SCIENTIFIC ABSTRACT SCHASTNEV, P.N. - SCHAY, G.

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SCIENTIFIC ABSTRACT
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SIMROVA, G.M., otv.red.; SEUWV# S.Iv, red.; BASHT-AVINA, O.H., red.; VORONINA, A.H., red.; GURIVICH, I.V., red.,, EASTAVSKIT, red.; K02LOV, P.X.*,,red.:; LARIN,T.A., red.;.RAUSH, V.A., red.; SAKOYLOT, I.I., red.; SENUMTA, G.K.. red.; SLUMM. TeI.A., red.; STROM, 1,7., red.; red.; TUTOGHMA, V.A., red.; IRM-T, V.G., red. [Geographical atlas for the fourth grade] Geograficheskii atlas dlia 4-go klassa. Kozkvaq Glav,uprav,geodez. i kartografii K-va gaol. i okhrany nedr SM, 1960. 16 p. (MIU 13:8) (Atla'ses) SOKOLOV, V.1-4. PrInimal uchastiye MYS1IFFSKAYA, Yf).11.; SHfiff, S. 1. , red.; BASHLAVINA, G.N., red ; BIBIKI A,Ye., red.; Z-ASLAVSKIYJ I.I.,, red.; KONLRATIYEV, B.A., red.; WIASISHCHEVA, Ye.I., red.; SOL0111YEV, A.I., red.; STROYEV, K.F.,.red.; SCHASTNEV, P.D., red.; TPIWIKOVAI i.I., red.; TEREKIIOV, N.M.., 'I!"ffa'.-,-'WBZOVA4-N.A., red. (Atlas of Moscow Province] Atlas Moskovskoi oblasti, Mosk-va, 1964. 12 p. (MIRA 18:3) 1. Russia (1923- U.S.S.R.) Glavnoye uprEirleniye geodezii i kartografii. SCHASTNEV, P.V.; ZHIDOMIRCV, G.M. Isotropic hyperfine splitting on a fluorine nucleus in eleetrciw, paramagnetic resonance spectra of free radicals. Zhur. strukt. ichim. 5 no.6-839--844 N-D 164. (MIRA 1814) 1. Institut khimicheskoy kinetiki i goreniya Sibirskogo otdeleniya AN SSSR, Novosibirsk. ZHID(X-fIROV, G.M. SCHASTNEV, P.V. Determination of the integrals of dipole-dipole hyperfine In teraction of electron with nuclei. Zhur. strukt. khIm. 6 no 655-656 JI-Ag 165 ('RTRA- 19tl) 1. Ins'!'tut khimicheskoy kinetiki i gorenlya Sibirskogo: AN SSSR, g. Novosibirsk. Submitted May 27, 1965. A. k. Q :Z SHUBTSOVA, I~G.; DNITRIYEVA, T.Sq SCHASTNEV, VOB.; GLIMW,' SA. Intrinsic viscosity of pectin. Vysokom.soed.:5 no.ltl35-138 Ja 163. (MIM 16: 1) 1. Saratovskiy gosudaKutveauyy universitet im. M.G. Chernyshevskogo. (Pectin) (Viscosity) S= TVI'M A. I. "Selective Systematization in the Functioning of the Cerebrum in Dogs." Cand Med Sci, Tbilisi Medical Inst, Tbilisi, 1954. (RzhBiol, No 3 Feb 55 SO: Sum No 631, 26 Au-n, 55 Survey of ScientLfic and Technical Diss- ertation Defended at USSR Higher Educational Instit-fttions. (14) SGHASTM, A.I. Restoration of temporary cortical connections present in a latent condition. Fiziol,zhur. 42 no.10:844-848 0 056. (KM 9:12) 1. Iaboratorlya f12iologii 1 patologii vynshey nervnoy deyatelinoBti Instituta fiziologii im. I.P.Pavlova AN SSSR, IsningrBd.. (RULAX, GONDITIOIM, restoration of cortical temporary bonds in latent cond. (Rua)) S C HA T97L-~ --I Changes in the bioelelectric.activity of extremital, muscles observed in dogs in the course of developing conditioned electrodefensive motor reflexes. Dokl.AN SWR 107 no~2:350-35:L Mr.156, WaA 9:7) LInstitut fiziologii imeni I.F.Pavlova Akademii nauk SSSR. Predstavle- no akademikom X.M.37kovvm. (CONDITIONED RESPONU) USSR/Human and Animal Physiology (Normal and Pathological) T Nervous System. Higher Nervous Activity. Behavior. Abs Jour :Ref Zhur Biol., No 6, 1959, 27o6g Author :Schastnyy, A.I. Inst Title Manifestation of a Selective Systemization in the Work of Large Hemispheres by.Meanfs of Substitution of Positi- ve Conditioned Stimuli in Dog. OriG Pub Zh. vyssh. nervn. deyat-sti, 1957, 7, No 2) 278-284 Abstract In 4 dogs, a system of conditioned salivary alimentary conditioned reflexes (ACR)-system A and system of defen- sive conditioned reflexes (DcR)-system B was worked out. One of the stimuli of system B (M 120) was transformed from defensive into alimentary, a fter which the charac- ter of action of substituted defensive stirm~li and elec- tric current on ACR were observed. Inhibitory action of substituted conditioned stimuli from system B to Card 1/2 USSR/Human and Animal Physiology (Normal and Patholok4cal) T Nervous System. Higher Nervous Activity. Behavior. Abs Jour Ref Zhur Biol., No 6, 1959, 2-jo6q system A had a selective character (past DCR - M120 was inhibited, other ACR were not inhibited). The applica- tion of a current of great power induced the decrease of the value of all ACR. In accordance -with being further removed from the moment of action of the current, the value of ACR increased, approaching the initial value. The Manifestation of selective system is explained by action of negative induction from a defensive center to the alimentary. I.A. Slavitskiy Card 2/2 143 USSR/Human and Animal physiology (Normal and Pathological) T Nervous System. Higher Nervous Activity. Behavlor. Abs Jour Ref Zhur Biol., No 6, 1959, 27064 Author --&_chastnyy, A.I. Inst _ Title Manifestation of Selective Systemization in the Work of Large Hemispheres by