SCIENTIFIC ABSTRACT RUSANOV, A.I. - RUSANOV, A.K.
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CIA-RDP86-00513R001446110015-8
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RIF
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S
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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3 2151 R
76/50/034/006 02'014
S/C 0 /0
Th e r m, o dy n. ma c theory of... B101/3208
(P (13) (1(3) .6(111)) + C(-,)
2
X('.')) + t!*;` WI) - Xt'))
,
(X( .') - X(2)
12 1 1
22 2
)(2)
7](1) TI(2) - (2;jO X(2))
~t]21
-q(3) -7 7](2) X(2))
J-1 art
U(2) - tMCW
2 --it 61-21-1
(6)
ter's
Abstract note: C*OCIVE, coexi t denotes ~the thermol i
s ent dynam, c
ibbs potential, (a 2uax ax X molar part of the i-th
T i
i k F
,
r
molar entropy; the superscripts enote the coexistent phases.
d
3ard 3/10
3 2 1.5, 1R
S/07 60/034/008/002/014
Thermodynamic theory of...
TOr the equalization of the second with the, third phase, the follovin,- i s.
written down: (dT/dx (2) ) (c,l)p = (dT/dx(3))(c") -(dT/dx (2)) (c,l)
1 coex. 1 coex.P 2 coex.P
(dT/dx (3))(c,l) = 0 (7). The index (c,l) denotes that the - -iva4-ive .s
2 coex.P a e::
are taken in the critical end-point where the critical and the -first phase
-ire ound: (d: (c)/,~ (c)
coexistent. It is f x /dx )(C") (c)/ (c) ~22
2 1 coex.P Ill 12 12
(9), This equation is identical with that for the isothermal iso baric line'
of the coexistence of two phases in the critical Doint. In the critical
point the following condition is satisfied: (dx /dx ) (c, 1
2 1 coex.P
(ax /dX )(c) (10)., This means that the isothermal isobar.-Lc line of
2 1 c0ex.PIT
-.h,2 diphase equilibrium of the projection of the isobaric line:of the tri-
1-~hase equilibrium is tangent to the x x lane in the critical -3oi-t.
1 2 P
II):Behavior of .'the, triphase.curve expressed in the,variables of 'that phase
which does not attain thecritical state. The first and the second phase
Card 4/10
-1 R
321"
/076 60/034/OOE/oc),
Thermodyn~~mic theQry of... BIOI B208.
becumol idt~ntical, the third phase- colexists (Pig.) The fo~lo winC is .-;ritten
(2 (2) (21) (21);'
U 0 w r i (d, )/d. "Y
21~ 21 'Y (12).
-2 1 co MY
ex.P 1 2, 2.
Division of numeratQr and denominator of the right side of Eq. (12) b
Ac and passage to the limit gives: lim -/\X (aljax (a ~/a" (2)
xl-~ 0
(c) (2) (2) :,(2)
/ax
t k (a~ .~#/ax x + k im
2 2
11 "12
r-~x 0 x 0
'(2) (2) )(c,2)
'~12 + k 22 (13), where lr~ (d:, 2 /dx 1 coex.P* Applying the relati ons:
)(2) (2c (2c) )(c) (8,:/ax )(2)
(al [*/a x)(c) - (a /ax (L1 L 3 )/T; (a -lt/a x2 2
(L (2c) _ L ~2c)'. he e L (2c) is th
2 )/T (14), w r e partial molar heat, of.the
Urarsition of t-e i-th component from'the second into the critical p1hase,
Card V.10
32151 R
S/076/60/034/008/002/014
rhermodynamic theory of... B101/B208
;(2 (2))(c,2) (2c)IL(2c) (2c) (2c~,
it is obtained- (dx )/dx L +.k(L L-
2 1 coex.P 1 3 ~2
(2) -(2)~~ (2c) (2c) (2c) (2c) (2c)
+ k L L + k (L L
12 i(P2
2c 11 1 3 2 3
+ k (2)- (2c). (2c)
2c 12 22 ~05)- Q2C T 2,; 'PI ~92 and -2c may be'
calculated from Eqs.~ (4) and (5) by repl,11cing the indices of the 2-r-d =d
3rd Phase by those of the critical phase. If the composition-of,
critical and the 2nd phase is equal, it holds: (dx (2) /d. (2) c, .2)
2 1 coex.P
~(2) + k (2)) ('7W+ k -(2) ), (16). For the temDerature deDeneeneo of
11 12 1 ~1? 1112 2
the triphase equilibrium onthe compositio
n of that phase coexisting with
t" critical one, it is obtained:
d T M T [k (,(H) W) U!,2)
L
(18)
1 cyw. P (p.(21c) [L(219 L"-H) J- k (L(21') - L(211) IQ (2)1 1
3 3 2H [~(I'-2-) + k~22
Card 6/10
---------------
S~2151
076160/034/C06/002/014
Thermodynamic theory of... 3101/3208
k (X00 X(2))' 412
t/7'W I " -(40-, ))1-U12
(L1(219 -7 L3!;"') + k (~2(2110 (2K)) j '
Q2,, K(2) + k~(,'!)j:
P
L It
folLo.vs from th-1*3 that, contrary to bi nary systems a temperaiure T. a xi. mum
In 't!'O! critical ands oint is possible in ternary systems. Theright, sides
of 2qs. (18) and (193 vanish, if 1) the compositions of the critlicall and
non-critical phases ~re equal in the critical poin'u;.2) the following
(c) (2) (c) (2))
cond.ition is satisfie'd: (x (x x k (17)., It is
2 2 )/ 1 1
Wri-%ten for the temperature extrerlum in the critical end--obint: k(x(c)
(2) (0- (2) 1
x (x x 0 (20). 111) The critical end-Doint of the -
2 2
isothermal line of the triphase equilibrium in the ternary system is
.calculated by replacing in the equation system Eqs. (1)-(3), temperature
by pressure, entropy by vqlume,~and changing the signs. The folio,.-.ring
ansatzes result:
Card 7/10
32151 R
5/076/60/034/008/002/014
Thermodynamic theory of... B101/B208
(dP /dx (C (dP/dx ) (C 0,(21) and,(dx Ix )(c,l) _,(c) (c),
coex.T 2 coex.T 2/' 1 coex.T, 1 -12
'(c)/,,-(c) (22). ondition Eq x x
C (10) is now e tended:. (dx /d
,12 '22 2 ~ 1 coax.p
(dx /dx ) (c,l) - (dx /dx )(c) (23). Similar e quation3 as Eqs. (15),
2 1 coex.T 2 , 1 coex..D,T
~(18), and (19) result. For the'pressure extremum in the critical point:
(2)/,,x (:2)1(6,2) (.;(2): (2))/(; (2) (2))
(dx + k + k .22 (27) is "Jund.
