SCIENTIFIC ABSTRACT PROSTEJOVSKY, J. - PROSTOV, AL.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001343310018-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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"iz zhurmal 14 n).W:796-71fi-'~ 164.
7-hysics of Charl-fil iniversity,

KAPALIN. Vle; PHDKOPDC, M.; PROSTIM.
Method for following growth in schoolchildren. Cook. pediat.
12 no.5-6:420-430 M&Y-Juno 57.
1. Ustay hygiony, Odbor hyglarq skolni, Praha Ustav organisace
sdrav. ZU, Praha.
(GROWTH. in Inf. & child
method of following growth in preschool & schoolchild.
(CS))

GeV,; p!RWTBVA Halo
'49orbed bY ths 109T@9 of
x1emtjon of rWO&c%jvq phos*Orms a 2.-397-3" -11 256.
nts. Soklm All SSSR log noo (KM 9:10)
lering Oftt Plft
Gorlkogoo SverdILOvske
univer~it~t isent A.M.
1. Uralogkiy gosudarstWOW47
edstxwleno skadesik(m A-L- XuPeanuv7so 1010gy)
pr (Ovali) (ILsai0ftetivo tvacers) (Botmw-ftys

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I- I L -11- K F a
is? AO~~L!R cvatfi*
t! S"P" I
A aw synthilais of m C am blib"I PrAcnik.
n
ir x"; is. I-201i lingush
(Chrm. 1114t.. Zureb). Th
1
iJ
f
i adiltv) at that Irtup. drop fly droll with Itiryn's
3
l
C
c ae
.
M1119. nuargW
M IL40).- rhr known molwds o
at
e'
for they are either
d%
l di
ll
(
I nio
i.
lIsSe In ethrr. the inixt all,,wed t,- oinja 2 hr..
-
l rooin lem
and the
;
th
Ii
l
lag
roin Wvrra
a
er
ac
.
j %u
(
(lute -conjujulog. doe to a long efirs of Intrtructdiates r
tuovc,
p..
errs
.v evApti. iln.
n twt
I
i
,rr J vartmin 4toalf,out /&.( divoilginal W"Ij to Kt%e N 9.1.
fle"VWy. or tbc-y give it twoduct of in'tillicient purity or
1e
ed h
r
6
im
Th
d
d
l or. 001"e') cryst. IV as light yrflow lAutcIlAx. fit. (12 4 (dried
b
ulli
9f th
i
i
ii
id b a' see
e
s
eve
e
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e proce
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in low yield.
p e retrut
ng o
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flor
y p
qu
ysuction). IV(S-9g.~ ;

gi~" a satisfactory frivid. and rcquirct a very short time
h
ZI
io 1:11) ce. aln. RtOll. heated to W-70'. tn-ated with 4
f
)
f =
00
e and.
T
for only a small Igo. of Jet)* are Involved. s o
ew ilroj)
AM
(Auttwit4rd in EMU), the 1306
Clip\v required is very %flu'll- hirified pWmilk arld ,
inixt, Ir slatullog a few fight. at the finne tritil'. unta
(11) wtvft as starting niater4d: It 14 Converted With VY111181iQU Of 0 has Cfacd, 111(ofe lgj() 1200
-.%;fjcli into pahnitoyll chloride (all and the lattrrCumbined the mixt. rcaux"i M fulu., -baken fifth saive C, filter"j, ~96
with ClIsS, to Kivc I-diazo-2-heptittlecautme (IV), which and the &k. di%td, oil, gim V, a colorless W, b,, 208-12',
with AxzO xit"- life Ut ester (Y) of 1. then sapond. to frm soon cr"tg. to 7A it. colorless ptitrittv. in. 2sc; the whole I**
1. Pure 11, tn. &I ' (Coln, samples m. Ill "). was prepd. unit. of V obliduej is ..jrqnd. by rrfbjjinK L hr. with (I Z. 2are
from rom. sttarin whkh was -terilied with ElOll and Koll in 31) cc. LO' EfOll. rxxLring the liquid into 4(Kj cc,
thertude PfcAuct subjected to fr3etiomil alit". through a %arm i-R)*) 11,0 with stirricur. and acidifying with dd- 1-040

culumn of high I,.1wrr. I%Irc 11 (10 ff~) is heated with 5
-110. Crude I plies. out as colo,"s IAjmffL,.dfitd
by
i 64*
ve, ~Ocl' I fir. at 74" on an oil bath, the excess SOCI, is tic-lion and rccrystd. front N)% Mcoll, in. (L"; yield,
_C1,14.1. jx tv..wa at 701. and the residue (contil. M? dis- tl.-' g. Cakd. on the basis u( It coniximed. the overaff j zo
olv.d in lo.v. anhyd. ether. The soln. is then cooled to yield it 597- IS reference., C. S. ;hapiro
KATIOO
b u 11 Ice MI tr it 10 'i a 'i 1, 5i PC Of a it n
0 0 0 0 0 0 0 0 * a 0 0 0 0 0 0
:1660600 0 0 0 & 0 0 0 41 0 0 000 i ~16
1
All A
ft-- Wee
x a I or a I a a 3 0 V
0 0 0 0 0 0 0 0 a 0 o 0 o o 9)
AA.S.JL 0 0 0466060 00 4 so 0

411 IP V W W
t h 10 it u 13 U Is IV a 41 U IJ W Due
L-MA %
JA -.4
totc 0,10, A-b OSOPINNIs
of
*9 A Illss benslap of loyd"O. U. with HCI(I:I). the exerm Hall rema"d by 41cam ditto
U. pro"C"Alt and I., Filipovi~ the remaining reaction II)Ixt- BIWited with sq. NsOff.
.00
ArUv-Ko~w-i is, a-v(itw) (in French, 0); cf. Ruidle and the liberated how estd. with CIfCIs the flit. dried
P mAvent trysixf., and the " ditd. is "me"
.. Cwvtij mod. i bi-I. (Atle Mod. Dial. Ooo)ka) 3, 86 K-CO,. the 1 hle
(1945 5-Diesbylpy"ne (1) was syntbestsed by P. The Ist fraction as discarded as It ewshled of 11. The
; .00
~ 2 rd as a yvilowish tAl,
sued both 2nd fraction, cents. in, . eun.-t
'the Ist if. by 2 Indeptailtut nietbods.
00 & in H W" bon IM-20 or bw 210', which fait yellow crystals.
00 zcoodeased with ' - e t In. 57.61 (ear.). yield, 10 If. (48%). 111 (33.4 11.) In 3W
B i It 2 1 14 22'. (DI)
11 W the latt. d,'Iid*t. -2-p basylic cc. sectoue was cooled with an kt-:,;&Cl fretting mist.
004 The Rt ester 05,01t, under'"'fot a Claben (the temp. should be maintained between 0 and &* during
00 1 Ift with EtOAc to give " eder of it 04teto the reaction) and t$3 it. powd. KMuO. added In %niall
11 (no hollated) wbkb was subjected to a keto portions in the course or an hr. with stining. The see
00 lZavasse, givins 2-aMyI4-dhyfP7Ti:CJV1 , Welff- Its- M. which formed was dried by suction. washed
00 aKistmer reduction yielded pure I I I'l.(8) In acrione, finely around. and boiled 3 times with water
y
0
0
karboxylic (using about IN) cc. lfO each time). The sq. filtrate
M
11n was OxJdiud to the corresponding 2. W"
?'&rid from which be di-Et eAer (VU) was prepd. VI addified with dil. HCI(I: 1) and the pl)td. HzOkl falmut coo
0
t1w-, also condextard with EtOAe and the corresponding I I g.) moored by pulling off C - sulwMatant duid with
0
's
0
0
dir4ter of a diketo add subjected to ketockavalt as before. suction. The latter was eztd. with fiber to remove the
'0
H This cove 2.8-discetylpyridine (M, ideatillad at the last tracts of W011. The sq. layer was heated to boiling
Idibirdra"ve 111). The latter was red dirtedy to I and 14 g. CuCO~ added In small portions wtitb stiffing.
f -1600
by the Wolff Kishner Procedure. These synthem show U ng, 14.5 It. blui It let crystals t IN Ad
0
that the ;;;~ofreactlOwetnpk1vd bore isapplicable both p td. Into rv 1. 1 suspended in 50 cc. W water Zoo
~4r.
H as introdu to ppt. all the Cu out as a
to morm- &W dicarboxylic acids of the pyridim series. It coo
J'Tbe Intermediate products prVd. were identi sutfide. A lye C was odded, th. fill . and the
d1. fied as their
0
sells. the final product as a picrate in both the A sual 0 clear, coloring boln. evapd. im vorm& it) r" to give zoo
1. Mixing the 2 picrittes did not lowe the M.P. 3.8 C. IV, lustrous colorless needles from beptant, Tn. I W.
0
A2 g. freshly distd. BtH, and 62 g. AvvO vs fleating 113 mg. finely ground IV with a few mg. powd. Cu
repusm W4 am t be dark bro" liquid obtained addified in a mirrodask according to Schmitt-CoutclIeu (CArm.
A SCULLUAGiCAL LITIRAILsIt too
414- ago
0 US AV 00 is;
0
0 0 0 0 it X 0
0
0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 * 0 0 00 0 0
0 0 a 0 0 0 0 Goes
000.0 0 0.
0 0 . 0 0 0
0 0 0 0 0 0 0 0 .0 00 0 00 0 0 0 00 0 * 0000 0 00 0 46 4P 0 0

PROSTENIK, 14.
Thcoslavis. (430)
Technology
Homolognom of pyridins- 341 report. The reduction of 2-acetyl-Tpidine to
2-9thyl pyridine. p. 10, ArhIv Za Ismiju, Vol. 18, no. 1-4, 1946.
Ikel IkroRM Accessions List, Library of Congress, Vol. 1, no. 14, Dec. 1952.
UNCLASSIVIED.

40
prite
F111101vit 11'rity. ZOIN!
17.5 #10N lot P1146h, Im. ;.1.
I ;
sma% I tlpt
Or"Irlilly
1011sipfrild
2 91kPli6(-4tifK1t,. J,1 j sjj,f (~~. of this, litethill and Atmi
4, All
I "'1 0 Colld"UAlitll 14 11411-
It-Irs with it) liviiaMir (1111-4'~
Nlip we" $A,
'Qth del ifilausel. Nlffck) At :Nji?
:00. Irs cmiram to Alloll 4 tilmeal in the Chichiltilbl" jsrts~
crilluirt. Stith Sri sksurd the rair tit rructitmi. Regmeratim,
of The cilicAlytic wlixity .4 lh~ S4,h %-% Acrossliph"I bv
pausims Oak I-S min. tbrattich thr Ism tuhr After rrmoval ig
111C 11111111it volAtik cumlsonirtito himn jibout 2111(l cr. of
denumle. the m-Sidual mixt. of tcTtLry Ituw, ( -
'llec.)Wwwried
9-W WHI ml fractiolulef to virl-I 1, 1) 1.1110. 1" fl.. 121
seLdively, miAll of
WAY01paw Oll, 1. --w, '111e 1, J!'.
-A- till"4109d in 10011 MINI A ifts!M~I hy
with Pkilic seat in Ale. I Pwruk, ml livrdls~, Itl6til,'
I 110M. MAO, I was himerated from thic pit rate by treat.
jag W*h k0ft UPI th"S. with mrain. ("hirl slits td I
Steil the 0110kimam, priwFli. In. 1131 ask. FtOAO.aud the
JI'vpAdmak, in. 140' (dertmispaA 111 1pittelf. p6les, In,
I-'n-S*0Mn FI(JII?I. W-44 ilfMtiC'Al With It drsirrilwd by
Visichilsolisix if, Rio it. J'kyt,-j.'ArjMp..S,*, J7. JJIAK 1 ill)
1111011 low %U1$ "Civ rowdro-i (ptr2w Is get *I 4134m. Issit
t.1111 i tx*mrr virld .'I t.111AFY 1~ I J111111 It W~r~
-howhillthm Al(tiliscmi arA,l tw "KvT.4.'lly CPLU-"l fit
I -
:1.5 g, .1iji..110 in the pretence cJ 3 g. NA in :21) tv,
Ain. 111C. by the Wolff-KMlitt ln(10311111! CAVT :.' a :A-
Ih.
dewrth
1,mig yvitow tit. 116" (froin KIOAO; Pki'01011141k.
at
)vllow p"Wim. in. 3W 01mmilisn.) (froill EWAO; and
ItYPA611 lartit y0tow rhointiLsimtrorss. m. 147' (decornpa-i
(frtun Hl'O'Aci. III (JA x.) and 5 cc. AcO relfulied 40 hiss.
with 5 cc. Ac,.,O gave 2 IS X. Zkdidyr#4~14WAY47ridi-
(IV), yelfm nev-d". tit. M-4' (from PtOll); p4tpak. Yeilir,
is,. (from MAO. The voin. of
IV in EtOlf ll~ml .4 ldukh-violct Ituarewence. JkNdk*
mid (V) was prel-1. by dissimilvint
I r) K. IV ill 20 ev. 'NIO'CO Ati'laddinK 30.) it poss"l. Kmno.
i.) mit.11 stilb viss$.I '1111ing &I W rise lwmltwt
f..t""l . 144-11
ttah M) ".. *41et. tillcl-l' the ppt. Itt'lled takv liture in th.
~Sttc 111.4111fter. she "Hubils"I filtral" acidili"I with IICI
(1: 1), cistd, with ether to Funove ROOM, arml the sq. Ly"
-pd.. bailed And treated With Cd 4%.11DO-ClAts' (1 19.); UPWI
rimilins, lht Cu gait of V furinvil Ithir cry'l.410. V wa,
111jrMted flont thj* Mit by fifitt. the -41411. W Ith Ill$. CrUde
V wjO4 siriwboxylainj with imml. Cis ill -11 ImAntAn AAA to
view 1; the pictAir "A$ Went "I with I vil-Ime oftained by
mhurre (A) And (It). C_ .14 Shapiro
/ir