Means of Substitution of Inhibito- ry Conditioned Stimuli. Orig Pub Zh- vyjeh. nervn. deyat-sti, 195T, 7, No 3) 398-4,01 Abstract In 4 doGs with stabilized stereotype of alimentary reac- tions (SAR), a second stereotype of electro-defensive reactions (SEDR) was Produced. Substitution into W of one or several positive stimuli (S) of defensive re- action (without reinforcement) was not reflected on the action of S of SAR, but inhibited conditioned secretion to Sj Which previously had a defensive si6-nificaace. Inhibitory S of SEDR, substituted on the first place Card 1/2 ffel:7vo Ysltem-_Wj~T-Wr Ner vOus Activity. Behavior. Abs JOur Ref Zhur Biol., No 6, 1959, 27o64 into SAR almost did not change the conditioned secretion to S of SAR but noticeably decreased secretion in test- ing of positive S, which previously entered into sm. The manifestations of a selective system Maybe explained by the effect of negative induction from the defensive center to the alimentary. K.S. Ratner Card 2/2 138 SFT~NYY . A. I. I . A.!. 4'Vs'Lol-ogical rechanisms of Jr-adequate m-t-Lons. lllauch.soob, Inst.fiziol. Ali SScAR no-3.,U6-:,-,',,S 165. Ultraparadoxal phase in the process of formation of differentiating inhibition In monkeys (capuchins). ibid.:149-153 (MM4, 18:5) 1. Laboratorlya fiziologli i ekspfjrJrrent.%l troy patologil vynahey nervnoy deyatellnosti (zav. - F.P.Mayorov [deceased]) innUtuta fiziologii Imeni Favlova AN SSSR. ACC NR: AP700*2940 UR/0020/66/171/006/1454/1457 AUTHOR: Schastnyy, A. 1. ORG: Institute for Physiology im. 1. P. Pavlov, Academy of Sciences SSSR (Institut fiziologii, Akademii nauk SSSR) TITLE: Physiological analysis of "voluntary" behavioral acts of anthropoid apes I (chimpanzees) SOURCE; AN SSSR. Doklady, v. 171, no. 6, 1966, 1454-1457 TOPIC TAGS: chimpanzee, experimentglanimal, animal physiology, behavior pattern ABSTRACT: The complex behavior of two chimpanzees, Lada and Bodo, was studies by thel. method of motor conditioned reflexes in the anthropoid diyision of the-Institu'te for Physio logy, AN SSSR, Koltushi (Institut fiziologii AN SSSR), to investigate the feasi bility of analyzing the behavior of higher animals by Pavlov's methods. In a first series of tests, the animals learned by experience and trial and error duri.nga pro- cess of inherent, tentative-exploratory reactions to assemble keys and to open the circular or square locks on chests, containing food or toys, respectively. In a. second test sdries, an additional apparatus was used, containing in the first and third of three sections the keys to the.food and toy sections of the first apparatus,, respectively. The sections of the second apparatus were opened by a sequence of 1 actions, involving activation of buttons and insertion of tokens into appropriate :-Card.Ir l/2.-_____. -UDC.-59-1.51-- ACC NR: AP7002940 openings. Associations between the arrangements of apparatus 1 and 2 and motor re-, actions were established. Thus, a connection between visual and kinesthetic nervous cells and the motor center of the brain cortex was formed, and subsequently, a con- nection between the latter and one of the unconditioned centers of food or play. The, animals learned in special experiments to go through the sequence of motions leading to food or toys, respectively, depending on excitation of the corresponding desire. The possibility of directing and predicting the behavior of apes proves that the studied physiological laws are actually the cause for the complex forms of "voluntary' actions of anthropoid apes. Paper-presented by Academician V. N. Chernigovskiy 17 March 1966. SUB CODE: 06/ SUBM DATE: 17,Xar66/ ORIG REF: 013 ATD PRESS: 5113 Card 2/2 MIRONOVv S.A., doktor tekhii. nauk) prof.; KRIVITSKIY, M.Ya.9 kand.tokhn. nauk; LCHASTN1Yq pri udhantii: DUBOLAZOV9 N.M., inzh.; SHCHEDRIN9 A.Ya., inzh.;-IFTIMA, G.A. redw izd-va; BOROMEV, N.K., te~6. red: [Instructions for manufa6turing large air-entrained concrete hrticlesl~ Ukazaniia po izgotcrAeniiu. krapnorazmernykh gazobetonnykh izdelii. ,-'Moskvaq, Gos.izd-vo lit-ry po strolt., arkhit. i stroit. materialamp 196o. 30 p. (MIRA. 106) 1. Akademiya stroitellstva i arkhitektury SSSR. Institut. betona 1, zhe- lezob*tona, Perovo. 2.-Chloh-korrespondent Akademii L. stroitellstv~ i ar- khitekt~aT SSSR (for Mironov). 3.leboratoriya yacheisty1di, legkikh i uskorew nogo tverdeniya betonov Nauchno-issledovatellskogo instituta betozia i zhelezobetona Akademii stroitellstva i arkhitektury SSSR (for SchAstnyyp Krivitskiy) (Continued on"next card) MIRON0111, S.A., - (contiriued) Card 2. 4. Laboratoriya strbitelInyWmaterialov Zanadno-Sibirsko o filiala X Akademii stroitellstv-a'i,arkhitektury WSR tfor Dubolazov~. 