2 ~coex.T .11 12 12
'Ph.6 curve of the non-critical 1Dhase is no' tangent in the critical poJnt.
to the curves of the phases becoming identical, but intersects tlh,~m.
Comparison of 13qs. (16) and 27) gives the important relation:
(2) (2) (c 2)p (dx(2) /dx(2))(c,2) (28). It iray b aseen
(
dx /dx e' 2 1 coex.T
2 1 c0 x dp 0
dT 0
therefrom that in the case of extreme temperature and pressure value~3 the
4
13-obaric- and the iso+~hermallines of the phase,that is not i n ~he_
critical state F-re tangent to each other in~the concentration diagrar- of
Card 8/10
PHASE I BOOK EXPLOITATION SOV/5043
Rusanov, Anatolly Ivanovic'h
TermodInaralka poverkhnootnykh yavleniy (Thermodynamics of
Surface Phenomena) [Leningrad] Izd-vo Leningradskogo bniv.,
1960. 179 P. Errata slip inserted. 3,000 copies printed.
Sponsoring Agency: Leningradskiy ordena Lenina gosudarstvennyy
universitet imeni A. A. Zhdanova.
Ed.: V. D. Pia tro; Tech..Ed.: S. D. Vodolagina.
PURPOSE: This book is intended for.students specializing in
physics and chemistry, and for aspirantB,' engineers,,and
scientific workers interested in surface phenomena of dis-
persed and capillary systems
COVERAGE: The book contains a systematic discussion Qf problems
relating,to the thermodynamics of surfacephenomena and
the thermodynamics of dispersed And capillary systems.
New equations are obtainedycharacterizing the1nterrelation-
"hip of surface tension, temperature, pressure,,composition
C a r d-- 1-/-l o
Thermodynamics.of Surface Phenomena sov/503
of phases and,the curvature of the.8urface. The properties
of systems containing minute nuclei of.new'pha8e8 are given.
No personalities are mentioned.~ There are 92 references:
25 Soviet (3 translations), 54 English,.12 German, and 1
French.
TABLE OF CONTENTS:
Introduction 7
PART I. PLANE SURFACE OF, DISCONTINUITY
Ch. 1. Basic.Methods,of the Thermodynamic Consideration
of Surface Phenomena 9
1. The Gibbs Method
2. Consideration of the surface of discontinuity as a,
layer of finite thickness 13
3. Comparlson of fundamental equatlons obtained by
two methods 15
C aYd'~;--~
//.,S-/00 3/076/66/034/008/002/014
B015/BO54
AUTHORS: Storonkin, A. V. arj4 Rusanov,.kn!jW_- (Leningrad)
TITLE: Thermodynamic Theoryri!of Critical Phenomena in Three-
component Systems. VI. Critical End Points of Tfrnary
Systems
PERIODICAL: Zhurnal fizicheskoy khimiig 1960, Volo 349 Noo 8,
pp. 1677-1683
TEXT:. The authors investigated the critical end points of ternary.three-
~phase systems by calculating the isothermal and isobaric lines o ,f the
three-phase equilibrium. They discuss the extreme temperatures and
'pressures at the critical end point. On the basis of the equationsl(16)
and (27) obtained, they ,derive.an important final equation (28) which
shows that, in the case of an extreme pressure and temperature at the
critical end point, the isobaric and isothermal lines (for the phases
not'attaining the critical state) are touching at the critical endpoint
on the concentration diagram of the three-phase equilibrium. There are
Card 1/2
Thermodynamic Theory of Critical Phenomena S/076/60/034/008/002/014
in Three-comp onent Systems. VI. Critical B015/BO54
End.Points of Ternary Systems
1 figure and 4 Soviet references..
'ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A.
Zhdanova (Leningrad State University imeni A, Ao Zhdano-
SUBMITTED: July 99 1958
Card 2/2
S/076/60/034/05/06/038~
B01O/BOO2
AUTHORS:, Storonkin, A. V., Rusanovq Ae I*
TITLE: Thermodynamic Theory of Critical Phenomena In Ternary
Systems. III. On the Shape of the Cusp in the Critical
Point of a Ternary System
,PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol-134, Noo 5,
pp- 977-982
TEXT: An investigation of.the shape of cusps allows the derivation of
thermodynamic inequalities determining the type of the critical point,
while a,comparison of the "coexistence" aurve and the cusp yields im-
portant information on the metastable and unstable field near the
critical.point.'In this manner, ternary systems were studied in the V/9
present case. Explanations are given in the following sections: shape of
the isothermal-isobaric cusp in the critical point of a ternary system,
shape of the isobaric cusp.in the critical point of a ternary system;
shape of the isothermal cusp of a ternary systemo The inequalities deriv-
ed characterize the possible relations between the unstable and,meta-
Card 1/2
>11
PIIAZ:E,l VWX EXPLOITATIC5
A,,d..!p _uk 55-'q. R.dly-yy 1.atlt-,
IX (TranahctEcr.. of the Itadium lnsttu-~, AzAdcV Of Sclor"a USSR.
L tta T11, Irr
vz; -r-
1,700'!. .9 printed.
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Ed
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Ezumoi G.M. Arco; Tech. Ed,; I.V. Sairn-'-
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LLi- in a w4orat~r (water), -4 *tlior prol:Aeo,ii c-secttd vIth U;o Qzvvry or
are 1-1. Tlo m*jcrIty of tl;o articles
rcutmn IntorACti,tA VILh 94-6. liMm-
C-cj~lot. d..
-are zlwarn.d ,1u-, pr,;bl,m. -if m,thod. T~_m, suti,~rs prow
3cr!ptl~n of Lim c4rstruction c0 equLp-ot ~~d ar tto re-ults o! tests prfor-d
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Tvrltat;~T; Iin F.-Itiving di .I, . !,Ila Ans!d - .7TI 107
X.A. ?.L_ IiAk. V.A. M.1. ~A~Amih.
