SCIENTIFIC ABSTRACT RABINOVICH, I. B. - RABINOVICH, I. M.

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SCIENTIFIC ABSTRACT
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Bill'' CHO k: 77 .1y too effe In Mo a bai t -vapor dry Wt. IS C044 I BT I U, lov ompotin i .40V Go 1ko ev Chaliev, W S. j e r o-com ~-~fbe vapor i~ dia- Iqjb --Vc, - - gmms of the 6 Ibt CRcIr- (2c0, C CII-E tit, 25 tic 35, and it, HIN and 111,0-csl at 70 75, Und Wand the b.p.-compst. dia m-rasof (CIIJ,cf-10 --clyrd at,700 C414 aud of (CHOSCII01) Dun. WercillycStj tad. At low CTICh cunen. In acdone IM vapor pressuro rhigher t1tan that of CDCIP, but conditimm are revers cd at 2 crinediste concns.; 't-hisisatftibuted lotbc!act that lite vapor pmssure of CDQs Is ~:omewhat Whimr than that at) CjfCI 3. Pmd thisaccounts foi th6jotalpicsnure of CDC$, +i Wbetvil IsmplactA by D, the %ere energy of the 11 boad is decrt-ased and tbe houd is strcngth~!I' uiecl. Thc Urcater strvugth of tLe mol. amwns ;of cif cis: Vith acetone whIch cr wmc. on ev4pn., rmsiu In a lmver Sol vapor pressure,* The-equit. diagrama of systems C$H#N- z" lipo and c&IJSN-D,0 and of Oe otlwr binary syi;temi ari preunted and CIL W. K Stvrq!~U& 20-Uh-3-313/60 AUTHOHSe Habinovich, I. B., Goloy, V. G., Yefimova. N. A., Hustamov,S.M. TITLEo The Isotopic Effeot in Compresuibility and in the Association of Deuteroalcohole (Izotoynyy effekt v szhimayemosti i assotsiataii doyterospJAov) PERIODICAL# Doklady Akadomii Nauk SSSR,1957,Vol,,114,Nr 39pp---590-593(USSR) ABSTRACTs The paper under review is devoted to the investigation ct the, ultrasonic vel8city a and 0of the density d in the inter- val between 10 and 60 - 80 for CH OR and CH OD, and several ot'hers, as well as for D2Oe The adilbatLc comiressibility... and the osmotic coefficients were measured. The deuteroalco- hole are obtained by hydrolysis, with heavy water, of appro- priate alcoholates of magmesium and aluminum. The ratLo of the cryoscopic molecular weight and of the molecular wei.-ht ob-. tained from the formula decreases in the follovini;.orders methyl alcohol, ethyl alcohol, n-butyl alcohol, as well as nornal, iso-, and secondary butyl alcohol. For.deateroalco- hols the acid ratio is by 2 - 5 % higher than for their hydro- gen analo.-ues. Although it is not possible to derive any- Card 1/4 accurate values of the degree of association from benzene 20-U4 - 3- 38/60 The Isotopic Effect in Compressibility and in the Association of Deutero- alcohols solutions of the alcohols, it is clear that the increaseof the osmotic coefficients, with increasin,-, concentration in alcohol, is caused by its de-ree of association. Therefore it follows from the results of the cryoscopic experiments that t~e deuteroalcohols are associated by the hidrogen bonds in a hi~;her degree than their hydrocen analogues. This is also confirmed by the higher boiling point of the former, and also by the fact that sub3titution of hydrogen bj deuterium in the alcohol hydroxyl leads to a reduction of its.vapor pressure. The authors of the paper under review supported the statenent macbby Tarasov that, generally speaking, compres- sion does not take place on the relatively solid hydrogen bonds but rather on the weaker Vandervaals' bonds between the.. chains (associates). Iso- and secondary butyl alcohol have hi.-her compressibility than their normal primary analogue. Therefore alcohols with a ramified chain are characterized bj higher compressibility than the primary n-alcohols. In all deuteroalcohols investigated the ultrasonic velocitYJS by lo - 2o seconds lower than in the corresponding hydrogen analogues. On the other hand, the coApressibility in the Card 2/4 former is higher than in the latter. From the pointof view 20-114-3-38/60 The Isotopic Effect in Compressibility and in the Association of Deutero- alcohols described in the paper under review this isotopic effect.of the compressibility means that in the deuteroalcohols the intermediate chain interaction is somewhat weaker than in their hydrogen analoGues. The occurrence of the temperature minimum of the~curve of compressibility in water, as wells:' as the presence.of the maximum of density, can be explained. by superposition of two factors at the increase in temperature and also.bj the transition of water from a more'strongly. associated state into a less strongly associated state, with a denser packing of molecules (reduction in compressibility)., The authors of the paper under,reTiew maintain that, as com- pared to normal water, the decrease in the degree of.asso- ciation in heavy water is delayed with respect to tempera- ture. In a way, the retardation of ultrasound in the sub-, stances investigated, when hydrogen is substituted by deu-, terium, is also caused by the increase in molecular weight There are 3 figures, 3 tables,, and 15 references, 8,cf which Card 314 are Slavic. PAXINOVICH, I. B. "E perimental Investigations of the Characteristics of Ultrasound Propagation in 90V/176-32-7-9/45 ."MIORS: Rabinovich, I. B., Yuchery--vyy, V. I., Nikolayev, P. N. TITLE: The Effect of the Substitution of Hydrogen by Deuterium on the Ultrasonic Velocity, the Refraction and.the Viscosity, of Benzene (Vliyani-,-fe zameshcheniya vorloroda de.-,,,t,~riyem na sko--,-~!tl tilltrazvul", re-t*----IktGiyn i vyazkoatl henz-ola) P:,-:Ii 10DICAL Zhurnalfizicheskoy ',a.-himii, 1958, Vol, 32, Nr 7, rP.1499-1505 ABSTRACT: p r es,w e investigated for a deu- ','he above-mentioned pro e ti er 'ture terium content of 0- 50 and 91 atom~-i~,-tithin the tempera interval from 30-60 6C. The viscosity of the deuterium benzene had already been in-.