SCIENTIFIC ABSTRACT SHCHEGLYAYEV, A.V. - SHCHEGOLEV, A.F.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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Expe rie n c, ecf T;)j:-b~ PrOc;ess az a ~Vflole, sliouid .1onsidered SatisfaGtorv. By compar:Lng agairi Fig 5 a,-rd 8 it is :;onc,iuded that the differentiator ti-me, wa--- t-C-0 Small i1a tilis latter case and tlLarat it should Iliave been of the ovdaer of 1.0 tc-, 1.1`5 sez~ C-overnor rerfoi:mance cLix-ves -for a turbine of 100 when fi.;Cil load is dropped, constructed by a semi-graphic~ul method al-- given in 11'ig 9, The various assumptions made are explained azid it is shown that the ~czaape of the -ur,-,..--s is very close to the ex1jerimenta! ones , It -Js aj,:,~a3-nn shG-,;vn that, the bes-It ouera-ui_r,6, -,iae of -the differentiator is abcut. 1.5 sec. .L 1Z is concluded .-IL-it -c-his system of go-verninp-, which i.,~ of hi-1.1 and haj a link, Card 5/6 ~--2-2/38 of -100--2 I! C, a. -L J:';~ Uuynam I c Pro -p e r-t- ~3 LF-! 7; et De (Mlos-c-w i)cl. ao r ut,~ Card C- sov/96-59-6-1/22 AUT"HOR: Shcheglyayev, A.V. (Corresponding Member of the Ac.Sc. USSRJ TITLE: Some Problems in Raising the Efficiency of Steam Turbines (Nekotoryyezadachi povysheniya ekonomichnosti parovykh turbin) PERIODICAL: Teploenergetika, 1959, Nr 61 PP 3-8 (USSR) ABSTRACT: There are two main ways of increasing the efficiency of turbine sets; either by using an improved thermal cycle with higher steam conditions, reheat and so on, or by increasing the efficiency of the actual turbine and auxiliaries. The increased efficiency of condensing steam-turbine sets that has resulted from improvements in the thermodynamic cycle and increases in the output will be seen from Table 1: -it gives the specific heat consumption and efficiency for a nimber of large steam turbines. The actual gain in efficiency will be somewhat lower than the tabulated values because of the higher power consumption of feed pumps at the higher pressures. The efficiency of turbine stages largely depends on the volumetric steam flow, which may be quite small in the Card 1/7 high-pressure stages. It is therefore advisable to increase the turbine output when increasing the stop- SOV/906-59-6 D-1/22 Some Problems iri Raising the Efficiency of Steam Turbines valv(i -ter im pro:3.,uro. As a rough general rule, the output of a condensing turbine 9xprej3,)d 1r, ffiqgaw~;I;~:" -0, 3000 r.p.m. should be equal to or higher than'the stop-,rairre pressure measured in atmospheres. The selection of "ating stages is then discussed. Single-row regu~ regulating stages are to be preferred for large condensing turbines and also for condensing turbiTlles operating at temperatures of 600 OC and above with .-eheat. Variations in the efficiency of regulating stages 1when the steam supply is partially cut off are discussedt efficiency data for single- and two-row regulating stages operating under different conditions are given in Table 2. The data relate to a stage 6.00 mm diameter with a nozzlc- height of 2.5 mm. In the development of regulating stages most attention has been paid to reducing the --'Losses in the flow path, and efficiencies of 0.75 to 0.8 car. be achieved at 'full steam flow in a two-row regulating stage. Much) however, car, st-ill be done to reduce the losses when running with partial steam supply. It has recently been hown that the end losses in turbine blades may be st-Lil Card 2/7 fsurther reduced. This is important for regulating stages SOV/96-59-6-1/22- Some Problems in Raisin.." the Efficiency of Steam Turbine~-- and for the intermediate stages of high-pressure cylinders with small blade heights. The improvement is expected to result from making the nozzles or guide blades with channels that decrease in width towards the perimeter, which is termed meridional profiling. By these means 4u,,h%-;, end losses are reduced and the stages have practically constant reaction over the radius, which reduces leakage losses. The importance of these effects will be realised from the data given in Table 3. The efficiency of active turbine blades of small height may be increased by special profiling of the inter-blade channels, In blading in which the relative height is small and end losses are very important, secondary flow can be reduced to a minimum by making the inter-blade channels first exDand and then contract, In such channels the velocity decreases where the curvature is greatest, and the cross- gradient, the pressure and intensity of secondary flows are all reduced, The available test data in support of these contentions have all been obtained under static Card 3/7 conditions and should be confirmed by tests on experimental turbines. Leakage losses are pLrticularly SOV/96-59-6-1/2-2 Some Problems in Raising the Efficiency of Steam Turbines important in high,-pressure stages5 not only at the glands but also at. 'Lines of contact between different parts. Leakage is sften caused by thermal deformation of the turbine casina, especially during heating up and starting- It is particularly important to design the high-pressure casing in su~,--.h a way that deformation is strictly symmetric~al both during heating up and running aryd so that bending is red-aced to a minimum. Only in this way can the necessary clearances be maintained. Difficulties are exDerienced with the mechanical strength and effi.- ciency of low-pressure stages. The design of low-, pressure stages is discussed and it is stated that, if the discharge -velocity loss is restricted to 8 kcal/kg, then the flow through a single exhaust is that which corresponds to a turbine output of 100 MW. If the output is greater than 100 MW it is necessary either uo increase the namber of exhausts or to permit higher discharge velocity loss. It may be possible to increase the output of a single-flow turbine and to reduce the exhaust losses by using light metal such as titanium or Card V7 synthetic materials having low specific gravity but ;3OV/96-59-6-1/22 Some Problems in Raisin,-, the Efficiency of Steam Turbines satisfactory mechanical and fatigue properties. Soviet turbine works are investigating this subject. It is, of courseq difficult to make a low-pressure stage efficient because the degree of reaction and wetness of the steam are very different at the blade tips and roots. However, the main reason why the efficiency is not higter is -that hardly any experimental -work has been done on these stages, The investigations are difficult because they must be made with steam and not air. and modelling is complicated by the blades and the dis~,s of the model stage being subject to the same stresses as in a full- scale turbine. Not enough is yet known about the thermo- dynamic and aeTo-dynamic properties of saturated and wet steam. Moreover, procedures for testing the stages operating on wet steam are not fully worked out. Loc-al ,ralues of steam wetness cannot yet be measured. Recent'ly, &-ittention has been paid to the exhaust casings of turbinas.-, which may be so designed as partially te restore the pre33ui~e beyond this last stage. It was Card 5/7 found by tests on models that the use of an axial or diagonal difff)_,sez in the exhaust pipe combined with a SOV/96-59-6-i/22- Some 11-oblefii.,' in Raj.'zLng the. Efficiency of Steam Turbinez, -3yq 'ba zonvert 10 - 20% of the exhat..;': . , t e m, of 7 _. .. - Y"Linetic; ent-_-i-gy Jz.!