
A , I i T to Y A_ Al @M V, tc _if . ., J@
0
-.7-00
so'.
so
*a
00 @.wtlcd tube hr4.;It followel bill treatment with 3-c @-Oe
so NAOll, jrtve CO(%'1111h), (in. and 0.5 9. "Alicyl-
The mechanism of cafboxylation and of analojous reac. allilille, in. 13.5" (fr,)tn .91,"o Acoff): %imilArly. 5.
a 0 tions, 1%. A.7 '.i4ilov and M. N. DogdAnov. 7hur. 'SkOCmIll Pvt 3-2 K- in.
04,h,hrj Nhim J. Gen. Climn.) 18, 152". licating 5 F. phoCoNlIpli (1) And -1.7 g MONA
of
'
-;3l yl-
cmiclu,imi, lit (,.-r,hzon W.A. 39, About the intra- 2 lim. to 100-2W pole CWNIII'Mi and 0A 9
' 'c
0* imil. courw oil thr--c reActmu- Arc invAid. .90bitaocrs anifide: 0.4 K. I Anil 3 it. I-C,,I[,ON.i after 2 lir,. at

00 which split oil Ph NCO oil heating call reAet with phenoli, 10, gave 0.11 9. 1.1-110C1,11'CON11111t And no 'dicyl-
,
i jX*0
elding t1a, %Anic aijilideot of 110 jC111S a% AM obtained in anilide; 8g. land-5.8K. I-NAOC1,11rafter 1.51'rs 'it 1"4)
J.. y
`
re
n
l
l
l f
G
ami
gementi o
v@rj
oel
iv
00
flPh- 2 F- 1-o-lPht"A' A
. The naly difference in gwe 2 g. f,2-llOC,,fl,C0N
h 00
t
S.
e rr.icimo,,,f PhNCOilm-lf I, it, tendenry topolyrnerize, ",metars. litititigp-CIC4[1.0.N;it;tiitil,hNCO !.:)fir
so
amhdr h-rination v.111 ft-cur only At tclul)l. at 21W gave 2-hyilrt)XV-;-)-Cill4lr4llX'IILLIIIli(ir, in. .1,17' 1
from
j

An
"Ilk-11 do 1411 VIII, WAIIIII ,I 111,NCi) I, litOll). p.CjC.jl,(),CNjllIlt.m. l:t%-9'(fr,)aiC0C1l
so
A,@iwor J - t--re.wtiou, I, mot @, vAid Argument, for it I, P-CIC.11.011, folloilr4i hir trinatillent with PhNild,
4 K
so
4oli-im-d by .& l,rgc .4tut. of Lorry by-lircolucts; further- wAs conveneof to the N,t denv. lit hill. M.%te mvi Ila,
00 moire, a un-r-, .a liormccli nal,lithl)XI'lm And .4- heattA 1.5 lim. at :.NW. itivinot 0.5 g. tripliettylpI.Inidine @4 a
willide ,I P,11 1, -A A gill mc acid w,,, ot-Tv"I. T11i,ocarlix:
and 0.3 K. 2-hyllroxy-:)-chlt)ri)twnzjniiiiie, to.
1
-0 0
-t rxill-illml by ioreliminiry loAs of PhNC0, which then heating 5.9 g. of the Above N;i deriv. ill 25 nil. 1
11NIC with
2
-
acts oil the orl.,plithoxide in preference to p-chlorophen- !i.:l g. l_%JA0Cl,11, 1.5 lurs. to) -NW c.ve 0A x. 1.2-110-
oxide. Ifeiting 4 1:. lIhNC0 trinter and 4 g. %Za0ph in a C,Jl.C0X1lPh, in. 1.52'. and no traces of 2-hydroxv-5- =00
clilorobenzanilideLj,ilcit),:fi,titti. Thecrosli-reactionthu,;
mrifirmi the intennol. InL!C1L1IIiiIn of the miction. 700
7

TJ. -0 0
t A S m L A lityli L- KAt LITERAT49F CLASSIFICATIGH
E Z-
go ire 0
U U AV -3 At r i- Ir I
ll it M K it K 1I K It it it

;Z AA A a W a
n I it. .3 A) a 3a ?so

#no
0 0 0 0 0 a's 0 0 19 0 9 0 0 0 0 0 0

:::: 0 * a 0 0 0 0 0
: 0 so 000 0
::
:
A
.60 Sao *ISO *so a*** OOO OOOiOOOOO SO* as a* a ooo I

0 0 0 -0 -0 Ow jU * 6 a 0 6
01 0 0 a a a 0 0 0 a vV

0 0
0
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I

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0v ImI) SM JIRO
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A 1. L A -"--1 -11- 11 L
Ole a
.4
00
'00 so
-so
00
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00 -so

so -,ml A. N@ KmAkiii. Zh.,.

0 Chem.) 18. A,t -li-u I,, IIW _001

: Awstr., sulfonatim A I,v fill,lit.g 11,;t), V.,_
!,so
0 -amitit rqtua alms. w m-atm P-tif,,r, I,,. nit, exo-i

00 lie trcruit theinv of Alevtwirt W_I. 41. OUISo im t1w Go
too
00 the,-,pail. 1,irtitei-ti ,41mv i-i. 1.

