SCIENTIFIC ABSTRACT SEVERNYY, A.B. - SEVERNYY, V.V.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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The Spectroscopy of Solar Flares With an Echelon Grating 78oo4 SOV/33-37-1-4/31 Is Card 2/11 Fig. 2. Diagram of the spectrographi with an echelon grating. Figure 2 shows the design where S is the slit; Ml, thE collimation mirror; E, the echelon; P, a prism; and G. a grating designed to spread the spectra of various orders in a direction perpendicular to the plane of dispersion; 14 , the camera mirror; C, the plate holder; and I is a mir--,-or compound which corrects the plane of atmospheric dispersion. This instrument The Spectroscopy of Solar Flai,eu 1,41th an 7 8 0 C-) L' Echelon Grating SOV/33-37-i-4/3i Card 3/4 is practically free from Rowland's "ghosts" and from scattered light. It is uzed for a simultaneouj photography of the whole spectrum of short duration flares and "whiskers", while previously such photo- graphs could not be obtained simultaneolisly. With exposures from 0.5 to 1.0 seconds, the spectrum is well exposed over the range from 3,200 to 6,6oo A. During the suimner of 1959, over 30 flares were photographed; three of these are reproduced here. The spectrum of a'flare near the solar limb obtained on Au ust 30, 1959, showed 11 emission lines of He; over ~50 emission lines are shown on a photograph taken on August 17, 1959; theze are listed in a table which indicates the intensities of the lines and of the same lines in Rowland's catalogue. The authors express their appreciation to F. M. Gerasimov who suvulled an excellent copy of the echelon grating. T'here is 1 table; 5 figures; and 4 references, 1 Soviet, 3 U.S. The U.S. references are: J. T. .,-SEVERNYY. A.B.: SHABAITSKIY, V.P. Generation of cosmic rays in flares. Astron.zhur. 37 no.4: 609-615 Jl-Ag 160. (MMA 13:8) 1. Krymskaya astrofizichaskaya observatoriya AN SSSR i Hauchno- iBBledovatellakly institut yadernoy fiziki Moskovskogo gosudarBtvennogo universitata. Oolar radiation) (Cosmic rays) SEVERNTY.. A.B. Generation of flares with the growth of solar magnetic fieldo, Aotron, zhur. 38 no.3t402-408 W-je 161. (MM 14:6) I* Krymakaya astrofizicheskaya observatoriya AN SS&L (Sun) AUTHOR: TITLE: 22107 S/035/61/ooo/oo3/034/048 AOO1/A1O1 -Severnyy,..A.B. An Investigation ot' magnetic fields connected with flares on the Sun PERIODICAL: Referativnyy zhurnal. Astronomiya I Geodeziya, no. 3, 1961, 53-54, abstract 3A455 ("Izv. Krymsk. astrofiz. observ.", 1960, v. 22, 12- 41, Engl. summary) TEXT-.- The task of this investigation was to check the conclusions arrived at by the author (RZhAstr,,, 1959, no. 5, 3659) on the origination of flares in field neutral points and on annihilation of magnetic fields by flares in their vi- cinities. Twenty records of magnetic fields of active groups'were taken by means of an essentially improved solar magnetograph (RZhA'str, 1959, no, 8, 61359; 8 of them provide information only on the location of the flares and 12 enable one, in addition, to judge on field.changes during flares. Field recording wa5 made in line)-4886 (Fe I) and sometimes in this line and in the H line. The problem of calibrating the field of both of these lines is considered. There is a similarity in the general pattern.of field distribution in H Oand ;~48W, especially above the groups of sunspots, although noticeable differences are observed in details. Card 1/3 22107 s/o-i5/6i/oco/oo3/034/o48 An investigation of magnetic fields ... A001/A101 The comparison of location of the main, most intensive flare seats at instants of their emergence with locations of neutral points, made for 61 cases, shows that in 46 cases flares practically originated in neutral points, In 8 cases differences in the locations of the flare and the neutral point might be due to errors, and In 7 cases they are beyond the limits of error but may be connected with absence of knowledge of the field topography and with different altitude of flare formation from the photosphere. Flares were never observed in the regions of magnetic poles, or on the neutral line far from the strong crossed fields, The correspondence be- tween locations of flares and neutral points is improved, if the field is consider- ed which is recorded in the very nucleus of HP pertaining to the chromosphere, In- tensity of fields in the chromosphere, in the limits of the active group, is of the same order as in the photosphere. A comparison of charts of magnetic fields made prior and after (sometimes also during) flares shows that after flares magnetic fields are simplified and In the vicinities of flares (neutral points) are annihilat- ed (individual poles disappear or recess far aside, neutral points disappear), and field gradient decreases. Field gradients in the flare regions amount usually to 0 Me 4- VeS from/--jO,02 to 0,1 gauss/km. Bright filaments emerging during devel p n. of fla tend to align along (or parallel) the neutral lines. An interesting case of or-4;;i- nating a flare along a closed neutral line is also noted, which is interpreted as Card 213 22107 S/o35/6i/000/00_3/0,34/048 An investigation oil magnetic fields... AOOl/AlOl pinch-effect appearing during the breakthrough of a tube of one polarity into the region of strong field of' the other polarity. Thus the present work confirms all the main conclusions drawn earlier. There are 10 references, Author's summary [Abstracter's note: Complete translation] Card 3/3 ILI J-1> 22108 -5/0.35/61/000/00)/035/o48 AQ01/A1O1. AUTHOR: Severnyy, A.B. TITLE, On non-stationary continuous emission of flares PERIODICAL: Referativnyy zhurnal. Astronomiya i Geodeziya, no.-3, 1961, 5-4, ab- stract 3A456 ("Izv. Krymsk. astrofiz. observ.", 1960, v. 22, 67-74, Engl. summary) TEXT: The author shows that non-stationary continuous emission of flares and nuclei of continuous emission can be considered as a long-wave tail cf the brehmsstrahlung of fast electrons originating near the neutral region (H=C) at pinch-effect in flares. EAtrapolation of emission distribution energy from the visible region of the spectrum to the region of X-rays leads to values in agree- ment with data of rocket measurements. The number of fast electrons necessary for the observed emission is eatimated (,;,,0.1% of the total electronic density), and it is shown that if these electrons start from the Sun's atmosphere, their density at the Earth's surface will be within the limits froml,_~O.j to 102cm-31 There are 7 references. Author' s sum;-mary [Abstracter's note: Complete translationi Card 1/1 4 6 /S-;9L Z) AUTHORS: TITLE:. 22388 S/035/61/000/005/021/04 2 AOO1/AlO1 aposhnikova, Ye.F. Severnyy, A.B Sh Dynamics of limb flares on the Sun and pinch-effect PERIODICAL: Referativnyy zhurnal. Astronomiya i Geodeziya, no. 5, 1961, 54, ab- stract 5A356 ("Izv. Krymsk. astrofiz. observ.", 1�60, v. 24, 235 257, Engl. summary) TEXT- Of 180 H4 pictures of limb flares 25 were selected and 14 of them were subjected to a detailed quantitative investigation. It has been discovered that most flares over the disk edge have the appearance of a bright hill (often with a conical top) the frort side of which rapidly extends and then contracts. These extensions and contractions are non-uniform (their speed varies from 50 to 600 km/sec); sometimes they have the nature of pulsation C rrespon5 ing accelera- tions of motion of the front side are very high cm/sec ). There (5 x 10 10 is an analogy with reverse ejections, although extension of a flare proceeds con- siderably faster (on an average 3 min). Altitudes.attained by the front side are no more than 50,000 km, and the brightness is the same as in flares on the disk. Extending and contracting of a protrusion proceeds practically synchronously with Card 1/ 2 22388 S/035/61/000/005/02i/042 Dynamics of limb flares on the Sun and pInch-effect A0011AI01 the change in the area of the flare bright region. Cumulativeness of protrusions is especially characteristic (formation of a conical top or tips), which excludes the possibility of interpreting the flare as a plain non-cumulative explosion and its subsequent contraction. It is also shown that the growth of the front separa- tion from the initial flare nucleus proceeds with time faster than at nuclear ex- plosions. Simple calculations show that liberation of thermal energy during flares must amount to rilo3 erg/cm3 see in order to assure observed accelerations on ac- count of expansion. If this energy arises at the expense of a magnetic field, then it is sufficient to destroy a field ofr,-.,100 gauss (e.g. at pinch-effect) to cover these energy losses. Cumulativeness of explosion-like protrusions in flares and, possibly, motion along the channels can be generally explained by geometry of crossed magnetic fields surrounding the flare which arises in the neutral point of such a field as a result of pinch-effect. The high-temperature plasma of the flare is in these cases in magnetic traps. The plasma tends to get out of the trap or to expand in directions of least resistance from the surrounding field. Fields of about 100 gauss are sufficient lest the flare should pass across the field. Cur- rent arising in a neutral region at pinch-effect is subjected to electrodynamical acceleration which can attain the observed values at surrounding fields of,_/100 gauss only. There are 14 references. Authors' summary [Abstracter's note: Complete translation] Card 2/2 AUTHOR: TITLE: 22384 S/035/61/000/005/ol7/042 A001/A101 Severnyy, A.B. Some features of plasma motion in solar magnetic fields PERIODICAL: Referativnyy zhurnal. Astronomiya i Geodeziya, no. 5, 1961, 53, ab- stract 5A349 ("Izv. Krymsk. astrofiZ. observ.", 1960, V. 24, 281- 292, Engl. summary) TM: A magnetic field of about 60 gauss was recorded in the chromosphere over the disk edge, near a sunspot, by means of a solar magnetograph (in the H~ line); simultaneously were recorded radial velocities in the chromosphere and in- tensities of the center of the H~ line. The analysis of these records has-shown ,that gases of ~he chromosphere flow into the sunspot approximately along the force lines. At the same time, records of radial velocities in the sunspot nuclei in- dicate, as a rule, the flowing of gases from the nucleus. The analysis of simul- taneous records of the field and radial velocities in the sunspot groups shows that neutral field points are practically always (in 30 cases out of 37) loca- ted on the neutral line of the velocity map where radial velocities are oppositely Card 1/2 2Z384 3/035/61/000/005/017/0112 Some features of plasma motion ... A001/A1O1 directed. It is shown that the concept of fluxes moving towards each other to the neutral point corresponds statistically to observational results. Some con- siderations are presented on the field geometry in sunspots and neutral points. There are 10 references. Author's summary [Abstracter's note: Complete translation] Card 2/2 38809 S/035/62,1000/006/015/064/ AOOI/AIOI ,AUTHORS: B !