SCIENTIFIC ABSTRACT PETROV, A.A. - PETROV, A.A.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


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PETROV) A., and SOKOLOVA, E., AS USSR, Moscow
"On the Effect of tert Butylithium on Esters," a paper submitted at. the 16th
International Congress of Pure and Applied Chemistry, Paris, IQ-24 july 1.~,57.

ALT 'If ORS i Bal Iyan, Kh. V; Petrov, A. A. ; Porf i r~avs, Yu. 1. j
TITIS: Study of Gonjugated Systems. Part 72. Ffydrogenation rf Al ker.7: acetylenes
(lasladavariya v oblasti sopryazhennykh sistmm. LMT. 0 1 dri M) vrLr. lye
alkenilnteet!lenov)
FFRIODTCALs Zhurnal Obehehey Khlmii, 191)7, vol 27, No 2, pp. 3(,'~-17()
ABSTRACT- Experiments on the hydrogenation of propenylacetylene (pent~n*-3-in-l),
butenylncetylene (~eyene-3-in-T) and Isopropenylacetylone (2--methvl-
butane-I-in-3) with collodial palladium as catalyst showed that in the
case of the vinylacetylene hydrocnrbons vith final acetvlpne grouping,
there 18 a greAter selectivity in the hydrogenation process than in the
case of vinylalkylacv-telenes. The chemIcal. processes occijrring during
the hydrogenation of the hydrocarbons described are explained. The
isoprene in the hydrocerbon mixture derived during the hydrogenation
of isopropenylacetvlene was determined in the form of tetrabromide and
by the product of Ito condensation with malaic anhydride. Tt was *a-
tnbliahed that piper-ilene and hexadiene-1,3 were ~ormsd during the ~y-
CArd I'
0 drogenation of propenyl- and butenylncetylenes wh'ch enter into reaction

79-2-19/58
Study of Conjugated Systems. Part 72. Hydrogenation of Alkenylacetylenes
of further hydrogenation (up to olefines) in a much lesser degree than
the very same hydrocerbons obtained during the hydrogenation of vinyl-
methyl and vinylethyl neetylenee.
A similar selectivity van also observed during the hydrogenation of
acetylene alcohols with final acetylene grouping. It was discovered
dur4ncy thot hydrogenation of the hydrocarbons that the entire surface of
the catalyst, capable of hydrocarbon adsorption, was occupied by acetylene
gmupings of alkenylacetyleres up to the moment of almost complete con-
version into diene hyirocarbons. After the surface was liberated, the
hydrogenation of the diene hydrocarbons began with a considerably greater
Card 2/3 rate. 7he differences in the behavior during catalytic hydrogenation are
explained.

USM/Phyaical Chemistr-j - Mole~-,j-a, -'hemlca~ Bozid.
Abs Jorar: Referat. Zhurma.1 11himiya, No 2y 1958, 357--.
Author A.A. Poetrov, G.I. Semenov, N.P. Solvv.
Inst
Ti tie StUies in Region of Con'uGate 3ystema. LXXIII. Question
of Order of Bromine Addition to Vinylacetylene.
Orig Pub: n . obehch. Wmii, 1957, 27, No 4, 928-933-
Abst;-ar,--t: 'Me ftf7ared spectra of I- and 2-brymblita(u- eap.-I.3, 1,2-dibromo-
butadiene-1.3, 4-chlo--obutad-t eae -1, 2 and tv-D urtin fractions of
vl.zqlacetylene dibromides were studied. It was shown that in
case bromire acted an vtnylacetylene, all the 3 possible (Librc.-
mide.3 were forming, the &Uene (I) and the 1,3-cUerie dibromidei3
prevailing. This confirms the conclusions arri7ed at earlier
basing on chemical data (Petrov A.A. and others, Zh. obstich.
khimii, 1950, 20, 708). The content of I in the mixture rises
at the expense of 11 at the bromination of vtnylae~etylene, if
Card 1/2 -36-

PNTROV, A.A.; PORFIR'(EVA, Tu.1.j SSMOV, G.I.
Research In the field of conlurateei systems. Prart 74: :nfrare!
apectra and ronctivity of vinyl ncetylanst hydrocarbons. Zhur.ob.
khim. ?7 nc,5,1167-117's My 157. (MLRA 10-13)
I.LonineXadskly tekhnologicheskiy inatitut imeni Lansoveta.
(Acetylan~ compounda-Spectra)
(Vinyl compounds)