L
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T
rcr Alph. ;? 34
,-Y,11. TI.4 Lirect frr Nterm~v!nr, 1- Udr,r. Co-ontr.tilli.
t
Air
V.I. V!.tritotl one of, N W..g-t III A.W~ul%%
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PL.-ImAti-Ij ~ttw~
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F.'r I't"irc
IA_,j
5W SOV/54-19-3-13/21
AUTHOR: Husanov, A. I.
TITLE: On the Thermodynamics of Surface Phenomena
PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i khimii,
, 79 (USSR)
1959, Ur 3, pp 71
ABSTRACT: According to Gibbs it is possible to calculate the,surface
tension from the adsorption equation for a geometric surface
in the inhomogeneity layer of the phases:
~S) n S
S dcT= - dT mdp,, (1); where S denotes the area of the
S S
tension sarface, and m. the excess of entropy and mass of the
i-th component with respect to the tension surface and 0 the
surface tersion, and Pi the chemical potential of the i-th com-
Donent. This equation may be used for plane and curved surfaces.
second method according to Van der Waalsand references*3,
4, 5 has been developed from the concept of tension surfaces
of finite thickness and has the followincT form for the plane
Card 1/3 surface-
On tfir- Thermodynamics of Surl"ace Phenomena SOV/54-59-3-13/21
n
Sd(S=-~(S)dT+v(S)dP- ~S)dp, (2). Both equntions have - al-
though they are mathematically very simple.- the disadvantage that
their independent variables are.themselves functions of pressure,
temperature and phase composition. Guggenheim made a transfor-
mation of equation (2) into a direct function of 6(p,T), and of
the phase composition; it holds, however, strictly only for
plane tension surfaces. In the present paper the attempt is
made of setting up an equation of direct dependence for plane
and carved tension surfaces. The representation made leads from
the theory ofthe heterogenebus equilibrium of Van der Waalsto
the multicomponent systems which were basically developed by
A. V. Storonkin. The surface tension of a plane surface is de-
termined on the basis of equation (2) for a molar surface and
the molar part x. of the i-th component. The calcalation is made.
for a two-phase equilibrium under consideration of the tension
surface. In the. case,of thermal and chemical equilibrium it is
possible to determine the chemical'potential,for the two phases
by two separate equations which contain cl implicitlyas a func-
Card 2/3 tion of p,T and the composition. The thermodynamical relations
On the Thermodyna--ics of Surface Pheno=ena COV/54-59-3-13/21
according to reference7 are introduced for the explicit re-
presen-tation,of this dependence, furthermore a variable of
thecomposition x. of one'of the existing phases Finally, the
three thermodynamical fundamental equations are obtained re-
presenting the equilibrium of two phases with the existence
of, a tension surface. They are mentioned individually. For curved
tersionisu.rfaces.the effect.of the curvature upon the thermody-
namic equations is investigated which is given by eqLLation
P(1)- P(2)= 2cy The thermodynamical equations obtained for a
plane tension surface are a first approximation toweakly curved
tension surfaces. The further -nvestioation is also based upon
the Van. der Weals equation (2). Also for equation (1) it is
possible to set up three equations for the state of.the surface
layer which, in combined form are the general equation_(2) for
curved surfaces. Next, the new variables pressure, temperature
and phase composition are introduced like in the first case
taking curvature into account. There are 7 references, 3 of
which are Soviet.
SUBIMITTED: 11.1arch 12, 1959
Card 3/3~
5
AUTHORS. Storonkin, A. V., Rusanov,,A. I., SOV/79-29-8-5/8'
Markuz'n, N. P.
TITLE: On the Equilibrium "Liquid Liquid" in Three-component Systems
PERIODICAL: Zhurnai obahchey khimii, 1959, Vol 29, Nr 8, pp 2480 2485
(USSR)
ABSTRACT: Many papers have hitherto described the equilibrium between
two liquids in ternary systems. However, only,few of these
papers dealt with the thermodynamic,standpoint. The empirical
mathematical interrelationships and peculiarities observed in
the equilibrium diagrams were in1most cases discussed with
~respect.to two liquids in ternary systems withoutthe aid of
thermodynamics. The rulesset.up by Krupatkin (Ref 5) and
Tarasenkov are discussed in this connectionoIn the present
paper, the authors attempted to fill this gap and to complete
and define the,existing results. It was attempted to solve the
.following problems mathematically and-by means of diagrame,in
a demonstrative manner: (1) The course.of the isothermal-iso-
bariclines for the coexistence of two liquid phases in the
three-component system (Fig 1); (2) The grouping of the nodes
Card 1/2 in the concentration diagram (Fig 2). The results of investi-
On the Equilibrium "Liquid Liquid" in Three- SOV/79-29-8-5/81
component Systems
gation offered the following rule: if-the content of one of
the componeInts of the three-component system is equal in the
coexistent phases, the chemical potentials of the two other
components change by equal values as they move along the iso-
thermal.i8obar of.the coexistent phases. V. F. Alekseyev's rule
for binary systems holds also,near the critical point of the
ternary system. There are 2 figures and 13 references, 11 of
which are Soviet.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet,(Leningrad State
University)
SUBMITTED: July 14, 1958
Card 2/2
-/042/XX
:S/076
S-1 )101
AUTHORS: Storonkin. A. V, and -Rusanov . 1.