~,tt) pc-'-'ential energy. Furthe-z' impro-~la- Mer_';3 irl rjii-.,~,ction are to '-e expected, The--,,e are. -1-ndica' ions t--.,a-,. li-.w-e steam governor valves have 11-igb vhi(,h !-,.-.ay te -reduced. by suitable ar -rang ement -he low ir. t'ne t:.hest -nd by improving the. shape 4. , f " '- - -, C. o 'L 4L-be val~il;--, ---nd rL-;_fi'~ser. Tmprovements are required in th.e rotal~i.n,;! dj_a-rhra:!-ms used on W4 th controlled Pass-o-ats, Is knc-~,.,rj abc-~ft the prcpelrties (~e-ji_-es, 1cl-o-vi-led-e o,:-1 turbine blading ~~hcnjld be present,~~d in a forr, ~-.Atable for uss in the t4 (, Theore L'aj dc-_:;i- methed's sh"ould be more wideiv appli.a0l. in the la'_-Icrat-jiries andi this. will be facilitated by the Use of ~,ompaters, Or4e of the first steps in ~~kp, -!_ng sl;ricter met1lods of calculation should be the generallisa- tion and systematisatien of available experimentai- datla. Further study is required ozi questions of modelling and criteria of similarity. it is most important w-her. mak-ing, L 11 f'ull-scale tests in completed turbines to have the Ca.rd 6/1 participation of the labo-_!~atories interest-ed in t_'-e- fl,---w paths of turbines and responsible for the improvements i-_- sov/96-59-6-1/22 Some Problems in Raising the Efficiency of Steam Turbines the machine under test. Special efforts are required to improve the accuracy and reliability of full-scale tests on turbines. The aero-dynamic investigations which have 'been made on steam turbines should also be applicable to gas turbines, which may be expected to develop considerably in the coming years. There are 3 tables, no referenGes. Card 7/7 SHIM, Yakov Isidorovich; SUCHEGLYAYEV, A.V., doktor telr.1m.rwuk, $-'f . . I retsenzent; SHAPIRO CS - --kd-nU-.-Vekhh.-nauk, red.; BYSTRIT-WAYA, B.B., red.izd-ve; MOIMI. B.I., tekhn.red. [Gas turbines; theory and design] Gazovye turbiny; teoriia i konstruktsiia. Moskva. Goo.nauchno-tekhn.izd-vo mashinostroit. lit-ry, 1960. 560 --n. (MIU 14:2) Was turbines) BZFEAII , L.D., doktor tekhn.nauk; RUBRISHTEYR, Ya.M., doktor tekhn.nauki SHCHEGLYAYEV, A.V. Selecting the optimum cross section dimensions of the exhaust and the number of shafts for 300 to 600 Nd gteam turbines. Teploenergetika 7 no.10:14-22 0 160. (MIRA 14:9) 1. Voesoyuznyy teplotekhnicli6skiy institut. 2. Cheln-korres- pondent AN SSSR (for ShcheglyRyev). (Steam turbines) BERMINY I.D.9 doktor tekhn.nauk; RUBINSHTEYN, Ya.M., doktor tekhn.nauk; SHCHEGLYAYEV) A.V. Reply to I.V.Shapiro, A.E.Gelltmah, and D.M.Budniatskiilo article. T loenergetika 8 no.8:13-76 Ag '61 I!T ~4:10) (TU*ne:5 (Electric power plants) Nhapiro , (Gelltman, A.E.) (Budniatskii, f.m.) SHCHEGIYAYEV, Andrey Vladimirovich; %IELINITSKIY, Sergey Georgiyevich, dots.; &JLMI, A.Ye., red.; BORUNOV, N.I., tekhn. red. [Control of steam turbine operation] Regulirovanie parovykh turbin. Moskva, Gosenergoizdat, 1962. 255 p (KRA 15:5) (Steam turbines) S/096/62/000/003/001/oo8 E 19 4'/C' 4 5 5 AUTH(-i":, A Y., Corresponding Member of the AS USSR, e ch, M.Ye. , Doctor of Technical Sciences, Professor, F I,Jlippov, G.\., Carididate of Technical Sciences T 1T L'. 'k"he design of steam turbine stages, frow the results of static blowino- tests on rows of blades D]. 'Ieploeaergetilka, no.3, 1962, 1-11-18 Ti-zo -.-ethods are in comi.-ion use for designing the t~low p-aths ctirbiries. Oiie is based on the use of generalized graphs oot0inud fcori the tests on stages. With this method the are simple and reliable for the given -type of blading, '111CI V-~~.rious generalized graphs have been produced. The second is o73 ti'le use of the energy loss factor and flow factors in gul.J(? and runner blades, either derived from static tests or from the velocity triangle. This method is also plirticularly with new types of blade. A -wealth of -test resuits is now being obtained on blades in straight bundles, giving botri a ~:iialitative view of the flow structure in various kInds of loss, anglez acid flow ~-Ind quantitative clial-acteristics for- Ca, r a _L S/096/62/000/003/,001/008 i r1 F19VE4~ 1"I L' Z. J 1 1,1~; oi !-afioiiiil 1j).ide proCiles has bciell built up Ovur a zmml)er )I' years, Lhe Kafedra pi,.rovyk.1i t,m-hiii (Dep,trtment oV Steam and Gas Tilrbines) of NET hos -itudlies uV I'low in turl)ine blades, ii~~;inq boLb Clat cond annular stationary models. Moreover, the Ulatles teSted were run in experimental turbines to obtain rt--1ationships between efficiency and velocity ratio, usin'. both .-;Upe_rica~ed zsteat:i and air. The results so obtained can bridge tl~e 'r._Lp between the losses deteri.,iined in static tests and the eff-ic-i-ency of actual stages running on steam. A number of loss cuz-v~~s obtained with various kinds of stage with different kinds of test are plotted and coi-iipared, and results are also ~,~.iven for a :)f a turbine consisting of tliree stages. The results lo.u,l to the -Collowing conclusions. When the design of single-row s t j2 4 L.. based on the results of static blowing tests -.:;n flat Liitidle.~ of' bludes -,viitii an irregular velor-ity distribution and in of overlap, there is satisfactory agreement with I z-z~ in expevirriental turbines in the region of low vel-acity r C1 opt-'..jjurj v.-Al.u(.s of u/C. ti-Le divergence between s/oq6/62/000/003/0'-'tI/008 Th E194/E455 I %, 1, t e (I v.,-k ti eA .9 1 - 5 t, 0Generally, a s- c v re I _i a 1, 1 e resit I t ca n b a ob t-I ine d- hy mul t i p! yn~~ t,.-,e c,i-Lc!-,.;-:ited uff-iciencv by a correction factor of 0.98 to 0.97. ~-~z IcLi--:itirig ~he stage efficiency from the loss factors given ir, t~-e -.tlot.-3 of blade profiles, the correction factor is 0.97 to in thie zone of optimu-ni velocity ratio. For wheels two i-o-Ivs or' ',)1;7tde,5 the correction factor is 0.97 to 0.95 1-then the c:iJ(-.iiI.0A(-,ns are from tests carried out with allowance for Jrre~r-i:L---irity of velocity distribution and for overlaps. When the.- low~s I-wictors given in the atlas are used, the correction factor sho~,.Itl he 0.91) to 0.92. The least divergence between test and cM.cul:ited -'ata is obtained in stages with long blades, which ind-icates that end losses in the blades are not beinr ; sufficiently alloi,i-ed for. Correction factors for relating the result of tests on st'-Jges in experimental turbines to calculated values from static L~Io~-dn~g tests are valid for stage.-3 manufactured with welded C', j a T.I. Ir I , . ~Jqins The results given in this article are only a first ster ir j j~ relating the results of static tests to total losses determined in an experimental turbine. Further material must be Card 3/4 S/096/62/000/003/001/008 The of steam turbine ... E1911/E455 accuniulated to improve the reliability of turbine stage calculations. There are 7 figures and I table. card - - SHCHE,GLYAYEV-,-A.V- Development of turbine systems in the U.S.S.R. Izv. AN SSSR. Otd. tekh. nauk. Energ. i avtom. no./+-.3-9 Jl-Ag 162. (KRA 15:3) (Turbines) SHCHILLYAY2,V. A~V. Tventieth Anniversary of the Power Ylachiliery Faculty of ~bscow Imtitut8 of Power Engineering. Teploenergetika 10 no.4-:91-92 Ap 163. (~ffRA 16-3) 1. Chlen-korrespondent AN =11. (Power engineering) SHCHEGLYAYEV, A.V. Some problems of constructior of turbines of great cruzimt in the U.S.S.R. Inst masz pmep, PAN no.14/16:125-137 163. 