SCIENTIFIC ABSTRACT SHAVROV, V.G. - SHAVSHA, T.G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548720017-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SAMBEK. L.; SHAVROV, Ya.
... ..._- -
Sensational discovery or advertising? Tekh.mol. 28 no.5;32 )60.
(MIRA 13:7)
(Gas and oil engires)

SBOROVSKIY, A.K., kand. tekhn. nauk; PSHAVROV, Yu.N., inzh.
Dynamic characteristics of AMg-5B and AMg_6T aluminum
alloy's. Sudostroenie 25 no.5:7-11 My- '59.
(MIRA 12:8)
(Ships--Welding) (Aluminum alloys)

BOYTSOV, Gennadiy Vladiplirovich; NEBYLOV, Vladimir Matveyevich;
TAUBIN,Georgiy Osipovich. Prinimal uchastiye_~AVROV, Yu.N.;
BV--'KOV, D.I., kand. tekhn.nauk, retsenzerit; KDROTKIT, Ya.I.,
kand. tekhn.nauk, retsenzent; SHAMTOVA, V.M., red.; TSAL,
n.K... tekhn. red.
[Strength of ship structures from aluminum alloys; design and
calculations] Frochnost' sudovykh konstraktsii iz aliumineievykh
splavov; proektirovanie i raschet. Pod obshchei red. G.O.Taubina.
Leningrad, Sudpromgiz, 1962. 211 p. (MIRA 15:7)
(Bulls (11aval architecture)) (Aluminum alloys)

L 12939-63 -EWP(q-)/W7(_m)/BDS~ -AFFTC/ASR.-JD/JG ... ....
ACCESSION NR: AP3004080 S/0229/63/000/007/0048/0050
lorlI
AUTHOR: Shavrov, Yu. N. (Candidate of technical sciences)
3~4
TITLE: FatigRe characteristics of the aluminum a3lov
_ANg-61
SOURCE: Sudostroyeniye, no. 7, 1963, 48-50
TOPIC TAGS:. Aluminum alloy, fatigue characteristic, notch aensitivity, streas
concentrator
ABSTRACT: Large scale cantilever ty imena (see Fig. 1. of.Enclosure) of
_Re spec
aluminium. alloy Mg-61 (unidentifiedi were tested for fatigue strength under simu-
lated operating conditions of actual ship elements. Vibrations at 1200 epm were
simulated by a vibrator located-on the builtin end of the specimen. The test
results (see Fig. 2) were as follows: The fatigue =Yea have no horizontal - Bectiod
up to 10,000,000 cycles. The 10,000,000-cycle endurance limit in 550 kg/=2 for
smooth specimens; 400 kg/CM2 for specimens with central hole, butt weld, or dotible
fillet weld; 250 kg/CM2 for hotched specimens; and 180 kg/=2 for itpecimens witli a
single continuous or interrupted fillet weld. Cracksialuays formed sit the
-J
Card -L~

L 12939-63
ACCESSION 14R: AP3004080
stress concentration and propagate rather slowly; the propagation time was
10-15% of test duration. A rapid fatigue test suggested by V. S. Ivanovar, whichi
is based on the hypothesis of energetic similarity between fatigue failure.and
melting, can bj used for steels but not for the aluminum alloys AYg-61, AMR-5B
[4-8-5.5% M -0.5% Mn;,. 0.02-0.2% V], and A14z-6T (APEX 411. Orig. art. has:j
2 figures and 1 t4ble.
ASSOCIATION: none
SUBMITTED: 00 DATE ACQ: 15.Aug63 ENCL:~ 62
AP NO REF SCIV: 002 OTHER: 000
SUB CODE: NLV
.0i Card 21#-L

SHAVROV, Y,t,N., kFind.tekht),nauk
Fatigue charac teris tics of the Ah~g-61 aluminum alloy. Sudostroe-nie
29 no.7-.48-50 Jl 16-L (~9RA 16:9)
(Aluminum alloys--Fatigue)

L 05214-67 IJP(C) qVyTd/JDAim
ACC NR- AP7000764' SOURC-' COD7-: U"/0229/66/000/004!0010/0012
5BOROVSKIY, A. K., SMVROV, Yu. N.
IA,
"Vibration Strength of Weld Joints Made From lKhl8N9T Stainless Steel"
IlLeningrad, Sudostroyeniye. Po 4, Apr 66, pp 10-12
i Ib
,Abs'racti The aut rs studied the fatigue strength of butt, T- and slot welds
madel' u-ith lKhlftqT~teel, ,Large, fl-aK,-s-p-e-Hilly-shaped sprimens were sub-
1jected to cyc c'Venq!I&Vvibrations. A test base of 5.0 10 cycles was used.
I
:An analysi-s-o-f-tFe-exper-imental data shows chat lKhl8N9T steel has a hi ( in-
dex of fatigue strength (0. 8aT) due to its -rf' xcellent ductile properties% A
comparison of Joints welded from OKhl7N7Yu ikanq_lKhl8N9T 4teels shows that
welding has a greater effect on-Ige -microstructure of llail8N9T steel. The
fatigue limit of T-joints welded from IKhl8N9T steel is 9.5 kg/mm2, which is
somewhat lower than that of similar Joints welded from OKhl7N7yu steel. The
Latigue strength of slot Joints welded from both types of steel is about the
same. The fatigue limit for weld joints of this type is not more,than 3.5
kg/mm2 in spite of the considerable differences in mechanical properties of
17
these steels. Thi?tAndicates that when there are considerable stress concen-
trators, vibration strength is determined by-.the 'form of the welded joint and
t-eajD-o-I-oXJCa1 flaw -is: I figur'e-and 4 tables.
various, Orig. art h,
i TP as. :6,902]
+Fend
TOI-IC TAGS: stninless steel, vibration strQss2 welding technolo-U2 fatigue
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TRUSHINA-TMANOVA, Ye.F.; SHAVROVA, M.M.; MAKAnVA, Ye.A.
Yurther study of antigens of the Dertussin pnthogen. Z~ur.mikrobiol.
eDid. i immun.,sunplement for 1956:4o-41 'q7 (MUIA 11:3)
1. Iz Moskovskogo inStitUtA eDidemiologii, mikrobiologii i gigiyeny.
(ANTIGENS AND ANTBODIES) (iENOPHILUS PERTUSSIS)

A"71'. Ye . Y. ; )a V;~ UVA, t , HARATEG , Ye .11
irowing the whooping cough pathogen on a blood-free medium and
atudyIng the properties of cultures thus obtained: authors'
abstract. 2-hur-mikrobiol.epid. i immun. 28 ac,7;14'1-,'-42 JI '57,
WIRA 10:10)
1. 1z Moskovskogo instituts apidemiologii, m1krobiologit i
tye ny.
kH6MIA.FHI_4,U_) ?.~jRTU_oIS)

0:
0 L Is & L A P F 9 1 1 1 .1 T I At 0 OL 00 it, I
of 4:

Deteravinsation of the rtdioactivities of gases of the sec- le
volcanoes of the Klyucherska a Mountain in
y
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Awolvit X-im.hwho 193S. No. J. 3.' W. Ah,ot R,1-1 90
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Anorthoclase from lavas of the volcanic regf2a of D ri an
USSR '(S.E. Mongolian S.S.A.). V. 1. Vlodavets~ and ~31. T C- P-
Shavrova, Vaprosy Petrog. i Mineral., Alad. NaukMT~--
3.zz-.-z, 11 (1953).-The anorthoclase phenocrysts of the
basaltic lavas have diameters up to 2 cm.; the crystals are
rarely triinsparent, ustially translucent, whi
-stanc-like. They Fire evidently of intratellmir Zn-oon.
. and
slightly Lurroded by post-effusive agents. Consts. of die'
transparent cry stals: -y - 1.530; a - 1.524; 2V - 42*
.optically neg.; d. 2.50. Chem. analysis: SiOz 06M'~ I'
MA 21-36; CaO 1.01; SrO 0.2-5; BaO 0.19; Na&O 7.68;
KjO 4.50; LiO 0.005; Rbj0 0.005; no Cs:O, 140 0.12;
sum 100.38% Or 20.5%; Ab 63.4%; An 3.3%; Celsian
tnol. 0.0%). Frain Belyankin's diagram (C.A. 21, 1238)
it is evident that the mineral Is an anorthociase remarkably.
high in Na feldspar and very low lit An, of monoclinic ryin-
inetry. a typical high-teinp. madificadon, metastable atj
room tenip. W
LO

Fw (260

SHAVROVA.N.N.
Some microelements in lavas of the Klyuchevskaya group of volcanoes.
Biul.Vulk.sta. no.22:67-75 '54. (MLRA 8:11)
(Kamchatka--Lava)

NABOKO,S.I.; SHAVROVA,N.N.
Pyroxenes in lavas of present-day and recent eruptions of some
Kamchatka volcanoes. Biul.Vulk.sta. no.23:47-50 154.
(MLRA 13:11)
(Kamchatka--P.Yroxenes) (Kamchatka--Lava)

SHAVROVA, N.N.
Report on the radium content in lavas of volcanoes of the
Kly-uchevskaya group. Biul.Vulk.sta. no.24:65-67 '56.
OLRA 9:10)
(Klyuchovskaya Sopka--Radium)

ZIf~' I,I,I 11, ;II W I ~ I
IV [I In r_1 t I I 1 00iiip I ~-x Compounds C
jt)ur 1'. 1 NO " ]~(Y) "I " 111
:"Althor V4-kt. I Spi ts, nN.fi. Sha,iro,r..
Inst
Title Stud,- o-.' lijdro,is So(V iu-,i TAntal.,ttes
n-rig p~lb ?_h-Obshvh._K_him.;_jI2D N,- 5 1-58 - 1260-
.,,bstract SOdi'um Wjre obtained j~- -cni:.!*~l n.-, Ta2c5
with NaOH (TI) i_-j tile we:.,Yht ratj G 5.
The Dised iq- ss ha: ii:-, bceii w,,rhcr1 w' th water in order
to remov.j. t! Q -~; '1' was di.,;solved L:i water
.0 0,0: -1
hnated 1, thQ obtrtLll`~d sol"t 0; w...s por-ted
500 Uilt-; 1thu 1--c..'st'liliz-1tion S'- rted. Under tlicse
c:)nd'_tions - 1~ -
PF2") (1II) was scPl'_"L~ted
la the forin of r1_1
*c f jA-Li.~cs W'th Uneqiial sidQs.
When 0.1 o~* Uhc ncri:rl solution c: II wLs Added Lo the
illitiLL1 mass f~t ft lo~v tLim-p-_,ra1L-1uz ,i prec,rAtate of
(IV) W-is this precipi..
t~-te_ cO!lC_*L:-,ts of' LAt)..e ne~_,dle crl--,stals of --
Card 1/2 -3--
USSR/Inorganic Cht!m1strY. COmPlex COmP`inds. C
Abs Jour Referat. 7.hur~na! Khirilya. No 6, 1957, 1-8624
prismntic shapa. IV was obtf~ilned also by evapora-
ting -the arjueous solution of the initial fused mass
at a temperature above 850, but in pr_~smS of a lar.-
er size. d2o (3-58 and 3.78); refraction indices,
pH of 1% solutions (8-58 and 8.48) were determined
for III and IV. The interplanar spacing of III and
IV is quoted. The authors arrive -to the conclusion
that it is possible to obtain two different compounds
- III and IV - from the aqueous solution of I combin-
ed with II, depending on the concentration of the
superfluous !I and temperature.
Card 2/2 -9-

SHAVRO VA. 14. It.
Radium and thorium content of lavas of the Ser7yachik volcanoes.
Biul. Vulk. sta. TIO-27:51-54 158. (MA 11:10)
(Serryachik volcanos s--Rad toact ivo substances)

3HAVEOVA, N,V.
i~adilm ani thorium noatent of lava.-; .-)f --te 3ezy-mjranr~j Volcano,
B-iul Vulk.sta. m.3-1 -.28 31 '61. 15 12)
(Dezymyamiyy Volcano- lava.) (Radium) (Thorium)

SHOROVA, N.N.
Radium and thorilUm contents in andeaite-basalt, andesite,
and dacite. Biul.Vulk.sta. no.33:67-70 162. (MIRA 15:12)
(Rocks, Igneous-Analysis)

IRKHIN, Yu.P.;_SHAVROV, V.G.
Theory of the spontaneous Hall effect in ferromagnetics. Zhur.
eksp. i teor. fiz. 42 no.5.-1233-1240 My 162. (KRA 15:9)
1. Institut fiziki metallov AN SSSR.
(Hall effect) (Magnetic materials)

