SCIENTIFIC ABSTRACT PERVAKOV, V.A. - PERVEYEV, F.YA.

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SCIENTIFIC ABSTRACT
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S/126/50/010/001/025/027/XX i8 0100 1 otj,~ /j., E 03 2/E 111 AUTHORS: Khotkevich, V.1. and shepelev, A.G. TITLE: Latent Heat of Plastic Deformation of Silver at -196 and +20 0C PERIODICAL: Fizika metallov i mctallovedeniye, 196o, vol. lo, No. 1, pp. 117 - 121 TEXT: The present authors have measured the latent heat of deformation Q, on the degree of deformation -'~~d/d and the vrork A done in comgressing silver specimens at temperatures between -196 and 20 C. The pulso method described by the second of the present authors et al in Ref. I was employed. 99.995c pure silver wires, having it diameter of 0.1 mm and length of 6o nun were used. The d-!formation was produced by compression between polished steel plates. Fig. I shows the dependende of Q (cal/g) on ""'d/d at -196 0C (Curve 1) and +20 0C (Curve 2). Fig. 2 shovs th.e latent heat Q as a function of A (cal/g) at the same temperatures as in Fig. I. Fig. 3 shows Q/A as it Curiction of A and Fig. 4 Card 1/4 872-1 d, S/120/1:)0/010/001/025/027/XX P032/'E*;i4 Latent Heat of Plastic Deformation of Silver at -196 and 42L, shows the latent heat Q as a function of the relative change in the resistance of the specimens, Acknowledgments are expressed to N,L. Zheldakov for assistance in building the apparatus and in the measurements. ,rhere are 4 figures and 7 referenco!s: 5 Soviet and :2 non-Soviet. -iz.l Fig.2 17 Card 2/4 s/i2c/60/010/001/025/027/XX EO~'/r3llf Latent Heat of Plastic Deformation of Silver at -196 and -2G F ig2 Fig. 4 Q0 - T 0 0 C, Q0 30 ?0 0 /0 ? II - 0 05 0,2 0 t=.10. 2 0 f-~196 Card 3/4 A-,, ~71 ~, S/126/60/010/001/025/027/XX E032,/L314 L,atent Heat of Plastic Deformation of Silver at -196 and +2'(` ASSOCIATIONS: Fiziko-tekhnichcEkiy institut AN UkrSSR (Physicotechnical Institute of the AS Ukrainian SSR) Kharlkovskiy gosudarstvennyy universitet imeni A.M. Gor1kogo (Kharlkov State University imeni A.M. Gor'kiy) SUBMITTED: February 15, 1960 Card 4/4 PXRVAKOV, V.A.; KHOT M ICH, V.I. Colorimetric determination of thei energy of formation of vaca,~cies in gold. Dokl. AN SSSR 134 no.6:1328-1330 0 160. (MIRA 13:10) 1. Fiziko-tekhnicheskiy institut Akademil nauk USSR i Kharikovskiy gosurlaretvannyy universitet im. A.N.Gorlkogo. Fredstavleno akademikom A.F.Ioffo- (Gold) -PERVAKOV,-I.A. [Pervakov, V-0); KHOTYEVIC], V.I. [Yhotke7yeb, V.H.l Thermal capticity of plaeticlly deformed copper. Txr. fiz. zhur. 6 rio.P:240-2" 14r-Ap 161. (MIRA 1j,: 6) 1. Fiziko-tekhnicheBkiy institut jUl USSR i Kharlkovskiy gosudar- stvennyy wniversitet im. A.M. Gorlkogo. I (Copper-Thermal properties) (Deformations (Mechanics)) - FT:HVAKOV I V.A. [Pervakov, V.0.1; monEvicii, vi. (Khotkevych, V.H.] Applica"',ion of the pulse calorimetric method for dot-er-izing the solva-~ion energy of oxygen in Ejilver. Ukr. fiz. zhur. 6 no.3,408-411 My-Je 161. WIRA 14:8) 1. Fiziko--tekhnicheskiy institut 0 USSR, g. Kharlkov, Khartkovskiy gosudarstvannyy unJ.vf:rsitet im. Gorlkcgo. (Solvation) (oxygen) (Silver) KHOTKEVICH, V.I.; PERVAKOV, V,A.; GENKIN, Ya.Ye. Low-temperature press, Prib.1 teai.ek.Bp. 6 no.5:20-202 ~-O 161. (MIRA 14.10) 1. Fiziko,.tekhnicheskiy institut, All USSR i Khartkovskiy goeudarstvow*,y universitet. (Low-temperature resear(h---Equipment and supplies) PERVAEOV, V.A.; MERISOV, B.A.; HOTKEVICT.', V.I. r- - Effect of the characteristics of crystal lattice distortions on the temperature dependencp of the electric resistance of silver and gold. Fiz. met. i metalloved. 12 no.1:38-41 Jl '61. (MIRA 14:8) 1. Khar'kovskiy gosudarstvenRyy universitet inani A.M.Gor'kogo fiziko-tekbnicheskiy institut A9 USSR. (Precious metals-Metallography) (Metals, Effect of temperature on) S/126/61/012/003/020/021 E073/E335 AUTHORS: Perva-kov, V.A., Petrenko, N.S. and Khotkevich, V.I. TITLE: Influence of the plastic deformation on eliminating excess vacancies in quenched gold PERIODICAL: Fiziha metallov i metal.'Lovedeniye, v. 12, no* 3, ig6i, 46o - 461 TEXT: According to M.A. Bol'shanina (Ref. I - Ivz. AN SSSR, ser, fiz., 1.9509 14, 223) plastic deformation of metal does not only cause formation of crystal-lattice distortions but also leads to their elimination. According to published work a sufficiently high deformation at room temperature in Al and Au leads to a decrease in the concentration of the excess vacancies. Data are given in this paper on the influence of deformation,at the rate of 1.00,c/min and 1.05%./min (impact) at. 20 and -196 oC,on the increase in the resistance caused by preliminary quenching. The investigations were made on 60 mm long, 0.05 mm dial wire, made of pure gold (99.99%), which was determined by compressing the wire with two polished steel plates. The quenching waB by raj)id submersion of the specimens in water. Fig. I shows the dependence Card lk!~' s/ 1:!6/6 i/ol 2/oc-dc.,Wozi Influence of' tho . . . . E07 / 83 "15 process itself, it can be anticipated t'iat for annealed Au speciziens which are slowly deformed at room teuperature the contribution of tLie vacancies to tlie increase in the electric rosistallco at low dogroes of deformation will be greater than at hif-h degrees of defomiation. Spocimeno deformod tit lour tez:iperaturesor specimens deformed by impact at room tem-)0rature should contain t-,iore vacancies than specimens deformed at a low rate at room tem,~,crature. These conclusions on t,ie vacancies are also applicable to other point defects whict-i have a lover temperature stability than vacancies. There are 3 figures and 5 references: 2 Soviot-bloc and 3 non-Sovi et -bloc:. The three Englisli-lanZ;uage references mentioned are: Ref. 2 - M. Wintenbej-~Ter, Symposium by the 1957, Lon(lon, 1952, 201; Institute of Metals, Dec., Ref. 5 - M. Wint anbarger - Acta met - , 1959, 7, 549 and Ref- 5 - R. MaddLn, A. Cottrell - Pliil. I-lag., 1955, 46, 735. ASSOCIATION: 11,,~iarlizovs'ziy gosuniversitet im. A.M. Gorlhogo (KharlIzov State University im. A.M. Gor'l-,iy) SUDMITTED: April 27, 1961 Card 3/x~ L 11~118~46 EWT(M)/EWp(.w)/T/EWP(t)/EWP(k)/VdF(z)/EWP(b)/EWA(h) 1JP(c) JD/HW/JG ACC NR: APS028563 ("/V) SOURCT CODEs UR/0126/65/020/005~(0733/0740;>:'I AU7WDR: Guterman, M. B., Mirkin. 