SCIENTIFIC ABSTRACT SHILO, L.YA. - SHILOV, A.YE.
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CIA-RDP86-00513R001549420017-8
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S
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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8111W, L.Ya.,.gornyy inzh.
Ventilation system with by-paBs ducts in the vertical plane.
Ugoll 37 no.11:52-54 N 162. WRA J-5:10)
1. Shakhtoupravleniye No.5-6 "Zhdanovskoye" tresta Oktyabrfugoll
Donetskogo souveta, narodnogo khozyaystva.
(Mine ventilition)
SHILO, M.P.; GRIGORIYEVA, A.I.. red.; GORIKOVA, Z.D., tekhn.red.
[For high yields in the Ukrainian Polesye; practices of leading
. farmers in 7A"hitomir Province] Za vysokie urozhai v Ukrainskom -
. Poleste; iz opyta perado-,7kh khoziaistv Zhitomirskoi oblasti.
Moskva, Gos. izd-vo selikhoz. lit-ry, 1957. 103 P. (MIRA U:5)
(7-hitomir Province--Agriculture)
15-57-10-14264
Translation from: Referativnyy zhurnal, Geologlya, 1957, Nr 10,
p 142 (USSR)
AUTHOR: Shilo., N. A
TITLE: Peculiarities in the Pormation of Placers in the Perma-
frost Zone (Osobennosti obrazovaniya rossypey v zone
razvitiya vechnoy merzloty)
PERIODICAL: Sov,geologiya, Nr 53, 1956, pp 102-117
ABSTRACT: The author believes that several of the assumptions of
Yu. A. Bilibin concerning the conditions for concen-
trating minerals in placers have become obsolete or
are not true. In particular, he casts doubt on the
view that placers are formed by redeposition. He notes
that the formation of alluvial deposits is closely
associated with the purent sources and is accomplished
in three stages: eluvial (residual weathering), delu-
vial (mass wastine and slope was h), and alluvial.
Because of the relatively weak chemical weathering in
Card 1/2 subarctic regions, such minerals as gold and cassiterite
Peculiarities in the Formation of Placers
15-57-10-14264
are only partially freed from the vein matrix. Consequently
these minerals, and a number of others, do not cheCracteristi-
cally accumulate in the ejuvial stage. The deluvial stage is
more favorable for the development of economic concentrations
of minerals; however, such deposits are relatively rare in
northern latitudes because in great part the minerals are not
yet freed at this stage from the vein matrix. Concentration of
ore materials in the alluvial stage commonly leads to the
development of large and rich placers derived from locally con-
centrated and lean parent sources. In southern latitudes
minerals are actively freed from the vein matrix in the eluvial
stage.
Card 2/2 Ye. I. Sobel,man
SKIWJ N. A. (VNII-1)Magadan ; and HELINMOV, G. A., (SOPS AN SM)
"Complex Extraction of Metals."
report presented at the FMh Full Assembly of the Central Adm1nInatration of the
Non-Ferrous Metallurgical Sci.- Tech. Society, Ybecow, 21-22 Feb 1958.
RUSUOV, Viktor Pavlovich; SHILOL N.Ajotv.red.; POTEMKIN, S.V..zam.otv.
red.; ALEKSANDROV, P.P.,red. -, APELITSIN, F.R.,red.; BMEZI11, V.P.,
red.; IrATA III, A.I.,red.; KUZNBTSOV, G.G.,red.; NkTSUYEY, L*P,, %;
red.; NUZHDIIT, I.I.,red.; FIRSOV, L.V.,red.-, FOMENKO, T.G.,red.;
VANSHEYDT, N.A.,red.
[Choice of an efficient mining method for thick coal seams of
the Nizhne-Arkagala deposit] Vybor ratsionallnoi sistemy razra-
botki moshchnykh ugol'nykh plastov Nizhne-Arkagalinakogo
mestorozbddnila. Magadan, 1958. 15 p. (Magadan. Veasoiuzny-i
nauchno-iseledovatel'skil institut zolota i redkikh metallov.
Trudy.Gornoe delo. no.18) (MIRA 12:5)
(Magadan Province--Coal mines and mining)
KOV Ser-ei Ivanovicb; SHILCI, Ni'll-olay Alekseyevich', otv.red.; POTHWIN,
GIVRI
M., 1.Pi, re&i-,-AftL'TSIN, F.R., red.:
BEIRIZIN, V.P., re@.; E;@IIBFT, A.I., reE.; IM113TSOV, G.G., red.;
,@ATSUYEV, L.P., re,7.; 1 -4 1--:@) I 'T'
ITU ;- I.I., rae.; FIRS07, L.V., ree.; -FOIES"ITKO,
T.G., red.; SHA-raRTAROVICH, L.A., -ed.
[Division of t@,e uoll)(,r Ind-i,-irka Vallcy into t-?ctonic regions] 0
tehonichesl@o,i raioniro-oli bassaina vedanego techeniia r. Indigirki.
t.ti-adan, 1959. 17 -?,. (Ma.@n,@an, Vsesoiuznyi na-uchno-issledov@-.tellsl@.ii
institut zol,)l.-:t i rin,"-Vch --itallov. Trudy. Geologiia, no-38).
(MIFU 12: 4)
Valle:-G-eology, Stmictural) iI
-,@HILO, NUMI&Y.-Alskseyevich--POTEMKIN, S.V. zam otv.red.; AliZSA@tDROV, P.P.,
APELITSIN, P.C. red - bpapsuk v.F*., red.- KALA.13IN, A.I., red.;
KUZ"3 S07, G.G., red.; MATLtYW, L.P. red.; NUMDDT, I.I., red.;
FIRSOV, L.V., red.; F011TIKO,T\1 G., redi; SHAKHILMVICH, L.A., red.
[Some -orinciplz),- for classifyibg placer deposits] Nekotorye printsipy
rossypn,7k!i proiavlenii. Mqgada@, 1958. 20 p. (Magadan, V999oiu%nyi
nauchno-issledovatollakii inet@tut zolota i rodkikh motallov. Trudy,
Geolo-iia, no. 36).
(Ore denosita-Classification) (MIRA 12:4)
SOBNOVSKIT, Nikolay Pavlovicb; aZURINA, Nadezhda Mikhaylovna;_SHIW.
__@.A., otv.red.; POTDMIN. S.Y., zam.otv.red.; ALXKSANMOV, P.P.,
red.; KUZBETSOV, G.G., red.; MATBUYEV. L.P., rod.; MIZKDIN. LI,
red.; FIRSOV, L.V., red.; FOMMO, T.G., red.; SHAUNLROVIGH, L.A.$
red.
[Treatment of hard to concentrate tin-tungsten ores) Obrabotka
trudnoobogatimoi olovianno-vollframovoi fudy.Magadan, 1958s 26 pe
(Magadan, VoeBoiuzzqi nauchnb-issledovatellskii instiiut zolot& i
redkikh metallov. Trudy.Obogashchenie i metallurgiia, no.28).
(KMA 13.,4)
(Tin ores) (Tangsten ores) (Ore dressing)
FOIUIF-'O, Timofey Gri-@-orlyevlch-, SHIM, N..A., otv.red.; POTMKIN, S.V., --am.
I.
otv.red.; ALEKSAIMROV, P.P., red.; 111MITSIlT, F.R., red.; BERa"ZI-27,
V.P., red.; K.A'JA3jIT -UZN.- -TSUY.&V, L.P.,
_, A.I.,red.; L ETS07, G-G-,red.; 14A
red.; TTUZHDIFj, I.I., re6,.- FIRSOV, L.V., red.; FOIK@RMO, T.G., red.;
VANSH'411YDT, N.A., red.
[Princi-oles of the ore 6ressinc 'Process with use of concentr@,ting
tables] 0snovy -protsess-- obogashcheniia rud na kontsentratsionnykIn
stola7ch. 1.1aradan, 195F. 35 P. (Magadan. Vsesoiuzn-!i nauchno-issledo-
vatel'skii institut zolota i redkikh metallov. Trudy. Obogashchanie
i -ntallurp.-iia, no.27). (MI-RA 12:4)
(Ore dressinF.-Ecui-omen' and sup-,Iias)
'U'
T
S M, Leonild P,-!I-avlr@!,; POTEIIII., S.V., zam.otv.
reld AI&K.S_C-TD-R,)V,.F.P., -rc-@ APBLI"IS! P.R. rod.- B-MEZIN V.P.
_iT U
re@.; M. I.!.,
FIRSOV, L.Y., red.; FON,'TO, T.G.1 r
e@ red.
FReimlaritias in the prot@iaz-3 of nisintagration and screening in
washinr,.- cl-@antirs an-' zaconomernosti @qzintr!-ratsii
i 9rokhoc:'lieL-,H:,, v boch"latich. MaCadan, 195@ - 36 p.
0-b-i-).dan. Vs-ai;oi,iza, na-_,,@' -@rit'zlie,)-ratollslii institut zolota i
redkikh T-4ud,,-. Ol);-)-,-?,f-,,-.-',l,,,,ae i no.?6).
(Orr., @rassing) (Scracna (Ilining)) (MIRI-I 12-4)
POTROV, Appolinariy.Stepanovich; :Vokj@@&A@.,otv. red.; ALNESANDROV. F.P.,red.;
APBL'TSIII, F.R.,red.; BEREZIN, V,P.,ked.; KAWIN, AeLgred,;
KNOTSOV, G.G's,red.,, X&TSUYEV. L.P.,riad.; HMHDI119 1.1olrede;
POTEMN, S.V.,red.-, FIRS-OV,'L.V..red.; FOMMO, T.G.,rod.;
VANSHEYDT. N.A.,red.
