SCIENTIFIC ABSTRACT RABOTNOVA, I. - RABOVSKIY, G. V.

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SCIENTIFIC ABSTRACT
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~j,~ ." .,, C,,, r ~ T . I . . ~ I - . 1 1. 1 - RAEUITCAIAI I. L. a rA 5T-2 PA 23T72 1. L. RA6,JTNOVA, i.., IONDRYATIEVA, E., NErTE, I.J. and OONES, S. Depart~-i6fit (Jacrobiology, Moscow State University, "Fixation of the Air Nitrogen by the Azobacter Under Differenct Conditions of Aeration, !'itkrob f2~~ Vol. 18, Ito. 6, 11av/Dec 1119. ML It 13 1. x k ft x A. .0 .1 4.t I 00 90 so--. so 00 go -00 00-1 -00 -00 00 0 4 zoo so -1 Use of -A 900 go-, age T MJ Zoo goo so* use .qF rise "'s floe still ad a.. als on a I w at 9 a a 3 9 a rg it 11010 is a .1 o 0 0 0 0 0 4w 0 0 0 00 0 0 00 -ww C-14 I- Infivemice-d awaims imommity so gad bow m - dam - . 1. L. Rabatupwa and 1. V. Kurjova (ftople*s Univ., MoKim). '3fikr0bif,,- for~vn 19. 24~31(19&9.-Culturr% of ChAorwU4 walicaris (1) xTmv Far better on mash than ort ptvpd. sugar mediums. rlir optivinum coocn. k 1-2' Killing. Under anavrt"- vornfitims at 111 13-1-4 1 li~ bint tf~ riot proliferate; wbcn acrAted to ru 11) -LM, it proliferatr%. In nistfit ioll I V&mes front hetertrophLian at low I" through a hetefutro- phic-autotrot)hic stage at medium rn it) a chiefly PrOu- !rophic (photasynthe,61 Inge at high ru. J. F. S. Ov"itsts"t6a on astowl G"4 atbothidtocallbom bda". HI-Rawmalk. I#.- 1111 VIV1~61VA.Wilt . V. AtAgnilAnya I . I .4 Aletiltrifi"s inwh all A(r.". ~1. aftle, 411,11 . -,f krr,-,,e. alk'alisn"t its, *lvfIrlAfrlI IIIV MMIS lion. drRil't.he'lors can utilis, Ctnj~ Aildtilill,4 Ntlith i.; RABOTNOVA, I. L.; YAFJIOLA., G. A. and KIPMTSOVA, V. M. .9 - RABOTNOVA, I. L. USSR/Biology Microbiology, Rubber Mar/Apr 52 "Growth of Bacteria on Natural Rubber," V.' N. Shapoohnikov, 1. L.,.Rabotnova, G. A. Yarmola, V. M. Kuznetsova, N. N. Mozokhina-Porshwjakova, Biol Soil Sci Res Inst, Moscow State U imeni M. V. Losonosov "Mikrobiol" Vol XXI, No 2, pp 146-154 Found that rubber hydrocarbon may be conail-d by the following microorganisms: Bac. subtilis, Achr. agile, My cococcus ruber., Wcobact. globi- fozve, Mycobact, lacticolal, Act. albus, and the yeast Torula rose&. SHAPOSHNIKOV, V.V.~ A~noNoll-,i, Ynsmu, O.A, xt;zlZrl"i-lsovA~ V.I. t" ---- - --ff RABOTNOVA. 1.L. ID JC2 T USSR/Biology Card 1/1 Author Rabotnova, I. L. Title Data on the history of technological microbiology in the USSR. Micro- biology in the alcohol industry Periodical, Mikrobiologiya, 23, 349-36o, may/jun 1954 Abstract This article is a historical review of the role of microbiology in the development of the alcohol industry in the USSR. Emphasis is laid on Russian, and especially Soviet, "firsts." The names of investigators, the locations of many of their laboratories, and brief sum ries of their work are given. There is an extensive bibliography containing 75 Soviet en- tries. Institution Moscow State University imeni Lomonosov; Biologico-Soil Scientific Research Institute Submitted April 19, 1953 t 1 6) CJ ients ainatrago acTe -i 'condIdohn of medfunis. Ittaboin Ot'': J., Toropova. id. M. Yu' . Rabaxv~i (jr~ ~!~~,"E ILE tate Unir.." Mc*ciyw),;* Mikrobiolop -52"1(1955) -The' 24, putrefactive anairobes- and t pueifims,can devoop,in br6th exposed to'atr II'the tube Is ~.io , fineclt" c~cm. deep and the medhim is thickened with 0.2%, i agar. ..The taltial rff of -40-22'drops.to 1-2, ind In the stage" -~Atl _..of rapid4krease (first few hys.)prolifer2tion stbpsbut the' . `7 cells grow larlicr.