PETROV, A.A.; PORFIRITEVA, YkI.I.: SUISOV. G.I.
Research in the field of conjugated systems. Part 71): Reaction
of propargyl bromHe with aliphatic aldehydes in S.N. Reformatskii's
conditional reactions. Zhur.nh.khim. 27 no.5:117')-117P My 'S'7.
(MLRA 10:8)
I.Lenino-rudgkly tekhnoloelcheskiy Institut Iment Lensov--ta.
(Propyne) .(A ldehydes )

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PETROV, A.A.; KOLSSOVA, V.A.~ PORFlR'YEVA, Yu.j.
Studies In the field of con.1,igated systems. Part 7119: Raman s-,-~ctra
and reactirity of vinylacetylene hydrocarbons. Zh,-Lr. ob. khiz.
2081-2087 Ag 157. ()CLRA 10:9)
1. Leningradskiy tekhnologicheokiy institut imeni Lenaoveta,
(Buten,yne)

PF-10V. A.A.; RALLI. K.B.
Cor,i1w,ated systems. Part 81: Crrder of adding brominp to
lial~-rl-vin7lAc8tYlOnYl- cox'jinols. Zh,1r. nb. khln. 7- no.P:
2402-2406 S '57. (MIRA 11:3)
I.Leningradekdy institut aviatsionnogo priborostro7enlym.
(Bromination) (Alcohols)

. I - I , , - : . . I
1 .1 . I . .
1 7 1 .

1, . ;,. . -1 .Leningrud lbehnological Institute fteni Lensovet
1. Acetylene-Infrpred sr-ectr,- 2. Vinylacetylene-.Icoh,-.Is-infrared
spectrp 3. Infr~-rel 5-ectra-,,pplic~Itions

LenIngrad TbehnologicaI Institute Lzneni Lensovet
1. Acetylene-,'. lds3tWdes-'Lnfr;tr,3d 3,pctra 2. Acetylene-Ketone5-
Infrared spectra 3. Infrared sj ectra-Applicat ions

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AUTHORS: Petrov, A. A., A,,
TITLE: The Reartion -,f 0~,. N Chlorcpentone--' ine
Pre son op of 7 -t 'o ReRK'~siya kh.o!,qpre,,Fi
khlorpentonom j,', - kli-.rn-)go )'ova
PERIODICAL: Nauchny)-e dr;k.adj ~mahey shku.y, Kh;.miya 1. kh,ir---hesi(aya
tekhnologlya J~Lq, 11,- (USSR'L
5~0-532
ABSTRACT: The polymerliza-.- 2- -:Ioropentene-5 with chloroprene in
the catalyt)r. et.- i S.. T- _1', Waa invest,.gated~ A3 R
I
result a c-,mr, I F -mil' a C if C!, wfts f,.rmed 'r
14
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In reac t 11F a o m p -) f3e s; i n! a -
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3orption -i- com~~),,;nd points, tc *hf- atsence of
Card 1/ 2 vinyl grr,-jpE,. J-e I isatk.rati~d halogen -n.,:ro

SOV 156
The Reaction of Cr.'.,,r ne pr--~-
Tin(II)Chloridt-
prpr-,p r t1 4. Tr.~- iirt? K'Are
and 3oviet.
ASSOCIATION: khimi:
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acetyle.,.t-,- in tt,e pregen !e of wilt] ~:.()vl?
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piperylene Ic- ~2--hloro~enter(?- t i r~--: e
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Investigations In tne Y ~K)~ 7
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ASSOCIATION: Ler , -,r:, a I s k i j i n.,3 t i
(Len ~ ri,-rad In ti i i m, - r t c
SUBMITTED: May 2
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A~ THORS Pe? r ~ ~ jk, A. , . '. , ": . , . 1'.'. . .1 " r. . *. . : .
Sh va r t s Ye . Y
TITLE inveit i ~7a i or~., 1 ro. 9 t k, 1'. H 5~
vaniya v J I 'I r Y'l t.11 r,.,f 21"1 q i s t pz. LXXXIX. :, r. e 1 r
cf Vur c.u.4 r,~ Y lo i f 'It: ran - 1 :p :.
Rea tl N f r' r) 1! .3 r () - ~ I I - I-I1 0 H ' X X Y 1 Y
r,3-,. i r
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PERIODICAL: Z~urnal o b:7 h-,. e y K V 2 r
'USSR )
ABSTRACT: In many invevig~itions of syr~tneslzinw erun.. e
a K: yle~,i ~q i -a a t e t i - r, wa 3 ; a i * e n
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Various Factorg r. 'he Y,~- C -
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aT,
f ie;,,r, of t:.e v a!.
t ,na* wi 3 am j ie; ~--, v er s 1 in 9 e - ur e
de pe.,, i t ~.e ;,I ii: e a I a : j 8 t t ~ie %a t t, i
ha ioi~(-v fa r ~L 1 qs . emreral - 'i re t ~, e r a
Card I r f I --. r , ie. f

