SCIENTIFIC ABSTRACT PORADOVSKY, K. - PORAY-KOSHITS, B.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001342510020-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

.753
597. THE TREATMENT OF TRANSVERSE PRESENTATION 0 liefte priel~nej
polohy - Poradovsk~ K. and Kraus E. Gyn. por. Odd.KCNZ, Ziline-
CSL. GYN-A-E-K-.-TT5T,-r--2-T73-80) Graphs 2 Tables 5
Of a total of 6,117 deliveries transverse presentation occurred in 105 cases (1.770).
The maternal death rate was zero. Total perinatal mortality was 15.270; hospital
perinatal mortality was 7.616. The corrected mortality among newborn infants was
3.876 (after deducting monsters and Immature foetuses). In the treatment of trans-
verse presentation, external version was carried out in 24.8% and Internal version.
in 39%; caesarean section was done in 31.516 of the cases. Perinatal mortality with
external version was 3.876, with internal version and subsequent extraction 56.410,
with internal version and manual assistance in breech presentation zero and with
caesarean section 6.1016.

NOW
MTZ' v L I., i n ~,l Al ;r.
)dd. it

FORADOVSKY, K.; KHRADECKY, L.; MACH, M.; KLUCKOVA, I.; POKORNY, J.;
PONTUCHY A.; ZAJACOVA, E.
Obstetrical surgery and perinatal mortality. Cesk. gynek.
29 no.6:534-545 Ag 164.
1. Gyn.-por. klin. Lek. fak. University P.J. Safarika v
Kosiciach (prednosta doe. dr. K. Poradovsky, CSc,) Gyn.-
por. klin. Lek. fak. University Karlovy v Plzni (prednosta
prof. dr. V. Mikolas); Gyn.-por. klin. Lek. fak. University
J.E. Purkyne v Brne (prednosta prof. dr. L. Havlasek [deceased])
a Gyn.-por. klin. Lek. fak. University Komenskeho v Bratislave
(prednosta prof. dr. S. Stefanic).

PORADGVSKrj K.
Importance of the parametrius for labor activity in the lot
stage of labor. Gesk. gynek. 28 no.7t466-469 S 163.
1. Gyn.-por. klin. Lek. fak. UPJS v Kosiciach, prednosta doe.
dr. K. Floradovsky, We.
(LABOR) (UTERUS) (LABOR PRESENIVATIO11)

PORADOVSKY, K.; ZIDEK, S.
Survey of perinatal mortallity in eastern Slavakia in -10,62.
Cesk. gynek. 29 no.6:41,4-447 Ag '64.
1. Gyn-por. klin. Lek. fak University P.J. Safarika v Kosiciach
(prednosta doe. dr. K. Poradovsky, CSe.).

POTILOOVSKY, K.doc. dr., GSc.; PACITT,J.; RDIAROVA, J.
.,nek. 30 no.1:26-31 Mr 165.
Anticoagulants. Cesk. g-
1. Gyn.-por. klinika Lekarske fakulty University P.J. Safarika
v Kosiciach (prednosta: doc. dr. K. Poradovsky, CSc.) a Krajska
ved.-inform. kancelaria SPOFA v Kosiciach.

(na ziemoenloa)- RIMAROVA, J.
PORADOVSKY,K. , doc. dr. CSc.;
Effective pharm-acotheraPY of obstetric shock-. Cesk-.
30 no.1:57-61 W65-
1. Gyn.-por. klinika Lekarske fakulty University P.J. Sa-farika
v Kosiciach (prednosta: doc. dr. V. Poradovsky, CSc.) a Krajska
ved.-Inforni. kancelarla Spofa v Kosiciach.

FORADOVSKY, K.
Medical management of premature labors. Bratisl. lek. listy 42- nc.3-1/12:
655-665 162.
1. Z Porodnicko-gynekologickej kliniky Univerzity P.J. Safarika v
Kosiciach, prednosta rof. MUDr. T. Schwarz.
(INFANT PREMATUM (INFANT MORTALITY) (CESAREAN SECTION)

FORADOVSKY, K.
on shock in labor. Cesk. gyn. 28 no.1/2:65-70 F 163.
1. Gyi;,-por. k-lin. Lek. fak. UFJS v Kosiciach, prl,6dnosta doe. dr.
K. Poradavsky., CSc.
(LABOR) (MIORRUGE UTERINE) .(MATERNAL MORTALITY)

PACIN) J.,, doc.; )EORADOVSKI, ~0, D. , GSc.
-K~; KAIWIL
Arterial and venous differences in mbilical blood coagulation studied
with the aid of thromboelastography. Cesk. gynek. 27/41 no-8:593-597
162.
1. Gyn.-por. klin. Lek. fak. UPJS v Kosiciach, prednosta prof. dr.
T. Schwarz.
(THROMBOELASTOGRAPHY) (UMBILICAL CORD)

PORADOVSKY K CSSR
no academic deFXec indicated
Obstetrical-gynaecological clinic, P.J. Safarik University (porodnicko-gyneco-
logicka Iclinika Univerzity P.J. Safarika), Kosice; director: prof. T.SChYffiM, LID
Bratislava, Bratislavske lekarske listy, No 3.1-12, 1962, pp 655-665.
"Obstetrical Conduct of Premature Deliveries"

doe.; SEDUAY, 11
PORADOVSKY3 K. ZIDE S D.
cf amliic'-,"
suor.'aanful
C,:::98-602 162.
L Cp-.-.k- gynoll- 27/41 no.'
p-lbolisr
ro,
1. Gy.-.-por. klin, Lek. falt- UpjS -v Kosiciach) prednosta p
L iw a rz,
(Fle-BOLISM AI-MIOTIG FLUID) (AFIBOLINCIG-10,1111A)
10'f,YTOGICS)
(sl!or",.-,,) k

PORADOVSKY, K.
On the fiftieth anniversary of Dr. Ernest Dlhas. Gesk.gyn. 251391
no.5;400-404 Je 160.
(BIOGRAPHIES)

PORADOVSKY, Karol, G.Sc
Indications for artificial amniotic rupture during the first stage
of labor. Cesk.gyn. 25139] no-5;391-396 Je 160.
1. Gynek. porod. odd. KUNZ v Mine, prednosta dr. Karol Poradovsky,
C.Sc.
(DELIVERY)
(AMNION)

PORADDVSKT, Karol
4~~
Surgical therapy of tubal occlusion. Cesk. gyn. 2408] no.9:
700-703 Nov. 1959.
1. Gyn.-por. odd. KUNZ v Mine, prednosta dr. Karol Foradovsky.
(STERILITY, FEMAL11, surg. ) (FALLOPIAN TUBBS, die. )

PORADO C.S.C.
Lacerations of the cervix and perforations of the uterus in
artificial interruption of pregnancy. Geak.an-251391 n0-9:
682-688 X 160.
1. Gyn.por.odd. Kum v Ziline, prednosts. dr. Karol PorRdovsky.
(ABORTION THERAPEWIC compl)

COUNTRY POLAMD
C A Tr,-'G 0 R YChemicnI Technolopy. Cbemicnl PPOdUcts 41)(1
Their Applications. Cellulomo and Its
ABSO JOURO* RZKh1m.,0 iv~o. 23. 1959, Zo,~ PA350
AUTHOR Jaros7ewski, J.; Pnrridows'kn, H,
03T.
-TITLF, Exnerimevitol Prodtiction of tba Blectro-Insu-
latirip A8bestns Parer
ORIG -PUIP3.:Pr7ogl. -ianiern., 1915'f4, 15, No fi, 1.50-154
ABSTRACT :On. the-basis of labori?tory and aommercial
casting a conciiision wp-s' made nertaining to
'I'lle noseibilit'y' of -nrocluc~.ion of such a -naper
from 100~'- r-sbeatos. TII)e conducted exneriments
emnloyed ELsbestos of the follnifing different
Prailes: Soviet, Afric6n and Minese. The '~west
results were oblnineOl witb tbe Soviet csbe-q-tos
lyno L-1-60, nurified of the accomi),)nyinpr mi-
neral sizbstiinces. As r. binding SIR-ent, if, is
recommended to em-oloy s-bareb Rs an additive to
a roll in a quantity of 5% basis weiirh+.of
*Derivatives. Pamer.
CARD: 1/2

PORADOWSKA,, Henryka, mgr inz.
Contribution to studies on the smoothness of newsprint.
Przegl papier IS noo8:246-249 Ag '62.
1. Instytut Calulosav6-Papierniozy,, Lodz&

~j 7
~F,r jn J!
no.6:1.66-139 Je 164.
--,ulp and Purev inaLit-lite, Uodz.

PORADOWSKik, Vanda
Clinical manifestations of mechanical obstruction of the esophagus
in children. Polaki przegl.chir. 27 no-7:699-710 July 1955.
(ESOPHAGUS, diseases,
obstruct.mechanical,clin.manifest. in child)

[ r"); * ~W " "11,
P0HjIPO',,,,ISKA Wanda; , KUBICZ, Stani-;I,'t.,-,
I
Pulmonary tissue rfsection in sstap~ylococcal pneumonla In
infants. Fediat. Pol. 39 no.O":67/-683 Je 164.
1. Z Klinlkl. Chirurg-Jil Vzieciecej (Kierownik: prof. dr med.
W. Poradwska ),. I z ZaRladu Radiologii (Kierviniki doc. dr med.
S. Kubicz) Instytutil 'Matki i Dziecka w Warszawie (Dyrektor-,
prof. dr med. B. Gornicki).

MTADCWEITA, W.
110 oparzeniach u dziecill (About burns at children), by W. Poradowska. Re-
.ported in New Books (Nowe Ksitzki), No. 1-1, June 1, 1956.

FORADWSKA, W.; JAWORSKA, M.; LODZINSKI, K.
On the etiology of nyolomeningocoele: Report of three cases.
Acta chir. Plast. 5 no.4:285-288 163.
1. Surgical Do rtment of Institute Of MOther and Child,
Warsaw (PolandrDirector: Prof. W. Poradowska, M.D.
(MENINGOCELE) (MATERNAL-FETAL EXCHANGE)
(GENETICS, HUMAN)

PORADOWSKA, W.; JAWORSKA, M.
Etiology of bilateral cleft lip and palate. Acta chir. plagt. 5
no.3:175-180 163.
1. Surgical Department of the Institute of Mother and Child,
Warsaw (Fbland) Chief: Prof. W. Poradowska, M.D. Director of
the Institute: Prof. B. Gornickl, M.D.
(CLEFT PALATE) (HARELIP)
(PREGNAUCY COMPLICATIONS)
(GMIETICS2 HUMAN)

JAWORSKA, M.; PORAD.OWS.KA,-W,.
Cleft lip and cleft palate: A su=arized statistical survey.
Acta chir. plast. 5 no-3:181-186 163.
1. Surgical De artment of the Institute of Mother and Child,
Warsaw Ubland5 Chiefs Prof. W. Poradowska, M.D. Director of
the Institutez- Prof. B. Gornickil M.D.
CLEFT PALATE) (HARELIP)
MEGINANCY CCMPLICATIONS)
(GE' NETICS , HINAN) (STATISTICS)

KUBICZ, Stanislaw; PORADOWSKA, Wanda; JANISZFWSKA, Maria
Cases of congenital defects of Pulmonary vessels. ?o1. przegl.
radiol 27 no.5:403-416 S-0 '63-
viruzlicze dla Dzieci im. J.
'i
l.. Panaluwowe Sanatorium jP-C
Marchlewskiego w Otwock*~'Uvald Radiologii Instytutu Matki
i Dziecka (Kierownik: doa. S. Kubicz) i Oddz. Chirurgiczny
Instytutu Matki i Dziecka (Kierownik: prof. W. Poradowska).

PORADOWSKA Wanda- LODZINSKI, Kazimierz; KUBICZ, Stanislaw; BOMINZ,
Krys yna
Congenital pulmonary cysts in infants and small children. Fol.
przegl. chir. 36 no.3:357-_!64 Mr '64.
1. Z Oddzialu KI.inlcznego Chirurgii Dzieciecej (Kierownik: prof.
dr W. Pr,-adowska), z Zakladu Radiologii (Kierownik: doe. dr S.
Kubiez',,,- z Zaklad, Anatomii Patologicznej (Kierownik. dr K.
Borowlc~., i z Instytutu Matki i Dziecka w Warszawie (Dyrektori
prof. dr B. Gornicki).

KUBICZ, S.; POHADOWSKA, W.; RONDIO, Z.j SWIDERSKI, J.
Surgical treatment of aortic coarctation in a 3-year-old bay.
Pediat. pol. 36 no.6:633-643 161.
1. Z Oddzialu Ghirurgii Dzieciecej--Icierovmik: prof. dr med,
W. Poradowska Z Zald-adu Fizjci)atologi-L-,-Icierownik: doc. dr ried.
A.Chroscicki i z &Lkladu -'Lentgenocl-liaemostyki--kierownik: doe. dr
med. S.Kubicz Insty-Lutu Matla i Dzieclka w Warszavrie Dyrektor:
prof. dr med. Fr. Groer.
(AUTIC GOARCTLATION surg)

FORADOWSKA, Wanda; JAWORSKA, Mieczyslawa
Classification of congenital fissures of the palate. Polski
przegl. chir. 35 no.1:65-71 163.
1. Z Instytutu Matki i Dziecka w Warszawie Dyrektor: prof.
dr B. Gornicki z Oddzialu Chirurgicznego Kierownik: prof.
dr W. Poradpwska.
(CLEFT PALATE) (CLASSIFICATION)

LQDZINSK-T, Kazimierz; KUBIGZ, stanislaw; BOWYwICZ,
Krystyna
Pulmonary echitiococcosis in a -child. Polski przegl. radiol. 26
no.2:123-129 162.
1. Z Oddzialu Ghir,13
,Wgii Dzieciecej Kierownik: prof. dr mod.
W. Poradowska z Zaklkdu Radiologii Kierownik: doe. dr mod. S.Kubica
z Zakladu A,n.atomii PatQlogicznej Kierownik: dr mod. K.Borowlaz
z-Instytutu Matki i Dziecka Dyrektor: profl dr mad. B.Gornialti.
(LUNG DISEASES in inf & child)
(ENHINOCOCCOSSIS in inf & child)

PORADOWSKIJ, Szymon
Report from the Third deneral Meeting of the Section of
Zoological Garden, Polish Zoological Society, held in Torun
September 5, 1962. Przegl zoolog 7 no. 1:112-115 163.

YQ~iADNYA,-A.I.p doktor tekhn. nauk, prof.; SIILYAPI-IIKGVA, A.G.,
inzh.; FUCHKOVSKU, N.V., I-and. tekhn. nauk, nauchn. red.;
DNEPROVA, N.N., red.izd-va; CHERKASSKAYA, F.T., tekhn.red.
[Organization, planning and economics of construction
work] Organizatsiiap planirovanie i ekonomika stroitell-
rjykh rabot. Leningrad, Gosstroiizdat, 1963. 258 p.
(MIRA 17:2)

Ferrompagnetic phases in
thermal
L: I:I
the nic;k~,I fc,1--i-y--Ir.-I-L~Jc%
1C
I., Unlvari~itot -,ry;ri LJL~skev~chu, I,Mnitoriy-~;

PORAY-KOSHITS, M,A.; 10NOV, S.P. ; NOVOMENUK, Z.H.
'ctructairp of the crystals of certain trivalentiridlim, conapol;rids,
vith inner-3ph-are sulfite groups. Zhur. strukt. khim. 6 no.1-
Y13 165. (141RA !E: 12)
1. Institut obahchey i neorganicheskoy khimii imeni N.S. Kurnak-ova
AN SSSR, Submitted June 22, 1964.

iomxo wq Fma-lowaTal N.A.
Y*lGaubw oryAlts 0t Wdoou2r&to Ion. 2bur.moorg.kbin.
10 no.8sl771,.1776 4 165.
1. Subidttod D"mber ]A$ 1964. (JURA 19ol)

FORAY-KOSHITS, M.A.
Electronic structure of thiocyanate groups. Zhur.neorg.
khim. 10 no.12:2835-2836 D 165.
(MIRA 19:1)

GOGANOV, D.A.; POW-Y-KOSHITS, Ye.A.
Chan,ye in the sUpo-rmolecular structure Of glass
D D 165.
due to heating. Dokl. AN SSSR 165 no.5:1037-1040
(MIRA 19:1)
1. Institut khimii Bilikatov im. A.V.Grebenshchikova Ali SSSR.
Submitted April 20, 1965.