~?val 1, A. N. TITLE: investigation of broadening of emission of flare strong lines and whiskers.I. I PERIODICAL: Referativnyy zhurnal, Astronomiya i Geodeziya, no. 6, 1962, 55-56, abstract O'A414 ("Izv. Krymsk. astrofiz. observ,", 1961, v. 26, 3-40, English summary) T--,',.'f- Profiles of emission wings in whiskers and an-eruptive flare over the limb are analyzed. It was found that distribution of_~mission in the wings of %..,hiskers and in the eruptive flare over the limb cannot be explained by the Stark effect. although in nuclei of strong hydrogen lines-the Stark effect may play a marked role. Distribution of the form e_'~ AA also does not satisfy the. observed distribution of emission in the wings of whiskers and eruptive flares; fair agreement with observations, which is s6metimes obtained, may be due to poor image quality, tremors of the image in the slit, and low resolving power. Doppler emission distribution shows good agreement with observations in all cases considered. The authors discuss the possibility of representing emission Card 1/2 S/035/62/000/G06/015/064 Investigation of broadening ... AOOI/AIOI of whiskers and wings of flares as emission arising in a comparatively cold jet with a constant velocity gradient, which was formed during a contraction or expansion of a flare. In most cases such a concept agrees with observations U even better than Doppler effect. Mov,,iment velocities of these jets 300 krq/ sec) turn out to be of the same order as mean observed velocities of extension and contraction of flares on the limb. In individual cases the best agreemdnt with observations is shown by Doppler broadening due to macroscopic disorderly movements at speeds of -1100 km/sec, The analysis of profiles of emission of an er-aptive flare on the limb presents a rather complicated picture of comparatively slow movement of the protrusion as a whole and more rapid extension of a region giving rise to broad emission. Superposition of emission in such a multi-step movement is fairly well presented by Doppler distribution. the analysis of ernission of metallic lines warrants the conclusion that it can originate in the chromospheric region surrounding the "nucleus" of a flare or in a region in Which originates strongly broadened hydrogen emission. There are 20-references. Authorts summary FAbstracter's note: Complete translation] Card 212 39U5 S/058/62/ooq/oo6/oi6/136 AO61/A1O1 AUTHONS: Severnyy, A. B., Shabanskly, V. P. TITLE: The mechanism o:r'solar flares and of the gpneration of cosmic rays in them PERIODICAL: Referativnyy zhurnal, Fizika, no, 6, 1962, 52, abstract 6B366 ("Izv, Krymsk. astrofiz. observ.", 1961, v. 25, 88 - 113, English summary) TEXT- The compression of a plasma around the central point of a magnetic field can be related to the pinch effect arising under free-field ccnditions when two power tubes (possessing, e.g., a force-free field) are approached and their azimuthal fields are mutually canceled. The possibility of this kind of compression in the case of a rapidly changing field of sunspots is considered. The authors come upon the representation of strong shock waves converging at t-he neutral point. In the vicinity of the latter (at distances of X4~-- lo7 cm), the incident shock wave does not appear as hydromagnetic, and its front out- 5trips the motion of the magnetic wall. After reflection in the neutral plane, Card 1/2 The mechanism of ... S/058/62/000/0co"/016/136 061/Aiwi the front of the reflected wave moves about in the compressed plasma, and the more or less stationary high-temperature region forming behind it draws its energy from the magnetic energy required for the plasma compression. The front of the reflected wave, in interacting with the magnetic wall, may slow down or stop the motion of the latter, so that compression may be replaced by expansion or pulsations, which is also observed in the flares. Thermonuclear reactions take place in the hot region behind the flont of the wave reflected from the neutral point. It is shown that fragments of these reactions (chiefly protons) with energies of the order of somp mega-electron-volts, being reflected from the magnetic walls converging tc t~a neutral point, are accelerated to energies of - 10 Bev. LAbstracterts note: Complete translation] 1, "ard ?,/2 MUSTELI, Evalld Rudollfovich; GELIFGAT, B.Ye., red.; AMBAMSUKYAN, V.A., red._;_~~~B ,red.; SOBCLEV, Y.V., red.; KRYUCHKOVA, V.H., tekhn.red. [stellar atmospheres] Zvezdnya atmosfery. Red.kollegiia: V.A.Ambartsumian i dr. Moskva, Gos.izd-vo fiziko-matem. lit-ry, 196o. 444 p. MiRA 14:2) (Stars--Atmospheres) 99VEM, A. B., SHAPOSHNIKOVA, Ye. F. "The Dynamic of Limb-Flares and Pinch-Effect." Izv. Krym. Astrofiz. Obser, v 25 f-11144-5 VM" jj~~OQJ. The H -film of 14 limb-flares are measured. It was found that in most of the casesll~imb-flares appear in the form of brilliant hill wLth conical top, which undergoes to dilatations and contractions. The Vsations sometimes were observed, The velocities :)f dilatations are up to and accelerations reach 10'-'-100 cm 2. 450 Stre sec The formation of cone like top of flare is explained by the geometry of crossed magnetic fields (cusped field geometry) surrounding a flare which appears in neutral point of such a field as result of pinch-effect. 35076 b./7j 12 '60/023/000/01, 0/014 is - D 2 X-5 01 Sevcrr1yy,_ .1. B. TI T L -E' An eqt-imate o1' the ultraviolet emission of solar flares in the resonance lines L , He I anI He II jOURCE: nauk SSSR. Xrymskaya zistrofizicheskaya obser- VUtJriya. IZVeStiyL, v. 23. N,Oocow, 1960, 311-321 T T Continuing earlier work the author givas calculations of the 0 -d intensities of the above three Lines. It is estima- profiles all I t-ed that the intensity of radiation in the th:_-ee lines at the boun- dary of t1,.e atmosphere is as follows: (ergs/cn2 sec) Tem-D. of flare Hle I,/~584 He II, A304 H, 41215 10,000 2.9 x 10-10 0 0.11 25,000 5.8 x 10-4 -0.1 5.5 Card 1/3 :)~0/023/000/010/014 S/7 ly .,',,n estim:,.te of . . . D218 301 The -eieral conclusion is -LIhat an a~~,preciablE increase in the radi- ation emitted by the sun in the region ~~klOO-121522 can only be ex- Pee-L,ed in the L radiation of hydrogen and the /1304 he II line duri),11:1.- the aj.)earance of flares of importanec. -reater or equal to 2 and occupying a considerable area. This rac.iation is variable: C, Ln L it :,ay continue throuSI-out t1le lifetimu of the flare (4 1 5) and it" is probable that it occurs !ai-;h a certain delay re- lative -,lo t-l,e F, . Secondly, in theA304 line the radiation is most a_ ol,obably eL-iitted durin.- thie "lash phase, whell., 'the emission in the helium lineo is at its maximum (duration -10'). The increase in 'U'-,-,e emission in -he 130i-, line, which is ind-I.,ated in -'U-he table, is very mucIi -reater than the normal level of t'iis emission from. the solar corona. Accordin;, to G. 'E'lwert it shouLd not be more t-han. U 10-2 e-z/c-.12 sec. The present results are saLd to be consistent aith r,)cket experJments reported by E. Tousef. There are 4 figures, Car~- 2/3 I S/712/60/023/000/010/014 i%.Ti eot-i'mate of ... - D218/D301 4 tables and 12 references: 5 Soviet-bloc, and 7 non-Soviet-bloc. Th,e referenice to the En-lish-language publication reads as follows: tz) - 0 C. 7,1.kllen, Astrophysical Quantities, 1955, Univ. of Lond6n, �28. SUBEITTIS'D: April, 1959 Lk Card 3/3 - SEMNf Y,..A. 6 - Solar physics. IUn.tekh. 4 no-3:14-18 Mr 160. (MIRA 13:6) - I 1. Direktor Krymskoy ob-servatorii, chlen-korrespondent AN SSSR. . (S=) , I SEVERNYY, Andrey B. ,1, tt&port of the Crimean Astrophysical Observatory: (1) Spaceship satellite investigation of the helium ,-k-304 line emission on the sun, and (2) Radiation danger of solar flares and methods of its prediction" report to be submitted to the 13th Intl. Astronautical Congress, IAF, Varna, Bulgaria, 23-29 Sep 1962. 3 09, S/033/62/039/002/011/01'k E032/E314 AUTHORS: Butslov, M.M., Kopylov, I.M., Nikonov, V.B., Severnyy, A.B. and Chuvayev, K.K. TITLE: Experiments in electron-optical photography of galaxies in hydrogen light using the 2.6 m reflector of the Crimean Astrophysical Observatory Pr-RIODICAL: Astronomicheskiy zhurnal, 4. 39, no. 2, 1962,- 315 - 322 + 3 plates T&XT: Detailed studies of extragalactic nebulae require t4e use of large telescopes. As regards detecting apparatus, the use of ordinary photographic techniques in conjunction with narrow-band filters necessitates long exposures and is therefore inconvenient in practice. The authors have investigated therefore the possibilities of image-converters as a means of avoiding these disadvantages. An image-converter was set up -in the direct focus of the 2.6 m reflector of the Crimean Astrophysical Observatory. The immediate object was to investi- gate the hydrogen emission in a number of galaxies. Four'. light colour filters were introduced in front of the converter and Card 1/3 S/033/62/039/oo2/011/014 Experiments in electron-optical ... E032/r..,.314 the screen of the latter was photographed by a motion-picture camera. Altogether 58 galaxies were photographed in N a and other light. Photographs of 10 of these are reprodlLced and their features are described (Ncc 6o4, .1-569, 4214, 44119, 4490, 4736, 5194, 5457, 6822 and 6946). Many un1mown clouds of hydrogen- emission -wrere detected in the galaxies. In many cases there is no correspondence between hot-star clusters and :,3-drogen clouds. The hydrogen component shows greater conccn- tration in the equatorial planes than the stellar component. In some galaxies the nuclei consist of isolated condensations. The dimensions of the nuclei in H light are in some cases a appreciably largerthan in other light, although in a number of cases the reverse situation obtains. In sereral galaxie.