00 ti@ Itcurih the eximenev it altlim-i.ibic fr4c..mifiv. iihivh so

so in icuts I lie sulfo gnitil, it, Or Imin I-ition;
z
ie 0

and Sevondary AIIIIIII,% aI.. Kite, vi'l t1w wm ......I.... 1 -11 -140

00
finite. the-urul
fix mcd V1.1 I he'S.Ir ....... ... 1. 1,
Nil'S
d tI
l
i
11
so an
w r"ti
t
'la
0,
C'-p It".1- 1, it,, Nit, u it,
I-Ittre ....
.%mines with SOo. thic to the-ir -Itlikc pri-1wrti-. bituld
-lin-vt its the timia. aml wit 1,, 1 liv -,rifw. ji,wa lit-it-ii, Cie 0
miltxrwtol by Alvitautlev. allittitigki I di-Kiree it[ 41- it t,-
firv -mlilir III.Iv primil 111C fire mililli- 1,* 101,111 (%vt- jl,p%t-@
NI. K-4 11-11

16 111

4 1 L A KETALLURGK.

L LItER.TLRI CL&SUPKATPCh _
=00
og`
'14"
C.C 441W13-Ir z4K cit, &S.
-

r 'i
u n AT -0 it
IT
f
Pt it tt it at All
A 0
kLa it I :In
I
.2)
0 0 0 *is
e 0 0 0 0 0 a Ole at 0 0 0 to a 0 0 0 a a 0 0 0 & 0, 0
.
0
00 0 0 *
sisislo a see 0 *oa 0
a 0 0 S * 0 0 0 0

E.A. Shilov and A.I. Slipdnc-v, Kinetics and mecha.-ism of the reactions of active
chl.-@rinp with orgnnic compounds. VII. Oxidatior: of formic acid Ir Pcid sohtiore-
Pp. 1-@12-21-
T@e rate of oxi@ption of formic Pcid by chlorine in acid wAter solution is
determined by the eauation
d [C 1 2j = K [CI?-] EqC02 ] + X 1 (Cl?)- EHIC02 JR
(it
200, K = 295, Rl = 0 .028; at 00, K= 28 -5, K' - 0 -0056. The oxidation of formic acid in
an acid environment 1)roceeds throuEh elementary chlorine and hereby differs- from the
oxidation of oxplic Pcid, where the active aeent, even in thr, i.resence of chlorine, is
hy-ciochlorous acid.
Acad. of Sciences Ukranian S.S.R.
Inst. of Organic Chemistry, Kiev
Chemico-technological Inst., Ivanovo
March 3, 1948
SO: Journal of Phyzical Chemistry (USSE) 22, No. 11, 1948

SHILOV, E. A.
E. A. Shilov and A. N. Kurakin, On the theory of sulfonation of aromatic
amines. -o. 2092.
It is shown that the hypothesis by Alexander dealing with the mechanism
of sulfonation of aromatic amines is based on inaccurate data in the literature.
Some considerations concerning the actual course of the reaction of sulfonation
are discussed.
Lab. of Organic Chemistry of the
Ivanov Chemica-Techilological Inst.
Augast 7. 1947
SO: J. Gen. Chem. (USSR) _@8, (80) go. 12, 1948

OOA
so
00
*0 1
60
0
4
,3
FROCIrsm AmPawleyWO NOW#
The kb*k atiodkem *1 tU Caniassari riectim. kc.
IA-SkIkW-WW G. 1. Kudk""Sel. Da"y Abad.
Seek S.S.S.R. 43, 681-41(190).-DisroutsUon of Am-
OIICCsI(.S01sNa (1) is of th4 Uh order, Im. 2nd-ortirr
with respect tolland Sed-order with respect loalkidi, In
sq. volu., at WtW comms. 0.1-0.4 U. the 4th-order rate
const., rftbx*d to Ow Ionk comm. 0.3 Af, at 40. 50, and
do. Is k4 OA9, OJW, and IA3 A-, ado-); in 876
a1c.. at 50 ke - 0.41. Them is a disduct pas. salt effect.
Cannizz"o dismutalksm of 2-pyridinecarbosaWthyde (11)
follows the 2od older (ist-arder with respect to U and Ist-
order with respect to allmli); at 40'. its R.O. k, - 0.0310,
at So I, In 49% sk.. kt - O.Ot76; no valt effmt. The
causes of the differences in the order of the reaction rute are
unknown. IN. Thon
Al@.IL! SITALLURGICAL UTZSST%W1 CLASUPICATAN
0" 93Q. SWONAPM
MP!
14RONO -A INJOSO MAP any 449 (004
u AT 10 AS A ; IN 'aK a A
f@ee @!. .04
0 : : 0 0 0 OR 0 * 0 0 0 0 :
0 0 *1* 0 a 0 0 a 0 0 0.0 9 0.0 0 0 0 0
a 3 9 T
: 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0
0 0 0 0 * 0 * 0 * 0 0 0 0 0 0 0 0
=00
as 0
ago
woo
woo
460
go*
woo
vo
"60
too

,z- T-, V;
y c
A. A. Qnd E@Jlov, A.
of T 7t'- -1:'Ol
ralcotakii c;@ltnov Vscsoyaz. kl-im. O-va
im. i'end-i-I I ss-uc 2, p. 8-9.
SC : T-7-463G, 16 -Se@)t- 53 (Letop-l'. s I Zhurn2ll I nylchi Statucy,
23, i9b9l) -

