SCIENTIFIC ABSTRACT PAVLYCHENKO, A.D. - PAVLYUCHENKO, M.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001239720004-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

'r
PAVLTCHE SAFRONOV, G.D.; GDNODUSHNOV, A.V.; PROTASOVP
- -W
A.I.; GOLOBOKIY, I.R_j GRUNICHEV, A.S., kand. tekhn. nauk,
red.; ALEKSANDFCVA, A-A., rod j EELYAYEVA, V.V., tekhn.red,
(Reliability of radioelectronic apparatus] Nadezhnost' radic-
elek-tronnoi epparatury. Moskva, !zd-vo "Sovetskoe radio,"
1963. 143 p. (MIRA 16:11)
(Radio Industry--Quality contrcl)

,-__PAVLYUCHMO, A.Pj inzh.; KHOMUCHEV, I.G., int.
Pulsation of blast furnace air preheaters.
Ja 162.
1. Yuvenergoahermat.
Stall 22 no.1:13-15
(MIRA 14:12)
(Air preheaters)

- - PAVLYUq!IkNK-O,-DA,-
Manifestation of rock pressure in long-walls in narrow-range
mining of coals. Fiz.-mekh.svois.,dav.i razr.gor.porod no.lz
188-202 162. (FaRA 160)
(Rock pressure) (Coal minon and mining)

PAVLYUCHENKO, D.N.f kand.tekhn.nauk
nFerrogum" magnetic belt nopfirator. Gor.zhur. no.12:63..64 D
163. (MIRA 17:3)
1. Vsesoyuznyy ob"yedineniye pn importu mashin Millisterstva
vneshney torgovli SSSR.

PAVLYUCHENKO, D. N.
Cand Tech Sci - (diss) "Study of bracings of cleaned stopes in
in narrow-gripping coal extraction." Moscow, 1961. 20 pp;
(Ministry of Higher and Secondary Specialist Education RSFSR,
Moscow Mining Inst imeni I. V. Stalin); 200 copies; price not
given; (KL, 10-61 sup, 217)

PANOV. Andrey DwitrtYOvich, kand. teklin. nauk,; TISHCHIWKO. Nikolay
AzAreyevich,; ZUffATIIIN, Ivan Stepanovich,; SHAVRINA, Rates
Fedorovna,; FAUTUCMNKO, P*itrly Hikolayevich,: GRIGORIYEV.
Vladimir Loonidovich,; pri uchastii:Adamidze, D.I.; Krasnikova,
Tu. D.; Cherkeshaninova, V.I.; Chu6yeveyYe. T. ; SOSNOV.
V.D., otv. red.; RATNIKOVA, A.P., red. izd-ve.; PROZOROVSKAYA,
V.L.. tekhn. red.
[Narrow-gauge mining of coal in thin and medium Beams] Uzkozakhvatreia
vyemko uglia na plastalch toakikh i srednei moshchnosti. Moskva,
1;gletel~hizdat. 1958. 321 p. (MIRA 11.12)
(Coal mines and mining)

- PAVLTUCHESK D-.N.; ZATTSIV, A.D.
Practice of roof control in longvalls mined vith coal plovs.
Ugol' 35 no. 12:16-21 D 160. (MIRA 14:1)
(Donets Basin-Kine timberiog) (Coal mines and mining)

SAKHOVAUR, G.G.; SUYNTIR, G.G.; SIRIN, G.Ye., redaktor; PAVLYUCHEDMD,
,D.N', redaktor; KDRDVENOTA, Z.A., tokhnichookiy 7~6~, Ce. - .1 ~ ~~
[Metal supports used in foreign mines; a collection of reportej
Metallicheskata shakhtnaia krepI za rubashow; obornik referatov.
Soot. A.IU.Sakhovaler, G.G.Suatin, Moskva, UgletekhIsd4t, 1956.
165 p. (Mine timbering) (HLRA 9:6)

SHPRUT. F.[Spruth. F.1; SIRIN , G.Ye.Ctranslatorl; -PAVLYUCHENKO, D.N.
Ctranslatorl; ULIHICH , F.P.C translator]; ?ANDY, A--U--,IWn-dTM
tekhnichaskM nauk, redaktor; DMITRIYEVA, L.H.,redaktor
izdatelletva; ALADOVA. Ye.l.,tekhnicheekly redaktor
[Hotel supports in second mining. Translated from the German]
Ketalliehbskoe kreplenie oshistny'rh vyrabotok. Perevod a
nemetskogo-G.R. Sirina. D.H. Pavliuchenko. F.R. Ulinicha.
Pod red. A.D. Panova. Moskva, Ugletekhizdat. 1956. 335 p.
(KLRA 10:4)
(Mine timbering)

I-M!PY~UCRW-Q. a vich; 2MOT, T.T.. otv.red.; SUXMNBA.
N.D., tekhn.red.
[Supporte in coal-mino stopes) Krep' ochistnykh zaboev
ugollnykh shakht. Moskva, Goe.nauchno-teklm.izd-vo, lit-ry po
gornom delu, 1960. 135 p.
(Kuu 14:3)
(Mine timbering)
(Coal mines and mining-Nquipicent and uupplies)

PAVL~CIITIIKO, F. 4.
Krasnoderemye raboty. Wobreno kachestve uchebn. Fosoblia dlia khudozh. remeslenn;-kh
uchili5hch. Moskva, Vsc-r,. uchebno-pedapop. izd-va, 17-,4?. 17) P. ii~us.
Cabinet work machinery.
DLC: TT19?.P3
SO: Manufacturing and Mechanical Engineering in the Soviet Union, Library of Congress,
1953.