1. L.; F~qvl yigc, A. A.; Pervakov, V. A.; Petrenko-, N. S.; Kho~ikevich, V. T. ORG: TsNII of Technol2a and Machine BuildinK, Moscow (TsNII tekhnologii i mashino- stroyeii-yaT; Kt~L*~ov osuniversitet im. A. -M. Glor1kiy Kharlkovskiy gosuniversitet) TITLE: Certain featwes connected with the K-state in Ni-Cr, Ni-Cr-Mo and Fe-Ni- -Cr-Mo alloys SOURCE: Fizika metallov i metallovedeniye, v. 20, no. 5, 1965, 733-740 ysics, ordered alloy, friechanical property, resistivity, non- TOPIC TAGS: metal ph- ferrous metal alloy, ferr us alloy, metal heal: ,treatment It heat resistant alloy, high temperature strength, metal hardening ABSTRACT: Changes in electrical resistivity b-1 Ni + 5% Cr, Ni + 15% Cr + 18% Ho (VAand F, '+ 25% N1 + ~61' Cr + K M; alloys were ~s~uidlied s i_T~Vlction of low tempera ture .2formation , m +200 to -1960C) and _ani,iealing14ate (from 2 to 106 deg/min) Decilosition of're K-state in the alloys -Za-s- obse ved. The effect of the K-state an high temperature citrength was also noted. The K-state causes microscopic inho- UDC: 539.4.015 Card 1/2 L 14998-66 ACC NR: APS028563 mogeneities Which retarl the motion of dislocations. In this work, the influence .of the decomposition of the K-state was studied in terms of high temperature strength. The temperature dependence of electri.cal resistivity waa obtained as a function of temperature and heating rate. For nach alloy, the resistivity in- creased initially and at 50OPC reached a peak, iAiereupon it dropped to a minimum (about 7000 to 9000C depending on the alloy) and rose again. The drop in resisti- vity was associated with the decomposition of the K-state. Deformation by compres- sion (60 to 70%) in the temperature interval fn:in -196 to +20012 showed that the de- couposition of the K-state was practically independent of deformation temperature. At higher temperatures (between 5000 and 100000 and at high rates of heating the decomposition of the K-state was studied by increasing the heating rate to 101 deg/min. The Interval for the maximum decomposition was displaced to higher tem- peratures (300 to 4500 higher), depending an the type nf alloy. In the K-state re- gion a significant str*ngthening was also noted when the speed of deformation was increased from 0.03%/min to 0.3%/min, while in the region of K-state decomposition no effect on strength was apparent. For fast beating rates, the rise in strength was mair~tained at higher temperatures than for slow heating rates. In particular, for Ni-Cr this region itas expanded to 7000C, while for the other alloys to 900 or IODOOC. Where the K-state was decomposed at rccn temperature, no additional streng- thening occurmd upon pulse heating. Orig. art. has: 4 figures. SEIB ODDE: IV SUBM DATE: 06Au&64/ OFXG REr: oil/ OTH REF: 003 card 2/2 A5 -9 TON D I 72~ ii~ p"f.concen age, md1s'6 in PAVLYUK, A.A. (Pavliuk, A.0 )- FERVAK011, V.A. (Pervakuy, V.().); KHOTKE:VIr,.H, V.I. [Khotkevych, V.A.T Effect of an oxygen admixture on the heat capacity of silver. Ar. fiz. zhur. 10 no.2-.237-238 F 165. (MIRA 18W 1. Kharlkovskiy gosudarstvenny~ universitet. POPOVA. N.M.. kund-tsikhn.nauk; PERVAKOVA, T.P., gidrobiolog Improving sanitary conditions of the Mool-va River. Gor.khoz.Mnak. -0 no.2:?9-12 F 159. (MIRA 12:3) Oloacow-Sewage) (Moskva River-water-Pollution) 15-57-12-16786 Translation from: Referatimy zhu-mal, Geologiya, 1957, Nr 12, p 12 (USSR AUTHOR: Pervakova, V. I. TITLE: The Stratigraphy and Lithology of the Jurassic Rocks of the Llvov Vpadina (Basin) (K stratigrafii i litologii yurskikh otlozheniy Llvovskoy vpadiny) PERIODICAL: Nauchn. zap. L'vovsk. politekhn. in-ta, 1956, Nr 46, pp 72-81 ABSTRACT: Within the Llvov-Volynia coal basseyn (basin), Jurassic deposits rest unconformably on rocks of the Carbon- iferous and the Devonian. At the base of these Jurassic sediments occur variegated rocks with a thickness up to 137 m; red, brown, green siltstones, mudstones, sandstones; and layers of conglomerates and boulders. The variegated unit is a lagoonal-conti- Card 1/2 nental deposit and is Middle Jurassic in age. Above 15-57-12-16786 The Stratigraphy and Lithology of the Jurassic Rocks (Cont.) it occur lithographic and dolomitized lenses of gypsum'and anhydrite and limestones of the Upper Jurassic. and molluscs may be found in these ranges from 60 m to 300 m. Card 2/2 limestones and dolomites with with oolitic and pseudo-oolitic Rarely, ostracods, foraminifers, calcareous rocks. The thickness V. A. Krasheninnikov PARVAWV, IV.G. Flotation method for separating imste water from oil and oil products. TrWy MI no.16:172-l!)4 '58. (MIRA 11:12) (Sev&8*--PtWificAt1Dn) (Y'Letation) ROZIN, B.B., inzh.; PUCHKOV, L.M., inzh.; FERVAKOV, V.P., insh.1 Using methois of linear prograumung in planning the charging of steel smelting furnaces. Stall 23 no.9t845-847 S 163. (KRA 16:10) 1. Zlatoustovskiy metallurgicheskiy zavod. JEVTIC, Zivojin, doe., dr.; TRNINIC, Borivoje, dr.; BESAROVIC, Kiso, Mr.ph.; PERVAN, Vatroslav, dr. %r experience with the treatment of hypertension with ismelin. Med. glasn. 14 no.12:566-568 D 160~ 1. Dijagnosticki centar u Sarajevu (Upravnik: dr M. Gajic-Jankovic). (AMIDINES ther) A-NTIHYPERTF24SIVE AGENTS ther) pEp,Vk,-TJ E, F. chmiciaAbst. A rapid and -..$,-A Me determina- tion of 1~ W me a _Um~ ~e i C mmium. titanium ~e'n r 0 0 n- Vol. 48 No. 3 i~n jk2p, r-11F. -7-0 n . ". Feb. 10a 1954 _M!=.__The sam JeWi4i'lo'y with HSSO" is reduced witbpo-A-FM. V-'lsreduccdtoV1'4nmJCr4* AnalAtcal Chemistxy toct"'. The.1 KMu% is added lit slitht excess until the soln. retaim a sl4ibt pink coloration. After I tuht. enough 0-02N Fe.A Is added to just destroy the pink color. DI. phenylamine ioln. (1-3 drops) is added as Indicalor, and the soln. Is t1trated with 0.02N ferrosullate until the Indicator color changes from vlolet, to green. The juethod is fairly ACC NRi AP6035884 SOURCE CODE: UR/0413/66/000/020/0124/0124 INVENTOR: Badayeva, A. A.; Pervaya, A. S.; Tutov, 1. Ye.; Katsnel'son, V. Yu.; Kuzmintsev,' V. N. ; Koloskov_,__M_7ff._, T-ul-f-n1ch, V. P. ORG: none ,TITLE: High speed steel. Class 40, No. 187314 [announced by the Central !Scientific Research Institute of Technology and Machine Building (Tsentral'nyy 'nauchno-iasledovatel'skiy institut tekhnologii i mashinostroyeniya); 'All-Union Scientific Research Tool Institute (Vsesoyuznyy nauchno-isaledovatel'skiy instumental!nyy institut)) SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 20, 1966, 124 TOPIC TAGS: high speed steel, chromium tungsten molybdenum steel, vanadium containing ,steel, titanium containing steel, DOC-Mr-l-rcl , 77.00G,14iU65-3 ABSTRACT: This Author Certificate introduces a high-speed steel containing silicon, panganese. chromium, tungsten, molybdenum, vanacium and titanium. To improve the strength, ductility, notch toughness, and oxidation and heat resistance and to reduce carbide heterogeneity, the steel composition is set as follows: 0.75-0.85% 'carbon, 0.17-0.35% silicon, 0.20-0.40% manganese, 3.5-4.5% chromium, 2.5-3.0% tungsten, 2.5-3.0% molybdenum, 1.9-2.2% vanadium, 0.03-0.08% titanium. SUB CODE: 1l/ SUBM DATE: 05Jun65/ J Card - 1/1 UDC; 669.14.018-252.3 L 2886-66 FSS-2 WAS(VL-ACC ,~EWA(dy ~(hL IGSIG~t AT5023607 UR/ODDO/65/000/ODD/0381/03871 IACCESSION NR: AUTHOR: Vernov, S. N.; Mtl~nlkov, V. V.; Saveqlko 1. A.; Sayin. B. I a T. 1. TITLE: Recording of charged particles of energies of 0.1-10 kev with a spherics electros tatic analyzer SOURCE: Vsesoyuznpya konf erenqiya pioL f izike kt)amicheakog!