SCIENTIFIC ABSTRACT SHIDLOVSKAYA-OVCHINNIKOVA, YU.S. - SHIDLOVSKIY, A.K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549410007-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

1
'Ki 4
4

VDetermlaalfon of lrin In its varlou@ forms Id iifaril:,
- 77'
Waters. yu.
S. ShidloTAmyn- Xulby
Pvchinalkvrva (V. V.
A kad N.
(o-j shev BuiMWcFZW. Id a

-
F.
S.S.S.R. 90, Fe- were detd,
'
ith HSC
H
d
ld
t
i
ll
H40
dJ
1
,-
ca
an
r
catorime
y w
aA
, rev.
g
1
pyr
y
Complex Fe was detd.jollowing prolonged boiling of the
7
acidified sWv. -with XMnO4 and subiequentreduction to
GarrGera-rd -4
J.
_j:

StqDTIOV8KAYA-OVCHTMKOVA,, Yu. S*

Detanp-laaUan of the different forms of Irou L- usturzi
watION'
wWs-,--kayW4NdhUjftj4 Hu"Ildin
Yu
.
.
-W p 4' 3;
I
n
(1935 c f . 0. A. =W'dui mf
In
a
ivH
t Oba equiv..
stat. (it IAV A d-,N AcOU4 to 10 =L- -watee).-I
0.5 he Was defA, by addinc,
ML loole, s 9& at .4 to la mi. viater,

Fe IW-W n7A. V w&tcrv (I mi, sixt 12 cu,OUM,
to: is iiiL V@.L. la@v*:
.5 hr4
Kmaoo wesi bbiled in 1.04
,
ixedo 41AM! Ld4
0. IN oxeic scal Was addotA4 W
KUn0j, and the sda, neu 44ith 16 zhL 940AZ sad'
ftaui,C4
dild to SD W ta'a 10-,iilt @l
L- vAt was added
and Fe dad. j@

t

SHIDIOTSKAYA, Yu.S., dote.
Using.a new method for determining the calcium ion ooncen-
tration in studying cement c6rroBion in water-salt solutions.
Nauch.dokl.vys.ahk-oly-, stroi. no.2:197-199 1 58,
(MIRA 12:1)
(Corroolon and antic.orrosives) (Dement) (Calcium-Anal4rais)

62--58-4-1//32
AUTH OR S K_-7pur-tin3-.J-, F. Shialovski@,, A. A. , Shi_djo_yg'-_ya -.', _S A
fu,
TITLE: Te Ueat of Pori::ation of Am-lonium and Al@-aline Yetal 11alo-
Jenates ( Te@ioty obr_,:@ovaniya @aloE;cnatov ammordya i
shc.helochiiyk1i motallov)
PE R7 GDICT; 1,,.vcstiya Al-ade7di lfaul@ 33' R,Otdoleniye Khimicheskikh Nauk,
L
193,13, jTr
" 'T On!-! few ex.,eri--.ental dLtzi have been pulAislied cin the heat
of for-.@,.tion until now. Kast stai-ted 'roi- the condition
17-1 iC" later on turned out not to lte quite correct - that
,,, e 2: e
u_U o' t-E! ion eych=e solid salts
ITac 10 '@ J.M C 1= 111T
I CIO , NaCl
3 4 3
nLit1_.er exot'--,e.@.Ac nor endot:-crmic. Starti-n-
frm this conrlitior '-e calci@lated t.-.e for.-.@atiori of heat of
c',loride _roxi@utely equal to 62,7 kkal/,--mol.).
1i2 Tic3e data z@re +'-,@ mo.-e int.--restinU for tu'@ermochemiztry as

62-5,9-4-1/32
The -le--t of For--'ior, o@- and --etal 7-alocenates
.;o:.-,e of t'@,azie avbstance3 -I,lLiy an essential part in pyro-
teclLnics, T',,c -ntl,ors ca-.:r;,e,l out measurements with ITH
JO
4
3
zt-nd NaDrO, ill 02',10,r to a.-,.roach tl.'Ie -@ValllLtion of some
still unkAown conot:@@nts by means of tlc results achieved,
By mo-ons o--F' tL'ie calorim,,@tri-, method th,-, Standard hea-ts of
ainmoniiirn irdide and solliiim b.-omide viere determai-ned
("III JO crys t . ZN H /4,0 + 0,2 kkallmol and
3 =
2
4
-
3
9
I!aBrO
11
- C
r7r3 L
208 = --76,8 + 0,5).BY -,ieans of the method
v -
of constant equilibria the unknown heat of fo=-.ion of
soi7ie aiarionium s,-.1tg werc calculated. There are 10
7 Of wb--*.Ct a,-:'e SU44-et.
ASSOCIATION: '.'oskovc!--Jy khimil-~~-'Le!.hnolo.-ic,,.e~-ki-y institut im, D@ I,
@.Tendeleyeva ( L I,,) s c ow '!.cmicz,1-Techno1oZ;ica1 I:istitute
i.-@eni D, T. I,Te:,dclc-,rev)

S T 71M,iI'D 7
February 1951
A7AIL.', 'I@T E,
Lil)rary o. Con;:ress
Card 2/2
1. Immi@nl,--A mnt@-:I h-lct-ea6--Heat of 2, MIr. @',a
metall 'Poy-mazi@@-2,-

KAPUSTINSKIY, A.F.; SHIDLOVSKIY, A.-A.; SHIDIDVSKAYA, Yu.S.
Heat of formation of ammonium and alkali metal halogenates.
Izv. AN SSSR Otd. khim. nauk no.4:389-402 Ap '58. (MIRA 11:5)
1.14'oskovskiy gOBudarstvenny7 -universitet im. M.Y. Lomonosova i
Institut fizicheskoy khimii Akademii nauk SSSR.
(Nitrogen) (Adsorption) (Carbon, Activated)

SHIDLOVSKAYA-0VCHINNIKOVA, ru.S.
Development of methods for a quantitative determination of dissolved
nor-ionic iron in natural fresh waters. Gidrokhim. mat. 35:168-176
163. (MIRA 16:7)
1. Moskovskiy inzhenerno-stroitellnyy institut imeni V.V.Kuybysheva.,
kafedra neorganicheskoy khimii.
(Water-Composition) (Iron)

Sli LDL07,@KAYA-OVC HI III,!! @' OVjlj., Yu.S.
',@Ullintita'.ive determinalJon cf suspended iron in matural frash-
--ater. Gldrol-him. mat. 38!131-136 164.
aL
(MITU 18.'4)
1. Moskovskiy inzhenerno-stroitelinyy institut.

SHIDLOVSKIY,A. Inzhaner
Removal of metal arched set in exhausting a drift. Mast. ugl. 4
no.3:21-22 Mr '55. (MLRA R:6)
(Mine timbering)

FON
It V a X b a a it a is be a a V a it
a is M is 16 U of " a 4 it Q 411
-A__L_.L_AL A- *_A__Lr*O
1*0 "til
A
XR.'Woai'O Uk" of d Al.WW. A. A.
jZhur. Priklad. Kki.- 1946. 19. 371-37 .8; V. AbA.. 1047.-4[C
IM-ei'l-1-fa Russian]. On the buie of thcorctival calculations of hest
evolution. mixtuns of nuiignedum or aluminium with "ter or Alwhols are
IN'tentially more powerful expkisives than the usual military materials. With
methyl alixthol-irmpraiu i ia.. ga@cvulufion, The experiments vrm-
ME"Twurro wit
t@mdueted in I.,.t. or lea enA h Wtryl detonator* to wt off thet
naixtun- (if the puwden-d mvt4I and the lquid. All mixtum were shown
be jx)werfully explosive, water-mapesiant being most sensitive to
!hock; wate"uwlaium and metbvl slooliol-magnesium were It-so sensitive
and rrquired a booster detonator. hotographs of the explWed vt@m-ls and
00 @-@n!@. a- P-Idw-
EYALLURCKAL LITER-11491 CLASSIFKATIOld
4-1
I
K a 19 It it G: it It 01
& 0 0 0 0 a 0 0 4
0 0 0 0 0 0 09 6 41 0 0 6 so 0 go
C.z
in
"0-
I 'LAARL is ado A INFASOO 3 a T
do
toRI !Is
- * 0 0 0 0 0 0 a 9 0 41 0 0 0 0 4
0 0 close Soo's see OZ 0 q & 0 0 0 4
.00
-40
-60
-00
Soo
=06
'fee
=416
see
so*
zoo

AD 0
0 0 tl a w
SO It it A! It a so It v a n'w 31 u 13 )1 a IS It 1) 41 a u
A L r, L_j AA.
A f.j* 45__
.2
Water as an oxidant In ?,YT*tKbnic MINW44. Ak_
00 SbiWuv,l AppikA Chrmi,l IV, I . _r'-f4-
('@R.S.S. St. 1:11 3t 10 16). of
11" -1,4 Nlg 0: 0.2nd IGO and A] 0:2), -hen @ubiclvd,
to ii-a- beat. are cat%able ofccinthu%tion. TheNtKiniXt.
can be detonateil with a sultabIc priwr, but the At inixt.
00 Cannot.
I L .11ALLUgGICAL UffliArtof CLASIWKATIC.
t' p 0. Al At a 9 0 K a It It ata
coo
COO
.ago
40
C-1-
7860
satol
am: o- Lit
Iff IN 13 a 1 3 2 v
0,0 a 0 0 0

.1 1-j-'73 .'I*,' @7'7
2@. Chr:. M-2 te S
7. 1-i-restigation cf the ce-mbjsticn (if innrganlc saIts, anmoniwm an!
trilchrcm.ate, Zh--ir. -,@rikl. 'A-hi-:,-. 26, no. 1, 1953.
9. Monthly List of Russian Accessions, Library of Congress, -1953. Unclassified.

