SCIENTIFIC ABSTRACT PETROV, A.A. - PETROV, A.A.

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SCIENTIFIC ABSTRACT
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ROCRNKO, S. I.; PETROT, A.A. Alkylthioenynes and their analogs. Paz-t 7t Synthesis ard prop- erties of alk7lthloisopropenylacet7l Ones and their analogs. Zhur. org. khim. I no. 120115-2US D 165 (KM 1911) 1. Laningradakiy takhnologicheekly inatitut imeaJ Lersoveta. Submitted November 22, 1964. I'll. .. . I . f . . . . . . . . . . I . - . - . : , 1 1 . , - , . . . . ;, . - . - . . . - - - I ~ . S I ~ : 1: . .-, 1 1 , . . .. , : : i'E-K : 11, , . i ; r., , 'I , . , h" 'Y ., o , . " ~ , : * 11 , .. .. . f ~,-n-- - - ~i - - " ' -: 1 "' - " .-. :" . r I Ir . . . I , , I , 1 0 1 ,~ ". ~w, - - , -1 , " - ~~ I , . ! ri . . ! . I n.. - "1., 1. ~ It. 1. t,n, I t-~ `~f -.. I 1 11 , . PETROVj A~A.j R&Ul, K.B.1 VIL'DAVSKAYA, A.Ie Sntheals and proportion of 1,3-nitroalkadion*s, Zhur,org.khis. I no.21240--243 F 165, ()C RA 1814) 1. Leningradskiy takhnologicheakiy institut imni Lensoveta. , ., ! . 'o .I. - ., . :, i I tj . I111 . , n , " ! I . , - z " ,, , , , '. ,- , ,.-I .r 'Y !j, rill."i : , , C; '" f!, . .4 : . 1. In ,1r~ , , ; ! `,~ 4'.- , '. ~I , '..I., 1 11 : /. ~ . 01-Al r) . t I P r ri 1 1 X" Y I r, ()If I . ot! '. ('!~fj r X - Y ~ nt) I I !". ,,2w t1 ".. rip -it, - -1 , CHISTOKLETOV, V.N.1 VAGINA, L.K.; PE7RGV, A.A~ Bipolar addition to unsaturated ~!ompounds. Part !(-.: Ad-l'-,.'-cn of vCj;--dipheny1nitrone to -inylacety-'ene compounds. Zhur.crg. khim. 1 no.2069-375 F 165. (MIR-A 1814) 1. loningradskly tek-hno1og1-hnE3xiy Inst',tut imeni Lensovela. 'JI P e n Mr K( -. - ; - I A I , . . . I I I " ~ M .+ , . r~ ; , PF T R, ~ , V , " . i . ,r/ . 0 .. , '. , " oz problem makes- It possible to,:deternias the s as. luaction, to,tbo: Cora Z mot dt"'r a ":"Are A 4 sli t, from 'i'" attic' -*Itis Of-tdardid&te fund- t -`0404t Otte. prdvldtij~ that li thw:4 a 'T ttoli-4 A 9n) ',LtA:. the, *don& In,; v-, I knowne ~ he th d of constructing ai_ ad based 64 simple -4onsin, (po Al'olepipedg right E cy.1 is or$ and4thers)MMve Loping, the,. domain, v,,for which solutions 4A 1 4MM 7~,or,Is - GOW20- After th" Ile: onvolopin"g-: domain Of ~:Ihi t1k k firs A- , 't- "to, the loci Of, ~tfii -;.4datian': T is chosent the a Vass g a, otobism:oz.!~ ditirm, tu'le th _zAtural' oscillations of'. ilia liquid Lis -radiecid''to, t 0 a of cis a itito Intigrils. and the solution of f, hom Th .1 --systsWo Og4neous equatioUso Wove ustions of the In- 1419td, $::,&n .~ t a 94titti, 'a LeCou't- do 4 h 3o-oE,th4,sYstsn w4rele cc else- 4'N on Ustut trots 4. couputers 0 ~The duve#tcal 8-0 "t1ba of thelptobt Allations "of liquids in `contains'ati- Ls,*-presented' in detail for I -botto' it d 'a sph of :c right' cylindisr.wLth k'sphisrids, a a orLcal Ipper Got dove V slad, 0 a i C a torus~..,., rt has s' 191otsulas and f ca's* iffig 'i A bA i (A.' c, L i ra r 7 11 r !i ol~. khlm. 31. I,e6 c ~l ons (,f .r.,qa rpt- 'dciiti(.n cf firy.,~r.t~ t.y r.J Action of 11 thl im dia'~kvlamldPs on vinylacetylone e r, s Fir I. .* . " : * - a . . I . . .1 7~~. . - 'C", Y A K' V A . A Ya3.9 e r. -id r,-, T, I 'fl S,-S 0r. ZI. a .1. ~3 K a z h K r v s~ : , :, ~ , , A . !,-..; f', , , , K. . !, . ; - , - - , - , , - - . . : - : I i, . . - .7 . - ;l h * . , !. . . .-, n -, . . : i' ~ - ' ' - . . 'IT ~ ! j7 r- a u, s " I , " - ! '.., I , , ~ , " . . je . , : . I .- :. , I I I . I . : . !(AZI "'OVA '~. A - Jjr,-r:,ffl I A. A. I . f .,, -1-3 - - , % *.a i.,, ~ -,,- ~~ *,,~ r, ,, ~ ar *, . : . , -,,. r-,, . . I - I I- I~fl tell "ol i , os: C, r-n,13 a - , ; - ~ . () r 3 a6 d, ','. , :r .:* . - ~T. ob.K!&r.. P ; . 1,,: J 1; 3. . , .. . . . j ~ . Lfjyi . - 1.)K ~y I,... - ~; ;,,,, , ., , ~ ~ , . I . _: i t. I ~. . ., .. , I. ~. I... t . VALfA~EV, H.G.; PETROV, A.A. Teatiag the desalting process or Fiq-lafevs~a.(si he-nvy ,- .,:- "1j Giprovostoknefti no.4.111-13o ',,I. f Y. -',, A 1, : ~ ) (Kaybysbov Provirf-e- -Potv,lmai Joqsiltin,,) PETROV, A.A.; VERETENNIKOVA, I.v. Reagents,dersuisifiers '"or preparing petroleums f'or field of Kashpir shale tar. Trudy 5iprovostoknefti nc-4:1~`-16c, 'b1. (K1 U 16: 8) (3odium sulfates) A.A.. SABO L 11 I 1 9 . . ,j amd laucra~.nri InvPstieati wt ol Pet:-qle aj -,~5a2 Theor processes involving the use of rotary-di-ir cnnt-q,-t,)rq. 7:-,; ~1., 1;iprovogtoknet'ti n r, . 1, , 7 " -')') I t-) 1 . 'MII(A ~, :4~ (Volea-Ural ;is PETIL)VI P?