-vWnly la length.-- -If M, is held to 6-or, proliferAtim does not be -stige stop. glri itain after, the fimt .1palle 66wifit thit Wesi are ablijitt artae&bes; Proliferaii '-., ~ '. :.. 1. 1. P t; tiort ~ not'inhibited bY7xuch iWindicators; as,neudal red,--*,,. V 'I Celt. P'henhsdmntne,~ Indigo di- or titrasulfollate,'Or. lmeth)le, t ene blue. (titrations -with ~-NPAO# or akarbic o5 plleiludng powei Is Aot Broiled t6 thq metilum, but 11 alsol, -exerjed flit living Mls.' Spores can krow at M 20.3,but latiod of'- are. ~fthl ited at rH'21.8; 1vith C. ip~iojexe.'f forn gipnk ecjl~ i=tui at M jultap F. Smith o. ? on Name i RADOTNOVAj IrIna Lemnidovna Dissertation: Siguiricanee 6f I A and nxiditation-reduction oonditions for the development and metabolism of miero-organisms Degree s Doe Biol Sci Affiliation; Znot indicated-7 Defense Date, Places 14 May 56, Council of Ybscow Order of Lenin and Order of Labor Red Banner State U imeni Lomonosov Certification Date: 18 May 57 Sources BWO 15/57 RABOTNOVA. I.L. iAB5. Jurt-R. FqA3. A B 3 Tj Pi, b. C, T USSR kln-3 1959, Mn- 10040 Rabotnovti, 1. L. ITistttUtc--Dt-.Ati::ti5-a-r6logy of -Lhe Academy of Sciences ME Active Cbange of the Conditic-as of the Medium by Microorganisms in Acco-cdance with Their Requirements Tr. 1-a-ta rn1kroMnI. ANSSF; "t 7 1t)58, No 5, 80-95 A review constructed an the bp-,;;:; of ztii aiialysis of the daLi. in the literature ;4nd -the experimental materialof C a the atltlioi.. Active hange of Ve surrounding medium by rnic-ruarganisms t.5 regarded through the example of a change In t1he d Eh of the medium by them. PH an L 36427-66 EWT(1)/EWT(m)/T - DJIWEIJK ACC NRi AP6015207 (RI SOURCE CODE: UR/Ohll/65/001/002/0167/0174 AUTHORS: Nette, 1. T.; Grechushkina, N. N.; Rabotnoval 1. L. ORG: Biolora*cal Soil Science Faculty, oscow State University, (Biologo-pochvonnyy stvenno fakul s 0 3 0 0 g go umrver TITLE: The growth of certain, obacteria6in petroleum and petroleum products SOURCE: Prikladnaya biokhimiya i mikrobiologiya, v. 1, no. 2. 19659 167-174 TOPIC TAGS: microbiologyp petroleum residue, fuel microorganism ABSTRACT: Research into the nature of culture of microorganisms actively using petroleum products was initiated because agrilland lubricantst/can acquire desirable new properties due to the action of these microorganisms* Soils from petroliferous areas of the Ukraine and the Tatar and Moscow areas, vaseline and spindle oils, MC-20 and fir-16 p oils were used for isolating the microorganisms. A liquid medium of the following composition was used (%): NHhNO 3 __ 0.1; KH PO -- 0 02; MgSQ4 -1 0-01; NaGl -- 0.01. Tap water pH after sterilizatiodwas 7,2L!~-,, and" oils introchced into the raedium made up 2%. Isolation was performed under varying conditions of aeration--stationary and oscillating at 30C,, and growth time was reduced from 7-14, days to 4-7 days under the more aerated conditions. The tabulated results show th 76 pure cultures actively utilizing hydrocarbons were isolateds the majority of them Card 1.12 UDG: 6l3m663+576,852.2 L 36427-66 ACC NRs AP6015207 mycobacteria with the dominant strains being close to Ytycobacterium muco3um and 114ycobacterium lacticolum. Cultures were grown in about 5 ml of the following medium t