SCIENTIFIC ABSTRACT SHAROV, V.S. - SHAROVA, A.K.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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Prom this, Z:?:mm:ibmdnw" P" rh.rvtbo truarmilm dws am dmmlp ibe bibty of the No-clor "nkb% wl-up"I"m4c"; tbo pa"kka on campkt* dKmpowd p == The rolults wbw.pkt to uw 5 t wg powd No satiustat with k em" te- r-e-Ow -.- -" such 6, mup;aw- -M -- --he ks of a pr~y WN t rw" mop"Am. god upom atmodws two 0 so 099"Od" of Pflut-7 pwticim into "Condary pwtkkL 0 % . a I-STLAO-91 a NJ f 00 a The dwo6old &d$"%& salwoo a "*@a& two FOAM U06" WU l N Cr zrom i a lk otbor WIA Cu an : am* aid d ti tiWto s . t , dked contact at am ood. by a tkin pa;w or see !r I W duet, Cu * * =m ~to the Ca bratcWto at a o mte of 0.6 Co. in 500 f.1. Bowman so* me* coo *00 use see CLAWKAiOR Wow "if ~""c oft a.. 46, I V=-. W, AN I ~l aIld 0 4 0 1 ff 0 9 A 3 u 0, &V 40 It : aa 1. W S , - , -WA 0 k 0. 0 * A 0 W, 0-4. -0 V~ A0 0 $wow gob SA #iwaj AUL, No 60 lee 41 day. 41+ OD% WAS.; by :C~--~ _. 7._ 1. W, & Go" fA a mw a d&&x4x2cm- lee "4m# ~ of twea 4 2 bm. Cw-d1w b60016 vo Ig. m& Ce ~~ ISO afta - - WOW ad coo at do diO Cmb0de M& OVA& don load to be 00 va miad in too oil, cm 40 be OPIL M" IW iwdm of SAO* 00 49A 09, Gloat Gm do-Wr 611 i FvM=dvo low bet"Oem is 4 isridm ASO f w I _ ;5~cb*"6~ the e1w im vullowl 300 an UWANNOO is OW 59* tbus imm 110114 6C9068-4 32 X Sao don is d1L 4"4- . ser.aAWn ad SA 4 X. too to tjo 8h" CWF a OVA" 4.7 V. too 14r", M/889-1 MMP , . 10- SON. 100 .................... .- vivo 0 off All WTALII"ICAL LnW-"" CLJ311"" a 11 4 a I sit W0 is Be 9 a 4 "Vissivs Om Mum 00000 10 , a Irk - 0 q, -00 * "Der: 5 Ar . AS * oe 0 e 0:4 .0e - * 1-0 SHALROV, V. S. 25561 Skorost' dvizheniya kationov v sugongele gliny pri alektrolize. KolloidrVy 2,11a Zhurnal, 19499 VYP. 4, S. 283-86 501 Letopis' Zhurma'rWkh Statey, Vol. As Moakvap 1949 ~z " .11-1 .. ., - - -- - - 25561. Skoroot' ;--ntdonov v z;us-7enilele fTliny -.)ri elektrolize. holloidnyy L> zhurnal, 1949, VYP- !,, -. 21586 SIO: Letuopis' Zh-arn-llultdh St,"eY, Vol. 34, ',',oskva, 1-049 , -V . o. -- - 255-01 Skorost' Drizheniya Katicnov v Suspengele Glirrl Fri llej,:trolize. Kolloidin-r . 19119. BYP. 11, s. 203 - 86 SO: IETOPIS INTO- 34 Cfl m ! owl c 'Most was deid. bY into ~ooral, 30 saw 26 X wo&vsccm)~ TwascWtV* % 6*-. and 10,41 per to t lot as lar1=11; t 4 In a low a I toy c M, Cult. &"allolm. SHAROV, V.S. Mechanism of the action of an electric current on a waterlogged cohesive clay mass. Trudy NII &sn.i find.20-17:47-62 152. Olay) (Drainage) (KLRA 9:9) SHAROV, Vladimir Semenovich; DULIKIN, A.I., red.; BDRUNOVp N.L., (Superhigh frequency asynchronous motors] Sverkhvysoko- skorostnye asinkhronnye elektrodvigateli. Moskva, Gos- energoizdat, 1963. 287 p. (MIRA 16:7) (Electric motors, Indqbtion) 79-2-2/58 AUTHDRS: Shchukarev., S. A.; Ybrozova,, M. P.; Kan Kho Tn.; Sharov,, V. T. TITLF: The Enthalpy of Formation of Lithium and Barium Bismuthides (Entallpiya obrazovaniya vismutidov litiya i bariya) PERIODICAL: Zhurnal Cbshchey Khimii, 1957, Vol. 27, No. 21 pp. 290-293 (U.S.S.R.) ABSTRACT: Lithium bismuthide (L3 Bi) was prepared by melting -the components, taken in a stoichiom8tric ratio, in a hermetically sealed steel crucible at a temperature of 12000. The compound obtained in such a manner was a coarse-crystalline dark-greenish substance. The enthalpy valve for this compound was fixed at - 39-5.10.5 kcal/g. The barium bismathide (Ba3Bi2) was prepared by melting the bismuth Card 1/2 with the barium, obtaimd by the high vacuum aluninothermy method, in a steel crucible at a temperature of 21000. The enthalpy of The Enthalpy of Formation of Lithium and Barium Bismuthides 79-2-2/58 formation of this latter compound was fixed at - 128.1 + 1.8 kcol/g. The bismuthides of both metals appear to be quite typical intermetallic compounds and the change in the heat of formation, resulting in the displacement of magnesium by barium, is subject to entirely different laws. The enthalpy values established were found to be different from the values established by Kubaschewski and Villa (6). 2 tables, 1 graph. There are 11 references, of which 7 are S3,avic. ASSOCIATION: The Leningrad State University PRESENTED BY: SUBMrTTED: March 24, 1956 AVAMUBIE: Library of Congress Card 2/2 ACCESSION NR: AP4036534 S/0089/64/016/005/0456/0457 AUTHORS: Ganzha, V.D-~; Konoplev, K.A.; Trenin, V.D.; Sharov, V-T. A TITLE: Ion exchange installation for preparing reactor feed water SOURCE: Atomnaya energiya, v. 16, no. 5, 1964t.456-457 a 1,.TOPIC TAGS: ion exchange water desalting, reactor water desal ting, kwater desaltings reactor feed water, water cooled reactor, moderated i-reactor ABSTRACT: The article describes an ion exchange water desalting install'ation to provide water feud for water cooled and moderated reactors. The installation has been designed at the Physical- Technical Institute im. A.F. Ioffe, An SSSR as a substitute for an unsatisfactory electric distillation-plant at the VVR-M reactor, which has low capacity,"rapid scale forming; and low electrical re- I'sistivity-of final product). The described installation produces 3 m3/hr feed water with 1 mg/l.salt, and less than 0.02 mg/1 chloride i3ns. The water supply is adequate for a regeneration cycle of 50 m . Artesian water is used as feed for desalting (400 mdl.salts, mostly Ca and Mg). Cation exchange resin KU-2 and anion exchange Card 1/2 ACCESSION NR:.AP403 6534 resin EDE-10P were used with 250 Lswolle'n resin loaded into each filter. Two airlift containers with 11 SO and NaOH provided for regeneration. A diagram of the instaliation shows 4 filters, 2 regeneration containers and subsidiary equipment. Water control is achieved by continuous measurement of specific electric resistivity and intermittent chemical analyses. The installation has been in operation since 1961. "The authors acknowledge B.P. Konstantinovts suggestion to itch over to ion exchange desalting, D.M. Kaminker's help in the op ration; P.P. Kory*stin's and I.V# Volf's help (All- union Scientif*c Research Inst. of Hydrotechnical and Sanitary Engineering) in laboratory tests and project recommendations." Orig.! Jart. has: 1 figure and 1 table. ASSOCIATION: None ISUBMITTED: ogAug63 ENCLs 00 SUB CODE: IWAG Nx REF SOV: 000~ OTHER4 000 2/2 Card L 25966-66 ___ i-rjT(--M)/Lvc(f)/EPF(n)-2/DIG(m)- --1JP(c)-- I.A.1 ACC NR% AP5026440 SOURCE CODE: UR/0089/65/019/004/0350/0354 AUTHOR: Ganzha-, V. D.; Yp D. M.