a' 2-Chloroethanol. VI. The theory of
t
iFb. ads. H. A. Shilov. Zkxr. Priikd.
A%@
Cr 'IS
W Chem.) 22'. -1@1949); cf. C.A.
43. 37MV.-The Gombers synthesis of CIClftC1frOII (1)
(C.A. 13,2309)lsexplained in !bebgbto(S.*s work. The
concn. of I cannot exceed I mol./l. for 2rr.%.*)nx: (a) the
accumulAtitm of IlCI and I in the!miln. sbift9 the homagene-
ous reaction In the direction of (C14gCl)j (U) and (CICHr-
Cift)tO; and (b) the appearance of slightly sol. chlorides
c-4uics a reaction in the org. layer which increases the forma-
tion of side-reaction products. In order to force the
tomogeneous reaction In the direction of &it Increased yield
fl,itisnece&iarytoremoveW]Cl-frointhewtn. From
this point, the theary can be used to catc. the yields of the
reaction products for Industrial design 'rposes. In order
to inhibit .1. in the or,. layer. n h.!d be removed
from the reaction mixt. to increase the partial pressure of
,be Cf and decrease the temp. A new technique which i@
introduced by the theory is to allow the C.H. and Cl to be
mixed In gaseous forn: within the soln.. which is in accord
with good technology. This new point of view requires the
consideration of certain points of design for Industrial units.
It is also possible to consider satg. the coned. IIOCI solo.
with COL. which requires effective diversion of the CjH4
in the solo. and an increase In pressure. The Ist require@
ment is self-evident but the 2ad is met with the probkm
nfthedepositionol'solidClisydrates. Theproblemmaybe
solved, however. by suspending the Cl hydrate in 1110
which has been gatd. with compressed C%H.. Thus. after
a few min., a soln. of I having a conca. of I mol-11. (or 8%)
was obtained. The method could be easily ad2pted to in-
dustrial use. Paul W. Honei on
0 cx S W6 S S (@

*AJIM21 ""Y'r -jv1F@j
14 Is 14 IT a
12 U
1 1 4 1 1 r
IF r M 1 11 it v 1 7 1 44
,A- 111-
A
parx.11111% AND Ob"F91111 .01.

Catalytic effects In tht Camilitzaro isaction. G. 1.

r Kud vtscv and E. A. 8
Wloy- Daidady Ak4d. Nauk
G4,'73-6(l94W@(tYAccekmtion of the Can.
numaro dismutation of BtH (1) and w-OHCCj-1,BO@ML

go (11) by peroxides is Illustrated by the following rate consts.
k
at 50' Ord-order for 1
4tb-
f
d
1
ff)
iWiLi
.
or
ff
or
.
:
,
coricn. 0.55 'V In 407c SIC., the NsOll 0.27 Jf. without and
"
with DOW Ai B
0
k
8
A
-
z
.001
and 0.002 1. 1 In
,
t6lconcuA).28Af,1nU)%d1oxant. without
00 IWOM M, 0.0019 "A O.OM, rtsp.; 11 111 11,0,
initial coucrts. of It anod of N%011 0.088 M. ionic conai.
66 0.170M, with IIA0,0.0M.0.0001
and 0
it
0018
k

00 .
-
,
.
0.57. 0.60. 0.82, and 1.03. (2) Dismutatioa at I is also
accelerated b
t
lli
A
C

00 13 a
y me
c
S.
u, Ni, and Cu. In decreasing
d
f
ff
i
or
er o
e
ect
veness. Hydroxides of Cu, IN1. Co, Fe, and
00 Mn are inactive, and so Is nwtallic Ft. The activity of
Ag@3 is due to its r
d
i
A
e
uct
on to
S. The CArmizzam re2c-
00 tion of o-11OCJLCHO is accelerated by metallic AS, Mt,

X and Co, not by Fe. 71ke catalytic effect of meuls is at -
ib
d
tr
ute
to dehydrogenation.. 14. Thon
S
X
Z!
BF .
oETALMOCKAL LFTERAT&ME.CLAS11FICAT100
I -- - - -
M2s i3---
r SIVIV)11-
t F
bU 'a )v '0 It;; P, IV OP 6C K a X it
;o - 0 00
o:::::!OooooO4O
00*00000*0000*00
if v 13 jo is ij V is 30 a 41 a a Id a
1 - -,-
t-'- T",
'
-W.
I
-VIAITi7re @5-' li-I
An i i a I)- a m R I ar Of 9 J2 0 3 1
0 e 0 0 0 0
Me 0
:00
COO
go*
Zee
age
-00
ago
we
too

A
06MIUS AMD PtW"146 NMI
Spidial orientation of tks siddition reaction to a multiple mature of the sol"Ut dets. mainly the formation of the
bond. I. Swilirnov-Zarokov and R. A. Woe. Dok- primary complex. N. Thon lee
"I"Y Akdj. Nauk S.S.S.R. 67, 11?114(119419)@'@@The
V11.1-ct of the addn. of Illir to MeOICCICCOtMe (1)
I"sIAckIAcO11.CJl,uMcNO,,.
g. anti IN pure liquid phase, methyl bromitimaleate (11) and
lif"MolumAratr (11 1 are formed In approx. equal ands.
:0 In C.11., over 007. Ill the product Is U1. Conen.andtlimp,
have no effect on the orientation of tbc addn., mw has the
presence of llcroxiArs or antlosidants. LiDr or HgBro
hifit-Ittilir reiVO.Ininfavorollil. Therittecifthefesotion
i. .. te .3til ordrr, - JIIIIIrj/J1 - kl1lIIIBrj' with k wee,
go no*
I in mols.jl. inin.) - 11.21 (at W' in glacial AcO11), I.M
(at 31' in C.11.). an.1.10M (at W in Will). In the pfes,
nee
i clice of LiBr, the rate follows -djIlDrIldt - V11111111ri-
'00 [fir -1, with k' - 0.91 (at W*), Peroxides and anti- Co 0
'3 oxidants have no effect on the rate; AcgO slows it dowti;
Illo in large arnts. slows it down, in smallanits. accelerate$
it. The reaction is conceived as proceeding over an inter- 4110 0
00 A mediate addo. complex between I and HBr. with a pos. woo
X charge located at one of the triple-bond C atoms, a neg.
-chairge at the Br atom of the IIBr mol. bound to the other Zoo
C atom through its 11 atom. This complex reacts further
with Br- which is bound at the positively charged C
atom, i.e. in a trans position, or. less energetically, with a
2ad 118r mol.; this stage Is the rate-deU. step. On the
other hand, a IfOr mol. can also approach the primary woe
Intermediatecomplex; from its ne end.inwhiciscasethe %0*
it atom of the IlOr moll. will beUnd at the negatively
use
charged Fir resulting in an addit. in the cis position. The
Igoe
js.SL_@ ACTALLOSCAL UnINATIAIR CLASSWICAIM
Imse WMLnV wool
..r out VIA1311 = ONT M qP*
ad 0 0 9 IN a I to a 3 6 V A
IT a, ; a, ;
is 0" 0 0 0 0 0 0 0
0 000 iso raleves" "is 1004 _0001 - : : : 1.0
g : : 0 *@* 00 00000 0