-TROV , A.A.; poR?11,1 f~'IA, fil.1 . ; .", ~ , :,. H. ' lz ' ' n,~ , pr, - - 4 , , ni nur :- ~t- - - Course .' - '- ~ ' '~ 3 . n -v I. - , '. `~ :ec _:I r ~ .,n,, . c,,, c~ -- re age nts ":-1) 41 ',3 1 t , , :11 - : - " - - AN Sg';R I ' I n . ' -- 1 ~ - - (- 1, 1..11 1, ~ . (M.IRA I,,- . ) 1. Lenirj,:-qi.4r i, -'K~,.r, "Grii .,, ~,( ~~y im. Pred a tqv Iv r, ~i~ ~, ~. A. :-, 07: -L. 10" O'l "1"U. 70t~'f It, La ir. v thr: t: at ~C'F r ow n ,~' :3,11.,:-,,, V, ( ."o3crm ; :-., : , ". . . ( ~.- I I "i I I kov) ; P'. . , ".A . '"("Jrow) "Cn sc;mt -iuw :roijlemE i~.' T :e *- ~e r., -- ' ~,t- ' i n -f a b . -.;i *-. - ~c ~ 4- 1~ -,. - A: " . re or I. : 1,o ; a t, 1,:i,, I-nd ", I , - ; I f" , f., , :; , . ..c '-- ~ a I ;,, ~ : ", , . : 1 c3 )! Cow, Z,; 'a, 1, L 'b ( ... ~AH(11, L.11.; PFT40V, A.A.; KATKP-1. ".Y. Testing the experimental petr-,Je,= desalting p'.lo*. plan's with the rotary-disc cc_ntactor in the Novokliybyshev P.-troleum Refinery. Tr,idy 'jiprcvrqtoknef'ti no-4:1DG-110 'u1. (AURA (7oL7,i-'JIr,,l re,,i-,n-Petr(-,leum lesaltirv) BAKAnV, M.T.; I'MOV, A.A. Seismic erfect of un,IF-rFrjund t,)a,,3t.ng In Lzhez~~fizean r-dn.-S. Trudy Inst. gor. (Jeja AN Kazakh. Li6SR 10:11"-14.1 161. (MIRA 16:8) (Dzhpzkiizw Fin I J ; '.r,' Cf-1 I !15t' ng ) k3f- I '47k-L)4. try ) PETROV, A.A.; YAY.'~'TLE'.'A, T.V.; KUPIN, B.S. 2,3,5-Trimeth-11-1-~-,exen-1-yne. Zhljr. ob. khtm. '3 nc.5:'.'Gl- 1702 My '1 3. (MIRA 16: 6) 2. Ionlnp7-Fidqk!v tekhnnloplc'leskl~ ingt'.tut Imeni Lensoveta. (Hexerlyne B(',GCLrJROV, ";.M. ; RA4TK"! A, N A., FFT.R( V, A.A. Synthe,913 -' P:.- S-1.111 '-1- q-' 1! 117)-, pnospnor.~-:on~,ainL-i,~ hAtero, L.N !:-. ').L. if:. 17.. 1 -- r-,~ . 7 ; 2,. . ~_ I - .fc Io s . _,,(, " -,. IMIRA 1,,;4) 1. Leningradskii lekhnoluji! -he qki./ Instit-il Imeril Long,)ve tn. ( Phospriol I ne ) PETLO~. Hydraulic trqns:~i s a ior. .9 j, .9 7, f! M -, f k~ 4 , j I , r, ~ . I I $-I 5-t . L ',M - *-~ '1,~2 . Elek. i tPPI. tiqga ne).11:46-0 N 'KI RA . -,: I . (Diesel locomr), i.v,,q--TransmIsqic,n devices) 2A 3/079/63/033/003/()02/005 5 V.. Ao66/AI26 'AUTHORSO Rasumovat N.Adf Petro ;;"TITLEs, Investigations in tfie field of conjugate systems, OLXIX- ".:Addition of dialkyl phosphorous acid and chlorides to diene OL PERIOI)ICAL o Zhuinal obahchey khimiij vv 33P no* 3s 19639 783 769 i',TEM The authors investigated the addition of chlorides of ethylene phosphorous acid and propylene glycol phosphorous acid to divinylq piperylene, and ohloroprene. The reactions were carried out by heating in sealed tubes, The rseultant 'addition compounds could be subli- A now kind of regrouping was obtained by the formation at I -:~o -containing heterocycles with a structure simi- I f five membered phosphorous lar,to -that. of the heterocycles formed by the reaction of diene hydrocarbons' -~~ith alkyl dichlorophosphines. A number of derivatives of 3-phospholine-I "is a des ribed for the first time. There are 2 figures and 2 tables XT 1JUveatigations- in* the field of S/079j63/033/003/002/005 conjugate.., A060"/A!26 ''"SOOIATIONs Leningradakiy tokhnologichookiy inatitut imeni Lenvoyets (Leningrad Technological Institute is* Leneovet) PETROV? A.A.; PORFIRIYEVA, Yu.I. ConJWted systems. Part 1M3 Course of the addition of hydrogen halides to dienyne hydrocarbonik- v-inylallylacetylome and its homologs. Zhur.ob.khim. 33 no.2:419-427 F 163. (MIRA l6t2) l.Leningradskiy tekhnolo icheski institut impni Leasoveta. (Hydrogen tv fButenye~ (Conjugation (CFemistry)i 8/05 /63/00b/001/007/022 B102~BW AUTHORS., Zaydell, A* No, Lazeyevap Go S*# TITLEi' On the possibility of opectral-isotopb determination of oxygen in metals PERIODICAL: Leningrad. Univeraitet. Vestnik. Seriya fisiki I khimil# no. 19 1963, 55-58 -'.;::~.:TEXT; The method of isotope spectral analysis "or determining oxygen in I:",, A :t.J..-'.;.meta1s is basso on the spectroscopic determination of the isotope 00iieentration ratio by a comparison of the band edgee of the molecules 12 16 12 18, The 4123o6 1 band of the CO molecule with an isotopic P 0 and 0 0 shift of +8.51 is chosen as analytical band. The spectral width of the instrument alit was 1*7 1 so that the band was not resolved. The :JIB 16 18 relation /I f(O /016) is re.-resented by a linear 450 calibration .