SCIENTIFIC ABSTRACT SHCHUKIN, YE.D. - SHCHUKINA, L.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548920016-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

t :7-_~
L 45,214-65 Ei ri (m JD Z_
p jjp(a)
ACCESSION NR: AP5007664 1357
01
AUTHOR: Shchukin, Ye D Zanozina Z. 14., Kochanova, L. A., Likhtmant 10,
Rebinder, P'K- 1-c- -an
'TITLE: The possibility of preparing alloys,with a highly'dispersed structure by
'hardening alloy emulsions
::SOURCE: AN SSSR. Doklady, v. 160, no. 6, 1965, 4355-1357, and insert.facing
p. 1333
TOPIC TAGS: alloy structure, alloy emulsion hardening, zinc alloyi
_jga4_.glloy, tin alloy, cast alloy
q,
ABSTRACT: The authors studied the possibility of controlling-the.at:iuctural dis-.
persion of a solid prior to its formation from an emulsion with low interphase ten'-i'
sions, using the Zn-Pb-Sn system as a convenient, readily melting, model (see-Fig.
1 of the Enclosure). Samples with N 99.99% Zn, Pb and' Sn and having a combined
weight of 40 g were intensively miiie-d by vibration, and heated, in.tightly closedp
cylindrical 70 x 20 mm steel crucibles, to temperatures 50-100C higher than that of:
the liquid-phase stratification region. Then the temperature was reduced to a se-
lected point (Tl) within the stratification region. ALf ter maintaining the tempera-~
ture for half an hour to achieve equilibrium the crucibles were cooled at a rate of.
Cord 1/3

L 432-14-65
ACCESSION NR: AP5007664
15C/sec to the ambient temperature and cut along the cylinder generatrices. The
metallographic sections, prepared by electrol tic etching frou-the halves of the
casts, were then examined with an HIM-8 microscope. The different structural p4t-
terns obtained in several series of experiments, by varying-Tl, the'concentration i
of and the ratio between the components, are believed to Ladicate.a, possibility of -I
effectively controlling structural patterns by this method. Orig. art. has: 4
jigures.
,ASSOCIATION: Institut fizic'haskoy kbimii Akademii nauk SSSR (Physical Chemistry i
~Institute, Academy of Sciences, SSSR)
ISUBMTTED: 26Sep64 EML:'. 01 SUB COD91. NK
NO REF SOV: 002 OTHER: 002
C,,d 1/3

L 4321k-65

L-1_07_71-66_ _ __ E'ViT(T)/qPF(n)_-?/T/El,'IP(t)/EliP(z)/ElfiP(b)/EViA(d) ijp (c) "11/WW/HW/-TG
ACC NRt Ap5027140 SOURCE CODE: UR/0126/65/020/004/0555/056 L",
AUTHOR: Kochanova; L. A,; Zanozina,,Z. M.; Shchukin, Ye. D.; Likhtman, V. I
Rebinder,-P. A. I Y,
ORG: Institute of Physical Chemistry AN SSSR (Institut fizicheskoy khimii AN SSSR)
TITLE: Use of emulsification for refining the structure of alloys with a limited
solubility of components in the liquid state q~' 5'6- 1% i
SOURCE: Fizika metallov i metallovedeniye, v. 20, no. 4, 1965, 555-560
10PIC TAGS: alloy, alloy structure, structure refining, alloy emulsification
ABSTRACT: An attempt has been made to refine the structure of alloys whose components
have a limited solubility in the liqtddqtate by emulsification, i.e., vibration applied
at tqper~tures above the liquidus curve. The experiments were carried out with
1~n-05JSn'allovs melted from com nents of no less than 99.99% purity.l'iThe crucible
P
19
containing 40 g of molten alloy1metal was heated to a temperature 50-100C higher
than that of "layerfn-g"and subjected to intensive vibration, then cooled to a tem-
perature below that of layering, held for 30 min, again subjected to vibrationl(and
water cooled. It was found that this treatment produced a fine-grained alloy strue
ture, especially when final vibration was applied at 400-600C. This opens the
possibility of using colloid chemistry in the field of metal science to control
the structure of alloys. The experiments should be expanded to higher melting alloy5
Card 1/2 UDC: 548.5

L 10771-66
ACC NR. AP5027140
such as Cu ~U-Mo, Cu-Cr 4using nickel and-ironias-the-third component in order
to lower the interphase tension. Orig. art. has: 4 figures. [AZ]
SUB CODE: l1/ SUBM DATE: 200ct64/ ORIG REF: 003/ OTHREF: 002/ ATD PRESS:
-4

rn C- A
ACC NR: -~P6020908 SOURCE CODE: UR/0369/66/002/002/0133/0142
AUTHOR: Shchukin, Ye. D Yushchenko, V. S.
ORG: Institute of Physical Chemistry, AN SSSR, Moscow (Institut fizicheskoy khimii
A N SBMr)
TITIE: Relationship between the selectivity of adsorption-induced strength
deterioration under the effect of liquid metals and interatomic reactions
714
SOURCE: Fiziko-kIiimicheskaya mekhanika materialov, v. 2, no. 2, 1966, 133-142
TOPIC TAGS: metal surface, metal melting, liquid metal, ductility, electron
structure, phase diagram
ABSTRACT: Adsorption-induced reduction of the free surface energy of solids
the solid-gas or solid-liquid interface and its effect on the processes of
deformation and fracture of solids are two of the main problems of the
physicochernical mec
,panics of materials. Liquid metal-induced embrittle-.
ment of solid metals) is of particular interest, since it represents a case o1
relatively "pure" adsorption effect, physically reversible and free from
(for
at
instance, general corrosion in the case of
accompanying phengmena
stress corrosion). ~%Tfte se phenomena have been studied thoroughly and there-
fore riip--resent the easiest direction for further research on the nature and
mechanism of the adsorption- induced intensification of deformation and

L 0446M7
A(f~__N'__R:___A,P6m0908
fracture of solids.
The effect of molten metals on mechanical properties of solid metals
has been the subject of intensive studies by Soviet and Western scientists
during the last decade. Many of these studies have shown that the character
and intensity of the phenomena resulting from the adsorption- induced reduc-
tion of free surface energy depend on numerous physicochemical and mechan-
ical factors. These factors can be divided into three main groups: 1) factors
closely related to the interatomic reactions, such as chemical composition of
solid and liquid phases, affinity of componerts with each other, and the crystal
lattice of solid metals; 2) factors associated with the microstructure of the
solid metal, such as structure of grain boundaries and presence of dislocations
,,Tid other structural defects; and 3) kinetic factors, such as temperature of
the liquid medium, deformation rate, method of stressing, and duration of
the contact between solid and liquid metals. Most of the research effort
has been devoted to the second and third group, although the first group is
the most interesting, since it represents the factors which predetermine the
very possibility of a reaction between a liquid and a solid metal, i. e. , the
selectivity in the effect of the given liquid metal on solid metals and alloys.
The present study is an attempt to fill the gap and to establish some ways for
approximate quantitative evaluation of the part played by interatomic

- , 44 -t -. ~ -
ACC NR: AP6020908
reactions in the reduction of solid metal strength by liquid metals, 5,
According to the concepts of P. A. Rebinder? s school, the micro-
scopic effect of interatomic reactions in the liquid metal-induced deteriora-
tion of a solid metal appears as a more or less intensive reduction of free
surface energy of solid metal, (7, at the solid metal-liquid metal interface.
Since deformation and fracture of a solid are always associated with the
generation of new free surfaces, every reduction in the magnitude of a,
I. e. , of the work required for the generation of new surfaces, intensifies
and accelerates the processes of deformation and fracture. Several ap-
proaches have been used In the approximate evaluation of a.
An investigation of brittle fracture tPf zinc single crystals 1 mm in
diameter, either coated with a thin layei4 of i~iercurj?Jr gallium and tested
aL room temperature or uncoated and tested at liquid nitrogen temperature,
showed that in both cases the strength is characterized by the same invariant
magnitude K= (PcTd 1/,2,where Pc and Tc are respective valued of normal and
shearing stresses in the cleavage plane. Also K= const -a / 2. The value of
a calculated from the experimental data was 800 erg/cm 2 for uncoated
2
and 120-200 erg/cm for mercury- or gallium-coated single crystals.
Card 3

04 t6C~_6::
ACC NR: AP6020908
Investigation of the fracture stress dependence on the grain size estab--
lished the magnitudes of a for iron in liquid lithium and brass in mercury ag
2
730 and 280 erg/cm, , repectively, compared with 1000 and 1525 erg/cm
for iron-iron va or nd brass-brass vapor interfaces.
P_ 7
T he respective magnitudes of a at _~~:er-liquid bismuth and brass-
liquid bismuth interfaces were evaluated from the temperature of transition
from brittle to ductile behavior and were found to be 90-160 and
50G-900 erg/cm 2. Lvaluation based on the magnitude of the dihedral angle
at the interface between liquid metal and two grains of solid metal yielded
magnitudes of 280 erg/cm for copper-bismuth and 330 erg/cm.
2for brass-
bismuth.
A direct determinatio of cy by the Tamman-Udin method showed that cy
rg/cm. 2
of zinc coated with galliumIlrops to 200 e .
These and numerous other results show clearly that in all the cases
when a contact of a solid metal with a liquid metal causes a deterioration of the
former the magnitude of a drops sharply. On the other hand, a solid metal
could be expected to retain its strength and ductility if the magnitude of
remains unaffected by the contact with a liquid metal. In a general case
involving a liquid adsorption- active metal A being in contact with a solid metal
11/8

ACC NR: AP6020908
andA-Binthedeter-i-
B, the part played by interatomic reactions A-A, B-B,
oration of metal B amounts to a gradual weakening, breakdown, and re-
arrangement of the B-B atomic bonds. Analysis of several A-B binary systems
revealed that the deterioration of B occurs, as a rule, if A and B have a
simple eutectic-type phase diagram with a relatively low solubility of A in
solid B. In all such systems the heat of mixing is positive, which indicates
that the bonds in the B-A-B chain are considerably weaker than in the B-B-B
chain or, in other words, that atoms of liquid A facilitate the breakdown of
the B-13 bonds.
The heat of mixing has been determined experimetIaRy for numerous
binary systems, including those of the above A-B type. This has opened the
way for further development of the thermodynamic method for an approximate
quantitative analysis of the interatomic reactions and the part they play in
the effect of liquid metals on solid metals.
All the concepts discussed above are, of course, of a phenome 'nological
nature. A direct solution of the problem, i. e. , an evaluation of eac-
tion forces based on the specific features of electron structure of the metals
involved and their solutions would naturally be much more interesting. At

04460-67
ACC NR: AP6o2o9o8_
present, such a direct approach is still unrealistic because of the lack of
necessary data. It is possible, however, to establish a relationship between
the way a liquid metal affects a solid metal and the electron structure of
both metals involved. The first such attempt was made by the authors and
their co-workers, who found that, in all but a few cases in which liquid metal
A brought about an embrittlement of a solid tal B, both A and B were
-bismuth, aluminum-
7copper
/\nontr nsition metals;, e. g. , copper-lithium
1, indium. germaniunliAalliurn, and many others, which have no partially filled
inner shells. However, this is 'not the only factor which determines the
qualitative and quantitative nature of the interatomic reactions. Atomic
(ionic) radius, valency, crystal lattice, and electronegativity are all of
importance. For instance, in all binary systems in which the adsorption-
induced effects were observed, the atomic radii of compo~Mnts differed
by 10-1576. No deterioration of copper in liquid cadmitun'(the atomic*radii
differ only slightly) was observed, even though both are nontrafsition metals.
Some other interesting deviations were also noted. Pure iroi~ (transition
metal) is not susceptible to de .)n under the
Aerioratic effect of liqui4 metals.
However, liquid alkali metalW some soldersr-and bearing alloydTfower
significantly the strength of sreels. Mercury causes embrittlement of

