SCIENTIFIC ABSTRACT RASKIN, SH.SH. - RASKINA, E.M.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


RMSKIN, Sh. Sh.

D Irfe
ertles of pol) hms arpak togz~poezodjs. borayl chloride, borrocol. and t7rJobimariM its dil. soln- in
%
I A Sh. -vh. a.-kin mrfanov state
? C4110 or CC14 weie 3.7, 1.6, 3.0, 10, 1.2, and 1.4 D., re%p.

IJQJ _= .i
V~ jLenifiguld). DO*MWy a&.
By
The dipole moments of 1, camphor, b-,rnyt ch1twide. lvwucA,
8l7 -IUrrUZ%TAT.Mr translation isZed- in
U.S. Atoms and cyclohexanot as the pufc suintancens (from the- 0imiger
Efte?,ly Comm. IISF-tr-118. 1-30053)).-The temp. de- equation) wpm 2.4. 2.2, 1.4, 1.2, anti 1.3 D., rc,;Iv. Its
pendence of the dielec. coast. c' and diclec. loss a, of cam- soln., increases In concia. affect 1_~ (ttmp. at which inax.
lhor, a-chlorocamphor (1). borneol. bornyl chloride, cyclo- diclec. loss" start) very little for camphor and boruyl chlo-
-
it
l
f
t
l
d
l
l
d
l
l
exancl, and also a-bramocamllhor (10 (camplior and its x)rneo
o
e
or
an
irtatio
an
tit
e, more strong
cyc
qu
y
,
dClivs. were used fit racemic fdrm) were measured in the strouglyforlt. The relainfinn time r lit I lie *441 state for
mkrcmivc region X - 3.2 cm. All of thew comll. except stauces cxrc!l;t 11 diffcrs little front the rclaxa-
all,of the suir
It dlspbved strong temp. dependence of t' and a
owing to tion times to the case of suins. Therotationalcriergieswefe
.
i 2nd-wl~r phase transitions.. ~ in comparison with the re- estd. by analyiing the curves lot r - f(IIII. hints. of
suits at lower frequencies, the temp. range within which nd bnrny) chloride have rotational energies clo%C
=
discohilnuot(s changes In the diticc. properties occurs Is liquids such as brotnobenzene anti butyl bromide.
t.
considerably wider and Is displaced towards higher trmps.
~ The rotational energy of mols. of I is consideratil lorW.
l
l
l
i
Wb
o
f
The *
values attain appreciable size, whereas at lower fee- ortico
na
ound
n mo
s.
The largest rotati
energy was
'
f I I
hi
d
fi
h
i
quencles they are almost zero for some of the sub3tanc" stenicti o
s ten
s to con
rm t
e ex
and cydobexanol
, t

studied...' The dielee. properties of II, which has no 2nd-
h hese
boads above the range of pnlymorp o= transition for I.
prefer tivasition, do not differ from those of ordinary cryst. SubstAtIc". Aubrey P. Altediuller
substances.- Ile temp. dependence Of MIXI.S. Of H and I
sh - wed dis lacement of the d' and a' curves towards high"
~= Increa
s
in
conen
of H
=
but th
l
f th
.
.
s
e va
ue o
e
p
g
,
lows ~ ~ernalried about 'const. Ile dipole moments go
Of th6w. compds. were ditel. at -varying concris. up to the
'Vire PoZar compels. The dipole moments of H, 1, camphor

Ai o Raskint Sh4' Sh.
Ined di=M-6n speotra,of certain molecular compounds 'ontalning
C omb.
Sb(C2H5)3"
Dok. AN SSSR 100/3..485-486- Ta
n,21, 1955
'7 Ab Ct I The application of the combined light diffusion spectra method for the
study of SbCl systems is discussed. The preliminary results obtained
C6H50H systems are presented. The
by studyinp, 2bdlq - C6H6 and 2sbC'3
spectral frequencies of these systems are represented in bands the width
of wbAch varies between I d 40 cm-'. It was establishel that the
.5 an
Intramolecular frequencies,.do riot depend upon the intermolecular reacAon
with exception of-sudh frequencies as OH, NH, G -': 0 and so forth. Six
referencesi 5 USSR and I German (1912-1955). Table.
astitution, ~The A. k. Zhdanov,State University, Leninerad
-~-'Fre3ented by: Aaademician A. N. Terenin September 13. 1954

K, IJ

AUTHORS: Malysheva, T. D. and Raskin, Sh. Sh.

TITLE: On the Raman Scattering Spectra of Solutions of SnCl
4
thane. (This translation corrects
land SbC13 in,Dichloroe
,
an error in the original title.)
(0 spektrakh.kombinatsionnogo rasseyaniya. rastvorov
dikhloretana.v SnG14, 1 SbG12-)
PERIODICAL: Optika I Spektroikopiya, 1957, Vol.III, Nr.4,
pp.405-406.. (USSR)
ABSTRACT: one of the authors (Raskin) studied earlier the Raman
Scattering of complex compounds containing SbC13 and
SnCl which are, used as catalyzers. Definite
4
changes of the spectral components were observed In
substances containing unsaturated hydrocarbons. The
present note deals with the effect of the catalyzers on
saturated hydrocarbons. As an object of study 1,2-
dichloroethane was used. This compound has rotational
isomers and is sensitive to intermolecular interactions.
Card 1/3 Atheory of~such Anteractions (Ref.2) states that the

-i"E I
61-4-26/26
On the Raman Scattering Spectra of *olutions of SnO14 and SbG13
'in Dichloroethane.
ratio of Intensities of lines in Raman spectra of
different isomers.9 and consequently the number of
molecules.of different configurations, is determined
primarily by,the dipole interaction. First:experiments
using photographic photometry showed definite changes
in the spectra of solutions. In pure dichloroethane
J75,30653 ~- 1.2 (J 753 is the intensity of the 753 =-I
line of.the trana-isomer of dichloroethane, J653 is the
intensity.of the 653 cm-l line of the other isomer)
while in.an,equimolecular solution of SbC13 In
dichloroethane the ratio J753,/J653 is 0.8-0.9, and in
an e imolecular solution of SnC1+ in dichloroethane
J75~T653~- 3- In spite of the presence of.strong
background and fluorescence the observed effect is
undoubtedly greater than the experimental errors.
Multiple records of the Raman spectra of pure,dichloro-
6tha:ne and solutions of SnC14 in dichloroethane obtained
by pliotoelectrie raeans confirmed fulli the ahl-lier
photographic) results. The changes in tnu
Card 2/ 3

