SCIENTIFIC ABSTRACT SHATENSHTEYN, A.I. - SHATENSHTEYN, A.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548710015-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SHATH~-.SHTFTN, A. T.: TZF,,'..T Z'V-,Ch, Ye. A.
L
"The Fhysico-Che::-ical Froperties of Solutions in Liquefied Gases--25. l-'ethods of
Spectrophotometry of Solui-fons in Liquefied Cases," .Zhr. Fiz. Fhim, 13, l7c. !,:,, 10,39.
Fhysico-C!:emical in.9t. ir,eni Karpov, Lah. of Liquefied Gases. Received Ju2y ](/-39.
R-efort .3 Jan. 195'

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!Z?ATLEVICH, Y~`.A.: SHATENSHTEYN, A.!.
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Lab of Non-Aqueous Solutions, Fhysico-Chermical Institute ir-eni LI. Ya. lwar~ov (10,42)
"Physico-Chemical Inve St4 gations of Solutions in the Liquefaction of Oases-29.
Catalytic rIctivity of !:itro-Indicators in Liquid Am~,onia; Salt Effect During
An-.onolysis of Filocarpine.11 Zhur. Fiz. Khim. Vol 17, No. 1, 1943
BR-192059019

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Absoldon 1111sectrill of 110111410118 Of aromatic nitro V.
dg in advents having labile hydrogen alms, A*
Crtenshteln and Ya. M. VArshAvskil (Kupov Ins[.
'
R
hetij. (U.S.S.
J. Phyj. (
-11hys.-Chein., hfowow).
60 21, 529-~)P(H48); cf. pim4lioig abor. The hyliothrois
-Ailus
in Nil
ml
n of nitro-coni
hi
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e co
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attr
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etc.. tocomplesslortnation between acidic uilutesand basic
&0 solvents is confirmed by detS. the ilirctra its other solvroits
hAving labile If atoins. This hypothesis accounts for the

The
color reaction of janowsky (Her. 24, 971(1M1)).
spectra (if nitrated phenols in alk. acetone arc very similar
to thow its 0AXM N NaOlf, but the max. are shifted to-
ward the red for 2.3-dinitroplienol (IM anti 47 suit for the
P
two bund,) > m-nitraphenol > 3.5- > 2.0- > p - > 2,4- >
ectrA bt-
The s
id > o-nitro
henol (16 To
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) zoo
,
a
c ac
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p
p
p
4ween 450,14nd 6W mIt of a dinitroxylene (m p. go"), m-
:=O
clinitrobenzene, 2,4-dinitrotoluene. and 2,4-dinitrounistsic
in liquid Nits and In UA015 Y XaOff in acetone are Aimi-
lAr. The absorption max. of the fresh solns- are at 635 (in
SH I) anti &52 (in acetone), M5 and W. 5M anti 578.
i
f th
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on o
e max. var
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but the intensity of coloration decreases 4trongly with

oo
time (lirs.). J. J. Bikerman

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USSR/Chemistry - Phenols, Nitro Derivatives APr 1948
Chemistry - Ammonium
VAbsorpticn Spectra and Electrical Conduell-ivity of
Solutions of Nitro- and Polynitrophenols in Liquid
Amonium," N.M. Dykhno, A.I. Shatenshteyn, Pays Chem
Inat imeni L.Ya. Eqxpov, Moscaw, 121 pp
"Zhur Fix Khim" Vol XXII, No 4
Study of absorption ape--tra of solutions of o-, 'p-,
and m-nitrophenols, 2,4- , 2,6- , 2,5- , 3,5-dini-
trophenol and picric acid in liquid amonlua and in
diluted a3-I,!!I% waters (0,001N) at room temperatures.
Also studies the elfwtrical conductivity or solutioni
of all abare-mmUcued substrncog In liquid wmanium,
at teMeraturos of 25 and -780. Submitted 1 Jul
1947.
67T15