~'.:;,curve which does not intersect with the origin but Is somswW shifted to lower intensity ratios. The curve was plotted for the 0 8 concentration range 5 63%. The accuracy in oxygen determination was 2-3% in the case Card I/?. /63/004/00.1/007/022 S/054 On the possibility of ... B102/BI86 of standard analytical conditions. The applicability of the method was demonstrated on the analysis of specially prepared powders of Armoo iron and cobalt. The reproducibility of the results was 5%. The sensitivity of the method is limited by*the correction of idle experiment which has 10-41A. There are 3 be reduced by a factor of 5-10 for an accuracy of figures and 2 tables. SUBMITTED: July 23, 1962 Card 2/2 BTJNINA-KRIVORUKOVA, L.I.; ~ A.A. . Interacticn of bivinyl and isoprene hydrochlorides vith sodium acetoacetlc eater. Zhur.ob.khlm. 33 no.2:427-432 F 163. (KERA l6s2) 1. Leningradski tekhnologicheskly inatitut imeni Lensoveta. (Butadiene~ (Isoprene) (Acetoacetic acid) PKTROV, A.A.; LEBEDEV, V.B.; )'(WIRITMA, Tu.I. Conjugated systems. Part 1671 Nuclear magnetic resonance spectra and structure of dienyne hydrocarbons. Zhur.ob.khim. 33 no.23416-418 F 163. (MIRA 16~2) 1. Leningradskly tekhnologicheskiy institut imeni Lensoveta. (Hy,drocarbons--Spectra) (Nuclear magnetic resonance and relaxation) WAYEV, G.A.; PETROV, A.A. Chemistry of organic oxides. Part 22: Addition of nydroxylamine to ot-oxides. Izv.vyu.uch.zav.; khim.i k-him.tekh. 5 no.4:608-611 162 a (MIRA 15:1.2) 1. Leningradskiy teklinologichaskiy institut imani Lensoveta, ka-fadra organichoskoy khimii, (Hydroxylamine) (Oxides) IONIN, B. I.; _4TROV,_ A.A. Prototropic isomerization of eaters of alken.71phoffpt.inic acl,~S. Zhur.ab.khIm. 33 no.2s432-437 F '63. (MIRA 16:2) 1. Leningrhdakly ti~khnologlchenkly 1natitut Imeni Lensaveta. (Phospi,.Inic acid) Osomer:zjitlon) RAZUMOVA, N.A. Conjugated sy9tems. Part 1619: Addition of dialkyl phospharyl chlorides to diene hydrocarbons. Zhur.ob.khi-M. 33 no.3:783-789 mr 63. (MIR& 1~&3) 1. Leningradskiy tekYnologicheskiy institut imeni Lensoveta. (Phosphoryl chloride) (Hydrocarboni) CHISTOKILTOV, V.N.; TROSHCHEBKO, A.T.; PETROV, A.A. Addition of bensonitri-le oxide -o unsaturated ermpounda. Part 33 Interaction of benzorLitr ile oxide with vinylacetylenes substituted in a vinyl group In r -position. Zhur.ob.khim. 33 no.3:789-793 Mr 163. (MIRA 16:3) 1. Leningradskiy tekhnologicheskiy inBtitut imeni Lenhqveta. (Benzonitrile) (Buteny-ne) PETROV,, A. A. ; YEI.~AKO'V, N. 7. 6 f f a , t o f so I ve n t 6 ') -i *, c i- q r* 11 c -~ s onar. ce p-.pe , -7n, of diacetylane and vlriyla,~et-;Iene, -'~h~.,r. oh. k~.im. `3 nr, I 319-320 11 3. (MIRLA 1~-.l) 1. Lenint~radakiy toklmolopicheskiy inf-titut imani Lansoveta, (Butadlyne--S p,, "tra,' (Bu te n-rne -3 p-- c tra ) (Solvents", L 11060-63 EWP(J)/FI7(c)/L',JT W/BW-Fc-4/Fr-4-RWW/JFW MISSION IRS AP3000492 S/CIL53/63/006/OM/0170/0173- AUTHORS Kheraze, Yho I.j Petrov,, A. A* TjTL3j Addition of --- 'Palto divinqlacetyleLand its homologs SOURMS Izv. vuzi mdmiya I Mdn. takhnologiyaj, vo 60 no. is 19639 170-M TOPIC TAGSs triphenyimethyl radieglas divinylacetyleneg "Ipropenylacetylens, vinyliaopropenylacetylenep addition reactions ABSTRACTS Crystalline adducte were formed between the tripheny3sethyl radical and divinylacetylene (1)., vinylpropenylacotylene (2).. and vinylisopropenylacetylene (3) in benzene solution@ Addition ocoumed chiefly in the 1#4--positions to form 7. 7, 7-triphw7l-3-tri~henyl-nethyl-heptatriene,, By 8.. 6-triphenyl-3-triphenylmthyl- heptatriene-1.0i4e Adducts were characterized by their IR spectra* Weak absorp- tion occurso Adducts were recryata3lized from propylacetate and formed molecular compounds with acetone* Origo art* hast 1 tableo ASSOCIATIONS Kafedra, organicheskoy kbialip Leningradskiy tekhnologicheskiy institut imo Imsovata (Department of Organic Chemistry, Leningrad Technological Institute) Card 14/ ------- ---- S/169/63/000/003/006/042 D263/D307 AUTHORS: Alchneyev, P.P., aesyadovakfy, Ye.... , Jiryuhova, L-t. , Golyahev, G. 1. , Ivanovskiv 4% 1., IZ"LOY. IA~.J.. Kokin, G.iL. , lWrilova, Yu*' LId- Itozhdestverw;-.iy, B.G., Solov'yev, N.V., 4peran- V. K.Ye. , Khvostilcov, I.A. , 5hvidkovakiy, Ye.u. Y t and Shcherba, I.A. TITIX: Study of the upper layers of Lhe aLmosphere with the aid of meteorological rockets PERIODICAL. Referativnyy zhurnal, Gcofiziha, no. 3, 1961, 28, abstract 3A166 (Tr.,Vaes. nauchn. Leteorol. soverli- chaniya. T.I.L., Gidrometcoizdat, 1962, 91-103) =(T: In the pr--Dcnt review-type article the authors give the results of studies carried out at Teentralnaya aerologiciteckaya obaervatoriya (Central Aerological Observatory) on atmospheric sound- in,g with meteorological rackets. Measuring methods are described and the main points aro given for obtaining such atmospheric character- Card 1/2 5/169Z63/000/003/006/042 Study of the upper layern ... D263/D307 istica an pressure, temperature, and wind. Certain results arc giv- en: data of seasonal temperature variations at heighto up to 50 km in the middle latitudes of the USSR and in polar regiona caaes of sudden warming up, characterization of temperature distribution curves, a table characterizing the temperature inversion bolow the atratopause under the conditions of polar night, and data regarding the circulation in the upper atmospheric layers. Information is given on the constructed meridional sections of temperature fields ajid on the sonaL component of the gradi:nt wind. (25 references). I Abstracter'* note: Gowplate translati n Card 2/2 -~ R:Iclv A , 14. P. , I'i 'I . " ~ .!. .. --.