ACC NR: AP6020908
Constantan (60% copper, 4076 nickel) but does not affect either component.
Thus the specific nature of the interatomic reactions, which is respon-
sible for a sharp decline of the free surface energy and, consequently, for a
deterioration of mechanical properties of a solid metal exposed to a contact
with a liqtiid metal, can be definitely attributed to three factors, i. e. , the
electron structure, the magnitude of the heat of mixing, and the type of
phase diagram.
It could be assumed. that all the above aspects are applicable not only
to a solid metal-liquid metal interface but also to the case of an excess con-
centration of component A in the surface layer of a solid metal B in vacuum
or in air. Experiments showed that a sharp decline in free surface energy
may occur under such conditions.
The liquid metal-induced deterioration of solid metals may also occur
when the concentration of liquid metal atoms in the region of the crack
propagation is below the equilibrium concentration. In this case the actual
effect of liquid metal will be considerably stronger than could be expected
from the drop of surface energy calculated under static conditions. The
Card-, 7/8

1- 04460--67
ACC NR: AP6020908
amount of liquid metal supplied to the front of -Lp is another
factor which ElIculd be ta~ken into consideration. This amount can be greatly
I reduced by the diffusion of liquid metal into the solid metal. In case the
I supply of liquid metal is limited the crack would stop, not because of the low*
P
activity of the liquid metal but because of an insufficient concentration.!
Orig. art. has: 2 formulas and 1 table. [FSB: v. 2, no. 91
SUB CODE: 11, 20 / SUBM DATE: 26Jan66 ORIG REF: 048 OTH REF: 024
55 WK, 4'4 CaCle - a C3t egt n 4-.1
Ccrd 8/8

ACC NR, AP6oxm
SOURCE CODE: U1, 69/66/0021002/0149/0151
AUTHOR: 'Mirkin, L. I.; Shchukin, Ye. D.
ORG: MGU im. M. V. Lomonosov; Institute of Physical Chemistry, ~0 SSSR, Yoscow
(Institut fizicheskoy khimil-AN MM
TITLE: Formation of a solid solution during a quasi-spontaneous internal dispersion
i of.tin in the Dresence of liquid. gallium
sob'R21
. Fiziko-khimichaskaya mekhanika materialov, v. 2, no. 2, 1966, 149-151
TOPIC TAGS: solid solutions, tin alloy, gallium alloy, liquid metalp chemical disper-
sion
ABSTRACT: Changes in the lattice constants! of tin in the presence of liquid gallium
were investigated. Alloys thoughp to contain a solid solution were obtained in two
ways: (1) deposition of a layerlbf gallium on the surface of a tin 3ingle cry!~~a
and (2) mixing tin and galiium in the liquid state, then cooling at various rates.
The lattice constants were measured with a URS-50I x-ray apparatus. The size of the
unit cell of tin was found to decrease uDon introduction of gallium: cL decreased fror
5.816 to 5.778 1, 1. e., by 0.7%, and.4 krom 3.183 to 3.164 A, i. e., by 0.6%.
The observed substaz~tial decrease in lattice parameters, associated with the formatior
of a solid solution1bf gallium in tin, is considered to be quite naturalf since the
lattice of tin is not close-packed, the radii of atoms and ions of tin are larger thar,
Card 1/2

ACC NP: ILP?003695 SOURCE CODE: UR/0020/6?/1?2/005/113?/1140
AUTHOR: Portsov, A. V.; Goryunov, Yu. V.; Portsov, N. V.; Shchu1cin, Yo. D.;
Rabindor, P. A.
ORG: 11-bsco-vr State University im. M. V. lomonosov (Moskovskiy gosudarstvcnny-.v
universitat)
TITLE: Fine i)ulverization of metals in the presence of strongly adsorotion-active
metallic melts
SOURCE: AN SSSR. Daklady, v. 1?2, no. 51 19673, 1137-1140
TOPIC TAGS: gallium, zinc, powder metal production, molten metal
ABSTRACT: On the basis of the assumption that the mechanical dispersion of solid
metals should be accelerated in the presence of adsorption-active metallic melts,
the pulverization of solid zinc in the presence of liquid gallium was studied. It
was noted that quenched zinc alloys containing 1-6% GiL are converted after 5 min of
pulverization into a powder with a par' ticlo size from one to several tons of microns.
At higher Ga concentrations the'oulverization ceased because a paste was formed. To
prevent this, the particles formed by the pulverization were stabilized with butyl
acetate. Gallium was found to speed up the pulverization and decrease the size of
the particles formed. The 6ffectiveness of its action (i. a., the decrease of the
work of dispersion) was evaluated by determining the specific surface of the powder
Card 1/2 UDC: 541.18.053..:,_546A _�_33z.6

ACC NRt AP?0o8695
formed as a function of time on the basis of sedimentation analysis. It was found
that the introduction of even 1% Ga into zinc causes a 200-fold decrease of the work
of dispersion. For the alloy with 10~'; Ga, the maximum surface is 0.3 m2h, which
corresponds to a mean particle size of about 1-5 p. Gallium also accelerates the
pulverization of tinj, cadmium, aluminum and bismuth. It is expected that theoro-
posed method Of Dreparing metal powders (fusion with small amounts of an adsorotion-
active metal followed by pulverization in a stabilizing mdium.) Will find broad
applicationsp es-oocially in powder metallurgy. Orig. art. has: 3 figures.
SUB CODE: 111 SUBM DATEI 14A=66/ ORIG REFt 006/ OTH REF; 004
Card 2/2

PATYCHENKO, V.S., inzh.;.SIfCIiUk.IN, Ye.M., inzh.
Concerning V.',,. 3iman's article "Sectionalizing of gas-oil
operated boilers for 300 to 80C Mw. superhigh-capacity units.
Teploenergetika 8 no.7:80-81 J1 161. (IaRA 14:9)
1. Taganrogskiy zavod "Krasnyy kotellshchik".
(Boilers)
(Biman, VJQ

SHAKH,
Technical and economic e--rlciency oil the reDairing of, tires.
Kauch. i. rez. 16 no.11:217-2'6' N '57. (MIRA 11:2)
(Tires, Rubber-Repairing)

U C "tichukin, Ye. P., V.
,'c d ore n k- o ,P ...arkevich
Jynthetic Ethanol ino"ustry ~~orliysiil,.:nnost sintc -
~ichesl.o_,o etilovo,,-o spirta za rubezhom)
PERIODICAL: 1:himicheskaya Pronys'llennost', 195,9, Nr 2, pp. 58 63 (U33R)
only
ABSTRACT: paper only contains/data on foreiC;n production methods,
output capacities. economic data etc. After givin:; statistic-
al details on the use of ethanol the development of this
ir~ustry durin.- the last years is mentioned. Then the enter-
i-rises in the USA producing synthetic ethanol are jiven,
lientionin~; the first year of production, 'the kind of synthesis,
o4well as some more -production data. '-!'his is done in form
of" a table. Also data on the processing, a diagram on the
nroduction of technical ethanol in the USA in 10.57 as well
as com-nercial considerations are mentioned. Besides these
crtcrprices in the USA the European plants for the pro-
duction of technical ethanol in 3n~jcind, Denmark and the
13erman Yederal Republic are --iven; in this connection it is
Pointed out that in EuroDe exclusively th2 method of direct
Card 112 ~~Ydration a.-,d not, as in the US- , that of sulfuric acid

~,.7i-.Ihctic Ethanol industry Abroad
..Idra'ion 4- used~ 7conomic hints are mentioned with respect
to the production of ethanol '. the fermentative as well as the
one, mainlv in the USA, statistical data and dia-
0~ th,- raw material conzumption being given. Ihere are
Z, fir-ures, 2 -'L;ables, and 32 r-Cferences, 0 of which are Soviet.
!,"-uchno-ic-sledovr-tel'sl-.iy institut sinteticheskikh spirtov
i or,-,anicheskikh produktov
(.1-cientific Hesearch Institute for 3ynthetic Alcohols anc
Grz~anic Products)
~~VAILZIB TL: Library of Con-ress
1. Ethanol--Synthessis
%lard 2/2

o ? , IL ~I . : j
1~
FXDORMO, N.P.; SHCHUKIN, Te.P.; MARMIGH, Y.A,.
Synthetic ethyl alcohol indastry abroad. Rhim. prom. no.2:122-127
Mr '58. (MIRA 110)
1. lauchno-issledovatelle)dy institut sintetichookikh spirtov I
organicheskikh produktov.
(31thyl alcohol)

T~,D)_R;,NIYO, N.Pp; Si(Cigy"'IN, Yfi.P.; FRIM.11, L.-,,.
Proilliction and unn of glycerin in the U.S.A. Biul. tekhn.-okon.
in,--rm. nn.9:94-96 1-58. (1-g-'at', 11:10)
(Urited States--Glycerol)

~A
I U
TTTL-: Conference of of -ne Synt.4ctic Et~,yl Alcohol industry
Branch
PLRIODICAL: Kh-J:.-,iche.-Kaya pro,,Ilyshi cnnost 039, 'I-Ir 'z , P 459 WSSR)
.1 j
ABSTRACT The rc-alar branch conference tock place this year in Novo-
kuybyshevsk from July 14th to 17th, to discas.9 problems of -the
industry of synthel.ic k~thanol. Th~- corZerence was convened by
Upravleniye komiteta Soveta Ministrov SSSR po khimii (Admini-.-
stration of the Committee for Chemistry of the Council of Lin 4
sters of the USSR) and by the Kuybyshev 3ovnarkhoz. DElegates
fro,-,, all plants of synthetic alcohol, of the Gosplar. ~rogrram
SSSR and of the Gosplan program asFSR and of the Gosk.hi;:komitex
as well as leading -aorkers of the NovoILI-aybyshevsk and of --
number of rese-nrch irstitutes (F-J-.iko-kh-Jmic.-eskiy institut
z:eni Karpc,.ra 'Instit-ite of Physical -and Cnezical Sciences)
VITI inefte~-hi-, 11=5 and others", of the Ku.;~byshevskiy indust-r-i-
I ~. L .. --! -1 -j
alInyy -;T,-~Litat (;~uybyshev Irstitute of Ind~ustry), Of the
Planning inz---Itatles (Gi:)::o'r-.auc',1u'tr, Giiprogaztoppro::,), of the pe-
0 -- -
Card 1,13 trolsum refineries , etc. partilcipated in, "his cont"erence, which