TITLE: Thermodynamic Theor, of Crit ical Phenomena,in Three-compo-
nent byatema. v Pquilibrium of Ifeterogeneoue Systems
Containing a Critical Phase
PERIODICAL: Zhurnal fizicheskoy khimii, 196o, vol. 34, 'No. 7,
PP. 1407-1413
TEXT: The authors start from the fact that the direct experimental in-
vesti-gation of the properties of a critical phase is sometimes impractica-
ble. In this case, an indirect method which is based on the study of the
phasej coexisting with the critical one may be used to study the critical
-state. In this paper, the general method of describing binary phase equi-
libria with a critical phase being,present is treated. Moreover,, some
cases of such equilibria,in ternary systems are investigated..The coexist-
ing phases bear the indices I and 2, and th e, generalized van der Waals dif-
ferential equation is written usingthe var iables of the first.phase:
Card 1/ 7
87761
Thermodynamic Theory of Critical Phenomena S/076/60/034/007/012/042/XX
,in Three-component Systems. Vd Equilibrium- 3031,'/Bo6B
f ifetero-eneous Systems Containing a Critical
Phase
n-1 n-1
(,(2)
V dp dT + d,(') (1), here,
12 ~12 i ik k
i=1 k=1
(1) n-
1112 71
(2) (1\ n-1 .0) (1
V v v (X~')- x )(av/axi where ii, the volume;
12
Iq is the molar entropy; x is the molar portion of tile i-th componen.t;
c is the molar thermodynamic Gibbs potential; a 2
i0m ( ~/"ixOP,T;
P is the nressure; T is the temperature; n .is the n n~er of compon ents.
/_.-i' Ym
In addition, it holds that d(q d(a~lax.) 2), (i,=
(2). Equatioz.j (1) and (2) result from the equilibrium conditions:
(2)
d M 1 1 d", dP(1) dP(2) , dg~') = dp ~2) ; (i 1,2,...,11) "S
chemical po ten tial of the i-th component.-By substituting index k of
Card 217
8 763
Thermodynamic Thp,~ry u~' Crit:Lal ?henor--n, S" 6- 007/017) .'042/Xx
7
in Three-com-;~,,nent V. Lquiillbr_-_~:
of Heterogen-.-,,.-_; Systei.-!_1 Containinl-'- a CrItlual.
.Phase
The follozin- conclusion i ~j drawrt .,.hich. is imuortant for practical purposes:
The invest iga tion olf ti.t, critical &tatp of a binary phase with acoexist-
ing third phase lea(1~3 L:) I.Iie. same rfic-u-IT, a,~ thin _,nvestigation of a binaiy
phase alone, There ui- 3 3oviet refererces.
ASSOCIATION: Lenin*1"03--~AY 80SLILIzirstvennyy universitet im. A. A.
5tate Urliveroitv imeni A. A. 7~1,4,qnov)
SUBMITTED: JI, 5"
'Card 7/7
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roe
the coma. of a tested element in 0
sphs and tables. The method is
roe
wnding on the coacn. Of CUnt2nii-,
Ch
Bl *0
as.
anc 1
a
L
ww
0
0
Igoe
0
0
not
I I L A It tALL06K At tittgAtM (LAWWATION
00 3
0
b u U At 10 'Uj; Joe
xx 0 a
0 .1, It K a it It 2 a a 3
0 0
0 0 q 0 0 0 0 and
9 0 0 0 0 0 0 C 0 a 0
0 0 0 a
o 0 0 0 o 0 a o 0 0 0 0 61
7 C III I I T a A Z is 11 IF x a a a a a 0
7
lot A IMP 000116 Am& Ain coo
Fams"I ws #40"4145 OKA
r
00A 00
-1-2
00A .
nVARATION OF MOTU= FM CARBON ZLXC- .00
r
name As So 11.0saimov J*,Applo Chia-* Russep 1935s -
X
:
'so 520"My-Z
odev'are freed frozi Fsp Alp Sip
5
97
1
T
0"
Tip and V by heating at 2700* forIO-20 seo.p and from go
i
by he,
Cu by heating for 36 sea* Cap Hip and D are not entirely
eliminated after 2 min. Re To
doe
,
sew
coo
see
Nee
Nee
U00
TALLVRGKAL tIT924TWIN CLASUPICATM
Noe
I
IC
/ Idneve -4 1 S41480 WAF dmv ad Got m an Ask- 0
U, a, n it a $A a I V ad 0 0 v I At at 0 A 6
0 046
0 0 0 a 0 0 0 0 0 0 0 0 0
o
1
o 'a
03 It At I:, Z: a r N A 1 11 34 L, V 1. L
IL- 611 X U k
00 -40
7
00 The question of the distributi-on of ge -00
rumnium in losail
COWS. V. A. Zilberntints. A-K-RiAmrsor and V. M. -00
Kotrikin. Akad. r. T rrrxaXK-;" k ri~j1ikjj*sjs1r-
00 ovu Nakeh. DeYaWRath 1, -00
00 ir
1930, 1, MN~The Gr contents of a large no. of fos%il( .00
coillis fro", almost all the deposit* in the U. S, S. R. war
drtd- by a specialty developed method- 0
00
Of the huge no. of specimens tinted only 19 from the Don. -o 0
Cts region. 13 from the Ural and Ptitchura, regiotts, I from
00 Barents Island and I from Nonhern Dvina showed a high .00
00 'ri Ge content 10.1-1%) in the a-h. In 58 samples the Ge 9
coutentirao0ml-41.1%. The greater p4tt of the cools rich re
00 in Gc were especially low in ash. The enrichment of the -00
41 coal with Gt is assuined to be the result of adsorption and ~A 0
tit metasomatic conversion of the circulAting soins. by the
00 j: coal tuass. It. G. Moore -00
-'jI Is
00 ulto a liquid toi. 'Alek"xidriiA 6rown i~al- ~j. K. 0
D*Yakova and S. A. 5~11Y-m- 114d. .5-M,62.-The cual
so dissolved hest at :Y*")" other contlitian were the same 0
00 as above. The tmtrntnt permitted soln. of 65% of th, zoo
0 9. Sult"tAnce of coal; 10% was ticcumpti. during the 0
P'rucem into gas and water atut 25% reinjuted wAi.j. The
00 t! bolus. Obtained were uncd. s, ftuso to 42-0)%. &00
and hydrogenated; tb'oy cave liquid products Sq.7, solid
0 IF e -00
coal 1,30, water 2. gas and losses S%. Thus M% of tilt
its. subsgance of coal was transformed into a liquid fuel.
A~ A. Poillortly
too
APO
00 AS-SLA METALLUPGKAL LitIMATtlit CLASSIPICAtIGN
of "a.,
00 It
it, F-JA - --
All A I it W 0
it to it it I W IN
I A. Ka 04C n it of L3n W I-
0 U Is AT W3 LV ty 0 1P op K K Is 0 0 0 0 0 000 of 0 0
;I " 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0
0 0 0 00 0 0 0 0 0,0 0 0 0 00 0 0 40 0 0 0
0 0,0 0 0~0 a o o 0 0 0 0 0 0 0 0 0 0 0 0 0.0 0 0 0 0 0 0 a
03 1 j j 4 1 6 1 A 0 mi it it it m h if a IT at 4 IOZI bvzijt A)f 12 11.un all XXX At At 43 a ace
A -V y A. Is CC, pp_ (I -L. -1 1 a k- A --Ao 0
III Q it I A R P, q- I - l- -L - .. .,7. -:!