InvestiCati-)ns i.,~ c,-
Vari oun .--a( tors cn U,.o Yi., f G. C:.
prene Wi th Its ifydx:) -,,I- ri 1,a j
ASSOCIA2ION
SUBMITTED
mr, r . z a, i,-. -1
t e r. o 1 t , e 3 e r F, r e i se r!~;;., W: i n
and jf frr,m 1 .'%ere ure res t c
1 r ef eren -,e ~, ir% . are
Lpn . n-r -JL;~ :y i- ..eskiy irig*. i t t
Le n IT i.7ru i te rpr..L
Y ay 2
Card ""I

PRTROV, A.A.; KIT111. !i.S.
I
Order f va*mr an~ al a-1 t' cn ~: 7' Z- --T.
-). -, - , , , I ~P.
() ~. -,~ ; -. - ~~ -~ . 7: 1 ),) , (-,c I I V: I. : , : -0 )
I.Lani,.i-ralskly tmk-noloplc~ifiakiy Inatitut i-moini Lons,,vota.
(A r-pty In na )

t n.-
r t i
t h -,e r 1m: r
1 1
re r

i o r. s i r. ~-.e e 1 _'o- -.~,7a te tems
a* e 7o,~ v
a t t z*,,-t ve i n,-e n e ~ r re s,~ t 9 r r,;7 i -- L- d t o h e ~n iv an,,
cDnv,r,c ,nfz It vag snc-mn that t",e abovo rcact;.,~i.
in two ma,r, ilre--tions under the fcrma'ior. of '-,hl.rine-5-
methyl' oc tadlene-I 0 ' 2 affi hation). jMI 1-( , i :rine- --
met~..-i' o~talilpne-2 6 ' 4 aff lliation~, , ir. art r,,Xlm tely
equa.k quant.lies '. by-product '2C -:) j "orm.-,i a.-., v-el I
ap:~ar,!ntly a 1 methy'. -2-cnIorD-ethy! c,-;c-.o*.-.ex,.,n-z--,'
-he
tion ). ~~.e main -,.,:Jjctg leadc
was obtained irom ne-',
a
::jpth,/: 7ctad-ero -2,6 accordlng to ~~ommle "Som-1- n tne
strei%.,-,tn r;. the comnarisor. of the results jhtai. - I bv the
affiliatior. reaction to tne analogous ones obtain,d In th(l
case ,)f isoL)rene congi IerRbIe _nfluence of the .r,-;c ',ure c f
the (lien- n"dricarbon )n the aff iliation p-roccF?
nalloi-en lerzvative2 coull be found. There qrs.) i ~-. re
tablp, anj 7 referonccs, 7 ot which are Soviet.
n. ~rFsveta
teehnolo--1r,~eekjy inqtitUt j77e
I-en n,--,,il in-7tit%ite of -ec,-.no-ogy i .-ni _-i,j7r!t,