1. Moskovskiy ordena Mnina energeticheskiy instituts Moskva, SHCHEGMAYIN., A.V.; SMLLINITSKIY, S.G.; KALASIMIKOV, A.A. Stndy of the pickup of boiler-turbine blocks. Trudy WI no.47: 145-157 163. (MIRA 17:1) $WCREGLYAYEV, A.V. Manufacture of turbines in the U.S.S.R. and its perspeptive growth. Teploenergetika 10 no.12:20-26 D 163, (MIRA 17:8) 1. Moskovs%iy, energeticheskiy inatitut. Chlenimkorrespondent AN SWRI L. I N! "I"S K I YS . GIt& n,~ . telk h n . na; i ..r.,z-. KALIASHIN 9 Lnzh. Problems of the use of discharge systems in bc-11-r-Turt're unftt~. "'c "norarget',ka 12 nu.l--'~-9 Ja 165. tWIRA 38 41 3 Moskovs*kily energeticheskiy inptitut. 2. APT SSSR, (for Shcheglyayev). 9,14', SOV/ 112-58 -.3-475 4 Translation from: Referativnyy zhurnal, Elektrotekhaika, 1958, Nr 3, p 198 (USSR) AUTHOR.: Shcheglyayeva, T. A.. TITLE. Universal Grid-Control Electron Circuit for Ionic Frequency Changere iUniversal'naya elektronnaya skhema setochnogo upravleniya dlya ionnykh ~reobrazovateley chastoty) PERT.ODICAL: Sb, statey nauchn. stud. o-va Mosk. energ. in-ta, 1957, Nr 10, pp 45-52 ABSTRACT: Of possible circuits for inverter grid-control at 70-170 cps - a magaetic-amplifier circuit, a transistor circuit, a ring scaler with miniature thyratrons --- the electron-tube circuit was selected that includes a three-phase sc aling ring, a trigger, and six pentodes. The scheme can generate square pulses 600 long at 50 v. The scheme is suitable for controlling an inverter having a three -phase -and -neutral circuit (control pulses are taken directly from the three-phase scaling ring); it is also suitable for inverters having the Card 112 9(4) SOV/1 12-58-3-4754 UrJver.-at (-,rirl -Gontrol Electron Circuit for landc Frequency Changers Lari,jnav's bridge circuit or the equalizing -reactor circuit; in the latter case, there I's no need for segregating transformers. Operating reliability and of al-ign-ment are the advantages of the above scheme. Tts d;',sadvan-tage ,.s the large -number, '12, of electron tubes needed. 1. L. R. Card 212 ., -1 ., I , I 1 .1 . , ,... I.. :I - . . *,* 41.- . -- -- " ". - . n - - . I - ,. - :-. . --- - - . -, . : - ~ . :, - - - - -- .--.-I . "-a , * ---- - I - - - - I L 1, . '--, --,* L 04742--~'i. ACC NR; AP6023322 (A), !AUTHOR: Shchegoll, "A. Ys.. ORG: none SOURCE CODE: U-4114/66/000/004/0038/0040 (Engineer); Pentsov, V. M. (Engineer) 19 TITLE: Development of an indicator diagram on a "Ural-2" electronic computer ~Iy SOURCE: Energomeshinostroyeniye, no. It, 1966, 38-40 TOPIC "L'AGS: computer application, internal combustion engine 1ABSTRACT: LThe calculations were made for the operation of a Type D70 1heat engine. The work was sired at determination of the following lindIces of the working process: 1) the temperature in the cylinder Iduring the compression-combustion-expansion period; 2) the beat !evolution, xj; 3) the heat loss during the combustion- expansion period# WW the volume of the cylinder at the end of visible combustion; ~5? the coefficient of effective beat evolution, 6) the temperature and the pressure in the cylinder at the end of compression, T and p ; 17) the pressure ai)d the temperature in the cylinder at the mocent wban Ithe exhaust valves are opened, p and T The article gives ma detailed Iblock diagram of a program adapt8d to de, "Ural-2" computer. A large number of indice.tor diagrams were determined by the block diagram Card 1.12 U-PC: _681-142:(oft.21).001.24-1 L 04742-b"i' ACC "'~ AP6023322 . I .0 shown. The error in the determination of V was not more then 0.5%; V i can br) clilculated to practically any d9sirea idetermination of V , the time required ~Of A was not more Kan 5 to 8 seconds. istatod Lo be considerably greater than !art, bast 3 figures. degree of accuracy. Aftep for calculation of one variant The accuracy of the resulta is wIth hand oaloulations. Orig. 5UB CODE: 211 SUBM DATE: none/ ORIG REF: 002 Card 212 YASTREZHINB~JY, L.; SHCHEGOL), -14. First in Moscow. Znan,--aila 38 no-4;47 Ap 163, (MIRA 16:8) sti ,It ajg 0 5 ;J i: ~ja it -59-5-17542 Trarsl~i-~..-. fr-om Referaull,n-yy Nr V, rP 532 - 533 (USSF) AUTFj ,I Shchegoll, "alkira, V.K. TITU. F--Ivmeta--ryt (Polimel-akrit-) -, a for Constrac~-Ion Purnoses P FF 1 C Za,. telkhn, progress i.3-ovnarkho-z r--kr-.n- adm. r-na), 1958, Nr 5,-PP 8 - 9 lectrograPh! ABSMIR r,7 Folymetacryt (PM) was obtained by impregnating e te ;BG) with methyl ether of metha~~ryli(:, acid and 0 ZOY-L Peroxide a-vid subsequent stepwise heating, havirg a compression -esistar-ce twice as high and Lensile strength and bending resistance three times as high as EG-, ~-he heat- and electri-j -conductivity of both materlalz -Are 4;he &ame, DePolymeric ether ,-,b4,.ained froun the waE-F- of organic glass can be u1sed -,s material Th~-~ me thyime .ba:,,ryl ate to I ton ; impregria~.ed EG Is 1-91-1 Kg., ~M is S'Altabl.-= for. the Card alx6r37,*IS as WEII as 112 W',"I/81-59-5-1,754P Po1,,m,!-t a cry t -i Mate ri. a I fnr -,orj'S .nu- ~ lon. Furposes ele:trodez f,.)r ?'Ploride baths) , Thp- wear :)I' 1--ne PM anodes is by 20 - 25% less than those made of graphite, ard their application decreases .h6 consumption of Dower per 1 c.-on of" caust-f,~-; z:oda I - by 100 kw hrs, T .he test results and the proper-'Z~Les of th-:-. In't.Lal EG and PM ar& given. A. Vavilova Card 2/2 SOV/132-24 -9- 1 /53 na s z, o qu e - u-, 3 c!.t I I an.-; Y_cxides (knaliz -vodnykh rast-orov ki~!.-__ritov i d-rackisi khlc%ral. CDIC~': Ve' -P 104j-,OO R 9, IUSS Z C T zne beCirring, refe-nance is made to methods which are e.--,,,I_-.ed -,.o t~he analyses mentioned by the title. The followinZ me-hods are explained: The determination by t-itration after Brw (Brey' (Ref 1), zhose after Oechsly "vksli) (Ref 2), Lazek (Ref 3), Perio 'Ref 8), White (Uayt) (Ref 9), Chernyshol! ard Semenov (Ref 10), Aznarez and Vinade (Aznarets and VInade-) fRefs 11,12), Haller and Listek (Khaller and Listek) (Ref 1"), Car,,i, and Raouet (Yaron and Raku) (Ref 15), Flis and others (Refs 16,17), Levi and Garrin -' (Ref 118), Buser and Hanisch (Bu-zer and Khenis-) (Ref 19). Kon-opik and others (Ref 20), Fr~.Pdman (Fridman) (Ref 21), Duval 'Dyuval) (Ref 22), Niel-Sen and Woltz "Nillsen and Volitts) (Ref 23', Rins and Gorriz (Rjn#7,, Gorrits) (Ref 24), Yakovlev, Rozentall and Filippov (R-i-f 26), and that after Loeb (Leb) and others (Ref 27)'- In th~ present DaDer the ammetric method after Haller and L 4 stek, Card 1/12 as as tne volume-6ric met-nod afte-.., Whiite, were revised an,.' 307,1-; 2-24---t-1 /53 T-~-- Ar, a Lys iL s of Solut ~~f Ch ri te s q!l k; Ci~ L,,1-j.n(-. Dioxi des w::----- variant,., rpla~j,-r~- ~f: them abovs-mentiurl-;d ha-Te. -,.Per, worked K. S~AFanova pani.:Apated Ini the cci-respondent ti~xperj.men-Gs recrvstalliza~ic- af ter Weir-1 (Veyner) (Rei* 29) x&!, carried througi, iii. -Ordic-~- to obtain anhy rous sodium, chlorite. In the explanation of the volumetric method referonce is made to a hInt giver b.,,, Hill (Khill) (Ref 31). TI-.