[Production and use of soil concrete blocks in the construction
of buildings of few stories] Proizvodstvo i primenenei gruntoblokov
v maloetazhnom stroitel'stve Magadan, 1958. 47 p. (Magadan. Yeeeoiuz-
nyi nauchno-isoledovatel'skii institut zolota i redkikh metillov.
Trudy. Restnye stralmaterlaly, no.7) OGRA 12:5)
(Soil cement) (Building blocim).
KA9-%SIIOV, 1-,@ ill R,.%,-Iovi(@h- .-:31! If -Ob S.V., zam.otv.
T V. P.
L.P., red.;
U7,`iDT*,', I.I., rp
r d.;
prognosis mps o.f plar--!- de-
-`tSI 0 geologo-geamorfolDgicheskikh prog-
1-0-18. 419 P. (Magadan, Vsesoiu%n,-'rI
C.
I -A Ins-LI-a' zolota i redkikh ne'allov. Trudy.
(0@:-e daoosits-4@ps)
M&MYLOV, Pavel Ivanovich: GALKIN, GeGrgiy Semenovich; SHILOO N.Ae.otv.red.;
POTEMKIII, S.V.ozamootvared.; ALHESABDROV, P.P. ed..--AMITSIN, F.R.,
red.; BMEZIN, V.P.,red.; KLIABIN, A.I.,red.; Y.UZNETSOVi G.G.,red.;
ULTSUYEV, L.F.,red.; NUZHDINi I.I.,red-.; FIRSOV, L.V.,red.:
FOMEMO, T.G.,red.; SHkMLkROVICH, L.A.,red.
[Peat lifting by means of excavating machinery in stripping
placer deposits in the Northeastern U.S.S.R.] Vskryaha torfov
zemleroi'pvmi mashinami na priiskakh Savero-Vostoka SSSR.
Magadan, 1958. 68 p. (Magadan. Vsesoiuznyi nauchno-isaledovatell-
skii inetitut zolota i redkikh metallov. Trudy. Gornoe delo no.19)
(MM 12:5)
(Soviet Far HaBt--Gold ores) (Peat) (Excavating machinery)
FIRSOV, Lev Vasillyevich- SHILO, N.A. otv.red.; POTEMKIN S.V. zam tv.red.;
AlaKSAIIIMROV, P.P'., Tea.; -APBMAITSIN, F.R., red.; BkRiEN, V.P:o, red.;
KALUIN, A.I., red.; KUZTILTSOV, G.G., red.; MATSUYEV, L.P., red.;
ITUZHDIN, I.I., red.; FONMIKO, T.G., red. (MIRA 12:4)
[Structure, morphology, and mineralization of the Igumenskoye gold
deposit] Struktura, morfologlia, mineralogiia i orudenenie Igumenov-
skogo zolotorudnoro muostorozhdeniia. Magadan, 1958. 71 P. (Magadan,
Vsosoi!i-nyi naichno- lsul3dovat-)Vskii Institnt zolota i redkikh
riptallov. Trud:?-, no.33)
(Ten-.@',.ce Valley-Gold ores)
Illicla;SFILD, 01;v. -@Lj.. - @J zE q
p0,7 1,E.[IN, S.V., -v otv.x-172I.;
-D'Rov, P.F.,,Zao_,Otv,red,; AL-@IEL-21DROV, P.P., red.; iiP@I-L"SIIT,
-0 -1
-,,ZITT _UZ-;@30*
rr)'.; V.P., red.; h T, G.G.,
-P -U
INIZ101IT, I.I.,red.; FIRSOV, L.7., red.;
VANSK,IYDT, 11T.L.,
[Unc-'argroull'I s i- n,,-rtheastern part of the U.S.S.R.] Pod-
ZO.-al-1ye 7ody Sev@-o-Vo,-'-- SSSR_ . ?-Lagadan, 1958. 85 P.
7!i@,@iuzn,-ii institut zolota i red.`,ikh -Ietal-
lov. T-rudzr. lbr7lotove'@o!:_;e, no.9). 12:4)
Ncrt'Iirn-Yater, Und.@r,n-Touud)
(F:.-_)-.--.in ;,round)
ANIKMV, N.P., glavnyy red.; BISU, S.F., red.; BOBTLEVSKIT, V.I., red.-
VASIKOVSKIY, A.P., red.; VMSHCHAGIN, V.N., red.; DRABKIN, I.Te.,
red.; TEVANGULOV. B.B., red.; =IMOVA, A.F., red.; ZIHKIN, A.V.,
red.; LARIN, N.I., red.; LIKHAREV, B.K., red.; MEHIM, V.V., red.;
MIKHAYLOV, A.F., red.; NIKOLAM, A.A., red.; POPOV, G.G., red.;
POPOV, Yu.N., red.; SAKS, V.N., red.; SE10YEIN, A.I.* red.;
SIMMV, A.S., red.; TITOV, V.A., red.: SHILO. lf.A.,.red.: ELIYANOV,
M.D., red.; TAKUSn-T, I.R., re(l.; V redaktirovanii.prinimali uchas-
tiye: AIM? YEVA, O.N., red.; BAYKOVSKAYA, T.N., red.; BOLKHOVITINA,
N.A., red.; BORSIX, M.O., red.; VASIL'n`V, I.V., red.; VASILEVSEAYA,
N.D., red.; VOU-VODOVA, Ye.M., red.; IEVSEYEV, K.P., red.; KIPARI-
SOVA, L.D., red.; KRASNYY, L.I., red.; KRISHTOFOVICH, L.V., red.;
KULIKOV, M.V., red.; LIBROVICH, L.S., red.; HARKOV, F.G., red.;
MODZALZVSKAYA, Ye.A., red.1 NIKIFOROVA, 0.1., red.; OBUT, A.M.,
red.; PCHELINTSEVA, G.T., red.; RZHONSNITSKATA, M.A., red.; SEDOVA.
M.A., red.; 'STEPANOV, D.L., red.; TIMOFEM, B.T., red.; ERTrDOLEY,
K.M., red.; CHEMIMOV, Tu.F., red.; CHMINTSHEVA, N.Te., red..
DERZELAVINA. N.G., red.izd-va-, GUROVA, O.A., tekhn.red.
(Continued on next card)
,%ANIKETEV. N.P.--(continued) Card 2.
.[Decisions of the Interdepartmental Conference on the Unified
Stratigraphic Columns of the Northeastern Part of the U.S.S.R.J
Resheniia MezhvedomB@vennogo soveshchaniia po rezrabotke unifitai-
rovannykh stratigraficheskikh skhem dlia Severo-Vostoka SSSR,
Moskva, Gos.nauohno-tekhn.izd--vo lit-ry po geol. i okhrane nedr,
1959. 65 p. (MIRA 13:2)
1. Mezhvedomstvannoye soveshnhaniye po razrabotke unifitsirovannykh
stratigraficheakikh ekhem d1ya. Severo-Vostoka SSSR, Magadan, 1957.
(Soviet Far East--Geology, Stratigraphic)
MARTASHOV, I.P.; AHILO, NA- -,
Regularities in the di stribut-Ion o 'L pIacera!)jmi!6-r,g'o' "*. 6 exogenet-ic
processes. Zakon.ram.polem,iskop. "60.
- (MIRA 14-11)
-,.-3everc-Vostochnj7 kompleksnyy nauchno--issledovatellskiy
institut Sibirskogo otdele I Ali SSSR.
po sillir
(Ore de ts
SHILO, IT.A.; ORLOVA, Z.V.
Middle Qgaternary glacial spore-pollen complex from the alluvium in
the Kolyma.River. Sov. geol. 3 no.8: 115-119 Ag 160. (IGRA 13:9)
1. Vsesoyuzny7 nauchno-issledovatel'sIdy institut zolota i redkikh
metallov.
(Kolyma River--Alluvium) (Phlynology)
ABDULLAYEV, Kh.M.; ALYAVDIN, V.F.; AMIRASLANOV., A.A.; ANIKEYEV,, N.P.;
ARAPOV, Yu.A.; BARSANOV, G.F.; BELYAYEVSKIY, N.A.; BOKIYj, G.P.;
BORODAYEVSKAYA, M.B.; GOVORGV, I.N.; GODLEVSKIY, M.N.; SHCHEGLOV, A.D.,
SHAMOV, F.N.; SHILO N.A.- YAWAOLYUK, V.A.; DRABKIN, I.Ye.;
YEROFEYEV, B. @iH @.A.D., IVANKIN, P.F.; ITSIKSOH, M.I.;
KARPOVA, Ye.D..; KASHIN, S.A.; KASHKAY, M.A.; KORZHINSKU,.D.S.;
KOSOV., B.M.; KOTLYAR, V.N.. KREYTER, V.M,; KUZNETSGV,, V.A.; LUGOV,
S.F.; IMAGWYAN, I.G.; lWdRacv) M.P.; 01INTSOV, M.M.,- FAVLOV, Ye.S.;.
SATPAYEV, K.I.; SMIRNOV, V.I.; SOBOLEV, V.S.; SOKOLOVp G.A.; STRAKHOV,
N.M.; TATARINOV, I.M.; KHRUSHCHOV, N.A.; TSAREGRADSKIY, V.A.;
CHUKHROV,F.V.
In memory of Oleg Dmitrievich Levitskii; obiturary. Sov.geol. 4
ho.5:156-158 My 161* (MIRA 14:6)
(Levitski.i,, Oleg Dmitrievich, 1909-1961)
N. A.
Di5sertation defended for the degree of Doctor of Geologo-v@ineralogical 5ciences
at the Joint Academic Council on Geologo-raneralogical, Geophyuical, and
Geographical Sciences; Siberian Branch )ql, -1
@11/
"Allu,,rial Deposits of the Yano-Kolymskiy Gold Field, Their Geological
Characteristics and Conditions of Fonnation.",
Ifestnik Akad. Nauk., No. 4, 1963, PP 119-145
KASHUTOVI I.N., glav. red.; BEREZIN, V.P., red.; 'M01IFOVIC311,
N.L., red.; FOTENIKIN@ -".V.,, red.; .@jL,,T:,,O A. doktor
geol.-miner. nauk, prof., red.; FROLOVA.,
[10 years of Magp&n Province] 10 let Magadanskoi oblasti.