C 22
7
-i; a L3 a tt by r on3 it a s n -2 d e
3 ~ r v , S c r e thl~- K"l-1--sh,~,vi3lk4y oblastn~y k: -it t K- S-
y S h ev .~~b 1 a s C r~::~ ~ i t o f` t e (~?S U L e c z -a r'~, hald
i n T, h ~- o 1-,na -,-,y .5 cs o i 6 n.~, c a ricE-. rn.~ ~.-,e t asks of 3 d s ry
(it &Yn i(~ eth a no -I L . 1 . Z1.1, of, -i Gcs"%- I i t and
r(:-;DrtS were ,-.ade on the ~.nrk of the pl.3nts durinl-- thie year
1~38 and dari-r', t",ie first ~,,uarter of 11959 (1. A. V-!Iishko .-
Ku-byshevsk.iy zavot!, sintetiches;,--c~o ~;~irta K-iY'.-Yshev Plant,
Slynt'-+ic Alcoiicl) A, F. L"t-,in Gro--.nensl,-i,, 'Khimiclzeskl~y
v o d -wy P !a, 1 A . Anis 4 mc'v - S arat cvsk 'y
zavcjd sintetich&j~'cl-o 9,~=ta (Sar-ntw; Plant of Alco-
'-101), A. V. Lik-ha-chc-l;v - Orskiy zavcd sintcticheskco.go spirta
Or sk. PI-Int of Alconol), Y. J. RYabova - Ufimskkiy
zavod si)~--'a (Ufa Plan- of' Synthetic Alcohol),
1. Ya. Ki`.z~nke - 1~~TSS). Le3ta::-es -irere a-isc eld 0!7 t"P- f0llc%
ing Sub.,Jc--ts; On the dcreaze of ti- 'e ~ri me cost of alcchol
y C- . p . S 110 r t J on' i t - ns 0 f C t ~i~; I n e
~;JTSS or hc 4
AS JSSR G. K. Bcreskov~ or
ns co n o e rn i n the n-rod--iction of
Card 21 (Dcctor cf Technical
1 3 alcohol and their analys-'s in E, jSSR

A 7
r_ - 2, __ 0 1SOV/6'
nc~ I sr.; 3 r c h
Ll. A. Dalin), on the U~jJ4 za-,-,Dr. of by-prodicts of t;Ie zro-
-~ct4On Of synth~_tic ct~-,anrl (Li-_.ector of TsZL Orskcgo zavc-,a
S. D. (Central PI-Int Lab3ratory of the Orsk Pla'
nt
S. D. Ra-LuM:)vsk4yl), on furthr aat L
)l Ozat~on of alco"Icl nrodac-
tion, (V. V. Aranovich - Giprokauchl--k.), on roast -,rot~-Cticn (A, 3-
17TISS', C.,- - -~i,
n C, ~ ( t', (
~ 1. E:r
1'r 1 , -,y 1 ~T. I. 3c.-olepova -
o':!- a u ch ak j) ar j r1 7-i- 0-'e~ence 5st-,idy z
mrou;:s d`sc._~ssed
~0110--';iY!" 'Prcble:-s : Preparing c~~' ravi T.-.ateri-al, ~_t`,yle_ne
alcohol !~rod_Xticr,
~I-e econcmic, auto-'atic and :~ro-
d~zc~ilon co'ntrcl. 50 1 ec-,ures -,,;e-re held. Tr was decided, a-- _- 2:_~
Ot 1~ ers , " o t.;,: - b --z i 1 -;
___4n- of 2-3 nez planLs and th-
"'.'Or'-rs Tt-,:'e --r7 e n e Y E:
a, r

s~06~/60/000/03/04/022
B 10 B006
AUTHORSg Fedorenko, R. F., Shchukin. Ye. P., Fridman, L. A.
On the Economy of
TITLEx Ace~toAne Production
PERIODICAM Khimicheskaya promyshlennostl~ 1960, No- 3, pp. 202-204
TEXTs The further development of acetone production with respect to its
most favorable economic aspects is discussed. kn increase of acetone
production by 4.5 times in the period from 1959 to 1965 is provided in the
new Seven-year Plan, and the cumenelmethod is to be used mainly. It is
pointed out in connection therewitE that the problem of the simultaneous
production of phenol is of special impo---tance. A comparison of the
production of acetone and phenol by various methods (Table 1) shows that
the cumene method is the most suitable one. This may also be seen from an
explanation of the calculations of the production cost which is still in-
accurate. Corresponding applications of acetone must be provided for,
since a large Increase in the production of phenol by the cumene method
is also provided foz, and the applications of acetone are becoming more
and more numerous. Acetic anhydrIde can be produced by pyrolysis from
Card 1/2

On the Economy of Acetone Production S/064/60/000/03/04/022
BOIO/BOOB
acetone and acetic acid. Although this method is -riot the most suitable one
economically (Table 2),1-- is tobe preferred to the other methods for various
reasons. A treble use of acetone as a sc-Ivent in the production of cellulose
esterlis provided for 1965. Acetone is also increasingly applied in the
synthetic materials industry. Calculations showed that, provided the in-
creased demand for phenol in 19659 1970, and 1975 be covered with the help
of the cumene method, the consumption of the quantities of acetone pro-
duced is safeguarded. The production increase of phenol and acetone by the
cumene method exclusivelS,, planned for 1975... is thus ccmpletely justified.
There are 2 tables.
Card 2/2

FEDORE.NKO, N.P.; FRIDMAN, L.A.; SHCHUKIN, Ye.F.
Production and uses of aromatic hydrocarbons in the U.S.A.
N.P.Pedorenko, L.A.Fridman, I.F.Shchukin. Khim. prom. no. 7:604-
612 O-N '60. (MIRA 13:12)
(Unites Btates--I~rdrocarbons)

FEDORLN)iIf,0, N.P.; FRIDV~E, L.A.; SHUMSKAYA, N.N.; SHCHUKIE, Ye.P.
Certain problems related to the economics of the phenol pro-
duction. Khim.prom. no-3:163-166 Mr 161. (MIRA 14:3)
(Phenols)
J

BAKUEENW, T.L., FEDOI`0111,0, 'IJ .; -SHCHUIN, Ye-,P.
J;eonom4c aspects of Lho indus-try ;f t,,olyme riza tion plastics. Plas' -
-Z )
masEy no.g:-~2-56 '(1 , ( Pa ilm I -~: 11
(Flastics industry) (Foly.7ers)

ACCESSIOIN NR: AP4039228 s/oo6l,/64/000/005/0339/0344
AUTH.ORS: Fedorenko, N.P.; Braginskiy, O.B.; Fridman, L.A.; Shchukin,
TIIT_T,E: Economic efficiency of the pyrolysis of low octane gasolines
"U!II?r':P,: Khirnicheskaya promy*shiennostt, no. 5, 1964, 339-344
J J-.,
T(TIC low octane gasoline, pyrolysis, high octane gasoline,
_,_ic hydrocarbon, naphthaiene, naphthene, liquid pyrolysate,
iiqui,_~ hydrocarbon pyrolysis, production cost, petrochemical,
cli-;; cal intermediate, hydrogenation, absorption oii, plasticizer
L.,TRACT: 'dork in various scientific institutes and experimental
itiduj',ri'ai 1:.Iboratories had shown the low octane gasoline fraction
tLLQ most valuable liquid petrochemical crude--in its chemical
there are obtained a series of intermediates including
and aroiiiitic hydrocarbons in addition to ethylene and propy-
Various liquid hydrocarbons obtained in the production, sta-
bilization arid processing or petroleum (gaseous gasoline fractions,
cond,ni,qate, directly distilled gasoline raffinates, products from
r n':~' --n
d subseauent dearomatization had been evaluated to

ACCESSION NR: AP4039228
determine the material most suitable for pyrolysis. Processing of
the liquid products from the pyrolysis of low octane ga3olines
vi,21ded a predominant amount 'of high molecular olefinic and diole-
:Cinic hydrocarbons, about 30.. weighV%aromatics and about 20 weight
aph-,orv~o. The products may be recovered by intensive processing
of- pyroconden5ateo, or high octane gasoline products may be
by hyd ro Fenat ion. of the fraction boiling below 200C at low
rf_,~3 (10-20 atm). At the NTISS (Scientific Research Institu e
Alcohols and Orr-anic Products) calculations were made
LY
c-10-1_3 involved in processinc, the p rocondensates to produc(3
octane r:asoline or to obtain the aromatic hydro
and other p-odi_icts. For the latter the calcula~-;ons
L;,,: coi,-,,plex 3ch~?m,_~ 'or most completely recoverinf al'
cornponen
ts. Such a scheme, derived from various
in the Russian literature, involves the separation
o" ~nt~s iri the six fractions- to 70C (mostly unsaturated C
70-120C (hi- L
_h p;3rc,:!nt c,' aromatics, subjpcted to
at 3-5 itm 0 5-0 i -CQ-1 space -V-10-
~Iy',.i.,Dcarbons f;r p;Yy-'.,-u-ric r;~,bins, to

AP1,0392128
~viith diis-)propylbenzene peroxide), 200-230C (naph-
to be r,2covereo by methods used in the coal tar chemical
(~o !~~e 3ubjected to high.temperature hydro-,~-ria-
rj- C4-
I-on to be usocl for n,
I U aphthal-ane recovei-y"
11!-, Products, as absorlbtion oils) , and pitch 17
for
"I"e calculationz3 confimed the suitabi-Iiiv,
;-It OC tll~e nationall ecOnoiny , of 11.31 nt I 10 llqui~'
poturochQ.-,iical processing. Thu expenses for 1-1he
and distillation of the additional petroleum
c'~Ozi;n the directlv disti'led - soline fraction fo- the
,a
vroce-3j are rapidly recovered. Orip.. art. has:
Oone
ENCL 00
'R R:
F P N EF SOV: 008 OTHER., 006

RAMENIKO, T.L.; FEDORENKO, N.P.; SHCHUYUN, Ye.P.
Polystyrene production economics. Plast.massy no-5:40-44 161-
(MMA 14:4)
(Styrene)

FEDOUNKO, N.;.~IIC~TUKIN Ye- 1',
Economic problems of the comprehensive use of chemistry in the
national econo5 ("Economics of the chemical industry" by N.N.
Nekrasov. Revi6wed by N.Fedorneko., E.ShchukJ;k). Vop.ekona no*5:
103-106 my 061, (MIRA 14:5)
(Chemical industries) (Nekrasov, N.N.)