*. gorov, A. I.; Kaminker, Kolyadin,-A. B.~ Konglev, K. A,; qaykov, Yu. P.; Sharov, V, T. ORG: 4649- TITIZ: Blectrophoretic filter for reactor water purification SOURCE: Atomnaya energiya, Y. 19, no. 4, 1965, 350-354 TOPIC TACS: nuclear reseapah reagtor nucle reactor meamm&dma, water purification equipment A&"# ABSTRACT: In January, 1962, a formation of turbidity in the primary loop of the VVR-M reactor of the Physicotechnioal Institute im. A. Fe loffe, AN SSSR, was observed. In June, the turbidity was so strong that a special electrophoretib filter for water purification was installed. The turbid water contained a 54-potp-suspension of hydrate aluminum oxide which was originated by the corrosion of aluminum reactor vessel and fuel-element cans. A daily amount of about 2 g/Mw of suspended particles was disobarged1into the water. The'installed filter was equipped with the platinizqd titanium anodeplates, while the cathode UM: 621.039*568 25966-66- ACC NR, AP5026440 plates were made of 1 19 9T stainless steel. A cylindrical prototype of the fill;er was experimentally tooted and the results were oxplained and graphioally Illustrated. The tests showed that the chemici-il. compositioni of turbid and filtered water was as follows: Turbid Filtered A1203 in m/kg 3.0 0 Fe +3 0.4 0.18 S102 6.0 1.3 02 0,96. 2.96 .optical density 0.065 0.008 The aelectod filter design data are silmmarized to-the following table: Water flcw rate in kg/hr 250-500 Effective water flow in ou M/hr 0.5 Mectrode voltage in v i 110-220 Distance between electrodes in am 1 ~ Contact time in min, (at 250 1/hr) 2 Total filter volume in liter 10.7 Interelectrode volume in liter 7.5 Eleotrode size. in mm 170x572 Number of anode plates 4 Number-of cathode plates 5 Filter dimensions in nm 400x;!24xM L 2~966-66 AM NR, AP5026440 The filter-has a small hydraulic resistance and needs only about 0.5 k-.11 for its operation. A flow diagram represents schematically the ciraula-' tion of water in the primary loop of the reactor. AnotherTi8ure shows a photo of the electrophoretic filter which was succe-ssfully used for purifyine water in the VVR-M reactor. The authors express 'their Grati- tude to Academician B. P. Konstantin_qff_for his continuous'Interest. Expressioni,of thanks are also given to V. P. Rodzevich (for apparatus design) I *V. D. Trenin and R. N. Rodionov7?-o-r--a--n-a-lYs-fs-l-and to D.-A. Yashin anC . a. - REFZ-Ov Orig. art. bas: table-6 ond 6 figures. SUB CODE: 19,13 / SUBM DATE: 4-Tuly64 /. ORIG RU:001. 0TH -RF-F,',0M cord 3/3 8/081J61/000/019/068/085 AUTHORSs Ifekhtiyev, S. D....SharoT, V,-Y-, Pasharev, T. A. TITLF,s-':' Calorific value of some aromatic cyclohexyl and dicyqlohexyl hydrocarbons PERIODICA,Ls Referativnyy zhurnal. Khimiya, no. 19, 1961 424, abstract 19N182 (Azerb. neft. kh-vo, no. 2, 1961, 40-~2) TEXT.s Data are given concerning the calorific value of aromatic cyolohexyl and dioyolohexyl bydrocarbons~per weight and volume. These data were .calculated starting from molar combustion heats and molar Ikydrocarbon volumes aocording to the method developed by V. M. Tatevskiy. ~bstracterls notes Complete tranelatiO4 .Card 1/1 MEMITIYEV, S.D.; ALIYEV, A.F.; YMMAROV, Yu.G.- SHAROV, V-V- Z)ernal decomposition of cyc'o~exane under conditions of extra rapid pyrolysis. Azerb.khim.zhur. no-3:3-13 '-159- (YJ-R,, 14: c, (Cyclobexane) (F~rolysis) SOLOMMKO, H.S.; CIMIKOVSKLY, V.S., redaktor; SUROV, Ta.l., redaktor. [structural mechanics of the ship]-Stroitel'naia makhanika korablia. Pod obshchel red. IA.F.Siarova. Leningrad, Gos. nauchrio-takhn. 12d-vo mashinostroit. i sudostroit. lit-ry, Laningradekoe otd-nie. 1954. 415 p. ~W""Ah 8;1) (Shipbuilding) NOVOZHIIAN. Y.T.; qz~, Ya.]F.. redaktor; CHICMUNOVA, V.S., redaktor; FRUMN, F.S., tommNOT70me y rodaktor [Theory of thin shells] Teoriia tonkikb obolochek. [Moskva] Goo. izd-vo sydoetroitellnoi lit-ry, 1955. 344 p. (MLU 8:10) (Blastic plates and shells) SHAROV, Ys.T.,knnd.tek-hn.nauk Impact of waves on ship bottoms. Sudostroenle 24 no.4;5-9 Ap '58. (Ships--Hydrodynamic impact) (MIRA 11:4) SEAROV, Ya.F., kand.tekhn.wu ---------------------------- Impact of ship hull bottoms agaient oncomin vaves. Trudy NTO sud. prom. no.35:29-38 160o fMIRA 132-9) (Ships-Hydrodynamics) 1. s=v,' Ya. V. 2. IJO'"M (600) 4. Chemistry - Study and Teaching 7. Extracurricular activities, Khim. v shkole, No. 5, 1952. 9. Monthly List of Russian -Accessions, Library of Congress, February -1953. Unclassified. KCKAROVSKIY, A.N.., doktor tekhn, naukq prof.; SHMVA) Ye.A., red*; YEZHOVA, L.L., tekhn. red. - (Structural design of accelerators) Stroltellmye kcnetraktsil uskoritelei-, lzd.2,-, perer-. Moskva# GOS. izd-vo "Vyoshaia shkolay" 1961. 133 p. (MIRA 15:3) (Particle accelerators) ACC NRI AP607,5928 -SOURCE CODEs Ult/U4-13/66 AUTHOR: Arinuchidn, L ' S., Dumov, V. I./ Xnyshev, V. A. Moskovskiy, V. D./,Polinovaidy, A. Yu./ Pharov, Yu. A. 10RG: none TITLE: Pump unit for two-eircuit fuel systems for power planto SOMICE: Izobreteniya, promyshlonnyye obraztsy, tovarnyye znaki, no.20, '1966, 19j; 1 a :_ TOPIC TAGS: pump.Muel system, fag ;n!ryi44=_z9%0 1.9=9=~_,ruei feed system, 1UNGRA VV "'~OT_hbrllpropoacd pump un1t conflicts of a pump with a low pre surej ,circuit and a pump with a high prounuro circuit. To 1mProve Jtgl ificicney and to decrease the nyoteml a size and woight, the imptillart) lof both pumps are mounted on a common shaft and an annular collector in !positioned between the impellers; the-collector Is connected by ducta-...I--- It-3 the low pressure pump putlet duct and to the high preasure pump 'Inlet cavity. In order-to improve the anticavitional characteristics of the unit, a vajh~aiio'n of this unit Is made so that the ruel bv-Dann from the high pressure circuit rbno through a duet-wh1ch is posiftoned tangentially to an annular chamber located at the unit Inlet. (see. Fig.1). Card 1/2 F~i; NRA Orig. art. hans I figure. suB coDE: 21/ suBm DATz: o5oct63/ Fig. 1. Pump unit I- Impeller; 2- drive shaft; 3- annular col- lector; 4- ducts; 5- low reanure pump outlet duct; 9 - high pressure pump in- let cavity; 7- high pres- sure circuit; 8- tangenti- ally positioned duct; 9- annular chamberl 10- unit inlet [WA-883 SOV/120-58-4-12/30 AUTHG1ZS:Bartenev,L. S.1 Glebovichl G. V., Gox7achev, L. V,) TITLE: A. High-Speed Pulse Oscillograph (Impul'snyy skorostnoy ostsillograf) PERIODICAL: Fribory i tekhnilca eksperimenta, 1958, Nr 4, pp (USSR) ABSTRACT: An oscillograph with deflection