SCIENTIFIC ABSTRACT RAZUMOVSKIY, V.V. - RAZUVAYEV, G.A.

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• Collection: Scientific Abstracts
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• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

RAZUMOVSKIY, V.V.
~4- -1
A.P. Elltekov's connections with Russian chemists. Ukr. khim.
zhur. 24 no.3:409-412 158. (MIRA 11:9)
(Elltekov, Aleksandr Pavlovich 1846-1894)

AUTHORS: Yakubovich, A. Ya., Razumovskiy, V, V.; 79-2-8-3-25/6!
Belyayeva, I. N,
TIT-LE. The Synthesis of Vinyl Monomers (Sintezy vinilovykh
monomerov)--
III. Note on the Synthesis of Compounds With a Carbonyl
Group (III. Zamechaniye k sintezu soyedineniy s
karbonillney gruppoyl
PERIODICAL: Zhurnal Obshchey Khimi-J, 1958, Vol, 28, Nr 3: pp, 680-682
(USSR)
ABSTRACT: There are hints that in certain cases an easy course of the
Mannichs reaction depends on the nature of the used base.
Thus Levy and Nisbet (ref. 0 noted that-. 2-acetylfurfuran and
4 r4.
formaldehyde enter "';?eactions with salts of dimethylamine
and d--"propylamine but never with a salt of diethylamire.
Liarinich and Heilner (ref. 2) described the synthesis of the
phenylvinylketone when using the hydrochloride of dimethyl-
amine. Joung and Roberts obtaiaed the same ketone with the
hydrochlorine of diethylamine- The authors synthetized the
Card 1/3 pheny-3-vinylketone with the same salts; they found however,

The Synthesis of Vinyl Monomers, 79-28,71-25/61
III. Note on the Synthesis of Compounds With a Carbonyl Group
that the reaction with the hydrochlorine of diethylamine
takes place considerably slower and that the yield of the
hydro~--hlorine of dialkylaminopropriophenon is smaller
than with the use of the hydrochlorine of dimethylamine
(65 to 75,5 % correspondingly), Phenylisopropyleneketone
was synthetized from the hydrochlorine of dimethylaminc-
methylpropriophenon. It turned out that propriophenon and
parafo-rmaldehydo do not react with the hydrochlorine of
diethylamine- A-;--ordin.- to Mannich alsc the 2..5-dichloro-
phenylketorie was synthetized anewc The 2,5-dichloroacetophenm
and its paraform react only little with the hydrochlorine of
diethylamir-e;easier; however, with that of dimethylamine,
The ketone obtlained here easily polymerizes in the
distillation, even in vacuo and in the presence of an
inhibitor. In publications referring to the most simple
unsaturated aldehydes, the acroleine and methacrcleine~
only patent data are known on the synthesis of the oximes
of these aidehydes, The authors synthetized in a new way
the oxime of ma,-xoleine by reaction of the meta-macroleine
Card 2/3 with hydroxylamine (yield 65 ~6).

The Synthesis of Vinyl Monomers. 79-28 -3-25/61
III. Note on the Synthesis of Compounds With a Carbonyl Group.
There are 12 references, 4 of which are Soviet
SUBMITTED: January 24, 1957
Card 3/3

"'UT"CIRS
Yakubovich, A. Ya. H--zumovskiy, V. SOV/79-28-7- 15 !6
Vostrukh-ina, Z. 11, o 2 c ~ns YFiTjW, '~X
monomerov)
fITLE: Syntheses of Vinyl ",onomers (Sintezy vinilovykh
III.On the Syntheses of the Vinylesters From Acet- and Chloro-
,mercuroacetaldelfiydes, and on the Mechanism of These Reactions
(II1.0 nirtezakh slozhnykh vinilovykh efirov iz atSet-i khlor-
me--kuratsetalldegidov i mekhanizme etikh reaktsiy)
PERIODICAL: Zhu-T-nal obshchey khimii, 1958, Vol 28, Nr 7,
i)P 1930 - 1936 (US")*R)
ABSTRACT: The method of the reaction of acetaldehyde vith the chlorine
of the correcpondin,-, a-cid in the medium of a tertiary
base described by A..!.S1E--.d':ov and G.S.Petrov (Ref 1) could
not be roved by the authors in any case. In using pyridine,
p
f~)r instance, neither tile vinylben~~oate, vinylacetate nor the
vinyl esters of butyr-ic-, caproic- or chloroacetic acids were
obtained althouCh tile conditions mentioned in carrying out the
t~
reaction were strictly followed. Besides, the cr,,s'talline de-
Card I/ itions occurrini, in t-iis reaction are not mentloned. The vinyl
3 _p o s 1

Svnt':.e-es of Mono-erc- III, On t--e S-;-nt:.eses of SOV/79,28-7--5/64
the Vin~,lesters FrG-~ ---et- and Chloron-ercuro-Lcet~-!,--;e---I=s, an,7, an t'-e Yec---an4 s --m
j
of Viese Re,
.actions
est, ers of t%e phosphoric acids could be obtained by t'-Ie reaction
of the acetaldehyde with their chlorine anhydrides in the
preseo!ce of triet?iylar-..iine (Ref 3), the yield of vin , /-lbenzoate
a!."QUntit'(,)' tc 15~0' (Ref 3)., In view of these facts another method
of s-,fntkesis was tried (Ref 4) accordinf-, to which the vinyl esters
of' Series of acids could be s,-inthesized in Good yields, Con-
cludin!- the follc,.-.,in,-, results -,iay be stated: In the synthesis
of t~-.e vinyl esters of the carboxylic acids from acetaldehyde,
acylchloride and pyrirline only the chlorides of a---cylox alkyl-
. y
pyridin-ium could be obtained. In using triethylai,.1-ine (instead
cf ;jyrid-ine) ,~.-Jth benzoylchloride a vinylbenzoate (yield 15-')
w,
~ Ls obta4-.-,,ed, By the direct coupling of ti-,e ',,,alo-en anhydrides
of t1io acids to t`ie aldchydes the follouin.- compounds were
synt-esized: u-chloretliylacetate, u-chlorethylbenzoate,chloro-
met -.ylmeti,acrylate, bro::,.Cmet-.yliietl,,;..crylate, and a-chlorethyl-
.methacrylate, This reaction is of ;,e.-eral preparative character.
B.-:r t',e r~-action of monochloromercury acetaldehyde with the
card 2/3 ha-1 ) -en ~ini.:,-'rides Pf t~.c acids t~ie vinyltrifluoracetate and the

Synthenco of Vinyl Monomers. III. On the Syntheses of 30'1/79-28-7-45/64
the Vinylestrars From Acet- and Chloi-oinerci~roacetald,.,hydes, and on the Mechanism
of These Reactions
vinyl-p-cyanobenzoate were synthesi.,;ed. There are 20 referencec,
0 of -vhich are Soviet.
SUBMITTED: June 3, 1957
I. Vinyl esters--Synthesis 2. Acetaldehyde--Chemical reactions
3. Chemical reactions--Analysis
Card 3/3

YAKMVICH, A.Ya.; RAZUMOVSKIY, V.V.; BELYAYEVA, I.N.
--
Synthesis'of vin7l monomers. Part 3: A note to the syntheAis of
compounds with a carbony-1 group. Zhur. ob. khim. 28 no.3:680-682
Mr '58. (MIRA 11:5)
(Methacrylaldehyde) (Hydrox7lamine)

AUTHORS: Razumovskiy, V. V., Rychkina, Ye. F. 79-11-48/56
TITLE: Structure and Ruactivity of Arimatic Hydrocarbons.
(Stroyeniye i reaktsioiinaya sposobnostul arom--t-4cheskikh
u6levodorodov).
II. On the ReLction of the Azobond of Phenylated Ethylenes
Uith fly droren-Cliloride-7-11i trodiazobenzene (I'L. 0 reaktsii
azosochetaniya fenilirovannykii etilonov s khlorist,)vodorodiiym
--nitrodiazobenzolom).
P2,RIODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 27, 1Tr 11,
ABSTRACP: By the action of 1,1-diphenJlethylene upon hydroEen-
chloride-p-nitrodiazoben2ene in pyridine solution two
compounds form: 1,1-di-pheziyl-2-~,-iiitrcz;hutiylel.-Iiylr--ne and
cFCnitrob~-nzyldipiien-..l-carbinol~. aarinE furthiar invesUgation
of this reaction in an acetic solution the authors found that
nitrogen does not split off and thaT an azobond w-'th
formation of 1,1-diphenyl-2,2-d.4- -4-,nitrobenzolazo)-ethylene
occurs: (C H 1109),. In crder --o prove that this
6 5)2 ' C(112C6 4 - C.
bond actually corresponds to a b-fazoformula, it -gas in 'he
Card 11 presence of hydrochloric acid reduced with stannic chloride-

Stracture and Reactivity of Arom"tic Hydrocurbcrs. 710, -1! -48/156
II. On the Reaction of the Azoborid of P.,,.enylated Zl.hylenes
With
In the reduction proclucts they founc ~-,-phenylenediamine
which waa for identificatic-i conv~~rted to juironedichlorimine.
It wa~i 2hown t1hat 1,1-liphenylpr~)elle-l in reaction with
in a p-yridine solution
,iei~ls 1,1-diphenyl-? 7-,-nitrophenylpropene-l an(] 1,1-diphenyl-
2 - fj--ni troT,.. ?ny I pro panol but that in an -acetic solution the
Y me-
t re, 1, unstabip- 1,1-dJrhcnyl-2- nitrobenzolazo)-provene-1
;.-ev.--!Dps. In th- reac'l-ion of 2-ohen-.,1-,;r;)pene with hydro_ren-
chloridt. %benzime in an acetlo solution two
f~rodljcts ar, 's~77-ilitroi)hcnyl-2-Dllp-nyloropene-1 and
I'le uno,--:met1 ii-'c~--,iltroberizol-.~izo)-retl,.yi-olien-,;lethylene.
The infra.-1--d cannot, as th,~ uuthors earlier thouCht,
serve as i.,~zr-kns of provinr, the s1ructure of the compounds
obt,ine-d. 11-1-~~Te ar'-- 'I fi Ure, --Ind 5 references, 3 of which
Slavic.
V,ird 2/3

S'ructure -~nd Reactivit.-Y of Hytirccarbc-n3. 79-11-478/56
H. On t-e Reaction of the Azobond of Phenylated EL"-.yieres
With 17~d-,-rjf,-en-ChlorideV,-Ni'6rodiaz,)be-iazerie
ASSOCIATION: Lening-rad- Electrotechnical Communications Institute
(Lenin,LradsKiy i,-,,---'ut svyazi,),.
SUBYITTED: November 9, 1956
AVAILABLE: Library of Coi-L;zess
1. Phenylated ethylenes - Chermical reactions
2. Hydrogen-chloride-jr-nitrcdiazcbenzene - Chemical
reactions 3. Cyclic ccmpounds - Chemical reactions
Card

M~ M
.1 MIT-11t0maffillaffi

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RAzTjmOVSKIY6L.V.
Y.Y.Markovnikov's scientific legacy ("Selected works". T.Y.Markovnikov.
Reviewed by V.V.Razumovskii).Vest.AN SSSR 26 no.8:130-133 Ag 156.
(Chamistry)(Markovnikov, V.V.) (MLRA 9:9)