e~h
SyMbegia of 1.3-filibcomor- and 1.3-discefoxy-2-aftanoturs.
Proitervilt (Univ. 7apeh). Arhrr Kem. 21, ]W-P 9
(M%XTM*Mn-suminary).-I.3-Dil)rotno- and 1,3-di.
acrioxy-2-alluumars were prr;xl. train iv-brorninated fati.v
ackf balides (1) which were converted. with Clfl%', in 111,0.
into the corresponding diazoketouc% (U). 11 with Mir
#Ave higb yiekis of 1.3-dibromfor-2-alkanones (111). which
can be regarded as hornalogs of (BrClfl)3CO. The Hr
atorns in III nieve replaced by AcO gratips try acetylatint tg
glacial AeOlf sunfension of AxOAc. All of the acrtavy la-
tones (IV) formed cryst. oximes anti semicarhazones.
The metimlif was general. since IV could be derivrd from
lostif-chahl homologs in The fatty acill series (r-- It
C10.
may befrossible bytbe abovir route to prep. dihydrosphing(j.-
-me anti its isonners, and attempts are now being tnvfe.
Patty airMs were brominated in the a-l"ition by the Ifell.
Volhard-;F~Iinsky ructhod. The reaction mist. was di,td.
to tolho and the product treated Willi SOCI, fur CS, :611.1
hi4her acids air with SA)Hrx for Cj& and lower acids it '
I vivid
1, 1 in ether were addetl druimise to Clfs.Nt it) c rr at
Ib
41 S* with coast. stirring. The mist. set aikle 2-3 fir', unit
the ether removed in racuo to yield 11. The crude 11 fruin
h-wer arlds, were liquiff and those frunt higher acids cr yst.
Crude If were dissolved or mentendell in xhicial AOM (211
ce.AcOllforthellfrom l0r.I)andfYic`r f(Br ulded
froji.
wise: a violent reaction with evalution gif N nceurred. ' The
r"t-li'lu "fill, W44 dild. with ffjO, anti life excess Iffir re.
intpred fly rdwhing with MilIC0,; Ill m-fol in the form ofan
Ml (C. < CO or as crystals (C. Z CO. The oil, were
extd. vrhb ether, and the est. th" over NA'SO, and diad.
TIw c"mals loore rearo4d. from 9070 MOIL The fallow-
flow, OU,
jug III 14CIC I)MI-1
,a.~, oil. b.. 934%
lk.,# M).-V; K-1. ji~~ 1.341bromo-!-Noll 97.3%
X.)rr Oil, he's 1
m. 3.5' (h-
.omiadritionar. in. 50.5' ((FOrn gd%
and 1)7 ric' I J-dibrow-i-22
g.) in 2,-, c. AcOif - biril-I Z, hr%,
i/, after I hr..). the
With paved. AKOAc (11. add"I ill the swt, Slain filter while
Agar anti the c%crw6 A11OAc resurived an a I gi.ciAl An-Oil.
waim. the pill. -~-1111 i,b a sinall unit- c
the filtrate and wAhings dild. with 11:0 to :1 linfr% the
or,girulv.ol and the acid neutgalited with solki NAI ICOI t-)
Is (C. >
Yi ';Cllow oils (C. < C11) or Yellow crypt"`
eld IV as over
Theods were extd. With ether. dried
C10- e cry% tystd. ffl)ln ti';'
., ;Koducts were rec
distil. Th I,. and oximes UTM Prept.
I-M)II. The wmicarbalot with 44
di.,~" ~ fitoll ~ud tFCAting. rt
,Vint IV it, t*1.1
WjujcaFjxUide-lfCI plus S~OAc. tic with M)%.111"Cl Id"
nixt. ill C.ilhL-r CA-e W;ls, allowed I
\;.oAc. The re-tiOll I n reffiStratt'l
in," temp. anti the
many bri. at ordi r FCC".,-
The Woducts in the fnwtn of glek-11 crystals W" 70.3% I.-T-
frig" 'I'lle I'Alowille IV wt:lc ptclxi.. 1111, colork-
dia'-floxy-j."ja Rome. th. IN 8'
14()*); 73 11147 F r1lo*
IPAII~.11 -1.'), Orm
I(* ,4rba:ane. enliffle" Pli*"-
y-z-hradr,tronar. PAY- Oil- hit
77.3% 1.3-stialtIOA I;N)*); 'o)%
,Ukxlc~. litisms, M.
ilo w* (jew"'bis- in. 390 (JeAvirarbaziolill. in
117% fixime, M- 21)mt 1141); .1nd MO-5,5 1,j-dis"r8`xJ`-2*
mlerartoxI. in. about NP (frOll! ""011)' . C. S. Stulpirn.

h559o
Z/055/62/012/012./0041/004
D2561L)308
i',U T H 03 Sicha, if., Vesel~, V., ctudniA-I,.a, J., k=
j,-gnd Novfik, M.
TITL'.~: Investigation of stationary and traveliW; striated
discharge in neon with local 11r excitation.
I OD I C i',,L Czechoslovak Journal. of 1-'hysics, v. 12, no.'121
1962, 919-929
Tk possibility was investigated of usirg; the dis-
turbance produced by a local 1W- field in systematic studies of sta-
tionary and traveliit striation of the discharge in inert gases. In
the method developed by the authors the MF.field interacted upon a
limited part of the positive column of A-d-c discharge oi-iginating
stationary and *traveling strata and striation waves. Discharge tubes
50 to 80 cra long were used applying across then, a voltage adjustable
C3
from 200 V to 3 kV. The discharge current was controlled and stabil-
ized with tiio pcntode tubes in series with the discharge tube. The
lurainous pattern of the discharge was observed visually and tubes
Card 113

Z/055/62/012/012/004/004
Investigation of stationary ... D256/ "308
could be moved -along and across the discharge tube by means of photo-
electronntultiplier. A toroidal resonator operating in the 40 cm
wavelength-band provided the local 11F excitation. A double structure
was observed in the statioitary strata differing both in shape and am-
plitud~e-;' the amplitude of onc rtructure against the other one increa-
sed uith increasing discharge current, but at the s=e time the sta-
tionary strata were independent of the znount of HF power absorbed
by the plasma. The striation waves were found- to originate in -the
region of the 11F excitation of the positive column. The resonance
frequency of the moving strata was investigated as a function of the
discharge current as well as the dependence of the wavelength upon
the frequency. The frequency of the, traveling strata in the stria-
tion wave and the resonance frequency of the -artificially produced
traveling strata were found to be equal within the accuracy of the
measurements. The pattern of the discharge could be controlled by
changing the modulation of the HF field. It was concluded that "the
possibility of employing the HF disturbance in the studies of stria-
tion in d-c discharges has been established. There are 7 figures
and I table.
Card 2/3

~/055/62/012,/OL2/004/004
Investigation of stationary D256P308
j=OCI.,TION: Lehratuhl ftir. Elektronik-und %!akui=physLk der Karla-
univerigitUt, Prag, (Department of Elcctr~uics and
Yacuu*m)Vhysics,.Qhar1ca University.9
5icha',','V,, Vesei~ I J. S,tudfii&d and J., Frost6 Ovaldy);
cho 1. A.d -t-
Thysilcalisches Inatitut der.-Tacheo
titute of Physics,.Czechoolovalc AS. 1?r")
Prag (Ins
04. NOVAIC)
MMITTEU:.. May 15 9' 1962-,
Card 3/3
0--m- w5., W-4 WWOMM

~z! -,!;e ~phirlgollpidez series. 1-S a
-T -rawenilc
U
Ilk Ig" ugust
11,qj
Cl 18, ~,!!AN05R~Ci u j 1 (115 g.) treated wit
9 131
, lid 5.,~,t g. rctj Pivel 9
17 J.1 r 1 '61CIII C1111rcoill
(1), in. 52.6% Adding drc 1W Cis i HBrCDC1 from 22.
Pw FT
g. I in 40 cc. ciller to CHIN, from 10.1 H.N.CONNIeM
1 at 01, keeping the mixt. 2 firs. at210, itnilevni;g. todrynesi,
give Ctil-131CUMCOCHNi, which, treated in 33 cc. AcOll
,with 10 cc. 66% F[Br, gives 75.6% Cij14X11BrC0C11,Br
(II), pri-m-i, M. 52-2.5*. Rrfluxing 3.34 1,. 11 with 5.0L&
11-1~lfme if, 26-E.-XwTrTn~ri.,
With NaFICOs, and extg. with ether give 3.32 g. brown oil
frorn which, on chromatOSTaphic purification, 1.4 g. Z,3-
Hacclaxy nec(lies, In. 56.5", is obtained.
-2-cclaftecanone,
U
1,34&B--0 arxlog (111), prvpd. with Ag0Bz in 38.8% yield,
ni. 72-3'. 1 lydrogenating I I g. III in 4(0 cc. MeOll ,iatd.
with Nit, 12 lirq. at Of)* ind 15W. 11ji. in the pre5ence of
Raney Ni gives 83% 2-cinina-1,3-dih3,droxyocladecame,
yellow resin lox-rdale, m. IN* (decompri.); tri-Ac deriv.,
~repd. with AcIO-C,11,N, needles, tn. 98-9% tri-Bz deriv.
IIV). nceillcr, tit. 1,10-7'; N-B.- deriv., prefid. by heating
350 nig. IV with 20 cc. IV KOFT-McOH 45 tnin, at,10% ni.
;1,1*1. RefluxIng 200 trig. 111, 50ing. HON11t, and 100mg.
NaOAc in 20 cc. MeOff 1' 2 firs., evapg. the inixt. in ractio
W drynes!;, taking tip tIv.- residue fit 11~0, extg. the soln.
with ether, and refluxing the oxime fortned 2 firs. with 200
rng. LIA1114 in 40 cc, ether give 35 ing. CILINCIA011)(711-
(AU[?)C111011 forufale in. 106" (clecortifin.)). flydro
gewiting 3.1.2 g. Ci%fhsClI(0Ac)C0ClI,0Ac fit IRY) cc.
McOlf satd. with N11-1, 6 firs. at 60' and 15M lbi. with'
Rancy Ni gives 21.5 g. Cl:lr2sclf(olr)cll(,Noll')Cll,olI
[oxalale, tit. 193' (decomplL.); fri-Ac deriu., tit. 02-3*;
N-Ac deriv., needles, tn. 125-C)']. F. E. Bratins