I,iagadan, Magandansloe knizhnoe izd-vo, 1963. 210 p.
(MLLA. 17-8)
1. Direktor kompleksnogo nauchno-issledovatellskogo insti-
tuta Sibirskogo otdeleniya XT SSSR (for Shilo). 2. Direktor
nauchno-issledovatellskogo instituta zolota i rodkikh ire-
tallov (for FotemkLn). 3. Seki-etarl oblas"nogo korateta
KPSS (for Rashtanov).
SMIRNOVIV V.I., akademik, otv. red.; HOZHKOV, I.S., red.;
TROFITA1017 V.S., red.; SHILO, N.A. red.; KAMSHILINA,
i I - I , . I
Ye.M., red.
[Geology of placers] Geologiia rossypei. Moskva, Nauka,
1965. 399 P. (MIRA 18-6)
1. Akademiya nauk SSSR. Nauchnyy sovet po rudoobrazovaniyu.
SHILOI N. A.
"Concerning the history of development of the lowlands of the Sub-Arctic zone
at northeastern Asia on the Anthropogene."
report submitted for the 7th Intl Cong, Intl Assoc for Quaternary Research,
Boulder & Denver, Colorado, 30 Aug-5 Sep 65.
D
TOMIRDIARO, S.V.; GOLIDTMAN, V.G., nauchnyy red.; SHILO N.A., red.;
KARTASHOV, I. P. . r ed.; DI KOV, N.N., red.; DRABXIIJ, -I.Ye., red.;
ZILtBERMINTS, A.V., red.; NIKOLAYEVSKIY, A.A., red.; FIROSOV, L.V.,
red.; YANOVSKI-Y, V.V., red.
[Thermocalculations of foundations in the regions of permafrost.]
Teplovye raschety osnovanil v raionakh vachnoi merzloty. Magadan,
1963. 104 P. (Akademiia nauk SSSR. Sibirskoe otdelenie. Severo-
Vostochnyi kompleksnyi nauchno-issiedovatellskii institut. Trudy,
no.4) (MIRA 18:11)
-4'
SHILOP NsA*
I Of minerzil " C'eO'- ' 900fiz-
Second conference on tha gaolcg- il .-a I L
no.7.,132-.136 164. (NERA 18:8)
SHILOP N.F.
Neuropsychic changes in toxoplasmosis. Zdrav. Bel. 7 no.8.*40-44
Ag 161. (111IRA 15:2)
1. Kafedra psikhiatrii (zav. kafedroy - prof. M.A.Chalisov)
Minskogo meditsinskogo instituta.
(PSYCHOS'OS) (NEWOUS S rIMFL-DISEA&S)
(TOXOPLASM031S)
SHILO, N.N.
Statically controlled zero-reference phase-shifting device. Izv.
vys. ucheb. zav.; elektromekh. 4 no.2:123-135 61. (MIRA 14:9)
(Phase converters)
LITVISHKOi, I.I. (Khar"kov); GOLIDOVA, T.G. (Eharlkov); -SHIW, N.S..
(1harl2kov); BREGADZE, A.A. (Kharlkov)
Hygiene of the oral cavity in pregnant women as one of the pre-
ventive methods against postnatal diseasee. Probl.stcm. 6669-
373 162. (MM 16:3)
(TMR-CARE ARD HYGIM) (PMWANCY)
OTITORS
1PITLE
S/079
,/62/03.?/009/003/011
1048/1242
B10kh, G.A., Shilo, R,Ya"j Tsipenpik, E*.V.j and
Yeroshkina, Ye.K-.
The effect of bonsoic aoid,, phtalic anhydrlde,, a nd
maloic anhyCeide on the -isotopic oxohange of sulfur
atoms
PERIODICAL: Zhurnal obahchey khImii, v. 32, no. (), 1962, 2900-2003
TFXT. The rate of 'isotopic exchange of S atoms between S and 2-mer-
_j3aptobenzothiazole in the system 2-morcaptobenzothiazola - radio-
acUve 5 - diphonylguanidlne (I : 2 : 1) was 3tlidled either In the
precenco or in the abs(@nce of benzole acid, phtalic anhyJrlde, or
maloic anhydride, in an attempt to determine the relationship b6t-
ween the anti-scorching effect of the above acids and anhydrides in
.the vulcanization of rubber and the rate of exchange of S atoms bet-
ween the elemental 3 and some S-containing accelerators used In the
process. The experiments were carried out at 125 or 1450C; the
activity of the 2-mereaptobenzothiazole was measured after 30-180
1-1
Carid I/,-
S/079/62/032/000-/003/011
.1048/1242
The effect of bonsoic acid.@.
min from the start of the roaction by counting Lhe soft- radiation
in an end-window counter. At.125C the rato of oxchnnge In the
presence of the organic acids (or anh-ydrideq) was much slower than
in their absence; in some cases, 00g., in the 120-min experiments
vilth phtalic anhydride, the fraction of S-atorw exchangod in the
absence of the anhydride was twice as largo as that e.-tchanged In Its
presence. The-antiscorching effect of the above acids is attributed
to their interaction with the 2-mereaptobenzothiazole to form com-
pounds with a less easily exchangeable form of S In a reaction of
the ty-pe
-OH
+ HS -- C
p.2802
There aro 3 tables,
ASSOCIATION: Dnepropetrovskiy khimik6-tokhnologicheskiy Institut
Me Dnepropetrovak Institute of.Chemloal Technolor-'i
SUBMITTED: At)gust 7, 1ID61
card 2/2
-- SHILO , kand. fil:6sof nauk
7@- -
Popular -nual (?Marxist-Leninist philosophy* by I.Vorobliov., A.Kogag,
Reviewed by S.Shilo). Nauka i zhvttia 31 no.6:56-57 A 161.
(MIU 1-4:7)
(Comrmini sm) (Vorobliov, I.) (Kogan, A.)
Vu@Yu., -411W V.A.
On-inturated tertiary amino alcoholg. Part 2. Compouroj- Yrv,,Jr.--,
p@@tentially-local anesthetic properties. Zhur. org. knim, I
no.11:19419-1963. M 165. 1% IIT'R'. 13 - 1-2 ,
1. Uzhgorodskiy gosudarstvannyy universitet. Subm:-tted
;4ne 29, 1964'.
GORYTRIOVA, IT.A.; KOLOMIYETS, B.T.; SHILO, V.P.
........ -
Glassy semiconductors. Part 2: Virification of phosphorus, arsenic,
antimony, bismuth, and thallium chalcogenides in alloys. Zhur. tekh.
fiz. 28 no-5:981-985 My 158. (ITIRA 11:6)
l.Fiziko-teklinichesldy institut AN SSSIR, Leningrad.
(Chalcogenides) (Semiconductors)
V..o..'uz')0je rovc-'.-t-ly" J 0 I-A
a 1,ninerhd,
Stekloobrarnn.- -tojaniye; t-%, Y
1959 Tr--actlans oft.,
femnce Oa tte Vitreous, nield 1% 1@751)
led-vo All ESSR, 191,0. 5.@A P. Errata elly 111sertei. cor-'-G Frirted.
(Series: It,. Trudy)
Sponsoring AZ"cle@t lustitut kil@l- silikatc-1 m@l Sfsq.. Vf"O@-Ivyc
klJoicheskoye obst&icstyo t,-l 0.1. Mendll@.Yer. -1 Cc-'@d2@rntvc=yy ord-a
L-14% opt'shcaLly inatitut 1-1 5.1. Vsvil.v..
Editorill E,@rd: A.I. Avguntinik, V.P. B"zakovuldy, M.A. F'czbor@30v, 0J., Dotvinkl.,
V.V.V@rgln, A.G. VI..v, K.S. T ... troplyel, A.A. M.A. Pa.'.,eyev, V.S.
Kolcbszo@, R.L. My-aller, Ye.A. Pomy-lzaahit@, Cin&i-n. N.A. Toro;@v, V.A.
rlorinzkAyn, A.K. Ya)@hklnl; Ed. of Publlahi4S Roaze: 1.7. suyorm; Tech. Ed.:
V.T. Dechever.
FURPXE: This book is lntrr-@d for researchers In the &:!cn-,e =d technoloa of
CaeMU;E: The bOO-1 co.,Lal., V@e -fort. -d disc.salow of t!,. Third A)l-U.Joh
Coafertnee on tn e Vitreo@ State, held in LeninZrad ca roymb.r 16-19, 19,9.
Tn'y deal vith the tz'thot. -4 re-It. of t.dyi,;g the of 61.4-A, tl.@
relatlon between, @L-xtracture @d properties or 'Aturc or V1.
clieOicAl. bond au@d Fln:z otructqm, w&d the of glass. Faaed
silIC4, seth=l@ or vitrification, optical prolcrtfe, zc@d glwz structure, @d
the electrical propertles of rl-cs am Alno, discuszed. A ouober of the m-
ports deal vith the del@cndcoce of &loan qolortito = con;,ozition, the tinting or
til"Pts and radlation effects, rcd mcchanlckl, technical, and ch=ical prorvr-
ties or eWseet. Other 1@;nm treat glass se@cicaud--tors; "d ecd. boroaLlAc.te
gla.a,zca. The Conference v" attended by core th@ _-40 dcle,3a.tca froz Sovict @d
East. German "Ientific orgsxil-tiona. Anong the participants I. the dl-waim.