~3, streams or ejectibns from the nucletis, which are visible only in H a light, were detected. Card 2/3 ........ SEVERNYY A.B. Some characteristics of mkgnetic fields comected with solar flares. Astron.zhur. 39 no.6:961-964 N-D- !62.(MIR-A 15:11) 2. Krymskaya astrofizicheskaya observatoriya MI SSSR. (Magneti# fieldo 4Cosmic physics)) (Sul) 43545 S/033/62/039/006/008/024 E032/E414 AUTHOR: Severnzy, A.B. TITLE; Instability or a layer of plasma with a netitrn] magnetic field point PERIODICAL: Astronomicheskiy zhurnal, v.391 no.6, 1962, 990-995 TEXT: It is noted that there.nre two hypotheses as regnrds the generation of flares, namely the flares appear spontaneously as a result of the instability of:a free fj.dId frozen into the solar plasma, or they appear as n-result of the effect of external fields. e.g. sunspot fields, which give rise to a contraction of the plasma. In order to throw further 1-ight on these mechanisms, the author considers the stability of a plane-parallel plasma layer lying between the planes x = -xo and x = +xo in which the field increases linearly with distance from the x = 0 plane at which H = 0. It is assumed that the density and pressure insid6 the layer are symmetric functions of x and the space outside the layer is evacuated. The conductivity is assumed to be infinite, the displacement current is neglected and the line of force are assumed to be straight and parallel during the motion. The Euler equations for small displacements are solved and it is shown that Card 1/2 S /0 3 3/62/039A)06/008/o2 4 Instability of a layer ... 1`1032/E414 instability can appear if the exterrial fie'ld decreases with distan6e from the layer. The above three restricting AssumRtions are then relaxed and the analysis is repeated in the case where the field. the pressure and the densityinside the plasma layer are of the form H 11 x P X2 y 0 1 P P0 ir -z x X- 0 0 while the field outside the plasina is fly = const flo. It is shown that this type of layer is unstable. It is argued that the stability considerations r eported by S.I.Syrovatskiy (Astronomichesiciy zhtirnal, v.39, no.6, 1962, 987-989) are incorrect owing to an incorrect formulation of the problem and unacceptable assumptions. There are 2 figures. ASSOCIATION: Krymskaya astrofizicheskaya observatoriya AN SSSR (Crimean Astrophysical Observatory AS USSR) SUBMITTED: July 5, 1962 Card 2/2 GURZAIJYAN, Grigor Ararrovich; AINBARTSTUWAN, V.A., red.; MUSTELI, E.R., red.; SEVERITYY, A.B., red,; SOBOLEV, V,V., red.; KULIKOV, G. S. , re-&.-;-- bRUD I -K, tekhn. red. [Planetary nebulae]PI-enetarnye tumannosti. Moskva., Gos.izd-vo fiziko-matem.li-t--ry, 1962. 384 P. (MIRA 15:9) (Nebulae) I. 45123 S/712/62/027/000/003/015' 1. 0 A001A'01 AUTHORS: Babin, A. I., Luk'yanov, S. Yu.,. Severnyy., A. B., Sidorov, G. G.0 Sinitsyn,'V. I., Steshenko, N. V.-- TITLE; An investigation of hydrogen lines broadening in a powerful pulse discharge ms SOURCE: Akademiya n4uk SSSR. Kry kaya astrofizicheskaya observatoriya. Izvestiya, ~,. 27, 1962, 52 - 70 TEXT-. Emission hydrogen spectrum of solar flares shows a great similarity. with the spectrum of high-temperature hydrogen plasma glowing in a pulse dis- cha~ge of high intensity. Therefore, the latter spectrum was investigated in thepresent study by methods used in studying physi cal processes on the Sun. At first the problem of broadening of hydrogen emission is 0onsidered. The-equip- ment used and the methods of carrying out measurements a~e described in detail. Discharge was studied with the aid of a spectrograph with a diffraction echelle- grating (dispersion nil.5 R/mm). The main results of the spectrophotometric study of broadening of hydrogen emission (H.,, - H wings are as follows: 1) The Card 1/3 S/712/62/027/000/003/015 An investigation of hydrogen lirie~... 'A001/A101 emission of hydrogen line wings"(extending to 30- 40 when observed in the spectra of a self-constricted pinbh perpendicular in direction, turns out to be broadened due mainly to the linear Stark-effect (at the initial pressure po = 0.1 mm Hg); 2) at po = 0.5 mm Hg the emission extends to 50 - 80 R and is broadened in the wing, probably-due mainly to the quadratic Stark-effect; 3) when the spectra are observed along the plasma pinch, the broadening of hydro- gen emission in the wings of the lines is 8due to macrosoopic motions of the plasma with velocities of the order of 10 cm/sec. The intemity variations in the wings are well explained by the hypothesis on the jet-type plasma motion directed along the discharge axis with velocity gradients; 4) when the spectra are observed outside the axis of discharge, the broadening of hydrogen emission (at po = 0.1 mm Hg) Is entirely due to the linear Stark-effect in both trans- versal and longitudinal direction (next to the-pinch). The mechanism of hydro- gen emission broadening in a powerful discharge is similar to broadening of emis- sion lines of solar flares. The variation of intensity in the line wings de- pends essentially on the direction along which the spee-;:r= of plasma emission is observed. It is concluded that the analogy between the powerful.pulse dis- charges in laboratory conditions and the phenomenon of chromospheric flares on Card 2/~ S/'[12/62/027/000/003/015 An investigation of hydrogen lines... A001/A101 the Sun, is based on the close physical essence of both phenomena. There are 12 figures and 2 tables. SUBMITTED: may 1961 -ard 3/3 45124 S/712/62/027/000/004/015 AOO1AlOl AUTHOR: -tseverpy_v~ A. B. TITLE: Nonstationary processes in solar magnetia fields (The generation of~. flares, heating of faculae) SOURCE: Akademiya nauk SSSR. Krypskaya astrofiziches,kaya obse~vatoriya. Izvestiya. v. 27, 1962, 71 - 109 TEXT: The present article is a continuation of the author's studies of magnetic fields related to flares, carried out in 1958. The initial concept of generation of solar flares is complemented with an.investigation of slow pro- cesses of heating and contraction of the solar plasma,'which are of importance for the explanation of solar faculae. The studies of magnetic fields related to solar flares show that the latter arise where magnetic polarity changes its- sign. The observational data indicate that the surrounding field changes in in- tensity, gradient and magnetic hills from the sta.~ preceding the flare to that following it, although in the region of flares proper no appreciable changes are observed. The changes ofthe surrounding field proceed sometimes very rapidly. Card 1/4 S/712/62/02227/000/0041/015 Nonstationary processes in... A001/A101 The data of 1~, films and spectra of limb flares show the rapid formation of cu- mulative jets with some gradient of velocity along the jet. The equation of in- tensity distribution in the contour of the lines looks as follows: I (4~ in' (1.2) X where Ck is some constant, and n?~m Is the full width of the wing. The picture of spectral lines broadening during the magnetic contractionlof the plasma de- pends essentially on the direction along which the plasma is being observed. The author analyzes the mechanism of magnetic contraction of the solar plasma leading to the phenomenon of flare, which he calls automodel. contraction, assum- Ing magnetic fields to be frozen-in into the plasma. Solving the equations for the automodel contraction, the author estimates the time of contraction to be of- the order of 3 hours and considers it to be applicable to photospheric layers. The next problem is consideration of rapid contraction process resulting from the growth of the external magnetic field (flare). The solution of equations of magnetic contraction is represented in Figure 5 which shows the origination of pulsations. The author concludes that even comparatively slow changes in the Card 2A S/712/62/027/000/004/015 Nonstationary processes in... AOOI/AlO1 field of sunspots may lead to very rapid and intensive contraction and subsequent pulsations during the times comparable with the time of flare formation. This can lead to generation of shock waves converging to the~neutral point and produc- ing considerable heating of plasma. Shock waves arige :.f the initial dimensions. of the condensation are sufficiently large (> 5 x 10 cm); however, if the ini- tial rate of the magnetic field growth.is high (- 0.1 gauss/seg), a*contraction takes place even at small dimensions,of the condensation (- 10 cm). the last problem considered is the slow growth*of the external maigietic field and proces- ses related to it. The process of automodel contraction is analyzed with ohmic losses taken into account, and it is shown that the latter are of importance in the slow heating of faculae. The initial dimensions of condensations do. prac- tically,coincide with the characteristic dimension .(^jIOO km) of emission nuclei arising in the photosphere and showing characteristic spectral features (nuclei of the faculae fine structure). The heating of condensations due to Joule losses leads to a strong ionization of hydrogen. The existence of heated condensations has been confirmed by both studies of the solar radio emission and studies of its ultraviolet spectrum. There are 6 figures. SUBMITTED: April 1961 Card 3A 3/712/62/027/000/004/015 Nonstationary processes in... A001/A101 F'igure 5. Approximate (dotted line) and exact (dots) solutions of the magnetic contraction equation ............. 'Na Card 4/4 S/712/62/028/000/007/020 E,032/E314 AUTHORS: Stepanov, B.Ye. and Severnyy, A.B. TITLE: Photoelectric method ?io-r -measurili-gthe magnitude and direction of the magnetic field on the solar surface SOURCE: Akademiya nauk SSSR. Krymskaya astrofizicheskaya. observatoriya. Izvestiya- v. 23. 1962. 