plates of transaissio_- line type is described; two time-base systens are the faster of which gives one complete syjee-,) i-a ~~.).xat 4, x in-9 9ec, There are two oscillators, a'200 Mcls m4 a 500 Mo/s osclllator. T atrons are used to develop -tne sweep, .hyr ages? and advantao-e is taken of their ionization characteri_~-- Cj tics to get really fast response. Post-deflection ion (3 Iff) is used; the vertical deflection system has a pass-band extending up to 1000 Mc/s. The deflection sensl- 0 - tivity is 9 V/iaa. Ex-amples of oscillo-rams taken a.re Caird 1/2 SOV/120-58-4-12/30 A.High-Speed Pulse 0scillograph presented. The paper contains 4 figures and 2 references, of which 1 is Soviet and 1 English. ASSOCIATION: -Nauchno-issledovatellskiy radiofizicheskiy institut (Radlophysics Scientific-Rezearch Institute) SUBMIMM: October 24, 1957. Card 2/2 KOTENKO, L.P.; KUZNETSOV, Ye.P.; MOWN, G.I.; SHAROV, Yu.B. Elastic scattering of 2.8 Bev./c:F--mesons on hydrogen. Zhur. ekap. i teor. fiz. 42 no.5:1158-1165 W 162. (KM -15:9) 1. Fizicheskiy institut imeni P.N.Lebedeva AN SSSR- (Mesons-Scattering) (Hydrogen) ACC NR, Ap7001460 (A~ SOURCE CODE: UR/OW316-6/000/02110211/0212 S:; INVENTOR:- Arinushkin, L. Dumov, V. I.; Luchkin, S. M.; Polinovskiy, A. Yu.; Sharov. Yu. A. ORG: none TITLE: Self-priming centrifugal-pump assembly. Class 59, No. 188308 SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye zaaki, no. 21, 1966, 211-212 TOPIC TAGS: aircraft fuel pump, axial pump, fluid pump, centrifugal pump, engine fuel pump ABSTRAM This Author Certificaee introduces a self-priming centrifuge Pump for fuel systems such as those used -in aircraft. A common casing contains a main centrifugal pump and an auxiliary fluid-flow ring pump. The discharge cavity of the latter connects with the fuel tank. The intake chamber of the fluid-flow ring pump is connected to the forechamber of the main pump rotor by means of a channel which'encircles, for instance, the hub of the main rotor, and another channel in the casting connects the functional chamber of the ring pump to the discharge cavity of the mi%in- pump. This arrangement improves the anticavitational properties.of the Card 112 -112 -ACC NRt AP-j 7C Fig. 1. Self-priming centrifugal pump 1 - Intake chamber; 2 - rotor; 3 - channel; 4 rotor hub; 5 - functional. %.chauber; 6 -,discharge cavity of j~ the main pump. astembly and reswIts in wre dependable operation. In another version of the above assembly the main pump includes an engaged axial rotor, and in this 'case the intake of the ring pump is also connected to the forechamber of the axial rotor (see Fig, 1). Orig. art. has: 1 figure. [SAI SUB CODE: 13, Ol/ SUBM DATE: 30Dec62/,ATD PRESS: 5110 Card 2/2 L 22h93-% AFWL/AEDC(a'I/ASD(f)-3/AAMC ACC-73310'al.' NR; AP5002420 S/b286/64/WO/bU/0O24/0O24 AUMOPS: Dobrovol'skiy, V. L.,- Kaspruk, Yu. V.; Fqabov, B. I.; Sharov,-Yu. N.; Mildmylina, S. "I.; I7anov, Yu. V.; Budrik, G. V T!"LE: A method of raising and holding a cassate, vith a source of ionizing radiatiQn, in a vertical pipe in a suspended state. Class 21, No. 1669?5 a"ACE; �yji4eten' izobreteniy i tovarnykh znnakov, no. 24, 1964, 24 ABSTRACT: This Author Certificate presents 4,_-meith6&~of acpp3,ying the dynamic pressure of a liquid or gas current to raise and hold a caseets, with a source of ionizing radiation, in a vertical pipe in a suspended stste. ASSOCIATIONt none SUBMWED: MovQ ENCL: 00 -ME.-, NO REF SOV: 000 OTHER: 000 SHMov yuriy Vladimirovich; BASOV, ym.T.,, redaktor; RYBIN. I.V., "fe-ftnichaskly radaktor Cjktracurricular work in engineering; a practinal m&UuAl for teacbers, Pioneer leaders, and workers directing the work of young engineers) Vneklasensia'rabota po tokhniko; metodlebaskoe posobte dlia uchitelai, p-ionervoshatykh I vueshkollufth rabotnikov. vedushchikh rabotu. s Lunpli tekhnikami, Moskva, Goes uchabno-podagog. isd-vo Ministerstva prosveshchenita MSARO 19,55.- 203 p. (HIM 9 '. 12). (Inginearing-6;tudy and teaching) CHURIN, V.; SHAROVA, A., DAVIDOVICH, V. 'r . I he now equipment and industrIal ITyglone. Sov.profool-my .- 7 . no.10:18-21 W 159. Nak 1219) (Industrial hygiene) INNO9990996: 000000*0 41044609 9 it 11 11 11 m a X. A04L 0 1- .00, 00 so, 00 t A rapid umbad for decannisting v*jar sad ximc jjrj;cg, and Sumhar products. A.,X. Shari 00 S 10, No. 7. 93-l05(lWj7=~"x fstpa. r=vwhrmir Udd. j4r mde to dcftlW raPid analytical methods for Toutint deta. of Cu and Zu in 00 or" and Metter products. Existing methodl and their dimadvantaps we discumed. and as the result of expti. vmrk a new accricrated nwtW, requiting only 2-2.5 brs, Is, propuwd. The nwthod is saki to be comtwable in mccumey with hmxw methods. H. N. D. OW VO 0 .A 0 1-00 .00 ap 0 go* ,90 .0,0 ,00 to's TALLOOCKAL UtINAUAR CLAIIWKATW* boo LA wee .0'a j 4LI ONI acc -i-j iTil ~w Witil I uLj1*-t! -.1 Ltj v m W I mr of 9 a a 3 1 !zk 1A L Is 'm 0 44 Ove 9 0 0 * 0 0 000 0 0 0 a 0 us 0 * 0 4 4 0 0 * off V'o 0 0 0 0 0 0- 0 0 0 0 of ; 0 oll F L L a SO O 4 4 1 V Y. -4 1. 1 0 (4 M U4 1 4 A 0 00 oo ..so 00 -00 00 -00 0 -00 0.0 Comiltions lot lovoworing Coppor fullole from agwrit -00 00 goading Vlovir"Iyt.. V. A ASIO'k.1 .#4,1 A k '00 0& J. Che.- Ind. tu. S. N. H.) 14. wi lAlangM)-lio. fecil, fWalls fur file ncfflfafilwi~'o -4 tkAtrolytr knonig. OA COA). with glaulglair'l Co; I-trysills. o( Ow -00 OOZ CU.'A)..'Rtt.. fire Rivet, M. 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Sharovs. 7' No. 11, ZI-7; KAIWIW~i' 2, No. 3,%3-4 (Igno).-Them were fatutif in the intermediate and.the &%to products of the nonirmtovs metallurgy of VrAt, In t cases incressa:4 arnts, of TI. 6a anti tk- Thl, 14 At e%plainicd gy the fact that they we COntsiuc-I in the ores of the nonferrous metab in the form of isomorphous admixts. and that a natural conazu. of these elements takes Place during the Process of the technologicul tir2iment of the awe. W. R. Henn ASS.St, OFTALLUNGKAL LITINSIM CLAOIFKA VON I ftI I kv 00 Is 9 F 0 0 dog a a ON ON it it a it at 0 0 to 0 0 0 0 0 0 0 0 0 0 0 v 0 0 0 0 0 0 0 0 .00 -00 0* -00 .40 ZOO AO UO 5 VNIMpo"d 3 4 0 0 0 v 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 c 0 0 0 a 0 0 0 0 too W_ PST AAW IND pows"ll AND "O"Alf" MOVIA pvas" of the mr* Olon"is dMam a" Vf- i l d f sea ". ar ac ftan wilturic ad *mkonsO wA "~ShLUR"- J. cv.. Imi. V, S *0 , & jvmsjr-Whcn flotatioa no Tj (w Ge ( So l, U a fount Q Works. Itowtv". p &,vmt Irm Lm I T1 t s hcr r** wwatctlah Cwtalm camS -00 Cd pb and se, to make its tim. r=u;;Q by estn. with 5% ~M wie Ge ma be tbw; mamyved Wad the aut gj C#CCU by pwWtlg 6 over tbc 00 it too 0*9 8 WOO ASAI-SLA ORTAU01104CAL UTCRATtow-CLAMIFICAl" '004 WHO "NARV U1400 MLV 4mv all Olstal dw 416Y all ' Zj~ JMLA * 0 0 f 7 ~ oe 0 0 0 00 00--o-999.0 mow 0,0000 meows 40060606049696004 * - ~4 ~~4 ~.. 