SCIENTIFIC ABSTRACT POSPELOVA, L.A. - POSPELOVA, Z.K.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
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• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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POSPELOVA, L. A., Cand Chem Sci __ "Certain complex-acid oompounda of cerium-N."
Mos, 1961 (Min of Higher and Secondary Specialized Education RSFSR. Mos
Order pf Lenin and Order of IAbor Red BRruier Stnte Univ im M. V. Lomonosov).
M, 4-61, 187)
-75-

GOWVNYA, V.A.; POSPZIDVA, L.A.; BOLOTOVA, G.T.
.-I ...........
Acidocomplax compounds of cerium(IV) and uranium(IV). Zhur. neorg.
khim- 5 no*10:2204-2210 0 160. (MIRL 13:10)
1. Institut obshchey i neorganicheskoy khimii im. II.S. Kurnakova
Akademii nauk SSSR.
(Cerium compounds) (Uranium compounds)

GOI,OvffA, V.A.; FWPWYA,.7 L.A._.
Carbonate compounds of trivalent cerium. Zhur. neerg. khim. 3
no.10:2253-2260 0 '58. (MIRA 12:3)
(Cerium compounds)

5(2) SOV/78-4-7-44/44
AUTHORS: Golovnya, V. A., Pospelova, L. A.
TITLE: Reply to an Article by D. I. Ryabchikov "On the Valence State
of Metal in Cerium Tetracarbonatell (Otvet na stattyu D. I.
Ryabehikova 110 valentnom sostoyanii metalla v tetrakarbonate
tseriyall)
PERIODICAL: Zhurnal neorganicheskoy khimii? 1959, Vol 49 Nr 79
pp 1699-1701 (USSR)
ABSTRACT: The authors investigated the potentiometric data of D. 1. Ryab-
chikov and are not able to confirm his statement about a
tetravalent Ce in the guanidine complex with a formula
(CN3H6)4 [Ce (C03) 4].2H20- Their titration with Mohr's salt and
with KMnO4 (Figs 1,2) lead to different results. They maintain
their opinion concerning a trivalent Ce and the formula
(CN311 6)5 [Ce(CO 3)4* 2H20] and show (Fig 3) the variously struc-
tured crystals of the two compounds, which exclude an error.
There are 3 figures and 2 Soviet references.
Card 1/2

SOV/78-4-7-44/44
Reply to an Article by D. I. Ryabchikov "On the Valence State of Metal in
Cerium Tetracarbonatell
ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. N. S. Kurnakova
Akademii nauk SSSR (Institute for General and Inorganic
Chemistry imeni N. S. Kurnakov of the Academy of Sciences,
USSR)
SU13MITTED: March 3, 1959
Card 2/2
usrAw-Dc-6i,?-
.5s

S/078/60/005/05/09/037
~2,3 0 o B004 B016
AUTHORS: Golovnya, V. A., PosT)elova. L. A.
TITLE: Carbonate Compounds of Tetravalent Cerium
PER]LODICAL: Zhurnal neor,-~~, kbimii, 1960, Vol. 59 No. 5,
pp.
TEXT, This paper was intondlcd Lo -Judy the capability of Ce(IV) of forming
cot;:-,J(,xF- A mainly on carbonate bas-is, v.nd to attempt to synthesize a con-
pound containing more carbonvAe groups thon the pontacarborlate of Lortic'
(Ref 3). The authors de~ic~ribc the follo%rin~,, ,' yfithcues- 1) sodium pentacarbo-
ceriate Na 6[Ce (CO 3)5 ff 201-1 1H 20(analysis in t.-.blo 1 , thermogram in Pie. 1)
2) guanidine pentacarboceriate (CN3H6)6 Ece(C03)5 H 201 H20 (analysis in
.ta-ble 2), and the same coml.ound with 3 molecules of crystallization wator
(Table 3) and 4 moleculc~s of cry stv.1 1i 7.atiori water (Table 4); 3) guanidine
ammonium pentacarboceriate ij'H 4(CN 3H6)5 EC e(CO-)2 H201 -4H20 (Table 5);
4) cobalt(III)-hexammine-Denta~~arboceriate o(NH ECe(CO H -5H
ec 3)6'12 3)5 A 20
Card 1/3

69Qsik~ 6- 'J~r__3 ~
Carbonate Compounds of Tetravalent Cerium S/078/60/005/05/09/037
:BO04/BO16
(Table 6). Fig. 2 shows the thermogram of th-is compound with 4 molecules of
crystallization water, Pig. 8 without cry4'stallization'water; 5) potassium
pentacarboceriate K 6 1Ce(C03 )5H201 .1'f"? 0 (Table 7, thermogram Fig. 7). On the
basis of the paper by Yu. M. Tolmachev-(Ref. 10)*the tetracarboceriates cor-
responding to the compounds of Th4+ were expected to occur, and their syn-
thesis was carried out: a) the guanidine salt (CN 3R6)4 [Ce (C03)4(H20)2]
with different crystal water content (Table 8, thermo'grams Pigs. 3,5,6), and
the guanidine ammonium salt (NH 4)2' (CN311 6)2 [Ce(C0 3)4 (H20)2 ] (Table 9,
thermogram Fig-E4~~JjFurther, the ammo*nium cobalt(III)-tioxatnmine-hoxacarbo-
ceriate (NH 4)2 C0. 3)6]2 [Ce(CO3)6j,4'f2O waa syriLhossized (Table 10). It
may be seen from the thermograms that the tetracarboceriates contain two
molecules of water in the inner sphere,,the pentacarboceriates only one,
and the hexacarboceriates none at all. The structure of these compounds is
schematically shown in Fig. 9, The potentiometric titration of gunnidine
pentacarboceriate (Table 11), and of ammonium Guanidine tetracarboceriate
(Table 12) is graphically shown in Fig. 10. The results are-indicative of an
2-
unequal bonding of the CO 3 -groups in the inner sphere. The coordination
Card 2/3

fen.I[ 6915-:,v
Carbonate Compounds of Tetravalent Cerium S/078/60/005/05/09/037
B004/BO16
number of tetravalent Cc equals 8 in its carbonate complexes. There are
10 figures, 12 tables, nrid 14 refe'relvicta, 4 of which fire Soviet.
ASIOCIATION; Institut obohchey i ticorf,-anicheskoy khimii im. It. S. Kur-
nakova Ak,,doviii natil" SSSR (Institute of Genorrl and In-
organic h. S. Kurnakov of the Ac-dem.71 of
Science's ('f 111(1- ff"!If')
SUBMITTED: November i1, 105r~
Card i/'-*

cl~ 5 f-'F- L_V V fj, L
USSR/Nledicine Whooping cough
Card 1/1 Pub 148 - 11/36
FD-2310
Author Zakharova, M. S.; Dadash'yan, M. A.; Bostrem, G. G.; Pospelova,
L. A.
Title : Application of biomycin for the treatment of patients with whoop-
ing cough
Periodical : Zhur. mikro. epid i immun. No 2, 34-37, Feb 1955
Abstract : Describe favorable results obtained in the therapy with biomycin
of whooping cough affecting children. One reference, USSR, since
1940. Two tables.
Institution : Division of Children's Infectious Diseases, 2 d Moscow Medical
Institute imeni I. V. Stalin; Institute of Epidemiology and Micro-
biology imeni N. F. Gamaleya, Acadeqr Medical Sciences USSR
Submitted : july 8, 1954

AUTHORS: Golovnya, V. A., Pospelova, L..
TITLE: Carbonate Compounds of Trivalent Cerium (KarbonatWje soyedineniya
trekhvalentnogo tseriya)
PERIODICAL: Zhurnal neorganicheskoy khimil, 10,58, Vol 3, Nr 10, pp 2253-226o
(USSR)
ABSTRACT: The complex carbonate compounds were ascertained by systematical
investigations. The synthesis that is formed by cerium-dicar-
bonate complexes together with ions of ammonium and sodium was
described. The complexes of cerium-dic-arbonate have the fclioz-
ing empirical composition:
'Ila2CO3 Ce2(co 3)3' 12 H20
K 2C0 3' Ce 2(CO3)3* 112 H20
(NH ) CO Ce ) 0 H 0
4 2 3' 2(CO3 3" 2
T12co 3* Ce 2(003)3' 6 H 20
These complex compounds are ex-%ressed by the following stoichio-
me tric f ormulae: Me [Ce (CO,) 2] . n H20.
Card 112 Dicarbonate-cerium complexes are soluble in excess alkaline 0~
carbonate solutions. The totra- and pentacarbonato complexes