11101
Damm of disda bkoddim nd A. A.
Yassukov (TeAss. IM. No. 11.
ame." In juch to". fibre 11-mago occurs in hypucl.f@., - blesiching,
ts in the pil range 6-& The rates of oxidation th mctic and L,
glucanK acids, starch. E' .011. and cellulose by H(X1 all &bow a
alsarp max. at pH S-& fly anakw) with the mechanism of
oxtdation of saturated alcohols by 1100. it is supposed that
hydroxy-acids. pollbydric alcohols, and cellulose an oxidised with
the it OWmation of unstable hypochlorite esters In 2
stages : (1) -C1111t
16
A paper of Abel coucerniuS parnitzous add. R. A. Shilov
Onst. Org. Chtin. Arad. So. Ukr. &S.R., Kkvr-ZT@mr-
Fis. Khixe. 25. 1137(1451).-The theoretical considerationq
of Abel (C.A. 44. JIMC). who asaibes to NjO, the role of
active intermediate in the oxidation of 11NO, by 114h lewl
I kinctle equAtion which is not catupttlible with thm
,:@4 J e%;wrimentally by S. und Stepanuva (C.A. 43,
4121d). who ascribe the Lune role to pernitruin mcid.
Michel-Boudart

The structure of tribromopheoul bromide and sme data
an the theory of itit formation. A. A. Vw%nikov
",hiloy,-Dokfady Ak4d. Atauk S.S.S.R. 78, 1051). -
7'tiilitt-mtqtrcisrcviewr,1(7rtieretacc-.). Anaq.qu,pvtt%ioo
of 2,4,"r.CJWI 1 (1) wits mixed with radio"etive Dr water
(active hr), tile plit. rterystd. frotnt CC14. taken Up in CAII..
anti the sAkIn. divided; I part was reduced vith aq- Nal.
Nal%Da, the other was Untreated. and samplei of 1xit h were
:Iried on filter paper anti their activity del@i. The liacti,to
A r"illaal activity vro found to depend CM the tnetfuml ,I
uli%ing tile reugrnt% in making the tribromopheriol bromide
(11). If tile @Ilipcn@ion .,f I is Addeti it) ar water, thell Upon
reduction of the Wil4ted prittluct umnewhat nvt-v %% I)( the
initial activity is retained, but if the uddri. ia dcoit in revrne.
the product oil reduction retain% only 2570 of the activity,
indicating exchange of all 3 fir atormi; " iticrex-,te of reagent
ratio can lower the activity 4till further. U in aq. suspen-
Sion does not exchange fir with fir water or '12TIr, but AOW
exchange occur, with concil. Mir in aq, or C4)14 inedia.
Tile rItchange of Dr between I ant] n 6 very slow in aq. sus-
prn4on, bul is accelerated by 2 transfer agent Me pyridinr.
t@arelltly the exchange occurring during the formation of
e" lailit'l by the "active" statc of Br during the reac.
tioll. lIfictict, adidit. of I to fir water afford% the only side
upprouvii to the tructurv of 11. The above resultb slum
that 11 has (lie structure of a quitione bromide. and not that
,if a hytxibruinite. I doet, riot react with Dr in CCI, or
AcOl I, but adtin. 111 .4 11 acceptor (pyridine or 1110) gives
an illonediale ppt- of 11; prolubly the It 6 detached froin
tile 110 of the. phenol and file prd= a@.Illllrs, the final
fir
Hr
fir

