SCIENTIFIC ABSTRACT PETROV, A.A. - PETROV, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001240410010-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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XXVI Synthesis and prop.r
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PlIrROV, A. A.
PA 1' 'T 7'
TIM/Chemlstry - 11neetmrated aampowde Kar 1947
Chomiatry - Buty-none
"Investigation In the Field of Conjuente Syutemn:
XXVIII, DIene Syntheses With Participation of
Butynone," A. A. Petrov, 5 pp
"Zhur Obshcb aim" Vol XVII, No 3
Study of the condensation of butyn-l-one-3 with
liene hydrocarbona-divinyl.2,3-dimethylbutadiene-1,3
and hexadiene-2,4.
15TT6

'USSR/Chemistry - rtboxy Group Mar 1947
Chemistry - MethOxy gyoup
"Investigation In the Field of Conjugate Systems:
)CXIX, The Condensation of Alcoxyprenes With
Methyl Vinyleetone," A. A. Petrov, 3 pp
"Zhur Obahch KhIm" Vol KVII, No 3 - ~-NO
Study of the condensation of the methoxy and
ethoxyprenes with the subject compound.
15T82

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.00
of d1ortism CiI,4UR)CIf CIICIWR in the tlllui~tkldl Of fa~ilitAt" looli tzt~ n( I I At 2 (M - Mot Of I ho, -*- r
IM from 1.4 -dih:do-2-bu tents by sk. alkafin 6 aluibut - 'd ciltu.cl 11 Icl Of Cil C(XjII .-I CIl,(_I C1 h)CI - Igoe
a able to tho, mobility of the hAJugrn al~ia and oww (d
clcli, C11.61 C119-
CIf CII CJ1
CI
tin (061
i
i C11 cli C(1011 ( 6) 1 n rnoltrast. PhC I I C I I C I I I, I
.
,
.
,
m
za
ell alvonm to-Mam ,1 -4 the doulAt bond, an IIXI -phl, 411 IICI In ft., 4 Ill.- I phor.ri 1.3 tmijo
k
'
'
-
t
1
1 ,00

aplast thor stabAlity of Cl fit I,J dihalo-2-butence owing s,
If (
11 t. 1
(
MAI L
. i
Air-. I
..00
to tbor vicinal effmt: this tnowhaubm for walls to the rem- ClfCI.Cli Of I;h opi-ans 11 1 2 AM lo~ Lil-
It.
10
tiono of 1.4-dielthim-24mitpne. I.4.d1tWOM-2-hUICIIr._ Alfll thAt tit X at 2
I
and with Air alkalies. *I,01dbl
v
V I a N 0 to a 0 5 As a
~
-1*
U 000 pait oil sit as man it is
a
!

ass
let,
d
4-A"
or
at le. Ills""
C
9C amp
I -
a

11
A. A. rtqsav and N. P %UP- (UW ult. Avi."
r
If. I..
StOn I -%I . w=ed wait arod bi Iti;iini4 To
il W
100947)(&a
["a.). J. ces. CA'a (U.S.S.R.) I sigreeseem with daft of x1lebasallul KOH pwm
00 A Russion).-Butadient was chlorinated under Condition. CH.:CHCH-CHa hoso the 1.4-dichlovid. "4 elsolo-
a, er pvviottsly (C.A. 40. 6KW) Disin. of the km-
*
0 Prew from this 424kMirWit. However. the a"bon of
OH
k
1.1303. or 1.415110) gave
0 1 hit (b. d:
V;i f
It
i
IN = a
. K
as the dicklorldest was failed to be different from
that
ivess b
Kleb
AW
tho 1
d
hl
id
i
2 'so
ract
on) pure
EVI
t the
o0 -
:
an
ic
as
ves
y
.
e g
g
-
00 kownew, wbkb An - that the low-busling fraction co"'
th
ci
l
b
A d
hl chkWaVreft but the 1.4-dkkkwW* gives almost exclu.
Givell
i Use 3-194
tither ad
%h
t
l
r
l
th
w 06
utanit levi
ent
e
oro
ic
taivoW appreciable ants. 4
y .
e
rea
yco
e Until rce
t
y
y
;
g
i
i
b
M
00
i,
00 2,34alsom) d the butallime used was the unpurifird 9Uv s o
t&
ned with
eOH-KOH
; sinul" reactions take
butedictir. lore. perudobutyleine. as rd by
?
= Place whea (BrCHgCH:)0 or BrCH.CH.C34rCH*Br are '00
14b) The
...JKM'kVC-A 42.
06 Kkbaadg . need. To 30 j. KOH in 127 cc~ MeOll heated on a ateam
00
09 1 anst. at t1se aid. product tend@ to rise with increased bath well added JID g (achch.), and the Mist Was fv-
.=Walty ad but"ene to form low polymers Disin.
go z
l
d
f duated 2 his. to give 13.3 # 1140CHoCif )*. bw U-"'.
d2l 0
41M
4M
a
j thi
i
2D
V 1
CH0
i
a -00
raction.
ori
es gave a
be bigli-boiling fraction *I the ch
w*
ossible to Imitate the filed-
t or
m
hi
h
f
0
~: .
.
. *
g.
n
cc.
. w
;
s
th
in "-?*
at In 5 Ga. CHC36 save 77% (MOOCH
CUBF4 I,**
-
c
a
a
rom w
11
p
'
44
73-4'
but this isolation tended to be snort
ra
M
ll .
,
Was 941011), his 106'. flooduly them were Pend ;
o
i
e, a.
t
,
04 difficult as the degrele of chlorination was increased. The .
(FJ0C11,01:),, b. 73-2.5'. df.- 0.9716. o'l,* 1.42M. and

lee
00 3110-300 fewtine coata3as tea Cl th&n theoriucally rt- (FJ0CH.CHBr).. tn~ 2&-30'. th. 11915-2t)b' tciC)I,-
qWried Ne, the tetrachloride and consists of the tietrachlo- ,CH.), (10 g ) in 15 cc CIICI, mth 4 5 cc. fir in 5
00 '1 lidit WOMM &W P01701"Ite of but"cor The fGtlOmug
a
WAs wei obtaised in the study of chlorination undo CHClopvc 98", in W
I -
Vi
100 25 (from FtOlt I To 1 7
hi
irob
t
di
I
00
vadow om"does: 340 4 butediew to 1000 cc CHCla c
t
rne in
u
a
g
cc. MR was added .30 is Ilit oindc and 25 g iodine in ~o o
ow 112 g. a gave 36% dichlorldto (30 6 1,24somer and
Cl to 1ENJO
d 210
t
t
di
660
b
9 Mail
s1
Jons with coollins and shaking. dilo of The
:::rt
mi
an
a
g.
e
g.
48 g. 1.44now); ,t
a Mi t with water gave 61T. 1CHC11(0Fj,(11
.
or. CHIC16 flave 2D% tficklasidesi (40 s. 1.2- and 35 j. 1.4-
10000
CHC1
Cl i
i
d 312 CMCl. b. W"', d:* I Mid, or
1,5319. this ~ it; C
c~
n
ew an
g.
.
istioners). 6W4. bosted
2- wid 61 9- 1,4400own);
ave 24% likkkwides (34 It. 1
I relluxed I hr With emrms sk- KO and gave 311, - I
11
a-
- I it.
h 101 5-2 5'
d:* o 45W
ft "A
setl
ieve
i)
x
.
g
0
eithe
ve
t
SW
Cl i
1 ,
.
,
.
,
y
y
t
?
s.
cc. pe
n
r ga
10 g.
300 g. butediew wad
'0..,
44soesen). To
2- and 23 g
1
klorldo (10 1
33% di I h
o 6
) brom,"AtC,l -ith 6 9 -Glam% fir willa roKsling.
c(i
ll
d g
ili
h 5
Z
h
hi
f
b
a
.
,
,
c
~
CHCh was added
a In 50 cc
CHCHCkH
V 40
CH owe
r
o
o
ng wit
u s
illings, gAvt
t
y
g
(4i
lb
I IV
f
b
d V* 0
.
o:
s
g.
~
sit Is cooodg 10 cc. at in Is cc. CIIC4; after rasolie in
) to prove the sinicturv
ti
trop
eny
y
oftliviododefiv hitiminationol I -ehlorotmi4diene gives a
with M '". I.. 'bere Was obtalsed 72% of a
* product b. 113-1,15'. d.#- 1 .9616. **b* 1 M76, which taurarr
liquid bw 130~2
j 19" on standing to a lacritnalory product bw 0 6-900. d:*
m
8 tell - 816-3
AM, gV $,6W. gad a wild isoilow, in 1.9M, or 1.57M. evidently an isomeritation of the 1,2- o0

T
ze- dibra ctilde into tbt 1,4-isomer tak" place. G M K

"
1, w r
-

400
I
1 jil
AA 1 9 '" 0 -
- I a13 1 W
r
0 ale 0 0 0 0 0 0 0 0 0 0 0 0 0
e

*04 F *11
I I r .-U4 Via ton
U
11 -1-1 -A-A I -IL -L a It r G a
'IL -L--L-Aok Of IX 0
L

Dl*uo ey"Ithelve with bale diesft COWOMA'6"
of menahmowbutatAllileve wUh
404 kettmee A A Ilvi-, .,,.I N
in'llulfit-ill I'l't - / ,,a ( iw.
0o i-Dr.. 114, Ill.. If .........
00 -1 1 a pyr"GAI"I. .."1
led wir IN his at if,', 1111''Jawt OA a rIjIA.Iv
n
.
0 1, 1, 1 111, h I- M. K it
0o 1A., A MINI., III, 1
4* ~Iluul aq Moll 1 2 1
o ,
Ii
'0"
frutu aq
d.-
oo 1,
(M
001)
j
..
oo .. I ...... 1.
..
00 4'..l ..Ih
a IhI, -- I[,,[ I......
00 .1,
N--H
M. k Ilk I I I
. . I 1.~A 1. 1,.1
VI- ..I"

115 1 I.W
Y, .1:* 1 1-'1l-

,
seat** *60
e
o*o0oqooo~:::
P ::0
*
a I- III u k a b 0 Ice
X4 k A a I a A L I _A

-00
k 11 -60
-00
-00

-00
N.. It III lea,
1 1.- 1.... . 1, -1 1, , d - 0 0
'1".4 J A i lit it 00
MOM.. Ill III.
1-r. -4 , -00
.00
-A S 4
It
ZOO
__ I ,. ,,. I.
It -A %II-k -K loo
PhAII, 111 .0
I..I, to 61
00,