SHAVROVA, V.S.;KLEMINA, Ye.j.
. . . . ...........................,
Certain data on the -Droblem of practical significance of laboratory
investigations in diagnosis of viral influenza. Vest. otorinolar..
Moskva 15 no.2:28-32 Mar-Apr 1953. (CLML 24:3)
1. Candidate Medical Sciences for Shavrova. 2. Of the Central Poly-
clinic of the Therapeutic Sanitary Administration of the Kremlin.
137-1-165D
Translation from: Referativny~ Zhurnal, Metallurgiya, 1956, Nr 1y
p. 18 (USSR
AUTHOR: Shavrova, Ye. B.
TITIE: Research on the Effect of Technological Factors and
Sintering on the Elastic Properties of Silica at High
Temperatures (Issledoval_-L~ vliyaniya tekhnologiche-
skikh faktorov na uprueJje svoystva dinasa pri vysokikh
temperaturakh)
ABSTRACT: Bibliographic entry on the author's dissertation for
the Degree of Candidate of Technical Sciences.,
resented to the Kharkov polytechnical institute,
~harlkovsk. politekhn. in-t) Khar1kov, 1956
ASSOCIATION: Khar1kov polytechnical Institute (Kharlkovsk.
Card 1/1 politekhn. in-t)

YJ-.YNATqSKIY, T.S.; SHAVROVA, Ye.11,
Mo,lulus of elasticity in dinas bricks and its derpendence on bps'zc
ter-hriological factors. Ogneupory 22 no.,4:241-249 '57. (MIRA 1C-7)
1. KharIkovskly politekhnicheakiy Institut im. Lenina.
(Firebrick--Testing)

KAYNARSKIY, I.S.; SHAVROVA, Ye.B.
-&W.
Interrelation of the stability and elasticity of Dinas brick. Mat.
T-,udy-KhPI.31 no.1:37-42 t59 (MIRA:13'.10)
71
k?irebrick

ATTM7, 0', - S
S: Y j'~Y, 131-58-7-6/14
IVIT LE R ~-11 es ~;Gvernin.,3 tne Cilan--e of t',,.e Elastic Prol,,erties of Diras
on HeatinE~; (ZakonomlernGsti izmeneniya upru6-ikh svoystv dinasa
pri. na-revanii)
1~
PERIODICAL: Oc-neupory, 1958, Nr 7, PP 313 - .3!9 (ussa)
ABISTRACT This papor determines the caitses of the chanCe of the shear
rioduluo within the temperature interval of from 2oto 15000. The
anE;les of rotation at various temoeratures -;,ere measured with
a number of samples (Table 1). A considerable change of the
shear modulus ~,an be observed on the heating of the dinas to
E~000, -'s is shown in fiCures 1,2 and 3~ as well as in table 2.
On a further heatinL to 11coO t-e shear modulus does almost
not chan,'e at all, at temperatures above 11ooo its decrease
~Lc,?ordinrr to the rules begins. These chan,-es depend on the
addition.q. the sDecific wei-ht as well as the formation of the
liquid -,)',ja,3e. Fi..','Ure 4 show. the dependence of the decrease of
the shearing modulus at' 175c' on the content of tridjnite of
tlte dinas, and fi,,-ure 5 shows th-t at 2500 on the content of
cri-stobalite, 6 shows the de2~~ndence of tl-e decrease
Card 1/3 (.-~ the ~"-.e--r mo,luiu~3 at 2ool on the content of qunrtz In the

A
Rule, s Go,; erni-n t- t: C-. - z,--e of -, I' P- El --Ist i c Pro ,ert -i e sju 03
of Dinas on,
jives the of the s,e--r modulus of the
te~i,-erature, interval of from -1150-10000. The
of tl-.e de-ree of increase of th-.--- s'-Iear
the case of a lieatin- above t-~e inverEion temperature
on ---.e of silicon oxide of the dinas can be seer, from
F--,--ure 7shows t-e dependence of the increase of the
.1c"ir ~in at 8ooo on the total content of tridymitue
s t o, -.-l i t e ~f the ~Iinas- Table 5 tre change of -the
mo, L.~Ilis of the 1-4-inas on a heatir.S within the interval
0
1.- 'Lh.--. dec-=,sa ull tKe shk-,ar modulus of the dinas within the
teri.ii~er:~t,,:re interval of from 2o to 25oO is dependent on the
ch,~--in--ez -!f t~,.e modification of tri,,Iy-ite and cristobalite.
2 The -Ie~;ree cf the increase of the shearin6 modulus within
Z,"e teri:,~erature in'erval c-f from 250 to looo
1 -1 0 denends on the
c o n t e:-, r. o -" ad" r! i t i o,~ i s
The 'e-.rE?,IsE-
c-f t',e olear modulus of t'~-e dinas at above
is jeoendent on t~,e fcr7,;ation rf the liquid phase. Up to
r"!IOUre 01 - 0
Card 2/3 a te,- ' 15 -'-' cIinas with a nofmal ~ozntent of Al 2 3

Rules Governing the Change of the Elastic Properties '~'0'1/131-58-7-6/14
of Dinas on Heating
has an elasticity whichinsures its performance in furnaces
exposed to heavy work for a long time. There are 7 figures,
5 tables,and 4 references, 2 of which are Soviet.
ASSOCIATION: Kharlkovskiy politakhnicheskiy institut im. Lenina(Kharlkov
Polytechnical Institute imeni Lenin)
1. Rock--Elasticity 2. Rock--USSR 3. Ceramic materials--Test
results
Card 3/3

SHMAUCV, N.A. , prof.; SHAVROVA. 4;.11.
Prolonged chamothf!r-joy in tuberculosis. Probl.tub. 35 no.7:50-55 ",7
(MMA 11:2)
1. 1% Iustitutq tal,vrkuleza AKII (dir. Z.A.Labadeva). 2. Chlen-
karresooodent AMN SSSR (for Shoelev)
(TUBMCULOSIS, PUDIORARY. ther.
drug ther., prolonged)
(TUBIMCULOSIS, MILIARY, ther.
drtW, thor., Prolonged)

KOGAN) S. M.; ~HAVRUK, A. D.
Experience in the use of pectolytic fermentation preparations.
Spirt,, prom. 28 no.8:34-35 162. (MIRA 16.1)
1. Bobruyskly soko-morsovyy zavod.
(Fermentation)

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can easily and vapilk-ally explain the recernization process
'I' ille reur"ll"getne"t Of c&ff
b
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lorneol, and
4inm-r%ely. and other Ispik-al intenriations oteaved in the
Snal'I'M11 TeCiPTOCal traffangeMentS of the UbStitUted
Jp I-amph"les and Istmlleals (cf. Houlsen and Pfanivwfl' zoo
C A. 26. 1 2V 2. 3245: 27. 2171,671 Chas. Bland: WOO
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00 it
I - -V o i T ZA An L I a ad o I iff w 'j a 0 1
10 so 'I prPlo orld stir %91 PC a U It of re 1 o' "o 0 0 0 4 0 0 00 0
*Tod: u: 0 0 0 o 0 0 0 0 0 to 4 6 0000 0 0 0 010 41 0 0 4 0 0 41 0 4 & a 41 a 40,

0 0 0 0 0 6 0 0 0 0 @1o 0 0 #10 o 0 a 0 * 0 0 0 0
0 0 o o 0 0 0 0 :0

a 11 J# A 14 11 IS ft :, P - - - - - " - -

4
0
A I AA III U W It

.
9
0

-
00
lartiiiiry propydeahyl akhol. A, L. NUAVFYFILI. 00
00 &~'*. Clem. kV.S.S. R.~G, l3lo-m(likW). t(. C. L29.

0 3,0401. - PF"PAJOl"hyi UJL. (1) opult) lint 1W list-lid. likoll,
oo A lenchme (U) and PrUgHr. AUylf"whyl ah-. r-talted m
,:i% Ticid liv adding, with nwelt. Jmking. within ~ hr,
of r A tlli%l. Of Ifil X. 11 andAll g. allyl bruniuk t,,.Nlg tat I;t.()
0 rimug a few I corstals. Afut refluxing fitc *-' da%% and
Im-ointin. of the renciii,ts mixt. %ith dil. HSAI,, it -00
of
fractwirtated. J! hit has d.'* nV
=09
00 J.49m. m . R. 'Jull. C-JlCd. CIII-MV11C IVILICIP'll
-
.
pt black) at tenilk. gave ni,arly llm)e~ 1. 1. . . lx zoo
00 J."' 0"2, -it' 1.44. M. R. Al.2. cid,d. ~AiAl;. llt~titiic
0 0
I with Na,~4). at I:Ul ro' bir 8 hra. gave im tinmid. hydi.,

ZOO
00
goo
00
00
00 roo
;; 00
t'l 00
00 ---Go
::0o
00
A I t L -t T AL 1. Lk WC &I
L ITf MA T 41ti CLISIVICAUGN t: 0 0
stes
.
.. I
-
':. -
---l ko0
,
i i- r i ir +
too
0 u A, -0 it I s OW 0
11 1- N it K a R u

0 0 0 0 0 0
00
700000060690000069
000 n 1 1.
4na
0 0 0

0 0
0 0-0 0 a 0 0 0 0 0 0 0 0 0,

w o o 0

L L I I L )I x L P, r I
.

a
if. C. A 29, 2157'. -111 lilt CallIpliclIr
III th, Ist type pr-p--d Ill and 1
iJ. Rais. Phvs-dw". S-1c. 29, 121,1pV71-. J-
1-k.gs-A ij~ gavt AU.

00 111
1- IV. It Igave I
p-p-Al,w Noom.,limot"I
a IIV4 F'Sph, it.. 1111) g.., Ih,
06 011.11-1 W III,, I h- 11 -A
J~t v t".k to I ~- L~- e%pWtw,I 1.5 -,,mm
of dulivilralum ul I xmvv 11 Limtousinat-I with 11
00 opwaiy uwtiv. it.-thyleyclem. (ki th, 1-
Isruluwy rxIst'. And % WXiCS Of Wlittlit-1 1.1 C-11
00 formulith it is shown ahat the 2 camplienc rturn
00 1 at and Ind ty1wo riptaiii not only [III, ruct-ii
l1w o4tv"'k'n Ij 'Anildwsm to and I

0 0
A
till :4
IfFUIIj(-
milevskif
-t ... thyl
11-10,11
00
00
..I --1 11 00
t1,.,1 111, *0
And Hk
oI pr- -00
JUFAIMI -400
guinmit~
Afion III
tv'r-tv.
wbww'
Ch- Ill.n.
00
*09 4000
00 :0 0
00
00 LO 0
0
1. IT 1. 1 4'X
0 0 0 0 0 o o a o 0 0 0 0 0 0 0 0 0 0 0 0 a 00 0 0 9 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 a 0 0 0 0 * 0 6 0

0 0 0 0 0
11 to4 11 111 ita 21 u a )i a 16 v a It mll uUms 161: at R w .1 41 &1
t_A ]-1 PA #1 IX W Ct4s k i d. j. 1. a 4 4-t a--I v
L 2 L-1 L. A A. A L a N.J.9 A I
00 -00
go -06
00 a 00
RACOMLUCM 10 the CSmpheUe reaffeapment S S.
00 Nistnetkin and A. I-Sbavagin. .1. Gen. Chem. (u. J,,K -00
R.? 7. 3-6(1-937).-Repty to flotiben and wantuch
go r C. .1. 30. 40001 Cha, Blanc -00
go*
00 J =00
coo
of =06
ro*
00 a'
!Coo
:O:0 ~11,
;600
Nee
L A &tTALLURC.KAL LiTtRATURC CLASUPKATICM tso 0
it v *71 An I % a tw 0 0 v
*I D U VS AT G it im n i
; . a 11 It rt
0 0 0 0 0 o 0 0 0 0 0 0 0 o 0 0 0 0 0 : 0 * 0 0 0 g 0 0 0 0 g 0 0 0 0
`Z944000000;0*0000000 0 0 0 0 0 *~* : :1 00460060009*6000901A

11 if 11 14 U b1i It WI 19 a a A pail Mil ids Jou a a a a, U
J. M U Y I- AA a a 0 aft , A t I--& - I A k A
l
".of S
41 pit .41, I~U fillo
fes
-of.
041 .' -- -- . - - - ~

Oc
hette, re-
dw in the cam
~
O
ti
l f
l
d '~i
oin an
racem
x&
ca
nvera
p
p
arrangement. H. The changul of optical activity In the
1
l
h
l
A
i
t
d
b
l
d
h
i
f
b

60 ,
.
cc
o
s.
on o
st
tu
e
ternary
ofny
a
e
su
ydrat
=gin. f. Gen. Chm. (Lt. S. S. R.) 7, 20',%1-77(in
I
NK
Th
I
qt type
.
e
2077)(1937); cf. C. A. 31,
I
oil dehydration cited in the previous palwr is acmutpanied
00
A by a change in the Cskeleton of the compd. anti a reversal
00 tit the sign of the optical activity. Inthr2nd type. there
i
n 3tructure"r the sign. Thu.,, tn~thvl
istiochangeinn
66
feuchyl givea a-methylefornithenr (1) bv the 2ral type
ale.