... I I I "a I I . . I . I - . . . 11 ., .- . . I ~ . . . - I - 0 - -
. .. . ! I - - . 1.1! . I I -. .., . - - .-I . .1 . ~ .
511 : --", . 7 1
.. . -.1 .
I I -
-)4r4 J~A

prenyl
k livinilij
.~hurnal )~.qnrt)ey khimi
on
,;inyl
o w F, r 19 n t
-n the n 0:
Ft ly ur
S 1 71 t 0
t he I

t 41 on j Ln tlio i ( I - ~ :I 'I. -f " ~ . ': - 28 -8 -51/66
. - I 1 0 f ~ cn:! j SOV '79
of Chloropranyl to Divinyl
ene -2 -L i
;",7 the
it f-;tn
react-l(r. tq r-,
m -j r - ro ziot fu;-77~j in ccorJ, r,.:,:
r,ilc ul-on thc af - iliat,-or. tne nrlo,7,-n
r' loi n .- ir " on of
,u-)I-, bon c - i c c to
0:1--Xerle-3, ut~.ine t'.-
an t i t i e j , t a c c -)n ' ini:
n o n o r 9 o r. -'. c are
o f .411-4 c a e 3 v 10 t .
L en i ngr Li I i t ek h n o I o -i c i~, i n t i u t
(--En4.ngr,." "nt!titule of . .:~nc-ot-y -,--.en'L ov
Jlufru F] t 1 )5'

PETPOV, A.A.-. POFYIRITEVA, Tu.I.: TAKOV1,MVA, T.V.; MINGALEVA, K.S.
Conjugated systems. Part 42: Order of addition of iodine to vinyl
acetylene hydrocarbons. Zhur.ob.khtm. 28 no.9:2)20--2)24 S t58.
(MIRA 11:11)
1. Leningradakiy tolchnolo4icheakiy institut imeni Lensoveta.
(Iodine) (Acetylene)

PETROV, A.A.; PORFIR'YEVA, Yu.I.; SEMOV, G.I.
Conjugated systems. Part 43: Order of addition of alol hjrpobromites
to vinyl alkyl acetylene. Zhur.ob.khim. 28 no.9:232_5-2328 S 158.
(MIILA 11:11)
1. Imeningradskiy takhnologicheskiy institut imeni Lensovets.
(Bromites) (Acetylene)

. . I ~ ~ .-.. ~ I . - I
F .. .
v,iniletilenokBidov
I
I
I
f
I

I I
t - I
I I
I

I
X . - "I I .. . . I an

3oviet r.,fVrel.ces.

. :1. 1. w I. . .
I

A'~, -;: c
.'T LE: 9 1
u r.,. ~i
s
7-x
f-v

r
xcv. Reactl3r~q J,
and tne 4 Hy r
r a n9
f
Z, r r s ar e r. r a -
1 W, t"
OF
Card e.

t 1 ~ a
Re act 1 w, R T,
and t r, p 4 d r
t
a ki
j , y t t. 11 ar e s fl
a a t t ass~.me '.na*.
af f ~ Ei t a r. -j :~*- 2-cn,cr, ~ente~-,e- t-
rj- Let t~y i I
A--;C-:AT:C:ii Le r Ei eK~.r.3 -.7 ,,np 3K rst t -it mer.. Ler~3cv,--';~
s t t t e i m e Lo.,. s t
J ii, " I :~e em,-er
Card '1, 3

A
n t~ru :t ljp;.
V IT f~y
IOJI CAL: J')
ABSTRAC'-' the works
0 f w h. C h s n
a C e t hy r"' a; ~3
:,-:ribed (refs 1 , ) . T~i. , r r ;i r. nl
rsf;~j ents, in thl. s case w, th iiazome,:~Fir.t:. r-
.,.!ereating (refs ",4, Di~izomLthane ease r-a-
'u;-O ty: en L, un d e:- f ) rma ~; or. -) f py ra Z- r"f
i t produc e s py razol i ne, hcw,.- vo~- r, a i ri
,uld not fnd data on thf- (-rder ~-f % r-,,
-azomettanp -.o viny: ace%;:,t~%e :n 'e':nn- a
formation ~)f vi I '-~ ': ~~'; : d X I
ny, pyrazo.
wi th the B t rong to-ndfincy if tr, t r,
connection if nucleopn,.l,.c w, v
Card 1/3 showed that the -orinectic.n '.akes