"00
01 1 LMIP-4 AM- !100
Oro 0
loo
u Cs LIP it a a
w Is (I a
00 00 0 * 0 0 0 0 0 0 0 0" 0" no 0" W~ o 0 0 0 19 0 0 0 0 0 0 0 0 0 0 00 00
a GIs a 0 0 0 0 0 0 * 0 0 0 0 0 0 a 0 0 Ole 0 0 Q 0 0 a 0 0 0 0 0 0 0 0 * 0 * :,

go a
00
ff?'SMOUT, 1. 1 a oil u All to 0 b
1 "1- 1 n, L r7-
1111
A. A
tJMif1==I4w, ln%lr
R 1 194 7 111.
In 111.v mepli briat"I IN hf.. :1 HIP Alg_
.- 1 - -1-4019-0 1 (1). 14. U4 It', -t-tiallik.4
flank with pyrmlknw during the r4anden~t1ca" is ta-Mnia,
'aamilm cWkirlistallun (cw 12 hirl. at 10" gives fklr~ 1. t~,
1 Va 'I d" 1 (KI23 ' AV 1 48114 , I I a ~ .,,.1
41 11. CIICN 1.,,d 14 ht- at 10' It,av, A
A
IS." h
I. go-
14.-.!, arb", ivr. liar ....
h.,.,-,. "a' 0101 14111tine4 Ilk IMI" -fair And I-
;1'a, Atli, 16). that, nitrile (to 1-1 -lov- Ilk I
/. ,. a-- ..1-
palp. Till all. I a,-- 3' 1 . j S , 1 1. *.
cc 11.4). and 15 cc Haluff budad 1. - I,,, I- ha~ -.1
after coccu., ~Jdililc-jaliora. And F.4pul (Irving I 's f ,
In &I cc 910111, ttreated with - I N,,. Ill. 1,1j Ith
Mi m 11,A) slid .11 It U1,A
go'. M."; I~ "alb ~~
jil" all, 11 W%N4, mi.' I IVIJ. fril"oko, A 11 J~,,
III M%
The Lattrv 0 aa ii i in III *.hV, II.So. tairtatral-11 with a
equiv &mi at NAOU V*111~1 an Ht.0-invill rr,m, 4 MUM.
bly, irell- aolut. whi, h Rpi-a-4 to Iaa- ~ p4a,oar, of th,
resulting Mi, omo*,. - N,. liar Ir- krt,, mine
Lf AS 0 do 0 61 A,
6111,
-06
so
;00
:00
-00
00
4
i
WI;
-d-I cog 1. soh" I,k I., A -it 00
61.411. J,liv a. %1 '00
A A a A L
old. 111visis".
AV 00 As
u
0 0
i a 0 fivai Apt' I'll-1 -5 1 v '71 an I a 0 am 0 A I as IN it a
" 0 , KW a 1 S4
Is .. -0 0 0. 0 06 go 00 00
0
0 0 0 0 0 9 * 0 0 0 0 * 0 0
600090 0000 go 0 000-000

0*009 goo 000 gee 0 0 0
eal I I , .
I & . L - ~ .
00 41,
go v6M, ~tgs am?-16111.1 1
00
eeeeqooeo*q*ooO
" " - " I - - - - - - - -
, . , . , . . OCO
-00
-00
go
14 T CL
00 .20
j 7 3,~
00 Z . . 1, 1 % -
-w
00 gj
-00
-00
'00
zoo
coo
-00
-00
Zx .00
WOO
U's E
lop'#
Woo
t goo
49 -in 11 'A
0 0 0 0" a 0 0 0 0 0 0
0_00,0 0 0 0_6 9 0 0 00 go 0 00 0
0 o 0 0 0 0 o 0 0 0 0 0 0 o o 0

A A.
VM/Chml4tz7 - AorooltrIle Nor 19%8
Ch4sletry - Condemstlom
"Condweation of Acronitrils With Piperylene and
Isoprene," A. A. Petrov, A. F. Sapozhnikovs, Chm
IAb, Leningrad Inst Avn XquIpment Constr, 6 pp
"Zhur Obshch Xhim" Vol XVIII (LM), No 3
w,4%.4-1
Eltrile nothyloyclobazenecarban obtkined as a result
of this condensation. Corresponding aminme. 2-
notbri-delt4O-tetraby4robanzylamine and mixtures of
4- and 3-nothyl-delta--tetrabTA-robanzylaalnes wdre
obtained by reducing produots of condensation. Show
that electron theory can be applied to order of can-
dentlon on looprons and p1psry1dus vIth acro-
altrile. Submitted 4 Jkr 1947.
IM .169TI6

USSR/Chemistry - Ethyl Alcohol, Apr 48
Decomposition of
Chemistry - Distillation
"PIroblem of the Nature of the Amylene-Piparylane
F,taction of the Condenaata Formed as a Result of
the Catalytic Decomposition of Ethyl Alcohols,"
A. A. Petrov, A. F. Sapozhnikova, Chem Lab,
Lenin4p-ad Inst of Aviation InstrBldg, 51 pp
"Zhur Obshch Xhim" vol XVIII (Txrr), No 4
1;t ~ .1-
Shove that the piperylena In the - wh~e-plparylene
fraction of the condensate obtained by the
d&zomposition of ethyl alcohol by S. V. Lebe4ev's
method does not fully react vith acronitrite and
Aw 8149T37
USSR/Chemistry - Ethyl Alcohol, Apr 48
Decomposition of (Contd)
consists of a mixture of cle- and trane- forms,
latter predominating. Fetablishes presence of
isoprene in initial fractions. Submitted 4 M&T
1.947,

UM/Chadstry Plperylsne Jun
Chemistry Acrolain
*ftoblem of the Structure of the Pro&ucte of Con-
d~W&tlOn of PIPerrylens With Acrolain," A. A.
Pstrov, Chem TAb, laningrad Dist of Avn Thetr
Bldgp 314 PP
'Zhur Obsboh M:,17g' Vol rM:r (T No 6
Zetablishes that only trans-A pery Ions takes put
In reaction. Shc-vs that oonaensation product Is
mainly or exclasit-aly 2-.wtnyl- d -tetrehydroban-
goin aldehyda. CaAparas amract-,we by oxidation
to correspcmdlng acild &nA prepares some hydrazins
derlvatlres. Submittal 10 Jun 1947.
IM 9AMIL

Diens Rydror-arbons Oct 48
Systems, Conjugate
Oftsearch in the Field of Conjugate System ~ XXXV1,9
The Condensation of Diene Hydrocarbons With Methacrylic
-,Acid (1) and gethylmetheLcrYlate (II)," A. A. PetrovIv
, N. P. Sopov, Chem Lab, Leningrad Iwt of Avr. Instr
.Constr. 71 pp
"Zhur Obghch Khim" Vol XVIII, No 10,.q,,-8
Condensation of I &ad II vith 1,3-butadiene, chlorO-
Prene,, 2,3-dimethyl-1.3-butadlene and cyclopentadiene
gave 1-methylcyclohexane-4-carbei~yllc acid, a mixture
Of 1-m--thYl-3- and 1-methyl-)~-cyclohexene-3-carboxy3.ic
48b 2 /50T40
USSR/Chemistry - Diene Hydrocarbons Oct 48
Systems, Conjugate kContdl
acids, l,'4,4-tr:lmethylcyclobexene-3-carboxy2-ic acid
and 2.5-end=ethylenecyclohexene-3-carboxyl-ic acid
Lud their methyl esters, resp-_ctl-ely Submitted
22 Oct 47
"up - i.,)
.T40

c '0,
T'he order of addition of allivi hTpohmilles V, bUtaidleor
k A ", t- I, -,, . : - % , - , ~, - I ,,, ( ., J~
"", ",w I ~ " I - - -P 19 , 1-111,111,
I .at ~, I I " I -,.I I I ,

T%o wroloot of addifloxis W alkyl hypo"it" to butudisone
A. A. Aletrov /hut Obihooliorl About, ij Gen Chtm 1 19,
I(M-42111949). Addis of alkyl hirpoctilswite to tPutaillent
(1) Vickie predominantly the 1.2-C1 ethers. along with the
1.4410mers; the Of and Mine analogs Vicki only the 1.2.
womers between - 12* AM 46* Generally, an irwreass,
of otiod"I cost reistere the tmal Vicki and the relative pro-
portion of the 1,4-nomei, inerrAw of temp inereaw-s both.
which may be in view of she higher thermal
stability of to. I . isonsers At - 10' (jLnd its
victnity)
PbSOoNCI, react, with I in RiOlf in 2 s", the lot ac -
tion is (be (Ormatooto of with I having an active Cl
got I he yiel a corn Pd
j at this SCA d Of Ci ethers is very low). and the
2nd step to the acOm of this substance on the H10111.1 -
soln- yieklins the Cl ethers I'mmoir Ph.401,1NII, Always
forms. apparently by the acts"n of the dichloraimide to
2mots. HtOff AM 2mols.l.areaction which is Losten2fi"rho
bligber Iem AAdn of M g Ph.4(hXCII over 4 to
68 mi. I (OT64 ii-mole) in 100 mi McOlf at - Won r-sist
with fitirring. followed tx~ t wring 2 hro _ filiation, and ithr -
ring the filtrate at -8 with an raivisof powd Sa#S(N,
flown steam distis, . gave 28 # (4A 5~) mixed Cl ethm, to
13041111'. which on redisoin wa% oepd tntcol!3-~ of-~chliw~-2-
owillo.-y-i4vions, (11). bra d" LOD41: 0?
I.C1,42, %rul 17'~ J~Jlolw--4~14oz -J-6afew, (111) b,.
161,1*. 11,' 1 W.46. xV 1 45M. floiring It with'sic. Koff
gave MWA t 4 1) 5 to V 1.44711, while 11 broom I.I
trave
box 124.5-5 A * do' I MR2 I 42m; III britted 0.6 hr
with PtO111 ,kt)ll v~ ot)CII.CIUCHCUO)MO. low
48 -ail', nip I CM Fwhwh on lar-smistatkoa glove Mot 2,11.
sli-fir torwoput . b.. Pool'. in AV (fruits RtOlll)j. and Me-
OC11FICIFIF-ClICHON, Ne Q 3'. which on bromination
gave the IJ-dt-ft, toonjid.. h.. 114 13'. The 1,414-11,00
CUMpd. was Also OtItAlneof from 21 4 g ( ClIC111,1101
and 2) 1 KOII In 41) ml Woolf As reflux; the product
Clicl, With its, vhe,.W~ 41 4 1 of is,m OW ,*f loose 7V
i, vAuj~sm, t~ i in .5 * eq,
1 U1. RU I J%110. APP4"nfly .. 4 mill J fee-.
wornrrs Rissisir 44 017 ml S4-ts.1% 1 Intel 1101 MI MCOlt
I= stWrtng .1 it, 2 wnh -~r,enl -kw .1-to of W is
PbSONCI, (~., 5 hr~ wid sitrying I hr. A.e after in
.bove puriflorown procedsore 35'~ -ox-t other. (7~~
U and ", III#. ooners"Itaii omtsimoriatird with I docklo-
kl~_ Adds. of lbir IICOfol) 11 trial I in 23m) MeOll.
followed by 25 S. posed. kidins, sit - to' to - 15'. Gkors-
tics, And Us gave 12-6 g.
Lw tw al" j 54 4s. J:* I rd-N. th, I I t-mer -as not
found ~kmjlfannjuz P&AURC 14 (M) mt I WW Arkin. of
117 of o-tinc to a oa, of 63 o- IlgO in 100 mi.
'Unison fhoo
NIC(Al at :15 Ve I of Lame COMPd. WO wine
higher-huding fractions contarnistatted with butaduraq do.
todki". Heating the kido ether with sk I(Olfgavrlf,l"~
rosethosyprene Adfin of W I PhSOsSCII at -~* to
- 12' with iewring over 3 his. to 133 sell. in M Mj_
HiOll. stirring 3 hr#.. sold Laraison jove 17 1 butadireur-
Ph-S"NO, adsJo. proluct. in 59 , while the fillorritor
yickied 34 g, mixed chloracthazybutecurs, the r"Wisso
g(ter die distri of which gave M I PbSOjNI1o ~ftom bat
110i And a rconsuleratile amt. at PbSO.NCIvioutiodleze
witin products which duf not have actlint Cl; IN thb
-sc (he halo r(hef ivirs" ratio was 961% 1.2- and 51",
1. 4 -tourner, rhe-e were OC11,0110M)CII-CIff, bra
1:16465', J:- 097M. oPV I 4MD~ and the
solo 62-4- d- to 1.0112 mijO 1 Otto, the small &M1 of t.4-
tountirr oitalned' retfootred repeated time "rominatioso
of the 1.2-iscomer gave
buolaote, b" 129', dl.' I M32. RV 1 3142. toonfing thor 1.4-
ivionef with rxer,,% ale KIM gave FOC11,01 CUCHo-
OFJ. too 72 -2 3 *. a 0 1 42M. while bratting with 35"o,
Kf)II -.%fc4)11 gave z)(7111CH C110100pi. but 42 -2 IS * ,
And the bromination of 1.4-isomon owe 11111"?, 14"ov..) J.