tM1,N03 -- 0-11; I'19SOh -7 0-06; K[f2PO4 -- o.o6,, Nailpoh -- 0-14; tap water PH -- 7.2--7.31 with I the addition of 1-2 drops of s terile, hydrocarbon mixture at 28--30C for 7-10 days. Results show that the cultures most active in the use of petroleum and petroleum products were M. MLICOSUMP H. lacticolumj and 3 strains of bacteria which grow well in all mixtures except in heavy# nonparaffin naphthene petroleum. Results of growing microorganisms in individual hydrocarbons show that all cultures used basically only paraffin. Mycobacteria were Imost active in utilizing individual hydrocarbons and hydrocarbon mixturess with N. mucosum and M.-lacticolum being most active,~particularly in the use of gases* The majority of strains grew in C 1-C4-1 C6-ClO-, C12 and C16 alkiness phenol., xylene, and toluyl, but Inot in cyclohexaneo naphthalene, a-methy1naphthaIene,, and benzol. Sthylene and isooctane were used only by certain strains. Many-strains of H. lacticolum growing in individual hydrocarbons and gases form red and orange pigments,, indicating the possibility of the accumulation of carotinoids in hydrocarbons. The authors thank A. I. Bessmertavy for supplying oils and fuels,, and they also thank microbiology students K. A. Nikitina-and S. X, Shust Sor participating in obtaining the culturese Orig. art--.---T~3 4 tables* SUB CODE 1 .219 06 SUBM DATAt 30ftv"/ ORIG REFs 005/ MR RJWI OU Ccwd 212,UL L 27402-66 EWT (I )/T A ACC NN AP6017700 SOURCE CODE: UR/0220/65/034/002/0200/0203 Nikitina.. K; A Rabotrwva, I* Le' AUTHORt Grechushkina. No N ORG: Biology-Soil Faculty, Moscow" State Universita~ :S]~e Me ie ~:-L"sov (Biologo. /3 pochvennyy fakulltot Moskovskogo gosudarstvennogo universiteta) -the decrease. TIME: Factors under3,Ting of the redox potential in cultures of sporoge. orobic bacteria nous a SOURCE: -AN SSSR. Kikrobiologiya, v. 34, no.,.2, 1965, 200-203 TOPIC TAGS: bacteria, bacteriology, plant metabollsm A T; Inex rimentsonthe!~ ~turi or Bacillui nes'intericue' U C'' b, at' ~STRAC PO revi ~Bad. caroun, and Dac. simple-x# it was established that the decreae in the rH2 e !of the medium during culturJ4 was aasooi&t,14 with an increase in the conient ofT .reducing substances for*med*by'the' bacteria, However, aeration of,the cultures ~also had an effects the rH2 decreased to a greater extent during culturing in* itest tubes than during cultivation in flasks. The effect of aeration could be aeon most clearly in connection with the culturing of Bac. Mesentericus on a ~dulcito medium, i.e., under conditions in which reducing substances are not iformed. The rN2 was lower when Bao. "sentericus was MdtUred in teettubess because the aeration win less effecti va. Flor bacteria or the gvoup inveatigatedpi. aeration probably had a greater effect an the the fozuatlon of substancesk.' Drip art* has: 4 figm-eso SUB comi o6. SUBM DATM. 30ifiw64 REFt 004 CaM UDCs V6;85lj1Aq8 _j -.0; i-min 'ACC NR:AP6033912 SOURCE-coDrs: UR/0220/66/035/005/0805/0811 AUTHOR: Avalcyan, Z. A.; Rabotnova,__j,!_, 'ORG: Soil Biology Department, Moscow State University im. 14. V.- !Lomonosov (Biologo-pochvennyy falculltet M6skovskogo gosudarstvennogo :universiteta) Determining concentrations of copper toxic for microorganisms TITL. ISOURCE: Milcrobiologiya, v'. 