Interaction Between 'l.ny'.
b ~ !, ~ ~7ie o.
s t ru c ~u r-1 f n. 1; 71 k r Aj
m,,an.i iT, rt
t
2) A 7 c r, .9 r ~i r, 9 e FLn d o f
iLn,i eroup i n tv z ft. w P r, o s,~ r-; n -
3pectrum, m,)r~-( v,-r, V, ;.Ve !-in.1 C H
no ~:y
a., .~nl '70C m- r, f ra e S 0 f
r- i en r, e ~ c r, -- ac r . i - W
b e t w (- e n 4,---0 and '00 cm- 3 r.~ 4 "T. s-,ierab.1,
W .
n o r d e r t c, v f~ p
v c h#- a i-.,, - 8 r e - r d e d r
i s - as 'i n . f r-
do,A le t i nd 1 no7s. Due th, s r~ ~t:~ ~i
doub: t ne n r. g ~i,(. I
e t hiry I pyrazollne .3 . n - t- re 1i v a : li~ -9 r~ r.
Card 2/5 rrAq encies correspcnd to these two -.,.,.rqs

Interaction Between Vi4lyl Ac-~ '_, ri: I :j,. itz-
folind In the ,rF-EiHnt ;.,ive.9 I lKal
renote with diazomethane as a con.uga'lo(l --i ,,a e m ri i
diazomethane is connected only to the
order of connection corrospondg t,- t he n:~sumf~ri
of vinyl acetylene and to the nucleopni..
diazomethane.
Thero- are I flt-.ur~- find '0 w
ASS C I n'r: CN LeninL:ra~i3k~y tokhno)op-i
P R ---'S F-'; T'-, D 7
Card 3/3

~-THGRS: Petrov, A. A., Mingaleva, K. S., Kupin, B. S.
L~polar M~,ments and Reactivity of the Vinyi Acetyiene Fly-ir
TLE:
c a rb on 8 (-11 po i ' ryye momen ty i reak tsi onnay a a poso bi-, a t
vinilatsetilenov~kti uglevodorodov
r~ DI :A L Do k I a 1y A kadem i i rifiuk 3315H Vo , I.'. Ir,',
I USSR ,
A -T: The invest.gation of th,? ~ildi tl,,)r,. re-~c t i ons (.)I the pn
hydrocarbon j I i to th~ cunc I us i in tha t i n he mo i P,-.i , ~ a
the vi ny I ace ty I ene Find n -a I xy i ace ty i ene s : ) th- e i - -7 t ro n
cloud is diapiacerf in the direction of the tri ~ie boni ~ei
However, in the case of the viny, alyi acetylenes (I.: and
some i5oalKenyl acetylenes !IV; a double poiarization of their
molecules had to be assumed which is increased in the one or
the other direction depending on the nature of the aa'.enaa; in
the interaction wi tn the hydrogen halides the order of adi. -
tion proved an electron displacement in the direction of the
triple bond Ref -/, however, in reactions with bromine, water
and aIc.)ho],3 it was the direction of the double bond Re~s 1.4
bird This twofold reactivity could have its cause in the weaxeninor

~,j;ar Moments aLd ~euctjvj tj zI V . nj z f= ty I e r, e H j
o f the pularity o fth- eri 1 :, system due to a r ar a e c ~ ro n
d i s P 1 itcem-n t i n ,j n e Iif- c t i on w h i ch i s o n t r,~ ry t the i s!~ a
d! 8p' a -ement in t h er. i n system
physicai proper t~ c s 0 vinyl al ky ace t I enes ter4l . s.,, , w
such a polar', za f, in 3rheme . The authors me,i:iur-d t h- I
momen t 8 of v! r, , I y I a P L j ri e a iv I t h t h e f 11r) w I n oi It Kj
groups: N ; - H ;!, -,
xH H,4 -
4
vel I as t h,~, i a - an t r ar, ~4 - pr-,peny Li ti , e r, e s the i so -
p r r) ; e n y I a, e ty ' e n P~tnd the fl- tart. bu ty', - v i ny '. , ~ *, J. n ~ , , 1.
f,,r th, r-- z~ , r. I-) ~, ,T. p , r i ,i,, n , ~t , s- th- mom--n t ,f h- ~ h-rij
,tce ty I . Th o f,, ow i r,,.- re H u I t 3 we rk. o b tn i n t, d T h e
moments of 'he vn.1 a e t hy s r . eny I a e r, e s r
-artl'.ari thn t ~,c- tj . ~np
bj the tr ~n 1.si.acement in trie oj,~ -,si te (1 1 e C t i on
n ~) n - .4 u t~ s tlut-i viny, Rica ty 1 ene wiA a P x pe r i men t I r,- v-
TnP I i i I r m m- n t ir,creaaes a I t I P vy i t ri t h i
n ~-- c ft r t. n rad 1 cit '. bu t then remains Itt,out c(,nstqn t n.
1 6- , r. 1 t r ~n j rr) perij ace tj ,en-s th#, - . Pc r,,,.8 re 5; ar6~ 1
rI t n e -i ,.M - I ! I - ~ , T. 1 r~ t t, I n ) r1 - s , i n ti t i t t P (1 r, ~, , e., . -- r