h. I:11) V. d-.' I 7W. xV 1.5174.
Repetition of the stirrer run willin Stbe mants. of ftwe is,
.uh -mphrt~mi ,I the reaction in 2 bri 'rilded We- at
the arrive Cl adduct ad PliSfINNICIl-butadwrit and 70J of
'V
the nuted CI C1.1117". AS Well A- S g Ph.Wtt\'Ifl rtCVVtn4j
d from the residue ftisage of 67 g I into 145 ml. MOH
~t 15 40' with *low addn~ of 112 .5 c Ph9liNCIf. (allowed
I,v da,un of mtnt of the FtOll and ttr~u distn . gave a solo.
Irm of active Cl And the r"idue yielded 7-5 g. PbSIDaNII,
_,ndZIj addit Products. fr- of -it,, Cf. -,melt &93&S a.
L71 ethrn. consisting .1 )0)'~ 1.2- and ;!1", 1.4-isomm.
Addri. of 45 5. lert-RuOCI over 5 hr%. with sturring at 12 *
to W) mi I in 3411) mi. PtOll (with the addr; of 0.5 p-
MeCJI~Whlf and illumination with a fig arc in the last
hr . as the reaction sea. vvry Ouggrish) gave 29 q. 133%)
Cl ethers. consisting of KM",
,umae. 1, and 12'; th. 60-70'. V
,I MAIr. mV 1 4&3'_l Addu .( 133 ml I to 31 g. No In WO
-11 Vtollat -.~'.Iollawr-ii,ypa~geoi7ls.Clat -6'
to _7'gavea"n contg.5.2g alkali-bound Na and 42-2
g CI ir. write ftirrn~ the *oln, yielded 16 C. (12%) Cl
ethers. (75c, 1.2- and 2.5",, 1.4-tsomere) Allowing 101
CffC)I.Cll, to stand 24 hr% with 1 8 j. No in 35 ml'
F.1011 gave 4 big 60-6'.
.1-1 0 (MM. mV fI4542. Addn of III) g PlIS(hNOrs over
.,hr. to 4111) mi. I tit 175 mi P1011 at - W'. followed by
treatment with NaINAh and steam dk%to . gave 36 5 g~
PhSO81411, and 43 1.
4w US 411 V. at well ai 0 8 1 be
1.1214'' d" JUX). mV 1 4942. Reprillior; &1 40-6,
gave " a , 'W)';) of the 1.2-lif ether, anti Again UW 1.4-
ivirnri could not be found To 135 ml I in 311) mi. FtOH
.a. added 1.54 9, freAly i,ptd. 1f9(). followed of - 12'
by 234 -bric &IM all- bul-. tlwre -1111
g6r, N %4-4 S', but
T
74'. d:* 1.5M. aV I WO). which with " K011 gave
A)~, ethotyprene, treatment uf the dt%tn re,idue (&(ter
t9tiLatim of the 1.2-w-lo ether) with &lC "fl gave ad
ucts of a wide tioding range. Whk h ort shaking wilrR
11,SO. gavv a test for A,,; r,twtitlon of th,- rrAction with
"fine-UgO at 40-3 * gave the "rise reult I , 63 mi 1. 1 &S
I Buoll. AM &18 PhSA),SC)' at - 111' to - 15 * 14" in 6
hirs. 42 1 g~ (OOf,) .,kiwi of I-PhS0,.NCI,. -mi& active
Cl. and only 6,7 S. fluted Cl ethers (0 V, i, distis pvv
about 7&% 1 -baker. h. 7&S-7 S' d--
O.SW, mV 1.4390, and 24`~ ffude be,05-iool.
d',* 0.93". nV 1.4498. kepettiton at 40-3' gave 17%
mized Cl others (&J% 1.2. and 19"r 1.4-asousers); the
1.2-teocturr diall. wtt!t solid K01i gave limisaryowesse, ba,
S&I., V.4445 , in Id It Is the 1A A
boated Coll in SSOCHIM.
CHMOAke (aiets abitatoold how ( CUCIiJk it sell KOH
in. MwOW, hill 130-112% uV IAM. d3* OAM, orbick ou
hromination in CHO, gave the P.j4#-M, .mod
1,3411A mi? 1 1*21 while twon,m.,im., ,j the
l1reilierstmitArl, give W, (7( 11,01 Mlu ( IIPI,t II,j4,
6. 1&11 4 P. 1-* 1 5713. If 1 .10171

~/Ch=19%7 - z1vinyl im 49.
Obamistry - Alky2hypohalites
*fte Order of Combination of Alky1hypobalites
rr-. V1%h DIvinyl,* A. A. Petrov, laningrad lbst of
Avn Instr Constr, 16 3/4 pp
Outtr obshch xhinO val x3:x, wo 6
M"estigated subject vith regard to type of
Wagon, sagaltude of the alkyl radical, temper-
&two, time consumed in the reaction and motboi
employed. A mixture of 1, 2-and 1, 4-chloroothers,
v1th a considerably greater amunt of -the first,
despite nothod. used, vere alvays obtained vhen
alWlhypooblarites vere used, but, apparently
4w . 64/49T14
MM/Chamistry - Divinyl (Cantd) Jim 49
only the 1, 2-" vao derived in reactions using
the acrresponding ccKpounds of iodine and brosilue
wt -12 to + 450C. Yieltl of the ob1croethers vas
decreased by an increase in the alkyl radical,
amd increased by a tamperature increase.
Reactions of shart duration initially produced'
d1ohlormaide, indicating that, basically,
ta,mation of chloroethers Is a Wo-step process.
Mmitted 26 YAr 48.

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 0 o
0 0 0 o 4 o '& ot
00 0000*0000000*0000 of W44*1W-01 9 0 0 oo goo* oo gee o 06
* at I I
A 1 011 1 1 1 .1 .1 j 0 m a N V a I a l. V L) W It it a 'j
6 A f. IL L L 0 P f AA Be cc m It a a 0 Fe
0e I
As 0
Of 00
00
411116
P,dimotribiabou of bydmg*n in OCUU&S On AJGBLiAO- _
*0 eah"tot catallystsi A. A. Nuns and A V Frost NAW), -00
00 C jk.d V,..k i N S R 63, R51 -2(1%1149) -The qelf~tn
I -I ,, 11), runtol pOwnbly Wror 2-tent 11.1 n-
J
go _. hmJ~A,iuj numnem was jnrt~116,jed At JIM% - trinill
;
410 high etiough to prevc"t polymerizatim and los, enot h In
f the mAin IrActm I toot
i
ld
th
d
00 o
e
crontlin
ritchult
e y
-o.lorx.,tt. 1. I-iS Ili*, was &i ttlio%, the high-lindling
00 Ftswilir (4mislittlio4i 11) 1'.117, The amt of coke depointed
-00
00 z lot the .ulysi i. rmShly prnl.mirtional in the aini Of
-Id birdr,"r1lon. in the ratAirlate, On the at 023- lee
00 Z3 g onke j mod hyd"ll-Artion- rber Aint of the IAIIer
00 *'1 to increaung sp~ velocity, 4, 9 . at (? 2. 0~ 5,
a," I I -hr viltd hydrar"tons we" 38.
' -00

0 j I-
, 3. and I I M*`sOf tilt -tAlVj,,te, Rf GO Of the MtAlyUte

e III,
imp At the Lillie 3 %j.4CI Velocities, at
mm
117
And 125 .
,
.
.
-ul hyd,mastmons W
00 a r 2. And Z2 114.1. 11, - of the C.Ialyc.tv 64. 11111, and list,
. ~p Conequctitly. redwrilinum of if is more inittle,
n olefin with A t"ttary donble bond The trield of
'
.
- -00
hydrocarbons in, rr4~,, with the vni of the catalyst.
aid
$
th". 0t CGIRWIL. ~W* Vtl(Klty U,2. Vol tAtM CAWY11t
~Ipimo t so 0
are I rAw 4, A 14, On-

hi, p-I ... . .. ...
Oli

-
*
1
1
10
41

;
0 0 0 0 0 0 0 0 0 0
~0
0 0 0
9
0 & 0 0 *
*
0 0 0 0 * 0 0 00 0 000 0 0 0 0

PETROV, A. A.
'I, -
Allirptlynn owy3teins, 1. Addition of bromine to v,n ,c,,,qe,,ro
N
!but-i-en-3-yucii. rk A lctr~v and no'
I', -IM-7-7 1~ , 1; t - n I I
N 20, , F. 7 Iji 7
of ;,r _( jl(~I, to I I I, ( I I C (, I I 'It III re-Itn in" 1-am'it '. in of
9-11" tettabrownid,-i (not itain-n-i, -I'l "I if" JI.,_
slilmirwd,-i. vii . CI I fir :it CI I 11, AS ' I I I I I fir ( I it
fS"- IIIIr If ll,llr r I;,-
livAing in JIM with (.illir, 4 Mir ( fir I If (.110.
_1 ht,~i_itahle tn colel KOH-EtOli. btit r,n prol,,nL!~l ho~ating
sij;"it, t M:t or fir.
r _ .1 CH
),o P,v addition ~)f TIr (160 If I in Clfo 1, to ( 11, 1 If
I IM R ) in Cl IC!, at -- K" in - 12' and rernoval of volatile- m., o-rial
afford mi xed bromides (190 g 90%) separated tiv Iractional
vac (hitillation into three main fractioni (,1) 17 1; R ~ - 1) 1) 4 1
4ti'l 10 min , 1~ - I ')(;-to. u4- 1 5721). W (44 K 1. 1, 1, 74 72 110
mm . off * I 99M. it!.* 1 6000. and the tetralm)mid" (r 1 (42 5 ~ ).
bp IIA-- 117 I's mot . df* 2 5203, "J,.1 1 6277 Vrmtion (a) on
oxichtion with KNIno, in aq. CONfe, gjvt-% If,( ()4 and 1 11,. rind
llttl~ rirg li.tlr,qrnat~l tnatemil .011 %FNo, I, aq NII, I toll
frartimi (a) (S ? K I gi-i (Allir'Clir -C C.Ag 1 15 if r-renp-iding
to I I % A aretv1-ur material in ra,j and ono-h.inw-di
CI[Ilr*C.Dr -(-.I[ 'C11, Will) nim , .11 * I Oit,; III.- 1 31012
Frnci
K011 EtOll giveti Klir and
1 pis-, IIII't -11, 1-0mv F. 111 1 '11
ItI .... .. .......
con-11111til 1: ra .m I I it 1 4 11 1 11,1'' 11
-1d""I hV - , - :n
4S at 1011
t
--thb, thn;:215 111ii ,Ildi ,)it I -w.wi-v 4 7' ,1 1,
mat_.'d. and - 0 11 2W., KI )l I I it )I I , -I- I I --,- "I ~t- I V
6 ('1 t t I 1 5 tnin ]\fir 0s I and
Pill If A it (;I;'. I p 52 SJ 17 n, in
1 (
1-51 111.