166-193 TEXT; The aim of this work was to develop a photoelectric Method of measuring the magnitude and direction of the magnetic field, the direction being characterized by the angle between the field vector and the line of sight y and the azimuth of the transverse component of the field A search for this method Was begun in 1958 and the developmeYrt was completed in 1959- Since then, the method has been.used to record the fields in active regions and a preliminary description of it was given in a previous paper (A.B. Severnyy - Trans. IAU, 11-13, 1961 (in press)),. The method is being used with the magnetograph.of the Krymskaya astrofizicheskaya observatoriya. (Crimean Astrophysical Observatory)'. + X/4 modulation'is-employed-in measurements of the longitudinal. i Yield and the photocurrents due to oscillations in the intensity Card 1/3 S/712/62/028/000/007/020 Photoelectric method .... E032/E314 of "I', and "12 components at the two slits of the photometer are subtracted. In measuring the transverse magnetic field a 0, X/2 modulation is used (ADP crystal.plus quartz X/4 plate) and thetfo Photocurrents are added. The azimuth of the transverse field is determined by recording the signals with the quartz X/4 0 plate in two positions separated by an angular distance of 45 In order to determine the relation between the signals and y, the electrical oscillations for a magnetically split line are resolved into two mutually perpendicular oscillations so that their intensities can be added within the limits of an optically thick absorption line, and the blending and interaction between differen-' tly polarized a, and -Tr components can be taken into account. Calculations used in the interpretation of the data were reported in earlier papers (V.Ye. Stepanov - Izv.Krymskoy astrofiz. obs., 19, 20, 1958; 18, 136, 1958). A method is described for the calibration of the apparatus with the aid of a special magnet. The noise level corresponds to about 100 Oe in measurements of transverse fields, so that the method cannot be used for regions with- very low fields (H 4t~ 100 Oe).' The noise level for the Card 2/3 S/712/62/028/000/007/020 Photoelectric method E032/E314 longitudinal component is about 1 Oe. Charts showing magnetic-field distributions in active regions are reproduced. The magnetic- field charts reveal an eddy structure in some cases. The spiral structure of Iij shows that apart from the azimuthal component H there is a'rso a radial component H This indicates that the Anspot field differs from a force-free field with cylindrical. symmetry. Further studies designed to obtain more detailed information will be concerned with the variation in the field with height. There are 14 figures and 1 table. SU13MITTED: December 20, 1961 ;Card 3/3 SEVERNTY, A. B. "Solar magnetic field.* Report submitted to the Symposium on Results of the IGY-IGC (Intl. Geopbysical Year) Los Angeles, California 12-16 Aug 1963 GOPAS-YUK, S.I.; OGIRI, M.B.; SEVERM, A.B.; SHAPOSHNIKOVA, Ye.F. Structure of solar magnetic fields and its variations in flare regions. Izv. Krym. astrofiz. obser. 29:15-67 163. (~ffRA 16:1o) YLADIMIRSKIYP B.M.; SEVERIM, A.B. --. I... Nuclear processes in chromospheric flares. Izv. Lrym. astrofiz. obser. 29:80-85 163. (MIRA 16:10) NOCESSION NR: Azj,cj',lfjl5 J%V I S/0269/6h/000/,D02/0058/0058 SOURCE: RZh. Astronomiya, Abs. 2.51-414 AUTHOR: Severny*yp A. Be TITLE: DistribuLion of atrong flares in the magnetic fields of spot groups CITEM SOUhCS: Izv. Kry*msk. astrofiz. obsery. v- 30.. 1963~- 161-164 TOPIC TAGS: sun, solar activity., chromospheric flare, solar magnetic field, cosmic ray, astronomical modeling., solar filament., magnetic field neutral point astronomy TRANSLATION: A study was made of 15 very large (with cosmic ray effect) flares' at, the Dhase of their maximum development relative to magnetic fields. All avai-1- able data on magnetic fields, both.ordinary determinations of the absolute field from the spectruia and isogauss maps obtained for eight cases using the Crimean magnetograph, were used for this purpose. The position of most of the flares was determired from HIX films from the Crimea. Laboratory modeling of the transverse Card 1/2 ACCESSION NR: AM021615 field by the H, method, described earlier (see RZhAstrj, 1964j, 1*51-418)p was car- ried out for each flare. Asymptotes (lines passing through the neutral point and like poles) were drawn. The filaments of flares were oriented in the magnetic field either aloni; '01-D mentioned asymptotes or along the neutral line of the longitudinal field, or parallel to these lines. This property is expressed the more clearly the g-reater the field gradient across the mentioned lines. The fila- ments of 'flares deviate appreciably from the neutral lines in the region of weak fields. The cited data indicate that the filaments of flares always pass through the neutral point of transverse field of the model. Neutral points can appear a". the centers of spots (even over the center itself) md also over the region of a strong transverse field. In the case of eight large flares observed in the Crimea there was no observable separation of one filament into two parallel fila- Prents, as reported by certain investigators -(,4ZhAstr., 1962,, 101389). Bibliography of 10 items. Author's abstract. DATE ACQ: SUB CODE: AS ENGL: 00 Card 2/2 KAPLAN, Samuil Aronovich; PIKELUTER, Solomon Borisovich; AMBARTSUMYAN, V.A., red.; MUSTEL', E.R.,' red.; SEVERNYY, A.B.,- red.; SOBOLINX, V.V., red.; K1JLIKOV, AKSELIROD) I.Sh-j tekhn. red. [Interstellar medium] Mezhzvezdnaia sreda. Moskva, Fiz- matgiz, 1963. 531 P. (MIRA 17:2) GORBATSKIY, V.G.; MININ, I.N.; ; AMBARTSUMYAN, V.A., red.; BUSTELI, E.R., red.; UVERNYY, A.B., red.; SOBOLEV, V.V.j red.; KULIKOVY G.S.,--r-er.-;-HSELIROD, I.Sh., tekhn. red. [Nonstable stars] Nestatsionarnye zvezdy. Moskva, Fizmatgiz, 1963. 355 P. (MIRA 16:4) (Stars, Variable) SEVERNYY9 A.B. Sun Flares and Magnetic Fields. Reports of the following Soviet Scientists were presented at the XII!th International t~ongress on Astronautics in Varna., Bulgaria, P: Tekhnika Molodezbij #1, 19639 pp.24-25 7 7 _~-- 65 W (l)/9WG(v)/EEC-4/EBC(t) Pe-~/Pq-4 SS L 85~22 (1upkt- -TESD(t)/'RAM(t) GW ACCESSION ITR: AP4046586 S100301641 21 ("7 AUTHOR: Sevemy*y, A. B. tCorresponding member AN SSSP.) 12~ T IT LE: rnvestigations of the magnetic fields on the MM SOURCE: AN 3SSR. Vestnik, no. 9, 1964, 62-67 TOPIC TAGS.- sun, magnetic field, Zeeman-effect ABSTRACT: The author outlines the history of discovery- and investigation of the sun s mwpetic fields. He points out thatf despite numerous studies the subject -i~* -~'.,'----; still one of the nost enigmatic of cosmic plWsics* Such studies were begun at the Kry-rmskaya astrofizicheskaya observatoriya Akadenii Nauk SSSR (Crimean Astrophysical O'h9ervatory of the Academy of Sciences SSSR) in 1954. Attention was first focused on strong magnatia fields concentrated chiefly in sun spots, and photographs were made of the Zeeman effect on spectra of the spots and neighboring regions. The study of w~--ak fields was begun in 1956 by means of the Photoeleotria method. This iqe.thod is describ,id briefly. The author states that the possibility of measuring -4 both longitudinal and transverse aomponents of the field and the position of the field vector in space was first realized by V. Ye. Stepanov and A. B. Severny*-y in 191 ". Inhomogeneities in the field, particularly transverse fields wi Vain the major field oil a sun spot, have been oonfirmai by several investigatiinso k strong Card 112 NFL, ..7'77 77 1W F4, L 8529-65 :ACCESSION NR: AP4046586 o' - ting to., 0 and, Totation of the magnetic vector has*been observed with depthi. amoun 9 more at depths of 100 km. Studies of flares (of 1957) in comparison with maps magnetic fields indicate that the position of the flares cannot be related to over points of differently oriented fields. An interesting point is that the strongest changes in a magnetic field are observed in flares that generate co a rays. bbiiating dat-a on the value and direction of the magnetic field permit e mination of the nature of the electrical currents. But the existence of cantr currents is difficult to explain on the view of a stationaryj long--4ived syste This needs further study. Another problem is the difference in properties of magnetic and normagnetic segments of the sun and,: in-particulart-differenced chemical composition of these zones. This relation should be compar Ied..with the known fact that magrietia-variable stars change chemical composition- with change~in map ,Tiptic field. Orig. art. hass 2 figures. ASSOCIATION: Kry-*mskaya astrofizicheskaya observAtoriya Akademii xi"k SSSR (Crimean AstropIxygical Observatoaj Academy of Scieftces SSSR): LJUBMITTEDt 00 MGM 00,-- SUB GODE: AA NO REP SOVt 000 011MC 000 "i Card 21 12 61002-6-~ L ACCESSION NR. AP5010424 UR/0033/65/042/002/0217/0232 Q 17 T 523.745 AUTHOR: Severnyy, A B TITLE: The nature of golar%agnetic fields (Lbe fine 'structure of the field) SOURCE: Astronomicheskiy zhurnal, v. 42, no.,2, 1966, 217-232 A4 TOPIC TAGS: solar magnetic field, solar surface oscillation, sunspot magnetic field, sunspot ABSTRACT: An Investigation Is made of the fine structure of strong solar magnetic fields obtained at high resolving power. Detailed treatment is given to 1) the appearance of a purely transverse field wi0ft regions of strong longitudinal 1111 unipolar fields, 2) the appearance of field peaks 2-511 in size; 3) strong rotations of the transverse field vectors at the surface and through the depth of solar atmosphere; 4) the concentration of field lines from the spots into separate radially emerging bands; 5) the joining (with spots) of H /) z region of opposite polarity; and 6) the convection with sunspots. The non- coincidence of Evershed motions vAth the lines of force of the spot fields seem to indicate a possible iefiltration of gases Into the intervals between the Inmches where the field is type fields, but on the other side the twisting, fine structure . H; remini cent of forbe- free fields. The general solar magnetic field which is characterized by the absence of any uniform coherent polar fields is also discussed. A comprehensive descriptioa of the general micropattern is given including the appearance of "higher modes" in one or two octaves in characteristic lengths of elements of the general field which seem to provide evidence of peculiar oscillations of the solar surface. Orig. art. has: 5 formulas, 13 figures, and I table. A ASSOCIATION: Krymskaya astrofiziches1mys observatoriya Akaden7di nauk SM (Crimeaq L OQ730-67 EWT(l) GW ACC NR. AP6019666 AUTHOR: Severra7t A. B. 1 ORG.