00
00 with no change of sign, while purified tertiarv niethOwanvi
.&Ic., (*IL, - 12.66% gives I with a changr.1f,iKn. Change 00
00
of sign occurs when tertiary phenylbornvi ale. gives a-

1116
phenyleamphene. but tertiary benzy1bortivI ale., !ah,
-23.12% gives benrylidine compliant. jalt, -67.97'
=00
00 3 rbedehydrationoftcrtiary propylbornyl ale. goc,tliv both
'
00,, ;
I Iii%r*
ulecan
typies,whielt plains thespparent exception- I
be tol"I to del . the course tit a reaction. Thus. tertiary 00
00 allylbornyl ale., [aft) - MAW, dehydrates to give a mixt
2
ClIlle
60 ~ntjr. a large amt. of a hydrocarl;on (11). 1),. 05-7% d!' '
O.Siridll, nj? 1.50M. [alp -0.5.47*, and snialler amtq. tit
00
K compils. bo P-1-4% d:' 0.896-18, PiV 1.4?L57, I.In
*
-
00 and ba W-2
. d:1 0.81X).%. Ril? 1.4921, f.11, -29.23%
rrsp. 11 1.% thus allylidenecamphane. This is provrd,
oo since it cannot be rehydrated, and h nxidired by KNtnf),
'
to camphor. (ClOiH), and IIC(NII. and by N30, to cam.
phor. H. M. Leic"ter
00 d
A
,
00

A I I S L A *ITALLUPGKAL LITERATURE CLASSIFKATICk
c.K a.. it, t 00
00 k Kx
0, 1, 1, DIP OW6C Kff- of A111 L S a Od 0 1 ME If
n I :is
0 0 q 0 4 0 a 0
0 6 0
f9 9 0 0 0 0 0
0 0 0 0 0 4111 a 0
0 0 0 0 0 0 0 0 0 0 0 0 0

-IS
0
0
4
0
0 0 0 6
0
.1 1. 1 ; 41
AA
A 6 A A It L a h r 4 K $ I Q I n Q W tt . t!
T

Racemization and optic&] Invill'21011 during th* CAM
phene rearrangement. fit ne sterectchemical nature
"f th reactions of 4 methylbom"i and 4 mothyllso
loorneul. A. I hJuvisguA. J. (;I," ~ I htm. 0 ~. S. S. R ,
7 ,-(j!I.171: if C 1 3.1. 21,1111 Whrit 4 owthO

... ........
00 . ..... .II !-
I it. ol-h 4
1-m 1.11-
00 Iml I

00 1.

00
00
00
is
roe; aso
09
0000
00 00
A I L a 0 1 A L t L 1 OL At t [I 1 0 A I Lilt I ItI10 11 41 JC-. t I
Gigs
AA L I a Dd 0 1 a I a T
It m or VE IT IT .1 if "I n I is WIG
0 0 0 0 0 0 0 0 0

A A
go
I
00,:
00 ic
60
00
00 4::
so r!
OG x
of J;
00
0 0
00
00
00
9 0 0 0 0 0 4
0 0 0 e 0 0 fWA 0 0 0 4 6*0***:::::*
Is _WPERW ww! UU 110111,
L J2 t 1- LAN I T 4
.-is .0 Iko 01viss 'IV
44dethyllboraylatic and its hydration. A.I.ShAryim.
J tt.. Chem.
tionvof 4-triethylborrivol and 4-cricthylisuburneW (1) is .y the
-rithatr method Civ" only 4-methyllournviessr. Wbeq
this, i~ lj~ted with AcOll in [be pr~-n~ of H,.4), oc Zo
Cis, only thcacrLatcof I is obtained. This i~ c~iiy~.pond.
:o givs- 1. -imict, no new isk. i, obtained, doubt i, cast on
he work of Achinattiviict. (C. .1. 22, 4517) and Krestiu-
kif and f;sbt-hcnko C. A. 31, 43M1).
-00
.0
800
zo:
~!
i :
0 41
zoo
WOO
i 1300
A I a L A A17ALLURGKAL LITERAYL41 CLASSIPKATION I Z tioe
3roo
K it K St K 11 Lt It 0 3 7. 7A An L S it Od 0 Is 6 1 IN IN I A3 0 3 1 T
1,7 KID q Is ano-
" a " so "! 11 :A
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 * 0 a 0 0 0 0 0 0 0
0 0 0 Ole 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 We 0 so 0 0 0 0 0 0 0 0 0 0 o

0 0 0 0 1
00 0 0 0 & * 0 0 0 0 * 0 . r 4
6 1 1 4 ) a t . , W if u it W u 16 ty it it 30
00 A I- _C .9 t F _r, ft I L L I- JL_ P_ Q a I . I - LL Y L1_.

0 preparfition of feacho
A. 1. 51myrygin. J. A
go IIN)1-3(in French, IW3)
00 fterretvveringanethole
i,
*
4r! was refracti
,
. 173-210
tions (IM-210% tatal o
IIN03 (if. 1-4). The
-
I'lic Yield Miq 10-1,21
,
j
00
00

0 L1_L_
ne
pphed
(19M.A.-The
,
onattA
f
ISM
j
S S L a SETALLURGXAL LITERITURE CLASSIFiCaTIC.
00 it -T
's A- 1-.
u u IV so LS
or . . .1 ; .1 ; .1 ; .1
ig a
TOOO & : 14
0.0 0 0 0 0 : : 9
a 34 a a v Is 20 jo J1 u 13 )d z is I? a x C it 47 a a JC
AA U Ix IM u JL. -)--. & i I_ 1, a C A I - 0 S a _L'
from the Witate of fennel oil
Chrn,. (U. S. S. R.) 12,
vrastu t,f fennel oti.
witsfractiotiatedand thc(raction
thrcr tum % and the frac-
4 fractions) w,re treattA with
fruchone Oitaint,tl b. 192 3% 00
I'v wt ~4 the wa'te It-d.
A. A. P-IK-Ity
A
=60
ago
1Z '00
40. Woo
00
~v a I W It s 13 a 3 0 1 WX
n i X, An L
0 0 0 0 0 0 a 0 0,
: :4 : : : : 4 0 0 a 0 0 0 0 oij

1000*00000000000
lot*
*Or
oom
0 O:r
o0=
002
0-
00
09-1
01
*G-60-0090000000000
lrx
I C 0 IF G It X L 0 0 0 FE; 4 S T IN V7 i I I Ol"s X 31 33 111 315 36 pb RE 30 Co #1 42 43 IS n
J-1- ~ --I ---- ~- t.
Ist ..V m LETTER I_-O Lill t& : J!
-Vg.
?s
mollyNOISIT"D lonlyfUll lV3190nlivile v I I
00
.00
pso
:4, 00
so
00
00
oo
7

*
-palasisamq But III maxud aql U! n -1 1
FN . -
, ;' 00

10 UOJIWPAq~p
ucliert-tuciel ;,Iq-pid aqi '(fl) loatu'll
o
i
-
l
du,'R
Uv aua
A

0
.
j"
m" p
Aq pauliol 1q jillwl Jqj amrq_
q
jo vijvd jwnW jo mius I muls p0qlatu alvqtuwx aqi 44 (1)
I
00
(Otial)
I-m;-M jo uD!IcjpAqaa-'." 'of 'r '3jsl
IFLOR 101 ('s 'S's *n) a".) fig-, r -v -
00

POTAM "WOU" ev L4 re-cm p
cj
Ir 00

00
33 m m In VT -T--U -T- 5 4 q -1 'r- T-r--~r 7- T--l -7--T - v -Y
0
It of K a III Ir ff u :9 It OKUL-F-A-ff a of a I IT 11 cl n 0 (1 ti 'A 6 1 1 f I t
- I* *-* 0 9 #-*99-9 0 9 0 0 0 a a a m m a A m ~ - - - - - - - - - -

0 0
0 0 oil 0
I L L L I k J! J L L t'
o cc 1(

0o

oil 00
-00
00
00 Hydration of boRraliene and its nearest homolog, 00
ALPd
~ 00
00 m ~.
W h.b.K.) 13. 4W),-M11118)(111 tit.
t3i)6.5-7% 1.11, -:111AW kin litoll), was convcitcd by the
00 Chusaev xanthate Tnethod to tuwnylcne. which. after
plunwation by pptit. "Ith 11,0 it.t.1 Aq. Atc. NA011 .1111
'
* '411411
stra dmin.. in li"A.6
tfrx)in HLO111. jalt, 10.40
(in
n
Mel
h). Thi, Jlfi g ). IM g. AcOll, and ZnCl, heated
30 111's , at .50 5'. x4vc 19 g. Initirct -- And P-dcrtAte., th.
'
*
111- 12
O.U8114, nt, 1.46W, Alydrolytetl by heating .5
, it:
oil hr, with aq. sk. NA011, follo*ed by pouring into 11,0.

J
0
0
10 the - an,! 0-ale. mixt., in. MI-V after repeated crystn.
front EtOll; a sterro6unter mixt. of the known borneol
00 and a new i,anwr, which wa% nut sepd. AcOll (1W g.),

0
5W,"v and 15 x. lwymytrite heated 'R) hm. at
3
0 4W)", gAVC a inim - if a,ristr,, hit 101-5% if." 0.9W.4, 00
mW 1.4048, C Om x.); )jydrulysis, as above, pvr
again . I'mt. if i.micriv l.witels6. in. 198-9V (in sealrd
capillary; front petr. ether) 4-16irthylLmwnylene. tit.
0
preld. by thc xAnthate inethod frous 4-irwlhyl- ~
iwihorneol, gave u single aectate, hydrolyied to 4-nicthyl. 90
qW 1-mcol, as ilewribed earlicr (C.A. 32,29181. 34, 4041).
C, M. Koolapoff

.
00
:

- 00
0 0
0411 woo

:
-
,
'
,
-r- T- I _7A
I
,
;o 0
40 r
9: a
0 it It An
Af
,
1( .1
~
13 n
, 4

Z 0 0 0 0 A 0 0 0 0 0 o 0 0
.9
o
0 00
0
0
0 0 0 0 0 0 0
0
0
: 0 0 0 a
o
t
g
0
0
*
0
0 * 0
.
0 0
00 ome 00

0
0 0 41,0 0 0 0 111 0 0 * 0 0 M_g 6 41, to 0 0
-* 0 0 0 411 0 0 0 0 40 000 00
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 010 0-04-6 0- o
0 00-0
1
U 13 14 13 111 V So ft 40 01 It 0 OEO
o 1--L-AA 64 OP Lt. I w a- A -- A
0
00
0
00 00
00 CAMpjLbene rearrangements and their optical conse-
. ,
1 -go
r 4
=h 4
00 I
.ptI,QI method geLvic
,f lite ... call with Avolt try (lit
00 rriAtioirthilm III th, oran,Gwitutwil of -,oce hylearelillcill. hydruclarballk.
;.,ndhy1iw,,hor,#yi aersair, It 0'
00 into 4-tairthyli.4s,rij-1 And of the notional ititer,haugor -I J jurt% Acol I, I III 2,r;) lliSO.. hiratcd 10 Illes. lit 54-P)I, i -6 0
4-invilitalwaltoriwA An-I d-inethyVainplivitv confifincal tit, which oil hydrul"6 for 3 hria on a steant bath with &4-
-
09 Fatrvi-mll -11 lite 01-tia-A of caul- I * (from
tIc. NAOI1 SAw 4-ffla`1Aje4&jOb,#r%#O1. tit. too- 00
1
00 f phent reart.4 nit iticial % (C.. 1. 29.21157 1) it( I ypor I (W 111,0), 1.11, 18.74'. -ri,,Wry niethylleachyl tak.. an.,
`%W
F or
ki
ith 11
1 li
i R
N
11
Oil
d
A -go

go -,rk
a, an.
1 11-
U
w
an
c
typt
I I S.) and 00 g.
_
t L22
6 1 ". I., I 1. 11 2V M01 1). (:it
_75-
It
,
1
hr
; i
l
;
N
a
l
li
C
800
o,
lil.
tio-
hf. A'. 60
L1
SM.
nvo
v"
II
_
alivT 4-autt
)1) -5
ay
.
it. loweir'l III hrl. to ;
00 vrra" tot sit r,tulwn. liar 1,4tt4-r inv-PIvi, 2 htvrr%oon, 1,)ttlyl Atytmr. hot 110- 11 *, which nit hydrol"is lias above =so
I
rettiAry iii.ihyllarn'llyl al'.. IFU'11 tallelluld rrikv- IiN)-I*- 1011, lie-ill"O"Ill
'
Iroo
inithellY.
two) rewlily 1~. 11,0, calocc4ily tit the prt,icucc of iodine, I leatitag the% with 3 part, KIISIJa 3 lars. to "
' -
*
00 and ria,146 a -mirth Yka mip4ew. lart, 170-2
. in. 23.5-5'. then at 170-5- gave 70'~ d-MeL kat hC9W M - '")_
'-_1P4'
' 1
1
aa'
*
i641
21 Oat LtOl 1). Trcat -
d:' 0
81521
1011);
I., I 1, 36
5F (H
Oll)
M
I
T
j j
.1=96
I .
00 .
.
.
.
.
.
,
.
.
~
c
.
(frout
(cloI&d tube
,
I
Addeo. of AtOll as above and hydrolysii of the "'vLate 1:1 coo
go juve 4-trittlavl6oloorticol, We) 7.38* (EX011). PUIV a- Z:9411
inpliene (5111 g.) and t5o g. AcOll in the Pmence
uncthylva `J 9
)f 3 drov, ,A)% fl.SO. beated 26 fers. to &)-5' gave - -
j
:j "41119
otore%icird hydrocatrbon and 2t) a. 4-nlthyI6oba:arnyI
: :Z* 0

