SCIENTIFIC ABSTRACT SHEYNKER, YU.N. - SHEYNKMAN, A.K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549330010-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

FREOBRAZHEKSKAYAl M.N.; UVAROVA, N.V.; SHEYNKER, YU.N.J'SUVOROV, N.N.
Syn-anti-isomprism of 3-aryl hydrazones of 6-mathyl-2,3-piperi-
dinedione. Dokl. AN SSSR .148 no.5slO88-1090 F, 163. (MM 16:3)
1. Vsesoyuznyy nauehno-issledovatel'skiy khimiko-fgrmntsevtichaskiy
institut im. S.Ordzhonikidze i Institut khimii prirodnykh soyedineniy
AN SSSR. Predstavleno akademikom M.M.Shemyakinym.
(Piperidinedione) (Hydrazones) (Isomerism)

DVORYANTSEVA, G.G.; STRUCHKOVA, M.I.; SHEYNKER, Yu.N.
Integral intensities of infrared absorption bands of certain
characteristic vibrations of cyclopentadienyl rings in ferrocene
derivatives. Dokl. AN SSSR 152 n0-3:617-620 S 63.
(KRA 16:12)
1. Institut khimii prirodnykh soyedineniy AN SSSR. Predstavleno
akademikcm A.N.Nesmeyanoiryu.

yj co'. t,~!- 7 i'.;V
r,- nni 6:, rec,
a p 0 1, z i n e Y, ma, t c, 6 air, i s-:1 Id, j v an'. i a o r Pa r,
1. Sc-v-:.,2n--rianiv.v vo fiziche. skim mercida:m, issledo-vardya
r,--ganiQtF-sl,ixh sovedinen-V i khill-ldc tie skikh -protsessov.
Fru.nz-a, -1c)62. 2. instit,-4. -crvr--dineniy
A,"'l --j-A, Lenirlgrad (for Vollkenshteyn). 3. lnst4t~;t k-h-Jlilli
r
priorc,rQikh soyredineniy ~!,' ,;'SS'A, T-,cI,3kva She"In"er".
Kazi ill i~ dar--Ivpii!,.-y un*,;;-,~ ti~et ~.a C!
gosu z --i f
mizov . c. Inati'at crp-cnesk,Dy kh4--,J
('-)r Afar~aslyev).

and
zv i r il L, :Irj, 5:80~-W,3
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PERELISON, M.Y-c.; SHEYNKER, Yu.U.; DMITRIYEVA, N.D.; LUKIYANETS, Ye.
A.; SITOSHERINA, N.P.; LEVINA, R.Ya.
Integrated intensities of C=O bands in the infrared spectra
of substituted'a-pyrones. Izv. AN.SSSR.Ser.khim. no. 5:938-
941 My 164. (SERA 17:6)
1. Institut khimii prirodnykh soyedineniy AN SSSR i Moskovskiy
y universitat im. M.V.Lomonosova.
gosudarstvennr

YAGUDAY-EV., M.R.; POPOV, Ye.M.; YAKOVLEV, I.P.; SHEYNKER, Yu.N.
Frequencies and intensities of infrared absorption bands of
the stretching and deformation vibrations of the 11R, group in
primary amines. Izv. All SSSR Ser. khim. no.7:1189-1196 Jl 164.
(MIRA .1-7:8)
1. Institut khimii prirodnykh soyedineniy AN SWR i Institut
organicheskoy khimii imeni Zelinskogo AN SSSR.

4/Pr-4 ASD(m)-3/A:S(m .p 5D
L 10666-6~ EWTW/FPF(C)/tv4P(j) PC.--
RP.wr RM
(,ACCEMM DR: AM41155
AUTHOR: Dw
MMptqtM, G. G.-_Shenker Yu. N..j, YU Sme anov
A. N. (Academician-I'
TITLE--- ~s Us~g the structure of several Isomeric disubstituted ferrocenes
by their IR absorption apectras
SOMCE: AN SSSR. DoklaW., v-q'.1561 no* 4.. 1964,p~873-876.
ILVPIC TAGS: ferrocene disubstituted fdrrocenq.,~ structure.. IR, ape a
etraj, alkylferro-
cenylamidej, alky1ferrocenylaitrile pheny1ferrocenylazild rroc trilA,
phew1fe enylul;
NH sub 2 absorptioa., regiono isomer, spatial hindrance,, spectral
integrai intensity
AWYNAM. The IR absorptioa spectra of several alkyl., aid #fteny2ferrocw#1audde
Of lbba.
ad &WIferrocenyinitrilea vere e=mined to datemine the,strtwture'
i isomers. There am differences In tbe absorption in the 910-9w region in
I mono- or heterocyclic d1substituted. ferrocenes and in pairs of howeyelic dimzb-
stituted isomers, but because of difficulties in Identifications In this region*
an intensive examination vw made of the frMeney and Intensity abaraicteriatic of
the CzO and NH2 grmyse la the 112-isomers tbere am dIfferewes In the 2600-
~crd
~