0
m n ii in P ; t
I r f, t
. The "OKFer-%~itar~ P ft R t can r~ t b
r, o Ie c ~; , , I i 9,.) p r i ny , acLtylene. Al though ,-tert-hutyi v,.r;j. a
I ene ~~a8 it higher 1;~(,) i,tr moment than itjo; rcq,enj. a- ~ t -, i - n f-
t h 1 a ri I i, , I tr m,,ment is f I )tie to tha t -, I v i r. y . bu ty I a e t y I ~ n e
~'ri u a , I-hp mf-tsurpment re s u I t a o I t hq I i j,~) r- mom- n t 8 1 v ny
;i c e ty I en- r.j 1 r-,c&rt~-~n s proved tne t ' the rea,~t,.Or,
mechani8m , I the ~ddi I ion in th-t ;laces o! tnp con, ugated
triple ..n,* d.u~lle bond, as earjer proposed on t~.P basis I
,~h-mica' chara,--teridti --a. There are ' tables and '(, ref-rpnct~s,
-17ol which are 5oviet-
;-SO'IAT1LjN: Leningradijkly tqXhn,):OgIChe8kIy 1n8tItut im. Lent3oveta
(Leningrad Te,:nn,-)Iogical institute imeni Lens(,v~.-,
F ;i A. Art~.iz, v

50)
AUTHORS etrov A
TITLE: Th e Te I ome r t! It t I It, 'If Q- ' 11 10 r0, tit 4 d i ene - With F,;,Oryio!,,,
Y e n a 3 o- . 1i vl~k)r-, ,,)m ;,i er i en~i ( 2-kh1,,,rpertfnom-
PERICr!'A L n F1 fl C h r. Ye 'I Y -J93~ ey O.k-)Ily.
to k Y ri,) I
ABSTRACT: The ; ro:ien t ur t ~r-wo t).n t the add 1 t ) un take ii pl a(,e
a ~, ov e a I I - t, ti t we r n I s? r. t ene - an I a- ch I )rul) ii t a I i en e
"he I
six -omq -)., n,1 9 ;ire i r!tpd . In. vif!w of the ~.-Iylro
p t`,~i t ane t C,V; of SOMMI e I S r t ~on
tne brorinat ion a-cr!,ng t , Kalifman 'only one I u~le honl
reacts' t) q 111 n-Otir ;1-id an.,, 'some
a MP t hy 1, 111, C- 1 ti 1 11 it 1 :1 -) 1i tn (-~i lorl rie-qi;1,.,; t i tu Led a,, He
anA on t h, ',us i q h e '.,11ustrutej) infrarol g ;-,ec t rum i t
i9 state ! that the -.Dm; c-,nJ
is fjrme~ e~~tl. fi 7IT,- C T I F 17 !7
Card

The 'elofner' z;~'.. -)f a I T.
enter.e
t
r
.11 r, t e q r. Z
71 ~j ri v :1 li-
t 040 1 e -11 e r e -
Rl'
t one i-,9 i ro, -,i i,I n i o
-~r t ar 1j -, r. tl.~, F-rm i r
F1 e So, I e r re.. c P s
ASSOC'ATIOIT; Kaf '.- -3 ra J-,kf, ~,,c
I.I.Stit., ci
C, 11-1,-L I rf 0 F3,: a 9 t ;. t It e
ST7'BMITTE"
Card 2,2