-3,etigated bY Dixon and Schiessler (Ref 6), however, only at three temperatures. From the experimnntal part it may be seen that the.deuterium .Products vrere obtained from benzene and deuterium sulfuric acid,, the latter being The deuterium content produced from 30 and heavy -tater.; . determined.accorhng to the data supplied by,Klit and Lang- seth (Ref 9) from the density, while the sound velocity.was Card 1/4 determined accordingto the method of I ir.-~-h tdiffractJon. SOV/70-32-7-9/45 The Effect of thc. Substitution of Hydrogen by Deuterium on the.Ultrasonic --orelocity, the Refraction and the Viscosity of Benzene The data obtained differ from thoze obtained by Collins and scoaLmeter used is simil,-ir to that de- Raffel (Ref 1) T h e- vi I veloped by A. Z. GolP., and 1-7. D. Ravikovich (Fef 11) the'~ flowing-out,laqting at least 400 seconds, and theviscosity of the deuterium bf-,nzcne having, been measured relatively to that of benzene. Density was determined in a pycnometer, whereas the index o.f light refraction-vas measuredby means of a r,~fractometcr of the type UW..'~23 (Pulfrich type) - In 'R f relation to the equation of Scnauiio ',.e 13)-for the ultra- sonic velocity based,on that of van der Waal, it is*assumed that ultrasonic velocities.iri,benzene ond its deuterium homo- logk~ -Must be inversely proportional to the mug-TLtudes of the square roots of the molecular weights. In the papers written by find Eyrinc~ (Ref 2) it was shown that the sound veloc-Ity in li-no-ids is directly related to the. "free volumes". From the equation gi-ven by those.authors the huthors of this enlargement of thefree volume in the paper obtained a 5 case of a 50 1/74 substitution of' the hydrogen by deuterium in benzene, Fnd one of with 91 -,. deuterium; this corresponds Card 2/4 to the dnti obtained in the isotopic effect in compressibility. SOV/76-32-7-9/45 The Effect of the Substitution of Hydrogen by Deuterium on the Ultrasonic Velocity, the Refraction and.the Viscosity of Benzene In connection with this it was found that a substitution in benzene of 91 ';" hydroeen by deuterium decreases the refrac- t1on index to 2.1o-3 and the polarizability to 0#52 %. As the zero energy of the C-D bond is smallor than.that of the -!I bond a D 11 nubstituti increase of the on causes an Pnergy difference between the respective.excit6d and the busic :Iectron.level; this fact is explained by obaervations .:,.ade by ?urton ot ql. (Ref 15 and is proved'by experimental d-.3ta obtained by Ingold and t7ilson (Ref 20). -Proceeding from the eIquation according to Slaterand Kirkvood (Ref 21) it is found th at a 91 hydrogen s ubs titution by deuterium causes a decreaze ofthedispersion energy to OA a; on the other hand it isjound.according to the data supplied by 'Nilkinson (Ref 23) that the equations according to.London Ref-241 as well as those according to Slater and Kirkwood Ref 21~ supply similar values for the,isotopic.effect-i .n the, ~ dispersion energy. The observed effects described were ex- Card 3/4 Plained by the increase in atomic dimensions and by, the de- SOV/76-32-7-9/45 The Effect of the Substitution of Hydrogen b,,IDeuterium on the Ultrasonic Velocity, the Refraction and the Viscosity of Benzene crease of the zero energy of the atomic bonds dependent on it. Since the dispersion energy becomes smaller in the hydrogen- deuterium substitution also a decrease,of.the heat of vapor formation isexpected which seems to be proved according to data supplied by Davis and Schiessier (Ref 14) although those data are doubtful. In the case of a.91 Cf substitution of ben- zene by deuterium an increase of the viscosity from.40to 5,5 014o was observed, and correspondingly less in the case of a 50 vl~, substituted one; also an increase of*the vappr pres- sure at r,6D6 by 2,5 - 2-% to that of,C 6 116was found. Finally the authors thank A. I. Brodskiy. There are 1 figure, 2 tables, and 24 references, 5 of which are Soviet. ASSOCIATION: Gor1knvskiy gosudarstvennyy universitet in. N.I.Lobachevskogo (Gortkiy State University imeni N.I. Lobachevskiy) 1. Benzene-Properties 2. Benzene--Analysis-". 3. Deuterium --Determination 4. Deuterium-Properties -5. Sound-n-Veloeity Card 4/4 Gorbushenkov, V.:Ai If IT 1, The Isotopic Effect in Critical Temperature (.1zctopnyy effpki', v kritlciieskoy temr-z?rature) P_-'Rt0f'NCA1,: fir 3, pp. 566- r-61) Dokla4y Akadentli nauk SS411., 1958, Vo-. '12o. ARITRACT: The present paper com.oarei the eritical temppra-tures Tk of It deuterium comuounds with the analogous hydrogen COM_ pounds. ;hovt reference is made to the representation of ~deuteron compounds. The materials tc be investigated are caref, ully cleaned and dt-gased, T wao determined from tire k vanishing and the occurrence of rreniecus. With each pair (deu- teron comT)cund and the hydrogen compound-,analogous to it) 20 meaAur,~,.Twnts w-t-re carried ob-1. Beside-S the dif'ft~.-rennes T ~. T T also the absolute values of T were de- k D k k kh 0 termined as long, as this value did riot exceed 30U C. Above ~'000 C unlv AT was deteririned. In al* sub Ic *,.nn ., ce a investi.- e mittpd when determ i ning &T' gated-Ttie quadratic error,com amounted t Io about 0,10. If the Iight~:isotope is replaced kby card I/i the hewry isotope. T is always reduced. Also in tile case k The Ifsotopic P!Yect in CritjLcal Temperature -,'OV/?o- 12o-3-56/67 Card 2/5 of previously investigated substances (with the exception of helium and hydrogen) an isotopic effeat with the same sign was obser,ied. Thus, the law T k 0 < T k H is apparently of. garerai v;Llidit1v fur the variobs clasbes of inorganic, and -z-ganie compounds within the range of me lum temperatures. By applying the knc~wfi*relationA a - 27 R T2/64 P and k 'k a , 9 11T V (where it denotes Vun~ der Waal's (Van-de v.