Carbonate Compounds of lilriva]'.ent Cerium,
SOY/78-3-10-655/35
cerium .,.,ere produced. The tetracarbonate-cerium complex was
isolated by guanidine and cobalt hexamine: (CIT 3H6) 5[C e(CO13)41
2 H 0 and Ce(CO 15 H 0.
2 [Co (Y-H3) 61 51( 3)4] 3* 2
The synthesis of compounds of pentacarbonate-cerium complexes
was also carried out by guanidine and cobalt hexamine:
(NH ) Co(I-TH ~e 12 H 0 and
4 5 1( 3413 (C03)512' 2
(CN3H6)5 [Co(NH 3~613 [Ce (C03 512- 12 H20.
The compounds of 'the pentaca~rbonate of cerium are coarsely
crystalline and show a distinct yellovi-orarge color. The compounds
were analytically, cryStalOD'.ically and thermographically
vestigated. It can be seen from the thermogram that three effects
appear: the first at 801C, which corresponds to the dehydration,
and the third, which indicates the decomposition of the compound.
There are 6 figures, 1 table, and 13 references, 0 of which is
Soviet.
SUBMITTED: May 16, 1958
Card 2/2

2 72- L) S/078/60/005/010/022/030/,:-K
.5-,:2- c) 'BO17/BO67
AUTHORS: G Pospelova, L. A., and Bolotovaq G. T.
TITLE: Acido Complex Compounds of Cerium (IV) and Uranium (IV)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1960, Vol- 5, No. 10,
pp. 2204-2210
TEXTj On the basis of the coordination theory, the authors derive genetic
series of complexes of tetravalent uranium and tetravalent cerium with
different acid addenda. Table 1 shows such series of uranium (IV) and
cerium (IV) from diacido- to hexaacido sulfate complexes. The coordination
number of complex compounds of cerium (IV) and uranium (IV) is 8. Water
enters these complex compounds as inner addendum so that in all cases, even
when not all places are occupied by acido groups, the coordination number
is 8. The thermographic analyses of the sulfate compounds of uranium kliv)
and cerium (IV) indicate that four water molecules are contained in the
inner sphere of complex compounds. Table 2 shows the dehydration tempera-
tures of cerium (IV)- and uranium (IV)-sulfate complexes with eight water
molecules and with four w-ter molecules. The distribution of the addenda
Card 1/3

85605
Acido Complex Compounds of Cerium (IV) and S/078/60/005/010/022/030/XX
Uranium (IV) BO17/B067
in the inner spheres of penta- and hexasulfate complex compounds is di-s-
cussed. It is assumed that bivalent acid radicals are also capable of
occupying two coordination places. The authors succeeded in syntbesizing
the following complexes with two different acid addenda by partial,
gradual exchange of the addenda of the inner sphere: .
Rb (C 0 ) (SO ) AH 0; (NH4) U ) (so )~ -41[20;
4Fu2 2 4 3 4 351 2 6112(C204 3 4
RbI6 r2 (C20') (SO 4) 4] '4H20; (CN3H-6)317H4F~U C 0 3) 3C2O~-nH 20;
(Ciff H ) (rm CO .6H O;(CN H H 1~e (CO ) F
3 6 8 4~2[U2( 3)8C2014 2 3 6 5 4~ 2 3 5 4 So
6)3 (NH4)3[0e(CO 3) 4S0 4J.H 20; (CN 6 4 (NH 4 4[Ce (C'3)4 )0
(CH3K. 3H ) 4 j
(CN3H 6)3 (NH 4)2 Ice(CO3)3 F3]~ ;(CN3H6) 3(NH4) 3[C e (C03)3 F,,~. The synthesis of
these compounds and their properties will be describi in subsequent
papers. There are 4 figures, 4 tables, and 16 references: 1 Soviet.,
1 Canadian, 1 Danish, 12 German, and 2 Italian.
Card 2/3

85605
Acido Complex Compounds of Cerium (IV) and S/078/60/005/010/022/030/XX
Uranium (IV) B017/BO67
ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. N. S.
Kurnakova Akademii nauk SSSR (Institute of General and
Inorganic Chomistry imeni N. S. Kurnakov of the Academy of
Sciences USSR) ------
SUBMITTED: November 14, 1959
Card 3/3

GOLOVIffA, V.A.; POSPBLOVA, L.A.
Carbonate compounds of tetravalent cerium. Zbur.neorg.khim.
5 no.5:1036-1043 My 160. (MM 13:7)
1. Institut obahchey i neorganicheakoy khimii im. N.S.
Kurnakova Akademii nauk SSSR.
(Cerium compounds)

POSPELOItA,,.,;.r -A.; ZAYTSLTA, T.F.
Trivelent c,~!rium azetate compownds. Zhu,-. neorg. khl~im. IlCi
no.5tlO97-1106 My 165. 18~01,
1. Institut obshchey i neorganiches~oy khimii imen'. Kurnak----.,a
AN SSSR.

PTCTUGTIUm V*P,,, vrach;_~.WPMr.,;-;A vrach
Treatrient or --%h3nq=s at a stomtologiml- polyclinic.
Vop, obshcbc!i stm. VtW-69 164o (MRA 18-n)

LAPITSKIY, A.V.; POBPXWVA, L.A.; AWAMONOVA, To.P.
1
Study of the dissolving action of water and of mineral acids on
niobium and tantalum pentoxides. Zhur.noorg.ldilm.1 n&.4:650-659
Ap 156. (VI-RA 9:10)
I.Meskovskiy gesudarstvennyy univernitat Imeni H.V.Lomeasseva.
(Oxides) (Solubility)

KUPRITANOVA. A.1.; ONELOCHENKO. A.D..J.o. Glaynogo metodista; YRRMOLANKO,
I.V.; POSPSLOVA, L.P.; ZROAVIXY.,N.N.; GRIGORIYXV, V.Y., otvettstyen-
nyy RSIATA, G.A., redaktor; PAVLOTA. N.M.. tekhniche-
skiy redaktor
(The wVolga W&lley8 pavilion; a guidebook) Pavillon OPovolzh1e;
putevoditall. Moskva, Goes izd-vo selkhoz. lit-ry, 1956. 29 p.
(MLRA 9:12)
1. Moscow. Vaesoyuznaya sellskokhozyaystvennaya vystavka, 1954-
2. Direktor pavilgona (for Zhuravlev)
(Volga Valley--Agriculture)
(Moscow-Agricultural exhibitions)
Card 1/1

ABRAMOV, Nikolay Nikolayevich, prof., doktor tekhn. nauk; F-O~~,
Fargarita Mikhaylovna kand. tekhn. nauk; SKVORTSOVA, I.F.,
tekhn. red.
.9
[Design of water conduit networks] Reschet vodoprovodr7kh setei.
2. izd., perer. i dop. *sVva, Gosstroiizdatp 1962. 2Z7 p
(MMA 1; 15)
(Water-supply engineering)

C
Dl~-sertaticn: 'IT-e-c-'r.,rological Amilybis or t~c YeUic,i~ for Plarmin~. !.,ml Cnic-111vi-ior'.
Ci~%r S=,Iv 3~,-stt-e:ns in t*,-.e t7-"L and :3~1*---!~tv C, z. z
f F
Yoscow Cr-ler of the lzbp-r Red 7-~- nn c- 7-nr*,'nec-rJ-r-- lr s t
27 Jun 47.
se, : Ilechernvaya Yoslrva, Jun, 1 7, c e c 17 6

0 go 4-4-0-0-0-6 Q-0-0- _a
1 41 GI a I W 011111,1114 "is is aIt 0a J4 16 a IfaIIs it Uit m 11 It vu I.
1-1 AA 14 U0It
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UPSHIIII., V.V.; POSPEI,nVA., N.A.; GRINBUkT, V.N.; Prinima-li uchastlye:
O.Ya.
Effect of the structure and molecular weight of polypropylene
on its properties. Plast, massy no.2:20-22 166.
(MIRA. 19:2)

A11DREY-EV, A.S.; I!QBPFWVA. N.A.
Determination of small amounts of phosphoz-us, calcium, mag-
nesium. and copper in complex alloy steils. Trudy LPI no.201:
56-76 '59- (14IRA 13:3)
(Phospborue-Analysis) (Calcium-Analysin)
(14agnestun-Amlysio) (Copper--AnalyBis)

POSPELOVA,N.
Vegetable and fruit gardening enthusiasts. Sov.profsoiuzY 3
no.8:53 Ag'55. (MLRA 8:10)
1. Instruktor Yaroslavskogo oblastnogo soveta profsoyuzov
(Yaroslavl Province-Working-men's gardens)