IC-1A-
- -,-- ---- -- - ---- - -- -- -- - ---- ----
Kinetics of the ad4Wm of hypochlorms aW to UWSC"
with a little-actlys double bond. E. A. ShIlov. G. V.
KoWnakara, and A. A. VILO"Ilray (ray-off. Chem.,
Arad. W. Mr. R.S.R.. Xlev), Poblady Aked. Ndetk
S.S.S.R. 81. 43S-14(1951).-Addri, of IfOCI to 16WCIII',-
ClICII.)NOO. (1) is slow ellough for a kinetic study,
The product of the adda. (Irrelevant for the kinetics) Is
!aken to be Mr4CHrOHOICICHONCIO.. Le. the addn.
it anti-hiarko"nikov. contrary to Schmidt (Anx. Mew.
337,-I4(jjX15)). in the absence of HCI the kinetics of the
reaction is represented by -delds - ki(IIIIJOCIII, where c
micu, of active Cl. with k. - 3.5 at 25* and 1.7 ut 15*
@Ullitj min.). The 2nd order in IIOCI Indicates
that the reaction proceeds over JCIzO) - K'1110CIII.
If the pit of the soln. is raised through adda. of alkati or
buffer%, the reaction becomes slower and comes practically
to a hAlt 4t PH - 8.1. Evidently, the CIO- ion does not
Mtrt with 1. anti Its catalytic effect an the formation Of
CIjO froin IIOCI Is unlragwrtant. as this step Is not 11mitin
Allyway. In rxids. at hIxbrr I;)[. The analytical activi-C.1
cm=. c is cqwentd b IJOCII throuilt e - I + (A/
9"DIRIOCII - CHM Lrolytic
@ whem K Is the *
disawn. cvnst. of N I- t % ves -delds - k.1110111 +
An em4t: AO femstins satit.
at 11-4 .9-8.1 with III - 0.1XV0.1, t -
.0-OBb-0.02. I-R, X - 3-A X ID-I. The eakne. beAr
out the assumption of CW as the active agent of the it-
action. In theipreseumof IICI (not less than 0.1 M), addu.
of HOCI is accelerated very considerably, which Indicates
Cl. m0h. as the active aMt: there is no "awn to doubt
that the product of the addit. rmudris the same. The rate
is slow enough for meastntment only at as low as 0*- at
that ttmp-, the rate const. defined lby -CArldl - 1,111
C - 40 z+ 3 (mok/I.. min.). 'ne values of kt and
I' comparison of the activities of C40 and C!,. with
. Lb. the et&H. [CWIIIIIOCIII - K' - OAMS at 0%
am '10 - 0.5 extrapolated to V. This gives -dcldj -
0.6fiIIHOCIII - (0.6/0.0(3356) (111C1,01 - ImflIfC1,01,
I.e. C40 Is 4.2 times as active as Cis with respect to Addn. to
a double bond. N. Thoo

Acirl :T=:;110::@d tho chloritto caj@a " Chiariattlon
.I.t. of a- WC costs Ind in aqwow awa.
Z
. H. A. Shilor 'JMG. V. cpi.'"Ya Onst. Ort.
Chem Ukr. S.S.R.. Kiev)
Xa DOkAsdy A k4d.
Ilk S.S.S.R. oil C21-4(1951): cf. Preceding abstr.-
The amelerating effect of carboxylic acids on the adda. of
IIOCI to a double bond. In a pit range high enough (above
3.5) for It direct addn- of Cis to foe inslittlifimt, III attributed
to intermediate forniation of highly active acyl hypochlorites.
according to IIOCI + HOOCR x= CIOOCR + 11,0. That
th"' "IttlYtic Rctiors I. due to the undissocd. cal,box,lic acid.
not to the cariloxvi.se olion. follow, from the fact
diI4IjIj,c%Ir1.% 'JI'lgeti" at A III I aroutod 7.5 wil thAt it
I- fill Idah, but the nlacu. of ' ce's tile arut. of
III the chlorination of free calboxylic &C-ld
""lium Perchlorate (A) in the presence trimethylallylam.
of , ndIMSOW.
carboxylle acid OfAn). the rate law is -deld, III kA,110.
C11' + VA JIIOCjjfIIAnj, where c . RIW. caacn. a, active
Clinn%OICA..and I-1-5at2h"(flaseinniln.). Atconst.
Pit and canst. A and 11300). the plot 01 -&1d, a, . ju.,
tion of JIIAaj should be a straight line. This is confirmed
by the following cxpti. data at 25", with A - 0. 1 M (Initial
"@ carboxylic acid fconcn. Mi. pit. IIIAnj, ko'): 0.0015,
3.64. 10-05 and 0.11. 0.41 and 0.48;
AcOH 10.1 and 0.2 and 0.11. 5=1-
010.ol. I@COH 0,- 10-025- 0-"5 anti 1.40; 0-01-
.0136. O.OM. and O.Of*341. 1.40. 1.4
1)64. 0.041). and
L,_OM. 0_1. and 0.7513.6,
CICHCOJI C g,!kl at PH 3M ac"Ienstes
0.111 3 4-I.wId4-5- Phthili
I pil 5.=. At the higher Pit. thi
Mot Z@gly than at -; at pit
c1lWyzing wat is he montsion O'@IIs(COJl)COj
l.M. it is apparently d_Cjf4COjI),. contra. IIIAnil. In
he rate equation illerr it .. -Idni- terns kr*AlllOCI
jItAntj with lit' ?a%' I - 21- The vailt" of W -11.1 k.l.
evidently Incled-N. wlih the c1t,,@tfulytic. dittocil. omit. of
the club"ItYlle Ischl. but there 6 no diwt Xseliallatity
in The presence of ItCl. In the last of U75 the 110-cl:
'&:-Id.cSl',Idtl..-wkHeAS(O".nlO.rS--
aind of a WOOS inwg- Will (11%08 0-
.() y). the rate const. 1, d,fined by
mains way close to 40, i.e. to the value previously found
with small sunts. of HCL 1-here are no Indication' CIf the
oresence of & C14 cation. N. Than

.. 4=@-MRM@ - -
- ---- - IM? - I @V'-
- - - w'.- -, - -
, --: i:,- @' , -- 2--, , `- %-
-- -, I - : - - 1 - - , . @ - - , - -@ '@- : -.- -@@ ,JL-1, @ - - ; -
. I -__ . - - 1 -__ -@ :-D *@ -v- "' - - .,_ - : .-:, - I. L:l
- - I .
s "hq / Z- OZI/ (@1.4 - ..1. 11 .I I -- .