V're, N.V. Solcc,$., Ye. V. K"chin.kAy, Y..A. Gastev, 7.P. Pryaalsh.lkoy, Tu. Ya
Got1lbj D.P. Hchcd1ov-Petrocyan, G.P. Hlkh.YLO@, S.M. A-U. IAMMY, D.I:
JAYin, A.V. Shatilows N.T. Ploah.".04y, A.Ya. E"hct.O,, S.V. beiltyarova, G.V.
Byurgenovahaya, A.A. Kalenov, K.4. Skonyakov, P.Ya. Fokla, E.K. Koller, Y..A.
V.P. P.zdev, R.S. Shevelavich, Z.G. Pl@@tcr, wid O.S. Yolchanova.
The final session of the Conremnee ran adimsced by Professor I.I. Kitayeorodekly,
Honored Scientist and Engineer, Doctor of Technical Sciences. The follndne,
Institutes vere cited for t@%tlr tontrLbutlui to the da@clo;rrnt of glass science
and techn.loat G.t.1ftr.t-rxYy opticheskly Inatitut (-'%at' Institute),
Institut lehistil at,I"Lov All SZSR (Inatlwte of Silicato Ct-iotry, AS V-SR)s
FizicheOkiy institut AN SSS1 (Physics institute AS USCI), FIZIko-teluinislieskiy
in-titut, As =R (Phy"Otoch.loal. Institute As USSP.), ir@titat ritik, All nsn'
V.16.k (institute of phy@lrs, A--d-Y Of Sciences, Dcl---k.76 S"R, Minsk),
L4borktory of Phy0ical CheotAtry 0: Silicates of tne luctitut obanrilry I ntorgmi-
ch,ohol khl.ii &S ESSli, Minsk (I.stjtut. of General __A I.Orglic Ch_16L'Y'
Aca&%Y or Sciences ikeiamask@ya ssil Minsk), tratlt4t TyfioJoaOIekQlynrny1:ti
soy.din.nty AS or Hit@`h'Mnleculftr CcstV-.!. AS USSR), Gosudar.tven-
"yy st.kla (Stete itstituto for Class), Gw-4LrAt%-en,1yY Institat Otek- @
lovolol.na (State institute ror GI@4 Pibers), Go&uJArs-.%*eww institut elaktroteXh-
DlchOOOZO st,Lklu (Statr lantitute for El'ectrics.1 Glaas), SibirAkly fitiko-
t-clu-Jc"-kly' lh.tltut, TwAk (Slbrl@ 2-titute, TQcdk),?-Ingrd-
ally d06.dL=t-m-,,y unlvcr@itet (t4ningriul State Univers-ety), Poak"skly k1tim1ho-
t9k), 9101ogtth4akly InAtitut (Kcacw Institute of Che=ic&l Technolozy),Ltnindra-Ankly
t-kh'Jolozacbeakly 149titut in. uracreta (L@ntnerai Tcc%4oIo,;tcA1 Inatitut tmeni
lAnsOvet). Felor-kly poll teklintcheskly inatitut Fi"k. (Belor-almn Polyteellic
In.tltats, Minsk), Novocherkusakly politekhnicheckly I"titut (Novoctiarka5zk
lratJtut.), ml 5,",Itc@.kty poLitek@Ia-,-,e.kly Institut (Sverdlovsk
Polytechnic Institute). The, Cwfertuce vez sMincred by t.@e Institute of Silicate
Chra,iltry AS USSR (A@ti.g Director - A.S. Gotlib), th, Vac.cy.-y. khinitchnsk.ye
.b.hche.t@o I=. D.I. Xm4@el,y- (All-Untn Chc.1c.' Soei.ty i-I D.I. '
Nnwl-l-yev), ".4 the Orders L@nl- Ttieh,skiy 1-twAt 1-ni
sa. Vavil@vn (St@tt 'Ord@r or unin" Uptical Inctio-,- Imeni. B.I. Vavilov).
71in 15 re4oluti@na of tne Cmfe-re incluie reca-- -@Utlmi to orilanix. a
Center for tite pirposo of thordlrAtln@ the mcenrch oc glass, to lhiblish a tiew
;.r1oJ1c-I undIr Lhe title "Flzlk@ I klilmlya rtekla' (Phy.1c. -@A Che.LAtry or
Giu.ao). ani to join the lnt-MtJw4A1 Con,,ittce = Gl@t. The Conference th=kn
A.A. I.Vedev, and Chniraw Of th, Orfl-Itation or C--
sitter; Y@.A. Pttr.y-Y',whit,, Doctor or Physics and Y@t-xsatlcd, Kerl@cr of the
Org"ll-tion-1 Cw-itt-; -I F.L. Kyuller, Doctor @f Ch-lcal Scl-C,4, t'e,,bcr
of the Org-'t.tloual C-Itt- Tl@. ed1tQrI^1 bcOr*1 tk-kr G.M. llnrt,no@,
M,V. V'11'kenshteyn, L.T. D-kt-, D.P. Dobyc),Ln, S.Y. D4.-r-o, V-A. lofr., and
B.T. Y.OluMlyttr. Befereu-, nr.-s@y individ-1 rppo-tn.
vitr- state (CO:'L.) su'/5%5
ClacnIcal Flo"ertleli of Gll.iocn
Dubrwo, S.):. C-i=l Prvp@,tln of 41-5
@ik.l',My, D.P., Yc./,. ll@t@rora, ev;A V.V. @f Vl- lltt,r-
.ct.ic:i of E'l-tr.,,4z vith Soiut"!@' L., lic- f t:,e
I dicutor Hcthc-l 4Z13
D-bro-kly, V.A., c.,id T.S. Dbrv,cL,.y,. On the Co.@-ltj- of' the
s,-ra@a Fil., f Scft-,-Unc Sill-t. Glv-@ 423
-V.P. Effect of AllAll E-%rth KctUl Cxl4oe 0.1 the Cnt=aCftl
st."ility or Gl@u- 432
Abrw@,.%, A..V. 1,4,clit.g Vit-cv- D-,tat. WjO, Aq-o@s. 1-ctd
Solutiona mid the Sti,to of tho 041da 1;. the Strac"ro or r-l-It Gl@-Q 4,5
Mazelev, L.Ya. Vitrificmtion mid lli@i@irtlt,3 or 11crate cl.-Z@a 457
Card 151?2
vitmo- state (C..t.) sal/5035
D.zLorollo-,, N.A., F.T. mm-ov, mid V.!;. r-Innniy. on vie vaid - --- -
cl-Ce. 441
B@ kh-klkhl S.M., and Vdl. Senor- CyntheaJc and Study Or tilc
'ropertles of llnral= Silicate Glaaacc 4).4
Discuasion 446
S131V. VITRZOM BYST5,10 0? h SWXUL 1Q.111,=
Scizd.o.A.ctor GlAaa.v
KOI-iy.tA, B.T. Scrilcond-tor Gla@aca
ioffe, V.A., J.V. Patrlr-@, and S.V. llacrovakEyn. Electrical rrofertlea or
BCO* f3coinonti-jetor Oxide GULoca
Kol.mlyat", D.T., H.A. Goryano@a, and V.P. Shil.. Vlt-o@ St@t, in
Ch.1coil-id..
Kplmly.t6, P.T. And h.V. P.Ylo,. 0-pti.&I Prc@,,tl-a 0.1 Clial-od-nide 01-01A)
C@d 19/--
vit-O.,is State- (C@'t.) BOV/5035
Kolce,ly-t., B.T., T.11, Maiontova, And T.F. Electrical llroTrtle.
or Chalcosentdc GlAxacz 465
VAYPOIln, A.A.. and Ye.A. Poray-ran?iltc (licctor of lityvica wid
X-Nny Dlfrrnctioi% Study of vitmoma c?jftjca,@ei,j4cu Or AracnIc 470
licainnovakly, V.A., -d v.v. T,,r"@. lltmlt- And Tendency to Vitrlflc.ttO,,
-r Bulfid,,- or Gr-p V In the ]'crll%c Sy.t- OF V.I. Y-jLlCl"J.' )1111
Dlac"diaq 41A
Boda Dar-ill.n. CLAo.j.
Davchill, P.P. Control or Por-r. 01-is f1tructuiv nni Probj'- of the C"',
Boroollllat-- 016- ^tructqr. Con,.octi,d Witt, it 4 (Vi
Aki.ov, V.V. Optical Cc,i.t.nto dill Ders-ity OF SodA borooll1cute Gl"uca 4wl
Card :@0/12
AWTION 9yrItsky,, X. K. 8/0,72J60/000/03/021/023
200313006
TITO a 3.rd All-Valon Conference on the Mr.oco, Statte
PERIODICALs Staklo I k4rasolks, 1960, Ir 3o PP 43-46 0332)
ASMUTS no 3rd All-Vedon Comforeme on the Vitreous State was hold In
Leningrad .6 the and f 1959. It sea argasti-4 by the X-tit.t
kkLnI1 alliksitor AN 5;SR (Institute of the Ch.sislr7 of 5111.at*s
As USIM). Ussayeasays, khiiabo.koyo ob.bob-st" laosi D. 1.
Msadola,7". (All-VaiOn Choule.1 Boal.tj inand, D. 1. 1knaoloyo')
-1 GosaAarstions" oplIchookly lastitat Isswal S. 1. T-Llovs
(.late optical Institute Issul. S. 1. Tarilew). Nor. thin 100
"Parts an the struntie" of close, iny..ticsitlon Methods of the
vitro state, the saaaaals. of vitrification and
.M t.eW*al proportion of Classes ser. delivered. Th. C.nf..-7-,4
an Opened by Au*4.aIuLan A. A. : .. -_ .