R.kZUi-IOVSKIY, Ye.
"Characteristic of the Temperature Dependence of the Viscosity of Lubricating Oils
by the Method of Blowing off a Fine Layer." Sub lj Nov 51, Inst of Petroleum, Acad Sci
U S 1-' 11
Dissertations presented for science and engineering degrees in Moscow during 1951-
SO: Simii. No. 480, 9 Mnv 55

BOLDIN, K.M. (Yaroslavl'); DROZDDVA, Z.5.; LEVIN, R.I.; VAYSMAN, L.A.
(Kuybyshev-obl.); PODOSINOVSKIY, V.V.(Kazan'); SAYFULLINA, Kh.M.
(Kazan'); BM-A.1,11, N.7.(Ka?anQ- RAZIU!F~A~MK Y,-Yu.L(Leninogrosk);
GELIFER, G.A., dotsent (Gor1kiyj; M~MISH, M.G.(Kazanl); RAFALOVICH,
M.B., dotsent; MELINICHUK 5 P 4nd.med~'nauk; KRAPIVIN, B.V.;
STAROVEROV, A.T. (Saratov~; ~~ih,;-T.M - POROSENKOV, V.S.(Romodanovo,
Mordovskoy ASSR); ANDROSOV, M.D.(Rbskv;~- ZARIFOV, Z.A.(U ssul,
Tatarskoy ASSR); MURAVIYEV, M.F.(Izhevsk~; KUZIMIN, V.I.('Batyrevo,
Chuvashskoy ASSR); SITDYKOV, E.N.(Kazanl); DUDIN, Ya.B.(Novokuznetsk)
Short reports. Kaz.med.zhur. no.4:81-91 J1-Ag 162. (MIRA 15:8)
(MEDICINE-ABSTRACTS)

~71~na in Lho p~pullatLon of the Sou~-h
-y of tne
162.
I%f tha T8t.ar A.S.S,R. K-12- z . - 6-
+ ern par t - - (I~PIRA 17:5)
'rj~iskaya ts"i 'rL. tza vrach - N.Sh. Khasanov)

LAP IFEV:i ) N V . ; PORIV A Yl-,Kv !,,'. F. UiNli'-~"',', if lY, Yu. K.
i-:, 4 :-r~i 4- e r ri .3
~4.
I. Kafedra ualt.ologicheskoy an-ator~'Ii (mv. - prof . G.G.Nepryakhin)
Fazanskog-3 meditsInskogo institlita i tsr-~ntraL naya bollnitsa
(glFjvr,yy V-1.",ch goroda Leninogci-ska Tatarskroy AS3R.

RAZUMOVSKIY, Yu.K.
ope ion o Qing abdominal extrauterine pregnanay. Kaz. med.
zhur. 41 no.3:76-77 14y-Je '60. (IMIRA 13:9)
1. Iz Leningorskoy gorbolinitsy (glavvrach - N.Sh.Khasanov) i
kEfedry patologicheskoy anatomii (zav. - dotsent N.F. Foryvayev)
Kazanskogo meditsinskogo instituta.
(LITHOPEDION) (PREGNANCY, EXTRAUTERINE)

RAZUMOVSKIY. Yu.K.
Fatal poisoning in a child by pyraphen and norsulfazole.
Kaz. med. zhur. no.1:69 Ja-F 162. (MNUL 15:3)
1. Leninogorskaya gorodskaya bollnitsa (glavny-y vrach -
N.Sh. Kasanov) Tatarakoy ASSR.
(AMIN 0 FMI ITE, -T OX I C OLOGY)
(SULFATHIAZ01E*.-TOXICOLOGY)
(PENACETIN-TOXICOLOGY)

VEVYURKO, I.A., kand.tekhn.nauk; RAZUMOVSKIY, Yu.V., inzb.; SELIVAKHIN,
A.I., inzh.
D.C. motor without slide contacts. Vest. elektroprom. 33 no.3:
34-35 Mr '62. (MaRA 15:3)
(Electric motors--Direct current)

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carbides, S
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L 1,:M69-6-6
ACC NR: AT6001392 SOURCE-CODE: UR/3180/64/009/000/0109/0214
AUTHOR: Kirsanov, V. P.; Zhilltsov, V. P.; Marsbak, I. S.; Razumtsev V F.-
Slutskin, Ye. Kh.; Shchukin, L. 1. 3
ORG: none 13
TITLE: New flash lamps with a high flash repetition frequency
SOURCE: AN SSSR. Komissiya po nauchnoy fotografii i kinematografii. Uspekhi nauchnoy I
fotografii, v. 9, 1964. Vysokoskorostnaya fbtografiya i kinematografiya (High-speed
photography and cinematography), 109-114 and inserts facing pages 112 and 113
TOPIC TAGS: flash lamp, gas discharge, hydrogen, xenon, nitrogen
ABSTRACT: The paper describes the design and performance characteristics of high-
repetition-frequency sealed flash lamps for use in high speed photography. Two
sources of frequently repeating flashes were considered: (1) a source for Toepler
schlieren photographs with a maximum space stabilized luminous volume in the shape
of a short filamentary segment; (2) a source for photographing objects in reflected
light with maximum power and frequency of flashes. The first problem was solved most
satisfactorily with a short capillary lamp. The second problem was soived with lamps
having a large spherical bulb and a short discharge gap between the electrodes locat-
ed inside the bulb. In addition, a rapidly deionizing multichanber.hydrogen dis-
C.,d 1/2

L 11069-66
ACC NN AT6001392
charger was constructed in order to provide for the comutation of the repeating
high current discharges at the maximum frequencies at which the gas gaps of both
types of flash lamps are unable to deionize and cannot themselves serve as the commu-
tating element. Orig. art. has: 10 figures, 1 table.
SUB CODE: SUBM DATE: 00/ ORIG IREF: 004/ OTH IMF: 001
Card 21

MARSHAK., I.S., kand.tekhn.nauk; KIRSANOV, V.P., inzh.;_ALZUMTSFV, V.F.,
inzh.,- SHCHUKIN, L.I., inzh.
Light emission and flash duration of bulb-type discharge lamps.
Svetotekhnika 9 no.lil2-18 Ja '63. (KRA 16-.1)
1. Moskovskiy elektrolampovyy zavod.
(Electric lamps) (Fluorescent lamps)

ROVINSKIY, R.Ye.; -RAZM4TSEVA, G.P
Degree of transparoncy of a dishcarge in xenon at ultrahigh
pressures. Opt. i spektr. 7 no. 6:725-728 D '59. (KM 14:2)
(Xenon-Spectra) (Electric discharges through gases)

67150
AUTHORS; Rovinslciy, R. Yo. and Razumt,-jova, G.P.
ly
TITLE: On the Degreo of Transparency of 6'Discharpa in Xenon at Very HiKh
Pres&urea fl -
FERIODIGAL: Optika i spektroskopiya, 1959, Vol 7, No 6, pp 725-728 (U'SSR)
ABS TR;kGT A high-pressure discharga column in xenon may be regarded as a grey body
whose properties can be reprasei.ted by a mean value of its absorption
coefficient ;i. The -7-Jue of this coefficient and its dependence on the
discharge power are of great theoretical interest and are important in
construction of -xenon lampa. The presant paper reports a determination
of the mean absorption coefficient )Z in the visible region of a xenon
discharge at very high pressures. The authors found directly the degree
of transparency of the discharge, d... wiven by:
,nhere f is the geometrical depth of the digeharge, The above equatiox
gives the optical depth of discharge and. if the value cfL f 1;
Card 1/4

6? 150
5 CV/51 -7 -r, -2/38
On the Degree of Transparency of a Discharge in Xenon at Vf~~ry High Pressure;;
known, the absorption coefficient ~k can be deduced . The method used to
d ate r m i n * t r a n s pa rency of the d is ch-urga was the sam a as tha t us ad
earlier by Fabrikant and Pullver (Ref 5) to determine transparency of
a discharge in mercury. The apparatus Used is shown schematically in
Fig 1. The discharp gap of a spherical xenon lamp Pl was projected by
0
means of a lensAl on to a screen Al vrith an aperture at its centre,
The radiation which passed through the aperture was projected by means of
a second lens -A2 on to the discharge plane of a second xenon lamp P2.
The image of the aperture inAl in the discharge plans of the F2 lamp
had a diameter of 0.3 mm. The lamp P2 could be moved both vertically
und horizontally at right angles to the optical axis of the apparatue,
The irtiage of the discharge Plane Of P2, magnified 2.5 times, was projected
on to a screen A2 with an aperture behind which a piece of watt gla66
and a selenium photocell V was placed. The authors first measured the
total luminance Bi2 due to the lamp Pl and due to the rigion of PZ
which ws traversed by the beam from Pl. Then an opaq-.-~ screen 3 was
Placed between P, and P2 and the luminance B2' due to the portion of
the dis,~harge in P2, which was earlier traversed by a bea-M from PI , -VZLZ-
raccrded. Finally the Isamp PZ switched off and the luminance B21
Card 2/4 of the beaxii frow. Pl which pasEad through the wulls of the lamp P,- -,;-a Y'

67150
SOV/551-7, --~,-2/36
On the Da-ree of Transparenc,,y ct a Di3charge in Xenon at 'Very High Pressilres
measured. These measurements yielded the value of the degree of
transparency e4, since
fA-.z (BiZ -- B-)/Bj
C
All the measurements of transpar6nzy 'were made on spherical d.--. -onran
lamus of DKs3h-3000 type using poverr, of t)00-3000 W. For the sake 04'
comparison similar u,.easlarements were carried out rn Osram lamp& c-'
KhVO(HVO)--10Ol and KhV0(ITV0,)-20Ol type using nowers of 570-1500 W. Tne
working pressure ip all these lamps was 20-,-[',') atm. The results of
measurements are shown in Fic, 2 in the fom of dependence of the degree
of absorotion a = 1 - & (in on the dizcharge power calculated per unit
length of the discnaru-s colizan (in the discharge power mas taken
to be the total newer minus the electrode losses. Fiir 2 shows that
absorption rises fairly rapidly at low Po,,,.,er*a. Above 2.5 W/cm this
rise slows down due to enlargement of the diScnarge channel. Fig 3 Sbowa
dependence of the degree of absorption a at the c-qthcL3a spot on the
power per unit len'u,th of the discharge channol~ The energy density at
the cathode spot is C-onsiderabl- hi~-har than in the main chanan! of the
discharge Lnd contaquently at the 6~ime discri~~rge powerF much higher
degrees of absorption are obseri-ed at the cathode spot than in the Channel
Gard 3/4 itself. Broadening of the cathode spot with increase of uower Is n '

67 150
a OV/51 -7 -b-2/,;6
On the Degree of Transparency of a Discharge in Xenon at Very High Pressures
great and consequently the degree of absorption is a linear function
of the discharge power. A wavelengths of 41-83, 530 and 608 m4 the
decreasesof absorption at the cantre of the discharge column (power of
4.1 Iff/cm) were found to be the same and equal to 18y,. The absorption
coafficle at Rwas deterained from the degree of ibsorption, a, and the
Geometrical depth of the discharge cham-lel. The latter vas takan to be
the diametrical distance between points on the discharge cross-section
at which the luminance fell to 1/4 of its maximum value. Fig 4 shows
the dependence of the absorption coefficient 5~ in the discharge charnel,
on the discharge power per unit length. FiF 5 shows a similar dependence
for the ca-bhode spotz The curves of Figs 4. and 5 are similar to those
shovin,v~ the dependence of the degree of absorption on the discharge
Dower (Figs 2, ~). Two points in Fig 5 which iie far outside the straight
iine reprasent the vAues oC~ at the cathode spot of a lamp of
KhVO(WIO)-lUO1 type; the construction of the cathode in this type of
lamp is such that the c.,tthode-soot temForature is high even at low discharS4
powers. 2"O-,knowledgments are alade to V.A. Fabrilant for 3u--e5ting this
work and for his advice on it, There are 5 fi-ares and 5 references , 1 of
(;a rd 4 which is Soviet, 1 English and 3 Gerrian.
4/ 0 ~r
SUBMITTED, May 13, 1959

RAILIVANOV, A,; RUTFOVSKIY, V.
I-
- -- L.
-on'LL-iuous ll-irie for repairing cornecting roda, Avt, irairisp, 42
no.7:34-36 i1 164. (m:=-~ -!5 :

RAZTJVATIOV, A., tekhnik
Stripping device for dismounting conical bearings. Avt. transp. 37
no.10:53 0 '59. OGRA 13:2)
(Automobiles--14aintenance and repair)

RAZUNOV, Ippolit Mikhailovich.
Technical standardization in the nonferrous metals industry.
1. Nonferrous metal iddustries - Russia.