00 .,crtate. b, 1'.11. 35-St"; hydrolysis a-A allow ve
r.11)
(cleamed tube)
l
13
)
0
*0 .
, an.
g.
1-tnuthylisotoorneta
(
When the hydrocarbon mcover"din ether
Above exilt, %%ji retreated as abovet, the amtotte aM the
the liat-runsartataks.
th
i
i
%
an
ty
21c. gave lo,,ttr optical act
G. lit. KoactUrooff

Zroe
WOO
4
I a 4 CF III I if N to _i-S

g- 1-
It ZI

0
0 0 0 0 0 as 00 0 a 411 0
0 a 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 o a .0

0 0 0 00** sees 00 go 0
-&-wote 0000004 iiiiiiialvivilm v v
~,jl T 04 1 0. 1 0 1, 0 IS To * 0 0'. 0000000000600 0 0
k '1 1.
it A I", AA
so "Jlf4
66 KT-- PF.,
00 A Transfortriation,4 trrtj&ry propylborneel into secondary
4-proKylborneol fit vninection %ith the mechanism of
camp ene restranjentent A. I SILivrygin, Zhur. -041
OhAtM Khtm 1 1 ( -, ti. Chein., 18, 1111,17-1104091S)
The previ-usiy pt-q--f chruie I Natrietkin and S.. C.A. 00
00 "ful tile re.l.jur hy. 0
Ivied -In fill lwt,() all't evilm. If ill,
telmov "'T1,1111oll, 1, 11 r I: f ill, h~dr-Articiii,, -00
00 a thr r I c%1- I., I.
ough ga".1,41WI: Illeb,"t ,vi,.I,l 11,4.11S, ; I %%a%of.t;uued froin (15
all tile 11111-111"I'.0, f..t!r,t-J1 ,1 11 ..fld hY tile cautphrriv ;00
~ * ..f ill, - I g. IS V-11"Warl.m. under tit, %,- c-tdition%. Itrger rup.%
a ~ I -"'I IvPe 'Nalmtkiii- lr)*tjc)v,&, J. Tile 1,11)%. pr.n~tli'.4 of tile fill.
00. _,I;5'Pf2A)j. '1*11, Cliff- it irti-il IKtrt If tile lipli-irloyn tit- Autseil unt-11AITS"ll,
00
fly] and I'llefly] fill "fil). 'It..I, A fit, -iftivily; tile Jr.
I,NWFI~1.41- farv 1-411IT'Illutrd tit, It,. H."I. df~t 9 fjjtl~. x3ve
I.Axwnr,d, I rr-ti.. III - It%
m.,h,g,KJ%lY. Camhor', -it' 41,21' -1.711'. '1114- rt~tIIIIIII: ITT. "i-, N-, !":j" 7.1#-.'
t rf, - I t,, I i rf jary Alyll,,rn vlalc. accurd - tile '1141. T-111ts q)f Sivk-fiv
17:~ii its 'NJ' C* vielif; [tic product. 40, 213~_"~ G. M. K-Aal"I'l
it" It IW K li-di, 7. 1
1. 15 1-1-, Hyar')9ellation wer Raney
b- Ill 12 , in. 30-L",
11.71 (1 ~4111` *
Ill !-"I tit I; v,,k. AcOll and 2h K.
U0 , I full it, :1 ILIA, heatcd 25 lirb. at W-0)" gave ZO 0
191 g. (*,,11., -., in.,t. of Im-pylAvriectitupliatir and 111,
b-Sil-l' "j," 1.17%Q, !"N" lly. f
dmly,l, ;( I Ill F. Phl, %13111~11-11. Ali 0
1111pruve.1 vi, 1.1 -,( I , , .... I I.v the following ctindi.
Join,- Ihe mitt, tit f; v,,I,. Ar(III wai
25 tit.. zoo
f'o 0
A I a I L A MITALLUt-GICAL LITEIRATURE CLASSIFICATION
:mt 4- is,
U vs if 'a sit An 1 a nd 0 9 1 1 M 14 A] a T1 I
D 0 ON 61 111 It w if it ri it or Kit; n I x4 411 a
o of *4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 11111,411 0 4S 0 0 0 0 0 a 0 0 0 0 0 0 0
010000 0 0 J9 09 0 0 of to 00 0 0 * 0 0 it, -0.4-s"0 4-6. 0 0 * 0 0 of 0 0 0 ot a 0

I - -.' ~ ~~ ~.';

bV 0! -A N t~ W It
C,
00
00 90
00 00
66 -00
09 4 Ptlipyllworisylene. A 1. Slmviv,m /4-
00 A 4- t I Cwn. Cliem I IS, I A~ III vi). . 1 4' 1 41,
. . ......... I. I I
;:
00
00 -
1-rneul (1) lc4d., to 4-
go stab%tilutc,l i-IIIoriaeoli. in contra%t to i-Ilmou-1. K.vr. ,it
%at'lliate delmiration. tit, ... I; I
00 i3111A and 3.3g. Na inheit xvienex,ive [lie N-I.-tiv. in 35

** eat"I .1111 C.'~' let I .I.[ Own '.
"'
'

I 'i
MvI. Ind it],- eu- M, I at"I k"
410 [1,,- .,1.
100
,
vr,it removed With -teant, yarldcd a voillut'. v,Ier'
tit
a
lica( ml to for the dmonilm k,t.! the tv-

l
ng I ..L.% Collecti,if it 220 '22% -th III., 0
06 N..Oll. tcaut.itstd.. and punfiv,,l by Iwat ... g itli N,,; -96
purI, 11 (120 1., -ji-). [s_ 12'.
4.03, 1, iii-I. its Ifs'
o' *1.1. 1-1:4), L.11., I-, -I hit -00
Outlatims -ith L"'; alk. KNIS.O. g.,%I- 04111
"..
nalihoric acid. in. Ileming ) it 11 %%3th 341 g.
,
A Ili and O.h g -50' 3.11 111, M 1141 g..V. 11MIll .00

00

A I

00 0
't 49
is a 4Y
It

0 0

I, amphrne rrarta.X~m-ls And th~ -PtICAI conse
q. 7n 6 It 'ha It gt~ f ptI C.1 ac vitv:". transformation
4 Nh- I%
4.1
% ...
I 4J, 1 1,
M
I
. ............ I.. .....
- I NIO I
I A
.12 3
1..l "01
fIrr ~,,Ih Vtt )If I h,
-wIv 5 1-.; At" -1111-r .1 .4 V,- III, V., -I h,- .
t, -A C 1 30.
.......... ...
M It --i .11'.1 1-- Id.

Moornem and 41-inellIvImobornew i;uj
,III drhytitatio,% by the xanthate method k I Sh i%Tvitti:
M. I - hmd"."
I 4i 61 A 1 1 14
re'ttli, J" ""t .'KI, r " 111 11"
op-
Ow ~1 ....... I"', '.f
1h., th, -Ula -nu,- tht,
4 th, rrl.o I -.t
.oh ic 1, I-mr, I-, I. V - 4 V!,
I, 't 0 "."AIV -I.- I he %'.I
L ,I 1,- 1, 1 t 1" 1 .4 , 1"
I it,, ,
.rh A.... 1, vwj~!knv'
d' P46 %1'h
It )1 1:1 Sv ... 1j, I, .,, u-, ph N., ih.l
1-tilvilwillial 0 jc'- I'd 1'24'ph'"V. r.j -Ik" ~"
dow.1hide, 11'- 116 1-.' lxf(ing M, I
'xithair 41and -, ", 10" P 'it M-Nil, g.11~
nAw" Id, . III I-'I -"'. R4 4'. WI. J~-(f
V, %,H-% -imilark
Or

1, 61 ki to *r
so vt I JUAF 1-1 0.4 11 110
AA It k 4
06
4.Ad Go camplox al MUG 91 tho premanyth rom$oft
ShavriSin. I-rumi. Pokaw)k,"
so A; in m4canctairitv _'O
Go appeon to tw cannrctrd with Ineror it, Agtlwlrl*d %1C.
B. C. A.
zoo
00
00
0
reo
400
so
As
00
.so
Ops, !
I
00 1 ACTALLVRGKAL LITERATIAL CLAIPPICOM" too
A. A
00 8 - - ___ ___ __ - __ - , -
J.4 ow
It __1r-aI An 0
-1 6 0 1 dj
u it 4. n r If I x4
it 51 It .1 44 0 00 0 0 0 so 0
o to
0 0'o 'a o 0
0 0.0 0 0 C 0 *

I o p r
00
of A -.00
001 IWOR"10I. AND ALMADATIO)l OY QUY IVOMT AOILU,
F.-~~.-Shavrlgin (Tra~m. Dokuohaiev Boil. Instep
24 1934, 10, No. 3# 47-80)*--Uveral stages or podsolivation
4 of Wiese soils Iman be distinguished. Degraded soils
1:i under steppe vvgetation or by cultivation aac%=ulato .00
org. mattor and Inoresso their exchange oapsolty and 41*0
Ozahantooble-bass sea W to Al, )4# .00
see
few see
00 a me-
see,
Ale*
see
goo
ti! moo
left
A 1 0 - I L A M4TALLUftKAL LSTIRATURE CLAWKATWO we
lie
-4 %glow "L9 ONT 404 al"n(PIC 43LIJI all Clav III J Edb~
U S AT 00 LS ' ' r I 1 1 4 1 ; FA & S a Ile a is 6 .1 W 0 9 a 3 4
a a a I, a I a 0 41 Me
0 0 0 0 9 9 0 SO 0 0 0 0 0 0 0 41 0 0 0 goo 0 0
q40, 0 0 0 0 0 0 a 9 0 0 010 000000 a : : : :-: : 0 0 * 0