ritrov, iuecovlav%, T.i. ind lomer, V.A.
,0V,'51-7 -? -2o/34
T1 TIZ Ji,f'r-artA )p",~trft of' ;ortxiin DI-Suristitut6d ~Iiena Fydrovirbons
(I11!r%Krf1Sn~'Y#3 b:)OKtry noKotoryKh JvuY.,vaoshchenripch allenovykh
~;,,l evyl o rod o v
0-tj oca I ti -_,ectro s dx ia , ol 7 r ~,67-271
T UC T i The iuthors obviined the infrared transmission spectra of the following
nine allanoti:
hept,idiena-2,3 (curve I in i f*i6ure orl p 268);
nonsidieao-2,3 (curve 2):
7--inethyloctadione-2,3 (.-urve
(ciArve 4);
octadi5ne-3,4 (curve 5);
nonadi-3no-3,4 (curve rj;
7 rothyloc-t-id ion*-,' , 4 (zL~rvo 7,;
7,7-~i;-i,qthyloctLiiane-3,4 (~-jrvo 9
rho frequen-tes Of thO nine 'M-,1'A1;(A6 ire i1sted It. a t,,it)Ae on
rhet;o ny~rocarboris o,3:-o .3repared by ro,i,~tiut, -7A' lithilal~ alicyls and
vinylalicylacetylones . 'he 6pocti-i werb recorda," by inoqns of an

li-11 -ir~jd e,7trIA of' Art~ir. ~:,stitu-,:ed .-Ilene
C - -~ ! -- - . . I
M-14 ii-,ectm,,notry4atar using tir, rism up tc 1800 cm-,L tind ar,
Lii :)ririr, for hi,,,her wu7a nuribars The stimples wore in th5 firr
la:,-jrG C.06 W, The wost _-r,,zirtict-jrI6ti- aad latanse aands
obB,jrved In tKa s~,ectr-A of' Ali tnese war-3 tne wnd-~
to the ttllan,3 , r~,,. it zi v j5 to a~ni-31aaar da"CrL ti -LL--:
vl rations of' trio cm-1. Otner
tire 1riefly dis -ussed. fn,.,re a-rs :i 4ure. I mit,jle tLod i re!v-,3,, -e-6
.-;hic,, in ;nlli,3t, I
7 f"ZD Fe brut-, r,f 23 1 Q )9 -

2 o 67159
-LUTHOR6 F5trov. In-
?I ME On tho Aydroe'arl L3c'IIJ'
A A IOD I G&L Optiful 1 ~e.&tl -,-t1 'I ...... .
,4," TRA,~ T Hyd ro r L oi., -. i t )~J lins) in 1 0 gy ~-,in~.q
Itolp !,of- '1 .31 i' , k1 0'."
ax[)oct ii"t, 13:1~ A' r T
tr:- A
L U ~j i t 4
'DOctri _19rtali, tf)l''Wil 4 Pjt,1,3'j-
formula R 11; - ( H-
b. ;.',e,in6 c~ .n i ~~el tr,-Y.,,iter vrith LiF and "Ift 1 - r CT.'~
thoul a re -ih owl! i z. a f I Pi r 5 (~r~ or,3 i , n r
0o ti v (), y A t
3 t i n n o - i .~,jr Ii n, q r tn 3
e r y
the to _ri, n rl k or
foqn'i & L~'Irvl h - L r ti ti r1 b t. It I At
4r oori 1'~" 'tt. C
O'n, p t Th'3 I a tt -l-lue,! tr the I mn n

H R 3 P
r, f rot r-o,l 3 p,~ St r,i t*-ire cif t no,-
It t 7 It rI, r, 11 W i t h H it D-j
ER D: A L: A k j 3 3 S R S t., r i y z i c sc 3.,
V I N r 1 C , - I n SSR
A T RA C '~~p rs -ai ;i' r-Fladj prp-1f-uqly that i;-' -I., r
reac t easi N 4 t a g o- r. 1l; rival ives in t e ~rLsc~r.r-
Ti-, Zr~-, F- ir-3 :t~-r ml-tal chlorides. Thi!i
ai. J 1 , 4 ~ r_ cl ; ~-, ' .3 , I h I- s t ru c t ; r a. d E! t "_ rrr. , n it t 41 c- r. C f x
wit', certain 1~ ff: c '-i ' t,' e 9. For the stru ct'_;ra_- do-~*.,~r::.i :.;i
t h e 3 -- t me r c, t ne ;,A ' h.-rs usei infrared s ~ e c t r a
I e t e r m j n P J t :,f the bands f valenct~ I
r, f 9 h,-- f t 1 ~ 1. a, r!- rresponiing deformation ::3,..
n i t h: r, t ~. e rot ng~ 6C0 - 1 C,00 cm- a n I e v a t~ e
Lands ~=C-H, ')0'0 the harm~r,;.c r.
61oc cm J. If, a S e *.w 0 p r-- 'i'1 9 -, f 7'.
C8H 13 C1 nc,:-e A' tir.,~A ~.n telomerizat4rn Df div".!., . &_ .~
Car I ~ ts hylr:~)cnl ~r4 d,s, t'~,e .,-,tre :)f Whig:-. -:- ;' J1 e 4~-