RAZUS, M.
G~i~ of periarteritis nodosa treated with antibiotics and cortisone.
'Bratisl. lek- listY 35 no.10,622-629 1955.
1. Z T. Internej kliniky LFUK v Bratislave, predn. akademik
L. Dorer.
(CORTISONE, therapeutic use,
periarterltis nodosa in progn.. with penicillin &
streptomycin.)
(PERIARTZRITIS WDOSA, in pregnancy,
ther., cortisone with penicillin & streptomycin)
(PREGNANCY, complications,
periarteritis nodosa, ther., enrtisone with penicillin
& strepto-Tcin.)
(PE:rICILLIN, therapelitic use,
periarteritis nodosa in pregn., with cortisone &
streptomycin.)
(STREPT014YCIN. therapeutic use,
periarteritis nodosa In pregn., with cortisone &
penicillin.)

EXCERPTA ~EDICA Sec.6 Vol-10/9 Internal Medicine iept56
51101s. RAZI'S M. and KRAM~OVILOVA ~. 1. intern. Klin., Lekirsk. Fak., Univ.
Bratislava. e jej lie~eme. Diabetic
neii ritis and Its I I*eatnii-lit I-EK.()IIZOR 1955, 4/9 (513-523)
Tables 3
1(o2p),-t on 16 cases treated with diet, insulin and vit. IS or 11 It is claimed that
vit. 1112 hnd an excellent effect.
Stransky - Manda

ZAJACOVA, E.; RAMS, M.
Effect of diabetes on intrauterine fetal d-mth. Cesk.ggynek. 28
no.8:552-555 0 163.
1. 1. gyn.-por. %lin. iek. fak. UK v Btatislave prednosta prof.
dr. S. Stefan]* a Int. klin. Lek. fak. UK v BrAislave (prednosta
prof. dr. M. Ondrejicka).

11-114v-5, 14.
HMGY 1, M. - RAZUS, M.
Food allerg7. Bratial. lek. liBtY. 30 no.8-10:649-658 Aug-Oct
50 (GLML 20:4)
1. Of the Skin Clinic and the first Internal Glinic of Slovak
University, Bratislava.

RAZUVALOV. Ya.A., _bhlen Komunistichnoi partij Radyanslkogo Soyuzu, agroliso-
In the flame of the Civil War. Mekh. sill. hosp. [81 no.12:10-11
D '57. (MM 10.-12)
1. Studenikivslka mashinno-traktorna stantsiya, Kiivskoi. ablasti.
(Ukraine--Revolution, 1917-1921)

I*-'TIhII'-NI ~*'..
0 vospitardi kolkhoznkh ka-drov Phe trair-ir- of collective fa-m si~ecialist-9/-
Moskva, 1,11oskovskii ralochii, Zl-954.:/ Cl p.
SO: 'Month LiELt of 11tussian Accessions, Vol. 7, No. 3, June 1954.

'. . ~.. , r-, ~ z -~,- - ;- -, -: ~ - I 1 1 , ,
I it - : ;-': '-- 7- '- :, .-, -" ' ' . - - . . - - : . : -
~~ I- . . 111. . ... ., , : '.
, ~ f~ :,. . I . I . .. - - . - . I

L"FLIS. V.S.,, 'MOFIMOV, N.~;.; ~UZUVAY__!T, G.A.
i
-,)r- 10 Q_ 8
Cid, inat,ion of olefin oxidr-3. Zhur. ob. khim,- 34 r - :27 4-
(,'-IT '-..A 1'/: 9)
2787 At, 164.

.ur-her i..pr~Dve.ai~nts ir
n. d I, S t Iv Ks pru;ii.,
9. Monthl List of Russian Accessions, Library of Congress, -r-rch --1953-, Uncl.

-WUVAYEV, A.A., redak-tor; KOPELEVICH, Ye.I., redaktor; ELIKINA, E.M.,
t'dT&ntdhesk!y redaktor
[1-6nual on the primary processing of
pervichnot obrabotke 11na. Pod.red.
nauchno-tekhn. izd-vo Ministorstva
potreblenlia SSSR, 1951P. 494 p.
flaT-l Spravochnik po zavodskoi
A.A.RaznuvaAva. Moskva, Oros.
promyshlennykh tovarov shirokogo
(MLPA 9:7)
1. Moscov. Tsentrallnyy nauchno-isslodovatellekty institut lubya-
n-kh volokon.
(Flax)

RLZUVAYEV, A.A.
...... - - .
Results of socialist competition of organizations of the ;L11-
Union Scientific Society of Textile b2gineers. Tekst.prom. 14
no-11:51-52 N '54. (KLRA 8:1)
1. Predsedatell shyari, po itogam sorevnovaniya.
(Testile research)

RAZUVAYXV, Alekaaadr. Aleksqadrovich~ SAPUKHIN. Aleksandr Aleksaadrovich;
GIMTSOV, P.P., redaktor; SOfOLOVA, N.H.. tekhnicheskiy redaktor
[The power of an example] Sila primera. Moskva, Goa. izd-vo
sellkhoz~ lit-ry, 1956. lio p. (MLRA 10:3)
1. Sekretarl RamenBkogo gorkoma Kommunisticheskoy partii Sovetskogo
Spyuza (for Razuvayev). 2. Sekretarl Kiyevo-Svyatoshinskogo
Raykoma Kommunisticheskoy partli Ukrainy (for Sapuk-hin)
(Collective farms)

KARKOV. Valentin Vasillyevich; RAZUVAYIIV, A.A., rettentent ; ARIIO, A.A..
retsonzant; SOKOLISKIY; I.F., r4dakio"-r"; M&DV.SDNV.L.Ya..
tekhAicheskiy redaktor
[Primary- processing of bast crops] Pervichnsis obrablotka lubianykh
kulltur. Moskva. Gos. nauchno-tekhn. izd-vo Kinisterstva legkoi
promyshl. SSSR. 1956. 291 p. (MIRA 10:2)
(Bast)

RAZTJ',1,,.-EV, A.A., kand.tekhn.nauk
For further technical progre3s in the initial industrial
- processing of bast fibers. Tekst. Prom. 18 no.6:9-10 Je '58.
(MIRA 11:7)
(Bast)

DMITRIYEVA, A.I.; SHUSHKE4, A.A.; YJRONOV, K.M~; DERBEI-11-11r, S.I.;
GRAINIC1916A,
Z.F.; OKUNI, M.M.; 14IKHAYLOVA, N,11.'- A11DRE-YEV,
V.V.; MA=V, V,S~; OS-TFCI,'A, V.M.; LIVOVYY, -V.S.f
SMIRNOV) GJT., nauchrry sotr.; ZAIKIN, I.:;'.; TALI 7 1! S2, IK'-;,,
G.N.; 1-IORKOVE1, V,A,; GALAGATI, V.A.: RAZ4-VAYXVj--".) red.;
SOKOLOVA., V.Ye., red.,- IRISHINA,-.L.A., tekbn. red..
[Manual on the industri-ed primary processing of flax]
Spravochnik po zavodskoi pervichnoi obrabot-ke lIna. izd.2.,
perer. i dop. 1,11oskva, Rostekhizdet, 1962. 755 p.
(MIIIA 15:12)
1. TSentrallwy nauchno-issledovatel'skiy institut lubyatWich
volokon (for Dnitriyeva, Shuslmlin, 1--lironov, Derbcnc-r,
Granichno-va, Okun', Mikhaylova, Arxireyev, Makeyev, Osipova).
2. Vseso5,uzr-y-,- nauchno-issledovatelIskiy institut okhrany
truda (for Smi-nov), 3. Upravleniye zagotovk i pervichnoy ob-
rabotki lIna Kf.lininskogo sovnarkhoza (for Zaikin, Tallnishnikh,
Mork-ovin, Gale-an. LIvovyy),
(Flax) (F-1ax orocessing machinei-f)

RUTKQVSKIY, V., inzh.; RAZUVANOV, A., inzh.; WDCHEDIKO, A.; K-U&NSHCHIKOV,
V., inzh.; GI-.1VAS, M., inzh.; CEITSOV, G.; GAYETSFY, A., inzh.;
Cil,'H, I FER, , 3. 1 i n z h . ; Z f f I ~ Rl F I f G V'j K I Y , 1) . , i n z h . ; ""'IRU ZH, , R . ;
31,14ENOV, A. I lllzh.
Exchange of experience. Avt. transp. 42 no. 5:51-54 My 164.
(MIRA 17:5)
1. Glavnyy inzh. Tarashchanskogo avtoparka (for Ludchenko).
2. Kaluzhskiy avtoremontnyy zavod (for Semenov).