L 2_598o_66 arr (1) In, d ow
[,-A C Nks AT601U53 SOURCE CODE: UR/253176670-6-071-68/0045/0050-
AUTHOR:', Pavljuchenkov, G. F.
ORG: Main Ceopby sical Observ~j~ (Glaviiays geofizicheskaya observatoriy .a)
A sounding ion counter
SOURCE: Leningrad. Glavnaya geofizicheskaya observatorlya. Trudy, no. 188, 1966,
Atmoofernoye elektrichestvo (Atmospheric electricity), 45-50
TOPIC TAGS: sounding ion counter, ion concentration, radiosounding modulator,
dynamic capacity transformer
ABSTRACT: A soundinA ion counter was built for measurin atural ion concentrations
with positive and negative polarities in free atmosphere%nder a cloudless sky. The
Ion counter is connected with a radiosounding modulator-transmitter and the measure-
ments are received by special instruments. The sounding counter contains a trans-
mitter, a dynamic capacity transformer, an.over-amplifier, an amplifier, a rectifier
with a filter, a time relay, a trigger, a multivibrator, and a feeding battery. The
ion concentration is measured by the aspiration method. The air taken for investi-
gation is blown through the measuring cylinder, which contains a transmitter. The
instrument operates by the charge method: ions of one polarity deliver their charges
to the inner electrode and change the potential of the inner system. ne polari- zz-
zation effect Is eliminatdd by screening the Insulator of the inner electrode from
Card 1/2

L 25980-66
-ACC NR, AT6014853
the electric field of the measuring condenser. A detailed descriptlon of the
instrument is given. The Instrument is fed by batteries of various voltages. lonien
the feeding batteries are switched on, the air for investigation is blown through the
measuring condenser. The,.potential of the Inner electrode Increases, receiving the
ionic charge. The slowly changing voltage is transformed by the dynamic capacity
transformer into alternating voltage intensified by amplifiers. The instrument
system of the ion counter is connected witl i the modulator-transmitter by donductors.
..The instrument is standardized before operation. The threshold potential is
determine'd by a frequency counter during operation.. Orig. art. has: 2 figures and
I formulr- [EGI
SUB.CODE,..,o4/ supm DATE.-, none/ ATD PRESS.,
Card 2/2

L ASV- ~P94/?a4/N4 RWW
4CCIMCK WEI JP300YM2 8/0190/63/005/CC7/0960/0965"
11YTEORSt On CWa, T, T PavO~yucbenlw 0. Mirestnev, V. A.; -XTIL71 IN. A.
Tl,= 3 3xm'volecular corpotm-do'by polymers at bigh terperatures
:SCUC23. Vy*sokvwjeku1yarnyAye. voyedinaniyap ve 5- 7.9 1963P 960-965
i T TWIC TAGS 3 sorytion., po3yner pOvolef in,-
An iiqvoved -9 cabstrueted-lo d' isrsdMe the-_vDrpAcn of
i-ABSTRACTi apmatup WA
e0ane 07, ana,of
etITIen lat 75-200C n-�oatane tylenalt 25-1150.
The apparatus vis entirely glvusB-sealed and peiRtted-Tihe recording of taimerature,
1pressure, and weight of the po%m2efln samples. Isotherms Of sorption at -various
!temperatures were charted,, and it, was found that the sorption capacitY of PD17_
etIVIens Increases vi tb. tenperature, reachizZ a mmdrum a 1300., the melting point
t
~for this crystailline polymer. In.polybutylens on the other hand the sorption
capacity decreases from 250 to 60C. From t1vre on it r1ages up'to Its melting
ipoimt. The conclusions drimn from the obtaired revalts point to a higher flexi-
bility in -the pol7butylene tacroimlemaoa as compared vd-tb pol7etb7lsne~ -trUch WT
pbe due -to a shorter carbon chain and a greater branching put of polybutylene. Orlg~
art. bass 4 charts.
CIATION: ftysico-Chenical Institute
1/0 t

S10201621147100110201022
B101/B144
AUTHORS: Pa-~ ~ucn~n-~o, G. M., Gatovakaya, T. V., Kargin, V. A.,
A-ciademician
TITLE: Estimate of the chain flexibility of polybutylene on the
basis of sorption data
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 147, no. 1, 1962, 150 - 152
TEXT: The isotherms for the sorption of n-octane by polybutyl ne with the
intrinsic viscosity 1.14 at 90 C in Dekalin, 0m.p. 94 .5 - 104.8 C, were
determined with a sprina balance at 50 - 115 - he isotherms for 94,
104 and 115 0C coincided%ithin the limits of ex Berimental error. Up to a
relative pressure p/p s of the adsorbate, the 50 C isotherm was higher. than
the 600C isotherm, which is explained by looser packing of the chains at
500C. The 850(3 isotherm intersects the 94 0C isotherm at p/ps~-0-7 and
if the 75 0C isotherm is extrapolated this too intersects the 94 0C isotherm.
Hence, capillary condensation is assumed near the melting point, caused by
the formation of higher ordered structures and of spaces betmeen them. An
estimate of the capillary diameter according to Kelvin gives 100 - 1000
Card 1/2

S10201621147100110201022
Estimate of the chain flexib'lity ... B101/B144
which io in a (Yreemen t th the order of magni tude of the fj truc ture
formations and pores foun(i earlier (DAIN, 146, no. 2(1962)) by electron
microscopy. A calculation of the thermodynamic segment characterizing the
chain flexibility gives a length of 60 carbon atoms. Since, however,
polybutylene ccntains lateral ethyl. groups, the segment of the main chain is
aesujo,1 to have a lenl7th oil only 50 carbon atoms which is consistent with
the leneth of typical rubber segments. There i a 1 f igure.
ASSOCIATION: FizIko-K*,-417Ticheskiy inst~-tut im. L. Ya. Karpova (Physico-
chemical institute imeni L. Ya. Karpov)
SUBMITTED; June 2), 1)62
Card 2/2

GATCVSKi,YJ~, T.V.; G.1-:.; , V.A.
Sorption o. low molecular cc) pound3 by polymera at high tomIx-n-a-
tw-es. Vrokori.so-d. 5 mo.'1:960-965 31 163. 16:9)
1. institut imeni Karpova.
(i,olyinars) (Sorption)