- ~;tatements, ciade by Konopik, Rins, Gorriz, and Loeb, u!-, W~.-,Li a- thooe made tit the IVVsesoyuznoyesovt~Fheii,-Iniye pc elektroki,imii 'IV A'L-I- Unj.0-1- Conference ot" E-lactrochemis ry) (Ref 5"') h2ve t-,eeil work;,~iz., th~- pcdarorrarhic it vias stated 'hat, in tthe preEen:,~ -.f La the Crar.---s ti---e cchlorit~ -ion ar~- ~,;:'-th those obt-aired, Fr,~mkin iRef There ars ~j figu-n--Ii~, 4 ~a*-,L,~o~ and 15 references, 8 of which- are Soviet. SHCHEGOLI , Sh. S. .. - . lity of the aqueous solutions of !3odilim chlorite during Stabi evaporation. Zhur. prikl. khim. v. 11 no.5:680484 K;r '5P. WIRA 11: 6 ) (Sodium chlorite) 19-1-27/52 AUTHORSt Grayevskiy, A. I., 6hchegoll, Sh. S., Smolyazi, Z. S. TITLE: The Physical and Chemical Investigation of Several Systems Containing Triethyl-Aluminum and Its Derivativeis (Fiziko- -khimicheskoye issledovaniye nekotorykh sistem, soderzha- shchikh trietilalyuminiy i yego proizvodny-ye) FERIODICALt Doklady Akademii Nauk SSSR,1958)VOl-11qpNr 1,P]~-101-103(USSR) ABSTRACT: Pure triethyl-aluminum, diethyl-aluminum-hydride, diethyl- aluminum-bromide and ethoxy-diethyl-aluminum were dissolved in cyclohexane and potentiometricaW~itrated by quinoline in a cell with a silver electrode and a platinum electrode or conductometrically in a cell with non-platinized plate-like platinum electrodes. The titration took place in a rare gas atmosphere. The character of the curves of the conducto- metric titration of the different substances mentioned above becomes evident from a diagram and shows the fcllowing: ,4uinoline with triethyl-aluminum forms the electrically con- ducting complex Al(C 2H ) X H N, with diethyl-aluminum- -bromide the electricail; cQueting complex A3.(C 2H ) Br.C H N, 7 Card 1/3 with diethyl-e-luminum-hydride the electrically noncKiuctigg 20-11Q-1-27/52 The Physical and Chemical Investigation of Several Systems Cortaining Iri- ethyl-Aluminum and Its Derivatives There are 4 figures and references, 0 of which are Soviet. PRESENTED: August 5, 1957, by A. V. Topchiyev, adember, Academy d Sciences, USSR SUBMITTEDs August 5, 1957 Card 3/3 Sh. s., "'aid Ghem bci -- (diss) 113tudy o-i PrOce-O--- For obt~;-rinp- sodi za claL.--)rjte-:l lu pp of H10iii-- Pdcation US:;R. G V U a e i iv s k i Y) ic r 45W PHA4H 1' SCOK R:(?LOI'A7!CN SchoanChanly, po elektroknir.111'. 4th, Moscow, Trudy... ; fabornikl (Transactions of the Fourth OonI`erence ~n E~ec rocnemtstry; Collection or Articles) Moscow, 11:d-vo AN SSSFI' 19~9. 868 p. Errata slip inserted. topics prllnil " SponaorinF Ar~encyz Awadlmlyft nauW oSSH, Otdolonlyo kh-Imiche k 1 ~.n naulc. Editorial Doard; (He Ed.) Acadomitlan, C.A Y-j A.N~ Frumkln Professor; S.I. Zndanov (Renp. Z2c;,otary), B.N. LaDanov. Pr- f:330r, 5.1. ZhOanov (Hoop. Secretary), R.N. Kstsnov, Y . K. KolatyrlkLn, Doctor of' Chomtcal V.V. LOA-, P.,_ Lukovtsev, Professor; Z.A. Solov'yeva; V-'J. 7-ncer. Prorc.,a,)r; N.O. Y~K'r.v; and O.M. Plorlanovicn; Ed. of Publ4snInj7 hc,;SeA Tech. Ed.: T.A.. Prusakova. PURPOSE: This book in Intended for chomleall and clectr-cal rnj:,4- neer3, physicists, atllur,latS and reao%rchorb Inlere5led in various aspoc&s f electrochemistry. 4 COVERAGE, The I.ook contains 1.1" of the 138 reports presented ht art- th. Fourth C0,11'erence on Electrochemistry sponsored ty the Dep ment or Chemical Sclences and the 'n3tItUtC Or P.1y31Ca.' Academy of Scllnc.a: u,,si. rn, c.,lection pertains -.3 llrrer,!nt branches of eleitrochemical kilnuzzica, double *ayar theories and g.IvanIc procenbea In metal elect.-Odepoatton And Indu3trittl oloct- rolyale. Abridged discussions &re given at the end Of each dlvl- $ton. The majority of reporta not Included hert have been published In periodical llzeral~rv. NO pe.00q.&'It.-e3 Are ment-lo-d. References are given &I tn~ end of moat or trio articles. KOUtct~kly. Ys. .,:i.w --.-7-.-tIrstItutr Of Pnyseal Chemistry, sklar. Academy bf Sc!dnce3). Survey or the latest Tnea.-etica. Woric at the Pra6uc rolarot;r4phtc School 113 Xi1kOlqyeva~PcdqtQvjch' And B.B. Damank-r. (Mosco. State Universityl. lnfl~t nce.r the Rad',a or 'Batkgro~n~l' Cations on the Reduction of Pdrsulfato Anions a, a fIercury Electrode 150 _mInLo-Sterar. fn1,1tICute, OChPMysIca1'C1-.em.1stry, V011511 Academy or Scion e )ITeI fluence f Structural Criangon in HNL)i Molecules on the Course of' Cathodtc PolarIzatlon or a Platinum Electrode In Nitric Acid Solutions ;59 Zhdanov, S.I., V.I. Zykav, and T.V. Kalish (Institute of Card 7/34 Electrochemistry and Pnyolcn, Dr~adell Sch"! for Advdneed Technology). The Influence of Or.7.4nlc Solveritt a-. Wave HeIght and Se-I-ave Pottntla! or Orianic Depolarlzors 17 _Labotln,. P.1, , S,P. snd Q.Z. KIr':114ov (InatIt1t lchlmll Alkadrmll linuk KitSSR-InstItute, nr Cherlstry, Academy of ScIcn-3, Ka.--,tkfi 5::H). inrluence of the itlon or 'Zoro-Charjt- Points on the Roductl0n. Of Indlum as w a -.-Prol, Elc~trod, : Kory-ta. Academy a.-' 201'ences), Kin.ticj -r In, Separ,~tlo-l or Cadmium Fz-om Cyanide, Complexes at Dr~pplrj; Xcrc~ry Eloct- rode* ant) Streaming Mercury Electrode* 166 Sh 3 (Tsontral*rinya laboratOrlya "ZavOdntroya" a ntral Libor.~tory "Z'hvolotroya~, Dterzh1n.4K~, Reduction of a C410rlte Ion at it DroppInE Mercury Cathode 19~ Card 8/ ;4 S/08 60/033/010/011/025 D216%306 AUITHORS: Fl~erov, V.N., Shchegoll, Sh.S., Armenskayap L.V., and Ga'1kin, L.G. TITLE: Electrolysis of hydrochloric acid solutions of bivalent copper 1'J1 ,', 1-L' 10 D 10 AL Zhurnal prikladnoy kh1mii, v. 33, no. 10, 19600 2245 - 2252 TEM: The regeneration of chlorine from hydrochloric acid formed in large quantities during the synthesis of DDT, polyvinylchloride etc. presents a very real problem. In their experimental Nvork, the authors studied the electrode characteris tics, of hydrochloric so- lutions of cupric chloride. The equivalent potential for the reac- tion Cu" + 3CII + e ' CuCl" was.determinvd with-. E~ p9jished pla- N~ 3 tinum electrode in a series of solutions with constant H0.1 concen- t1ra-11-ions (,-~20 ,t) and varying concentrations of CuC12 and CuCl. C,,---,i,d 1/4 S/C)8 60/033/010/011/029 Electrolysis of hydrochloric ... D216%306 The sum of the mol,.r conc en trat ions was determined with a potentio-f- ineter type PPTV-1. To avoid oxidation of the monovalent copper the measurements were taken in an atmosphere of C02; cupric chloride ~.P_ solution ,-;as analyzed iodometrically, cuprous chloride using perwariganate and irori-ammonlunt alum. Hydrochloric acid was titra- ted with sodium hydroxide so'lution usinG methyl orange as indica- tor. The equivalent potential for the reaction CuC111 + e Cu + 3 + 3ClI was determined with a copper electrode in a series of solu- tions with constant HC1 and varying CuCI concentrations i'from 29 'to 138 gm/1). To prevent cupric ions appearing in the solLition, copper metal powder was sprinkled in and the experiment was conduc- ted in an atmosphere of CO 2' The article shows the normal poten- tials of certain oxidation-reduction reactions; the reletionship between cathode potential and current density; the relationship between potential and current density in hydrochloric acid solu- tions of cupric and cuprous chlorides. Catliode-imperviou-- praphite, Card 2/4 S,/,08,~ /6 3/10-5 1./02 9 1~5 2 -j, r0 c D21 0,1,~-,-6 tia e r e a o n s h I p b e t,,,, e e n -. h e a h L d e - tro'y-, eS; toe change of poten- IOUs e1-- . . _ tAl c) d e v, ii denS7 ty ';f,4fjoUS in r1ji In FICI cii c f L, T i, -ly 1 Z3 so; u- C -_-i C 4 C. s o a r r e L a t I n r, b e e en. r e nt n 7 7 ri e ciens--~Y~ I- is ~Ahat 1) TI- & .1 - mi "I C n 7 1 s r a p n i r d e s iE increa- 17-.