~__plo~~"!!stva..- Hoscow, -1965. Issledovaniya kosmicheskogo prostranstva (Space research); trudy konferentaij. J~ SEW, Izd-vo Nauka, 1965, 381-387 TOPIC TAGS: satellite, satellite data storage, particle counter, electron density, ion'density/Elektron 2 satellite ABSTRACT: Identical s herical electrostatic analyzer 'ew/ere used to record positive and neantive varticles mos-151nd Mth nergies of up to I kev on Cosmos-12 and Cos UP to 10 kev on Elektron-2~ Each analyzer was comprised of a spherical capacitor some 60 M in diiiaiiii-,--iil-th input apertures leading to plates spaced 12 mm apart, on which a periodic high voltage was progimmed so as to allow passage through the annular Sap.of only.partleles of a desired energy range. A Faraday cylinder at-thel., L;TLIJ3 L 2886-66 ACCESSION NR: AT5023607 gap output served as the collector. The input apertures and the faraday cylinder were furnished with biased grids to eliminate thermal particles and secondary emis-i sion, respectively. A diagram of the two analyzers used 'on Elektron-2 is shown in Fig.-1 of the Enclosure; accumulated charge was converted to binary code. The Cos_j nos data generally showed that electron flux at the 1-kev level did not exceed 107./CIZ2/sec/kev at night and was only slightly higher by day. A maximum was noted during the vouthernmost portions of orbit, in a region south of New Zealand, attaining up to 12 x 108/cm2/see/kev. Electron fluxes recorded on Elektron-2 showed strong variations at sunrise and sunset (referred to the satellite'); these variations !reached values on the order of 109/CM2/sec/kev. Irregular v"arlationd in flux readin a 9 correlated with known geomagnetic .'e~rents obsez-~ed during the- flight.; Data show that the satellite was at all times within ihe magnetosphere. !Positive ion flux regis- tered by Elektron-2 in the 0.1-10-kev range did tiot exceed,, 5X.107/cm2/sec'. Orig art. has: 5 figure' br~and I tabl6. ISH ASSOCIATION: none SUB CO ISUBMITTEW 02Sep65: NO ENCL:. 03. DE! ESt NO REF SOV: 008 OTHER: OD3 ATD PRE S S Card j _1 M -0-6. L 2886.-66 ACCESSION NR: *T5023607 kki,69 i-Vi S c Collve urre-A Scalerr witch' 41 owet Tr 119V auppl Al uce comma S. Com COM- Pwitcb- mand unit mand 000' Lid r Com- rc switc%, Fig. le Spherical parricte analyzer an EWA 2 Tr High voltage transformurs Cow'-, conmutators;- Al:-,O.I-l kev range; A2 1-40 keV rang0,1 Cmd 3130,~_ VERNOV, S.N.; SAITNKO, I.A.; 3HAVRIN, P.I.; NESTEROV, V.Ya.; PISARFNKO, N.F.; TELITSOV, M.V.; FERVAYA, T.I.; YEROFFYEVA, V.N. Some results of radiometric ob!~ervations at altitudes of 200 to 400 km. during 1960-1963. Kasm. issl. 2 no.lt136~146 Ja-F 164. (MIRA 1'7:4) PERVPMEY.. A. . p I sa t e 11 . ; HD I VANI, G. . p I sa t a 11 , -, KLEBANOV, S. -. BLISHTREM. A.; ROSTOTSKIY.S.. rezhisser; SEGAL. Ya., rezhisser; BYSTRITSKATA,L.. aktrisa-. USHAKOVA, V., aktrisa; PUGOVKIV. Mikh., akter; TIKHONOV. S.. pktor; ZAKHARCRENKO, V., akter; GINZBURG. V., kino-operator; DULITSBV. V., kinc-ciperator; SVFrOZAROV. Ya., direktor kartin; MARON. V., direlctor kartin. We ar)eak to you. radio amateurs! FL,dio no. 6:) Je 15B. (MIRA 11:7) (Radio-Receivers and reception) PaVFIITSLV, A. In Iceland; ar, c-x(,-crrt from. , book. -,i-. fron th(: ruoLian. P. I[-. Vol. 5, no. 7, 1955 mo(aoIIA So'i ~ )s, i~ulrarizi 6c: Eastern uiro,,ean ticccz~.,,cri vol. I -o. 3. Jan. 1956 P.E;tV-:,~TSEV, Arkadiy k1ways Ugher an-~ higher. Av.i kDam- 46 no.2:6-9 F 164. (MIRA 17:3) FZRVEI;TSIV. ArlmdA7 Reflectio on M3r '59. the Soviet officeir. Voen. vest. 39 no.5:15-19 (~VU 12:10) (Russia-Army-4Tficars) FIRvmtmv,. Arkad - - -, Supung Hydroelectric Pover Station. Smr.mor. 16 no.17:18-19 6 '56. (Supung Hydroelectric ?over Station) (KM 9:12) PERVOTSEV. Arkndiy Alekseyevich, MiTYIfOV. Yu.,red.; KOROBOVA, L., teldin. red. [Put out to sea] VYI--hod v okeali. Nookwal Izd-vo TeX VLESM "FlolodRin gvnrdlia.' 1958. 131 P (MIRA 11:9) (Rusgin--NaVY3 PERVENTSEV Vl I - I - Mountains call. Sov. voin 43 no.22:3?-39 14 #61. (I'dFCA 15:2) (Mountaineering) MMDUNI A.M.; DAMUN, M.G. - Ufactive spacing of a bisecting series Of inJeCtion wells uzed "Monuds, flooding. Azerlb. reft, khose 37 no,3:19-21 Kr 158. intra . ry (Oil field flooding) (MIRA 11:8) L 41641-66 EWP_(t)/aI -jjP ic L---JD ACC WN, AP6WIU4 SOURCE CODE: RU/0004/65/000/002/0059/OC)68; AUTHOR: Barosu, Mircea (Graduate chemist; Bucharest); Nastase " Constanta (Engineer; Head researcher; Eichare8t); Pervescu. Xarlana..(Chemical engineer; Timisoara); Tatucu, Stela (Chemical engineer; Timisoara); Sudresan, Sever (Chemical engineer; Timis ra) -5--' ORG: C?Barosu; Nastasel Laboratory of Electrochemistry, ICE~ (Laboratorul de -11 electrochimie la ICFE); [Pervescu; Tatucu; Sudresan] Electro-Banat Factory, Timisoara (Fabrica Electro-Banat) TITLE: Contribution to the establishment of the utilization conditions of some MnO sub 2 types in manufacturing galvanic batteries SOURCE: Electrotehnica, no. 2, 1965, 59-68 TOPIC TAGS: battery, depolarization, manganese compound, carbon black ABSTRACT: The authorjqstudied the effect ot hanging the C/MnO2 ratio as well as the use of artificiai"*O~ and carbon black 01 the activity of depolarizing agents and the electrical chir_~acteristlc_s of 3R12 batteries. This led to some suggestions for improvements in the manufacturing technoloi5r, which have been tested and have now been introduced in production. The structural analysis of the x-ray was done at the IFB by Doctor R. Gri&2rovici and R. Manaila. The authors thank them for attention given the analysis and interpretation of the MnO2 type x-ray structure; Directors of the Mlectro-Banat" Factory and Tochnicians A. Bol?6, M. Sociu and W_ of ~_ C. Butum for assistance given in preparing the industrial p aso he solutions. Orig. art. has: 20 figures and 5 tables. (Baned on authors? Eng. abst.] [JPRSj SUB CODE: 09 / SUBM DATE: 05Aug64 / ORIG REF: 010 / SOV REP: 003 OTH REF: 009 Card I /I af B A R 0511 ,Mircea, r-b'mJs' dinlonat (Buc,iresti); NASTA-31-7, Constanta, cfrcetator nrincipal (Buc,iresti); PE~iI.IE-SCU.- Wiriana, inj~. chimist (Timisonrn); misoqrq --!