3f C, T'
U ll" . :VJ "' " (j r 5
"In f I u,--: -e !.~Od Illa, ~J" ') ti". i ~.' ~~;; '~ r-1 9 -,-1. " " ":-" C. - 1~:R. , a-"? "
Yi .
A. A. letrov
"Lx)r Ak Na;k _>_W'
7.t:
:3c A'j t i t
I'a
4-ve s r-: H
Ly Aca.1 j. iavll~:i.
IA lt,5T88

1 44

lwmtftc trandurfamouns W I I I trainothOtWoprupen
A ~ hif '1-4, 11
an"
4 %4,( k. Ii I Al,
hvi.

mmullan"Us dimarlialwo .1 a.... hfd,~40-1. end
b.4 N. k
Ow tljerr,,,l W4-.enzjiwn .1 t.11, -,)I, I ith
twrylene. Pw,pr-,. %I,t It 01,. ItIl, L :.1 - ,
h-4-- -1 Ik-,i-- I-. ho ,
th, ji
ni I
H-f"., 142 -Ih t
mf'. I in I h, J." -o~
14"", 0" im",
I, IAI COV ~1-4- Y,, h f 1 -11.
12 _h
"It q.
h,, 1, ht' 1-nellm, .,,.f
~ht-ng in in j ul it nirt urr Ur grly J 1 .7 4~4 Y? #~ a v,
i% 14"Illuiv 1 -1 h hlw~p-vi, wl,W ~ -1,
I 4fk IN - 1- h Ii..
.11, Cl Al"n, I Ili, duld, -W I, it .1, KI-11 fi'l,
Pd CI -.1 PIN, I,
- -ih I- I I,
471., .1th I If,(*// I /I I'vo
417_~-, .0, , ~ I "t'-d-, I - .I *. ff:, 'I.' I
1 49 -. .1 -0, -14--ft-, 7' 1:.
1 4 7W., ith th- h. N4 W I:- -, i& Viet
f. Nf

C"q
It A. A Petrov sad N P Sopov Drmb'ody
M.- S.S.M. ", Oil 13(IW) Mvtnyl and its
hornalop vr~re Condensed .1th MeCCW Of nd the re-
sulting ketones treated with l6frMst to lurn, ib* ryck,
dienylifirmthykarbisiols. (km -- obWned in pure state
b. 97.Z, 8.0)*~
04M. %V 1,&)12. Dehydratiam of the .", ffuen
divittyl imagirtuc, of dUienwopertyl by slow di
with R!OJI)v p- alk-yrfic hydrovisibotts,"".0hrZilitz
with 4 crystal of Iodine 1(mvir monuitic hydrKwbmts. Out
the latter were obtaimA from the &"~ ditrivni from pilm"T
mir off ditinnorvilri. Thus were w1cured
,ya-Awxmidtemse (1) b 172 d' d- OAX)m . aV I S."
. 6. 4M
its #-Me (0), b 19--a- t--,O:AW13. OV 1.8166, and 4.3-
&MO ~~ 97.3-14)A-, d:- 0.11919. *V I.SIM; ~
NPA. ti~ 151-3* ' 11* 0 M") OV I 4W, CJI.Mf.
11 174 -6*, 11:1 () F~42, "'-V I h h 174 9-.
cls. r1.1 OL
JATW. .11 1 ,AM8, ad the h 1117-9,
r) )(74 1, 0? 1 W)4 Th,
t-mettat int. the imp ~pmpylt ..... r-tily (in wi,irm
frig with IICI in lim" th, jor-".1 .0 -XI, gt,.p twmg .
great 1,arflitating Wfor. sonce dthysirstyii 4 urh ~" in
-otably viAls only the ar,in%.tw J~n- (temostalsom of
I gave 4 "Ist kd,4&-.do, in I IS 14 ', wbik If gas, .
in IM' I with 5"r, KWO. xa,s PkA-
only. heated with maku dak)NOW, it gave i alter hydrolysis,
4 tst ad. in I "N * G. %I kiwaj~tmfi

Dwation of the phosphoresence of beasene and its defiv
a P V % A .,.. it, % .. f-, ~ , ,
' ". I, I I " , 4 "'C' 44
h, .1-
%t
Pit 1,
I', M.

.. . . . ..........

USSR/Cheyn' try - Chloroprene, Conju~ption I MaY 51
"Several Peculiarities in the Reactions of Chloro-
prene With Hypohalogen Compounds," A. A. Petrov
'Tok Ak Nauk SSSR" Vol LXXVIII, No 1, pp 63-64~-
New data atter.* to the possibility of addn to
conjugated systems in the 1,4-position. In the case
of chloro-Drene, 1,2-chlorohydrin cannot exist and
hence cAnnot be a source of the 1,4-product. It
bas been established that the predominant place of
attack in reactions of chloroprene with hypohalogen
compds depends on the nature of the halogen. With
217T2
eblorine ccmpds this place is the 1st carbon atam,
whence the reaction is completed at the 4-position.
Thus chloroprene reacts as a conjugated system. In
the case oil bromine and Iodine compds, the reaction
sta:rts at the 4th and ends at the 3d carbon atoms
It follows that there is no conjugation here axLd
that addn proceeds at the more reactive double bond..
21M

PETROV, A. A.
USSR/Chemistry - Hydrocarbons 11 Aug 51
"Preparation and Transformations of Vinyleyclo-
hexedienic Hydrocarbons," A. A. Petrov, N. P.
Sopoy
"Dok Ak Nauk SSSR" Vol LXXIX, No 5, pp 811-813
Synthesized Yinylcyclohexadienes according to
A. A. Petrov, "Zhur Obahch WWI Vol X, 1682,
1940; "Dok Ak Nauk SSSR4 Vol LIII, 531, .1946,
wd describes their properties. Brief heating
vith HC1 isomerizes these compda into aromatic
hydrocarbons.
210r24

PETPnV, A.A.
USSR/Chemi6try - Dlene Syntheses Apr 52
Synthenis anl Properties of Some Isomers, domologues
and Analogu-~s of cc-TerplneoI8 Prepared on the
Basi6 cif 1,3-Djene Hydrocarbons," A. A Petrov,
N. P. Sopiv, Chem Lab of Leningrad Inst of Avn
Instruments
"Zhur Obrhcb Khim" V,)! Ull, Nc. 4, pp 591-602
Describes the syntbesis of secondary and tertiary
hyd-roaromfili( qlcs from 1,3-diene compda and unsatd
aidehydes and ketones. 6,ives the structure and
phya chararteristirs of the rompris obtained.
224T34

A.A. TF`
fj
'7ew mt-7
Zh
1T,
ai- v r I f:,
r1
n 1,~f,,q ri,
Ka
a _i c s
r: T- p ny r h,
t, t:~ ~ 11 All 1(~ wi..
mi-l-, -1mi"ne I a m

"-7. 77 't licrflic i. hilf t r,
''!A 14.11"!w I IrmsWim- 47 S

PATROV, a..&.
Action of chloramides on chloroprona in aqueous and alcohol.c soluticna.
Zhur. Obahchey Xhim. 22,1516-28 '52. % K-LIA " :9)
(CA 47 no.17:8643 153)
1. Leningrad Inst. Aviation Instruments.

A '-AVqMl. matoW&I f22'e.) ftmftd
-84 fifturmarma 287 0 Iq
-Jqwrww' r."Jq 1; f. V--
40; 8811'r-Aftl bn,&Mltco - I Opi). do
C"s &w bcouliVM4 Oedliu~tly in, i cc
do IAW,
~"Abgoudj't* the byp"Item. oil
am to bcomap"as --atgd In hot Et Ch
predombitntly In i'6 1.4lixaltim. TM am". cmilcica
that the
TOM$, tin
W, 150 all. MeOll was added at "*. So g.
it"m dittai. left W g. PhSOlUffs mW some I C,
thd ratio 86/14
*Camtly an adduct of the gwide to used *Ufque (d. ibave r
t'; dtd I te4pave 2 qu I'S *oqjtuwe.' 127,
lscts, 41). bw 70-50
Tceawent'Q I with 10 sk. Koll 1; i
10
02
jj'O~Na
2'g. Z.
bis 724.6% doi: IAW, at$ IAM, ,Omdud; bw 824', Identl
excen BtOH-KOK 0.5 hr. at "Aux rald Fj dAff* the. hie- NO
OU0.4 CHu 6 6844A*~ do 1 X63iV4
nsaW the 14- s4dA, ov
'pteften.-do 1.0601, MV 1.4113. thZedustgAto
l.t9cw
c.),wzs
Vol .2 c. slat-W. b- 93-5 Ld~
UtWOMMICS; MIA MA-
'
smva
BrCHXOiH and S-kh
dust pv*' Cffg., C: C11- 1 (6.8
'
xmd and 80 f. PhSQr
'd
O
d .
Pvt
'
r
e
vs. w lkh vme
~',mnd,n umemus smaH ;*
I
ndxt,
ewer on rodktn' cave : ., b:* M
A~~s!.*'IAM .I -dust
Ive 46 g.
12% do I
aq. F%0
at
'do I

C---7 4 V I/.
WU
:;
&o6W*ntvW.gmtvab=tW%pmA(p
4W-b V-41-do OMIS. xV 1AW. 'Ac1'd"j4m='; IT pi afer OA41, 1.494;!
m.'' o oil LQ-
RF"F IT% "woe a( m"Oval 0
Rer the of the a ei4feethec du 0441 *1*
~'Wic ds(cr# ba OIA-2.50'
d, 01pime was red(Ad.1 bo 73-40, "if 1.4950, and Sol ater.les131-2.50 do 0 QMv,
"Idolt1flec' " ivWe 3,4-addu. product wh1cU was stable 0 'a" 1AOW-14-d*rd% 'He ater., ba 00-1.40, 'R 0;Q717j-
? -;.u a OsC ittatrAtnt - (hMation of M with KMnC.4 Some memi, Xt mos. 1W. #v, do O.M34; OV~ 14470
ene (L. ester Iftv 101- A*o do 9. a 1.
-cleg,6611, To 66 j.,bmmopc
-O&W his oV I I.J
-isal.;McOH, %vae added, as aboov, 40 9, K%O%Nl I the .1.1.
Atea up 16 i' (MONSM.''Aht MOM'- bv'019" 11% die OXMi wig 1;
tmed j%vt 43, S. Alstil able products b
1110064'. Rt #4-64st-sivi 8*W(ir, bis 14 -4U' U0AWS; *18 1.46 ., Hy
d6t". givo 16.5 g. AU:f"4rom
't 1,08 at
AN ".S*,rdsj 1.1613, nf,1.5145, Wbkh heated with't. by ftifticing WMAK roll Pro -,a
t H - 10. gain.: an bath bout 60% following "T41W14S
N4 40-" ,,'if IAO, Ic 144341;
$I CS? 0.6, do 1Z I
1.440; (6,
aboat 2 a. imAe t.4-
g m
-20*. whkh was fict studW beyond
XLIV. Condensation 49 adm d,, 01; 53 IU Me etter 44 Ike kttvi was triated w
with 4(oie droccagbous, A. A Vettov' t" oth"
9 RO', ~stv,11U
M.P... Am. 3W13; d. C.A. 43. 3M- 48~. -vet, 4hg W. the de. .0 it
,dUs:C(Ch6)CO&H- hestel uhh,.Aena~ L 'to YM a
qatutitmation mAdldw
',,!-.~jbydvoftdms In.ampais 16-16 firs. at 1606.g&" altho athiiMe erUm Ali MeMCI fasted, to)*id
rdds of esters of I-mthy14-cyclobezenecorboxylic - acts.
wad The c034 moiday&wIpce -15"m thi-f
144 itilit" ' Dfters of the dicues oet (amcd as by., aM'Aod,-ROWim the Oem-ca-,A'at HAO~ fit 7&-W%
.="iieCH:CHCIVCR. and Cut.-CmecH,.k - '(110
vt
, 3 'Q
2 products in such condensations tM sbut-, #1
,,vidudm oete not oftsfied * Wotber GAM vtW 1.41 Be
&C 'Vem WMQU - the ones dtim~( b~-
t doubt
11MW s methacrylafts: Me.. Ht. Pr., Iso-W dsm'MAM sIV:1.4238t..". .,G
%s,
p
"i dad UWlenes: I-Me. 2-Mai 71
a mm The follosluji
%cm A& cvger~ b" 79% do O.VM;
Ail