BARSOV, Rikolay Nikolayevich, dotsent, kund.geograf.nauk; BONIFATIYAVA,
Lidiya Iveno-,rna, dotsent, kand.geograf.nauk; BURENKO, Sergey
Fedorovich, dotsent, kand.geograf.natd,.; GITLITS, Secen Aieksaadro-
vich, dotsent, knnd.ekonom.nauk.; GU.UVICH, Priam Vladinirovich, prof.;
DARINSKIY, Anatoliy Viktorovich, dotsent. kand.geo.-raf.nauk; DCLININ,
Alekaey Arkadly8vich, dotsent, kand.geograf.nauk; DOROSMVICH,
Lyudmila Ivanovna, dotsent, kand.,-eograf.nouk; YETIMOVA, Yelen3 Se-
menovna, kand.geopraf.nauk; LATROV, Sergey Borisovich, dotsent, kand.
geograf.nauk; L-EDOVSKIKE1, Stepan Ivanovich, dotsent. kand.geograf.
nauk; NEVELISMYN, Grigoriy Solomonovich, dotsent, kan4.geograf.
nauk; NIKCLAYEVA, Nadezhda Vasillyevna, dotsent, kand. eograf.nauk;
OGAUESOV, Vladimir Artemlyevich, kand.goo-raf.nauk; PINKMSON,
Dmitriy Moiseyevich, dotsent, kand.geograf.nauk; POSP OVA, Nata-
liya Geor_-iyevna, prof.. dolctor ekonom.nauk; SEMEVSKIY, Boris Nikola-
~6i~ich,-'prof.-,-'doktor geograf.nauk; SUTYJAGIN, Pavel Grigorlycvich,
dotsent, kcand.geograf.nauk; SHTHYN, Viktor Moritsovich. prof.. doktor
ekonom.nauk; YEROFMV, I.A., red.; SKIRNOVA, N.P., red.; TYMUNHIK,
S.G.. red.kart; BORISKINA, V.I., red.kart; K02LOVSEAYA, M.D.,
te k1ul. red.
CEconomic geo.-raphy of foreign countries; student unnuall Nkonomi-
cheskais gaografiia zarubezhnykh Btran; posobie dlie studentov. Moskva,
Gos.uchebno-peda--og.izd-vo M-va proav.RSFSR, 1960. 702 p. .4 maps
(MIRA 13:12)
(Geography.3conomic)

POSPELOVA, N.N.; PAVLOVA, Z.Ye.
Possibility of false positive serologicall reactions to sy-
y
in examinations of blood doror plasma. Pro'bl.ge=-a-t-i ;:,e--e,,
krovi no.5.156 ?62. (MIRA 15t8)
1. Iz,.Ivanovskoy oblastnoy stantsii perelivaniya krovi Idir.
N.V. Samoylova, nauchnyy konsul2tant - prof. P.M. Makelmov)
i Ivanovskogo oblastnogo kozhno-venerologicheskogo dispansera
(nauchnyy rukovoditell - prof. M.S Bragin).
(SYPHILIS-DIAGNCSIS) ?BLOOD DOIIORS)

POSPELOVA, Nataliya Nikolayevna; ROZEnUL,, M.A.j red#; ZUYEVAy N.K*j
tokbn;, red,
(A.I.Pospolov, 1846 - 1916] A.I.Poqmlov,, 1846-1916. Mo-
skva, Goo. iad-vo mod. lit-ry, 1962. 85 p# (MIRA 15W
(POSPELOVI ALMLSEI IVANOVICHI 1846 - 1916)

POSPELOVA, N.V.
KHO14UTOV, N. Ye. ; I
Anodic processes taking place in the electrolysis of carbonates.
Trudy NMI no.26:85-95 159. (KIRA 13:9)
(Carbonates) (Electrolysis) (Electrodes)

POSPELOVA, T.A.; KOBOZEV, N.I.
Catalrtic synthesio of hydrogen peroxide from the elments on
pallachum. Pt&t.3.- Active centers of the catalytic decomposition
of hydrogen peroxide on palladium. Zhur.fiz.khim- 35 no.6:1192-
1197 Je 161. (MIRL 14:7)
1,, Moskovskiy gosudarstvennyy universitet imeni ALV.Lomonosova.
(Hydrogen peroxide) (Palladi:um)

MIILXU,St.M.,acad.; POSTAINICU,D.; TEODORU,V.
Some observations an the structure of the pineal gland. in
aged birds and animals. Ihmanian M. Aev- 3 n0-3:14-15
Jl-S '5 9.
1. OProf. C.I.ParhonO Institute of Geriatrics,and *Dr. Victor
babes', Institute.
(PINJU BODY)
(POULTRY)
(CATTLE)
(SEDW)

Automatic Control (Cont.) SOTI/427-5
COVERAGE: The book is the third collection of reports read at the seminar
on ELutomatic control and computer engineering of the NTO priborostroyeniya
(Scientific and Technical Society for Instrument Making), the MVTU im.
Baumana (Moscow Higher Technical School imeni Bauman), and the MAI im.
Ordzhonikidze (Moscow "Order of Lenin" Aviation Institute 'Imeni Ord-zhonikidze).
It contains papers on current topics in automatic control and computer
engineering which, according to the authorare significant for the solution
of problems involved in the complex automation of industrial processes by means
of control machines and includes discussion of the design of linear and nonlinear
automatic control systems. The book covers some questions related to the
dynamics of such systems, ways of increasing operational speed, and means of
obtaining optimum transient processes. Automatic control systems involving
discrete computers, systems with variable parameters, sampled-data control
,3yst~)ms, the dynamic accuracy of these systems during random motlons, and the
theory of sampled-data systems are discussed. No personalities are mentioned.
References are found at the end of each article.
Card 2/4

Automatic Control (Cont.)
TABLE OF CORTENTS-
Foreword
SOV/4275
3
Solodovnikov, V.V. On Control Algorithms and Control Machines for Complex
Automation 5
Petrov, V.V. Stability "in the Large" and the Self-Oscillations of One
and Two Cascade Nonlinear Servomechanisms 36
Pcspelov, G.S. Sampled-Data Automatic Control Systems 1111
Getmanov, A.G. Dynamic Characteristics in Performing Certain Linear
Operations an a Digital Computer 188
Potapov, M.D. On the Nonstationary Properties of Sampled-Data Systems 218
Shatalov, A.S. Engineering Methods of the Linear Theory of Control Systems
With Variable Parameters 233
Card .3/4

Automatic Control (Cont.)
SOV/4275
Batkov, A.M. Certain Problems of the Theory of Linear Systems With Variable
Parameters During Random Actions 302
Oatrovskiy, G.M, On a Method of Improving the Quality of a Control System
by Means of Vonlinear and Computer Devices 373
Pavlov, A~A,~ V.P. Poputsillo. Design of Simple Optimal Relay Systems of
the Second Order 419
Bodner, V.A., V.V. Kazakevich. Stability of Self-Oscillations of Acoustic
Systems With Compressors and the Suppression of Self-OscillationB by Means
of Feedbacks 44~
AVAILABLE,- Library of Congress
Card 4/4 AC/rb/sfm
9/21/60

GOLOVITYA, V.A.; POSPELOVA, L.A-.__
Determination of refraction values for cerium sulfate -
compounds. Zhur. neorg. khim. 6 no.7:1574,1581 J1 161.
(MIRA 14: -1 )
1. Institut obshchey i neorganicheskoy khimii imeni N.S.
Kurnakova A-kademid nauk SSSR.
(Cerium sulfate)

POSPELOVA. Ifatallya Georgiyevna; BORISOVA, K., red.; CHEPELEVA, 0.,
-tikfiii.isd' - ' - --- 11 1...
a
[Algeria; an account of its economy and political situation]
Alshir; okonomiko-politichookii ocherk. Moskva. Izd-vo
sotsiallno-okon.lit-ry, 1959. 1o4 p. WRA iz:6)
(Plgeria-Sconomic conditions)

POSFELOVAJI Nataliya Georgiyevna.
Leningrad Finanae-Economics Inst, Academic degree of
Doctor of Economic Sciences, based on her defense, 17-
18 Juae 10,54, in the Council of the Moscow Finance Inst.
of her dissertation entitled: "Formation of National Markets
Under Conditions of a Colonial Regime Based on the Ex-
ample of some Arab Countries (Syr~ia and Lebanon)".
Academic degree and/or title: Doctor of Sciences
SO: Decisions of VA K, List no 8, 2 April 55, Byulleten'
MVO SSSR, No-14, July Moscow pp 4-22, Uncl.
JPRSATY-429

1. POSPELOVA, P. "I.
2. ussp (6oo)
4. Lenin' Vladimir Illich, i87o-1924
7-0 For the twenty-seventh anniversaxy of the death of Y. 1. Lenin. Visnyk AN MSR No. 1
1951
4
9. Monthly LiLst Lf Russian Accessions, Library of Congress, AT)ril -1953, Uncl.