-T -, '. ;!r I - YV 1 4 ~ ..i . 'r.,. I I "v ~i ~-'. . iii lanr, -~w -,- '," ' . ':,- - - - ,j,;' I , r1 :t, 4 -"4 k TF. L'~-) A Y "i , I ~ v . : i ~ -, 1 7 , . . ~ A Studying H-1-onrls, formed by ficetylone liyrir,. 'tirton.,., Ph 'f,P ild ,.' ,iurlphr rr~ignrtic mo,jn;i.,icp sl)ectr-)sc(-jfy. [)I ~. i q-e '.r. P, Il". -~ Li,P - 1 , I., .1 , 61. . USSR/Chemlstry - Petroleum, Isomer- Nov/bee 51 ization "Isomerizations of Olefinic Hydrocarbons Over Aluainosilleates," A, A. Petrov, A. V. Frost, M.I. Batu.yev, Petroleum Inst, Acad Sci USSR "Iz Ak Nauk SSSR, Otdel Khim Nauk" No 6, pp 745- 752 Investigated catalytic isomerization on alumino- Bilicute catalyst of a number of ollef inic hydro- carbons under conditions excluding cracking. Pro- poses mechanism of isomerization involving split- ting off of olefin from catalyst under formation 19MO USSR/Chemistry .. Petroleum, Isomer- Ncrv/bec 51 ization (Contd) of intermediate alkyl cyclopropane product - The cyclopropane derivs then undergo ring opening through fission of the most highly assym bond. In the unsatd products, the double bond is usually next to the side alkyl group. 19M0 USSR/Chemistry - Liquid Fuels 11 Jun ~l "Conversion nf Nei -Ir Ac- tive Aluminur .31,11-ate -Rtaly~' A, Fe~rov. V. V, Shch,~,Kin, lTist. Petrc,~eim, Arafi Sri '.; L;S R "Dok Ak Naue SSS:~" Vol N~ pr ~_~-915 Monome r f re,: - i uns oi Pr,)duc t )bt a,. %ed t,,~ - nversion, at 2501) dc -),.t c~ntaln ~ -membered napnthen-5 Poly- mer I)r:,duct ro~sult,~m, frc~rr, -. ~nvt-r-n-. r, c! _--nethylcy- clopentene- is ~_ycluhexyLmethyl~~, -opentane, sub- stance ldentlcal with that fcrmed Ir-m cy,-I-_,hexane under the srme , )nditi,,)n-, ApparQntly rine:. expan- sion of pentamethylenes pi---eeds o-,,,y 184T15 USSR/-Cbemistry - Li uid Puels 11 Jula. 51 ?Contd) similtaneously with polymerization. Dehydroge- nation over this catalyst of 6-membered rings into aromatics also seems to occur together w-Ith polymerization only. 184T15 344tic ttansformatfall of 0101113 over IdualjnUill alu- Calej, 8,.,j._Vcjr" I vies. uz Sores Itamn..; Pa !L. J ruts W Nsl~kcp (lWatel. n, S.S.R" IlItIcts) 1053, 144-50- 'Refcral. ZPur., Xhim. 1954 No 2ull ~ dl~ctm%icfl Of i oh-Kni which practkally pre- C-.tt:liytlc Irmi.lurmatlous Cbemical Abst. Vol. 48 No. 6 Apr. 25, 1954 Orgenlo Chemistry Retilstribution of hydrogen In hyd,ombons ~n an 110 C ;IT- 1 47 FjORM If ,3 hro do and structure of olabs dtqohi; broM 0d, Al. A. Petrov (ftuoloeif ifAcad. Scl. U.S.S.-A., Alosaffl.-Zhar. ONEVeMhm. 23, 18"IBM?.-Testo with 49 olefins with different struktures am reported in the reaction of these with 1% Br soln. in MeOff satd. with -NaBr. * The hydrocarbons were treated with excess rt*Mt* land 'he excen Hr was back-titrated with MOM after addn. of KI. Usually I min. contact was sufficient s'or the "2ction. The colorlem soln. %.-as treated with 8% X&OI ju3d the liberated Iodine was again titrated As usual. It was shown that the amount of liberated HB:- depends an the structareoltheolefin. Linear oJefins and these with aside chain that i3 not proximate to the double bond eliminate some 14-16 mole-% 118r. Olefins with branching at the double bond give 27-0% HBr, while thm with bruching- at the double bond and in PAW. having bulky groups at the double bond (iso-Pr, AfeC) give large amts. of HSr (41- 75%), The course of the reaction my be represented by the Wowlog scbcwt.~ the McOR-Dr, complex yf" MeOR and the olefin dibrmitle (straight chain olefins), at it carbonlunt Ion after a4dr. of pog. Dr Ion, whkh Is then =Mby MeOliBr-, yielding HHr &A a methot)r-. (for btanched otefins). Both courses are JIV, adected by steric factm. The reaction of 2A-dimtth*S-. hertne gave a colored product, ot 1.4WI di - IMM, which contained 6% Met) and 46.6 Br, thus confirming the above hypothesis. 0. U. K060140off I - ... The order of adijklon 2t hounifors of Vinyl- 11C" A, &'Pavq ~1711 "'WIP), aut S S.r R. 89, P73 11-ffOr0% rf. CA 4. 