FOLY-U-C-H-EK-KO, -G-*H-; GATOVSKkYA, T.V.; KARGIN, V.A., akademik
Evaluation of the flexibility of polybutylene chains
based on zorption data. Dokl. AN SSSR 147 no.1:15(~-152
N 162. (MIRA 15:11)
1. Fiziko-khimicheskiy institut im. L.Ya. Karpovs,
(Butane) (Polymers) (Sorption)

GATOVSKAYA, T.V.; PAVLYUCIIENKC), G.M.1 BERESrNEV, V.A.; KARGIN, V.A.,akademik
Evaluation of the flexibility of polyethylene chains fro= sorption
data. Dokl. AN &SM 143 no.3:590-591 Yr 62. (MIRA 15:3)
1. Fiziko-khimicheskiy institut im. L.Ya.Karpova.
(Pol,vethylens)

LIPATOV, Tu.S.; PATLYUCHMO, G.R.-
Folywr filler interaction. Part 1t Change in the properties of some
polymers attached to a Slass surface.Tysokom. soed. 2 no,,IOsI.564-i568
o 16o. (MIRA 13:9)
1. Inetitut obahchey I neorganichaskoy khivdi AN BSSR.
(Polymers) (Glass)

S/020/6"/143/003/016/029
B110/B138
AUTHORS: Gatovskaya, T. V., Vqvlyuchenkoj G, M,, Bereatnev, V. A., and
Kargin, V. A., Academician
TITLE: Assessing the flexibility of polyethylene chains from the sorp-
tion values *
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 143, no. 3, 1962, 500 - 501
TEXT: The chains in crystalline polymers must be flexible for good
ordering and crystal lattice formation. The sorption values at room templer-
ature can be used to find the flexibility of amorphous molecules, but they
must be determined during melting, when no crystalline ranges are present.
Another method must therefore be found. The sorption properties of poly-
ethylene were ascertained within a wide temperature range and below the
melting temperature of its crystals. The melting point of a regular poly-
ethylene specimen with molecular weight of about one million waB determined
on a polarization microscope. The spherolitee disappear at 131-1360C and
drops appear at 1640C. The sorption isotherms were obtained by using
spring weights in an air thermostat. Sorption gradually Increases between
Card 1/3

51020
./62/143/003/()16/029
Assessing the flexibility BI-IO/DI38
75 and 1300 C. The sorption isotherms for 140, 150 and 200 0C coincide with
the 1300C one. This means that sorption reached maximum at the melting
point of the spherolites. The merging of the 1250C sorption isotherm with
the 1300C one at about 60~-' relative vapor pressure, is probably due to the
plastifying effect of n-dodecane, causing the polymer to melt at low
temperature. The size of the thermodynamic segment was calculated to find
flexibility. The graph showing the size of the thermodynamic segment as
a function of relative vapor pressure of n-dodecane at various temperatures
shows that the presence of a low-molecular compound does affect it. It was
therefore necessary to extrapolate to the zero content of the adsorbate.
At 750C the segment consists of about 600 carbon atoms. A temperature rise
increases the flexibility of the chains, and the possibility of realizing
a large number of conformations. On melting, chain flexibility rises
steeply and all conformations are realized. In this Case the minimum
segment value of 60 carbon atoms is only five times higher than the length
of the adsorbate molecules. This appears to be the optimum flexibility for
crystal formation. Rubbers and rubberlike polymers with highly flexible
chains with 20-40 carbon atoms in the segment show poor crystallizability
owing to the great difference between the entropies of the crystalline and
amorpho a state. There are 3 figures.
Card 2 3

S/020/62/143/003/016/029
Assessing the flexibility ... B110/B138
ASSOCIATION: Fiziko-khimicheakiy inatitut im. L. Ya. Karpova (Physico-
Chemical Institute imeni L. Ya. Karpov)
SUBMITTED: December 19j 1961
Card 3/3

!~-11517-66 EWT(;n) /-Ewp(j) rim
ACC Hlb AP600ION SDURGE CODEi Ui~~ Q96DV612fil3~12IF4
AWMRSI N V.;
bikuchankos 0. No; Gatovokaya,I Kargin, V. A
,p
ORD: "icD.Ghenlcal Institute in. L. Tae Xarpow (Fisiko-kbinicheskiy institut)
7
TiMs Influence of the cbprjkcte5 of mperaDlecular structures on sorption properties
PAMS,
of, isotactic p 1mr-D J%kAV;
SOMBs VyxdkM19ku1yanW9 soyedineniyas Y. 7,9 no. .129 1965,p 2139-21h1
TOPIC TAUSs adsorptionj, sorption., spherulits, polywerp polypropylene plastic., ootanj
ABSTUCT: The effect of supermlecular structure (different sise, of spherulites) on
the'sorptive p"parti" of isotactic, polypropylene was studiede The sorption of
mtW:&1cdb61j n-octme.9 and n4W*cww on two different specivans of polypropylene
was invostipted. The "clams consisted of spharolites of 3OD-3501L and 20--30,&L
In diawtw reapectively, The sorption of awthanol and n-votme was determined at '25Gj
and.that of a-dodows In the rogion of 200-20W,'~ The results are presented
gr&Pbk&W (MISS F149- I)* It is ougg"ted that the adsorption effect depends mainly
on ths vphwuU~tk also and occurs only oA the outw surtwes of the lattwo

PAVLYUCIIHNKO, I.A.,kandidat maditainskikh nauk; ALI, S.K.
-------Cl-tni al ~vsrGlhts of lanbliasis. Klin. med. 35 no.2:76-80
F '57 (MLRA 10:4)
(LAMBLIASIS
clin. varianto)

AVLYUCHYJ;YO. K.
GiVe the IDODUlation better iaformation about air com-minication.
(;rathd.ov. 12 ijo.9-34 S 15~. , YU,.A If) - 7)
(Aercnautics, Commercial)