GOGANOV., D. A.; PORK!-KOSHITS, Ye. A.
"Some new results of applying the method of X-ray scattering at small angles
to silicate glasses."
report subaitted for 4th All-Union Conf on Structure of Glass., Leningrad,
16-21 mar 64.

AVERYANOV, V. I.; PORAY-KOSHITS. Ye. A.
"Investigation of exfollatiov of glasses of lithium silicate system by
methods of electron microscripy."
report submitted for 4th All-Union Conf on Structure of Glass, Leningrad,
16-a mar 64.

PORAI-KOSHITS, AL. It. DECEASED 1'7Yf
See ILCC

FOIAK, Folilca;_POIUSIEWICZ-KACZ~IAliSKA.P.Jitdwigct
Ilarrov- and wide-pore silicagels as drying agents. Prze-- cham
40 no.12:702-705 D '61.
1. Katedra Technologii, Chemicznej, Universy-tet Jagiellonski,
Krakow.

FORADOWSKI, S.
-
Now nam of the zoological garden of the city of Umosc. Fru.-gl
zoolog 6 no.4;315-316 162.

FORADOWSKI , Szymon
From the activities of the Comission for Systematic Idantification
and Nomenclature of Animals in Zoological Gardens.. Przegl
zoolog 6 no.4:316 162.

SUMWIEj, Given Names
Countrys Poland
Academic Degreess b;ot giveA7
Affiliations got givea7
Sources Warsawg 42dycyna Wetar 9Vol XVIlt No.89 August 19619
467-4680
blue "Ca Oulesle an the 209r&" of I&MVIAG*f*
ntrol of cattle of
Authors:
MR Jan
KI-p-Jan-
KII Wi lave'
on 901")

1/tO r'~ /,-~ ou j r~ S~
SUWWIE, Given Names
Gauntr7s Poland
Academic Degreest Sot given7
Affiliationt got giveO
Source: Warsaug Medy-cyna Veterynaryinag Vol XVII9 No.8, August.19619
PP 467-468.
Data$ "Control of Cattle Tuberculosis on the Terrain of Zakopane."
Authors;
GAILHOFER 9 Jan
-R-ATTI~66-kd-$ Jan
POWISKI, Wieslawe

Sod iv .7 Fer. U%., t:
. .~ A
38 Ja ~65. (':!!' 18:3)
lnj~-.Iwt imeni lensovet.a.

R, A V DI 1, A . A"0 3 H i 1; "1 A13.
De termil-aticn of the cceff~-c n- ts Of "d illf'-fZs lor-I cl' Sj:--e Or7a--c
substances in, waz,--n and crlcanic solvel:ts.
38 no.1:205-206 Ja 165. 18-3)
1. Lenlngradokiy telrchxiolocric~eskiy institut imeni Ixmsoveta.
r. -

00
fe A
00
so c
so a a
00
of
I**
*0 1
00,3
00.
0 0 0
a $4o@ 0 0 0 0 0 0 0 a
III of it is 4 Is 16 t a
a L u v I I -Y
00 90 0 -0--w-v
It u u m 8 list 11144; it vai 440r*
Aj
-00
-00
b!nmv pnmwy ftrwit eftestim u4 tuaimp itown.
H . RIMA, M.1,M, Wit. :R). Itul,
Ivullo
rise 'ii dry mratims mv- vitIml. ("An thc wtA*ki&ty jwjDWL
risixf. 44 weamlary and tertimtry In Ilic forlm W.T-dryl- =00
phibillictlioW, stid writ liv ftluati. by liso liftial 0
I L A INIETAL1.411GIC&L LIT11111,110111 CLASSIFKATIOM
~-w ns a I.. 'An A % rm
isTo OU 10, 0", "lie; *010 * 0 0 0
0
-0-9000:16:0000000000000000000
0
'00
00
z:00
=so
&09
Wall
It I
goo
0
1 w w 0 a ) 0 T
0 0 a

4,9000640*6004
oil ) its$ Is INJILIU14
0* a j K L it-A-1-
kA,I
90
00
0*
919
00
00
00
so 8
a
00 a;
00
so
00
lee
WAR a
.~
-14
5 is .is m 1) u J4 is 16 u a 19
I-IL.M III cc FA K - A q , j 0
0" 411._1~4jqtj -0
-0 0
'149
Mb*AM d IV-07*66"-
swifts". use, 34A0. Feb. -00
29. 1934. T6'tbV&kW mkt. ad a=ims is added a
.00
mits! to or in excess ol the wrtm -
dary amiadc amboe. treated itt the 00
unW mant- with chtholk awshydride. $00
- - -----
law O"Oltv.
SNIGNO
0 n, M, J, In is all a"
o o o
so 00 0
-_00
400
06
-.00
-00
-.00
-so
o
woo
v a if 2 st j a a 3 4 v
n
9,1004040,000*060906
:10, 0 0 0 0 Wo 0 0 0 OL
_r 0 0 0 0 0 0 0 0 0 * 0
a 000 0000i : : :I: : o goo 0 o o
00000

'
a a 0 0 0 0 6 004 00 6 0
X at a A - - - - - -
is 0 0
0 3: 1
is it u 11 W m 14 " a 4
21 v a If a 4 0
119 x 30 41
U11 11 1
1
At 41 0 a a c 0

A X-P-A 1-01 0.0 1
~
A 4 p
so
00

-,::11teaction balworls phlbalk A"Yallds and *am# aft,
-90
3 LjQpj~=. Trums. Latmi ad
globe mm6mftjjj;8L.TA.
A "g
Jig
Th
7~JM
709W)
b
1

-
c *
,
i
, Y. .
I
p
11nida Me firctem 24 9._pw 1. in PhNHMc to 13 In WNW,
a '
!the Wirl asd% alk
ON
l
hth
li
id
l
h
h
i
.
a
a
m
. UP
t
a
am
e, p
c,
p
-00
phtnylphtheJamic. Methylphertylphlbalmink- and 41bvl.
M46 We altummix If -00
am or equiv. apato.
phtha* malsydriik wilb III Ict 1. ,41 AcOlf Xe
w
;.~ In. *-'t*%*. N-1-hraviph.
of N-pbmy"Iballm

so .3
thakmlv and om reftah4with PhNhfe. fur I hr. and
coclaing
~
gave 07 of the @me prodwt. N-Arylphthalunid" are
I -is 0
furmw
by tin metim c# dry HC1 on the sk. solm. of coo
the clarrempWiling W-mylphthallamic "s or by the
rquiv. Wit. of prhaary anme mA phthalic anhydride;
,
2) b
b
i
N
l zo 0
riat
4
m twethrr the
-phtlai
amic arid. will,
y
a V.m vowflary and"".
111ki- Vanvailctmi- to the qu&Mky -8 pwim-.ry ntisi. -likiv. I..
Tbep"matyarmainletunhwy
db*bkv the me. aw thr". forruing Mono-
wylpilithahmic aciols. The mobility of the matual-
111
1kYlM
01001kiNKF-1141 StOW IS '/. that Of the Miline Minn- 00
Watom. Primmy wykinimes are wracated from sm. anti
teti. by mixing in tbt cold with phtbalic anhydride anti
Imming In dry 1110 Im 2-3 hr*. The ppt. relwe"ta the
2; 1-6111ary alum", the filtople theme. and Icrt.
It to *
. R"111111ann

-200
n
rt L % a W 4
U It AV 00 IS
10, 0 It 14 it tt If tt
(A ft
p it tp at A
i
No A
.
49 * ~
0 s 0
0
00 .0 0000 * 0 0 0 6 0 0
0 00
0 0 0
: : 00 04 4 000 000 00000090 00

~00000000000000664
t ~tt
0606 000000000004000010 0-6-0 _# _Uff-Y-W--V-
M IS 14 it to Nil on J41S ja V Una At QU 60 6PS
0a; 1 0 Is 11 u u IF a a a A V a
,A a P. il-it-A-1- I I A 12 1A M 1111
A "J_L LI 4.0
------ -211t
00 1 . ~ . 1 -PAIMISSIS .%a 01101#1111, -tit -00
an Gi arom* ismain" laft dw am of OAMSC lu + -Mvu, MN H.%I-"- mist. o, -00
00 it
4du...'A"Nob-booloys of PhNH.%Ic and I in Hilo
S. Aw go" U9.70 od,
of .4,29& .-The stpa. of PhNHs, Ph1NHMc deoxnra. by distu, in law". A tnixt. of .5 -00
011
MW ftNUft Is a mixt. with thir aid of CoM(CO)%O (1) is mol.) with 40 cc. PbN%Itt att&9.31. JOA awl.) I'lul;1fa. ~-00
so 9i!~ 16 bialled Ott the omvu of PbNHi into CAL(CO)iNFIl boiled I hr. on a mad bath then .1lowed to
I moom A firs"
00 0 &(Laumt and Coerhaildt, Allen. 3, 24, 198; Tingk and filtered and washed with 107 1.00
p HCJ, produced 21.7 g.
C. A. S. 443; Hak will Williams. C. A ~ 9, 1065; (07.7%) U, to. The nitrate, 'wrlsistitig of 40 g. 1-00
Pumenerer. C. A. 27. AM) and that of PhNHMe into PhNMcs and 10.7 g. PhNIIMt, contained u.6
90 a. i S. 11. whictr -00
*0 4 CJl,(CO#H)CONMePh (M). while PhNMe remains was scild-on dissolving the mitt. with licl. T0100g.of
11130changed. PhNII, reacts with I first with th-e formation uflote4 &Mims(#. g.. )as. PhNH~. 42 g. phvHhfc and 42 .00
00 9 of Csll4(MI0CONIIPh (M~' M. IGO,, which on beatip! i. PINUct) in 2OU cc. UrOlf was added in the cold 32 a.
09 abme Its. it). P. (in C,ollp 111111MIM, L 0 NPUts Off (12.1% of thetiry of Ph'411 ) the mitt exotheraticelly
UKA. at Ifro,%irylioll joractiestUy a thowltical ykid of 11. heated to M-01', was LZ.3 ;~ 16' an:1 livaled with a
so a solve"to Contaillinateli the am hicit and It current of dey I ICI lot 2 41 tie, to main. anti inked with 21)
1. of ice then Alivrell witaboilt! with c4l 1110 anti drialt],
00,3 1 not &ulled Int the OrPtl- Of PWHMQI ThO
41C. I (Wp h. nw mrote, onts. PhRume.. '000
90 Was tficelt(I III the -ld with ft HCS IN to 11C1, PWh go-fle, some (4114(CW)e and dil. ak-,.
12 it the Method it hisplerile" was in&& &III. with NSOIII MW the
Iter, 22, 3247 (1 ~414iij), IM amines were
so u It wall f-Auld that. IV. b4AW with Ph-
Com. prodi tiodely stelam-distd.. giving 018 C. of MVII It and PhNife,
jjIIMc or PUNNIc.. - heir milt., is nearly qu- iafo
411141111 .4 (80% of the original unit.), which were seN. with I and
clonvertrd into U. The pAy- of 12 in alkyiated PhNH# subsequent treatment by the method of Gtrma Igotill
40 1 d. out ..mmd 2.5%. which can be wpd. from the MLPDQd- n Pat. =.-
00 OW(C.A.25.3ffilt). Amixt.of[Wil.o(mixedamines i zoo
filtrate. I'lle anti. of I u3e4 in the reaction is based ot: nely powd. I was rauxed I hr. on a mad
bectinge the welocity,g ttioo oi and 35 r. of fi
11, in the Illixt.. .00
, Wisir, Pits 4 dulft 9MACC than that a' "" A yield of 9D7,, it both. allowed 1- stand U hr*.. filtered, the ppl- was
IV is washM with 10170 IICI and dried, Wiring 9N~; U, M. LNJS.5*.
of about sot7u expectedt %howil that In the sm
Instead hNI1, PlINJIMP ADII PlINN'll't in tilt filtrate "re wr. as above.
pI besting a part of Ph. 19 U1 is distokced hr P
41IMt- Illaric
.4r L40 0
too
atIALL1.111, K-L LITER-11LAII CLASSIFKAIMN
1200
solo*) -IV -.-I oat os, Ail Joe
it 14flotal a a 7 a
1b u IS &1 0 Is of a It Is W It 1 #13
0 ft a It " ; , a a it If Is -
to 0 0000 00 '00,9,609 00000 010 000004000000 06 0 00, 0
ITS OF 0 0 0 i
400009 00000,0006000000000100040000000000000001
'I

a I&
9 0 0 0 0 0 9 0 0 0
0 0 0 IS'A ...foe 000000000
ty in, I a22 If it u 33 0 Is 36 1? x IN a -1 44 a cze
A I I z I, I - I . j . I , a
" cc --d
4r. .... .. ...... _1.n _p _01, C2011's
411411-
00 A
-go
PwUyifq quimilm-sm-m-sunadvic S. A. Paral.
go sliks. RUN. 4T.W. jum-30, low. QN16AW, -
am
pwo. by tin Emp mwhw an fmd km .00
twbnwy endow by tr"taft" wkb phthwk sawdoille
't so ,as*
a4 ON wylphibdamic "itle lb" k
=00
90 1goo
00 -00
00 s too
go g ~00
sell Igoe
400
too
too
t S4101) to 4~. Got __-811111 Cot a.. 1%,
zoo
Igo'; %#odo 0 -1w iota a T
u 9 At NO 'I. . . OW
0 ;0 0 0 *4 0 00000000 0 0 010 0 0 0 0 v 0 a 0 0 0 0 1 w
0 0 0 0 0 a 0 e 0 0 0 a * 0 0 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
00

00 00 00 1 a a I
-WT~ ~0~ 00 0 e 9 0 0 0 4-0-#-W-6-4-
09.6-0.
If 12 11 14 11 1$ 11 4 19 A [~~.h )o 0 )a If )) MIJ Mb )FJJ 160W.) sit) "OEf
I L I A, -1 AA- n -(X M -ul~-- I
A PO M4 tkmsww Pre"WHOS of the modem.
Usal gc*6~cb 1mAdkmPWGWWW"KoWmW$W1s Marild tVh* IMPseirrNkti.
tw AS. 13.
0r9. OWn. lmd.'-'(U. S. S. R.) 4, 164-711(10371.-A !-Oe
modified method of (ter. Pat%. 204,527 and 2"WAY7 w&% ;
used In the penm. of 8 new cooderim.tion protfucli In the 4
duame wrics td the ecatiral type RHN.C.lfs.Cll,.C.H,-
NUR (St - 2.3-timpbsbionic wid (1), mlicylk- atitt (H)
a I and AcCHCChHt (111)). To this end. 0.01 inal, s4 2,"
:e I dissaimadtaim"Im (IV), 2,7-diminoduummine M &~l
ee 2.7-dimstimodmovemol (VI) witire reftud with (IJ12 nmA 060
of the Wid OW W% vtom Pct. In 23 g. IP-CiLch al =00
sAmt. For thm cmdmatkm of IV with M o5 m.
sylmn " solvent wu Lmd. Of thm mmpds. IV and 1. Coe
0: W1. 21111) G and U, its, 2fl-j
andM,m.167 (44-6 V:ud 1, in. approx. =00
330 (4( amnAd sed I. m a .3100 42"%). 0
40
C011411 -'slus ted with theme compile. awl then
ed wkb d:m urml age
(rut am (up to 17 no
00 compomms wm twed) pve shades of cokes
rawgim from *Ww thrmch md to dwk bitm. The* -00
comptlis. end im mbstatittivity mW tbefr ifyclav in the j
intemkyp futmimme to light scid other drobabia propert~-t
Naphthol AS and in derivs. The thictorial
I it of lbta complis. "!at fnm,tbe IV to VI urbaplaIN
deiiivs~ occupliftic the Int"mediste Pomition. Approit. be 0
Chas. Blew
0 A 01TALLUP.GK&L 1.171047t,41 CLAWFICATIO" i,
U 9 AV 40 It -0
W (T 11 It OF Kd ItIm it t9tt 1101morl I tu
0:41 0 0 0 0 0 * 0 0 0 0 * 0 0 0 0 0 0
a 0060 0 0 0 04 000
N see* 0 000 0 0 0 4 *

oij; 1 0of it
a ! 4 " " "
L 0 If L a x If 11, A, I. tog

r64
4 lot at~ P!Vf1R1
'00 to

0 11, 16, "1 11, Ill it 10 1., of a l' 1;
let, atoll tit. cavioll
00
0,
00
oo C
The action of hydrogen chloride cast substituted plathals it I% muvorittral anti. alit, lumic. Tho interaction of wine
smines with X-alkylarylphtholarrait adds. P-sof ~;H
00 a role adds In alcohol. It. A. lwal-K"siia, J. (;,x. 'Ille lilt ImilitiltV ti.,,rho, 4wit, illm Ill. -00
CArpla W. h. 1, H.) 7. 1*011
00 a
1
-
"
4),with if
'hl
l
011
tF
IICI
I
f
7
NI
If off ofort.. Alkylstrylamill- all 1,111halompl, acidoo I'V total
-90
fa
.
111-
l
. "r
.
fy
f
'
.
a
0
gave
f
t
040 a off V
614011)
1 are (-nlnq-ll
29
A iC 6.111111111till off nimicurvilifichalAitaw
il
Alnilltol Witil
'
-
.
,
. it
l
1. I
h%"%It Cl W.11.0 kill -00
'Whe" a 1,411 aralililliol, iiiiiii. off 1111thAli.- luillydride (11)
00 #
III&NII, - PIN11COC.11,011,11 he for-