Z
WO
'AUTHOR: Raskin, Sh. Sh.
TITLE: On :the Ra an Spectra of.tho Lient of Complex Gomjl~ounrls Which
m
Contain 3bC1 and SnCl (0 spektrakh kombinatsionnogo
~3 4
rasseyaniya sveta kompleksnykh soyedineniy, soderzhashchikh
'nC1
SbCl i S
3 4
PERIODICAL- Doklady Akademii nauk SSSR, 1958, Vol 127, Nr 4, pp 645-641
(USSR)
ABSTRACT: The present paper gives results.obtained for the spectra of
crystals of the complexes of naphthalene and di ,phenyl ether
.'C
. The inves'tiga-
bC1
0 and 2SbCl
Il
with 3
(2SbC1 ~*0
)
'
, 0
a
2
1
,
3
5
ifficulties..
tion~of these compounds presented the well-known d.,
A 'table contains.the frequencies of the Raman'spectra of the
compounds under investigation.~The,spectra of the comnlexes
show characteristic differences from 'he spectra of individual
components: Firstlyi a marked new distribution of intensity
and a shift of frequencies can be observed. Secondly, new
- lines appear in the various,spectral ranges,and several
freauencies ofthe spectrum of conponents are split up., The
authors devoted particular attention to the complexity of
Card 1/3 the spectrum in the range of the valence frequencies of

SOV/2o-123-4-19/53
On the Raman Spectra of the Light of Complex Compounds Which Contain
SbCI and SnCl
3 4
SbC1 Thus, in the.-spect rum of the complex 2SbC1 (C-6H520
3' 3
there are um
4frequencies.in this rangeg whereas in the spectr,
of pure,SbCI in the crystalline state, only the two
frequencies 313 and 349 cm- are observed. The occurrence.of
the new linesin the range of the valence frequencies of
SbC1 is due not only to molecule deformation, nor is the
3
complexity, of the spectrum connected with the second com-
onent of 41 ting
p the complexes, nor, obviously, with the exia
~traces,of H 0. Thesenew frequencies are probably due to the
2
hew bonds between SbCl and the molecules of the second com-.
3
plexes. The possibility of the existence,of a similar effect
in the crystals of other metal halide compounds is Pointed
4,-er.inves t4
out. The authors are at present car.-yint; out furth
gations of the spectra of SnCl complexes and of other =etal
halides with~various organic Ampounds.There are 2 tables
Card 213 and 7 references, 6 of which are Soviet.

.,.AUTHORS; Polyakova., I.D. and Raskin, Sh.Sh.
-ra of Certain Halide Derivatives
TITLE: On the Raman Scatter4ng Spect
of Acetic Acid in Variou-3 Phase States (0 spektrakh
kombinatsionnogo rasseyanlya nekotorykh galoidoproizvodnykh
uksusnoy ki3loty v raznykh fazo-vykh sostoyaniyakh)
PERIODICAL:'Optika i Spektroskopiya, 1969. Vol 6, Nr 3, pp 343-348,
(USSR)
ABSTRACT: The paper reports Raman spGotra of triehloradatio
~(Ccl,3000H), chl-ora-'et in" (CH201000H) and bromacetio
(CH BrC00H) acids.in liquid and solid states. These spectra,
2
were obtained In ccnneation with earlier work reported in
Refs.Ij 2. The results ats given in Table 1 for the three
acids in solid (crystal) and liquid forms;.,for the
chloraoetio acid the authors report Raman.speetra.of the
three polymorphic. modifications with melting points of 51,
56 and 6100. Characteristio ahanges are observed in the
region-of intramoleaular vibration frequencies on transition
from, solids to 'Liquids. The. sharp lines of crystals are
Card 1/2 broadened and spread in t obands, and for some of thema

SUV/ .51-6 -3-1U/28
.'On the Raman Scattering Spectra of Certain Halide Derivatives of
Acetic Acid in Various Phase States
background (sometimes unsymmetrical) and satellites appear4
Some of the lines disappear altogether, others are displaced
and in certain regions the number of lines increases. All
these changes are particularly clear in the Raman spectra of
trichloracetio and bromacetio acids, and are somewhat.less
prominent in the Raman spectrum of chloracetic acid. These
effects are due to changes in the association of molecules
of the'three compounds when they are melted; they
are particularly clear in the changes of the number anu
intensity of C= 0 frequencies. There are 2 tables and
.7 references'. of which 3 are Soviet, 1 translation from
English into Russian and 3 English.
SUBMITTED., April 7,~, 19 58
Card 2/2'

5%4), 24(7)
AUTHORS: Ras n,. Sechkarev, A. V,.

TITLES The Origin of Certain Di ra c-1
f f ererices in Raman Spect A
Acetamide and n-Phenylene Diamide in Various Phases
PERIODICALS Doklady Akalemil. nauk SSS it 1939, Vol 128, riz~
pp 67 70 (USSR)
A3STRACTs This artic' e, presents the results obtained by,the authors
f rom arn in.-.,,~stigation o the Ra---ian spectra of aceta=!de and
phenyl dia=ine.' Crystallin.':~ acetamine was znveslt.gated I.n tw:~
polymorphous variations (melting points eo~2 and 480) and in
the liquil phase, A comparison of the-ir spectra dis,~Icsr-s
."Zifferences,between somr~ 14nes of T--
!at-e.- be2cng both tcr~ ~.ralence.osciiiations ')th"r k"'n;s c'
molecular'oscillatiors. These differences are due
o *the ability of acetazide molecales tc assoc,-ate ty Mear-M
of the hydrogen bord N-H; 0. Th,? authors give a sh,~rt desorip-
tion ef pravicus art,`zles on this problem- The a and
variations have compl. et ely differeiit.~--rystal-str,,Acl~l,,iresi~- varia-
Card 1/3 t ions are found w i t in t'~ range of valLInce frvqjen:-.. a an

A
The Orl.gin of Certain Differences in the Raman Spectra 307/2c~-128-1-16/55
of Acetamide and n-Phenylene Diamide in Various Phases
deformat-on frequencies of the 0-11 end C-11- gro-aps and -,v~th-
in the range of deformation frequencies of the
groups
It is possible that there are differences between.the ape-.tra
of the two variations also in this frequency range of the
hydrogen bond. A detailed interpretation, however, is compli--
cated because of the blurred N-H- bands. The influence exer-
by association upon the spectrum is also noticeable in
n-phenyl diamine. A comparison of the intramolecular spectra=
of n-phenyl diamine in both phases indicates that a much larger.
Ilow
namber of lines.is visible in the ary3tal spectrum. The fok
ing results were obtained from a comparison with experim-antal
data. All active frequencies are really visible in the crys"al-
and liquid spectrum. But.the two frequencies 16a and 317 cz `5
which are not contained in the liquid spectrum, are visible
as -weak lines in the crystal spectrum. This may be explained by
the fact that the symmetry of molecules in the n-pheny'. diaml.-ne
crystal is considerably reduced by the effect of intram-olecalar
interaction with a deviation from the symmetry D2h' Yet the
Card '2/3 data available a It present does not zuffice for a complete ex-