FEDDRDV, M. ; PAVLYUCHEIMD, K.
,%% ...... ~
Increase the productivit7 of transport flights. Grazhd.av.
13 no.4:28-30 Ap 156. (HIM 917)
(Aeronautics, Commercial)

YEROF-EYEV, B.V.; P"LYUCHENKO, K.V.
Kinetics of the thermal destruction of amylases. Report No.2.
Sbor. nauch. rab. Inst. fiz.-org. khIm. A19 BSSR no. 7:103-109
159. (MIRA 14:4)
(Amylase)

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PAVLYUCHENKO, I.
%,- ~ -,
Unexplaining interprptation. Graz!-,d.av. 20 no.12:2-4 D 'D3.
(KIRA 17:2)
1. Nachallnik 1mtno-shtw-pianskogo ot.dela GrFlzlictanskogo voz;'Juslinogo
flota, Syktyvka-r.

PAVLYUGHENKOp I.A., kand.med.nauk
DiagnosiB and trdatment of chronic mild dissaaes oJ' the biliAZ-7
tract. Sov.med. no.2:57-61 F 161. (MIRA--14-J-35
WMARY TAQI~~ZISFASES)
I

SMIRNOV, N.N.; PAVLUSHENKO, I.S.; ROMANKOV, P.G.
Effect of some factors on thr. rate of ti:e chemJcal r--rac,~ion
during mechanical mixing. Zhur. prikl. khim. 36 no.11:2419-
2425 N 163. (MIRA 17-1)
1. Leningradskiy tekhnologicheskiy institut imeni Lensoveta.

GORDASH, Yu.T.; SHEVCHIK, A.M.; IARY-UTINA, E.A.; PAVLYUCHENKO, K.V.
Group composition of organosulfur compounds in benzene-
keros6ne fractions of Mukhanovsk petroleum. Dokl. AN BSSR
6 no.7t442-444 JI 162. (MIRA 16:8)
1. Institut fizikorrganicheakoy khimii AN BSSR. Predstavleno
akademikom AN BSSR IB.V. Yerofeyevym.
(Sulfur organic compounds)
(Mukhanovsk-Petroleum)

FAVLYUCHENKO, G.M.; GATOVSKAYA, T.V.; KARGIN, V.A.
Evaluation of the flexibility of polypropylene chains and
some features of its sorption characteristie- A+ high tem-
peratures. Vysokom. Boed. 6 no.7tlI90-1192 Jl '64
(MIRA 18:2)
1. FizIko-khimicheBkiy institut Ameni Karpova.

PAVLTI~ 'HFNKr, E. V.
A S s 1-
0 rz Z e C: A.N' F
ru d e 3
g
t i t. ~; t
n e o, k 0 v k
akaderrikom Yerofe.yev-~-,..

8/250/62/006/007/002/002
1032/1242
AUTHORS: Gordash, Yu. T., Shevchik, A.M., Laryutift, B.A.,
Pavlyuchenko, K.V.
TITLE: The groups of sulfur-containing organic compounds in
the benzene-kerosene fractions of Nukhanov oil
PERIODICAL: Akademiya nauk BSSR. Dokladyj v.6v no.7. 1962,
442-444
TEXT: Commercial petroleum from Plukhanov was fractionated In-
to 12 fractions, the highest fraction boiling between 3250 and 3500.
The weight percentages of sulfur contained in mercaptanes (mereaptane
ouffur), sulfides (sulfide sulfur)p disulfides (disulfide sulfur) and
other compounds (remainder sulfur) were determined for each fraction.
'Practions boiling up to 1000 containeA mainly remainder sulfur, where-
as fractions boilUW between 1000 and 2250 contained mainly sulfide
Catd 1/2

3iT(in)/EPF(C
ACCESSION NM -AP4045693, S/0250/64/008/008/052610529
AUTHOR: Pavl.yuchenko K. Vs; Shavchik,,A. M.; Yemellyanov,N# P,
TITLE:- Adworption of -morcaptans and a u rom
f ur. compounde,f
~Iukhanbvo c rude o i I -_gn . 5k and 13X z6oliteel
$OUjkCz-f 'AN - 2ISS jproklaoy -a' n 0 1964 -526-529
ri*i k,-#d'0qrp~.1*nq_ wwrcap* 'an -.-aulf a, .,dt-.
t id
V,
ollite-.
1,04 MLa)#qV#-!evJA'd4~ 0 SA,,.;Z*01 "to -AIX is
AIBST~RAM: A, a tudy -4 a -a' bdatf-made of -the adiorptiOn of-individual
nopma I i p'rkmavy. marcaptass and othtr au-Ifur compoun.do from Mukhanavo-
A
crude_on%.5A;a.nd 13X zoolite'sa Adsor~tlon of-octyl- and nonyl-mer-'
.1 ca:ptanj sulfides, and disiilfides from the 240-360C cut of Mulkhanovo
crude was carried out on the 5A 202-175 and 5A 202-247 zeolLtas at
I 240-350C andion the 13X 202-208 zoolite at 222-1,161C, in a.-istream
Of n.itx_9A4n#, Tho zoolites wara regenerated at 375-380C in a stream.
tom

?* "'Y ~~' -V.f,, ".. . , i.qni. i~ ; , , A.
T4-P.P ! Pr t -*' n tY,-- -,r ~cess o.' O.lr rrim-vR'. : r-!7 cr~k-- *7,, ~ .
F him. pr- :- . Ilk r . I no. 1: 2';--27 Jq4tr 165. . R
2." , ". ~