SHIDLOVSKIY, A.A.
[Principles of py'rotechnics] Osnovy pirotekhniki. Izd. 2., parer*,
Dopushcheno v kachestre uchebnogo posobila dlia khimiko-tekhnol,-gi-
cheskikh vuzov i fakulltatov. Moskva, Goe.izd--vo oboronnoi prom7sh-
lennosti, 1954. 284 p. (@aa& 8:4)
(Militar7 fireworks)

--
7

Ist of I
am ry SMEM-C lit. Method
ramo Teciz com us it afjuor".I@
2@4 in a calorimetric bomb. The bout of formAtion of;
1151 Calurn blebromate and :hrmnaln. _F@ Kann-
stlas
W,4 D
'gohgoli=4 ?,411gaW. , In-est. SMara Pl atiny i D u
IjId 01
!
S.
Ma
k 5. R..30, 31AMM).-"Intraniol, catubustlou"
isthcpxidationby0prks~ntiisatnol,~6tu~oaeni- Onede-
feet of "bomb calorimetry " when nsed to, det. the heat of
fortuation of 6rg. compods. is the fact tba t the beat of farina-
ti.n appears there as it differenct, betwc-w 6rge beats of coin-,

stion each of 'which must be.exceptianally accurate1or
bu
reliable resulu. fix inorg. chend3trythe methM offers"re,
liable tesults (ibid. -1. 152, l6q1OP4), znd,- may bii - con-
fornuxtion of
sidered accux@ti,pjthin7 :E2%. `71eiteat of
-tsaic
Nfr,),CrA aujipf (NH4)2Crx0jo %vas fit" 4by the method
and :k, 0 -had - 6W :L- 6 kcal./mol. were found for
the2sMts. An attempiwas made toexpand thchoniologous-
Series Concept Of Org. Chemistry to inorg. ciaupds.. and the
heat of fortuadoo,of the 3ra meiiiber of,the Cr%-(Izylifj-
thetical).member of the"homo@)gous s6riv-i; (NlT,)Xr40u, ,
was calcd. to bcISO L- 10 kini./mul. IV. 7
he synthesis
1
and heat of foringtion of cobalt chloride diacetonate. A.F.
Kapustiuskil ajid X. A, SnIg0jin. Ibid, 31.) 13.@--Tli hedt
of solm of COO, in water found
firms the vulue obt;ihiud bY Katzin and Ferraro (C.A-47i
itimah) -if ISA kcat./tual. -A cryvt. diactitonau: CuC42
jvas @yuthiisizcd, and t)jc beat of its foril ation
CII@Cocll@ I :, .
. I
-
at Is' 0 kcM./uI.L Sternberr . ,

51AIDLOVSK i
Y3
_11:66ry 61 CliefilkUl structUr6 of
T
he -A
poly com oun a: an
d I . . -m-17 @ 1 1 ; I ---
e e eev
-Blagorod
j, 'Urug.
ex.. ra g A d. Nauk:S;S-S.R- 30, 4448.'
Obshchel i Neorg. a
CA,-, 2, 2346;.. R.'
(1955).@The mfolatti-Rosenheltn@(M.. , , -. , .: i.. -: -
-14, 241)
and jdjlicke; C.A. 12. 1624) and Pfeiffier (C.A.
explanations of structures of poIY CGUIPAS- are inadequate.'
and a theory is developed, based'on spatial models-that'!
elilninates the apparent contradictions existinj in t,he stru.V;
tum of con Iiplex col"Pd- it permiti designitit pin" electron-
ersion of spatial -
structurnI f6miulas for structuni, -the entiv
representations to plane projections. being considered. The
an Z610i grongt-tob: central MO
heat of couibilliltion of d d
AL-creased with an increase in the group no. On ten s to-
tional satu.
a min -as it approaches the codrdina i; .. - , - 11 . I I . . -
-fornuition in a-homologol 5
0. tile other hand; the beat of pprax. propor-
series @f isop.1y, salts from the elements is a
ti6nal to the no, of Otom3 in combination with tht.anion 0. 1
The exptl. thermochem. data Wild co firm the Proposed
spatial model of isopoly;cnthpds. Tile H10:mols. in the
heteropoly cry@tlll hydrates are distributed in@theouter
anion ]aver, H bond.- being formed with the@0 of the corn-
Plex tetrahedrons (or octaliedrolti) of the, brLeeding layer. -
A "water: bridge!' concept is introduced -of a chain of. (3)
-in the heterop6ly anion
water ntols.@ns tile binding unit
Ilvdi-ates. The.'jl0jlAdhCI-,!ucL of iorne isop6ly and. hetero..
11,1tv C(Itopdi. to (be lawts of.cotkiL and multiple proportioni:-
cat; be V411, les and ber-A
ained Fronz i ac ijewpohaof daltomi
tholidei. The consideration of inert-gas hydrates as a high-
est forns df oxymaddi permits prediction of the'compn..
,of the crystal hydraici of tile iftert The- provsed'
Is e-q)lnill the experi-
structure forniuLis of heterapoly acil
mentally found higli acidity of these acids. which e3cceeds,
tile acidity to be expecte&from stnichiometric consident
ljol1q. New &.0rdination.formulas of isoroly and heter'Q-
)w!y compilil are propoicd,_ which show gruflbically @ the
W. 7@ Skert#xFjt_2 -

USSR/rhermodynamics. Thermochemistry. Eqailibria. Physico- B-8
Chemical Analysis. Phase Transitions.
Abs Jour : Ref Zhur - Khimiya, No 8, 1957, 26o84
Author : A.A. Shidlovskiy __
Inst : I1d`_sc-6-w_Tn_stitute of Chemistry and Technology
Title I To The Thermochemical Theory of the Influence of Salt Addi-
tions on Speed of Thermal DecomDosition of Ammonium Nitrate.
Orig Pub Tr. Mosk. khim.-tekhnol. in-ta, 1956, vyp. 22, 84-88
Abstract The influence of the addition (1 to 2%) of.various inorF-ranic
subst@m ces on the speed of decomposition of NH4N03 at 160 to
2000 was studied. A chemical an thermochemical explanation
of the accelerating action of Cr9+ and Cr3+ compounds, metal
chlorides, KHalO N 'To others is given, and the kine-
.. aN 2 and
tics of the acc2ration of the thermal decomposition of salt
melts by any ionized addition is investigated.
Card 1A

SHIDLOVSKIY, A.A., kandidat takhnicheakikh nauk.
""WI-11, @-'-
Anatolii Fedorovich 4puq@inakii; on his fiftieth birthday. Khim.
nauka i prom. 2 no.2:248-249 15@. NLRA lo:6)
(lapustinskii,,Lnatolii Fedorovich, 1907-)

SHIT-,LO.VSLrIY. 11.3., kandidat tekhmicheskikh rauk.
, @ --'- -@- 9- - -
---- - It
St-qtistics of the discover7 of chemical elements, ?rlroda 46
no.6:106 Je '57. In: ? ,,
1. Maslrove!:Ay k-himiko-tekhnologicheskly institut im. D.I.Mendeleyeva
(Moskvn@.
((.her-.icnl elements)

50 )
AU@HOR: Shidlovskiy, A. A. SO'V/1 53-53- 3-1 91@': C
TITLE- Thermal Decomposition and Combustion of Ammonium Jitrate a-,
Atmospheric Pressure With Various Additions (Tenaicheskoye
razlozheniye i goreniye pri atmosfernom davlenii ammiachnoy
selitry s razlichnymi dobavkami)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya :L
khimicheskaya tekhnologiya, 1958, Nr 3, PP 105 - '110 (USSR)
ABSTRACTs The most effective catalysts causing the self-decomposition
of ammonium nitrate, are chromium and copper compounds, among
others (Ref 4). However, the reaction mechanism, especially
that of various chromium salts, is not yet clear and needs
further investigations (Ref 4). The author investigated the
processes mentioned in the title with additions of chromium
(VI), chromium (III) compounds, as well as with copper (II)
chloride. Additions of ammonium, potassium and sodium
chromates and bichromates (1 e.) were tested. The mixtures
stuffed into glass tubes were ignited by a small nickel-
chromium wire caused to glow by electric current, The
measurement results are given in table 1. It is striking
Card 1/t that the.combustion velocity with additions of potassium