5. TSen- traltnaya nauchno-issledovatellskaia laboratoriya Rovosibirskogo sovnarkhoza (for,,Shchedrin) (Lightweight cozierete) SCIIASTI.IYY, N.G., inzh.-polkovnik; KISELEV, A.M., podpolkovnik "elw-.-- sluzhby; SOLDATOV, A.S., inzh.-polkovnik,* KOLENSKlY, L.Ya., inzh.-polkovnik; STEPANOV, I.P., podpolkovnik; SKIRNOV, V.I.p inzh.-kapitan 2 ranga; MOROZOV, B.N., red. [Invention and innovation in the Armed Forces of the U.S.S.R.] Izobretgtellstvo A. ratsionalizatsiia v vooru- zhennykh silakh SSSR. Moskva, Voenizdat,, 1964. c)3 p. -12) (14IRA 17. ZYKOVA' A.S., SCHASTNry' V.A.. TEFREMOVA, G.P. Determination of natural radioactive aerosols in the atmosphere, Gi-ge i ean 23 no.lo:62-64 0 158 (HIRA IIS11) ?ArR, natural radioactive aerosols, determe (RUBD (RADIOACTIVITTP natural radioactive aerosols in air, determ. (Rua)) RIABKOVf A.I., inzh.; SCHASTNYY, Ye.l.,In--h. Traction force tran5mis8ion to the carry.-Ing belt cf a K"-T,~-3 belt-cl-iin conveyor. Izv.vys.ucheb.zav.-, go-..zhu--. 9 no.11. ILO-I'tj, 165. (WRA 19:1) 1. Kharikovskly Institut. gornogo mashihostroyenlya, avtomatiki i vychisliteltnoy tekhniki. Rekomendovani kafedrof gornykh mashin i rudnichnogo transporta. Submitted Feb.25, 1965. I el n d MA ORY AB3, JOUR. RZ-Xhiin. , .:~.'O. 22 _1939-, .1~0, AITT"HOR Schatt. W. Not Tiven. T Z-~ Results from Recent Studies on Alumina-Based lermets OR111. PUB. Przegl&d Mech, 18, No .5, 131-135 (1959) ABMIRACT A review of recent work done at the Institute for Materials Testing (Dresden, GDR) or. the dev- elopment of the production technology and on the testing cermets containing ('in wt %):- A1203 1.5-90, Cr 10-98,5. Aluminothermally produced ( a-- 5 metallic Cr ( -t 40 /.A ) and technical A).2 O~ , ,&_ ) are ground together in atteel mille for 50- 3~)O hrs in gasoline Pbenzin'j; the ground prod.- vct contains about 2% Fe. The powder is compacted C in hydraulic presses under a pressure of 1,000- C.i RD 1/5 all ABS. JOUR. AZXhim., --~O. 22 19-39, -;o. 79246 ATUTHO? 0K(1. PUB. AB%STRACT the shrinkage is 10-14%; when the luat-named sintering process is used, products of improved properties are obtained, except for impa-atetrength During the ainter-ing some solid solution of CrO, in A12% is fcrmed, thn Dr--ticipal result being the formation of an Al, G~ skelet-ozzi held toget-her by (or v-ce versa). Data are,given on the struc- ture, reaictivity. mechanical properties, and heat resistance of A12 f)3 + Cr cermets as a func- tior, of Cr content. Cernets containing 10-30 and 3/5 .CATEGORY CARD: 5/5 H-13 ABS, JOUR. RZIhim., 60- 22 1959, NO, 79246 AUT.-HOR ORIG. PUB. ABSTRACT containing 10% Cr. The cerinets.teated were found to have a rather iow imp&ct strength, 15-25% of the impae-Vatrangth of cast iron, In the present state of th'e technology and knowledge concerniAg the properties of A-4 C~-Cr cermets, only two possibl-3 fields of,application --an be indicated: rods exposed to high'temperatures and protective sleeves for immeraion thermocouples. S. G H fl f-7-1 CzECiROSLOVMA/Chemical Technology. Chemicai Products and JI-3 Their Application** katural and-SYnthetic Rubb,3r. Abs Jour:.Ref Zhur-)Wmiyaj 1958, Wo 11 320b - Author B. Meissner, m. Schatz Inst Title Statistical Methods for Rubber: Conpounding Orig Pub: Chem. Prumysl, 1956, 6~, vyp. 67-70. Abstract: The principal methods were considered which are used in developing formulae for rubber compounds: the classical method, the factorial method., the method of aqua-res. The latter is applicable to a large number of variables, is characterized by accuracy, and permits the determLna- tion of the effect which individual factors have quan- titatively. Practical examples of calculations aire Card 1/2 'Thdustrial Use of Silicones CZECH/3510 hydraulic fluids, pils, lubricants and pastes are tre&ted extensively and the role of silicones in medicine.. pharmaceutics and cosmetics,production is discussed. The use of silicone resins in the plastics industry is also, treated. No personalities are mentioned. References are given at the end of each chapter. TABLE OF CONTENTS., Preface T Ch. I. The Chumistry of Silicones 9 1. Basic concepts 9 2. Preparation of simple organosilicon compounds 17 3. Production of organosilicon polymers 22 Bibliography 35 Ch. II. Topical Properties of Siloxane Polymers 39 1. Effect of the structure of the siloxane chain 39 2. Effect of organic substitutes 49 Card-2711r- SCHATZP Miroslav 411764 S10611621000102311061120 B101/B186 AUTHORS: Matoua4ek, Vladimir, Sc.hiitz, Miroslay, BaXant, Vladimir TITLE: Method of producing the-r-mm~tl-c -Polyorganosiloxanes PERIODICAL: Referativnyy zhurnal. Xhimiya, no. 23 1962, 728, abstract 23P399 (Pat. CzSSR 95379, May 15, 1960~ TEXT: Thermoplastic polyorgano3iloxanes having the composition Wx (RI)ySio (4-x-y)12 are obtained by hydrolyzing the mixture:of the corresponding