RAMPAYEV, A., polkovnik
Coordinating a division; a method of carrying out a co=ley
exercise. Voen. vest. 44 no.6MI-76 Je 164.
(MIFA 17:6)

KORONKEVICH., V.P.; GUSTYRI, L.Ya.; RAZUVAYEV, A.N.
Interference method for measuring thread elements. Izm.tekh.
no.2:8-14 F 163. (MIn 16:2)
(Interferometry)

S/115/63/OUO/002/001/008
E194/E155
AUT11uRS: Koronkevich, V.P., Gustyr', L.Ya., and Razuvayev, A.N.
TITLE: An interference method of measuring thread parts
PERIODICAL: Izmeritellnaya tekhnika, no.2, 1963, 8-14
TEXT: Since the shadow boundaries observed in the microscope
do not coincide with the actual profile of the object, special
measuring blades are used to reduce errors when making measurements~
If the part is curved in the optical axis, and the measuring
microscope has a small aperture of illumination parallel to the
part outlined, interference bands are observed which can be used
in measuring the part sizes by taking the first interference band
as a reference line and calculating the distance from this first
band to the shadow outline. However, difficulties arise in using
interference bands in this way mainly because the distance to the
first interference band depends on the focus of the microscope and
on the aperture,,of the light beam. The present article assesses
the influence of these factors. A solution has already been
published for transparent objects and large apertures
:(D.S. Rozhdestvenskiy, Trudy GOI, v.14, 1941, 112-120).
,-Card V 4-

5/115/63/000/002/001/008
An interference method of ...
E194/E155
Calculations are first m6de of the positions of interference bands
at the edges of a cylinder, assuming a parallel light beam in the
optical axis. The following formulas are derived;
/(r Cos a + + + x - r sin X (1 + cos u), (2a)
2 (r
Y)
U U
x r cos t tan u r + r sin y tan u (3)
where: 6 - difference between the distances travelled by the
direct and reflected (interfering) beams beyond the point of
reflection; u - the half-angle of reflection; x - the abscissus
of the interference pattern; y - its ordinate. The position of
the first interference band is found by putting 6 = one half-
.wavelength and y = 0. Then a table can be drawn-up relating the:
distance to the first interference band in microns to the cylinder
diameter in millimetres. Various errors are then analyzed. Quite
a small error in focussing the miqroscope has a considerable
Card 2/4

------- ---
An interference method of ... S/115/63/000/002/001/oo8
E194/EI55
influence on the result and the development of a simple and
convenient method of focussing is a prerequisite to the application:
of interference bands in the measurement of parts. A small angle
between the incident beam and the optical axis is shown to be
relatively unimportant. The formulas assume a point source, but
in fact the microscope always has an appreciable aperture. Up to
a certain point increasing the microscope aperture only affects i
the outer bands; however, above a certain critical aperture,
given by the expression
f% Cos U
d =
u
2 r COS -g + Y sin u
the interference bands near the object lose their contrast. For
example in examining an object of 100 mm diameter, the critical
diaphragm of a microscope type IJVIM -21 (UJ~1-21) is 4 mm, and with
an aperture of 8 mm no interference bands are observed. The radius
of curvature of a screw surface R is given by
d
R cp (12)
2 sin a
Card 3/4 2

An interference method of ... S/115/63/000/002/001/008
E194/E155
where: dcp - mean diameter; a - thread profile angle. Tables
may then be drawn up for the correction in microns to be applied
for threads of various mean diameters and profile angles. In an
experimental check of the theory, to obtain precise focus, a
cylindrical gauge of known diameter was measured by the
recommended procedure and it was taken that if there was no error
the focus was correct. Standard threads of various mean
diameters and profile angles were then checked by measurements
with blades or by the three-wire method using the same microscope;i
divergences did not exceed 2 microns. It is concluded that,
provided precautions are taken to ensure accurate focussing, the
interference method of measuring screw threads has advantages
over the usual blade or wire contact methods.
There are 5 figures and 3 tables.

A,!_ I., c~,koric in. naitk; KA'ZAFOVTSFV, N.M., -'31DCRO'!'JC If, Ye. A,, lnzh.
irlzh.;,,YA.i',ll-VAYl:V, A.S., inz?i.
Imprc.vem~--nz, of Tne econGmic work in stations. Zhel. dor. 'xan3D.
Z"7 no.3-5'7?-72 Mr 165. (MIRA 18:5)
1, Nachallni-k proizvodstvp-nno-fekhni-cheskogo otdela startsii
Novosibirsk-Gla-myy (for Kazakovtsev).

RAZUVAYEV, A.S.? inzh.
Dependability of the basic allocation expenditures of railroad
services on the voltme of operations. Trudy NIIZRT no-33-161-177
16-3 (~~! 17: 3)

-BA,WOY zhener (st. Mikolayevka)
~.A. Iu
1 ~_~XX
How tbi snow melter works. Pat' i Dut. khoz. nw.3:4-5 Mr 9~".
(Railroads-Snow Drotection and vmmoial) (NW 10:5)

RAZUVAYEV, F.A., inzhener.
. M61V We~eC6MM12e on materials for track superstructure. PutJ -,ut.kh02.
no.4:28-30 AP '57. (MA 10:;)
(Railroads--Track)

I I A I I I to 11 ft 11 u is $6 It 96 a It- 22, IS A 25 gat IF
A It L-A I r
I'nk Pel-I N X No Tit,- Im
(fir Awtillitiou ft'llis ode'l is( tsoltd. 1,1411 t,-l
lit
n. 11, mI in the I)TrWnCC Of Catalysts 93 *14(h. Ni,t),
is der differrut preutims and tempo. For A.'01111 the reac
AcIl f~ If.; AM ---v- Cit, + CO: CO + Mit
*0 1 211, --P- Left, 1- 110). For MeOll: Nfroll --W e
---W ell, 1 11,41, or. 11.1t,4111 I Its -W ell, I If,()
00
V%plto hit* the fAhmills: (1) The traction protersk still,
~,-I oI Vil.rvoliv-1 r-maitt the vni of 11, lakril (2) Th, Is.*
velocity wilts Ni,(), a- with Mitts + Alto.. (3) The eyolt
jprr-m.-A 11%) solm ) Ow anloont .,I ell, L4;11.
& 40 Al."ll, WIT.. Nit k never quaml, This Call IW VIL111,1I IIV I
;hR)' thir viototlyst. N60s. he"Hor. kilverr'l wills illp taffy It
00 lumIA. Thraddit of A60, dorts not lirrvrtit this pls(n (4)
diva not drlwnd tat the quantity of ale. takru. but depends In
Thus at LIW'and 25 atm. and at 22%) * and IM atm.. 5.5 and
09 respectively. (5) 1 n the unchanged ale., Cli,O anti Acif sort,
0 with alsovir rquatimiq 00 With 010 + At.(?. clltmI
19 An 42 sa ad a
A

1111to"'Ib." .1- e. 00
1. .-t 1- It

- Al,t), anti Cut) + Al.lh
-00
onq Orr a% follows: FtOlf 00
('11, F M41; or. KtOll
p I It., CII.o 1, 21(. -90
loblikir-4 1-1111. j 1:1
.*e
A h- of itt'-wile. a. l1w 041
I.Ill pt.k-J. will) I lie -nt.. .
on of Cit. .14it. at
I-ell- NP;-, .1 :;111 :1.1,
V IdVt (Ildt 41 lentil, o%rr
In
Its, .811oullt 'd ell, 101111-1
r oil the initial lit l)rr,%%urr.
411.4 C I Is were obtained.
0 0
sv~p . I-iod in ace-miance
the mactom ll.mllv oo,
00
00
ft It L tTA%,LI,PGKAL LIT(Rall,111( (LAWFICATICot m
00 8 10, t I.P. I ago
400
LU Is 4. It a ad 0 0 a 0 3 0 W394
Am i so 4
to to a 411 a 11 Is 9 R Is rt it Its n is WIG
0 0 0 0 0'0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1111 0 0 0 IS 0 * 0 0 0 0
0
4
0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 a to 0 0 0 0 0 0 0 a a 0 41 0 0 0 0 0 0
12

e U-6-0
6 0 0 O
0 6 0 * 0 * 0 # 0 0
"1 11
l
I Ii.tilt old If SO Lit Ij It A It 1110JI111
AA 04 4PL W it I
L
t
A a r F .
--
a 14 f 9 It

Synthesis Of te-chl-oil"lilkhlorearsillt. W.
RA2UVAl1V AND A
.
Slit)
%" " 1?ujj Pkvj -Ciem- IRki---4(19~:9 Ber. 6313, 174-N, llk;()~--AtCl,
7
IS
and 3
M
. ir. MC C11 he2led for 4 bm at 11W pie 5.; C. !,:;~) ol-flivrojiv.W.

A;!
dichlar-jime uftrt belin. by crytn.. whitt-, m. 411,6 1 21% Tlw c,
anpd- &-cmpd '1~rn
4h
t
4
" was acuussited. thus shv)wing the imlaAsibility of f,ftpjg. it ACcorJWx to (be
metht.1 of Turner W
A
19
H
d -00
.
.
,
y
rolysis of it a, with hot diL NA011 pmfucrd
4
f
id
4 i

6
ar-tr
6. o
oroityry
irlixtr oxide, in, 115-117, Oxidatim of 7.5 g, of the original amine -00

00 X: , in air. with ff.(), virldrtl 11.4 c. a-ckloreittyviarsmir ". in. 1,1& AP. =00

0 J!
Action of hydraps as mmitic oramak componside under h4h pressure. L Ac-
lion of b
l
d
la -:2111
rogem an mil
m
y
c arpsic ked c da0fthii type PbS. V X lr4T'v%-,
G A- RAzvvAxv Axti Wtntoimuv
J
PA
Ck

0 j i .
, am
YS.-
inv 61, Mil
,.Mrr 639, *M 42(i10)).-The action of H cm tetraphroyl. trtraffirthyl md tetia.-thyl
-
1%
~00
drriv%. was im"tiPteff. The initial prmturv of ft an't duration of reaction Wert,
00 u ft,und tit havc an imlm)ttant influence on the anit, of metal obtAinvd: MR, -r :Ift
I-h + all. 0

ZOO
00

-40
00
L I I k L U Pr1K AL LjTfo&T~Rf CL*SvF1C*T1Cm
FPO

t

D
, -
0
-,
U
-
I An I

it x
P
a 0 0 * 0 0 0 & a 0
0
0
T S
0 o * * *
0 * 0
4 0 0
0
000
0
o
0 00 0 0 0 0o00 00 0
-
: :
0
* 0
0
-
- 0
0 * * ,

- - - - - - 7 ; ; ; - ; W
Is w W W W W W W W
-*7-
11 W Is
11 11 U It V
A 11 C a L.1 A 2 It
a -1 - L-L A NJ L-L *4 111 CC,* 111GA-1, S g- J. 4 1 '1 - 1, 0 a
.
[
Sergration of snetailk serclary him its largamk 4141LATUdVOL (1-A RAZV%AJLVA%
7
o
s
. %f. 41 rqm; J. Ccis. Chem. (if- S. FL R~) 1. W4-
74(1931 ~-Tbe dtc=M of sweta.50.
-
K. cutupda. with "It. of mew Mad fogrostion of the corresponding byitrucarlb,'"
was carried out with lilt derim of the mietah of the Sth group by I
4. n77) and of M by lpatiev, IL and Bogdanaw (C. A. 24. 2CWr=Mb."-in=C-
2
gated in the orm of III from the Ila-mg. amnpdjL of the types of U.14S (R - Ph and
i
PhClf,) And RJIgCI (R - l
lt and MeCaff.~ anti also from IIxC4 by heating 24 firs.
6