L 32199-65 EWT(1) Peb GW/GS... J; .
[ACCESSION NR.-' ATS005426 S/0000/64/000/001/0098/0099
-Yu., K.
AUTHOR: Drumya, A. V Shchukin,
TITLE: Seismic characteristics of the Moldavian SSR and the adjacent 'sections
of the Eastern Carpathians
SOURCE: Nauchnaya konferentsiya molod~kh uchenykh Holdavii, 3d. Trudy, no. l..
IYestestven-n-o---t-elEffn-icheakiye nauki (Natural and technical sciences). Kishinev,
Gosizdat Kartya Moldovenyaske, 1964, 98-99
TOPIC TAGS: seis 2i2a?~Moldavian seismic region, Carpathian seismic region,
earthquake cause
!'ABSTRACT: In view of the strong earthquakes (up to 8-9 units) that have occurred
Iin the past on Moldavian territory, the authors studied the entire.
Carpathian
region with respect
to 1) earth layer thickness and types of layers; 2) tectonic-A
mobility; 3) deep ruptures; 4) quake seats; 5) perturbations due to the formation
of new superposed:--layers; 6) location of groups of seismic centers-, 7):strength:
iversus depth of quakes; 8) isoseism shape during shallow quakes. The paper does'
not present the chart of seismic dangers.which has been prepared on.the basis of,
the above investigations. A"
Cmd 1/ 2

Var.; ye%,jrAi. k, nc' - 9P C"I -
i
Y Yuriz
'mill. DMIK,
y -aria J v,, tio v na k, gn .
o n an t,41I oV 1 -, h kand. f,oot-mirmer.
T
red. red,
b1 n-f Qip tef--t.c.-n z-, a I I "i Ee 4 ST-.(: ivy I.Iolda-viaj Froblerry
ne Fa r ti
c
1 2- Vj
"e-~ p Fi -'~ -'~C- , -I .

siw~etff-*thaut C w

d A
W
n
an
. ~-
k a
-
'06fiWaifida of
continuous instmment to. mmsuie 4alt caucus. of 0-0-5f,-
mg./I. is described., The usual calih~atioa with the help of
below I mg.A.
Me as sofas.
standard solus w" impow
absorb deviations in the electrocand. of the
bra . b
gain
rmits Cali tiou
Instrumen
.
t pe
mewaing -resistances. The principal element of the in-'.
strument is a transmitter, cousistingof an outside -and iu-a -
Mde electrode hooked Into one branch of an.unbalanced re-'
sistance bridge, the diagram of which is given. 1. The mternaf
electrode. (1) COnSiSt3.Cf a stairdessmAeel tuba 48 mm. -in:
coni
diam.. X 3 min, thick, polished inside. A threaded ical!
to.
aple screwed on the bottom of the tube admits the soln.
M_ Is'
measured through auother-tubew~ The botto of
.closed by an insulating insert (U), one side of which-is6oni-~
-
cal and the reverse fiat with'a nest for the internal eleetrode.1
Eighteen 3 mm. diam. holes-through ]a admit the 661n. to the;
inside of the electrode chimber. The internal electrodel
consists of a tube 25 turn. in diam-. and I mm. thick, dosed
at one end, motuxted in the nest of 11 wncentricall
y with 1.
Into this'tube a Cu resistance thermometer is tightly fitteA
in, Vie coil of the th4innometer consists of 0.07--0.10 111M.,
thick Wire (resistance at 0* of,1575 ohm). The whole-",.
assembly is capped by a split head made of an insulating ma- i.
terial With tangential holes to release the soln. A shunting
resistance for tenip. compensition. of 13M ohm and 2
terminals are attached to one side of the head. The~uormal;
vol. that can be handled. Is 20 Idhr., but it can besitivid to

&E. without affecting.accuracy
150.1. -------

KVYATKOVSKIY, V.M., kand.tekhn.nauk;, SHCHUKINA, A.G., inzh.;
MATSKLVICH, G.V., inzh.
Automatic proportioning of reagents at the water treating
installations of electric power plants. Teploenergetika
8 no./+:15-19 AP 161. (MIRA 14:8)
1. Vsesoyuznyy teplotekhnfcheskiy institut.
(Electric power plants) '
(Fee&water purificati6n)

0 * 0 0 0 0 0 0 0

Is It V n 2, !is 31 U u $9 B it I? Is V Al 91 a W Ai r0
A1- Ll r I r. It I IL IL a it I T U it -A --I- M -14 a W M - -
1.1~11%fl A.2 '-f.
Utdixation of by-products of Ity"ystis of shrow for
f
ll
ti
f a
b1
1
t
A
M
.
o.
on o
m
e mo
es.
.
allilrep
c W

0( aq. cxt%. cl straw. t-1119. mclin%. protrin, %usar%.
2 t..
eincredws tile sile of soil awrigutr% tbun Irodlux to
;
.
'
I r plant growth. The residual IlItnin tMII lurfural -00
0* U; in-Ouction wanaotoclaved with 6% KOJI. and the pr,lduct

- - 4 neumlized with 11,SO.; the product so obtained was far -00
:'
!- inore active than were the above &q. cits. Addn. of -00
00 1 %VI'AC or cellulcoe to soil (lid not surnent it% fe"ility.
C. 11. A.
zoo

00 _0111111
0 0

00

00 x .0 0

.09 so*
zoe

90 Wes
00 t: 00
00
:
00 S L A tTALL-K-L L1T( ..?1Hf CLASSIPiCAlIC- It Z - too
0

00 8 0

A. .0 is
2r 6C
*000000*00400 r .-I

61 K Is It 19 x
K it q
00 000000 0 I Ar 54 1) A] C 2 4 V 7
Kra n I

06900000000006006

0 to 0 to & 0 A 000 0 0 0, *
0 0 0 * 9000 0 V *~* 0 0 0 00 00400 0 0 0

0 0 0 0 0 0 0 0
1; 11 OfA J4 ry
F to a I i A.A 06 4
0

of
-00
-00

ncr
ptrqvv
0
- ," t.;;, il'.11--
~
0
l?"ll- .f 10 to it, 11
00 o ............
I It,
zoo
tz

0
00 0
:
e
-.00

Z.0 0
00 f =00
'4

00 A IL L f ll. it L a t, r i I I v 44 me ~t

oo -
0

of z :
0
es Organic cniloldri Ill the smAs of the Kuibyshev revous in
A I -sill 11
t3kIll-l"
connection with their fertility-
-
,I.

00 "."J. I- 'I. it! 11" lhl -0
so

00
00
ir
.0

_oloi
0 S S L AMITALLLFG)CAL LITFRATLRE CLASSIVICATIC" C z
: :;0 0
oe's
-- ~'. 14". ..1, .
00
I s 6 -Wa IW -a I -.Ix
-[
10.1
n
.
K
ft
X
K
M Vtrk
I
A
it
%
CE
t(
LJ
. 4na
0
0 0
0
0 0 :

0 0
0
6
0 0
is I/ to )in Aida X Vx)1 Vill IJU "Al bulf)"Au .1 till
l" I# v lJL_ II-I AA 16 M 0u
L I a m
69 41 il
of .... W (m 'Im"I'li.11.11t
P.qswum lit ..... ..... I I-
Ig
00 19411. N..
I kill III,-11-1 of NvIvv jo, &i,, K all It,, it ...... IlS.Ill
'
11 the Kialby,hev regum wA, con
larvd with 111, 60
%

catims
1c.
"
"a
f the Kir nov inethod (with 0.2 N I . and -00
t
Nacl) lies res"It.4 were ob ained with thc %econd
t
111"Illicati-m 'rhe InctIlml I% halted an forrinK nitt the
ell hmigr K 11Y mcan- of NaLl (L, g of toll l- 7.7, ,f V
00
1, ~md 'I".1 till .41
00 ...... ... .... 00
o0 '00
0& 13 1; ttill 0
=00
00

00 zoo
00
00
roo
00 f goo
00 zoo
00

too
00 it t t 111 1 L.1 t 111-P 11 -1 Ill- %as

T '476 0
T I p -4

t? K Ail A, % a I'dI w (3 3 S

0
0
0 0 0 0 0
0 0
0
0 0 0 0 0 9 111, * 0 0 0 0 0

d, a a

MO
0 w V J~
A
A_

4 1
so C
00
'4 see
to

nos

go z Zoo

00 ZOO
go

00
00 Sol
09

902
Wei
jot CLj%IFKATtGw
04
ad U
An I
to 01
00
so
The
-lt3.e Soil 9e&- 0.? V'*
T Vith Vb3_ -beea
~ajjbjs . -a -Pot's - I bad-
13cu- zal), regets;t1c) of 501 1/2 Y-201
go, -per 1/-- 11, CL f 0-r
Vii,eat Vas -4-L -90 acj&e
62 & C).1 -tae 61 Pill
SA of a. 40if, of f or
-atesce%ls sa oots)
L . 'P~P5' -I)OL qa'Ctdacea- at _9181~ 130
0.015 9 . ,ere
- irtro f ~h
&Ose -ase to 40$
d. 8,t +~ljres -mea-
-p the ls.
.Lace of 1- 'MO oa6 of 86V9 ~..,,jirec vas
_4ariau . ...race
).& Tae 501 j)eTl
t ... tale 91811-t
t.r~.tl . 1U. the firs$. The Je
V:lix )Cit'y - IrL t ),,,a
t,,re caV . -t-Oxe o BO - vass
-Mois tiale 'MOl . 'at ose 'he above g
L4 days I 'at Or t
coraw '49X'a- - g
the s e a3r, we'
the
01
110
zYar_.-Bjo3_O9'1a)
P,bG Cal leaves
theSis
shcb,3. Sjate re8a6093 SbVlerlt
palthor K -.511e . ty ~r ?h0tas'p, - 110 16 31~43
111b -jV'l M3_11eral 561
?rodxlct . txlre 5ad- t) 19
Ogy Of
3_1
Car& 1/2
Usa
Abs
--e~Lya, 110 1958.F 1125.
tthaeknenthseeven tiales dux-ing the
Productivity of assimcialuartsi'-zonofwnthe _e-xl_)eriment
to the forMllp _+' n-- z t,, -1 ., , _
1-2

SHCMXIIIA, Avgusta Ignatlyevna, dotsent; TIMOFEySV, V.ye., dotsent, red.;
I - - - ~ SHCHERBAKOV,'A.I.,_tekhn.red.
[Methodological directions for practical summr field work in
plant physiology] MatodicheBkie ukazaniia k provedeniiu letnei
polevoi praktiki po fiziologii rastenii. Kuibysbav, Kuiby-
shevskii gos.pedagog.in-t im. V.V.Kuibyshava, 1960. 83 p.
(MIRA 14:1)
(Plant physiology--Study and teaching)

SHCHUMIA A.T~
Effec' of gabbe-Iiin on the ,,Tcwtb arid yield of alfalfa~
Fiziol. raa-,. 8 mo.L t61. (MIRA 1-/:, 1 1 )
1. Ku7byshc..7 Pedagogioad institute, Kuybyshe7~-.
11' .1. - )
It ribbere' lin
Ifalfa)
k
~

SHCHUKINA, A.I,
Effect of potassilwa on the water balance and yield of Leukurum
wheat. Uch. zap. Kuib. gos. ped. inst. no.35:47-56 '61.
(MIRA 15:9)
(Wheat-Fertilizers and manures)
(Plants, Effect of potassium on)

LAPTEVA, L.; SHGHUKINA, A.I., dotsent, nauchnyy rukovoditell
Physiological difference in the quality of the car7opses in the
corn ear. Uch.zap.Kulbagosopedoinsto no.37:57-59 162.
(KMA 16 %1)
(corn (YAize))

,SHCHUKINA, A.I.
Effect of potassium.on the drought resistance of wheat. Fiziol.
rast. 10 nc.3:313-318 W-Je 163. (MIRA 16:6)
1. Kuybyshev State Pddagogical Institute, Kuybyshev.
(Plants, Effect of aridity on)
(Plants, Effect of potassium on)

L)roui,' t and 'o- iwlt o in the wz!.*..er balance Of
1. !le - I
r10. j,: I(j,t)_jr
COrn. Fl-.iol.rast. 12 074
T", 1;-, : J-)
imeni V.V.Ku,,-b,,-shev-a, FuyL-7.-shev.
~Jjt

SHCKKINA, A.S. :
SHCKKINA, A.S.: "Increasing the winter-resistance of winter wheat by sexual
hybridization witri neteropollination". Leningrad, 1955. Min Higher Education
USSR. Leningrad Agricultural Inst.
(Dissz~rtations for the Degree of Candidate of Agricultural Sciences.)
So. Knizhnaya letopis'. No. 49, 3 December 1955. Moscow.