N i
RM

(Rman effect)

j,
W(J).Azmf CVWVW~M -Pc -4/1'r-4 -
"',`%AbCtSS1ON NR: AP
3W2670 0020/63/150/005/lOP-2/1025
Raekin 'h
__LIELh. Sh.
Raman light spectra of cortiRin coWowx1s in the adsorption state
n-, "f
.1022olO25
-.',-W OM.- Doklady, 1 ...5' 1963)
Vo so no
TOPIC TAGO roman. spectra. scatonitrile,, acetophenone antimony trichloride
tzibitcmide
an light spectra. of antimony trichloride and tribrcmide.,
-ace tonitin. and acetophe'n bave been studied,,vlth micioporous glass and
allics, ael ~ u7T ads nta,
double monochronator with photoelectric
as;-
jqj9A
registraticn of spectrward a ow-pressureppIral awreury lamp vere used for
a ow
"reeording the spectra. ~ romn spectra of Antimony tricbloride molecules on the
adsorbents were recorded for film layers mi" in thickness frcm Ov 2 monolayere
~'to the.state of capillary condensation* The spectra exhibit a broad band of
60 cm SUP -,1 width in the region of valence oscillations and of 130 cm sup -1
width in the region of deformation osciIlations., Only the capillary-condensation
a 1e e3fttbited linear spectra identical to those obtained from the antimony
-;z-~ Caid'
t VW 1, j 1, P 1'FI Tw . . . . . . .

.6.3
L' 10284
ACCEMN BE: AP3002970
'solid phase.- -Raman:,spectra'of antimony trichloride Molecules on the
glass ardsilick'Sel were practically identical.. Raman
epee ra, of acetonitrile and ac henone exhibited-the valence frequencies
etop-
in -the Enclosures Vas
abovii items I and 2 of It found that these spectra were
identical to.the spectra of adsorbed molecules vhen displacement of valence
-frequ6haies took place in the CK and CO groups, Intimony trichloride also
exhibited.;opectra.which were assumed to be the result of adsorbed molecules, It
was cbser~red that acetonitrile end acetcphenone possess continuous fluorescence
twe w1dch increase in magnitude.toward the blue spectral region. The paper
spec
~.,waa -presented by Academician A. N. Terenin on 14 January 1963- "The authors
_:expresa.to'A. N Terenins on vhose,lnitiative the research vas begun,,their deep
'for his advice,, The'.authors express their sincere thanks to 0, S.
Holchanova for- -the donation of aemples of microporous gWs and to A. ~L Kaganova
.,for, the -ftiation of samples of silica; gel* Orige art. has: 3 figures.'
-6y universitet im. A. A. Zbdanova
IATION: Leningradskiy gosudarstvemW
ningrad State Univers
~7-
63`
SUBMMMU): ~,..,Mec62 DM ~ACQ:r Wul -INCL: 01
CODE: ;00 No F", WV: OW 001
2441
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PME I BOOK EXPLOITATION 80V/4147
SOV/2-9-100
Leningrad. Glaynoya georizichesk"a dbeervatoriya
Issledavanlye ra&atsionnykh protsessoy (Investigation or Radiation Processes).
Leningrad, Gldraiesteoizdat, 196o. 197 p. (Series: Its: Trudy, vyp. 100)
Errata ally inserted. l..000 copies printed.
Additional Sponsoring Agency: USSR. Glaynoye upravleniye gidrometeorologicheskoy
sluzhby.
Ed* (Title page): K.S, Shirrin, Doctor or Physics and Mathematics., and V.L.
Gayevskly, Candidate of Geography; Ed. (Inside book): L.P. Zhdanova; Tech.
Ed.: M.I. Braynina,
PURPOSE: The pub1ication is Intended ror meteorologists and students of hydro-
meteorology at higher technical schools.
COV11RUM: This issue' or the Transactions of the Main Geophysical (Ybservatory iseni
A.I. Voyeykow contains,2T articles on investigations or the radiation processes
Card 116

-Investigation of Radiation Processes SOV/4147
.occurring In the atmosphere and an the active surface. Individual articles on
the following topics am includedt light dispersion in a tva-layered atmosphere,,
capparative analysis of sighting conditions under a cloudy and a cloudless sky,
investigation of long-vave radiation (f the ataospheree1wt=& temperature con-
troller., aircraft instruments for measuring the spectral optical characteristics
of the atmosphere and the under3ying surface, and the dependence of long-Vave

S/10,9/62/000/005/051/093
D228/D307
-AUTHORS: Shilrin, K., S. and R
T
The,theory,of x of sca-tZer4-
atmospheric 4ndica,
2SRlODIC`%L: Re z4 ka no.
fera~ivr4y. --hurnal, Geo.- 5, '962, 28-, ab-
szract 53192 "IV sb Aktinometriya 14 atmosfer-1.
-eoizdat, '~961, 178-!Z05)
G4 dromle
~.-XT: Proceeding Sr o m a 1-1 approximate method of exazIni-r-, the sca-.-
ter-Ing and n o~'~',ight by partic"lea, whose proper,~jes
t too d,' ~'-om those o4' -.he s,Urrounding med. um 'so
are no
particles), the authors ponst-ruct a quantitative theory for the op-
tic-I propert'ies of atmospher4c ha-ze. for=1ala Of -.he
*x is -4.---ro,-~uced -~'or -,he Rokar d-Strbution, and
ind ca tr-, the error,
i
o
-ied by Rokar when deducing his well-known atmospheric il"alca-
+..--'x f or:nu-lc'l, Is rec,4%-.-_*, is de---ived for e zo-i7ais-
ffi c v
persed coer- of sca-~,terin- o-f a-,=osphlel-ic Laze sa=e
distr*but
1 -ion. The optics of atmospheric ha,- e W -'h e Y z -
-b u to i o n is c al cu I a t' e d an apipprox- a,
f
_5 d:-,r:.ved for
Card 112

S/169/62/000/005/051/093
The theory of -Whe D228/D307
scattering indlcatrix in.the case of the Youna distribution, and it
is shown that the formula can be utilized with a precision of 10cia'.
for sca-"I-erin:, an:,'es -rea-e- -,.han 50. A more comp3ex 47 ula, ac-
L - orm
curate ford the.scatterina ano-le 3 = 0, is introduced. A scale is
calculated for the special function, required'in the compu-t.'a'tion
of.the.indicatrix. A formula is.derived-for the coefficient of
f
scattering of atmospheric haze with the Young distribution. Ab-
stracter's,not-e: CO=Dle-41,-e translation.-7
Card 2/2
4W...'ro )i6~