0 0 0 W W , v It M j? , a a(l 0. a 0 ~ F- tAl -1-01. U. AO 4, 1 1--l- 00 rilKillit &n0 0401trortto 'Was . 00 - Of "baw w~w. C K. awc," C). Chufarov, Shmv. 0, 44-01(lOW).-Thl. Ood cancertied the Opthaum CMICIllims for Wpil. CO and by P"S. the Ca with %CaOCI, -A "I bep". Was Ob- as PH 5 in a Oda. cowt. wstl C. per 1. of activv 0. Mier addins XaOCI the uAn. is neutrahzrd with K~ o A 40 NallcOl own. OMIrrably) or a 2110 yaln. of Natco, at rom temp. Tbe ppl, is vrasbnt Milt O,ul N )let of *0 41.01-0.05 S If3sch. Sf. I Imh 40 00 goo 00 goo RPM S OS L A-,l-L,UR4K&k Of(AtUalt CtAS'.lF&CAT#C% 11- 416- Ila. c", 1281 ia 'j, I - S it Ai Pw 0 x At 1 21 v o aav v AV rb b it a At al AR a Ot a a 0 0 0 9 0 0 0 0 0 0,0 0 41 0 0 0 0 0 0 0 0 00 so .0 il of 190 *'0 0 9 0 0 * 0 0 0 0 0 di 0 0 0 Mi 0 o do A, K..Mmwvva, c.. t. and ~rsl :'l v:8-S.R.U.M. Nlar .11. 1047. lit the procvm AV utiliml niat"Ji4s. mwb us slicolitir and low-grade muttatts whk uw of lot ities, e.g. P, Mo. and the like. cannot lit at bythe crall a ted ract 0. 111,31, AX art. fu I witri *4 Lutd. and coal, Vic fuslim 1% carried out tlv%t in a ncfudnx attu. atkil t1wit In an o0lisint atoi. T1& causes N'aaWO, to dismAve In V4j$0, mul as it it, tit irl.a. "VIr it- %P. sr.. to concentrate In the upper Uvrr, - r. the lower )Kqvier layer con4sts J~Nhmdnmttly "t silicat". -416-11LA MITAWWWAL LFIRIATUM CLASWICAlift- 7~A roe 0 "Sodo Adle tool vvrz-_- 0446" *A- %magma .4. SMA54-1 .....1 .11 0 1 1 T 9 31 T of VP P At .&dun I I SEA& JA A t a im a N v I W of 0 A a IV -4 U it a .1 lit Alit 0, W 04. 0 0' 00 0 40 0 L 0 9 49 0 0 0 0 1. DEKMV, N. V.. SgaoVA, A, L.. POLYAKOTA, V. M. 2. Tim (6oo) 4,, Oulf ate s 7. Reaction of titanium sulfate with Potassium sulfate. Doki. AN SSSR 87 No. 5, 1952 9. Konthly Lists of Russian Accessional, Library of Congress, K_a_r_t-h_ 1953. Unclassified. t) Chemistry - I'liermodynardes. ghe.rmochemistry. B-8 USSR/Physical . Equilibrium.. Mysicochumical, Analysis, Phase Transitions Abs Jour : Referat Zhur - Khimiya, No-2, 1957, 3747 Author : Chukhlantsev V.G.., Sharova A,K. Inst : Kiev State University Title : Solubility Products of Uranyl Arsonates Orig Pub : Zh. neorgan. khimii, 1956, 1, xo 1, 36-41, Abstract By the isothermal method at 2& vere secured data on the solubility of uranyl ars,,=tes UOpMA-sO4 -. M = H, N94, K, . Li and Na) in dilute solirtious of nitric and sulfuric acid. 'By utilizing previously derived equations i 'Babkc "IU, 1935, 4) determinatioa was A.K,, Naukovi. zapiski K, made of the solubilit rod ts of the arsenates under Y stUA 7 T ~y'L U02 -7 ZM _7, Vnich are (at 20P): I. 2 1.71 10-24 (M Nffk 2.52 10-23 (m x); 1.35 Car& 1/2- -.92 d-li -k t-, Y 4- 587 AUTHORS: Demenev, N. V., Milyutina, M.I., Sharova, A. K. and Shtin',A.P.- TITLE: Preparation of an Acid Sulphate of Trivalent Titanium. (0 poluchenii kisloy sernokisloy soli trekhvalentnogo titana). PERIODICAL: "Zhurnal Neorganicheskoy Xhimii" (Journal of Inorganic Chemistr Vol.II, No.2, pp.465-467 (U.S.S.R.)-Iqf~ ABSTRACT: The formation of a violet-coloured crystalline precipitate in quantities strongly dependent on sulphuric-acid concentration was observed when working with reduced acid solutions of titanium. To determine the composition of the precipitate and elucidate the conditions leading to its formation was the object of the work described. The solutions used contained either 15.25, 25.0 or 37.5 g/litre of TiO i initially, and the final contents of this and of sulphur c acid were determined. The results are tabulated and indicate that with 700 - 100 g/litre of H SO precipitation occurs to 90-97%. Analysis of the salt pKp&d with careful exclusion of oxidation gave the composition Ti (SO H so .8H C ~4 2 4 2 i 1u It is a crystalline powder soluble in water, d sulphuric and hydrochloric and concentrated sulphuric acids. It is recommended as a source of trivalent titanium for analyAical work. There are three references, one of which is Russian. 1 Table. Received April 26, 1956. Card 1/1 S/137/60/00()/006AO1/015 A006/AOO1 Translation from: Referati-nyy zhurnal, Metallurgiya, 1960, No. 6, p. 70, # 1223( AUTHOR: Sharova, A.K. T=: Studies of the Chemistry and Technology of Rare Elements PERIODICAL: V sb.: Uchenyye Urala v bor'be za tekhn. progress, I. Sverdlovsk, 1959, pp. 137-146 TEXT: Studies are listed, carried out at the laboratory of rare elements at the Ural Branch of AS USSR, on the chemistry and technology of rare elements. There are 19 bibliographical titles. G.S. Translator's note- This is the full translation of the original Russian abstract. Card 1/1 SHARMA, A.K.-, FOTIYZV, A.A. Production of titantui-n dioxide from the product of the sodium sulfate reduction synalting of an 11TIenite conenntrate. Izv.Sib. otcl.All SSSR no.4:52-63 159. WIRA, 12:10) 1. Ural'skly filial Akadenii nauk SSSR. (Ilynenite) (Bodiuvq sulfate) (Titanium oxides) SHMVA. A 0 CEMFAROVA, I.G.; VITTIKH, M.V.; SHDSTAK, F.T. Recover7 of germanium from dilute solutions by an ion exchange method. Izv. Sib. otd. AN SSSR no.8:36-42 159. (KIRA 13:2) I.Ural I nki)r filial AN SSSR. (Germantu*--Analrels) (Ion exchange) SHAROVA, A.L;SHTIN, A.P. Rioblum phosphates. Izv. Sib. otd. AN SSSR no.9:40-47 159 NIBA 13-3) 1. Ural'sk'y filial AN SSSR. (Nibbium phosphates) SHTIN, A.P.; 9HAROVA, A.K. Tantalum phosphate. Report 36.2. Izv.SIbqotd.AN SSSR no.10: 87-94 '59. (MIU 13:4) 1. Ural'skly filial Sibirskogo otdeleniya AN SSSR. (Tantalum phosphate) S/598/60/000/004/010/020 D217/D302 AUTHORS: Sh v A.K-- Demenev, N.V., Fotiyev, A.A. and Ivakin, A.A. TITLE: Production of titanium dioxide from ilmenite concentrates by sodium sulphate melting SOURCE: Akademiya nauk SSSR. Institut metallurgii. Titan i yego splavy. No. 4. Moscow, 1960. Metallurgiya. titana, 95-101 TEXT: In all experiments, ilmenite concentrate from the Irshinsk depo- sits, of 0.056 mm mesh size were used. The chemical composition of the concentrate was as follows: 51.46% TiO 2, 33.78% Fe, 1.04% Al203, 1.56% Sio 21 0.86% MgO, 0.26% V2051 0942% MnO and traces of CaO. Wood charcoal with an ash content of approximately 2% and 0.4 mm mesh size was used as the reducing agent. The main reagent, Na 2s0 4' is a