ZAZ9VSKAYA., I.A.; PgSPELOVA, R.V.; SHAVRIN, O.N.
Evaluating the dimensions of mosaJc blocks by'the width of X-ray
Iii4eni Fis. met. i metalloved. 14.no.2:301-303 Ag 162. (MIRA 15:12)
.1. Petrozavodskiy go3udarstvenn7y univeraitet.
(X-ray crystallQUaphy)
j0

PCSPELOVA, T.A.; KOBCZEV, N.I.; YEREMIN, Ye.N.
Palladium catalyzed synthesis of hydrogen peroxide from the
elements. Zhur. fiz. khim, 35 no.2:298-305 F 161.
(MIRA 16:7)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.
(R~&ogen peroxide) (Heat of formation)

S/076/61/035/003/005/023
/A //c/o B121/B203
AUTHORS: -Pospelova, T. A. and Kobozev, N. I.
TITLE: Catalytic synthesis of hydrogen peroxide from elements on
palladium. II. Active centers of palladium in H 202 synthesis
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 3, 1961, 535-542
TEXT: The authors studied the active centers of the catalyst in H20 2 syn-
thesis. They discussed the mechanism of catalysis in the formation of H202
and water from detonating gas on palladium and platinum catalysts. The
catalysts were prepared by a method described earlier by the authors to-
gether with Ye. N. Yeremin (Ref. 1: Zh. fiz. khimii, 35, 298, 1961). The
effect of an inert carrier (silica gel) on the reaction rate and on the
H202 yield was investigated. Volume processes were found to play no impor-
tant role in the If202 formation. When studying the structure of active
centers of Pd in catalytic H 202synthesis, a palladium doublet (Pd2) was
Card 1/4

S/076/61/035/003/005/023
Catalytic synthesis ... B121/B203
found to be active. When comparing the activities of Pd black and of the
adsorption catalyst Pd/SiO2 (containing the same Pd amount), the formation
rate of H202 was found to be 15 times higher on the adsorption catalyst
than on Pd black. The catalytic activities of platinum and palladium in
H202 synthesis were compared; the mechanism of catalysis on Pt and Pd cata-
lysts was found to be different. Hydrogen peroxide occurs as a primary
product on active Pd2 centers, whereas water occurs on the atomic active
centers of platinum. The active Pt centers were studied in papers by one
of the authors (Ref. 6: Zh. fiz. khimii, 13, 1939; 14, 663, 1940) and by
N, A. Reshetovskaya (Ref- 5: Dissertatsiya, MGU, 1947). The higher affini-
ty of Pd to hydrogen is the cause of the catalytic formation of hydrogen
peroxide on the Pd catalyst. The following mechanism was found for the
catalysis of detonating gas on the Pd catalyst: first stage: adsorption
of hydrogen to the active Pd2 centers, and dissociation into atoms accord-
ing to:
Card 2/4

Catalytic synthesis ...
S/07 61/035/003/005/023
B121 YB203
Fp!f,,. ~ [Pd
+ H ] H second stage: adsorption of oxygen with formation of
jPd! 2 LPdj H I + - FP dI H H
i-he-adsorbed radical HO 2 or of ion pairs 11 + 110 2 : [P_~.I H+ 0 2 FTP CAI. I 10 or
FPdjH +- ; third stage: formation of H 0 or HO_ ion according to 2
P~_ HO 2 2 2
2 H
FPddj H+_ Pd + H Q or IFd + 30+
jPdIH0 2 2 ~Pd IiO_
2 in the gas- 2
eous phase in solution
The mechanisms of the catalytic reaction of detonating gas on Pt and Pd cata-
lysts differ in the cleavage of the bond of the oxygen molecule. On the Pd
catalyst, the oxygen chain -0-0- is maintained and, thus, the formation of
H2 02 made possible, whereas on platinum both oxygen-molecule bonds are cleft.
There are 4 figures, 4 tables, and 14 references: 7 Soviet-bloc and 7 non-
Soviet-bloc. The reference to the English-language publication reads as
follows: R. P. Donelly, C. N. Hinschelwood, J. Chem. Soc., 131, 1727, 1929.
Card 3/4

S/076/61/035/003/005/023
Catalytic synthesis ... B121/B203
ASSOCIATION: Moskovakiy gosudarstvennyy universitet im. M. V. Lomonosova I
(Moscow State University imeni 1A. V. Lomonosov)
SUBMITTED: June 4, 1959
Card 4/4

A rt
oo C
006
00
lo*
008
'0404
46: Y
0
00
a
a
LOWSMSEbm *I as WP-WA"W amy mod,
F II t*AC-
a# 60 Now, of "dwe assessawaa. 1. X.V; in
79a 41 &OWIlk hydledft W WdOM.- , T. &. Paspelsura..;
1. Va. Sfilya*tulth, .14, 1. Kolsitcy, and UA. Nikallic"
(State We., MUNCOW). J. /'by$. C/Min. (U-S-SX) 21,
W84(1947)(In RussLin).-The furinAtiou ul Act[ frout
CA and 11.0 in 2.3 N 11.50. in the presence of Its'*
is acceler;4ted about 2.5 times when, iustead of 1ISSO.,
nictruj. i.e.. O-ICJI,COOifscli(clikOCIIS)cli,.%,Iico
CJf.OCII.CO..Va. is used. abwt 7 times when fig - I-
1~1
adsorbed on WO&, ww about 9 tinstli when usercusal U
adsorbed on WO, or a cyclic 2=1 *and then 119
is altixtebod on WOs. The of Cyclic comptis. is
Vaster tbt greater their wal. wt.; whcyw acid was the
"Ballast and I-pbmyl.2,3*ditmtbyl4-dimethylamino-
&pyraso&we (be beaviest compd. SUbk ort. Hs
complo. asich as CJI.IlgCJ. (Cjfj),Jf1, CICILCIM&C1,
CIII&CH.C110. etc.. am km active th4n flaSO.- The
ratio of Acil to ctotonakIchydc In the reaction product is
high (over W) and indcileadcut of the adsorbent. Ad*wp-
tion of fig an active C, Siol, gel. kaolia, etc.. does not
activateit. AdKwptiano(lmth"U.OUSC.offig"by
I S. of cawill incrmm the activity of Its ", but caftin
has no C&Ct &I higher adsorbed amts, The activity 0(
Ilt " adsowbod on cassin and sane Wos samples decrease,
itben the wic r od fig to WO~ increases. this shows that the
"active ensetable" contains I ion of lit (CA. 39, W229).
in adda., gonse WOs mupia give rise to a ---. of activity',
Fit some astau F, and one sample showed only thil umx.;
from the r corresponding to the max. it is concluded that
the "active Cnsemble" contains 2 fig ions. The area at
"usigralion cvU.%" (C.A. J9, 372=V-) it- C". for W06 and
Mew. The "p. coeff.al the reaction between 40* and-
30, is smaller for fig * * or 14*01 (h4a for lIgSO1. and the
activity of fig I ~ up cascits is independent of tern Som
Stisorpsion isoilstru" for jig- on Wch am IFI~. [L-~
ass -A 149000 "if ON,, a"
lilts .09.
Caterl
Mpaymerhafim
H. . awnlinson and .14. 1. Robosev. 1W. 9640.-
%%-ftn Csllsis brought intocontact with& Wo. of CuCl and
NHXI in IM, a Cu cotupd. cmtg. about 4.3 C111, Prr I
tomCu6pptd. The condensation of CsIls is accelerated
213-20 times by introducing active C In the above soln.
The catalytic activity of an adsorbed Cu ion shows a mu.: ,
when about 6 MS. CU is adsorbed by I S. of C* this gives
4 for the no. (A Cu kns in the "active ensem6.- The
"migration cells" on the C wdwe we 30 X 10-14 cm.0
In sin. Silica gel, bentonsite, etc., cannot 'be isabatitatcd
for C. As it was believed that lid is frquirw only to
k-mp CuCl in the soln..,thc catalytic activity of Cu-SA +
carbon in a neutral soln. was tested. This catalyst was as
active as CuCl and formed "" bles" coats. 4 Ca ims.
For Cu adwwbed on C the temp. coed. between 30 and 601
is less than without adsorbent. The lowering of the teinp.
coed. by adsorption is typical for ionic cat"
J.
-90
.00
041
~019
.0
.00
goo
=00
400
aoo
too
4100
goo
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woo
!200
CIOGI
11001
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li T1-
10*00660404100900006000'soo;,46 0000600*00600090
-1 *00000$oeoooooo,ooooe00000.iO*00*0*0000,0
-0000001

PITSKHEIAURI, Ye.N.; POSPELOVA T.A.-
Desulfurization with ozone of ligroin ard kerooene diatillates
of Devonian oil from the Rnmgshkino field. Izv. vys. ucheb.
zav.; neftl i gaz 3 no.3:91-98 160. (MIRA 15:6)
1. Moskovakiy gosudarstvonnyy universitet imeni M.V. Lomonosova.
(Rcmashkino region-Petrolopm-Refining)