35, no. 5, 1966, 805-811, TOPIC TAGS: toxicity, bactericide, copper compound, Zz=nk*M* pAfg ABSTMGTI. This study concerned determination of the Concentration of copper to various nutrient media, and of the concentra- tion required to kill r, utitis. It van found that In nu- trient media (1, 11, V, VI) with mannitol, sucrose, and glycerol at pN 6oO-7*0. copper in precipitated an a salt and cannot be detected In the solution, However, In the mesa media arps 500..-Coppor-to ptalsent In solution* -.7 CWd 1/2 BARKOY, Y.Ye.; BYKMVSKIY, T&.L.-, GRZHIBOVSKIY, Y.T.; FAVLYCM, L.Ye.; SOKCLOV, T.B.; SOLOVITS-7, P.M.; IMSONSElY, ZmaGORODSKIT. 1.S., red.; SATALITEV, V.I.. red.; BORTMOT, N.I.. takhn.red. (Savety rules in the construction and use of coramication structures and equipment] Pravila tokhniki bezopasnosti pri ekeplustatsil I stroital'stve sooruxhanii i ustroistv evipst. Noskya, Goo.energe izd-vo, 1959. 103 p. (HIM 13:4) 1. Ru sis (1923- U.S.S.R.,) Kinisterstvo stroitellstva elektro- stant:ly. Takhnicheskoye upravlaniye. 2. Takhupravloniye Nk- nisterstva alektrostantaly (Nos) (for Bericov). 3. Tassonza" nouchno-issledovatellakly institut energetiki (TNI13) (for Dykhovskly, Pavlychav, Sokolov). 4. Gosudaretyannyv,trant po organizatall I ratsio- nalizateli elaktroptantely (CIRGMS) (for Grzhibovskiy)..5. Leningrad- skoye rayonnoys.upravleniye energokhozyaystva (Lenenergo) (for Rabot- nova). 6. Mookovskoys rayonnoye upravlenlys energokhosysYstva,(for Solov'yev. Khersonskly). (Blectric ongineering--Safet7 measures) (First aid in illness and injury) RABOTIMA, T.N., lrand.tekhn.nauk; KOIUNCHUK, L.V., inzh. Data on parameterR and technical charactAristics ofpboto- tuban with multislot cathodes. SvetotelchnIka, 5 no.9:1-7 s '59. (MIRA 13:2) 1. Ifoskovskly Plektrolampovyy zavod. (Photoelectric cells) 17(14) SOV/177-58-11-43/50 AUTHOR: Rabotskiy, G.Ya., Captain of Medical Corps TITLE: The Application of Novikov's Antiseptic Liquidin, Tank Units PERIODICAL: Voyenno-meditsinskiy zhurnal (U 1958, Nr 11, p~88 SSR) ABSTRACT: The author writes that for 2 years Novikov's anti- septic liquid has been used in tank units for treat- ing fresh wounds in order to prevent purulent proces- ses. About 5 Idinutes after the liquid has been applied to. the injured part of the skin and the ad- Jacent surface,_a dense elastic film develops which, protects the wound from external influences. The ap-plication of Novikov$s antiseptic liquid reduced the sick rate due to purulent processps by half.within the 1954/56 period., Card 1/1 RABOTTAT I BYE L L- 7aJT'1),/FBD/FCC;w)/BDS!~EEC-2/'F-vD.-2/ES(,,r) AFFTq/AMC/ASD/ ~b255-63 ~~D-3 P!3.-4/F~--4/1?j:-4)/ /PM- AccEssroN NR: AP3004417 S/0020/63/151/004/083-1/0814 ALTZHOR: Kotel Inikov, V., A. IDubroving VL M , Dubinskiy -L. A.; M. D. D Xislik. !(Vznetqov. B. I.; Petrov 0. M.t Rabotv&eov. A- Rzhiga, 0. N.;.Shakhovskoy, A. M. TI=: 11JIMt Nara in the Soviet Union SOURCE: AN, SSSR. DoklaW. Y. 3.51, no. 4a 1963a.811-814 TOPIC TAGS: 14ars radar observations,, Mars reflected-slm2al spectrum, Mars Doppler-frequency shift' Mars rotation time, Mars reflection-coefficient 1 * 30# to 14 ABSTRACT: 11gar t~~V~O~M of Mr sphere from 14 ___O_ -@-!,northern heml latitude and from 310 to 360*.snd from 0 to 1400 longitude were carried out in the Soviet Union on 6-10 February 1963 at a frequency of approximately 700 Me. The polarization of radiated waves was circular, with antenna polarization changing to linear during reception. The energy-of the signal