NlKITIN , G.A.; Prinimali uchastive : - - , , . ".. : !- !Tr, '1'~ j,,'KO, L. .'.
S tu ivLn 7 t'- e f e :--- e n -~,, t -' = ccnl~ t '~ - ::~ ~ - " - a - -- - - - - - - ---zec
sti, p
-age by met,&ne-fcrming Dacter~a for L:-.e ~-
vitamir B 12. Trudy I:krN:ISP no.9:139-144 16,..
---7: Ij

o0660 air 'me 's -:all
'
00 0? 0000000 000000000 $9009090909004
&Pbiod a 41) At
b
sh *Wls
a 0 t 0
001 i
l
09 it 11 ti m 11 06 it is of At a mo
to I
Iij, it - Ike -1 J.-AS - ~11,
i
0 0
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The Otildatirm of Irlds slide by molecular Q) .00

0o 1
brillict
T -00
I'#,- J. Nit 4, '2h) -it 191m, t #w*j 'enip MI, 11, Wit) loo
'it 1.
, A he rate ill otiulatkm ill fesik a, uk 11Y Lh at fitl in-
00 "*- &kmlv. then ineveamrs more still interr ratitilly until ISM. aft" whwh it t~ allowed ill tAnd in a closed t1ask "t. -00
it passes fhtuugh a max., after Which it dectlawt. r1n, the dark fill 1% hm- 11 it then tttl,l with 14111 cr of wAtei -00
00
' pecilkwis of obt reaction have an ar"Irrating effect on the
' and the litterated I is back-titratni with o I ShiTomillitr .00
040 to and the
reaction. IncTresinit the trinp. front A) to 69 In optliff to drt~ the anit. of I addril at The ilmillk bood

040 i I 4 up to 51' (4 vistry vark-r in tbe (1, have im T4_
re=
4
11
t
b
h
t
k
d
h file KI-Ifeso. mill I. pert"I stut miltme'l 1" .1atut 9 h?% moo

j! .1
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e "%few .
T
e mit
al
W ari
r" i
I
e
1l'
t
l
l
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l th
il
th
l jum as above. but 15 cv of an sit, 1 kiln. is added almr,
ZOO
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int
m
nlanrr &y%
at il
e vi
triairli
j,
3
ss
e with the 100 " of wafer anif the w4n. ii Imck-tittate,11 C

000 %slor: the stlit. of I which the mat-ml will ad.1 1. fe. after 7-14 min A mninill muo Ile run
. ilm-ed to about half after the mulAtion, The
h which I% dild. univ with seat" after the m lirs. standinif
ISO J1 A. 1xvii
m gffar"~ at, 1.1oli'les. The nlrtN.1 Finally. OAA g tif the (milit"I material is ilt-Avett in ~41
, livifocil for the dirin of thc it IS C .4 1 he m*. sit-. treat"# with W tv (it an sic I %Jn
and 1(k) - too
imodiml inat "tat is distilml In '.N I N- Ale. and lreaat~l Willi .
water And litrattil With hvpteulfite after 7 N inin Th,- Poo
10 cv. of an %Ill. 0 2 N K11 -kiln. anti 11 (it. amt. of I consummi in each me is sub,litulvil Into tht-
goo
t
a
a I a, S L a 14TAL _UKKAL UTIffitilliftl
8L
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a No is 0 it a at a ci 19 U 09 Of It to 0I
gooosooo*Oo*Oooooeeoo0*0000006000000
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t :
proper formU13, the evaluation of which indicates that :.1
if.-equivi. of I am liberated in the oxidatinit of I ii-mot ::* 0
r4 the perox0m M G mcsitr
see
XOO
we 0
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coo
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41
life ZVOLMINK see 440 410 agates F. gnaws
NMAvvdmtwm wavagul lv3"4"llT&w q I IQ a v
00
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to M." 00
maa$mmm sunk m Sdmn Man If 11" w" 0 r 00
Fee
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a 0 o4p 0 0 Odra it

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oiddation 91 &Yampa by &-it a y 24. 1. V.
!
r
% -0.9
io'll," IV ,
kwnk J. Phys. C". (U. S
b -00
tA ibr oxwlaii.xi o1 bydroSen by 0
41twis profluvel by UTMAIMI" ul thr ll.-OT Inill. of it-ill
IstrPaisfra 44 0.01 141 0.10 Mill. No% ItAkOWN) ruJiMbIlk'111,
ondjtw traik& air OaWWW slid I"Ird. 1'.'w
:~J
If
l
i
l
i so*
-
t
km
l
t 0 atoms
ll a quoits ov u
. by tnetasta
vered-quaits teactim vrowl is a volulut rtwtioa; (be
Owtv of acti"we is wo from - 183 to 0'. the effectivv.
tK,&I of W-(Jig ittid of Ot-fil cullisksils fol tit'selivatioil and
00 '%kistion. texl,.. 6s the savile lusplatinumvcootlaudam
:
atalyas also takes ptax. Me tate ol trortson with 11,
00
00 ,givem by v - v, X 1.7(tisli(Ithl ~- 1.7111.1) wbTic P, is
00 a F.
the total ratc of dvappewsom of 0 atoms.
if: R. a**
.
.
zoo

t 1
'00
b00

MD Ali Is 003 a.. 4-4
i It V
a N " U ts it IS 81"p, cla ip%. Sol too
will 0 9 1 W a 9 a a 31 0
W A I I WA
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Ole 0 9 0 0 0 * 9 * 0 9 * 0 * 0 a

but
a c- t U-4 4 0 pu a
ell
low
IV If am a of If a a 41 a o (A a
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a"Iplivj aqi III po&3oi
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4
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chtaka.
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abw
:
Ca iba bwMabry betwem tow a" fbypd

it 0. The abwrp" WKUM Of to*
6on bbm tug tbwe is lowmtd " =UWnwwe 9
coos
Good A%. Thm appamme cl 2 tum. as 010 bowWk CWMI is
ZOO
dut4atba 0jol A+%-A0aMWA0S_t.!k-A1D~
h
J zoo

sod t
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J~atafffi*ft
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1
r

n ewthtu.W.
13.IIX)cjw q,
Tbr 4&mwt b dw to too 6damnambUamm
IL o
goo
Po &be Cr"Ma Imtka.