chlorosilanes or alkoxy silanes4 R H, F, or a.monovalent aliphatic radical; RI is an organic radical which contains ~~6 c atoms,- preferably also halogen atoms, and which ha6 a noticeable steric effectj x/y'~I,'and x+y is a number between 0-5 and 1.9. After hydrolysis a .nd removal of the solvent, solid brittle resins are obtained which are soluble in nonpolar and in most of the polar,solvents. These polymers (PIA) are thermoplastic because of the steric effect of the substituent, which prevents further-polycond,ensation of.the solid PM. The PM are .,cured, by the usual curing agents, e.g. triethanol-amine. Prodifets with good Card 1/2 S/061 621000102311061120 Method of producing thermoplastic... BiOl/Bleo" mechanical, electrical, and thermal properties are obtained. Example: 112 g CH SiCl and 475 9 C H SiCl are mixed with 500 ml toluene. In the.. 3 6 5 3 course of mixing, 1000 ml water, 500 ml toluene, and 500 ml ether are gradually added, After removing the aqueous layer# the mixture is washed with water until attaining a neutral reaction. Then, the ether and toluene are distilled off, and the molten PM of,the composition (CH 3)0.25 (C6H 5)0.75S'01.5 is poured into a bowl. Abstracter's note: Complete tr anslation.] Card 2/2 HASIK, Jan; IMHOF, Peter; STEINMANN, Bernhard; SCHAUBO Hans Results of cardiological examination of patients with bilateral paralysis of the lower extremities following the administration of noradrenalin and hypertensin. Pol. tyg. lek. 18 no.41:1509- 1513 7 0 1163. 1. Z II Kliniki Chorob Wewnetrznych AM v Poznaniu; kiercnmik: prof. dr Jan Roguski., Z OddzialujWewnetrznego C.L..Loryhaus (Inselopitak) Bern; kierownik: prof. dr IBernhard Steinmann). (PARALYSIS) (LEG) (NOREPINEPHRIVE) (ANGIOTENSIN) (HEART FUNGTION TESTS) (PHARMACOLO(Z) teftIffiffriffletm, P.M.-M, r4-*. SCHAUER, F. ~ I ~-~~tscn of h 9Ljm4Lwwsvjlh -:-.- tu, ~4 mwbbne- a-.Jwivf CTO 4 4 '1 the itqqjicjtj,= of !h,s t,~ a ne 0 preparation Uf4Dr -Tophlaroglucirsol The --:rl-ml mecill- nism of chlnrn~nlfnnsflnn &nA nt -m-v1stion I- Ltlu SO -te A new synthesig of I eft2eve and the 2 3 5 trAvL1r=b decolorized with C In 10 cc, Ft K 'rear.Md" 3 - ' . . . 'Pr lem an 1. flic z , `~ L yielded, 1.23 g. pure W, colorless dks; nest m4 ~ W~ ' ' h. Univ. U-u r- I % = wartz (Teel ffir-ffirr-- IH . 16 1 I C.FL(OAc)* (50 g.). m. 121-1.5 yield and (prepd. In 9790 " , dried in must at 3046 ), added slowly during I hr. with - * CjTt(OH)4 (1) was prcpd. front ~-Cji.,(0111)2 40-40% in stirring to goo g. IINOs at -3 to 5% the mixt' stirred 10 ' l x -of I -over-all yield. The (r-T) m n. tit 0% poured into appro . 11. crushed ice and the & W L tr-,ttcd Witti 1' 'NOolcuni at 0* gave El,!: 4-01N der V. (III) - ppt. washed with four por- ' oM. -1he feireenrle.-fe (IV) of I 5r.,t%,q with Br t ha di-HP deriv.. tiogs of cold I IzO and dried in racsio at 30-40 gstv~,40.2 j 0 4 d A M N e - . with Est ane, IICI yielded (V1. ' 1l , 11rc l ! t W .4- e 4, )., tit, 94 cOA )AMOH (0 (V ~ ) cru leld irecrystd. train 10 vots. 952; EtOH ed with 15- urs s. crys a c ye sw ), pa ( z ' I 1 17% loss pure VIff, tit. 95.6-M NM (13745 j.) 12 9. -7.) in :TM cc. beat HeO refluct! 5 ~rs. fit.;i rl (15 Dry l , land 570 -cc. SuCl - IM g. 'ghantilated Sri (cii So filings) 2 ov.-isli-brown soln. str=nt of CO-, the -cwW=~ px!e yel ' 1,~t stand 2 bra in a st:-tan, oi H to 35 :c n ice and c ncti , , s:r;ncd . 110 heated slightly with frequent shiLking until, . i . ., u , fltzr~,! of;ntid dried invaci4gave after about 10 min., the reduction'started with taming : (VII) HCl salt and the mixt. heated 45 min. to gentle boiling after the fomtn; lind ezisedi cooled filtered through l; us wool treated OX) kro..... wi:ica the Y_t; c,,,:!r be isoLvt!tl ony by acetyla , , , g ' l7r. at 0 with ri strong stream of HCli cooled 2.6 hi-A. In. 1", ' r hydrolyzais oz' the Ac dariws. prtzee&L' only very.,slowly and watcr,:and the cryst. deposit filterid off.thiatigh a glass, ' - ~ . not yla-ld zolid prcilacts. The mixt. of V.11.1-10 and fit ter, washed wit I i three I 5-m. portions of coned. Hel, and dried in vacsto over NaOH 'gave 30.4 g.~ (92%) 2 6 14- -, 't1%2 sdin heated 10 his frecd from aIr by bo- nz) , YTiN1sQ1TK0H)j.21rC7 (IM, wh darkenid - within 'i~3 . . _ . , ed t- Amys a airi but could be kept ifthbut de6ompti.4ji Oicits. 2. ' ' 1.0 drops 207vaq. 1Y_ (74 g.)In 150 ce. 1% HCl (previously balled) heated Is- 4 Pb1OAc the fl-trale treated with II-S. filtercd, filtered : 14 luj. In a sealed tube at 1" In the. presence of , . . %td. with fve 70-cc. portions of EtO, the ext. dried with (7 ing. Sn foil, the brown mirt. cooled filtered. conc& to 35 ' Q 1 a H strewn. the brown tacky evapd. to drynt--i in cc. in ra"a in a H stream an the ter bathi theconcest . . ODhe and tesidue (LIS -.) relluxed 1.1 rain. with 1.5 g. N. trate ext& with seven 100-W.