Chemical Abst.
Vol- 48 NO- 9
Ma,Y 10p 1954
General and Physical Chemistry
XF4 -0 M-d-wat-M-TI-M of reafflo-n-s-o-r-aeffiR cbI rk-
vith 0
,N(no ruilematmnadl olkoffm Soluttrns.
Ivadnev, and -. Y; Q01skayn, J.-VeR G/few. U..Y,.
'S.R. 22,
2U2b. tMnSIQtIon).-%%-e,C.A@.4jK,,

V4 I I-OVj
CA 48, 4944b.-Oxidation of glycotaldehyde (I) and d-
gluco,-tt 111 hy act ive Cl in aq, soln @ was examined The
varla,ion of che rate with pH is such that the state of HOC!
(pil 4-') appti@s to correspond to the slowest reaction.
.Tne oxidation rate rises an addii. of HCI or alkali. In the
range pH 5--13.5 the rate of oxidation increases with pH
but in a complex manner. In pH range 5--9.5 the oxidation
of I.and II follows: t. " t) k1q[HQCl1PL@ , C is
for I and 4 X IM Mr Ir (Urne in min. 1. At off 1()- 1 Ix th
rA 61 oxhlatiori of I and U Is given best by -(dc/dt)
te 0
k.C, where ka for I goes from 7.5 X 10-6 at pH 10 to 2.5 X
'10-1 at pH 13.5; for 11 these are 2.11 X 10-4 and 4 X 10-4
v.-,p. In acid medium the active agency is C]; in neutmi
or weakly alkaline medium it i3 HOCI the latter case pro-
ceedhig through tio steps.
a-ld (11), a,3 well as piviintlaary stady of pyravic acid M)
was examd.. at 25* in aq. soln. The rate of oxidation
11. amd III by active N Is very low in HCI, brut r
increase of pH rapidl-r, reaching may. rate at pff 7. after
which itsteadflydectires. The rateoforidation in descend-
ingorderfs. With deficiencyof HM, I is oxidized
to chinwopyravic acid. while 11 gives 2-_qxoghtconic acid.
1-9 the raid-range of p3 values the rate of oxidation follows'
k.AC, Witere A is coam. of the org. acid, C is
;.(dcd@,
;- a s ific- consta -, txt ka for I
active CL I -u-t 16, c
--JUUet1C-d*ta-( I V gMPltfqtUYJ - l1nd(WO'that the ftdtivei'
of pH is HOO iwhlb@HO ion i3 to sq@,
extentatatalyst. Cl ind CCI- an rektively -- Mynctive.7
The mochartism of, 04: oxidation appean to in,lude forraz-
tion of -an ester of 11(n, which Is traudc)rmc,@ into a --
bonyi compound by lotis of HCL Similar considerations
are probably true for reactions of ales. =d carbohydi-iles-
Kqsojapol:

USISR@Chemistry Chlorination 11 Jun 52,
"Chlorine Cation as a Chlorinating Agent in Aqueous
Solution Ye. A. Shi.lov, Act Mem; Acad Sci Ukrainiax
SSR Inst of Org Chem, Acad Sci Ukrainian SSE
"Dok Ak Nauk SSSR" Vol LXMIV, No 5, pp 1001 - 1003
De la Mare, Hughes, and Vernon (Research, Vol III,
192, 242, 1950), concluded from their work that
chlorination with hypochlorous acid in aq soln takes
place with the formation of chlorine cations. This
is contradicted by the work of the present author,-
who established the. reaction with the chlorine . .
223T2_1
cation does not play a significant role in the over-,
a.U chlorination reaction f or hydrogen ion concns
below 1M.
223T21

Mechanism of rearrangements of aromatic atulno
"' a I ' a
u
li'd F
L
d
A
Shil
. . c
r
.
.
L
*
3
5
R
3
.
.
.
,
03-OrTUMM--fTle- tuLchanisin of ' direct sulfaitation of
ar(auntic coinpiN. by 112N and 110 sulfouic aelds Is dis-
enssed. III media With [I high level of acidity. a mode of
migration of the S031-1 may change to a hydroiytic one
whieb Is connected with isotopic exchange, III the present
work S" lalieling was employed-, a mixt. of 811-labeled
Na2SO4 with ordinary naplithionate. (@r other salts) was,
iallowed to react and the test result interpreted by the,
tratislocatio,t of S4. If the rearratigentent takes place by
hydrolysis, 'he resulting 113SOA or Its salt will yield radlo,
ucLive stalfainte. 11 the rearrangement of Ila.- t;ulfouatQ.ls,'
i Intratiml.. the product 14 inactive. Although flic systems j
wem licterogeneotis, the reaction took place readily. The
rcsults ate snuituarl7mcl below. No naplithionate wid Clol-fa.)
lit ;3.3 hrq. at 190* gave bl, % 1, @)salt, wl0i 3% S exchange-
witli I-CioTT714113 In 2 lirq. at 180-200*, (10-Do% i,2-ITXj I
ci@irtsOjNu imq obtained with 5-10% S uxeltange; with
I-Cwfl,Nfl, lit the firmeuce of Na-COa no 1,2-sixlt foruivd'@
nji(I no S exchange took place; I-CO-1701.1 lit 4 firs. :it LOU',.
0
formed Zfh% l,2-1TOCIQl-IgSO4Na with 4
/,, S CXclualge.
7
htlIiQIIiC acid and I-CIOU7NII-1 IR 3 at I SV 9%Afc@
@Xl )
I-CjolI,NIISO,Na'ad
'
'
C10118 in -1 lir,@. at 1650* fit the presence of I-C,41INN, aod,
MASO, guve (R;% 1,2- and 7% I.4-salt ivith intieft 8',ex@-
d

Image; if J-IsSO4 wereautitted, 1.3. firs. at 1811' gave 07%
C
.1 2--salt and 6% S exchange; - Clolfu and I-C)DI-17011 gave
Nasulfanl-@
IrIte n'ud I-Citil-JiNllt in 3 bri.. at- 193' gave 00% A 2-W
tatif 5% S exchange; aildn, of NaiC04 gave 0% und-
Ito S exchanife. Stilfaullic acid and I-ClaRTNI12 lit 3Ai
at. 16P.Savo'42% 1,2-salt with'38%. 8 exchange. ."21, 1171.:@
-14 SOIN6'.."
11211C1014.4004a the free acid, and 1,4-LIOCIOI
Y @sre
guvL a 51111flu distribution of products... It Is readit
that lit inany cjL-&-s (lie SO,ft group mi6rates *I ouC
hydroINs or S exchange, or tit. most witli a sintall extent
CXCI However, unplithloule meld unit 2,1 H
l4a.90,11 produce 45-00% S exchange. VAth 1.