3/169/61/000/011/08/1J65
D228/D304
-3 s,~ Isd
AUTHORS: Shifrin, K.S.,_,an~ F -i-n-V-P.
,ask
TITLE: Atmospheric indicatrix.corresponding to the generali-
~zed Jungedistribution
PERIODICAL: Referativnyy zhurnal, Geofizika, no. 11, 1961p 27,
abstract 11B195 (Tr. 61. Geofiz. observ., no. 109,
1961, 155 - 160)
TEXT: The optical.characteristics (the indicatrix of scattering
and the coefficient of,scattering) of polydispersed aerosol systems
with a Junge type distribution were obtained by theoretical means.'
It is possible to.state on~the grounds of experimental data that
the microstructure in the troposphere's middle and upper layers may
be described by the.formula;
f(a) A/a n a :;iRw a
min
f(a) 0 0 a amin'
This:kind of distribution is termed the generalized Junge distribu-
Card 112

32279
S/169/61/000/011/038/065
Atmospheric indleatrix corresponding ...D228/D304
tion by the authors. Formulas for the indicatrix of scattering and
the coefficient of scattering of polydispersed aerosol 8ySteMS Con-
sisting of particles of the environment ("soft particles") are in-
troduced in the work with n equal to 5 and 6. Indicatrices corres-
ponding to n 5 and n = 6 are.tabulated,on the basis of the der-i-
-lion],
ved.formulas [Abstractor's note: Complete translat
Card 2/2
MRS"""

-VIESWESM

r
~'JACCESSIOWNR: AT4033568 S/2922/63/009/000/0253/0260
AUTHOM Shifrin, Ks So; Rlskin, V. F.
TITLE:~ The theory of the optical method for the investigation of atmospheric
Aerosols
SOURCE: Vsesoyuznoye nauchnoye meteorologicheskoye soveshchaniye. Ist, Leningrad,
1961, Pribory* I metody* nablyudenly (Instruments and methods of observation);
frudy* soveshchaniya, v. 9. Leningrad,.Gidrometeoizdat, 1963, 253-260
TOPICITAGS: meteorology~ aerosol, atmospheric aerosol, meteorological instrument
A4TRACT: At the present time there are no sufficiently complete and reliable data
A
concerning the aerosol component of the atmosphere because most existing Instruments
f)r measurement of aerosol particles have serious shortcomings; instruments based
on the optical method are free of these inadequacies. The optical method makes
it possible to make measurements wi'thout virtually any disturbance of the aerosol
system. The method employs various optical-characteristics: angular ~haracteris-:
ties of the scattered light -- the indices of scattering,.data on spectral trans-
parency of the aerosol volume and polarization characteristics. This article dis-1
i cusses the possiblility of determining microstructure from data on these indices
I oefficlent (spectral transparen erse
en cy). The direct and.inv
theinattering c

ACCESSION Nit: AT4033568
o em n'the theory of scattering-are discussed in detail; certain of these
r bi sA
p
have'been summarized from earlier papers of tle author (Trudy GGO, No. 109, 1961
(two p.pers); Trudy 2-go soveshchaniya p0 akt nometril I atmosfernoy optike,
Gidrometeoizdat, Leningrad, 1960). Particular attention ts given to the possibili-
i ty of using data on spectral transparency for solution of, ihe inverse problem. it
is shown that by having an experimentally determined spectral trans-
parency curve and using formulas cited in this,peper it is possible to obtain a
;,partic)e-size aerosol distribution curve; the very existence of these formulas is
j,evidence of an unambiguous relationship between the microstructure of an aerosol
and spectral transparency. Orig. art. has: 17 formulas and 2 figures.
maya geofizicheskaya observatoriya (Main Geophysical Observ tory)l
ASSOCIATION: Glav4 a
SUBMITTED; 00 DATE ACQ: 16Apr64 ENCL: 00
SUB CODE, EIS NO REF SOV-0 005
OTHER: 000
CWd 2/2
or

AtC NIt, ANG032613
.1 t4)
StrdW, Borin Nikoloyevich; Revva,.I&ftid Dororeyevicb; Raskin, VenismIn
Geselev1c4;,_Epshteyn,, Abram Semenovich
D100 automated higb-power diesel generators (Avtomst1z1rovsnnyye d1sell-generstory
bollsboy moshcbnostl tips D100) Mosew. lzd-vo 09ashloostroyenlyew,, 1966.
259 p. Illus.,, b1blio. 1800 copies printed.
SWIC TAGS: diesel *Wnev swine englneerlng,, generstor,, electric generator,
electric generator unit,, automation, automation oquipment/D100 diesel generator
PURPOSE AND OOVERAGE: This book is Intended for technical and engineering workers
engaged In the plannIng and operation of stationary wid shipboard automated
diesel generators. The book discusses the principles and methods or automating
the control, servicing,, emerpney-varning signalling,, and the protection of Mgt
powered,, type D100 stationary and shipboard diesel generators. Technical charso-
teristIcs, an presented, and domestic systems of automation, remote control,
esergency-varning signalllng,, andL the protection or diesel generators are de-
scribed. ?be pecullwItIes or automation systems, thelt electrical diagrams,,
and the desilp or sepwate slaments or tbo de"ces for monitoring these system
am examlovC Recommendations 'w* given for the InstaUstion,, cbeck-out,, and
operation or automated d1awl gemaratore. 2bere an A vWwasees., aU Saviet,
TANX (W OOKIM (AWIW)
CAM
CMA V11

- . z~ ;,' - - 7 . I j , I
; L ..~ I I ~ . I I V-1 . I , n - I

0 0 0 0 0 0 it 0 0 0 411 0
0 0 f 0 0 0 0 0 0 '0 a Al di Is gs
to a a 1, A is Is W Is Is a
AA. 0f
mhadbom for bm"ed
p
it in
ev a amaw WhImt Ow -td- a little 11,44 *ad
00 an tme Used to bW The AWW in lmndflr ONO.
M. Lew"ttr
zoo
00
00
00
0
0 10
--00
0
ra 0 Aj I a I ~40O
0 On Ow ON to
,a 0 0 0,00 1 it it 0 : a 0 0;0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 41 0:
690"00000*0000000006000,

41 -skii'
.5 1

Sbornik 2, 72 ife-afinz 15

RAM- ff,--M,
coil I ill

Scaled tube 5-:).:; Im-'. on ~L A,-foi~ ItIfIl rxp ('11 ill N
atilt.

b,sS3 .7-- -1 J'" - (1,,, i~' tn:
O-CCAP: C If- I
itccr-arv t -nd
1.4r"7~ f, k,-F,l