OEM===
f, -1-11 1Lj I , 'I $j It 15 It it 11 It M i 11 H n M is :4 v A '-P s, it 1; 11 J, JS it 17 s 0 x U 1 0 JC
I A-M, V A 3 IS CC CV Et4t I -t f A 4 1 k
-.t Sit 1 ..L; #.~PW I
A
so Or The Arsocal Proportion oil chostinat soils "w glapir refs. W&W-lifUng vwpowity was deld. 1)y noting ifir time r -109
am to tM excliandissials, haws. 1-, 1. shvrumpn. quired to rut, tbrotigh 0.5 citi. of sud with the following
00 v;- lfkiwAkirv W Wftjqivj in jAj G,&,jis goof Goood stailts; It 4 It", NH. W day,t, K 9 days, Ma 0 his., 44 -00
PAY
SPOIS 1943, 213 -23(in Kagiiih).-Satuples of the 1) a) min.. Mn 4 hr,.. 43 min.. C& 3 hrs.. 30 join., Be 2 bn.. 3
ith
90 t-m- foyer 'd A chestnut SOil "Junal frurn dw Tranovolms, min., and Fe I hr.. A) min.. Li row 2.5 on. in 3 months.
rrSiOn wrrv washed with normal "as. of UCI. 14a6l. No 3 cm. in 3 months. The dispersion of thfte tolls said.
06 Nil-Cl. KCI, MgCl,. MuCls. CaCh. B&C6 or FCI, or with iwiow catkxLs on" d0d. by shaking 3 X. sod with 00
of IMM N [ICI an. until ttSL4 show-rd no CIA ptrimt. watec. alkneing to -ettle for 24 hr*. and dttg. the voilv?n-
00 rhr exer" of electrolyte "us removed by dialyts, the sod ient of a layer 8.3 cm. deep. The pcocentse. di*PCWMM 600
so 11 i munPkm .10 Ptepil. were Allowed to air-dry, ground and varied with the cation sattf. the sod as follows; H 4).Z10, =90
Passed thr""ll a 0--'i-mut . Kiven- The--v air-dry samples - Li 1041). No 73W. MI. L~W). K 1=. Ma %An
thus "'Id. With VIOU'hitis ciltiowcoutained the pertcutage of 11.41 . Ca 0.2k). Ba 0.21 M), Al 1). 114 and Fe 0. I:A T1W 0
6 j hyglutin'sc .6tet ilidicoted After the 'ALion: if %Wcifi,, weight of the cloy particle tki;rraors on taking =00
Lt 4 76, No 4.4s, Nil, 4.10. X 4.60, Mg 5.14J. %In tin a bytirstioti fitnt while the surfam in coatart with the
ze 0
Ca 5.05o Bit 4.93, Al d-W. and Fc t;.'*J. flygruacopic dmprrwd phww increases. Iloth then factors slow up
00 water was detti. in the sampIrs by the Wthin., method the sedimentation which e%plains salty the ascov bydrated
with rcaults an folk)ws: If 0.71. U 12-91, No 12.27,NH. alk. caitiotis product a higher degree of dispirsion. Ali
8.32, K 8.56, AIS 10-00, Mn W.M. CA VAQ, Ba 8.49, Al samples were adjumed to the lower Atterberg limit of 1!;,! CIO 0
A.47 " Fe 8.52. 'nit m&%. MIA. water capacity was flowing and stickineas was tsid. with a vAitably adopted
:0 K cktd.by the Prmurr inethad of LebLN]cv (a pretsure up to SLhopper'sbalancc. ALk.catiou~prodLoLvtbeaus.sticW-
04 6-5 its. Per &q. "n. was applied for 5 min.). The total ness. Plasticity was dctd. by the Atterberg asetbod (cf.
ISO water capacity wea ik-td. by pouring 250 cc. of wour oil C. A. 10. 79). The nests of wetting of theme sanaphs
26 E. tif still and measiLring the filtrate with the following expressed in unall calories per g. of sad we givest. The
to to a*
00 results in percentAge: H 62. U IM No 103. NH. 18. changes in pbys. properties ad soils due
o~ K 73. MS tW, %in o5. CAL 6 2, Ba 59. jj W and Fe 53. M& Are anoijogims to those brought about by 'is bui thew
value is much 'malkir. Medium clay particles in OL water t:*O
00 &1 L A VETALItvWAL LITEPAILRE ~LASIIFKATICN r :too
r I An L I U -1 4 1 W 4. a
tv 1, 1, or it -T a K it it if eq n
0 0 0 41 0 0 0 o 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 IS 0 0 6 0 0 IS ore 0 e

I Iasi to 'KIII)IJunI4 1y ts to m 21 a n 1, is a all U13 JdAlfunio a 61 u a) 44 a
A I A L V-R-IL I I -" -0 . -0
t, 4.v TD
AW P1CV9Pf'1$ -Dl.
The ja6wate of A voc"mium ft ow p a
propeed" of the MO. P. L TTT~. paidirgy7M S.
00 6rd-11-b- am,*.
",,,ejg Olud chemmem wem utd, whh Ca. &4 mW Na
and subimted to, a writs Of tests. The Xf5 WU 41d Out
j filter as Well as (be Ca Wil. its Witubm, vw-
Ic"icity and tuoisture capadty were
and lower than the Na "L
00
see
00
-06
roe
o0v
06 00
4r
0 ~Oggr
:zoo
00
'00
we
00
Aj-jLA fTALL4R4KAL LITE..T~.f CLIMPICATtOk
00si Ir z- 7;-..
woo
lie tl~ It.
An 1 a a I If V I in a 2 9
U
Ds u tp lo At or It R it Ff a it It of
:N000699990000060 0000000000000 0 0 * 0
TOOO 00 *Otso 1*91' 1 001~ 7002
000*600000*00000 0*0000*000*0000000

t- -s- -;-- g- :t- -R~ -e- _- _& _- _-
0 0 * 0 as 0 0 4 0 # 0 . .
1 of to u u III is v Is a .if ...A -Iw - I M
A I I it fly I I I M-A-M-M
4 ST A" Lwq~
so
400 Ct
s- 4- -t _- -s- _- -I-- _- 4 _AA- _t -k _~~ t- &
a 0 0 0 0 0 a 0 0 0 0
je it no
a a The pbyviW pope ,of mail and th ir relation to the
COMPankloat ad ndm"r*
-99
Trani. PANCIMn Sad /sit. i, R.) 13, 51
99 (in broenowut~h"rwnom
MA14 were wild. with Not. Nil., X, UK. CA. 112. Al
anit Fe hy treating them with the chkorides of the -P.
or Fr H ..-in. 0.025 N HCI was used. The
fAlowing phys. por-verti- - tested thc_~ wnl%:
hcat of wettbl& jLm. ad. miti-,ture-holding capacity.
total m4oure4a" capacity. hylp filtralum
~pacitr. capiusly - of water. plotaicity, coh"imi.
~tickhievt VA. wt. and proity and diq~ion.
mak" a %prcial point abotit the effect of MS in the com-
00 pks qhowing that As far as the soolonetzic properties of
WT roncerrocif the US is not of much signifi-
chernment
00 rance. The destructittoa of mg. matter in chernozOn by
HA is conlucive to the appearance of volonetzic proper-
Joffe
tk~- J.S

ASII:sta AWTALLUWGXAL LITEIIATIONE CLAISOKATICIIII
slow
T_
U IS AV 10 BI;
0 It 0 a 9 a is I
0 0 0
0 0 0 a 4
-low 100"ItIv
j;;MI $aim a 0 a I r a to A 0 2 a V
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 * 0 0 9 0 0 0 0 0
-00
_*O
.00
ISO*
note
P wee

-1 -ii .-A -L LL. a11 r tip 1 1 Q Y 1 -1 1 L AA N (L U 1 4.
of
so 17110 dY11AIIIIC4 Of alkalinity in golf SolUtfl Upon UrIM~
Eloa ~. A. K-da. 1, &,,,1 1,. A.
00 R.) 1044. N.A-3. 6&-;1 It.
4; Sukxwhakt~ullateau(icitkridevigmey
00 h~
trylgaltim becont" mort: aik. mH through the
00 9 I'lir I'iXbcst int rct~ all Pli It"- Place its the surface b6n-
ZINI. These increases in m.1ky. are dvlcteriim~ to cotton.
By 111creasing the quanitity of urrigmt~mi wAter it is pus.
.04'. 1., --w-mir thc A twoct- nwthoIl .4
oto -It, I.- I.* or 1.1" 111, 11$
00
00
o0" 00
go,'.
goo,
00, -;0*
00 !goo
as
00
Z-A] 111110,
eel
eel
Go
002 z
boo
00 A 1. -L a atTALLuRGICAL LITIERATUME CLASSIFICATICA
,11131 C.C C- L%'
S.)Gmj
T-'-. V-T~ 0 3- An i A I w 14 0 il 0 3 6 0
IS -A,-0 1%.; K a N Cr K Ct tr it Or n 714 0
:14 : : : : :1i : : : : : : : : : : : Z : -0 0-0 00 0000 0 0 foo

USSR/Soil Studies - Black FArth Mar 1947
"Relation Betvoon Soil Solutions and Aqueous Extracts
In Salinized Soils," P I Shavryugin, 5 pp,
"Pochvovadenie" No 3
The authow studied aqueous extracts and soil solutions
pressed out fran slightly and strongly salinized
meadav soils and from moderately and strongly salin-
ized chernozems of the Golodnaya Steppe by the press
constructed by P A Kryukov.
2T75

0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 9
0
41
0
0 6 0 a 6 0
0,14 0 1 ~ . - , 0
0 0 o 0 o 0 0 0 6
. ; I , ., I " .. V 4, 1
't R; to

.1 A,,

00

-g
-60

72 1, 111,
-CI
11A. 11t'. 111)(11. ~f
00

I L
so
0
ao 0

too
60
00 0

0 41

Oxidation-reduction conditioris of salonchak meadow
sods a# the Forgets Valley. 1. 1'. Serdoliol'.kil And 1'. 1 - -
.Sitavrygin. Tady Pochrexxoto less. im. V. V~---Zyokv~
, Ajm;'A Ndd. Nawk S.S.S. R. 3 1, 9!-M 1950). -Two areas,
one slightly salinized and the other a strongly saliuized "I.
were invntigated for the Ex values. Eleven measurements
.cre made in the field. before and after irritriting, between
]une 17 and September 6. Each test covered 9 laym in the
ivrofile, down to a depth of 130 cm. In all.:I(N) Em. lill. 4nd
11.0 detris. weft inade. With the natural ruiti(All the itiv.
value throughout the summer varied from 4d0 for the inure
~Iinc sod mind 4M) for the less saline and. Twenty-four ties.
after irrigation the mv. value dropped from 460 to 3(X) and
;,. low as 2W. After 13-IS days the value went back to
the original. With the lowering of the mv. value the NO.
o-ittent dropped. The iwpleths of Mn and Fe showed a
buite increase of thew elements after irrigation, inure than
lix)o timesof Feand tensolf thoussaidsof 26fa. Since in the
dry state the Fe and Nfn were extremely low the increase was
not so significant. In the layer near the water table the
ctnecti. of sot. 261n may reach 8-10 mcA.. and of FeO.001-0.01
C /I. J. S. Joffe

The significance of the ash composition of several wild
growing plant species in the process of sod formation at
Baratta, It W C-lilti-11 11-111 V L -Still-VOll- I'M h -
,.~ des it I US 1. 7 11 'Ai. - Wat, r ext 4 of mr.,dot, . lwrim,-,
-I ...... tile Illeadow itil"ll, hAtc. ... I, -loutOwk.
.-, I 11I If,, I I-. J.k M)101 I vt2-ikd1iI.. ILIL It I I I .,'it- t 1,., 11 ,-.1 I,q
k I -'. I ICI I" Cl. it).. k'.. %1,I. K . N... "it I., ..."i ~O 1,
~'ljltllm im'llvsca wvtv lilalfe -% (fit- X111111t.1 it.11, I . ..I I It.
I I p- I " I- -lk ""'I III 111, 1, il. I .-I I . -.1 -h ..I 11" I.M.-
mv. tAtuf ..Ilrr tam. , . Ig-jr, v""' I.- -
(;JI'Stella PuRcitit's, EIP-1
Nalut Xmithilt, artif Alr.,pij disAifij. File ivatut-d
_it% I)( tile '11.4111s exceeti the qualititV of S'Alts III tile Still
:,arcr l; hilv"Cracc., of %.I I, erv I"u"d ... 11 ... .... f" , I
'r ,I. edi" " And Ag"IPY-4 fm- ml th'. I 1"i,
"r ........... .,If. File K "t"I :..' "I Ow
'-, A, 11.0-1. Tile higher tile At LI'Mullt ,I tile ".11
Ill. hixher the Mr. Na, and CI content of [lie plxjI5 at ths
I il,eue of C;t. K, 11, and S. The t,It.,l %At uttistrOmitol i-~
;lie I'll 13w, file biol. cycle 11.14 I'v'll cAculAttl to be 11
it 1121 1 is It.,. 1. S. J"IT"
is-

- 77
(/The salt regime offr.
ton at varying dialance from dra;ns. P. 1. Sha
Tr,,,,d xetaviga last, int. If. Irr.
~61 Va ,v Pock
S'S.S.R. 44, 3278-47(1954)~The salt content of ir-
rigatet! snJine soils was studicd at vuri,)us distances frvo the
colicctor-drainage !4eves and vvit's va:icus gputing of the
drains. Collectors of 2.0 and 1.2 m. depths vrereeffecdve at
up to 150 and 70 m., -esp., in reducing salinization atul c=s-
Ing lmpruvcd rate and quality of cotton XTowth in c(!njunc-'
tion with a lower tround-mater level. In the central part
of the alluvid fan, drafTL4 (1.5 rn. deep) had to be less
than M") m. apirt to give uniform desa!inizatiori, The
satIni" meadow solonchaks contained chlorides (approx.
V'total salts)
0.7-42.07 and sWIntes. (approx. 40-96% of
a, nuLinly of Na. or sometime5m salt.$ of Cc. or Mg.
The ground waters contained chlorides and aullatts of Na
andUlli SoOsaitcauttnt was studied byean. with water
orb -Uscola, draullepresg. CIdorlde and sultatticoncrts.
for YO plots athdlpths up to 100 em. were tabulated Jn detail.,
A jalt content of MA tons/ha. vins recorded for a meadow
soliAchak 190 w. front the collector. When dis4ance be-
tv.,wn drains was Increased from 120 to 160 m. In the same
area: the no~ of plants decreawd from 1065 to IM.), the av..
wi. from 7.2 to 6.8 g~/boll, and the av. yield from 64t tot
A. Vt.