1959,
re !,r ~r
o a t.,. n t i n
t-lic Foll-
I J. n -or s o 43
z; o "'oent-'er, c) -ra of the no
o c o c r;
e
t! c, r, ri r. I,

BELEVTSEV, A.N.; MILOVANOV, L.V.; SHCHUKINA, G.A.
Purification of plating plants' waste water containing chromium.
Ochis. stoch. vod. no.3:~7-38 162. (MIRA 16:5)
(Chromium) (Industrial wastes-Purification)

AKOLIZIN, L.Te.; LISHBERGOV, V.D.; SHCHUKINA, G.F.; TSOY, D.; DUGIN,
Ye.V., otv.red.; DUKALOV, M.F.. red.; BUBTRI, V.A., red.; TYUTYUNIK,
Ta.I., red.; MONIN, M.I., red.; PANCHENKO, A.I., red.; VARSEAVSKIT,
NI.N., red.; BELIATEV, F.R., red.; RABINKOVA, L.K., red.izd-va;
KOROVFdiKOVA, Z.A., tekhn.red.
[Standard cross sections of mlne work-tnga]Tipovye secheniia gornykh
vyrabotok. Moak-7a, Gos.nauchnc-tekhn.izd-vo lit-ry po gornomu delu.
Vol.l. LCross seut~on of timber-supported workings for 1. 2. and
3-ton cars] Sechsniia vyrabotok, zakreplennykh derevom dlia 1. 2
i 3-tonnykh vagonetok. 1960. 34a4 p. (MIRA 13:11)
1. Moscow. Gesudaretvennyy proyektnyy Institut Tuzhgiproshakht.
(Mining engineering)

BnILO,. V.Ye.; KALINCHUK, I.G.; LISHBERGOV, V.D.; NIKC&IYEV, G.P.; TSOY. D.;
Prinimali ucht)stiye: KOLESNIKOV. V.F.; OSTAPMiKO,
P.V.; SEDOV.A, M.P.; TKACHXV, M.V. DUGIN, Ye.V., otv.red.;
ILIBIIFKUV.A, L.K. , red.izd--qa; KOROVENKOVA, Z.A. , t alchn.red.; SABITOV, A. ,
tekhn.rad.
[T,,rpes of mine cross section] Tipovye secheniis gornykh vyrabotok.
Monkva, Gos.nauchno-tekhn.izd-vo lit-ry po gornomu delu. Vol.6.
[Grons section of mines lined with steel arches and anchor bolting
for 1-. 2- and 3-ton railroad cars] Secheniia vyrabotok, zakreplen-
nykh stallnoi arochnoi i shtargovoi krepliu, dlia 1-, 2- 1 3-tonnykh
vagonetok. 1960. 503 P. (MIRA 13:12)
1. Khar1kov. Gosudarstvennyy proyektny:, institut Yuzh.giproshakht.
(Mine timbering)

t4ollS ~n. C*---,::-'.c -V
obse-:a
a ss E: s, T-n iy "a Proped. viutr. bo 3: Z-~ 3
a-nd cup testL; Lr. rl-,rl-natic fever Tb~d.:

SHCHUKIRA, G. I. ,,
lr':-',.~_:__~~- 4 "__
Coagulation test in myocardial infarct. Tar. arkh., Moskva 25 no-5:
24-29 Sept-Oct 1953. (C1XL 25:4)
1. Candidate Medical Sciences. 2. Of the Propedeutic Therapeutic
Clinic (Head -- Prof. S. Ya. Kofman), Leninp
,Tad 'State Pediatric
Medical Institute.

SHCHUKINA, G.I., kand.med.nouk
Dynanics of indexes of cutAneous tempernture~in hyperteinsion ditring
prolonged sleep therapy, Terap, nrkh, 30 no.5:54-55 My '58
(miaA 11:6)
1. Iz kafedry propedevtiki vnutrennikh bolezney (zav.-T)rof. S.Ya.
Kofmnn) Leningrndskogo pedintricheskogo meditsinskogo institute.
(HYPERTENSION, ther.
sleep ther., eff. on skin tempe7,n-,ure (RUB))
(SIMw, ther. use.
hy,pertension, eff. on skin tempe,-nture (Rua))
(BODY TEMPERATURE,
skin, eff. of sleep ther. of hypertension (Rua))

071 1:.7 --OCI
TU r

KOLOSKOVA, A.V.; SHCHUKINA, G.N.
Physicochemical properties of water-stable aggregateg of various
size. Nauch. dokl. vys. shkoly; biol. nauki no. 1:196-202 161.
(~MU 11+: 2)
1. Rekomendovana kafedroy pochvovedeniya Kazanskogo gosudarstvennogo
universiteta. im. V.I. 'Ullyanova-Lenina.
(SOIL PARTICLES)

S- OUR-CE CODE. -3-5-61602/010/i876/1877
t'CC INR. URT-OY6
AP0032953
T "ikol'skaya, G. F.; Berger, L. I.; Yevfimovskiy, I. V.; Kagirova, G. N.;
M-i',OR: N
A
Shchukina, I. K.; Kovaleva, I. S.
ORG: Institute of General and Inorganic Chemistry im. N. S. Kurnakov, Academy of
Sciences SSSR (Institut obshchey i neorganicheskoy khimii Akademii nauk SSSR)
i TITLE: Electric conductivity of CdSnAs2 in solid and liquid states
SOURCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. 2, no. 10, 1966,
1876-1877
TOPIC TAGS: cadmium tin arsenide, arsenide electric conductivity, liquid arsenide
viscosity, liquid arsenide conductivity , cadmium compound, tin compound, arsenide,
i electric conductivity test
ABSTRACT: Cadmium-tin arsenide CdSnAs was synthesized by fusion of stoichiometric
2
quantities of high-purity components. All the specimens had a single-phase structur&
Heating and cooling curves indicated no structural changes, except for melting and
solidification at 595 and 592�5C, respectively. The conductivity of the compound
undergoes a change from impurity-type to intrinsic (see Fig. 1). The shape of the
conductivity-inverted temperature curve indicates that the compound remains semi-
conductive, melts without decomposition', and maintains a close order in the liquid
Card 1/2
546.48'811'191;537.311

. ." '~ U - -, - ~~ V - W
1 'W W W W - W - IF - -.0
OVF
7*
14 mbn ba 27' A A 11 11 m a so a so e 0 0
4 P IN P a 41 Q it Of 1349
9D
t

Vitfilwo "K,, p. U. Tactolamork "d oxi x .
t
so reductift bn=a of ---4 ~

0 none and Its derivatives. --L,-A. ~jhuktft Yu, B.
'
'tWW `tF
d M
Sh
NI
ki
J 00
lei 1 -
411
.
9X.
-
elitya
n.
. G
S~ & k.,
32-,-:1A1jl9Wi)jFngli%h miturnary); cf. C. .1. 38, WV,
Fie~rr, rt at.. C. J. 35. 40W.-Thc authors investigated
sorne propertic4 of 2-methyl-1,4-naphilloquitione and re. 1
lated compits. The quinone on proinged bifing with
-ter yields phthalic anhydride and a deep violet, crypt.
4 Jid (doett not in. 3M* (front AcOlf)). Boiling with
"
so W'
, KOH lemuk to thuilar mults with a Ill sull-4
'*
K
the viij~K pr(whict. Boiling with tumd.
C
l Icads on1v -00
so AN it) t4irvitlirt solid, with only trams of plithalic acid. K.-
*0 tnSAyl-t,4-tiaphthoquirmcm-3-sultonsit (A) g.) boiled for

Yh
with 2 1. 1110 and cooled. yields the qUiRkytilf,me
r
90 /whi
h is filtered off (3,3 it., in. 2434* (front water)).

so W
hik- evapti. of the water soln. yieldvt 0.8 g. plithalk, all. as*
It dride. The K lullonale (A jr.) was stirred with M cv.
7
2S-; KOII for 4-5 inin. and immediately filtered; till,
i
h1trair rap
dly deposited the emaklit 41), which w4,
filirml off suit dried after washing with HtOH and MeICO.
3
I(A x.) in M cc. water rapidly dmrkrn~ and precipitat"
zi i he quinhydrone dewribed above 0 .8 9.) and phi ludit COO
aeld; 3 g. of the rnotate we shaken with MI cc. 251;
KOH for 2 hm. and filtered; on standing them ocLur,

, less
CG-C:C
Ht O.CCHIK
I C.H
<
zoo
-C(OK): CSO.K
O&K use

(U)

cry%tn. of 0.5 C. of an orange-ml conjpd- (U). The
i
i
i
h
fi
i
i
mot
er l
quitr on av
di
cat
elds the or
ginal K %W.
on y ties
is. ILA G, SL Koo4jullf
14- ".0,
-
I All aa
--
- 6.;v itj

U Is AT 10 is r
j' a rw a a I
q
K CE a it K 14LO n I ~Xol lor IN 1 113 13 3 11 1,
s 0111tagg led Is a
: 0 0 0 0 94
'* 0 fee Of& 0 0 0 0 0 * 0 * 0 0 * 0 0 * : : * : 0 0 a 0 0 0 a * 0 0 0 0 0 010!
0 * * * 48 at 0 0 0 0 0 0 *-A 0 1: : : 0 000 0 0 0 41 0 * 0 0 a 0 0 101

w w
4F fF 1;1 Ar Ar 41 4r a
JL a a 0
t V
A

i 1
o
o
0
I
* _
-
-
0 0 0 0 0
oil t
t l
4
n 4 1? i
t 1
1 1
s to a a
I it 0 31 to b J? III A 11 w to a 16 It a 4. 6; 0 4: it 61 64 re
A t
v
I FA 1~ L A it, I r a t v _11-1-
k,4011% t-A-001 W t1tv b & 11 a I o ~a_ iIt
60
so IM11'ed"P *w
Tit. witillulft K 1110UP 111, 1:111011, " "Des at
a-
4hrin
2V V6
k
.
111
y
witairomin K and of its Bylithel
'A
'
00 tao-
A- (
kill, 1, A mild Vu. It. -Sbvrtm)v- J- (;#
'l
Ulustwy); CI
st
.
i
.1. Jill, VIII -After egnosmlermtkorz td kritowndmisson the
-00
..,a Wcon ICY J the %itamut K arsiuls, Our &II1hsw% I-'Iigvr

00 that %11A 4tv j,r,."tmcmIn,I. hdr th.
A. tual ~11.1-aoolrt t~ philialk Acid, -116 Is t, Comb-
00 a 41 1y 101114741 litull VILASIIIII K sold itSAIMIOP61 t1l`iVUtM. "I

'
f 114 -1 site tsdatmas ordiwaic"I -%,trm. IV. Sitructwor
l
l
l
w
t"
with bi
W
:
o
J
-
"WA&
coll 1.4-naphtboq
rostog"O
l
d
ects C
1h
o
is
' -film 11"Illatel

1
it %I M -M
imildho Isiallialitsmortals 11 A 11--lo,miall-IM - -
th
*1 111119V lit is
'"Ili-041141 VkId, ItA.`A),cjjI Ilidilikeell Wit II&CI, to 0
oo,
16a. 11,; ;t% lelkljb,h .111m.41 V) - - Vhr au -Ittly rtitirim-ly limly, thyl-1,1
1,1-itAlilithouquitiomor% %tilt I
11APICIINIQUilmmic IleatIA zoo
00 a kAll I'lulfit-. S.411. f i so. tr."', MIS" ill lilev. water after filtrationi and evapt'.. gave 31`~ .01 a t"Illpforso,
ddrd tO t; so
" F., practiml use, it it msdiri~l RhAt 2

. Theirs-
,tcld its, K all u1 II)VI. %%atcr at 40-5
`
w Najf.,~W C 1. jj~,ed stood Ijw .4,1 1 valid r
.00
;).
A. tilt, mil. '.1 CdbiviK.Kikkk Ws so dryvima, wtilumst _pu. .4 %,_ rho, ,.tit to 0
i-Iv d I ...... 1-1 md "t.a,lllv ~4. its %later
ot 1,h-% call for I)-.td fla"n mairf tor I IIACI, au_

00 Millis it 111fill loattlal 4%,lotlAIMMI 111111 its *0111
th h). juallild "ill' IICI Ylcld- 9h
r trTA1.1 "tail Itak.A. vicid, A I-PC.. %..I tit 110. KX0. in solid a dt-vis."Ifrt PPI.;
%trosits alLali plot%. thr quitunir
goo
KOIIr ,-Apt, 1d-mnpn.cf I III IICI 4
" illlt&'ItIY; CI 1,4,1- told, I., tra,- if K 2-nuothorl-1,S.
dectnill)[4 fUpsdIV tollIV.111 SAFIIIIIIII. With II.Cillost"..
Jfcvt, ill. rise incillistr ...,upl_ :;0 0
4 4 lid twist I-lit, otih livith. this 11111114o,% file I M Iti-alilirtil wish vastuu,; oftihifusm r&pWly
MI.
see
A.M. . Its.-I It 1., 1,1.1. 4m,,& it, lu'amble 'Ifts'Liltv 01, a
' C.
1l, woo
clullpirk .,14141 I"I'l, J tilt *sllto. I
00 .1 ,
Y
t:e
tie
ion $L k Oll"I'VVIK-L LITIIIII.4t (LA1111PICAIM).