At the 5th aw.tLeZ, 9 reports d.sit I'b
The I vestication "#all& of sodlum-boron-sM.", 91111*1* 1* 11*
ic . Yu-31. *3orom and Alumoboroo, loosely of till
Meet* Glas.*8.1 Ri3l ca-lual. -On the Coordi-tit., r,,,
bar of Alussizzon am Baron
an :truaturel. chances in boron-sl1lo.t. Cl%M3..j To. A.
-a- 3
and S. F. ZbCaaOT "parted a. o*.o ocat"vvrvlal pro
the0treaters of Vomn.sillosto classes ani their porous preluotill
I.. A. Poray-loshit. and 1. S. Ax.4 _q -, --_._bjcro9.opic Inh-i-
Card 3/8 Sinvitio. in the Th. 15 re2orts at
rli's of
the
th dealt .1
h be
ri, V
AX& "parted On the strc.tur. 4.ta,,sjmjj.3 of. ff,, 7,
-Nfth -eb- eld Or " I"hocuscion.090 electric fieldl.K. If. T,r0,j-',1A
and T. 1. 06.14,akiy. -Struator. .*a Prop.,tiss Cl
son Polyaer-tbacr7 of the Titrecus Stal14j
I. 19MIl "."Port-4 Wo, the agility -4 lb. d*Xr-6 Of diisz.l @tl on
1 .1 . f fte Ionic end atosar coo;'Osition of ths Clacal
1. 0401oveXty reported an the nature of dielectric laivio -4,
Claselik. -4 ary.Wlizz. T. P. Pot:@Lywa
venticstion of U. 21.1.9tri P arlzatj- sad 3
phate Claae.2-1 T,_A_2r2-o,, T. 1. C-aa =4 I. M.
reported an Investigation. of *fi-*-.-.-zT,@-.1j,ItY
hiSh-l-Mial field-, X- X,_MVA1tQ221",, on the dirf.si.n of
and X42 in son. jljad@t-* glnsgog, T' A. Ioffs ,
_qk*_M% "4 q,j. Th"Ptooka an electric of cryst.fl'IFT
and T. ?&-cxIa po%. an his
which war* G@Isd out under the suipe-m-FI-al-on of Profs3ror X. S.
T.vatroptyev at the xafedra sutla LTI J-,=i LeasiT.U (C..Ir for
Olson of thi LnUg-rad T*cbaolo.Ic.l ineni L.nvo-!,
he r parts "Th. D.p.ad.aoa of the of .1.2
4/0 :n 1kb: Chemical CoapowitionO. T. A. 0. T. Unsorin "I
N. X. Subko" Save Investigation r.3uls. an the
son nofl-vITY of &L..s.s of*he t"' 3102 - B203
:71 - BRO to the to.-
persture range of fr-- 400-13DO and an the influence of additions
Of Iran' =4 time oxide an the electric conductivity of this$
b* 7t h meeting, 6 reports dealt vith gln3-9 an eonl-
.ad t;
rat 9 with the coloring of glasses mad the influ'.O. of r.-
dial.104"a4 "Port. Ith ttbAi.ftl propertio. of T. A.
loffs and 0. 1. 1rh"stonko,Xlootrla Pro;mt.-U.8 a f Some
-du-o'vbr
reported on method-T-for -1ho produotion of c1mlec nLds-gTn-aaea;-
f their Central properties and On the lltdto of the vitrvous-
:12..,4t:`*,1.Q1ha dy-ts" T123' - A.2$93, Tj2So - Sb25*31 Bba.4.3- A.. 28#31
Tl - ka - Be. 3. T. I.lcmiy.t. and B. T. F.,Ly r.portcl on the op-
tical absorption In a number of binii'77ih-alc,@Vzldo 1yote". B. T.
1010MIYO19. T. K. K%mOZtOTK MMJ 0. F. Samarows r4porivd on the else-
tron L. A. V@jp.lin To. A,
rtS- .- F-Vi
Sr. Kits Udlographl. I.YestlCition . v Stiiitig Tf -
M- - L_ Y
O!i No"Ic Cblcognid..-. T, T. Tare,"r and T. A. R-ctt@ly
reported on the chain structure @f tT% -is rmanToG sulphid.
- Witroo
d -=onto. Z. P. Atarov
,:t:rmined by them with calorimetric menaur
Card 5/8 p ried on structure and propirti.s of rerroa. baron C14soom and
RABINOVICH, B.D.; Prinimali uchastiye: VDZENtKOVSKIY, V.I.; DERKACH, I.I.;
KOCHKINAY L.V.; POLOVKO,, Ye.T.;_,SHIW,_Y.P.
Investigating the performance of a vibratory screening machine.
Trudy TUFNIISP no.5:21-33 t59. (MIRA 16:1-1)
81774
6-1 Z/
S/181/60/002/02/16/033
B006/BO67
AUTHORS: Goryunovaq N. A., Kolomiyets, B. T., Shilo, V. P.
TITLE: Vitreous Semiconductors.1'9. Vitrification in Complex
Chalcogenides on the Basis of Arsenic Sulfide and Selenide
PERIODICAL: Fizika tyerdogo tel6,' 1960, Vol. 2, No. 2, pp. 280-283
TEXT: In investigating binary chalcogenides on the basis of sulfur and
selenium it was observed that the elements of the 5th group - phosphorus
and arsenic in this Case - which have no vitrifying properties when
alloyed with selenium and sulfur, easily form glass in a wide concentra-
tion range with essential deviations from the stoichiometric ratio.
Also alloys of phosphorus and arsenic chalcogenides with chalcogenides
of other elements of this group (antimony, bismuth) form glass 15
Chalcogenides of any other element proved to have no vitrifying proper-
ties under the experimental conditions of the authors, neither alone nor
in alloys. The only exception is germanium.The chalcogenides of the
elements of the 5th group are called vitrifying and those of the 1st - 4t]
group (with the exception of Ge) non-vitrifying. Vitreous substances were
Card 1/3 LIk"
817714
Vitreous Semiconductors. 9. Vitrification in S118116010021021!61033
Complex Chalcogenides on the Basis of Arsenic Boo6/Bo67
Sulfide and Selenide
also obtained by fusing chalcogenides of the elements of the 5th group
with chalcogenides of the elements of other groups. Furthermore, the
authors investigated the influence exercised in such melts by non-
vitrifying chalcogenides on the vitrifying capability of the melt of the
two (interacting) chalcogenides. Melts on the basis of arsenic sulfide
and selenide were produced with the sulfides and selenides of the
elements of the 1st - 4th group (extept for B, Al, C, and SO. The
syntheses were made in the concentration ranges of -5 mole% of the
ternary systems Me - X - As, where Me is an element of the first four
groups, X - sulfur or selenium. The vitrification of the systems As Se
Me is illustrated by phase diagrams for the elements of the groups I IV
in Figs. 1-4. The sulfides yielded similar results. Figs. 5 and 6 show
the experimental results in the form of diagrams which illustrate the
ratio between the vitrification ranges of all elements from Cu to Pb.
In conclusion, the results are briefly discussed and compared with those
of Zachariasen and Winter-Klein. There are 7 figures and 4 references:
3 Soviet and I American. X
Card 2/3
S/109/62/007/006/021/024
IL @-O D23-'/D308
U@
T., `tvinova, E. Miselyuk, Ye. G.,
Ya. A. and L;hilo, V. 2@
E'ffect of fusible glass coating on the characteristics
oi germanium diodes
Radlotc%@:nika i ulcktronika, v. 7, no. 6, 1962,
104 - 105 5
T" .'-I'T Thrr-, ctypuu o,' glaou coutings an germanium diffu3ion diodes,
werc teuted; Aa,,Se I ; A T Be; 2A T125. The 1uhole ex-
3* 1.5 132:'c3 12 s2S3 '
pojod L;Lirf---ce o2 the semiconductor, including the p-n transition,
waz coated. A graph of a typical variation of V-A characteristics
a-zor coating is given. The characteristics so obtained were prac_
1@0@lly Unchanged over nany days. Glass coating is found to ib-
prove essentially the inverse branches of the characteristics. The
effect of all three types of glass is nearly the same. improvement
of characteristics was also observed when the glass had been re-
Card 112
S/109/62/007/000'-/02-,/024
Ef--:,ect of fusible ... D234/D308
moved i=medlately after coating which disagrees with the result of
other Soviet authors. There is 1-fi6ure.
ASSOCIATION: Inztitut polaprovodnikov AN USSR; Piziko-tekhniches-
kiy institut im. A. P. Joffe AIN SSSR (institute of
Semiconductors, AS UkrSSR; Physico-Tec@nieal Insti-
,ute im. A. F. Joffe, AS USSR)
S @u7 BiD Pabruary 13, 1961
,;@rd 212
S/051/62/012/002/013/020
E202/E192
AUTHORS: Bashko, A., Prokopova, G.. Kolomiyets, B.T.,
Pavloy_,_B_-V. , and Shilo, V.P.
TITLE; Absorption spectra of glasses of the As2 S3-A32 Se3
system
PLIZIODICAL: Optika i spektroskopiya, v.12, no.2, 1962, 275-277
TLXT: The purpose of this work was to extend the study of
the absorption spectra of the above system to the region of 25 )&,
so as to determine the wavelengths of all the absorption bands.
The glasses were compounded according to the method given
previously (Ref.4: B.T. Nolomiyets, N.A. Goryunova, ZhTF, 25.