7751c -ro +t jf~ m,c ceircif, I,, L,(x) out cifcl, at -x' ,,,as qddcd A:j It I" 111 10) out. CHOI. diffn Ira- Q no of it jell, Ill I't) to 14V/ 11) of whi, h flip m'At at"m4i"t It-, h,. 7" Hjj r7 or I It, fol)-vtog I-,- ka-an T)-fron, of the fret uency =41) con. which I, th~( if . triple link 1 (72 g ) ott room temp, %vith 2 7 g Koff in 2.5 nit Ftoff rve If& 4 firs. 1A)"/0 bromble lon. while flip win Virlded tw)% roffloMitertyne. fleariju I with concd Iffir-Cu.M, -I ,0 4 lim- gave wine 110/f, stable dif,romide, Af,(*B,: CP- L ~Itfi: C11,, big 57-7 5', d. 1 ")5. -'~ I 57M. which in ale KOII lost but 5% of its Dr. under the attove conditions Ozzmalysli of I and treatment with 11,0i, gave A,011 rid B,CH,C11B,C0,If. sit. 04-6". With KNIr.O. I gave the same products. The high-boiling traction (blo 132-11') was impure letrabrooniffe. (in 2.3498. .1,, 1 0160 Similar reaction of 40 g. r,-CC:CCif:Clfl with, Be in,cf(Ch save 52 S. mixed di- and polybrotimideq which fixtri p to I(Y) /V) ITIVII From three was Mialed 21 or m-aertal, b. gn-Oi*. which after redistro. gave pure FIC CC111l,Cl1,13,, his 87 7 5', flip 1 6921). n',,' 1 5170, %vljo%r clipm properties were ii1entical witty those of the Isle analor Along n,nto thin dibromide wai oblainril 10 S. crude felFabrinni4r. 1),* 144 liff", d. 2.2(r,15, 111.' 1 6020. Similar Inonom.wnt or 45 or; JIC; CC.Me: Cif, In CIICI, over 9 ties gave a rauKr (if fca- Hoots of which the principal one (40 ic ). b,. 44-63', .., redi,ul.. yielding I ... re fl'C ('CHe1J,( lf,lf, (11), h.. 511 1 5" da, 1 7.1111, ?1,,, 1 SUN), f"'jur"'Y _211M IF, If with union Local AgNO, jr:,ve a title j,pt of the Ag .dt, but thin could fit)( Iw r-cr-I by allifo of IfUl With A, KOII 11 g;Iv, (Y)% of-b-in-3 ~MVVT _'. h. :0) C. ve CHB, CB, C'Afe - CH, b. 4S." it 1 7741) a-- I !kIX). which was quite stable tn air KOif. rcrs~g b.i 4%' of its for after 4 h-. at to= temp. In affilm to ff. di- bromide the original reaction mixt. gave 2.3 S. product, 1),. 711 W', probably C1fB,:C:CA1oC11,Br, which. h,.te,l with 1IBr-Cu,Br,, gage the above dienic dibromide, b,. 49 9'. An unstated amt. of impure letrabromtfe, his 1~ ' 45', wm% also obtaineIl. but this deciomp during ili~ n H'I" (*C8, C11, 1.. 52 1% d. 1 4010, nlj I Fic ~ f` CBI (71, 1 3531. 1 SIM- G M Ko%oIASo(1 11 0 PE~'Fa)V, A. A. ".". A 4 - , 6, ~ it :A,' ~ ~ . T - -~-- 4. - -,;.-MIC(IL Attit. 48 No. P A, r. ) 5 , 1954 ~)rgFinlc Chemlstry 114 0 PICTROV, A.A.; AULMOV, A.Z., akademdk. ; PORPIR'UVA. YU.I. Order of addition of alkylhy-pohalogen ides to vinylacetylene =mologs. Dokl.AN SSSR 90 no.4-561-564 Je '53. (KT.RA 6:5 j 1. kkademiya Nauk SSSR (for Arb,izov). (Halogenides) (Vin7lacetylena) PETROV, A. A. USSR/Chemistry - Fuels 11 SeP 53 "Isomerization c.' Ursaturcite(l Hydru:arbur~6 1111virg the Compositlon C ~2-~' A. A. PE-trGv, Ins t , f Petroleum, Acad S~I USSP DAN SSSR, V~,l 92, N~, 2, pp Studied the dcidecene-!, tzidezene-1, and hexadecene-I usir,F Ai2, arA H,:~ as :ata.yst. Aluminosilicate cata.yst vas-' used for the isDmeriza- tion of hexadecer.e-i. Did ,.ot detir, tne struct,,ire of the isomers. Preseited by Acad A. V. Top~:hiyev 1), Jul 53. 269T17 46M.- Di-, Of-ic -Oy 411-rn a too$ O~dwuat thl, nO6i Id Me ' - d rftab ,u p 3"2- BNU'Am cyc Odlefifts Ilmdr SPICUIP . A rc k-.041kelij, Vj 0) f or tlxqts in whkb: Bit 71hercd cyclej nd to form ~- ur qt c atom$ In sid 'J rts Waft obsclved lj ~'-'Ie,4 (cum ' AfeOR. a sum a save Auo-' i of 2 4 - 21*4 2 we. Pic IW fU , -IfIQI'Clf' no. C V etclIMLICILI'le'~ flild 1111CHMe'; M"ClICNIcclit gave I'tt"ClIcUtu and a bmall runt, of CIII(ClIMC& Mir CIL:Cffg), gave PrOINle and (CIJNIN~; Rt,C-CIlMd 4 tavc AfeC]IBu, MCHNIeTr, and ClIs(Cf-fMc,N- PrCH:- Chf - zicilivift). avc BlIcIlme ri-ClINIest and c1l . , I g f. bt td,% work the attention wo Isirgely dimetut to the satdo product,". tile tuoutil, pr,.xfis-,ta wric4hown to h Cold OfAtIOn U3 the lkild. all(11011 fisittl UbOVV. M AW Il the loolowing proilucLi fursned.* Jr-om I-q-thy IcycUlptutene -l 45 l l lexalne o % 5-me"fixted cy0allex and 65% nieth) eyc front I-ethylcyclohexene, ~ 33% &membered cyclanes an -dimethylcyclohexane; from I-propy !665 1,4 lobexene 0-memIxitd and 28% 5-mensbcred c-t-datics; fro f~- ll l t l h (W G b d o es c ar cxane, - and 3079 &snem cre cyc 'Q y 7, fmin 2kylbentene. , At 4W0 I-ethylcyclo-.! G. 9 27 l 1 h Ni ph LM7 pwitcue Have "lute, e % Inv cycla ly 0 % , taw. nitutbetul cyclants (larliely 1,11-dimtthyleyd 1 ~" ! = - , bcc d Y 1 :1-pthylcyclahexene shniWly pvc 42% 6-me clane-q, 20.7 G-m=ed -9 arolnutics (xYlenes), an4 38 4 l b h i I - wid a l cyc 'a-ditucthy cyc o ines (1, ttle Mescligmesof forinntion of.the productil Ufa discusped. PETROV,A.A. Effect of sulfuric comocn-inds on -itrilytic f,.nctlons o! m Q, krudy Ini3l..nefti n-.4,: -QQ I , . i(MIRI P:,2) (COnlysia) (Aluminum 91licates) (Sl;lfur cr~mpounds) I D - 4 it Y69 aros a .50, 46111. g2l wml J 9-5u- tmm~"UJ,J.