USO/Chamistry - Phenols, 141tro Apr 1948
Derivatives
Chamistry - Hydrazine
"Absorption Spectra of Solutions of Nitro- and
Polynitrophenols in Anhydrous E~rdrazlne," YR.M.
Varshavekiy, A.I. Shatenahteyn, Phys Chem Just
imeni L.Ya. Karpov, Moscow, 71 pp
*Zhur Fiz Khini" Vol XXII, No 4
Measure absorption spectra of solutions of nitro-
and polynitrophenols in anhydrous hydrazine. Due
to the unstable nature of hydrazlne in the.presence
of air, develop method whereby Preparation of the
solution and photography of the spectrum Is done
in zedia'lacking ~Lir. Sulasitted. 1 Jul 19.47.
67T16

IChmIntry - NItro CaMpominds wy 1W
Chmintry - Spectra, Absorption
"Absorption Spectra of Solutions of Aromatic Nitro
C=pounds In SolTents With Free Atcms of Hydrogen,"
A. 1. Shatenahten, Ya. M. Varshavskiy, Phys Chm
Mot Imeni L. Y&. Earpov, Moscow, 11 pp
"Zhur IPIz xhW Vol IIII., No 5,
Describes absorption spectra experimants using (1)
solutions of nitro- and polynitrophemolates in allm-
3.1as "etone and (2) solutions of meta-dinitro caw-
pounds In liquid aimmonla and alkaline acetone. Re-
sults we shovn graphlc&lly. Considers results ob-
tained omflm Interpretation of omplex formation
of armatIc nitro eampounds In liquid ammla " a
reactim'of &ald-base type. Comparison of abnorp-
tim spectra strengthens hypothesis whereby band
ShIft in absorption spectra of these compounds is
attributed to formatim of complaw ions. Submittad
1 Jul 1947.
6ft28

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A Cmparison D,orpTI.um a-ihange arid the SOV/76-32--12-9/i2
I eta L Sub-
Y i-i n A', ky ` BQ nz e ne
The d!L,, - -_- i um sul~c, ti ~,n shows the saire regul ari ties as 'the
~3i_ibst f-; 1--_*--~n by a 1 I-a.!_J:L me tal 3 as already stated by ingold (Ref i)
~P_-,eS the lydrocarbons act as weak acids with -the basic
M-f-'r'n llrtef 18). h-wever, gave a wrone interpretation
Z.
M 1 :1101, ni' fhe- :-eac"'on. 'aka~.- u' leclrophil.4-
-ace by an e
th,-- comnound on 'he H - atom v--'',h
Roberts and D..T,, Curt~ n
a s s, irr,,:~ (i I i n, t h c~ ;.rn or +ho carbanion ...hL
a.2 a str,-~ng base attrar-ts the H_atom in
4'
f t,
p~_-.4~0-_ r :) on -~e H bindJng. G. Witt-g (Ref 24)
al-2~1 D. 16) th4s asslamption. -he
Sm h (.R~F
lenr,.' the C-a-~cm facilitates 'hp
thc, tDr,~t.--m, whereas a high electron density has an
inh, b~ Phe slow]ng doim of 'he reaction Jn the r-ng
L effec'
of' th~_ alky_ lr,~_nzenes is due to 'the indirect influence of the
alkyl- group.,Bryce-Smith (Ref '6) showed that the ortho-position
_~n the r.ing as deictivated to the Ereatest extent. 11. 1. Rikhter
arid F. N1. Mar.--chkina i'n the i rive s tigatJ on. are
abl-s and _~G refe-r
,1 1; _ences,~-, of' :,,hicl, are Sovie-,
Card 2/3

k C' Lmmca r I sr- n Betw, een Deulue SS T"/7 2) - -1 2
Substitutilon in A',k,,,! Benzenes
3 C I A T ID ~-.ij Z 4ko-khimicheskiy institut im. L. Ya. Kar~ova, 1,1,cskva
(Physir~o-Chemical Instil tute imeni L. Ya. Karcov, Moscow)
I
july 25, 19--7
Card 3/

,-S4414ZlUIT-;9, ~A. I.; PWVIKf)lll,, N.A.
Effect of comple- foration on the n.ronerties of silutions of
methyl estAr poly,,ers of rjethracr/lic acid. Vysokom.soed. I
no.~1:215-221 1? 159. (HIRf, 12: 10)
(Mpthacrylic acid)