~,-,7-ist (Timiscare); SUP7~:FSANI, 39ver, inz. o n.,3 -)nfributl ons to I.he determ: nati on of' thc u* i 11 zR tion -on~ I gnlvnni~! batteries. of' !,.ome MnO~. typos in mnnufficturirV Llle~-trotRhnlca 13 no.'-:59-68 F 10.. I . ~*, ad o*,' E '.o trochemicql Laborit,orj of the Re search qn(I PI-innim, In3titul.e (for Ba-rosu). 2. Re3earon Find i ~hn~ c Planning Ingti tutp, (for HIst-ase) . 3. Bawi' ' Plart , Timi!-,nqra (for !,erve.?cu, Tqtticu, Sudresan). 1, mi t to-j Aiigii3, -,, V-4t,4. PZRV3TINSKIY. L.N. Use of graphic plotting in computing Leveling nets. Geod.i kart. no.8:72-75 Ag 157. (MIRA 10;10) 1. Otryad No.23 Sredne-AsiatBkogo AGP. (Triangulation) PERVEENTSU,, Arkadiy Alekseyevich Geography & Geology Visit to Iceland kloskva, Sovetskii pisatell 1952. 9. Monthly List of Russian Accessions, Library of Congress, August -19W.2 Unclassif ied. PMENTSEV., Arkadiy ........ Why do we strive for culture? Staroh.-serzh. no.5:29 HI 162. O-IIRA 15:6) (Military discipline) PERM7SEV, Arkadly Strength of the people is a mighty fCTce. Av.i kosm. 1+5 noa2a 2-5 Ir 063. (KM 16 x2) (Bissia-Armed forces) ~ I Nh , ?AACW~iSV. Ark-adLy Alekseyevich, S. . re&'.CtOr~ A . , or- LCreDtive werk of millions] Tvorches--.vo millionov, Mosi-va, Goo. izd-vo Dc.-lit. lit-ry, 1957. 65 P. UILRA io.1i) ~!Dt-or and laboring CiSE;Bea) PERV-PNTSEV, V1. In the boiling of the waves. Starsh.-serzh. no.1,0 Jl 162. (MIRA 16:6) (Submarine boats) 71~11111~stry , Sit ammietry - 11samerl"Um 'Asmssivb In the Yield of Isamiwic Mmyeralcmi of Zotmes and Aldehydes of the Aaetilskio Series. F. Ta. Perveyev, lab Oft Chmip Sol Roi'Ckim Instj, L=IW&d State Order of Lenin U, 51 PP wzhw obahch xhim" vol xvin (LM) s No 3 Xotelch's reaction maed to synthesize 1-phoDyl:-3- m0ftl-h-chlcr-Pentm-l-ol-3 and Its corrospmdftg wMes,- frcm m~peslum-brcmi=-pbwy3.wAyIvn9 mod 3-abler-butanme-2. IsamerIzation of' oxIdes-by's3m oblorlae produced I-pbmyl;-3-mothyl-limtm-l-cim-4. PA 6?11"9 REDIM" Character of laimmis'stl= a l1wift b6imm-MAID&U. MmItted 10 1* 2#7!Pn 629 rn UBM/Chemistry - ReatTawgaments Apr 48 Chemistry - Ketones, Acetylenic "ftudlas in the Field of Isomer ConverBion of Ketonam and Aldekbydes of the Acetylene Series, II," F. Ya:. Perrayev, Lab Org Chem, Cbem Inst, Leningrad State U, 81 PP "Mur Obahch Rhim" Vol MIJ (I )j, no 4 2p 5-Dimethyl-6-chloro-3-haptyn-5-01 was obtained b7 coadensation of isopropylacetylene with .3-chloro- 2-butanme and converted to the corraepmding oxide vith povdared potassium brdroxide. The oxide was zemerIzed. with a 20% oolution of ciftlic eald ~t 1000 to 2, 5-di.-.--.b~,1-3,4-haptadione-6-cr.. Th UaM/Chamistry - Raarrangemanta (Contd) Apr 48 reWrangemnt of the hydrocarbons of the type RC = CCR(C~)CCRI is facilitated by tertiary a1)[718 ;nrl 1 to a 1 aser degree, secondary a1kylB as substituente of the acetylenic hydrogens. Submitted 10 Fab 1947. 4M 8/49Tk3-- USSR/Chealstry - Acetylene Series Jul 49 Isomerism OR"earch in the Field of the Isomeric Conversion of .-Utones and Aldehydes of the Acetylene Series, III)" Ya. Perreyev, Chair of Structure of Org Compounds, .~Chm Faculty, Leningrad Ord of Lenin State U Imeni, A. A. zhdanov, 6 pp athur Obahch Xhim" Vol =, No 7 4-ftthyl-5-chloro-pentyn-2-01-4 was prepared by ccudensation. of metbylacetylene with chloroacetone- and .9 Its corresponding oxide formed tiy reacting it with pmarod c~tlc soda. T1w42-metby1-rMtYZW3-&1 w" 4&rlvod by -acid on tbis Oxide and debydration'6f the alph&-glycol. Primary alkyl radicals, Vhen wftUtut*4 for hydro. gen in acetylene in prototropic system., had effect of stabilizing enol form. Submitted 26 is= 48. 4M 2/5OT25 USSR/Chemistry - Acetylene Series Jul Isomerism "Research in the Field of the Isomeric Conversion of Ketones and Aldehydes of the Acetylene Series, IV,," F. Ya. Perveyev, Chair of Structure of Org Compounds, Chem Faculty, Ieningrad Ord of 14nin State U imeni A. A. Zhdanov, ~F'~p "Zhur Obohch "Im" Vol =, No 7 2,5-Dimetb,YI-6-cbloro-hezYn-3-01-5 (1) was pre-. Wed by condensing Isopropylacetylene with tbi~rv acetone,, and the corresponding oxide of I pre-"' pared by reacting It with powdered caustfIc soft. w" then pmpued by Ismerization of this oxide Vith a 29% soluticm or c ac1d. Subadtted-26 Jan 48. 2/50M FFERVEYEVI F. YA, Chemistry, CrFanic Ninetieth nnnlversar-j of Uie theor- y of cliomicnI qtrnicture of orpanIc compoundi. 7(,, -1 t. Len. un 6 No. 11, 1951. Monthl Li3t of Russian Accessions, Library of Congress, 3eptember 195 '71CLASSIFIED. 1. PERVEY114V t F& y&. 2. USSR (600) ,4. Chemistr7, Organic 7. Intramolecular reciprocal action of atoms, 'feat. Len. un., 7, No. 2, 1952. 9. Monthly List of Russian Accessiorls, Library of Congress, February 1953. Unclassified. I F71T1,177, F. IA. Perveev, 7. IA., Kuirlashova, '-I. I.- "l-iterac!tIon of -), t'- ''~ v -, -, - ", :! - -, -.- ~ -, r- sprips with oxyi~en-c:)n'liinin-,7 nni compounls." (r. 15~() SO: Journn] of 'lenpi-Fil Chemistry, (Zhurnal 01).qhchel Whim-ii), ', o' " -1 '47 '- . ' -, - - _ --- 12~~_ t USSR/Chemistry - Acetvlene Nov 52 "The Reaction of their-Oxides of the Vinyl Acety- lone Series with Oxygen-Containing and Organo- Magnesium Compounds. II," F. Ya. Perveyev and N. 1. Kudryashova, Leningrad State U, Chair of the Structure of Organic Compounds "Zhur Cbshch Rhim" Vol 22, No 11, pp 1964-1970 During the reaction of 2-methyl-oxido-1, 2- hexene-5-yne-3 with alcs in the presence of sul- furic and oxalic acids, tertiary monoethers of glycol were separated out -- derivs of methyl, propyl, n.-butyl, isobutyl and hexyl aics. During the re- action of 3-methyl-oxido-2, 3-heptene-6-yne-4 with all-co in the P-rc=ce of the ethers were obtained which were the derivs of methylp isopropyl, propyl and n.-butyl a1cs. During the reaction of 2-methyl-oxido-1, 2-hexene-5-yne-3 and 3~-methyl-oxido-2, 3-heptene-6-yne-4 with ales in the presence of alk catalysts (alcoholates of Na, II&OH, Ba(CH)2), primary and secondary monoethers reap were separated out. These were derivs of mCthyl, propyl and u.-butyl alco. The action of the Acid catalvats resulted only in the formation Of tertiary monoethers of glycols. But elk catjL_ lysts produced a primary monoether for 2-methyl- oxido-1, 2-hexene-5-yne-3 and a secondary one for 3-methyl-oxido-2, 3-heptene-6 yne-4. The rate of formation of monoethers of glycol in the presence of alk catalysts decreases in proportion to the decrease in the acidity of the H in the hydroxyl group of the reacttng ale; the rate of formation ~H Of the monoether of glycol, in the presence of alk catalysts, drops in accordance with a decrease in the 801Y in &lcohO1 of the alk catalyst belog con- sidered. 