CO
12 r. NaOAc !it C-0-709 and refluxiiq the mixt. I hr give

*
.26
Go 50 'toll
t__glut.,,lnjc acij ill 30 CL a m 05%
n
ng
-4fter chro- ata-
.0.4~ (111, in. 76.5-R
S2% CEJ112COCIf. .
and 1.4 g. VI in 40 cc, M011 -,it(] cooling he
tnixt., giving
11
trafitie Purificatim-, Refluxing 31M g. 11 in abs. St0H
,
to;l it, h
F
ft) i
Tict ab
i
HONH
(t
1 I U1-2' -.it CT
nr phi- in.
X&) 1, . L( + )-~, ngsre L
s.
a
r
n "
ram
w
I
t I
0 g.
I
miri-131; the rrMilm' ulta iot" cm. 11,C).
d!StC. oil ttic r5tolf avollit'r f(cul 10,4, Wit. FlW l"Othit7- hqvor-
,
1 '

.
C.-Voll"101011
r-td cuX. with ether, give. 25% Cliffil - k -
1 -
r-'r 1
572 nia. v~ - ~45rw- (VIII), 'it 11.1~-V.
VIt xvith 31V N't,
d 2
8
C0
and Wi
WWI ethcr
ive
1
i
Frtrn the motbmx liqu- ,
l
1
g.
.
g
1,
78.4 7c Lr + ~Sphing ire (m), ni. FZ--6 *' fal "' 4.82, (C 3.7
. C),
of a wU-v rlattrial (IV), probably a mixt. of IT lmime amf tn. 100-30
-".9' (z 2AM6
C1103) id.-Ac deriv.
DI
OH 'md 20 cc.
1U. Reaucing IAM g. U in 90 cc. atk- Me .
,
,
CHCI,); N-Ac 07-8~, 1.1 12.Z7* (z 2.73-4)!
'
MCITiMs with 100 mg, PtQi in 0, cc, aty'. MCOH .
D ompti. oi VIII with Na-C Cs
r,(- ~lh~in~lne (X)
cc
03 giv

r1kc-'ed nli't'
9 hra. at atm. H pressure alid 20% inaking the ,
I S. in. 93-5"
e
-4.02' (c 3.04) Idi-"IC deriti., In.
11 at
alk. with 3 g. KOH, extg. with ether,and cancg. the washed
Ph)C11-011
CH(NffCH-
60
C
11
i
d d
h
t
d
i ,
101-3'. (a] IJ 221 (e 2.145); N-Ac der`v., tn. 97-8.5'.
er ex
ve
an
r
et
.
c
. g
jz
,l
%
a transition in cryst. fom at 67-8'.
tn, 72-4* with
M [fY111 11.74' (c 2.49)]. An Lquimelar mixt. ai M and X in.
1 11
'
.
,
cr with 1,12 g. Li-
Rdluxi"T 100 cc. abs. eth
-
i
,9 I~R-80.5
and shows no depression with racemic sphii-igine.
-
N hrq. gives S5'704Cjj1!uC11(Nff-)-
211ti
AMA"Iti 1
2 F. E. Brawls
C0j0jT~(DL-splltlngine)(VT-). glistening plates tn.794

11

TM blagollpides zwti&~ M Pro*atloa s
unk-weinert. D.-K-SU~ni, M. Proftemk
zanyo.- Yugoslavia), J. Urf, Chem- 054)_
d. C.A. 49, 173ki-o-Tribentoylsphincosine (1.1 ff.) in. 118-
20'. Is hydrogfazted.W.90,co. EtOll with 200 mg. Adams'.
PtOs catalyst 3.1irs. at, 24famintm. pressure, tht filtwd
sola. Is evapd. Jo Wcoo to-drynes3, the residue taken up itt
ether -and the washed (..NaHCO,, H,O) ether soln. evapd.,
jag 72A O;N-dicycloA=ano)4pAikSCm% (1), tn. 90-1%
Val 2U6 (e 2.3M; WC11). - Frout the aq. washlags
`cy4:Uxanccarboxylic~Acidj m. 20-30". Is Lqolated. Heat-
ia~ cc; M KOH-MeOff I fir. at~40* gives
3W mg. I with 15,
1
ia N-cyciahexaffoAphingind (H), ptatelets, M. U5-5-
10 . Refloring 250 mg. L wilb 5 g. 10% HSOj-MeOH 24
bra. gives 85.1% D.-sphingine (11.1), m. 84-5*. - Refluxing
ShnIlarly,W mg. It xvith;10% H.SOAfcoll gives 07% 111,'
w. 88-7% -5.V'& 3.14, CHCls). F. B. B.

72-
Tu 00
The reactilart' *-ph' thalimJ[doaild'
Of th su
WWtd soditimalonates.- , A method for the prepuRtIont off
-D. F
rd related Compounds; - Sunko
ilk (I iv. Zagrebb.-Yurrislavia I.
inctlind. (C.A. 47,
i, -I %I&) f6i Me iyoth"is of Letotse3 Njis used to prepare a-
phthalluddo ketnne% and a-aminn ketoup-q. A soln. of'r g.
PhC11,C1](COEt1j In 30 ml. C,11%mms added to 0.02 mole
of dnr NaMt, then 4.32 g. PliCH,011 %vas added, n C4111-
EtOFI amotmim diAd. off, . of
a 4.48 g. i;-C.I(,(CO)'
NCII;CGCI (1) In CJIG:ul,',vl to the rvsidue, and the inkt.
relk"ed 30 min. and pmrvil it) 100 inil-Ace water acidinvi
with HiSO.. - Thit erg. layvr ivm v~pd., the aq. laver extd.'
-x(s. tt=
With C41-fs, the coutbined c. Aed trith MO, dried and
evood., tbr rt~iiliw dis-iolveti In 25 in]. dioxane, and 200 itil,
BtOlf added to give after wratching 0.1 it. (21.4%)
a - C.11~'-V)1'4cfl-coc(c()ICI!Iphhclfplt (11). colorhz~q
prinins, in. 101-2' (frr-n UtOIJ41ioxanc). To a actlit ' of
25.2 It. 3jfifiydro-21j-pynL-q In 100 int, C41h contS, ic
IL

drop 11,50, 19.4", g. Phcff'cllfcOifl~ (III) wits addCA,
the MINT. stirred .41 islim, I 9~- ~snh 'vd~ K.,CO. added- the
mixt-, airred, asrain 30 suls.. th-, --In. dee-awed fro-.11 i~orgl
matc.-Lil, evapd. in r4icho J,,-A-nv -30', and t1m. zeiflue di-
;t snlvk-l in KKJ ml. -Thizi niAu. wzu adifcl W 2.3 r. Ka
fm~qxodm is] 219) tpL C.1L. mirml tiatil rlizvllved. a saln.
nf 21 g- I to 1W-nif, ~jbwfy-, kt stwid t.hr., 14
ml, Am)J1 :Wdoi; reflaxD1 :3.5 hri., w; ,Oic-1 . witla 14:0.
evupd.,~the m4duz dicolveAl In 60 nil. M014 wid let. Mind
In Coll$ tr) give 11) 4, 1"T1.
'
r vi-ne e-wilt-cf.
1' 5' ffmm EtOfl). Th
%vai 1,rcpd. by a 11-fir. Ity6rogoialla- I I-. If in .11) ful.
RtOAcoycr I x. VA.', Pd-BcSrJ,a1 rown prP~ififire all"i It"m
gt lorj* i'l "Is'It1t;
'evvi". 0t ~Crlycqt
Bad h~fttlllg It) alitt
.
'
yield; ~ oxime, in~ 144-11' (frwn R1011). Asaln. is! 14,~',-?
tot. C.TL %a~,
-cit:(CO-130- and XaOlit Omits 1.15 c. iva) in 11R ini. Csstjo,
rcflttxv(i 12 lim, IM nil. 1 [-.0 udded and ncidifted with dit.

110'/0.3 min., a solti. of 1A g. KOll'ba 12 nil, 1110 od,led
to the reiidac, hyttroly~44 s!'Tcc(ed by shakirtig, W md. Ifr)
'
addr(l, the Inkt, nchlifled with 5.V
JICI, rxtd, with FIA
evalld., ri-Idue mud. from C.U. to givc 8.0 x. (83%)
C1.1141CIT(COM); M. in. 114:16". A suln .nf C"li.61-
(CO~R)- (R - tetrah),dr~2-pyrany;) (preud. front 8-114) z.
Yin the xarrm manner as dt.-wribed, for M) spas added.to
0-04 inoft- dq NiOEt, then 1~1-96 , I An 30 mi. C.116 wa-1
dd
d 14
od
f
i
u
a
c
at4
2
k added, rduked 3
ops
,its., 4,,d

ith If evapd, and J~iolf-.Ofla t';
the rpsirfue to give 3~9 g.
M-8D-W*(fromEtOH): oxit"jm.1()&-t1O% Atioln,of
0.5 K. IVA ml. (IIOCII.)s and turz C. p-NjcCIj,S(jAIf in
30 mi. PhNic wail slawly ti6rd, olft-clinz 11) nit, of 4fiatill'ile,
dodrig 4 Iris, the rr:6dut! %raslicd with and
If%(). dried anct evarid. to give o..It X. ethylene ketal of IV.
nk. 114-18* analytical sainple (1.-" g_rri. 12r-5.114 (front. "I
81011). W.W111, ~l I j. IV it? 10 nil. MOH was hcated Willi
MI, III (d- 1.90) for 10 fir, os) a Mcyn bath, the solym
evapd. in vaclw, tile reAdue di'Abived fit MCI atA ex(d.
with CUM, Elie aq; -cohl. cGned. in tuctio and fiftered, Elie
filtmte MIA, in Waco tile rc-Adue Mmolvixi in abi, RtOl I,
MjOaddecf, the iolvent de,,uteil, the d6icilulbit 4nd ppin.
of crysLds repeated twice, wid finally crystd. from alys.
Etoli-petf. ether to yield OM- g..Gf cularle4s ricalle'; of
M. Thil Wag di-~-
PhcIf'
s-.jtvcd in 1.5 mi. AcOll, 0.39 g. Linisyd. NaCiAcawl 0A nit.
BzCI was added, heated 10 rnim on a ilc:ttrz fmth and dild.
With 15 MI, 11,0 to give OZ.-) g. 1`11CII-elfc0c) list; B.,
m. 86.55-7.5* (from EtOftlf:O 3A), oximr, m. 151-2*
f1rcitit IV (.1 K.) S-.is reduced with 1.5 X. LiA111%
in 31y),ml. MrO In it Sjxl)lrt exti-wtor to give 2.N2 c~ 1,.trtlv
t
th
&
l
A
hi
h
i
h
CO
)
R
i
4
, 1
e
t
e
Ys
, w
rur n
n
1011
)II
t
(
OxaUte or l"""'