0
r
h
l
N
II
h I
P
artiom viluil. ticip-ml-nal thr ttlalivr -ty- of ill,- jotiA- -00
AO
fCI. N-
1ha.
or
Il
.
and their pptd. "It
hen),
P
" lictl in 1hr Flitifilltil tawil (f.110. PhAN.Nfrl). 1-1111% ill flat goo
. N-- 74viphik,ilimde, tit. 17X -81'. N-p-
00 j tomodfr.m.2111, interaction of ...d oorith PhNII.Mr, to,
=00
1.1 ; llhN%le, 76% N-ph,
raylphlbalamic "i'l tlaj
It.
00 all. - i..
UP I I N-P- PhNII, wrfo: I'mitird. N-Dophenv1plithalatme mid (3.2
.roe
0 Acid, (A.taill"I from P-11'-
%'C
11
()H
O)
i If i
d
Pi
t
bA
B
M
i X.) final I R, I'bNIf' all .111 Cr. E.1'0 Viii itilliviril if) evilp, COO
.
ant
I
atil
it.
n
utt
e,
A
,
,
. ilooorly (S Ill ilay%j. giviuat ,A to A g. N-ph.-tiviphillA131111,
0 34' twilitigif). gave all. Swid, In. IIN It*' fille. 1. acid. an gee
04110 a -Viol, 611" 1111" (mill O-Nit-COI.Nillif lill't 1.11111all.- .,1- 00
(the IICI oos "I Wi. It
11.1.1. onto thOwill""Phortayl- livilfidor in Callo, anti o-MrCoII.NIIj gavir
00 z plathalarnic aciti. tit. 157". obtAined I'min P-lf,NC,11,- mic acid. tit. 1711'. 1-*ihvl.,,-ti~al,hiiii'll.litti~L,itt. avid. tit 2SO41f
Stit, anti 11 Ill Call.. liailing
iLaphilialie attlaphidr in
00
f 165". and "-C'.II?.Nl 1, 1gave ;wifl .1
zoo
clim'.1 Of 1
t
h.NII: Gir ;4' -411 ilia.. ri-maltol in N-ph. nyl- file inlide tit. The

I
o
frapht1kilimide, all, This hooded with 101W all
NaOll fivar 12 hirs., then filterril and the filtrate avidifitA

1
*
v
r
.00
'
-ith JICI, gave -vlra,aphth.latuio~ avid. Im 214
.
e-
,
:J flat mandinjr in tho, air or tutwe rapidly with IICI in mic..
"'
p
t Woo
(a
liffALLURGICAL LITERAIL4~1
CLASS#PKATICN
_
kl Q- 041
I- -of oil

U pr DIVII, on air ms Kurt trot l ran An A S a ad 0 0 - I ar IN 5 'a a 3 1 v
aw A
0 0 0 0 11111141111 0 0 0 0 0 0 0 0 0 0 0 0
so 0 0 0 0 0 0 0 0 0 0
o
0000 010000*00000000::: 01:
::
00000000000:::: i

Of 1.010. a, owleuli 14 L11 a j$
v 1,
00 M ROO
PSMIlItts A"* "O"41-ts toctg
IN* I
0
comdoo"ti" of
0 D. A, Por"l-kmitits and A. M
0 .0 9 N- -v' ~Y-' cu." 'd, Ofth, I%W. , -00
o No. 3. 43 00- c(. C. .4. $5 (32M.-AMMAtt'llkAtorvier
o' (1) and O-C,,jj,(co)jO (U) 6 11.0 (A hro. at the b. 11.)
09, aIf yirld #&W to be Ul. m. 290' (decompri.).
(IV), 0
JCmHXOgH' He ~ti'; couvwted low a subskaw (W). m. 3406. by bmwm
In ACOO or C44N (at tin b. P.). or by
000 120"; T Is &W Prrpd. from I wW 11 to mtv ha goo
490 a b. p. 2-Amloolumm wW U In PhNUe. (2.5 hn. at th
o0 ~ I yieki Y-*WimidO$wrv". Co. 2ml. the T..VC doe
-NH N m - 3W. of wkkh is mduc"t Mas im EtOH-Ca") t. moo
00 (M. to. 2512% frorn wbkj
V is obtained by boRing for 5 Ism with PhNMe, V1 an, moo
BEH k35 min. at the b. p.) y*ld Z4WwvjdjA"~..i.-,- MM*
M. 246'. rtawratitq TI wW B&H 46
wbc= hydrmlynd (10% HCJ). VI and U in pkNUe, -
(S Ism at the Is. p.) afford 11 t doe
the M3&kl is I U-
mad IkH (35 at Ilea b. Itlea goo
r.O.- 2- (30 900
min. at t1w b. p.) ykm Z-bow)d"ftmm
IU*. r"d0y hvJMT" by SIMS, B. 'so
"048 0
5104 1"firiv. moo
-i-fte-S -j-T- tol(361 $dip omv 0*4
U 9 Aw . - 1. . . -1-T-4- I p allill Olt a" Ass AD
to. -1 w a 9 A a 3 0
b tv a at a It 19 21 K It t it ;F"' '11:1AX see 'm 0 m 0
0 0 0 * 0 0 0 0 04 0 : L' qe~~000'0000 0 0 00
el~ I : : : : V: : :I:
*00,410-0000040 -:00960406004 60009

PORAJ-KOCHITZ, B. A.
"Sur la structure do la QzLinophtalone." Poraj-Kochitz, 1. X,# Fora3-Koghjtr, B. A.
Louyk, S. A. (p. 123) -
SO: JouZaal of GeM&rpI Phym (Zbirnal Oba-hhei Khimii) 1938, Volume 8, Mo. 2
IL=

00000000*000n:
set f
son
so-
0 M 13 13 U 0 b V 2 0 0 41 41 0
PC f
~v i I J60 tw
4
V, IN
p ;7.4
jjj?JA JJl%jVJ.)j!j )0 AJ!A
-put 'YA(I
T"
SO*
t 00
r 00
so
.."too
is so
00
00
11.1 11.4111ifIll10.11lit 1>04
a 's-iO44-60f 4~4 lit
it, 90
W--Y-'o
It vo
0 see 0 00 0 0 0 0 0
0_9 9

4 r 11 f4 11 16 it
UU us lag vino 4, L''Imne*
Of A
~46 0
0. K. Nikilmova Alld
Dilmidaso Val djell. lu 1-00
porsi.Kmhits. Russ. 67,'.M. jutie 3U,
CaIM-SYMC-acids of the naphthalem or ptrylene -00
C1,1341c"Sed with o-tliaminm of the 11,10mic. BuOfleuouc of -00
fluo-.l ~k-
peg
=00
Of
00
0
~18F
LAO
-ILA 491ALLUNGICA &ITINA110111 CLAISWICAIJO26 046
use
IMIG" Lp amv Get
It
'It rw 01161WIMIJ041, 6 1 WX!
0 0 OL voow -0 0 00000

0 0 0 0 6-0 0 0 G-
I- 111jW.)4 Uts NX111121J.--na .7 a I, x v U $I M n it, Ij M N .1 4; It '5 Pe
A IL, C 0 L-1 r MI A It L r -A F_ 9 It I T V Y_L~L_Ait 04 CC PQ CE t
A . ~ 1. 00
oo -

0

0 a Pro stion and study of condensation products (tow
10 g. 1. anti cimlinx, litilverizinit arid Imiling the reaction
idi
It
A
P
l
hi
id
d b
K
h
d
=r -00
!- -
tyra
enz
de.
.
m%
vt
e an
.
c an
r
ph
y
'- '"Ass with ale.; yield 15..4 g. When 5 g. IV was added .0
11z arid P. Nf. NItAtryukov. J. Gen. Chron. (U. R) I*.
gradually to.50 g. molten 11 arid the mai, wai then ctx)lrii '111

41 .
t
oftler to ~tablish clearly he *tnicture
i Rulvirrizeti and extd. with ale., the resillue C10-i't"t of V.
hiltali
a
h
dri
t
I
(1) an
h
h
f
d
f
t
t
en%it
itt Pro,
iv
c
n
c
i
i
ini p
con
y
SiniiUrly. 5 it. V on an atlikl"X'M~ reActLin with NI it. iti.d.
bruiridinr (11), the wtoik pit-viliosly cattivd out by GuilLil.
ten 1. give IV.
mclfi (C. A, 26, 724) fin thi-w subitct hatt been repeated,
Of To 14.8 g. I di4u)lvcd in VA) in]. litit ak. was added 9.2 it. N~
'
1
s

0 J.'
2
It.) which
11 in 100 ml. ale. while stirring. The [,fit. (
_
CO

:0 is c"Ily di-olv~J in soda anti alkalies was boded with
f
A
li
i
t of
ant
s.
canit
Pb.N,%Ic3 (M) whereby water wa% sp
IV and V
as deicribcd by G
IV and V were obtained
.
,
were sefid. by means of cold n1c. whereby IV retitainis at
'o the txjttom and V is obtained in the form of a suspensPon ;*o
and may be iwiated by 41ccaniation. Condensation of I (IV) (Y)
*
anti 11 in III guvra mixt.of Mamt V. PurcIV,m.406
,
(7tertrude flerend
00 ynth"izcti from IM g. molien I to which 10 g. U
'

u
i
was added in small portion'. The cmlcd mit,ss was Pul-
F
i
ri
d, then wtirmed with l0c,', stmia milti. until, the cxcew%
z
I was rentoved, the undiswived pf'Auet was filtered off and
washed with hot water. yield 14.5 g. Nte V, m. 3&J*.
ze
was synthettlited by adding gradually to ILK) X. molten 11

- t
AS-SLA METALLLFGKAL LITIPAURE CLASSIFICATICk o 0
too

#7 0
A,
It DIV (94 KIC ICU Ktt19 It(X ML34 1:114 An 1 11 Od 0 4 )V 14 D

0 0'0 0 0 0 0 0 0 0 0 0 0 0 0 * a 0 '01
a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
: 4
41111 0 0 0 0 0 0 0 0 * 0-0 0 * 0 0 0 0 o1 * 0 0A 0 o 0 a * 0 * 0 *
0 0 0 00

V
Ir* -** _16 "F-
0 0 0 0 0 0 0000 ::0o
.X is it .1 3. a U
13 M 1% 4 IT to 11 303 a )9 11111 a" 34A j6jrxx4 41 ads
0 L__L I-p ..0 .41. co. 9.111
boaqvil pitsintililk Manliness sad illituboxylic
It. N~4411mafbpntMhwwi
anhyd",
tl_A~ I1i**vKs.hhfi alid N, N, Vrillit".
%.A N.'? IsIT-W-1`110,0441(fillatish VAMOSAly);
sod Moltell I (it") Xj "a' licated Willi 10 1. 11; list
12-W.-Thilipplic S.) in uoo'm. mixt. was extil. with 10% %*ICOI VAII
Witte; Yield 14.5 s
11 hol ElOII was tirratird _"Ith 9.2 x. bessitidinst (H) in Iipbthato7llwnsiiine.ni,41r."(m.406*
008 IfV) cc. )-*.I()I I to yield 0-3.9 a. tT%ixcd mosupplithaloylli,enil- Five x. 4 -nit ro-4 -ismine"rhen yl and 4 1. 1 we" Iffiti'led
oo dit'10,1m. 21148'. *,,,1 dittlithitictyltwushline. in. at~xlj *hi7*. 1ohlU
Whep slip almnre im I fir-In ls*)Lv.
00.1 ft"'Illiellihi " 114 Ir"ImM fiw I lit, illelf 1.11* Imid"llithen)4, pit. :01.2% letinell.1 tth Fe-7n tiat in
it. ill I.I.killut, 111,;G11" ItIllich WEI itivillicul with The li]K)vt AcOll solve a nou-4iAtiolitAble 1111iJklet idellIkAl With
mm. &I'Ate" It 01X) 9.) -was irripled gradual y Witt, 1() g. 1110110plithelaylbellifiline, wilich apparently is 4'-amluo-
000 1: file MeR was cooled, ground. anti builed wlIh HtOH to 4-plithallosidolillillcurl having a amino
yield a reidne 'd 11) it. M0,M"J"Ihalayibeirsids owe, its. mr2- STOCIP. 1 (26-0 9-) lit") 36.8 11- 11 wttc ttl1lixtil in am cv-
00,3 1
(fit. IM' (Tons PhN'(~): the proillict j*ojllfI stirs Ile dinso. .&ter for 9 h". to yield 21) K.
O*v ifird. pilthonsh a fire NI 11 gionlip esio, A% 111,,wo liv In(n, &h4jivic ar4l, in. 21X1-3011% ber"WidePIP d0ellv. M.
1 lion.4 a Ae"g)4jealf drrip.. lov sclillillid Milt Ill ... :1., 1-v1. (after IVIWA(M ciryon. froill 11111, in. XCIV).
004 H ll. . -
,i 2'. whh-h r,.e ta:ul) ,up *,gttet . _11 11,11 11 (Mi S.) wAjp trefilvil Willi 5 Is, dipht hiskq1tilen pith tit-,
1, triwatc-1 Vivo" (r,
jj; Loolcd, anti tteated with hot RtOll to yield mont);phithialoyl.
Itentidine.
I YW the diphthailoylixtusidine, 4.4l'-diplithedintitIoN.
Avg
All
tIONI 1111'"0111%;
Weis U940434
ORO( an 4* $can It as 0 ft I to
0 ,0 0 0 0 * 0 0 0 0 0 0 a 0 0 : 0 0 0 0 0 0 0 a 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0000-0 00-0 0001111000000 000000 4
-00
nos
a of
too
sties
too
Cos
goo
Ito 0