Thermal. Decomposition and Combustion of Ammonium SOV/1 5 3- 53 - 3-1 L/',, 0
Nitrate at Atmospheric Pressure With Various Additions
salts is several times that of the cambustion velocity with
additions of ammonium salts. The catalytic effect is
attributed to the ions CrO 42- and Cr2 0 72-. The potassium
ion probably plays the role of the accelerator. Additions
between 5 and 10% have little effect upon the combustion
velocity. Additions below 2% cause no constant combustion
(Table 2). The diameter of the tube (between 3A and 1,7
cm) is of no importance to the combustion velocity. The
0
combustion temperature was between 350 and 410 . It was
proved that the 5% addition of potassium bichromate decreased
the decomposition temperature of ammonium nitrate (energetic
decomposition at about 2500) down to 215 . From the analysis
of the combustion products the author set up an equation of
the reaction of a flameless combustion in the presence of
potassium bichromate that corresponds to a heat formation
of 528 cal/g of the mixture. In the calorimeter, however;
this heat quantity amounted to 480 cal/g. Therefore the
equation must be regarded as approximate. About 60 - 70%
Card 2/-P, of the compound of hexavalent chromium may be found in an

Thermal Decompoaition and Combustion of Ammonium SOV/153-58-3-19PO
Nitrate at Atmospheric Pressure With Various Additions
unchanged form in the slag residue. In the formed thick.
smoke wat.er-soluble compounds of trivalent chromiumi were
found. After an unsuccessful test of several other compounds
as additions the author used such additions only which
increase the velocity of the thermal decomposition of
saltpeter at 2000 several times. Table 4 gives-the results.
It may be seen from these results that besides the salts of
chromium (VI) also chromium trioxide CrO,, copper chloride
(II) and iron.chloride-(III) are such ad itions. The.effect
of the potassium"halogenates" KC10 and KBrO (Fig) is low.
3 3
It has probably another mechanism (Ref 4).' Table 5 shows
some more compounds that form dontinuously burning mixtures.
The catalytic effect of the efficient compounds in burning
ammonium nitrate is mainly based on the acceleration of the
thermal decomposition of the bonden .bed phase of the salt-
peter melt. This is shown by the equations (1) and (2).There
are 1 fi@ure, 5 tables, and 5 references, 2 of 'which'are Soviet.
ASSOCIATION: Moskovskiy khimiko-tekhnologicheskiy institut im&ni D.@ I.
Card 3/ Mendeleyeva (Moscow Institute of Chemical Technology)3
F _411(1-el
9

J
62--58-4-1/32
AUTHORS: Pn t 4 S k, F,Shi@kj 1-i
Shidlovskaya, fu. S,
TITLE: T!,e Ilea' of Forcation of Ammonium and Alkaline Lletal Halo-
-enat03 ( Teploty obra@@ov--riiya -@,.lo-cnutov am-moniya i
shc,iclochirrkh mcLaliov)
PZRTODICAI.: iya Al:ade!-,ii 111aull- SSM,Otdeleniye Khimicheskil
kh Nauk,
-5-380 MISR)
1953, Nr 4@ 3n i
"'STP
A'T: OnlL, few ex-,:erinental d, L.-a. h::ve been published on the heat
of for--.,@ation until now, Kast started 'ror" the condition -
-uluic:i on turned out not to be quite correct - that
rcac'Lioi, of t-ie ion e.-.-c*-an,-,-e bet--ae-m solid salts
TTaCIO -L ITH-,Cl = NIT 4 jjaCj
CIO_
3 4 4
Diace 11Q-it'ler e-cot':er..,iic nor endoti,ermic. Starting
fr=: t'iis coi@-Iition he cLiciilated t'-.e fcr---,,ation of heat of
a.-,onium Cii-loride (a ---roxi@ately equal to 62,7 kkal/,--mol.).
C r d 1 /2 T'-Lez;e d--ta Lre more int-jrestinl- for V.,ermochemi z3 try as

62-53-4-1/32
T h 711 et o f F o vL, t 4- o n o f A: o n i u m -," n d '. L: a 1 in e Y e t a 1IT alo@;enates,
,-o:.-.e of t'-ese :37,Cbs'Lances -Auy an essential pLrt in pyro.-
technics, Tic carric,!
jo
out mousurements with ITH
.
3
4
L"nd flaBro in o-:Ier to roach the avaluation of z@ome
'
still unkgovin constants b
,r means of the rcsults achieved,.
By means o-f the calarinctric method the standard hEats of
and solium bromide were determined
(TIH JO
-,01,4,0 + 0,2 kkal/riol and
crYst - Z-\ H2-
4
@,B
3
@T P
0
, a-r 3 cry3t + 0,5).3y neans of the method
of con!3t@-,-,L equilibria the unknown hoat of fo=@:tion of
so.-..-.e ammonium s,-,.lts vie-rc calculated. There awa 10
7 --f whIct azve Sveiet-.
ASSOCTVT'jO*T: "oskovcli- institut in. D. I@
endeleyeva Moscow ]',-e@Jcal-Technolo:@-icai Institute
i.-:eni D, I. 11.endeleyev)
S T'B7,@ I?"'I-"'D:
1 1-1 - - Febru-ry 1, 1957
- I
AVAIL:.!IT E": Lil@-ra@y of Con@-ress
Card 2/2
h@tllcron*,--Heat of Fo:--ration 2. A-1ka-II.-Ina
metal )-p @7crn-atit%

V KAFUSTINSKIY, A.F.; SHIDLOVSKIY, A.A.; SHIDIDVSKAYA, Yu.S.
Hout of formation of ammonium and alkali metal halogenateo.
Izv. AN SSSR Otd. khim. nauk no.4:389-402 Ap '58. (MIRA 11:5)
l.Moskovskiy gosudarstvennyy universitet imi M.V. LomonOBOVB. i
Institut fizicheskoy khimii Akademii nauk SSSR.
(Nitrogen) (Adsorption) (Carbon, Activated)

82107
S/153/060/003/01-1,/02/009
POO 0 B016/BO55
AUTHOR: Shidlovskiy, A. A.
TITLE: Intramolecular Combustio Capacity of Inorganic Ammonium
Salts
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i
khimicheskaya tekhnologiya, 1960, Vol. 3, No. 3, pp,@ 405-407
TEXT: The author discusses publication data on the intramolecular com-
bustion of several ammonium salts (Refs. 7, 12, 13). He believes that
even in these substances under certain conditions a constant propagation
of the combustion process is possible. Data on the heat of formation and
heat of decomposition of 11 ammonium salts are listed in Table 1. It is
of interest that the heat of formation of ammonium bromate does not re-
present the mean value of the heats of formation of NH 4C10 3 and NH4 103,
but that it is much lower. The same holds for the heats of formation of
the bromates, chlorates, and iodates of the alkali metals (Ref. 14). The
author suggests the following method to bring about a constant combustion
Card 1/3 WK

82107
Intramolecular Combustion Capacity of Inorganic S/153/60/003/0:5/02/009
Ammonium Salts B016/BO55
of substances which do not burn at 1 atm and 20 0C: 1) addition of' a
catalyst which accelerates the thermal decomposition of the salt, 2) an
increase of external pressure, 3) an increase of initial temperature.
By combustion of several ammonium salts in a manometric bomb (Table 2),
the author found that at P> 75 atm ammonium nitrate tablets burn evenly
without any admixture. Ammonium perchlorateNurns at p>127 atm (in
agreement with Ref. 8). An admixture of 10% MnO causes NH Clo packed
2 4 4'
into a glass tube, to burn at a rate of 0.05 cm/s at atmospheric pressure
and room temperature. The author, in collaboration with L. F. Shmagin,
showed that the same holds for ammonium perchlorate containing 5% CuCl or
CuCl 2'2H20. It is evident from Table 1 that the heats of decomposition of
NH4103 and (NH 4)2 CrO4are low. Ammonium iodate burned up completely at
increased pressure (Table 2) developing a pressure of 523 atm. On
ignition at increased pressure, ammonium chromate burned up incompletely.
Apart from green powdery Cr 2039 its combustion products contained con-
siderable amounts of the yellow-orange initial substance. Thus NH 4NO 39
Wrl"
Card 2/3

8
Intramolecular Combustion Capacity of Inorganic S/15;VZO/003/03/02/009
Ammonium Salts B016/BO55
NH4CIO4, and NH 4103 are capable of a smooth intramolecular combustion.
Data obtained are summarized in Table 1 giving calculated heats of de-
composition. There are 2 tables and 21 references: 10 Soviet, 1 American,
4 German, 1 Italian, and 1 British.
ASSOCIATION: Moskovskiy institut khimicheskogo mashinostroyeniya; Kafedra
obshchey i organicheskoy khimii (Moscow Institute of
Chemical Machine Construction, Chair of General and Organic
Chemistry)
SUBMITTED: October 27, 1958
UK/
Card 3/3