MOTAUMM" MORMON MUMPKATION
avvesAva
no*
rpm 40okav
0 AF ID ali ; i, i, i v a 9 a a 3 0
on we as

..v -

am"161110 d roww wd I stamps by
-uc ko and V. M. Auk
%icb.- I Alf". X46
'.1's.R. IOU. N.. 4.
103-18.-Tbt citu. o1 tosin from rakhW tnt slump% that
had been Wt in the ground for several rem after caltins 4
the pin in". as Well as the low.", of turpentine valu"
Innn such worm. lots examd. 71w drp" OW rate of
exim. by CJCIIsCIW am much lpealer than in the cam of
exts. with swoune. In eats. done an chips of the slumps
the rate of asta. is invast17 pvponi" to the dimensions
,J The chips mood; tbm were of cubical shapr Me ton"
readycosupwipon. T1w wasintion can for readily av%~mntrd
fos by lbe usual eoaA&s*t6ow of esta. pnwews am) the
ctsecurnst diNsWoo 4 the ratrarlant Isom the intreim ni
thewaDd. by repeated Cato. It is PLUS" torlit. ove? 90%
I Use loud '-s Content of the - . CO, is a lets
effseti" MIMI and appears to be more etwrotive to equip-
ment than CICIIsCII.Cl. G. M. KowUpoff

- v I I
.- 1. 1 1
i. . .. . - -
-1 : - I - :
. . - I
I )
? 1. -.

olaidators salt pinaze anti all cairnif by mol"utar v3yarn
%I I*Ai,il,10-11,11 .Ipl M No /hoop
1*T,,JW Kilim ! I At plled ( )trial i ill, IPA 7.1(IUIMJ
IT, .4141 asmfif -I-q pf'smuls, rA (h - "'Islullil fig, *lilt
" I.I. a Intont. it :1!", tile file r 14 d"ll"I ... i4im 4 th
,nrrea~d with lizaase. r x.. 4. M. 12% IN his., r - it 1.',,
,I Z2. 0 2A. 11.34 ant fir If the run is interrupted. the
IF I'victlAted, MITI IIIV clill fa~lllliesl. t 29-1111 5"It" 91
A
J--I. 1.1 all, -ne ...1. -4, I'm C.Off
11,0 .,,1 .... lt.d .,I llj~ .1a.1, .1-Mg
[h, 1,1 4 -S lit- , 1--,- litt-rah -, . 11 .... m-'te - , ,
ill, -me 1, I-T-l "I.vn tile Il't) kri-I
Immt it,, rim klitkdAlm, 4 Calartil 1,
]TV N. lWill, %1r1. h; ... g"1 .,I fast kI.
1-,I. PI.C11.4 111. 1.1., -11. 1. 1'% p
.11. 1 It I I,. 4L*.I 1. a 111 I'll, N I I i hIdA list, .4
tl-lgly lith.1,11 L~t ),I I S.
And
'Ilk list Ill. alth-Ch the litter 11- have hardly ,n%
c1l"t - vare". ITT ill, caw If Istri'lle. IT lit I; I'laciffoll
or C(J,11~, 'I-il d-,. the raractm 15 20 timm. After
.. ~3 lif mIrTfialititin, alit mme eflects are observed nil
1-11till.1-ti TunwritaTir oal with tC(Mf..
p C.11. 011). I"Imill.] etAticlem 3-4 nimilts in last
ItL. Isilt Isecaule Yell-, F,,w-inx to Oxidation, in the at,
,ce c4 as% anti--ittilarit. The effect of antiOllillAnt,
I,f,)%r, tile TeAvllml qakr~ I'lace ill the tiqukl. not IT)
t1ts pb..~ ITT tile ple~encr if the AT
:11 ell'-frv I.* tIIV n1l.tAtioll so pitlelle 1% WIN,
..T.-I Its "Alith -I-l all . ..... . I efle"j" ccFIII ......
tile g,- ph-- -suld 1, mu" the so. of m,,I.
r,- it te-1. 7 J X 1104 lit , N ~- ; herk-e. a rewtion IT,
11ii g- pla.- w-mald rc,lairat .. c.jnm,Irt4bIV Inallirf
t.-I . ..... all. . ...... ..pir"Ov. (tic tram'sal take. Illin
the J-h- ...Iv I ".let Ornit-I c-milljoll'.
.1 -.1- is'.1 if Ihe 11(juli, r With
I Aura .4 ,, Tic. c till 11.3. 1 1 it, "fid Visa It
- 11 U, 24. anti Lhi thar other
It '11d. TIT,. I-Trame of I " Ith Increasing Surface area cif tile
I. stanch O-er Ostm-quently. able reaction takc.,
1-1 tit- Ivith at tile interf.ocar ITO in the Itulk III the liquid.
lilt imr, so 44 r will, mfi--g it: I- ... 4tv t4 it; alit fe-i
11-Y the d,ttA Form Aint ld t Ifent, Pf-sA[ft 14 Alf I-
a'-'. A,,,] 'ON) Trans flat. r 1, -111Z. -1 IJ' ant h,
k [tic ple-n- Tit '1-i9 c a I, 'I'W'.
F-1:1. 'J if,, I ..........
% 1-
1, ., -1 '['l, 1-41--
---- "t I ..Ill 1. .... t% -its A .1. .K,,&tmK .,-l
,,after "I cm-.'r. III,-
a
6v the Innic A - V. A' a 1,
-%I At A -- A, 1. A A, )I - At 1 1. A
At I - . As I - ~ A A 1. 1-1 A - - - A,
as .11 ... 1 -4 A- IF pf, ............ it, it ill,
.1arl, " I to.- lakc pl-I
I" tile I"I'lld I'lle lotal I it- 1, 1 tic out of rate,. I -
is "+- M.-I , .11"c " - I- of ~ late M.6 " - lr,,gtlF
-4, A"ml, I .'.I '.' I" tile J,vnali"
ldlt~ 1-till4ify I alit IAIILI reirt"ll,
lit the lita-wzicr T4 mhthii-,F~, ll:~*%- I, -ir inalle st sait
I- ", 11 all, t~ , i-L pl-, --h it th~ plia-
lxmti(ImV. the no. 44 Cl1VVtj%C (t)JIF"Oll. of Lh with surli,,
(,1.45 941. can , would tic I h X PO mv whereas the Fit,
is. 7.21 )k W` mil, -- in other woard,.
-tr hAl .,f tile ..,-ti%atv,I iit,,I% ite dcactlv.tt~i IDY the
Tile vfh%-tivrnr- J Anil, of inhibil.ts,
-cr tcri-k Tit 1 .... c -..1,i ... di-le th,,t it.,,
VILIM- life en'TeY Chat- 11n, ., Nwnc -I try it,, ot,
U-rvatlull Itim I'lliene a ... I Calcite to Willd) VFFIC Tf 1!1,.r
pr-plut-t% li.,%c I~F-u -Wril unilctg~- turih"
... .bti .... ... I illmumati-mi with A If& % I-i Ump
11 11 lit v-1.1, I.gliti. the al-- d ,.,h
pt-Olut, tile
I am[ 1, 141'. .1 lilt kligqb flit -,Tnjal~l
VVI.ll-llllV l1FIWi:1 1111 N I IT.
UWAI- I -.I,+-.