,
N) alm-4 If litruiurr In Clilfeand UtOll, the lilt licing tirlivailrd im titild-1thret siviral.
1
11c, -I'll. of Ill; froul UaCll and RJlxCI dri-ends on the nature of s,4%rut- thus the
rractitm with llgCl,
'MeC.H4IlsCI and 11h), gCI in C#1lj begins at 34.15-504
while its
00 1 .
.
EtUll 75% of fig is deposited from HgCJ& and 95% from ?*feC#lfJicCI at 20()*~ The .00
f V septi. of fig front IfgCI, in water is even greater than in EtOll. Sintilar reaction in
' ago
f
a
the MIMInCr of If XhL)Wrd no ppin. of lix. The decoullm. of I
h.tlg And (PliCifthilif
0;
00
dclicuds on the Irtup. anti Li pracdcally indeliendent of the nature of the *)IvrnL (Ilh-
CII,),lIg is decontpd~ into lig and (MCIIA with and without the prcmnce of It showing
Go 0
that the reaction is purely pyragenetir Phjig in CjIj in the abomee of H aboirs Do
Coo
0 wlill of fig after licatuts 24 Ill%, at 2-W, and tinty 9~e after heating It; hn, at MW. coo
:0 IN while with 11 theselm, of ItS reaches W17, on heating 24 brit at 275'. the traction pro,
' moo
omiling thtt%: Ph,11% + Ill -'I C411. + jig.
I he Im-mall"ll #4 C.11. was 11riluinstral"I
00 4f 1 wotking with I'llaill in ligrocti anti %cpg Coll, as VhNth b% tistratxv. %hie tvt traces
7 11h
ld I
d
l
"
00 ~C
, cou
rioctri
- Soll
t rraciton talcs placr W stli,itit the UW 4 a "%Tnt- 00
It is assumcd that with the increw-tif tritir the Nmd twt-rvn Ph &z,4 Hj becomes '

weakened wW Wtlallr di~~icd. with fLwwatxm tit rTvv radxx:~ which revict with It goo
Philix z-- 2 Ph- + Ili; I'll- -t- 11, C.11. + ll~ M41; 2 H C.H6 -r
7
,
118 t1tilpert And Olriittncr. C .4. T. 2
7S4. Gdmaxl~ C
A -1.'C. Px-*t!L C A- 13~
.5, IM); and I'ai Lw "J jorw!L C. .4 M IS-411 S~bhs,~-= Mazid

atTALLURCK41. LMO.TLAC CL.S$WK-tiCO a-z-
a.". moo
too
0 I a 0 Age ill T,-";
Is
0 wo 0 0 9 0 0 0 0 a 0 0 0 0 0 0 0 a
o 0

00

0
:
0
0

0
00

JN~ all %it I'll'
'00 1-411111111"., .1 'p,tila smito ,111 I'vil -.VI to
-
.
f
e
d

0 0 d
) rf uplow 4111 ifflim
"All tj XmIr.11 tit oil pi
.q (q it, till"I "1111.11w Jill upirial
fl
.
PY. Uo 111 1.1fil.m. 3111'.1 jitAti.41.1p Jill P. Istitl v .%711 it, "It f;- 201(sirmi m pit pidd in
00

00 j
. ..-.A .j I.-, unts; 1XMI.Ints ills vat"Jalix1v JIM11jilliv lip P? 'fil'ift, atls 71"Illaw-u Jill IM
~tu.iujjui tit t.Tv pwq PIT '"llvisjul Io -ultl.g uy -tgjtnk3 rw %I int!)"tw iql so
00
L atil EXI 13aya Ou llvq 1101..1 Fit Slisq,f P) 101w jql
fa P.SAU Jqi sfitil 7111 to a 00
m >mL~sp a irqs puncil SVIA if PUN '11411"itIM03 aWW ff W"Xlj,l .3q1 lia.1juall *jjz1v
'
i,cid :3u-q- if-soMiatil cn
+ 11113 c- flo;ffz).I;v + -q,f r :4,1 z + 'if - Il so
futIM13" 'Palw uwqi w" Neu tiog3mu *qJ SAM HOUR U! 3PwPir Jill 10 -lissr Jill -,in-
pidd PIT r, -I,ttv J41 at Pilliktcas'"t) ruttli"19119.1 j. -3tttvjq.(, -,(wtr pitv,q!j '.(PVI I-
11(liq tit Ijl,ij,l pi unts.7ow jqj papaic cra AJAM3 JjalV 'Inp-ru qlfw r, t3it-10 )ql
of ut tiv to cit"situi (tit lytiv jl vit go ~uf ifrpwaj rixqa tunipwit jitila Atiff Jet 11(ju'l tit
00
IT i-qis- x, qiftta it Patio.pT u,, qjl~j intir IT( aim I,(-q.1 p, Aq 41-i1. t
IT
-040

0 0 0 0 0 0 a 0 0 0 SO 0 0 0 a 0 0 0 0 e 0 6 0 0 v : :
- -&-Alk-A-A -Z-0-0-0 1_0 0 0 0 0 0- 0 0 9 0

-- r, a- 4, & e, a e- t Mi 4-4- W W M 9
0 6 0 o 6 o
I it a a 24 D A V 3 ?t X 11 Ij
16 11 1 1 1 -1 ' I - - I L -J~/*
A1, C D L I,-! R A L -L A M P Q R I I "Y 11-1-1- L -7- Z a cc - U A,
4
00 .
j

A i Rupt~re Of this Hugs of heterocyclic arsenic derivatives, G. A. RAZU-VAEV AND _0
M M. Kovoti. J. GM. C". (U. S. S. R-) 2, 529-.-WI932); ct C. A. 25, ixil-. z6. -06
M34-The stability of the rings of dihydrophenarsazint. phenexarsine and diphenylenc-
AflinC Combined with chloroarsince and aninic acids was investigated. By analogv -0 0
with 10,chloco 1j,104ihydrophenarvasinc (1) (Zekk mul Gocskil, C. A. 24, 122) chlorn -00
phenox2riinc (11) and diliftenylenechloroarsine ( )
~alst) the non-cyclic antipili , itich
as Ph,MCI (TV)) are decompti. or) heating with TO with liberation of MCI, by r- .40
1 ersing the reaction of synthesis. R(C,114~AsCl + 2HC1 == l'bik + AsClj Pit,-
00 1 Ci + 2fiCt AsCls + 2CJij. (a) R - NH (Lewis, Lowry and Hcrgrint
00 x! 15. 17-10); M R - 0 (Blicke. Weinkauff and Hargmvrs. C. A. 24, ItIaS.,
- single bond; (d) reaction of synthesis (Wieland. C. A, 17, 1783) AsCl. +
0 3C.11. ---s- Ph.As + MCI. The dccompn. proceeds at 125-200' in the following
00 oraler: phcnar%azine derivs.: 1, to-cbloro-2,7-ditnethylU.10-dihydrophenarnaiiii~-
(V). I G-chloro-P. I LLdihydro- 1,24"zophenarsaxi ate ~Vl) and 10-chloro-9.1"ibydru-
3,44wrtzophenarsazitte (VU). then phenoxchloroarune and diphenylenechlorousine.
roe
For the synthesis of h, c and d was used AsC4. which with equal force catalyzes the !
reversed reaction of decampti. Arsinic acidi am decompd. on beating with 11,0 intty goo
1h,R and A3(XQII),. The reaction proceeds more easily in acid sohm, while the salts
00 of the acids are comiderably more stable. and the addit. of alk. salts retards the decurupti
1 he results in the decompn. of various cyclic adds showed that the stability of the riusi
changed. phenozarsinic acid (VM) being most stable fo[lowed by dipbenylene"sinic
o0
(M) and thm phenarsaxinic scid, (X~. The cyclic arsi~ acids are ie~ stable than z
the non-cvclic acids. A inixt. of 0.002 mol. of a chloroarsine and 20 tx~ CC14 (conts.
(MAM 811ol. of JlC0 was brated:14 bra- in a sealed glass tube. the mass was then shAmn
j with N*,C0# to hydralyn AaC4 &ad tiftaW with 1. optimum deeomptm: I witjoot
catalyst 57.5% at -'q)O*. with AlCh 85 at 1750 (rcsinification); V1 W.5 at 175- and SS
*
'
at 160
; VU 67.5 at 200
arA 97 at 175% V 10.2 mA 4U.S at 175% IT 48 and ro 5 at
AW; 11124 ard 49 at 2()0*. A MlXL a( 9 g IV and 115 et of CCI, at& with
bested 48 he$
t 250e
d
i

I L A . a
uc
, Pro
ng C41h, A,Ch and rtsin. Ar%inic acids (1/6s inol.
at I it L UP h
t
d
i
h
)
A I e
w
ea
t
10
ce. 140 or aq. alkalies in a Ax tube under prmurv, the mass
was was!,
d
~
with alkalies. water and E40. the alk. soln. was extd- with Ft.o.
tj~'lr ,,.,
th-- armnic
act filtered Gff. dried and weighed. A%(XOH). and M(Mitt were d~'A -rhe eth,
m -
6 j ext. of I gave I%Nlf m 531- ph
0-
,
d
f Val
h
.
,.
; an
o
:(J. .1lic
, p
I h. tr
an ,
ated 0
r, ti tt with Br in L S,
front a1c
in
M V

0*00

0 .
.
..
, ti
CHAS
0 0 0 0 M o 0 o a V - W- w 0
0 We
0
0 o o o o
0 0 0 0 0 0
0 0 0 0 0

0 11 11 t. 11 14 )1 is 19 a,), 22 Z, )d J, 16 P 20 20 JU P 1: U U a k j/ a of 4) of Q 41 43 f!
a L F I I it 1, L a h, P f. 0 S T V AA 14 CC W U-,t w - d U
00 -09
-.00
Migration 4nd Nomination of heterocyclic arsenic derivatives. G A- RAY.-v~r,
st, NJ XI Kt.i-v .1 (" Cheng (V S S it I J, APQ1 0 C .1 27. 1K9 -00
09 R Ih- (1) will diplicityleurchlonmrJur (11) suhj,-c(~d to mild ituidlimi -00
410 pr-luk-,A the nurates of pbenozargenic acid. 1()(C.IJj)jA%(OIfhjN(h guid diphruylene- -00
Arwtl6- acid. j(CsIIa)&As(0)I)vjNOy, resp. A more energetic nitration of the chloro-
00 it amiurs and the corresponding seift rtsWied In the foriguallms of on-dinitro %ilb Ilee
t lie lorolmoble igirmulas (XC#H&N": O)OH and (C,1I.N(jit,),A.4: O)OIf. Ilvanakgry ..0
with nan-c
00 yrik- chlorusissinn I aw H add Big. the re%ultinft halo derivs. 1~ing ~wily 40
hydri4vird to the Mh O(Ce1I&MsRr,CI + 1110 - (XC.IlOvAs
( 1?1j)JJ Urdike ,=h, '10-chlora-D.ladihydn-itheitarioxine (1111 is iwt
.1i'llied by HN(h to an F.F =20 but forms mooo- and dinitto deriv%. tif chlorw
airsine, while the action of Hr causes tb* rupture of the heterccyclk nuclcu4 with forma.
These rractions W to the propow for ID of the frilloviing ~true- C:
tural formula ~!1=00
+
A /Als
or Zoo
00 4
Zoo
00 21 whit-h served mi explanation of its coloring (Kappelmeier. C. A. 24, 24:1.4; Gil-ti,
Johnson and Vining, C. A. 25, 107). The specific reactions of [if may be characteristic
of the general prnperties of the phenariazine nucleus and other &rivs. of dihyd~
phctmr~ine (rvt~pt the tertisty arsines) might react %imilarly rcxardl"~ of Their
cokiring. The colorless 10-sicetyl-9.1MdAydropbenigirssizine (FV) rracts an2lognu%ly
t,, 111; i. e.. the nitration of IV in ArOff pmduced a ppt. of ruano- and dinurn drri%-%.
of IV and a soln. of cfinitrophcnsv~ziuic acid, while bromination resulted in the rupture
of the phenargaizine rinx. CHAS HLAMC
:lee
A Is I. A &EIALLLPGICAL UTIRATLAI CLAISIFICATION zoo
Ike*
it An L S 0 04 0 9 0 1 N P. 1 13 0 a I
it ax n
0'
to 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 61