,07
Isit is 910111211144L6818010 a 21 ull 1415 Nit mpg at U43 41
a ra t P---ft . 9 1 . W n s I I if (0,11- -1-11- 4-- A -L-s-k. j
the fluoressid aerfm U. Preparetim of ..02 -- ---------
love of -
0o vat "M=1 lye$ of tkV flucevEd $strists. B. A..fy - ~ftO
X st.
pm_Ut Nikifortive. J. Applimst'Mm.
~ and 0. K. ,
R.) 13. 21S-21 (in German, 221) (1W); & C. A .32..
00 11115".-Thc pc,"bility of mpplk:uallosi a( she more runspicn
0-40mines to tile synths:06 J slikMi4lastsic dyes was In-
r1% As an initial substance :,11-48'ammi .160Aboreme
M* I Wes PrCPd. as follows: Fluarene Was ni-
trzt~7
-nitroduorvue was reduced wills Zn dust In
trated, the 2
ak. mda. in the presence of sq. CA". The 2-simina. -00
go fluorm (20.3 S.) was Imilrd with 150 cc. of glacial AcOll .40
under a reflux condenser for 7 lirs. The hot reacting mixt. .00
treated with boiling water yivMed 2-micetylonsinodluumne
so (1(10%). its. ISO', after wask6w with 50% AcOll and '00
go then. with water. The product (25-2 jr.) was dimolved As
in buk aleciat ALOR (27.0 cc.) and. after cooling to W"
00 .3 wall nitrated with 12.6 cc. of 11,N(h K 1.42). yickling coo
113% W a mist. (its. 1101)-441') of 2-acetylarnino-3-nitro.
so J do*
Gmucirme and '21-amstylasnino-7-nitrusluorene. The mixt.
00 of isommo J=U s.) was suspended in W.V m. of abs. iLk-. ~j Lee
be and boiled in the Wernm of 441 cc. cooed. ilCl for I hr. j : do*
umr~rr the ritilus tottaknorr. After disin. of Ih of 11'r ak'.. Ils, toluene. and iLylrnc, m4. In boiling Ph,14%. ppidint
00 the reactions "jitt. was silloweJ to stAull for 12 lit*. The and 11ho'llilre. 'Flit thim-notie dye was a itii%t. of c6 and $00
Mt. was Meted and 6ikd with ttxl V. cutivd. Rel Its ttens 6mmis. Oise culoicit cotton tsiswu6h yvUuw sail -60
:11l.odwaierfor2lim Moolicrationwassrepwatedd-7 5 other vissict. The first kid a "tax. absimption at 4114M A.
tins", the 2-411liOU-3-111troduumse, in. 187'. Immed was and the second at W5W A. The isoincrs were wpd. by spes
~ltevtd out, washed with NlI#CI solm. and dried. Thell,"i- /treatment with 11,50s W. 1.34). The second Isolner was
mmwr can Lse plitil. fruits the filtrate with N114011. The "Sol. In IN90s than the first. Tfratmentolig.offitior.
d 2.3-isimuser (I I stj wall reduced with W j. of Zu dust by cnims: dye with a inist. ol 3,v. i-1110SO.Clintsmolpy.
bodift In U.W m. 4 7,11% ale. in she invotnim of CsCl, Wine to tile ptcwlkv of 2 It. Fe fillitax sit (W Ior 7, his. 00
,V in 6 cr. of weirs) for 3 lim yk-lifind 7141" of 1 'rho y1rdrd "Jiulwzol," oil mi-id P,dfork- &,:lit clics, 4 Itwo
net ([a
Mt coudensatisms. of 4 g. o( I with 1.746 tl~ of nAphirz , c - mulmll. of tile fluotenotit dye, which dyl-d wl%A Islight '0 0
we cuboxylk acid in 16 cc. at water in a cmkd tube at 170- yellow. 11 A. P '-S 0
M)* for 12 lurs. yielded 3.9 g. of dibuidamole Vat dye. in.
above 3W'
The dye was 3cpd. frosin unchanged
with 10% @ad& slid tbtn vrith HCJ sill U Tl~
by bW*l r
dye was oxidind with N&uCr4h to a d
TV
I
(CaHnNA). instal. in &k., MevCO, eLber, =Q=hEt. n 14 dftQ
- - - - - - - - - - : eif 0 * 0 0 0 0 0 0 0 0 0 10 0 0 0 0 0
me 010 0 0 40 0 0 0 0 4 0 411 0 0 o TOO-11 0 0 0 0 0 0 0 * 0 0 4 0 0 0 0 0 0 0 40

141~
140 *no
19 SX" :V'4kdiWI* . A
of tb ilized with 1.76 j9.
jascan betwe" aressit with - .dketiXe. ul. 204-M a (r5
Is
CcW, 1. no read6a of 0.1h-71" rated to 1"* for 5-10 Mbt-; go CXWBCO tbe
at be
B.A. pmd.Xashitsandid. M.Anto- I we, b
J.Ges. Clm. (U.8. 9:93-13,33"(100) rodu!t = pmrd-d arld vVd. with NAOM soft. at tbW
Inymissini the p fwdu*. on. 4N-6*. (3.6 it.) was CrU& a-
lyi d IF
4vUsjtft.':la=j._Tba aul'I) 'W'd O-WIANIfe. ~v*.JO".Q*&Mkt Ible was paqvW %T toia. to -00
ties WCO)SO
*0 H isliand. 11 Was prvpd, as ullows: 6.7% HCI. SJUSOM Wid dew UI .. as 9:664" of 190
tol HCI "It: the latter was M.
with the fogovial obsert tram IN
water was bee the .100
I to
4W S. fused N&A (80%) 10 12DD -- X)o g. .k.
son , lkjn~,\ water with H to Yield the free wat
a after jUtration, to 9D* and treated with 2mr.N., Ila,-77 -00
0 Nor, added with, ukrwg Over OA br - the Mist- WIN re- treated with lot btsat
0
s Outed with stirring Ice 6 bm at IW6' filtered sod let filtered bD4 and the ppt tw= hot bm~, tbm
00 _bab..d to vield a Pam prodoc Ott - IF U -00
stow Iff 24 IMIS., wbW do pptd. U ;a; filtered off and _!L
004, a M.101.5-2.51. 110gJand _C5_C.) vat treated with z S. acn-y- see
(Irw at fo-70*; go g. So%). o OthTlng
oed 6.96 IWOMWedmiuffindbeatfidtol" with Wn-kg; (be cooled melt wed Xmckred. estal. see
I the evolved water; alta 21) 196' will I
SrA pit don of Mists 01 UVW ab abW44 SW vuliavmd~%; yk!
0- 0 min. the alit. ==dcred and qXtd With 30 cc. bdUal Nlk hot Iff". P midande. 0. 416*. 009
pu'fl "beaYININ
padloa well dibassi
AC.O. Tbm!r I ;r. sad was timMseals (2 S.) mixed with 10 1. 1 was beatad 8 -09
&ad rMs D
O-P468 zj?~Hocj, ~crym~vkd dMa. to at 1950. then to 320' to CDmPktc the reaction, dm wbkb z0 9
SCpd i=xlt wit -.am sah. the powd. melt was on,
yield-pro&ucts Do* sad 4112% m'P td. with v8, nhwul unier
SIOU . M. 2 . 2: L409 -061. then condition, the startblg products '50141
an do a total cd 7.6 g. li~~. 9*0
ACSO). The I"- for e1w. BoitiNg 1 (10 1;.) was treated with 2
=20910 (ft- ; It. p.; tin
:~ cry-ts. leads to " impure product., which 1-411-tel dawle said bested for I bf- at tb WOW
the PrOMM In the mek of 161~astllei wwlt was extd. with NsOM softy 610111 tIM estd- 400
bzy& seld (which by the actIri the AcvO Is converted Jtb holting KtOH sod, 0 td tMet AcOMI to Field al-
to the betwoYININd . I (too g.) be" to I a 23D-
Nag was treated'alth, to S. cd U ova 2D-M tnia.; aft- W=bove(2.56. 11". so*
boi ;iA bo*n
~be meft was poured Into 4 dish. PDW- 40'. for oil min.; the cooled well we. exti.
b"" lor 0.6 br. I
- with Goo cc. NaeM st the b jtv'o; tbrawk Intret"t ykbkd
eln,.d sad *xtd t
the andisatOrd material was Icred ON, 1". *18' 41AD.317.). Wbik be WMA. Flose- Zoe
we wit] 'M 'tubulgis"k, 0.
tec &W dried. to 7 cirade
'b' p'"_O_'bV OW
Sn. 193-6 wlift MW'FVtR- Pbrny- N W7110 13 with 2 r 3-2.6 1 see
enedismi-, M.
d the usual
WItm. with bat MOM V**
by %D0- 80"IMT
,e- 0_ 00
U 0 AV ity W i'llu, ;91 falls Pieft t1ason I
P a 9
000 M e 0 0 get 90-00000
'000
o o 0_0 0 0 0 0 0

a 0 0 0 0 o 0 0 0
linn, to yiehl Mr, of a j.,mjwt w 4t4-17'. pbwyk%v,
dfl*ftzlw,M&..A. (I ..) '.d 10 d. I "ted Ow I loon. at 106,
01), fam"I to frwi i mma. of The - -t. 0d the Grow
t. to g. I-Alla aba go- on- tod m. m dW IW Will! Of
bm MUNI Of pymkw
too lows" "Cr" ~d up to a
S. "ash-, fib* 6"
0. M. Kowkp.sg
of
0 o to 0 o o o
0
00
00
Go
00
00
00
00
00
00
00
0*
09
0
00
00
00
00
00
00
00
09
00
*0
00
0:0
0
00
es
410
00
00
00
0 10
00
00
00
100,
00
00
00
eso
00
00
00
k
0,000000000*00000000000:000*
000000000o0 0000000000 6900
go 0%,69060
00:000

-7-7-T
r 11
J_ ~Oq IYJAMP't-
4-1
Reactim,betwess arowat&c diamia" and rikailioiltig
Adds. M. - Reactim 4 bansWito with soplithslie an-
000 ddo. it. A, Pogal-Kcahits anti Z. V. Arkhkwva.
f Gen. s42-?(IL44)(K11st6h
quilom"O I cf. C.A. 39, 4NO" -444"Slifism (M) 6.) VIVA
luelto-I at ICW hk a poet-4141o 411s11 alid Witted Isaduallf
with a 4. naphilialic sabydWe (1) with 06110tk* I after a
miW .at 175-000 the num was coultd, builed with MOM,
k1d I A , d- . A
1 40 -40
~.4'31 "16 'a V(df'. o y M :04! 1 Mi s IS " W. t b e vvnu
d cannot be diamotimed. Tbemmeampd.wasobtained
by battles equirnol. arnts. of the reavests In a maled tube
at W-200. Heating of cqWmW. mats. of the rcqrnu
in sq. waspewslum gavt a anall amt. of alliali-PA. product,
in. M', which could be dismized and which an beaUng
to IW76* lot this property; It Is proumed to be N-
4000 '16-1-mic acid. 4'-Nitf"-
anelmobipbessyl (OM gj mad 0.51 g. I we mduired for I
o- 0 hr. with 15 cc. MMer withatit. reaction; Ow mine mutt
wwobtainedirMuptoMni.bead". llowever,heating
in the presence of warier in a waled tube to ISD-200* for 8
hirs. gave a good ykM of d'-sio
in. over 500' which doms sm* dimsodme am is its Nos
imle to milectim by any ad the tmtba& tried.
MIT g. was heated to SD' and tradvally trmted with
IAI g. bensidina with the final t=W. being 2501; after
treating to 360' and the omml trestramt, there was ob-
tained eublimation in.,
about 5t;;, Insol. In the umd solvents. G. M. K.
0 41 a d 0
/0 .06
.00
age
Coo
coo
Nos
it
A 14 - S L A MIETALLUKIC" UTRItATUAll CLAMPICATMOO
low 910183Lva 21000 6661mv U99
34JOSO "it Omv cat since 1111411 m MT All
a "' - \ ass
U 19 AV 7 TRA 1A I I I OA 0 P I
It W, U, I-am 114
It ; 'It CIE it a v
e a
a 0 40- L 0 a 0 a 0 90 0 0 00 00 0 ~00 :1010 -0-00-0 0 0 0 4). 0 0 0 0 0 0 0 0 OLA

PORAI-KOSHITZ, B. A.
"On the reaction between arovvvtic, &-nines and dicarboVlic acids. V. Rxactlion of 2)
7-diaminocarbazole with plitalic anliNdride.". Porai-Koshitz, B. A. (p. 1919)
and Salamon, G. S.
SO: Journal of General Ghemistry (Zhurnal Obshchei Khimii) 1944, Volume 14, no. 9-10.

0 00 0
0 1000099
I IS I
S, 0 3
0 a IS I g J. , i IS a a A T u I, It 1
. a Is Is
v I AMA
W A 0 41 a u 0 4 0
so A lot S" I 1
____ - 1-1 .-1 0
1 so
0
0
00 A ea
rA 1*0
0 1010

s: _00
.00
a OCWL Vs. Moan -of sliftto ad dkoldam wm deviv. Time Yield of 11 4 m. MP". Tftstmmt
'
'
X
A "00
.
.. and D, A. DOM with I tm ~ im. 31C-12
cave
t Mat 80
(frout, ANavLO
tab. LKh"'t J. GOO 1111)~ bon. be" ukk PlISNUey at
I cbm'. x
(US &R 15
26" Oug
.
H d. tog a dam labal to Change air to son a M

: WING that- W4- S.) was, treated in nwftm Silaw with a jr. 10-
with I Md. pbtbdk Wqdd& (1) to 15 Safe. at IW-SD*, heated to 18D* 1W 0.5 hr
ftdwl Mud
goo
a
00 derim witboat Forimme of ,H,,. Naround with b* Na&COb mAn. to AM _" _~_ - -
'
0 stma
- Thin the K
ll
i0ji~-MW
f
kMi
d1
1
Ad
b
: I =00

0 4 .
wm.
au
er
ww
s
re
m.mP
&
at a
).
j
Ndther blbAW dwfv. Is 4mp" of dehydmdm to tTxbc*":G7pc4j WOdolmnelawt 40-200" kv I 7* 0
goo
heat a =" nealue. to cialiabeem.. U_a
jk" bam) baled SeM acm I to 17U' lpvt Smd

*D
drifv
-
v
~
b
b T
M 100 &-)
W
i
f
d
kb 1
=

O 0
9F

so e. an
w
m ew
on v
. a-Tabdine. vid, 4 .
m
..A b
u
tb
d
n
I
yidd
*
.
1
20
tr
%W I
) wa
l
U
t
7 O 0
s
*
n
w mo
C.
ten sta
e at 2W
with 4 ll. 1
4
% .044miswov. M. 2W10
. am& a"
'
with MWA
W b
W I
h
so
OM
m I
r. to 220,50
R. a
bm,
. The rewyd It failed to cycvm am I
mW w"
round and h
t
d with SM
10
NO
i
h
N
=
ca
e
cc.
g
and iris w
Pb
t
ug#, , PkKO* of
%
mtervd; the residual hak
l-o4a"
1701
mc?
U
t
d
O
) 90
u-
) 1116"Itsmid"WIR
.
at
an
be" for
y
(
am tD!L9.
wft seep-Sied in dy. jTq, 'muwjQ kb Naxo~, and 0.5 hr. to ;
338'
A I
~Y,
goo

1 ,
coupled with elk
solm
of 24mVirchol to
a bel
from PhN
W
t r
d goo
.
.
e
Y
(
p
.
goo
t:04
teoo

Ata.SLA WALLWKICAL LITtRATURt CL&SWKATMN too
via." 41,.in. 0
as( imuncittl 4111111 09 0-1 LIS
-
-
AAL sand a a a I a a 5 a a 3 a
U W as SO
,
0
:

0 0 0 0 0 0 0 0 1 0 0 0 0
0 :~* 0 0 so 0 0 0 O'o 0 0 a
00
0000
-
I
::
-o
s, AALAL 000 0010 so* 6641060-1
00000000000000
oil 11 INN