23M7 Chemical Abst. Vol. 48 No. 9 ,'Reaction catylene aties vithV, of a~gljdll A Awl ~ea I%Y 10t 1954 beaduS an r.:; Organic Chemistry pervetv an !11 U.7-3-W 22, 2013-18(1952RBngi. tmnslation).-bee C.A. 41, 10491h. U3 Reaction of 0 Vlaylatetylene sesin Wilk oxy- pounds. -Ceavage of tht oxide ring with RMgX ocr re at the a atorn. To HtMjDr was added 30 g. C11j: CH0 CFM71 Chemical Abet. CH)-ro.3 (1) in Etoo with cooling, the mixt. let stand over- Vol. 48 No. 5 night, and treated with 30% AcOH, yielding 54% J-mrAyi-: Mar. 10, 1954 bjqSl-2', do 0.9215, ditO.M. XV 1 Organic Chemistry 1.49 4 wbkh with cold 3% KMnO4 pve (COoll), and a 110 tc4i, Cill0o, Isolated as the Ca sail. Shnilasly, CIA:- MCI C&#. (M. and RtM gBr gave 00. 5% 2-mdhyl. 2-dk-d-S4exex4-yn-1-ol, b. 72-3*. d* 0.9041, nV 1.48N,1 whicli with KMnO4 gave a HO acid, CoffiA, isolated as the ,Casch. Passage of 40 g. CHs:CHCiCH into EtMgBr and 'addnof34g.lpvt2Og.Cll,:CHC.CCMeICH(OH)Mol- 'C 034' b d 0 7 C H ( : Cffs, .959 i a 1 " 0.9M. do , xM 1.5M, , which hydrogenated over Raney Ni to the said. analog, blo 107-f;*. do 0.8". dt, 0.9458, n1j 1.4471. Si~~ilarly 4D g. It ga re 23 g. Cffo: CHO CCAft(MOH) C1 C CH.- CHj, N 109-10'. do 0.1)M~ do 0.0476, ts'al 1.5292. hydrogenated to ;the irid. analog, by 95-8*, do 0 8427 Of I b ;;~ d f l l i h Mji 1 W t r ne t t , ng open ng w by the gresterl ~o p N i n the above oxideal A pas. charge on the a-C atom of the ring o becauK of the Pre3enc-c-of r-!-CJlnk.--G-K-Kml4wA-: Af 7 jrjag7, -aujf- Va. 1. Kit Ul. H. i a RV-Eysv- - .:op 7' XeAcfirl~ of VA, Mv- &"!A A. .41b GalibLof the d ety an rinyla; &T, 19MORM ova tk Zhur. Objrhckel =am. 23, 976- re of oxides of the CHj and Cffs:- CHCiCH ii;erim Irith HIS in the presence of Bi(011)i Is a general tritthod for the prelm. of vinyl- and alkylthlophents. 3%e rftctiork consists prolpiAy of the Initial formation ol a vicinal th'lul aln., Mydrs%n of this to an unsatd. thlot. stfid ring claFure by addit. of the SH group across the tr!Ple bond, 11A pansed into a % 11-alitated'mixt. of 20 1. Ilia- 1(011)~ in 114 ml. 11,0 witfi simultaneous addn. of 30 C. bis 50-10, do 0.9249. PtV 11.47p, at Slich a rate &a to keep the temp. Wow 50', f61.. 'lowed by pwmire of HIS I hr. longer, acidification ivith '10, gave 73-5 AcOH .and eibi. with U 0 2-vin 4-Methyl- bip 67-70% nV 1.5,580, dw M11 10, Mch slowly ilkilymerlicd in air; It KIVCA A ChArACtefiStIC lodapheninc reaction with latin and fornis ik ctyst. product with lill- (OAO~. 113-dr6*ation in V40 over Riney Ni gave a dih o drpiii., nV I.M. d3a O.W52, wbich miter MrO, g.-sve 4-trethyl-Z-1hiophencearboxylic acid, tn. K _I., -1 compd. a also obtained on oxidation of the viu) Similar reaction of Xmahyl-2,3-oxido-6-he fers-I-)7se the JJ-S streant was:;Wsed lit 8 hirs. at W-7 ') gave .1 g. 4,5~twcthjLWophcr;r, bi 6&-70*, tj'D* 1.5,5-15. d:s With J1;(0,r(c)3 this yields a solid, decornp. 250% vrith isatin and HSO, a deep red color is formed. If the synthesis Is nin at the reaction is complete in 2 hrs., with a slightly higher yield, along with tarry by-products. P ageof 2()I.,,IeC:Cll intoan LtMgBrsoln. over 12 brs., as& followed by addii. W15 g. R tCOCII%Ct and treatment with 30cf AcOll gave b3 75-7% WLI 1. 4111 1 d-, V,M)", 1. Th k; -with powd. KOJI in Et2O gave b, .10-1% 11'ro, 1.4435, d-a OXNW, ivbkh treated with I ItS as described above at 50-60*, aed, .15 K. fro ~~5 K. oxide) tit., 1). 116, d., 0.WJU, 1.5070, giving a violet color ividt J-14 orld Niminr a rolicl witla lfr(OAc)2; oxida- iii acid, i;%7ii~-TJ__(Cf.. .8JI(pird. n C.A. 26, 4330).' S11111atly the Gripard reagent froin MeCICH and bleCHCIAc gave 05,~ I,, _,AM5, yielding 4-kexyn-j-ol, bl'66-7.6% WJ 1.4671, 4-hrrypic, bjj 4, with powd. Koff j-metkyl-2,3-oxida- d#. 0.8W, n'60 1.4410, which with 1115. a% 1, at 60-001 glive, Itoul .00 g. oxide, sono! 8 it. Abon torimet il',Acpie, 1). 162-3*, n'j 1.5)04. tIm 0.9730 for a t some 10'e. oxide failed to react. At Sfl- ici "'Lyth'- " _~- rnpletion In a shorter perirxf. 90 e to Col 3~a? e -4-yrie, bl, 54-'5*, d.-, O.OW5, "'0 3_ G. Al. K0.101alUX 4* with Loi -- And Synihe nTWyi,- Lar af vinyl a th 0 v an v an a, .1017-: . Kudfrv A. 953XEngT, tmnTa. 48-:3219i. H.L. q "R Y~ f E, J J, 48, 8219i.-PIICI CMKBT- (Q.7" tmted with 80 -4. EtCOCILE overnight and fretted witkSQ-0/. CCCOH)m al, c1, b. j4c~l 43 M, d,,j LIDII IM ral. HtD~ wt and extd.-:wlth UtIO yiddi &yUbioj". bt 1= , im , , 1, violet rifal(14 4.5=. d3, I M78. gave 5C-51 'Which with Ug iiectate j~klds a saltimi s-p*exj14,5-diuwA*Uq gave G2-99L A 30 t ~ n. w W e onns with ljjaectxi 7 O=pa isada-1,131104, It gives a c r!-- yi- J. J i Was ib 1.7- yl- 20D H with 2$1 9- gave. =UnrAcien Ry ml t" iwf brs ...... coam 9&=n n With BUO, 60M. CAN CHO CCAft_ 1.5165, C. oM -bkb. After Cff,,VH., b. 91-2'. 22 ;t3;. and- R,%NI In - McOll: 4! H and yiddO t t mad., emejer, , 1 1: L M-t k up abW 3 IM 0 Mg3 whom 14 jjI,NCO rC%c* i AM, d!s 0 3, b, OD 0 mnl, tim P-ducl, C%'H' with t0) a KNmj)i6ls bi .1 CHCJ CCOC(OM, I MN" dN to 9 dais P,. 43% df-_' 08 1.6ml, 4!6, b.0771:. CICTIVAt ve 3D%. 97-8 r 9 hrs. whh, king dg, '0_75 lc unmOr - W7s. xV 1.4 dis I Cu.OCI, b. I SO 2 1:1~= Wafting, witli powd_ y4:)H mder - -wh ed IL bm 13"- oil' 1.4111, d" 0-130 at looo. pve F, I in sg-&W tube 2" IVS' -with 38% MWTI ;Tj,,r)C7yj&bj 8" 1. %V 1.4HO* do' lmywdofBucjfi ILI e UY04 *rif-- MI wi, 1.;Cijl?N P" oM Ireacth 0 ter and an 64- ldn- Of "0 1 . Ets R~10 1(15 g.) gave io K. CH'.. Ciro CCA(,(OMCffrl jmm temp. . hro. at do 0.8915- Itfu 4 days to 86.0% 7~ fi7 7 Zl!" 7 - ~6 ~R, ejt Al ozd C Per"Yev, F Ya., and Kudryashov.a, N. 1, Title Reaction of alpha-oxides of thd ao-etylene ~series with hydrogen sulfide. Part 3, Zhurb Ob. Kum., 241'~ FAi. 6,,: i019 1025, June 1954 The, reaction of alpha-oxides of Vie acet lene series, with hydrogen sul- ~y nce of Ba(OH),) led to the.synth,esis of, hydroxvalkyll; hio-'-' fide, in the prese 117- phenes: 2-(alphs.~oxyi:sio~ropyl)~4.4wtWthiopbone,, 2-alpha-oiy-secondi butyl)n-4-methylthiopbene and 2-(aipha,-oxyiso0roPY1)-4) 5-dimethylthioj~h- ene. Dehydration of hydroxyalkyli~hiophenee with,diluted sulfuric acid, results in the forration of vinylthiophenes; 2-isopropyl-4-methylthio- phene, 2-(alpha-mthylpropenyl)-4-~~methyl--thiophene and 2-isopropenyl-j~, 5-dimethylthiophene.. Six references; I G6rman since 1885; 2 USSR sirwe 1914. Tables. ,-Institution State University, Leningrad Submitted January 15, 1954 llt~= Name 1A.,-: PubW 22 P, F. Ya. and Kud ashova NI I __:hue I Reactlow of hydroten sulj1de -with "b;cIdes of the acetylene* la cetylene' seriell' (synthesi~~-O~ virw,l-;, alkyl",_and phepylthiophene's Doke All SSSR 98/6p 975-wM' October' 21., 1954 Absuract v.