- Vaal 13 k 8 V constant), a D/,Ii T k~ P , ,/T ~kjD and a /a ~ (T kV ) (Tk R . 1) k k.HP D H k JU /, k obtai.ned. Thus it holds for the isotopiu, analogues of water that a D/a H -~ 0,0,89. Various details are then discussed. The IsoLopic elfeeotz3 discussed and thus also the conclusion drawn as to the reduction oC Van der Taal's (Van der Vaalls) in- teraction on the occasion of' the replacement of the light by the heavy isotope must in:no case.be ext ended to the range of low temperatures. At thetemperatures of liquid helium and hydrogen the replacement of the light iso,tope by the heavy one leads to an intensification of Van derWaalls.(Von der, V,ial's) interaction, which is the opposite to what takes place at medium temperatures. In conclusion.. the authors thank 1. Brodskiy, Corresponding Nfember, AS USSR for his dis-- -cussion of the, results obtained, ond they' also express their Critcal Temperature -qOVi2u--i2o-3-36,?6j t-.; Ravikovi~,h +,L~r hi- advices on methods. There arf~, 2 tab-!~S and 24 references; u 01, -grilck, aj,j~ ~OVjet, Naucbnc-issledovatel.~akly institut kh~mii .ai 'Ruve k6go im. ji. (~'.cientifio qesearzh Institute for~llhemiatry of C c. 1-, -4 ur)iv'-r.-~4-ity imeril 1. Lobachevz;.Kii.~f) i,-E- b x, u a ry 10, by A* U. Fruinkir, 1! enber, Academy of ciencei, Uz )R SUBMITT-ID: December 28, 1957 1. Denterium compounds-Temperature factors 2. Hydrogen compounds-Temperature factors Card 5 TITIE: PERI"'i"ITCAL A 7 S T R;~. C' T C--trd -2-7 '56 Rabinovich, I. B. , Volokhova, Z. V. SOV/20-122-5 The Influence of the SuInstitution of lly~lrogen by Dentorium Upon the Pol-arizability of Molecules (Vliyaniye., zamczhcheniya vodorod-- deyteriyem. na Dolyarizuyemosti Dokla~y Ak.-,.de!.-,ii naule SSSR, 1953, Vol 122, '-'.r 5, 844 847 (USSR) This oa-,)c~,r deals wit!, the investiy-,4~.tion of the diz;-,~rr;ion of light and wi-th the calculation of the czatic polari,~qbility (a of 12 lil-lizid deuterium 0 compounds at'd t-'-.eir hydrogen compounds. E;e of L-lese compound's- are given in full -n a table. The rrffr~ .xtion index ,-,ras meazured b.~ means of the refraC'607:'O'u-C�-' IIW-23 (Pulfrich (Pullfrihh) t_~7pe, rein,tive exactness 21.W-5) at 293;L 0-05'K for the lines Ha, D, Hg HP, and H- The Greon *blue-violet statio, Doiari7f-bility was determined by extrapolation 2 2 2 i'o 0 o;k~ the dependence of (n +2)/(n -1) on wiIiare -0 denotes the frequency of the light. For L11 Tl:o of the Sui;otiti,.tlon of ffydro~;en by 307/2o-122-5-27/16 Upon t,,(! Polari,,:,~biliLy of !3w inivn!'Li ated tl~4.D dependence was L''IQ rft'qII('-(7y illtevvinl. All have a lower L~~Iiox and a lower polarizability than the cGrrOOj')on,' hydro~;en compounds. The decrease of Aho be erplained by the dec- -ease of t1-le zero enerL;y of the atomic vibrations. the -.W-stitu ion of hydroGen by deuteriui T.,r-~ctic~~Jly does not (-;-.2~rCe the potential, curve of I _M L..c orer'-7j - d t',,o force conctants of, the io -- i inp-1 e-, t c a - eof a 2-aton molecule, decroa--e of t",o vibmtion levels of t~e electron o,~ectra increases V-o ei-,era of the cloctron trumsJtions from the Groluld (0) level to e- :c ic-.. dlevel W An for T t 1 i:; d uc e d t' t '10:10~tco I.-ef req_en, CY N)j.D T JrIjU,1n,,ce of t,--,c S-u*--+i'ut4on, of SOV/2o-122-5-27/56 Deut.er-~um U-,ion the Pol~riznbility of 11olec"ZIes of the electron tranl~ition. This inequat,ion, is valid prob%lhly for polyatomic molecules. The ab,ove- eivoii ine4tiation i!~ confinmed n1no by experimental tt--ta.A dispers-ion forniula for t1ne polari~~--bility oL of the molecule i_ given. Probably, a D /. aif to t-he e x jor -i,- 0!- 41 a 1 data. T~'e tlir-, ks L.S. 'ayant2 for diccussinG the rez:ults. author I fi~yrp ard 14 7 of which are Soviet. universitetc: !,1. 1:1 . I . L ol;,-~ c',-c v!- kiy ~Inrtitl~te, of Cho.l."C'Ury of Goi-"-iy Stnte Univercity i:,.eni '-o) .:'L ED: June 27-, 19513, by A.N.Frunlkin, Academician Ju,.,Ie 6, 1950 Cox'I Pun 1 11009 UPLOITATION SOV/4186 hisadomiya nauk a= VQ&hQb tv& I Apektmakoplya (Structure 0r "tter stroyonly and 3 roe co ) Moscow, Izd-vO AN SS3R. 1960. 113 p. p:ct ;; Rrrata allp Inserted. 2,300 copies print*d. Id.s K. V. Astakhov, Professor; Tech. 3d.s T. P. Polonove. FUNPOMI This collection or articles Is Lnt ended for physicists and chemists interested in spectroscopic methods or research on the structw" of molecules and related problems. COVOME: The -artl Is$ contained in this collection wore takon from the *ittorlal filed or the Zhurnal fizieheakoy thlAll (:ournal or Physical Chemistry) and a" concern*d w1M.opoctroacople methods In research an the structure of molecul *. the hydrogen bon , Isotopic effects, problems d : t..homistry. the st in W ructure of aqueous solutions or electrolytes, and the chemistry of complex compounds, Refer- oncem accomoanr Individual articlos. author thanks the following for having p&rticipa ted In determining the density or douterocompound3i V. 0. Golov, P. N. Nikolayev, V. 1. Kutheryavyy, Ye. Z. Zhur- avlov. V. I. Murzinand L. 3. ZhIlkin. He thanks A. 1. Brodskly for his discussion of the r4sults. hr A M and Pt. B. Lkl.~Jjhuler (HavochorkAsekly poll. _ - .FF ET NovocherWile Polytochnic Institute)) Problem of Change In the 3tructuro of Polyethylene at nano-PAdiai Extension 7-wL__1AIm To. I. =Uava, S. D _aAxjjVAUacj4 nA 1, 'v a lbor*klr State Uhr=e;;rty ~m I.., N. L. Lobachevszry topld Effect on the Viscosity of Douteroalcoh 73 _1_Xe.MrcNtko_ and V V Pasenko rXivesti. " :-W atl f S f j; fu ace on o ur nsion or Liquid s. 1. Sur- on S face Tension or a LA&A-Ulver System V*M2bLr9__T___Z_ Coordination Equillbrla of Nickel Ions In k0 PbO :-'- =02 System Glass" ~84 imI203A yX _VA,.