1955, 984; B.T. Kolomiyets, N.A. Goryunova, V.P. Shilo, Tr. III
Vsesoyuzn. soveshch. po stekloobrazn. sost. (Proceedings of the
3rd Conference on vitreous state) L., 1959). The following were
prepared: As 2S 3; 5AB 2S3' As 2Se3 2As 2S3*' As 2Se3*' As2S 3' As 2Se3*'
As S 2As So ; As S Disc-shaped samples
2 3* 2 3 2 3' 5AS 2Se3 ; Az2Se3'
20 mm in diameter and 0.15-3.0 mm thick were cut out, ground and
Card 1/2
Absorption spectra of glasses of S/051/62/012/002/O.L5/020
E202/E192
polished. Transmission spectra were meazured on spectrophoto-
maters, CO-4 (SF-4) (0-5-1.2 VL); OKC-111 (IKS-14) (0.8-18.0 iL)-,
and Zeiss UR-10 (2-25 4). In the region of 1-18 vL. the authors
found certain discrepancies between their data for the absolute
transmittivity and the position and depth of the strongest
absorption bands, and those given in previous papers (Refs. I and
2: Proc. of the 3rd Conference on vitreous state# L., 1959).
In the long wavelength region all the glasses had their absorption
bands beyond X = 25 11, and hence could not be determined
accurately. optical absorption curves for As 2S3; AS 2S3* As2Se 3;
and As Se were given. Some of the absorption bands -were
2 3
attributed to traces of As203, and others to the so far
unidentified contaminants.
There are 2 figures and 2 tables.
SUBMITTED: February 11, 1961
Card 2/2
-L 17897-63
!.'ACCMSION M'.'- AP3001PIM
stOichiOmetric composition of glasses@ of the Tl-@As_S. and Tl_As-Se@ s@rstems and
Antroducing Ge or I into some, of these -g2jisses'as- additives. The glass-foxmiation
t regions of these systems are showti in, Fig-o';-L of Enclosure. @. Samples were prepared.
@by heating the requisite amounts of the elements in:an:evacuate*d and sealed'
qi@art
test-tube to 700C (in case of
Ge containing compositions, to.900c).for 2.hr;
samples were then cooled to room temperature in the furnace. The softening@.tem_
peratures were determined with,:Lazurkin's-apparatus. The results indicate that
an increase in the Tl2S.or-Tl2Se-contezxt-of the glasses resulted in: a noticeable':@
T drop. Two glassy compounds were selected as: Oarting materials - for finther'
sLdy: T12S'AS2S3 and T12Se. 3
-AS2Se . One-half to 2 germaniimi or 3 iodine atom,
per molecule were introduced into As S _AS2Se5, and. T12Se-As
2 2Se3 Germaniun
was introduced to strengthen the it Aidids
system by cross-linking it - with covale
to form a three-dimensional neb@ork structure. Iodine was adA6d to weaken the
tem and shorten the chains of-the original,thain structure. rn.the e.:
Sys -presenc
S3 and@".
of the additives T ranged from 30to 450C for As Se3.and rose
2 fioli
2
109 to 214C for TljSe-As2Se I__ The germanitincontaining glasses vere very 'stake,
but those containing iodine'seem to ."bee unstable @aad evolve iodiiie
-if the iodine content is high* The istudy indicated.'thatV can be re
irange from room temperature to 450C Miquio can.-be obt0ed W - introductibu"-"'@.'-@
iodine Into arsenic sulf1do or se'leidde.- The remats seem to c-cafirm tba'_ic@
Card 2@
7
----------
f@7
@L 1039&-65 Eam
q=
-
AP4044636
ACCESSION HRs 1,1/0048164/0'2810i@s -1
1w
VT
TITLEt Oxychalcogenide glasses
SOURCEs AN 985R. Izv. Seriya f is Lchoskaya:g v, S. no.-@ 4- -1964, .3
1285-1287
TOPIC TAGS: chalcogenide glass oxythat Cogan- ide -glass f.nize'd
oxide chalcogenLde glass, substLtutLon...solid solution, oiy.chalcd-
genLde glass properties,, semiconducting &I-ass
ABSTRAM A study of the fe.asibilLty-of p-reparing -mi.xe*4 and,-
chalcogenLde ("oxychalcogenLde") glass-es, h- -a S. been unde rt Ae: ain com-_
7_41-t -n
-of the Third. -Out
pliance with a recommendation 0 @Con drence -7-
the G -by.preparin
lassY Stdtes@ The experiments were first conducted 9
substitutional solutions of components similar in structure, such'a
A: S 3 or A: Se 3 :nd Sb 203, Lt wai shown that large glassy-state
-
i
b
A
d
b
l
r
ions exi
in
th
s S3-Sb an
S
0 binary sys1eas
AYe;
203 2 3
and the As S
-As Se _9b 8 ternary system* ther experiments Coll-
L-.
-3
2 2 3 2 3
L 10306-65
ACCESSION NRg- 40464GAO Eq
CLOSVItzi
t b 16 -A i
a
pa rame a -r
Some.
.a
0
f
bxy*cha -d
lasses.
l@cb
gen . a g_
ConductLvity 84f tenLng DensLt@ ' HicrOi;-,.
l I
l
Point (dj.
-
- r n6fis
ii
Mr Sys tem,.- ,6a
ohm7 (T G -
C M
c
it As @)S .4 - AG2Se3 Sb203 10 -101 2,
:194
@.---21-5
3v061..--:
.747
4
@::145
.2
A92S3 - As2P-3 10-13, 10-12
- -19 4' , 2 0 8
3,045: - .
3-.9
48
9 45
3
AS2S3 As2pe3 H90
Ie113 lo 10
-
197
. . 208-.: 4
, iq.192 .
4 0605. .45
- 9
4 COSe2 As2SG3 U90 -11
to 2
:2L2.
-''-:260-:.
:
4: 498 -
-4-,675
4.,,-
5 Sb203 Pb
0 SB293
- ,
Region'Noil
' I V@- 3 10 .2 1 4--:1
1-51,- 4 19j 129*42v,189
Re
tdn-iNc.2 10-13 10 12,
278,
- 3187
5.'&090F
L 12888-66 EjjP(e)/EW(M)/EWP(b) Mi
ACC NR: AT6000487 SOURCE CODE- UIR/0000/65/000/"000/0171/0174
q
AUTHOR: Kolomiyets, B. T? -1 Shilof V. P.
q /V
ORG: None 4k1
TITLE: On the possibility of obtaining oxychalcozenide ses
_glas
SOURCE: Vsesoyuznoye soveshellantye po stekloobraznomu sostoyantyu. 4th, Leningrad,
1964. Steklo-obraznoye sostoyanlye (Vitreous stafel; t;rudy-_s_o-v-es`fi`cfian1ya. Leningrad, 124-vo.
Nauka, 1965, 171-174
TOPIC TAGS: glass, glass property, arsenic compound, sulfur compound, selenium com-
pound, germanium compound, mercury compound, copper compound, lead compound
ABSTRACT:- In an attempt to obtain mixed oxychalcogenide glasses, the regions of glass.
formation were investigated in the following systems- As 283-As2 Se3-Sb 203) As 2 8 _AVe 3-
PbO) As 2S3-As 2Se -HgO,' GeSej-As2Se 3'-HgO.- Sb2 S3 -Sb 203 -PbO, and A .b2S3-As 2Se 3_CuO.
The corresponding triangular phase diagrams are given. The data indicate that oxychalcogenide.
glasses are indeed formed in these s steme, and that they constitute a large new group of
glasses whose properties should be studied. In a preliminary study, certain parameters of
these glasses (o-, Tg,,6 1-1) were determined and found to be similar to those known for
chalcogenide glasses. Particular attention is drawn to the As 2S3-As 2Se 3-CuO system, which'
Card 1/2
SHILO) V.V.I, arkhitektor
Regional planninigg of Moscow and the Mo@cow Province.
35 no. 3:41-44 Mr 161. k.
(Moscow Province-Regional plannin )
Gor. khoz. Mosk.
(MIRA 14:5)
S--IT-,,O, YU. I.I.
Shilo, Yu. M.- 11"The tomic reaction of rhe molds of the Astergillus genus lapon the
fermeznt@in@@ activity of anfrm@- tissuer-," Sbornik trudov Kh-,---rtk. vet. in-ta,
I Vol. XT-X, I- Irsue 2, 191,,8, F- 1@1-92
SO: U-1()"I', 2'@ U'ct ::.3, (Letopis 'Zhurnal 'nlikh Starey, 13o. 10, 19-9).
SF,17-C", '-I:. -".
"T-e -,jr ')- ::. cf the X-rav diamosis of fo6der affecte@ 1- mold,"
I C Dy
Sborni-17 triarlov 7,r.-irlk. vet. i-n-t--, Vol. XIX, Tesue 2, 191', p. 19-1-09
SO: 2r, Oct 1,7:3,(Letopis 'Zhurnal 'ryidi Statey, IT0. 16, LQL9).
Yj rh
No. 10-78t.-Seven ma res, ivere studied-
the first yeir and 3i inares the second year for the entire
@ctatimi miod. ThL av. ascorbic acid content in the milk
- - @1: 04 ing. per I., varying from 62 to 1-90 mg./L In
:;.sg at the bt ginning of lactation the content of ascar-
@M ill, it kne., -.@ in the middle of the lactation
fnen toward the end. Thpe varia-
't"', to if), varying anits. of ascorkiii: acid in
Ao-i,mn poorer in ascorbic acid than Ole
j -i 6ir wid content was alike in working- and
:I. W- I 1lig lu-lfus. and was inde-pudent of the breed and
the j),!riad of foating. M. Hosch_
USSR / Farm Animals. Cattle. Q-2
Abe Jour : Ref Zhur - Biol., No 14, 1958, No 64426
Author : Shil2,.Yu. M.; Beletkov, M. P.; Sobolyeva, G. S.
Inst : Kurgan Agricultural Institute
Title : MAterials for the Study of the Composition of the Milk of
the Kurgan Breed of Cows.
Orig Pub : Sb. nauchn. rabot Kurgasnk. s.-kh. in-ta, 1956, vYP- 3, 211-
217.