Ichloride as Film--Formirg YA-,erials
Perchlcro linyl Resins and Various Copolymers of Viny'
Ref 4,/. During dissolution a q~;xige of ~the f orm of the pcly7neric
macromolecule takes place /'Ref are dibutylphth-_'i a-,a,
tricresylphosphate, , eta. Monomerio plasticizers increase the perme-
ability to moisture in the films fRef 7_7. Stabilizers, like dibutyl-
-tin-dilaurate, are used as light filtsrs for, ultraviolet rays and a-:~-
ceptors for TIM which prevent the det.;omipoaition of "he polymer. Epoxi-
dized oils are as efficient az inetal-organic compounds (Table 11). The
adhesion of the resins to -.he paLited surfa_-e being low, research ' is
going on to use other monomers and grafteed copolymers of vinylorloride
as film-forming materials:. Copolymers of vinyleh-Loride with vinyll:ratyl
ether and methylacrylate with a molecular weight of 30,000 produce coat-
Ings of hij&YI elasticity and adhesion and good atmospheric and water re-
sistance / Ref 18_7. The copolymer of vinylchloride wi-,h vlnylide7ne-
chloride is highly soluble in varnish solvents Z Ref,197. It is
elastic, adhesive and frost-resistant. It protects equipment a&airist
concentrated mineral acids and alkali for 3 5 months Z Ref 20 A
system of primers, intermediate enamels and covering enamels has leen
developed for the protecticn of lower parts of ships against corrosicn..
Z Ref ZTj'. Graffted copolymers formed by the polymerization of a m-ix-
Card 2/ 3 ture of monomers of butylmet-hacrylate and metha,-.r-jlic acid irt a la?,ex

FLYFLINA, A.I.; RASKIN,,j&,L.,- F4WVIT1, Z.A.
Investigation of the processes of photochemical destruction
of nitrocellulose coatings. Report No. 3: Effect of stabi-
lizers on the resistanew of nitrocellulose -in laoquer-paint
coatings to photochemical destruction. lakokrao. mat. i ikh.
prim. no.4:2-5 1610' (MIRA 16:7)
.(Protective,coatings) (Nitrocellulose)

5/06 62/000/022/060/068
B101XB1e6
AUTHORS) s Raskin, Ya. L., Sverdlint Me Set Kronmanj A. G., Yanovskiy,
TITLEs Fain t and varnish. coatings lased on the copolymer obtained
by,the suspension method from vinyl.chloride and 'vinyl acetate
PERIODICAL: Ref erativzVyj zhurnal 0 :Khimiya, no. 22,,1962, 552, abstract
22F464 (Lakrkrasochn. materialy_i.ikh primeneniye, no. 2,
136ZI 10 12)
Data~are given 1cr the composition'and properties of copolymers
(CP), synthetized by the suspension method from Vinyl chloride and vinyl
acetate, and for coatings.made on this basis. In addition, recipes are
given for primers and enamels based on this-CFboth in combination with
other resins (epoxy, modified alk d resin) and without then. Test results
y
prove the high resistance to atmospheric effects, the good physico-
mechanical properties, the resistance to water and light and the good
appearance of,coatings based on CP containing 16 17 Of Vinyl acetate#
[Abstracterfs notes ComplIete-translatione)
Card 1/1

- ~ - - - , i."_-- - 1-1
ftL,- -

SOV/i37
Translation from: Referativnvy zburnal. Metallurgiva, 19;8, Nr 12., p 77 USSR
AUTHOR: Rask;n, Ya. M-
TITLE: The Kinetics and Working Loads of Automat~c Nut-upsetting Marbines
gaykovvsad'
(Kinetika i rabochiye nagruzic j%:+omatw,'
PERIODICAL, Izv. vyssh. uchebn. za,vedewv. Cl-ern. Met~tlltirg-va, 111;8, Nr
pp, 1,03 - 114
ABSTRACT. In an effo -t to di' ovrt h eon re-kdowns of
sc e reas sfor the frequent b
automatic nut -upsetting macl-ones M)w--ich P"event ittainment of
planned output ratesi to determine the working ioads occur?-ing in
upsetting, and to estimate approximate formul~,s for. analysis,a
special investigation of the A412 M was, run Examination is made
of the kinematics of the M, of the planned cyclic programming
~gram") of the various operating mechanisms and of fl-e dctual cvclo-
gram recorded on an oscillograph by means of rheorhord elements.
It. is established that The Iransporter-mechan,syn c,mi sh-,pes reqwre
corrections and that the size of fl-e clearances-in mesl-.-ng.)!nks of the
plunger and transporter mec)-antsms require reducl-,on to an absolute
Card 1/2 minimum. Experimental determinat;on s made of tle for c ere quired

SOV/13
The Kinetics and Working Loads of Automatic Nut-upself-rig Machinvs (cont
for upsetting, for,punching holes, and fo rejection.. This is done by dynamomete,r.
and round wire strain-gage elements. An evaluation is Made of stresses calculated
by Gubkin ' s formula, the values of the coeffic)ents emploved being those of
Nistratov, Navrotskiy, Misozhnikov and Grinberg, -and the results are compared
with experimental data. It is noted that Nistratov's values for the Z and nfactors
and the formula for al due to Navrotskiy are in best agreement vvith the experi-
S
mental results. It is desirable to introduce a thermal coefficient in deterlnining
the force required to upset a hex nut.- ,Reliable est-.mates of Z, it, and a
determination of.the ultimate stres.ses of deformation under laboratory or shop
conditions during manufacture of nuts of all shapes and sizes.
M. Ts
Card 2/2

ON Nk; ~&P4047433.,
rkil6rin-rbece'Alistribution.
p4ttern in.1 !p span ptecies of aU fdur columns.' The
uthors warn against pre 41hi -. with'& cold: dki.
:
-, Th6j-recommendthe~useofa-
I-
-.
~..:: -,
- if.
2PI76--BK.. nu)tor havin _2xl320 kw-capacit
I
,
94
.
U
y; furthermore co pling and fly-
-
1,
~
ih :,
e1 are to: bot removed from. the drive (see Is) Orig. art. bas: 7 figures
"
rid. L~:table:.