-_[1.na.Ltut khIzU sillkatov. (Institute or rA1IAAtt8)j. StrUCtUr- Of' SPO't=tne Glass 93 V. 1. Ayer'yanov Is thanked for having plotted the curves for a- and j5- spodumeno and for the crystallization - product or spoduz-Ane glass. .ban* T 9 (Phy3leachemical E"'Itute Imesni L. Ya. Xarnvj_ - - -FATE' ~r Excess -A-El.ctron DIAMA?ndtle SuSeeptibilLty :ulad. or Certain Naleciles C-ntalning the Six-Member Carbon Ring jgLth the Aid of the Pz--~ FAectrons Model 96 The author thanks 1. N. Xalachovaya and S. Ye. S&mosulov for the numerical Calculations. and Ye. N. Ourlysnova Ada=~ for their sugZt3tion3. M. N. B43I&YeVa EIn3tItUt ob3hchoy I - ' 7 r',L-n9;CoVft (rnstitute of rWo-rianiche3k;Oy V. 5 . General and Znorgazjc Chemistry Iment N. 3. -Karnakov)). Temperature Dep~n,lence.of Coordinatlon Hunters of Alkall u-stno &-rllral-20~ polltekhnlzhis-tly In3titut - r- 3 Kirova vard V . K Form or Urraca Tension J. S Kirov, IBOthe=s AVAIL&BLE. =trAry Of CJngre33 Car.1 6j6 10-20-60 15. 68857 /POO AUTHOR: Rabinovich, I. P. 5/076J60/034/02/024/044 DO I O/DO 17 TITLEt Influence of the Substitution of Hydrogen by Deuteriumin the Sound Velocity and the Compressibility of Liquids PERIODICALs Zhurnal fizicheskoy khImii, 1960, Vol 34, Nr 2, PP 423-431 (USSIt) ABSTRACTs The prosentinvestigation was carried out with the cooperation of V. G. Golov, Pa N-_Nikol~lev, Z. V. Volokhova, and V. 1. Kucheryavyy.* The propagation velocity of ultrasonic wavos and .their density madependont on the temperature were measured for the following deuterium compounds and the corresponding hydrogen analogs: deuterium benzene, methyl deuterium benzene, deuterium nitromethane, deuterium chloroform, methyl- and ethyl-iso-douttrium propanolp primary n- and iso-deuterium, butanol, and deuterium glycerin (deuterium in the bydroxyl groups). Since the publication data on the sound velocity in heavy water are not in agreement, measurements were carried out also in this field. The method of light refraction was applied on ultrasonic waveagand the investi- gations were carried out at frequencies of 3 Wes. The majority of measurement values.(Table Is density of deuterium compounds, Table Card 1/3 2, ultrasonic velocity in deuterium compounds, Table 3, adiabatic 68657 Influence of the Substitution of Hydrogen by ',eaterium on the Sound Volocity,and the DOIO/DO17~~ Compressibility of Liquids compressibility of deuterium compounds, Table 4, Isotope effect in the sound velocity, density and compressibility of deuterium compounds) lie between 20 and 700C. In all coupounds.investigated, the hydrogen substitution by deuterium effected a decrease In.the sound velocity and an increase in the adiabatic coupwasioibility. The sound volocitioslin the Isotope analogs In the percent ratio are by 1.5 - 2 times higher than the reciprocal values of the square roots of the corresponding molecular weights. The Increase in compressibility iift the substitution of hydrogen by deuterium in nonassociated compounds (which form associated chain complexes through hydrogen bridges) in explained by,tho weakening of the dispersion interaction between the molecules (and thus also bo-w tween the associated complexes). This holds also for water and glycerin. Furthermore, the increase in compressibility in the .substitution of hydrogen by deuterium in water and glycerin Is explairod by the formation of three-dimensional lattices. In this connection, the number of the nonassociatod molecules (which are in equilibrium in the lattice) Is reducods and thus the molecules Card 2/3 are lose densely arranged. In conclusion, A. I. Brodskly, Cor- 1XX S/076/60/034/009/028/04 1 B020/BO56 AUTHORS: Rabinovich, I. B., Murzin, V. I., Zhilkinp L. S-~ ~TITLE- The Isotopic Effect in the Viscosity of Deutero-glycerin and Ethylene Deutero-glycol PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 349 No. 9, pp. 1973 - 1975 TEXT:. The authors.wanted to ty, the relation between the isotopic difference in the viscosity and the association by means.of hydrogen bindingy an d for this purposethey inve3tigated the effect produced by thesubstit ution of hydrogen by deuterium in the hydroxylgroups of,:. glycerin an d ethylene glycol upon the viscosity of these compounds. Deuterium w as introduced into the alcohols by repeated exchange with heavy water under vacuum evaporation. The deuterium contentp the density 20 '), and 4 20 in ex the refractive d 11 -) of the isotope analogues are given 4, D in Tablel. The viscosity wasdetermined with an accuracy of,about 0.2 As may be s een from Table 2, the isotopic:effect in-the viscosity for Card 1/2 The Isotopic Effect in the Viscosity of S/076/60/034/009/028/041XX. Deutero-glycerin and Ethylene Deutero-glycol B02O/BO56 deutero-glycerin equals 16.5 and for ethylene deutero-glycol 8.3 with a molecular weight differ ence of 3.2.~,, in,both cases.,By:the sub- stitution of deuterium for hydrogen in the hydroxyl groups of glycf~rin, the viscosity is increased within Ithe temperature.range of from.20 to 900 by from 16.5 to 9.0 ~., whereasthe rise In the case of ethylene-glycol, - within the temperature range of from 10 to 900,amounts to 9.0 % to,2.0 The great isotopic effect,in the viscosity of the associated,liquids-1 investigated is explained by the fact that it depends exponentially on the isotopic difference of the activation energy of the viscous flow, which,~ in turni is exponentially relatedto the isotope difference of the zero- energy of vibrations, which correspond to the hydrogen bond., The authors thank Academician of the AS UkrSSR, A. 1. Brodskiy and Professor A. Z. Golik for discussing the results of the presentpaper. There are 2 tables and 1, 10 references: 7 Soviet, 3,US, and 1 Belgian. ASSOCIATION: Gorlkovskiy go,sudarstvennyy universitet im.