-
'
~ IF 11- to _1M t
t
1
3 tv to N so a 19 it It ar Kw n I on
4:
00 0
0 0 0 000 0 0 0 0 0 0 0o000 0 0 00 0 0
0 * 0 0 0 0 0 0 0 0 0 00.0 0 00
10 0
0 0 0000410 0

1

SHCHUKIINAP L. A.
"Experimental Study of the Mechanism Underlying the Biological Action of
Quinones of the Vitamin K Type," Dokl. AN SSSR, 45, No.4, 1944

d; W EE It b C -j
I Sr' AND' 190_ O'?,gs
Condenuttda a
u
7
__
chlorobemene. I M and L., A-. i5ft_ch~L (Mtfi~
Ii
K
dtleev Chem.
l,"
qcrlx~._~, E.,
MIMR-) 19, DAY-Sul).
6Vhen 20.g.
'
quinotink acid.!s heated with 30 j.'Ailo at
iov 5 hrs. It
gives 16.6 j. of the anhydrW-. (F ), mA When 4 g.':
.
100,
1, 04 g. PhCl,"afid 14"g. AICI, are heated 2 at
I
triated with'. 70 ml.;110, and *.%team-disid.- to reinc
rve
PhCl, they,give 5.7 g. 3-p-ch1oro&=sqy1pkdioic arfd-'

HaO, sab, m. 16W, 9 fortned. Mhen H is Cry3td. from -.00
H~O it forms the monohydrate of the -free Acid, which

*
*4
after dr [picolinic.acid
gives ?-P-ddo~*Unzoy
ying.at 110
j (M), m. 147*., M forms a c amplex* Cu -salt.. m.'261*.; n 66
0 S
The Co. Nt, Fe Zn, and Ph salts are slightty's6l. -in U20"..
the Na, Ca, B~l and Al salts ate very's-A. Oxidationof..
M with atk. KMnOt gives p-ClCgMCOIH. MandSOC11- -
' < sue a
give a yellolk acid cWoride (M whlch~wilh N%-givies the
*
* 4
ve ring closttre
_ IV does rat giv
with AlCls
.4mkk m. 176
In FS; or PhNOs. . Ifeatinf 111 with 11,504 at ~W'. for 1
-
- Reduc-
tk. dvrs 10.8% V, in. 246; i.qCJ saU m. 201*)*.
-
k
M
N
U
ion V
aOll gives a green solu.: of the,
.
V
. dust and
regenerates V when
g~bydvocluinone which
.
ken aw.

3

SHCHUKINA, L. A.
"The Condensation of the Quinolinic Acid Anhydride with Chloro-Benzine,"
Zhur. prik. khim,., 19, No.9, 1947

SHCM KIN) L. A.
USSR/Chem-4stry - Quinones
Oxidation
Nov 48
"Oxidizing and Oxidizing-Hydrolytic Conversions of Organic Molecules: I, Hydrolytic and
Oxidizing-Hydrolytic onversions of Quinones," M. Ft. Shemyakin, L. A. Shchukin, Iab of
Org Chesp, Inst of Bio.and Med Chem, Acad Med Sci USSR, 19f pp
I'Zhur Obshch Khim" Vol XVITI, No 11
Discusses reactions of the hydrolytic and oxidative-hydrolytic clevage of quinones.
Submitted 2 Nov 47.
A 67/49T24

USSR/Chmistry - ed=wx Nov.~
Oxidation
"Oxidizing and Oxidizing-Hydrolytic Conversions of.
Organic Molecules: II, Oxid:Lzing-Hydrolytic Con-
versions of 1,4-Naphthoquingne and 2-Alkyl-i,4-
Waphthoqulnones," L. A.. Shchukin, A. P. Kondrat'-
yeva.. M. M. Shemyakin, IA3b or Org Chem, Inst of
Biol and Med Chem, Acad Med Sci USSR, 10 1 pp
Zhur Obahch Kbin' Vol XVIII, No 1.1
Prolonged heating of aqueous solutions of 1,4-naph-
thoquinone, and its 2-methyl*and 2-ethyl derivatives
led to the formation of phthalic acid. In addition,
67/49T23
USSR/Chemistry Quinones (Contd) Nov 48
phthiocol Vas formed from 2-methyl-1,4 naphthoqui-
none. Submitted 2 Nov 47.
67

ShChIf-KINA, L. A.
L. A. Shchuklnn. A. P. KondrRtievn nnd M. M. Sheminkin, Oxydizinp, and
oxydizine-hydrolytic tranFiforraptlons of orgnnic molecules. III. Hydrolytic
trannformAtions of 2-me thvl- 1-oxy-1,4-naphthoqul none. 1). 2121.
It is shown that the quinone ring of 2-metkvl-7-oxv-!,h-nar)hthoquinone is
ca-oablp of undergoing hydrolytic splitting. This oroceRs -nroceeds at boiling
of the oulnone with water if the -nH is above 7.
Lab. of Organic Chemistry of the
Institute of Biologic and Medical Chem.
Academy of Medical Sciences, USSR.
November 2. 1947
SO: j. Gen. Chew. (USSR) 28. (80) No. 12, 1948

USSR/Chbadstry 1,4-Naphthoquincine Tan
Chemistry Hydrolysis
cr:
"Oxidation and oxidation-Hydrolysis Conversions
of organic Molecules: IV, Oxidation-HydrOlyOIG
Conversion of 2-Metbyl-1.1 4-Naphthoquinone Oxidep"
L. A. Shchukinal A. P. KOndrst,'Yeva, M. M-
ShwWakin, Lab of Org Chem, Inst of Biol and Mom
Chem,, Acad Med Sci USM, 8 pp
"Zbur Obshch Xhim" Vol =, No I
Boiling of this compouhd with water ultimately
results in formation of phthiocol, 2-methyl-1,
4-na.phthoquinone, and o-lactyl-phenylglyoxylic
58 4
USSR/Chemistry 1,4- jan 49
Raphthoquinone (CaAd)
acid. Stud-tee the third compound and its cycliza-
tion into 2-oxy-1, 4-naphthocuinone. Submitted
2 Nov 47.
5~B/49T35

USM/Chenistry - Hooker Reaction, Jkr 49 r

"Oxidation and Oxidatioa-Hydrolysis Conversions
of Organic Molecules. VI, Study of S. Hooker's
cq Reaction," L. A. Shukina, A. P, KDndratlyeva,
M. M. Shemyakin, Lab of Org Chem, Inst, of Biol

and. )%d Chem, Acad Med Sci USSR, 11 3/4 pp I-A -A

'"Zbur Obahch Xhim" Vol XIX, No 3

In oxidation by an alkaline solution.of XM04,
phthiocol is subjected to a series of oxidative
hydrolytic transformations, vhich can.be intero
$~

rupted at the stage of f tion of o-p7ruv7l- 4
p4onylglyoxylic acid. Describes conditiodi.for
Cowerting the latter coMound to
4-riphtho-quinone. Discusses mcbsnism of
0
looker!4 reaction on the baslopf the expert-

a. -Submitted 2 Nov 47. z
~C.

62/49"
7N

C C

r.
r_ C 0

:
_

C 0
V, t.

L

ei
7 7-7

Oxidative end oldriative-bydrolytic changeir of organic
/molecules. MY. Hytholytic cleavage of 3-hydroxy-1,4-
riaphtholfuloone. L. A.-SkIlukhts.,.A. S. Khokhlov, said
M, M. Slamrskin. ZiNuir 064thel Khm. (J. Gen. Chrui.)
cf. C.A. 145, " WAA; 46. 109i.-3-
11. 9M
lfyd (1) readily splits on I al* *
PA In
aq- =at pit 7,7-9.2. yielding li-AtC.H.C064)" 1).
I'lie conditions and the nature of the cleavage of I art eiwn-
tl.,Ily identical with those of fattviati-Ir described reactions
-A :-nartbyli.-bydroxy-1.4-naphthoquinme (cf, C.A. 43.
441-rfh?. Aeration of a boding -oln, of 3 g. I in pit 7.3 phos~
pUte buffer for 414 hn. gives a red color anal acidification
Y1,14. I's S. I and I I g (10 7', ) U.1fO, tn. 72'-. a imilar
t".'rlion at pit 9.17 5'aye'lo""013. and t pit 0,K.)70 plithalic
,id, '12% 11. and unreacted 1, along with a black irlsol.
in,ater-Lil. At pit -4 in the absence of air. 4770 1 i4 rtvovered
mid 31m, n isolated. 11 formi a powly ~~I. Pb salt; the
i..Prlv .4. At saJ$ with Niel yields the Mt r5$": in. W."
,,,,,"a io-AmO). hydrolyated with 10% 11,SO4 in 10 min.
~c
2,. tl~ a jeawirarbavme, m. (munithydrate). It
with art. I,KI-NatCO9 )icklia T-17. CII I., while CrO, tatihia-
tion of II giv" 1.3-inilandionar. in. 131% pbthilk acid, and
1~c plathal . acid. Aeration of 1.4-oaphthotittinotic In
lottling 17c &q. NaOlf 8 lurs. gives a black 4oln. from which
a, i~olatrl 2001. phthalk acid, along with 0 91" plithalonic
u none oxide
.wid. IV Trarailfomastions of 1.4 J
I ~"i. 917-2.5.-The react ions of I,4-jta;A1hoq*;in,"ve owide (1)
I!, NAling in sq. scattas. were studied. The initially formed
giveol urailergon a 2-fold change: dehydration to:l-hydroxy-
1.4-naphtheaquialorte and oxidation to isonaphlbazarin. the
r~Lttivr f It roducts dcpc. ding on the corldi-
tkynA. 1~~th tubject to further thainge%
products art
under the conditions employed, the fomer being cleaved
to a-AeC4H,CVCOdI (11) in the ab%cnce of air at pit above 7,
white the naphthatatrin is changed in the presence of air
into a
products yielding ninhydritt. laydrindantin.
arid. Hence. the cleavage whemes of I
di~crr I- I of he 2-Me atrudoc. In the abionce rd.0,
It HtO 24 hari. gives a red color and working
'ling .5 ar
'he iv" I M g. an.
S .9 '~ 3 r i -C ijonaphiMfar;", in. 2R-". and D.Z., g.
a h, a i':~ Repetition for 4,14 firs. in a buffereal
at pit 7.40gntri'* Mrl.
11. anil a tractaildark tax. Doiluilg I in 1110 with acrA-
t Man X) hr% save 17% 22% ifiralaydrin. and
M- phthisdonic "I (isolated a, the quincatuiline deriv., tn.
_4'1 S1. the %epn. of the t4tter eutvt;an"~ being accomplished
,i.% the Pb all-: %mue 4% hydria",00s, in. '21219", was also
-,lated. If the reaction is run but 6 lirs M"", isonatalitha-
r.triq M frwm"i, lh~tjg with tracet (it (111thalotlic acid (6o-
LattJ as the quitiovalint deriv 1, G M K~IajxuT