Abstract : The milk composition of cows of the Kurgan breed was studied
on 10 cows of three calvings, older than those in the herd
of the Institute. The production of cows was 3,600 I;g., and
the fat content of the milk, 3.9%. The average compositiazi
of r.,iilk during a lactatation was (in %): dry substances 12.05,
fat 3.84, protein 3.33, sugar 4.21-5.1, ash 0.664, calcium
1.184, carotene 1,879-2.247. Density of the milk was 29.84
A. Fat and dry matter content Uradually increased toward
Card 1/2
USSR / Farra Animals. Cattle. Q-2
Abs Jour Ref Zhur - Biol., No 14, 1958, rio 64426
the end of the lactation (fat from 3.54 to 4.5% and dry
substances from 11-34 to 12.42%). Pr *otein content was
rather high in the first month of lactation (3.3%), and in
the subsequent months its amount somewhat decreased; in the
2nd half of lactation, the protein content gradually
increased again, and in the 9th month attained 3.4og%. Fat
content in April (stall period) was 3.76% and in June
(pasture period), 3.44%).
Card 2/2
17
SHILOKADZE, T.A., inzh.
Effectiveness of installing mirrors on mountain roads. Ayt.dor,
26 no-4320 Ap 163. (MIRA 1634)
(Mountain roads-Safety measures) (mirrors)
i v cr
AID F - 5431
Subject USSR/Aeronautics - training
Card 1/1 Pub. 135 - 8/31
Author Shilokhvost,, V. I., Eng.-Lt. Col.
Title How we improve the routine habits of students in
exploitation of aviation materiel.
Periodical Vest. vozd. flota, 1, 40-43, Ja 1957
Abstract A detailed description is given in this article how
the student-pilots in a unit are systematically trained
in exploitation of aviation materiel. The article merits
attention.
Institution None
Submitted No date
SHIM40VICHY M.IQI, ---,
Equipment for testing instrimento for the influence of ekternal
magnetic fields. Izm. tekh. no.6:35-39 Je 160. (MMk 14:2)
(Electric instruments-Testini)
L r If -7 _11_; 2-.1 Q; -- I- V IM. .n .
Elektricheskie Kontrolno-Iemeritelnye Pribory (Electrical Check-Control Measuring
Instruments), 295 P-, Moscaw and Sverdlovsk, 1951.
SHIL0140SOV, M.A.,; RUDNTT, N.M., kandidat takhnichaskikh nauk, reteen-
zenr-,@t=tU,ADIIjKOV, D.A., dotsent, radaktor; STUDNITSYN, B.P.,
redaktor; DUGINA, N.A., takhnicheakiy redaktor
[Electric control and measuring instruments; repair and t8Bting]
glektricheakie kontrollno-izmeritelinye pribory; remont i
ispy-taniia. Izd.2-e, isprav. i dop.Moskva,Gos.nauchno-tekhn.
izd-vo mashinnstroit.lit-ry, 1955. 404 p. (MLRA 8:10)
(Electric measurements) (Electric controllers)
PHASE I BOOK EXPLOITATION SOV/4532
Shilonosov, Mikhail Alekseyevich
Eleki,richesk.iye kontrollno-i2meritellny-ye pribory; oborudovaniye elektro-
tekhnicheskikh laboratoriy, remont i ispytaniye apparatury (Electric Checking
and Measuring Instruments; Equilmient. of Electrical Engineering Laboratories;
Repair and Testing of EquIppent) 3d ed., rev. and enl. Moscov, Mashgiz, 1959.
W P- 30,000 copies printed.
Eds: D.A. Bezukladnikov, Docent, and P.G. Nikitin Candidate of Technical Sciences;
Managing Ed. (Ural-Siberian Department, Mashgizi: L.A. Kon'shina., Engineer;
Tech. Ed.: N.A. Dugina.
PURPOSE: The book is intended as a handbook for the personnel of electrical
e-Wineer-Ing plant laboratories. It may also serve as a textbook for courses
aiming to improve the qualification of industrial workers concerned with the
operation or'repair of electric measuring instrLunents.
COVM&GE: The book presents the fundamentals on the organizatioi of electrical
engineeeing plant laboratories and on the repair, adjustment, and checking of
C.ard 4@@_
SHILOV,A. -.0.
@
Popular films on problems of landscaping. Zhil.-kom. khoz.
5 no.4:27 '55- (MLRL 8:9)
1. Glavnyy inzhener Upravleniya blagoustroystva i kommunall-
nykh predpriyatiy g. GorIkogo
(landscape gardening)
L 03'773-.67 C"'JuIV ptrr) Cx
ACC NR: AP6028334 SOURCE CODE: UR/0293/66/004/004/0552/0557
AUTHOR: Shilov, A. A ; Zhelnin, Yu. N.
ORG: none
TITLE: Minimization of the ultimate deceleration of a vehicle in an
atmosphere
SOURCE: Kosmicheskiye issledovaniya, v. 4, no. 4, 1966, 552-557
TOPIC TAGS: atmospheric entry, I control, space-
cr;aft deceleration.-
np CLX_
.A-6BfTRACT: The problem of selecting the vertical component of the
aerodynamtc lifting force which minimizes the allowable deceleration of'
the space vehicle during atmospheric planetary entry is analyzed. The
equations of motion of the vehicle in the atmosphere are written to
include the condition that the drag coefficient CX W const and an
expression is established for the axial deceleration component nX as
a function of the aerodynamic lifting.parameter-R(x). For given flight
parameters at the initial and terminal points, the function K(x)t with
constraints of the form
Kmin 4 X(X) < Kmax,
Card 1/ 2
-592z629.13(203
(1)
L 03778-67
ACC NRI AP6028334
is sought which minimizes the value of nx at the terminal point. The
Pontryagin maximum principle is applied to the solution of this opt-imum
control problem's The minimization problem of the allowable decelera-
tion is reduced to the minimization of a certain auxiliary function.
A general qualitative analysis of optimal control structure is pre-
sented, A more detailed analysis of the optimal,control structure is
carried out for certain particular boundary conditionse Origs arts
hast 3 figures and 20 formulas. [LK).
SUB CODE: 01/ SUBH DATE: 12May65/ ORIG REF: 005/ OTH REFt 001
ATD PRESS:
L 148o6-65 TEAT (d ')/FBD/FSS-2/E@MT,(*jl.I/EEG.--C'
EEC p -,L
k r VEWG (V VONA( d )'/EEC -2/FS )
Ph-4/pi,--4,fpi-4 I J P t I/A FF.T-'
ACCES'SION NR: A P 4 0 4@� D' j
0258,
Rae
619/6625
S/258
/62/002/003/006/008
1006/1206
AUTHOR: Shilov, A.A. (Moscow)
TITLE: On Pliminetion of singii1srities fr.)-n -,he general
equations of motion of a flying
PERIODICAL: Inzhenarnyy zhurnal. v.2, no.3, 1.962, 158-160
TJ'
,XT: The representstlor of motion of a flying object by the head-
ing, pitching and bankiro, angles. W.-&,71 is encumbered by singula-1
rity of representatlor for %h. *IT11, where one position of the ob-
ject mRy be described by many 1P.,2- values. It Is .3hown that by the
--Wi'd of the nine cosine angles defining boay coordinates with respect,
to enrth coordinates this- difficulty can bn avoldtid. There are 2
figures.
SUBMITTED: January 23, 1962
Ca@d 1/1
SHILOV, A.A.; AKIMDV, R.A.
r - I.,
Economic effectiveness of the power and chemical installation
at the "Vakbtan" Plant. Gidroliz. i lesokhim. prom. 9 no.4:28-
29 156. (MLRA 9:11)
1. Kanifollno-,ekstraktsionnyy zavod "Vakhtan" (for Shilov)
2. Lesotekhnicheskaya akademiya (for Akimova).
(Wood--Chemistry) (Boilers)
SHIIOV, A.A. (Mytishchi)
Nomogram for calculating the emission of heat by heated surfaces.
Vod. i san. tekh. no.12:27-29 D 158. (MIRA 11:12)
(Heat--Radiation and absorption) (Nomograpby (Mathematics))
AFANASTEV, A.P.; ANUCHIN, V.G.; VINOGUX(YV, K.V.; GARANINA@ M.M,;
GILEROVICH, M.M.; DUBROVSKIY, Ye.P.; YEVSTIGMEV,, A.A.; IOKHVINj,
M.R.; YAUCKOVI P.M.; KRENGELI,, I.TS.; LOSEV, I.G.; MAYEVSKIY.,
F.M.; MAZELI, S.I.; MIZIMITSKIY., G.S.; NOVIKOV, M.I.; NAZARfM.,
ON.; PCHELKINA, I.A.3 RAZUMOV) V.S.; R02MIBIYUM3, I.M.; MGVj B.P.;
SKRYPNIK, T.I.; SALWIN, Ye.S.; SMOTRINA@ V.F.; TEIEPNEVAI N.S.;
FILICHAKOV) N.I.; KERAFUNOVA) Ye.L.; UNDREVICHp G.S,; URITIYEV., P.P.;
S@qILOVO_A.A.; SnYKCV, A.P.; KIRILLOVO L.M., red.; MARKOCHp M.G.,
tekhn.red.
[Regulations on the construction of minicipal telephone network lines]
Pravils, po stroitellstvu lineirrjkh sooruzhenii gorodskikh telefonnykh
setei. 2.izd. Moskva, Sviazlizdat, 1962. 511 p. (M]RA 15: 5)
1. Russia (1923- U.S.S.R.) Ministerstvo svyazi. Glavnoye upravleniye
kapitallnogo stroitel'stva.
(Telephone lines)
SHILOY, A.-A.
"Pulmonary gas-metabolism and the heat production in highly productive cows."