~ N.~ I. Lobachr?v-. skogo (Gor I kiy, State University imeni N. 1. Lobachevskiy) SUBMITTED: December-16,1958 Card 2/2 S/076/60/034/010/006/022 B015/B664 AUTHORSt. Rabinovich, I. B., Lobashov, A. A., and Kucheryavyy? V. I. TITLE. The Negative Isotopic Effeot~ in the Viscosity of.the Deuterium Compounds PERIODICAL4~ Zhurnal fizicheskoy,khimii, 1960, Vol,-34i No. ~10, pp, 2202-2204 TEXT: An exchange of hydrogen by deuterium leads.. in the case of non- associated liquids, to a change of themolecular weight and the energy- of the intermolecular interaction. An increase of the two last-mentioned., values leads to an increaseof the viscosity of the liquid., Rabinovich et al, showed that.in the range of..Medium temperatures, an increase in the molecular weight in the substitution of hydrogen by deuterium.As accompanied by a reduction of:,th,e intermolecular dispersion energy (Refs 2-4), i.e.., that an increase)'but also a deer Iease in viscosity.,may occur.due to.the isotopic exchange in dependence,on thefact whether the increase in molecular weight, or thechange of energy of the inter- Card 1/2 The Negative Isotopic Effect in.the,Viscosity S/076/60/034/010/006/022 of the Deuterium Compounds B015/BO64 molecular interaction has.a greater effect upon the viscosity. The In- vestigations hitherto conducted (Ref. 5) always led to,an increase ir viscosity in the isotopic exchange. The present paper shows that isotopic exchange may also bring about a decrease in viscosity. In chloroform and, . tetrabromo methane the hydrogen was exchanged for deuterium and an, increase in viscosity was found, i.e.,.in contrast to the cases hitherto investigated a negative isotopic effect was observed. The decrease in viscosity amounted to approximately I%- in both substances, which is five times the error of me asurement, and.may thus be regarded as a reliable result. Thus, it was clearly proven by experiment that an_increase~in molecular weight due to the exchange of a light isotope.fora heavy one may affect an increase, but also a decrease in viscosity. Finally, .the author thanks A, I, Brodskiy, Corresponding Member of the AS USSR and, Professor A. Z. Golik for discussing the results. There are 2 tables and references: 7 Soviet And I US~' ASSOCIATIONi Cor1kovskiy gosudarstvennyy universitet im, N.I~Lobe.Aevskogo (Gorlkiy State University imeni N. 1. Lobachevskly) SUBMITTED" December 6, 1958 Card 2/2 -,5/020/63/149/002/016/028 Thermochomiatry of tetraethyl germanium B117/~186 The following averaged valuen.were found: comb. H Go] - 1515.64.1.5 kcal/mole 2 5 4 comb. C H ) Ge Ge(Yl ) 1 + 2321.0-2i0 kcal/mole. 2 5 3 5 3 the Standard enthalpies-of formation, evaporation and atomization for nd gaseous phase of the compounds studied were calculated from.th liquid a J4, d fro 'datl an M combustion- and evaporation enthajpies of theJiquids studied, ,.; published on the formation enthalpy' of the , combustion products!, form*- evap- Subatance U form. 6natpmo' -AH g. e G 50-3tl-5 10 + 6 "i' 2 .5 4 -2.0,_' , Ge-Ge(C H 92.9 1,4,; 9- 5 (C 25 3 2 5 3 + -10 - ' t~ ': t~ "'~- 1 ~ - Prom:the atomization enthalpy and mean':- bond energies of the C-C and C H, bonds the:averaged values of bond energy of Ge-GAn--E tGo were found to 4 Card, I.B.* RAZIIVAYEV, Thermochem.-Istry of tetraethylsillicon and he,~setlr.71dlsil lcon. rt 'L -1:108 D oirl. AV 535SR 15~ no.r-.1106 'Irs4 lns!,it.at khimil, pri Gor*kovskom Uc;.qud, E-,M~ .1 Uj, e te 10, ~sn l, A NIPPON- L 1646-66 W(m)/FN(c)/kdP(j)/JETc(m) RpL *I/al/RM iACCESSION NR: AP5021427 UR/0076/65/039/008/2076/2077,~ 541.11 J3, AUTHOR: Tellnoy, V. I.; Rabinovich, Ld-B. 16 !,TITLE: Heats of formation of tetramethyl and tetraethyl compounds of elements'in igroup IVof the periodic system 1965, 2076-2077 ISOUP2E: Zhurnal fizicheskoy kt!Amii, v. 39i no. 8 I - I anidj co~-, TOPIC TAGS: tin organic ompound.' silicon organi compound, germanium o: ;pound, lead ond energy' d, heat of formation, heat,-of atomization, b i organic compoun ) Eli :ABSTRACT! To find 1he heats of formation of the compounds (CH )4El'and (C of comp2H5 where El = Si, Ge, Sn, and Pb, use- was made.of a graphical me?hod arative ;calculation proposed by M. Kh..Karapettyants (Zh. fiz. khimii, 30,593, 1956) and. ibased on the fact that form form AH A +.BAH where AH form and AH form are the heats of formation in series I'and-Il ofre''lated I Ii I ~ serie -: 't,- ~ icompounds under identical conditions. This linear relation applies-to the' S- qqrd L 1646-66 ACCESSION NR: AP5021427 ,studied, (Cu.) El and (C H El, because in each of them the members of the series 2 5 4 ~differ in the K atoms, which are electronic analogs, andlor both series these- atoms are the same, whereas the other parts of the molecules are related radicals. -Fig. 1 of the Enclosure shows graphs of aform f(AHform fo* s r the gaseou (CH3)4E1 (CiH5)4E1 .and liquid phase under standard conditions, where El C, Si, Ge, Sn, and,Pb. The ~AHfOrm values for the tetraethyl compounds of.these elements were-borrowed from ex-_ perimental studies. Within the.limits.of error, the heats of formation of (CH ) Si 30~ znd (CH3)40e, as well as (C2HS)4Si and (C2H5)4Ge arethe same., From the heats Iformation, the heats of atomization and the*average (thermochemical energies of:the :El-C bonds were obtained.. Orig. art. has., 1 fi gure, 1 table and I formula. 