- qrimean Astrophygi Observato=9 Acadegq of Sciences SSM (Krymskays, 10 astrofizicheakaya observatoriya 40 Lkademii nauk SSSR) TITLE: Magnetic fields at various depths of the solar atmosphere SOURCE: ABtronomicheskiy zhurnal, v. 43p no- 3, 1966, 465-479 TOPIC TAGS: magnetic field, solar atmospheret chromosphere, photosphere, astrophyaics, hydrogen, spectroscopy ABSTRACTz Measurements of the chromospheric magnetic fields in the H, and XCa' lines are reviewed and are shown to be misleading. In fact, the blending of the H9 -lines, Vj with magnetic lines may pertain to fields in the photosphe-re rather than in the chromosphere.' The author contends that H. lines will be more suitable for measure-: i ments of chromospherio fields. To this end, the double magaetograph of the Crimean Astrophysical Observatory is described. This installation permits the simultaneous recording of the magnetic field in any two lines. ~Extensive amounts of data obtained! by this magnetograph seem to repeat all the features of tha photospheric magnetic field at the chromospherio level. Cases of anomalous appearimce of fields of F_ Card 112 L 00730--67 ACC NR: AP6019666 opposite sign in the chromosphere are discuseed,-and the appearance of small loop- tubes of lines of force in the photosphere is noted. The direction of the field in the photosphere is found to be opposite to the chromospherie fieldep leading to possible contact between fields of opposite directions. Aiso noted is the presence of isolated fields of z-ae sign only at the intermediate letrel of A - 6102.7 between 9L = 5250 and k -lineb. This factq-plus the appearance of zigsage in the Tr- component of some spots, is considered to be evidence of the very fine structure of solar magnetic fields. The author expresses his thanks to N. S. Nikalin, G. A. S. 1. Gopasy , and T. T. Tsap for their part.in constructing and running the magnetograph. Orig. art. has:-13 figures and 1 table. SUB CODE: 20, 03/ SUBM DATEt 28jan66/ ORIG REP: 013/ OM REP: 004: Card 2/2,~~ -- A.B. I -- Experimental investigation of the effects of rotation of the Folar- ization 11ane and of the nonmagnetic polarization on the sun. Izv. Krym. astrofiz. obser. 31:126-158 164. Obiervations of tvansversal and longitudinal magnetic fielas coninecte~i with solar flares. Ibid.:159-199 164. 17.9). r I C ACC NR: EWT(l) GW AUIMOR: Severnyy, A. B. TITLE: Studies of the rotation of a magnetic field withid,6~th in the ,Solar tmosphere SOURCE, Ref. zh. Astronomiya, Abs, 8,51-.442 SOURCE: Izv. Krwsk, astrofiz, obser ,.*v. 33, 1965,*3-33 TOPIC TAGS: astronomic data, solar atmosphere, solar magnetic field, rotating magnetic field ABSTRACT: A deduction previously made by the author (RZhAstr, 1964, 10.51-367) on the rotation of a polarization plane with depth in the Solar atmosphere is subjected to verification. For this purpose records of the transverse mag ,netie field were taken on the magneto- ,graph in three lines of different powers: "5302P 5250, and 4808; for checking the possible rotation of a polarization plane, a record was.later taken again in the original line (usually the x5250). Studies of the records and maps of lateral oscillations of the a vector showed a strong rotation effect in the transition from one line to another, which was analogous to the effect described earlier. In the majority of cases the effect of the rotation of the vector uDc -. 523.,76 'AH601339'7 S.OURCE-CODE t~/&69/65/obq/01-1/0046/6471! AUTHORS: Bruns, A. -V.-.; Nikulin, N. S.; Sg~~j. A. B. TITLE: New method for simultaneous recording of the transverse magnetic field parameters SOMRCE: Ref. zh. Astronomiya, Abs. -11-51-412 Rai-e SOURCE: Izv. Kr, astrofiz. ob V., v. 33, 1965, 80-85 TAG3: 'so ar magnetic, field, transverse otic field, etic fi-ld magn mam r- ;j3S'-`1-kr-T - A Taetiiod is describod which allows the simultaneous recordin- ;)-P both --,,npoue~As of thf,. transverfie fiela tind the direct recordin-~ of the trrLn3verse vibra- ojoa r-~ZimJLII x on P- st'rip ch,-~rt by reprocessing the signals. This is arcom-plished ,Lcin- in frouL of the eriLrance slit of the upectroar-aph a plane pola-iz ti'017, the lollo-11--Lng :r.3-ru-ter- A compoitnd plate o Z1.4,1ILL er marto :Ln f two quarter--tave. plates -;-1050 - , na~-v, ,roo-j ,,, 45o i,,j placed in front of an ordinar-j ei-,cular pularizati.or, Ll-nalyzer consi!j(dng of art amrjouiuz phosphate cryst-P.1 and a polarGid. I'he -,:,'Late mount L3 the armat-ure (,.C a polarized rolay- to which is qnprlied a 20-hz voltage from an audio ooo-L.1-latur, Thu.,-, tht, at-tt-'It- between the extraordina-T-j axJE3 oC thq qunxter-wave .L 1.11- p.-in-1pal axiij of the crystal alternately ta1ces the values 00 or Is. To calcula.Le the vibrati ii cacd ntc; 522.61 SEVEIMY) A.B. - S',-u.-dy -)r solar mgnc+i~ f-leads. V,-s4-. :,N SSSR 34 no.0162--~? S 164. (KIRA 17:10) J. asLrofiz-lcbesl:aya observatc-r-1-ya AN SSSR; Chlen-lkorres- ponde.m. All SSSR. L-06357-67 On (1) GW' ACC NR, U1601339_6___ ___SOURCf 65/00T/61-1/0047/00471 AUTHOR:. , Severnyy, A. B. TITLE: Investigation of the magnetic field and electric currents of unipolar ourspots! SOURCE: Ref. zh. Astronomiya, Abs. 11-51-416 . 'q 9' 16 REF SOURCE: Izv. Krymsk. astrofiz. observ., V. 33, 1965, 34-79 \Y TOPIC TAGS: solar magnetic field, sunspot, transverse magnetic field, longitudinal magnetic field, magnetic field measurement ABSTRACT: The transverse and longitudinal magnetic fields for a number of unipolar groups, recorded on the Crimean solar magnetojraphj?~xe analyzed. A method of calibrating the transverse field by comparing the magnetograph readings with photo- graphic measurements is suggested. It is noted that the vortex structure of the transverse field recorded in group No- 53 from 8 through 16 July 1962 is a rare phenomenon; fluctuations of curvature of the vortex spirals reflecting the bydro- dynamic torsional oscillations move quickly. Thetfield of unipolar spots is con- centrated primarily in ropes proceeding from the spot outwards. The appearance cf strong Iransverse fields inside spots is again noted. The values of the total field vector H and its inclination to the vertical Y are calculated for two groups. Analysis of the variation of -1 and I'HI with distance from the spot center shows a I slower change of these quantities than found at Mount Wilson observatory and than ,Lcord 1/2 UDC: 523-7461 L 39743-66 EWT (1) GW/GD-2 AM IV: U6005464 SOURCE CODE: UR/0053/66/088/001/0003/0050 AUTHOR: Sever 992, A* Bo ORG: Crimean Astrophysics Observatory, AN SSSR (Krymskaya astrofizicheskaya observatoriya AN SSSR) TITM: ~Iagnotic fiolds of the sun and stars ~ ,- SA, SOURCE: Uspekhi. fizichesk:Lkh nauk, V. 88, no.' 1, 1966, 3-50 TOPIC TAGS: solar magnetic field, sunspot, transverse magnetic field, spectral line, Doppler effect, stellar astronovV, solar activity, magnetic field, magnetic field intensity, solar photosphere, solar atmosphere ABSTRACT - ~After G. E. Hale discovered Zeeman fission in Fraunhofer linc~'-O`f sunspot spectra, the problem arose of the existence of magnetic 1 ;fields on the sun and stars. Although much research has been devoted to 1 4 1 this- problem,..the nature of solar and stellar magnetic fields has not. been, thoroughly investigated. Many hypotheses have been developed, but .none of them can explain these phenomena in detail. The stellar mag- netic field must be stable. because of high temperatures and good plasma Card 1/7 UDC: 52 13-638 AC AP600YP641, conductivity. Observations prove a variable stellar field with a sudden' change in stellar plasma. Stellar magnetic fields of the intensity of i 34 kgs have been found. The field intensity can be measured by the magnetic fission of ''spectral lines of the wavelength x using the formula -MI9I)t (M297. C where H is the positive or negative field intensity, m represents the magnetic quanta numbers of the upper and lower levels which may change their sign, and g is the Lande's factor for each level. When the field direction is inclined to the sight line under an angle Y, the triplet components al 02 7r can be determined using the formulas a,=- -Cos 2, x--isinty, 4 02 4 +COS Card 2/7 a; 4 L 39743-66 Acc im: Ap6oo5464 Figure I shows the change of the components of the triplet under the', action of the magnetic field. Fig. 1. Relative intensi- ties of components a,, r, and uz, depending upon the angle y. Solar magr'ietograms of-the Institute of Terrestrial &agnetism, Iono- sphere, and Propagation of Radio Waves at Moscow contain records of Ahe hydrogen line H from selected solar regions which make it pos7 a sible to investigate the magnetic field.of this re-aion in detail. Card 3/7 L 32743-66 ACC IIR: AP6005464 According to Hale's and Babcock's investigations, the solar magnetic field has variable changing polarities and, sometimes, loses its intensity for longer or shorter periods. Measurements at Cambridge i land the Crimean Astrophysical Observatory showed that no magnetic ield could be found at the solar South Pole during the period 1961-196.4 t the same time a negative magnetic field was recorded at the North ,A Pole. Changes of the polar field were recorded in 1927 and 1937. There is some time coincidence between the change of polarity of the solar mag- netic field and the maximum *of solar activity. The minimum activity oincides with the maximum phase of -positive or negative fields. The fine structure of the solar magnetic field was investigated by A. B. Severnyy. Statistical data show that observations with an instrument of low resolution found a weak magnetic field, and an increase. of the instrument resolution revealed an increase in the total field. Uni- polar regions on the sun became multipolar when the instrument resolu- tion was increased. Histograms. of 'statistical data show the intensity andi polarity at the North and South Poles of the sun during the first half of 1964. South polarity was predominant at the North Pole of the sun, and no polarity was evident -at the-So,uth . Pole.