Oxidative and oxidative,hydrelytic tiansiormations ot
organic molecules XVI The, oxidative-hydrolytic trans.
formation* of 2.3-d1hydrozy-1.4-naphthoquinone and I.I.-
3. 4-tetraoxotetrahydronaphdWene. A %i, Khokhlov. L, A.
S'whokttiiL. And M. M. Sheinyakin. J. (;e-. V,S -
4W-If, C.A. 46,
i XVIT. The oxidativii-hydrolytic trandomstions of
substituted hydroxytisplithoquirimet. 11, 11. VitkovAfl
A1111 M M. Slwtuvakin. Ibid. 1131-41--Sce CA, 46.
15~., Id B R

USSR/Chemistry - Quinones , Jun 51
"Oxidative and Oxidative -Hydrolytic Transformations
of Organic Molecules," A. S. Khokhlov L. A.
Shchlakina., M. M. Shemyakin, Lab Org CheNInst Biol
and Med Chem, Acad Med Sci USSR
"Zhur Obahch Khim" Vol XXIJ, No 6, pp iol6-1033
Studied conditions~ character, and mech of above
reaction on 2,3-dioxy-1,4-naphthoquinone (i-
naphtliazarin) and 1,2,3,4-tetraoxotetrAline. In
presence of oxidizers and hydr~i~,zing media these
ccmpds can undergo number of alternating oxidative
and hydrolytic reactions which are additionally
186T21
USSR/Chemistry - Quinones (Ccntd) Jun 51
complicated by transformations of intermediate prod-
ucts,, Detd basic stages of t)As type of processes
and their dependence on pH of the mediun, on temp
and on presence of oxidants.
186T21

L. A.
USSR/Chemistry Biological SeP 51
"Oxidation and Oxidative-Hydrolytic Conversion of
Organic Molecules. XVIII. Synthesis and Proper-
tles of Certain Quinone Oxides," L. A. Shchukina,
Ye. I. Vinogradova, M. M. Shemyakin, lab Org Chem,,
Inst Biol and Med Chem, Acad Med Sci USSR
'ITZhur Obshch Khim!' Vol XXI, No 9, pp 1661-1667
,/Synthesized several oxides of 1,4-benzoquinones
an.di,4-naphthoquinones; studied certain of their
namely, their oxidizing ability and
for,being converted into esters of
-,.)-,-!sp3nding glycols.
19 1 T47
19-1T47-

!S
Orl
USSR/Chemistry - Biological SeP 51
"Oxidation and Oxidative -Hydrolytic Conversions of
Organic Molecules. XIX. Relation Between the
Degree of Oxidation of Carbocyqlic Compounds and the
Capacity of Their Ring Groupings to Undergo Hydro-
lytic Splitting," M. M. Shemyakin, L. A. Shchukina,
Yu. B. Shvetsov, D. P. Vitkovskiy, A. S. Khokhlov,
Lab Org Chem, Inst Biol and Med Chem, Acad Med Sci
USSR
"Zhur Obshch Khim!' Vol XXI, No 9, pp 1667-1677
Clarified principles and nature of relation between
deg of oxidation and capacity for hydrolytic split-
ting. Showed expediency of use of concept of
191T48
USSR/Chemistry - Biological (Contd) Sep 51
oxidative-hydrolytic conversions in study of oxida-
tion of carbccyclic :tnd acyclic compds,
191T48

3i:C',JJKINA) T. A.
U351R,,Chemistry Antiblotics I Aug
f Alrho-Dicblo--ottoetylemino-bete-4tdmxy-P-NltroProPlo-
,tmthools and 'rorartles o -
pher,one WI.E.m. Badres, Ye. 1. Vinogradovas D. H. Vitk-ovakiyo A. 3. n4khlovt
Yu. ZB. Imtf;ovp L. A. Shchukin,,,, Inst of Biol and '.VI Chomp Aced Med 3ci USSR
ItIkk Ak flauk SSM" 701 aXIX9 go 49 PP 601-W3
It was shown reoently, that I is an intermediate proluet of the enzywtic spl-ittIng
of chloromycetin by bacteria (G. S. 3mith, C. ". .~brrel, Arch Blochemg Vol LIME,
i9 232j, 2'60). In the present workg I wrs ayntheslwd. Gives a description of
the synthesis.
PI 2UTZ?

5HCHUKIAIA, LA
Cliemical Abst.
V01- 48 No. 5
Mar. 10, 1954
Organic Chemistry
MS
kAk.4- Y'#," taw L4& ~W)j -
Qv
A~IA,fi" and oiddatilb of'
or h I LC 111-d-110-
- .9 -.4A-
xx
chew.-UZITR. Zv. W57-rrKMILISnjg'P-tftn tjon).-See?
CA-41.2741e. . Hydrolytic ties of 6-methy14-L
hy none- L- A Rebt7dri. tbid, 7334.
8. See 47, SM. XXH. Hydrolytic nd oxidative
of I 4-dlhdMq40dwL
010 =1 M. M-9hem
i;,E;ft
XM Me, ftm In the
wd hydrolytic trandormations 61
'ffi~%, I MI.-D M. M.
ING. I &W. 7Q*-W. M7`5379q. '
H.

USSR/Chemistry - Quinone5 Apr 52
"Oxidative and Oxidattve-H.vdralytic Transformations
of Organic Mblecules, XXI. Hydrolytic Splitting
of 'C'.-MethY!-3-Hydrox.;-1,4-Betizoquinone," L, A
Shchukina, Lab o~ Org Chem, inst of biol and Med
Chem, Acad Med Sct USSR
"Zhuxr. ObshchL Khim" Vol XXIII, No 4) I)p 668..675
The above process takes place in 2 9tages.,. hydro-
genation and subsequent hydrolytic splitting of
the ring grouping of the intermediate hydrogena-
tion product, The structures of the intermediate
and of the final compd are described. Comparison
of these results with data previously published
224T45
leads to the conclusion that the hydrolytic
splitting of the ring grouping is characteristic
for all oxy-1,4-quinones of the benzene, naphtha-
lene, and phenanthrene series, which contain a hyd-
rogen atom or alkyl radical in the 2-position or
a hydroxyl group in the 3-position. The mechanism
of the reaction was proven experimentally.
224T45

SHCHUXINA, L. A. -, C k-,-
1~ Alva if synthesis 4
of ouliale" Whick rMosin
outliml. D- or "?*&
O"Nsifief (1) treated with
of the Carvespooding 4Y.j
(ftam MOH), (alij -1
WV 1210; DWorm. 0.
duced with It over active
Wri"thetle paths for prepn.
tkitrits Other than NO' Am
mod OAN NaOH gave 70,
i
Fft. M; D40M. M. ITI
MeOH). L4orm. m. 1711,
1 (k~m Rtoei).. These, M
it age 0d 50 atm., gave the
~'Mjl 19 96% Yield: D-IMM.
i7FF, wv -100' (MeOlf). L-form. a. 1710# folV
99% ix-Form. m. 1520. Dhodionitina of 1111 at "* In
110 or 1:19901 (3 hm.) And hvinama with the customary
U
L" P
Is the b"WW foollows: CUCI pvc
;5
75 tep.=~m. 1172".k1o'J"jo"30; the D-$*$SWF, M.
177. jai W -103'. CI in . adot. after 12 hirs. at 0'.
followed by treatment at SDO, ova flovisdau";
zi-jories. ou. 179% JaIV -W*; L-invow. M. I lailif 86
ps.-Jorvor, in. 174'. Heating to 70-901 04 br. at
gave the p~110 owleft- L-6m,
IOIV 103*- CUCN Al PH 7 Sold -5* gave AIM P-NC
dcdv.; "arm, 0. 14W. Idol "0"; !:fT. 90- 140%
WIV -130*. NSAOb W" = alk 16 go- 22% 10--
MA4s "V.. L-fam. donnomp. 1434". ImIV W'. Treat-
samt th Z
wi tollilca IPVV the sumbdiiew "now L4ovft.
m.l8fl*,jaIV99'. These corninis. M an relill"Ing Severai
Jon. with 20% HCJ fait the N-Bx group aud yiddel p-
zC.1464014CH(S115C11,011 or the threo type al follows
f (zililms): aw%: L-torm,m. 147% fall,,' 9-51; ti-form,ni.
147 ", fal lot -34 *o ledo M% - - L-form ' no. 104', [a) 20424%
D-form. M. 104': COJI. GS~o: Woral. decomp. 349-J)".
I.)qj 33,; 0-forni, decornp. 34S-O'. I~IV -32'. The
former 2 substances heatvl Melly with C1.CllCOz.Nle at
-jkj-. or the la3t substance treated at 5* Irith CI.C11COC).
gave the X-diWaroacetyl deriur. P-substituclit shown);
. 47%: L-form. M. 93% fa)V n4orm. m.9 3%
a V go. DOorm, m. 120% [ad*, 721 . L-fonn. M. 1041.
I
a Ij -11% D-form, rn. 104', In) 10 ; DL-f M . M. M%
H, 70%: L-form. M. 191% Y-189 -14'"; "orm. m.
Racentates obtained by mixing the L. and
a-forms at the P~a or p-iodo derivis. were ideat" with the
Cl at iodo "alis of chloromphanical, thus %flowing the
_r servistion, of thirco-structure. The 2nd route was as
=wt. Hydrogenation Of 0- Or L4 gave 9ek of the corm-
sponding p~HN derivs..- L-form, m. 130' al',? 28*; D-
. r
tam. m. 136". WV -20'. These with Cl-CHCO-.Nfe lit
MeOff after 24 hrs. at 18-23' gave the 2-dickloroacrianjido
derivs.. Millet! as 11C1 sails In 25% yield: L-fOrM. (aIV
-9% D-form,jJ-.S*. These diazatized rapidly and were
cm-werted eouventicinully to the following derivs Cf.
idesitical ivith th it it, cribcd above; p-CN; &.1%, L.U..
M. 136*. [-)~! , 1""'; D-10rM. W. 135*. Jelly 15* (by-
7drolyzed to ih,- 0.: if analog. identical with that dL,
sciftea above. :io,leriv., 48%: L-form, on. 136', 1.
jV
tiiorim, M. 1.56" liz)v -90. G. 14.
t

SHERYAKIN, M.M.; RAMDAS, E.M.; VIROGR&DOIIA, Ye.I.; K&RAPICTYAN, M.G.; KOLOSOV, M.N.;
KHOKIEWV, A.S.; SHVXTSOV, Yu.B.; SHCHUKINA, L.A.
~,-,*rx!
Research on the chemistry of chloroaWeetin (levomyeetin). Part 2. Study of
the courne of 8ynthesis and the synthesis of optically-active analogs of
chloroWcetin (levomycetin). Zhur.ob.khim. 23 no.11:1854-1867 N 153.
(MLRA 6:11)
1. Institut biologicheakoy i meditsinskoy khimii Akademii maditsinskikh nauk
SSSR. (Chlormweetin)