f
r,7

-~V, A. ~7
F; f r! 3 Vir,
A L: e er,
R A L -?s t' A k i n au k 3 3 SR S r i f i z 4 c r. S k a a
R C ~-t al 7~ ~ m' r r) f t- a r I e, ~ a i~ L :_3 EL ~i
reactions to vi.._,: acet-. -'ene
carbor.s ir, nucleop~dliC, and rai-J--~il
7?,~ adjil~ n c.lmpounds were
find ullene-c,mp(--~nds. Tlhe~ all! had very characteristic
the infrared :3~pctr-um: 1600 cm-1 , 2100 Dr 2 20C c m- 1 ..l. :
cm-'. For 'r~wf le~erm.':~ation of str-.icturL, at-ove t
ence- an J ~ ef t i or. ., :o ra t ions of t I-,e CH F-r - w
Tnt- cid ii t i on r ~-& -i t i or. o f h r -)min. t o non-sut 5 t i , ~; t e ~ V I.-,, I
a,~e t~- lene f urr. i siie cJ t wo aJ d i t i on c ompound s : one 1 Lw-
ll'~' 8 find 1621 cm-l and 928 and 969 cm- and one
Ix- 'utter CD.;.
6C, c r, The slr,.; --ires of the
afi --inr CllBr-C-Rr-CH-CH- and CHBr-C-CH-CH Br,
i-i t so sm,, ~1!, 1
was conf.rme che-n:cul mi-thods. A,

S07, 48 - 2 - 'C-, 1. * ,
7- In f 3--,-c' :-,i lin 1 t :-H S r re he A 114 1 t i cr~ Cc= ;n
cet.~ .'-ne r- -ns
f
f t t ~: a r d T~ 1 t' e i s --) m e r 00 c m
-.H`C-llHBr-CH,Br. Tlhe aditior. of
e
p-~ive R-C-zC-C!Dr-CH 2 Br and R-ClOr-CH-C~CH3--.
t n- f ow i rg .9 om L f -~; r t r '~.- r r e s u 1 ' . s o b t a i r, e d t y j a r I i ~ r : -. -., - -
e-ati ~ns 'R~if g 4, 6, 7,8) are briefly discussed. Str-,lc ta r,~ .9 -1-
a at tnc,4 r ends may be determined .v' ~a
g rou p I
b e c au s P, A I t h4
re -a~24 11; ty t,~ me~tns of Infrared spectra,
range of CH-valence vi"rations of this group \~5100 ~m- ~o
.ther frel,iencies tire found; an identification of allt2ne~ - -m-
pour.~!s according to t-e frequency 1960 cm-' is, hoilever,
difficult. Detpmination of 1,5-diene compounIs fic,,or~;,,q;
tne freju,--nci~~s in the range of 1640-1720 cm-1 13 als: iif-
f-:c,-lt h~ca.~se in t*,',-q range there lie also the c-)rr.~
c,-,,-racte,--q-c -.f some acetylene compounds. Tne:-t ar=
1C sov'i~ft
Card 2,1"

.P

.- . I . I .I
t
T.-I - t i ... ~ I. Addition

ga
Addition 0
In
B. Kil, ian.

r i
addition 0
.
osite I'.

f h

F-S

nv- i :7-j t i r,.; i ri
v :v i i Addition of'
7, C

the
c'.ra
ri -.-i,;
r r,) '-i-
t'jo 13, -it, ri
'j r, .9 r.

-,o t ri i n
,-v, tti- nec ~ r,,i c
ro - r-, rl nir-
7, r i i t 1 on C
,,I t ., " t t i I I 'It I
in' --i L - n n
r! r 9 t 1 -4 7
rl
t n

et)

-a r : I