PETROV, A. A., SOPOV, N. P.
Studies of Conjugated System. XLIV Condensation of Eaters of Methacrylic Acid with
Diene Hydrocarbons, page 369
Sbornik statey po obahchey khindi (Collection of Papers on General Chemistry),
Vol I, Moscow-Leningrad 1953, pages */62-766
Chemical Laboratory, Leningrad Inst of Aviation Instrw2ent Building

ty
o--- - IV- A-104--
C40 u me
tems. V. Condensallan of
stars of malt.-Ic and fumde aeldg. A.
tit LT.
~&nlu Inst. Aviation V64~
.5bormik Slaw 061kha Kh""I 4. 8w:lhl
5374 '49. Mi-Equirnolar mixts. of the cviellft
tht esters
I mcle each) were brAted In 30 MI. MCI% It,
f06-
ed p Ims 90 11M. to 111,0401. Di-Nle ma"te bm
M-1.5', tin 1,16M, nV 1.4432; di-lit ester, Ns
I)m 116 f-10 7' d. I OW nV I 4H6. 131-Me Inmimto
tn. 101"2'; ~i-it citei, bn&.h-7,i-. tin W412, PU 1.44W)..
anti crude 2,4-hkaditne pvc tht following pithlucts (the
:"Rclds were nbtaintA by hydrolysis of the nttrs). Di-Ald
Zishexenr4,5-dicarboxylalo, diform, 68,579, b. 141.11,2
1.1450, "1,? 1.47J.3; Ime acid, in. 166 ; Irani itomer.
di-!J4 W-r, 8-111% 1h. M-0.6' dtj 1.1272, %13 IAW;
frfto,4d. in. IM-704; Cii-ijolner.di-Eleiter,61%. b. 1.13-4-,
it,* IM-M, nV 1.474; Irani isomer, 69.4%, b.
d'V 1XIO, "u IAW; unkyw(J'Als 011140 (it acid, in. 103-1%
OVER

that of tile halls form, fit, 155.5-d'50'
k4excrg-4.5-dicarbox)~.`afe, cis farm, 6.1-37o, b.
1'.1141, s;V 1.4733; transfoon, 48.0910. It. 14P-0.5'. d.,
1.1010. rtV 1.4704; I= acid. cisform, in. 151.5-2.5*; trars
form. rn. MIA"; apsh)tIrNe of the cis atU, m. 69'. th2t of
trans form, in. 141-121. DI-Ald 3-mohy1cyclahexene-4.5-
dicartioxylak, thfortrij, G4.6 1). 144-S" di'11,1101, "J"
IAWA; 40 Iv, 143,&41, (1;6 IXAV, nit
1.4 cis
-form, 03%, dn I.ftYJ, pjIV tA778; trang forns,
M'; Irrvis form, in. 213-45"; a)i.'jrIriiId. cis form, tit.
that of transfe-,rip), m. 160-7'. Di-Afe 3.64hitelkyhyd-
6sform. 551.270, 1). do
I.OW. %V 1.47A Irani form, 5270, b. 150;5-1.5% d.
I AJ.': n V JAM.' Di-Afe
dicar.?~*xylalv, cis jiftm, 14.51; . in. 70-7[1,51; I.jux
29A%, tit. 24-74, XLVI, Candanution of &Ik(,7pfvnfO
lbid.8(111~ -Cott.
dousation ef cAwd if mahle nr futnaric neld with alkoxy-
prenes wa.5 rtin In sealed [Lbc,3 At 150-60' 1.1-20 tir-.

The tste" Were hydroly?411 to #J1e addl ill 10'YO Nabli.
TIcatinent of Oto esters ivhh 25% jjl$oj pyv till: 1-cyclo-
henurnicilfeitrbovylat". 11mia were o1gultied; DPMO I.
Ciz form, i73". 11
3,
.
I
, x V JAIM' fraystj ivoiner. tn. .67,4", b. 18D.&-70'
M
t
dy fon*. 6
M-8.6", dro 1.1425. io%l 1.4769, traxi form, tl~,j 170-0.5",
1
11134
d
1
h
.
neu9
o
.47U Vi-FJ 1-w1hoxrydv
, nV
1.47DI,
1
g? 1.4072. Di-El I-
ifiv LIM, x
44-dicobor,4xil, cis form, N W-7kh",
Mkhaxeiie
'
I
die 1 5, xV 1.4684, Irlinsforon. h,. ISG*, do I A17M.

traWay"t. M.
A.5" their Silm"'tobutann, al, LA-9, olld
ff. tis fqrri. fill JW-ry-
d. 1.137-1, tritay Ion; b.* I
1.1254
I.Vt~:!I.
.

PETROV, A. A. and SOPCV, N. P.
I
Studis~.q of onju~-ated Systp--rz. XLV.. -'ondensation of AlKoxpr~-nes with
y , Csn rs~i
Fzters of MhLf-ir and Fi-aarir Arid, :V6, A ornik statc- fo -, c ,
khi-nii k",ollection of Papers on general ".-,emistry), Vol :,' , .~oscow-L-eninvrac:,
1953, pages 1UO-Iel~6.
Chenistry L-qboratory, Lenim-rad Inst of A~iation ~,uilding

T, R.
.. ....... .
VOL. 3 NO- 4'
Apr. 1954 P
Chemistry-Organic Dvu.,I~U, 'J'l.'m g .-d I-kMl 11" 1.11
.pph,oson t,, rubl., ,..11,, ,, Y.. I j
i,f,,rv of tagant, , h, m,lo 7111 t. i

77

M4

system
(font.

c#

qq

PETROV, A.A.; BRAVO, Te.S.; DAVIDOVIGH, V.V.; DTjLTKOVA, O.S.; KTANiCTSUYti, Li.V.
Investigations in the field of conjugated s7ste=s. P&r* - . .~
adding alkyl hypohalides to tertiary vinylacetylene alcohois. Zrrar.o~..
khim. 23 no.7:1120-1124 JI '53. (KI-d- t~:7)
1. Laboratoriya organicheskoy khimii Leningradekogo tekhnologicheskoKo
inatituta imeni Lenooveta. (Halides) (Vinylacetylano alcorol )

USSR/Chemistry - Conjugated Systems Sep 53
"Investigations in the Field of Conjugated Systems.
1. Synthesis and PropertieB of Homologs of Bro-
moprene," Ye.A. Leporskaya and A.A. Petrov, Chem
Lab, Leningrad Inst of Aircraft Instrument Building
Zhur Obshch Khim, Vol 23, No 9, pp 1471-1474
A series of homologs of bromoprene was obtained
from homologs of vinyl acetylene by the action of
HBr in the presence of Cu.Br 2' The addition to
these substances of dimethyl maleinate and dim-
etkoi fumarate was investigated.
268T27

APO,
C
4 onjugated sWsana. LU. OrderaM
Sxen g4re 6211 C.' bromides, from which A,A!s i-IWIIN
to. Yin Wid
X40"Ad" 11 A =."Iftraction Of, 21 A C. ArCIAICUBrCt CE4. tha V
(kAMMAM 4MM-1ft2?rffffK%T L
M11MIRs. Mi IWT~73(19W); d__ C.A."t- 451 7.69# de~ 1. M.1 XV IZA70, %$W& *Jih 4 Small arrit, of
f; Icrude k1rabrinniAr. bit 100-40", a. 2-UO, al J,M')
1481* 8181b,-In contrast to vinyliecetylene, the hornoksbus 1-11(epten-3- no P2 C.) pvc 103 g. broinides. wilich Yielded
vinylAylacetylertg uM Br mainly at the ethyleak link.
-
'The structure of the Oroduds was proved by otoriltition, So d* ixWS. nq
1 t-Octen-3-yne SiMMUly give Lugtly BrC112-
'and oxidation to DrC1TsCJJBrMH and the corre%ionding fis, )10 IIBYCI.Cpr, ba 100 all i~
C1111,0COu, ba, 114AV, do 1.5191, 1- J
u,nsttNlittiteditliph:kticackts. The course ofiaddn. of Dr Is; Z-vilak I-Nies- jmve luxely BjCMCJ1BrC1Cr.11-r
Uptalned by disptacemeut of the reactive ccatter under the C11,CIVIM-es, bit da 1,439D, XV 1.6233. The iiLov,:'
Influence of tht rAdleal R In direction of the ethylenk bond, !,brotgIes,!q,1 molol in 00 ml. Ht,O were U110,01 4-6 llfi-!
$ter a
k ( Oars May be Contrif Addis. of fia g. or In th 8% IlDr #ad 10 C. Co.Dr, nrid,,ulter
100 vriL CHO. to 43 t I-peatta4yne In ClIC11 lit -80
er 5 with IW and exta. with etto. Pve the folljivirlog dicai,.
0v
grni, lilj~- "(01 !1, Y removal of the solv"t and TL d1brornides by LaxnerIvAtion (V~dds tj 70-Mfo, of pure Fls'j-'
L11. J,?J~Jjjclwaged matedat gave 120 C. bra-.,
Cs, - bit 60~-j . tauces were obtained): C t: C110r: C) Psfe. No 57-
Tui autta fraction, To bit 79.5-
the Reanall spectrum Unel 0M.-,) at: 1-7 and 2240 7.5'. d2a I.M, al 1.3768; C14:01CYr.-C&M. bit
It",10 bondl, 1012 (caused b Partial Isorafthation of the WIS-70', div 1,7089, nvj IMAO, C1fl:CffCH1:C1TrPr.
y1eiiii, d bron,fd4 Into a %ne. undcr 11juininittion bit dse I.W75, 1,M18, C11g.- CJ103r; Vilrll!el
(C I and. V-
OZonolyjjS PVV DrCII jlnrW the do 1.6310., air 141A C113:01CHrA,
m- 6"* Ws4,AcOHI oxidation with CHOIXIM(s, bo 111-13% do 1.4014, I&Y 1.5310. lit
contrast to the acetylenic dIbmildet, wh eh tave 1101 Woz
'the same Products. The product was s 1.
tCIAXIMCICAfe, bit 79.5-M.6-, 1 odan, these have pleasant adors; they darken untl pc4-
a higher b. fraction, the 13", 2. 10"Iest in sLmv, ii proem that Is blocked by uztvl in.
do
1. IN, rebrMithoke, gl~ &fly, V) S liIM(W. -,Them (fi4romilift practically do not felict ill
WAS An impure ld
C
;?
L