82564
S/080/60/033/06/05/006
P000
AUTHORS: Shidlovskiy, A. A., Semishin, V. I., Simutin, V. I
TITLE: Thermal Decomposition and Burning of Hydrazine Nitrate\\
PERIODICAL: Zhurnal prikladnoy khimii, 1960, Vol. 33, No. 6, pp. 1411-1413
TEXT- The thermal stability of hydrazine nitrate and its capacity of
steady burning were investigated. The formation heat of hydrazine niti?ate from
elements is 59.8 kcal/g-mole.. At high temperatures starting from 1800C hydra-
zine nitrate N2H4 - HNO is a substance with lower thermal stability than
ammonium nitrate. At 2@0 0C its ignition is observed. The.addition of potassium
bichromate to hydrazine nitrate reduces its thermal stability. Under the
conditions of room temperature and atmospheric pressure it cannot burn steadilyLK
in a pipe of 20 mm in diameter. In conformity with the theory of burning
developed by Andreyev (Ref. 16) hydrazine nitrate acquires the ability of
steady burning at atmospheric pressure in a 20mm-pipe in two cases: a) when it
is heated preliminarily to a temperature of no less than 90-1000C; b) when a
small quantity of a substance reducing its thermal stability and catalyzing
burning is added, viz., potassium bichromate. The addition of potassium
bichromate makes it possible to bum a mixture of hydrazine nitrate with
Card 1/2

82564
S/08()/60/033/06,105/006
Thermal Decomposition and Burning of Hydrazine Nitrate
ammonium nitrate at atmospheric pressure. There is 1 graph and 16 references:
3 Soviet, 4 French, 3 English, 2 German, 2 American, 1 Canadian and 1 Swiss.
ASSOCIATION: Moskovskiy institut.khimicheskogo mashinostroyeniya (Moscow
Astitute of Chemical Machine Building)
SUBMITTED: November 12, 1959
Card 2/2

KUDEYAVTSEV, Aleksandr Andreyevicb-, STEPINOV, M.N.,, starshiy nauchnyy sotr..,
kand.- tekhn. nauk, retspr.,--3nt@ --O@IISKIY@A.A. , doktor
@HIDT t$kbr
na:ak, prof.,, retsenzen-tj TANANAYN7,, I.V.., akad-9mikp prof..,-dvktor
khim. nauk a 2
,, red.; PLETNEVA, IT B., red., ALAVERDOV, Ya.G., red. izd-
va; VORONINA, R.K., tekhn. red.
(Chemistry and teohnology of selenium and tellurium] Khimiia i
tekhnologlia salons I tellura, Pod red, I.Manamaeva. Moak-ra,
Gos. izd.-vo "Vysshaia shkola,w 1961. 284 p. (MIRA 14zlO)
1. Deystvitellnyy chlen AN SSSR (for Tananayev).
(Selenb1m) (Tellurium)

SBIDLOVSKITY., A.A@; VIUMNA, K,V.
Heat of formation of sodium iodate and dichromate and of ammonium.
Aloroplatinate, Zhur. fiz. khim. 35 no.2:294-297 F 161.
(MIRA 16:7)
1. Moskavskiy institut khimicheako o maBhinostroyeniya.
(Sodium salts) Ummonium. salts)
(Heat of formation)

SHIDLOVSKIY, A.A.; SHMAGIN, L.F.
Thermal decomposition and combustion of ammonium perchlorate.
Izv&vya.uch.zav.; khim.i khim.tekh. 5 no-4:529432 162.
(MMA 15:12)
1. Moskovskiy institV kbirnicheskogo mashinostroyen:Lya..
kafedra obshchey i or qnj heskoy khimii.
Nzconium perchlorate)
(Combustion)

at
AUTHOR;
TITLE:
S/08 62/035/003/006/024
D258Y1,1302
Combustion of inorganic salts-ammonium iodate and
hydroxylamine sulfate
PERIODICAL: Zhurnal prikladnoy khimii, v. 35, no. 3, 1962, 511-516
TEXT:. The author attempted to prove that every chemical system ca-
pable of undergoing an exothermal reaction, is also able to undergo
combustion under suitably chosen conditions. A=onium iodate and
hydroxylamine Sulfate were chosen for demonstration because of
their reduced heats of decomposition and their inertness towards
ignition. Specifically, quantities of both salts were tightly
packed into glass tubes and electrically ignited. Complete combus-
tion of NH4 103under atmospheric pressure was achieved at room tem-
peratLLre only by admixing 10% of K 2Cr207 or Cu 2C1 2' The pure salt
burned only after heating it at 600C and more, prior to ignition.
Card 1/ 3

S/08 0/6 2/03 5/003/0 06/024
Combustion of inorganic D258/D30_2
NH4103 burned within 0.27 sec when ignited in a manometric bomb un-
der an initial pressure of 127 atm. Similarly, (NH 3OH)2 so4was ig-
nited in 2.0 cm glass tubes and underwent complete combustion at
room temperature and atmospheric pressure in the presence of 10,C111
Luid less of MW .2 , and especially Cu Cl combulcition
21 CuC]'2 1120 0 2 2;
without catalyst was achieved only at 100 C. These results are in
agreement with the author's supposition. There are 3 tables and
13 references: 6 Soviet-bloc and 7 non-Soviet-bloc. The 4 r.@iost re-
cent references to the English-language publications read US fOl-
lows: J. Taylor, Ind. Chem., 24, 289, (1948); R. Friedman, R. G.
Nugent, K. E. Rumbel and A. C. Scurlock, Sixth Symposium oil Com-
bustion, N.-Y., 612, (1957); W. H. Ross, Pr. Trans. Nova Scotian
Inst. Sci., 11, 98, (1902/1906) cited by Gmelin's Handbuch, 23,
(1936); P. Rossini, D. Wagman, W. Evans, S. Levin and J. Yaffe,
Selected values of chemical thermodynamic Properties, Washington
(1952).
Card 2/3
YJ

S/08 0/6 2/03 51003100601024
Combustion of inorganic ... D258/D302 -
ASSOCIATION: Moskovskiy institut khimicheskogo mashinostroyeniya
(Moscow Institute of Chemical Machine Construction)
SUBMITTED: September 24, 1960
I )
Card 3/3

S/06 0/0" 2/03 5 /004 /004/02 2
D204/D301
.MUTHORS: Shidlovskiy, A. A., Semishin, V. I. and Shmagin, ii. P.
TIME: Thermal decomposition and combustion of hydraz.-*I-ne
perchlorate
:I_*-'aIODICAIj: Zh-Lxnal -orikladnoy khimii, v. 35, no. 4, 1962, 756-759
TE@'XT: The above was studied as an extension of the authors" ear-
and N H salts. Thermochemical and physico--chemi-
lier work on NH4 2 4 U
cal properties of hydrazine perchlorate were investigated and the
preparation and analysis (iodometric) are described in brief. The
density was found to be 1.927 g/cm3, heat of solution at 298OK
9.77 kcal/mole for 1:1000 dilution, heat of formation 42.9 I:cal/mo-
le and m.p. 140.5 - 141.OOC. Sensitivity to impact and friction
was high (greater than ITH4Clo4). Thermal decomposition was studied
by heating the samples for 6 minutes at set temperatures, between
1600C (no decomposition) and 2400C (5.4% loss in weight). Fast
Card 1/3

S/080/62/035//004/'004/022
Thermal decomposition and ... D204/D-301
combustion took place at 250 0C. Comparative studies showed NH 4 C104
to be more stable to heating Addition of 55; I-InO decreased 'he
U 2 0 U
flash point of N 2 H4' Clo4from 277 - 283 to 254 - 259 0 and that of
5cl'. CuCl2caused an explosion at -1700C. Combustion measurements
showed that pure N 2 h40104burned only very slowly at room t-empera-
ture and atm. pressure but the rate could be appreciably increased
by 5cp additions of I-InO 21 Cu 2Cl2or CoO. The order of effectiveness
WIS CLI ClI)/ CoO> DInO and combustion was 2 - 3 times faster than
2 Z_ 2
that of NH4Clo 4 under the same conditions. There are 1 table and
17 references: 5 Soviet-bloc and 12 non-Soviet-bloc. The 4 most re-
cen-U references to the 'English-language publications read as fol-
lows; F. Audrielh, B. A. Ogg, The Chemistry of Hydrazine, NT. Y.,
(1951); C. Gilbert, Cobb, J. Am. Chem. Soc., 57, 39, (1935); J.
Barlot, S. Miarsaule, C. r., 228, 1497, (1949); L. Medard, Mem. de
l'artill. Franc. 2me fasc., 447, (1954).
"lard 2/3

S/060/62/035/004/004/()22
11hermal decomposition and ... D204/D301
rOy f.'21iy a
.@U"'j-'SJCIATHON: Moskovskiy -ingt'-tut khimicheskogo mashinost
(1-loscow Institute of Chemical Machine Construc-;ion)
S-L;BN'TTTED: October 24, 1960
j"
Card 3/3