ZKNIN,G.V.; ALMANDROVA,V.D.; KRAVTSOVA,V-I.; SHAVRYGIN,P.I.
Division into natural regions of the new reclaimea farm lands in
the Altai Territory. Izv.AN SSSR. Ser.geog. no.2:69-72 Mr-Ap 155.
(Altai Territoz7--Pbysical geography) (MLRA 8:6)

/j, T- [Y
U.9SR/Soil Science Physical and Chemical Properties of Soils. J-3
Abs Jour : Ref Zhur - Biol., No 3, 1958, 10512
Author : Kovda, V.A., Letunov, P.A., Budakova, A.A., Zemskiy, P.M.,
Shavrygin, P.I., Kuznetsova, T.V.
Inst
Title Elements of the MoistiLre Regime of the Takyry
Orig Pub Takyry Zap. Turlmenii i puti ikh s.-kh. osvoyeniya,
f.k)skva, Almd Nauk S11SR, 1956, 513-521.
Abstract In the takyry moisture travels exclusively in capillarily
susi)ended solutions. Ground waters ordinarily have no ef-
fect on the water re6ime of the takyry. One characteris-
tic of the water regime of the takyry, and of the takyr
soils, is the extreme dessication of their upper horizons,
up to hygroscopic moisture, /?/, in the summer period.
The drying up of 'the crust horizon of the takyry can occur
also during the winter (in the intervals between deposits
of precipitation); this is due to certain
Card 1/2
TJSSR/Soi! ScIeLce - Physical and (7hemica-1-Proper -t-iesI-,f Soils. J--s
Abs Jour Ref 7hur - Biol., No 31, 1958, 10512
characteristics of the structure and mechanical composi-
tLon of this horizon-
Card 2/2

T 111% C! 1 a la i t ir C Sc
1. j
~s jour: Eef aiur-Dicl., !',o 6~ 1955,
irrigaticn. nciT.-.s: 7COO-10,CCO T-..3 yer 1 ha. in
'utilizing the sait flats for cottm-plants and 50CO-60CO
,_3 - fc)r cereal:,. Sanding, at the rate of 500-60C1 t.
An.. ir..prr-ves the aqui-physical properties cf the
scils, averts crust-formt-im and ccnsidera'Lle incren-
ses the yield Gf the plants. Tle effectiveness of
timely applicatim ~~f nitroGen-ph'-sphorus fert~li-
zers auGr.,.ents the yield zf winter wheat 15-321p. Dy
cultivation of peremiial Frasses, rarticularly cf
the leb-umincus grass fai-.Aly rixtures, an errichi.-.ent
of :3--i-1:3 with cumnti-~ies cf crF
~aniz sub-
stances owin-E: to rj~ct residues (tc 87 C./ha. in a
!aYer c.-L one :~:etuer)., salt~nt-ss, imprc~venent of struc-
-ure Lakes place. T1,;:! yield of hay of lucerne-rye
s,3 r:ixture in 'Iia _~~,,d year -f cultivatic)n ~,f "alt
2/ 3
69

USSR/Soil Science. Tillage. Land Reclaration. Erosion. J-5
Abs Juur: Ref Zhur-Diol., No 6, -1958, 24831.
f,uthc,r Kizilc,va, A.A.;
Inst
Title influence of Various Phtes of Irrigation on the
Saltiness of Solochak Salt Flats.
OriE Pub: V. sb.: Takyry Zap. Turkmenii i puti ikh s.-kh.
osvoyeniya. M., AN SSRI. 1956, 648-662.
Abstract: The Greatest freshening of a thickness of soil of
the solonchak salt flats (foothill desert of Kopet-
rag, is achieved by an irrigation rate of lo ,oco m.3/
/ha.(the experiments were conducted on fields of
12 E,..2 in conditions of irrigation with the applica-
tion of plantation ploughing an 45 =.; crop - winter
wheat). A thickness of 1 m. was.-liberated fror.
Card 1/2
70

SUVRYGIN, P.I.
Formation of the chemical composition of soil solutions under
the influence of ground waters. Fochvovedenie no.12:98-101
D 16o. (MIRA 14:1)
1. Fochvennyy institut imeni V.V. Dokuchayeva Akademii nauk SSSR.
(Minerals in soil) (Water, Underground) - 4'r~

S.HAV.,-tYu-!lN, F.I.
Toxicity of various concentratims of soil solution for cotton.
Pochvovedenie no.11:44-50 N '61. (MIRA 14:12)
1. PochvennfY institut imeni V.V.L)okuchayeva.
(Saline and alkali soils) (jotton)

SHAVRYGIN, P.I.
Toxicity of various concentrations of soil solution.in the
Baraba Lowland. Pochvovedenie no.D85-91 Ja 163. (MIRA 16s2)
1. Pochvennyy institut imeni V.V.Dokuchayeva.
(Baraba steppe-Soils-Analysis)
(Plants, Effect of salts)

~HAVRYGIN, P.I.
Tolerance of cotton to various compositions of salts
in soils. Pochvovedenie no.10:15-20 0 165.
(MIRA 18:11)
1. Fochvennyy institut imeni Dokuchayeva.

NAZAROV, I.P.; PROSTAKOV, N.S.; MIKHEYEVA, N.N.; SHAVRYGIWL, O.A.
Hnterocyclic compounds. Report No.40: Sy-nthetic anesthetics. Part 5:
Asters of 1,2.5-trimethyl-4-phenyl-i~-piperidol with aromatic acids.
Zhur. ob. khim. 26 no.10:2812-2820 0 156. OGRA. 11:3)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni M.V.
Lnraonosova.
(Eaters) (Piparidine)

NAZAROV, I.N,~';FROSTjjKOV, N.S.; MIKHEYEVA, N.N.; SHAVRYGINA. 0.A.
Heterocyclic conq-,ounds. Report No.-'l: Synthetic anesthetics. I'bLrt 5:
Naters of 1.2,5-trimethyl-4-aryl-11--pi-peridole. Zhur. ob. ~diim. 26
no.10:2R2O-2834 0 156. (MIRA 11--3)
1. Hoskovskiy institut tonkoy khimichoskoy tekhnologii imeni M.V.
Lorionosova.
(Eaters) (piparidine)

AUTHORS. 1. :1. Me-- , .1 2- fi~
USSR, C..." 0. P. 3~ 11. ,T. B. , Na=sxCV!,.

TITLI. The Conda-ation of Lostylon, lith an-- :to
A"I ogues (Kond*naat.z:& atnetil-a a motilgeptanonja - ,go
.logaml) The Synthesis of Linalool and Its Analogues ~Sthtas,
I y-g- ...logo,)
FZRIODICAL, Daklady Ak.d..11 Sauk SSSR, 1957. Y-1. 114. X~ 4. ;;- 7~--793
(USSR)
A3STRACT , Several yosx. ago & staple method of synthesis 0.1
1oOhols - oriced out in the laboratory of the
-
n
*
&
tyl
a. hor.she of condensation of aldehYdes and k,zcnas
Z
,
.
:
y
,Olllh
influenco of powd.rl C&umtlc
dor tho
.
high Pr -ur. (5-1- .% ..per of
)

*
0pIcy this main. in ,ca. of ..air... ..-h ..t.-.y,-
!h
d

the ..r-
... , to _d_ -I-
1r II. blaz
h: tan as and i.
1..~
:
;
'. a to
10.1 and .... snal.
*hl.. Lin
1 bydrogenation with . Pd-oxtsi;
ob ad ... Illy by,-,,

'
'
t
*
Ili rt- such -. an as have usually been c
:
1,
Co,d 1/4 .Id
ammo--
~
the Influence ortt: f I
q
"
at
Kah and &..Ill.
say ba 411densed very easily with Gau.ti ;
-om~o.
aeatiOnod
At
o
%h.y give as
pr
2~:C
a' In &101:
*::
:
.
,
,.
;
.
,
,
..
,.b
Orr P. adLag % rt ary, " ty a Ihole with -
SIA021 qulatitItly. yield (more than 94). This rotation me,
,or. ,o
how
els0be carried out without acetylene pressur
e
,It b .b
:
,,,
list or. .1-11 slid with . yield of Only 6.-
...
r-lou,ly how,, iIbe same laboratory that
;
b.I. which :.at &Ia....substituted ac.tylon.hydrogen a^, be
.I
pro aof .,or
bydrat.d
hl hlX
.ti 1j 10 th
,:

d
o
;
d
Oat
allaitse srhane . oo;;.r a I'ov
h:b
rl l.
d ;,;
rlalooholm with an almost theoretical y Ibtined.
,11:
ot ber-
t".11
-':'
':'
re us Is.
tI
dtb ri
I
r ",1y
:;aI!ro-
L, pit tur.
Ind. 0.9ur. 11. 1 Icahn
0
r4
!
!
, 'he bo,.-d ... rib.d aco-
I.
104 A
"0
4 with th
hydrog..
o
by oondeAsation of acet,-
Visa* Moh.la which are obtaitind
A%b sathy1hopi -one amd its analcgues ,Thwll Losty'11
1
170
:
21 . may also be highly splectively hyd tad i.tas pr-
sic a to
Card 2A son** of a Pd-cataIjst. They fom linalool and its analog-e
with almo.t
theor.tic.1 Yield. The purity contr II of the
.
Ly - (linalool and its analogues) was ca,~jod out
I`I:0h
;I
a
by 0 O
tbM a.. %.
"
! with -0 -ti. of
a

Ive
01 r .-Wt I..... do% r.
or copper xt who I-
:
iced
Iky special tests and -.uMt
d
%
O,2-0,3%. At the hydr.g...-
11 04 of Ili*-at, "'.I Ili'"""'a
:
.
:i
*
p
'
'
X*
h !
to.. test .say. dl--1;
.
I Ili. , h-
-
r;
t'--1 1-14
t:
ara on cal uIs is ong
014 on go str ljr -tt
oh-d. Th. anaty-
~yd
:0
..h.i
"I
a
b,., ad 1
:
the course Of this ork are oum~,-
:

ri.
d
A table
A
l. Liaalool and w
its _10 0. (I
r
obtained by 9 partial bidrog-Autio. of It. has -t
:
:
60.9711A with Fd-catqlywt ' I' in a,,,
L:I1ohoIa
.,-
:
the swb
end Yield. Of the sold
.bt- xo~ dlb-4 1.
detail. Thar. ox. 2 table. -M 5 reference., 3 of hl.b ax.
Soviet.
ASSOCIATIM Institute far Organic Chemistry i.o.j I.D. Z.Ij..kjy of the
AN
USSR sad XQ~0OW Institute for Refined Chemical Technology I.
"L
Cy. Laon.wa, (Inatitut rg-ihwkOY Iths.11 Im. N.D. Z.1j.:
C~4 3/4 koga kkd.eil a..k SSSR A VQ.k ... kiy inatitut tOnkoy khlaiaho;_
kay %.khul.gii Im. M.T.
SUDUITTID, marsh 12, 1957
-~41 1
' '7'

AUTHORS: lsa.ra,, 1. 1.. 1..d.ml.ian, liaki.. S. I.,
lochs,lin, T. B., fiasminva. D. I.,
Atmpt.0" 1. K., xm~& 1. 1. and
TITLE: ?he Synthesis of K*thylbeptenche and Mothylh.ptadionono
Analogue@ (3int*z "Alogov metila.ptenona I motildeptalty-ta)
MICYDICLL: Dckl.dy AN USSR, 1957, Val. 114, Ir 6, pp. 1242-1245 (USSR)
&S*MCT; This sy-vithool. 1. air Interest for the production of a
Ansibor of co"oOpon4ing analogves of nat-I tooprenold
."Pounds. The initial an.tylen-alcohols for this purpose
no" produced according to %he author., method (rsf.romce I%
by a selective hydrogenation 1. the pr ... a-- of p-ll-dt-
on O&2o1"-&rb.n&Z* ao.tyl... alcohols are almost
itatively converted %a analogous vinyl alcohols

ref!rence 2). These latter yield the corresponding
=
am"Oemoo of asthylh.pt.n... In three different my.
(reference 3). Method 4. Dy the i.flu.A.. or 9 ......
hydros.. chloride sr hydrogen bromide upon t.r%&-y vinyl
alcohol. at 0 - 2a C primary halo Id-dartwat two. of - .1171-
-typo easily fam (r*f.roaca 4). ?heir condensation with
card 1/3 with a o.bs.q ... t ..pazilfio.ti..