'ASSOCIATION: Nauchno-issledovatellskiy institut khimii Gortkovskogo universiteta iimeni N. I. Lobachevskogo (scientific Research Insfitute.of Chemistry, Gorkiy Uni_':.~ ,versity) -SUBMITTED: 24Jul64 ENCL: 01 SWCODEi. GC NO REF SOV: 006 OTHER: 005 Card 2 n 28456-66 aip (e) /M (M) AW(S) IT IJF(a) VdIRMI.M. ACC NR: AP60180.60 JP) SOURCE CODE: UR/0020166/168/003/0599/06 2 Sladkov, A AUTHOR: Rabinovich, I, B.; Lebedev, B. V:,; M.; Kudryavtsev..! Yu. P. ; Mar tynen g-orshak, V, V corresponding member Ali SSSR) 1 ORG., Corkiy. State University im. N. 1. Lobachevskiy (Gorlkovskiy gosudarstvenn~yy universitet); Institute of Heteroorganic Com~ounds, -46 Academy of Sciences SSSR (Institut eiementoorganicheskikh soyedLneniy Akademii nauk SSSR) TITLEs Carbon polymerl with incressed.heat capacity 02 SOURCE: AN SSSR. Doklady, v.-168,,no. 3, 19669 599-6 TOPIC TAGS: linear polymer, carbon polymer, chain polymer, polymer cross linking, carbyne, semiconducting polymer, heat capacity ABSTRACT., The heat capacity of synthesized carbynelhas been measured in,the 80-300K range to determine the structure ofjphis carbon P9 lymer in view of the increasing Interest In semlconductor~&nA thermal/ftro I-A . arties of the simplest linear chain Rolymer with coniugated the carbon polymer* Carbyne in the form of a black. fine-grain produ t,_ stable in air and containing 99.5% Cc wqs synthesized.by oxidation- Ylene copper, polydehydrocondensation of aqet Tin the presence of bivalent Heat capacity C measurements were carried out in helium atmosphere p Card 1/2 UDCs: 341.12 L, 28456-66 ACC NRt AP6018060 with 0.001* accuracy The C value was accurate to 0.5%. For the P purpose of comparlso;, CP was also measured In Acheson graphite, C-3 domestic graphite, and acetylen? black. Hpat capacity was found,to vary in the sequencel diamond/ -C &EALhLtelok acetylene black 4 carbyne. Heat capacity of all nine carbyne samples was significantly higher, than that of graphite, although different in each sample. This differenc in C from on& carbyne sample.to another was correlated with e p the different ratio of the chain to laidellar structure, i.e., with partial;fcrose-linkLng of carbon chains. The samples with highest C p were assumed to have a low degree of cross-linking, therefore to bo nearly linear carbon polymers, since the value of n in the formula C - AT11 was nearly 1 for these samples. The n value for.other samples p was 1#2-1.5. Therefore, itwas concluded that the products synthe- sized as described were different from graphite and had a lamellar- chain structure. Orig. art. hast 2 figures and .2 tables. [JK] SUB CODE: 07/ SUBH DATEi 280ct65/: REP: 012/ OTH REP: 007 ATD PRESS36-aa,5_ Card 2/2"wzc_%" ACC . N% _LTJ ljp.(C) Dl~jqZq,,~ 610 )1 __ ---6[ SOURCE CODEJ W[6o7 6616461667[f5W~ 7 AUTHOM-TelOpM, V.--I.1 Rabinovichy I* Be ORGI Scientific Research Institute of ChemistrYs Gortki_v State Unlvers!~y (Nauchno- isaledovatellakly insti khW pri Gor1kovskom gosuderetvennom univereltate) ;rtji~f TITLEs Thermochemistry f organic compounds of.silicong german and tin SOURCEt Zhurnal fixicheskay khtnti, v. 40, no. 7, 19016 s, 1556-1563 TOPIC TAGSt organog ermanium compound, organosilicon compoundr organotin compound, heat of combustion# heat of formation, bond energy ABSTRACTS The heats of combustion were measured calorimetrically for a series.of alkyl and some phenol compounds.of silicong gormaniump and tinp including compounds .whose molecules contain two atoms of these elements boundto each other. The com- i (C2Hq)uGo' C Go, ounds werel C"H Si ~02H 5)6S1 (C6H5)4Si .1 10, (CH))4Sn r ~H,4 n~S,4C 6 H5 ) S n ~ C CZH~Vn, (C" (C,H5)jSn0C0C6H 8H3YOCOC05. The . 5tto 21, 4 v 6H ) 5 heat of the reac n between hexae11,hy-l3X:2;nd benz6yl per6oxrldpe, associated with the .formation of-triethyltin 'k---+mAwas measured calorimetrically and calculated from the heats of formation of the "ag;nts. The heats of formation and average energies of the El-C, 91-E1 and E1-0 bonds were calculated for the indicated compounds. The data show.that in the series Si,, Go, Snq the average energies of EI-C and EI-El bonds in.the allyl compounds decrease with Increasing atomic weight of the elements, anct Card 112 UDC 1 541 e1 I ISHCHUX, I.A., inzh.; RkRINOVICH,.,.I.F.,-.inzh. ISHCHUX, I.A., inzh.,- RABIIIOVICH, I.F., inzh. I, - , , '' I - I/ "\J ", V I I- hr 1; i,~, , Tf?C,,-,-fTI--.'lfL7, V. i",. - Fhuciozhnik i, CF(II-KI, V. b. - Kand. Tekh. 1"auk, Axkh., KOVA, J. S. - Arkh., BUYAll-N, Yu. P. - In7h., BY-.-'.0V5KlY, C!. L. 'OTIW:'~IY, IM. P. Arkh., (Rukovoditelltemy) Kand. lxkhitektur-,r, ILA?, Kand. Arkhitektury, RABIEOVICINI 1. L. Arkh., C.Mqij-(.V 9, L. Ark1h., ANIT-REY-EVSKITY, 11. Frnd Tell-ifin. ll'auk institut suroitle'no.v tekhni-ili I~kademii -irkhiteltijry T)o oborudovaniyu i Adelke kvartir rmo--'oeta-,hrIykh zhilekh dorriov v P.OSkVE (Allbom) Pn.-c 67 SO: Coll;r!cl-ion of Annntntions of Scientific Reae;;roh Work On CMstnicti-on, =MPLII-t--ll-in 1950. Mo-!cow, 10,51 (Gonlometry) KISELIVICH. law Nikelayerich.; RABINOVICH, Isido&. L'yovich,; ACBSHKOV, A.?., red.; SVIRDWY. (Development of standard planning in 2ultiatery housing construction; based on examples in Kier. N14e, Stalingrad, Zapororhlyo, and Nagaltogersk] 316switio tipizatell y mmagootoshnom zbiltshchnom strettolletvo; no primerakh 110TO,. Minake, Stalingraft. Zaperosh' is I Nagnitogersks. Moskva, Gen. izd-ve lit-ry p# stroit.. arkhit. i strait. materialam. 1958. 