-The ri~aiction between. hydroren - sulfidb . and (nddes of the 3cetylene and vinylacetylene :i eri e swas investitlatedo It was found that thase wddes, um ro# en,reacting idth hydrofen sulf de in the presence of bari hyd de,' forift all.-yl-J. vinyl-., phenylthiophon(~s and other derivatives depending upon the structure of the basic acids.. Mher dompounds,.synthesized through :ddes w:itIvhjrdrof.e4 s,,Llfide, are lis ede Thirteen ref er- thn iraction,6f m t ences: 7-USS14' 3-USA: and 5-cerhan .('1899-1952). Tables*, Fr~-scntcd b,.,r: Acv-demicinr. 1. L.. KnimyantT,, Ikq 20',1' 1954 PEAVEYF-V~ the 0-2 Oxy muntno -is exild les ol the tYO RCI &M Oj Va. pcw~vgv. 1 VC-1mix Leftimprad xidt:-i dl yxe more readily thm ro -War,, 'em, I Whips. 'lly'lln trbulinfilnud wmkw. Ilia) LLLLMA~11L 101LA Ing glycols-were prept! widjax IWilli Stirring Lite, 1"A1 41nd vilqlamf~;Vlle - by. I ~! - ... ~,-,ipm "Ad Omcg*'d mcidifint 110, ~-;i. P-) T 1191itsting the F)Y- tipc lliO by VAM11111 kejunis, ajcs.~ hulf~: tither by rveryting. 0 Ju e33ew JCjCQOl1)Alr- kci CNIOX + W-V' (frixii Wis).4 ANO It If-j)=ft v iteoll), MeMICIcabil).3 f.' riw li. M~-T~ (froui A ,he, Cc J v4dis (bijo./mm" x9pil - d1st 11f&,i U41rid, AIRP iliv. (OH) "4 Fftm) 'woe .17 -it. &(On Afe 1Cj ce(OH)WOW11, w, .4 M.) ;;w I f, ut 1044' PA 1704, j,_C(0jj)k.ejj.0j16~ ns. 49-4)", lb g1-`41' ) C; 1~c(j)jjy 1"Ili. 0 44~79,. 4 (311 65. 105--1(e'1 Alf, 105-6 At /2.1.47 7 W1, ~Cjjs:ClIClCCN1e ~iojj c1 cc J (1) Asti 4 1 3ommor Illid, I Cl(,X liMlecili 'hie 11(f.10:0 (11~ (d., C.A. 47.:11lit-thl i49.61i,18.5.; Th 4 (11111CIICICC X Inlit, (A ke f oils I)_SOj. -woe iLt Y Lll),,of bi is) awl a 3444 excess of kc W Ic I 14 Stich tji:%t tlj~ tesup, ilk) not "ceed 400.. The $jsg~ as~e jgwi AY~ Oij)~jc-CAlli,r j. ji8- ting abow INV. lAiww,; 0. .11,,( pjl,lewou~tawlitij in air asid expl(sile tm Ima 38-81, W; 1r,itiaLut with Lllkl, 11t504 readily bydffAym thr-no 141 ket6les.11111 klyvolq (lit burr i-MADritiling unsfUr thu re~v- 43-95 43.43 fitif ~ coliditio&is to The foilo.% iug: VAlf-CHAle-0. 8D- 1.468,'0.9637 xW-Afka culvd.j AIRp lfpnw1,' Afer 1-4050, OX47 CA _11: aAj no, Y fire li-,tcd:, C11j: C11Cj C :41~73, 43. 1)11 C.-CFAfl-ew. 0. J01-2-lim), 3 Fj 111C. vp~'Xifle~ re, CAIN: 2.0, 51 ~'_`/3, (0448,1.4658, 47, 0,. 49.6.1... AlthOligh' p act %villi JJ4) Very Slowly Ill the llissrJILL. (if a cawlv~,t, it, the ---- -- ------ 4 l!-cF0ftk w3cefif w k;04 the rmct~m I (-;itljlv I ,Ct:%1ll:.Cll3.0.QfrELO. 11, - Weil r",!jOjrk! O1 C. 71-2'/4, f).04 1.46NO, wilb 13)11,b vvjs)l3jil)jj of brat, lit vdill mw to "Iflitt "Wi. VC -r14 0.11378, 1.4 tme,cums.0. .-Vis" 0.11225, 53j, I ~ W) 1.469 CNCJ 04- CCA clis: C11 Cl I - .47W. 5r..6,: r.7." 1.%*33" L-I" Fit 0.9, W, CHO C:CAFe-(V1A1e-O,CMt- CU) IV.-!, -L 211 T6 m1hus (Tort 1 W14 U the latter vrere addr#d to. an'MmktintX. 2-3 droji r, i HIS(". at. a '~ttc' "imich tbal'the temp.'did il'ot rme above -Ili% amrtM mht;; _colorteci. thm stirztd With: NijOh umb wilift HAW. issmed,m3thecatalrig, Yor 11 is oddi-A to thf: lwnling st.~ HAO, , With cithvr.03~1:' qrulc'-f 6t ".8s.-Nao) ink AW t1be k7121. btaged,jo 6G, W an(I tok-11ted ViLh I I't C~.~ 'd d owe jrmd0j,'tbzrf 11 %i-ilb a6lir orbroir cat. yt;u. -:9,(cataly-st, mwDuprtbe: '!,, ft=M%rjfjtD Wed.. t.A(Rp, '~'rr yiJd)1vqrc prept, CA1, 76- Ilz.M. -:7'14. LOGO, 0.0 3#0, 41).g. 39.8. 1.1"$j; CH$:Cjj,".^-j4 CAMOH)CHAVe, NA *w- NaOH. C~40'tJ. 1.4102, 3, 30.6 11'73, CUs: CHQ CCAfc(OPr)C,11r I (MOMA, 41, 4 - M, 5D.4. A9.2, 4.2, k0m, 1TXAOj' 03-5 1.47~ 0.9 58; U11:471MCC(Oll jC8, Fr. Nik. 01-2*/.0, 1.41pi, "MCC (0) Na. W-ODI/B. 1.46M. 0.91,90, if 53:7. 1.4, 24;--EWo.-CHCiCCM#(CitaCtlMft)(.,!Tr~, t W., HM4,'PCH */5, 1.4713, 0.9M. 65.2, 63.7. I.6. 14; ~Cti-l-'CIICICCAte-(Or4fl1i)CHSOHP' HIM, IWI"(3, ifc- fMi,0.9126, 04.31,029 -14 65- cHs:c1fc'cc 1.4811, O.WW, 45.4,1 44.3,1.1. 6940i,'CU2; CUCI CCXOH)MeC11(OMc)A[c, Pla, "4~.80/8,1.47rj4,t),9543,45.5.44.3.1.2,3D; c11':c11Qc-i -13, OSY CMr(OPr)a1(OH)Me, H.Cj%; 9"*/10, 1.47. t.33,, M.1 3.t, 4g, Clill:Ciiciccme(ocillfe-)CII(011)-! Ale, IVS04 of )TYCA, 72--S'/3. 1.470D, 0.9=, Z,5.2;. 53A, C111. CIM CCJ[e(ODti) CH(OW)AIc, I ItSO., K- lluznonocth~lrs , are oArvilm mobilc liq" which on otainding in air in The h ence of. aWksidunu yellow -and vally - thicivii.) Vic pute'liquiez distil i absence aAr with little tar m f4matips. but the hury products which tam explodcL'on hi ting Ithove, 140% In all cam the e1hus obtained ~ by ra er *'4 0bus ObtaintJ by; ba4r. cavilysis.- 0 huic it jo OIL5 4slablW16d tbut ttrthtry tt~us are by QCW cutalli4. 7 rmh bmic tntedysh th-s'lorltolary Ot I kcmjal . 1.01- t PAiding t~c'eptixidrii to a Wod tue" pf %1% Nit 0. oy I l ior aiAut) at room fenip. and atkAut 4 6c miA. unt -111L Wex-j- di PMT. I' 1~5 'ht fuumilsl (b ./sl 11 N e - - lf". C I . dn. Af D cAfc4.i MRD locind) were meM acc(OH)MCCHINJI, (III),. 01-T1-1 ~ 1.5165, I.OU78' .C - CH 97-8*/7 %6i 4 37 CvC vjdvHAfe 6 OH)Af &f . . I: . j ; Q IZMI O.Wnl. 41.63, 42.47;'Bwc(dH) . , AfeClljNll, (IV); 1"1/5, 1,4540, OAM5, 119.47, 30.29; j M.-ClIC.ICC-~ 92-W7.1.4762. J)Sg lb, M-99, 57.36- -1 ponloydrosenatknoat 105utin.and W ~',withj(aucyNi WMS to I-C.N jNCO dPIV 0 strisirlins Ul tryAlif. - (la'. -estechmilin t A 4U%vtw4.hi of ifse. I, r1c. . "( Ow "'IT O"Air fitig 4u.1 rcview llllk ~tcj tilt fialmir'i'- 5 01! dut coce., PARTRYNT, Y.Ya.; XURSNIGINA, T.N. Interaction of alcohol oxides of I;he acetylenic series vith h.vdrogen salfide. Zhur. ob. khim. 25 no.8:1619-1623 Ag '55. (MI&A 9:2) 1.Leningradskiy gosudarstvenW wiiversitat. (Alcohols) (Thiophons) USSR/ Organic Chemistry Theoretical and general questions E-i on organic chemistry Abs Jour Referat Zhur - Ehimiya, No 4, 1951, L1590 Author Perveyev F.Ya. Inst '-Leningrad University Title Isomerization of Alpha Oxides. III Orig Pub Vestn_ Leningr un-ta, 1956, No 10, L03-115 Abstract On the basis of literature data and the author s work (Zh. obshch khimii, 1948, No 18,479, 686; 1949, so ig, 1303; RZhKhim, 1955, 13883) a study was made of the effect of substituents in alpha- oxides on the nature of rearrangement following opening of the oxi- de ring. In alkyl substituted alpha-oxides the oxide ring opens mostly on the side of the least hydrogenated C-atom, and most reac- tive are the disubstituted oxides having the asymmetric structure RR'CCH20, which are isomerized exclusively to aldehydes; monosubsti- tuted oxides RCHCH20 yield predominantly aldehydes; disubstituted symmetrical oxides RCHCH(R')O and the trisubstituted undergo rearran- gement to ketones. In oxides with mixed radicals (aliphatic and Card 1/3 D16tri: dio With W4 80 it., zx= vedg!! "B aid Y. M Y Md" 7 4, 12"KI956).