-,. Card 4/7 L 39743-V) kcc niR: Ap6ooy~& A strict dividing line between a sunspot and the photosphere and between the umbra and penumbra indicates that the cooling layer is thin. This layer is located in regions where a convection is developed in the solar atmosphere. The magnetic field in sunspots impedes the heating in the convection region. In 1958, during the maximum of solar activi'f_'_.1_,_ a spot couple with different polarities had the following magnetic fields: the forward spot in the Northern Hemisphere and the following spot inthe Southern Hemisphere had positive (northern) polarity. Both spots usually have opposite polarities. The polarity of a spot is determined byZeeman fission of spectral lines. High resolution ability of the spectroscope shows a filament structure of the spot umbra. The heterogeneous magnetic struc- ture of the spot may be checked by measuring the transverse magnetic field, the vector of which makes rapid turns in transition from point to point. The nature of the magnetic field in sunspots is a coexistence of inconsistencies, as the absence of electric currents or the presence of a system of electric currents. - -_ - - I Solar active regions (M-regions) appear in bipolar (BM), multi- polar (M), and unipolar (UM) forms. Bipolar regions are associated with calcium flocculi and an increased coronal emission.- With weak.in- Card 5/7 L 39743-66 Acc m: Ap6ooy~64 no changes in spectra. Orig. art, has: 27 figures, 8 formulas, and 1 table. LAM PRESS: 42o4-_F7 .SUB CODEi 03, 20 SUBM DATE: none. ORIG REF: 040 'OTH REF: 124 Card 7/7 84671 S/020/60/134/006/014/0-Al I 1941w BOI 6/B067 AUTHORS3 Andrianov, K. A.9 Corresponding Member AS USSR and Severn ------------------------ TITLE3 TelomsrizationlReaction of Organo-cXcloslloxanes PERIODICAL~- Doklady Akademii nauk SSSR, 1960, Vol. 134, no. 6, pp. 1347-1349 TEXT3 The use of telamerizat-ion reaction. in organosilicon compounds is rendered difficult due to the lack of elmental-organic monomers with double bonds between element and oxygen, and capable of polymerization. Ths authorsq hovever, effected the telomerization of octamethy! cyclo-, tetrasiloxane as cyclic oompound and dimethyl dichlorosilane as a substance effecting the rupture of the molecular chain. Experiments showed that, in additiong the former compound is polymerized by the latter. The authors found that the reaction of the ring cleavage without catalysts proceeds rapidly at 200-2500C. At a ratio between the first and the second substance of 2 3 1 it was completed at 2500C within 3 hours. 01~Jgomers were obtained corresponding to the compounds of the Card 1/3 84671 Telomerization Reaction of Organo- S10201601134100610141031 cyclosiloxanes B016/bO67 followed by the rapture of the ring and the formation of a linear ccvb)- dichloro dimethyl siloxane. Thase presumable reaction mechanisms are explained by schemes. The authors continug the study of this reaction by the example of similar cycles , and they investigated further reagents effecting the rupture of the molecular chain. There are 3 tables and 11 referenoe83 4 Soviet, 4 US, 1 Britishq and I Japanese. ASSOCIATION3 Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR (Instit-ate of Elemental-organic Compounds of the Academy of Sciences. USSR) SUBMITTEDi July 9, 1960 Card 3/3 26402 -'33/062161.10001008/0061010 31, 17.,IB206 AUTHORS: Andrianov, K. A., Severnyy, V. V., and Zavin, B. G. TITLE: Telomerization reaction of dimethy-1 -..,yelos-111anes., Communication 1. Production of MLear a.w-d1ch'joro- dimethyl siloxanes PERIODICAL: Akademiya nauk SSSR. Izvestllya., khimicheskil'sh nauk, no. 8, 1961, 1496..146i TEXT: The authors investigated the t,-?Xttrre thy! -cyclo - trisiloxane and octamethyl-cyc1otetrasilnxqne iwi~,h silane, as well as the effect of the ratio cf siloxane to dimethyl-dichlorosilane on the ~f 'ht., reaction products, The following were used for the syri 11 ho -,.-3 ta 11 nr, hexamethyl-cyclotrisiloxane, melting point 2 - b 132-1360C; oc tame thyl -cyclote tra-3 iloxar,,;, boilint-7, dimethyl-dichlorosilane with a chlorine was found to proceed according tci n[(CH 3)2 SiOlm + (CH 3)2 Sici2 1 m 91* j Card 116 ~/062/6 110001008100-6-101 -0, Telomeri~zation reaction of'dimethyl... 117/B206 methyl siloxanes showed that conformable to law boiling points, specific gravitids and refractive indices change with the number of silicon atoms in the molecule. No anomalies are observed in this connection. The telomerization of octamethyl-cyclotetrasi.~oxane with dimethyl-dichloro-, silane was investigated.at different molar ratios of the components: 10", 2:1 and 3:1. Experiments showed (Pig. 3) that telomerization doole not yield pure products for any of the ratios investigated. Telomer mixtures with maximum yield of the product corresponding to the ratio concerned, develop continually. When in -creasing -the ratio of the reacting components, the yield of low telomers is reduced and the amount of high-boiling products is,greatly.inereased. There are* 3 figures, 5 tables, and 2 references: I Soviet and 1 non-Soviet. The reference to the English-language publication reads as follows: W. Patnode, D. Wilcock, J.-Amer. Chem. Soo. 68, 2291 (1946). ASSOCIATION: Institut elementoorganiobeakikh.soyedineniy Akademii nauk SSSR (Institute of Elemental-brganic Compounds, AS USSR) Card 3/6 2'i,49o B106;V!611000100910051014 Tj Telomerization of dimethyl B117~BlOl where m denotes the number of silicon atoms in the initial ring, n - 1, 2,4 etc. In this study, the monofunctional trimethyl-chloro silane and not a difunctional compound was used as chain-terminating substance for the telomerization of dimethyl cyclosiloxanev. Equimolar amounts of octamethyl cyclotetrasiloxane and trimathyl-ohloro silane telo:nerize in .,an autoclave at 2500C within 5 hr according to the scheme CH 1 3 n CH + (CH ) Sin --> (CH ) Si OSi__ C1 3)2S'014 3 3 3 3 1 CH 3-4a Pure telomers with n - 2, 3, and 4 were obtained from the reaction mixture by fractional distillation. The physical'constants of the telomers are listed in Table 1.. The physical properties exhibit no anomalies. Tests carried out with various molar ratios of octamethyl cyclotetrasiloxane to trimethyl-chloro silane showed that at ratios of 1 : 1, 2 : 1, and 3 : I mixtures of telomers only, and no pure compounds were formed. In all of these mixtures the telomer formed in maximum quantity did not correspond to the stoichiometric ratio of the reactants. The telomer having a chain by 4 dimethyl-siloxane units longer than would correspond to the Card 2/4 27490 S/o6 61/000/009/005/014 Telomerization of dimethyl Bi 17YBI 01 stoichiometric ratio of the initial mixture was observed,to form in maximum yield. An increase of the octamethyl cyclotetrasiloxane : Tri- methyl-chloro silane ratio lowers the yield of the lowest telomers, and highly increases the yield of high-boilin' products. Within the range of molar ratios studied, lower trimethyl-chloro silane contents in the initial mixture did not decrease the conversion of octamethyl cyclotetra- siloxane. There are 2 figures, 6 tables, and 4 references: 2 Soviet and 2 non-Soviet. The reference to the English-language publication reads as follows: D. Wilcock, J. Amer. Chem. Soc. 68, 692 (1940- ASSOCIATION: Institut elementoorganicheskikh soye6ineniy Akademii nauk SSSR (Institute of Elemental Organic Compounds of the Academy of Sciences USSR) SUBMITTED: November 28, 1960 Table 1. Physical properties of a-chloro~L)-trimethyl-siloxy-dimethyl siloxanes. Legend: (1) formula, (2) physical properties, (3) b.p., OC, (p, mm Hg), Card 3/4 OK 17 27492 s/o62/61/000/009/007/014 B117/B101 AUTHORS: Andrianov, K. A., and Severnyy, V. V., TITLE: Reactions of bis(trimethyl-6iloxy)-dichloro ailane with alcohols, phenols and alcoholates PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh nauk, no. 9, 1961, 1624-16~9 TEXT: The reactions of bis(trimethyl-ailoxy)-dichloro silane with monovalent alcohols, its alcoholates, di4alent alcohols, mono- and divalent phenols were studied. Bia(trimethyl-ailoxy)-dichloro silane (b.p. 1730C, d20 1.0017, 20 1-3983), was',prepared by heating hexamethyl 4 9 disiloxane with silicon tetrachloride at 2500C in an autoclave. Monovalent alcohols used were methyl-, ethyl-, n-propyl-, isopropyl-, n-butyl-,and isobutyl alcohol, Etherification of bis-(trimethyl-ailoxy)-dichloro silane with a 105/11 excess of the corresponding anhydrous alcohol, without a hydrogen chloride acceptor, is highly exothermic and accompanied by evolution of hydrogen chloride. It was not possible, however, to isolate bis(trimethyl-ailoxy)-dialkoxy silane derivatives from the reaction Card 1/4 S, 27h92 o6 61/000/009/007/014 ReactionD of b1l)(trimothyl- B11 7YB1 01 bis(trimethyl-siloxy)-dichloro silane with sodium alkoxides. Tile physicsA constants of these alkoxy silane derivatives are listed in Table 1. The reaction of biE;(trimethyl-siloxy)-dichloro silane with divalent alcohols was studied using glycol and 1,4-butanediol. With glycol, an infusible, insoluble precipitate and products boiling below 1100C consisting mainly of hexamethyl disiloxane were formed. In the reaciion with 1,4-butanedic)l the latter is dehydratized practically quantitatively to tetrahydrofuran. The hydrolyzation is obviously modified by the tetrahydrofuran present, !to that compounds which can be distilled off between '1500 and 26oOc under vacuum and a small quantity of a liquid residue are formed. The properties of these compounds are being studied at present. Hydroquinone and 1 4-dihydroxy-diphenyl propane were used to study the reaction of bis(tr:.