09 ist 1.0 C-pill
4 ms -0 -.1411ft.ft
00
0 a
00 OIL
Tho '.0q
0 0 oecuffw-w 0t b"IW= Ill NOW colds~ V. A
lilixitilintr and A, K. kuanov. COmpt. firad, iwad. -00
ui.
S, IN. S-1.4.-27 31(ItM)tw F-ghsb).-Thr
0 lame coal %amplet WiTe Urd in thiv wfwk that WeTr ,Wd in .0 0
The Itork on V and Cc. Ithe He waif drid.
so -Ily hY healing the 2%11 (Cnnlg. I"; P0 In a pule C a IS 0
Me aint. of Be wai estd. vioinally
so ic by L~Xnpafiujj He line 0
0 :.W4121 with Pt line 2tZ(J.44 and fit 31311.42, with Fit lie 0
MOW.-N. Trsts were made with known arnts. it Be.
lie 614 ruals examd. none %h,jwcd
0 ove" it. I '~; Be, onty 38 00
Owwrif over while avt-v fiall J.-I fum'-'
00 j it I V and Cc. the t(%il% with the lru.t q, h,d I,, ,,,w :.a 0
00 fir- W #he C'MI. frt.411 file 1h,114.11 IIA'in lh#.r (14411 the 0
"TAW"o had the nuAl lie anti CC, $kith a gradital detv
00 a ,thr Cs"ter. - ;:~7~
JtAn F. %fit
00 f
00 b!
10
so I Ull"At0`1 CLASItFKAMP
go is,
it :i- I I (W
u IT IT tv it 49 ic it R It p, It tt It mto n I to 0S 0 0 S 0 0 0 0 0.
0 0 0 0 0 9 0 0 a 0 0 0 0 a 0 6 a 0 0 0 * a a 0
0 00 0 a 4 0 0 0 0 0 0 0 0 0 00 0 00 0000 0 0 6-
010 0 O's 0 0 0 0 as 0 0 a 0 0 0 0
0
0 is I It 10 4 11 IS It to I.
L AtA f 4 it 1 .1 ~ 4 v L,~AA N (L 00 U k d 4 1 4 4 G
.3 ~.v ho
PvC*t-Tq* '.01,
00
0
00 Ila
Spectral analysis of Alkaline ndalkaltne earth metals in
aluminum and lead. A. K. kilk-Slillf All'[ It. 1. 11.011111imp.
Itb. 5. ?;41 ;1(110"); cf. C. 'l. J9, -IV
I'lle IllrVil"I'l tilt-tilqkl If %'illldl
"( I Icoo
NA.
j i. CA ASM S III Ow pir-11. rof At nd III, Itave m1w
Vt
see
of It
0 0 YJ
see
Ote- a see
00 nee
:j At. it A lit Ott k i,.Uk At t ill.016lif it OIWK -110- 1 to 0
40.
t o~ . .4
-o
r
.1 n a it w
0 0 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 SO
01,
0 0 0 to 0 a 0 0 0 0 0 0 0 0 0
0900099,99904booo 000000
0
a c 0 L 0 0 PC p I T or ~-31x.Jlvjts%JVx stead a a As 0
00
&no= wife fl I
"D A-0 41. coolas 1 0. **our$
.41glIA1.6 *as&
-ZLI.
104.0p 7:400:4-
On
004
F
004 1.41r,
is on JDAW U-M) %M0 LL
Sol It 10.0 off Wm" is 'too" go Ifte 31 lmooo
LOW" rl IN . ea ~."Njw ton
OZ 2
9q in uaow 14 "m u coo
tn' pupbaz 00
60= aqj jeaq olppnmWp. *P&Mll
(you"' )a' SA"In 00
00 ~'"Mom'
0 1 smog *Roo 1 4
JO p ~lqllql m Pte Ap" 7 60
its"W"Pu4-o"am Lwlo
-1
00- 00
10 opwqwv TompWI. W-W 00
040. 16,
So. ISO
oo.. ,00
0*- 00
ij! roo
00 "1 coo
o 7, D r Do
V v T
6LML
A Ja )A 0 0 It At At
A a -j-j-k m IL L -A- AL r A L--L-.4A-M-IX 90 Uts 1 %_1 A I A v A A
4
04 P.Oct Situ b.0
:-so
00
00 detamLimatke of VA and beryl -
SPOKbIwopic
M.
minerals and was
A
nt i
h 00
80
.
u
n
-
XmItiMn. J. Appfird t'Awm, (U. S. S. R.) 9, ZI(MV 14)
-00
sit Girmian 2311) MCOO-Ow and lic wtrm dod. in the
so - "unriwing the following line paim: Ge
lvtrvnwe of Pt h)
-00
0o all 31KIPAN-l't 3144.71 ; CC 1 01.641 and 2651.15-Ft ;'IWAI.44.
-00
Ite 21MA) 31 14 '.NNP.44 and ReM31.1.42-1`1 ;MW4.71 A. A
00 -00
so 4r A A"I . ..... .I. I.m.1to wnts 2% llt~ the intrnmitv- J
-00
to ZI ltr-r lint. muldr. III thr lior-n.v III vaium, Ainl%, of 1-.
see
TO lic site Iffilifilfilr4l. 411.1 IIwd
A. A., Poidg4weiv -so
so
so r
'00
of a! moo
r
so
ei jco 0
to, I
zoo
AS-SLA ot ?ALLLNGKAL UtINAttillf CLAISIFICATICO ego 0,
go
AM'. 43.4..