SHIDLOVSKIY, A.A.
Heat of formation of ammonium selenate and ammonium hexacUor*-
stannate. Zhur.fiz.khim. 36 no.8:1773-1776 Ag 162.
(MIRA 15:8)
1. Moskovskiy institut khimicheskogo mashinostroyeniya.
(Aluminium selenate) (Ammonium stannate)
(Heat of formation)

L 17W@63

@,Fpr

,L 172-26;.63 EW Iq ED@_ Sa
* AT
'ACCESSION NH
06102 j
6@6@3 154k
..
,
3
AUTHOR f f
j3hidlovskiy, A
:
i
h i
i
!
ni
@reaations w
sigen
t
norgan
c
TITLE: a or a
oxidizi
z In
q
materials

;SOURCE: Teori a vzry*vehinLty4kh veshchastv' abornik'stateyj 19611, ij
IL

540-
U
j
TOPIC TAGS: explosive exothermic boroup: sillicont

hosphorous
p

;j"
ABSTRACT: Continuin his:- i6rk on a xploa Ive
-reactivity of waterj@64.-..-,
'

(Zhuriu
imetals (DAN SLSSR, I _g@ 0 @ 5:1 9, iy*p, 20 -.19.27) axid
9
# A
is, a, ii@xtr6zlo r6@;
'I v - 19, 1946* P. 3714 the authot :sh6wed_ water
so IT
-
active, especially at elevated temperatures with 'refteing non tal a
and metallic lower oxidei, lh.2gLothermlc @ reactidna/fbf4later .B,1
7
.
Si. or F and its oxide P205i temperatures and pressur a can be ae-:
lected which will cause combustion or even explosion In the prooess,,1-
,Similar reaction results from steam with S02.-With Metal or non-metii'
Card 1/20

k 17935-63.- -EW.Cq
VWT
ACCESSION KRt 00610543/6546
AT3006103 @P/293816316061
kiyj -A. A;
5 Id ID
AUTHOR Shidlovs
4
cons
TITIE i ExpAndin the areA.0f Oplication of-th6rm6cosmical principle of
d ng @@tave! of 1
xp@
_1 diffeiences,@ Calculation Of upknown-heate of to' rMatich - of amonim silts
SOURCE: 'Te6riya vzry*vchaty vebhdhestv 6ornik- s"tateyi 196j, W3446
a=,o@nit_u perrhenate ammonium iuA
i TOPIC TAGS: ammonium salV, 4elenate, ammon
hexachlorostannate, amnonbin *trachloropalladate ammonium bexachloro
p@at
ammonium hexafluoroaluminate, @rlnciple of constant diffe rie"Pce,
ABSTRACT: . The thermochemical @ule of constant diffi3ranoes was use&for mlc'
u
J-1atin''the h9ats of formation@6f-crystallinp. salts of stron s ha'*
9 g electrolyte v
a common anion or cation and. n@arlj equal heats of soluti -on. , USDIR potassilzi
...,.ra.mmonium salts@with identical:6nions, the [e-mail] -formatidir-of ammah
-nate hexact"iostannate- --tr-atrachloiopallad-ate !hexachloroplA
perrh, selenate,
nate and liexafluoroaluminate were calculatAd with an 'accuracy, of
% or
2 kcal/gm.equiv)..@Orig. art. has: 2 tables.andl @equatiofis.
CaM V2
-A
A.-
J!.
J-
A

@:-)HIDLOVSKIY, A.A.; VOSKRESENSKIY, A.A.
Heats of formation of strontium, lead, and silver sulfites.
Zhur. fiz. khim. 37 no.9:2062-2063 3 163. (MIRA 16.12)
1. Moskovskiy institut khimicheskogo mashinostroyeniya.

57 FNT(rn)/EWP(j
!R6032310 SOURCE CODE: UR/0081/66/000/010/V172/V173
AUTHOR:'- @hmagin, L. F. Shidlovskiy, A. A.
TITLE: The effect of the oxides of some metals on the composition of the products
of thermal decomposition$f ammonium perchlorate
SOURCE: Ref. zh. Khimiya, Part 1, Abs. 1OV148
REF SOURCE: Sb. Issled. v obl. khimii i tekhnol. mineralln. soley i okislov.
M. -L., Nauka, 1965, 112-114
TOPIC TAGS: thermal decomposition, perchlorate, ammonium perchlorate
ABSTRACT: A study was made of the composition of gases emitted during the
thermal decomposition of pure N-H Clo
4 4. During the decomposition at a tempera-
ture 240C Cl is liberated mainly in free form. As the temperature increases,
the amount of iree Cl decreases and the amount of HC1 increases. When t1ie
2 0 MnO Fe 0 Co 0 NiO d
decomposition occurs in the presence of Cr2 , 31 3* an
Cu 20, the ratio between the amount of C12 emitted in iree ?orm anY n the form
Card 1/2

L 05022-67
kcc NR- AR6032310
of HC1 depends somewhat on the chemical nature of the added oxide. An exception
is ZnO, in whose presence the amount of the HC1 formed sharply decreases. Dur-
ing the decomposition of the pure N114 CIO 4 a significant amount of N20 is formed.
In the presence of metal oxides, the amount of N20 decreases (except in a series
of experiments with ZnO). Very little N 20 is formed in the presence of MW32 and
Co 0 3, which accelerate the thermal decomposition at a greater rate than tile other
adlitives. A large part of the nitrogen is liberated in the form of NO with A1n02
and Co20 3 edditions. [Translation of abstract]
SUB CODE: 07/
:ard 2/2

p 77

AMMSION NR-. Ap4o41764 8/oOT6/64/00-V/006/1701
dim
AUMOR: Volodina) lis A* ; Shidlovskiy, A. A.; Voskresenakiy, A. A.
TITIE: Heat of formation of alkali metal chlorates.
'SOME.- Zbu=al fizichaskoy khim4ij, v. 38s no. 6, 1964P 1703-1705
TOPIC TAGS: cesium chlorates cesium chlorides thermodynamic functions calorimetryj i
alkAli cbloratep alkall chloride., explosive) chlorate, fuel
jABSTRACT: The purpose of the study was to investigate the change of the diffeyaiwe,-
16H298) Cl- AH298,C103
ifor salts with the same cation and tfie-consideration of salts of different zietali.;
It waa also of practical interest to evaluate Q in reactions of the%type
l/n Me(C103)n -1/n-MeCIn + 1-5 02 + Q'
vith fuilo dnpend-
joince, the explosive properties of chlorates.and their mixtures,
Owd 1/2

Acamw NR: APW41764-
to a great extent on the sm@unt of heat which is liberated in the decompositl:on of
chlorates. Cesium ch-lorate was the subject of this investigatione The iodaietric
assay of cesium chlorate was 98-5 %. The heat of the solution of cesium chb)rate
in water was determined in an isothermal calorimeter. The temperature meastrrements
were accurate to :t 0#002 C. The calorimeter was electrically calibrated @and the -!
time was measured with an accuracy Of 1 0-5 %. The delbirmined standard heat of the
Isolution of.cesium chl in water was AH 2 - 3-1 8 kcal/mole end the calculated'-
heat of formation of crystalline CaC.10 3 'a -9VYk'c"I le. The tabulation of the
heats of formation of alkali metal chl6rates indicates that the difference In heats'@.
of formation of oalts with the same cation am not strictly constant (10*3 1, 1*3
kcal/mole) and it slowly decreases from Zia to Co. 'Orig. art. has' 3 tables.*
ASSOCIMON: Moskovskiy institub khimlcheskogo twihinostroyeniya (Moscow Izistitute!.*
lof Machine Building for Chemical Indust
ry)
SU2bMT=: 25Nov63 ENCLI 00
SUB CODE: TD
NO FEF SoVt 006 001
Card 2/2

SHIDLOVSKIY,, A.A.; VOSKRESEN3K*I-Y,, A@A.
Heats of formation of lithitzm, strontium, lead, and silver
iodates and potassium metaperiodate. Zhur. fiz. khim. 39
no.6:1523-11526 Je 165. (MIRA 18t11)
1. Moskovskiy institut khimicheskogo mashinostroyeniya.
Submitted July 22, 1964.

m F @c)/Krc q,
10 m)/Dlp(.f /z-1P(j)/T/RjP(t) IjP(c)
;ACCESSION NR: AP502368@IPL RD71W i lp" RM UH/O0T6/65/O39/0O9/2l63/2i6'8
541-11
AUTHOR: Shidlovskiy, A, A.
TITLE: Thermochemica]J Q&n e of the ability of inorganic -ammonium and hydraziniuk
salts to sustain combustion and exDlosion:
SOURCE: Zhurnal fizicbeskoy khimii, v.-39, -no. 9, 1965, 216-2168
TOPIC TAGS: combustion solid propellant
ABSTRAM. A method was developed forlestimating the exothermal 'effect' of dtocmpo-@
sition of ammonium salts whose heats of formatin are not known@.- The auth6ri -point-..
out that ammonium salts -ghich decompose exothermally can, under cofid 0 2
sustain and propagate combustion and ex@plosio@. From the standard heats@of
Z"
of several acids it was calculated whether their-ammonium-salts can propagat..'
1 kcallo@le bet--an
bustion and explosion. A constant difference ofZT-5 a c,
do
ue*3uiun an bydraytujum 4alti-. Monvtv@t.
I heats of formation of corres;Vwtamg d.
M I
was determined. The heats of formati :,%@_t'alwdrazinium marate and dibydi
e to ftst;aj combusti The I *
determined; both compounds zuld be abl ca*
[.Card