0 IS 4 0 0 4 *4_Q_~_"[_
IF 30 31 V 13 Is Is 36 V N M 0 At Q U it
0 q__1 #A~M IX 00 K
-A A-J-6 I L
4 imli
*
00 --"1 WI J-D PAIGPIMIS -Dt I
-04
00 ill
-00
*0 I"s than 11, the o-N*11, ilctiv. In all ca%c-s in &Ill. wAms. ~99
the P-011 psduct larthmainated. with v-011 yield In. -00
00 if A- dies tram 34malao-I -naphthol ack loom Of its crra~iujt with lo"mA pit. The o-hydroxy dye from
deriTS1111104. 1. -00
00 a A. E. PbrW-K0d1it3, B. A, Poml-Ko!,hjt3 and V. V. tlh%.Cl "i,t. in 2 (urju% which are readily intefcon-
so a %-rrtiblc. All 4 the dyes obtained are weekly acidic. atod -00
Petrilmlin (Unisogrual ChWin-7rech7j,'jit Gels. C". dye wool it) 134mlcaux, brDwn or aray-violet Tbe prod -
00 1 it (U.S.S.St.) 15. 446-W(I94.%) (Engli,is summary).-Moslo- ucts had the h4lowinS charawterwics: .00
1,; &w condemation of S~ottnitto-l-uaphthul with equiv. aint-i. (a-hydroxy dye), no. 1264%
00 at !a ut j0-nit"henyidi"osolurn chlimille and phenyidimiumillin abm."tim max. COX) A.; 4-(p
Chil"rid" its 8 wide range 0( Pit gave only the o. and p. J_x'4pkth4 (p-hytlrnxy dye), In. 24543', absorption roax, zoo
bYdr(JKY- Ain't --aminuaw dyes; p-aminnazo dyes wtfc 61(m) A.. 6-(P-I"*10t'"Y(410)-5,4ffviolo-)-"IkUbd (o- Ge*
00 ndg "ktAill"I At All- P-Niffs'PlICISY14HAUVIIJIlln cjjl,)rjfC ill
Rmilln llyc), M. abvntinn intax. indefinite,
00 13 all Pit Y-Alu- 'A-c al-t c2cluAMY th~ hydnisysiz. (a-hydroxy dye)- m. 184- ZOO
")III0., while phelly1dials,"jul" '111-mide Kave. at pit atmwIltion maw. 5100 A.:
06 L-O 0
mtpkk,d (P-b)"Irmy tire), fit. ill~ffpri')n max. 7
SW A.: lfa-attiiiio dye), 11
00
in. 174-5', als-mIrption max. MW A. The alk. mins. of 2 m0*
the a-ainino dym become dcollorited m standing.
G. M. KrAnIGPOR
&$lI.ILA
woo
164,301) .91 C.. as( W114810-C fossil alt 4-1 it,
r 4
It .1 10, 1- -.1 a a 19 it It a ti a pro R i
UG :1110 : 00 0 0 0 0 0 ; 0 9 * 0 0 0 0 "S 0 0 0 0 0 0 0 0 6 0 0 0 0.0 0 0 0 0 a 0 0 0
* * 0 0 Ole to 0 0 to 0 0 0 0 0 0 0 0 0_0 a 0 0 e 0 0 * 0 0 0 0 a 0 0 a 0 0 a 0

w it Ij Ij U Is 14 1 o~90 0-*-q-0-W-4j-w-w-,,-,--
'AI It
n If Jo I VU Uis fit,
go i - "-~p -.Q I --L-1 t-j -k-i. .
M- W'.
eoj
09'r Dyn wftb andipyrime nodal. and a special case of de-
hydrogenation. . P. Pm*I-Kthbits, 11. A. hiral-Ko-
00 rill hh4,an O.P.(*.iiulitug(Lenisigta,[Cficmzumfl'mhiitA:,-
:0 a I t-T. rmd. "Ad. iri. 47, IM.9
(190
_j42
008 tylidt"WantipyTinc. lit. :NXI W11 in. 15L!".
a An 94.51,iyidd from PhCILO*iid anlipy iur (1) WA,
'mictiled (as the sulfate In lfcl) by teflux fig With 11NO,
1.4) to form a Iffick-ml fly(-. flemmi.41. t11),1111 I $V,
(I'liff trysill. as 111P Ifivos tall. In, 265'. In y1cid;
00
It It*. all al-veption in-sx. itt 41W A. mml mIhfiA.-#,qHy
.000 00
410 Y C110 rcacting its IlC1 %Wrt. gave PAIInetbylawimawtt-
1,1 itylidenebliantipyrine.2110 (11) (66-75% yirld) Which 0 0
00" '"clictlandbecatuctrdst 120-40%aflisillic4l .and its. 1-W. =00
00,4 11 e"JVW If when licaltil in a current W C(h Im I lit. at
1705 40% and gave a leticolmse.111. lt#7~s*(1ltvA1n%j,11.),fr-
cipt. fmn HIM. whctj treat"I with NmOll.
Orville Sevting 0 0
Pik, I
zoo
ts
I
ts Os
INJONJ .10 ".V off
U is 41 PC Is 411411
9"Wit 4wit Ill fix 1,11n Rx n 1 X4 V *1 5 3 9 T
I I I n 11
100, 1 Ines" -0*~, 0
010 0 0 6 0 0 0 0 ~ 0 0 0 0
0 0 0 0 a 0 0 0 0 0 * 0 0 0 *0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
-0 0 0 oil- 0 0 0 0 a 0

'.10 0 00*00 * 0 0 0 0 0 0 0 0 0 0 0 *' !1 3.
IT
~4
I
.4 11,jul, I'm Ills "Nzin DMIS 84vxn xj, 1-1 IT tr
to I T--LM-A-MwU1j - A I d t

00.1
00 'Structure and transfornuttioas ot dt&10 Compounds. 1.
00 Reaction of p-nitrodisjobotizento and theory of the struc-

00 tuft of 41480 compounds. It, ?cil~Klphi,4 and L V.
A-11c"T
-
" flr~-
10.
R-
( 19 im.
Grachev. J. GCot. Ow M. 0 1 -
00 ticratioll oI %-arieftL, of P-

00 will, file gtas!~ clectiotic licrillitted liv-
'ril
111-1
l
f th
t
l
e
e coi
.
lix
1e structure o
"hoes as to t
0 forits is lite diavittitim catioit. T-o -Wtlike forim
thowit it) C11W all.1 (1) tw tnittliAlly ititcrCiltivectilite;
were .00
'
OUT IM111% IrMn lite AVIRM ill 4iCill #)If lite 11411314C NA If- a,**
41to(atc or ill alkili 4141 lite litaldrilluill chl'"Mc. tile .1111cr
=
f6will. list Aciifific-Atioll 'A mable Na dulvitate Alld kch.1fac.
00
terilvil fly tliffercul acid liters, delicildit.1 oil the ratir ld
00 -3
titf.4thiti: thi, I-wilt A., ev,,Iv,-- IINO, And b0fill, all
0 v
0
relltiv, -It. dt It, ~%,ti w.., let iv. rile fe-liall- V.M-
:v;)t Ill diwu,w.%I it IMAth ll- -tth Oil, omij.f

o
00 A
And ollivilmil La air prrwwv~l e
G. M, 0
coo
~:O 0
At
o 0

woo

& I a. I L A M1TALJLUnfCsL t1fillfiisig C%AAWK&T%,*
I rip 0
1410*0 Rip oftv cot
I P 1411,31amt
I I
it It a A An I 1 9 #w a

,
1 Poll
0 0 0 0 01 ;
00 0
00000:0
:

000000090996::0
0 0-1111-4111 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a
0 0 0 0 0 0 0 0 0

PORAI-KOSHETS, B.A.
RT-118 (The mechanism of the diazotization reaction). K voproey of mekhanizme reaktvii
diazotirovaniia.
Trudy Vosmo?-o Soveshchaniia Ro Anilinokrasochnoi Khimii i Takhaiki 74-78, 1947.

4_4
if _"_
if ro
a it A of L to- v v it -1
A
A
min, AILI the jw..hpf, '1.1. 1'.." jil'~ by m
Ama dy" front 1-ionol"m I-noplotw *ad game at It* v"IW X ;I -j 1-00
116toladfleflust of Cho Aftuictutod W I, " 1 96
00 A jeavoll", it. tit, otc.11c" In Jilt- lim.1 Mot if 4;111" 1 IJ t -
14 7~1
c usea"ju dye& lovilik A. It, lhwal- mL NAM thM, it, 1INI fill , vii(h toll fill, f -
00 kuolli(o, H. A. Punal-Kwfut,. and It - V. P~wekaltjk (Letifit- j).1 v Acitilif,11 with IICI gave ?RK", 00
too, It ivad Client, Trehriol. Inst.). J. Grov. Ckem, (U.S.S.R.) Crude dye, this Was clit.l. kit lim, lid. hot Nltjc(), '00
A 11. 1768-4011,H47)(in Ru"Lul); cf. C.A. 40, 48W--- fullowd by 50 nil. Mc,CO and the residue was rrpljttt.
so In part 1 6 was shown that Coupling of 5.1-11INC-.911*011, rr"In lf)~~ 'Naoll Ily IV;, 110, while the (lye Ito NIC301,
with 1112NICI And JCf-OINC4116t1tc, yiOld"I 3 i~lllm tile a,,, putifird in a simittr mAtuter. The prix1lict, u1. M'
2 each r ..dvtlt These vivie -ivvll tile Imovi,iou'd atistl. V. %4A Identical Willi that libultiv.1 fly heating 2-tut It.
00, a ... of the lye off. 1.1-1, (sec liart 1) With 1,18 1. plillmlit.
.4 the ststictLut-s Wei flow twell 111adc ,it tile II4~t% of ill f1hytifide 1-2 Ifills, 1111til a Inch is a0l6w,I. filk v,1AG-
go 111 _Nj 1 an liylljltt bdimide. A"
1)o fishes I lit %tructutr I-m,jpkjhvh
00 &A-ilapni, wid. Tile 4wilivir fit 215".
0 11,61116dirl.41141w ate "I 'I$.. A' 1.10111"Al %1111 0W 1111lillik-I 4
.~blmils'd I.v remplilix N hyllm. V, 1 -11-1011 IlYDI'llill"I 'If aw ityr lit. ttll' (we $'At I I I ; I lit, cel"I'li'l-I I Iw
4040 `3 Amic "lilt PIIN,cl ale "ith 41ye, 114VI.I. 1.).
1.1111WOVIAII'm J 11 -phrilylbs"'N -I .1u plot 11,31 jild fructuir
09 0 a,od. Attempted emilitinig I,( the atmove i~,tjgvnt, tit IICI
Dye, (1,111% I'llsict IARNI to tAke it I it, (41
go `1 wd tllc.*~.(:I-Ilitfl,IW83syli.irit.~ailiiii,,)-i-iiii,fifl:,J are hirti. old. . ;,* o
warin AcOll was aj.1rd to it X. IWI i
8;61 tiLAI W101 the IM)INtAl ill tilt' M406-11 14 3'"I-NC-111011) ill 30 fill. Not", Acoll. Itivitic it. Im".
7 With 0- jIItVt1YUA-A 'AadUll - I -ti,41111111111 1110 8 - Illit'n' airvi. 144fr'. lit. Iv.%'
.I i X-(6-Nitrvo-5- (truti, ic-) . na, is ud. Ili' I NAill w4l ~,tp
i tuplithyl)phthALtittic acid droxf; toot react With diAzu 14. I:,OjI dild. to IM till. will) W.Afer, .- uli.M ith
composand.. HcptAcenteut f the It fail,, of the Nil, too Q. 0.1 N PhNict, and tile psltd. dye taken till in
jErmtopi ill thc new tly-t-4 fly acyl or Im-norylittrue firo'll- 101) fill. 10% ale. X4011 .-I plad. by life,, AvOf I. giving
vAu.," a hypswhrumfe shift; the "lfm 1,lmomv, devix-r. 7411"~ cm-fe dys.. whiell mul effid, with bill I"1011 -ut
When (1.6t) g.) W144 h1wil "Ith L-L4 i"I'lAirli A' R dIffit l-WIlec. .1. IIIS-70% it Was 1,1141tivAl
AnhYS11111C. the fr4VIhIll WAS C1411PICIr 111.1 With (lie IlflklnVt 010.111MI by hViltilig .4.116 19. 1-( till fee
izi 195%aviurt I)with I.3C.m.0jNC,fI,CIIOinAcOI 1.
;~--. - -e
Z
I L A littALLURGOIZAL UttRA (Atf CLASSIMAMP, t.z--
lit,
[,.-- 14.0 41, IS L
-W. F
U" AV 00 11 ir
0 tv IS 1* 04 a AN 111 9 tit Ins Is for 10 14 M IM 111 4 3 9 V ,M
00 0 040 0 0 0 0 0 0 0 0 0 0 0 6 4) 0 1 9 0 0 4 0 0 0 0 0 0 0 0 0 0 0
* * 0 0 0 0000
s0 A-0 0

0 0 0 0 0 0 0
:0 as
Ole 9
a
a
96
00 1
e 't
0
Ole j
6)4 Is a Its a 41 G -1 o g.
/so
!-Go
latiliassale derivatives. 1. Mischanim W fartmolicla Of
derivatives "d the relle W bydreekk*
acid In this tvactloss. 11 A Nst,61,Kolshits 0, F. 01116-
tiara. and L. S. lust.). J.
Gtra. CAwor. (U.S.S.R.) 17. 1766-73011,67)(In Ruselan).-
blany derivs. of brostimillsizole can be prelld. by heating
an o-distinitur with carboxylic acids in the presence of IICI
under ptessurr. 1-he free dissurthic, troulflng ffom hy-
drulysis of the 110 sail. it trnwar-dile for the reaction,
As the IICI salt i, int-apable of reirction. The catalytic
action .1 IICI is explained by activation cd the CWI girrocill
by addn. of a pcotou to 0. forming a cation of the atilt
with electron deticicticy at the C stow. Theintersisediate
its the reaction is the product of addn. formed " the result
of entry Of (tie mutilated CICCtf(M pair of one N of (he di
Airline ititil tire CleCtliso-41"fiCiCut Cation of the acid radical.
,,_CJl4(Njjj)t (0.01 mol.) and 0.01 tzbol. add In 10 slid.
ICI were heated in seated tubes at ISD-5% after arldn. of
I
MicOll the licsiducts were filtered off and dried. The
following bessimiddst,45 were prepti.: 2-M#, in. 175*
Worn 140). in 70.511 yield after 44) miss. real rising
hl'~ IICI (110 )all. tit. *-v3,),. 2-bessityl. M. 187. (froto
lisruslent) (110 sail. tit. U-1-4'). In yield front PhCli,-
C0,11. using 101,-,, 110, duration 40 miss.-. :-Ph. m.
(tronst )all. its. 3011% ill Ill front
114011, slaills 25";, 11CI'Alualloll AO odo.; 2.( .riv,141).
its, 24o-7' (film,% "Atrt) (1117 salt. tit. 2W.14 ), form
nicotinic acid in 40% yield. tul to,:; 1[C1, duration
hrs.; Z-44PAA.Ii. in. 116tv-2, (front 30`- etc.). from I-
ColliCWt using 157, IICI. duratiori"`40 min.; 2-(p-
aminobtlitl tit. 2.-1-13* Ifroill,01C.), front P.M.W.H.-
Cthil (110 ills. sit. 31,11 12' 1 toot 14011-1(011)). :
klsokydryl, in. 2116-10, ([film (ill" : H1010, hoto
11hiClICCMI in 44% yield. using I0l,`vrIICI. dur4tiofs _4
?If*. ir!!C/ salt, in. =13-8, (from atc. IICI) 1. Ifeali"10.01
..I. o-C.If.(NIfj)j And 0.01 mot. NOR 40 min. to 1p40-5'
in & sealed tube gave 65% 2. phenythensiscridA tote; repeti.
tion using o.CjI,(NIIj)j.uIlCl Save jy,,~,Yirld. arldn. of
11.5 Ml. list) to tire [Alter twist. gave 30
luddattrille. Heating an equinuill. mist -of the diamint air,[
lixalf in li"n 40 miss. to IM' ve 48% yield, while
replacement of the ligroin by IlXde=l the yield to
71,~r. Heating art equittiol. Mot ismil.) mixt. of the di-
amiticand IlsOlAin 10ml. liClof ststrissuserincus. 41) min,
to UM-S' FAve the (oll'orins tickit of 2-phellyti,enLillud -
attile: 51., acid. 10.3%; IW_ acid. 21.717.; w"s, lo-W.
-,#.7';; :M% arid, 100%; 35% acid, 48'70 yield.
0000
I
= 0 9
'40 0
1:9 0 0
tie*
allIAL11111111741 ""W""1 CLASUFACATICAD
d"t
tilt NuM
T--1 __T_ 1 An
U *AVID0, V, aassa of a ItAIMADA
O_LAjLAAjLA_2_&*O*66C *fee* 0