Incident on the visible surface of Mars was 1.2 v. Both transmission and reception lasted approximately 11 minutes. The signal had the shape of alternate rectangular transmissions iad intervals of a duratlan 6f 4.096 see each., at two frequencies Card L JJ44-55-63 ACCESSION Tal: AP3004417 differing by 62.5 cps. The signals were recorded on a magnetic tape together, with a 2000-cpa oacillation,,which served as a scale. Receiver sensitivity vas calibrated before and after operation on the basis of Cassio-Deia-A dis- crete-source radiation. The correction for frequency shift due to the Doppler effect was regulated by an electronic digital frequency meter. In all, 9~i obse- ations were made, and the signal reflected from Mara was reliably de- tected on the nights of February 7-8 (28 observations) and February 8-9 (2o observations). The results of spectral analysis of these 4,8,observations, carried out with 4-cps filters and a storage time of 8.5 hr,,are shown in Fig. I I of the-Eaclosum. In the reflected signal spectrum, there is a darrowband com- i ponent whose energy exceeded by 4 times the MIS measurement error caused by noise. The average reflection coefficient, determined as the,ratio of the reflected-aignal energy to received-signal energy under the assumption that "The authors Mars was an even, Ideally conductive sphere, was found to be 7~9 thank V,.-A.-YAL~-, K._X.j)odlQvsk:Ly, 0. A. Zhurkinal A. M. Luki , KM,. SLnodk n, A.- A. Steppnov. A. V. Fra]ntsesson D. M Tsvetkov and L 1. A. Sharabarin for their assistance." Orig. artflEas: figures, ltable, and I formula. Association:' Inst. of Radio and Engineering and Electronics, Card 2/90-- 1. 1 - 11 1 - - - - I r- - - T-,r - - I - . - - - - - IMONROD) A. S., RABOVA, Z. S., and SbIMTSEEVA, N. M. CU crys 9 I Wine "Id.xi , - bettril. d: Oak. Ibid. meqj. 4. mist. with I.Ar., 2 hr.. Go No* ago MAN I RAI MrAlI t. '- 00 JKL by (hi. 77 2v 0000 010 0000000goo000 0 0 0 0 00 e g a0 ~ 0 71 000 o 000 0 0 9000 0 0 0 0 -- - s 0 0 i-04 0 0 0 0 0 0 fib Of 00 00 00 0 'a air; they Jut devolupd. by orms scitl% with cv,gulionol 00 ll&~;- M NY tile thiograllate anion type, 00 00 00 Ga fristst At anti AIUIW% All Almlogy with In anti 11 00 of "Y'll"tly Ow"d to the 1-8-ClOctron IhIll of the ion, in con: % 00 00 . trast to the 8 ttr cle"rons of At N. Thoo 00 00 .00 00 00 00 Of 00 0* 0 0 00 00 00000 0 Off 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0,0, 10 -- 0 0 0 0 0090. ooo*000*00000000~00000000*000**ooooooo o 'UTHOR3: Ivanov-Emin, B. N., Rabovik, Ya. I. SOV/78-3-10-35/35 ----------- TITLE: Hexamolybdenum Gallates of Alkali Metals( Geksamolibdato- gallaty shchelochnykh metallov) PERIODICAL: Zhurnal neorganicheskoy khimii 1958, Vol 3, Nr,10, - pp.2429-2432 (USSR) ~ABSTRACT- The production of potassium and ammoniumhexamolybdenum gallate was carried out in the weakly acid medium when solutions formed by potassium molybdate ( ammonium molybdate) and gallium sulfate were heated. The compounds have the following composition: K O.Ga 0 1214o0 .20 H 0 2 2 3 3(NH .20 F~O )20.Ga2O 3* 12MbO 4 3 It follows.from the analyses of the molecular conductivity that alkalihexamolybdenum gallates consist of four ions. The following coordination.structure was suggested forpotassium and ammoniumhexamolybdenum gallates: Card 1/2 K [-ra(H 7 H 0 3 14004)6] 2 (2) SOV/78-4-:-10-0/40 AUTHORS% Ivanov-Emjn,,B. If.,,-Nabovik,.Yat I, TITLE-, Complex Compounds of Halides of Gallium and Indium With Pyridine PERIODICALi Zhurnal neorganicheskoy khimii, 19591 Vol 4, Nr 10, pp 2228.r2236 (USSR) ABSTRACT: In, the introduction the authors mention the complex compounds ethylene diamine-I. of the halides of Ga, In and Th with ammoniap, . and urea hitherto known. The ethylene,diamine and ammonia- ethylene diamine-compounda.were-described by A Po-Kochetkova and V.; Ge.Tronev (Ref '~.) who have also synthes-.