-66
---L 1599
AM5009848 BOOK EXPLOITATION UH/
662.107),
Principles of pyrotechnics (Osnov7 pirotekhAW) 3d ed.,, rev. and enl. 11M'Oscowd
Izd-vo 'Washinostroyeniyel't 64. 0338 p. Mus., biblio.,, tables.. Errata
slip inserted- 4,000 copies printed.
TOPIC TAGS: pyrotechnicsp combustion# combustion product, combustion temperature#
oxidation,. chemical composition oxidant,, fuel, combustion mechaniM4 chemical
stability
PURPOSE AND COVERAGE: he book presents the basic principles of pnvi:
the modern methods for f6mulation and calculation of various pyrotechnical
compositions and information on their properties. In detail.are described:
the properties of components, fuels and oxidants. The physical properties
of burning processes are examined. In a separate section the properties of,
diff rent pyrotechnical compositions (illuminating,, incendiary solid =cket
fuel pmpositions) are considered. The book is a textbook for enginewring
college stitddnts. It can also be used by scientific workerep engineers
engaged in pyrotechnics and other adjacent fields (explosiveak gunpowders
rocket design).
Card 2/4

1: 3687i-66 EWT(m)/EPP(c)/EPF(n)-~/T/EWP(t)/gin~(b) IjP(,t)/RPL JD/Wi/w
ACC NR. AP5026V24-- SOURCE CODE: UR/0153/65/008/004/0,li33/053a_~'.
AUTHOR: -Shidlovskiy. A. A.- Shmagin. L. F.I. BulanovaA-Y. V..
al And 0 im a Chi
ORO: Mosdov Institute.'of ChLimi cal. Machine: Buildin of Gener rg eM4_
istrY __(Moskovskiy institutr.@ khimicheskogo mashinostrpyeniya,-Kafed@ra. obshchey A- organfa-;.'@
cheskoy khimii)-.
TITLE: The effect of some additives on the thermal decompbsiti6nq
of per-
SOURCE: IVUZ. Xhimiya i khimicheskaya tekhnologiya,, v..8. hot 4, 196% 533-13.38'.1.--:k@
TOPIC TAGS: solid propellant. oxidizer. ammonium salt
-Lon of
ABSTRACT: The purpose of this work was to investigate the thermal decomposit,
ammonium perchlorate\\(AP) in the presence of oxides, chlorides, 'carbonates, slid oixalat is
of certain metals. The decomposition was studied gravimetrically t atmospheric pres;..'
sure and 214-470C. The following values for activation ener ierAeare found: for:th6@ -
orthorhombic form, E = 40 kcal/mole; for the c ic form, E = 514-28 kcallraole:,: for the
residue from the low-temperature decomposition, 9 = 36-39 kcal/mole. Compoinids: of
manganese and cobalt promote c6mplete decomposition of AP at T -c 240C. Compounds-of
irori, nickel, and chromium promote complete decomposition of AP at 270-280C.- The r'die"
of decomposition of AP is increased by the addition of compounds of copper? a6;canesei,_-
cobalt, as well as zinc oxide; it is retarded by the addition of compounds of iron
1/2 2.2
um 66 -30

L 3667-66
ACC NR, AP5026424
bivalent nickel, chromium, and vanadium pentoxide. For the- same elemeht, the activity."
of the compounds added decreases in the folloving order: Carb6nate- (oxalate),,oxide-
chloride. Orig. art. has: 3 tables,i and 3 @figures.
.' , -:,: .'..'.. [VS1
SUB CODE: FP SUBM DATE:. i:346@w'. ORIG REF 0661@: OTH @EF: OOT/
J..

4
I Cgrd 2/2

L L6203-66 F7WT(m)/F3dP( DPW JDA*IIJWIJWD M!
ACC NR: AP6030318 @A) SOURCE CODE: UR/01531661009/003/0358/03615
AUTHOR% Fragina, A. R.; Gol ysheva, Ye. Ya.; Shidlovskiy, A."A.
ORG: 11-foscow Institute of Chemical Machine Building (Hoskovakiy
institut khimicheskogo mashinostroyeniya) IV
11
TITLE: Thermal decomposition f ammonium nitrate in the presence of
catalysts -79
SOURCE: IVUZ. Khimiya i khimicheskaya tekhnologiya, v. 9, no& 3,,
19665 358-361
TOPIC TAGS: ammonium nitrate, thermal decomposition, decomposition
catalyst, combustion catalyst
ABSTRACT: A study has been made of the thermal decomposition of
ammonium nitrate at 200-220C in the presence of 5% of such additives
as chromates of metals of groups I and Il of the periodic table,
potassium dichromate, or chlorides of various metals. The highest
catalytic effects on the thermal decomposition of NH4NO3 were produced
by L12CrO4, K2CrZO7, CUC12 and CrC13. Study of the effect of such-
binary systems as CUC104 or K2Cr2O7 and various chlorides showed that
the highest catalytic effects on the thermal decomposition of NH4NO3
were produced by the systems K2Cr2O7 + BaC12, K2Cr2O7 + MnC12, and
Card 1 / 2 UDC: 662.2.393

,i-,4Cc-N-R: AP6030318
,@CuCr04 + MnC12. It was concluded that these binary systema or L12CI704
@can be used as combustion c.atalysts 11 for ammonium nitrate-. Orig. art.
has: 3 tables.
SUB CODE: 07/ SUBM DATE: 06Jun64/ ORIG REF2 005/ OTH REF: 002
Card -2

3-1P(J)/&7(m)/ET0(M)-6/T RWVM1JWD
ACC NR: AP6012842 SOURCE CODE: UR/00810/66[039/004/0754/0758
AUTHOR: Shidlovskiy,' A. A.; Volodina, N. A,
ORG: none
TITLE: Study of the combustion of potassium chlorat@-iditol mixturen
with catalytic additives
SOURCE: Zhurnal prikladnoy khimii, v. 39, no. 4, 1966P 754-758
TOPIC TAGSj solid propellant, burning velocity, combustion catalyst
ABSTRACT: The burning velocities and combustion temperatures of
KC104-phenol formaldehyde resin mixtureal@containing Mn02, KMn04,
Cr203, COC12-6H20, C0203, and CoO as i-tives were determined. The
-kkr-jjjq&_velcLcit.y11vs. resin concentration curves showed that the burning
velocity and combustion temperature are maximum at a resin concentra-
tion of 14-18%. The addition of Cr203, Mn02, and COC12-6H20 had tKe
strongest catalytic effect among the additives tested. They consider-
ably increased the burning velocity and pdrmitted a low caloric mixture
containing only 0.8-4%*resin to burn at atmospheric pressure. Ve
h
strongest catalytic effect was experienced when the additives were
present in concentrations ranging from 3 to,5%. A stoichiometric
Card 1/2 UDC: 546.32tl35+541.126+541.183

n v

SHIDLOVSKIY, A. B.
"Transcendental Quality and Algebraic Independence of the Values of Entire
-Funciions of Several Classes." Cand Phys-FAth Sci, Moscow State U, Moscow,
,-a953..-; WhMat, Jan 55)
-------
Survey of Scientific and Tedhnical Dissertations Defended at USSR Higher
Educational Instiutions (12)
SO: Sum. No. 556, 24 Jun 55

SPIDL-OVSKIY.., A.B.
Shidlcvskiy, A.B.-- "Transcendence and Algebraic Independence of Values of Whole
Functions of Certain Classes." Cand Phys-Math Sci, Mechanics-Mathematics Faculty.,
Moscow State U., 22 Jan 54. (Vechernyaya Moskva, 17 Jan 54)
SO: SW 168, 22 July 1954

USSR/Mathematics E functions
Card
Authors Shidlovskiy, A. B.
Title About the transcendence and algebraic independence of.values of
integral functions of certain classes
Periodical Dokl. AN SSSR, 96, Ed. 4, 697 700, June 1954
Abstract Siegel's method is described for arithmetical evaluation of certain clan- -
es of integral functions. The-functions are called E-functions, provi-
ded they satisfy linear diffirential eqs; coefficients of-which are
polynomials in Z with numerically Algebraic quantities. The author
points out that Siegel's method can be applied to the,E-funations, satis-
fying both homogeneous and heterogeneous diff. eqs-j:and even@specifilca_
tions for the E-functions can be made less restricted. Three references.:,-
Institution The V. I. Lenin State Pedagogical Institu,te, Moscow, USSR
Presented by Academician P. S. Aleksandrov, March 26, 1954

Authors 3 Sh;.dlovslciy, A.:3-
Title I About the criteria for -th(! algebraic independence of values of a
certain class of f uiiations
Periodical i
Dok. AN SSSR 10012, 221-224, Jan 11, 1955
Abstraot I Necessary and sufficient conditions are sought for. the algebraic-
independ.erice.of values@of a clas,s of certain functions. The E
functions belong to.that:cla .ss. The definition of the E@ functiorls;@
is given in the DAN 96/@.- On the basi's of that. de,finition'the
following theorem is proved.
Institution V. 1. Lenin State Peda- gical Institute
.10
Presented by t Academician S. L. Skot-elev, November 16, 1954

Periodical Dok. AN SSM 100/2, 221-224, Jan 11, 1954
Card 2/2 Pub. 22 V52
Abstract If a set of E-functions f .... represents a solution ofm
linear diff eqq of the first order
yw-
, 41 e!) Y-1
the coefficients of which A; t: 4z),# @ht ra /Z' a
4
are rahc@;ai functions of. z with algebraically numerical
coefficients, andq any algebraic number different from zero
and the poles of the functions. Then, in order
numbers of fike), ((A) are. algebraically indetendent. It is
necessary and sufficient that the, functions /-(Z)
be algebrpically independent over the field of rational functions
in Z. Application of this theorem to Bessel's functions is
discussed. A series of theorems is proved in order-to give a nor.e
concept of the theorem. Four references: 3.Russian; 1 German
(1929-1954).