00
t
' 14 111J .4. Z.,
"-- "LIMP't Ga 41,
It
AV
u
~
,
J An I j 9 Od 0 Of a -1 W ja C 3
5 a a V
0 g it a It a IT it IN
K
C, KID in
0
N 0
~ 0 0 0 0 a 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 9
0
Is * o 0 0 o o o .0 0 a a 0 0 0 a 0 0 o a 0 a a a a 0 a 0 0
w 0 o -0-0-6-0-4-6~ I I I 1 :1 . ,
00 it 91 ti 1116411114 fix "A I&VA21 all unum 11 9 X ill 4 #1 412 4--d-W-L-W
S -1 V * CC 900 Iff 1-A- t-i-O. k~ . .--j-
A ..a.- 4-Z 4 0 1 It -00
A J1.1
0
00
of
a
#visual spectroscopic D44ruilostiou of tudium in Solutions. A. K- U11,114-
faod.-4_1f. S.1ollovitill. JR41ir Willy. 1937.0.15 0),2111 31 1~ 317701%.
32-1,329). -j III Itumitiall.1 Tlw 1-1 int.. .11 ., *-I h'I", IIA111'. .00
thition iole,t-
mnif a lil-lig-IllAr4l rJulitilli-ir ronlaining.1 41-211, m see
I-I t- flasor Anti the militnator of IN-
I
to ilia I it III is I.wd 4,11 t he I hick 114-64 of J-dut ion mt n't tool.,urt. tll-- [it litu.,
ji 1*11v Inrilliml van Iw ii-I in thi- mogn-0-11mr.1 112",, w1i in titillation, Willi An Allf-or, zz:::
of alm-lit coo
red,
00,
aA
of's
of's 1.00
44 0
04
- - bell
Al-Ita MITALLOMICAL OffOATURI CLASSWICAM. %:00
so free
u is A, Ls'; it
7605 20K Ilia Otig Kazz ICK Kw n 1 [16 a oil a It 14 -J 3 a
0 0 0 0 0 0 St at 0 0
0
0 0 a : : : 0 : : :1
to 6 6 00 goo 000 0 0 a 06 a 001
RP 90 0 00 0
03 11 1 4 1 1 1 1 . w s, a
A - J I At Y J -V_J,.J_,LAA_ a, IM It At'is") I,# I
4 If A 2,
C_
06 J.
Wmud #pef;Wqqf;o& methods in the quAntitative an&ly-
sis of solutions. A. K. kusAnuv and S. 1. Kunitia.
00 fl kirw1kaw Lob. 6._M-40~RK;P: cf. C. A. 29, 718,
217,14,--the apill timll of I`~ dus Methods to the don.
04 .,f In in wAns. obta2illed in irgem13'alysis of sullstlic orv4 and
11licat" i. dewtilmd. Chaq. 116sk- -00
00 ft?"
IS 0
00 J
00 0"
40*
00
00 a ass,
see
"0
0
.100
fee
*I
see.
r
SICTALLUMMICAL 1.111100ITURE CLA$SWKATICW
r..rr
41 it 0, 1=4 0
0~1
0 0 0 0 :10 a 0 0 0 0 q a 0 a 0 6 0 0 Is 0 4 0 Ole a 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0
0 0 0 0 6 0 0 0 0 0 q 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 4 0 4 0 a 4 0 0 0 a 0 a a
tp
0 C 0 AN 6 00 AM L 0 AA 0 FIN 4 u n jw is b v x
A, A
b
JL
q I c" &I
9
J
~ Ad) LOW -
__
IND Al. (C1ki _
,
t
F
I
A.
~F:
F
,
*0
OU J-m 'Mm"19 ?Ui, lr~ 99.91p qjj
to-lop qV-~r,Wgjjt
10cm WD
C,
ftm -W p so". MP
"M Paw X Jo w` t
; uv
M= ;c,
q
R
Ul Ino POIAM oua
0
"
0
$"Aor=i
sta
m
q
4L g"in" U! 11f) hqqwa",w Fvm wampo*
.
t
i~b
4L i
r
3
'
AZrMTA '
1319
vi
.,
,K
.j
P
am
041
00
A 10-i A
i It-
Y,
l
I a p is to I) it W it 14 1) to 11 ~IiI it v It U a It IF x p 0 so 4: As iiigo
A I ~C 0 a Of P- 9 ..A I T~ 0 't M--" -CC W U -4 A 6 0 L- JLJ,
Utative Spectmitritphic Analysis of Solutions. 111.
TAtirn-tion of Thallium and Indlum. A. K. Ituxanov and ft. 1. 11-whinkov
f/ -0 0
It is shown Umt. the spark diwitarge in Applicable- not niv
in the vistial quantitative niec-tmumph)-iji'metzils, but almi formlutions. An
o: At Anitlytival Inethud ft" been (levelolicA. wh!Lh is muitable f4ir the (justititativo -0
estimation nfll ml In In sillutions, lxm-d on the nimparimmol'the intensitiea
4 the, h4ming lines: TI =0117 A. vith Ve 52170-361 A., &nil fit
1.311-31 A. -ith CA 4=3-3 A. Pr ati-I CA Am mmMmI 14) tho im-ltitiqt *A mmi-
Ivititim uh-ments. Ilia vothmitbin iii eArti#%I Aint in III fnioqw With skit
!.~ I '-~'
111111111`43.1,Y (if -0-11",, for 11 (emcentrstimix U41111I 11-11" 1 and eif 1: 7-11" f,-?
0
00 -a
to 0
P
0 ..
1~j A S 9 - L A LLUP.GKAL UTFRAT1,49 CLASSIFKATION 0
it., to
100 via., 03.111V Ito
0 U Is AV 00 IL% A An L a Od It jr As (1 11
K At It dna
0
'a 0
0 0 0 g 0
Is As As 0
:0 :61999090
1 009900460006
u Orm 31 31 32 n M 0 TS
A a C 0 V 6 M X- -L 4. WITIISO I S T UW 12 A 1! IS ST Cm
13ND LS'fttn
_ C . & . a . I . (010
'1t0 &"o &J" V#Dt* -ITN"Ailviaw T I I v
.wjVN,mT-13 alALVNILII I
00
U If ux j0 D" 1-10-0 muluma
00
wuopnloa -i %4.S:F v
A
W-Pum -1 %QW. .91 ADAM' Ou
0 03 -CQ-Otgt W41 "T LpcftpuN-ql-ggauz,*vO9 00
-16-661tpo"O"Pill I I Wwo =='Apq 00
al pmqwnm on WE r"
.Ml "q" 'POAIZ)
go.' ---
W *A- Pm AO"mN
'Al
;17 00
'Go
00
-.00
90- or *0
.00
rot
TO ITTIF
I z I
I) it it 16 1) 11 It 20 11 J3 n I* A 26 ?y A n A; v v it w a I. it v
L la L, I f.