-ed compound '(Ref 4)* InCl 3', 4NK3 Preliminary experiments.'showed thatthe., formation'of pyridine complex-compounds of gallium from aqueous solutions is not possiblep The synthesis was therefore carried out in alcoholic or ethereal solution.,The following ' compounds were obtained for the first time:. GaC1 C H M, 3* 5 5 GaC1 2C-H N, GaBr 3C H N'i-GaJ -30 N Ni- InBr H N and the 5 5 3*3C 5 5 3' 5 -5 3 *- 5 5 3 ~ . a-picoline complex compounds InHal 3*3G5R4CH 3fle-The analyses Qf.~.: Card 1/2 the preparations, the-variation 'of pH on dilution and titration SOV/78-4~10-9/40 ,,:mplex Compounds-.,of Hal-ides -,of Gallium and IndjLum With Pyridine wiih KOH, the melt�ng points-and the molecular electrical con- ductivities are given-and the crystals shown in a picture. The' absence of the tri y p' Adine compounds of GaC1 and InJ and the 3 3 low stability.of the GaCl -dipyridine complex is explained by 3 the tran's-effect according to-1. 1. Chernyayev, on suggestion of B. V. Nekrasov. The indium complexes are completely hydro- lyzed by water, whereas the gallium complexes form acido com- p1exes without-noticeable hyclrolys,is'* The aqueous solutions are of adid,.rea-ction,~their.electrica1 conductivity ranks in the decreasing ordei'of C1-4-Br-~~J. By determination of the molecular weight-of the gallium-r-halogen complexes they were proved.to be monomer when dissolved in benzene. There are 3 figures, 8'tables,,and 9-references, 3 of which are Soviet., SUBMITTED: July 23 1958 Card 2/2 IVANOV-EMIN, B.N.; NISELISON$ L.A.; RABCVIK,__!(a~,.; LARIONOVA, L.Ye. Ya.l.; GREESH,~M,,;, 0.1".; UIEACEEVII, Ye.G.; red. [Laboratory ranual of qualitative analysis for correspondence- Courts* students of the faculties of agronomy.and zooltechnyj Rukovodstvo k praktichookin zanlatilain po kachastvennorm ana- lizu dlia studentov-zaochnikov agronomicheskoi!o i zootekhniche- nkofro fakiilltetov. Moskva 1963. 170 p. (MIRA 17: F) 'USSR / Human and Animal Morphology - Digestive Tract 8 Abe Jour Ref~ Zhur& -.Biole, No. 22, 1958t No, 101432 'Author Rotenberg, Ya. A.;:Rabovskaya A. Ye. I n s t Title Surgical Anatomy.in Injuries' of the Organs of the Peritoneal Cavity., Orig Pub In the collection:- Neotlozhnaya khirurgiya or- ganov bryushnoy polosti..K1ev,4osMed1zdat, UkrainianSSR, 1955, 225-232. ,71/81-59-8-28434 Translation from.- Reftrativnyy.zhurnal, Khimlya, 1959, N~ 8, PA07 (USSR) ya,-N.S., Kadherovskaya,.V AUTHORS: R~bcvi&' TITLE. An Invest1gation-of 'Whe Prc-.-;5ss of- Ester-Ification of e Glypoll by Acetic Acid in the Freseac-.e~ of Catlonlt~es as Catalyste PERIODICAL.