SCIENTIFIC ABSTRACT SHAMSHEV, V.N. - SHAMSHUR. V.I.

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Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R001548310004-5
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RIF
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S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
August 9, 2001
Sequence Number: 
4
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Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
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L 27364-66,APEWT(I)/EWT(-m)/F.WP-(J-),. IJP(c)--.,VM/GG/RAt.-. AM-Mr.-- 6o1155,3 SOURCE CODE: U]1/0051/66/020/00~/0424/0426 - AUTHORS: Alfimov, ~1. V. Buben, N. Ya Pristupa, A. I.; ! Shamshpy, V. N. ORG: none ITITLE: Determination of the concentration of organic molecules in. ithe triplet'state upon excitation with fast electrons ISOURCE: Optika i spektroskopiya, v. 20, no. 3, 1966, 424-426 !TOPIC TAGS: electron paramagnetic reconance, electron bombardment., !electromagnetic wave absorption, line width, absorption probability nonmetallic organic derivative., iABSTRACT: Tbis.is a continuation of earlier work (DAN SSSR v. 156., i630, 1964 and earlier) in which it was shown that the method of.elec-,-.~ agnetic resonance~lcan be succes6fully used to study triplets ,tron param I states of organic molecules excited by bombardment with fast electrmsi ~To improve on the accuracy of the results, t~e authors determined !experimentally the ratio of the probabilities of absorption of a Card L 2736"6 ACC NR:-' AP6011-553 CR Imicrowave quantum for the transition with Am + 2 to the transitions with Am = + 1, by investigating the stationary concentrationsof 110 D mole-cules in the triplet state and the kinetics of their ac- 10 8 1 Icumulation at different irradiation dose intensities. The sample_ 1preparation and their measurement technique are briefly described. lIrradiation of a solid solution of C D in polystyreneat 100K pro- 10 8 1.duced a single paramagnetic absorption line at a field 5927 Oe (f :9205 Mcs), the line width between maximum slope points was 7 � Oe. t !The probability ratio was determined by determining the stationary. !concentration of the molecules by comparison with a'standard. In iaddition, the kinetics of accumulation of C D o ecules in tb i 10 8 M~t Itriplet state following irradiation with TasE e-1 rons was measure :by the procedure used in the earlier investigation. Expressions are Igivenfbr the stationary concentration and for the characteristic ac- !cumulation time, which agree well with the experimental data. The ;experimental value of the probability,ratio ( %,22) is much larger ithan the theoretical value It is shown further that by using Card L27364-66 ACC NR: Ap6oll553 the EPR method to determine the characteristic accumulation time and the lifetime of the molecules in the triplet state after cessation of the irradiation it becomes possible to determine the molecule concentration in the triplet state without involving the probability- ratio coefficients. In view of the uncertainty of the actual value of this coefficient and this disparity with the theoretical value, the elimination of this coefficient is considered an advantage. The authors thank I. V, Aleksa]2dr v, V,, L. Yermolayev, and K. K. Pukbov for a discussion of the results. Orig. art.*bas: 2 figures and 6 formulas. SU13 CODR: 20/ SU13M DATE: IlJan65/ ORIG REP-. 004 Card .313 --------------------- Do ne-, Lng wit li 12ar;. 4s Formatfc.n cf de-ai-Is in the J IDeS C" fo-,. -CQ02-213 S/1 17/62/~/O 11/002/002 A004/AlOl AUTHOR- Shamshin, A. P. TITLE: Milling cutter for machining heat-resistant and titanium alloys PERIODICAL: Mashinostroitel! no. 11, 1962, 29 TEXT: In forging and die-forging blanks of heat-resistant and: Ti-alloys, surface cracks appear, which makes it necessary*to increase the machining allow- ances. In the roughing of blanks with a machining allowance of 10 - 30 mm, the milling cutters used cause the machine tool to vibrate at cutting depths of more thim 10 - 15 mm. The Innovator V. G. Gulynin has.suggested a milling cutter hav- a ing a lead angle o