SHIDLOVSKIY, A.B.
Transcendental numbers of certain classes. Dokl.AN SW-M 103 no.6:
977-980 Ag 155. (KW 9:1)
1.Moskavskiy gosudrtrstvennyy universitet imFjnj H.V.Lomonosova.
Predetwleno akademikom F.S.Alekoandrovyms
(Numbers, Transcendental)

gidlovsWA.B. Gvtr4ns~ewdentmUtvof--Ihe,valuetoff
class of
jatWng linm
:x a serles -A papcr-j by the author safog
-%C. 160 @?551%, 2-2 C-2 i
-2
6, 7:17. -C` 4661 exteiidinq
Trar
icend-nt@! mimbers.
Nflix 11. or. E-functiins. The
art 2-III-10LIfIced: 1 Let the E-functioa
j(:i be a solution of the linear differential equation,
- .-7Pj(z')y'-j-Pa(z)y=Q(z), whose coefficients
P,kz) and @)kz) are polyuornia_ls in Z with algebraic nu-*
ine.tical coefficients, and let m be an algebraic number
d@ifcrcnt from 0 and the zerus of Pg(Z). Then the I number-s
i = 0, 1, 1- 1. are algebraically in-'
dependent if and only if the functions 101(z), i=O,
1-1 are algebraically independent over the field of
rational func*ions of x. 11. If a function / as in I is trans- L
cendental, and if a-7t-O is algelifaic and-nota zerc of Pm(;),!
then the nunibers fffy(ac), i=O, -1, _ake,_ W1
and all zeros and all A-values of f and aff its derivatives
Z 'If
except 0 and the zeros of P,.(. are transcendental for,

I T , '. - .
.@ 0, 1-
II I

Call Nr: AF 1108@@5
T-ransactions of the Third All-union Mathematical Congress Moscow,
- ul fye'5()' V. 1, Sect. Rpts., Izdatellstvo AN SSSR, Moscow,/I 56. 237 pp-
@Rn , ci6,9T@ud
;r@e axre e re&es, 6 of whIch are USSR, 2 English, and-"
Geimian.
Freym,an, G. A. (Kazan'). On one Elementary Method of the Theory
of Numbers and the Theory of Probabilities. 14
Chudakov, N. G. (Saratov). Classification of Characters of
Number Semigroups. i5_16
Mention is made of-Bredikhin, V. N. and BronBhteyn, B. S.
Shidlovskiy, A. Bi,(Moscow). One one Class of Transcendent. .15-:L6
There are 4 references, 2 of which are USSR, 1 English, and
1 German.
Algebra Section
17-41
Card 6/80

SHIDLOVSKIY A.B.
New criterion of the transcendental nature and algebraic indepon-
dence of values assumed br a class of integral functions. DokIj.
AN SSSR 106 no-3:399-400 Ja 156. (MiRA 9:(;)
1.Moskovakiy goeudarstvennyy universitet imeni M.V.Lomonosova.
Prodstavleno akademikom L.I.Sedov7m.
(Functions) (Numbers, Transcendental)

)VS K'
@)l DLL
SUBJECT USSR/ITATHEIUTICS/Algebra CARD 1/2 PG - 43@-
AUTHOR 9IDLOVSKIJ I.B. '
TITLE On the algebraic independence of the transcendent nilmberE; of
a class.
PERIODICAL Doklady Akad. Nauk 108 9 400-403 (1956)
reviewed 12/1956
The author proves some theorems on the algebraic independence of certain
general hypergeometric E-funations (see: gidlovskij, Doklady Akad. Nau-k 105,
No,i (1955)) which are solutions of certain differential equations. The proofs
base on a result of Siegel (Abh. Preuss.Akad. Wiss. 1,10-1,L 70 (1929-30)) which
4s improved by the author.
Let 00
kn
Vk (z) k k=1,-jr r>/1
(ni) k
n=o
and
00 kn
(Z) = 1 Z . -- ( -a ) k-l,...r; r@;,1; s=1,..-,mkj mk>,k.
A@k,s n-1 r(n.-!)! ]cns k
""yk,k(z) -Ark(Z) and these functions are so lutions of the system
i ) - 1 s-2,3,...m
*,S(Z) z k

Lo
519 1.
:41
.111! v
1.4
91
rx
Igo A
;R, I i I
9.
it a 1 40"

SHIDLOVSKIY, A. B. Doe Phys-Math Sci -- (diss@ "On one class of transcendental
nmbers." Mos, 1959. 12 pp (Kos Order of Lenin and Order of Labor Red
Banner State Univ im M. V. Lomonosov), 150 copies. Bibliography: pp 11-12
-L/
(40 titles) (KL, 47-59, 112)

16(1
AUTHOR: -ShIlidlovskily, A.B. SOV/38-21-1-2/6
TITLE: On the Cr-itericri of the Algebraic Independence @-"' the 7alues
lif Entire Functions of a Class(C- kri @erii algebrai-@'Ao@j!;v,,r
neza@,isimos-,'-,i znacheniy odnogo kiessa tsel.-kh iunktsly)
I
PERIODICAL: Iz-7estiya Akadem-.i nauk SSSR,, Seriya matematicheskaya,1999
Vol 23, Nr 1, pp 5q,-64) (USSR)
ABSTRACT: With the aid @jf 12 lemmas the authsr proves the results
announced by him in Z-Ref 8-7 -
Principal theo.-,em: Let the E-funntions (Zompare Slegel
,@-Ref 1,2
-7) f,(z),...,f.(7,) be the solutions of the system
M
yj = Q (Z) + Q (7,)Yi k
kv o k, i
Let the Qk (z) be rational fun--tions of z. '-etr/- be an
algebraic Aumber different from 0 and from the poles of the
qk,i (z) . In order that the numbers f 1 (OL) 9 ... 9 fM(-.L) are
algebraically independent it is necessary and sufficient
Card 1/2 that f1(z),...,fm(z) are algebraically independent over the

on the Criterion of the Algebraic Independence SOV/38-23-1-2/6
of the Values of Entire Functions of a Class
field of rational functions. Theorem: Let the E-function f(z)
be a solution of
Pm(Z)y (m) ...... Pl(z)yl+ POWY = Q(Z)
where Pi(z),Q(z) are polynomials. Let otbe an algebraic number
different from 0 and PM(c4) / 0. In order that f (00 1 f 1 (-11) 1 - -
.., f(M-1)(c-') are algebraically independent it is necessary
and sufficient that f(z), f,(Z),..., f(M-1)(z) are algebraically
independent over the rational function field.
There are 8 references, 3 of which are Soviet, 3 German,
1 French, and I American.
PRESENTED: by I.M. Vinogradov, Academician
SUBMITTED: March 20, 1958
Card 2/2

SaIDLOVSKIY, A.B.
Transcendency and algebraic independence of the values of certain
classes of entire functions. Uch.zap.Kosk.un. no.186[a]:11-70
'59. (MIU 13:6)
(Functions, lintire)

86397
S/055/60/000/005/003/010
1000 C111/C222
AUTHOR. Shidlovskiy, A.B.
TITLE;,, On the Transcendence and Algebraic Independence of the Values of
E-Functions Connected by an Algebraic Equation in the Field of
Ratio-n-a-1--yunctions 16
PERIODICAL; Vestnik MoRkovskogo universiteta. Seriya I, matematika,
mekhanika, 1960, N0@5, pp.19-28
TEXT4 The paper is based on the author's publications (Ref.1,2),
An assertion is satisfied for almost all algebraio values 0@, if it is
satisfied fo-r all algebraic values cK, with a probable exception of finitely
many ones.
Theorem 1; Let the E-functions fj(z),---,f.(Z), M.>1, be solutions of the
linear homogeneous system
(1) Y; = @-,'lk iyi
1=1 9
Let all Qk,i be rational functions of z not connected by a homogeneous
algebraic equation the coefficients of which are polynomials in z. Then
Card 1/4