:0901W
let "treated
Ih
In t e c5d with ate, 60 of the Dr cootent SO
after iteam dista. save the (of of bromovirlylacetylen-
in ", -31, do 1-4010,
52j7 yiefrij: Clit i Cor C1 C)ft, bee, 62
aV ui I - C111., C& Ci CFJ, ba 67.. 8.50, do I.Ml. MT
1.51W; C11'!CBJ'Cj Cpp, bo 83-4*. dos 1.2443. WJ IM",
CJ1j:CSrjCHsi. b4s 1&2-3*. do 1.2W5, x9 LWSI: C11s.-
C&C, CCjj1CjjtCjjjfej, hie 113-151, do 1.1619, x1j 1.499S.'
Thete have Irritating odors and polymerize rapidly to dark
resins even In thc pre""Ce of inhibito", theg do not met
with ainthonUcat All and Ahow coumen it tnitalion
of refraction (J,Z-1.8). I%e tetrabromide of the bexcayne
treAted with 10% Ate. KOH In the cold %xv- a wide angc of
product.q; a friAction, bj# 116-21", conudned less Dr thad
extwct&f for a tribromide. Thebrominatloooftheoriginxi
alke"""t 'a I
*5 ]ways gave Small amb. of low b. products,
which we. probAly the dienic clibcomides, with their bights
re values, thew umWly wem formed In Jes# than 10 yields,
G. 16t. ~Km-lllpnff

USIM/Chemistry Conversion processes
Gard 1/1 Pub. 151 - 21/38
Authors I Petrov, A. A., and Sopov, N. P.
Title S Conversion or hydroaromatic aldohydon and Imtonos Into aramitic 1,*Mrocarhonq
during dehydration
Periodical : Zhur. ob. khim. 24/2, 298-302, Feb 1954
Abstract I The dehydration of hydroaromatic substances having two double bonds and the,
oxygen atom in the side chain in alpha-position relative to the ring, was in-
vestigated to determine the possibility of their conversion into aromatic hy-
drocarbons. It was found that durina the distillation t th P205 v
ri or tith A1203
at 350-4000 the unsaturated hydroaromatic ketones and in the case Of P205 also
the aldehydes, which form during the condensation of the diene hydrocarbons
and their derivatives with alpha,beta-unsaturated aldehyden and ketones of the
fatty earica, enaily HuWlt to dehydration f0ming VlArioun 411%)1%%t1o c(mw"ki"Ittia.
Fiftoen referoncon: 7-06.311; 4-118A; I-French and 3-Wiimn (1894-1953).
Institution : Institute of Aviation Instruments, Chemical Laboratory, Leningrad
Submitted : October 2, 1953

Card 1/1
Author t Petrov,, A. A.
Title I Investigation of conjugated systems. Part, 54,- Sequence of
addition of hypobromous acid to vinylalkylacetylono. Synthesis
and proportion of alpha-oxides of vinylalkylacetylones.
Periodical : Zhur. Obo Xhim. 24:, Ed. 5p 803 - SW# May 1954
Abstract t The sequence of addition of hypobromous acid to vinylrethyl- and
vlaylethylaostylones was investigateds It was established that
the addition takes place according to the ethylene bond. Separated
and characterized were homologous bromhydrineso their acetates and
bromide. The reaction of bromWrines with alkali hydroxide led to
the derivation of oxides of vinylmethyl- and vinylothylacetylones.
The 1wdration of the first oxide and the addition-of methyl alcohol
and Ibydrogen bromide were also investigated. Sloven references.
Table.
Institution s Laboratory of Organic Chemistry- at the Lonsovist Technological
Institute, Leningrad, USSR
Submitted : December 12, 1953

STWV* A.A.
UM/ Chemistry - Conjugated system
card
Leporskaya, E. A., and Petrov, A. A.
Title I Investigation of conjugated systems. Part 55.- About the order of addi~-
tion of alkylhypohalides to 3-chloro- and 3-bromohexadiones-1, 3
Periodicua t Zhur. 0b. Khim., 24, Ed. 6, 1005 - 10141, June 1954
Abstract t The order of addition of alkylhyNhalides'to 3-chloro- and 3-bromohexadi-
enes-1, 3 was investigated. Eaters of 1, 3-halogenhexene-3--bl-2 are the
main oroducts obtained in all investigated cases. The differences in
the order of addition of alkylhypohalides to halogenhexadienes, as com-
pared with butadiene halides, are explained on the basis of the theory
of electron displacements. Five references. Table.
Institution : Institute of Aviation Instrument Construction, Leningrad
Submitted : December 24, 1953

C.A. a
SIM'. cl
ad% k tmw S4
R
A% c ad #A
ww"t
10141, do 0
Won COA
Was
u 744
lk awe
24

S R
9*41W". A. A.'=
Ind
tw
M)c"-,,,:%m",,Dl
0.5 s. ZxM mW 02 ouL co
~7 dayi yk4dW obome 16 x.,
40.5 do OAM xV I
PidlUCO.H ;.i N
Cl in cold utol(-K4
-8~. eir'l.4242. A s1
b
. 42
ZnBrv pvv AfvCCHCll. C
do 1.1 IFA; Ife.Cl shnitaily
dot lJ4W is 16150 IH
CCUPCOCIII c
2~9 M, lb"
"AO4 cafft U as
with di-31a fumwxe 20 hm
P.011). Reacinj a with
bath mWud An km a#
rftd~mtwkh. Ift.COr. Vv
146
did, tu. IX (mm mooll)
K. V. Lum (Lad
4j'AAkW- NmO S.SJA W;!
I WA601.0.45 Utah m4kccl,
1. KCI keo IN a Chad 444
eASk-
r: CH a (I b
XCHtCh CHI
cmuntiom wl
RL
an .1
7
",*`
Wl:
71:

IttlitiM and mecbmnkm of n Ulm
liopik- '"floa of cous
w:lh conjugated doublo baads wl b
pa
,ldror
-LJWWgLAp4 hypoltaUtes. A. A. P
''AsHd;Fi,-KaAd"a i R A W. Nawk
-S.S.S.R. O*W. -1
avaUaMe expl. data (27 itittencts), pshcipaUy ob Ued
g the author, on oritatatloss of addus, tcr eonjupttil
h
ll-`~ Cf. C-4. 49, SOSW iwd bufla w
t. !T, G. poif-

AID P - 1569
Subject USSR/Chemistry
Card 1/1 Pub. 119 - 4/5
Author A. A. Petrov and M. L. Genusov (Leningrad)
Title Piperylene
Periodical Usp. Ichim., 24, no.2, 220-239, 1955
Abstract Various methods of preparation of piperylene, and its
physical and chemical properties are reviewed. The
article is Illustrated by numerous formulas.
257 references (64 Russian: 1893-1955)
Institution: None
Submitted : No date

V5 114,14,

(Imp
*III
451
1
,
lc"

P" 2-P

6( the ej
IU4?.
jPxdA
Im

lo",
99-opemyl

:IA410
dom gawl
(diw. bw
or
3*) wkM
of
rdma. LVLL Condensed=
o
tdo lb
b d~~
Tee . tuft.
-r
'd
23U::~S=' .
OrMine (6-128*i do 11MM. MY 14M,
r save M-l-V H boGO 4047".
Ig-)lm TH ~,W. l7kne
10 firs. at 170* jave 60
M', do 1400, is
ft to.ro); oilcilaym with 9 rwvi*
w - 0,ft, M, 1,
yd_mpfttkft - I,
ridisepholated as picrate m 170-10 while
2-4
-ld'hMimlehie: ~; 1244Y. do.
DS, wbome pkfate in. 1040. gmadnatiom,
Awiv, Is CHCh pve the dOrmMo. w.:
and piperyleme 6!e~&Xvt 40%,
OACC9,11-1 inc No W-3 , OMW,~
de, M-110- IV;
10, MY', IAN lo"$rlle
82%
With
l4winho 154
b*
m. 101 1., WIth cycloveatadiame
yk"4zyd~Accox-f-A
butav
w~j poor;
bal
M. I
sk,
G. M.
0l

(R given), Me 12 g.. Ft 21 X., Pr 22 1., On 37 g., and iso-Du
20 C I only the Pr and t lie Ou decivs. were pug ified by dism.;
the N deriv bs 130% be 144'. dw 1.10)0, xt9 1.4942,
absorbed 98.i~. of the Calcd. t. .111 over Pd.
G. M. Kosjklpoff
alkylpropawl
glycols:
tatter was usually accornponleil by considerable demnlin.
and charfing. 17he following were pmpd.*, 11C; CC11-
011)R (R, h.p., do, xl*, % yield) Ate. 6. 1OR-O', O.WI2.
1-4275. 6"; A Ina 124-5% OSM. 1.430. 35-40;
Pf. bit M-8.5". b"s 141-1.5- OAM, 1.43M. 20-6; is*-Pr,
this 131-2% OAM. 1.4351 -- am 6 72-2,5*, N6
161.5-2 lit OJM 14412, ill-26, i';:Bm bw WO', lini
~116115-P, b.8610, 'I.Wi6i U-40; JMCM(M)R wele
prepti. with MCI In pyAdlne (R. b.p., Ili?, Cf., shown):
Ms. ba 37."*, 1.4152, D.9M; FJ, lis 50h- 1.5% 1.4200,
O.OW; Pr, W 415-60. 1,423a, 0.9210, ito-Bu. bit 71-2'.
1.4260. 0.W72. The aks, readily formed dibluraides by
treatment with ur-cips: Drcn: mcn(on)k (R. h.p.,
As. xV sho", resp.) Me, bit Olt. I.Mfi. 1.5M: D. N.
W9% ISM, 1.5488, Pr, bit 168-5'. 1.7,195. IX~04;
The yieldsol the glycols
HC1CC11(Off)C1CC11(O11)R per inole aldchyde were
49 eh Wkk
A. A. 0v aSOV
A
U-S-Y.R. 25, low-
tion).-4hidation, 401 11CICC14011 with d hronuite gave
up to M-5% IICICCI do 0.9152, xV 1.4070
Icli. Wilit. d 4d.. C-Toi~&M1-61.0- This (0.5 mole) In I
1. E40 was slowly added to 0.6 ma!e RXI&X with ke
ewing. With Molkigur the reactlon prciduct rentained In
WAn. while 130-1 [if gave a flothict which 1C." inell In
the i~lki phase; tighet Gtignard feagents save lipslacls
which were d6tributol I)efwttn both phases. After tmt-
rnent with ke and 25% IfySO# the org. Jay4'was d1514-
.(C"tn. of 2q. layer with 91,0 9AVO Only small addal.'sunts.
at products from the lower Ctignard rpalignts). yielding
dian. of the
a1cs. and dLuelylenk
*0'
4*

PETIIOV,A.A.
Letter to tn- editor. Z, ir. -)t - .25 no .7 : 1L. -I ~' : 1 ' f'
( Fl (KIRA -1: 12 )
y rldl ne )