IP
6

'7 CmntSoj@U. and J-C417NMOAL the -,"t Oi,
change JA -detd. by the,acidity of the li iniatt Add i
p iomodng 6 cxdmugc-,Tht(s cAll, bL',
deAc!rlbc4 as followg. , A [e-mail] tAtc HiNciettsSoxNa j
ji al the S-i @arrylaj C ixtoxiii' foMililgi'a qtiinonold stiructure, @
7.which jh@u sulfoitMeganother mul, Ofnit Awhic or ti-palilt-1
Lhol. While 1.;QoTl7Nll* It 6 %tot
esAelalcu"! In tlm@ab=icc of
d1sullonate and,a free', Cioll,N III,, UA0 @whlcli thc
above schime li op@mtllvel (L WKWalalwiT:

rhe _WUC-1-
LICI reaction also--yklds@ AcOLi.- - ada@. 1@@
A:cCH follows theequation" -: (dC/di)-- AsAC, *hcriA W
the concn. ol,the acetylenic 664 and C that of LICI,,kj -',
3.4 X 10-4. niolwl. min. @ at 30' and 26@ X 10-4 at 50*.,

The Committee on Stalin Prizes (of the Council of Ministers USSR) in the fields of
science and inventions announces that the following scientific works., popular scien-
tific books, and textbooks have been submitted for competition for Stalin Prizes for
the years 1952 and 1953. (Sovetskaya Kultura Moscow. No. 22-40, 20 Feb - 3 Apr 1954)
flaw
Title of Work
of the ffieor-y
joi
of -, -c:Ave Chlorine !w"J,11
Nominated by
of 3ci@ncas Tkr!Ani@ui
IiR
SO. W-3o6o4, 'i juiy 1954

SHIWV, Ye.A.; MOSPAN, V.S.
Dichlorofumaric acid and some of its derivatives. Ukr,khim.zhur.
20 no.1:35-38 '54. (MIRA 7:3)
1. Institut organicheskoy khimii Akademii nauk USSR.
(Pumaric acid)

--) "Ll / / C@ il, 'Ye - I-, -
SHILOV, A.Ye.; SHILOV, Ye.A.
Reaearc@ltlwt7@r@@i nucleophile additions. Part 1. Kinetics
of the addition of hydrogen chloride and analogaus compounds to
some acetylene derivativea. Ukr.khim.zhur. 20 no.1:39-52 154.
(MLRA 7:3)
1. Inatitut organicheskoy khimii Akademii nauk USSR.
(Hydrogen chloride) (Acetylene derivatives)

SHILOV, Ye.k.; SHILOV, A.Ye.
Studies in the theory of nucleophilic additions. Part 2. Kinetics
of the chlorination of the dimethyl ester of acetylenedicarbo-xylic
acid. Ultr.khim.zhur. 20 no-3:279-281 154. (MLRA 7:8)
1. Institut organichesk-oy khimii Akademii nauk USSR.
(Chlorination) (Acetylenedicarboxylic acid) (Esters)

1 . " n
,_::1 L(@ "- - .
SAVINOV, B.; SHILOV, Ye,
In the Council for the Ukrainian State and Kiev Departments of the
Mendeleev All-Union Chemical Society,. Ukr.khim.zhur. 20 no-3:340 154.
(Ukraine-Chemistr7) (Ghemistry--Ukraine) (MIRA 7:8)

Authors
Title
Shilov. E. A.. Yasnikov, A. A.
Regarding the structure'of isomeric pentachlorophenol chlorides
28/9,
1680-1681, Sep-1954
Periodical Zhur. fiz. khim.
bbstract
Comments, on the report by PO P. ShoMin.and M. I. Gostev stating that'low-
melting isomer of nentachlorophen-ol'chloride,has A structure similar to.t,
of hypochlorous acid esters, are presented* The use of marked 01,,.for the:.--.:..
purpose of determining the structure of isomeric pentachlorophenol chloridesil,__.
is recommended. Four USSR references (1950-1954).
Institution
Submitted

ONIKUL, Ya.Ye., inshener; STRASHUN, KiZ., inzhener; ROKANOVSKIY, V.P.,
kandidat tokhaicheakikh nauk, dotsent;. SHI P,'.S., I&
n;hener,
or
ratsenzeat; VATBTRAUIB, D.A., inzhener, re or
[Stamping non-metallic materials] Shtampovka nomatallichaskikh
materialov. Pod obshchei red,. V.P.Romanovskogo. Moskva. 4oB. nauchno-
takha. i2d-vo mashinostroit. lit-r7, 1955. 56 p. (.Bibliotechka
shtampovshchika, no.8) (MIRA 9:12)
(6heat-matal work)

S14140-v.
-47

el'Donor-ac-eptor mech@nlsm and its significance 5@
,
netics of heterol
C Cti ns E A. Shilim Vaprqsy.
re"
I lccaklsl@i
Khim. Kbrelik tall.
C IT' @.-k S S -
R, 01M. Mint. Nalgh
t many heterolytic reactions in solus. can be
@
t
readily @reated by the electron-donorwameptor'concep
Several reactions of halides are thus@ briefly discussed.- . I
references. G. M. Kosolluaf-