a U 46 no*
ft I Me L A as r a. 11 V IF I r z
00 4 Isr A D 0 Its
00 Snip r,,zn. E,,,,c ~r,.X. 0 2.
It P. A, V..M~K-Iat, it, M V. S. q'-
00 00
I, b~ru III Ow d"Wildrster of tile (air 14 laydrolyd. all Ifir
Th
I lwhjvior tof luses from Araniatic Con1pj,,. txLswity of the base u.,td. In alk. oln. the primary rc-
; '00
on arid And talk. hydruly4is wwi irev"filated. 111 the version is vildev. of Oil-, followed by: RCII(Oll)&IIR'
I 1114j,xily 44 V~jw~ there let a dirmt aviation lwtwrrll the 00
lt~lloll I 'Nilk, - R-,-Il, + Rciloll - RCII(P.
00 catr r4 *641 hv^lroly%i% Attil the lvvvt,~-ily of the towlillill.: -0 &
00 1 tile Wert l1lost frequently dr1wildson 11 IftsIclay 44 file -00
anthir used. 'riar,weticai ex-mt. oi stir nimhani%iit iiiiii- Ilete 111C All(Itt. of Oil is SinI1111ARVOILLN With JbOlari$A64111
0* of the CN leoud-, 5upleort few this is steel in Intare difficult
X 1
4P X181 hydrolyNis Ili alL.s.1n. thAll ill ACid solve. if such grotil~% 0
0
. a castes that the major rolc in " hydrolyealle Is Played by 'are intrwiteced which Are not achlic enough to counteract 0
00 i ; A
the proton, An aplwox. cukn. of the nusVItu4ft of the tile lxk%;c pfulpertics, of the azoinethisic. llydrolyws its
'ifcct and she saItcrualte chArge effect "Lot the u.1 s IICI were followed at rooni ten 1 50* 1,
00
field effect of the -b%lituted stroosps, showed that fol -&x aualnbtuf free atilhir vine, aldehyde. Thel,041o'W"ma"Itt"Y C:0 0
00 NO, irr,nil, tile rt-Itionce rNct I, 4Z tionm crnit" thAn wa-rc obtained (the figures tire in the terrier: hydroly,i,
00 V Ow 1'. W, It,, t. .111, 11 0, LA litters ell,al~r ill,ko Ili.- At,,m~,t. tqtV ~mst%. at toolin tNitil. and 5W. actiVAtiOU cttcFKv ro 0
, It,, tthr a6d 110toll", I, o-A.). alldor dissm It. rolipt.); V.
00 :4 00
a. 1-1.11 x ill a. a*K1. 4.3 x 141
i kCII: N1114, - It ~11'Nllfl' '# kill l(ClItU10-Nilil' tiitt,ilwtiAylidrskr)Aaiiliiie. 1.7 X 111-1. 1.0 x Ill-$.
It- ~,,R, - 2.2 X
IjCII,OII). + ,,i;R, _21U -5.3 X IU-w. S 1~00
10-A. .5.7, X I0-&. 4W. .1.3 X 10-0. X-tirnsylidenc-p-
nitrouniline, 7.111 X It)-'. -. - , 1 .24 X 10-v,; V- Soo
If 1.2 X IW'. .5.07, X 10 6. 400
14CIM11 HC110. Tile -0-11aull,itloti of the nwhoulim f1tv.,ij, I X 1o-11;
"4)11 Ainhoe. 2.7 tit Ill ". V-(P- evil t,,IwlltYl - too
'i X It)-,'; p-lwnsvl-
t a6d. 1.2 X 11) 8.15
x c*0
I... x lo--i ,I,;:
_!~AL U*GKAL 1,1711114111111t CLASSIVICATICH It 2- Z--
.001
s*jQVj .1. a., 0.. 111..' Oot -1 Ili
t #-_F_T__eF__r 0 3 V
U 0 AV W3 is as 011,014XISIXIN K it ff it Ca Is 1 *1 An I S nd se N I 1 11 Iso 43-a-3-1 T-Rr.
0 11; 0 a 0 so 41 440.
0 : 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * 6 0 0 4 0 a a 0 tile 0 0
~.00000010*0000000000000.0000000000000*000::::::Il~

The dy, t. ml" lint,
WAS. in adoill" 'lealliblated toy 1,1 limilo. 111,
11(Afic rittrel'it"I (4 Stich iuraro"6= tail- the

00 1
It* djaxositillin firriv. Its 11'so, with atVS. V I
` 11
11.1filwilig t rititt'll"Al fr4liffs: 1, 00
at Itill', yiehling a tell molid, Itinifirif fly 111,01, foots" lfl
~ .4iiihnsic MCM, And -St
00 NuOll fly IICI. ph-littliell 14% shmild lint lotions 41 YVI. w bill- A-asubm. I -It's 141111,4 .2, 00
ilecstsup, WA'; 110 rVillAkTul"Ji Sit the N111 b) it ullijklic arid atilt msif 00
to oil groull by the Vista writ I ballot diar4athom irac0on gaoic
4 ~tlllbll. -I AlS tall
ithouill readily emiple twice; sillillarly, -
00 dre-atip. 2,111"
title I hot 4 -Sillfitflk- act,[ And -2-411110"It. a6d ilb,"1111 f'. tit di-I.- 00
.tliasw "if. wm hrdt"l with 10"Ir IIN;04). SimllAr *I-
,
'
dy". while Acid atilt .4.
00
so (we joirt
c ilyr in. 1.44
placenstnt of the Nil* grimilt In Ili AH41 'Imul'i wit give
0 1), i.e. gave tlyrx. unit 111-alldn", Achl 00
: I-mapmM. n;, 1:18'. The muminhis dye ilinmer (-vv ""Iftollk' field tillf"llt, fileill 1IN4101 .1yi,ol. 'tb~ 1114 SLIJO lilt 111 so
0 Inset 1) wal, Amim, It it) lot
r Will% hyllf-eAlIfile
ir il
l
l
l
l .11f WOU11 0I the silwittleniq .3. U',,111110 (is lie she ilats

Z
i

10
o ~
llv
ow
lls: srf
q the f(A
y
' a
differing only in list, affirbrale lill, Anj only tile ilimn,
: ,
gave tjrvimilo~
At-()If wills
it' lit sic
d ilk !
hi
0
h
t
h VOIC11tv ImUld, Were anmillir'l tit tic (lin-falivr, Sime
'
I 00
.
.,
e
W
c
ea
(73
X.) wit,
`t.
iving 5-AY4?,,xV-j 4,11114.111C Acitt., tile IlWance br.
..m -1141 Jobs lot
In 1,5- atilt

0
00 .
. -
st, g lifern tilt- 0 id SA)
off (ind tilt- w1jacent rifix It if," $I'll
fine, well'slos.lorsmil. us. first exceed 1.7 A. (prriq-itimi), fit,. fiql1latiml .4 1% 11 1-11.1 00
0 Pficl). Ill, Soisommm, anomalous cause of reaction of i~ likely. Its milcr tit 11tv"llitafr the jw^%jIjjII(Ic% nalilvd
00 m!nInsin"b"aultsinic acid& with d1misit compolundst.
af-Stic, Ihr bill-kisilig exilts, oillmoord that file ruuw floor 00

lie
% I V. Pro,rLdIns. Ibid. I'M14 1,100fin Stl f4illife oil *.'.lot emlilling toy I oloor'A not tic Ill (Ile %1xvilic 00
411111 e.g., Itt achl (A-A"SH140.
I ...6-41taliml "I Ibe Sultlitsirlit. Not in (lie prv
,ruce of the
0
I
ISA1,11111"I .3 - slill'otil., arid) (1), -, -at-lif U -rinits .
istsmp. 1.,
(N.k I., on v%pil. , ta 00

: is, ill) (11), and 8-millim-l-tiaph is, Arr slimi.) -2.111wityl., 00
0 ;1,1 ~111.11114111W After mulding wit I Nset In Ulls. r0u. 11,11 fit.5- I I.A) slave
nilsk, .4 111410 deviv. It$ "rift An. 'h) it," I ill V '1
while all hirwhIll 00
With a 2fal ul(A, Its alk. win. 411111,441111t th'tr see un up. (Ishrn Y1.1m) -5-31114104 -HJIlht 11.4. W A% Ili.. 111, Ill toy 1111111.s$ 00
0 loatent merit, fart(sr, to, riplain neh is liclsavicit, It nmy fre%flowsit 14 villa,-r
0,10 his, explAilled toy ft.-mancr IthViloalletlis allit toy foorinsell'in
' .....
lnlvil' tilt- hi,tt 2
~. 00
-If atmil.
14 A 11 bould belowes-it tile mdfa KoSitill atilt a per tr
fill lifil "fill Ill I I's nrid 111C.Hum, flmm Ph- 00
00 Ity militillAtittis 14 thr fe"mmit %trttrttlrr~ ftorlsord hull"Ill- %let lit lilt U.11 AA Willi 4-.601,11m I
00 Ally fly rilvis mill,littivill it wall lawl4ildr Its arrive at the
..anil 4-.01milc sici.j. Ib,-q 00
feAh'soing tattle toy activlllf~ tit C offmin Ill ch;srm-t~fiml fly .14" ffillit alsAly.l,t An't 00
00 ci& atilt In their tjj"'Jj",I~ I fill dilta (hr f-11111119
00 drtiv,~: 1: C Activity its tile parent l-UlAidner, 1.
P-lipit 4). ill limilmlip (Jeriv.- O-Oli 0. P4)II +t,, m
00
A,*hj "till
alk. siolot. failetl to, yiebi Iny pfs.ljj~-ts; I it )1 00
failurr tmyk tilace with tile luitimrst it, which the kt 0
00*000000*000000000 000
0 0 0 0 0 0 0 0 0 o 0 0 * 0 0 a 0 0 0 0 0 0

a Of 00 0 *1000:04to 0000000000*000
is it " ~! aft
I s 1. is to Ac 34 AS ZS Nil 1113 1435 1611 Almost Lill" is J~
t-V 14 1 --1-L AA. 60 PPjI.4j-k- t --#-j_ji ~1
04 -00
00 Coupling was govrrnc(i by the fill group. d-Illicuirlimarn. I-00
ii"sninct-1 -napht hot -2~olfonk- field anti fl-Iwhenyl4&o4- a Iscow" %hadr, Wilts MV 11111111JIlt lit gr4--gri"d 4111.14PI.
00 (1 1.) 11) A fill. R101i 1111pi'llsioll ";k* warlord oith t., t -00
amina-l-itaplithol-I~uItank- acki, howcvvr, savv dlit"n
so derivs. which showvf a illopueernent tot tbe almarption off. PhNIIN11i; .tftvr subsillener of the frAvtiott Aft:,, ~1111110
cooling, there IWAA,obtAillrd 0.9 K.
00 a in&%. toward longer wuvc lesigtki lit comparison with the xapWh44 (111), ~Avjily plate,. sit. inilefinitcly, clarkrionst I 1.016
Initial Materials, Sitste the fill of the narclifun does not 143". decimilp. 185-7'. mil. in oil. vieliN still alkali-,, voi 11111,4111
00 affect the locAtion of the abscirption mat. in cf-hydruily cal,atll, tit twilld klidlotiml &lilt Coupled. I GI it I
oe 4mito dyes anti ~incr the Oil group In them call be titratetl -00
: ~ ~,rjidrtl ill 7.1 lilt. AcOll was 1-milisr,l *life 'J .1, 1-11 I'll
, with dilliculty. the asoM structure (Auvirris. C.A. 20, aft"r life mist, .4, diM $its .00
o A 12 .Ill alipcotit tit be d6jmrotiv,,I Cliff tbxm %Nutifift.. 'rllv stivittig t a. see
v 11"Itc.hirilrazolie" structure is also disproved by the
oo ahActKv of chAracterlatit: -.1411- infralml aboortill . ajimaphIANdi-me, red ro"llei. in. 2LI-W (some dectitfilm.;
Thus, the It of the Off is attachtJ neither to 0 r" too.". IToin ale.). which Is alintf~t frivol. in wi. al"li- I =00
anti the Oil group 11 bonds to -N:N-. This 6 Von- MA c.) atut US 9. -41liNliCtillo were warowd in 1~5 fill.
0 drined fly the higher pil titratirm requirement for o4)11 AcOll; filter u&lKitletive, ()it- juromfoct "&,, grolloil %ilh 1:0 0
a Voln ft" IIIATS foC the t(MMItol5ifing #611() stir p.lialliol) 111011, 641oviril fly cold N,&Oll And sta-long %lih coo
littivs. IV. Niuvissatwo of 3'gc~i6Wd0.j.d4*tW.. Illo. AtivillA I'S S. R. ill. 311-13' (hom Ai,011); the
,,..~wodstct was obtalticd fly tre
L S - Efrom, A. Ii. Poral-Kooltift. anti H. A. Purill-Kollsitai sjone ating 4 Cold %UIIW91~iAln goo
I Uningrall Techroll. I nit.). of C. M In 10 nil. We AcOll with ILLN's is. Cy mi,
0o % Mill. RU3- Ir aGro 0
S '-dan).-Nitrosation of 5.1-AcMICIJ1.011 j;jv",j-xjirojv- lit .5 lot. Avoll, dilit. with W cr. 11,0, rAIK. wilts 010,
(1). wilt" %fracture W44 colifiritictl rVA1 the r%l.. unit wayming site trAillize with w2l At. o' see
-WCJ(. tit 3 lilt. AvOIL Ill (I it.) it-[ 20 ... 1. 11,4)
11 Ily 10"FlAtion 14 line (11). (11.1 COO
heated 13 miss. with 14) tit). A,A) slaw oil c-ling 0.7 S.
To 11) it. 5.1-11.NCOI,011 ituilientled lit too fill. liso Wo-l-mijoshikol. tit. 215" (from ill]. Al:011 see
,i was Luldrd 215 off. AttO atilt ill. inixt. vras wanued until Z.5-dWiriapmtk I.
soln. occurred, on Cooling, S." 1. This (S g.). treated In IM nil. cold A,~Oll wilt% IAN it. goo
AW, of. I- MAN47s, lit IN fill. IftO taild fill- Vitt. rccryall. frool AC011.
.4-5' (front water). w.IxI. This (4 x.) fit U) WOO
lot. Cold 70"t. AvOll with 1.4 x. N4%,X(h its (I fill. 11A gave 0.8 g. tell nerdirm, fit. while iiiin. of the
Ill'. gavv 4 C. 1i, lilloof g4vc brown-YrIlow Ill-rdt". Ill. ;kr-1-4 *; 1-th I tioe
o1. ioderinitely *!ill clorke"Ing At '.,tit)*. $"I lit
W ~Jkalicq, I )ill. fly Avid.. I tlyrs wthil In Ali. Juspeni,lor; to steti are ill Alkali: chat structure N unknown.
lV&%.LUP.ClC-L UTERATU41 CLAWFICAT1040
~. -:-- --- -7- 1=
00
.11 0-1 4-t 511SI-1 44&611 1W Q- fit
ILI
-"--,--A . . j V 'W--Y--v-zr -Ani- -1w '-ft --j "-n-a to e
IV it is 2 " is is It of MAX" if C
0 U 0 AV 03 It n 00 -1- t
0 a 0 0 0 0 0 0 0 0 0 0 0 0 gli o o o o o 0 0 o 0 0 0 0 0 0 0 o 0

0 V. CAMMIUM of with iflatousitts tt
adA. 7b_M Mr-1151in RutifiJan).-Couplins, of S.1-
AcNffCJlaOll (1) and 5.1-ItiNCiXtOlf (U) with diaso-
lized It acid at pit over 4 gives p-110 dyes. while at pit ticoducts obtained were Identical. incWtic-AxAbig

V
below, 4 1 does not cmPle. Il 61VTS a P-aminalaso 41
;
V
lbowlict.. with color behaviur Ohnilar to that cd the Ac
011111 I
I
which hitherto bm been considered to be on ii-O
or an a-110 deriv. The
Pat. 9.3
190)
deriv
(Ger 'Jeriv. L-W; the atf-frPtif.11 Itis. "ait bit)
00 .
.
.
.
0 '
Orwitire was colAhlished by reducti a followed by mida-
o
d 21)
t
KOtf
~ nim. The "tile product was w;talnnj by dea,,vtylatlort
tit the Ae contlKI. by hot 1-4 IICI. Reduction I z I
.if
It
i
.
an
lot. 10
tion to juslone. 1 2 g.) in t
.
4 ~l
IICI xvive It acid and I t 'y
I
00 h the flialinnillf" derly. Imn :1.2 X.
11.0 was trrains A114111- of IICI to the filtrate). which of, heating with Act M
90 If acid in .10 ml. 11,0. and (lie little soln. arlditied with
7 g. of a pointer, forming
AcOll
giving 4 ~od 1:3 IICI gave Oic -allar IlliblaztAr deriv. 444 dc*crit I
'
'
l