3SOMATOKi- None
It= ~'ENCL: 01 SUB CODE: IM
U13 ED: 00.

rEt REP SW-.,,'003
_COMA* 040

W"- 2/3-,

O

7-4CCRit-AM5017937 Monograph
Nozhevnikov. Ser Nikolayevich (Corresponding Member,, Academy of Sciences of the
R eY
-) ; TES i
Ukrainian S.S. penko,, YAkav Ivanovich; RazkiajAkwt-,Atkh#jjWc4
Mechanisms (Mekhanizmy) 3d ed., rev. and enl. MoscoVo Izd-vo "Mashinostroyeniye" 65.
1058 p. i1lus., biblio. Errata slip inserted. 16.,000 copies printed.
TOPICTAGS: mechanical engineering,, automatic machine, automatic control, durability
PURPOSE AND COVERAGE: This book contains descriptions of 2,030 mechaniBms and their
elements,applied to present machines of different branches of industry. It also de-
scribes elements and apparatus of automatic devices. For most of the material the
~classification of mechanisms is principally functional. For many mechanisms the de-
4ign formulas- are given in finished form to facilitate plaming. This book Is useful
as a annual for technical engineers in factories,, technological and planning insti-
as well as for students in design of mechanibms and machines.
Cr, CONTDTS (abridged):
~Preface to third edition-6~
Introduction-7
Ch, L Survey of kinematics and OjEafflgee of nechanisuw-9
Ch. J1. " Lir" kinematic pairs wid bar mecJsanibms-73.
Ch. III. Gears -17A,
WCs621*01
CWd 1

TABSUT, V.V.; KOYMAN, G.F.; VOZNENKO~ G.V. ; GORDONOVA, S.M.;KUGUSU*V,

(Hul-I (Naval architecture))
(Ships--Cold weather operation)

~_ACC NR_'AR6035-.84 SOURCE_CODZ% UR/0398/66/000/009/4022/1,022
AVAMOR: Raskin, Yu, X.
TITLE: Experimental determinationof the external forces acting on the hydrofoils of
the motorship "Meteor".
SOURCEs Refs zbo Vodnyy transport, Abs# 9A137
REF. SOURCE; Tr. Leningr. in-ta, vo'dne tra'nsp*, vyp. 81, 1965. 06-93
TOPIC TAGS:. ship, hydrofoil, stress analysis, stress distribution
'ABSTRACT: in October and November 1963, running tests were made In the Finnish Bay-,
of the strength of the hydrofoils of the motorship "Meteor" under rough sea conditioass
The ship was equipped with apparatus.for the measurement of overloads and stresser. in
,the ship's hull, and,also with awave measuring device. Accelerometers were mounted
in three sections along the ship,, to det ermine the wave and shock components of the
accelerations. The stresses, due to the overall bending were measured in five poin.8
Condit,ona~
of the midsection. 'Abe teats of the "Meteor" were zaade under six rough-sev.
at wave altitudes 0.5 1.6 m.. It is Concluded that the recommended rated load for
,the hydrofoil is a static load equal todouble the load acting on the hydrofoil when
the ship travels iu still water. , Attention is called to the long-term fatigue
strength of the hydrofoils, which'can deteL mine their strength when materials with in-1
Card
UDC: 629 620.~

ACC INR, tv%0" .657 SOURCE CoDZ: Lii/01 911671060100-1.,
AMMR: Koraleva, T. V. Krasovskaya, T. A.; Sobolevskiy, X. V.; Gor---cL~,, L.
Raskini Yu. Ye.
ORG: none
TITLE: Lu,3ricating properties.of polymethyl(chlorophenyl)siloxaries
SOURCE: Plasticheskiye massy,~~no. 1, 1967, 22-25~
TOPIC TAGS: lubricant, silicone lubricant, polymethylchlorophenylsiloxane
ABSTRACT: --!-h 0e _e content in t h e p1h, L
_ffect has been studied ofthe chlorin -nyl
~radi lymethyl(ch'
caj. and of the chlorophenyl group content of po L Oro-
?henyl)siloxanes on their lubricating properties. Polymers 1. a, or M.:
prepared by hydrolytic condensation and subsequent rearrangemen: in the!
oi sulfuric acid were used:
presence
~CH,
4. (CHS)J$iO- _~1_0_1 _1-0_S1iCH,).; rAe"n-0-~:4
4
UDC: 678.84.06:621.892.28
Cafd 1/3

ACC NR: A?7002657
d-
[I. (CH~Ao_ I_O_'__ i _541N#
f
C4H
~H& "H
X4
C
0
9CHA.
III* g(CHJjS1O--:- _S
61- -in L 41,3ax~
whenm-0-4.
'rhe lubricating properties were determined.on a four-ball apparatus
, 11, the
nder nitrogen from the diameter of the wear pit on the lower ba
u
e character and magnitude
r ction coefficient at various loads~, and th
of the friction force. The test temperature was 200C (at this tempera-
ture the viscosity of 1, 11, and III was virtuallythe same). it was
ZOUL-Ad that for all three polymers, optimum lubricating properties are
prod n oductF*7.
uced by the i tr - -of four chlorine atoms per polymer mole-
1-cule, I.e., at a 16-17- '-:orine content. At this chlorine content,
aineck when all four Cl ato=s
the poorest lubricatinz.propertie -s are obt
phenyl -grou - s
areconcentrated in single p; uch a concentration also con-
siderably .impairs thermal-oxidative stability. Polymers cohtalning I or!
"have virtuallythe same lubricatn"
2 Cl atoms per phenyl group g prop-
are g3
arties. Properties, test conditions, and test result or 1,

L'1154946, EWT
~d)/&IT~m~/EWP(w)/ (c)/EWA(d)/EWP(V)/T/-W(t)/fWP(k)/fWP(h)/D(P(z)/.
d1BW JD1DJ10S
ACGESSION-'NR:
4T5020436 UR/OM/65/000/000/010?/OW
i-AUTHORS t. Raskin, Yu. Yeej- Gornets, L. V. I- Mosov, Yu. A,
TITLP. Evaluation of lubricating propertisAof working fluids for aircraft
hydraulic systems
AN: SSSR. NauchW sovet po treniyu i smaskam. To
SOURGEs criya smasochnogo
i novyye materialy.0hoory of lubricating action and now materials)*
~Moficow' I24-vo Naukas 19659 107-113
TOPIC.:, TACIS ilubricants lubricant'propertyp hydraulic fluid,
ABSMCT.,t The lubricating properties of Al hydraulic fl&Ld (No@ 7; 7-30s;
7-4os-;-3j:DS-l8-lj AMO-10, -1OITj AMD-10AITj AV OSVI ARG-10S-2. and No, 2)
AMG
-A were investigated on a four-ball friction machineft(( 9 mm steel ballss HHG-60-629
1500 rpm of top ball) and on twoiiial-piston hydraulic pumps (at 210-220 kg/cm2
and 2900,4000 rpm),s The results are shown in Fig. 1 on the Enclosure. It was
found.that lubricantswhicli have the same or better properties at 3,50C in the
friction machine than AMO-10 at 10OG worked,wen in the pumpop xhile the others
were unsatisractory. To determine the effects of loads sliding speed, materials
of the friction junction# and gas used above the huide in the accumilator,
CC 1
A