Ove"I"p[L) ([run, rinj 0, A mivt of , 10 Mi. O(Clfr;
'-4" 1 fr. 1 -1102 g. KOH
clloff),. 1.1ig. iv, 1!7 fill, , r-(), .
Imateft if titter X.-flar: to? fr.) mi It, fit 1-104 ;, IA Y lirg. ..' 21V) - 4f
COO!-'-d' di"'solvUl it) f!'0' distill. lVith stvwn. (114tillato. (fR),
mi.) mcd. with KIC(,)-, cxtd. %vith rt'O' text I. dried, evApA.
and the re-uhle, 41,5 g. oil) m-ated in Rtol-I sala. mith,
it'. file t'irairte of
to gi
142-5' (dmirs,im.) jrato I~tllil J),- pier- te, Ill. (irum
'tolit'sen "I.). T,) a saln, prVild, by ad'111.
aq. F
Inult: (N - totralrydrel-2-p~-nmyl) In 40
-nit. effa bs O-at mife dr v N%OVt a witti. of 9.5' ic. L-0-
ClffACQxfXc!fhfvcOC in 40 mi C4I-f4 wa5 added slonty
-rig, rcOptirig fnr 15 Tim,
belo'A 30' to give. aitm I, lim, itand*
oWing, W.Oling With lip mut ev'30g. *?A vaearl, LO.2 r, (if rL
'u?, 1333 g., rcfl,sxc,f I fir. -z, ith a -An, of 10
Yellfvoil. V
Girard T migent and 15 qr~ AcOU Ili 135 till, abs. ITIOR.
then ad-Icd (a an ice-mlit !,toln_'of Q g, NDOII In 10-W MI.
extri, tvith P*tO (fl.c.5 g_ 5070, m noliketonit maltriA),
aq. layer rvidifici with IbO Dil. 12.y IJCJ~ let stand I fir.,
yletd-d SM g.
aild
J.397q) crade Die fractlow, 22.22 1, of it Ili no till. Cliff
was cliromatcgraphed oil 20 g. alumim. and efuted with Vy-
pertions of C41T., Fractiores 5-16 were 6nibiaeft
oil) and convrrILA to fire oxinle ~f
'I-petr. ether), ta]'D'
COC11,CHIT'll, Ili. t70-2* (from BLO,

!!~j

op-t-w-- A.- xr,
313 0? Ica J~ act vis
and a 0-1
Plq'tcW'c (11MY
't tL
_
it
QI&
1
.
s
utti. ur, AL-Cli R&COXI Munt 5.18 jr. Mi. 100 Itul. Et it,
rin,15,5 rill. AcCILCOXW 05.15 z. C,.H,,Ur ma added the -
11111Tt. MlLixed 6 lirs., Of) g. KOH in 60 ml. H-.0 added: the -
-bixf.4 2 hm-with
inkt, kept 30 rniii. at W wit:i 6Unking, tu
'Wo 1111, ON t1Q, vitil, Oil L10, wailmil with 516 KOU
-
-
u
d H
0
d
i
d
m
f4
n
e
r
apd., and the
ablue #a)
std. tw
, m
imm
,
,
~EtOlf to 9;v6 33.2 t. 05 r) Cl,IIuAc W, vi. 634:2 4-dinitra.
hru
drazorm
u
91t (fr
m L
.
o
, r
p
) y
(from M011). A bnIn. of 2.69 Silwid 5 rul PIACII N It i,
~
in 25 Mi. F-tolf im, brs.
ovt:~ P16t
!otn
-
45 Tug. Pt()~) to give 3-23 L.-A - -
--r -ittral exalate, m. 131-3'
octildrcaut: UJI), b--C4 -%Ak ) , f14
(froin ahi. &0H), It (5,7.) In 100 inf. auh3d. FtO W23,
dropped intu a soln. of 1.4 g. LiAM, Ill '5 ral. anhyd. JR20,
milurrif I fir., throretimd ont, of 11,roaddzd, E1.0 layer,

driid and evard.'to , -1 g.
ka%e 4.6 xu& DL-2o-mninoijcta.
decaue(IV).m.45.-W. Thciuine coin pd., hj.a 1354 %sn.
65-76* joxalmc, in. 10-2* (fram aW, YtOlf); d-,;Artritte, al.
-ale
(frum IhOll); dibenzop-J-turti -, lot. 10fi-2*

"T I g. Pd-ri'l-t-O, VilAyst ill 3'
(if, Ill ill 13) Ild, Viol I (IV.

Antixt.ofo.',
IV, I
m% Aci,0, wid I miL CJUN livattA 0.5 br. .at IW* gavc -
0.21 g. M. in.- 82* (fpwn
Etrili). To a of IS S. Ill in 'to inl. Nxc~co 9;0 g.
beamyWaniric ('11) -.v;Ls nd(Ul, heated rat ~ rtewu bath,
It( NUEnd nveridgN, ~,up& filicrrd off (13,35 g.,
'
.16 7%r) and cry,,td. twice fmm
51) mi. McjCo to -,i%,e Sst g.
W:;ul, 22,6"C2.5117 t(JH).

milser It Uors (alit V1 We"
Etro, was, cd with 2N gniCO, and HrO, resithm (8.95 g. od)
diisolved In 25 Mt. Afe&W, 4.812 g. 141 added w0 the:
Sepd. crystub, crystd. twice frons 35 tn]. Me'CO to give 8.93
'
"
*
1
I
g -22.0
F90
(c 2.5, EtOH)';
7,) (-)-VU tn
g (64
(al
X SZ. 0F6.06 g. (:~J.Vli aCd w.' mixed with 21V Nor
COj, thir Et:O layer washed with H-,O, dried, evaod. aud the
'
idue distd. it; vacua p Rive 3.Y9 g. (-~V"zYhMI40--
octane (VIU), bs-es M -8.95", da OSM, By -
-catalytic debenzylatiott of 17.59 g. VIff In the sante: titanw:
as described for M, 1.94 x. (-)-IV, 5-j: 132-3".
-2 62* (c 4 58 CHC1g) Was obtained, (-)-IV, 0.54 g.;
in"; 0.58 K. -I'. JaIV 4.344 (t 4,84, CHC4).-
14. 90
and 0.07 o-q 4
From 0.135 td I
t 140% OX 41 Id if Cohop)hc%t
bth
h
2
b
15 (
o
)
-
-
-
-p
n o
r. a
ctan wax o
61-21
fri
2
tained
8
.
.
,
,
gously: (+)-IU 4.4
,
la]'J 8.24"; (+)-1V, bo.si 132-4% [a)lj 2.90" (c S. CH");~
~YV~ m.-W-V (front EtOll), Imj'j -4.751 c 441.t
70
-IX, ra. 61-2* (from III
CEIC (Cali
I'. Gultak.

f", C"4 -7-z- /v; k, x J -
YUGOSLAVIA/Organic Chemistry. Natural Substances E-3
and Their Synthotic Analogues.
Abs Jour: Ref Zhur - Khimiya, No. 8, 1957, 27011.
Author : Prostenik, M., Stanacev, N.Z.
Inst : ------
Title Studies in The Sphingolipids Series. V.
Synthesis of Racemic Dihydrosphingosine Deri-
vatives Startinla with DL-serine.
Orig Pub: Arhiv kemiju, 1955, 279 No. 1+9 197 - 201.
Abstract: It is shown that derivatives of DL-serine can
serve as initial compounds for the Mthesis of
fragments of the C18 chain of sphingosine. The
following derivatives of sphingosine were syn-
thetized: 1-ethoxy-2-(N-isoindolinyl)-3-07.7-
octadecane (I) and 1-ethoxy-2-phthaloylamino-3-
oxyoctadeC2ne (II). The initial oC-phthaloyl-
amino-A-ethoxypropionic acid (III) was prepared
Card 1/3
1

YUGOSLAVIA/Grganic Chemistry. Natural Substances E-3
and Their Synthetic Analogues.
Abs Jour: Ref Zhur - Khimiya, No. 8, 19579 27011.
by boiling Gr_-&mino-,,8-ethoxypropion1c acid
with phthalic anhydride in toluene distilling
water off (yield 78%, melting point 135 '0 ), or
of ethyl ester of (:X-bromo-A-ethoxypropionic
acid (saponification, reaction with M40H
further same as mentioned above) yield 6R.
Acid chloride of III (prepared of III and 0)
SOU I yield 91.5%, melting point 70 to 71
was introduced into the reaction with dibenzyl
ester of natrotetradecimalonic acid9 the reaction
product was debenzylated by catalytic hydrogena-
tion in alcohol solution (10%-ual Pf/BaSOi+). The
filtrate was boiled 4 hours in order to decar-
boxylize it, c6neentrated by evaporation and di-
luted with petroleum ether; the precipitated
Card 2/3

YUGOSLAVIA/Organic Chemistry. Natural Substances E-3
and Their Synthetic Analogues.
0
Abs Jour: Ref Zhur - Khimiya, No. 81 19579 27011.
deposit was discarded and 1;ethoxy-2-phthaloyl-
aminooctadecanone-3 (IV), yi ld 10.5%, malting
point 40 to 40.50 (from abs. a1c.). was separated
from the mother liquor (by chromatographing with
A120 from solution in C H6) I was prepared
by r;ducing IV with LiA K i~ ether (boiling 10
hours), yield 37%, melting point 59 to 600 from
a1c.). ~I was prepared by reducing 2 g of IV 0
with NaBH 24 hours at 20
f~,(in CH OH+ dioxane;
and puri d by c9ematographin with A120 39 Yield
55 mg, melting point 8o to 810 ffrom alc-.). Seo
R.ZhKhim, 1956, 23203 for report IV.
Card 3/3

R~
Necrosamine series. II. Synthesis of raceW c 4. 5-diaminonadecane. III. Preparation
of 4-(O-ca7-boxvbenzamido-)5-1,.enz-viaminr,(-icosane and its hydrolysis to h-anlino-5
hydroxyeico sane. IV. Preparation of 2-mettiy:L-3-hexahydroplitlialimiin-4-a.Minononaciev-,Ink--.
In English.
P. 211(Croatica Chemica Acts. Vol. 28, no. 3, 1956. Zagreb, Yugoslavia)
Monthly Index 6f East European Accessions (EFAI) LC. Vol. 7, no. 2,,
February 1958

no med= with
PrepamtIm of
Ar
A ~-4 ( 0 in -~
CHI(CO'Eth in 150 Inl- (1-14,
I t! wit', tj N&OEt preW. from 40
liomd
PI,CHOH ic 100 ml. CH. add,-d, EEOII dbtd. azwuvpz-
HgOaddtd, EhL aq, laytrextd. twke with and_
the C~Fr~ exu, d-1-td. to yie"d 67 g. UcCH(C(%CHjFh)t 1.
ti-, 13C~40' A Scia of 13 1;-
214ci and 28 X in ZW ral. AcOH was re-
ouv--4 3 hm. with" "Ili N red fa 1 V40 ml. kt-uso.
axd- the Wpd. cryulls ansul. fim 60cj' Et
rR - D-Cjr4W&)l%?"
!704 U7711g.NaMml-

o 9 /<
YUGOSLAVIA organic Chenistryi, Natural Substances G
and Their Synethetic Analogues.
Abe Jour Ref. Zhur. - Khiniya, No. 15p 1958, No. 5052-2
'tLut-l'or Stanacev, N%Z.; Prostenik, U.
Inst -7-
Title on the Roaction of dipthaloyl-DL-Lysine chloride
With dibenzylsodiomethylmalonate. Preparation
of DL-4,8-dial-aino-3-octanone.
0-irt Pub : Croat. chem. acte, 1956, 38, AM, 291-294 (Eng.)
Abstract : A synthesis of DL-4,8-diamino-3-octanone (I),
beced on the reaction of diphthaloyl-DL-Lysine
chloride (II) with dibenzyl-sodlonethylmalonate
(III) is described. Attempt of proparation of I
from III and DL-2-phthalimido-6-benzamido-
caproate was not successful. Into a suspension
of 10.12 g of pulverized Na In 150 ml of benzene
Card l/ 5

YuGosuxIA organic Chemistry, Natural Substances G
and Their Synethetic Analogues.
Abs Jour Ref. Zhur. - Khj-p-iya, No. 15, 1958, No. 510522
were added 40 ml of ethanol. Upon dissolution
of Na a solution of 70.5 g diethylmalonate In
150 ml of benzene was added, followed by the
addition of a solution of 95 g phenyl carbinol
In 100 Lil of benzene. At the same time excess
of ethanol wa- driven off as an azeotrorl'i, mix-
ture with banzene. 62.5 9 of CH31 were intro-
duced and the mixture was boiled for 6 hours,
finally 150 ml of H20 were introduced and benzene
layer was distilled off. Tjje yield of dibenzyl
methyl malonate (IV) was 51%, b.p. 130-14(-'3 (0.
02 rLi). A solution of 13 g of DL-Lysine
dichloride and 28.03 9 phthalt-1 anhydride in
250 ml of g1 acetic acid, was boiled for 3 hours
with 25 ml of pyridine. The solution was then
Card 2/ 5