natural producto The charges of ilmenite concentrate, Na 2 so4and wood charcoal were Card IA S/598/60/000/004/010/020 Production of titanium ... D217/D302 thoroughly mixed and transferred to porcelain or graphite crucibles. Charges weighing 200-300 gram were used for the experiments. The mix- tures were melted in a silite furnace. It was assumed that the melting was complete at the moment when gases ceased to be evolved from the melt. Each crucible was then withdrawn from the furnace and the melt cast in a graphite mould. After cooling, the melt was ground and subjected to leaching with water and acid* The residue was calcined and analyzed, for its iron and titanium dioxide content, When ilmenite concentrates are melted with Na 2S04, the following reaction occurs: FeTiO 3 + Na2so 4+ 2C = FeS + Na_'TiO3 + 2C02 0 The reaction intensity depends among other factors on the method of melting and the surface area of contact of the various phases. In order to find the conditions under which maximum extraction of iron in aqueous leaching is attained, the following factors were studied: Volume ratio between solid and liquidg time of stirring, temperature of leaching and degree of grinding of the melts. In all experiments, leaching was carried out at 25 0C for 15 minutes. The Card 2/4 S/598/60/000/004/010/020 Production of titanium D217/D302 particle size of the melt was 1.6-0.85 mm.. It was found that complete extraction of iron from the melt can be attained only when the sodium sulphate and carbon contents in the charge are sufficiently high., The optimum ratio between concentrate, sodium sulphate and wood charcoal in the charge (in parts-by-weight) is 1:2:0.6. At 1000-1050 0C, complete decomposition of the ilmenite concentrate0occurs (up to 98 or 99%). No melting of the charge occurs up to 900 C. At higher temperatures, intense melting occurs with much evolution of gas and a homogeneous fluid melt is formed. Extraction of iron sulphide into the solution depends on the time of leaching and the degree of grinding of the melt. An increase in the time of leaching from 15 to 60-90 minutes decreases the amount of iron extracted into the solution owing to the transforma- tion of the sulphide from a soluble form into a gel. The optimum condi- tions for extracting iron sulphide in the aqueous solution (up to 80 or 85%) are as follows; ratio solid: liquid = 1:10, solution temperature - 0 70-80 C, degree of comminution of the melt = 2-3 mm and timeof leaching = 15-20 minutes.. As a result of treating the residue, titanium dioxide Card 3/4 S/598/60/000/004/010/020 Production of titanium oo. D217/D302 is obtained in a form suitable for metallurgical purposes and for pro- ducing titanium tetrachloride. There are 5 figures, I table and 9 references*, 6 Soviet-bloc and 3 non-Soviet.-bloc. The reference to the English--language publication reads as followag J.C. Witt, Am. Chem. Soc.. 43, no. 4, 734, 1921. Card 4/4 SHOSTAK, T.T.; VITTMEL N.V.; SUROVA, A.K.; OWAROVA, I.G. Separation of geresulux b7 an ion exchange method, Izir.Sib-otd. AjF sm no.a.-69-74 160. (XIRA 13: 9) 1. Nizhne-Tagillskoye otdelsnly4~ lauchno-iseledavatellskogo inatituta plasticheskikh mass I Urallskly filial AN S33B. (Germsaium) (Ion exe,hange) S/828/62/000/000/009/017 E039/E420 AUTHORS: Shtin, A.P., Sharova, A.11. TITLE; Investigation of the physico-chemical properties of phosphoric acid compounds of niobium and tantalum and their separation SOURCE: Razdeleniye blizkikh po svoystvam redkikh inetallov. Mezhvuz. konfer. po metodam razdel. blizk.ikh po svoyst. red. metallov. Moscow, Metallurgizdat, 1.962, 107-115 TEXT: Complexes of Ti.-Nb-Ta usually contain phosphorus. In order to determine the effect of phosphorus on the behaviour of these metals the properties of the phosphbric acid compounds of Nb and Ta were investi.-ated. Nb and Ta precipitated from solution in sulphuric acid by the action of phosphate ioas can be presented in the form: 2Me2O5-P2O5.6H20 (where Me is Nb or Ta). The dehydration of these phosphates is shown to be a gradual process ,largely complete at 5000C. However, X-ray diffraction analysis shows that at 8000C in the case of niobium phosphate the composition can be represented by 02Nb2O5*P205,O.85H2O and in the case of tantalum phosphate at 900 C the corresponding formula is Card 1/2 5/828/62/000/000/CO9/017 Investigation of the phyalco-chemical .. E039/E42o 2Ta205'P205-0.81H20; in addition the transition from the amorphous to the crystalline state is observed on dehydration. The dehydrated salts have a higher density than the hydrated salts. The conditions for separating Nb and Ta in the H2SO4 solution by the Pphosphat,01 niethod,,2;1~i- -.'s-i4diied. Precipitation of tantalum phosphate from a solution containing 850 to 1000 S/litre Of H2SO4 gives a separation of Ta from Nb of 90 to 95"'0. With a high Nb content in the solution (Ta20g:Nb20 5 = 1:25) the product has a higher N1b concentration (i.e.-N 205:Ta205 = 1:2). When the ratio of Nb2o5:Ta2o5 = 3:1 and 1:1.8. the ratio of Ta20 :Nb205 in the product is 8:1 a-nd 14:1 respectively. After treaLent. with an alkali the phosphate precipitate contains more than 90% Ta205, Repeated precipitation is recommended only from solutions with a high Nb content. There are 4 figures and 6 tables. Card 2/2 5/828/62/000/000/010/017 E039/E42o AUTHORS: Sharova, A.K.A-Demenev, N.V., Polyakova, V.M., -71-ilyutina, N.I. TITLE: The physico-chemical basis of methods of saparazing titanium and the earth acids . SOURCE: 11azdeleniye blizkikh po svoystvam redkilch metallov. ,%Iezhvuz. konfer. p6 metodam razdel. blizkikh po svoyst. red. metallov. Moscow, Metallurgizdat, 1962, n6-123 TEXT: This work was undertaken because the properties of the fluoride complexes of Ti and Nb and their solubilities in various mineral acids are of importance in the development of separation processes. It is shown that the optimum.conditions for the separation of Ti and Nb from H2504 solution are: 107/9 11i2SO4, 154' HF and 10%. KCI. From a study of the interaction of potassium salts with Te and Nb in H2S04 a method is developed for separating Ahese elements from medium and strong acid solutions. This separation depends on the principal valency change in Ti. Vhen a potassium salt is introduced in H2SO4 solution containing Ti (180 to 250 g/litre H2304) the double sulphate of Ti and K is Card 1/2 S/828/62/000/000/010/017 The physico-chemical basis ... E039/E420 precipitated. When Ti and Nb are present in solution both metals are precipitated in the form of isomorphous compounds. However, if Ti is present in the trivalent form, it is not precipitated and the Nb is separated from it in-the pre.cipitate in the form: the solubilities of K2S04(NbO)2(SO4)--4H20i Nb and Ti in the Ti02-SO--H 0 system over a wide range of It .) 