154 P. (MIRA 11:11) (Aaartal*nt houses) 24(0); 5(4); 6(2) PHASE I BOOK EXPLOITATION SCV/2215 Vaesoyuznyy nauehno-lasledovatel'Skly Ins titUt MotrO10911 imtnt D.I. nondeleyeva Roreraty nauchn, lssledoVatel I skikh robot; SboMik go. 2 (Scientifig Research Abs-eacts; Collection or Articles, Kr 2) Moscow. Standartaiz, 1958. 139 P. 1*000 copies printed. Additional Sponsoring Agencys USSR. Xomitez standartov war I liaoritellnykh priborov.. 3d.t S. V. ReshotLnu; Tech. Ed.: M. A. Kondratkyova. PURPOSE: These reports are intended for scientists. researchers, and engineers engaged In developing standards, mdafiUrtap and Sagom for the various Industries. COVERAGE: The volume contains 12B reports on atAndards or measure- sent and control. The reports were prepared by scientists of institutes of the KomItet standartov, mar I lzmerital4nykh priborov pri Sovate Ministrov SSSR (Commission on Standards, Mossureop and Measuring Instruments under the USSR Council or Ministers). The Participating institutes arej VKIIM Vaesoyuznyy nauchno-inaledovacel'skly metrologil Iment D.J. Mendeleyeva (All-Union Scientific Research Institute at met- rology lamni D.I..Mandelelmv) in Leningrad; Sverdlovsk branch or this Institute; VMIIK - Vseso)ruznyy nauchno-insledovatellsk.-y Institut Komiteta stand4rtov, mar I I=erltellnykh prl~crov (All-Union Scientific Research Institute or the Commission an Standards, Measures, and Measuring instruments), created from RGIRIP - Wookovskly gasudarstyennyry inatitut nor i 13marltal-nykh prlborov (Moscow State institute of Measures and Measuring Instruments) October 1, 1955; V);IIFMI Voesoyuznyy nauchno-imeledavatellakly in3titut ftziko-takhrij- chookikh I radiotakhnithe3kikh Inmerenly (All-Union Scientific ::::arch Institute or Physicotechnical and Radio-anglneering I i uremen to) in Ploacow; Kh0IKI? - Khtr kovokly gosudaretvennry Inatitut mar I LzmeritolInykh priborov (Kharlkov State Institute t of Measures and Measuring Instruments); and NOINIP - Novosi. blrakly gosudArstvonyy Institut nor I lzmerltej~nykh priborov (Novosibirsk State Institute of Measures and Measuring Instru- No personalities are mentioned. There are no reference 4. Studying a Screw Pair 14 and 1j.B__ZA 3imkin,_qj_ (KhGIKIP). Measuring the Tooth Profile of Large- -aj~er Reduction Gears 15 31sk1n, O.S., and T T_ R,bl-M& (-GM?). Investig:ting In- k struments and Methods for Measuring Elements of Worm 0 are 16 Ommolovskayas Ye.P., and B.31,_Davydav__(MG1KIP). Comparative Rating or Probe and Contactless Gages ror Measuring Surface ' Finish I i Jogo x1- DAvydov.oV.P_KuMo4enko_ and T.3-JA qUna 1~1 Y-A TO ;, 0 -a 1, . volopi. oth d for Testing Surfac Finish Swsples 1 , and Instruments far Surface Finish Quality Control (VNIIN). Making Improved Surface Finish Test 3amples I Ye. (NGIKX?). Developina Methods and Means of ~ _ k0~ ffi' I r d 7. , I:, ;-;V-, C: ~ -L.-. - a PAB11:0VICH. 1.1k%; IKIUMEK, Ya.Ya. (1kaunieks, J.], kand. fiz.- m~ a t. Auchn. r,~d.; TEYTELIBAUM, A., red. nauk, n- [Watching over precision; pages from the life and activity of F.I.Blumbalh] Ila strazhe tochnosti; stranitsy iz zhiz- ni i deiatellnosti F.I.Blumbakha. Riga, Latviiskoe gos. izd-vo, 1965. 81 Po (I-1 IRA 18: 5) 1. Direktor Astrofizicheskoy laboratorii All Latviyskoy SSR (for Ikauniyek). MARKMAN, A.A.; MAUZWIYAN, G.M.,, kand. biolog. nauk; KARYAN, A.A., aspirant; SRARAFUTDINOV, Sh.A.; RASULOV, F.K.; SVANIDZE, N.V., starshiy nauchnyy sotrudnik starshiy nauchnyy sotrudnik; DERYABIN, V.I. , SU iy hauchnyy sotrudnik, SHEVTSCIV, S.I.v starshly nauchnyy sotrudnik (TSelJnnyy kray) From the practices in the use of poisonous chemicals. Zashch'Lftat'. ot vred. i bol. 9 no.9:21-23 164. (MIRA 170-1) 1. Armyanskiy institut zemledeliya (for Markosyan, Mardzhanyan, Karyan). 2. Sredneaziatskiy institut zashchity rasteniy (for Shara- futdinov, Rasu:Lov)o 3. Zakavkazskaya opytnaya stantsiya Vsesoyuz- nogo nauebiio-issledovatellskogo instituta lekarstvannykh i aroma- ticheskikh rasteniy (for Svanidze, Rabinovich). 4. Zaviduyushchiy otdelom zashchity rasteniy Samarkandskoy opytnoy stantsii (for Deryabin). 5. Samarkandskaya opytnaya stantsiya (for Suleymanov). Pribor dlya mekhanicheskogo resheniya sistemy 1-ineynykh uravneniy.. Ves'-n. voyen.-inz,h. Akad., Sb. po stroitelln. mekbanike, 1 (1934), 137-160. SO: Mathe"natics In the USSR, 1917-1947 edited by Kurosh, A.G., A.I.P Markushevich, Rashevskly, P.K. K)scow-Leningrad, 1948 artis 4 A , / / I . -~, / . 6 1/ 1 1 , - .1 *~~.-,- !::-~ V i 'V;;, : . I . U3SA/Mectricity Inchiction K'otors May 5 2 Machiner-f "Increasing the Power Pactor at X~nterprises of theFlour Millint,, Industry," Engr ~A. 14. Orzhekhovskiy, Plain Admin for Prodw--tion of 'Flour and Meal, -&ngr-S. G_Znma, Tilline Combine imeni Tsyurupa, and Zn& I. M. Rabinovich, Milling Combine No 3 ."Elektrichestvo" No 5, PP 57-59 -Discusses e)q)erience of milling combines No 1 at Tbilisi, No and Combine imeni Tsyurupp. (latte-, 2 in Moscow) in s~,nchronizinE centralized transmission drive of roller wilis and other milling machines and mechanisms. Powerfactor efficiency of motors were increased. Refers to use of selenium synchronizing units VSWI-IrTO/525 produced by "KIP" Plant of Rlin of Petroleum Industry. Submitted 17 Sep,51 P.'~, k-~OT52 I I C-1 Ic' ti, I- VI PHASE I TREASURE ISLAND BIBLIOGRAPHICAL REPORT AID 576 - I BOOK Call No.: AP650592 Author: RABINOVICH, I. M., Corr. Mem., Academy of Sciences, Doc. of Tech. Sci., Prof. Full Title: COURSE OF STRUCTURAL MECHANICS OF SYSTEMS OF BARS. PART Ii STATICALLY UNDETERMINED SYSTEMS. 