YUGOSUVIA Organic Chemistry. Natural Substanecs G
and Their Synethetic Analogues.
A
19,12, ',r,. 5G522
Js j our Ref. Zhur. - Khimiya, No. 15, D
poured Into cold water. The yield of diphthaloyl-
DL-Ijysino M) was 75%, m.p. 169-1700 Cf r. 96%
ethanol + viater (1:1)_7- 10 g V were boiled for
1 hour, with 30 nl of thionychloride (VI), and
the excess of VI vias driven off In vacuuLi. In
that manner 10.98 g II (oil) were obtained, but
could not be further purified. Into a suspen-
sion of 0.593 g of Powdered Na In 50 n1 benzene
a solution of 7.71 g IV In 50 ml C6H6 Was added.
The mixture was boiled until the disappearance
of Na and cooled to - 200, Bubsequently a solu-
tion of 10.98 g I-1 in 50 ral 06H6 was added.
After stirring for 12 hours the content6 were
poured into water, containing a few drops of
cone. H-S04- Benzene layer was evaporated In
Card 3/5

YUGCSL'iVLI Organic Chemistry. Natural Snbetanoes G
and Their Synethotic Analogues.
Abs Jour Ref. Zhur.- KhImiya, No. 15, 1958t No. 50522
vacuuLlt the residue was dissolved in 50 ni. of
dioxane and hydrogenated over 1 g of 10% Pd/
BaS02- When no more hydrogen was absorbed a
fresh portion of catalys ( - 1 g) was added
twice. The filtrate was bolled for 2 hours,
(decarboxyla',jd) vja6 dried in vacuum end the
'~ in
residue was heated for 1 hour (1000Cj
vacuum, after which operation i'U was dissolved
in 50 01 of C6H6; and chromatographed on ac-
tivated A1203. From the eluents were obtained:
31.4% DL-4,8-diphthaliriido-3-octanone(Vil)(oll),
which crystallized from an alcoholic solution,
m.p. 90-910 (fr. d1oxane), VII-2,4-dinitro-
phenylhydrazone, n.p. 104-1051 (fr. 96% a1c.
containing HC1) and 2,4-dinitrophenyl hydrazone-
Card 4/5

YUGOSLAVIA Organic Chemistry. Natural substances G
and Their Synethetic Analogues.
Abs Jour Ref. Zhur. - Khimiya, No. 15, 19582 No. 50522
I-dichloride, 64.5% Yield, m.p. 216-2170 (fr.
ale. cont. H01). A mixture of 6g DL-2-amino-6-
benzatildocaproate and 3.55 9 of phthalic anhyd-
ride was heated on an oil bath to 130-1400, then
it was cooled and the melt was dissolved in 100
ml of 96% alcohol. Finally water was added(until
appearance of turbidity). The yield of 2-phthal-
imido-6-benzamido-caproate was 88,c-~, its m.p.
161-1620. -- Y. Shvatchkin
oi~l,a 5/5

i~ 44;

zz-
jT;~j.

V
A gynthetic Investigation, in' the pecrosamine eeries.:
-
A terd d P. Auk i U p o r i 6(Univ. rf~~tia
11 Tagreb,
~
=~
M
Saluruvisse
se em
4=3
K7 19M)
Prepn. or ractrale n=osamine, MC(C1-f0vtC1l(NH,)CH-,
(NH,)C,H, (Ikawn It I., C.A. 49, 10575;) proceeded from,
'
tradecyl-
aBowman ketone
synthesis between dibenzyl te
malonate and N-phthalOYI-IM-110
rvalive acid chloride or N-
'
hth I I -vallne acid chloride which yielded 4-phthal,
n=Oy
4
3
;
l
3
h
h
l
-
--
-
-
-methy
t
3.5
ru. 38 and 2 p
a
-Imldc"~nonadecanone (11), m. 52-3% resp. I and U h
-
l
M
T, - ith. HDr gave 4-auduo-S-icosanone-F-Dr
dro
yzed v (I
-6*. and 2-methyl,3-amino-4-nonadecanone-HBr (IV),
in. 05

m. 127~7.6*. Oximes of M and TV reduced over P 0
t I and
e corresp
th :)nding diamines isolates is the di-RCI salts gave
ir ~4 5-diaminoe1cos;me-2HCl, m. 285-7* (H20) idlacetyl chj~
HIZ rn. 122-3' (MeCN)I, and 2-methyl-3.4-diaminononona.-
dccane~-211CI, m. 225-6' (nic.) Idiacetyl deriv. tn. 13"
-----------------

YUGOSL.AVIA/irganic Chemistry. Synthetic Organic Chemistry. G-2
Abs Jour: Ref Zhur-Khim-, No 13, 1958, 43256.
Author Stanacev N. Z., Prostenik M.
Inst
Title Studies in the Sphingolipids Series. IX. Synthesis
of DL-2-Ainino-1,3,4-Trihydroxy-Octadecane and of Its
C~-Methyl Ether
Orig Pub: Croat. chem. acta, 1957, 29, No 2, 107-113.
Abstract: DL-2-amino-1,3,4-trihydroxy-octadecane (I) and its
Cy-methyl ether (II) are prepared over the inter-
mediate compounds: 2-methoxy-hexadecanoic acid (III)
-.,, ethyl ester of 2-methoxy-hexadecanoylaceto-
acetic acid (IV) ethyl ester of (2-p-nitro-
phenyl-hydrazone)-2,3-dioxo-4-nethoxy-octadecanoic
Card 1/6

YUGOSLAVIA/Organic Chemistry. Synthetic Organic Chemistry G-2
Abs Jour: Ref Zhur-Khim., No 13, 1958, 43256.
acid (V).-----;;rethyl ester of 2-acetamido-3-oxo-
4-methoxy-octadecanoic acid (vi) ---:~1,4-lactone
of 2-amino-3-hydroxy-octadecanoic acid (VII).
0.659 mole methyl ester of 2-bromohexadecanoic
acid, obtained by brordnation of palmitic acid
(see Sintezy org. preparatov, 3, 275, M., 1952)
and subsequent esterification with CH;OH, are
boiled for 3 hours with a solution otNaOCH
(18.4 g Na and 450 ml absolute CHjOH), and ior
1 hour with a solution of 40 g NaOH in 200 ml water,
poured into 500 ml ION' H4SO~; yield of III 74.8~,
MP 73-740 (from petroleum ether). SOCII is dis-
tilled off, after 24 hours (200), from 0.035 mole
III and 25 Ml SOCI-1, to get the anhydride of 2-
methoxy-hexadecanoic acid (VIII). A suspension
Card 2/6

YUGOSLAVIA/Organic Chenistry. Synthetic Organic Chemistry. G-2
Abs Jour: Plef Zhur-Khim-, No 13, 1958, 43256,
of 6,9 g Ila in 150 nLl absolute ether is stirred
with 0-35 mole ethyl acetate in 100 ml absolute
ether for 1 hour at a boil and then for 12 hours
at 200, 0.245 mole VIII in 100 ml absolute ether
are added within 15 minutes (0'7)) the mixture is
stirred for 2 hours and is then boiled for I hour,
50 ml 10~ HC1 are added and 90.% crude IV are
extracted with ether. Solution oflO.75 g IV in
250 ml 86% alcohol is mixed with 30 ml 54 solu-
tion CYOONa and stirred for 30 minutes at 20
then the- mixture is stirred for 15 minutes with 20 g
CH COGNa, there are added 0.03 mole p-nitraniline
(aazotized with 0.03 mole NaNO-, and 9 ml HC1,
and adjusted to pH 6.5 with 12 g CH3CCCNa and 2 g
NH~Cl), raixture is stirred for 1 hour (200), diluted
Card 3/6

YUGOSLIVIA/Organic Chemistry. Synthetic Organic Chemistry. G-2
Abs Jour: Ref Zhur-Khim.,, No 13) 1958., 43256.
with water, and ether is used to extract 34~ v,
MP 73-74C (from alcohol). To mixture of 15 g Zn-
powder, 60 ml glacial CH~COCH and 30 ml (CjfjCO)4O
is added dropwise a solution of 12.8 mole V in 90 U
glacial C113COOH at 15-200, the mixture is stirred
vigorously for 3 hours, and then for 3 hours at 4o-45
.yield of vi 64.8,p4, mp 83-84P (from petroleum ether).
Solution of 10 m-mole VI and 15 m-mole NaDH~ in 100
rpl CH OH containing 3 drops of 45c,'o KCH is allowed to
sta2for 48 hours ht 200, is then diluted with
water and the evaporated ether extract is boiled for
5 hours with 50 ml 48~ HBr to get 78.9% vii. HBr,
MP 120-1350 (from ethyl acetate). Solution of 3 9
VII. HDr and 3 g LiAlF, in 100 ml tetrahydrofuran
is boiled for 4 hours, excess MJUH~ is decomposed
Card 4/6
6

YUGOSLAVIA/Organic Chemistry. Synthetic Organic Cher;-dstry. G-2
Abs Jour: Ref Zhur-Khin,., No 13, 1958, 43256.
with water, the oil thus obtained is diluted with
25 ml absolute alcohol and allowed to stand for
24 hours with 10 ml saturated solution of oxalic
acid in absolute alcoho16 to get 680 mg of the
oxalate of I, MP 200-2020(from alcohol; decorTooes)
and 240 mg 'if NT 218-220 (from alcohol; decompoBes
680 mg oxalate of I (MP 200-202 ) are shaken with
25 ml % KOH; CHC1 Z extracts 9 .24% 1, MY 112-11.8 c'
(from CHICN), and there are obtainel 17.64% of
CHC1~, -ilisoluble form of I, MP 136-1381 (from
CH3CR). To a suspension 3f I, MP 112-118 0(100 mg'))
in echer (50 ml) are added, -gradually and with vigo-
rous stirring, 10 m.1 1 N NaOH and 1 ml benzoyl
chloride; the resulting partially cryst'allized oil
Card 5/6

YUGOSUVIA/Organic Chemistry. Synthetic Organic Cherdstry. G-2
Abs Jour: Ref Zhur-Khim., No 13, l9r-8, 43256.
is allowed to stand with 1 mi 45~ KOH in 20 ml
CH_;OH (18 hours, 20f), to get 55 mg of D-2-benzarido-
1,3,4-trihydroxy-octadecane, MP 112-1-13"(fron acetone'.
After boiling for 2 hours and letting it stand for
12 hours, a mixture of 3.7 m-mole V, 1.05 g LiAlHf and
70 ml ether is decomposed with water and the substance
extracted with ether is hydrogenated over Pd/C in 50
ml alcohol, 50 ml ether and 3.43 ml concentrated PC1-
acid, -md evaporated; the portion soluble in ethyl
acetate is shaken with 2 11 Na,,,C03 and II that is ex-
tracted with ether is precipitated as the oxalate
from absolute alcohol, yield 395 mg, YP 174-176" (de-
composes). Communication VIII see RZhMin, 1958,
36323.
Card 616
7