2 2S04 concentrations (180 to 1000 g/litre) and the conditions for their separation found. The separation of Nb and Ti is attained by the successive fractional precipitation of Ti in the form T:L2(SO03-HISOI,-8H20 and then the nioblum sulphate complex (NH4)JTNb603(S04)l2j *21H20 with an acidity of 800 to 900 g/litre 112SO4, Th~ product of this process contains 98.26 to 98.8% Nb205 and 0.3 to 0.55' TiO2. As a result of this investigation the above inethods are recommended for the separation of Nb and Ti. There are 2 figures and 2 tables. Card 2/2 )~ILYUTIM, M.I.; SPITIN, A.P.; SHAROVA, A.K. Studying the interaction of trivalent titanitm sulfate with sulfuric acid. Titan i ego spiavy no.5:301-396 161. (MIRA 15:2) (Titanium-Metallurgy) ACCESSION NR: AT4042095 B/2768/6i/000/007/0007/003.1 AUTHOR: Sharova, A. IL; Polyakovi, V. M.; Bamburov, V. G. j Chernpirskaya, Ye. L TITLE: Separation of titanium from &0blum in mixed solutions of hydrof luoric and: sulfuric araids no. 7, 1963. Khimlya I SOURCE: AN SSSR. Urallskiy filial. Institut khimil. Trudy tekhnologiya redkikh metallov (Chemistry and technology of rare metals), 7-11 TOPICTAGS: nioblum, titanium, niobiumpurlfication, titanium purification, silicofluoride method ABSTRACT: - The authors studied-the mineral acid extrdetion of igglomeiates obtained d4r- ing enrichment of complex ores by sintering with KCI plus K2SIF6 or Na2"';'F6 as well as the separation of titanium from niobium in th4 resulting hydrofluoric and sulft-tric acid ~olutionb. The agglomerate samples were treated at 70 and 80C with 3..6, 5.0, 7.,0 and 10% H2SO4' 1. 0, 2. 0, 2. 5 and 5. 0% HF, and their combinations, with or without addition of KC1 . Treatment for i hour at 80-90C with a mixture of 1% HP and 5% H2SO4 was found to Im expedient, y1elding up to 88% and 81% of the total Nb2O5 and T102, (plus ZrO2), respectively. Effective separa- 1/2 - Cc4 ACCESSION NR: AT4042695 tion of titanium from niobium in these solutions was achieved by adding KCI to the solution (up to 40-60 g/L11, cooling from 70 to 15C and allowing the precipitate to settle for 1 hr.; 94. 3-95. 6% of the total Utaaium* then precipitated. in the form of potassium fluorotitanate. Org. art has: 5 tables. ASSOCIATION; Institut kWmii,. Ural, skiy filial AN SSSR(Cheir-ical Institute, UrELL Branch) AN SSSR) SUBAUTTED: 00 ENCL..,00 SUB CODEt IC NO REF SOV-1 001 OTHER: 000 242- C6r~ ACCESSION NR: AT4042096 8/2768/63/000/007/0013/0017 AUTHOR: Titova, Z.Mv Sharovap As Ke TITLE: , A study of the conditions of precipitation of niobium from mixed solutions of hydro- fluoric and sulfuric acids. SOURCE: AN SSSR. Urallskiy filial. InBtitut-khlmil. Trudy*, no.' 7, 1963. Khimlya i tckhnologlya rodkikh metallov (Chemistry and technology of rare metals), 13-17 TOPIC TAGS: niobium, nioblum oxide precipitation, silicofluoride method, niobium. purification ABSTRACT: The authors 'studied the conditions for the ptecipWition, of Nb,,O, from the hydrofluoric and sulfuric a&d solutions which result from the processing of"pyrochlorine concentrates by the silicofluoride znnethod, (concentrate: K2SiF6:KCI - 1:1. 6: 0.4 at 750C for 1. 5 hrs. , followed by. extraction with 1% HF and t% H2SO4and precipitation of most of the T1 as potassium fluorotitanate). Preliminary studies with ammonium. hydroxide showed that complete precipitation of Nb In. achieved oiAy at pH lo. In MbSGqUent studies, RqU60US sodium hydroxide solution was slowly added to the sample at 70-89C, in amounts so calculated Zrd' ACCESSION NR: AT4042096 as to leave a prescribed residual acidity In the sample. The niobium. containing precipitate was separated by filtration, washed with water, dried and analyzed for Ti, Nb and.Zr. The yield of precipitated Nb.was found to increase with a reduction in residual acidiV of the solu- tion, reaching 97% for a residual acidity of 14.7 g/L H2SOj. An improved purification procedure for tht, niobium, precipitate was also developed which requires less'NaOR and yields a Nb 0 containing 3'. 65% Tio~# 0. 08% Zr02, 1% or more Cal up to 1%'Al and Fe, and up to 0. 01;?M,g.. Orig. art. hast 2 tables, ASSOCIATION: Institat khImit, Urallskly filial AW SSSR (Chemical Iwtltute, 'Uril- Branchj. AN SSSR) SUMUTTED. 00 ENCL: 00 SUB CODEt IC NO REF SOVi 009 OTHER-, 006 LCOSSION NR: AT4042097 S1 2768/63/000/007/0079/0063 1UTHOR: Sharava, A.K.; Mlyutina, IVLL 'ATLE: Separation of n1oblum and titanium (IM In sulfuria'acid solutions. filial. Institu khimil. Trudy*, no. 7, 1963.' XhImly' *UrtCE- AN SSSR. Urallskiy t a I ekhnologiya redkikh metallov (Chemistry and technology of rare metals), 79-83, :OPIC TAGS. niobium, titanium, nfobium purification, titanium purification, electrolytic -oduction, titanium reduction LBSTRACT: The authors investigated the possibility of separating titanium (ra) from qiobium V) in strong sulfuric acid solutions on the basis of the Increase in formation of an Insoluble itanium.(DI) compound with increasing concentratioa of the acid. A curve showince the yield -f precipitate versus acid concentration Is shown in the Enclosure. Analysis of thc~precipitata Jentified it as Ti 2(S04)3 2S04- 8H20. Solutions of 600 - 900 g/L H2S04 containing TiO2 nd Nb2O in proportions of 6:1, 4:1, 2-. 1, and 1: 1 were then used in experiments In which 6 he TiO -was precipitated in the above form by electrolytic reduction, while the niobium. re- aained in the solution. The process is Mustrated by diagrams. Orig. art. has: 6 figures Card, 1/3 *and 1 table. ACCESSION NR: AT4042097 n 12 8 ENCLOSURE: Oi- fVV 70V YOU YZ 5 04 214 Fig. 1. Decrease in the content of trivalent Ti inaDlution (in g/L) in relation to sulfuric acid concentration (g/L). The Ti0i, cont6nt In the original solutions was 18. 5 (1). and 3 9 (2) g/L. caid '3/3 AT, ACCESSION NR: AT4042098 8/2768/63/000/007/0086/0069 AUTHOR: Atilyutina, M. I., Sharova, A. K. 0 -TITLE: Fractional pro of titanium and niabium sulfates from aolutions of sulfuric Wacid SOURCE:. AN SSSR. Urallsidy filial. Inst.itut W ~imfi. Trudy*, no. 7, 1963. Khimiya I -tekhnologlya redkikh metallov (Chemistry and.technology'of rare metals), 85-89 TOPIC TAGS: titanium, niobium, tantalum, titanium purification, niobium purifidation, fractional prec~pltation, metal sulfate fractionation I ABSTRACT: 'A solution containing 245 g/L H- SO 48 g/L TIO 10. 