PC-Tie 0
'A, 1 4 tmn-
. rd ZIJ. ..23. OW-0)
ULAgL 19,L, jVjM
rQ. C.-Redusing tinsatd. halides with
n51
IN sic. KOll multed in the following pctxlmt%% Due[
'gave, after 21VIlversion, a uskxt. of Duel and OU011t,
coutg. 17.3%y OU the latter (82%of theoredmIly prmlble)
and about 6% C11rXIM. Crotyl chloride atO9.21YO con-.
veriiam rAve 79% MeCII.-ClICII.Oli-it and less than 1%
butadiew. 4-ChWo-l-butesic after SIX% conversigm gave!
IrAs than 2.5% Qf2XllCkl,CfijOHt and W% buLadicut.
pvc after 9oJ% conversion U 0%,
yield of ether and 73% hydrocatbotts. estd. con vinyktyf!
enc. The mmul. hydrocagbons were cstd. as like poly-,
C" INI. KIP401.11K)IT

AID P - ~4-4~
.Sublpct
u USSR/Chemistry
:7 3 rd 1/ 1 Pub. 152 - 17/18
Authors Petrov, A. A. and Ye, N. Fritula
Tit1f, 3ynthesis and propertlem or Isomer1c ethers of Aso-
butylene glycol
Periodical Zhur. prlkl. khIm., 28, 5, 556-560, 195c~
Ahstract The reactlons of prImary alcohols (methyl, ethyl, propyl,
and butyl) with isobutylene oxide were studied. In the
presence of alcoholates, primary ethers of Isobutylene
glycol were obtained, and In the presence of boron
fluoride, secondary ethers. Three tables, 15 reference3,
) Russian (1911-195~).
In,9titutlon: 1,aboratory of Organl- Cheml3try of the Lentrigrael
Technological Institute Im. Lensovet
-submitted Ja 5, 19 5 1;

USSR/Organic Chemistry. Synthetic Orgnnic Chemistry.
Abs Jour Ref Zhur - Kh1miya, 110, 8~ 19571 2669L
Author Zyryanova, T.A., Petrov, A.A.
Inst
Title Research In Region of Conjugate Systems
LXIIL Action of Bon?enesulfodlchloroamide
on Piperylene Solutfons in Alcohols
E-2
Orig Pub Zh. obshch. himii, 1956, No. 6, 1593 - 1601,
Abstract The action of benzonesulfodichloroamide (1)
on solutions of piperylene (II) in CH OH
and CAs~OH was studied, It is shown chat the
additlo-fi takes place in tan 3 4 and ltl+ posi-
tions of the diene system of fI and produces
a mixture of 55 to 60% of CHICH*CHCH(OR)CH Cl
(III) and 1+5 to 40% of CHICKOI~CH-CHCH2C1 ?IV),
where R- CH (I11& IVd respectively), or
R =C2H5 (Mb and IV-b).. It is establishedo
Card 1/6

USSR/Organic Chemistry. Synthetic Organic Chemistry. E-2
Abs Jour Ref Zhur - Khimiya, No. 8, 19579 26691.
OCH3 group (at C( ) of the diene system) In
III is proved; d at the action of alcohol
alkali on the received mixture of IIIa and
IVa CH CHC(OCH.0nCH2 (IXa) and CH CH(OCH
CH*6HCH OCH? (XIO was obtained in ~he moll;_
ratio oi '+ 3; the structure of IXa (ob-
tain*d from Ma) is proved by its transforma-
tion into methylpropenylketone (by the action
of 5% H2S0j+ in the cold) and the structure
of Xa (obtained from IVal is proved by the for-
mation of CH CH(O1H )CH CHVHjOCH3,at the hy-
drogenagion ~f Xa"oA coilo d t. t was es-
tablished that together with the reaction of
addition at the action of I on alcohol solu-
tions of II, an insignificant chlorination of
II with the replacement of hydrogen took place
(compare with RZhKh1m, 1955, 37172). 135 g of
Card 4/6

-J.'r6

CA. $0. 1193ft
-7 7

PETROV, A.A.; 1YETb, K.V.
- --11 -
Research in the field of conjugate systems. Part 61. Addition of
alkyl halides to diene bvdroc&rboni3. Zhur.ob.khim. 26 no.4:
1113-1121 Ap '56. (MI-RA 9:8)
1. Leningradskly takhnologichaskly Institut imeni Lensoveta.
(dalides) (Olefins)

7:
.7 7
A-
/Al&viArboax vdib.- Prop A ut -m#4
'A. A. Pettuv; ind K. P.. Ralf 4hut. AvU =J~
26, IA89ALK1956)
-~tfcattux:a c. HCiCCOJU
;ith-d M1.1
14
~7
f Cf nt. McPh with'O,
Fly none,
~h d
aled tube la bcs- aki 145-W" give ST
2.5, ikydro"
r ic ac
in -hich failed to condewc wit waUir,
161c.~ The uld -htaicd with &'45 sula. pvt,
V
-mbile irk-Atinent, With rjr in CHC4 lave a, brominated ick!
Ifeatimi.G.&g.' HC, fe Ith "10-'m
CI-f':CHC1-1-CEft I
ph yvilh 0 g 1, t-q I,
'I me Y, u
t 120' pvt 70PIc"A61,54ibydrokpitade, bu O"ZOP-1-
d
-1.0720,'talf 1.4038, which rapoc& with 10% Wit
9giperyletre in: McPh %Rith 0.1 g. hy&oqWnon4 12 hrs*~
1 0 gave 74u/c 2-#tdAy1-Zi~4ikydrohcn3Vic acUi tn.~,
which failed Ea con se witk maleic anhydride and
den
wIth 6 pvc B&OH; heatiliz With WI/c, HM02 to 2M e
M&Y
IT - CHCH - C
phtfuLlic acid. Similar rtaction of CITt.CHCH. g
Me-
hic at 1.40-S'
HCi CCChMe. save in, 10
71
Z'54UYdrQ6"zOak' b?& 68, d" 1. -_~J%jf
_90" 02409 11
4u1 A,
d W04 -
Wuch with 100/0, NAOR gave thefred aei , in. 9:6
Id U41
cilwIth'theabove. i treating 34g. HCiCMF1. w
3.5
Ita #4
hopreue And OJ C.- hyd"utuouc in-M&PWIO bro. it 14
-0~
.60 gave!
1801
J' whkb failed to condmwwithtit~ anhydride
on
heathic. but heated
X. wfth It in the prcrent-p- of- HQ stul
black 6 firr
.It &Ave p-1,feCjfiC(hH, ox
Watkni with I
N(h
ie
-()Wj~u' -1-41."20;j.
gmvi the He cikr, lht 110.5*~ d141
samc ester,
dn 1.0435, J% A930~
form&
formed In =OvNfe and tn
HC
L

Riph iiith 0.1 r" d- 0
prepe heated, m
tocirg-,
Mor-iiatibu did prm-w4 uvvs Raney 11cafinj 4
ilt meph.lit tile Pws.*
RCICCOSIt With 0 C.
eam bf 0.1 g. hydroquinnile 7 firs.'at 115-20" gavc scatic'.
c%Wshtf 40%'OtOll, -Hmti~sv liciccolil with.
40 2:i6j"butadictic in MtPh4itli Oj bydroquinotic
ot 116J20'
add, at. 2104T*i ~rhlclt witli dil.HNOv at IrA-* In 10 hre.
gve.
7
VIA
-20
if
fend 5i Siff,
CU'CiA. $0, :iftw.-T~' 135 9-%olf
1j: fn,:k-4 I pt
wi ter
standisix. until actitti 0 *u-s Utz
dbtcf~- lit, tk,preut~tjcc of ct littk. Xa;S~)p 'I?
pi fery
uf:, in of
X g.of
JreC11--C11C1[COMc)Crfja afid
cf oil
04
M 1.4 1 M
14C.
itlctqmrot~ partwly xclki. Isy
-aittICICII.Cchlf. *c1luxitir-ilic cthos with
'K0111 kt M-0111 18 firs.- gmv~e.jf~,Cjj. C11
FI*k~j- d& IC
A.,i*.!:Yl, which hyffs-ogovaM ov4-1, 7
1,41 up ttiv~ 1,11d. au;okj, 6~1 41 -OK&
lit 1114'. O.C.L0 F*4
TA-flv~ -44 tnw441~.- ~~4t
W 1-~ Ise ft

ZYRTANOVA, T.A.; PETROV. A.A.
Conjugated systems. Part 63: The action of benzeneslilfodichloramide
on alcoholic solutions nf piporylene. Zhur.ob.khim. 26 no.6:1593-1601
Je '56. (MIRA 11:1)
I.Leningradaki7 tekhnologichaski7 institut imeni Lensoveta.
(Piperylene) (Chloramide)

Irlstow. war,~ Cadden"HOM

m6
Witt pm
retravanax.f 74-11. J.Irfex.
--&e CA
Em
.
fmmbt=vuamao=Mfda an ate
[tat. T. &- ZytyanavL ud
-sim twi.

USSR/ Organic Chem.Jstry Synthetic ~)rgani~, -hemistry E-2
Abs Jour Referat Zhur - falimiya, no 4, 1-95Y, 11652
Author Petrov A.A., Al'bitskaya V.M.
Title On InLeraAlon -)f Divinyl Oxide with Amines
Orig Pub Zh o$5hch. khimii, 1956, 26, No 1,, 1907-1909
Abstract Reaction of divinyl oxide with primary and secondarj amines takes
place according to Markovnikov's t1ale with formation of alkylaminobu-
tenols CH2--CHCHOHCH2MR1 (,)' Addition is promoted In alkaline media
To an excess of aqueous, 35-40% solution of amine the divtnyi oxide
is added dropwise, while stirring. After 3-10 hours treated with
K2C03 and I isolated by distillation. Prepared were the foiiowi.ng I
(listing R, R1, yield in %, BP In OC/20 mm, n 20D, 120, MF of pt-rulo-
4
nate in 0C): H, CH 3) 65, 8o.5-81. i.46o8, 0 9282, 192-193; H, C2H5,
'(2, 86-87, 1.115'(0, 0.91114, 2Li-21.2 ("e"MPO'"), 1f, C3"(' 33, 9~-96'
Card 1/2

USSR/Organic Chemistry. Synthetic ~rganlc CKemlstry. E-
Abs Jour Ref Zhur - Khi-miya, No. ~, Yil?l
Author Zyryarova, T. A. , Petrov, A,A,
Inst
Title Research in Reginn -f Cnnlugate .;ystem!i.
LXIV. Actlon -)f
on Piporylene -1'oll~fl n- ~n !'e'hyl !"Lhvl,
Al coh,-)ls.
Orip Pbb ZI-L obshch. kh irm I II
1,):)6.
Ab-,t* rac At '.h- ac' ~-)r
on. In met!-.an-l ar.1
mthanol, th- a~11--r-.
or c-)rres nndin;~!:~, ;-" -~h-Ir'hynolromIte t-~ if
In thm ~,P~ and 1,.i -!-It.~Inn- take!! 'he
7,olnr ratir)
o conilleraldy
Card 1/6