-; ions lr, -,ion and riEing tem- d S .!1e basi - fa-~or is ~hle r &Te of -ca-.ire atn-_-~ th-Tckness of the s e - - - - - - when ol a t c m f 1:' -)7 Cu -s ccimarati`_ lei_ y :;z pen,~ - on ~he de-S-.- a-ir. the ra-LE Irr of flovi 'Ll-ures, 2 rables, and 15 referen- The ref"erences to the n c rj, nr s n p JI 1*7 T 'I" ED0 b -? ead Paz follovis r i- G.:)rdon. Chem. 4 6. SlOd 116 2/000/0 16/0 310-8/.8166 A UI I. , 6adykhzade, S. I. , ~~ricnefol' S. B., knundova, G. Yu., Krasnokutokkiy, V. P., A., lh.ukharamova, Kh. F., -urbanz-~I-Jyeva, T. Kh., I'likolayeva, L. T I T L III, jynt;'-,esis ;,nd use of'silico derivatives of nauhtlLienic acids "n t'l-to .)roduction of dUvinyistyrane rubLer Ro'I"cr,,jtivnyy zburnal. Khimiya, no. lt~, 1962, "t"rict 0 U 0 1;!F405 -.erb. khim. zh. , -,0. 5,- 1951 , 55 - 63 rzum-:~ry in TEXT:' t1i,~ Idi chlorosi lane reacting i,;Ith naphthanic acids in Lhe oil trieth.-I .,i,ire oraJlices ~ ime thy ~dicarDo.,cy-bis-cycloalkylsi Ian e The nrcduct was used as filler for b tadieliestyrene .(CII "j, ) . J. OU 71 10 40 9 rubber instead of lubricating oil 18. The Defoe*n4dlber of the ra& buti- rubber 2000, t'.Iezrmal plistification time 40 -1-An, Jefoe- t.-.,a )Iisticized butadieneutyrene rubber 1100, tensile StrenGth, Card 1/~ 1-LE I I . I " ~ . I .. j ~ t . . .. I.- , . -~ -, :~ - : - ~~ 7 ~ -, ;- - . -o -- . , I) T 7 i Wi,~ 1 , I , , C, : - I . I YCII .. -N - 4.3. ; lc , ". G; 1 , - 1, -. I. i ~j 1. - 11 1 1: , 011 . S ~ ; ~ , R . E . ; 1 1', 1 " I t) , I-,. . .1 1 'athoclic -~,rotrjction of' i.esA exohar;gt-rs cooled by sea water. Zashc'2. met. 1 rlo.2:2L5-246 l,x-Ap 161:1. ( MIR A . 6 ) d. Suagaitskiy zavod sintotichoskogo kauchuka. SHCHEGOLI, Sh.S.; SklYKF.-ZADFl S.I.; ASKFROVP A.K.; !-.UKlH,' -"a e__" z Uiri:.ng azolyat..A as an rmulsif_~er in the emulsion polymerization of -_i:bL-_r. Sbor. naucn_tekffi. inform. Azerb. inat. nauch.-tekh. J. . Inf arm. Ser. Nefteper, i kh-Im. prom. no.2:3-14 162. (MIRA 18;9) GFVCW~'iAN, A N, cc f to bivinya, Azerb. 'khim. 2.8-11 165. "'-!IRA le-12) il S-,Amitted. Dec. 10, 1964. INP9 7 iOW-121. 0 I I I I I 1 4 f it it 1) 13 m U is IV is 19 a a X1 is a Is v an )9 a it v m )A is Is IF A AN a .1 a ~3 a 11 r-lie-Y I A... - - 1__T___l_AA A M K k 6 C.-A __ L a k -A.,. k.- A &--L-- 1.0 AMP_ a 00 ----- - ------ 09 00 'The Effect of Aluminium on the Itreneth of the Calefincil In 061v 1;. K. L%ov S. Shchegld (Vrrd. Meltallaryi.0i (Viul j1riallurnM ,.a , 9, (3), It; IV. Ch,yn. legir:_191D. till (11). 37M). --(III ItuadiAn.1 L. -fi~kcu~ the funnation of internstilitiste layers fictu-swu irun and zinc its list. vallixing. IG-sults ofexpersinivatit in galvanizing % ith purr title. still, - till. till, - 41 1 U',, alunitniunt. and zin, - u-5% till - I)T", al I'lligurn. Aft, ul viven. Atidititintif till tit the title bimthe undesirable Oftvtoof r"Milig the of viiml, I,r,,I,,-rtws of the xine etlating, juml causing a 9111ater c"IIS1111111tWit, Of ziliv. thus tile cvl,to of the pruevws- The U'l,ble .1 Ill.,% f so j alumilman 1, 0-",,; this greatly increasen the strength of till, zine lawr up ' I,v it front 3:11) to 1341 grin. III,- . 00 0 0 00 00 ate 4,009 .09 .00 .00 .00 -00 .00 so Ss see 00 coo also War 001 60 '00:9 06, 00 1! $4.SLA AITALLURGOCAL LOCRATOE CLASIRPICATICAl 1.Z__ 0g k '.ILtIl all- All 6 Sol Odo --Ivmsdaa3o ,U is AT .0 'it 9 IV IT IV at 6C K CE Or 91 K C1 t[ Or ONT44 000060000*004*000001000000000006000*0 ::::::r*O*OqOOOOoO*G*Ooo4 6044000000111,0910110*6 ,-Increasing dbucasioaul accUrIlcy of p!ugs of plercingfrnift. It. P. Ldue'va. 1. NE. Ludeaskil, unii 'r. (LLuititube R-Alifig Mill, Dimprolm!trorITT 'I nude of 1-1-1.8% C, 14-12.5% Cr st"l u.~ually cant, groatid to"t;ize, uummliLtd at M-10-10* awl tciatpere,i at ON) 70' could imt mett dimensional tulm 11ces- flotit Shrillkagc and C.-p.111.6111 Occurreel in- INSCrullillately and Ividwat way explaluttion, particularly whell rtsiduat Nj vuricd ulk tt~;% lly norinaliziiig beforeK grinding the residual austeniu: ~vLA stabiliud and sub-w- quent tcuzp~:ring producLif acceptatle dioneasionul chaugm D. Qat -7 137-;8-2-3003 Translations from: Referativnyy zhurnal, Ivietallurgiya, 1958, Nr -1, p 1-11 (USSR) AUTHORS: Akimova, Ye . P., Shcliegol' , T. S. TITLE: Introduction of Metallized Mandrels for Use in Stainless-steel Piercing (Vnedreniye metallizir*bvannykh opravok dlya proshivki zagotovok iz nerzhaveyushchey stali) PERIODICAL: Byul. nauchno-tekhn. inform Vses n.-i, trubnyy in-t, 1957, Nr 3, pp 86-91 ABSTRACT: A new method is proposed for increasing the durability of piercing-mill mandrels. It consistr, in metallizing the mandrel tips. The chemical composition recommended for the metal coatincy is the following, 3.0- 3.5 percent Ni, , < O.Z' percent,G, 0 . 4percent Si, 0.41 percent Mn The metallizing apparatus is described, also the procedure for preparing the metal wire to be used in the process. The mandrels are annealed for 3 hours at 980'G, then cooled in the furnace down to 5000C at a rate of 100o/hr. Introduction of this method at the Lenin Plant increased mandrel durability 2-3 times, which made 4t possible: 1) to cut mandrel consumption by 40 percent, 2) to lengthen the billets for Card 1/2 piercing from 700 to 1300 rnrn, 3) to cut the quantity of 137-~;b-'-3003 Iritro(v,:ct~on of Metallized Mandrels for Use in Stainless -steel Pie-ci-a unpierceable billets from 8 - 12,7 to 0 - 1-07 percent, 4) to cut from 3 to 0 3 -7 pevc I Ont the Wbing rejected because of internal scabs. The metal- consumption index dropped from 1.196 to 1.107. G.K. 1. Hard ourfacing-Lpplications 2. Piercing mills-Equipment Card 2.1"1 13 iO/-D AUTHORS: Finkel sh'UeYn7 Ya.S. , Candi&tte of Techi-lical Sciences, and ShcheF-oll, T.S., Engineer. TME: -AL, Improvement in the Duratility of St-ationar57 Mandrels --for Iliercing Mills (Povysheniye stoykosti nevrashchayushchj:__ khsya- o7r)ravo'L%- proshivnykh stanov) Stal t 19 57, No. 12, p_ . 1099 - 1103 (USSR) ABSTRACT: Causes of a decre;_ise in -the durability ol' Stationary Mandrels of DiercinS mills were investi6,;ted. It found that the main condition for imnrovinG their durability is to produced and then to retain durin- their work, a wear-ezistant austenitic structure of high manE,;aanese steel. HiE-hl37. .,.,ear- resistant austenitic stro cture of mandrel's metal can be obtained by us-MG: a) steel of tilte type P18; b) a rapid heat-ine for hardening, -and c) by -a~Lcin- ma~ndrels of am elongated form rith ~ cylindrical end. To preserve high weeir- resistant ncrooerties of i:,andrels, t.he folloi-:ing conditions -hould, be satisfied: 1) correct -.ositionin2, of axis, of rolls olf the piercin_- mill; 2) optirriw:; positioninF of the maxidre! in the focus of deformation, and 3) good cooiin- of the mandrel durinG intervals. As a result of -the above reasures) the durability of mandrels increased by a factor of 6 (from. '-'g/ton to 0.2-2 kL/ton of semi-finished product). ,ard An in the Durability of S-ctlionary 12- dr,~'! s f.)r P-iercinE Mills are 6 fir,,ures and. 9 Sla-vic references. A.Sj IS 0 C i A T T ()'I Dner)roi)etrovsk Tube-nollinC. Mill imeni Leni'm (Dnepropetrovskiv truboprokat-nyy zavod Jim. Ler.