- portions of Mg0i the ext. ' d,!d. with 15 ce. cold H1.0, 41 the mixt. cco!cd 5 cc AcjsO IriesIxith Nk-SO4. the RtsO distd. off in a R stream. &n& . . , , and the ppt. vrashed -.,:Ith four-3-cc; portions M HIO,a"A ' the salld resildue powdered ve~ 3,5:3.145 Z.: 77-27,D), in - IG3-4' oy3dized readity'r. y stored as 1 ' .*w1sk-111 'Ariedin mcus; over H.SOt gave 2.01 z.IV, in. 054 , V i; Ui t A oM I ch it could e Rb td ~M _HCI In , e Y tr_ 2t 407 e, rMeOH. J (3S6 g.), M. 163-4*, 5.45 NaOAc, and 15.2 g~ Ac2O refluxed Ifintim, the mist. cootedi'aruli the resulting :browriisih-~grqy solid ground with 55 cc. with four 8-cc ti 9- ddidin cu&atSG:(10*yieJ&d7-77. g. (92.6kriv"7, lov. "Crude,IV (7.70 g-) in 40 cc.*ahs.. !HtOI1 treated with 0.4 g. C. filtered lint, the filtrate re- frigerated 10 hrs., and the cryst. deposit washed with three 4-cc. portions of abs. EtOU and dried in ractic, over coned. :112SO4 gave OZ2 g. pure IV, almost colorIcss rrystak. ra. ~104-5% IV demethytated with HCI in AlcOlL and-the :resulting I pptd. from its soln. in LtOAe %kith -CHU 9~vc pure 1, m. 165*. 1 1 g.) in 1.5 cc. diaxan6 heated 1.5 lits. cc. CSs an the-water b th thc~.~cilji. cooled, piiured into 20 cc. cold,lizO, lei stand ~vcraight ,and the resulting solid washed with three I-cc- portions of M% MOH and dried gave 0.66 g.,(43.4%) crude V, in. 55-7*, which, recrystd. from 8 cc. 9570 RtOlt with C, 1 cooled 5 hrs. In ice water, -washed with three 1-ce.-portions 'of MOH, and dried in vacito over P20s:yielded 0.41 g.- re V, m. 158', unstable and decompd. within 2 motith4 to rbrownishblarktackyrnass. I (I g.) added during 15 ruin. :with stirring to5cc.98% IIN03at -5*fundthe-brownish i red mixt. let stand, 40 min. sit 0-5* and poured on 40 cr 'crushed ice gave 00-W mg. oil which decompil. completcl . Y ,onstanding. I (0.5g.) in I cc. glacial AcOll treated within 5 min. at O~5* vnth 2 cc. glacial AcOll and I cc. 08% IINO,, :the resulting red-brown soln. let stand 40 min. at -30 to()',~ poured into 20 cc. crushed ice, and the solid ppt. filtered, ,after 0.5 hr., washed with three 2-ce. portions of cold 11,0, and dried in vacue yielded 0.42 g. crude recovered 1, pale, yellow powder, m. 93-6*; recrystd-twice from abs. MOR, m. 105 . Crude I (I g.). m. 164-6*. in 15 cc. dry pyndine ;treated during 5 min. dfopwise, with shaking.-with 5:g. 'MeSO2CI at -3*, the mixt. refrijrm. ted MY hrs.. dild.. with q -140 cc- ke water'. Wa.-me, -iu COO- --via to- 0 adjusted witIr contd. HCI. to 011:1. and tile 111tc--ed olf after 0-5 hr.-, washed with two 6-cc. port!ons of; EtOR, and dried in iarma at-501 gwm 3-.2 -Z.: (100% II, slightifYcHowWbrown solid m. 1354*- the crude Pitiduct dL"rilred-in 12 cc- hot !R.AcOlni the -:o:U;,trea-4 ~qith C, refrigerated 12 ltrs*.l and the resultingcryst, deposit : - tOR arA dzicd'-~ 1'-: * wxshed with five "-cc. portions of 95?~ E In.1141CRO at UP nve 2M g. ]I,- tn. 147 , which, recrystd. froin 4TOIS. Mc-co, yi"Od pi~q:lr, co!o-.!csS, CUS-15, m- 162.5', CMilY SOL in. Warni'' glacial 'AcOH aiid Me-CO 'Slightly Sol. in Clio" practical"Y iuqDl_iii.co:d 56R': sol. in 200 vok., lint- aOl wd. 11 (0166 L-rineq po :-fix ~ 1521. ad(lediiithin 10 nln.wLthstirrrn;~t-5*,t-o,,I-rc., 03% lIXO:. the soln-~Pourcd Jazinediately on 15 cc ice, and the solid i~pt. ira,~;ljed with three . k 2,cc~ rtions cold - 11,0 and drim g.LN 0.1210 x. recovered N, tal.,150I.-ji-, wai recovered unreacted V1116 treated similarly 0.0 fir. ai. 37 to 0* Ivith IIN02i A g.) In. 152,, added With stirriAg at to-2 cc.1100%.M& and 2 cc. 20% Gleam, the mivt- let stand,20 min. at 0', pouxed on 30 cc.: crushed ice, and'the pale );Llloiv Ppt. washed with five 0-5- cc. liortious of 11,0 and dried.in vacuo yieldM.0.1 gag (0-1.5%) crude 111, in. 44T-S-8-50, which, recrystd. afrom .. 2.7 cc. .50% hot AcOR with C. gave 0.1470 g. pure M pale'. solid, in. 148.5-49': also obtained wh th 'i , en, e mixt - - =pt 75 mirt.'alf 40~4*. in (0.1192 g.). In. 148* add;~ Within-16min withithrint" Cc. 50%HROan -1 GO% oleurn at -51. t arts, I pa her i-t- let stind 20 firs. at ()*~ se~~d into 2 p. rt heated 4 lirs. at 75-M*, poured on 10 cc. ice and tile ppt. washed and dried gave 0.0421 g. recovvrcd.~ in. 143*; the other part of the mixt. let stand 7 clays at 0-, heated 4 hrS..at 75-M*i and worked up in the usual r"a""rr pit-, g, r"'rerett 117 In '14q* WA i`7 ~2 tt he i Myl:t~oq by t ile Stark n rMee of the Mviyldo~ tollp'! ~RVPOA66h,pq tiM IL an On -ilea 12 "~713 G-Ao- 40 W V r6orclao -7 ~11)~ trimesyl emter of phlatzglucin6l (11) `the Miloafii~ td ativ. (M) of M and ~?,he I nitro (Y) derim of.Ua=1,d.frota viduclof boadlerisiths'i ;Valence angles, nut at. radil, and the results am st wn Inl tables olmak.