- Tr. po kh1mii I khim. taekhnol., 1958, Nr 1, 3~p 1190'- 191 ABSTRACTs The kinetics of.the esta-rification process of is-tIvIene glycol (I) by acetic acid (II) in the presencz of 10-2 cation-axchange resin has besn studied. It has been establishc-:1 that '-',a quar-tity of cationitg startirg with 0.5% ofthe weight of the reac~tion mass* pr-actically does not, affect the process, and a 9-fold application of one and the-game sample of KU-2 resin does not decrease the activity of the catalyst (the activity which is spent nearly completely after the 11th qycl-, is restored after 6 days). In the absence of the catalyst the monoester of I (chiefly) is formed, in the presence of KU-2 (or SO),) the diest*r.- The reaction rate in thi , Card 1/2 presence of H 11at7~-Igher than in the presence. of KU-2, bu-~ in, 2S04 is s0mew _5717-200 66859 SOV/76-33-11-14/47 AUTHOR: ' l TLE: TI in the Organic Use of Ion-exchange Resins as C,~~st~a Synthesis PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 119 pp 2467--2470 (USSR) ABSTRACT: The author checked the applicability of ion exchangers as cata- lysts in theesterification of ethylene glycol with acetic acid-.. Ref 9). At first, three-cation exchangersp KU-1 and KU-2 lfo cation exchangers) and SC-11(carboxyl tation exchanger) M were investigated* Asthe catal tic activity decreased in the order KU-2 > KU-1 > SG-1 (Fig 1~j the further experiments were carried out with KU-2. In the presence of KU-2 and sulfuric acid ethylene glycol diacetate forms, while without catalyst the reaction only proceeds up to the monoe0ter (Table, Fig 2)., The, esterification could be accelerated 3-4-times only with K'U-2 and thus proceeded as rapidly as in the presence of sul- furic acid alone (as a catalyst). KU-2 loses its catalytic activity already after 11 working periods.but regains it after I Card 1/2 tzner a 6-day storag6. Reed and Wenzel (Ref 10), Hamilton and Me 66859 BOV/76-33-11-14/47 Use.of Ion-exchange Resins as Catalysts in the Organic Synthesis (Ref 11) carried out a gaseous-state hydration of ethylene oxide with cation exchangers as catalysts. In the *Present case the reaction took place under less rigorous conditions, and it was found thatv already at 00, ethylefie oxide in the presence of ion exchangers is capable of adding water and low alcohols, in which case only the cation exchangers KU-1 and KU-2 (Figs 394) proved effectivep while the anion exchangers EDE-10 and AV-16 were ineffective. A special advantage of the catalysts investi- gated in the two above reactions was their selectivityt i-.e. they accelerate the main reaction considerably more than the side reactions, while sulfuric acid equally accelerates both the main and the side reactions. Finally the author expresses his gratitude to G6 A* Razuvayev for helpful advice6 There are 5 figures, 1 table, and 11 references, 1 of which is Soviet. ASSOCIATIONs Tsentraltnaya laboratoriya zavoda "Zavodstroy" g. Dzerzhinsk (Central Laboratory of the Plant t'Zavodstroy", Town of Dzerzhinsk) Card 2/2 ACC -mru_-kr~628.Z~i _GO-D__E_ -I- WV66~6&th6_~/ /6~1/6340 AUTHORi Rabovskaya, H. S.; Kogan, L. M. CIRG: Moscow State University im. Me V. Lomonosov (Moskovskiy gosud&rBtvernyy univer- sitet); All-Union Z-ai-e-n-tMT-Research Institute on Plant Protection by Chemistry 1EHM he_iki sradstv zashchity (Vsesoyuznyy- naucbno-issiedovatel takil Ins t1 tubc as La- ni-Y) TITLEz Radiolysislof hexachlorocyclopentadien~t' SOURCE: All SSSR. Doklady, v, 165, n0.2, 1965p 337-340 TOFIG TAGS; x ray irradiation, ethylene, butadiene ABST!LkGT: Radlolysis of hexachlorocyclopentadinne proceeded analogously to that of tetvachloroothylone or hexachlorobutadiena. Twenty ml of hexachlorocyclopentadiene