0 toII I I I T- t- T-1 It I - -v'11;V;j1uu unlit? Uri m : 0
A4 R III- ~LM Mil AV ft.
o0 A (f & a 16 _I& . 'u
.00 L #&its '.0j.
-00
00
00
00
00 -00
00 -00
Ilk-
-00
00
00 014 P. GOL. -sump-dw IF NJ~DAXOT
~ 'i
00 -rij
liw
0 0 T" by the sdjn 0(
0001 r
o j Se sb"Bm Of a 8Wvent. x60
0 M. Z. coo
:
Sao
2 moo
02
coo
moo
x0e
-00
rAO
-f T1'--Al 07!~.Tt;.E CLISSIIICITIAD~ bee
lee
Ilia,) L.
LS i-w-w -% II ~ W, ~
Or a ---- age
00 'Ofooooo;oooooooooooiO*0090000*ooooooooo
oo::::?Oooooooooooeowooooo1000000000000

7
W W IF W W
a I f I Ic t 12 11 U Is It 17 1# it x V 24 zS 26 27 A n ]a 11 U13 S, Is U v Is J9 4; 41
~ 0 43 as f!o
a L__f_ _ it L y L AA If CC h 4 -
L

Oxidation *I arsenious v
In aigWe wM atmaW.
heric oxygen
= alkali" Medi
um 11111der
AMU V and h4h 1cm-
-Ail ";i
to
*
S S. R.) 6, 2W'_ I
(1933) .-Oxidati
9
f

go f, on
MA in NAOH
-In- under prmure
Probably takes o
f
alm (a) at low ternp- (100-11(r) ae.
cording to AU

9 j N ' + 4N&OH + 21/,% - 2,V&As(.h +
~ S + 2H,0; (b) , 150-3%
As
+ 70
% + IoN
1
.
aon
7 - 2NajHAzO, + 3N&,So, +
4H
O
44 i
l
h !1=00
go .
.
n t
nnffjd.,[
e bomb fct&fda th .
c rea"'On. while an exc
.
nu effect T
b
4so

0 es,
,
,
he
th contact gurf- has much ind c
c reac
u nee of'
"on vel
i
i
m
t
.1.
cs in the liquid and vapo
he oxidation in ~,O
r pbasL,.
C%
i

0 ,
W
n. ij slow
5-~ er and requires
higher tefnps. i
i 0

00 on
n N&OH soIns. The
CIP11. Promfure is In detail asS,

to X . A A. D,

g0 0
Zoo
.40

A I& -I L dtTALLI,vf.VAL tlff*ATLRF (LAWFICATIC 0 Z" age
00 ::K00

-

i I
'
n -
ff ;o, 0

o
0 U An I S a 'Id 0
9 '1 0
n j
7 It ff tt It CC
;
la 1
~

0909;0 'n
a
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.
:
0660009066006 0600000000-000000000009~

00 e a 0 00 0 O'~
0000000009 0 * 0 q 0 let
I ! I j f ! ! f 1) Y 11, 1 k I g 1. 1 a
OQ A, I 4:j 0
L - 1 4 It A I, A 1W
00 A lif A-ty- Nh
00 F__
00
00
00 di ft*PK*M"WA6Wl'__G. A.
AppLftm. n
timm., 1933, 6,
ompaimile have been -00
(too the dih Mid nmm
0 x: come 10. . the
0 .3 :
"himillv- ML
BL
1-4Nr
'P.
coo
06
147" (dliooomjp.)~ MW -.10-ism : I
m.p., 146"1470. The movs
Or (11) an mcludim wil
k*O XGUS(k. ow an tmat.
It
III =12 (U), In flidue" with as 0
way
-4pkmyl).g: lo. 2*0
and
00
i0
R. T.
*-ILA WALLURGICAL LITC.1470C CLASSIPICATIC06 z
woo!) squ.; -IF ON, 4-C OK O-V As;
0 ~'o
S I 'W 0 w a 1 9 " I Q 3 11 1
u cpall cog Icit K IT cg It cog .01 ixjk I
ONN::1906066600999999 00 0900000*00000000000
000000000000009*eooioooooooooooo*oeoooo

go so' 0 0
a 1 4 1 1 1 1 0 111 it 1) 13 W 11 1, if bf 41 : : : * 0 100
A I It 21 1
L a it P 0 1 4 R j It is J, 1, x J.
__ r
so
-.00
0
lke&4Uam betwoom 1K and
cItmin d1hy two
:J. S. R.) 4, &2"l0iM)--
with H01h. 041*
(1). HS. CC), AU-1
c.,Ij., with MiRt. it yields to-ethyl-9.10-d1hydrophrnar- *0
~,Litw tu) and ( 11CO0,111. (HI). &it.] with I'M% it Yield-
I and 111. 10-Chkw--0,10-dihydrtvphenar%szim OvIll,
I and rW'h&CI, with PhPh, In C,11..OH. U and PbritsCl. ZIP*
kith PhUt., -nd I and IIrPhCI with llitl'h,. P. C. A.
00 0
0
5W 0
is
Zoo
-00
0
00 ~o o
0
coo
wee
L S M Od 0
IN 19 09 19 K Ir I, Or n I Im I i3 a 3 0
10 0 0 0 0 g*0"'O"O" 0-0;-o 0 0 0 0 10,1101, 01.,
0 0 0 0 0 01-0 6 0 v
00 goo 0
*400041100*000000040,

0---0 0 0 0 0 0
: 0 0 * 0

W -0 0 0 0 00 0 0 0 0
0 a 0 0 0 0 00 0 0 0 4 0 0 01 0 0 a
VV a
Me 0 0 0 0 0 0
I I I I S 6 1 1 to it 12 11 14 11 t6 11 to " 0
l a .A J5 III V is )t It) it V 31 M z kuRN4;
il 41#)Ij CEO
A 5 L S -L,J 11- Y' A R I ~ .1 V. y
a 11 a I AA of CC M It
411 A pt, I M,- It. 0 1 -I
"

00 -OCISS&S --V INCrI.I.I.

C~Wydc
41 "a-
71 -00
G. A. Razitiv
if. L I wir and M. J61. 21
.
it U. S. S.-Jp.)~4;-647-52(1934) -. d. C. A - 27. &313-14.-
Pd
j4patiff-stes decompa. of p-suhatituted Fbjjg in the
fIAO-ing ill-asing cirder: M-CIJIFT, MEWL. B1`Cjf,,

1'1()CJI.. MeD(411i. Ph, PhCH..
The comptis. an first
'Imirapused into metals and radicals, the latter uniting at
the sutface of the catalyst to Plis catupda. The relative
0 %Iiccd of decomlin. of (a-Collihifs ii Out given by the

above scries; C..Ho is formed at the e"nse of some C'elf.
groups which tire dehydrated to C. The relative raect%
00 11
of citiailysts in sk. we, in diccreasing ngder: Pd. Ni, Au,
40 As. Cu; in tetralin Pd. An. As. Ni. Cu. fit ale.

00 Ci-HY)sHssivcsRHcowpds.;aflothercompds. treafe(Igive Z:04
RR; in tetralin hydration alone is observed. 16 tables
so J
I give the results of expts. M. Compounds of Issid and
tin. M. N1. Koton. ]bid. 653-7.-Ph.Ph (1) anti Ph.Sn
06 (U) undergo decantim. at 15W tinder the catalytic action
00 of inetal tiling3. In the absence (if If the relative jj&--
~~ goo
creating effects on (he decompa. of I we rei
hy
200
LtA the stries I'd. Au, AS. Ni and under pressure of It hv 11.1.

06 t M. Au. AK. Cu. Decumpn. of U in prcsencc of If I% not
ii,hserved at 150'. but is complete at'20()o rexardk- 4 the
z 0
OO *nature of the catalyst. Inthealmriccollitheffeconifin.
C
*4 isrlightaith)0'. The relative decreasing effect %of rat a - :-0 0
ly-Ats in the can of U, In the absence ut it. are I'd, Ag, Au.
Ni; in the presence of If. Pd, Ni, As. An and Cu. C.11.
results from both I and U in the presence of Ni, while wit It
I'd Ph. is fumed; An stimulates both reactions. In the
-
;:W
0W
L tIAL0.1-GIC' absence of H Ph, is formed in all cases. G. Tolpin -
0

,
t -Rxt

t
It It N API L 1 14 0 4 1 V 11- A] 1
MID 1) 3 a F
r
If p
0 0 *
Ze 0 0 0 0 :1 0 0 0 * 0 0 0 0 a 0 4 0

0 0 0 0 0 0 0 0 6 0
0 0 0 0 0 0 a -* a A 0 0 0 000 0 0 00 9 00 * 0;

0 0io 0 0 0 0 0 a 0 0 0 0 0 0 0 a 0

0 9
o 0
'I it
q (k if
00

Potentlometric titration of small quantities of vanadium
9 in steelli with high contents of chromium / L. Ra/u
'IMeN'a'14t,-4skaut lab 4. 414 1111113.1- It it, It,.
n3-i.n 'If t1w mrou.] -.1 mut I it, L, it~ ~ c A
.
-00
f& ".) ill,
23.
Mill" 00
00
-00
00
-00
.00
Z*
.00
99

-t 0
-00
.00
.404

0 0 0, 0 0 6 o V o 0 0 4 00 0 09 to
1:
0 0 0 0 0 0 0 0 4 0 a 9 0 0 0 0 0 0
0 0 0 0 0 0 & 0

w W-W WW
1-4--vur
i-
Z
1
i
-1 1) .4 IS A 11 'a it Z? a u 19 11 11 11 bd Is Is 11 If 0 Ou At 41 41 0

00
01

A. Ris.!~asrv mal M.
CAstiss
2119
(11
S
S
R
361 cf
) S
C
A
36 0
.
.
.
.
.
.
.
.
.
.
;
29, Wl'.-Furthw expd. evidewe is hmdAt!d to the
0
effert that the derumpn. of the Ph derivi. of fig. Ph stul -00
Sri of the type PbpHg is accurrijamatied by an imemoiliate
formalim of free Ph radicallit. which then react with .00
vation, vornlifts.. while that is# the IvIse
a puxe pyrogvmlic reaction. latijill with tl,hNlt)2 its
ligroin, when heated at MW for 12-0 hrs., retarted 1(%)~

00 accoll ing to the formula: PbHg + PhNliN1fPh
2C4116 + Us + PhN:.%Ph. P%Hg, listated with hivinvi
00 unit iianisvrse~ at 2W 300* For 24 hr... ft-M. Its; :;zoo
00 aml gavi, mme inmil. isilid darcornlin. pr"hicts until It#,
Calls and 1114. Amilar results were obtained with livrr-A,-
G 0 mtlZ&-2W'. Evidently In theft mum the frev Ph rod",
rrect with the tramstd. consfids. with the formation of
polystiffistati-as proaluets and not the mMn. iorsijki5_
111i'lls with 2-buteric at AN), qrm. fig and fiWto,,if a 00
avAtraw in.4. voniT41.. 1,robehiv f~cll.llm (a.
'
.00
ft". 28. AM(IIQAS)). PhilsOll with 11.0, h-at~i at 175
00 for 48 hr%. at SO If stiff.. wm smoothly av. -.00

00 tuvwding to the reaction- P%HgOH 4- H. - C.11. + Z400
Ifff 1- 11,0. A inks. if Ph.Pb with S heated at M11' fia-
24 hr*. and that of Ph,Sn with 8 at 215 a prodocril I PhS)s ~00
Aml PIS arml Sng.. r",. (PhOlls),lig with .14, hmt~l at NO 0
IIW 1,,r 24 Ism minal at BW fist I hv. stava- (MCII.I.. 111,,;
&list S. Chms. 111"tiv

f --00
0 0

_ v00
0 1
Z' AM L I a 3 1 W H -7 If
:
0.