At
pp
nAn-~."4E21
to
0 0 "nth the do 1~-Hec NH4C(:NOH)(C1fs)oKG4i
'Uti 61 the c6 6A f _MWLWj2Wb 4 diaml
OAc), Vwas cooeittci W Ow P-Me[W
car at 0=1 d yW
twol"~
(CHOIXt.2HC In the followlar,wayL (1.5
"In Y 14vt "td. front. a So et thimble with Et%O Into a SOW. of
Ada #qOMMi ~7
)tIoRnIx -To it suspeasion of Olt
: MAIM In 5W ml. Et%O during 50 brx.-, 20 mi. JjO add
1.93 g. NdL- Oowdirln 250. ml. Cjismas added a soln. of, the Et.0 dried, sqtd. with IM, and allowed to stand
4.04 -9. Mt(CHJs;CW(CO&CHtPb)s in 250 MI. CA, the a a m(rigeritor yielding 1.25 g. IV, 4n-W-O' 0
I t stirred 1-2.hrs. at room tmp,, a soln. of 20 g, 1,
[M;&9RCOC1 119", 1
Ht.0), 141V 0.860 (c 2.69, HtOH)., M (0.4 g.) In I
QR - o-CM41(COW throusbout this %bstr.] 113tOHan Lral.HClhydratinatedwitJ3AdawAcatW
La 1W ml~~ Cs t added. the thick, turbid mixt. a IlWed to L'24 hrs.,'the Pt fterect off, the ffitzate p4pd., the i
stand ovemlFbi, poured Into ice HSO contg. few drops of 11r -
treated with l6m]. 2NNaOH,extd.wMBttO,&9dth1
M, extd. vnth C4He1tfieso1ventevapd-iirocu*,W residue Et
ro 3-g por- 0 satd. with HCloveO.22t, IV. IVAIN.)WO
dissolved in 400 ml. HtOff, hydrogenated over t~
relved W 5 mi. 2Pr NaOH, extd. with RtjO, the solvent
Pd evspc
_040j for 12 brs, at 20% the catalyst the residw! dissolved 16 10 W. RtOH and CSs y
refitixed 2 hTs., the solvent eyapd., the residue Irbiunate salt, M. U&-7" *Wclivas retizeii
~dissolvedin_Wml- C411s.allowedtostadd overnight. the dithloca mij Etog, ;he Mienj tvopd., and: the I
crvst--Me(CjFi2)uCH(CO3j1)t (4,05g.) filteredoff, thefilUute w1th 10
chrornatogniphed on 150 g, Ali0s, ahd eluted with CoHm gave r ystd ro .pe tli:r y1e][41n g Me&1.NH.CS.M
12.2 j. D-MeCHRC9SCHj)jMe (7). W. M-3.5'(130H), c f rn tr' e 1
(Ci1j)jMe, m. 89-09, jail? -3.5* (c 24j- RtQ
[*IV -3-,1* (c 11; CliC4). I (g.9 r.) reOuxcd with 30 mi.
penSion of 2W Mi. IV Lin 10 Mi,
QAc and 25 - mt. 667o HBr 10 brp., The acid evapd. in 2N MOH, I. mt. BzC1 "d M nil. 2N NAOH xM4,
[pacuo," the. residue reaured with 60 ml. CHC4, o-CgH4;.
I hr.,. extil. Mth 400 ml.'EttO, the solvent evapd..* a
(COMi (1.1 gj Altered offj the filtrate evapd. jx cacao, and residue cryltd. from MOH gave dibeasoyt-M, in. 15
I'the residue crystd. from UtOA0 gave 2.3 S. a-McCli- A rnixt. of OA C. M, 8 cal. AcgO, and I ad - COW hg
(NHjCO(CHz)jXi-.RBr (H). m. IM-18* (from 10-1
ji)
3
over-i
hrl*. at 10)', ponre4 Into 120 ral. W4
2N HrW
RtOAc-J3tOH),.fajV -3.5* (c 3.4, CilifIg' 11 R g.) re- Hl., SN'the r;
fluxed 3 hrs.with a soln. of NHjOH.HDAC (prepd. from 4 g. 'FttO,'the ext. washed with H%O. mg
cry'std. from MtCNL gave 0.1 9. dlwdyl-M, in. -12
-HO#.HCI. 10 S. NaOAc, and 80 ml, EtOH) the solvent - to D-eirythro- and D4,1q,e&MeCH(16".
qytd 14 1 was converted
Ild M tic trrited with 200 a ffj()
gave 3 g. j4Ltiie fC)lWWjng VjjLV5., U_" K')
-rem - ; CH(OT!)(qjg&)jAjt (Y)

Ala
I
'
'
0
th
rtfluxedw
' 2 hn. at 100
, the
Pour6d UY HiSOL
eiK with
added, thaom.laytr~
!J.5.j.IJWH4 for 12 lira., - ml. 1110
filtend,*Ied with -Nat$Ou the solvent'evapd. in vaciso. the 1 HtO,evapd., dth oll re!ddUeeryst4,-(t6nMeCN
0.16 (Z'MCH )CH(OAq)(CI
dbsW#td in B40, and satd. with HCI yieWing 1.02;
' m.7t0-70.5*-VUJO-I ff. washented,withiC, y
a0
ei~dk V.HCI, vi. '177-9? (froai.2:1 MtCIJ-EtOH),;
jf~;
'
:(
- A San
of 1
5
Uja M W
f 249
218
MOR) in EtOH at 40-60 for.1 hr.,-4he mlxt~ pdured Into

R
-
'
th
t
td
ith B
O
th
A
*
o
d
W
h

0
-
.
.
K.
.
p
.
,
Adams
eiiAted -4t room tesup
200 jug
dro
with
H b . tx
-t
. w
g
e
a
U
,
wi
Hz
.
e
ea
ev
Md 00
O
M CTUNHA
)CH
y
g
.itwiti-tbc -Pt Al -
.
-
.
tered off, the EtWovapd., the residge C
P--TYO
(
I
t WJ
IMM;A ME MMI4. No itc
~
Uh 2SO W
Snam wi ,
.'2N N&OH and 200 ml Bt,O 'tbe EtsO 6 -
occurred w en "rAhf&Vl (0
1
) y
-~fta ties

-,.740
dried
Satd. vvi~; HCJ ga
H.O
444 -
-
X
10 mi; UtOH-and 5 ad
26
efliatiol
le-HLI for IS
t)
,
.
,
.mt. O7wv--VI!CJ,: the'ethereal mothee liqtwr was eva
- .
room temp., or with OA mt. eUi"oH
1 a
c.HCII1br420Jui,at,
ddii
reMdue'cr td. ftotq MOAcyleldiag
'
W _y;
-
:
room temp., or with.EtOK and.10 -RCI V)T'S
% him*
17&7` 1*1_J? -;-O.P6* (; 2.77, EtGH)-
A Wht-
jn
N HCI
20
EtO
andO
4O
2NNaOU
i
;~O
W
th~~V
iOS'
5; nflux, - D4hreo-VT Wa3!=VftU4 to'1>4h?e~-V-HCI.-
.
,
t
d f
IM b
4i
C
.
.
.
,
m
t
.
,
,
y
" reate
or
", at room
t
p- with elbanalic O
I
13 :1-shakitzi-20
min., thp-ppt; extd. with BOD W-i VM was recoyered anchingod *Ijen treated yrith W7q tMa-
Ut cd:*ith HLO.-and the EtsO dried and mpd.

G,3 9~ D-etjlkio~MeCH(NHBz)CH(OH)(Cfft)l4Me
o0

49

Z 6
J eCN), [all? -4.05 c 2.47, CHCIj).-

Q.4
D*
P Cr was prew, v4keo-~, M. 95-6?

0
ted
0. C.U.N hi~a
4.Acs.0, and 10

7

PLUSCECP J.;,USIC,4.; PROSTENIK, M.
On the reaction of 2-phthalimido-l-octadecanal and 2-methoxy-
1-octadecanal with nitromethane. Croat chem acta 35 no.2:
93-99 163.
1. Department of Chemistry, Faculty of Medicine, University
of Zagreb, and Department of Biochemistry, Institute "Ruder
Boskovic", Zagreb, Croatia, Yugoslavia.

MA.THOM-ORESCANIN, B. (Mrs.);--PR04TENIX) M.
Studies in the sphingolipids se#efs. III. Croat chem acta
33 no./+:219-228 101-
1, Department of Biochemistry,, Institute "Ruder Bookovic*,,
Zagreb., Croatia, Yugoslavia*

PROSTENIK, M.; KISIC, A.; MAJEOFER-OR.E.-SCANIN, B.; MUNK4&IZRT, M.;
S.
OccurTence. of C20-sphinoolipide bases in animal and plant tisoue.
Bul om-..,Yq~g 7 nodl/2:1 F-Ap 162,
I., Zavod za komiju Medioinakogo fakultotaj Biokemijaki odjol
Instituta-*Ruder Boskovic." Zagreb.

PROBTENIKp If.; STANLCEV, N.Z.; MUNK-WEIRM, M.
Identification of normal higher allphatic aldehydes by ans
of the melting point data of their thlosemicarbazones. Croat
chem acta. 34 no.1:1-6 162.
1. Department of Chemistry,, Faculty of Medicine,, University
of Zagreb, Zagrsb,, Croatia,, Yugoolavia.

MAJHOFZP.-MSCANIN, B., Mrs,; FROSTENIK, M.
Studies In the sphingolipids series. W. C20-Sphingosins,
a now long-chain base'of animal origin. Croat chem acta 33
no.4:219-228 161.
1. Department of Biochemistry, Institute "Ruder Boskovic,"
7AWreb, Croatia, Yugoslavia.

PAIAMETA, B. (Zagreb); FROSTENIK, M. (Zagreb)
Chromatography of the lipide bases on paper impregnated vith
cilicle acid, Croat chem acta 33 no.3:133-135 161.
1. Department of Biochemistry, Institute "Ruder Boskovic,"
Zagreb., Croatia, Yugoslavia.

PALAMETA, B.; PROSTENIK, M.
On the erythro and throo-2,3-dibydroxytetracosanoic acids. Croat chem
acta 32 no.4:177-182 160. (EUI lotg)
1. Department of Biochemistry, Institute "Ruder Bookovic", Zagreb,
Croatia, Yugoslavia,
(Bromination) (Oxidation) (Acids)
(Configuration)

MUNK-WRINERT, M.; PROSTENIK, M.
Studies in the sphingollpid series. IWII. a thesis and resolution
of 1-bydroxy-2-aminoeiconane 020-spbinginer. Croat chem acta 32 no./+:
197-202 160. (EFAI 10:9)
1. Department of Chemistry, Medical Faculty, University of Zagreb,
Croatia., Yugoslavia.
(Sphingine) (Sphingolipidea) (Eiconanedioic acid)

KISIC r A.; (.Pl~ ~STENI~KM.
Studies in the splilngollpids aeries. XIX.Note on the distribution Of
C18 and C20-pbytosphingosine in yeast carebrin. Croat chain act& 32
no./+:229-230 '6o. (EEAI loig)
1. Department of Biochemistry, Institute "Ruder BoskovicOv Zagreb,
Croatia, YugoBlavia.
(Spbingolipift) (Cerebrin) (Chromatography)
(Gases)

,,,PROSTENIK, M.; MA-ROFER-ORESCAIIINg B.; KJNK-WEINERT, M.; RIES-LESICt B.
Studies in the sphingolipide series. XII. Structure of the cerebrin
anhydro base of yeast (C q - phytosphingosine anhydro bass). Croat
chem &eta 32 no.1:11-15 0- (EW 9:12)
1. Department of Biochemistr7, Instute "Ruder Boskovict" and Department
of Chenistry, Medical Faculty, University of Zagreb, Zagreb, Croatia,
Yugoslavia.
(Sphingalipides) (Cerebrin) (Yeast)
(Phytosphingosine)

RIES-LESIC, B.I_PROSTENIK# Me
Studies in the sphingolipide series. XIII. On the ceraxides and
ceramide esters of C20 - phytosphingosine anhydro base of yeast.
Croat chen acta 32 no.1:17-21 160. (EEAI 9:12)
1. Department of Biochemistry, Institute "Ruder Boskovic," Zagreb,
Croatia, Yugoslavia.
(Sphingolipides) (Cerebrin) (Ceramides)
(Pbytosphigosine) (Esters) (Yeast)

GERENCEVIC, Nada; V.~'Q�TENIK, Mihovil
IT- --11-- -
Synthesis of photographic sensitizers in the thiazole
series from alpha-amino acids. Kem ind 23 no. 2:.
98-101 F 164.
1. Department of Chemistry, Faculty of Medicine,
University of Zagreb.

PROSTENIK. Mihovil
Formation and structure of dyes in the processes of their chromogenic
development. Nom ind 12 no.8:597-600 163.
1. Wicinaki fakultet, Zagreb.