- methyl-siloxy)-dichloro silane with divalent phenols. With hydroquinone, both in the presence of anisol as solvent and without a solvent, an elastic polymer (C 12 H22 Si3 04)n is formed which swells strongly in organic solvents: on prolonged standing in air it becomes sticky and deliquesecs. On boiling in dilute alcohol it hydrol,,~zes readily with formation of hydroquinone. The reaction with I 41-dihydroxy-dipqenyl propane yields a darkbrown, tough polymer (C 21 H32 Si304)n which remains unchanged on stan6ing Card 3/4 27492 S/c62 ,/61/000/009/007/014 Reactions of bis(trimethyl- B117/B101 in air and is easily soluble in toluene. There are 2 tables.and 3 refer- ences: 2 Soviet and 1 non-Soviet. The reference to the English-languago publication reads as follows: R. 0. Sauer, J. Amer. Chem. Soc. 66, 1707 (1944). ASSOCIATION: Institut elementoorganicheskikh soyed_fneniy Akademii nauk SSSR (Institute of Elemental Organic Compounds of the Academy of Sciences USSR) SUBMITTED: February 2, 1961 Legend to Table 1 . d4 1) Formula, 1101 11 N b.P., oc , 0 Fo T - KgM. 1C ~3~ calculated, j(CH,),SiOj,Si(OCH,-n), 232-7~ '34 1 4003 0:8847 96 96,6, 225-227 1,3968 08757 96 94 90,81; 4 found. [(CH3)3Si0j2S1(OC4Hq-i)2 I : I jCH3)3Si0j.S1(OCH?-n), 214-126 'j(CH3)3SiO1,S1(OC3H7.1-)2 202-203 1(CH3hSiOhS1(OC21is)2 191-1'93 1(CH3)3Si0j..S1(OCH'): 174-175- [(CH3)3S10jjSi(0C,jH5)2 157--~159 (3 Card 4/4 1,33943 1,2875 1,Z870 1;;1855 1,4750 0,8903 018752- 0,892t, 0,9155 1,03W 87,68 69,16 106,59 87,2!, 87,3t!; 78,10, 68,841 106,8! 28271 S1/0621611000101010061018 B117/BlOl AUTHORSs Andrianov, K. A., and Severnyy, V. V. TITLEs Telomerization of dimethyl cyclosiloxanes. Communication 3. Telomerization by methyl vinyl diQhloro silane and met',&Yl phenyl dichloro silane PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh nauk, no. 10, 1961, 1788 - 1791 TEXTz Telomerization of octamethyl cyclotetrasiloxane by methyl "inyl dichloro silane and methyl phenyl dichloro silane is described. The aim of this paper was to investigate the effect of various substituen~.s on the course of reaction. In the experiments, octamethyl cyclotetrasiloxane with boiling point 1740 - 1760c, methyl vinyl dichloro silane wi-,*h boiling point 930C (Cl 50.6%), and methyl phenyl dichloro silane with bolling point 2000 - 2020C (C1 37-Wo') were used. From the reaction of e:.Iui- molecular quantities of octamethyl cyclotetrasiloxane and methyi vinyl dichloro silane, a mixture of telomer homclogs was formed. Frora this mixture, a-chloro methyl vinyl siloxy- W-chloro dimethyl siloxanes with Card 1/4 A 28271 SJ'062/61/000/010/006/013 Telomerization of dimethyl... B117/B101 n - 1, 2, and 3 were isolated and identified on the basis of boiling tem- perature, refractive indices, specific gravities, molecular refractions, results of elementary analysis, and bromine numbers. The properties of the compounds obtained are listed in Table 1. The mean conve.;.,sion of vinyl methyl dichloro silane was 32.8%, and that of octamethyl cyclotl-,tra- siloxane 54.0%. The yield of telomers was 45,154 by weight of the ini-:ial mixture. Contents of the individual telomer homologs with n - 1, 2, ;-..nd 3 were 18-5, 30.8, and 14.6%, respectively. Higher telomers with a polymerization degree n-1-.3 were formed in the amount of 36.1~;. Thus, it was established that telomerization is the only reaction at the moment. by which compuunds of the a-chloro methyl vinyl siloxy-L-r-chloro dimethyl siloxane series with given atomic number may be obtained. The reaction of octamethyl cyclotetrasiloxane with methyl phenyl dichloro silane showed low conversion under standard conditions (3 hr, 25000- k1so -,he experiments with 2 M methyl phenyl dichloro silane and I It octamethyl cy clot et ras iloxane resulted in a total conversion of only 18.40/6' at 3COOC in 5 hr. The conversion of methyl phenyl dichloro silane was 9.1%, aad that of octamethyl cyclotetrasiloxane 19.0%. From the reaction products, telomer homologs with n - I and 2 were isolated. 49-Vlo of the telomers Card 2/4 Z~ S/062/61/000/oio/OO6/018 Telomerization of dimethyl ... B117/B101 had a boiling point higher than 3500C (3 mm). The properties'of the resultant a-chloro phenyl-(,).-chloro nongmethyl pentasiloxane and a-chloro phenyl-o-dhloro heptadecamethyl nonasiloxane are listed in Table 2. Tbus, it was proved that telomer homologs of the a-chloro methyl phenyl siloxj- b3-chlaro dimethyl siloxane series are formed by the reaction of octa- methyl cyolotetrasiloxane with methyl phenyl dichloro silane. There arl] 4 tables and 3 Soviet references. ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR (Institute of Elemental Organia Compounds of the Acad--~av of Sciences USSR) S UB MITT ED sMarch 23, 1961 Legend to Tables 1 and 2: (1) Formulai (2) boiling point, OC (p mmHg); (3) calculated; (4) found. 4 Card S/079/62/032/005/004/009 D204/D307 AUTHORS: Andrianov, K.A., and Severnyy, V.V. TITLE: Hydrolysis of trimethylsiloxychlorosilanes and conden- sation of their hydroxy derivatives PERIODICAL: Zhurnal obahchey khimii, v. 32, no. 5, 1962, 1633-1636 TEXT: The hydrolysis reactions were studied to determine the reac- t, tivity of the above com ounds with electrophilic and nucleophilic reagents. [(CH 3) 3S'OJ2 M was hydrolyzed in acid and basic media, with and without solvents. In the absence of solvent# aqueous h-trdro- lysis at 1000 resulted in the removal o:t the trimethylsiloxy groupt yielding (CH j SiOSi(CH (II) and a polymer (CH SiO.Sio 3 3 3 3 3 3 1.5 (Sio 2)n (III). Solvents decreased the tendency of the trime.thylsilo- xy group to split off; thus in ether and THP aq. hydrolysis gave an insolubie polymer and crystalline [(CH 3)3 Sio 12S' (OH )2 (IV). No poly- mers were obtained from the hydrolysis of I in the pre'sence of HCl acceptors (pyridine, NH 3 NaHCO3 under similar conditions, the Card 1/2 -19 S/079/62/032/005/004/0(. Hydrolysis of trimethylsiloxy- D204/D307 only product being IV, in -"-'50 % yields. On heating at 200'C for- 30 min. IV condensed to HO ([(CH 3)3 SiO12S'0~2H and HO [[(OH3)3sio]2~ SW H. Trimethylsiloxy group was also split off [(CH*) Siol Sicl '3 3 3 3 in an acid medium, without a solvent. In aq. NaHCO the latter com-, 3 pound gave [(CH 3)3 Sio]3SiOH, in 60 % yield. There ard 2 tables. SUBMITTED: April 22, 1961 Card 2/2 ANDRIANOV, K.A.; SEVERM, V.V. Hydrolysis of trimethylsiloxychlorosilanes and condensation of their hydroxyl derivatives. Zhur.ob.khim. 32 no-5:1633-1636 ,vq 162. (MM 15:5) (Silicon organic compounds) (Hydrolysis) S/062/62/000/007/007/013 B117/B180 AUTHORS: Andrianov, K. A., and TITLE; Splitting methyl-phenyl cyclosiloxanes with dimethyl dichlorosilane PERIODICALt Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh nauk, no- 79' 1962, 1237 - 1242 TEXT: The reaction of trimethyl-triphenyl cyclotrisiloxane with dimethyl dichlorosilane was studied at ratios I j 2 and 1 1 1. The telomers CH CH CH CH 1 1-3 1 3- ' 1 3 Cl - Si (05i) - 01 (1) and oligomers C1 - Si (OSi) Cl (II), I 3n n CH CH ud bil 3 3 3 3 with n -2 - 10 were obtained. Despite the change in component ratio, the products are not dominating individual substances, but always mixtures of homologs. Reduction of the dimeAyl dichlorosiland content reduced the yield of lowest homologs considerably and increased that of highest homologs (distillation residue). In the reaction of tetramethyl-tetra- Card 1/2 S/062/62/000/007/007/013 Splitting methyl-phenyl ... B117/B180 phenyl cyclotetrasiloxane with dimethyl dichlorosilane in the ratio 2.5 : 1, only highest oligomers (> silo) were obtained, with a 35.3% yield. Products with three and four silicon atoms were hydrolyzed,' to confirm the structure of oligomers of formula (II). The authors are the first to have obtained 1,3-diphenyl-tetramethyl cyclotrisiloxane (yields 181/lo, b.p. 138 - 1400C (3 mm Hg); d20 1.0679;N20 1-5017; MR 95-52) a six 4. D membered cycle with methyl-phenyl siloxane and methyl siloxane links, from 1,5-dichloro-1,3-diphenyl-tetramethyl trisiloxane. The hydrolysis of 1,7-dichloro-1,3,5-triphenyl-pentamethyl-tetrasiloxane yielded 72% of the. ,,.rell known 1,3,5-triphenyl-pentamethyl cyclote'trasiloxane with a boiling point of 198 - 2010C at 4 mm. Hg. There are 1 figure and 5 tables. ASSOCIATION; Institut eleinentoorganicheskikh soyedinerdy Akademii nauk SSSR (Institute of Elemental Organic Compounds of the Academy* of Sciences USSR) SUBMITTED: December 27, 1961 Card 2/2 41336 8/020/62/146/oo3/ol2/019 B101/B144 AUTHORS: Andrianov, K. A., Corresponding Member AS.USSR, Severnyyj V. V. TITLE: Telomerization of organocyclosiloxanes with dimethyl dichlor,osilane PERIODICAL: Akademiya nauk SSSR. Doklady-, v. 146, no- 3, 196Z, 6ol-603 TEXT: The telomerization first observed on dimethyl cyclosiloxanes with organochlorosilanes (DA119 134, no. 6, 1437 (1960)) proved applicable to other organocyclosiloxanee also. The reaction was studied between (ROR"SiO),, where RI (1) or RI (II) and R" '. C2H5 CH3' R" ';' C6H5 (CH 3)2S'C'2 (III). Six-membered cyclic clompounds were chosen becau4e the.. eight-membered proved to be less active. The reaction proceeded according,- .to (R'R"SiO) 3 + (CH 3)2sicl2 Cl(CH 3)2S'-(OS'R IV) 3n C1 forming telomer homologp with n - 1, 2, 3 The reaction of I with III took place in glass ampoules with 5 hrs heating at 2509c- Conversion of I was 65%, of JII 53-4%. The yield of telomers with n - 1 was 64-8%, with n - 2, Card 113 . S/020/62/146/003/012/019 Telomerization of organocyclosiloxanes ... B101/B144 17.6uj'a, the residue containing 18.6~. telomers with n> 2. For the telomer with n = 1, the b.p. is 150 0C/5 mm Eg, d20 1.0102, n20 1-4303; for a i- 2 4 D 0 20 20 the b.p. is 175-178 C/0-01 mm Hg, d 4 0.9988, n D 1.4364. The reaction of,II with III under the same conditions as for I with III yielded 32.9% telomer with n - 1, 4.9-/o n - 2, residue 63.2%. Conversion of II was 88.6;4o, of III 36.5~*. Telomer with n - 1 had b.p. 198OC/4 mm Hg, d20 1.1276, n 20 1-5116, and with n = 2 b.p. 201-203 0C/0.01 mm Hg' 4 D d20 1-1310, n 20 1.5304- Reaction of II with III in a ste*el autoclave led 4 D to cleavage of the siloxane bonds and formation of oligomers Cl(CH 3)2S'-FOS'( CH3)(C6H Oln C1 owing to catalytic action of the resulting FeCl In the reaction of trimethyl trivinyl cyclotrisiloxane with III 3' in glass ampoules at 250-20ec no telomers could be identified, owing to intense polymerization. The hexaorganotricyclotrisiloxanes