-ovul pleg Vidues and dlapaiw of moddsot, L (cf. Ilriegleb, V_4.~44,',7783g)~ JtAs SbOmInt ~that a G* deformation'of1the O~C-O valesmangle, by-. Which the OSO Olte (ruesyl) group Is moved away fmlii them X% group, a shnilar V doomation, of the corresponding 01 rotution of die~~Mi, q. valence angle OUthe NO~ N.R. 0 Uf of the beAxcne'nnrj-. around'the C u)6d on bf the plati Lnd a 70* ratation Qfjbi,,raesyl a thQIC-o~O _groilp arou d' Pflipping 0~ bo'd result in! af out ivin th room tar all 3 sulistit4ents.;; -13y it sinfliar rotation and, %1 . - - - : I 2nd mesyl:group, W.." defomation. a, the vaTxncq atag o a 4 7" 2nd NTOj Until) With shallat valence angle deformaddri and", uud the bdidla~'avdlablt- S 00* rotatioti: aro pace, J knj of M:"Ilven Ni jwfth. slight overlapping) for the format ence elnglechmixes, alterAmilar val d is shown pp~i rotAt rotatiqat of the 3rd mesYL and NOz groups. Suce J M bf the gioups Are stexiedij- bindemi Intr6ductim c candi he,lst;NO, 9=0 int 11' M-Cluirw rA*r*e einergW 01 than does the tdtratloji -bfthit. triacentle of cp ~Adt!A. Pf 9~" A. fm f expt pfLm~_IILS cmr4W~' 15 'A A_ ' " pd%vtl.- at'01, chirtag 16 ;4a. to .2 11N0" ol'.~ 4II&JU nil, 201,,o' 1"tittifn It'AllAo iiiln~-Iit ino 161 Yv)w, yidkil 2,4q K;'(0J1pP cttkk IV., ro. '0411t, 14134- d nil - n9t - froin hot r)Wto -Moft anti Mu'l - FronI . O ." -M&CO gaire 6.59 x; pitrc,M, in-- Under. th _;e'Mft( R - - G~ t no V roquftfdl~ pri)4 2bly wwwlly bocittw 111ndrance.-Ijul:a1so bt~caiisajjle groiallic rinf, As strim ly da.' act vate -.h th ck;ctrotl I d -itibstwelits alrim(If -0 t 1 en 0,32 gJ lit 10 ail. ~UsCO. treatt:d ivid'd 11. V 'V I ' ~ ' .5, N. ft ,:Rtixe,f 10 lt~s -at 05 on At Hit) I)dfji C~Va (I ; iff Mrao to tf"~zwe.L. ihe lasaltili ri:Maining ~nud "Il mo vet a I f A inI.ALU and acidificit ~dtb 2 rw~ Cmied; TICI, yieldi'll - - -P) I k -(1.512 g. (70 1) crude dinitrophlorogiticinol (VI)j Ir It age T m f; frum H-0 ovr- 0. 1()') tcmpk I fig In, abo#4 ISN . rocr~std, -Ah 9. Pam 'W" M. 2Mz ~' sorption curvm httprctti 200 and ' -h NO. MIL am s ovvti *for VI, and for c non tn)~, ~otnliafisoti, in* I , Ind ttin Lown Ch. _ Is' l til Goguonyl Acylation with MothJIM Chlodik. 1U. A W lfi 601 dent i nosylates of 0,0-dia WO 4154 4~ 20 H A d M Chi c EI!U_, I d cde) _W. . m . ung, o , i C-4. 40, JJ583Z.-2,0,I,4-(0W)sCJ1 0 abs. CJ18N was treated with 0,11 ml . at 0* and dild. with H.0 t Pt. Yellow mono-mesyl ester, V1 - CO U1 I n3m ). Tre%tiug 11 .f aq 0 T 'abs. CstfiN 4 min. w th 0.14 S. I at 0* dil with 6 Mi. ket o 8 2 i f 051 d 50% j . rom m . recrystg, j gue g. HjO, an . I60' t I OSO K 1U M d h e was orme . ),M. v( 2 ( .QsN~W B el - not be Notated d after 2 min and could 6 ; after 10 2.6,1.44O.N).(kO)CJ1rQA, (IV) (0-484 g.) 'in 12 mi. abs. CGH*N was treated with 0.3 ml. iato% Mg., Ith lee HiO after 10 min. pptd. an oll which solidified to w orange-red crystals. Recrystn. from 4 mi. 25% aq. MejCO. !.OAinitro-4-hydroxyphenylpyjidialuin methanesul- e rv 159'. a te on 2.6,I,3A4-CIAMeOX0jN~CtHOH in 5; 7 mi. abs. CJ4N wa3 treated 5 min. with 0.26 C. I at -40.~ ' Working-up as Wore gave the methanesullonate, m. 171 475% aq, hfc2CO). IV in Etz"ioxane gave with CH,N, *r(V), m. 68*.- , Boiling V In MeOR with HC1 the Me ett :'Z gave 4-HO compd. (VU, m. 152*. VI at 0* with 118 brB. nate (VU), rn, 100' (70 aq. me2co).; aye methanesulto Refluxing 0.58 g. V11 with 3.1 g, Br in glacia APOH 10 hrs. in the ptesence of 20 mg. Fe filings gave after pouring Into 20 ml. Ice a pt. which recrystd. from 50% aq. MeOll and -i B l 128% 1 l bf 3 d 8 YO (110) - il e r . m comp i,m. . gu . Henry Feuer~- I I 1 -0 -W wil wil -M "ll TA X11933343bux v of 41 41 0a ace A I f.. .-A AL-A-A" XI- T 0 IV --l-L-A a-CMC IWA A- A--.g A A-0 . 1 -.1. . 'It'. -Of cow4stmticn. C~. Kij,,let. K~zlemamyrk 31, kTa ptim. Dit FlCALT moo go es ago so, q i;** 00 oes 0 see coo sof, See .00 ct.11WIC.11C. Moo 0 too 01 n L, a a a q a 2g a ft it t tw a I a 4 3 1 dqd: 0 0 00 0 0 0 41 o o 0 0 00 4 00 000 0 0 0 ~,T: 0 * 0 0 * 0 * 0 eall : : : : : -100000000009090 a as 0 D'O 6,09W09006960006000 0~0 ~0*0000009000*000000~00,0000*000000000000~0,0*00:::o 1:9 DO a c C,T S, .4 41 In M It V A V j IT C~ AT Is n 0 If 6 " ~t. ~ a . to d . .-A-2-4, -j- __ p , . A ~j _ 11, 1-6 _~ If I.f. j fit* 4!. .. _ * 4 00 On T14,4tv so 00 00 00 P j : 00 0 60 C, 00 0= All-01 I ap 'Q -pultrur aq v Go Aut PU -,p%ITnn., 3tjj %u!vjIjnj Arippoi Iilxa ;tql Ur., II(I!I.1Sjl julpt.1-11VIII 'III all PuT, *up- 0 umqtntla mis '.1j. littv 131P. .,I q. 'q 140. ..-1 Sw 1 '1 1 oil pi 00 . 10 1 ' k, I J . IAIW~ 11011.611,1 J~Vjj )JI11tiq 110 Iff .J Irv 00 In vt 4A -saaq 111u) jOj Sivids lj~-J114 j0 u0niumvia 00 00 so so- *a so- 0 -- - --i r--T A 4 It a It 00 TO 11 11 3 T IT 7 r A` ] pi w m ti n III p rf It ff 61 , ~ 9 1 A. A. A Ak A 91 as Al 41as woo T'he 1a fitom an the sur6wle. This mechanism seems to be fat!