-. AA- 1 - \,,- . I . . I "! ! . 44e v.-I A I IS3 91. ctivated shiminum oxide. K. G. AL S him. 2! --Tlie catalytic properties esd f At i h i i t I - vat w t m nera ac ds n the isomerization ^, act The activating actions of the ackti Increase In the Witt- inK order: lf.BM. Hilt. H.M. HCI. HF, H2504. IINO, ha~'no effect. The activity of Ah0ii uctivated with I(CI is ditectly related to the #-%tent to which the surface Oil groups ate replaced by Cl-. Itisproposed that the active centers of the catalyst have the structure o l --406-A --O-A if K cil bo,!-,.:~ :--, I . . . I . I w .... . . , - - 1 1; 1 f% 4: "q ra J HO lif 1h# o4armination or unaac=ted hyd rbon UM'Solution at trA ta~ mahanal is -o=mod in the light ot results n1th 120 IM.Up of compounda. OcItaffling acce clefffts,and Mrsm~btr. OYD 0006j'gaVe a fitgfter bromine mmber than the calatlated o6eeff' This phona;%1106 IS IaLnod.' : BromIrztfat, la'aacomp6led by afvamfon ~4 hydroten broml oi Moood is proposed Cur deterafning tha mobW Lot tawaaa. ~.In alk6nos W lenes tran %be results of broatraClort. t S 4- j2ff'. oda-' PWROV, Al.A.: 3ERGITINKC, S.R.: TSIDILINA, A.L.: TWOROV, Tu.P. isomerization of ineaturated C 12 -C 16 hydrocarbons. Xhim. I takh. toPl- n*-1:26-32 Ja 156. (IGRA 9-.?) (E17drocarbons) wr 12* W4 MW di POU 41h t4" ----- - 4F.- auylcy "Man4 cycromit hem lih .,rem, -:'.2 cilybtet Ne It&-. "oh, -mcthyl it 2-Wethy -1-pentme., .2 -21~cat=Fi 'elbyj Y o Y, A,, A-1 " Y d6mc, S-ca;~hyl-S-Oezttadtme, 7-meth' -peatedcxacit yt4 t ep Y dlwthYW-CyCwhextr.C. lAkilmethyr-l-cyclobezene. One Y1 . y =- l belene" ene 2, Uftethyl i W ~1. : -J it ' ced butylene et y04, trilso 9,4 b mtthyt-3-undecwt. 54so utyl-4~uoneaa, ~ ,7! * ~4bmncj 3,5-d!mtthy[-"odecm&, %4-di=thyi-3-vmec- "tactityl-&tetrademe. IUirnethyl-!-eydo.~ -4- Cent. 1:450butyl-cy Pen-i Pen , J t6hi b t I = ime, %P h % - -cyc =ear Wsd clo exene, uty l tio e bro i t = Th - -1-cyc en I Y t-P n m e as n gue", P he p4 of -jaded om the average 12-1M Oult I f group W astm me, in - swe-cham of eydoadmi on Ini th mt, tham the Presence Ot icterwe of the coefficic of the 20C. groupimthering. ~ In the buitance of aliphatic hydrocarbons. the bruneWoror the'WO-chaim W approxinmately *aSuae-1. t effect ott the value of the-coeTw(eat as the awnce of tvio - ' ; r . TbeamCot 111 subitituticipaht. the di4fim. , : ~Iova& to- [it directly refated; to the; structure. cit- a cotapd.." for developing a method thedetit. of' mi'UtIlix-ed , if thedcgrvaof bratichincof uaj4tdI-hvdrombmx from A. P~ KO xm. tim dat4 ma USSR/Physicai Chemistry - Molccuic. Chemical Bond. B-4 AbsJour Referat Zhur - Khimiya, No 6, 25 March .957, 181-5) Author Ygorov, Y--P. and Petro7, Al,A. Title E,~terminatlon of the [Ie~rree of RamiVicatior, of Paraffin Hydrocarlons of C12 - C16 Conposition by the Method of' Infrared Spectrcscopy. Orif~ Pub Zh. analit. chemistry, 1956, 11, No 4, 483-488 Abstract Infrarul spectra of 28 alkanes (A) of normal structure and iso structure Of C12 - C16 composition are examined in the region of valence C-H 3.35 - 3-5/%,u in a solutici, of CC14. The character of change in intensity of peaks observed allows us to show the groups where they belong; CH 3 3.38 /- , CH2 3.50 and 3.42 - and CH 3.48 -- - As the n,imber of groups CH increases vith the ramifica- tion of an alkane (while I number of groups CH 2 decrea- soa), the measurement of the ratic, of intensities rf peaks 3.5C %nd 3.42 tc: 3.38 /1% proves to be a measure 7,1' Card 1/2 - 26 - i ~ETRCV, A. A. Doc Cherr. ~ - i - - ( I is 5 ) "St (t, i n tr,,- !'i e I - -, f of hydroc,irbons." !Aos , I ~: . : I ; i ( Acq,, 1---s' of ~-e* 17 ' , I -I. co,, ie ,; (KL, 4L- 7, (W _ - f " ~l . /4 T.'_ - I V . T1,SR,Chemi-a, Te-hn(- -_h-~rr.;'-a- P-la-_7 Ein,l The.r A: -)- .' --ati ri -Trea'.Mp!" f Na*, rfi~ 'Ase 3 an~4 Pe,r M,:*,-)r an,! Jet. Fu,f"~- L -v, R e f Zh ur - IQ,, a; ja , N- Ba,;hara Ya.% Ya .:7. . Pf--' A.A. a'. f. lhi*~ t. w, "n i~ Ka. . n,,v7-~Ij F. The jj,i t a* Ka n v ;i,~. y !7, -f K' ne- 'ne*'*- eh Y,i ra t e r,, e p r-1,i - t i o n , f -,h e feI S whi-h has an a,iera,'e wade!, n'-en'' r 65--0%. T- en-, ~rrl ',he nereq,3ary h- ry; th,~ -rivie ~je-,r - . e -'un : q ";' t , " - - 1, - -'! !, 'i .!- .1~ llcm~ u. refil - m(,nt whi, -h lt2-r-a,~-, U,,_ *-mt,,-r *,hf, avl'ru~"~, '. -.- !