USSR/Organic Chemistry. -~ynt- 1 r~a,.I-_ Z_
-)~ ~- r, -~
Abs Jour Ref Zhur - ~',him I.-la '71
more 1.4 adducted matt-r than 'he~ o~arlimr
investigated divinyl. J.,. 'he )th-r hand,
alkylhypobromite5 adjoin II in th,- '~,4 posi-
tion to a -,reat,~-r !e7r-e than 'h,,! earlier In-
vest1gated alkylhypochlorites. 'W .~ )f a
mixture (A) with 'he bolllr,-, pnin* at 6'_ to
710/?^/ mm, of 4-br,)mo--l.-metoxyrent-.,.r)l-' (111)
and (IV) wan ---
ceived fror, 6~ g -~f 11 ('70 to 71~q' of th,-
form) and 94.5 E of I In 2~0 mlit of C11-,-
under conditions lescriho!-1 earlier; he ~, ! d e, i
methylpropenylket,,ne formiriv obviously frn- III
was separated. CH)COO11 and BrCH7,COGH wo!r,- -)b-
tainpd by *ho! ozonTzation of A. Df A
with 28 g of KOH in 1~'; mlit of CH-10H was
heated 9 hours. ".15 g of '-me+oxyfentallen-
p
193 M) (mixtuxe of ~is-trans form) ()oillng
Card 216

U55R/Organic Chemi.9try. -~2yn t h o- t I c ,r pa., i -n .1 '. r
Abs ur R-f Zhur Khlmlya, -4
I nt 'j r)
I Im-thy I -,qtpr .pne-
(VII) oint,
-20 ~o r
n L) x
,.4

If - ; .
r,r; c woor z,
t
L+
molar ratio 'I r7r, I 'r,:7 I I I ani
(forming fr,~r 17) -f
boilln-, -cint 1
V
n ~OD
1 )10,
, 4
w a, 17 f -11
Wj th
i t f H 4 1 t r 0 Ph ny lhydr a-
bniling
zcne o
,
A In
,,as hylr-!-rato--d
on ?0 p, o~ rn,,ldar- -,,r
0.~
Card

,:h e- i s
'Orr f-
j
17
A

1r t
11 olrr, ;t
were

+ r)

af

ri _~ SD 14

CH
-ind L
xy

car,j 4/6

UL; 3 R Ori~ a n i c, r
r -~n
r 71
Car~

US-,'R/'C)rgani- Ch-mi-qtry, -~yn' n h,-,-i Ir 1/.
Ab 5! 1 r Ref Zhur
d, r .7c-6r , an-I .-m-ox,,rpentane
boiling point r~ tD -im, whjc~. 'rro-luced
pent~--ne-l after ~reatmen+ wIth Zn lunt. Pur e
cis forms of 71, bollfT,.~, point l' -' to I
n D 1.457j, d- and r-f VIIII b,,Iling
werm recelv-l ty Jn*r-,h.,-tI-n )f Puro- -'I-
11 fnti Ih- re-acl!-)n with I 1--I C!130H and
Cari

ZY-RYAZIOVA, T.A.; PETROV, A.A.
Inveatigations In the fle'd of -or_ltigated aystems. Part 66- ?he
action of benzoe,illrodichloro- md benzosulfodibromnamide on alcohol
onlationa of leoprene. Zhur. ob. khIm. 2~'~ no.P:21P9-2l9S Ag '56.
(KLRA 10:11)
1. Leningradskiy NkchnologichAskiy institut Imani lAnsoveta.
(Amide8) (Isoprene)

PETROV, A.A.: SOPOV, N-P.
Research In thm field of c-n,ugute sveteme. Part 6?. S0adeL%&'.. L
of propargylic allehyie with 2-halo- and 2-a,Lcoxyl7utadlerea. Z,.-,r .
-h.khIm. ?6 no.9:24~2-245? S 156. (MLRA ),11)
1. Leningradakiy inotitut avlateloanogn priborostroynniva.
(Prnpiolic llehyde) (ButadiAne,

-77
o J
tip
7~
W~ iAd 0.5 j-~
7 wl.
I at Lw g&" 20
ig d
164-5% 6162arly'. A _Z =wd Iftdroprene La-meph
t sit 140! WIG hri. ve 73lr
0," 'j d*,, . 05i illf JAW
07
Vit" molvill, 67M
.,-AN02)otlyr)f bw I dts .0478 ft IAM (afttatt.
I by, hfttlnt with AziO ta'2001 tontaliud wtnt
jbw .44 a onewigioUrmc. bw -68-62-1 doi O-W250r
tic , Pt.C a W VLve Cmde
1~
tzgwg 1~.- 151-3*v doi.OSSU" I&V 1ASSMI... Beat-
4gopreae With 60 Mt. Keft'sola.'d about 12 C.,
,ill"' - r
!~~'AXK Us. at 120"
Mg~ A87
I I=
j- OW
14 1 M 41-2f fdttr chMs w WkIt
an 6 v4cao-mudoxtum afterl=fla
.-
221-V (f iq,mgldt~;
M
6); or M. WS-1611 Vrom,liq
W bw tOG4* I
ow IM
It
arp
lool WE
;,sv LOW. Whkh with 257, IINCh NA, looo pvt J~:
"Oil
GkId. Ucdtlbg't wkh chkmnU ve MON.,
,-7.

tow. X. D(wo spilLeds: with
jugawd
d
i
*i
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2
f d
f7
C
d
0
. -
t*-
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OA
d=
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U
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j
M with &riwatl[ves of w4t4d"ftwsw =046t4-C tci".
E*uyv mad A. V. TumAtwwv~ 7.6se. Mik"KAhm.
C,,f. 59. ll~'Adflc,34 g;
CIG-CPCI
1XIC, (1). Its flic jKv-ALfsA-4,t4ft litek,"444ityl-
c%trcfta,-*((ls Q lc. C(fjlCiIC'Ch&f4.- its 210-all. Ateph 10 h".
At 110' CAVV 59'V~Afd it.,
.140-10% t6 LL~lj, x1f 1.40XO; this.-WW6 U
9. 9011 VIVO
-
W","v'Irctodid 00. bmMO-V 61.39-40* 'Ahk 'Mfg
(A With s
yk-kled 79l;,i cc)4, rklvidc. ~; WA~8.5-,, 1 40M, 1.47M.

"Ot ef"vettal witII*tuw:u N to &1% al"ide. 111. 1494

h(Q-11(achit It
-4k o-dus"l.with A c t
tuu k I Ott Coc Iw W
tstcr -e nwitnea. Thi* atic
(11). hentical
Witt, lit-we
IrAyt W% diod U- xem~3cfaieum-fji)-.
'
i
M
i
h h
a
.
r
e
ted s bra
M
t N492-3,6% 1A
i 1.4 wh
-
M. with exc. ACX"
r
bA "-4% O.M. 1.4&0,

90"W"
S'f*P;QxMAdM oil ght: taixt. witisdil. 11NOa pwot.tz HIM.

CJ4COLW,~- "d EtUaBe
'
j 4Wvg4rjo**xwx-f-yj)"Tbixd bo 117-48-.~ bo
p
'
ACO Cz A clixt-
aCIM with
17W. dchili" at
14M 14
of ow
A
w wrap, bago-lov. the maw Putba
'-
m ~
Cff
5 20
14
G
Od
r, o ' j d.
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C.
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g
iludow It hm at
l
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-bo B&W-~

-Wrli ()V r A,.,, ; ML*JJ OVA, A. V .
bynt h Os I a i n tt. 0- f I O~ I d Of - 11 ~ ' a.1s to--i a . Pja r t . "' . :d I - %#! 7:'- - '~ e;: ! A
with nid of' f I,iorf- rerim . Par! -4. ~,ondanss4t ir n (,f rl io-o- rPle wit'. - tor a
w' - . ' --uns ritii ri t ed d I hri n 1, ru- 141 s . Zhn r . o ~ . kl~ I m..'6 Ti o . I I : )T: ~ - ' .). , " N I , ," .
(MW. I o : )
(F ', u , r oi)r m -ia ) ( `~- ,(Jm ?In 4 t I ,-i 7ir nd.ir to (-M imm ~ i * ry )

.7777.-
LXXL DU 9" at,
1" t ink
-ate
N Z;d
6
w
6521 1.
ay Olt 12r ia
and W,
-, ~W,, polyma. IU Aw o. I.W
*
tkad Ista. maiAl$r t pkduct. bjo* M4
,
-0* doi-
of oxac mot. wt. wem colletted U to bvi 120
-s
1
001L
LAM :
in
r
U

-
t
at of clmer with
Tf% t
M
sit
w4
iitc~k acid and A-cuboxyadipice". tn.
lydrog=atme)(thtdimeraverPt-Cst2M 6cavearsum
1.4140, v
hat4ijifalam IV"
4
U

1
0c we HxOK "d FC#fr4Cojjj.
Tru(Mut of. the
df%e with PhSOWRec. Ulowed brateOnlar ud hftt*c
the cruda'
ith'Z
rWu
L
t
A
Ol do
il-
c
w
c
p
law "M&"
6s 'd
IdWhimudoPh"u
U
&S
b
.
.
o
,
w
bw9o,-M.-
sftg~ t22-41). - Intmed spoti'a o! the ftectiont of the,
dimet Indicate (speeft'areshown) that It cousisto wwaly oV
bi
t
dl
I L d
44
12
i
l
M
:b
l
L4 . W-
a
ene at
L
xu
ity gova
(
mem.
70 m
91 hick xvc2tl%Uutmiteddimerofthe2toWpmeau,
'
o
M

this over
vrh .l
OO.
01M. Mr I-
Dftdrb9e"a=
Pt-C~SxVO~ C
'
,
h UNN'
kb t
IdAtk
B
O
I
Ov
o
n
"It
S
EI
tive
U4

V&'
of add(Itiii a
v
Gib -fen*
A. _tsc
Y
alyreabnoL lint., I
It .
I.
-0143R-= -26,Mfg~ d"
~C _W'
-4. 6 t,. 40M
-Pamg. of -CI&E
1.5 lr,~ atorns Wowed b
ICE
W 40"C Cth" and dro
RddJi OUI male f, rga
I. I Cffcff titer "flux(ell, I
4 t With 11104MGO-5% ifc;,Cffcfr
Art Cff
bui in - al.. . I I .
W, (6 0.7m, 4 1.4368, Rwu'
CMI-9 367, '407(4') 402 A ifectrum I
4), ah.. "Igw .
-0 t
Ralf 14 4), Im(g) 224000). 2= 1
2451
116L Sol 04 a
am ~: : 111(oomlw La
A Mcewat MAW w th
0.11:W4014 Br Im CI[Cli rjeldlu
tt"Xjumc 93--a.S* ba to" rp L 1244
u 327~12),.3&4T, 'X
JIM
2
141-4( 11,224 231
44 a
3
to
MUKOH WV~ojf,gnd CT
I 1w b!UF letter.
-Of 44% WgIllarOllmide and
r` the mixt., b. 15",%
_jd 11Wmeftt Of I With
11044"'u. b, 154" d.7-2M nVI 10. 4U*
''If"Wed to ad O-Xot
me extent In the fat
hm I .i- - Is C.
Ith 25 mi. 08% HBCI I W
7' IF-W MD. bju 4 =a-] 4.--
5".6 lap,
Till
W50)
w 4 .9
4 ,
got 4 i'30114).
g
In
th. the use55% H
th Br In.
a hm with
aks KOH
9P 4070 9 1
.4~

pt ra
ur
4
ap
P(wtmft, blWloamphY.: aad r-
of Oil. Wmaidon.
on utethods
77.
Ao.
a