PROSTAXOTA, T.N.
.0-PON"m W*44.
A came of intensive invasion by Ascarides. Med.paras.i paras.bol. no.5:469
8-0 '53- (MIJU 6:12)
Lis Oelpeakovskoy protivomalyarlynoy gorodskoy stantsil.
Oforme. Intostinal and parasitic)

BAROIISKIY, Isaak Vladimirovichp inzh.; VIKTOROV, Georgiy Borisovich;
VOROBIYET, Vladimir Illicb:, KIIII, Anatoliy Senyurovich;
LEONTIYEV, Sergey Nikolayevich, kand. tekhn. nauk;
MUZYKANTOV, Stepan Pankratlyevich; PROSTENTSOV GrigorJy
Yevgenlyevich; TSAY, Trofim Niko ic~.
[Building of mining enterprises) stroitel'BtVO gornykh pred-
priiatii. Moskvap Nedra, 1965. 323 P. (MIRA 18:10)

V~')SR/Pharmacology. Toxicology. Chemothera- V
peutical Preparations
Abs Jour : Ref Zhur-Biol., No 8, 1958, 37680
Author :Balandin G. A. P=aketova N. P.
Inst :Rostov na Donu State S`c-11rnttT1c--11e search
IntiDlahue Institute
Title :On the Problem of the Mechanism of the Thera-
peutic Effect of Syntomycin and Levomycin in
Brucellosis (K voprosu o mekhanizme terav-ne-
ticheskovo deystviya sintomitsina i levomit-
sina -Dri brutselleze).
Orig Pub : Tr. Rostovsk.-n-Donu Gos. n-i in-ta, 1956, 10,
364-391
Abstract : -7,iterary data indicate that when patients
afflicted with brucellosis are treated with
syntomycin (1) and levomycetin (11) the
Card 1/2

-~J-949,q/Phfjrmacology. Toxicolocry. Chemotherapeu- V
Abs Jour : Pef Zhur-Biol., N'o ~. 1958, 37680
Abstract : symptomns of tile disease quickly disappear; how-
ever, neither of the preDarations have an etio-
tropic effect. 1 and 11 tailed to prevent the
generalization of the infection when mi.(,e wore
infectpd with brucella. 1 and 11 administered to
mice which were Dreliminarily vaccinated Drodu-
ced the same results. It is assumed that the the-
raDeutic action of 1 and 11 is depended on their
development under the influence of the areacti-
vity of the macroor-anism. Relapses of the dis-
ease are caused by the restoration of the nor-
mal reactivit7 of the brucella infected orga-
nism after the administration of the antibio-
tics was halted.
Card 212

USSR/Plant Physiolocw - Mineral Nutrition. 1-3
Abs Jour : Ref Zhur - Biol., No 5, 1958, ig%6
Author : Zabluda, G.V., Prosteva, R.I..
Inst
Title On the Movement of Radiactive Phosphorus Absorved by
Leaves in Growing Barley Plants.
Orig Pub Dokl. A,-N SSSR, 1956, 109, No 2o 397
Abstract Barley of the Wiener variety was raised in vessels with
soil containing 70% of its moisture capacity. The lea-
ves were fed with a solution of Na 2HP32-o in a concen-
tration of 0.1 curio/mi for a perii3d of ~ hours. P32
moved from the main stems into the secondary at a grea-
ter intensity than it moved, from the secondary into the
nain stems. The intensity of p32 movement decreased
with the age of the plantas Thic work was carried out
in the Ural University in Sverdlovsk.
Card 1/1

- :L - - v.
y7 ~j -N~ - ~ ~ - - --
- ~r - , ,

PFOSMETOVA, tT. P.
Prostetova, 11. P.
117accine Therapy of Experimental Brucellosis." Rostov na Donu Stato.
1,11edical Inst. Rostov na Donu, 1955. (Dissertation for the Degree. 6f
Candidate in Medical Science)
So: Knizhnaya letopis', No. 27, 2 July 1955

- --TIROSTLVA, M.I.
ZABLUD4.. G.V*;
Peculiarities of the effect of gibberelin on the growth and develop-
ment of healthy and degenerated potato plants of the mRannyaya Roza"
varioty. Wattah, dokl. vys. slikoly~ b1ol. nauki no.W81-185 161.
(MIHA 14:5)
1. Rekomendovana kafedroy fizio2ogil. rasteniy Bashkirskogo gosudar-
stvennogo upiversiteta im. 40-le#ka Oktyabrya.
(OIBBERELLINS) (POTATOES-VARIETIES)

PROSTETSOV, P. A. Cand Biol Sci -- (diss) "Pigmentation of the membranes &#+d
I-a4Jzj*:~1 -
40FV6 o~;iapoir'tebrates." Kharlkov, 1957. 16 pp
,Wnw of the interral orgnnsl
(Min of Higher Education UkSSR. Kharlkov Order of Labor Red Banner StIlte Univ
im A. M. Gorlkiy), 200 copies M, 14-58, 112)
-41-

.-,..PHOBTNNV, G.I.,mater
.... .....
Shorten the fitting time. Stroi.truboprov. 4 no.1:7 Ja '59.
(MIRA 12:1)
(Pipe fitting)

-I
Two caies of murins bymenolepiasis inchildren. Ned. Wasit., Koskv&
no.3:278-279 May-June 1953. (GIKL 25:1)
1. Of the Halminthological Department (Read -- T. N.-Prostakova) of
Osipenko 14cmicipal Anti-Malarial Station (Read -- Ye. T. Grigorlyev).

IPROSTAKOVA. T.N.,, 2aveftrushchiya otdelom; GRIGORIYEVA, Ye.Y., zaveduyushchiya
Two cases of rat hymenolepiasis in childrea. Ked.paraz.i pa--az.bol. no-3:
278-279 M7-Je 053. (W-RA 6:8)
1. Gellmintologichookiy otdol Osipenkovskoy gorodskoy protivomalyariynoy
stantsil. (Worms, InteBtinul and parasitic)

PEMAAKOV,
USSR/General Problems of Pathology. Pathopbysiology of
Infection. U
Abs Jour: Ref Zhur-Biol., No 8, 1956, 371o6-
Author : Prn.-m+inknir, A.P. -
Inst :Leningrad Veterinary Institute.
Title ;Disproteinenda in Experinental Piroplasmasis in Dogs.
Orig Pub: Sb- rabot Le-ningr. vet. in-ta, 1956, vyp. 18, 43-52
Abstract: At the height of the piroplasnosis invasion stage,
for a period of 3-4 days, the concentration of ga,=.
globulin (I) in the blood increased by 3-%, the
albunins decreased. During the period of une ap-
pearance of clinical signs, the value of I decreased
by 3-10% of the original level, the beta globulins
increased almost twofold. A second infection of the
dogs caused, within 4-8 days, a sharp increase of I
Card 1/2

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112 air -se Was Qbtj"tct viph rz'rnnce
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.:Os t x Zea ObE,2111 CL
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253

PROSTIMOV, K.14.; BEYUL, Ye.A.
Determination of the absorptive function of the small intestine
by the method of radio--indication. Med.rad. 5 no*6:27-29 160.
(MIRA 13:121
(INTESTINES) (IODINE-ISOTOPES)

PROSTOKHAN ,,A.F,.,-,.,kand. voyenno-morskikh naull, podpolkovnik
, PL -
Shifting of flight formation for surveying a sector of the sea in the
shortest time. Nor. abor. 47 no.1:54-58 'Ja.164. (WRA 18:7)

PRIOIZV'. M.
14
In the Shcherbakov Grain Blevator. Muk.-elev. prom. 23 no.11:10-11
11 '57. (KIRA 11:1)
1, Direktor Shcharbeacovskogo elevatora.
(Shcherbakov-Grain elevators)

PROSTOPIOLOTOVy F.; TSULIMOV, A., red.; TELIPIS, V.,, tekhn. red.
[Reorganization of industrial management and prospects for
industrial development in the Moldavian S.S.R. during #e
seven-,,ear plan]Perestroika upravleniia promyshlennost!iu.
Moldavskoi SSR i perspektiV ee razvitiia v acmiletke.
Kishinevp Goo. i%d--vo "Kartiamoldoyoniaske," 196o. 59 p.
(MIRA 151-11)
(Moldavia,:-Industrial organization)

PROST0111OLOTOV, F; PETRYAKOV, A.
(Light industx7 in Moldavia during the seven-year plam)
Legkaia promyshlemnost' Ifoldavii v semiletka. Kishinev,
Kartia iroldoveniaske.. 1960. 94 p. (MIRA 15:3)
(Moldavia-Industries)

DRIZIN'B.; KUIAKOVSKIY, A.; PROSTOSERDOV, A.
Air-supported buildings for grain storage._, Muk.-elev. prom.
27 no.10:14-16 0 161. (Mm 14:12)
1. Gosudarstvennyy komitat zagotavok Sove -ta Ministrov SSSR (for
Drizin). 2. Gosudarstrennyy institut po, proyaktirovaniyu
predpriyatiy mukomollno-krupyanny i kombikormovoy pro-
myshlonnosti i ele-vatorno-okladekogo khozynystva (for Kulakovskiy.,
Prostoserdov).

RABINOVICII, A.I. kand.tekhn.nauk; PROSTOSERDOV~ A.N. inzh.
- --
Granary with a precast roof. Bet.i zhel.-bet.
161.
construction)
(Granaries)
no.8:345-348 Ag
(MIRL 14:8)
(Precast concrete

C t
SOVAILY, I.G., kandidat tekhnic.heskikh nauk; redaktor
izdatel'stva; VOROVNEV. N.K.. tekhnic6skiy redaktor
[Safety manual for concrete worimrs] Plamiatka po tekhnike bezopasnosti
dli*a betonshchike. Isd. 2-oe, ispr. Moskva, Goo.izd-vo lit-ry po
stroit. L arkhtt., 1956. 23 p. (KLRA 10:8)
(Concrete--%Ufety measures)

DAV7DOV, Natan Isakovich; JPROSTOSERDOV, A P ., red.; VAGIN, A.A., red.12d-va;
KARASBY, A.I., tekhn.red."---
(Industrial oxygen plants] Stantaii tekhnologicheskogo kielo-
roda. Moskva, Goo.nauchno-tekhn.izd-vo lit-ry po chernoi i
tovetnoi metallurgii. 1959. 302 p. (MIRA 13:2)
(Oxygen)

e 7,
GUROVSKIY. N.Ya.; nObVOSXRDOV, A.F., redaktor izdatellstva; STEPANOVA, B.S..
To-r
tekhaichaskiy redak !~
[Safety mewal for gas welders and metal cutters] Parmiatkm po
tekhnilm bezopasnosti dlia gazoavarshchiks i reschike metalle.
Moskva. Gos.izd-vo lit-ry po stroit. L arkhit.. 1957- 15 P-
OCLRA 10:10)
(Gas welding and catting-Safety measures)

TRI
S
JAZAJMV, D.I. PROBTOBAMV,..A.P. redaktor isdatelletva; BOROVNIIV. N.K.,
tokhniclaswr%7---recLaRV6r-----*"
[safety manual for drillers] Famiatics po tekhnike besopasnosti
dlia buril'shchike. Moskys. Goo. Isd-vo lit-ry p0 stroit. i
arkhit, 1957. 18 pe (KLR& 10:7)
tBoring-Safety measures)

WA
Tj
-V C
DANILOV, F.P.; GRIG~aIYANTS. A.S.. spoteredaktor; PROSTOSWMV, A.P..
redaktor Isdatelletva; BOROVUV, N-1-1
[Safety manual for scraper operators] Famiatka po tekhnike
besopasumett dlis skreperists. Xoskva. 4s.isd-vo lit-ry po
strolt. I arkbit., 1957- 21 P- 012A 10:7)
(Scrapers)

CKMOKOV, A.S., inshener; PROSTOSERDOV redaktor; TORO. A.M., tekhni-
cheskly rodaktor.
13&fetY VlaDUAl for operstpre of rolling. cutting and punching presses.]
Pantatka po tettnike besopasnostl dlia rabotalushchikh na pravillnykh
valltl8kh, nozhnitsakh I dyroproblynykh pressakh. Moskva, Gos.izd-vo
li~-ry po strolt. I arkhitekturs, 1955. 23 P. (MLn 9:5)
I.Russla (1923- U.S.S.R.) Ministerstve strottellstva predpriyatiy
ustallurgicheakoy i khimichookoy promythlennosti. Upr-- '--- ---~bochlkh
kadrov. truda I byte.
(Power presses--Safety measures)