2nd ed., rev. Transliterated Title: Kura stroitellnoy mekhaniki sterzhnevykh sistem. Chast' II: Staticheaki neopredellmyye siatemy. Izd. 2-e, perer. PUBLISHING DATA Originating Agency: None Publishing House: State Publishing.House of Structural and Architec- tural Literature Date; 1954, No. PP.: 544 No. of copies: 250000 EditOrial Staff. -Scl. Editor:, Snitko, 1. K., Kand. of Tech. Sci. Appraisers: BezukhovJ, N. I. and Kiselev,.V. A., Profs., Doctors of Technical Science PURPOSE: This is a textbook approved:by the Ministry of Higher Education for technical institutes and it may also be used by construction engineers asa handbook., 1/2 Kurs.stroltellnoy mekhaniki sterzhnevykh sistem. AID 576 1 Chas,t' II: Staticheski neopredelimyye sistemy. Izd. 2-e, perer. TEXT DATA Coverage: This book contains materials conforming with the teaching program of the course of structural mechanics (statically undeter- mined systems) in construction technical institutes. Some other materials have been added which go beyond the scope of the course in order to allow a deeper understanding of the whole problem. As a supplement to the computation of the systems of bars the princi- ples for the computation of retaining walls have been worked out. Most chapters are provided with a historical outline and bibliography. No. of References: A large number of references appear in footnotes Facilities: A large number of Russian scientists are mentioned.in the text. 2/2 i d p --s t-':ing into on of r ob, 1 em c, f laf; f v r t call T- "Ces of is r-rescrited. T*-e etiic-d s c c*ia4 n Ca:-,rc--~ed o f T v, ~~,u Uaol de I IVO strloul.-' 6at:t on f c s an fcr;,..~ of Cree -jib- f L i fol- .,jlU, C) 1, 01 1 t 0 r~ . 9 5 L SOV/124-58 A-4507 Translatiun from: Referativnyy zhurnal,- Mckhanika, 1958, Nr 4, p120 (USSR) AuTFlOR- Rabinovich, 1. M. TITLE- The Geometric Representation of the Motion of a Damped Elastic System With One Degree of Freedom (Geomet riche skoye predstavleniye dvizheniya uprugoy sistemysodnoy, stepen' YLI svobody s uchetom zatukhaniya) PERIODICAL: V sb.: Issledovaniya po teorii sooruzheniy. Nr. 6. Moscow- Gos. izd7-vo lit. po str-vu i arkhitekt. 1954, pp 39 -44 ABSTRACT: The author of this work has previously presented a geometrical synthesis which gives a representation of all the characteristics. of the motio.n,,of an elastic system with one degree of freedom under the action of an arbitrary disturbing force (Vestn. Voyenno-- inzh. akad. , 1937, Nr 20). In the paper under review the method is expanded to.inclu,de the.action of forces of viscous resistance. Another version of the generalized use.of this method for the case in question is offered by V. 1. Gofman (V sb. : Issledovaniya po teorii sooruzheniy. Nr. .7. Moscow, Gos. izd-vo lit. ~ pIo str- vu i arkhitekt. , 1957). Card 1/1 1. Vibration---~Iotion 2. Nathematics Ya. G, Pano% ko- RABLUOUCII, 19aakMoi.seyovilch.- SNITKO, I.K., kandidat takhnicheakikh nauk, nauchnyy redaktor; YAGOROVA, N.O.. redaktor Izdatel'stva; PIRSON, M.N.. tekhnicheskiy redektor [Principles of structural mechanics UL bar framework systems] 04novy, stroitalgaoi mekhaniki sterzhnevykh sistem. Izd. 2-oe. parer. Koskva, Gas. izd-vo lit-ry po strait. i arichitakture. 1936. 453 P. (NLRA 10:2) 1. Chlen-korrespondent Mcademii nauk SSSR, -toystvitellnyy chlen Akademii stroitel'stva i arkhitektury SSSR. (for Babinovich) (Structures. Theory of) RABINOVICII, -Isaak Moiaeyevich, red.; TUMARKIN, D.M., lnzh.,red.lzdRtel'stva; BORODMA, I.S., red.izdatelistva; SLIKINA, 'E.M., tekhn.red. SOV/124-58-2 ???7 Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 2. p 102 (USSR) AUTHOR: Rabinovich, I. M. TITLE: Graphic Determination of the Fixed Points (Relative to Moments ard Angles ) for Continuous variable Beams (Graficheskoye opredele- niye momentnykh i uglovykh fokusov dlya nerazreznoy balki peremen-, nogo secheniya) PERIODICAL: V sb. Issledovaniya po teorii sooruzhenly. Nr 7. Moscow, Gosstroyizdat, 1957, pp 593-596 ABSTRACT: . The author presents a fairly simple version.of the graphic, construc- tion of the, fixed point of a succeeding span based on the known position of the fixed point of the span preceding it. As a first step the author constructs the curves of the curvatures M/EI for the individual span of the beam due to unit support moments, and computes the position, of the area centers of these curves and the angles of rotation at the supports. 1. K.~ Snitko Card I/I SOV/124 -58-A 409 Translation from: Referati,vnyy zhurnal, Mekh.an:ka .1958, Nr4, p 143JUSSR) AUTHOR: Rabinovich, I. M. TITLE: On a Problem of the Theory of Trusses (Ob odnoy 7adache teorii ferm) PERIODICAL: V sb. Issledovaniya po teorii sooruzheniv. Nr 7. Moscow, Gosstroyizdat, 1957, pp 607.-615 ABSTRACT: It is noted that.in the design of a truss' having rvi members a a un- wherein n members are indispensable nd (m-n) re red dant, it is always necessarv to make an arbitrary assumption 'or m parameters., Thus, for a slat ically--dete rminate truss the stresses in all the mrn members are assumed. For the design of a statically- indeterminate truss by the method of forces the cross-sectional areas of aWthe m, members are assumed; for the design by the assumed-stress method.. it is the stresses (or the elongations) inthe n indispensable members and the cross sections (or the forces) in the.(m-n) redundant members that are assumed. In all these caie5 the Card 1/2 displacement of the joints becomes known as a result of the SOV/124 58 4-4679 'On a Problem of,the Theory of Trusses calculations, and, therefore, arational control ove r the rigidity of the truss is difficult, Such a control, which is -necessary for. the desicyn for another limiting load condition and for dynamic-load calculations, is poss-We by means of.a proposed "method of given stresses and displacements,".. In this method the number of assumed parameters includes- a) p