SO: Hygiene of Agricultural Animals, Proceedings of the 29th Plenum of the Veterinary
Section of the Academy, p. 87, Moscow 1950, Trans. #191, by L. Lulich, Unclaasified.
Vologod Milk Institute
Monthly @@st 2@f Russian Accessions, Library of Congress, Au@@Tst _195A, Uncl.
2
@@:S C;S 01' Ur-kn T'll 11-n
o s
1"'t- iolcgy
,To 209 19 9-755
:is Jour A.,
hox,
u-al Instit-utc.,
In K v c, cl 1-gricult I
M : -@@ H,@,. -iilltis Jn Young Pigs.
p p@ G
Q U-@7 19579
ci@jb Pub Tr. K-12OVS]',C)90 ill-j 12, Yo 249
13
-libs';--act Penicillin and norsufazol [sulfathiazolc-
j -L .1
successfully used in c.---i.Jbinatio.-a vith
disinfoction o'@' buf""clingj an,. iEiprovc-7iont
iin zcohygicnic cone@itions for the provo-n-
tion o" th- disoase, on sovoral fams i--,l tho
Kir,-wl-MY-a OblDst% 0.3-0-05 g of norsulfa-
tr.rOCL tr@ -11 %rCUj-jg pj,,
zL)i verc-@ al-i-inist U gs per"
-L./2
SHILOV, A. A., (Assistant Professor of the Kirov Agricultural Institute)
An instrument for in:ection
Veterinariya vol. 38, no. 10) October 1961) pp 6a,
SHILOVY A.A., dotsent
Device for injections.
Veterinariia 38 no.10:62-63 0 161.
(KL@A 16 12)
1. Kirovskiy Bellskokhozyaystvennyy institut.
(Veterinary instruments and apparatus)
4RILOL-A.A.
Scaup Ilyroca fuligula L. on the lakes of the Baraba Steppe, Orn-itologiia
no.4:297-302 162. (I-MI 16:/+)
(Bar-aba Steppe-Ducks)
AUTHOR:
TITLE:
PERIODICAL:
Shilov, A. S.,
89-1-15/29
Elimination of the Influence-Exercised byp, -Scattering Radia-
tion "11*hen Calibrating Radiometers (Iski@-ucheniye vl-.iya.-_iya ras-
seyannogo,p_-izlucheniya pri etalonirovanii radiometrov)
Atomnaya Energija, 1956, Vol. ij, Nr 1, pp. 84-87 (USSR)
ABSTRACT: It was determined experimentally how much scattered radiation is
measured in a closed roc;m by different counting tubes at various
distances of the counting tubes from the walls and at various
distances of the standard preparation from the counting tube.
The respective curves are shown.
On the basis of these experimental data three possibilities are
mentioned how to eliminate the disturbing I-scatterinrr radiation
when calibrating radiometers in closed rooms. There are 5 figures
and 5 Slavic references.
SUBMITTED: August 28, 1957
AVAILABLE: Library of Congress
Card 1/1
SITILOVP
Determining L*ne reg-a'arities of the ch nge of temperaturp,
in mer-aury valves. Truci; 0 IM -11 T 497 163.
IRA 71-3.7)
SHILOV, A.S., Jnzh. (Tomsk)
2 1 1. -
Methods of preventing back-fires in rectifiers. Elek. i tepl. tiaga
3 no.4:22-23 Ap '59. (MIRA 12:7)
014arcury-are rectifiers--Maintenance and repair)
Y3B-EMIN, N.Te.; SHIWV, A.S. (Tomsk)
Method for measuring the voltage drop in the are of a mercur7-
arc rectifier. Ilek.i topl.tiage 14 no-3:28-29 Hr 160.
(KE" 13: 7)
Ollectric current rectifiers)
ANTONOV, M.F6- SHILOV, A.S., red.; OSOVSKIY, A.T., tekbn. red.
[Selecting the best economic variants) K vopro4'u vybora eko-
nomicheski nailuchshikh variantov. Tomsk, Izd-vo Tomskogo
univ., 1959. 43 P. (MIM 24; 10)
(Electric power distribution)
PAKHOMOV, V.Ya., inzh.; PENZIN, L.I.; ARKHIPOV, L.P.; 5Hjj!O
@A S@
starBhiy prepodavat6l'
The mercury-are rectifier has been installed outside the traction
substation. Blek.-i tepl. tiaga 6 no.11:12-13 N 62.
. . (MIRA 16ii)
1. Zamestitell nachallnika Barabinskogo uchastka energosnabaheniya
(for Penzin). 2. Nachallnik tyagovoy podstantaii Kozhurla (for
Arkhipov). 3. Omskiy institut inzhenerov transporta (for Shilov).
(Mercurp-arc rectifiers) (Electric railroads-Sub*@ations)
SHILOV, A.V.
Hostaphane, a transparent plastic material, its use in carto-
grapby. Geod.i kart. no-4164-69 AP f62. (MM 15.-12)
(Cartography-Equ3i ent and supplies)
Plastic .
.r
(
-15395-66 EWTW :(;W-
ACC NRt AP6001009 SOURCE GOIDE: UR/0286/65/000/022/008 2/OOE2
AUTHORS: Kopylova, A. D.; Shilov, A. VO q
ORG: none
TITLE: A method for preparing physical-ge hical mgM with a continuous wash-
,2grap
off of the relief. Class 57,, No. 176486 Lannounced by Central Scientific-Research
Institute of Geodesy, Aerial Photography, and Cartography (Tsentral'W nauchno-
issledovatellakiy institut geodezii, aerosnyemki i kartografi-i)
SOURCE: Byulleten' izobreteniy i tovarnykh znakov, no. 22, 1965, 82
TOPIC TAGS.- cartography, map, quality control
ABSTRACT: This Author Certificate presents.a method of preparing physical-
geographical maps with a continuous wash-off of the relief. The method includes'the
preparation (from the original of the continuous wash-off of the relief) of a map
of the screen transparencies. These transparencies are used with-the subsequent
preparation of printed forms (based on the number of colors) of the hypsometric
layers and of the printed form of the continuous wash-off of the relief. The.method
increases the quality of the map and e-livninates manual retouching. Two tinted nega-
tives are prepared from the original of the wash-off of the relief. One negative
has a precise transference of the reproducible image of the original and is used for
obtaining the screen transparency and the printed form of the wash-off of the relief*
Card 1/2 UDG: 776,7:528,927:655.3
L 15395-66
ACC NI.Ap6001009
The other negative, with a softened reproducible image of the original, is used for,
obtaining the screen transparencies and printed forms of the hypsometric layers based
on the number of colors. During the process of separating these transparencies into
hypeometria layers, masks are used directly on the printed forms of these layers or
on the transparent plastic.
SUB CODE: OS/ SUBM DATE: 27Aug64
61&
2
Card 2/
SHILOV, A. Ye.
USSR/Chemistry - Hydrogen Peroxide, Jul 53
Nitro Compounds
"New Work on the Kinetics of Oxidation of Nitrous
Acid With Hydrogen Feroxidey"@`Ye. A. Shilov2'Inst
of Org Chem, Acad Sci Uk SSR, Kiev.
Zhur Fiz Khim, Vol 27, No 7, PP 1103-1105
In their work on the kinetics of oxidation of EN02
with E Ralfpenny and P. Robinson (J. Chem.
S.' p1091 1;52) arrived at results different from
those obtained by the author Zhur Fiz Khim, Vol 24,
p 820, 1950; Vol 25, P 1137, 1951). They apparently
271T17
had no knowledge of the USSR work. Their expl
technique is deficient in some respects %0 Leh
reacts with EN02 under formation of @ @ 6,
acts on aromatic compds with formation of nitro
derivs.
on 9( hjA
lqudeaphilic addid
@fz@dftg@ E. A.'-I= 'a' nauu'@' Saw. Domry
-
Ak,zd-
HCJ to (;CCO@Nfe), solos. of UCI in AcOH form HCJ ad-
ducts mom rapidly than soins. of HCI alone wider compar-
able conditions. The reaction yields di-Mechloro(umarate
which does not add HCI uMer these couditicus; thus the,
UCI reaction also yield. AcOLi. The addn. of LiCl In
AcOll follows the equatinn: -(dCltil) - k,4 C, where A is
the concn. of the acetylenic ester atul C that of UCI; k' @
3.4 X 10-1 inales/l. min. at 30* and -16 X 10-1 at W*.
With free HCI the reaction is also of 2nd order but ks at -
30' 1!; 0.9 X 10-1. When both JICI and LICI are pre@ent
they react independently of each other and a summational
rate prevails. Etrong acids, such as CljCCOFI, do not af-
feCt the rate of the LiCl reaction, but addn. of H@O (up
to 5%) accelerates the addn. of LICI by some 50%. Un-
dissoed. mots. of (:CC03H)j In aq. @oln. also react almost
equally @-apidly with NaCl and HC1, thus showing that
the rate of the over-all reaction is lim' tett by the reaction of
Ine Cl ion. Neither the neutral nor the acid salt of the
acid reacts with aq. or AcOll solr4. of the chkn+lei. Bro-
mides and iodides am more active: LiBr in AcOH reacts
@ith the esAvr 5 times a@ rapidlv a.@ LiCl; HI adds (from
KI soln. in 80% AcOH) some 260 times xi rapidly ws HCI
from LiCl -41n. Thus the addn. of HO from the salt soln.
initiates with a nucleophilic attack of LiCI on the acetylenic
link, followed by reaction of a mal. that contain-, active If,
but the 2-id reaction is much slower. The nucleophilic
nature is shown by the fact that replacement of Ac by H or
Ph lowers the rate of reaction of the acetylene deriv.; HC .. -
CCOiNle ii less reactive. while PhC:CCOiNfe I--, even lem.
mactive. The kinetic data are given in, tables- G. N1. K.
-.@:7777777'