-3. ', f- )f' rea, o%*, " '-, - -` r~, er )n H ea', t~m: v_- ru r A" THORS: Kusaiov, M. M., P~--trov, A. A. eo-4-30/51 ~'ITLE: Note of, ~tl tne Of C) il Enkl 3 r. R-~ u I q K I .. -- q V ).. .4 V 'L 3 11 oy e v n Fj f- I rl: t 9 ., r,i Z,, ~* 1;, r, f t -v.)jti i ikt. r V U St OyCrli VC 9 *1 r. elf t.. ;Lr.., .~,j ~ r2l~)r 1,AL: D(, S F P ABSTFACT: The autherg -7; u., - J r, e E, .1 u I ulr, ` I vC) s t. t u rq f. " 9 ro r t .9 F N, -u 7.j -3 i T. C' h r t tne a., - r st, f ai c, ri r. *r, U D.q if, u:i- q j rl ~m , A:. I - :n o t e',,i.qtic-v,. 3 r , u i Tj t n. Fhe m- x n ci s t i v t o r. c na r a c t .- r- - t r,.-- f r 9 - an b L o t t n r r n.. 7~ 3,~ rv 11 9 C - v C, u 3 -r. c t r, D f n t DF-31 ~rL C, 'IM . A I . r M I . ~u 3 t r t t h t j I n m - o v.: -B t~ rA 0 car"I d- :~rma i Dn of' t r, 9r f ;, c - I r t%, in* a c t w ~,! n Note on the Hneoio#-i,:~ Pro., x ! ic.- L r,; t,.,. 50/51 Cl 1-fiiitpr 11n* ~.,rf ace jr,,j r, - I, I t Emu 13 ns L tro I eum f o rira r. f,c., jr I v 'in a I OIV. I OU 3 U t 1.4, 1 - 1" rma t r, I r, t 9 r,, 11 --r:, sik~ un 1 n u . 5L, , , L, p- o n - v - r t m bu caused t)j t~jr~f- j f 1, jj.j 1, Lj t iij, jj~ U I eas t i C I rT-, I I 1 3- 1 t e f f i_- c t Li in r: --v--rqi !--f : ri it 7 n t~ t e ,I uant 1 t I r. ~ r,, , t :- : z 1 rio. t ,I.? r h - o 10'. 1 t I tr- enum~.,rqted. F r t r,,- ~ r: -, s, of .r.v.-- fi, t ~ -, n I ' 'I ~- n:: f t. h e n it tu rk. o r. ce '. r o u m r. t n r r t ,i tn.. 9 u r f :t c e 1 ;1 t n rn, 31 -) # - -1. r .9 r f 4 rf c c- 1 aj e r9 n q r., x:nI r"~ t of NaCl h f i um, from Eh !3 1 r- t .r,.- rim invest IOj I r. 9 :t -,r: ! . 71- 3-. rl"IC - r '3 0 f *he vir-l -,u s t j p e 9 n t f - r f a c - b e w ~ P n o qr, i w EL t e r 8 3., 3 9 9 an -I v 3--~.- ou s ~ r~. rl- i ~q . nf~ surfac v 1 3 - t r i v u e s ~ f r it T, t Card of lo4 surf F, C 9, r in o : ~t m a -x ~ m u m :3 r n,- t n. No 1-~ on the Rheolo,-Ic Pro: ez ti ea of Surface Lajers at tne "0 - 4 - 30/51 011 -Nater Inter f ace an I 7ne I r '181e In I h e o' i Emulsions in th" gurf ft-e ',,ty"rg Rt tfie of lr~e whter 'n trp f Mio.,V of ii ,I, fl( luti-r'n 1 -1 11 re n , I j 7ora -, t e, .1 vr . t n a murt, it~t. I. 1 1 v 1 .1, q t I, It I ti "1 1111 qs~hft I teou r-, 4 ri oug t, r, - 3,: fac.a Fij erg - 7t~- I n V,! a t I p'Fi L Ion n I ri f I !, ~I n t r, -, 3m ~ 6 4: t I _- r. :) f n p IJ j1h)II11- 11 "1,' -' r Alft III? U t~':L -.rpit'ir. I of' t t, 0 me f o rm It t i -) r, tti., I -,jf-r in 1 f trlol fw,t, r-1 .Jr. thf. rheol ot- Ic I r rt i f t " e .9 r! 4Ce . 'Lj e r .9 M hk M 1 t p .9 1 t () s tj le c t v, i t ~i b T -I I S r I, h,- ie~.ydratioii Find de- .tliltl f 1"qI.1 r, f t,. ro ir, i onirac tti i za .i ~-)n of *ne ; -i r Iiin k, t,-rg f th" ! r -.1m A 1; qn -v A T~ 0! t he ~ f f i c ~ ..n- t .1. 1. - -:I. i; t r ~q rhere Are i r-9 t ;i ~~ - v I ". 1 A5S1_C:A!`IJN: Petralffla LWftj1tu1te AN I'IESR AKa1..-m1,', riquK SSSR I RFS.-,*N TED A rt A V r u r. i .. I-- v , A - -rr, u n SU BM I TTE D F-~ruir~j AYAILAbLE: Librare of Car-1 Pr6TROV, &-~. Specific conductivity of oil .3v;lsjons. Trudy Giprovostokoefti (MIR, 13;'~) (Fjmulstons-~Iactri,~ propartios) m I I A Iz 1-j --eri -t -.on of 3 -. r-ted -~ 'r !j C.-)nvcrsi.)..s of Al -!ien W. t- C.. 70 3~~' re n-.::7'ier of new 1 t- were in*, T-t'w a f3 t -- *, ~e t i - n t L: !3 r- i,re U reactiv, ly -)f -,s.T - - --e -'. : '-e:.ces, .!.e A333C:.*~-.I~": T7~stit--t A~~ (Petroleum Institute, AS USSR) S"BY1"'TED: "love AVA 1 LE' L i ".-Y -if C-)n -:-e"43 1. Hydrocarbone--Saturated-Isomerizatim 2. Alkanes c6 - c. -Isomerie converBians CLrd 3,13 A T;.'(). i J? T I T LE .3 - -e i z a t i o f ~at~ :,a .3 -ovodorG -- v 3 1 C, l,S Of *,.'I e A I K ar,03 r e 2. l,:omor.,..yye 'll-LLUI ~;CAt PERIODICAL: Izvestlya Akade~;,,i J -li.U ',l*:l-'.-,/L' -.j A B ~i TJA -'T i 'I'Le use of ata, j', stigaticr~ cf t elscL'eriz '1~~n ~lf a builine-~olnt up to 1'oOC ioasi~lu. :.evt:rt~,ele32, it ILI v. r.,, dliffi';I~lt t ac I i'eye tie isomerizati--. ar,~. f f i '. I t.-a above 2,.0C " III t~'e irt" I` :. C 1, e.. cataijsts, The purpose :)f vur- .1 1 1 . the structure anq of -.:,e pr~Fertiej o' U 'I, the Jso:.-rzat.,un c,-' a i a serie.~ -C16) was ir.ve-ti,'ated ;.n t..e 1.re~;ei..-.- 1j, at a It was to4n~ ti,at rw:.if,.e(l :.Jurce :-.j Card 112 ~L re Isoc.erizatiGn -f Sat,.,~ratea -.j rc -- " ~'. -:, - c a t 2. Isu...Qric kwo.,Lvc,,rsicr,~' (,f t!x Alka:.-~s ' ":.e -12 the alfar, .3 river, h zata.j t nilt. Wa3 A thermodyi,iL ic ~alcul~iti~iii I t,,e z- u of the al&u~.(-,i of tl.e C12 Cl,,, wai tablea wA 1~ r,!.e,-nces, j. vi.,.ic*,~ ai-r! AS")OCIATIOlit I n s t i t u t ie i I i ~j< i i AS USSR)" 6UB.MITTEDs oove:.