L lo666-65
ACCMSMCff n: 'AP40411.55
f (C ZO) and 3100-3500 cm-' W2) regions: -the band for the-defomed ~:vlbratlon~ ok
v 46 Utting of t114 bands
the NH2 group OPlit'i Olmultaaeous4y vltlx a dec' As 'A the V
!in the region of the NH valeacy vibrations; the spectra coatoAn absorption bands
Ifor both free and bonded NH-groupe. In the ls3-19owere of
and phenylferrocenylamide there is not splitting of the, .4% ba6d (in the corn
ponding ethyl derivative the slight splitting is explained-by the,effect of the
ethyl radical on the amide groupT. The spectra of the 1.,3-isomers in CCJ4- am
somevhat al-11 to spectra of solutions of the corresponding 1011-derivativesi
i
they have no bands characterizing bonded NE-groups. The Ismars -differ in-the
integral intensity of the caxtoxyJAe_AmiAe,.group. The ethyl group In the 1j11
and 43-isomers increases the integral intk-nsity in comparison to that of the ua-.-.~
substituted ferrocenylamide. In the 112-isomersp-methyl d~md ethyl substituents do-'
not cause this increasej, apparently due to loss of c9nJugatica of the amide grov
-with the cyclopentadienyl ring because of spatial, hindrances These conclusions
about the structure of these compounds based on IR spectra ~Lre In agreement lwith~ -a.
;oxidation-reduction potentials, UV spectra and comparative adsorptions on A
Further studies axe being couducted., Orig. art, -has,. 2--tsbles~ and 2 figures,,
'k SM
pri=dny*kjj Soy~~ Ak#4eUj:U _nijj._
JA&WC1=Cff: Inatitut k-114-14
i Car
L

L "2565!-65
ACCESSION NR: AP5015797
+
C H )'3PCHC01QHal were found to possess froq~encieil of i1ii, end4
6 5
R
vibration of carbonyl close to the known values of 'the-fre~uehoies for
a li''A' - * `Ij
;Saturated carb*onyl-containing-compounds, o sp
1(C6H.5)3P-CRj-Cd-R, the position of the absorption band of carbonyl was**
shifted 100-180 cm into the low-frequency region.. The intensities of\
the carbonyl bands in the spectra of acylmethylenetripheaylphosphoranes I.-
!were substantially increased, while in the spectra of the salts they
were somewhat lowered in comparison with the normal values. The data
Jobtained agree with an ylide structure of i'Lcylmethylenetripheimylphospho-1I
rauea, in which the polarity of the C-0 groups is greatly increased, and,,
-the negative charge is localized to a considerable degree'on*the ox
h
rather than on the ylide carbon, 48 in akk
oranesC Orig
arts.
has 1 q, graphs, and 1 table.
ASSOCIATION: Institut khimii prikodnykh Akademii nauk S~SR (Institute
soyedineniy
of the Chemistry of Natural Compoundsl Acade= of figlAnces.- SSSR)
L: 00 -SUB CODE: OCt OP
SUBM O6Feb63
NO REF- SOV; 003 OTHER: 012 JPRS
,d 2/2

SHEU,KEF, Yu.N.; SITYAV EA
I i ~, L. B.
Position and the intensity of anti symune t-lical strete' ig lbard
of the 11 group in the infrared spectra -f' organic azides.
Iv,r. Aft 2SSR Ser. khim. no.11:2113 11 104 (MIRA 18:1)
1. Institut khimii prirodnykh soyedineniy AN SSSR.

FERESLENI, Ye,M.3 SHEYNKER,,-YU.N.
Tautomerism of some derivatives of heterocyclic compounds.
Part 15. Zhur. fiz. khim. 38 no.9;2152-2157 S 164.
(WRA 17:12)
1. Vsesoy-uznyy nauchno-issledovatelOskiy khimiko-formatsevti-
cheskiy institut imeni Ordzhonikidze, Moskva.

F'-,-K, C,.Yu.; PEREL'SON',
reqcnEnre mjectni of natural c(~Umar',!:s
S SE! 0
and Loki. AN R '15F. C IIE~4.
(MIRA 17;12)
1. prirodnykl,, soyedineniy AN SSSR -J Vsesovu ryy
lekdrs,.vernykh I arcmatJcheskfkh rusten'y. Predstavleno
M.M. Shemyak~Jnym.

PERETISO'll NIKONOV. ",K.; PEK,,. G.Yu.; SUMM, Yu.N.
, u
of xanthogalol and zosimol. Dokl. AN SSSR 159
N 161 (W-RA 17ti-2)
L..
1. Veesoyuzryy institut. lekarstvemnykh i aromaticheskikh
rasteniy _3 Instit"'It, kh-JrL4-i pr-4rodnykh scyed.-1neniy AN SSSR,
Pre,4stavieno akademikom M.M. Shem-fakinym.

- Yu.l;.; -,-,,A'.TSTsV, B. Ye.; PERELISCN, M. Ye.
integral intensities of carbonyl bands in the infrared spectra
of some cyclic compounds. Izv. AN SSSR Ser. khim. no.l-lt2ll4
N 164 (MIRA 181i1)
1. Thstitut khimii p.-irodnykh soyedineniy AN SSSR i Vsesoyuznyy
Lnetitut leknz-stvennykh i aromaticheskikh rasteni.y.

11MMEYMNOV. A.N., akademik-, DITORMITSEVA, G.G., KOC;HETKOVAv
M~3RTXOV'fi, R.B.; SHEMMI L4.N.
Properties and s*.-"Uctu--- of dicyclopentadienylmermary. Dok-L.
AN '175-SR 159 no.,/a8.1,?-850 D 161, (M-M 18-.1)
1. Thstltut elementaorgani.-heskikh soyed-Inen-ly AN

PERESMU, Ye.M.; SHEVIKER, Yu. N.; ZOSE4011A, N.P.; P%IMWJTSKV, Yu.1.
(Moskva) -1-1-
fautome.r-f-qw ov'zroww P3 z=sj&tMdR,
SLwpz.r-