go W Wow
0
z's A.

&boom d say emblylk
boo d
an its Ibm "MOVI p0bic 11 Ibr rtartion mult ffm
1b? ropm amp elms Ow Asymah to tbr COW.
tbr am ef Ow 11=11mwar" Immmrs; this nPIRIP1%
the usual "autmislyfir" amckralk-m cg tractions W
solicts. The 41secry 6 appIkat4p also to reacthm,
=91 01 er"tal edq". In twAb In"nces, stop to s, c4
res"inn Paws thrmth a max.
-
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are a 11 0 It thm). It the rtactim qwmi% Over The mdace
000 mmv ~srdly tban it pmettatto Into ibe crystal, v I% rivas,
1M
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5/081/62/C-00 0 2 C C I,:
B1066/B166
A UTHOHS Kononyuk F. !I.
Radioisotcpe study of the diffusion of sulfur in nickel
PERIOLICkL; Referativayy zturnal. Knimiya, no. 20, 1962, 32, aDStract
2UB209 (In collectiont Geterogen. khim. reaktsii. Minsk,
1961, 251-239)
TEXT: To study the diffusion of sulfur in Ni (electrolytic and commercial
grace mark H-2 (N-2)) the methods of layer stripping and autoradiography
were used. At temperatures of 11000C upwards volume diffusion predominates,
ana at lower temperatures diffusion is found along the grain boundaries.
Tne coefficients of volume and boundary diffusion of sulfur in Ni were
determined for the temperature ranges 1100- .12500C and 800-9500C. The.
greatest mobility of sulfur in Ni is observed at 650-7500C, apparently
associated with the presence in the Ni-S system of an eutectic with a
.melt-ing pcint of 64500. The rate of diffusion of sulfur in commercial-grade
Ni (N-2) is 1-2 orders of magnitude lower than in electrolytic Ni. At nigh
temperatures there is a non-uniform aistribution of sulfur in commercial-
Card 112

SA~81/62/000/020/003/040
iadioisotope stucy of the a;.,'fusion ... B166/B186
grade Si, causea, apFarently, ty tne influence of impurities.
,Abstracter's note: Complete trans.Lation.,
Card 212

C/OFJ 62/000/020/004/040
1166YB186
AJTH6RS: Favlyuchenko, U. Y., Petukh, M. L.
TITLE: Radioisotope study of the diffusion of sulfur in steels,
cast irons ana coDalt
PERIODICALt Referativnyy zhurnal. Khimiya, no. 20, 1962, 33, abstract
20B211 (In coilectiont Geterogen. khim. reaktaii. Minsk,
1961, 249-252)
Ti;XT: Diffusion of sulfur was studied by the methods of layer stripping
and autoraaiography. Sulfur in the diffusion layers in steels and cast
irons is distributed nonuniformly in stiparate inclusionsw such inclusions
being greater in cast irons than in steels . The intense spots on the
autoradiograms correspond to the nonmetallic inclusions which can be.Been
on the specimens through a microscope. In cobalt the sulfur is soncentrated
along the grain boundaries. In pure metals (Ye, Co) the sulfur is
distributed either throughout the metal or along the grain boundaries,
aepending upon the temperature and nature of the metal, whilst in steels
and cast irons it penetrates and is concentrated mainly along the
boundaries of the inclusions. ';.bstracter's notes Complete translation.,'
Card 1/1

!b
POKROVSKIY, I.I.; PAVLYUCHENKO M.M ; SHIWOVI~M, I.Ye.
Diffusion of copper in the sulfide film formed 3n it. Dok I. ,,% VSR
5 no.11:499-502 N 161. (MIRA 1~:I)
1. Belorusskiy gosudarstvennyy universitet Imeni Lenina.
(Copper sulfides) (Diffusion)

PAVLYUCHENFO, M.M.; FILONOV, B.O.
Use of radioactive isotopes for studying salt evaporation in an
a.c. are. Izv. Ali SSSR. Ser. fiz. 26 no.7:878-881 Jl '62.
(MIRA 15:8)
(Radioisotopes) (Salts) (Electric arc)