/Ty
DANILOV. F.P.; GRI~ORITANTS, A.S.. spetaradaktor; PROSTOSIMV, A.P.,
redaktor izdatel'stva; BOROYNIT. N.K.. t~zrnZe_QI~"f*
LSafsty manual for operators on caterpillar cranes] Paniatka po
tokhalke bazopasuosti alia abinIsta gusenichnogo krams. Moskva.
Gos.izd-vo lit-ry po strott*? L arkhtt., 1957. 22 p. (KLRA 10:7)
(Cranes, derricks, etc.--Safety awasures)

SULIZaNKO, K.M.; PROSTOSERDOV,.A.P., redaktor izdatellstva; BOROVXIV, N.K.,
tekhni a he srrrrwdwmoi~
[Safety manual for firing boiler furnacenj Famiatka po tekhnike
bezopasnosti dlia kochegarov kotellnykh ustanovok. Moskva, Gos.isd-
vo lit-ry po stroit. i arkhit., 1956. 19 P. (MMA 1M)
(Furnaces-safety measures)

GORBATOV. V.I.; FROSTOSERDOV, A.P.. radaktor 12datellstva; DAKBNOV, V.S.,
tekhniche
LSafety manual for plasterers] Famiatka po takhaike bezopasnosti
dlia shtuiraturov. Izd. 3-e. ispr. i dop. Moskva. Gas. 12d-vo
lit-ry po stroit. i arkhitekture, 1956. 26 p. (MMIA 9:8)
1. Russia (1923- U.S.S.R.) Ministerstvo stroitel'stva. predprya-
tiy metallargichaskoy i khimicheskoy promyshlonnooti. Upravlentye
rabochikh kadrov, truda i byta.
(Plastering--Safety measures)

Ammov, Ta Ih,; PROSTOSJRDOY, A.P., redaitor izdatel'stva; MILINICMMKO,
Y.N.: t khRr69A'VtY"VA~-
[Safety manual for operators of lathes and milling, planing, and
grooving machines] Pamiatka po tekhniks besapasnosti d1ta rabotaia-
shchikh na. tokarnykh overlil8nykh. froserrqkh, strag&llnykh I dol.-
beshafth ate,alralch. Ixd. 2-os. Moskva, Go*. izd-vo lit-ry po stroi-,.
I arkhitekture, 1955. 28 P. (MLRA 9:7)
1. Russia (1923- J~S.S.R.) Ntnisterstvo stroitel'stva pred-
zetallurgichaskoy i khtmicheskoy piom7shlennosti.
Upravleniye rabochikh kadrov. truds. i byta.
(Machine-shop practice-Safety measures)

IAZARJIV, D.F., inzhener; FROSTOSMOV, A.P., redaktor izdatelletva;
MELIMICHINKO. P.N.. tekRZfEe-bil-redaktor
[Safety manual for workers putting raw brick into kilns and drawing
the fired brick from them] Pamiatka Po takhaike bezopasnosti dlia
sadchikov syrtea i vygruzchikov kirpicha iz obzhigateltn3rkh pechei.
Moskva, Gos.Azd-vo lit-ry po stroit. i arkhitakture. 1956. 28 p.
(NLRA 9:8)
1. Russia (1923- U.S.S.R.) 14inisterstvo transportnogo stroitell-
stva. Otdel rabochikh kadroy. truda i zarabotaoi platy.
(Brickmaking--Safety measures)

ACC NR: o
AP7002411 SOURCE CODE: UR/0363/6 [66~1 12/2252/2254
AUrHOR: YestaVyeva, G. N.; Prostoserdova, I. V.; Pumper, Ye.. Ya.
ORG: All-Union Electrotechnical Institute im. V. 1. Lenin (Vsesoyuznyy elektro-
tekhnicheskiy institut)
~:TITLE: The effect of annealing on the electrical property on indium antim"onide
ISOURICE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. 2, no. 12, 1966,
12252-2254
!TOPIC TAGS: indium antimonide semiconductor, semiconductor conductivity, pn junction,
jpnp junction, annealing
ABSTRACT:
A study was made7 of t1ie'*causes of inversion of electrical conductivity after I
annealing n-type InSb semiconductors. Annealing axperirants were carried
out at 410 or 48OCin vacuum with I ram thick InSb wafers with 10 14 cm- j
donor conceatration and 100 cm-2 or 104 cm72 dislocations density. Also,
experirents with zinc diffusion were conducted at 440C before a;,,d after
annealing. Inversion of electrical conductivity was found to depend on
dislocations density and on the interaction of the semiconductor with z1he i
Card 1/2 UDC: 546.682'861:541.12.03

i ACC NR- AP7002411
ambient. -med-lu'm' and -was cau'sed by vaporization of In'and -Sb atoms. The--
greater vaporation from the surface defects of the wafer than froz. its
interior explained the higher concentration of acceptors on the surface of
the annealed specimens. The Cu and Mg impurity atoms which were detected
in the InSb wafers were separated from the surface defects by annealing
and contributed to an additional accumulation of acceptors near the surface.'
The p-n-p junction was formed in the InSb wafers by annealing at 480C and
by subsequent Zn diffusion or vice versa. This was due to the chemical
reaction below the diffusion layer between Zn atoms and the impurity atoms
.which were-separated by annealing from the structure defects in the.bulk of
the wafer and which were diffused to the surf ace._O_rjg__aZt#_jjas. _2 figures.
SUB CODE: 20/ SUBM DATE: 24Jun65/ ORIG REF: 004/ OTH REF: 005'
ATD PRESS: 5111
Card- 2/2

PUMPER, Ye.Ta.; PROSTOSERDOVA, I.V.
Zinc diffusion in Indima antimonide. Fiz. tTer. tela 6 no.3:
899-902 Mr 164. (MIRA 17:4)
1. Vsesoyuznyy elektrotekhnicheskiy institut imeni Lenina, Moskva.

_7 j-
..........
AGGESMON IMS AP449856 S/MW64/006/003/08W/09M
'Abvions Pumper, Ye. TA.; V.
TITLE: Diffusion of zinc in indium antimonide
SOURCE:. Fizlka Wardogo telas v, 6. no, 3# 1964, 899-9o2
TOPIC TAGS: single crystal, indium a~timonide;v- electron hole transition, atom
capture probability# diffusion coefficient
ABSTRACT: The airtributica of zinc concentrations by diTfusion into m=o=ysA#1*m3J1=1
n-type indium antimonide has been investigated. The four-probe technique was
used to measure the concentration level at 77K* The accuracy in determining
electron-hole transition denth was 2r3 ~A. The criginal material cont4ined a
donor admixture with a 1014'-1015/cm~ Concentration level. The zinc concentration!
.distribution curve is found to have a stop form. To solve approximately for the !
equilibrium and homogeneous concentration No oftraps, the assumption'is mad; that''
'he probability of nondimensional atom, capture by the traps is unity, while the
~probability of atoms leaving the traps is zero. This leads to an &-cpression for
'No.in terms of diffusIion coefficient and rate of cross-section,transfer, Compar-
-Cid~/2

ACUSSION NR: AP4019856
ison with the experitiental results shows satisfactory agreement, despite the
:simplicity of the analytic approach, Orig. arb.'hast 5 formlas., 2 figures, and
;1 table*
ASXCIATION: Vseaoyuzromy elektrotekbaicheoldy institut.U6 Vo 1, Leninas Moscow
(All-Union Electrotechnical Institute)
samTEDi 18oct63 DATE ACQs 33mar64 ENCL: 00
,SUB CODE: PH 50 W SOVS 000 OTMt 009
C04/2

GELIFAIM, M.S.; GIZYZER, G.D.; PETRAKOV, I.S.;
SAAKYAN, S.M. (Moskva)
Structure and content of the mathematics course in grades
9-3.1 of the evening (staggered) secondary general schools.
I (MIRA 15:7)
Mat. v shkole no.3:46-47 14~~e 162.
(I-Sathematics-Study &W teaching)

I. A.43-66 EWT~m,~/EWP(t)/&ffl(b) LJP(ULE JD
AL;C MR: 0 so CODE: UR/0181/65/007/011/3255/3259
AUTHOR: Prostoserdova, 1, V.; Pumper, Ye. Ya.; Troneva, N, V.
ORG: All-Union Electrical Engineering Institute (Vsesoyuznyy elektrotekhnicheskiy
institut im..V. I. Lenina); State Design and Planning Scientific Research Institute.
;of the Rare Metals Industry, Moscow (Gosudrastvennyy nauchno-isaledavatellskiy I
proyekItnyy institut redkometallichesk.0y promyshlennosti)
JITIX: Mechanism of the anomalous diffusion of zinc in indium antimonide
3-7
SOURCE: Fizika tverdogo tela, v. 7. no. 196S, 3255-3259
TOPICTAGS: zinc, indium compound, antimonide, metal diffusion
ABSTRACT: Various models have been proposed to explain the anomalous diffusion of
~zinc.in AIIIBV compounds. Nearly all these models are based on the assumption that
the:zinc atoms exist in'two state S1 and S2 with different coefficients of diffu-
sion D1 and D2 and concentrations C1 and C2. The.author conducts experiments to re-
cord both diffusion fluxes for zinc in indium antimonide. The zinc was diffused in-
.to~n-InSb plates at 4400C and the specimens were then annealed for various periods.
Card 1/2

5363-66
:ACC HR: AP5027402
.The distribution of acceptor concentration was measured by the probe method, and
total number of Zn atoms was measured by the local x-ray spectral method. The
.experimental conditions.made it possible to record two separate diffusion fluxes of
,zinc in indium antimonide with comparable surface concentrations and coefficients
DI.= 3-10 10 CM2-sec-I and D2,< 10_3DI. Probe measurements of Zn con-7
,centrations.in InSb indicate that the S2 state is substitutional. The experimental
.data indicate that the form of the distribution curve is determined by interaction
Pbetween the two diffusion fluxes. The mechanism of this.interAction may be simi -
~ilar to the trap mechanism (Ye. Ya. Pumper, I. V. Prostoserdovi, nT, 6, 899, 1964)
!or to the mechanism responsible for diffusion of charged and neutral zinc atoms
10. W. Allen, r. Phys. Chem. Sol., 15, 134, 1960). Orig. art. has: 3 figures.
'CODE, j
iSUB SUBM DATE. 09Feb65/ ORIG REF: 005/ OTH REF: 003

r-ROSTOSINSKTI, B.
Problems, putei iz Sibiri v Zapadnuiu Mongolilu. ffhe problem of routes from Siberia
into Western Mongoli_j. (Kobdookii i UliasutaiBkII raiony). (Zhiznl Sibiri, 1926,
no. 1-2 (41-42), p. 103-108).
DLC: HC483.Z5
SO: Sovie& Tranquortation ar 2M
A Camunicati Bibliographyp Library of Congress,
Reference Department, Washington, 1952, Unclassified.

PROSTOV, A.
"The nesting of the thicker bill sea gull Gelochelidon nilotica nilotica Gmelin
in Bulgaria."
p. 603 (1zvestia) Vol. 7. no. 7, 1956. Sofia, bulgaria
SO:: Monthl~ Index of East buropean Accessions (EFAI) LC, Vol. 7, no. 5, May 1958

PROSTOVI A.
PH05TuV,A. 'How data on tho ornitho-faima of Lho BuIparian Plack Fwa
coast. P. h5l. Vol. 4/5, 1955 VV&STILA, SoMa, Dulparla
SOURCE: East European Accessions List (EEAL)
, Vol. 6, No. 4--April 1957

I
. .- FROSTOV Al
Studies on the ornithofauna in the Fetrich region, Sout1western
Bulgaria. Izv Zool inst RkN no.13833-77 163.