LESSR/Chemistry - Antibiotics 21 Mar 53
"The Structure of Aureomycin and Terramycin," M. M.
Shemyakin and L. A. Shchukina, Inst of Biol and Chem-
istry, Acad Med Sci USSR
DAN SSSRY Vol 89, No 3, pp 499-500
Carried out the final step in detn of the structure Pf
aureomycin. The N(CH )2 group was found*to be located
in the 10 position ang not the 6 position of the tetra-
cyclic nucleus. This was concluded from behavior of
the compd towards HI. Using an analogous method, ter-
ramycin was found to have the N(CH3)2 group in the
10 position.
272T3

ST&MYhKIIi, M.M.; BAMDAS, F,.M.; VINOGRADOVA, Ye.I.; GUBERUIYEV, M.A.;
ORiXHOVICH, V.N.; KHOKHLOV. A.S.; SHVETSOV, Yu.B.; SHCHUKINA, L.A.
Research in the chemistry of chloromycetin (levomyeetin). Race-
mization of P-threo-l-(-OL-nitrophenyl)-2-dichloroacetylamino-1,3-
propanediol. Dokl.AN SSSR 94 no.2:257-259 Ja 154. (MLRA 7:1)
1. Chlen korrespondent Akademii na-ak SSSR (for Shegrakin).
2. Deystvitellnyy chlen AMN SSSR (for Orekhovich). 3. Institut
biologicheskoy i meditsinskoy khimii Akademii meditsinskikh nauk
SSSR. (Racemization) (Propanediol)

Theoraticall basis of oxidation-hydrol ic transfoquationsCH!
of' organlc cg!gnoundo M. 14; U111 Rud
"4215"M S
hemIxIna. vaprory Afilm. Asm,74K . I
prIVmmVr-,fpmabnosti, Akad. Nook s.s'sR., Wel. Xhim.
Natsk 1955, 757-0,1.-A brief dlsws~ion* of the Ossible
utechanisms of oxidative hydrolysis reactions in the field of a
naphtho- and anthraquinomes. 33 references.
G. M. Kosolapoff

SHEMYAKIN,M.M.; KOLOSOV.M.N.; KARAPETYAN,M.G.; BAMDAS,E.M.; SHEVTSOV,
Yu.B.; VINOrsILADOVA,Ye.l.; SHCHUKINA,L.A.
Investigation of the chemistry of chloram-phenicol (levomycetin).
Synthesis of new optically active analogs of chloramphenicol
(levomycetin). Zhur.ob.khim.25 no.6:1199-12o6 Je'55. (MLRA 8:12)
1. Institut biologicheskoy i meditsinskoy khimii Akademii meditsin-
skikh nauk SSSR.
(Chloramphenicol)

SHCHUXINA, L.A.
Treating hymenolepiasis with acrichine. Wd.paraz. i parez.bol. 25
no.4:301-302 O-D '56. (MLRA 10:1)
1. Iz protivomalyariynov stantail Kirovskogo rayons g. Kuybvehava
(zav. stantsiyey K.O.Maerobyan)
(QUINACRIM. therapeuticuse,
hymenO16DiaBiS (Rus))
(TAPSWCRM INiMGTIONS. therapy.
hymeaolepiaBis, quinscrine ther. (Rus))

SHCIMKINA, L.A.; SEMKIN, Ye.P.
Oxidative and oxidative-hydrolytic transformations of organic molo-
cules. Part 25: The hydrolytic and oxidative-hydrolytic cleavage
of 2-phanyl- and 2-benzYl-3-hydroxy-1, 4-naphthoquinones. Zhur.ob.
khim. 26 no.6:1695-1701 Je 156. (MIRA 11:1)
l.Institut biologicheskoy i meditsinskoy khimii Akademii meditsinskikh
nauk SSSR.
(Naphthoquinone) (Chemical reaction--Mechanism)

SHCHUKIIIA, L.A.
Oxidative "and o'xid'ative-hydrolytic transformations of organic
molecules. Part 26: Preparation of triketocarboxy-lic acids under
the conditions of the Hooker reaction. Zhur.ob.khim. 26 no.6:
1701-1707 Je t56. (MIRA 11:1)
l.Institut biologichaskoy- i Meffisinskoy khimii Akademil MditsinBkikh
nauk SSSR.
(Acids, Organic) (Chemical reaction--Mechanism)

4
SHCHUKINA, L.A.; SED94YAKIN, M.M.
Oxidative and oxidative-h7drolytic transformations of organic mole-
cules. Part 27: Tautomeric transformations and properties of
hydroxy- and chloroketocarbox7lic acids. Zhur.ob.khim. 26 no.6:
1708-1713 Je 156. (MIRA 11:1)
(Acid% Organic) (Tautomerizm)

maIA, L.1k.

I't

X-i ~t4~

t-b4dative and oxidative-hydrolytic, trinsforruatib"-ari
organic mol "cas. - XXV - Hydrolytic and oxidatiVC4
'
,
4-nIL
Iyticcleava of 2-pbeftyl d 9-b"TUIA-hvffr.~J
-RnVu
!~WI956)(En"gjish translation).
ClItig. UIZW.-4,
mtlon of trloxo'car-- -
Pm
C
A
St
1920h
.
. -.1.
.
.
p
boxylic &cJdq under conditions of Hooker reaction. L- A
-Shchuldna,
Tautomeric b-ansformations and properties of hvdrwry and
-
cfklbr6 oxe b
U cids. - L. A. Shchul-ima ind M. M.
7D0 ca
-See C.A. 51,1021A
Shemyakin 1915y

nil

USSR/ Phyrical Cheniftry MolociilQ. Chemical Boild. 13-4
Jjur Rcferat Zhur - lGii-ii.,-7a, N, 3, 1957, '1233
Au-'-.hor Shigorin, D.N., Shem)W~in, M.I.I.,
Kolosov, M.N., and Mcnlulyevich,'F.".
Inst Academy of Sciem_,es USSR
Title On the Nature of the Litrarlecular Hycirogen Bond
-L956, voi ic8; No 4, 612-675
Orig, Pub FYjkl. Pal 3SSR;
Abstract The Ili ~;p-_-(Ara of mol(~~ul_,u with intrtu-iolecular hydrogen
bonds (11B) involvi.ng differcut degrees of participaLion
of the ' -electrons of the C 0 group and of the multiple
bonds conjugated with it have been investigated. The fre-
quency of the valence- v-.brations of -the O-H groups (the
first number in narenthesez, in cm -1) and their shift to-
wards longer wavelengths in comparison to the unassocia-
ted OH p:oups sccond attriIber in parentheses) as well as
the BH enei-Ly ~Bad --er and Dauer, J. Cheri. PhYs -, 1937; 5,
839) (third iiurfoer in rare.,Ahesos in kcal), the
Card 1/4 - 29 -
-------------------- -------- ----------------------I------------------------------------- -------
ber in parentheses in A.U.) have been determined for the
following compounds: the vapor of the nonomethyl ether
of ethylene glycol (I) at 120-12200665, 0, 0' 0' - );
I in CC11, (II), in the ratio 1:400 (3605, 6o, o.96, o,
1.80); phenol in 111 1:400 ratio (3605, 0, 0, 0, -); gu-
aiacol in 11, 1:400 (3530, 55, 0.90, 0, 2.20); oxyoctenol
in II, 1:4oo (3475, 14,(, 2.38, 59.7, 1-95); benzoin in II,
1:400 (3468, 147, 2.39, 60.0, 1.95); 2-hydroxy-1, 4-napht-
hoquirione in 11, 1:400, 3398 (187, 3.07, 68.7, 2.25);
2-benzYl-3-hydroxy-l, 4-i~a!--hLhoquinone in 11, 1:600 (3395)
190, 3-il, 69.1, 2.25); 2-(',..-napli-thyl)-3-hyd-roxy-1, 4-na-
phthaquinono in 11, 1:0600 (3370, 215, 3.52, 72.7, 2.25);
)-. -riethyltropinone -in 11, 1:1,00 (3110", 504, 8.19, 88.2,
Card 2/4 --)0

USSRI Physical Chemistry - Molecule. Chemical Dond. B-4
A.bs Jour Referat Zhur - 10iirdya) No 3., 1957) 7233
2.25): vapor of the wnwetbyl ether of trimethylene
glycol (III) at 1600 (3650, 0, 0, 0, -); III in II,
1:4oo (358o, 70, 1.12, 0, 1.65); o-rethoxybcnzy1 alcohol
(IV) vapor at 163-164o (30552, 0, 0, 0, -); IV in II
i:4oo (3585, 671 1.08, oj i.65); diacetoile alcohol in II,
.2
1:4oo (3524, 94, 1-52, 26.' , 1.65); methyoxybenzoic acid
ill 11, 1:400 0357, 228, 3-74j 70-0j 1.65); salicylic
acid vapor at 1440 (3265, 320, 5.25, 78.7, 1.65); salol
in 11, 1:400 (32301 355, 5.82, 80.71 1.65); methyl saiLi-
cyl-,tc in II, 1:4CO (3205, 380, 6.23, 82.0j 1.65); ace-
tylacetone in 11, 1:400 (3050, 570, 9.26, 87.9y 1.65);
nonomethyl ether of 1, 8-dihyaro%ynaphthalene in II,
i:4oo (3431, 189, 3.o7, 63.5, 1.63); 9-hydroxy-l-netho-
XY-7-OXY-9-rie'l~hyl-5j6,7,8-tetrahydroanthracene in IIj
1:6oo (3620, Oj Oj 0, -); 10-tydroy.-y-l-,-~etho;-f-7-OXY-9
-i-,Ietl'Yl-5,6,7,8-tetrahyclroanthraciiie in 11, 1:400 (3423,
197, 3.20, 65.0, 1.63); 10-hydroxy-l-methoxy-g-nethyl-
Card 3/4 - 31 -

USSR/ Physical Chernstry - Molecule. Chemical Bond. BA
Abs Jour Referat Zhur - Ehiiuya, 110 3, 1957, 7233
5,6,7,8-tetrahydroanthraceiie in 11, 1:400 (3425) 195, 3-
16Y 64.5, 1.63); alizarin vapor at 29CP (3150 ( -,\ ),
470, 7.64, 85.3, 1-65); 1, 8-dihydroxyanthraquinone
va-por at 3000 (3150, 4,7o, 7.64, 85.3, 1.65); On the
basis of the data obtained, the authors conclude that
the magnitude of the f~, -electron interaction energy
depends on: (1) The presence of a system of conjugated
bonds comprising both the HB group and the rest of the
m,olecule; (2) An even number of terms in that system;
(3) The planarity of the HB groups and the other parts
of the rnlecule; and (4) The number and nature of the
distribution of ; -electrons in the system.
Card 4/4 - 32 -

SH&MYAKIN, M.M.;
Theory, of oxidative and hydrolytic conversions of organic molecules
Lwith summary in 3nglish]. Biokhimtia 22 no.1/2:214-225 Ja-y 157.
(MIRA 10:7)
1. Institut biologicheskoy i meditsinskoy khimii Akademii meditsin-
skikh nauk SSSR, Moskva.
(CHEMISTRY, ORGANIC,
theory of oxidative-h7drolytic conversion of organic
molecules, review (Rua))