0
"L3 n i
tt u if .v
Is
0 0 0 0 0 0 0 0 0 : : !q 6 0 0 0 0 0 1 0 a 0 4 9 0 0 * 0 0
::
:
166600004*609000000

- - - - - - - ~ .-v
lk * *,r W-W 9-0 -- 6--1-1
1 4 4 f it U k t$
004
00' 4T PXCK95195 ANO F10091114% INUS
W,
00
It U a v n is it Is x 43 41 Q 41
ffy&oxy-d=4vaUv" al
A M" pao.
i Of WAMQk"hvMy-5-R-5-W-5: t04J.

:: I
=bdatft tMp. FAR
o
00 a V:
;f~ V., S. MAUSOVSKI . Gen.
j --m 'I[ [wi
37"74, 575 SMOAT"
:
d1l jWfth 0. E. A-Mus,A]. 5-Nothyl-5: 104hydro-
at (w)"
M1 CHqO)JI In C,
H
l
Id
Z.
L AsAwal ftwthiodkin of 54&yl(
zli
d
i e
.
.
Y
tertarmsiTivVirM tbr, following brims
ibrnv
-
An nitvat" with A H arml AgNO
rftpeetivel
m.p. 237-M4 (No imw (%'), rn,p~ 1198,; Mitrwe 0
.,
y
pho"ydnwWc of M.P. U2. r,,jOW, M.P. 170'; 1"NiONW4k, M.P. 13tt-140'; piemir
*

1118*; Iff'-4rivative (11)), of S.*Xgl. 199
tu-
1; the armlopm II-Ef dcrivative, m.p.
4 -
170*)
Or ;z (marak
m
is obt^ine(i i4imil
l
M.P- -'1&2-2N* [xisruk, m.p. 210*;
NOjr
-
-
d
i
i ar
.p.
,
.
y.
im-aba*
rn
(IV) or (V) aford an aaky&,We (VI)
p
er
vat
ve (111) In 120-1
24
1, &M Of 5--dAyl-
5-i0oamyl-5: 10-d -
11
1
i .
.
,
,
of the beWrA type. when lamted with &q. X&OH.
. I-P~e 00
"n
g
(SUruir, "1.P. 191-1931. Attampta to redum the jU djftjjro~.tiT8 of (VI),

*
NO. of (11) and (111) resulted in its affininAItion. obtained from (IV) wW HNO Ids (%
I) when
Z
l
d
ith F
i
OH
NZIr It
T
roc
uoe
w
.
n aq.
.
e(
),
WiJ i
, " RM-F~
A I I L ".A'.. CtA 5AAFICATKI0
tic., Smaji..
0 . . I F 4
U AV No 0 V,U
Ig it
to
0 o 0 0 0 *1* st 9 0
1440 a 0 0 0 *1* o 0 0 0 0 : : :
A Z"*
a
Op
-09
If*
=00
zoo
go*
Igo's
see
too
ctoo
'ZOO

:1 T) 4 15 j, 17 to 21 D B .4 5 A 1, 19 J, 1, jj 4.40
00 -00
0 0A .00
0 arsomftm
00 0. A.. Raguy'Im,
00 v. 8. MAtinovszz md D. A.,"i*k In.
RumL, JOW, 5, 721-727).-Aalool 0 md HNO,
. 1 .00
the aWROW*16, a.p. _JIImJIW H
00 4 0~1;
004 M60 to
the ~tme hyam" dy, dWdWAN
Ted.
.:no AX4NO&
00 Asmei-off wa A:&. The
=00
as hi bmn
following axopm y
IS P. Cie 0
1 M15
A W W - 0, IHL -00
I Jos-!
M.P. IWA W , -JDb T- -
00 107'~, AsPkJ&J. M.P. AmS IT =~OKI
I age
1419-4510).Aar4Ur _0s,
R 1. M.P. I xe 0
In. A 10- Ad WL, b.K
rve so
F;, 0
171 T
147 =xyl).
14r it
(plitram, M.P. T.
Oo.-
*0 too
00 .00
0 0 0.0 o 0 0 0 0 0 0 0 0 0 0 0 0
00 0 0 0 0 0 0 0 0 0
0 * so* *a 0 * 00 es *see 0 * 0 0 0 WO see 00 4060 a 0 0 00

ar c1 Olldtko-,, -Le
j
-VZ
53,

V_ Bill ;W_W ; W_ _-__ ;;;;-_*
0l: 4*00
'I r
14 1$ 16 n so is 16 5 a 9 a ill , las u ill 0 a 41 13 Voo
A I C A N J __L___L a ft r Q A- 4 IF -1 1 M JBAL go U44 1 a 11 1. al -
eo all Pbsescacbeenical reactions of MOW otramanic compukands
olosencuryinspelutine. 1. Reactions of diphenyimercury.
G. A. k"ustactr And Vu. A. 01*darkiolt. Zhur. Obsk-hek
00 Kki-mo,- ij. Varn. Clicut.) 10. 7.341-001"W; IT C.I. 43,
III MOM -III I..."
00 11,11,111jig i -- :X'.11. I 11V a Ilk,1141, 1.1 .;.*, III,
mALit I, with ., 11A quatij Umv. v_ VIOIK
mt NIO all X.,%c 1 2 X. 11K. I., _4 ... ... CO., thl, p-1". I
,ivTv I'MIXIC1. MIC1. All'i ctcl.. all
N whruir Phallic J- it, - Mille I I'll ; I'lliff - CCI.
VIIIIdCl I CO. . I'll- I CO. - 1,110 t LCI,
- C.Cl.. I'lle IrAction I~Iaav.u I'll .,11.1 Ccl. 1, Ill L"
00 J! mat wills flar itrartrilumilhij %lel; timilvrat Ili ilia- ic.litt-m
I-Cl"ven Wills land CCI., rhr "mr atmb)xy appli,, I-,, =00
limid. ill,- re... liams 1. I-vil m.l ClICI
md, -I Ille '.111vt h.m.l. I.-tvacctl 1,11,11al .111.1 C110
Itstmas 1,111111C1. Call.. as1 *0
if,, 14"llas 1 4. - 1,101al I I'll I'MIK I t lit'l.
00 VIII[xi'l I CIIVI, . I'll I ClIt'l, Call. a s. 1, 1, . -00
~,Vcjl - CIO.. Visa. L'I.- W tbc 1-11-0 CIRT " .-I
A-t-! 'I'llc I~t 141,11K a."ILC4 goo
&9_91 "I C,II'VI. 1111111-1411 Al %ilia flat' I"I 1.01'A 490
jlaiav~ rtmvt4 "ilia Ille 11 al"Ill all file -1vir.11. vl,.t ,Ilia
Ow 0 A."11- %%ilia .11 :1 -Imit, coiltr_ INIIII C1 .111.1 1(. as*
Illetv I~ A v..2, taliglit 'i.le tv.1"thall Ilt.011,111% Im-l"Ilt. lix 200
lmll.Ilioll a 1,11,11g Wills CIO. ill C.11. 1-0mv,
I
PI'll't"L N I b.m
tie 40
A%kk C1.11.101.101).
woo
a',
as -71-TIN
IS A. .0 A%
I; ; tv ft at a -4 n ill Is .9 a a Is as MI; S
0 0000
0 so 0 41 0 00 0 . . . 0.
ae LA

Photochemical reactions of organamercuiry compounds
In solutions. 11. Reactions of dipheny[mercury, G.. A.
Razuvativ asid Vu. A. Ol'tickoll. Zhidr. Obibehel Khim.
(J. Cwn. Chein.) 19. 14K3 -6(1949); cf. C.A. 43, hm&j.-
Irradiation of Philix (2 g.) in 15 ml. C1111r. with ultra-
,-i-Ao liglit 12 firs gave 1.9.5 g. PhIliBr. m. 278', x% well
.1% C6114 jidentirml a~ -C.l-f,(,%O,1,j. In is firs. Ph,lis
tit CCII:CIICI timiLirly save 9517t, I'MigC1, tit. 257',
atilt C#II*. lot-11130, howevirr, ever) after 200 lum
v but 16.6% I'MISCI and 0`70 Its Only a trace tit fig
red after 3 weeks' reactlatit of Phitils In h1e;CCIlls-
=
CJIMse. In 100 bre, Phjf# In PbM* gmis 20% ms-
chatig-I I'listig atilt it t.trry unselmrAlife in.%-. Ili 214)
hrii :1 g. Philig ill i.Vl-PrOU 6CAV12- W2.31~ lfg, C4114,
Alto) Ntr,CO, with Ili'; I'litlig fmivviy, Ili 41) firs,
1,11:11K ill Ft,o g:,., !kill. Jig, C.11., and Avif; in '.15 lim
in Rtucll,cll,oll it K.ive 71.1'-, fig, C.H., a I Aelf.
while ill 25 bm in NICICO it gave _02", Jig, Call'.
.l.nd an unitlentificif YOow tna,ii. After 2l-hrs.' Traction
with rtChClf there -as lit-atiot, of Jig. complete in 1*1
fly,., along with C.11. atilt a small atilt. of I'll, IU..
Photoreactions of dibenzy[mercury. f6i& 1487-9-
1PhCII,)jfIg It irradiated ill MeOll itith a fig Limp 50
firs. gave 98"', fig jiul N)";, hilwnzyl, tit. 53'. A 40-hr.
reaction ill Clict, g.tvr NO',' Jl;;Cl atilt bilic"ityl, wt Well
.is a vlillaix undi'till.16tv ,it. 1,1111g0fillh (bv ficuttlig
llhcll,)Igcl will) PhIS110, ill F11)li collig. :.V', N4011)
mujil.irly it) 2.11 hr,. tit NIOM g:ivc lig tall 70`~
Philig, 4mra: C.U., atill 6s',' lid.-itivi, while 25 Jim tit
CHO, g.iVe 6-9,; Jig, w,-, IlhJJgCI Cliff.. and ;'iS"; -
1104-rizv], :Ipp"triltiv LV vinim-tr1r.1tioll, foll-med by
r-11tilm if ill,- ~vm d, r,,,. i,Amdu.d!v. C. N1 K.