-Ina) AV A 1L'-,ZF'. LE Librs.'ry of Uo-ngress Oard 2/2 jjical nn' I.--al grindi 9 of carbida tubze-.i.vawllng dff~5 q 7'0. 19-06, T:,c in, rinding r machine toel olect--rospark Z 'U'D e at t"in ;%7~ T tr~ extend the i-Fe of Wbe iftra-wing din-, -rawing tubes up to 50-70 P./min, the ordinary alloy use"~ T -.-i~3re veolaced hy the hard alloys VK-8, ITK-10, ~L-` VK-15. r- E. an 0 '-Iothods were used to machine -and polish the dies: anodic-mechani- c a i '-rosion Drocess wh-,ch removed large amounts of -matc-rial but roug'r'.enecl roabrasion, using an electrochemical process for cleaning che sur.- 'thout electric cunrent. A schematic Z!..! --on , asing the working fluid w-3 ~e 1) o~ the technioue showed the work (+) ar-,(,, 'tool kept In tact sillcate solution havizv a specific gravitj of i.23. The operattion UDC: 621.789.1 : 663.27 Cc:r-J INP: I.;-, t:.,-, -rind` ing mlllcllln~,,I t~!chnicall data i:or all three 1: T The lapp, ncr material , - Daramieters, surface N a ZI-a "i s , _Md gri nd ing t Ime are ii s z- 4: OZ- One anodic-mechan;ca! handle al 1 of ~he WWI]< ng J m lz~-rmal cold drawirw f. lud I! Fig. i he ard a 11 C. )")00 _)ie-as or cuue "7ures, 1 table. Gri,~- art.. has: 2 fl- SUB CCIIJ",: l-,115/ C-71,S FEE: C03 2 N.MTIN,.A.V.; Frinimali uchastiye: SHCREGOLI, V.M.; KU11, I.P.* ANTCNIK, I.V.; MEERBU!"H6, I.N.; LOZINSKAY-A., K.A.; BASHINSKAYA, L.I. Finishing relevision cabinets by polyester varnishes. Bum i der. nram. no.2:53 Ap-Je '63. (MIRA 1'11.,2) S/065/60/000/010/009/010 E030/E412 AUTHORSt Pankov, I.A., Zabryanskiy, Ye.j., Zarubin, A.P. '~~~~V and Aronov, D.M. TITLE: Apparatus %AT 9-6 (IT 9-6) for Determining the Research Octane Number of Motor Gasolines PERTODICAL: Xhimiya i tekhnologiya topliv i mas*l, lq60,,-,.N0.l0' pp.49-54 TEXT: A new single-cylinder apparatus, IT 9-6, has been developed for determining the research octane number of automobile fuels. After 150 hours of trials, the results were verified to conform to the specification roc"r 8226-56 (GOST 8226-56) . it was put into full-scale production in 1960 and is being used in the domestic production of motor gasoline. The effective cylinder capacity is 652 cc, the cylinder diameter being 85 mm and them stroke 115 nun. The compression ratio can be varied between 4 and 10. The coolant in maintained at 1000C, air is taken in at 52*C and there is no heating of the mixture after the carburettor. The oil pressure is maintained at about 2.0 kg/cm2 and the engine Card 1/2 S/065/60/000/010/009/010 E030/E412 Apparatus W-r 9-6 (IT 9-6) for Determining the Research Octane Number of Motor Gasoline& runs at 600 rpm. As usual, the mixture is adjusted for maximum knock and the reference fuels are iso-octane and n-heptane. Complete linearity between pressure and compression ratio an measured has been checked for compression ratios from 4 to 10. The accuracy of the octane ratings have been checked against the 5tandard ASTM fuels. There are 8 figures and 2 tables. Card 2/2 ZABRYANSKIY., Ye.I.; LOSAYEV, K.N.-, SKH~E~L_!, Y_,_V.; ARONOV, D.M.1 ZARUBIN, AP. - - Electronic detonation meter DP-60. Khim. i tekh. topl. i masel 8 no.6*.65-69 A 163. (MIRA 16-06) (Gasoline-Testing) 3ALASIIOV. [deceased]; SHCHEGOLEV, A. Soviet equipment on the markets of economicallv underdeveloped countries. Vnesh. torg- 30 no.12:30-34 160. (KIRL 13:12) (Ehissia-i-Commerce) (Machinery industry) "ICHEGOJEV 61 , A., inzhener-konstruktor lie have rebv-ilt a woodor- grair. ~Invator* Muke-elevo prcci* 28 n0,6:29 Je t 62 , (MIRE '15:7) 2. Saratovskoye(oblastnoye upravloniye khleboproduktcv. Grain elevators) KOST, A.N.,- TERENTIYEV, P.B.;_SHCHEGOLEV, A.A. ------- -- -.-- Synthesis and some conversions of athynylearbonols of the pyridine series. Zhur.ob.khim. 32 no.8-.2606-2612 Ag 162,, (MIRA 15:9) 1. Moakovskiy gosudarstvennyy universitet imeni, M.V. Lomonosova. (Pyridine) (Alcohols) PETROV, K.A.; NIFANTIYEV, E.Ye.,- SHCHEGOLEV, A.A.; MUDDITSEV, N.A. Synthesis and chemIcal properties of phosphinites of 1,4;3,6- dian~ydrohexitole Zhur.ob.khim. 32 no.9:3074-3080 S 162. (MIRA 15.9) (Hexitol) (Phosphinic acid) PETROV, K.A.; NIFANT'YEV, E.Ye.; GOLITSOVA, R.G.; SHCIIEGOLEV, A.A.; BUSM-IIN, B.V. Synthesis and reesterification of diphenyl phosphite. Zhur.ob.khim- 32 no.11:3723-3727 N 162. NIRA 15:11) (Esterification) .(Phenyl phosphite) PETROV., K.A.; NIFA.NTIYEV, --4,,Ye.; SHC.HEGOLEV A A Synthesis of 1,2--dialkyl phosphinites; 5-6-diisopropylideneglucoses and their conversion to 6-halodeoxyglucose. Zhur.ob.khim. 33 no-3:896-899 Mr '63. (MIRA 16:3) (Phosphinic acid) (Glucose) FETROV, K.A.; NIFANTIYEV, E.Ye.; SHCMGOLEV, A.A.; BUTILOV, M.M.; REBUS, I.F. Re-esterification of neutral phosphites and phosphinites. Zhur.ob.khim. 33 no.3:899-901 mr 63. (MIRA 16:3) (Phosphinic acid) (Phosphorbus acid) (Esterification) L'I," T'r. V, A.A.; 'l 0 rer ctiors 0, pyr! dylethiry1carbinols t-El 14:11) -4i no.1:11C-113 N 161. uvernyy universitet in, 2. Chlero-*,c,*.-:*-:'!',ol,Cc---'4 - ,, ... I - -71 (f'cr A.P.Torpntlyrm). ("eth,,.nol) FETROVI K.A.; NIFANTIYEV, E.Ye.; ~M~(?4VA.A. Glucose phosphinites. Zhur.ob.khim. 32 no.3:1006 Yx 162. (MIRA 15:3) (Glucose) (Phosphinic acid) IL3312 B/07 9/62/03 2/011/010/012 D204/D307 AUTHORS: Petrov, K.A.t Nifantlyevt E.Ye., Golltsova, R.G., Shchegolev, A.A., and Dushmin, B.V. TITLE: Synthesis and peresterificatiqn of diphenyl phosphite PERIODIC.t'%L: Zhurnal obshchey khimii, f. no. 11p 1962, 3723 - 3727 TEXT: The interactions of diphenyl phosphite with aliphatic alco- hols were studied since the alcoholysis of diethyl and other simple phosphites (to higher phosphites) and phosphinites requires, in some cases, inconveniently high temperatures (this journal, P. 3710 Dialkyl phosphites (R0 )2POH1 where R =-C 4H9? i-so-C-5 H11p C6H 139 C8 H17# C9H199 C 10H21' ClCH2CH2 , and C2H5OC(O)CH 21 were prepared in 91-96 % yields by adding 2 moles ROH to 1 mole (PhO)2POH and heat- ing for 3-8 hours at 1000C, in the presence or absence of catalyst (Na), The high reactivity of diphenyl phosphite as compared to those of simple dialkyl phosphites is ascribed to (1) the existence Card 112 Syrithesiti and pc.-(,~!cter,Lfication FP h 0,,,, R of transistorv forms LI, P OH] and ho,-' OH S/079/62/032/011/010/012 D204/D307 [PhO,,, P R], H ROI_~ OH which prefe- rentially eliminate FhOH rather than ROH, owing to the considerably higher electrophilic character of the PhO group, and (2) the fact that the tautorieric eauilibrium favors the trivalent P form i'ar mort, in diDhen,, ri than, say, in diethyl phosphite. Similar reactions took place readily with substituted alcohols such as e.g. (CH ) 3 2 NCH2CH20H. Diphenyl-I phosphite was obtained almost quantitatively by the equimolar interaction of diphenyl chlorophosphite with metha- nol (sealed tube, 1000C, 3 hrs.) and by the interaction of methyl dichlorophosphite with phenol (1:2) at 1000C for 1 hr. The latter method, which is generally convenient for the preparation of diaryl phosphites, was also used to make di-p- and di-m-cresyl phosphites, in ,j1OO % yields, by reacting CH 3OPC12 with paEa- and meta-cresols There is 1 table. SUBMITTED: December 14, 1961 Card 2/2 FEMOV, K.A.; 141FAWMEV, E.Ya.; SHCHEGOLEV, A.A., TUSEYEV, P.P. 112,3,4-Diisoprooylidenecralactose 6-methyl phosphinite. -71,u--.ob.khim. 0 34 no.2:690-693 F 164. (SERA 17:3) ".1 7 Syn tr -~,nicnl -7 I C, ':"t r i c -ec~-nlca~ :a n 7- e r e n,: e ~he ~lovocherkassk Tnstitute of F.