6n
v A.2or..s. method
:%'hyH;p~ ''
:
.
r
:
ry vinyl l:.h a1- directly -.t I% in
other. An almost thoar.ti.11 qu .4 %1 ty 0f
.th"
1
"
d
C02 I.
"W"od dthe sane, oiialogu . as . at b .1 4
:
t
.
.
t
A
)
to 1. in
the acll.a of dLk:t.a.
rs ry r jr:
p..
I. the presence of small amount* of triethylaa--
or p1porldIno. ace%onacette *%hero of these &lcohola are
obtaici.4 (table 2) Their pyrolysis also leads to %he above-
-nWOO110-nd vM-I-gU;. ("ftr.ac. 6). ?be
-h-p%O-o-6-on (IV) 400-6-7 far the sytba.i. of Ivan.
PrOdUQ*d all thrs# -&YG montlon*d. Dine thyll.opropquyl.
4mZbImO1 (LAW&I muh4toace) van produced by the influence
Of "tAWI-Iltblank upon A.11 mathjl-

&1
d ... 4 are .*.pria.d in table 1. Tz.
:'to an *An,
pr
:
,
r
,.
:
"$h ruir, bar 9 q 4: allyl- (1) (reference 9). rrotyl-
(I I) mad . crOar-tyl-ac.to.. (IIIJ 8), 4%..thyl-
.... tat., dL4.thy1h.pt.u.a. (IT).
QycIDbOXJTlido&P&0t&oan* (IX) and tertiary butylbaptast,cons
Th. production method. and oA.tmat. of the..
or,
?here ars, 2 table. and
given 12 reforonce.,
Card 2/3 6 Wit -a 1. ,;.
'
LSSWIA?1011~ I..tttut. cr C'__I~ Ch.-
.1"'.
AS US-0 and r1--11t1t- fer 1%~
1. L
him,.
SUBMITTID; March 12, 1957
Card 5/3
. lt-kay

SHAITRYGINA, 0. A. Gand Chem Sci -- (diss) "Synthesis of alcohols, ketones and
acids of the isoprenoid series on the basis of divinyl and chloroprene." mos,
1959. 14 pp (Min of Higher Education USSR. Mlos Inst of Fine Chem Technology
im M. V. Lamonosov), 150 copies (KL, 46-59, 135)
-11-

5 (3) SOV/79- -~9-3-4/61
;5
"XTHORS: I'lazarov, I. N. (Deceased.), idarkir, S. Mochalin, V. B.,
Shavry-ina , 0. A., Nazarcva, D. V., Kruptsov, B. K.
TITLE: Synthesis of Analogues of Geranyl Acetone and Pseudoianone
(Sintez an.-Ilogov geranilatsetona i psevdoinnona)
PERIODICAL: Zhurnal obshchey khimii, 1,959, 1%1 29, Nr 3s PI) 744-753 (USSR)
AB6TRACT: These analogues are initial products for the synthesis of
the corres i) onding analogues of the most important natural
isoprenoid compoupds, of vitamin -, carotene, farnesol, as
well as of phytol, a compcnenilk.- of vitamins K and E. Recently,
the authors reported on tAree syntheses of ketones cf the
isoprenoid type carried oui: by the-,-: 1~ 73y reaction of soe,.-,.zm
acetoacetic ester with halo6en der-f-TatiV-33 c-F the allyl type
(method A). 2) By reaction of vinyl- and ethyrtyl oarblnols
with acetoacetic ester (method B). Bi- pyrolysis of the
acetoacetates of vinyl- and ethynyl carbirols (meth-3d V;~.
This me'hod was used to obtain methyl hept-enone, methyl
heptadienone azii their analo,-ues ( Refs 1, 2). 3y cont-'ensation
of methyl heptenone and 7-tc analogues with accetylene under
pressure (5-10 atr%ospheres eycess 1iressur-2), dehydrolinalool
Card 1/3 and its analon-ues resulteq a'-,-.qost quant-i tat ively. These com-

3GV/79-2qj-_', -4/6 -1
Slinthesis of Analo;rue3 of ',eranyl A(,etone RmA P.-je-Hoionone
potinda viere transformed by partial hydrogenation o%rer a
I'd-catalyst into linalool anul J 't3 anzilo,,,vie3 (Ref 3). The
three methods 11sed for the synthesis of the ketones of the
isoprenoid type were also c-,:itloyed for the synthesIs of
various analogues of geranyi acetone (Scheme 1). The s,,r,-.
thesized analogues of geranyl acetone are shovin in -tab
The synthesis of the pseudoionone analogues was carried o-.-,'.
according to the methods B and V. In heating the analoj~u-3s
of dehydrolinalool with ace'loacetic ester the analogues of
pseudoio-none were formed (Table 3) (Scheme 2), In yields
of 50-70". The pyrolysis of acetoacetates of the dehydro-
linalool preponderantly leads to o--.e of the pseudoionone
isomers; the other is obtained b-ct in small quantities, which
is not the case with the pseudo-Joylone analogues (XVIII) and
(XX), where two stereoisomeric forms (Table 3) were separated
in form of their hydrazones. The compounds synthesizze,' are
characterized by absorption spectra in the liltraviolet range.
There are 3 tables and 7 references, 5 of which are Soviet.
ASSOCIATION: Yoskovskiy institu+ tonkoy khimicheskoy tekhnologi-i
(Nloscow In.?titute of Fine Chemical Technolr,,,-y)
Card 2/.,

SOV/79-29-3-4/61
S--nthesis of Analof U
_;ues of leranyl Acetone and Pseudoionone
SUBMIT'PED; January 2.7, 1958
Card 3/3

.!7- -0
-4 7
A, 3. :.!., 1.1ochalin, V. B. , 2
I !.. Decessei'
0. A. , Nazarova, 1D. V. , :.azprov, I.
TITLE: 3,yrith=sis of 4-ho Anzalogs of ',.erolidol, Farnezil !cetone !nd
Geran,,l Linaalonl (Sintez analogov nerolizola, 'L~,rnezilat.,~etona,
i geranillinr-looln.)
PERTMCAL: '-Murn'll obshchey khimii, 1959, Vol 29, Nr 4,
n ? (USSR)
-'BSTRI.CT: In the present paper the authors investigated thoroughly
the synthesi.,;'of isoprenoid alcohols and -ketones (of the
analogs of thri abo,:e-mentioned products) and of the inter-
mediate nroducts ace,-,rding to the given scheme. The
condensai,on of 'he nnalogs of geranyl acetone (a) with
acetylene was carried out in the steel reactor at 0-200 and
at 13-10 at,!:osoheres excef3,j nressure in the presence of
po,.,,,de-..,r ca-.7stic notas'-. The yield of tertiary acetylene
alcohols (b) was f~G-W; The condensations hitherto used
Re 1 1 ) are f",rlr no-inlicated. All analogs of dehydro-
5
in this investigntion are
presented in table 1. AccordiaC to previous experiments
Card 1/3 (Ref 7) it -.,ihs possible to carry out the hydrogenation of the
k - M

-Yn tho s i r; f th,? A n.- o I rn es,
r r~ t,) n -n r nn.1
an-
ri
or tn;~ r
(v" !"A'L.I.!d "),- pr-1-ti-I "Y ty! cm~
():Io 1:~ b ) -u i I 1~1 Liii s cn. tIr: i .10 nn 'h
~o i..;ie .--r_,ctirn V,. Uz I v_ t'; --ocr' ',-,r--d thf!
-~thor7, nblc to
O."t t':-.~ C n"-~ t i 00f
L C 1. V L I I -. 1 - 1;o 1 CO-ic os~-er n-t I ;C-1~0
'lls" -~.'Uhottt caL,:1,,,~,ts, fmd 3bt--j'jj,-j 4n Mli~,
i3er'~nyl :,c,~t,~,ne, and their annlors (9cf7, 2). In
the rjr,!.-cnt stuu~y they applied this mcthod to L:ic :~yntu'iesiz;
of the analogs of f-.rneFil acetone (C) . '.'.rhen hnatino tiic
nerclidol nnalo-s 4escribed above (Table 2) with -.cotoncetic
ester at 190-2001 the analogs of farnisil acetone (C) were
obtp.ined (liable 1). The analogs of farnesil !!cetone (g)
3ynt-hesized were then conlensed aith acetylene. Vie resultint-
tertiary acetyl~mc Picohols (d) were converted by partial
!-;6rogenation on the analo-s of -~r-nyl linalobl
j, into
(Tables 4 and 5). The compounds obtained conl~', be used in
Card 2/3 thr: synthesis ol;' the correspom1ing ~.nal_-.gs, the -ohytol., a

Syn'~i~esis of th--- f;n,-lcgs of ;'lerolidol, Farne-i.1 -10*11/7?-2(,- 1. ~)9/77
Acetone an(l ,,~ranyl Linnln5l
cow-.titlient of vit-,::ins K an,i L. There 5 t%bles and
~' 1'e.'L'OT-ences, ) of which nre Soviet.
ASSOCIATIC;*-., :'.losknvski,'r institut tonlroy khinicheskoy tekhnologii imeni
Lomonosova ('.Tosco,.,,, Institute of Fine Chemical T-ech-oloM.1
imen-i Loi-,.-onosov)
SUKHTTED: 'Tarch 2-5, 1958
Card V3

t.-;' .4
70-,j
7
AUTHORS: Na:-,avov, 1. N., Mlakln, S. M., S3',iavryL~iria,-----0.. A.,
Strili-nya,t-1v-, V. A.
TITLE: Synthesis OL ffip'hei- Fatty Acido and Fror.-.
PERIODICAL: Z;iurnall ob-,-iiche:i klilmlil, Vol 30, Nr 2, pp
'; 43 -1;
Ir (ussa)
ABSTRACT: T-ie hi-her unsatUrated acids were synthesized
using aectoacetic and nalonic esters. Diesters
(JIT., R - Clf'~h"-OC2If,), (rj), (XXII) and ()g,!X)
weve obtall,,ted uy sodium derivatives of
malonic or u-,etoacutic esters wit.~i the respective
bromides (see sciietneo I and 2 for designations
and for syntlietic voutess).
Ca-!,d 1,/7

sov,
Cal" 2/7
4 od
UH
011)
COCH
CH -CH
z
cooc H

C0014
0
51 '4M04
HCj

CH ]ECH

AN UA 1!44
Jl
CH
c
14:; F&
f

r Jr
CHISr
4a
-COCCZH,
CH
COCC285
I
(XV)
cooYs
-CDOCH,
GIM)

OH C 0 L'
IxxI (XV)
I cooc
CCOC
XG)
(XIQ 1)
MV)
CODC,HS
i
(xx cm,cocm,
CH-cm
-e~ H,;Pd /~'z
OH
(Xxv) (.V4) OH
CHZBr coac'",
CH
Cat I OC.H.
3/7 co z 5 Qn)

77 ~"_S
Schijtnt~. 2. Syntkhc-,~!:~ t-)!' rS-e-anyla--. tic acid and
~D~' lto
R R (oh, CORI
fir I"
C Z_
COOCZHS
R R
~ NOR UAW4 61~ EH'OH
6
I IV) (v)
K C C ~N S , C L Fe = oc'lls , CHI
The, dlestei,.-, wei-te converted b-, L;ucc('_L;2ive sapol-lificat'oll
aitd into (2, t~l-d,-rietliyl-2,6-decaO,'C-'.IL-
(t~evan,,71acijt'c) acid (IV, R-Cll,), 6-meth,
L~/7

L,
11
XX
-
-
LU

P
T

P

n

X -,20

(XXIV) 1-1 a

x I"

D 1) C;
I

t

A
,

Cound;
b I do -
i
PC).
13) (y,)

H i A( I

fix) It III, Lv.r,
~'7 .3,; 1.17:0

Alf
:
1,N,-,'
7.M. 7.72

,
27
".1.77
C If
7 'Q4,
7.7 1
7" S. 19. S.411
IA8-121093`11 7#; S 1 1 Ith '19
((I. I Fill
'

liz IAY1 '18.77 77.12 141.56
7h
N
. 79 Ill 7 1
ill
I:L't 1 1, 1 07,0! w
' 44, H,,I I-X,~, 7.86. 7.ij

1113--fil 12, 1AS711
1.11' 7.,M
111; 117 IN. S~ 6.90. 7.11 1

1- 1i 7,

0
S, n thes- is of Hi~~-'h-er Fat tL y A c ids and Alcohols 778'8
From Tertiary Vinylcarbinols 3 011/7 9 - 3 G- 2 - I
ASSOCIATION:
SUBMITTED:
obtained from the previously hydrorenated dlesters
(e.g., 6-methyl-10-decatioic acid (XVII), bp 128-12,:~0
(3 mm), n20 1.4548, d20 0.9209). There are 1 table;
D 4
and 9 references, 7 Soviet, 1 ilermai~ 1 U.K. The
U.K. reference lo: M. 0. Poro~er-, D. Cardwell,
J. Chem. Soc., 103, 1346 (1913).
Moscow Institute of Fine Chemical Technology (Moskovskly
institut ton1coy lkhimichskoy tel:iinologii)
February 4, 1959
Card 71T

SHAW,.YGL'lA,, O.A.; L,Ur-*.IN, 3JI.
Chemistry ol' unsaturated etiuws. Part 17: Synthesis of acetals
of aryl polyenp- a-ldehydes. Zhur.ob.khiia. 33 no~10:3176-3180
0 163. (MIRA 16:1-1)
1. Moskovskdy insUtut torikoy kiii-miche,3koy tekhnologii im. M.
V.Lomonosova.