0 It A L L a it L k4 DO w R
90 of
Spectroscopic invest1lation of :inc bleades for terms.
alum, ludium. cadallum and sallitint F I Altwillovaild
A. K, Utmituiv - Norte, I'V4. 8. Nit 19IN! - -00
Of VAfj,',j' ajjjtj'l.-' .00
Of v1s,lophAtIv vitsd '110-hLi- M'wl- lot Ml k"l 1,
(.It '10
m"'1 14,1111fill, Ilw iml. 1 0 C.'. lit m.1 C., i.4
06 :
I'mall it IIIII'mil -Poo
of j 0
=00
=0 0
roe
90
;zoo
so f
W-0 0
00 x00
00
00 :40
00 it
t:0
7Z
-
t
L I
t
iw,
9
ff it ,v L3 It I v4
[ a
0 0 0 0 0 a *,%a
0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 * a 0 0 0 0 0 0
1
0 0 0 0 0 0 0 0 IS 0 0 0 0 0 a 0 9 0 9 0 0 0 0 0 0 0 0 0 0
ki IV it U is 16 It it of JOTPI'm m 8 As I bff"m $,I, IV, u- 11a all 41
r 9 a I f 101 go U
fit A-01 I" talffet
00
of
00
0
Spectral analysis of minerals and solutions. A. K. -00
Ru%afulef And K. N. Vmmt,v~ Z-tt,.f,k,,vt bib, 8, .04
in the %I~IrA anAym, ,l raoit, -.,I, Ih.- J.'Wil.
111:11%A46 WrIe. "Nown- onto as ~641
aC' I
IfI
and frum the Intensity of the IiIii-s it %;L, I-jtj, t., r,t .00
00 Ii -ticn.o(Cetand RbinO.fvIl,fI,I)l,fJl aml 1"'. Feet "lowe,
-itcurair t"nits the chlixide, ~,In,...( C,. W."A K cmtig .04,
4 00
00 %in ai a sevemulary r1ritirtif veg re- isvd. A%:"IIfjCiCq VII rr a
66 few 111). -3.11~,', f.,r 9, and feet '%let
zoo
lberitin.mim.4m,lis
00
zoo
too
go
~
00 coo
see
'so's '00
41-1141- -CIA&& V06K4t 1.11111414,119 CLA1311FKATIGN 0
.#(3 %-a a,IP. 0
Q..j INIONJ -1. 0... 4J11110-1,
U 11 AV .0 LI 0 1 AilI S a -04 0 a a I W IM '3 dil
it It ow IIIa It ign Platt Isis
I -. ; - '0 0
C 0 a
: : : : :1 o g : : 0 a 0 : : : : : : : -I : : 0 61
6 1 a I ki 11 It 11 Is 14 111$ "MOIll 111015 AVIS.-likil I: It It k, 1.m it U 01 " a
Isr"a L_f .6 it _ 1_ L L I it v AA to CC M f(
00
.00
Spettral analysis of solutions and minerals. A. K.
00 Rus4nov slid V. %t. Alck~cva_ ZijrW3kLiya LAA, OM .00
5^10-10)""The InIrtailtirs of Or litivs Sm LAIMM) 010)
00 "NOM ~,~C4 47,167.94A. Slid M 1110MAIA. - Nlo'14~111 "N 49
A. stm Inta,used tutict. No Stitt M. W111142-1111 NAIHIPIP
list Na tan lie dett]. clown to a covert. of 0-001 7v njul 1.11,0
wir,'v. Timm clenitntacan Im drttl. in the pte-twe J
" -0 0
00 (-~r M
alk, Isivials with a ptobAble trfut of A, 1.61
r I
A 1
3
-
W NA
Within 111crolu'll. ralip of IMMI M2%. Will
~t
06 j
1.11 the concn. range of 0.101 0. 1Z. K 0
so
00
do
0
00 0
00:
A I IL A At ?JLLI~PGOC At LITINAl"I CIA ISLOJC A T$C* of
.40
t soo
1
U A
0
I
mi
.
P It 61 IF it R19 Is Its is It OF ,
i
0 d
41, d
0 111, 00 0 0a0 0
J
0, 0,
0 0 0-0 0 0 9 0 9 0 0 0 0 0 0 a 0 0 DIP
: : 0
Y, V, L,
A f. A-.L-.L m r Q R
AA LC LAP (f. 4
7.00
-00
00
00
Kato lind actalfrfous melals, spettral s"Mysis of
scAutions and mintrals. A. K, R,%-Vw,w froms. .411, -0
I'mium S's Ii- S. Wl
0
147, 611 K-It 110,11-Swr C. .4. 34, chan. 1114tic
00
zoo
00
04 3
00 ;.0 0
00 -60
so
~.O 0
00
600
80
F a**
4i
of
s, ze 0
Ole
t I I. f 1 .1. 1114K ILtTvVI.t%,*f c%.WIfKATIQ.
tjo 0
00
'O'5
,00
, .
I., C;
,Ivlplvm all "a K fl j I I Co 1 0
0of 0 0 0
01
0 00 a a 0 4
0 0 0 0 0 0 00 0 0 0;0
_s 9-0 it it is W is is I? is " a 21 V D 'a V A 20 'N It 2 13 It 5 Al V 31 IN 4 Of Q U it Of!*
A- 1, C a A A L X_,R_ F,,-Q A _I _1 -.V-,Y-L- -A of, 91 W 1[ 4-1 b
00 4T 00
0* r
go a
Use of a carbon arc In a direet quantitative study of the
composiltim of Wisars!S. A. 9. Russuov. BbU. arad. 0
sci. U. R. s. s., s&. Lzagush. 14A-9) -00
(IM).-The spectral analysis of composite minerals,
woo
studied directly in the form ol arc, cart 1* traliard by
continumv Introdurthin id tire lkwwtlpr on ImIler batiole .00
itim the are The uw of a C nit, briolor" Pleritutleq filh-of
with NxCl inuires an aivulary of ~3-A% In d,ti. C, Ce
0 j with lines of Ili wtvins tot Looiltarivin., The rati.v .( =09
00 intensities of the lines of Hi and Ge depen.f. till the adellix.