24786
S/152/61/000/006/001/003
B103/B206
AUTHORS: Pitskhelauri, Ye. N., Pospelova, T.-A., Kruglikova, V. S.
TITLE: Desulfurization of straight-run kerosene distillate by
ozonization and adsorption
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Neft' i gaz, no. 6,
~iq6i, 81-87
TEXT: Starting from the results of previous investigations (Ye. N.
Pitskhelauri and T. A. Pospelova, Ref. 1; "Neft' i gaz", no- 4, 1960) and
ublication data (I. L. Gurevich et al., Ref. 2: Pererabotka nefti
Petroleum processing), t.2. Gostoptekhizdat, 1958, str. 158; L. G. Gurvich,
~
Ref. 3- Nauchnyye osnovy'pererabotki nefti (Scientific basis of petroleum
proc'essing),.1925, P. 515; Ye. N. Karaulovap Ref. 4' "Itogi nauki" (Results
from Science), Chapter "Khimicheskiye naukill (Chemical Sciences). Izd.
AN SSSR, 1958, P- 130), the authors assumed that the method of the oxidation
of sulfur containing fuel compounds by ozone with subsequent adsorption of
the oxidation products, will considerably increase the effectiveness of
desulfurization. The methods of ozonization and analyses were taken from a
Card 1/8

24786
S/152/61/000/006/001/003
Desulfurization of straight-run ... B103/B206
previous paper (Ref. 1). Characteristics of the investigated kerosene
distillate of Devonian petroleum from Romashki: boiling temperature
155-2550C, density 0.802, total sulfur content 0.35%, iodine number 6.6.
Alumosilicate catalyst, Cherenkov aluminum oxide, silica gel from the
Yoskresenskiy zavod (Voskresensk Plant), bentonite and activated charcoal
were used as adsorbents. The distillate was oxidized with ozonized oxygen
(ozone concentration about 0.5-1%) at room temperature in the presence of
water (5:1). The adsorption of acid products and resins was made in a glass-
and metal column, respectively. The rate of introduction of the distillate
was 0.5-1.0 ml/min. In the case of bentonite, the distillate was previously
rinsed with 10% NaOH solution at low temperature (0.5% of the weight of the
distillate). Before the process, the adsorbents were roasted at
t - 400-5000C. The adsorption effectiveness was judged by the relative con-
sumption of the adsorbent A as ratio between the amount of adsorbent in g
and the amount by weight of the refined distillate; A = g adsorbent/g dis-
tillate. The distillate was considered to be refined when its acid content
amounted to 1-2 mg1100 ml, and the resin content did not exceed 3-5 mg/100'ml.
The consumption of ozone and adsorbent was decisive in obtaining a suitable
degree of desulfurization. Therefore, the authors investigated the effect
Card 2/8

24786
S/152/61/000/006/001/003
Desulfurization of straight-run ... B103/B206
of the ozonization intensity a (a = ozone adsorption/9 sulfur) and relative
consumption of the adsorbent A on the degree of desulfurization
P (P = Sinitial - Srest /S initial ). When the ozonization intensity is
varied between 1-7 and 4-01 the optimum result (P = 96% and A = MO was
reached at a = 3. As shown in Table 2, silica gel and alumosilicate cata-
lyst are the most effective adsorbents. Tables 5 and 6 show the changes of
the distillate in the ozone-adsorption refining process. The authors
summarize their results as follows: 1) The ozonization-adsorption process
safeguards and ozonization intensity of 97% when using kerosene distillate.
The ozone consumption amounts to about 10 kg per 1 t distillate, and the
yield of the refined product to 97-98%. 2) The high effectiveness of the
ozone-adsorption process is achieved by the interaction between the oxida-
tion of sulfur containing compounds and the subse'quent selective adsorp-
tion of the oxidation products, which results in considerable desulfuriza-
tion and reduction of heat consumption during steaming of the adsorbent
to between one fourth and one fifth (as compared with the method of direct
adsorption, MNI imeni Gubkina (Moscow Petroleum Institute imeni 1. M.
Gubkin) (Ref. 2)- 3) The ozone-adsorption process yields a product puri-
Card 3/8

24786
S/1 52/61 /00C/0006/001 /003
Desulfurization of straight-run ... B103/B206
fied to a higher degree (from acid compounds and resins) than the ozoniza-
tion method, with a simultaneous reduction of the heat consumption to 6na,
tenth during the second processing of the distillate. 4) The oxidation
products formed through the effect of ozone from sulfur containing com-
pounds are selectively adsorbed to an almost equul degree by the two
synthetic adsorbents (silica gel and alumosilicate catalyst); but the
alumosilicate catalyst reduces the concentration of the peroxide compounds
in the refined distillate four times more actively than silica gel. 5) The
special tests of the refined distillate for stability showed that the
distillate can be stored in daylight for two years without deterioration of
its quality. Tests for thermal stability under dynamic conditions proved
that the purification process described increases the stability of the
distillate, specially at 1500C. Studies by Gallpern and Novozhilova
(Ref. 4) are mentioned. The specific surface of the adsorbent was deter-
mined by the senior staff member A. Ye. Agronomoy. Thermal stability was
studied at the Nauchno-issledovatel'skiy institut goryuchikh i smazovykh
materialov (Scientific Research Institute of Fuels and Lubricants) under
the direction of senior staff member Z. k. Sablina. There are 1 figure,
7 tables, and 6 Soviet-bloc references.
Card 4/8

24786
S/152J61/000/006/001/003
Desulfurization of Btraight-run ... B103/B2o6
ASSOCIATIOV: Moskovskiy gosudarstvennyy universi ,ie-t im. M. V. Lomonosova
(Moscow state tniversity imeni M. V. Domonosov)
SUB11ITTED': Fobruary 11,,.1961
Legend to Table 2: (1) Adsorbent; (2) refined.distillate, ml; (3) yield
of distillate without steaming of the adsorbent, %;.(4) degree of desulfuri-
zation, Sinitial - Sre'stISinitial; (5) relative'consumption of a.d.sor-
bent A g adsorb/g distillate; (6) silica gel; (7).alumosilicate'catalyst;'
(8) aluminum oxide; (9),activated charcoal; (10) bentonite.
Card 5/8

POSPELOVAp T.A.; KO,90ZEV, N.I.
Catalytic synthesis of hydrogen peroxide from the elements on pal-
ladium. Part 2: Active centers of palladium in the synthesis of
H902- Zhur. fiz. khim. 35 no-3:535-542 Mr"61. (MIRA 14:3)
1. Moskovskiy gosudarstvemW u~iversitet imeni N.V. Lamonosova.
(Palladium) (Hydrogen peroxide)

POSEUOVA, T.A..
Moscow State U imeni 1-'..V. LomonosovJ
POSPELOVA, T.A.: "The catal~rtic cynthesis of hydrogen peroxide from its
elements using palladium." Mioscow State U imeni M.V. L6onosov. Moscow, 1956.
(Dissertation for the Degree of Ganc1idate in CherrLical Sciences)
SO: Knizhnaya Letopis', No. 20, 1956

S Y6 010 0 O/C- 0 4 10 0 71 In- 0,7
B001' B054
AUTHORS: Pitskhelauri2 Ye. N. and Pospelova, T. A.
TITLE: Desulfurization by Ozone of Ligroin-- and Kerosene
Distillates of Devoni.an Petroleum From the RNmashk'-
Deposit
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenly. Neft-5 -' -az, 1960.,
No. 4, PP. 91 - 98
TEXT: Because of an in,-treasing share of up to 75% of sulfurous pqtrols-um
in the total, pro1uction of the USSR) the problem of efficient, desulfuri.-
zation of the.above-mentioned diatillates is of great importance. Con-
sidering the saientifi~.- and tec%hni3al progress made in ozoin0production
(Refa- 4-7)~ it is convenient~ to use th-Is strongest oxidizing agent to
desulfurize petroleum distilla%es. The present paper studiea rhe ozoni--
zation.- and temperature conditions, the naturo of the gaa to bo ozouivtd,
the water addition during oxidaticri of the sulfurous compound, and the
formation of neutral and acid products during the desulfurizing experi.-
ments of the above distillates. The opt.,.mum ozonization temperature was,
Card 1/3

Desulfurization by Ozone of L."grcin- and S/152/60/000/004/00-5/cvO3
Kerosene Distillates of Devonian BCO1/BO54
Petroleum !from the Romashki Deposit
in general, between 10 and 20 0C. The degree of desulfurization of the
distillate depends or, the intensity a of ozonizatior.: a = gozone/gsulfur*
In the case of kerosene- and ligroin distillates. the maximum desv.IfUr4-
zation degree is attained at a - 5-6. The efficiency of the desulfuriz-
ing method is determined by the desulfurization degree P (percentage
ratio of the sulfur removed to ifs initial content). In the ozonization,
not only the sulfurous but alse the unsaturated compounds axe oxidized,
which increases the acidity and the resin -,ontlent and makes a purifica,. "/
tion necessary (treatment with wa-,er, steam distillallion of the ligroin --
distillate, or vacuum distillation of the kerosene d.tatillate with ad-.
dition of Ca(OH )2 ~,o bind the acid -omponents). The sulfurous disi-illate
may be oxidized by ozonized air or ozonized oxygen (a purely economic
problem). If this process is conducted in the presen,~e of water, It is
possible to reduce the formation of resins and prevent the formation of
electrostatic nharges. The following was observed in the oxidation of
the fraction distilling over between 935 and 2350C of the Pe,roleum 'Ln--
vestigat,ed which contair-ed 0.446 of sulfur: 1) The -light sulfurous
Card 2/3