USM/ Chemistry Organic chemistry
Card VI
-Authors I
Title
Periodical i
Abstract t
Institution s
Submitted
Pub. 116 - lo/2.5
Shilov. E. A., and Vaynshteyn, F. M.
The migration of sulfo group in armatic sulfo-acids
Ukr. khim. zhur. 21/li 58-65, 1955
The regrouping of p- ande-toluenesulfonic acids was investigated in the'.
presence of radioactive su'.furic acid at 120 and 1269and at@different
reagent ratiaB* It was es-;ablished that the s35 converts with measurable.
speed from the radioactive sulfuric acid into reaction products. The for-
ming regrouping products ( o- and p-isomers ).show A high radibactivity:-:.
already at,the start, of the reaction. The data obtained indicate tW-
the regrouping of p- and o-toluenesulfonic acids take s place almost
exclusively according to the intermolecular hydrolytical mechanism.
Eleven references : 2 USSR, 5 German, L Swiss., 2 English and i,USA
(1870-1953). Graphs.
Aced. of Sc., Ukr-SSR, Institute of Organic Chemistry
July 23, 1954

d the
6.111, !@Ats ill the Ilwt JuIllism of c;IrlwXylatiral. J@. j
T---zr _R2
v, allot I,
In K bm'. Yht1r. 21. 110 !H9 Wh5rssl Ittls@ialo.
fr. ,It I-II(A.11-NaMat 170' kiiatn d
If, 2-C,JL,4 K-4 @N.. (H)
0-
f-m. N- if jilt.
aul, jilt "ilgh'i 1w Kns phaw. [e-mail], ill Uti-_

SHILOV, Ye.A.; bMIRNOV-ZAMKOV, I.V.; MA.TKOVSKIY, K.I.
Theory of the Kolbe-schmitt synthesis. Part 2. Role of disub-
stituted salts in carboxylation. Uk=.khim.zhur. 21 no.5:600-613
'55. (MLRA 9:3)
IInstitut organicheskoy khimii AN USSR.
(Ca=boxylation)

Periodical 1 Dok. AN SSSR 100/4. 727-729, Feb 1. 1955
Abstract I Experiments were conducted @rith dis6divin -salt of para-benzenedisulfonic
acid and geTma-pyridine sodiun sulfat6@to determine*the form of the-
intermediate domplex.forming during the. regrouping of aromatia:sul fo..
acids. The results obtained are described. Five references: 2 USSR,
1 USA and 2 German (1899-1945).
1W)titution I Academy of Sciences, Ulw-SSR' Institute of Organic Chemistry
Submitted August 2p 19.54

SHILOV, Ye.A.; STR ITSOVA, S.G.
.Stareochemistry and the nascent-hydrogen reduction mechanism of
multiple-bond compounds. Part 1. Reduction of tolan by metals in
alcohols and acetic acid. Ukr.khim.zhur.22 no-3:341-346 '56.
(MLRA 9:9)
l.Inatitut otganicheskoy khimii All USSR,
(Acetylene) (Reduction, Chemical)

SHILOV, Ye.
Chemistry as topic of the session of the Academy of Sciences of the
Ukrainian S.S.R. devoted to the problem of peaceful use of atomic
energy. Ukr.khim.zhur.22 no.3:409 '56. (MLRA 9:9)
(Radiochemistry)

StereochemliLry anI WPCh.iDI,!IL of rudU@dOn 'if C9=-
unds with mult@p.G bo4v, y
in 1i .-a
!ductioti -d-takriv by-90jitigAi
ku-1
q-w7e-.-4Ph
A. st,
i, retiuced in liquid Nil, io r- @i i MICH: 1i and then to
C 11: h. c 3 Pli C I I L, i r: i z I u a d c i L,: -j u d iti nm@
I V, !;I,
aisd rrars-Ph\Na'@: CH'I'll. Repetition of ThL pruv@ Wt.u.4
i'!rii (P1iN'aHC'Ij- The hydr-ocartywi productu were re-
-:r@,td.frumalc. EL-0 lus no effect aa the.eactinn. Addn.
of HtOH@ PhNfl:, and p-A1.-CJl,NHz nra-ke the reaction
much more rapid and no (PhCll! ), 15 isola". 11 naly julf
lilillgli N;i is used for total tedLetion, an etlifimolar mixt. of
:111,[ (1,110 is form"d.

Th6wy of nadMhfffc ad (m. M. Kinatla d th'i
h d b -dIv.
tvione& 7
dditlon oL 13 nrol, a to d1methyl ace
carborytat Wlle. of lithium broffildoq V. U.
@,-iv Zpy. E A @;ii F-T
590-50OW(in Russian); r-f. C-A. 50, 0-5d-la the addn.
of HBr to (:CCO,,Nf,), (1) uing an AcOH soln. of LiBr,
-d[HBrlldt - 4k[LiErl JA - conca. of 1. k, (moles/I.
min.) - 5-% X 10-lat 3ul, 1.49 x 10-lat 40*,auda.86 X
at 50% B? - 18.2 kcal-/mole. AS' - -18-9 cmI./
10
Jter much with addus.of
degree mok). The ratedoes not p
BgO, dioxane, or McCN. Ii K,' is the rate canst. in the
presenceof molarratla
ot 140 to Lift-in HOAc @oln, D tdc, Cmt-411
d==
-themixt.). PhCjCCOghlH, does not add HBr under WM.)
conditions. John Rowe $C&t

w

T7-