turrs of differrut elements In the ore. and varies In pro. re 0
of a portion to the volatilitirt of thew elements. R. 0-
2i so's
00 2 ;;go
All-Union Institute of Economic Mineralogy, MOSCO16r.
boo
A I it ti a wAlts, -Cot k tiff At~wr CtAlls O'Kalm fif
U U if .0 it ------ i-i -a _w if a 4 1 IF
1W PV P 0 it 30 44 K a 19 9 11 ft It IF n 1 '24 AM
~4 0 0 0 0 0 a 0 0 0 0 0 4 a 0 0
i;S :i : : :j
_~ it 0 0 0 0000 0000 0 10 0 4 0 0 00 0 0 a 0
-- - I I
1 1
r .0 ~ 4,
1-Ax. a- I "t- 6 1-- ~ 4 . I.- J., 4 a,
k '* -
&- 0
I
,
.
$1 A!S) PIP- WIM
ONOMS11 A.0 000plat'l
I.C
11
1
l
0 lee
00
09 Use, of a quit dlg&wge and an acetylene dame in the
.
Sobdwe ajad gala"s. A. K.--R
p4p. 4, 195 '(LI"O4 )
sci. U. R. S. S., Sir -7 0 0
a 60
0
0 272,79, A624B.-Thc quaot. swc-j~
Cf. C. A. 34, -100
of ImIns. for U, No. TI, In. Zu and Cd, vW
=1
of the
l earn
f vis
b
h
d
l
.
ua
o
o
e nW
out:
g) by %
juign leg III nwetral 0" in a nmrk illwharge.
ti
l ee
vv
re
a
lf"111111" ""I"
J
with * I"
h
101
hi
t
h
0 o"
o
Il
otopap
c P
1
(2) by p
in an acetylene dame. $fineral powdets were analyitil
by the method of photographk photometry In an oxy-
tro 0
acetylene dame. The results obtained sue tabulated.
UnkRalana GQMGW
All. -Union Institut
e of Ec
OnOmic Minerajo
l
MOSCOW.
9y) ee
,
We 40
!goo
AS-SLA AITALLURGICAL LSTI*.TURE CLASUPKATICa
'lee
leg
M1 L
$
9
a 3 a
0 0 010
0
0
0 0 0 0 0 00 000000 06 00 0
0
0 so * 0 0
0 0 0 0 0 0 la-A-0
1 0 0 0 see 0 0 0 0 : 0
00 0
A &no 4f" C40141
VOC'evy'rS .at.
s
thod
for
hod the quantitative =Ala
nalyals Of
.a and soludoes. VU. Dim "ties of
,
i
. i Iluln. [odium and gallium In shads: Nos". A.~Xjtndmuoir ill the selecicd iwidrs ot lines with A lit.4jable error of -8-
:
A
anti V. It. Airkweva. Zatridirlaya L4b. 9. No. 1. &)-g 13%. The wave length*. the intervals 0( COUCH. gild the
;
(IM); cf. C. A. 35. W51.-ZnS powder (0.2 g.) was Probable errors cre. rnp.: TI M,5.73-Co W04-011 A.,
distrilbuted cvcstly over thin cisam paw mid. with 0.0111-0.3%. - W',. In 41MM-Co 40L112.4 A., O.Ool-
0
03%
12
G
.
.
%;
a -14IM-01-Co 40102.4 A.. 0.01-0.03-
(Nil.).SO. and Ow lwlwr placed in the center of an asy.
;Ii~ arriylenr IlAlur anti kept there fur 30-40 aide. The deice. 'I)%; 4172.02-Cu 4411,12.4 A.. 0.01-0.3%.
MCH . ,I UI (grivell. III Ollur) MW (M (violet) anti Van In I Ile jurvetwe W &&j,Hite
tallir %I :Haiti
Ant G* C&O tic dVtd
mr
ill the Ilft-IK-C
trup
: tit sinebtroide (ZnS) 0
01M13
111
1l
I
U
06
n
aO
01
i
-
.
r
.
.
.
.
I
.
t
de
.
te Ze S,
pyr
%;
TIMnuollsedettl 41111I.Willflir
4 ill llyllir I Fr~,) 11 1111115 0 11111, 0011.1l"I'MI and 0,01%, 1
-
lift-su
z"8
i
a
- I
, ~j J.
,
V lln, inscl
rs With file Cid
'
I
O xSe
(mq do ixtri. to iiiii an-t rho intrit.-
dabl"W"Imlly later milli%
rs of the I
l
In still (14 hitir. *9 variout colit'lli. Inc. Inild at I q, 401 1) file Its ZrIN tuddluvris in
1he sticriluill 41willef *CAL
PC I
G S
0 Be
.
j J. In aut- rears TI Can 1W, dicta. only
d"ilin [)right. tWahns twight anti @silly Perceptible;
by
the T1 3776
73 A
blight
bright and pcrcr
tlbk
and Co 3841
at 0
01% easil
4d A
400
0 41111 .
.
.
,
.
p
,
y
perceptible. es-ily perceptible and very weak; at 0.001 % Deins. In and Ga can be tuade simultancediLgy
0 0
weak, weak anti absent. AtOAMI%ailline2arealnent. in I hr. In 0. A g. of ZnS. Seven ftlemna" toill,
0 9 Man. t- ZnS of const. units. of COvO. (0-05 S. 0( COA W. R: 11r.- Ct
added to 0.2 X. of ZnS Powder) makes pumi6le the detra. of 00
S The cutticus. of T1. In and VIA trilin the relative Intetwitic.
9
g
A
tl 'Ats ItA ONIALtUPSKA1, MINAlUdlir C4,4"WICA110"
wee
%.lug,) ." M,
to-046 .7-r--
--
-
I I -
V
1, a 1 7 LA Aft I 1 4 FW 0 If a I If so 0 a 4 1
a AW 10 Ll ; t
a a It a
of 0 0 0 0 0 0 0 0 0 0 0 0 06,00 0
I J ou 1, if it 7li-J. it
A A--C-jL_t i of (X M Vu "M bit Anti; .1
P-Dt-w
"lle