25 g/L Nb 0and 2 3. 52 g/L Fe 0 was used in a study of the succesiVve precipita&4n of titanium obium in the form oi leir low-valence sulfates. - Titanium reduced electrolytically to Ti+3, was precipitated (as Ti (604)3 - H2604 -by adding sulfuric acid to the solution to-a 2 8H20) and Nb+ !'concentration of 800-900 g/L. The Nb+3' 5 remaining in the solution was then precipitated in the form of ammonium, sulfite-niabiate,, 2]'. 21H20, (NH4)8 "b603) (S04)1 C 7 ACCESSION NR: AT4042098 H., by adding ammonium sulfate to the aolution to a condbntration of 7. 5%. 98-99% pure Nb 0 with less than 0. 5% T102 was then obtained from the precipitate In yields or up to 2 71.Rby oxidation dryin,~ and calcining. 'Tantalum Is not conversiqA into hydrates , , preelpItated by the proceftre "The analyses'were carried out by Lhb. Asst. G. V. Milovidova. 11 Orig. art. has: 4 tables., ASSOCIATION: Institute k1himil, UrallsIdy filial AN SSSR (Chemical Institate, Urals, , Branch of the AN SSSR) A .% SUBMITTED: 00 ENCL: 00 IC,'IM BUD CODE.- NO REF~ SOV; 007 OTHER: 001 2/2 Card ACCESSION NR: AT4042099 2768/63/000/007/0101/0106 AUTHOR: Sharova, A. K., ghtin, A. P. TITLE: The behavior of niobium, and tantalum phosphates with respect to various acid. i -reagen ts SOURCE.- AN SSSR. Ukal'skly filial. Institut khtmil. Trudy*, no. 7, 1963. Kh1mlya I tekhnologiya redkikh metallov (Chemistry and technology of rare metals), 101-106 TOPIC TAGS: niobium, tantalum, n1obium purification, niobium phosphate solubility, tantalum phosphate solubility, selective extraction, oxalic acid, hydrogen peroxide ABSTRACT: The solubility of niobium and tantalum Ohosphates, alone and combbied, in 2.3-13.6 N H PO 22.5-81. 0 g/liter of (COOH)2, 6, 9, and 12 N HCl, 3, 18 and 36N H2 S04, and c&Xations of H2SO4 + 1-7 H,,O, or 4% (COOH) or HCl + 1-4% (COOH)2. was determined in order to explore the pos;flAlity of their sXctivo extraction from a mixture. The salts, separately or combined, were treated with a measured volume of solvent without heating, the undissolved residue was separated by filtration, and the filtrate Was analned for Nb and Ta. The two phosphates showed insignificant solubility in HQ. WIL. 1/2 q ~CCESSION NR: AT4042099 Although Ta phosphate Is much more soluble than Nb phosphate.in high concentrations of H3PO4, this could not be used for its selective extraction; in the other solvents and combinations, the Nb phosphate was more soluble. Addition of 1-7% H 0 to H SO 4 7 sharpl increased the solubility of the phosphates, but their weight raia I the ffitrate- y remained constant at about 11!10'.7. Selective. extradtion of moblum phosphate cculd be achieved only by treatment With a solution of HCI plus 1-4% (COOH)' in which Ta is insoluble, although with H SO + 4% (COOH),:the NIJ:Ta ratio In theilltrate was 133:1. 2 Orig. ar*t. has: 2 figures &d tables. ASSOCIATION: Institut khimffl Urallskiy filial AN SSSR (Chemical Institute, Urals Branch of the AN SSSR) SUBMITTED; 00 ENCL:- 00 NQ REP SOV: 008 UM C ODE: IC, MM OTHER: 008 ACCESSION 14R- AP4047787 5/02,89/64/000/002/0121/0126 U113La~ovaJ.A.; Bharov~~i A.K.. TITLE: nallium extraction from sulfu--ic acid solutions by means of methyl vinlet 11 S0U.-RCF: AN SSSR. SH rstmyp otdolenf.yn, Izventlya. Sartya khirnichoskikh nauk, no. 2. 1964; 1121-126 TOPIC TAGS- thallium extraction, Uiallium determination, methyl violet, quantitative analysis ABSTRACT: The reaction (in. v ~) 4 11 34- C I (m. v. )'11 C1 whore m. v. - vi t3thyl violet.- was used by the autliors aj a metahod of separating Lhallium irlum sotlltioJ13 of (:(?Mp!ey: compt-'s', res'441-nZ from di-~~-,Iving ;ubliniates of the nonferrous metals indupfry in ffo~SO - 0' 1 , - Inic pH of the solution, the thallium concentration, Ltle n-eLh'v1 violet consumect, ;und 0-'e. rate o1 precipitate sedimentation %k-erp th c f,) i 'Prip amount of mtmthyl vblk,t irt T.1 I 7 nc, j pq- < 7 in -iddidon tr > primiarfly arg~nnc slikslano,,ac and n,-nUrnony, plus insignificant amounug o1 raner ~'L-ink-nLz'. co. d L/i Caro 2, 2 H -6 t 1.. P -4 -UR/4 FAP AUTHOR: Chufarova, T. G.; Sharova, A. K. TITLE, -Niob and tantal%un arsenites -1-leorganic sl SOURCE: Zhurnal he oy khimii, v. 10, no. 4, 1965, 877-982 r;TOPIC TAGS: niobium arsenite, tantalum arsenite, inorganic slmthesis !ABSTRACT- Tn this work conditions were investigated for precipitation of niobium tantalum from sulfuric acid solutions with sodium arsenite. Niobium pentoxide containing 99.9% Nb205 and tantalum metal (99.9% pure) were used for making sulfate sniutions. Niobium and tantaIum arsenites were precipitated by the addition of a 3--,Jium :7- sl'fate solutiong containing a.-,talum an~ n:obium. On the basis of chemical analysis it was established that the composi- ~,-)e precipitate.-I ~.i*-,t`~,m arsenites may be expressed by the Cormulas 2Nb2OS -As203' SH20 and M2.05- As203 -BH20. LC.,d 1/2 L 522974-65 :ACCESSION NR: AP5009948 Keating curves display an endothermic effect at 1451C for niobium sait and at 1801C for tantalum salt an(! Exothermi-- e"!--ct-s at 7300C and 9450C for niobium arsenite an6 tantalum arsen--te T~)P endothermic effect is due to remc,,-), of water from the salt whiie vie exother-nic effect ocCu--s ~!ue to trans-iDn -he ~salt from the amorphous to the cr-Istalline state. Hydrochloric acid solutions with small amounts of oxalic acid as well as oxalic acid solutions containing potassium chloride possess some select4-vity with respect to nicbium arsenite. Using these s,~,!Iitions it is possible to obtain niobium solutions containing very little tanta- 11.1m or ~;Z, ig. ables and 5 figures. ASSOCIATION! none ~4; 77r.~;: 27NOV~~ rMCL. 00 SUB CODE: IC) &C, L 52373-65 FATW/ZP-F(n)-2/&WP(t)/W(b) Pu-h !jP(c) ACCESSION NF: A,500991"? TJR/0078/65"010/001-/0883/0888 AUTI~OR: -MilTatina, M. I.; Sharova, A. K.; Titova, Z. M. TITLE: Niobium arsenate SOURCE: Zhurnal neorganicheskoy khimii, v. 110, no. 4, 1965, 883-888 ,TOPIC TAGS: niobium compound, inorganic synthesis, arsenic compound, chemical reaction, precipitation, thermal analysis ABS-PACT: The precipitation of nio-hium ar-senate from sulfi-iric acid sC)L1ti:)r'S was h sr)(ji-jTr arsenalte. T- P;j-r -:,f r- ~: Q, S 7 -.2~ 5 'irs e n a T .of the Enc los ure I iZ -r~s 4~-r -'niobi-um-.