L--1~49-66
40CESSION NR: 02
H5 0436
it AMO-10
additional experiments were performed wit and 7-~5'03-3. At a constant
sliding speed of 23 emlsec (AMD-10 at I 17-50S-3 W 1750 Ad loads of 10 20
30~and h0 kgs for steel on steel (ShKh-9 teel balls1J
560-62 OC) and steel con
br, f s -1b
onze riction junction (ShKh-w9'stee 6 YBRAM-9/4 -ronzJq it was found that
ij-after 30.ninutes Lhe beat performance was with steel on steel and MIG-10 lubricantl
in air (d iameter or wear spot 0 mm at 10 kgs 006 mm at 40 k t 100C). In an
g$
N2 atmosphere the wear was maximum with 7-50S-3 lubricant at 17 (1.28 mm at 40 kg
as compared with 0,84 mm in air)p For steel on bronze the weaXereased smoothly
with load for both lubricants with maximum wear for 7-50S-3 lubricant in H2 (3,2
at
hO kg). Wear as a function of speed (ANG-10 at 100C, 7-50S-3 at 1M") was
investigated at a constant load of 10 kg (time of experiment was adjusted to give
L total number of ball revolutions)* It was found that for AMO-10(steel on
isteel). in air the wear remained, almost constant with speed (7:0-,5 mm for 23-92
ed
for AMG-10 and 7-50S-3.(steel on steel) in N the vear increas
with speed (from 0o35 and 0#48 mm at 23 cm to o.56 and 0 at 92 cmloeo
bronze wear remained almost cons ant for AMO-10
respectiv-31y), For steel on
(in airi -om 2eO
(in air and.N~) and 7-50S-1 and decreased for 7-509-3 in U2 (fr
an at 23 cm/sec), Origs art, host '5 figures and 5 tabless
card 9/4.

L
AT5=436
'ACCESSION NRa
"AS SOO IATIO No AID no ;,!q,

SUMUTIDs 22Nmy% BUD ccoze rp,

-OOD
NO Asr:9*6
i,." -io
0~

Card

.1549

=JM10N, NRS AT5020436
RIC 1 01
LWIWSU

- - ------------ 7

-77-

$4

A
-H i

Af 410
,
i;D~ ka

v9
Fig.,l. 'Wear spot diameter axial. loadi
-
-1 fluid 7 at 20G; 2- at 20OG;
3- 7-303 at 150ci 4- organic.ester at 150 5- 7-4os-3 at 15o1 6- 7-50S-,3 at
:7- 503-3 at 1750 j , 8- DS-18-1 at 200j
150 9- A140-10 at 1001 10- general curve

MIG-10S-21 AMG-103-3.,
or fluids AM-10SV
~ OC, 11-
At-SU-10AIT and ANG-10IT at 15
flui. abJ2 j A- zone of saMs.f dotor.-y pump -operabiaht B- untntisractory pppration -

I 04Y/0043--i
ACC HR, AP7ooW9 0
AUTHOR: Koroleva, T,V.; Raskin Yu.Ye.; Krasovskaya, T.A.;
olivskiy, M.V.; Gornet a
Sob
ORG: none
"AI.ITLE: :Lubricating properties of polymethyl (chlorophenyl) siloxanis
AOURCE: Plasticheskiye massy, no. 2, 1967, 41-43
.ITOPIC TAGS: lubricant, silicone lubricant, lubricity
ABSTRACT:
'A study was made.of the effect on the lubricity of polymethyl(chlorophe~jl)-
siloxanes of 1) the-methyl/phenyl group ratio in the*middle and at the
of the backbone,-and 2) the chlorophenyl group distribution along
'the backbone, The
lubricity was tested in a four-ball apparatus; the
'criteria used were the diameter of the wear spot on the lower be-Us, the
fricti6n.coefficient at various loads, andthe character and magnitude of
the friction force * The effect of the methyl/phenyl group ratio was
studied for the'following polydisperse mixtures:
-2
Card 1/4 UDC., 678.84.ol:621.89i.2

ACC NRs APT006909
Polysiloxanes I
(CH3)3S4OSiai3C5H1hOSi(CH,),,
(2)
(CHJj$i(OSICHAII,14OSiCHCH,,CIIOSI(CH2)g (3)
(CHs),SIIOSJ(Wj)a)AosiW,,q",CljoSI(CHj), (4)
(CHs)sSilOSiCHAHh(bSiCH.C.H.C-l.]OSi(CHb (5)
(CH&ivsi[OSi(CH3),I,IOSiCHAHXI,'IOSI(CH,)3
(6)
Polysiloxanes II

3)3S'IOS'(CH3)2140SICHC
(CH HC1j30Sj(CH,1)2
(CHS~C4"#S'IOSI(Cf4)1111[OS'CHSqHCll%OSiqH,,(CH3),-~ (2)';
1~ CHg(QHJlSilOSi(CH,~lIOSiCff.C.14.CII.OSIiC.H," (3)
It Wai found for polysiloxanes 1, that at a constant number of trimethyl-
siloxane end groups per molecule, an increase in the methyl/phenyl ratio
'im-proves lubricity. .'For polysiloxanes II, it was found that the replace-
-ment of melqql end gra~u Aadvorae effect on
y! ~y.phenylend.groupa has

Cc 2/1&
rd

ACC_14Ri___AF7O06909-'_-----
lubricity. It was' concluded that'an incre6e ln*ihe of p'njr-nyl
groups in the'middle and at the end of the chain has an adverse effect on
-the lubricity of polymethyl(chlorophenyl)siloxanei3. Therefore, a determina-
tlon of the effect of the distribution of eblorophenyl radicals along the
backbone on lubricity required a comparison of oligomers having not only
-the same chlorine content but also the same.numbevf of methyl and phenyl
radicals. The effect of the chlorophenyl,radical distribution on lubricity
was studied!-,~or.polysiloxanes III-
(CHJ,,rH,CISIO-l ~.1-0_ -Sr_,HC1(CHj4 (1)
W: CH CHI
(ayAlikslo- 1-0-- _S1_0_ _S1qH,(CHj, (2),
2. 16302 1
c: CHI CHI'
-$1-0_~ e_sf_o IC1~1"C14CH4, ;j3Y
141 (WIS
-7
C

'000 1o "1
1019
W 111 :0
04 m0f)IJ2 Bigh Al p aA R it vv to la V it 1. a81 46 4;ais0
04
A a. &-I aS 1, 11,11OP-1 1_1 AA 0 4A UP U 16 s 6d
00 06
.00
0o
W 00
0O.A r,. -00
Atemy"
M. lot 7WO d-ionot I'ar
00 f~ qhw% VA.t lmpt.,Vr the #IIMIIIV 1-1 bor.11wrl pffl. 1""
go 11"ar vqlvps~ lJou'rIrl. 141.4.11. Is-".I -00
00 0 Ifie trafil OWN III VIVIV ortimms rtjkm'~ 1,84 1.1~ It.411 .00
a be Cairo.. 31,
00
.00
04
00 .00
09
so 400
zoo
40
00
got ;Go
I.J
40146~ 9 , . ~' . . I II II .~ 1. 1 11 11 1 1 1 1 1.I
00
0 tv 1A am md a a 1 0 1
_70i 0 0 #10 0 0 0 0000000 fee 0 Wo 0 0 0 0 0 0 0 0 0 0 0