DeSUlfUrizal,ion by Ozone of Ligro-,n- and S/-52/60/000/004/003/003
Kerosen=. Distillates of Devonian Petroleum BOO!/BO54
From the Romashki Deposit
distillates are practi,:--ally fully freed from all sulfurous compounds.
2) The purified produot still. contains 0.01-0.023~ of sulfur, is free frDm
resins, and shows an. acidity of up to I mg of KOH per '00 ml, and an
iodine number of 11-4, 3) The yield in purifled dis-,illate 4-8 97% by
volume; its mean molecular weight and boiling point remain unchanged.
4) Between 6 and 9 kg of czone per 1 ',on of raw dist~lllate are used to
desulf-,irize the light d.4st--Ilate 0.14% of sulfur). There Arab'/
3 figures.. 4 tables, and 14 references: 9 Soviet. 1 US~ and 4 German.
ASSOCIATION: Moskovskiy gosudarstivennyy unlivers-"'eo. im, M-V- Lomonosova
(Moscow State Un.-.,versity imen-i 14.V. Lomonoso-)
SUBMITTED
July 20, 1,959
Card 315

9/076/61/035/002/005/015
B124/B202
AUTHORS: Pospelova, T. A., Kobozev, N. I., and Yeremin, Ye. N.
TITLE: Catalytic synthesis of hydrogen peroxide from its elements
on palladium. I. Conditions for the production of
hydrogen peroxide,
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 2, 1961, 298-305
TEXT: A comparison of the free formation energies of water and hydrogen
peroxide from their elements (-56-56 kcal for liquid water, and -28.23
11cal for liquid H202) shows that on catalysis the H2-02 reaction may
Proceed in two directions, i.e.,
II H202
H + 0 + (catalyst III where, due to the low stability
2 2
I H20
of the H202 molecules in the presence of the catalyst H202 and water are
decomposed thus causing the masking of the second process. For this
reason the authors studied the oDtimum conditions for the synthesis of
Card 1/9

sj'076/61/035//002/005/015
Catalytic synthesis of hydrogen peroxide ... B124/B202
11202 from the elements on palladium on the one hand and its decomposition
at the same catalysts on the other. The detonating gas was catalyzed in
a kinetic vessel of Shpital'skiy type. The time dependence of the H202
yield was studied on palladium black in a mixture of KCN(O.001 N) and
sulfuric acid (0.1 N) as well as on aluminum gel (YoPd - 5.47). The gas
mixture conainted of 20% hydrogen and air; the activity of the catalyat
was measured from the absorption of 2 cm3 of the mixture. The experimentnl
results are given in Fig. 1. They indicate that in both cases (mainly in
Pd/A1203) the H202 yield is strongly reduced with time although the
absorDtion of the mixture continues (6 V increases). In this case, the
initial yield exceeds 80% on Pd black, i.e., almost pure H202 is formed.
Hence 11202 is formed as primary product of the catalysis of detonating
gas. Its catalytic 6ecomposition causes the formation of water. The
authors studied the effect of a number of acids, mixtures of KCN with
different acids, ammonia and Hg2+ solutions in H2SO4 (Table 1). Without
introduction of catalyst poisons only water is formed. The most efficient
inhibitor of H20 decomposition is plumbic acid, followed by dilute HCl;
and H_2+ solutions
the effect of the other acids is weaker while NH3
Card 2/9

S/076J61/035/002/005/015
Catalytic synthesis of hydrogen peroxide... Bi24/B202
inhibit both, formaiion-and decomposition of H202. In this case, the
acids do not enter an irreversible reaction and their decrease in
quantity in the reaction is caused by absorption on the catalyst (Table
2). It was found that*a) the stabilizing effect of HCN (Figo 3) and
HC1 (Fig- 4) is especially marked at low concentrations and that it
passes through an optimum; b) the optimum synthesis of H202 is achieved
at a stoichiometric ratio of H2-"02 = 1, c) the H202 yield increases with
increasing temperature.(Table 4), and d) the acid carriers S102 and W03
give higher H202 yields than'the amphoteric A1203'(Table-5). The - ,
following scientists.are mentioned: N. I. Kobozev and V. L. Anakhin
(Ref. 3: Z.' phys. Chem., Abt. B, jj, No. 1-2, 1931), M. V. Polyakov and
collab6ra'tors'(Ref. 4: Zhs fizd-khimii, .1, 453, 1933; 1, 954, 1934;.~,
1241, 1249, 1932; Acta.phys.-chim. URSS, 2, 911, 1935), N. D. Zelinskiy
and'*M.'.B. Turova (Ref. 6: Ber. 18,'1884,-1885), P; M. Stadnik (Ref. 9:
Dokl. AN SSSR, 87, 1952; Zh. fiz. ~himii, 28, 1954), N. A. Bakh (Ref. 11:
Trudy Bakha, no. 1, Abt. 2, Kap. 1, 1937),-S. Levina and R. Rozentreter
(Ref. 13: Zh, fiz. khimii, 13, 1939), A. I. Shlygin (Ref. 14: Uch. zap.
Kazakhsk. unrta, 13, 1951), T.- V. Sokollskiy and collaborators (Ref. 15:
Card 3/9

S/076/61/035/002/005/015
Catalytic synthesis of hydrogen peroxide... B124 B202
Dokl.-AN SSSR, 11-3, 1957; 493-, 1954)- There are 5-figures, 5 tables,
and 17 references; 7 Soviet-bloc and 10 non-Soviet-bloc. 1 reference
to English-language ptiblicatiaftsreads,as follows; E. B. Maxted,, L. K.
Moon, E. Overgage, Disc. Faraday-Soc., 8, 135, 1950)-
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. it. V.
Lomonosova (Moscow State University imeni M. V..Lomonosov*)
SUBMITTED: May..14, 1959
Card 4/9

Catalytic synthesis of hydrogen peroxide...
Fig. 1: dependence of the H202 yield on the
reaction time.
Legend: 1) H 0
2 (y) yield on the Pd/A1203-
2
catalyst, ) r202 (1) yield on palladium blacki
3) absorption of the gas mixture by palladium
black A V) a) t, min.
z0
S/076/61/035/002/005/015
B124/B202
AV
of
ej
lee
9
Soo t,
Card 5/9-i

Catalytic synthesis of hydrogen peroxide...
Legend to Table 1:
1) name of the poison; 2)
concentration; 3) yield in IIA883111M flaa
H202; 4) total rate of
catalysis.of the poison in
(31~ea jTAa
the solution; 5) without HCN
poison; 6) not determined; KCN
.(A = total rate,of KCN + H2SO,
catal;tic conversion of KCN + HNO
detonating gas).
KCN + HCI
H'ASOA
HNOs
11CI
HBr
HJ
(C00103
CH3COOff
HCOOH
C6115011
N11,011
TIgCI2+HtSOt
Card 619',
S/076/61/035/002/005/015
B124/B202
Pio"ImmPeaRR MAI
B PICTSOPe (Nuxo;t
Hoot Y. %

JAIro
.
0 0 0,59 0
0,0003N 51,7 0
tI 0.06
0,0006N 37.0 0 05
: 0,02
H,SO,-0,075N 62
0 Oj5 0,10
KCN -0,0003N ,
HNOs - 0 025A'
W 59
0 0,20 0,13
KCN -0,
3N ,
HCI - 0,025N 58
3 0,12 0,08
KCN-0,0003N ,
0 03N 38,8 0,60 0.27
0:03N 40,0 0,65 0,30
0,03N 55 2 0,80 0,50
0,0003N 46:9 0,44 0,24,
0,0002N 22,0 0,07 0,02
0,005N 25,0 0,50 0,10
O'(YAON 27,6 0.52 0.18
0 1001V 22.0 0,51 0,14
0:0,50N 0,67
He O"PeA. -
0,003N 0 0.05
1 0
119CI--O,OOtN 0 0 0
it 2S6, - 0. 1001V ...