-.ber -ard 2/2 t r j v , '11 T 7 TLE T~i c I!; f 3 t (I I !j, --levolor,! vj' Tri i;fo:-,tIor. of :3.*. r.'I e n i.,-,a t 5 1 k Iv ITH I C' A L Izverti;:I A. A S C Ii, v rious c.~~rlier %i ~fra tn( i r i c- t r i f ,ilk. ines -re 11 s~,;- v .V:., love'. t-., t ~t t '1' F~ t 9 U! e r re T.. n ;~u r ont-, o r! r -3 of ;-overni- t~.e t e t r t 0.~ t 0' % r -i e rg o n t L: r T 0 t rt 1t -1 j i a r -i !'f i th- -t i 07 1 1 :t f Furt--r '-re, it I e:-i -Lt 1,-, ti '7 r r, t t t'.e i7 t ,,l, f t 'Petroleum f t i 1 SUT-::.:I-.1ED N 0 v e er mi e f- Card 2, 2 ri, 3 3 5 Xly-Je O~3 ii.,, i eolo,-ii i ri;;r,,IoLkA goryunk-L~kl- iskup yvryk~. ',osA-;- ecml.-e,-a ~Cjl,nuy Pri L.,,tlanL- A rL I'r a r a LrIA c, a i~ ne Ne : te k.'. i I i X i 1 -, A Ij 1~ t rit. 1 Y, T~P I.IYL.VL' I r r -I b6 4.1 Y- o. ta tOr - I VJWIF Pt Uln~j-,!.- Ik ~j 0' on-e o -Ile 'ol r 3 G &t Card 2/~ ua i WO ho r4 4 i:a rf": r n r; ~j 3 a ;,t i i nr 1i k (Petroleum Institute, 13 USSR) y b.- r, uzov, cienceig, ii :~bv'- 17 1 Hyd roc ar bons - -,',Yn t he.,~ i s2. Hydrtwarbons-)pe-r grit t: ana ly s is ('a 1-d TT, L, Icv I e Of PETROV. Alaksey Aleksandrovich, ki-ind.khim.naijk; TAKOT-WV, D.A.. red.; P%TROPOLISK,~YA, II.Te., red.: TI.SMIKII.A, Te.A., telchn.red. [Desalting, and dehydration of petroleums] ObeRsolivanle i obezvozhivanie neftei. KiiibyFshev. Kuibyahevskoe knizlinoe izd-vo, 1959. 82 p. (MIRA 1):2) (Petrnieurn-Refining) AUTHORS: Fetzov, ;~I. A., Ser S. R. Ne,,hitay:o, N. A., Tsedilina, A. TITLE: Synthesis and N-11~erties of the 11,~n -,met!.j' -a.,".13! i.',-1 I of the 7ompositicn I -C,,, svovgtva 12 alka-xDv sostava PERIODICAL: Izves* Akalimi,. na,;k SSSR. , T 1,- '41 -17-q" 1 nc~~ ABSTRACT: Since t~ hydrocarbons o f th i s str*;- r~., n - F~ ently inv"Bti#.:at,~rl, the syrithesi3 cf the mon".,rehylalr,~ ,p~ratUre r)f m(.r(% than Wan kanes wit!, a bf,ilin~~ tp~n gated. With th"s mon(,meThylated alkanpa one mq~- theoreticullj p-,ss-'tlt, isr,mers (there are -~rly .~-7n They are f-irthermore of interest because they have micilly stable striictures and meet with all men,a (,f motorization. T1,v h~drocarbrna were nyntl.esi7p~ i coiling t-, Grlt:nardla rpt -tion (maj~nesitimbrnmoalkyls N , I ~, thylketones~. in this reaction the purit~j f the c,)fr,~,~inds cb- tained ieTends in a high degrpe on the p,ir,,Iy f thp Card 1/4 811~stancea (alriyl bromides',. T~~is fact was Synthesis and PrcDert,.es -f 7.-*1 -.,3 Is~itu Alkanes of the Compositi,-)n :12- -- 1 i. in the vresent i-iv-2sti,-atijn. The methylketnnes we,--- by alkyl-a,7et -aret.- As intermediates tertary al7ohOls wore qt f,:-st were dehydrated At redist il 1-1 and hylratpt,in auto,--lave on nickel at a temperature of from , `., ~ , -n perature at wtic~. tho-, hy,.Ir-,r:arbc)ni3 obtaine! -rysta.11-.z~ W~,s termined by plottirgt~i,~- heatiriE curve by means rf th~ -recording KurnaVr,,v pyrometpr. The purity degree was by means of a special thermographic device.N. 7.. :,yaqhk,~v.:~- to whom the authrrg express theJr gratitudo, (~arriel -)ut 't- measur~ments in the laboratory for petroleum chemisIry f institute mentioned in the Association. The purity, dAf,-r--- f the synthesized hydrocarbons was 97-98'7"0. The thermoj-r~tm was r,- corded by a special aluminum block which was deai6n-d i,i tt-? Inatitut obahchey i neoreanicheakoy khimii AN SSSP of General and Inorganic Chemistry of the AS USSR,. ?y thin ii tomatic recordinp of the heating curves the melting process could be fixed exactly (Fig 1). With almost all (-ompo,injs "- Card 2/4 tained two stages in the melting process (-46 an-i ' i,,~ Synthesis a.-,I i-r- 0:*:-Z .f Alit anti a cf tK~! -a it I Ing ari-I crys'.3.11 i3 at., cm-, r~ s - 7. e pert i es , f Ole 1'ij I &rt -)ris are ji von n -1 t~ibi (2 shown 0~.at the dons 41 ty an i the rofr:i- t. 1", i :-.1ox 0 'al ju-nd (,r, ~i? I iiitj,,n ,f tj~,~ :,ut,,r m,-. t t, j 1 1,. : I j a '. ~ *, rhaiii, wllr,.t !H wiil lr-. line NIth data by -'at-vskl ) R,-~ The crystallivatirr, temierature 'is, % vw,'or, strl r,,,: 9 n c' Q b y 1. :! 8 e h y I r ", I -, e T -. Cf - ~. L: , - '-~ f t r-j .9 t 1 o n e m r- a t u r t t i. t r,t n t i ri o f and o f u nd i a om e t,) t t t. Ei n,-. t E3 t I c,,mr-arati -, e data f r-)::. I,,e f 'r 9 -instead"ness i .9 h 3 r1,1 r f i t? i* a ri u i e r Li% odd r. imf:-~ r i % Lhe !aa . , ': I ),. , . -.'!. o t t-;i:. ~,I f 17'. J 111 3,:. f y I runs v x 1 3 a o Irfl :cr.- LI 1 r" t t 4 'g an 1 r - I I v tj i""h i x r t.i Y, L% t I ;~aral 1 e I i n f r, OF 9 i C ~ r f f I ;I uf; ( ft V, .. I : w r] !"iI if I -q t I t a 'J