are in the following order of telomerizing capacity: Card 2/3 0 S/020/62/146/003/012/019 Telomerization of organocyclosiloxanes ... B101/B144 if si6-~ > [(C H H (C H )Si > [(CH There is (C 3)2 j 3 2 5)2S'013 IC 3 6 5 033 2-CH) C113S.'01 3 L 1 table. ASSOCIATION: Institut elementoorganicheskikh -soyedineniy Akademii nauk SSSR (Institute of Elemental Organic Compounds of the Academy of Scienceg USSR) SUBMITTED: June 4, 1962 "Card 3/3 LMIM -1~1~1-wiWOWI-IMN&I-a 3/06 62/000/012/002/007 B 1 17Y131 01 AUTHORSt Andrianov, K. A., and Severnyy, V. V. TITLEi Catalytic cleavage of dimethyl CyClOBiloxanes in the presence of dimethyl-dichloro silane PERIODICALi Akademiya nauk SSSR. Izvestiya. Otdeleniye khimic.heskikh nauk, no. 12, 1962, 2133-2138 TEXT: The effect of catalytic amounts of iron chloride on the reaction of dime thylcyclosi loxanes with dimethyl-dichloro silane was studied. Experiments with 1~i by weight of iron chloride, and without- any, were conducted under equal conditions: sealed glass ampuls, kept at.2500C for 5 hrst rectific4- tion of the mixture first at atmospheric pressure, then at 4 mm Hg. Results; Without iron chloride, only a,to-dichloro-dimethyl siloxanes containing 4, 7, and 10 silicon atoms formed. When using iron chloride, telomerization takes place with the Si-O-Si bonds being ruptured and all homologs of the formula Card 1/4- S/062/62/000/012/002/007 Catalytic cleavage of dimethyl ... B117/B101 CH C'3 1 1 3 Cisi - (Osi)nCl CH3 ~H3 being.formed with 2 to 7 silicon atoms. The following mechanism of cleavage was suggested: The reaction begins by a coordination of the iron atom with an oxygen atom in the siloxane chain either of the telomer or dimethyl cyclosiloxane. An active complex forms which then decomposes. The assumption thpt this reacfion takes place in equilibrium was confirmed by experiments with octamethyl cyclotetrasiloxane and dimethyl-dichloro silane at different component ratios (Fig. 2; Table 1) and also by the fact that the composition of the reaction products is determined by the quantitative ratio of the Si-0- and Si-Cl- bonds in the system, not by the type of compound used. The reaction examined was suggested as an easy method of synthesizing low-molecular and high-molecular 1,63-dichloro-methyl siloxanese There are 2 figures and 4 tables. Card 2/4 S/062/62/000/012/002/007 Catalytic cleavage of dimethyl ... B117/B1O1 ASSOCIATION2 Institut elementoorganicheskikh soyedineniy kkademii nauk SSSR (Institute of Elemental Organic Compounds of the Academy of Sciences USSR) SUBMITTED: March.31, 1962 Fig. 2j Yield of Cl[(.C'3)2"O1n-" (CH 3)2C''oligomers depending on the ratio dimethyl-dichlorp silane : octamethyl cyclotetrasiloxane = curve (1) 2': 1; curve (2) 1 : 1~ where the y-axis gives the yield in and the x axis gives the numbei of silicon atoms. Table 1: Dependence of the molecular weigh t and oligomer yield on the molar ratio octamethyl cyclotetrasiloxane : dimethyl-dichloro silane. Legend: (1) ratio; (2) calculated; (3) determined; (4) according to viscoaityi (5) yield, Card 3/4 S/062/62/000/012/002/007 Catalytic cleavage of dimethyl ... B117/B101 Table 1 Fig. 2* Hagaeno COGTHOme- m Ilue I Sin I Af SI, Buxo;j. % I . I I no GI n0 BF13KOCTU 10.:1 40 2960 35-38 2750 2900 75~85 20,:j1 80 5920 71-76 5250-5630 5300 70-80 25,:,l 100 7400 89-93 6560-6870 64200 1 70-80 501%1 200 14800 150-170 11200-12600 13850 65-70 100j:A 400 29600 220-250 16700-18500 18709 55-65 Card 4/4 ; chi S10621631000100110111025 B101/B166 AUTHORSs Andrianov, K. A., and Aevernyy, V. V. q1 TITLEz Telomerization of dimethyl cyclosiloxanes~ dommunication Reactions with,silicon tetrachloride PERIODICAL; Akademiya nauk SSSRI, Izvestiya. Otdeleniye khimicheskikh naukj.' no. 1, 1963, 62 - 86 TEXT: The reaction of dimethyl cyclosiloxanes with Sicl was studied'to de- 4 termine its applicability for the synthe6is pf* tetrafunctional telomers, and to obtain missing data. The reaction of'equimolecular amounts of hexa- methy! cyclotrisiloxane with SiCl in a glass ampoule at 250 0C confirmed*the 4 occur Irence of telomerization according to n 1( CH5)2 sio]3 + Si-Cl4---,> C 133i The reaction product contained 71-5% of the compound with -[OS.i(CH3)2]3nC" . 7~ n = 1 and 13.5% with n = 2. A much more complicated mixture'formed in a steel autoclave-under the same conditions from oe'tam'ethyl cyclotetrasiloxane. and SiCl' by the catalytic action of FeCl traces. Compounds of the struc- 4 3 Card 1/3 J j �/062/63/000/001/011/025 Telomerization of dimethyl B101/B186 tures ClSi(CH ) _103i(Cli3 si-fosi cif WnCl (2), and 3 2 21n6' (1); C13 :.3 Cl3Si-[OSi(CH 3)2]n_OSiCl 3 W 11 were formed. At the, molar ratio SiCl4 .octa- methyl cyclotetrasiloxane 4:1, the yield of substances with high chlorine content, such as Cl Si-FOSi(CH ) Osicl OSiCI ; increased. At the L -3n- 2- 3 r 3 2 3 0 ratio 1:2, the yield of substances boiling above.250 C/4 mm Hg rose to 38.% I M' Chem. Abstrs Contrary to S. Maeda, E. Noj' oto (Jap. patent 3660 (1957), 52, 5880 (1958)), no formation of dimethyl dichlorosilane was found. The cat- lytic action of FeCl is explained by binding,of the Fe atom to an 0 atom 3 of the siloxane chain. -The resulting active.,complex Fe--O-Si:~ dec "'poses under the action of a compound containing Sk-!Cl bonds; Fecl ~-.et fj!ee 'Ch 3 again, and an Si-O-Si bond is formed: 'Cj/Fq-Q-Si, The data for the newly \C1 2Q 20 synthesized compounds are given in the order b:p. (mm fig), d4 , and nD oligomers of formula (2), n - 3: 65(4), 1.1475, 1.4079; n - 4: 91 (4), 1.1043, 1.4081; n - 5: 112 (4)$ i.o968, 1.4092; n''$- 61 132 (4), 1.087.0, Card 2/3 S1005216 3/000/001/011/02 5 Tolomerization of d."imethyl ... Biol/B186 1.410B; oligomers of formula (3), n - 3s 86 (5), 1.2207, 1.4112; n - 7- 1890), 1.1256, 1.4118; n - 8t 2050), 1.1165, 1.4123; n - 16t 2150-01), 1.4135; n - 17, 226-230(o.01), - , 1.4137. There are 4 tables., A330CIATION: Institui elementoorganicheskikh soyedineniy Akad:emii nauk SSSR (In'stitute of El:emental*Organic C'Ompounds of the Academy'. of Sciences USSR) SUBMITTED: April 16, 19062 Card 3/3 S'/06 2/6 1/000./002/011/020 B 144" "B' 13 6 AUTPORS: Lndrianov, K. A., "~cv-Prnyy, V, V., and lzmaylov, B. A. TITLE.- Telomerizqtion of r3imuthyl cycloailoxanes. Communication 5. Reactions with trifunotional compound~i rEHIODICAL: Akademiya nquk SS C R ,Izvestiya. Otkleleniye khimicheskikh nauk, no. 2~7 1965, 2e2 - 290 TEXT; Reacting hexamethyl. cyclotrisiloxt~ne (1) with organotr1ohloro silanes at 2500C led to tile formsition of telomera of the formula ) I Cl in which tile degi.~ce of tclomerization depended on "'(C1)2_1OS'*"_3 2j 3ri the oreanic radicul R, The ztetIvity of qSiCl 3 devroa2ed in the order R - C113t C It CII r,,H, C. 6H 5' 7,llhpn R was CH3or C Hci 1 s2 excess of I 2 5 f 2' 2 effected a reduction of th" yield in the. telomer with n - 1, a slight in- crease of the telomeri wit), n = 2 and n ~ 3, ard q sharp increase of the higher telomera. This effect wa* absent, -wher, the reaction with PUH 3 Sial3 was brouE:ht abotit in two stages with socparf;tiozi of 1,1,'7,-trichloro-heptfI- methyl tetraoi-loxane. I~hi3 ip. attribuLed to the dependc-nQe of the HSM 3 Card 1/3 Telornerization of dimethyl B I 44/B 186 activity on the number of CI atoma bound to one Si atom. The boiling point3l. 20 20, -nm I - C1 40 11 1) molecuier weigMs and c . positioni Rre given for the lt new tri functional Lelomer3 obtaivied. Ili the presence of F,~,'12' not only tTi- functional form but, also the di-Ptinttiora-I tplomers C15i,(CH 3)2-[O:-:'(CH3)2]n cl~ For P = CH C? v ", "H wixture3 of tri- and difunctional tuelorrv~rs witb equal 3 1: 51 n formed. Wif-h R - C9114 or C H.-I the rrelalirn n,?,n was foiznd to depend on the type of the 4-1 Ili t ial d, I.Me, thyl [(Cfi ~ SiOlm. The physical V2 it 110=10aUCS WI!,11 11 7,8,16,20 and C Propertkcs oF the new 06 5 'Z I ~ 41~9 homologuee with n - 4,5,7 aro givc;n. Ir, thin of FeCl 2 the percentage of dimethy3 t2yn1nr3i.Io7-ane convers-Ion decrvzised in the ~5ane order aa in- dicated that n-bove fc)r the I.- thrt roa-~.Aion with r.Lnyl and Phellyl COMPOunds, T proved 11JOIre ty-t-i-riketh.,,ri There are 8 toblen. AES'60CIAIL'101,1. lii!Otitut ~--,oyerjiaeniy -Ikademii aauk SSSR f ~In-".-'Xtlite r!f t-'%r,,~rinic '.cmpoun~-, or the Academy of n r (1 2 17, -a c! A19 /--G' Telomeriz,ition r L .;f' dimethyl ... JB 1 114/13 1 G (I S UBMITT ED i May '16, 1962 I q ", Card 3/3 ANDRIANOV., K.A.;._SEVERNYY, V.V. Telomerization reaction of organocyclosiloyares with dimethyldichlorosilane. Dokl. AN SSSR 146 &t3 3 162. 1 . tMI71 :10) 1. Institut elemomtoorganichookikh soyedirieniy AN SSSR. 2. Chlen- korrespondent AN SSSR (for Andrianov). (Siloxanes) (Silane) (Polymerization) ANDRIANOV, K. A,,; SEVERNff,-V. V. Catalytic cleavage of dimetbyleyolosiloxanes in the presence of dimetbyldichlorosilane. Izv. AN SSSR Otd. khim. nauk no.12:213-1-2138 D 162. ' (MIM 16: 1) 1. Institut elementoorganicheskikb soyedixenly AN SSSR. (Siloxanes) (Silane) (Catalysis) ANDRIANOV, K.A.;.~EVE~MJjtj IZMAYLOV, B.A. Telomerization of dimethyleyclosiloxanes. Report No-33 Reactions with trifunctional compounds. Izv.AN SSSR.Otd. khim.nauk no.2:282-290 F-163. (MIRA 16s4) 1. Institut elementoorganicheskikh soyedineniy AN SSSR. (Siloxanes) (Polymerization) ANDRrUNCIV, I.A., EVAMI V.T. Telamarizatian of siUcam-argmio cyales. Peport subadttefi for the 12th Ccofermos on hi4lb solsoular velabt oaq*undo devoted. to amamrs, VWm, 3-7 4rU 69 ANDRIANOV, K. A.; SEVERNYY, V. V. Telomerization reaction of dimetbylcyclosiloxanes. Report No. 42 Reactions involving silicon tetrachloride. Izv. AN SSSR. Otd- khim.,nauk no.1:82-86 163- (MIRA 16:1) 1. Institut elementoorganicheskikh soyedineniy AN SSSR. (Siloxanes) (Polywrization) Silicon chlorides) SEVERNYY, Vadim Vladimirovich, kand. khim. nauk; IICVITSKI'l. Eduard Grigorlyevich, inzh.; STAHOSELISKAYA, N.Ya., nauchn. red. (Synthesis of organosilicon oligomers and polymers and their stabilization; survey of foreign patents] Sintez kremniiorganicheskikh oligomerov I polimerov i ikh sta- bilizatsiia; obzor inostraraUkh patentov. Moskva) TsNIIPI, 1964. 34 P. 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