was placod in a Mo-glans ampule and the ampule was aeLed without the removal of air. The radi~jysis.of hoxachlorocyclopentadieno was perfoTgd at 20G, using 0.66 x 1022 15.7 x 10 ev/ml. doses at the 1.95x 1()16 - 3.82 x 10i ev/ml,- see. rate. Wi th an increase of irradiation dose, the conversion proceeded fast at first and than be- came slowert.After distilling the residue of hexaciLloropentadieno, the reaction products were.eeparated by rectification in a vacu" with a subsequent freezing-out of crystals which formed in different fractions while standing for 10-15 days. The Card 1/2 UDCi ~47*514.72 ACC NR, AP5028281 I products or radiolysis weres 20-301, yield of octaeblorocyclopontenoo me 41-3-1a.5- G; X% Yie d of a viscous red oil of Cl()Cllo composition, mole wel t 3, b. 180 - 8 h 48 g nn 6049, dZO 1.8085; 1 - 21av yield of yellowish crystals, having a mole weight of 4158 icryoscopic det6rmination) or 485 (isothermal distillation) and an absorption mayimum at 273 and 320 m/Iwith the absorbance equal to 5000 and 32000, respectively; and traces of a crystalline compound of tho composition of Ci?042, me 340 - 2C, bav- ing an absorption maximum at 268 and 27e%m)U-. ~Iolecular G12 d not form. Autoconden- sation of the bexachlorocyclopentadiano was not observed. The paper was presented by Academician S. I. Volikovich, 6 Apr. 65. Crig. art. hass 3 figs. and 3 formiLlas SUB CODE: 20/ SUBM DATE: 18Mar65/ CRIG REFs 0031 OM RU 1 005 Card 2/2 CIGOFODNIKOV, S.F.; KOROLI, N.G.; RJ4BC)VSMA,,,-F,7y',,_,. . ~ GUTMI, Ioalf Hoisayevich; FICUK, Fedor Ivanovich; RABOVSKIY _A_,V., lnzh., --td~ SUV/51-6-3-22/28 AUTHORS: Finkellshteynp A,I.p Malachevskaya, F.L., Fisher, A.M., and Rabovskiy, B.G__ TITLE: A Simple Method of Preparation of Potassium Bromide Plates for Infrared Spectroscopy of Solids (Prostoy.sposob prigotovleniya plastinok iz bromistogo kaliya dlya infrakrasnoy spektroskopii tverdykh tel) PERIODICAL: Optika i Spoktroakopiya, 19591f Vol 6, fir 3,,,pp 415-417, (USSR) ABSTRACT: The paper describes preparation of rectangular XBr or NaGl plates containing the substance to be investigated by infrared spectroscopy. The plates are prepared from dried (12-18 hours at 2000G) powders. A small amount (0.1-3%) of the investigated substance, also in powder form, was added to KBr or NaCl and ground in a porcelain. mortar. The amount of the substance studied which is used depends on the spectral region to be investigated and the sensitivity &nd accuracy required. The plate is prepared using simple apparatus (figure). It consists of two Card 1/2 stainless-steel. plungers (1 and 2) and a stainless-steel SOV/51-6-3-22/28 A Simple Method of Preparation of Potassium Bromide Plates for Infrared Spectroscopy of Solids ring (3). A plastic form (4) is placed on the lower plunger and filled with powder, which is then lightly compressed by means of a plastic piece 5. The form 4 and piece 5 are removed and the resultant thin rectangular-, plate is further compressed using the ring 3 and the upper plunger 2. It is-necessary to apply 10-15 -tons for several seconds or 5-7 tons for up to 30 minutes, The area of the plates produced is about 1 CM2 (20 x 5 mm).. There is 1 figure and 3 references, of which 1 Is German and 2 Engliah. SUBMITTED: June 24, 195B Card 2/2 r. - A-A--A-A. a A f 9 It I I U T LA -A. 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