-MC11) (Rm CM ;,C11 ~x TUSS fom In CHCII and Aq Bri(OHN undcr Jkn N atin. 2-. ethY14-jhethYIs--lcuoiAuWe, a2"0'. x1?- 1.5518. dm .1-3WO, and 2.vhlyt-I keti, 1wiritopbene, be.&- 32*, nj? 1.5". do Lam 0911JUM, -PGIYMCtIC tar$: if ~;, CV1, I, form. cwn 1P reduction.of W-vinyl coo d.- to, The alkyl. lorru x),a1kVJ-4,ucthyjv r hen RIW~OH)R - 2-h ydj nap es Which. can bb - delivdmted to '_I41k-tflYj cmP& Th mII)p&. girt *pQJounaus, it i-h expostue to the impois 1111jug injee, knoph ited I ubztltui~nt, ti.p. min.) Tf ft, C 0 11 pit, dis Id IM33; T -3P/2, 1.6T82, RtMeC(OH1. 734*/0. CHI .C~lv, M .1.5553,-A-3m, CHOCIII (31-20/0161 1.6 M,A.277401' Cff2:Cjjw1so, -84/0:5.. j two, I. 77 1847; isf)-41'r$eou, IX14*10.11. 1.5310, U_1169;- I-tyrlo nttniYI,,78 IADUY' Spec ra Averr 0 1U. Infrared t t ained and compared toAhote are rbarw of Oie tUVbeun. -The fulU wing.banAs (cm. W tedmic., :3075-53, cycEic ~ H; ,. 1578-.57, ~ cyclic duuble bond; - M-Wi not dm- to ~ ttro atom since it dovt not' alter In "nj ftom*nkno Iive lo thiophene7 - 760-59i the baml at M;_ 12 -095.73~25 absent fortht, Iflophrm, batitut0i u4su A thiaphe"t flud" tenDplicne but prewin iii the 2.4-smbstituted cumpds.;~ A vinyl group; 578 and S -85., (CH. -his thipawlt for aulp. D5 thc:.fwcm~" whid Ing %ba-.8tructurcs asA-alk Ivinyl -con, .'and not its a I rowe X9"*t-- Ile ve -Air ABROUQUO i6ewSmfkq_- LX loft AU "Jew ITAY1401 Airy -AUG: , W-M, 1=11401 *WS 9, 1 s theds of attwo was de froul'. unsa . epoxy i J, the addn, 46 1 APP1*2 td C=P& Derme -0 side I oaf eft and bnu of chala Ion a nop, -the, tIvIty-W-Ho d- heve lint In 00V, thalin " thuspjkr*lh 3cen to ins, - to, fis Pc Im'-0 only tow f tuisatd. do riva;A 0.6 q t~ ~O)CIICH' to I fume JAMSDr. 3 n .1 hr7aad'maddg~ 1. CICHIAC, ve after sm" houre rAjq,- Ilowed by trairagat with_~ t( 16- Lows j and V44 AV 1.4790.* lot the - g followIng c0 supd1s.). - 61mllarl j'__PrwqOIi1IIIc I CH- gave; -bi z he" A16ri es -wuh pomi'. You - 11tio r"-P" I'S'7-4rh"#YPI'j4P -Ant- I% I.: And '"Mom- Pali bw7se i'vo of' H&-10 "0' 0=.. Ba(OH)t wjLj paj et w 11nin. Nth: there wax. u4 cd::21W.. 2-mithyw.2. rXY-vhcxctWI-YAti tht H& - S was cwtinuiDd 16. W6.0 the truted with A OR and exid. with EtgO ~-Pg.ghtd.;-the Ist fratflontbu tied - being treated with yl ldh on ~otnblnatl Irmill-if as . on of the be 29- Wil-U18, Me It thbadd t I A. 1 6 ox do werl Ifie yldd t* muldemblyj With Ai NiandkIsClith rAvo the ehlQMMCMU4_i dUIV-, H the above oxide, - _7Z 146 gm It, At W. lwd if the mixt., It It ti 4 with lfxS* 4.hrs;i qd - M-O flag mba%, z 2Ad methA;1.2-i dl vt 0;1 --s6 mrse Save 43!&Ml4*b H :gave 80% 1.1-785, 1 M40. mtyu-S-ol gave 4M I hmo, b,4 W-8'. 1.5MI, M84. It , =ovyl-laeepay4-11 iin go. -2-mabyl-4 hydrazycydc tayt SK J-tyk Wes 1-01 78- j Lom' loul$bj 4-teth) -Vwilafly- OMAPAMI bA 03% 1161 to i With N rg i lalvo~ op X A l Ot *Yd VIX04- PXRV , Y.TgL.; VFXMU. U.K.; SMNKOTA, L.N. W !~In~._7~_..~.- Interreaction of amonia wA &miaes with Ck -oxidem &ad bydro- xyoxides of acetylente wA vinylac,etylesic series. Synthesis of alkyl, -vinyl, -phsay'l yrrolse and prTole-carbisole (with sus- "5.Vest. Lea. us. 12 no.4:134-144 157. ?mry in Inglish. P.154 M,rrolsa) (Nothazol) (Mlah 10:4) -if licatt.4 -ink k to_ t i e pve- 4MS -,VAth,-- - Z~ 4.1 Ktx tJ,!i-! w1b Nr M gnj~L sw ~;.Ifa ftht 4l o c li", A 0- 1p 9 tg*. Wit watkg 10 hr~ to I~rve 12 M. kave b4-10" car.. ell Awil- in, taw _u'"Law 1414~*Pxyi r, Ch" illip 14 Ot I Wrde. JJwi th timll I w 0. -.101L 50 at: M";- 4311- N!14 -- t; ~,' R,-- , '.1 . V'~ . ; , . ~ ... . I - . - I . ~ ~ , It e ar *1 1 ( y: ( f - G )t ~ d H " , ", 1, r. f, a . m t Y 1 9 1; 1 C 5f! r 1 (- ~, './ ~ 1. ~. 'I I F, . /. y , '. :: . , - ~ , . . I n~r . o . t '. ~m . -~,. r)( . ! -- 3 1-3-3 1"'? ( ' ( 4 . ,.! 1 1, . 1. . .. it,?~iv . y t in I v e r H : t e t . PERVETMV, F.Ta.; KUZNMSOVA, Te.M. Interaction of smonis and amirms with oxides Of vinylacetylene series. Raw synthosim of pyrrole. 28 no.9:2360-2371 S 158. aceVlOnO ond Zhur.ob.khim. (MIRA 11:11) 1. Leningradekly goeudaretvanan, imlversitat. (Pyrrole) 5(3) AUTHORS: --XaZyeyev, F. Ya., Statsevic~i, V. Ya. SOV/7~-29-7-6/,-, TITLEt Investigations in the Field of the Dioxides of the Acetyl,~,~(.- Series. I (Issledovaniya r oblasti diokisey atsetilcnovL,.,-,- ryada. 1) PERIODICAL- Zhurnal obshchey khimii, 1959, Vol 29, Nr 7, pp 2132-21,57 ABSTRACT: The purpose of the present paper was the reaction of the acetylene series Witt. ILMines, a comparison of the of di- and monooxides of this seri,;s as vell Fta the so'lliti C the problem as to how the oxide cycle cpens und,;-,- thi,, amines, and under which COILditions the forming dian~no are transformed into the corresponding ~-aminopyrryl ca-r' Pyirole homologs of this structure have hithe:rt,3 not scribed in publications. TI.e dioxides of thc a-r-etylene have equally been little investi.-ated so that thc inv.,~ti of the openinc, of the oxidc rin- under the n, ti,---. f in alkaline or acid catalvEis vas of interest. d~~ dimethyl dioxydo-1t2-5,6-~eXYne-3(l) served as bard 1/3 Iw%estiGations in the Pield of the Dioxilpt3 of 'n 7 the Acetylene Scriec. I 0 0 0 H C/~~ C-C =:O_ - C H 2 __2 -3-' CH3(1) CH3 CH3 In the reaction of (1) with ammonia, methyl- and et!;yl aminc it was found that this dioxide has a higher reactivity than tuh,'~ monoxides of the acetylene oeries. Thus, (11) reacts with amine's x7hen heated in clo3ed ampoules at 1000, in contrast to (1) reacts explosion-like even Yith methylamine (without coolinG). By the reaction of methylamine r7ith (1) compound (III) is fornod which in the case of longer heating passes into compound (IV),. Thus, N-methyl-2-(I-oxy-2-inethylamino isoPrOPYI)-4-methyl py--rol,- and 14-ethyl-2-(I-oxy-2-ethyl.-amino isopropyl)-4-methyl pyrrol.? were synthesized. In the reaction of the dioxide with alcohol it was found that in the alkt.line catalysis dimethylhexyne-3-diol-2,5 and in acid catalysis ?,5-dieth-,x-.- 2,5-dimethylhexyne-3-diol-1,6 is formed. Card 2/3 9')_7-"/,9 3 Investigations in the Field of the Dioxidcs of the Acetylene Series. I The spectroscopic inverti~,ntLon confirmed the above There are 6 references, 3 Of Which are Soviet. ASSOCIATION: Leningrad3kiy gosudarstvennyy universitet (Lenincrad State University) SU13MITTED: July 4, 1958 Card 3/3 5(3) AUTHORS: Perverev, F. Ya., Hartinson, E. SOV/79-29-9-24/76 TITLE: React:,.on of the a-Oxides of the Acetylene Series With Diamines. A New Method of Synthesizing Dipyrroles. PERIODICAL: Zhurnal obshchey khinii, 1959, Vol 29, Nr 9, pp 2922-2927 (USSR) ABSTRACT: Following the papers quoted in reference 1, rhich deal with the synthesis of pyrroles fr= 1,4-dicarbonyl compounds the author based their new investi.