- ine e ring and Zoil ,--ovq:ren~ ;l?:hronikr-. XIX Yuhileywiyn nauchno-tekhnicheskaya -~n r e -o----e-rlassk,3gc. 4n--,enc-rna-melio---,~tivropc) in- n~siyp. N)j 7 pp A h zr-. -hE V~+ "o -In l entific technical con- ,. . l -er~noc- oF the 1C. -,.,L) C !I e Z-I,- a 5 Sb- T, U pr4 f 1P. n neering an(! Soil -,rnrovement was convened. `he ;-.Dni'~,-ence discussed t~-e nrobl,~ms tt sections. The first two plennry t i n g o ~1, nd :L r ~l F -irector of thE institute, e n!). ry s i i n L, wn~ opene,4. ly ~~e U ,he 5Cth Anniversry of the "nul wich n report on "T 'Institute o-F' Enrineering and Sc4l Imnrovement i~~3 ;.r:tivity Iuring 40 yeqrs of the existence of the Soviet '-he meetinpr '~eavl the follawing reDorts: Professor .7hum,~kov, 7ember-Correspondent of and Doctor o-F Technic~,!- 'S'c-iences, on "The History of the Development oi7' the ~~,-ience of Soil r-rrovement in the IT orth Caucasus and -rh= Don I A 'IVI), CandidaLe of :~-ion": Dotse,~~ --&egolev (I, -:ird 1/10 '-istor 111 on "'lationni Economy of the North Cau~,asus n r - I z zo. C. n n e ~2 n i, -1 n n ~~ron an~ o~' ~h ~K-o r, E :I r: 'c r D c) r 0 r n o v ~l a n,4 Ll c r: 0 rl c Dnc e 7n ;.n,~- I ri, ion 71 me r.,! o z 0, n ro J r o, n in 7 i 7 -:,f 'enl i c I o n -n~a:ya -p A.-A 7, T e T ~a fr. 'n r 0 m., ti 0 n p -n E.- I n C. D T, j~ a c%. - u D., r e c r rr:L z-7i 1~~ r: e r., r n - 0 C.:, 7 y e v o a P I'j 7 Z S f3 n n o c n E- o rm n c ct i zits the 7c 1;~a - A e r V L j. eV -I :P i rip-r, on :-he c -3 1 u b s v t r r s I r, ~ h P r 1 F-, a t 1 , n e M E o f h e e r r g;.- n - ec + i o n c rm,-~ n o c S otsent F-7~. oll Agncu-liral E n s e r 6 r h e f o I 10 W I n r S -Lo s,- n -4 K, 3a r r. on r ~i i ~)i: "u, p',: of Ccrn 71 ~nt-- in %z--- t-,c- Tn.~ 2-ca t~.-' r-, f ~-or t he r 10 US r~c~, on i na" i r,;) e n Y u z n 7 i n n r u:.- - s -:'U r n o, n e e i I --e i :--. n t I f i c T e -- n. n i c n I r. r e r c o v!:, - rnStitute of -.Fn~:-Jneerintr in,; ~~oil 'Improvemen. T ",-n:,ilate of 11gricultural Sciences, heal of ,he !.-41r7iratory for ,rri-Pntion of tiie Don-`one ",cientific search Tn~7,ti~ute of 'gricuiv~re, on "Fertilization and Irri- t F on of "',~rn in the Cis-Caucasinn I lack 'oil Re-ions o~ tne '11. ., F.Yplpshnikov, Candidate of Ap-ricultura' 'o' t o v rj t Fresident of the kolkho- "ber-insk-o.,le Znamya" (..i.zov re4cn, :-ostov ob'ast'), m "Peculiarities of th.P Vater 1;.Ystem uf the 14 ~--au,-asinn Flack '7oil Repions"; Ya.V. Smol'skiy, of Agric?;Itural Sciences, on "Mechanization of the ~i,.-tion of Tn~er~ilied ~'rozvs 1.7naer Irrigation in the Foo- I 'a u c a s- s I.F. Kruz-hilin, Asnirant N I &I T .0~ the orth h tov Cblas4 C.., rr- F-n ticr. L t ems f o r ,,!-;n il ov.-p- rs i n t he Ro s T o,- the 3p-atov on "M.,echan - za tion o74~jedir;~, nd 7nder Various Irri-ation Nlethods"; v e r -i c on "So~iking Irrigation her of t~)e Kherson Mhl, in t'r: ec u t'~, of T,',V, Rodionovskiy, Candidate of ~ -- i c ~ i Ii r`i .-cipn!-p--, on "7he )~ccumuiation and -hnnge of in i u s, t n c e i i n t ~- e -~ o 7 n A e r V : i r i o , i u 1 -1 i v a t i o n s o f "-)D t I C- nS s i i: time or -c i Tn. 7rovemenit on j T,,;!-iII- -_`cientific :`onferen~~e _,f the rlovo- crerkps-~In- Institute of and :7oil imDrovement n ~! i. r r i vlon i o n c- h a t -:n n n Pr o f e s s o r MIRk o v ~:ear~ tnil foilo~f,~in;- ronorf-. T . Nefer4ov, Fnzineer -ind i Y i zy-h i A e ru t i r. .--,er of w.-itE:r economj of tne o 1. 1 k o branch of fu~h-,riprovo~kh z" =.,J V Va r t e ns e n t*niz-ineer "'ini~.~try of Vater 7conorry of the zer- z~ in S":.. on the tasks fpcing ter econom:,r in the .7,plin~?rad oblastl Pn:4 ..'7,~rbaydzhan ~rzR; A . A (~vc'-Ainnikov, of Vu.-hgiprcvcIkhoz, on "Several questions c. n lrrig-~ion "Yotem an,_J Agriculltural of 'A'inter -in.-.' 'eve-Iopment of Rice 7eeding in the ',ostov Oblast"; -icultural Sr~ 1 1 5,0-4 nai:latp of Agi encpS and P,I- chiell economist oil YuzhP-iprovodkhoz, on principles lor econo-icil efficiency of irrigation systems; L.V. Skripchin- S-kaya T"T r7a rd id P t e o -ochnical Sciences, on actua-L u e s t i o n!~ o jtITi.:ing river valleys and 1-;eltas, V.R. Zeytsev, ~'a n,, 11 ~-i t ~- -) t' :,ciences, head of the laboratory of ~Ie Vu.--n~ _-.-Ice- .'.',!tion on "The ~,atpr "'upply of Rice irri- lon e - s -he section of ne--ricultur-I water supply and ch~-I,.rm,,r ~i-pr `.T,3, Cvodov, heard the T 1.1 1 -he T~e - t P. r o i n re. r ..- r t s rofessor ~vo A Ili on -vplo,)- e .-n r 1!-.A all Tmrrovement :!:;!nt of tl`e T,-er,,r,,,- C., .~.'-ter ~Supply by the 'N.:)*I..-,- InstiLute of ;-npineerin~r nnl improvement"; :arambirov, -,,n,4idp.*,e of 'Fechnicpl Sciences (I".0scow I(-.- _;7e 0*:' 7rrigation Fnginee= imeni Villyamsj and I.F. Vol-!' i.o k! "". 1-'.'.-Iion -;tf;~ te .1 ns, ti tute of' on general irri- grition problems; ",%7. Kozenko, head of the Krasnodar Gipro- sailstzrcy, or, "i-.e Classification of' the .',*.Rters of the T~riq- Z~.,.,.,O-Xub!~n' Artesian "as-in"; '..Ya- Yel-iseyev, Cflndidr~te on the development of unreinforce-... avv -;:o r w C -ment -1 e6 gr, -1 filters . ell. drilling, D.T', ",avvin, of Tec'5~nicnl ~`ciences (NT~,T) , on "The Experience in perat,.onal ol inertia Fumps of the A.V, Fa- n n sk Systlr7 , 'or Pro-v iding Dry FeFi ons .y 1 C~ r. 4 ~ J - te -o f -_ e c h n i c e n c e- S Dol-inskaya, of ~Ikrzi_,nan on "!.=:er Conauminl~ '.,O_rz:z T.ines or: r'a~tle Farms"; A.A. 'oma- nov, Chi?~:t ~f ,he 7,taI4r,,,-r=d office of Yeliovodstroy, T i T ~_n Construction --ilters ade of C,- r d -oln"oroed c~'ha`~ Nelis"- M.T. Pastyapin, I~i"h lie, t r;f- the of ooil Improvement Ergincer n i tai: i c C o r i n r! t o 1 -:3 cl r t hi s, i n f e c t -i o n -of Lo-.v .-er :j.N, Linevich, Engineer v--)c~er- ir,.-~tituz ( Novocherkassk Folytechnical ,titut~- on ",-:xpEraenje in Using FnOiometric Isotope :~~ethoazi for '--.e.,;earch in !.@ter Froce-ssirg": M.G. Vukhlak, In e e r , on " A ~',ravhic Methodi for --'e I e C t i n:,~ :---conomicAl F-1T)e ria:mezer3 for Steel Nater f-ipes"; V-~. 11,yin, ~'and-HD.-Ile of Tecnnical Sciences (NIY.I), on "The influence ot" the Location of Tater Pressure Reservoirs on the 'perationT.1 System of Pumps, Vater Pipes, 'Nater Systems and I,ater Towers". The hydrotechnicil section whose chairman was I heard the I.K. Feiichkin, Candidare of Technical Sciences, followings reports-. L.A. f-'hernikevich, Deputy chief engineer of the Vses-.nvuzny,, proyektnyy institut "Giprovodkhoz" IA,11- 71rion ~-'l,-inninpz rn,3titute `,','irrcvodkhoz"), on "Standard Flan- ninc, nni !,uestion:~ in ~3Cjentif4C Research"; Votsent V.Y. Avol- 1,3sov (7.11VKh ir- Vil"'aMS~ on "Prefabricated and ;;*einforced :-oncrete ir. "oil 7--provement Structures"; A.F. -'ikcv, ~~neineer -4 vo 4'~ "Prefabric9led ','.Y:~rotechnicai -structure-= P~ ro --ho. o n Card 7/10 in, --'zerbaYJ--hPn": V--, -':--.e:-zhnev. -!