S/07 61/035/002/005/015
Catalytic synthesis of hydrogen peroxide... B124Y3202
Legend to Table 2: 1) moles' to.
ON A04#11 R-e-z~T- Hol -MA#Q
0 2) g-atom.
2,73 -24.6 20 3 .0.076
2,90 6154 41:1 0,031
3.41 2,00 46.9 0,0ts
5,30 0,76 58 7 0007
5,30 O,t9 68:3 D:OD5
5.81 .0,10 66,1 0.003
4,78 0,02 61,3 0,001
'Fig. 3: Dependence of the total 4-3
rate oficatalytic conversion of 1,70 1o -
detonating gas and the H202 yield
on the concentration of HCN.
Legend: 1) total rate of
0\
catalytic conversion (A); 2) qj. 0 \0
E202 _(?)..yield; a) mole/l.
02 0
L L
Card 7/9-1

Si F076/61/03,c//002/005/015
Catalytic synthesis of hydrogen peroxide ... 3124/3202
'Fig- 4: Dependence of~the total rate
of catalytic conversion of detonating 14V
gas and the H202 yield on the ratio Ode
,,i6
H2:02 in the gas mixture.
Legend: 1) total rate of catalytic ja
conversion (A); 2) H202 (y) yield;
a) mole/l. 0/
01
Legend to Table 4: 1) packing degree
of the catalyst; 2) exnerimental
temperature; 3) Yield in.
T
H.O. % A% AH,O,
To*. ;c1 1
0,0042 M 34,0 3,23 1.35
0 0098 35 33,0 3,83 1.52
0 00/92 255 40,2 2,09 0,98
0,0098 251 /,t,6 3,57 1,73
0,00112 11, 50,5 1,33 0,77
.00098 14 51,7 2,30 1.33
O:OD42 3,6 59,7 0,57 0.38
Card 819 0,01093 3,6 59,0 1,241 0,82

Catalytic synthesis of hydrogen peroxide...
Legend to Table 5: 1) % .. ..... .....
-oalladium;- 2) carrier; % nail H
002mb
lift
3 yield;-4) aluminogel'; 0 (SDI
5 tungsten trioxide; o,o7 DAmmorem.
6 carbon no. 1; 0.28
0.72
7 silicagel no. 1.
Card 9/9
S/076/61/035/002/005/015
B124/B202

I
pHrO.04 I
V. A AH.c,
%
0 -
6
1 0
0
3,8
7
1
t

.0
T

1 6.1 t
8 5
0.1
9,2 1 8
.8 0,22

0,08 Buff aEl-
rIIAPNA
4,2
0 75
0,04
0,25 238, 1:56 0.46
0,42 20:8 t,38 0.35
0,60 20 7 1 30 0,30
1.56 28:9 1:04 0,37
ID, 73 j(pyroah m 1 16
4 1 84 0,38
1
1,83. 20 6
: 1:41 0,38
L~)Cznnmarenh 281t 3,11 1,07
0,05
0 2's 37,2 3,49 1,54
0:66 34.7 3,42 1,42
1,03 30,7 3,1 t t,t5

K.- SLATBA, T.P.; ARKHIPOVA,
JoGMIZEN, B.G.; LAIlirT, I.P.; P-W-P-=--VA-4-54k~ N.I.
N.P.; BEWV, M.I.; BURGILkK-ABRAMVICH,
64
geog. b-,a 96 no.6t528-534 1q-0 '
Bookreviews. Izv. Vses. (mi~,A 18:1)

POSPELOVA, V.M.; KOVALENOK, A.V.
Morphology and biology of the gall gnat Dasyneura sibirica Marik.
(Diptera, Itonididae) injurious to the yellow acacia. Uauch.dokl.
vys.shkoly; biol.naukd no.4:20-24 162. (MIRA 15:10)
1. Rekomendovana kafedroy zoologii bespozvonochnykh Tomskogo,
gosudarstvennogo universiteta im. V.V.Kikybysheva.
I - - .~ I. I -r-. lr.(SIBERIk 'WESTERN-.rGALL GNATS)
(SIBERIA, ESTERN--ACACIA--DISEASFS AND PESTS)

1. Pospelova, V.M.
2, ussR (6-o0)
4. ASINO Disrucr - AGRICULTURAL P.-~rS
7. Material for studying harmful agricultural pests of Asino District (Tomsk Province).
Trudy Tomsk. un. 114, 1951-
9. Monthly List, 2f Russiala Accessions Library of Congress, March 1953 Unclassified

1. POSPELOVA, V. M.
2, USSR (6oo)
4. Agricultural Pests-Asino District
7. Material for studying harmful agricultrual pests of Asino District (Tomsk Province).
Trudy Tomsk.un. 114, 1951.
9. Monthly List of Russian Accessions, Library of Congress, March 1953, Unclassified.

POSIPELOVA, V. 1/1.
6836. POSPelOva, '1- M. Opyt nashey krollkovodcheskoy formy.
(kolkhoz "Pat' k kornmunizmull. Grigorlev. Rayoria. Lit. zapis' A. A.
Shilova). Ylolotoy, K-,. izd., 1954. 23 s s. ill. 20 sm. (UcIIjstnik
Vsesoyuz. s.-Ib. vystavki). 51000 ekz. 25 k.--(5,r--2168)
636.92.083 st (47.813)
SO: Knizhnaya Letopis' 11o. 6, 1955

USSR / General and Special Zoology. insects,,Insect P
and Mite Pests..
Abs Jour.-' Ref Zhur-BI61 No 12,,. 19581, 54349,,
Author Ponelovas. ~VES-
Inst -."Tomsk Unlv.~
Title The ClIckBeetles of the Forest Zone of Western
S I berla
Orig Pub.- Tr.~ Tomskogo un-ta, 1956,, 142,, 195-200.
Abstract: This article deals with the species composition of
click beetles (35 species) In the southern areas
of the Tomakaya Oblast, The article give3 the
distribution of the species according to three bio-
typesi the characteristic of the destructive acti-
vity of the larvaej and the phenology of the dark
click beetle (Agriotes obscurus). The results of
the application of poisoned bait and of seed dusting
with hexachlorocyclohexane are also given.
Cdrd 1/1
30

KUDR7YJVS;0l.f L. I.; IOSPELOVA, V. T.
it
AuiDliceuion of variational -,thods to solution of , s-Llea,--.-.-
uroblems for different boundar-.,, conditions."
report. submitted for 2nd All-Union Conf on Heat 8c Mass Transfer, Minsk;
4-12 may 1964.
Kuybyshev Aviation Inst.

POSPEIOVA V v
Biological characteristics of diphtherial bacteri-ophaEes. Report So.2:
Adsorption capacityof bacteriophages; properties of secon4.ry phage-
renistant strains of Shigella; antigenic properties of phages. Zhur.
mikrobiol. epid. i imman. 29 no.11:90-95 11 '58. (MIRA 12:1)
1. 1z Instituta eDidemiologii i mikrobiologii imeni Gamalei AMN SSSR.
(BACTIRIOMG1,
of Shigella. adsorption, phage-resist., & antigenic
properties (Rus))
09HIGELIA,
bacteriophage, adRorption, phago-resist., antigenic
properties (Rus))

USSR/Virolo -a - Bacterial Viruses (Pha6es),
Abs Jour Ref Zhur Bioli 11o 6, 1959, 23779
E
Authir Pospelova, V.V.
Inst
Title Bialo~,,ical Peculiarities of Diphtherial BacteriDphaL~es.
Report It Obtaining of PhaGes fr,:)n Patients. The Ra:i(,e
of Action and Sta~ility to Inactivating Agents.
Orig Pub 71. nikrobiol., epidemiol. i imunDbi3l., 1958, No 6,
43-49
Abstract In an investiLptL)n of 32 washinCs, obtained from the
fauces of 23 patients with diphtheria, for the prese-ice
3f diphtherial bacteriophage, it was possible to isila-
te phares in three washinC~s; in one patient ance and
in another twice. The discovery of phage in patients
coincided with the period of recovery. The phaGes iso-
lated from patients (B, Ip; In) as well as from cultures
(C, Cp) were active against a mjority of tested
Card 1/2
USSR/Vir:)loL,;y Bacterial Viruses (PhaLes).
Abs Jaur Ref Zhur.Biol., No 6, 195% 23.779.-
cultures of _,Tavis type arA'lysed an insignificant part
:of cultures of mitis type. krelation between the toxi-
~.city of diphtherial cultures and their stability to
phaSes was not discoveired. Tested bacterial phages inac-
tivated quickly: in acid buffer. Olution after heatii.g
to 550, under influence of UV-rays After irradiation
with visible light, phagea, inacti;ated by UV-rays, reac-
tivated partially. With a midium pH within the limits
of 7.4 - 8.6, phages stably preserved activity. -- Ya.I.
Rotutenshteyn

ACC NR, AP6024441
-0-phage on either S. qaZZinarum or S. typhimurium. Since
all group B SaZmonolZae containing 01 antigen are lysogenic,
17it is obvious that the phage controlling the occurrence of
the 01 component in S. typhipturium (group B) cannot be
xelated to H-phage, which.causes formation of the 01
antigen in S. gaZlinarum (group D); this*autigen must
be -controlle4 by different fact.ors-in- th-e-two bacteria. [WA-50; CBE
No--. 12J. - ----- -
SUB-CODE: 061 SUBM DATE: 14oct65/ ORIG REF: 004/ OTH REF:006/
r
5 0 CZZ'
Cc d2/2

DAVTDOVA, N.V.; ~OSPEWVA, V.V.; TELITCHENKO, M.M.
Interrelations between algae and micro-organisms. Report No. 3:
The effect of Chlorella vulgaris and Scenedesmus obliquus algae
on the survivability of bacterlophages to Salmonella typhimurium.
Biul.ekop.biol.i med. 54 no.11:84-87 N 162. (MIRA 15:12)
1. Iz Biologo-pochvennogo fakullteta Moskojokogo ordena Lenina
I ordena Trudovogo Krasnogo Znameni Gosudarstvennogo universiteta
imeni Lomonosova. Predstavlena deystvitellnym chlenom AMN SSSR
N.N.Zhukovym_Verezhnikovym.
(ALGAE) (SALMDNELIA) (BACTFRIOPRAGE)

PETROVSKAYA, V.G.; PROZOROVSKIY, S.V.; CHZHOU GUANI-YUANI [Chou Kuan-yuan);
POSPELOVA, V.V.
Auxotrophic variants of Salmonella typhimurium obtained
under the effect of'ultraviolet rays. Report No.2., Studies
on virulent and immunogenic properties. Zhur. mikrobiol.,
epid. i immun. 33 no.7:116-122 J1 162. (14IRA 17.-l)
1. Iz Instituta epidemiologii i mikrobiologii imeni Gamalei
AMN SSSR.