-ations on the oxides mentioned in table 1 and studied their reaction with ethylene-, hema- methylene-, p-phenylene diamine which proceeded according to the given scheme. Pyrrole derivative (IV), a product of the reaction of oxide with an amino group of ethylene diamine, and pyrrole derivative (V), a product of the reaction of oxide with two NH 2- groups of the diamine resulted from the reaction of oxide (1) with ethylene diamine. The oxides (11) and (III) form the conpounds (VI) and (VII) respectively with ethylene diamine. Oxide (1) together with hexamethylene diamine yields pyrrole (VIII). Oxides (1) and (II) with Card 1/2 p-phenylene diamine yield the compounds (IX) and (X). Table 2 Reaction of the a-Oxides of tile Acetylene Series SOV/79-20-9-24/76 With DJamines. A New 1.1ethod of Synthesizing Dipyrroles shows the constants of the synthesized compounds. The infrared absorption spectra obtained from six compounds prove clearly that the synthesized compounds have a pyrrole structure. Bands from the pyrrole spectrum were found in their spectra (Ref 2). The intrcduction of a large amount of sub- stituent8 into the molecule of pyrrole was of course bound to have an effect upon the oscillations of the molecule. This makes clear that some of the bands are shifted and that in several cases double bande occur instead of a single band, or even several bands which do not occur in pyrrole. Already at a f:.rst sight a close relationship between the individual bands and the structure of the molecule can be observed (Table 3). There are 3 tables ifid 2 references, 1 of which is Soviet. ASSOCIATION: Leni.ngradskiy gosudarstvennyy universitet (Leningrad State University) SUBMITTED: Jul3- 4, 1958 Card 2/2 5 - 3400, 5 - 36 30 SO" 'A AUTHORSi Per:eye-v, F.. K. TITLE: Reaction of' Hidro~ren Ph)sphide WI.th Acetylenic a -0.,-,ides PERIODICALt Zliurnal obshchey khIml.1, 1950, Vol 30, Nr 3, PI) ';-4- 789 (USSR) ABSTRAM Acetylunile ox'.des (I)-(IV) in reaction with phosphine gave new acet:rlenlc hydroxyphosphines. 2-methyl-1, 3--ePoXY-3-o.-:tYne (I) stirred for BO hr with NaPh2gave I-pl)ospiiinyl-2-inc-thyl-2-hydroxy2-3- 0 0 oct.~ne (V, yiEld 73%, bp 64-65 C at 0.5 mm; r1 1.4948, D d20 0.9360). Similarly, 2-methyl-1,2-epoxy-3-pentyne 4 (II) ~;ave in 46 hr 1-plic-sphinyl-2-methyl-2-hy ~Bo -51C) C at 1 mm, 1.506.3, pen--,y,ie (V!, yield 73% IP 50 11D 20 dij 0.9,980). The ahov~.~ pho,,3phlnes were mobile liquld!3 with the characteristi., phosphine odor; they were 4 readily soluble in metnanol, ethyl acetate, F-chyl ether, rd 1/ but were insoluble in water. Reaction of Hydr-o;::F-. Phosphide lviltl~ c Acetylenic a -oy,,-- 7, (Ak -"8 1 25 9 sov//~7 (11) C113 Carcl 2/4 17 J .) Reaction of Jiydrojre~n Ac ety I e nic GL-Ox:-d,'3 me' x -d Y wi'h NaPHI, the react'Lon product polymerized cmpletely. ',,-Ilietliyl--I,'~-opoxypeilt(itte (III) 1~,, ---0 1,41, stIrrIng oilly trace3 of hydroxy-penty--, photph'-ne. !R sp-~ctra of the nydroxv- phcsphine5 taken ~.~;ith IKS-11 spectr3graph showed 'lie characteristic, freq,,~eric,~ of the P-H bond C.1r, Dehydration of' V arid VI with die thylethylenediam-'n~ gave products with 1bp 1400 C (1 mT,) and -,780 C ( 0 mm. respectively; the str,--c-.,ire, according to thelr eleme-~,,-al compcsition, ~~p--~ctral aria ly.-31 -9, a~A Oc ~,d corr.--9pund to the Card 3/4 Reaction of HydroFe,-, Pt,c),gplilde 141-1,h Acetylenic CL -Oxid(--~o ASSOCIATIONi SUBIKITTED: (83259 Tnere are 3 table2; anc r-~ferencess, I ~;.S., '-~.K., 3 Ger.iian, 4 Soviet. TI e U. S and U.K. referen~:es are: H. Beachell, B. Katalaf3lly, J. Ch-jTi. Phys, 27 1.82 Ro b er t.,3on, Fox J. Chem. Soc., 120, (1957); (',)26) . Leningrad State Uni,,,,ersity (Leningradskiy gos idarst---ennyy univers'-tet) JulY 6, 1959 Card 11/4 Ma.; K.G.; N.V. nt~-ractio:, of QK-oYldes f-,f the a~-etylene 5er't-s j-'t~ pot,aasiain cyatl-,Ae. Part 2. 20, r,0-2"- 1--~--1.49 16%. RAZUVAYEV, G.A.; STEPOVIK, L.P.; I!WIEM, F. Ya.; DEMIDOVA, V.M.; ALANIYA, V.P.; SOKOLOV, N.A.; KHAR,HINKO, V.G.; KRUPINA, T.I.; KLIMBIKO, S.K.; RASSUDOVA, A.A.; GDRELIK, M.V. Letters to the editors. Zhur. org. khim. 1 no. 12t2244-2246 D 165 (MIRA 19:1) 1. Nauchno-issledovatellskiy institut khimii pri Gorlkovskom gosudarstvennom universitete (for Razuvayev, Stepovik). 2. Le- ningradakiy gosudarstvennyy universitet (for Ferveyev, Denidova). 3. Moskovskly institut neftekhimicheekoy i gazovoy promysh- lennosti imeni Oubkina (for Alaniya, Sokolor). 4. Saratovskiy politekhnicheskiy institut (for Kharchenko, Krupina, Klimenko, Rassudova). PEIMLEV, F.Ya.; VOYTOV, A.P. Interaction ofcC-oxidea of the acetylenic and vinylacety:enlc serieB with nucleophilic reuRentD, Part 1. Zhur.org.khim, I no*2:226-229 F 165, (MIRA 1834) 1. Loningradskly gosudarstvennyy universitet. ~ i .. k . ~ . I ., . .- - - . ~ - I- . I - . . I I 'I- C-. - - . I n~ : -. ..I I. . . I . I . . . . PFRVFY7rV, F,Yq,. Rea 2t r~- S., :~Tqa7~CF 1 primary !inn !!w.*t-,wFiry n I , p .rc- rif* I., i'. ii'.; V. yfl. .". i'YEN ) - Dioxi,,----3 C-f a~C-*.7~t,.%iC SC-r~E:I. L.. ,,ur. ot). 34 no. t *. i'i ~l 1, - 1'/ 3', .'e I , . . .3 n ~ !, 'L, -( , v g ,osudarqtvt-rtriyy univ(!r,,iitE,L. GOLODOVA, K.G. Oxynitriles and nitriles of the ace-tylenic series. Part 1. Zhur. ob.khim. 32 m.7:2092.-2095 JIL 162. (MBA 15:7) 1. laningradskiy gosudarstvennyy wAversitet. (Nitrilen) MINGEYEV. F.Ya.,i SIATSEVIGH, V..Yu,, I Dthyd.roxides of ibp- acetylera., iw-ies. Pa-r-% 3. Zimr,ct,k-hi . - 3-1 662~ (Kru I r ~ -7 1. LeaizX.-,-wl.-Iuy Losudaxet,,eruzyy ia~,Yersltot. (qplroxy -owjx.-and5) ~ketylene compoiwds) PERVEYEV, F.Ya.; DEVIDOVA, V.M. Interaction between OC-oxides of the acetylenic series ~Lnd alcyl- and dialkylamines., Part 1. Zhur. ob khim. 32 no.l: 1.17-121 Ja 162. (MIRA 15:2) 1. Leningradskiy gosudarstvennyy tniversitet. (Acetylene compounds) (Amines) MUM, F.Ya.; DDLEDOVA, V.M. Interaction between oC--oxides of the acetylenic series and a-Uylamine and diallylamine. Part 2. Zhur. ob. khim. 32 no.l-.121-126 Ja 162. (MIRA 15:2) 1. Leningradakiy gosudarstvannyy univeraitet. (Acetylene compounds) (Amines) IRMEY, F.Ya.; YMHDVA, V. ~ 77 Reactions of hydrazine hydrate and dimet4lbydrazine withinme oxides of the acetylene series. Zhur. ob. kbim. 30 no.11: 3554-3558 N'60- (MIRA 13:11) 1. Loningradakiy gosudarstven-urr universitet. (Hydrazine) (Pyrrole) (Acatylene compounds) PERVIUEV, V.Ya.; STATSEVICH, T.Ya. Dioxides of the acetylene series. Part 2. Zhur. ob. khir-. 30 no.11:3558,-3561 W160. (JIVU 13: 11) 1. Leningradakiy goeudaretvemly)r universitet. (Acetylene compoundo)