0 .
,
a violet min. In 11,0. blue In tilt. alkali". red In stronger u
.*vv. It Ow coupling of 111, roodawted its AcOH-11
C
I
for "I Jilt ;I, aftllis hh-ulival lwodocis are ubulned:
00 alkali", abuwption max. XV roil, dyes wool violet. PuW'lVr' giving a Violrt Vail. in wAtwf, little ill acid" old

00 Titratirm Itave brrak-% tit lilt If and 4.7. the mol. wt.
l
Fm
l
l
d
h
b red ill alkalies. with pl,to. of wmw L4 the dye; heAtiog
uct was o
1e Vooe pr-
ta
ne
w
en
; t
found being
coupling wat rull lit IfIl 4. 11te lircidtict to ;wobahly;
-ill alkAtill yield, Nits (detected by mlor) "lilt A hill,
l

:g
X(S-artlamido-4-hydroxy.) -
-, ""'. &U) out (pit 3). Reductiou 'd
111i. twilauct Willi Z11-11cl gave It arid iold . a
11,0andalittle No- 5,8-dLindsio-1 oaphillot. width will, Ily',
1.*,~Cj, in 111m
011, treated with Zn du.4t. follmml by 10 M). com-4. lIC1 ,
gave jualofte. mi-.4"olge ocudir.
tit. I P (ft.mi CIICI
)

go
aridboiled. gave the ,
.
,
Th6 cutifirol. t lit. %i roct tire ot t tie d yu c,:
!
The o-auj~l.
Woridasar (m),,YvUow icedles without a detwite in.p.
00
WIN" U was call ed, as a=, in alkali &ad at pit A. the
00
'XIC
400
00 N Nit
go.
00
410
00
00
Alf 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0
JLA 0 0 0 0 0 * 0 0
nu MINXI and U (P.
K. and Pvrc-
kalilt. C.-1-40, MV14) fif:X)od. Ilsoand lond. joe;1 Kull
Wal m4li'vil by Na hydroulfit I Acidified; after
rcluovul U S tile filtered suln. wasenallfralisrd by NwAc,
1
rratrd with 0.8 g. pbeamthretmquitimne it, :") cal. it,()
with N:ailSO,. and boiled &-to tuin. to give 0.75 S. at
the cla"'C'I"'I'llillm azine, Yellow needles. in. 307-1()~
(It"In PhIJF)- SimiUr treatinent -f the above dyes
failed tit Agive tile alinco thus confirming the al~ncc fit the
M.
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
00
so
of
00
00
00
00
00
00
00
00
00
00
of
00
00
00
00
0*
00
of
00
o:

~A A _C h I
A
to
-3
i
0 0 0 0 at 0 0 0
a x I If L a N V
SUMMe and
DWWftt (OnU Of A-GiU0dJAWbM4Mj. 1. V. Grncb*v.
J-Ge". Clwm. MSS.R.) 17.1143"'.1(1947)(in Russian);
r(. C.A. 41, 12M.-The existence of the following forms,
4 Jw been showti: dwolifum
chloride. N.& sails of the diatotAte and nkroii~tc,
Anti the diAmaium ~.Its of the latter acids. p-Nitro-
phenyluitrovusnine i~a sirmgrr achl than the diazotate.
The great" extent of hydroly5is occurs in the diazonjurn
diaiDiatc. Titration (XL-m clectrode) of p-sitrobenitene
dialonium chloridemA.,. with 0.1 N NaOH at 13' gave
curves with 2 potentiji breaks: at pff 5.0, which cor-
rc3ponds to the max. concn. of ji-nitrobenzenediazonium
lit ideandtheal),rijecof
kcororipouds to the prrsc free IICI, and at pH 10.2, which
rt, ace of the max. conen. c4 Na p-
nitroLenzenediazotatc And the absence of free NaOll.
Vim& the formuW for neutralization of weak acids with
weak ba.", The following dWributions of tbe.3 principal
forui* (R.Nt*, R.N:,XO-. and RN.N011) at different pit
V.,lues were rated.: pit SX: 09.91, O~01. 0.08; pit 8:
91. 1. S; pit 8_25: K-1, 2.1. 15.9; pit S-5: 4,0,3,,6.3
, .
,47.4. pit 8-6: W.S. 10.5,79; p1 110.2: 0M.97.75, 2.0.
When 0.1 M -.w!n. .( the 1- nar-ominate (to it.)
in M nil. 1110 is treatt,d with 5 ml. 0.3 X IiC1, Attowed to
stand 2 firs., and rapidly titrated with U.1 N NaOll,\
the titration curve i, identical with the oncobtaincd above,
SiOng breaks, at fill anti W.2; immediate titration
The point whe"tlwplll%V.fl
_1~1.111DA102 CLAISIVICATION
so., ilri"L-
(xPf#j
'the hydrol"is const. X.. anti the degree r4 hydrrAY11, a at
infinite diln., are: R.Nj% Oil-, Kd 4.4 X 10-1, R.N,1
ICl-. K& 9.5 X 10-1, a 0.0)1; R*%*:.NO-, If*. Kd fSZ )~
10-10; RN:NO-,,Na %K 6.3 X io-4..0.(r25; RN:,NO-.
R.V:+, K& 14.5. a D.79; 4RN-.NO. If ', Kt 2.45 X 10~-
RN-NO, Na+. K& 1.7 X 10-1. a OM; R.N-.NO, RX,
K, 3.6 X 10-0. a 0.057. 111. Mewmerism and no-
menclature of the diazo compound "des. DA FySai
Kostilts and 1. V. Grachev. Ibid. 1&13-8-~irrr t5r'cu-r-_
-Tent nomenclature of dijzo couipounds is at variancr with
the modern views on their structurr,a new novirriviaturr i's
proptyed. which takr4 into account inmomeric ion, and the
A r.* s* I 'N)
amphoteric opcrii" of the diazohydrate forms.
pr
Cl-(Ars:!N)++Cl':dWus)iusneblisidetc.s...O-nitro-
benzctiedLizoulumchloride): Ar.V(:.N)Oll
OR-: hydrat4oldiasouiuatoxitIci StNiN: ds"anitun
An I a 1W 0 IS 4 1 W W a a S V
'00
'00
=0
=0*
r9
0
U66
it's
W--19 W obit CVA4 wit It It PC a n is it ?W
n I its
0 0 0 0 'D

00
00
00
so
00
00
00
0 a
00.
*0
go
00
00
00
00
00
00
00
00
00
00
:00
00
00
00
ion; Ar.V.N;:O: nittmoaminAte ion; ArNIIN:0 00
(ArNN:O) + It": nitrosomine (nitrosmminic acid) 00
ArXS&NO-(ArN&:O) +Nal-. Nanitroumminatv; 00
ArN:NN(,N0)Ar-(ArN:k) + (O:N.RAr)-. diazo- 00
nitm-oamittate; ArN(iX),N(,N0)Ar - (Ar.41N) +
(O:NRAr). diazonium nitrommminatc; ArV:SCI -
(ArN:i) + Cl-: dLuochlockic; Ar.N:.VOII - (ArN:-
~) + Off-: hydrate of diazoiKide; ArN:' k: di3zo ion;
ArN:.NOII-(ArN:NO-) +H*:diazoicacid;ArN:NO-:
diazoAte ion; ArN.-NON4 - (ArN: NO-) + Na 1:
N;:,~) +
sotlium diauatc; ArN;.NON:NAr - (Ar.
(t]MSM: -d6zodiamate, ArN(;N)OX:.NAr
tAr, iN) + (ON; %Ar): iliazonium diazimte.
0 0 0 0 0 0 a 0 0 0 Wo 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0
00
00
00
00
00
00
00
06
00
:06
0 0~
94
0 0 0

'
0000
10000000000*0000 00000 *00000000000000000000oo
O'DO
000000000000000:000000000000000000000000000o
A a c a v 6 m x l. 0 PQ a I
L(Iff.
Ox
.0 lynx
oor
00.
O*x
slon!
OR
:0=
so-
so-
u r[ n 21 it ill
0 00 00 0 00000001*99
10 00 00 o 0000000008
Ad a
co At It
41. (-*of*$ I I - c! u s a i
'13111,3 all 03 sa aql 10 11-13"Odilu'a uIrtil
all) .'Koljs laux j3qunj 'It L/(W %VA qZqqlA "IN T! (11 2Ul
110,1M u=au1sAdjjuv Jo *610tu 9 4111A 01QW.
"JIV-00 V-1102 uo!jnUaplsW aq) 10 aj)pOP4.%)Sj)Aq!j) -141
Will G-l 10 '0t ' F-0 13) P411ilOd" U041`11' '0111
!M1111AUOU0012,06
'0 PlM * 'Vjl~j 'v a
M".
Mllllka Oup"Puill low Saa
ca" Rota allor4w fill "51 frill
P-A-01WAD -41*411 0 0 0 0
v4--s'! .-A-A~
C4
00
-
.1 00
POO
000
000
Ile
j.00
0*
00
oo
oil
e 00
" 00

A.
UM/Chemlstry Dlazo CampaRn" JW/M-' ]LOS,
Chemistry Titration, PotentlometrIc
"Composition and Tranerormation or Dlazo CMPOwAs.,
D. A. Poray-Koehits, I. V. Grachev, Inot or Org
Chem, Acad Bel MR,, 14 PP
-Is Ak Nauk SSBR, Otdal Zhim. Nsuk- No 1
Using potentiometr1c t1tration method with glass
anode, authors established number or basic laws
and ometructed now theory an the structure or
diazo compounds. Theory has clarified number of
previously Incomprehensible phenomma.
vW 66?26

USM/Chemistry - Dyes, Azo May 48
Chemistry - Dyes, From 1,5-Naphtha-
lane, Amino Derivatives
"Information on Azo Dyes 'Produced From 1, 5-
Aminonaphthalene and Some of Its Derivatives, No
B. A. Poray-Koshitb, L. S. Erros Lab Tech of
Org Dyes, Leningrad Tech Inat, 6~ pp
"Zhur Obahch Khim" Vol X713:1 no 5
Describes potentiometric titration of azo dyes
and states some conclusions on their structure.
They are resonance systems In vhich, in the case
of the ortho- position of the eLzo groups to the
0271" there is closed resonance through the'
8/49T66
USSR/Chemistry Dyes, Azo (Contd)
bydrogen six-member ring. The resultant increase
of energy makes the electrical dissociation of
an ortho-o3wazo dye vith a detached proton
impossible. This considerably decreases the acid
properties of the compound. The quinane-bydrazme
and azide forms of artho-cayazo dyes are mesomerst
not tautomers. With a para-dispositim of the ago-
group to the hydro3tyll the energy of dissociation or
the dye and detachment of the proton is available,
due to the formation of a strongly resonant ion.
This considerably Increases the acid properties of
the compound. Submitted 20 Mar 1947-

051 1 1 1 # I A I I
A I
of .5
A f:1
VI
I
r. a _L_L__AA
1"jpolios
AM dya hm 3.40AD.,

"
4 b dadvatil".
V1
P
U
N
i
2
*
O
R
441116tr
t d&gd=
2
a
10 dy" and Issias Coua-
deelms abold thtsir &w butmg.

nd L
S
111tos
Zhur
tm
h
b
l Kki
j -
.
. s
e
.
e
ml. . Cen. chem.)
12, 9-V-M(194M); ef. C.A. 412,
'k,,mle
`
'
l
t
tr&t
ous Of 8-X,
o-QuI10Q-1-nAphtho1 (1), 4-X4~mjno-

J
fit 1--Phth-I (11). the -V-Ac deriv. (M) of 1. end 4-.':-
Oil N..\--

AAA IA)31 f
2,5-916cetAnjillo- I -naphthol (fV), 'Theft X equils the
for"1111111 shown W
orm prooooord that only alk. Soln,4 of
I- M. and IV. moo Ii, are titrAtable with 110. th~* I,(
114TALLMICAL LITESIAIUMI CLASSIPICATICII
&noel -j taludi -11 C., Jet
o U 11 AT 10 ASJ; '-E-r --- 1 1 4 - I A
to It a at K it $I It It It IS 1, p
~~W- 01-1
WI-151-w-WI
0

be cc WAX it u M M U 1.1 Is " IQ 41 Q A)
1
1
A d
T i a 6 Eo
-, :w . - I -
-
-
-
I Wi

-1 giving indmtious it, rr,p., pil 9 and &2. 8.9 aM 41- Vo
And 0.2a ndS.l. Cousequrntly,unly the Oil grmp in the so
JMFA tINDSdian to the %.S group 6 titritabie. Tlse ab-
- "SO
M nip
owplioni Irtax.osl I moves frum.510 moo at pil -1. to.
;.I toll 5 (U.Ifl-r konijutiou). IVA) mot at pil 7, andSMI on, loo
t~m). An anilollou%
lot PH 9 (Ahnint complete lunita nmoo
bhift of the nu4s, is found with U1. The absomption spec-
1

trunt of completely lonited I is close to that of 1l. The zoo
01yuzoo dyes art resantance sy%temso in which. in the caw of
*
:.,;group, acloerd
Oil groups in the anho position to the N
1 b
d
on
s.
six-membered re4onancr ring ii formed by 11
OlVing to the energy gAiu due too this rrCHIAnCt. OC'Ctflo-
Soo
lytic dismocu, and acid proloo-rtics are %upprrsni. I'lov
i
h
d
i
400
razon
c
nour
"Void --C(.N-.Nk):COII - and qu
y Jr
C(:NN*ifR)C(:O) - forms of the ogtbo cuinlools. are -., moo
)t tautomeric. but rnewomericst-uctures. With the Oil
In
group in the, loara 1~6noo to xlw N: N Wrioup. rk,"rulytic
400
of 11 IX MCIrgetiCilly favored owing to the form,
I'on of a high'"XM&nCe anion, hCuVC the strongly acidic
i
prowrt
cs rot tFW-
Than
too
too

11so
0.0
t is,-
An I 1 0
0
1 At
Ka
o
I
n I

USSR/Chemistry - Synthesis, Dyes Aug 49
Imidazole Derivatives
"Research In the Field:of Imidazole Derivatives:
n. Synthesis of Several New Phenyl- and. Alkye-
Phenyl-Derivatives of Benzimidazole," B. A.
Pora,y-Koshits, 1. S. Efros, 0. F. Ginzberg, Lab of
Tecbmol.of Org Dyes, Lenin ad Tech Inst, 7~_'qp
"Zhur Obshch Khie Vol XIX, No 8
o-DIsmines of benzene series, both v-1thgreater
and lesser basicities than that of c-phenylenedi-
amine, have cbnsiderably lower tendency toward
condensation with carboxylic acids in an aqu"us
4W 140M
PM/Chemistry - SyntheBis, Dyes (Contd) Aug 49
hydrochloric acid medium of optimyn concentration
under pressure. Nevertheless, this method can
still be used, in preparing benzimidazole deriv"
t1ves; except In cases where oxidation of o-diamine
prevents its entering into condensation. In -these
cases derivatives in question may be prepared by
melting reagents at IW C in absence of oxygen.,
Rumles of condensation of 3,4-toluylenediamini
and 31'4-diaminochlordbenzene with benzoic acid
confirm-earlier conclusions on the mechanism of
formation of derivatives of benzimidazole,in an
acidic medium and explain effect of basicity of
E_
original P"'inp on course of this reaction. Sub-
nit-ted 27 Her 48.
W4M AMO

FORAY-KOSRITS, B.A.
i~l
Basic character of asines and their reactivity. Vqprosy Aniliukrasochnoy
Xhii., Tr~Ay VIII 8oveshchaniya nix.j Takh,, (Trans Sth Apili6i-DI-y's C-on-f.)
1~6 9, 43-5.$1 - -.1 -- "NUA 4:4)
(CA 47 n-o'.21:10980 '53) .

Dyes with gatipyrift" nuclei If It,
'I'relitiol. In.t.
A. , 'I'jx;41jkn 1.
C.A. 42. IS:~--In q. -In. tim, lunlyition of wbiool ife-
riv~ hwmcd by the action of alk.&H on tri.ry1%oVdmne-
(if-, %1%.,r% i~ at"itnimmictl liv Ar~sviiKe of hvilmsyl hot and
1.4mAllon of l'olotril OWN valion, The Iki'lVifv Vol"Imul of
(1) At 17' 1, Ill " ,, -1,14 $-
(Vill lonlet I i, 411 Y. Two intledoll Air foond in tile
111mli,m curve. ki at pil about 14.5 of the riul of tittation
jillatitmithat theendoltilm-
tion.of 1. G. M.