~'nzir-er (F-.-Ptizcrsk branch 9 G - 9 - 7 - 1 C'~, -'.1 C 4. 0~ +he NOVC- i tu t e of . ni r, i4 :boil Improvem~.-nt of on "A Ir(-,fab--jratP-i 2einforced ":oncrete ver 'pil:xpy fo- "aver ~:eservoirs of 'r'olkhozes"; A..P. Sol- ,',ito,v, ":nPizneer, on "T'nc. of Fref?bricated Reinforce-4 'Olumbo c-"r' obser- ;oncrete Bulkhendtl i:.v ~',inrorechtrans"; V,'.*;, r ..rations or, the f:[-', tr-ntion through the Tsimlyt~nsk dpm; 1.K. Fe- e,: n i "c e nc e s -a n'4 3 , Ku z n e t. s ev c,, in , -i n 1 ilate . -1 - ~-Ingineer ( Ni I V I ) , o n al, o r9 t o ry Research or, t1he Hydroelectric '-)owe,, FI--1nt on the 1:iver Aley for the Purpose of -Supplying 7-qter to the '!'ractor Plant and the 'roAn -of Rubt:scvsk"; V.P_ T Kononenko, of Tec!~inieal Sciences, P."', n n " 1 a b o ra t o ry Re r, e a r c h ~~ter ilrillways of the Hydroelectric Power Plant of the Fub~lri'-Kainus 'Jys em':; V.V, !;rp-k(-)v, Fngin er. on '~Comnlex Methoda Errigation t e to Control the Slidirw7 -!m- Funture of Shores"; 11.7. Pashchenko I on `~*xperience in Using SvIr7-,ionary Continuous '.hore-Supporting' .1 ,.on=tri;etj.cn". The hytiroenergetic a n d hlyd r o I o g i c a I -ection w',use c-a_-rrr-,n w-- ','otsent 7ikiba, "'an,~idpte of e-'-nical ;'cienceS, 'near-; following renorts- Soldatov, ,n.-,, nee r , on !.-ho'erve'i -`.Csults c~f the Trn-nsfcrm!~tior of e s e. r )hores"; L,- onrITzh-_vskiy, 'c ip -'onFerenc-r of t~-.e a t 'ub i 1 e e n i f i c e c h n i ca I and "cill -,~:~-.)rovement C', 'nstitute of ~*-.LlineerinK I EnF7ineer uzhi-irrovo,"kho:~.) , on "Surf-ice 7.'Pter .~al -sk .-3te-ppe"; ~',otsent A. F, "':imol-hin (Rost7ov State 7U nv e r st y on "'leorraphicol BorIiers of the Distribution of '.'Pya trc-" I, un- ,.'nown~ in the US",R"; I.Ivov, 'PoTsIent of the Dnerrnpetrovs~k ~lel 'skokhozyaystvennyY institut (Dnepropetrovsk Agricultural. nstitiate on "A ';-:~noral Yethrd of Mlonomial 7-x-r~-SionE 'or the Calculation of Turb~-ilenr, 7iow Streams"; K.1, !-ysov, andidate of 7echnical '-c-~ences on "The Cavitation of I umps in .,oil Imorovem e rt Fump Staitions of the Rostov Oblast": ~'avenko, i..'andidate of Techricr-l Sciences (NU.'fl, on "2,e- ,~tl 1 ts y -)n the -Xinter System of 'inter of intakes .7ithout Pqms": V.1', levon, ~')talingrad GES, on "Adv,-,nuei 1,1etho the Construction of the --c:vntion~:! ds of Fitting in JtqlingrFd ""'ES"; F~,11 16,nn-tenko, Candiiate of Technical -.;'ciences and A-y". Tilin 'N!7-,`,I), on "Hydraulic Calculation of the .~'ater 'Intake at the lr'erzection Place of Two Flows". T~-10- join" meeting of -.he hylrotechnical, hydraulic, hydro- eneriretic anl hydrolo-ical sections heard t-e followinp- renorts: Ca - -~ki*na, Candidate of -echnical -,ciences ~NII!41 1*1. ~.n -~`ne TU-~ ie. t 4 J c;: v~F:-. n .9 i t,_ t 4~ o f;,'nz- i n e u r i nri n d Lo r C v E:- M, e n n t --~ rn a of the -7ater jump"; Az,'t~ Koshintsev, L Envineer -in~ licni of the hydrotechnical zection of tlie Pelo_ r* e r " i i, n s 1, ay aon thod r t a Con t ro 1 the Fi I I in P- in o f t n,~- 'fpj,;:v ";tt,~r H--id of' the ~',arqtovskiy nni ;,npiner:r, on `;Ii? *",:,)ntr-cl of' lco Disturbr,.nces ~4n Hydrotcchnif- and f'nnnls"; V.t;.Sukharev on hyriniulic prnblcmf~ Ji. 'he activity zone of the FystiTorsk branch of Yuzhe,,iprovc.,!lr-h-_.- The section of forestry whose chairman was S.F. Bessarnbov, :'andid;ite of ral Scie-aces. heard ~he fo_-ow4ner re- norts: ',essprabov on "The results of the Scientific and 7.ork of the Forestry Department of During ,L.nt_- of Its ".'xistence"; Dotsent F.,A,, Lashkevich and V.P. -4 or~-s-ry --.niineers in the 1'ori an~ Illort"r, nuc-isi~n regions; ~.,2, T.Ulikh, ;,'~~nzdidiate of Agricuilurn-1 --~,4.~~nces, 7~A ~mirnovn, En,~,,ineer, and Yu,T. "olotarev on soil improvemcn, afforest-ition of sandy regions. The second plenary sit- l1r.Rr arreed to nonvene the InCtlh scientifi-c technlcal con- lerence of tne Institute in Fel-.ruary 1959, Car- 1. SrA.1 e2oginee-ring-Devel,-)pment-JSSR 2. Soil engineering-Development- China ~,, AgTicul-bixe 4, Irrigation SYS+-em 5. Watei-Chlorination SHOW.,OLEV, A.A. .- -in brass die casting. L Izd.. j WNITOMASH 45:138-149 ,58. (YI?-k 11:6) (Brass founding) c ,j Dill" lb. - C-Jb-,fE:GObZV.1 A.A., in2b. I t. X, Mold for making large castings under pressure. lit. pro, zv. no.9-36- 37 S 165. (%MIR.-" lp-l~) NT)YEV E, Ye and alkylatior. of dipropyl nl-josphir' -t- p'"uc,~se,, and 3,4~-Lioprwc ov. 3er. 2,Khiru. 20 no.4:80-82 -rl-,*g '65. idrr.. kh i,-.i khes ko.y tek~,nclogii ~'c-kovskc.gr g,~1--.%-t--4,-._' ,Xliversiteta. SHCHEGOLEV, A.F.; IRGER, I.Yu. - * New exhibits at the All-Union Industrial Exhibition. Leg.prom. 17 no.8:10-11 Ag 157. (MIRA 10:10) (Moscow--Exhibitions) (Manufactures--Exhibitions) SHCHRGOLSV _A,.F., IRGER, I.Yu. P _ P_ Awarding diplomas at the All-Union Industrial Exhibition. Tekst. Drom. 17 no.9:54-56 S 157. (MIRA 10:11) (Textile industry--Exhibitions) SHCHMOLEV, A.F.; IRGER, I.Tu. New sewing equipment. Biul.tekh.-okon.inform. no.2:14j~ 158. (MIRA 11: 4) (Sewing machines) 01 r&I -;* K - - SUGHWOUV, !~.?. ,c .elia ~~-DV-type cott-on iiber-3xtra.7.-ting -1- hin-e.. Biu-1. inform. no.3:49-50 '58. (MIRA 11:6.) ~urjtl,cn tl~-Oainar7) KOPTSOV, G.P.; SFICUIGOLEV, A.F. The SFY,3 automatic silk-fiber reeling machine. Biul.tekh.-ekon. inform. no.5:4~~l 158. (MIPA 11:7) (Reels (Textile machinery)) SHCHEGOLEV, A.F.; IRGER. I.Yu. Awarding diplomas at the All-Union Industrial Zxhibition. Tekst. prom. 18 no.11:68-69 N 158. (MRA 11:12) (Technology--Exhibition) tnzh.: T11GY11. F) ght industrf at the All-Union Industrial Nov, equipnent r 11 Exhibition. v.vva.iicheb.z".;tekh.leg.prom. no.1:131-141 159. MRA 12:6) 1. Upravieniya propyablennosti Voesoyuznoy vym~avki dostl2hpniy narodndgo khoz7aystva SSSR. (Moscow-Industrial exhibitions) BOTEEGOLEV, A.F., inzh. Important objectives of the REhibition of Achievements of the National Economy of the U.S.S.R. ~!ekh.! avtomoproizr 14 Do.6: 4-6 Je 16o. (yLqA .13:7) (Moscow-Richibitions) (Technological innovations) (Automation) SOSUIIOV) Nikola- Alekseyevich; GRUI;12%YSFEV, Eik-olay Aleksandrovich,- EOJZII-~E., .ik-olay Ivanovich; POt-*.,'V-KANOV, Nikolay Nikolayevich; S red,; CROMOV, N.D., red. izd-va; Ye,3,,, tekhn. red. [1'.echanization of loading and unloading operations in transporta- tion; review based on the materials of a thematic exhibition] Mekhanizatsiia pogruzochno-razgruzochrjykh rabot na transports; obzor po materialam tematicheskoi vystavki. Moskva, Gos.nauchno- tekNi. izd-vo lit-rr po chernoi i tsvetnoi metallurgii, 1962. 223 P. (MIRA 15:3) 1. Nozcow. Ilystavke dostizheniy narodnogo khozyaystva SSSR. (Loading and unloading) SHC!'R-;G(!U`V, A.F. Practicen t'-c- Txhibitior, of 4.;;e Acni-vements rf t-p- Lational F'conomy in pro.-I.Icting the acY.-IevernenLs of Scviet science; and techriology. MI'l no.9: 1e-20 165. (1/11171, 19-.1) Icb tai ni - Wis dtococ.. ill vf-t,.,o r"Id ~-Ee n c ~-atm- C: C!! -i Lo s , 1,; 11 ( -econd -.rSA P .1. Proirov) Ll:;-; copies 120) U L