-F isf~ciory both from the kinetic and the energy It I Ir 1. Fiuijy lee lAw of Nilsill"nupti.xvins tolichicurmt It emphasizes ; thAt tile 14 tinly ullimol. In be weekly a,1- 00 th" 114 14 1y a,lmwlvnl' l 1114t it 1.1.4vt W.Illy file whole 'Uti,44V Anil "Wes v little free slkwt for tile advivitition of Nils. ResuamisU. X voo%itirring this rate Liw inetwrect am: (1) As a coarlse- .3 (picnce of alontic Julsonni4m the Langinvir a(luIrption Iso-_ 1 Ifirrin 41f III Ism tile (0fill d - 0. % j/(-.4 + Vj) 4nd f l h A f 00 12 u o-u kvitwquent Argument. Inc %quAte rolit o ly t y. Ihe 11 m%%uiv shoulti be placv(11 in the dennotinatur of the 00 .3 , p to law in ac oa d a r 2) Takin t the be t of: 00 u . a a ecoutp r nn . ( g tctivaliott of the dix-oospit. (40 cut. on Cu unit 44 cal. on it 00 Pt surIA 0 in. unial.4. "accimnWit which could sive C 1" l i d w0 r%t ~-Mvr rate law is 1xi-A fife to a b e on energy gnman %. 1 o I jr In order to avoW timse difficilittict it Is prolloatIll that the thtsic picture (accurding to which the deconspis. takes' plaice in the weakly ads-xbcd Nils layer and Is retarded by the strongly ad"bed fit) can be rttalned. but It wasst be ' completed by the following: (1) Similarly totbead=ption ~ of filthe Nits uccupir-t2adjacent placeswlscnsdwsrbed, Atilt thus it Mill. livvtours suchtwell fly 2 of Its H atolvol. the trul.4113ing N It litilk-al IMAnting AWAY ItUM the PUffikV, rarighbor- (:I) The timmupts. Is the reaction of two Hich WOO ing rallicals f(willing NJ And He atilt leaving 4 adsorbed 11 melt LINKAT~ see IF 111,1111,01 ____ -_ we ip 1k. Sasebo map ONT set vaslal ME _V A ' 41 u u 1 1 " a ad 0 0 0 1 v 6 6 A IV IS a 'a 01 p a D a Is a a of it -0,00 6 0 00 00 0 0 0. 0 Ole. 0 0 000 0 0 0 to 0 0 0 0 1 0 e 9 0 0 too 0 a 0,0 0 W* 0 *go*** 0 0 00 0000 G. 3C'IAYJP P. SZOR "Stress-Strain Relation of rubber blocks under compression" P. 3-17 (ACTA C-."IT-:-!:-CA ACA.0,3.1-1:" 3,-~T--7,i-TIAzIYIz ',TJ-NIGARICAE, Vol. 2, no. 1252, Budapest, Hungary) 30: Monthly List of East European Accessions'. L.C., Vol..2 No.7, July 1953JUncl,,,., -,--Wwfiiem-mttcd -dilcugfm d Me tjoiitbi" ~i ~ ~, . - -- ~. , :- . .. ,- , - ~ 4, 1=:-': 'i7-1 = i i ~ ~ I ~: - ., 1: ~. . ~ - I . 1521 ftdt f Gas-atkorption measurarterstj in flow ~p;lo 1114. Gi-In (Vell. 1114~. F lt17-,R(T57-M,,rG%MT17 F' 't (b.to of nlls")rptian fit "%Y~f--17' lit"I'l coollit 1,111 -,q. ,itnd- t thoi~ H n i~ifdllh- reflool, khert -, dr-t(r,k d a -or,0"14 oo Ille bf frow..1 011-MIMurgratillic I low 4 1W ..'I"Whrite '[1--W r-T 1w, I -'r , , " ~ ~,- t ii bcj~- "Ad"lly 41:d 1*111, firov I reqo(riti f,jr ilic fr,-,t I -,e exit ;.q Inea'u'r1l by fi,j! ... ~illi; ib, O',rulki f ,I"e,it gnq Tht, -t uh-rt-l i~ a - ii - w,(. 1. is the bmak-through dme --,' the Incit X-4tj detd. 'felY, 0 1$ tht VOL fet1d -att find C i5 tht RdS*fIkltC in tfieptm, hatherims tjp uIttid from its of a and Dens. cm SO, at 0 vid 15.3' witr COj u nd- h,tle and 11 as carrier give d4ttentlat jid"Igion tr _,iog ft(. with increashig d 'm 86M to OtW mj./tno~ qurfare coverage. A varlatiott nF1 the method In which the gi, i- introduced In "slup" tgth, than mithiuc4tily is di--ed, but tills Involves an wficertmin atut. of acbmrb- W. 3 Brvy, Jr. 0~1 I LL 11, J 11; - Mill Category : HUNGARY/Atomic and Molecular Physics Physics of High-Molecular D-9 Substances Abs Jour : Ref Zhur - Fizika, No 2, 1957 No 3638 Author : Schay, Geza; Szor, Peter Title : Visco-Elastic Pr6p,6%rties of High-Molecular Polymers. V., Spectrum of Relaxation Time with Allowance for the Experimental Log -109 M Relationships, and for its Dependence on the Deformation under Constant Stress Orig Pub Magyar tud. akad. kem. tudoszt kozl., 1955, 6, No 3-4, 289-301 Abstract See Ref. Zh. Fiz., 1957, for part IV. Card 1/1 .CUsgOvYY::hUGUffjAtomic and ~Iol#cular Physics - Statistical physics. Thermodynamics D-3 Abs Jour : Ref Zhur - Fizika, No 1, 1957,No 824 Author : Halasz, Istvan; Lchay, Geza; Szonyi, Endrene Title : Conclusions Drawn from the Analogy of Adsorption and Condensation of Vapors Orig Pub Magyar tud. akad. kem. tud., oszt. kozl., 1955, 6, No 3-4, 315-326 Abstract No abstract ,Card 1/1 Siress-strain re, fiomi In rubtir-blatks valer cvm- .-j T'7771 d a khaviour of pblosr,~UJW 1' The i -MrW theory of AM dultibutiod to the W111116" NUUM ktwfta~ft-i MO-SISM4 Its -Trith ormallon ooptant JV. -. Delmmatton , Lmi funcilm of,fime.--- P~ _ i under uai k on VS Iii 0V UUM of retards&m times an ibe UN - ' gribe empirical Unear between la aawallou with deformatim' v and log M and Its t itrem --QL~~,d P. Szor 4Acla cki"L hulte..', 1 55. 9 -W 14' -MT7403- ~T 132 IM 4 75 96 - - - ~ , -A: n 4 v ew ). . 