86297
S/055/60/000/005/003/010
C111/0-222
On the Transcendence and Algebraic Independence of the Values of E-Functions
Connected by an Algebraic Equation in the Field of Rational Functions
each of the numbers f,W,,,,fm (cc) is transcendent for almost all
algebraic values 6@,-if the corresponding function fj(z),-,fm(z) is
transcendent.
Theorem 2: Let the E-function f(z) be transcendent and a solution of the
equation P yH+P y!+P y - 0, where P P,9 Po are polynomials- in z. Then
2 1 0 2' !
f(c-,,) is transcendent for almost all algebraic values 0(,.
Theorem '3 cc-nsiders E-functions f (z), m,@--2, which are solutions
of
(7) Y, +5m q
k k,o i-I k,.iyi
whexe qk,i are rat-ional functions of z; it is assumed that the fiare
3onnected with each other by the relation
(B) P[fm(z),,,9f,:(z)] - 0,
Card 2/4

86P7
S/055/60/000/005/003/010
C111/C222
On the Trnascendence and Algebraic Independence of the Values of E-Functions
Connected by an Algebraic Equation in the Field of Rational Functions
where P is a polynomial with coefficients rational in z;it is shown that if
P satisfies certain special conditions, and oC avoids certain finitely
many values, then the numbers fj(oC),...,fj(.C), are algebraically
independent.
Theorem 4: Let f(z) be a solution of
(18) P y(m)+...+P Y'+P ym>
M 1 0 ,2,
where Pm 0-vp0and Q are polynomials in z. Let m-1 be the maximal number of
functions f(z), fl(z),,..,f(w'-')(z) being algebraically independent over
the field of rational functions where
(19) P[f(z), f'(z)'-'f(M-1)(z)j - 0,
where P is an irreducible polynomial of degree k:?,l with coefficients
being polynomials in z.
Then: 1) in P there exists a term with coefficients M different from zero,
Card 3/4

86197
S/05 60/000/005/003/010
C1 1 IYC222
On the Transcendence and Algebraic Independence of the Values of E-Functions
Connected by an Algebraic Equation in the Field of -Rational Functions
which contains f(M-1)(z) in the k-th power; 2) in every algebraic point De.
different from zero and the zeros of Pm and M, the m-1 numbers f(C(')'f'(0Q'.-
..If(M-1) (I,-) are algebraically independent.
Theorem 5 generalizes theorem 2 to the case where the E-function is a
solution of an inhomogeneous equation of second order,
There are 4 references. 2 Soviet, 1 German and 1 American,
rAbst:r:%cter's note: (Ref.1) is a paper of the author in Doklady Akademi-i
nauk S6SR, 1955, Vol,100, pp.221-224; (Ref.2) is a paper of the author in
Izvestiy kkademii nauk SSSR, Seriya matematicheskaya, 1959, Vol.23,
PP,35-661
ASSOCIATION: Kafedra matematicheskogo analiza (Chair of Mathematical
Analysis)
SUBMITTED; January 3, 1960
Card 4/4

-*"-'--' . A .13.
Trap-seendc-..-cc .nC, algebraic independence of the values of
E-functions. l'osh. ,i-a. Ser. 1: -@A lj@-
no.5:44-59 S-0161. @-IapurL 1,/:11)
1. Kafedra toorii chisel Moskovskogo universiteta.
(F-unctions)

SHIDLOVSKIY., A.B.
Generalization of Lindeman's theorem. Dokl.AH SWR 138 no,6:
1301-1304 Je 161. (MMA 14:.6)
1. Moskovskiy gowidarstvennyy universitet im. M.V.Lomonosova.
Predstavleno akademikom P.S.Alek-sandrovym.
(Functions, Transcendents.34

SHIDLOVSKIY, A
On the transcendence and algebraic independence of the values
of E-functions related with any tumber of algebraic equations
in the field of kational functions-, Izv.AN SSR.Ser.mat, 26
no.6:8?7-910 N-D t62. (MITRAL 19-7n@
(Functions, Transcendental)

NILYAKH,.A.N. [Mliakh, O.M.] (Kiyev); SHIDLOVSKIY, P..K. [Shydlovollcyi, A.K.]
.....
(Kiyev)
A static converter of a single-phase system td-a symmetrical
three-phase system. Avtomatyka 7 no.6t4O-47 162. -(KMA 16:1)
(Phase converters)

/D Z-o V-S)
AUTHORS:
TITLE:
S/102/62/000/004/006/006
D201/D308
r'-';'RTGDj0A7
11.1ilyakh, 0. M., and Shydiovs'kyy, A. K. (Kiev)
A three-phase filter for symmetrical components
based on a multi-phase transformer with rotating
magnetic field
Aytomatyka,'no. 4, 1962, 60-70
T'-,',XT: The authors describe a three-phase filter for symmetri-
cal components based on a multi-phase transformer acting as an
asymmetrical filter. A unity transformation coefficient is as-
sumed, a symmetrical voltage system being.applie'd to the input and
a symmetrical load at the output. Owing to the symmetry of such
a system, one phase only is mathematicaliy and experimentaliy'
anaiyzed and expressions derived for the determination of filter
-parameters. The asymmetrical filter-transformer consists of a
three-phase asynchronous motor with phase braking of the rotor;
the axe's of the phase windings of the latter are shifted with
Card 1/3

S/102/62/000/004/006/006
A three-pha8e filter... D201/D308
respect to the corresponding stator windings by 90 electrical Ide-
grees. The filter may be used for separating out symmetrical com-
ponents of the direct and reversed phase sequences. A system of
voltages of -the separated sequence is obtained at the filter out-
put. The symmetry of this sequence is independent of.both the
value and character of the symmetrical load. Owing to the magnetic V
symmetry of the multi-phase transformer windings acting as an
asymmetrical filter, the unbalance voltage is practically independ-
ent of manufacturing errors. It is concluded that there is a pos-
sibility of designing a new class of filter for direct and reversed
C,
phase sequences. The advantages of such a filter are as follows:
(a) easy and simple adjustments; (b) the possibility of reducing
to zero the unbalance voltage due to the assembly inaccuracies,
which makes it possible to disperse with additional elements of
control; (c) stability of the filter parameters, irrespective of
whether it works with direct or reversed sequence; (d) independ-
ence of the symmetry of the system of the magnitude and character
of the symmetricpl load; (e) easy design for any power, voltage
Card 2/3

S/102/62/000/004/006/006
A three-4phase filter ... D201/D308
or current, which makes it possible to apply the filter in power
installations. There are 8 figures.
SUBMITTED: March 20, 1962
v
Card 3/3

nz;.
lrj)

MILYAKH, A.N. [Miliakh, 01M.]; SIIIDLOVSKIY, A.K. (Sh-ydlovslkyi, A.K.]
Reciprocity of the single-phase equivalent of a three-phase
qnmetrical circuit. Dop. All VRSR no,6:765-768 t63 (MIRA 17.-7)
1. Institut elektrotekhniki AN UkrSSR. Predstwrleno akademikom
AN UkrSSR K.K. Khrenovym [Khrienovp K.K.I.

SHIDLOVSKIY, A.K._[Sh*lovslky-i, A.K.] (Kiyev)
Reciprocity and irreversibility of a transformer with a rotating
magnetic field. Avtomatyka 8 no.1:67-69 163. (MIRA 16:3)
(Electric transformers) (Automatic control)
r
I

KAPICHIN I.I. [Kapichy-n, I.I.] (Kiyev); SHIDLOVSKIY. A* KI .
1--- .1
1-shYdlovsIkyI,*A.K-.]'(KiyeT) , @ z . t.
II
Schematic for the transformation of a single-p4ase system into a
,,,two-phase system. Avtomatvka 8 no.2:76-79 1,63. (MIRA 16:5).
(Automatic control) (Electric networks)

L 21608-65
ACCESSION NR: AP5003856

ASSOCIATION: none

suBmiTTF.Dt-o3mny6
3
'ENCLi 'SUB'
CUDS, @-Il
, .
NO RFT BUVs 003 OTHkRt

Card 2/2
7 @7@7! --777

MILYAKH, A.N. (Miliakh,, O.M.1; SHIDLOVSKIY, A.K. [Shydlovs'k-yi, A.F.]
Theory of a two-phase electric circuit. Dop. AN URSR no.8:
1046-1049 165. 04IRA 18:8)
1. Institut elektrodinamiki AN UkrSSR. 2. Chlen-korrespondent
AN UkrSSR (for Milyakh).

MMAKH, A.N., doktor tekhn. ntuk; SHIDLOVSKIY.,.A.K... kand. tekhn. nauk;
14JZYCHENKO., A.D., inzh.
Balancing features of current compensation networks with inverse
sequence. Energ. i elektrotekh. prom. no.4:27-29 O-D 165.
(W RA 19: 1)