MI MEM LIM-M
.
T

Gimburg asill
ith antiffrine nuclei. 11, 0' '
;
tf, . J. Gets,
D~es w
jecil L'
W tIj 11%st
-
ll-KashiN
is,
r
i
)
.
t
i
OH
7
J
22
R

Abs tVIC ts
L .
,
Che,Dicu
401. 48 No.
Mar. 10 1954 chemistry
s
l
e
8 and Texti
1
1
DY

1.68 .5403 an d
~h, phtay
and lzwand IX*O
and IJ358" -2,3,5.0-Ictrachloropheny) and
667" 4
- Itrophenfi -analog. L637 andl.
---m; p-analog 1.603- irwifen Ph.*.: -
45 aild
Ew~ i,r, nnd I
RAMaM,
~NHNO- givti bandi nt'l-521 find L.M IA. W

tra ^--I dructur of sodl G
p,,, a uni salts of arykItmniines,
s
S. UyamonundVa. 1332-6 -Na 221ts
of AryInitratninic owids in,aq- solm,-show.0 elvarartcrist c.
.116, #ouo im fie 'in th R 'tn'.3pectrum. .,rhio -they
-
s
l
fo
A
l
A
Nmu ma
i
l
ra
r
n
pcc
tru
r
r
pan
y-
$
v
2
diM
d f
n
l
4
h
l
l
a
-
n
orop
eny
or m
, phe
,
,
p4oly
,
y
thc-- -.-AMIACM
'toapids )j~-PhNHNWgivin_~ All nitramine

PORAY-KOSEITS, B. A.; RE*m-ov, A. L.
Mutual Displacement of Aromatic Amines from Axomethines and the Influence of
the Basicity of the Amines of This Reaction. IE. Determination of "he Relative
D'.splacing Power of the Amines, page 1577, Sbornik statey po, khimii (Collect 4o-n
of Papers on General Chemistry), Vol. II, Moscow-Leningrad, 1953, pages 1680-
1686.
Lzboratory of the Technology of Dyestuffs imeni A. Ye. Foray-Koshits, Leningrad
Technological Inst. imeni Lenso-.ret
C,
.1

P014Y-KOSIIITS~ B. A. ; SOLYAMN, G. S. ; qnI GMLCT-11, 1. V.
Structure of Aromatic N:tramlnes. W. TautomerLc Rearrangement of AryInitramine
Acids to Aryl -9-11- 0-,odiazohydrates, r!?oe 1337, Sbornik statey 'Do ob~hrh-y
khimii (Collection of Papers on General Chemistry), Vol II, ~-'Oscn,I-LeningM4, -1153,
Pages 1680-1686.
State Inst of Applied Chemistry

PORAY-KOSHIT S, B. A.; RDEMV, A. L.
Mutual Displacement of Primary Aromatic Amines from Azomethines and the Influence
of the Basicity of the Amines on Ihis Reaction. III. Mutual "isplaceateents
of Highly Basic Aromatic Amines,_page 1590, Sborinl.k statey po obshchey k:-zimid,
(Collection of Papers on General Chemistry)., 701. 11, Moscow-Leningrad, 1953,
pages 1630-1686.
Laboratory of the Technology of Dyestuffs imenj A. Ye. Foray-Koshits, Leningrad
Technological Inst. imeni Lensovet

S R

inallics Imti
u-9utual displacemout of primary agmalLn
Axomothinex ind Via Influened of ~ _4$'R Wor the Imjw all
two rea-ekm~ 1. . Ruat'"In of anniothines from p-Ditm.
- L
.
with panisidinv; R. A. PomT-Koshits and A.
Remlix)

-R
f I'l
ti
106
Z
1671 1063)
21
l.
vac
on o
.
Shift 4
. 1m.
'
C1l.NC&UjN -p or.m-OjNCclICflNCJ14NOp with A-
MeOW1,N1lj rmults 1u displacement of tile P-0,NCJls-
NHI lu the bemylidtat structure by thc more basic atolue.
la Completely x4byd~ sollis., tile reliction Proceeds I vinch

WKily thin under tim' conditlons. SuiccUtetaixts.-
tuore
C*nt;iln III RH CIUM $MXII alotS. Of P-MCOCfi,'1;J1j' It 15.
tb-
evi& at the ruction. promils only to a certain degree.
-in be, irun withant a solvent Ill a sealcd tubt
The rizaclian L
1,13 his. tit 1204U', tunmell as [is McPh, CA, and CCI,.
lit arilinary wIvcuU. -fee reactiou manifftis Itictl Withill a
minklics. The dell]. of P-mewlifiN111 was ptiforincil
i
ft
r ti
e
l1
ith DAN NoNO
11CI
l
t
i
i
i
(
n..
r
n
w
a
e
l
tr
am
ca
y w
,
j
-O
NC
NHj which gim tbt. lqi and polat)
titration of
H
l
6
#
p
-2 g. KBr. in~021VQ/14CII:
with addn ~ of I - MCAOMe
lm.-82-V. IT-. Determination af~relittlvo dWacemeat*
ability of tanines. Ibid. 1677-89-lit displamment of
i
m d
b
h
"
oth
ti
aromatic (uninn from t
& bcatyl
ed
,
y Ar
anitnes, the, teaction t-Aes lilac* r,:velsibly aud the t!-mil;
coustants virre d4td; for displacement of sulfardUmIdii Glit
Its bmrylldeae deriv. by P-McMHMt (K - 890-1460),
Fbt4ll$ m-OjNQHjNl.'l (IM), and p-OgN-
C4UiNHv (0-13), Th~- rebtive ability toward 41splate-

-7 7 ........

TS

Ile relationship between these factors is given by equation-
Is log Ifou + b log w + C - 0, where w is the displacemeat i
iability of aa aralne and Kou 61 Its lonizatloft conStant.'
The displacement proceeds by a mcchunis;m analogous to,
that ofsalt (OMIA(lan of the 4011116, Wilt cquIL being estab-

Ribcd among the hrisineg, L aldchyda. and - the ben
jy)IdCnq
derlyi. of - both atulues.. 11t. Mutual disodeasnant of
highly basic aromatic &mines. Ibid. 1690-7.~rjlsplace-
Meat of PhNHj and 2.4-dimethylanilitte from. their )w-
ltrobeexylldene draivs. by eAch other vras examd..-, This
dhp was, found-to take place among these relatively
bas reerdless of the basic properties of competing
antine3, ~ the displacement ability depends first of all
a
0
amiae basicity. then upon structural features. Ionization
constant of PhNHj was dctd. to be that of 2,4-'
Amethylanillne 10"." The displacements were run in,
scaled tubes at 120-2'. -The cquil. constants were: for
displacement by 2,4-dimethylanfline 10.0, for displacement
~by PliNK, 11.2.
G. M. Kosolapoff,'
J

Vp 10
0-lu:-10-11.T. j.Cj
,
rmy 04HTT
V
-10-11 and 10-4-1, add,
basic consts.'

dfdridvee.-~ - V. chiricter ov- - kczfcmv,~107ff, 10 ZACH: CES.
W
10-2~8;-:&GN, 10-*~, , 10-my; i-Hill basic co~ms.'~
ts and their tsurmnerle tmmforms- IW-Aand 10-11.7 add:comst.AO-i~% 10-5,;
I

Nor, 064*1 KAN.- -~705
23 ' 697 ibo- .2.
-W; S,64itWro4-fgd
6-K
-.10 4LA'li 10" 10 j:
loy
bal
castj
a
:

524e. 0l C.". -r
.
.
"
y
-10-IM: -31.6, 91d const -w-0;- 6-mdhyl-2 be I
and lb 10

mphotefic. Thettautoul"3'
-gu
ilt., -1. 10-PA, z Treato te (S i.) I l3tOCl
10 ient of be"Wzo n
tom '
[In - OcIns. the ame cations; and In Alk"
-
-
- with 0.6 g. 161c.NPhOll and 3.3 g_C9v!:Lz -CN a t W-O!
mits nm,
the Locim-
point
W6. the jame aulon, while it
and dilu., with UtO gave 83% 14eVxodhyl*ttzi
mUawle
JoMed _ frM the jaMe loni,jM& anionS.
cat
Zo e SaVe
lbearlinidUole -and L benzImIda I
with 2-meth -0' (from Its% basic const, 10-V. A
(1). m.

i
i
fl 51
milar
y
s, which am baly bms and have no acidic,
(cyiinceibyl) deriv t
u
rcaction with. 2-mtthyibenxfinld3zofe requ
m
hr. ~nd_Actds 70%
ftl F )M potellftnetriC titrationS the acid d
r1
f' __folloWed _City.

_((flOM_JItO; by-long-
_
~
r
-
A o

Ical curm .:am shown). Theze are a3~'fqllom (sul)
typi 1~
const;
Hydrolysis 611 in -10% hot KaOR gave bwz-
10
ImIdamle with loss of the CHICIACOSTI group, - boning lu'~
lutuent and bmsldty'~ and acidity consts. resp. shmm)"

-4
10-1#.f.
4
10-12J
If
I
20% lICI also gave befitimidawle,,,-Iloweveriby4foI
-
.
f,
H (t1 SUbStItuted) 10
n
"
. it I
I Ba(OH)2 lpive 95%
e

d Its
IatL
'd as tile '94 Salt Qv Imitarfy was obtain
hamalog, cryitals:(from dil--lietCO). llmmve
l
H
id
j
o
eav 0
wM- HCl d
rot cause c
ojySiS
f
h~d
MC&&Yjj)L=imidazoIe. - Cyanoethylation.of 2-pl=
-

.7
A K.
benzy1benzfiridazolts failed to take ph~ce. lkt.

r< z; 14 r s
.
I-Id"digs detrivatisagg. VL -lizalligg-s rA 6-0 ggelyblft-
zkmidamillm
-41(lubjj;ct. gold. (Ail-figi.32
s 1U.NJO

e RIGNI
thylW Awle In 10 mi. 1:3 H40a was added rop-
I A'
66::3-7;72
l
h
l
id i
10
l
H
SO
1
3)
-
w
se at
rom
c ac
n
m
.
:
g. c
..(
and the mixt. chilled after 15 min.. yielding
boxylic andstilfate, which with NaOAc gave t~e free
Tn. (from If-O). This (1-62 g.) and 1.08 g.
1. to ml. 20% TICI heated in scaled tube 4 hot.
at 180-200 , then neutralized with NIT.011 and filtered. gave
's42t4e=;m~&w1yl)beaim;&wk, isolated a. the di-IrC7
sart, rn. 362" (from cooed. HCI);, the free base could not be
grified owing to the formation of gels. Similar oxidation
2,UlmethythenAnidazole pv6 70-5% ~2-ntdhyl-5-

Abet, Aertsi'mdazolecarboxylic arid (I),-m.' 301-2* (from ITO).
This with o-Calli(NIfth in 20% HCI as above gave after 40

---
-*01.- 48 NO. a min. at 180-200* 2-mdhyl-S-(2'-bens;midazolyl)&c#..imLia-
.
Aft, - 25 9 1 54 sak-2HC7. m. 339-40* (from. HCI), which with ~%TlIgOff-

'
*
i

Orpa'a a aistry s with
m. 340
(from dil. EtOH), th
gave the free base (11),
NH40H-AgNO. in EtOH gave a flocculeat di-Ag sisil; the
'
'
krate. go. 282-2.5% 3.4-(H
-N),C;IT.-
free base yields a d
Me (1.22 g.) and IAO ff. I in 10 mt. 20% HCI heated in a
scaled tube 4 firs. at 18D-200* gave
rimidawlyl)bessignidazok, m. high and unsharp, which
:gave a di-HO salt, m..above 300' (from 25% HCI); the
free base yields a pLt:rafe, ng. 274*. This oxidized with
chromic acid - as above gave 2-ggge1hyl-5-(5'-carboxy-2'-
bexzimid=lyl)bensimidazole-211(.7 (M), m. aboot 350*
(from 15% IICI). this, decarboxylated by heating with
"
). 111 with a-
eggdallmc at 300' gave 11 (plengle, m. 274
CglQN11j), anti 1579 IICI 4 firr. at 180-200* gave 750/p I-
*
*
'
'
'
b
-
tnxinis
-ben-imUazolyl)l
-benzi
-(2
methyi-5- (2
inidazotyll
*
'3
il
l
Si
dil
d
f
IICI)
l
1[
. -
ar
e-3
m
rom
.
azo
, m. above 30
y
t
(
condensatfoo iv-Sth 3,4-(IftN)jC4Tf%Me gave 8&-907c ".5'
itnidainle,717Q, m. about 400* ( rom dil. 110). 2-Phenyl-
C-methylbenziniHazole with,chromic ncid it: nq. I rso, gave
acid, isolated wt the 11CU
salt, m.3GI-6* (frornati. HCO. Flectrometric titrat ion of
this gives 2 pit breaks; at 9.4 and a weal otic whose pos~i7

don li unstated. Thli heated with fit 15,",
IICI In Stated tithe 6 Ws, at 180-200, fave
m. 308-10 (from dit. P1010;
IM stilt, m.'32:1-43" (from dil, I ICI). Shnitarly 3.44111,%'),
CANfe gave
Infidm4le, m..120-31 " (from dil. M011); 110 salt, na..31 I-
It)* (I'M fit. HCI). Thii iral oxPlized all i
J'belp Y/ '.; -(j, - rarbary- 2' -bell. ini ...... 7
lated as the 116 jail. in. 314-19". which, tinted with o-
Offt NH, and 10 a fl 1. gave Z-pheiYyl-5-jZ'-bfn.-hnhla-
e
zol '(S'-b nsind azol )1benss'"ddawle, isolated re; the
W-110 salt, d not (from aq. HCI). .3,4-(fl%N)2--
HA e gave 2- heny
2
lbensim Is Lsolated as thedi-11CI Saft.does
not in. 360% the free ~,tse Is insol. in org. solvents except
AtOll In which It forms the coffmponding salt. licating
2M g. 3,4-(lfjN)jC4lf3C(NlLflC.' with e-C,11.(Nlfj)j
and I mi. 20% 11CI In a settled lube 40 min. at

0.1 it. J,"i6a;ixoAenyfbenziinUazok. sit. 315-30'
t:m 10% HCI); this reacts with 11NOg without forming i'L
r
diaxonfurn salt; In AcOll it gives a green ppt. with phen-
arithrenequirione. Condensation with HMH or AcOFf
ve the pcitielandi described bis-benifinklaxtile derivs.
P1. C-4. 44. 1100b . Beatiraidazoies have C112racterisfle
absorption inax. at 2700-800. dibenzimidazoles at 3100-200,
and t6benzinsiduales at 3400-M A.; even the latter ab-
surb but weakly in tM vimble, being pale yellow. - VU.'
Preparation of -F if I acWW of bearlinklazole by baking
issetbad. L. S. Am. Ibid. 842-,3; cf. C.A. 48, 26M.-
BonsfinUmak (11.8 C.) gnxwd with 6 ad. conctf. HISO, and
W-16
d
m RIP
19
L
9
N
HSO
a
C
e
ar
ga-
"
..
g- 07S
lek.
7
4
4
(1). 1 (3 q.) beated to 22D-40* in a wide test tube until
H%O evehifices stopped, then to 25D-80' tmtil a tot with
R&O failed to Oft a of beoxiimi&nole an addrt. of N11.,
gave +-4.5 g. Mialidawkselfoak uM, in. 365-7* (from
"so). also 16, (OM 0 by besdins 1.12 ff. 3,4-01,19r-
C4111I%9061111 M) wM I ad. HCOjR mod 5 nd. 1110 40 min. m a
so" tvk* M IWW. 2- With 113SO4

ZAMAROVA, A.A..; PORAY-KOSHITS, B.A..; VILM. L.S.
- .....
Investigation in the field of Imidazole derivativea. Part 10. Acylation
of 2-oxymethylbenzimidazole and products of its methylation. Thur.ob.
khim. 23 n0-7:1125-1230 Jl '53. (MLRA 6--7)
1. Insitut ekBperimentallnoy meditsiny Akademii med~tsinskikh nauk SSSR.
(Imidazole derivatives)