AC(- W,: Ai-0 S01WCE. COD;-',: 111~'/0366/66/002/009/158c)/1589
ALITHOR: 0. A.; N~lz;irov;i, D. V.; Makin, S. M.
0 RG :'Moscow illstitute 0~1- Fine Chcmical Technology a.m. M. V. Lomonosov (','-',oskovs'eiy
institut Lonkoy 'r-1hir-,iichcskoy tekhnologii)
TITLE: Chemistry of unsaturated ethers. XXIV. Preparation ofvitamin A ethers
SOURCE: Zhurnal organicheskoy khimii, v. 2, no. 9, 1966, 1586-1589
TOPIC TAGS: vitamin ether
ABSTRACT: Ethyl ether of vitamin A (bp 144-147*C, -n20 1.5735)was
D
obtained by the following reactions:
Card
C113
Cl1'.Clf-C.CtI0C.11' (C1f,C0),KBr BrC1121-11=t -Cli(O'C21i3h C,H.ON4
- C'II'0H
C
113
H3C20CH2C11-C-CH(0C2l15)2 H+ H5C.0(:lJ2CH=C-CH0
ell,
(IV)

ACC-N~.-
011
I
H5C2QCll2L'II=L;-L.1I-L,=-CH
I
C 113
(Y)
CH, c 11,
Cll=cll-c-o JIc-=cU cll=cJ-c-c=-cH
oil
(VI) M (IV) (VI 1)
CH3
/\-C1l=Cl1-C-C=C-C1l-k-=k ll-LINWL21-15
Oil Oil
(Vill) LIAIH,
11, CH,
=L-H-LIJ2UC2ll5
Preparation of the starting compounds-Es--also described.
JWA-50; CBE No. 121
H 13 002/
Card 2/2 SUB CODE: 07/ SUBM DATE: 24jul65/.PRIG IREF; 002/ OT'.F-F-.

SHAVIRYUKOVY Ya.; KOILMEEYTSEV, L.
Pile foundations are improving. Na stroi. Ros. no.6:17--19 Je 161.
(MIRA 14:7)
1. Glavnyy inzhener tresta Stalingradstro- (for Shavryukov),
2. Nachallnik tsentraltnoy laboratorii tri,st Stal-ingradstroy (for
Kolomeytsev).
(Stalingrad-Piling (Civil enf-ineering))

"eA, 006*6 W mWe W Misaill
busov and T. 0. Shavalta. Vokkdy Allosd.
Namb S.S.S.R. U. 6I6;-17(1W7-Vrom divec.-c:onst.
messurrusents In dil. solos. in CJi. at 20 and 25'. with
the clectroak polarization taken equal to the m if. refrac-
two, the digmic mousents of the following tetraa'kyl esters
ni C(OH)t were detd. Me 0.83, Ht I. I. flu I M, heityl
(X).,,nyi 0.98,,nonyl 1. 17. decyl 1.00 1). Tht valtic fut
C eater Is C ~C tu lbAt of Htx-r I And I lartri : C.. 1. 11.
but at variauce with Fuchs (C.A. 14. UM). All
CxptI. values are close to an av. 1.1, and cu-~ixidcrbly
below the 1.70 D., culcd. by Zahn's formula LC.A. 26.
4219) unda list autimptloes of free rotation o' the OR
SlUU114. N. Thou

kWy Ah". NmA SJ.S.X. 4k 49).-M
Prowl MOSOMMAMIS W dw dbju, cam. in cjv~ Own. at
me With ip (dwWank + &I PAW"fia, - 'A
WN, tin d mewsm d !&Z at WOW& a in &td. -
me New lizi. lk 1.70. 1pr I.M. Ilia 1.616 CAIIA 1.041.
Cilia 1.64. CAS I.W. CO's 1.78. COHN 1-0- 1). POW
cam of TI(OH)4, the ---I. vshm an. Bu 1 68, CJI.
1.62, CvHu 1.60, CJia I-T. C0111, 1.68 D. in t.Dth cabc.,
the valm an chm to 1.70, coW. on do ans 01
. yusmiriesPy tdndmkW wound tin Orl Ta
atom. and sehisdarsd rowc,01, It 0--k Wo% ps. Tin*
as t costuasts with the big diff bL-wetu the
cxpU. and the cuW. rosmasts of estm at artb warbouic
%cId(A,andfi.,C.A.44.3M). (2)TbxcskncT'Ti(OJD,
wem wwly WnfbeAsid by exclemp with TI(O,3t)j. aud
had the foDowing cowts.: Do, bs.s 166'. djO 1.491, al,%
IAM; CJf,,, b. 201-4', 0.9573, 1.49W; ;:,H.. t,.
:M2-6*. O.SM. 1,4610; CJI.. bo 25"*, 0.933t.. 1.4810;
Cwlfts. bs-a O.Ml...1.4785. 1%; Thon

Mpols MOOMM of Irew own a Wbow nw~
It, A. Asbuisov and T. 0, Khavitlis. DdbWY A~". Naak
S.S.S.N. is, wu~ c'.
Thommm's cakw. (C.A. SS, W16) of dipok wament4K-
(or the 2 prosiblo configuradous al Me*CGo ssW the 3
culsewuntiono of 84COS, kadius to the r9miusion - i I fir
110111xvurrriwe of the "Oficurations
dons. of the d1pok twxnents w= matle, by dielec. c,mibl.
ro'c"Urcu"te in CJU volst.. low 3 cyclk caters close t ) the
abort improbable cowliguradous of Meer-O& and Ktj Co..
Hzpd. valucs are O.CO.O.M.ClIs 4AV, OXO.O.Cll-
I - I I - -
CHs.CH& 5.21, O.CO,O.CRMe.CIl~.CHv 5.11111 D. Thr
excem of then values over Mane caW. by Tboasso t for
the improbable configurations is due to ring ckware, and
did no 0 6 Debye, cbeeb with that
fcaind by kables-W.A. 32. 17W) for des ftole-mot 2vat
difference between dn*k alkyl and poiymethylens ax des.
Six-matobated rings have a dipole moment about 0.3 4).4
ter Than five-membured rings, owing to
00n. 0oufth,"oon-
=

CA
Dipole momerift of Cyclic motors of swurous S1.14, 11, -
A. Athustiv itud T. 6. *Vj~ba, VeAWy Ak,idf. Mia4i
A.A.S.M. 69. 41 he expil. value of th? tilIX)IC
tuotuctit of d;ethyl still'otylate, S(01(t)j, j, - 1.9 j D., is
fairly close to p - 1.73 calcd. with the ancle 0- 1-0 -
DO , the bond motnents S-0 - I and O-Ht - 1.12,
I On tbC aSSUfftPtiOU Or free fOtAtiOn Of (he 01": grOUPS
C
aniund S-0; it is intermediate between 0.90 a id 2.42,
CAVIL for the 2 extreme rigid structures. Fruri dielec.
101111. 10r4surruicrits its Coil. soln., 0.Cll'Xll'A3'.S:0 (1)
L. - -- J
lu" 3.65, t11) 0 - 3AU) D.
I
For- 1, micn. with the abovv angIc (ILV3') and I-Dnd mo- f
ulf"Is t i--o - 1. 0 -C I It - 1. 1,7) anti S--O -- 3.0 1)..
-I thr a-Utuption of a plane structure A the Ti is, xivrs
" - 3.411 ; this, plus tot Increinctit of 11.3 for rvir oval of 2
it atointi avA ritis closure (on the basi,%of the digerrocr o(_
A RtS and CH,.CHs.ClIs-CIla-S) gives p - 3 7d. close
it) the expi). 3.05. 'nie closeneza of the a of I GA 11 c%,n
iwaue either to nunpiatim stnatute or the ring it. u alone.
LW its twili 11 and 1. The value of 3.131) i* the we,.,n of 5.211 1
.nd 1.30, cakd. (or the 2 liomibic uouplww onfigura-
Iions. plus 0.3 for ring closure. 111. Thm-

i~r~ )ru; Comil Ounds
Nov/Dec 53
F 1-4
r! _j~y
'0 V Z re. n
P 76-
-,;islire,l rii- nom."'Its j fut'hyl, n-but-1, n-hexyl, n-octyl estern )f
-i c fl r: Li t
tl d Ospl. ori a (-:. d .~~wan h.-i av di:)olf- moment of thase esters dl.!"', 3 t le
tho av dioole vu)iaent )f acil esters. lhe dir'de moment of Lhe
PcS '->ond is nractically trie swme as ti.at of the P!&(.) '-toncl.
1)7T14

USSR/Chemistry - Silicon and Titanium 1 Aug 51
Compounds .
"Dipole Moments and Structure of Esters of
0~,L'thoaaflbonic, Orthosilicic, and Orthotitan-Ic
Acids," B. A. Arbuzov, Corr Mem, Acad Sci USSR,
T. G. Shavsha, Chem Inst imeni A. M. Butlerov,
Kazan, State U imeni V. I. Ullyanov-Lenin
"Dok Ak Nauk SSSR" Vol LXXIX, No 4, PP 599, 6oo
On the basis of data on dipole moments previously
published by them, the authors fIlKared out the
structure of the esters in question. The results
were in agreem n with parachor measurements
carried out earlier by B. A. Arbuzov and V., S.
Vinogradova.
26

S-11TIA, T.. U.
Chemical Abst.
Of 'a'=
Vol. 48 No. 8 .,d T. G'.Th Bull.
Apr. 259 1954 aead. In. .537, . M77-id.
Organic Chemistry translation). See C.A. 47, 104MC. If. L. 11.

AIMUZOV, B.A.; SHAVSHA, T.G.
Dipole moments of diesters of diethylamidophosphonoformic acid. Izvest.
Akad. Mauk S.S.S.R., Otdal. Khim, Nauk 152, 875-81. (KI-RA 5'11)
(CA 47 no.20:10458 153)
1. Kazan State Univ.

USSR/Chemistry - Organophosphorus 21 May 52
Compounds
"Dipole Moments of Some Complex Compounds of Com-
plete Phosphorous Acid Esters,"' B. A. Arbuzov,
Corr Mem, Acad Sci USSR, T. G. Shavsha, Sci Res
Chem Inst, imeni A. M. Butlerov and Kazan I State U
i,.reeni, V. 1. Lenin
"Dok Ak Nauk SSSR" Vol LXXXIV., No 3, pp 507, 508
K. A. Jensen successfully utilized the method of
measuring dipole moments to det the configuration
of the complex compds resulting from the interac-
tion of trialkylphosphJnes with platinous halides.
225T2
It was shown that compds which had been considered
cis-isomers were actually trans-isomers, and con-
versely compds thought to be trans-isomers were
cis-isomers. .5rbuzov and Shavsha measured the
c13'.Pole moment- oil complex compds resulting from
the reaction of complete phosphorous acid esters
with different metal salts. According to A. Ye.
rbu,-.ov and V. M. Zoroastrova, compds like
C`~'-"(O_',~)3 have a triple mol. Similarly, as with
the complex comT)ds constructed with tertiary
Phosphines and arsines, F. Mann, D. Purdie and
A. '4e~1:1 add a quadruple mol. (Exptl data lie be-
tween a triple and quadruple mol.)
225T2