1[-Alfrey'se Ation for ilZe 4itrbqtio'n function ofTetarda l rr ped and WIthea used. to dete. paw., for, ,One: (igis,dOZoo . th_ U I Ile deformati0fi` 1(4 a! Com j Wi PO ymer. t (&l.. The re~mlft enable the -viscous ti Ar 1; _ ^ -t L- Li f t i l b idi d l 6 m oir4 xv te .strac to d e. fh yrt~po 0 g ~em ,; pq '4%tended time in (d on the OF pfpo ymerd r f* l :. ' '~ r l if f ti I tic = 1 t e d . onna on ra 0 at . e s a qua U ymet a po og 41 moL'of different shes, lnc f ress~ of, With i is retizzled ' 21 j de -ding -on; W ra j V 1. j o (ilia _ 1 VjUg Am equation M _ '-~ilh tho raw. V-t~.- ating y(o r ' Miasuraments* on. natural - rubl)d- - show that Me ba relation betwOtri 10) and i is -valid only It tiu differmt ith diff t i t l ti t d f eren m n. re &r ra o at on me I w PeC in. cham iroups. cn6skctxura, inv~jvft mo - -Yand. the other .segment rnoyament wit oup Z. chain -atomL This twofold behaviour al, the p I 0 YMCT by, the diffesing rnobilities of chWn atoms at ifie nodal The,'effect of temp;,dn the tim"eformation: curve can. I_ 1;::. r- 7~' S' C, ed in terms oll'two, activation int with* th in a be - of low-MOL t -de t the h t W e es c arac c: pen it nerg p. , ng * 1 i " - : ~ and 36 nd of pol iitrl 0 wt. - ~Ifq ' i%a = the na- that of natural rubbm~~ but ai b vi of r above 49.80 them lssomv1rue flow although no permanent defor-, mation Occurs. 111. It is shown theoretically and experim6atally that when the M is not Initially free tram Internal stress. the twadifferent en of retardation times for natural rubber (cf. Part 11) can be - ~ l f EE i i StieSSM t 0a O ~Ie Of 5UPtipOll ying the PrinCi by app W. There is no difference between the retarded (fint) mechan- Ism of natural and vulmniud rubbcr'(0-S-I-.S%*S), but the second nag inechAnism.is obsent In the:vulc~nizcd tqAWAL By com4dp . the moll distribution,of lymcr-4balAt~.tan equatioa-rl;Wlng st,cons*% otress is derivp4 and Is y(l) with I for Vulcapired rub ' shown to be In ageement with Ott, iobsekvv~d - din"erarilkimi I i l2ed rubbers at,25!.~ cuirves for Yu can. 0114 V. : rox tj a/. ~ have establishe d,t Uk,0r;hig1i-moL'wt pol ymen ij I& cc log Af:; The elket of t hlX qn,the distribution function P1 !r (cf.: P64 1) is examiaed, V a-vew equation relating Y(1) with I at constant stress is deji~, ' hd!ils validity is tested turperi- iitnltally. The.modified i,~~'Ofj(fjjhus obtained and based, on the Ing .*-Ing At r - ~ractico only if an Instan- elation are vand In; taneous -elastic deformation: is, assumed -A 'satisfactory q a, u exolanation of the visco-elastic. behaviour of hig _0161 Ii wt~pojymers is based on'a mal. mechanism glidin g'etemeuts) de- (springs and l . , and theoretical veloped from a- comparison of ~the experimental time --ileformations reported in Parts I-V. W. J.: R&KRit, :7 a a ec c c the 09 t liquids by multipli reffiRtroa m trowaves.. Piter Hed-: V, LASZ16 Nimeth, and Uzi, Schi~y, Jr. (M7W E .-M-4 !~~UUMJYCMj Hull Tudom&iyaj Akad.' Kjzpo~lf Pis. KalaM 1Wx4la4k K&.' radiations show, kmb;yvi 4. 48-67(1958).-Blectromagnetic multiple reflection from the boundaries of liquid. dkiec. ' ' layers. The mutual Interference 61 these reflected rays dis- - turb the detu. of the dielec. cousti (1) by the talemwave method. This disturbing effect was studied. and It was ' found thatititfielf c= be used for thedetn. of landthiloss 4 angle. ' The app. consists 61 a 3.2-cm.. reflex OSW-2013 Klystr6n~ tube, the output of which is led into the measuring circuit, contg. a. vertical wive coadLictor with square cross- - section, through in ittenuator. Another Wenuutor Is pro- Z vided to absorb the radiatioms reflected from the liquid in the mekBuring area.., A crystal detectoi-IS used to indicate the -detector is pro. transmitted microwave output. Another vided to check the function of the'oscillator. ~The layer. thickness of the liquid can be varied from 2 to 8 cin 'Can- i ~ 1 in etao. d traction data and operating techniques are given fly exarug~ toluene and EtOH-benzole inixts. It was found . that the method. is - suitable for a tan 6 range of, 0.1-0.001 and that the accuracy. is 11% for tan-6 (a reductlow cail be effecied. by Improving the. ampfitude.and frequen sta-. 'l l thi l Cr bili i i d b d te on ayer accur, I 1% for m ty) an (l y y B i k i h t inemsuremen ness and %vare-l th c ngt s). J. ..- _T- lit 12) 2 l mit gm IfXX T'O F. TO E90 P Ri Ilk LIQVIDS AT.MXW4WAVE8,lDSWQ VIR EVFEWCZ~ a l OF MVLTIPLLP-OFLBX'EON.'- LN&tatti 9M G.Sch .Ret l . a, A ild 337~4(17PT) NoL 6 Azta phli llungir - . ~ .; , Me tranmx!tw~ imeasIty.in-awaveoddils e4 G-bxgupg wave ael funcuaft of sample thicItteso, thii W"i did gwt"~ beLnd the saln,44 lsoq-iiol Fortalflae a~e'&QrtL j ed6ld catimated IW foi i mad 2% lo~ Upi 6.~ da I fv~ 2- 4 av, 4T. Simplified f", the