-aret...Ze-are:.15Q-300 g/X of sulfuric acid; about 4% of Na2tiAsGo".111-.2- ticL; A6205 a IT624S.' lb-20). I I" Ag ng- of precipl ate:--fdr- -20- hrs-, - Hiobium arsenates are forn*d by reaction of sodium arsenate with nioblum In sulfuric acid as follows: (N-v07' ) ,.904 -11- Na:,q AsO. - (N401) ~HAsO4 + jNazS0, Card 11/3 L 52373-65 rACCESSION UR: AP5009949 ana-lysiS +he arsenates and interm.~Iate dehydration products -,c di"- ca,cj- 2/3- L 52373-65 A CC E: S So 1 ON AP 5 0 OTI: - 4 't u C time, hrs acid sol'utiors a-9 SlUaM.I., .. F. Sharovai, A. 1K. "On the rcl'~tlonship between L~10- structure and compcs!Llrn of Devoni,,,,n Bauxites of the Ural 11 Trudy Corno-geol. in-ta (Ak-nd. nauk SSSa Orallskly filial) p p Issue 14, 1948., p. 74-80 SO: U-3`5-)~ 16 June 53, (Letopis 'Zliur;.al Inyl-h Statey, No. 5, 191M. GLADKOVSKIYp A.K. : �WOVA, A.K.. VTORUSHIN,A.V. Turgay Straits-Petrology, Rocks-igneous Age of the igneous rocks in the central part of the Turgay Straits. Dokl. AN SSSR 83, no. 1, 1952 Ural'skiy Gosudarstvannyy Universitet Im. A,M. GorIkogo rcd. 8 Dec 1951 Monthly List of Russian Accessions, Library of Congress, August 1952. UNCLASSIFIED S03 Monthly List Lf Russian Accessions., Library of Congress, 1953, Uncl The AsWic CretwAous bawrite prcmictce. A. k. Glad- - k " d A K Sh i l d V N j S R - wi arova- a, . . ~ ddy.-I ok .- auk S.S.S.R. v - -Rprt b i so in f A m S -im s eraccous aux tes o swAlc , r Rwmia havo a pb%ilitie strurture. The little wealwed bauxite mcks con.6t of rM ernient and bla ck inagoetite -bt;us. The beans are built up with a finely di"r-ed lay of magnetite of scdhn~ntary c,rixlu. nanmd &-inagnetite. Four,varictfts of vibicrali are desiimated: A400.1-0~& I HA A400.7-1.3 H.O. AIP.J,4-21.3. 11,0- and At^.3- - UsO. The cheiti, wapit, of the bewls. the &beat, and the 'bawxite ii giveo. Another table gives the of tile CIZT inagnetic fractious.' It ~% amunied-Utat tt" ;' acjtnus; , bataltes are primarily a mech, and partly a chem. sedim6t~ ~~kineralogicxl composition of batixites from the lower Cre- PtaceouR Period in S.S.S.R. X77. , a kovskil suid A K IMI,316 Dakfad Akad 89 151- Nauk S S S R . . . . . , y _g~ , (1) of the lower Cretaccous Period himul in . U.S S.R. are composed of black magnetic pisolites (11) held together by a rerlokh brown norunahnctic cement (111). Oicin. and v)incr.%IoXicnlrf)mpni. of 11 and IH were tietti.and the results showed that flawd Ill were fornuxl undcr different physiro-chem. conditinns and that 11 are rimlly Ixtoxite pebblex brought - to the I-Jact! of formatIm of I by cortalu forces. Efixthet'i Mimbash 911 geov Olt 9p. Ne og?"'W; V. 9 -%O601 sooe,. -IAO* -10 0l 8:08 G.,L. ee -100 IP-49 t4 at$ leic, -0-0 VIVO- twe VLOS Vo C vplw~ k. 2 L I e OV6 tAC 1 Cs ce ajo- 110 *. - - ses-OlL . COO' we for ~a, ;~~v k, ev 0,0 dovP COO so-tu 1,9~5 tsVIP eviel IV b1 Tec~lo 1DOC~~ TO 0f a CeS t stsopl ti-StI6, tueo tis eels Ve "e ext"clo S. ~Ooiool .11006 &Joe-as ~ Von Orr ae& as .ST, ava IN -gsr~taa wa,~o cvat spo vodw- tve eetto O'So Ue 00& j.31 toor5p tip-, Coal tee Ne I jj3o I - oirttl I T 'bsV-a ~~q tj~~o te (, ou r4,es Lee, me oTiov, aw Teo GO 2 jSOMP -refG coq~--C-bog,~, -0 etAe '0., 6 t SO 01 a oclou o VST se OT19~1 tUe Leu CIO OVA - et C~aose yTev L jjt~ W~~s 50 eas d sovae 01:i sa ol V ,Ole to' is, -lg~o OT A's OV, aa,cle .8*6. CIA vr SeCIN Ole" t Mineralogy and Origin of Bauxites *TABLE OF 0 Foreword PART I. MMMMM OF BAEMMS Mineralogy of Sedimentary Bauxites (S.1. Beneslavskiy) 1. History of mineralogical investigations of bauxites 2. Alumina-containing minerals 3- Silica in bauxites 4. Iron-containing minerals 5, Calcium In bauxites 6. Magnesium in basixites 7. Titsmi- minerals 8. Sul:16r minerals 9. Phosphate minerals 10. Sodium and potassium in bauxites 11. Trace elements in bauxites 12. "Lode facies" in bauxites 13. Some problems of mineral formation in bauxites 14. Genetic classification of sedimentary bauxite minerals SOV/1254 3 Card 2L3.4- Mineralogy and Origin of Bauxites SOV/1254 Bibliography 49 The Origin of Aluminabearing Minerals in Bauxite (K.F. T*rentlyeva) 52 Bibliography 69 Mineral Composition, Origin and Metamorphism of lAwer Cretaceous Bauxites of the Eastern Slope of the Urals and the Turgay-Plains --(A.K. Sharova and A.K. Gladkovskiy) 70 Bibliography 71 PART II. GMWRAL PROBIM ON THE ORIGIN OF BAUXITES A.D. Arkhangellskiyls Theor7 on the Origin of Bauxites In the Light of Modern Science (G.I. Bushinskiy) 83 Bibliography 91 Regularities in the Dlistril~utl:on of Bauxite Deposits and Conditions Under Which They Were Formed (Yu,K.Goretskiy) 93 Card 3yt]4. - t- - j -A - Structures of Ural Paleozoic bauxites. mat.po geol.i pol.1skop. Urala no.6:91-102 158. (kam 12: 10) (Ural Mountains Ilauxite) S',ii-LOVA, A. K. i- :Y, A. X. Imegtones and 11,s Importance in prospecting for Ural 1;mrorijim ~,,Ixjteo. Mat.w- pnj.lslOp.Urala nO.6: 103-11.0 158. (AIRA 12:10) GLELI)KOVSKIY, A.K.; SH&ROTA, A.K. Minerals framed during the weatberirg of bauxites in the Southern Ural Basin and their role in the geophemistry of bauxites. Izv. vys. ucheb. zav.; gaol. i razv- 3 no-7:130-1~4 J1 160. (MIRL 13:9) 1. -Sverdlovskiy gorWy institut. (Southern Ural Basin-Bauxites) GLADKOVSM, A.K.; SHAROVA, A.K. Regularities in the COMP00ition W Abftation of bwnite deposits I in the Urals and the Turgay Maui. Troy 416r.-geol. inst, UFAN SSSR U00582169-205 162, i (MIU 15t12) (Ural Nomtains-Rumite) (Turgay Tabileland-Ilauxite) GLADKOVSKIY, A.K.; SHAROVA, A.K-. - nm-- ,riassicn bawdtes on the eastern slope of the Urals. Dokl. AN SSSR 151 no.6tl420-1423 Ag 163. (KIRA 16ilo) 1. Institut geologii Ural'skogo filiala AN SSSR. Predstavleno akademikom D.I.Shcherbakovym. SHAROVA, A.K.; RUDNOVA, M.Ya. Strigovite from the Southem Ural bauxite baBin. Trj&f UFO SSSR no,64:59-64 164. (MIRA 17:12) ---- - --- - - - -- - - - - - --- - - ---- GLADKOVSKIY,, A.X.;_�_W0YA-k KHRAMTSOV# V.N. Characteristics of the composition, origin, and char-ges of Yesvzoic and Cenozoic bauxite deposits in the Asiatic part of the U.S.S.R. Trudy Inst.geol. UFAN SSSR no.64:3.27-166 164. (MIRA l7sl2) OLADKOVSKIYr A.K.; SHAROVA, A.K. Significance of the facies primary and oecordar7 characteristics of bauxites in forecasting. Trudy Inst.geol. UFAN SSSR no.64:167-176 164- (MIRA 17:12) GLADKOVSKIY, A. K.; SX~40YA_, A. K. Bauxi-te potential of the Lower Mesozoic sediments of the eastern slope of the Northern Ural Mountains. Izv AN SWR Ser ggeo-- 29 no. 5: 67-75 MY 164. (MIRA 1. Institut geologii Uraltskogo filiala AN SSSR, Sverdlovsk.