2q362
4-3 0 //143) //5-0)
0 L, S10201611136100 /024/032,
ILI 1100 LI -5', 5
~210i/3206
Voytenko, R.~M and Raskinag'
AUTRORSi
TITLEs Some propertiea of polymIer semiconductors
PERIODICALs Doklady,Akademli.nauk SSSRI v- 136, no..5, 1961,1137-1136
TEXTs The eleatrical.'eonduotivity of pol7mer semiconductors obtained
lately on the basis of polyaorylomitrile and polyvin lchloride is an ex-
ponential function of temperaturetf."-- exp(-dE/2RT) M. For these ,
materials# the actJvation energ7d E varies between 1-7 and 0*18 ev, accord
Ing -to the treatme-t of the initial polymer (.Refs. 1,2). IfG- - enu
(n - concentration,~of carriers; u -. carrier mobility)is assumed, as is
customary, the temperature dependence of electrical conductivity can be
explAined either a) by, exponential Increase of the number of carriers
(when using the bona mod4.1,QE is the width of the forbidden barid)t or
b) b;T exponential increase of the carrier mobilityi uf%_dexp(-AE/RT)& An
answer to this problem can be given by studying the temperature dependence
of, t:he differential thermo-emf. If conductivity increases owing to in-
crea-sing carrier concentration, this must be accompanied by a decrease of
Card 1/4

20362
B/02 61/1 6/005
3 /024/0N
Some properties of polymer semiconductors B101YB206
the thermo-emf'. In this case# the following is valid according to the
band theorys (k/e) (A,- OE/Nff) (2), A being almost independent of
tempitraturs, If, however, the carrier concentration does not depend on
temperature, the thermo-omf in bound to increase logarithmically with
temperature (Ref- 3)- ;Fig. I shows theconductivity of polyacrylonitrile~
specImens as a function of temperature; Fig. 2 shows the thermo-emf of
the eame specimens as a function of temperature, and also the temperature
dependence of the thermo-eaf calculated from Eq. (2) for & E - 0.18 (dash)
and4, E 0-51 (dot-dash). For specimens 3P4,5, the integral thermo-omf
was determined as a flanction of the temperature gradient by charging a
capacitor. Fig. 2 shows the differential thermo-emf obtained by dif-
ferentlating the experimental function. As shown in the figures, the
thermo-omf depends only slightly or not at all on temperature. It can be
concluded therefrom that in the materials studied# the temperature depend-
ence of conductivity is mainly caused by an exponential increase of the
carrier mobility with temperature. [Abstracter's notes This is a full
translation of the originafj. There are 2 figures and 3 Soviet-bloc
references
Card 2/4

2o362
32
5102016111361005102410
''S e~properties of polymer semiconductors BiOl/B2o6
0m
ASSOCIATION: Institut neftekhimicheskogo sinteza Akademii nauk SS$R
(Institute of Petrochemical Synthesisp Academy of Sciences
USSR)
PRESENTEDs September 12t 1960v by V. A-. Xargin# Academician
SUBMITTED: August 4,.ig6o
to Fig. 1. a)- specimen no.
6E 0.18 ev; specimen nos 2 t
6E 0.26 ev;'G specimen no- 3
AE - 0-32 ev; I specimen no.
AE - 0,39 ev; Z specimen no- 59
AE 0 0-51 ev.
of
00f
Card 3/4

4 fi~ 203i2
5/020/61/136/005/024/032
Soe ropertieB of
m polymer Bemiconductore B1,011B206

Le nd to Fig. 2.
go a) specimen

I
p
'
i

T

"
Card-A/4
.
,

SOV/79-25-9-12/76
Nazarov I. N.,Proslakovi No Sol Raskin&, E. Mop
Mikheyeva, N. No, Stoyarova, L. *G-.
synthetic Anti-spasmolilic Subs-taAcas.-Synthesis of I-Phenyl-
1-cyclobexyl-3-(20,51-dimethyl piparidy,1-11)-propanol-1
ZhurAal obahchey khimilt 1959P Vol 29f Nr 99 pp 2861-2864
(USSR)
2,5-dimethyl-4-piperidone (II) (Refs 1, 2) obtained from am-
monia and propenyl-isopropenyl ketone (I) according to I. No
Nazarovp was made use of for the synthesia of compounds struc-
turally related to the efficient anti-,Spasmolitic Axthan.
(I) is an intermediate in the synthesis of ahesthetics Promedc'
Isopromedol and a-Promedol (Ref 3). Compound (II) was trans-
formed to (VII) according to Kizhner by reducing hydrazone
(III) of piperidone (11) as well as by,cleaving the piperidine
compound VI) with water; the latter compound is formed by
compound M and lithium. Chloroderivative (V) was obtained
from the reaction of piperidolj~IV) with Ahionyl chloride..
Condensation of piperidine (VI with acetophenone and form-
aldeh de accordina to Mannich caused the separation of ketone
(viii~ which was,further transformed into compound (IX) by

SOV179-23-9-12176
Synthetic Anti-spasmolitic Substances. Synthesis of 1-Phenyl-l-cyclohexyl-
3_(2',P5'-4im*thYl piperidyl-li)-propanol-I
the reaction with magnesium chloro cyclohexylo According to
preliminary jpharmacological data by W. D. Mashkovskiy (VNIKhFI),the
chlorohydrate of this tertiary amino alcohol exhibits a
marked anti-spasmolitio activity and is but little inferior
to Arthan (Reaction Scheme). To investigate the structure do-
pendence of this activity of tertiary amino alcohols con-
tainina the 295-dimethyl-l-piperidyl group as amino radicalt
the authors synthesized propanola (X)q (XI), (XII), (XIII).
The synthesis of these amino alcohols was made with the al-
ready earlier described ethyl enters (Rof 4) of 0-(2,5-dimethyl
piperidyl-l)-propionic and a-(2,5-dimethyl piperidyl-l)-pro-
pionic acid as well as with I-acetonYl-2,5-dimethyl piporidine
and the corresponding organomagnesium compounds. There are
4 Soviet references.
~ASSOCIATION: Moskovskiy institut tonkoy khimichookoy,takhnologii
(Moscow Institute of Fine Chemical Technology).
SUBMITTED: July 10t 1358
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