POSPELOVA, V.V.
1.L'olo'gicnl characteristics of diphtherial bactariaphages.
Report No.1: Obtaining phAges from pAtients; range of action and
resiStAnce to inactivating agents. Zhur.s1krobiol.epid. I Immm.
210 no.o's43-49 Je 158 (MIRA 11:7)
1. Tz Inatituta eDldemiologli I mikrobiologii Imenj Gamslej AM
SSSR.
(CORYIP3ACT-MIUM DIPMWMIAM,
bacteriaphage, detection In patients (Rua))
(BACTER IOPHA.030,
of Corynebacteriva diphtheria@. detection in pntients
(Rua))

-P'OSFBWVA, V.V.
Z;ectron microscopic investigation of diphtherial bacteriophages.
Zhuremikroblol,apid. i im-n- 30 no.2:40-44 7 !59-
(KIRA 12:3)
l.-Is Instituta spidemiologii i mikrobiologii Imeni Gamalet AN
SSSR.
(BACTERIOPHAGE,
of Corynebacterium diphtheriae, electron microscopy
(Run))
(CORTMIBACMIUM DIPHTHERIM,
bacterlophage. electron microscopy (Rua))
(MICROSCOPY. WZCTRON,
of Corynebacterium diphtherlas bacteriophage (Rua))

PCSFP-.L4D'!iA V. V, : Must-W Fcl (dirs) -- "~'cop-rtllcs of lbfzctel~lr-,-
I
phages". Moscow, 1959. 1u' pp (Acacl Mad Sci U9M, Inst of E-plOcalolo!ly an~
Microbiology im Honorary Acad N. F. Gamalriya), 200 coPies (KL, No 19'59, 117)

I POM'EWVA. Ye.
Development of the meat and dairy industr7. Top.ekon. no.1:135-
140 Ja '59- (MM 12:1)
(Meat industry) (Dairy industry)

POSPELOVA. Ye.: VASIL'YEVA, Ye.
1conomic conference of industrisl and academic workers in
the Ki6v Distriot of Moscow. Vop.ekon. no.8:146-148
Ag 16o. (MIRA 13:7)
(Moscow--Costs. Industrial)

POSPELOVA Ye.
Concentration and specialization of the focd industrf. Vop.
ekon. no.4:140-146 Ap 162. (MIRA 15:4)
(Food industry)

POSPELOVA, Yevdokiya Alekseyevna; OPATSKIY, L.V., otvetstvann3ry red.;
iOllYUKHO T t..--re lzd- 'VICHh
va; MOSL TA, II.I., te;--hn.red.
Nain Droblems of the distribution of the Soviet "iry industry)
06110vaye voprosy razmeshcheniia molochaoi promystilennosti SSSR.
Moskva, Izd-vo Aked. nauk SSSR. 1958. 167 P. (MIRA 11:3)
(Dairying)

POSPELOVA, YE-
~Pp
.R91250
Rukovodstvo dlya sborshchikov moloka. 'p-,oskva, Fishcheprommizdat,
55 p. diagrs., tables.

suPANymi, Ye. P.; TARARKTNA, E.D.; POSPRIDVA, Ye.P.
Significance of determining creatine phosphokinase for the
early diagnosis of m7ocardial infarct. Kardiologiia 4 no.4!
27-30 JI-Ag 1 64 (MIRT 1911)
1. RLokhbainheakaya laboratoriya ( zav. - prof. Ye.P. Stepanyan)
i sosudistoye otdeleniye ( zav. - prof. Yu. Yo. Berezov) In-
stituta serdechno-sosudistoy khirurgii (direlctor - prof.
S.A. Kolesnikov; naur~-vy nikovoditelt - akademik A.N. Bakulev)
AMN SSSR, Moskva. Submitted August 15, 1963.

,. POSPELOVA9 Ye.P.
Comparison of the traywaminase level and antitoxic function of
the liver in patients with mitral heart defpcts. Khirurgiia 36
no.7:124-126 Je 160. (MIRA 13-12)
(TW;W-411ASE) (LIVER) (MITRAL VALVE DISEASES)

POSPELOVA, Ye. P.
Study of the activity of serum lactic dehydrogenase and the
antitoxic liver function in patients with mitral heart defects
prior to and after commisurotomy. Grud. khir. 5 no.2:44-47
14r-Ap 163 (MIRA 17:2)
1. Iz biokhimicheskoy laboratorii ( zav. - prof. Ye.P. Ste-
panyan) Instituta serdechno-sosudistoy khirurgii (direktor - Of.
S.A. Kolesnikovo nauchnyy rukovoditell - akademik A.N.Bakulev~
AMN SSSR. Adres avtora: Moskva, V-49, leninskiy prosp., d.8.
Institut serdechno-sosudistoy khirurgii A101 SSSR.

POSPELOU,-Ye-.-P,--
Fimctional state of the liver in patients with mitral heart defects
before and after surgery. Khirurgiia 35 no.9:46-52 259.
(NITRAL VALVE DISEASES) (LIVER) (MIRA 13:12)

TCSTFICV`~p Y
US'MIAletals Le~:CA, Intimony ~Ulovs Analy-ais Jan 50
"Determination of Sri-all :Juantities of Nickel in Antimony ard Lead-Artimony
0. P. Azrellyan, A. S. Andrevev, Ye. S. Pospelova, Sci Res Btry Inst, 1 p
111,7 avod Lob" Vol XVI, No 1
41
Offers new method for determining nickel in antimony without its zerarotion and Simple
and very sensitive method for deterin'.ninr very small amounts of nickel in lead-anUrnony
alloys. Latter method employs electrolysis for eliminatinp-- lead from solution. One
case of analysis by this method ~--ave results: O-CO13, O.C611, O.CO111, and 0.,C-Cl3dC
of nickel.
PA 159T53

POSPELOVAP Ye. S.
USSR/Chemistry - Nickel lAad-Acid Storage Batteries Nov/Dee 51
ODetermination of Small Admixtures of Nickel In laad and Active Substances of the TAad-
Acid Storage Battery," A. S. Andreyev, 0. P. Azrollyan, Ye. S. Pospelova, Sci Res Storage
Battery Inst, laningrad
RZhur Analit KhJLm" Vol V1, No 6, pp 375-382
Finding method given in GOST 2076-43 inadequate for detn of Ni in Pb, proposes new
method. Sepd Ni by electrolytic pptn of Ph as dioxide, makin copptn of Ni impossible;
detd Ni colorimetrically with dimethylglyoxime; found max conans of Pb, Cu, Fe not
Interfering with reactions and opti-- conditions for reaction. Worked out method for
soln of active substances of storage battery using Feigl's reaction. Proposed method
for detn of small amts of Ni in Pb and aqtive mass of storage battery.
PA 195T34

POSPELOVA
Alekseyevna; SLASTENKO, Yevgeniy Naumovich;
MAYEVSKIY-, I.V.J, doktorekon. nauk, otv. red.; YAZOVER,
Ya.A.,, red. izd-va; SHEVCBEIKO, G.N., tekhn. red.
[Production specialization in the food and light
industries) Spetsializatsiia proizvodstva v pishchevoi i
legkoi promyshlennosti. Moskva, Izd-vo AN SSSR, 1963. 310 P.
(MIRA 17:2)

KUSOV, V.K.; POSPBLOVA, Z.K.; FITISM, Y.M.
Changes in the blood and urine of animals infected with
tick-borne paralysis. Trudy Inst.sool.AN Kazakh.SSR 12:
226-235 16o. (142k 13: 7)
(Ticks as carriers of disease)
(Blood-Ana3yeiB and chemistry)
(Urine-Analysis and pathology)
(Veterinary medicine)