F
USSR/Chemistry - Organic Compounis, Jan '49
of Mercury
Chemistry - Light, Effect of
'Thotoreaction of Organic Mercury Compounds in
Solutions," G. A. Raiuvayev, Yu. A. 0111ekop,
Gorlkly State U..4.,Pp
'Mok Ak Nauk SSSR" Vol LXIV., No I
Investigated photoreaction of several organic
mercury compounds, dipheny1mercury, o-ditolyl-
mercury, a-dinaphthylmercury and dibenzy1mercury.
Submittei 20 Sep 48.
AM

CV
E-
Om/Chemistry - Mercury Compounds Aug 49
Succinimide
"geaction of Bromosuccinimide With Several
Mercury Organic Compounds," G. A. Razuvayev,
N. S. Vasilaysbaya, Gorlkiy State T~, 3k PP
abok Ak Nauk SSSR'!. Vol Lxv:rI, No 5
Gives general formulas for the reaction of
brcmosuceinimide with symmetrical and non-
symmetrical organic mercury compounde, and liste
Uw Nnew" compounds: n-fi92-C6H4E[6NC4H 0
4;2y
66/49T25
/Chemistry Mercury Compounds Aug 49
(Contd)
C6R5C~2WC0402 , n-Br--C6'14WC4R402,
92~~C444021 n-CR30--C6R4UNC4H402,
n-(CH ) NC6E1 WC H 0 Y and CH WC R 0
3 2 4 4 4 2 4 4 2
Submitted 3 Jun 49.
66/49T25
tq

UM/Chemistry Photoobealstry Avg 49
'notore'actions of lodoorganic Compounds,"
G. A. Razuveyev, M. A. Shubanko, GorIkiy State Uj
4 PP
"Dok Ak Nauk SSM" Vol LILVII, No 6
Tabular outlines of the patterns, of the re-
actions of (1) C6N5 vith mercury-containing
bldrocarbons (C6115)24, n-(C6114CK3)A, o-
(C6RtCH_3),,4, and IC6R5CH2)23g in C65 I CH as
C91 OR, and CH -CHOK -CR3, (2) C6R5~ witi
Ox )2Sb in CkOE, C6B6, and CECII, I
1/5oT16
MR/Chemistry - Photochemistry (Coutd) Aug 49
(3) C05CN~' v'th (C6H5)24 in MACK, and C6K6,
and vith o (C 11 3 2 -in CE30HI ind (4) C1131
~R2%CN ) H9
vIth (C6E5 (C6H9)38b, and (C~;)2R9 1h
CH309 and C6'U6. Submitted. by Acad A.
Nesmayanov 3 Jun 49.
1/WTl6

Photareaction Iof metAlloargenic compounds of mprcurv
in "lutions IV. Photareactions of dI-.toIyJmercnrv
U. A. Razu%,irv mill Vii. A, (st~st, I ill
(;~wki)- Zhia. o?,~h.44 Khiffr. I]. Gvii. Chrin.f Pl.
JSI-409W): cf. C.A. 44. ;M',Ih ll'-NII-ClIld-11K A'
,2 X.1 in Ill itil. MINI irradui-l :PI hr, ga~~ I~W
fig mid I'll Niv (i.dated U,
III g.1 its l"I'd.
lit,1.11.1two g~i%e 0.52 g. [ill. 41,a ml. PlOte, m4 A-Af~
~,mlllaly I ill I..'IC),01 Jl,t Iq lit-. g,l%,- fig, HINIC. 1-1
Al while CICII,Cfl.Ci 4' S'llv"tit K.1%, ill 1~, III,
fig, llh.W, an,l :lff~ Cl I L'I I .
[-,,l %imiUrly xa~r 510'~ fig, -mt, unrt,.wtv-1 1. 17' ,
T
1\I,C.Il.IIKCI. :([Ill aq -01 ;1- lccl,t, 14,'. I-kI
iss CCI, for 11) hr-. 7W', -M,CjI.jIgCl, CA 1.~
17l ; 1, triff a liquid which with K.%tw 1. g;tv,. -UC,114,
01,11. Apparently the reactims, N-gm t,y ., .,(
Mcph alill NIX41i'lig radirak. I" \1 K

Reaction of bentoyl pstaxide with 1,2-dichlotoethmne and
-'~"chi '. ~ -. Yu. A~
I r MFI . _ j, ';' ImWI,
... ... v. P,,kljdy
auk S.R. 74. 73-tugum-rbe radic,.O-Ivl~
eactions in systems Conte. Bz#O~ with balgenatfti ethan-
were studied. Heating (water bath) 125 g. BztO~ anti 75~v
Mi. (CH,O), some 20 hrs.. until the KI test for Bzr(-), wj~
nee., pye 61 g. BrOlf. 1.5 C. p-PbC411.CO%H. 0.05 11. Ph,,
~hned 40% CJU(isWated uthe 04NO~~ deriv. by uitr2tion):
nonaromatic constituents were: 13 g. (16%) trichlor~
butenc, t4s 95-103", osV I.W7, d:: 1.4040, 4.9 g. ruixed
6ichlorobutene anti tettachlurrobulane, ba 105-1W. and
1.2 g. pure 1,2,3.4-Wrachlorabadane, tu. 73-4* (total yielel
of halogen derivs., 25%). Some tar " formed. BrA
75 g. with 400 ml. (Cllcl'~' similarit gave 24 g. BzOll.
0.5g. PhCJl,CWl,C.I-f4(iSOlAtrtl as the m-dinitruderiv..
3.5 g.~ and 21.4 g. (23%) heptachlorobutent, CCIt: CCI-
CCI,CjjCIt(bylouof 1-10 from theoctachloride), m. 79-9)"
(front MOM. G. hl. Ko%olapoff

C"It-
Reactions o( diphenyl- and diethytruercury with bromo
all
:id.%, hyptibramit em. and with perbentuic scid- C,. A.
111%,lrv '11141 S. S. %'&.,ilrf,kav. tStaiv I'lliv . (;,w'kiii.
0,.khj,lv Ak,nf. Nauk S.S.S.M. 74. A tvi"
TV, '111110, of evil. r%"11115 oil file 11.111or of thr mn-tl.,114 .I
Phrilgand Eftl1g. Broinusuccinimide oil healing reacts fly
the imlic roole, Willicalionoitl lit being allachell to the ralli-
,al of the Rillit Colupd. us"I. fftlwr~rr, when ullraviolet
artivalion is nsel, l1rattaches ill the llg atorn and not to the
14 l1roup) atuidvs of AMII, 14011, and O~NCJIXOJI
-'rner nustatcl) rr-let with R.-fig like Jk.ilie-,. cleaving
1111C.A1111-111th the WOU 1101. lit MtCtillo.
oul fir pdoetl the radical R .( R-fig ill A 'i'le-reactlon. Urn-
AK %altkof c-PrCO-11 tn,f lizoll
Ill CCIl K.I%'r the re-NI). hYjKlb((noitV%0f th-al Ws. whICII rC-
with R.lig 4-. typical pos. lit reagent, (W is bound to
k after the rrictiotO. Reaction of Ph-lit %oh HiChIl in
ClICIS was complex. going through radical forruation, which
reacted with the solvent and yid(W I'hl[gCl. PhligOW.
C.1f., 14011, and phthatic acid (probably by Ilvdrolysis of
ci,(,C.I(.C(vf i. C.. Ni. K,,~.Upoff
Ile
s1

Photoreactions of phenybatercury hydroxide G A.
RAZU, Lev and (;~ U. Pettikhov tStalv I niv Gorki,, Zhu,.
Ohsh.hrl Kki.. (). G4.11 ChI,m.) .11.
Phl/kOll '.ith Clict'.
.. ..... I . 1, Ph I'l- ... I till .... till J..... .
411 tit. IIJC CmIIJML 111to raj)"J"I. %till '116~-41114 lit Actom of
the (III radical tAing If hoin tit,- to forin 11,0
Reaction with McUll in 20 Ins. gavc C11:0, Ph:. CIII,, and
11g; LtOCJI.CJI,OII gave Jig, Pht, C.H.. The ts~ of
CIICI, gave PhIIgCI, IIXCI, IIjCI,, Jig. C.11.. lizo, and
C'CI'; CO. "vivId"I PhfIxcJ. 11,0. CIO., Ind an uni'lenti-
fi,~l org. Jig conilml. Reaction with Wit in 90 lit%. gave
.,7% If,O, 55% fig an-1 21~ Ph.: re..ction with Md'h in
,'At hus. gave W211o il'o' N1110 1[g, 4% C.11.. aml a mixt. of
ounwric inethylbiliftenyls. The reaction of PhIIXOAc
with I:tOCIIICII.-Oll in 30 hrs. gave 9-Scc fig. 82% C.11..
"Hill AcOl I, A trace of Plij. and Ad I. G. NI- Ko~lapofl

of MOUNW-9KC& -peawk of =--I
in suotims. Vt. Resdicate of dinaee~ A.
RAZU V
Vu. A. OlAtkup. as
kJ), Zhur. MIA" KEW. Olen. Cb"ti.) it.
430-ti(ILMI); cf. C.A. 45,
in phot.urvactious front PhHg by the eaw of ckavr4p of the
rorg. radicals from fig. RcduzinglI6.5g.3%P14pFFw,W.3
X. bcomomesitylene, 26 ml. dry U#Pb, and 1.601. HtOAc
14 bra. at 130% decanting from the Hg and M4 Is, filtering t
but. and eats. the ppt. with but ClIfe, pv*M.I% diwesilyi-
"Wresiry (1). in. 23S.. IrmaiAtion of 1 60 bra. with RtO-
cUsClIsOlf gave 97% fig. some AcH, and 71% tnesit-
Arlic (U); I and ivo-PrOli~aftet 440 bra. pvv M.3 HS,
lot R'lld. OMW, (7). and 771 1
,~, It. "d
1111"lac r, ~Ccl
CL In 130 hTs. JAVC 14% SCI,. lu'llic )fact. 4.4% If
.#ult 11, and.C.C14; Similar reselloil 'A ith MAWS It,
. I cl
(UNN.) C.C4 Mild Ifiriffluff 1 1, 1 Or 1h
1.1 it. ~kvhdpiddw A his, i4t 170' pisve 70% U. 9% 11g, and
31.6% 2A6-Mr.Cj1j11j,V(COC11j)j (1111). m. UN"" (!rtxn
aq. M011); ibe welcurrruily formed diixeciniaw4mepropy
Was detected (tk)%) In thi ftW" aq. soln. by twelitment
ith U.S. yildizix IINS. M with coned. IICI in hot Sq.
HtOl I rftdily gave ligClw. It the heating of the original
mixt.isrunfor4iltuin M" M may be obtained. Ifeating
t X. I with 2 S. freshly pwd. As 3 It.. at 3W' save
.;9%1I,tZ11.AndAj-Ilg&tina~tu. Intherlmnipa.reac-
don%o(j, the f(wmficmaijbtditnorappeantol)epmvmted
by the stcric 1-t- ~ I , C.. M. Kowupeff