PAVLYUGjjEjr,fO M. M.
176T25
UM/Chemlstry ftddantm mar 51
"Kinetic 7hvmt4*Jws of the DecomposItIon of Silver
Wde " M M Pavlyuchenko, E. Gurevich, Chair Pbys
Chem,,. Bel;xQsian State U
"Zhur Obshch IMIW' Vol XXI., 110 3, PP 467-473
,Studied0rate of deconpn of Ag2O in temp interval
118-222 . DecmVn vas alvays Mribabmt at tait%l mo-
ment. Ag2O was detd to be amorphous powder with
small ant. of cryst admixt. Activation energy of do-
COMPD: 10-5 kcal. Hg accelerated reaction. Deca*n
must occur through formation of adsorbed atoms of 0
and Ag.
im
17(425

Sri. tj.s~s it c mya. and %, It
!km of tbr awid is W6 . .. bew. Ing.. jqi~
- *9 16*1) -7u
MW kioml- of oxi'l
atudird at 4o SO
ON hn.) TU rewtic, is . . w,
TI,
r"P', 20. 6. 4 13 IS IJZ ns 73%d tlw ;~h an
100' ADd
lboui,ft 8140 St)' - 7, SO'. A
. the fth d'oom
v at the pa " a rnull of lb, .9
Pressure betwelmo 'W0006' IU rate drpra& lioewly an
I of Fmam abd 4W (h
owe, lbb am. tbem bomn~s Wt.
'"8V315 0~ 44xWim
C+AM~__ at 23' 40- &)- W mad go-, The
'p. (cc. ,
11-W3. I -bed. 2.233 low 1 1. of sot): 0. W3,
lkMann"bacti *-W&Ma: tbet
0~ attarb" it" voted odmwptim at - cftff. 01 adaurp-
cgs &bow
or" 10 omJY Oft doub;t* bond ot I . t I
5 mm to d"mr, rwoms"O of me W411. and X I
O~rk is pwt ot . ix the
. "emalle inrw p"dact Thi.
Ocxk4W4iOjv C' &b"" Wid mad Itsiplts of the t
(CA.
Michel Urt

pr
u ss R
V.,ne witel cl told raortion products on Iffig Tilt
o
b
ueltenku
~q-
-C-., 1171'a>f zapfJi BrIgFu3s. 7till
14-11" whim, study;
ME We IUI Vlrid3ti= Of W2~ Ca. arld 1% abktates
It I
un The -urfacts W tbrircry~W%- 31W3 wis n-liievv c . ty:
)y co-rccr)nn. of %noJidized "a oxijizw Mits or by sidda.
'of wd v
an
A -at 70, 60, and 500 and Opreswred 720 min,11g. lfnthe~:
midatio;i purr Nu abictate the Initial rate of rcution 15 ,
0; in all vthrr cw~vs It i~s 0. All r=tioui proe"ded
wiLb nutnacvvTeralon, aud tht kinelk invve3 jt:t--3*-j VITM311 i
a liw,'- The Tmcfion PmAict'. b;4 ki 411 ca.9-S a bindering
rffrtl orl the trite alalytic
I tile 'xkfutW1 01 Na, CCL: alid Mr iitli, raftg iq not 1~~
1u'.. WJ wilit ule catal~tk oction &the E:o:
lid rvaction

7

77
The C~fect of 6 the r AtO Of (OrMit; DU Of tilt AMITI'M CS
-
A
itadmium thloi

of ziAc chlorl
0' zAc c'
l
rn
tjAQ
I

4
M t
dars am. S 'na, Ser, Mim. 1054, No. 20,
d
..
)....
52-9, The r t of the reactions brMccu pscom-l uld
es
*
detd. rrianometrically.. Tui-
C-ic-13 (1) an, nCl, (U):were
d z
fially'the iutt4 & independeut of any othtr gases present:
The We iS SILbS.-qUMtly drceloratcd for I by 11, N. 0, or
alr~ Me tffcct being ifiversely proportion2.1 to the d. u' the
gase-.. The r3teof adda. of the Isi raalc of NJIj per molt: of
l
113 34UIrc,/ruln, in thtabst-wee ofvtbrr gas, 1.58%vith air.
td 0'f3 with H. Whh 11, the rexction Velocity Paw
through a =X~ at abotit 33% salt. Onadda oftlva~ndif-i
ferent ra3cs. the squ. graduilly disapp~.ars and the nandip,
becom--s.zero junler. Thelte inhibl-ing. cfftcts am ascribed,
to the rcdwed coocn~ of NI-11 at solid Interface

4~

V LY u L 1-~
USSR/Physical Chemistry - Kinetics. Combusticn V~~s T-:~pozhemlsi-ry.
Catalysf s, B-,o
Abst Journal: Referat Zhur - Ehimiya, No 19, j956, 61-~~o
Author: Pavlyuchenko, M. M., Shlyk, A. A.
Institution: None
Title: Kinetics of Oxidation of' Powdery Coppe.- 161-'th '-XYge:D
Original
Periodical: Uch. zap. Belorusak. un-ta, 19~4, No 20, 6c)--7()
Abstract: Study of oxidation of powdery Cu.at 1300-160c. At 1300-1500 kinetics
of the i*ction is defined by th)9 equation x 1 kt1/2 where x - depth
of Cu2O layer at the point of time ~; k - velocity constant. At
1750-2600 oxidation of Cu occurs in' 2 stages: during the first 30
seionds 'up to 20-50% of all the Cu are oxidized; thereafter over
several hours -5% Cu,are oxidizf,-d; the kinetIcs BatJsfiea the equa-
UOD X = k, (to t L)1/2 where Lo I B COnUt-al)t. OD IMi-eaue or Po;2
from 14-6 to 700 mm hg the nature of ki:netic curves is Dot changed
but the amount of Cu akidized in the first stage increases. On
Card 1/2

GLAUBERZON, M.Ya.; PAVLYCHFV, I.M.
Pneumatic mail transportation in the Lvov telegraph and telapnone
exchange. Vest. sviazi 25 no.9t16-17 S 165. (MIRA 12~G)
1. Nachallnik LIvovskoy telegrafno-telefonnoy stantaii (for Glau!,~erzon).
2. Glav-nyy Inzh. LIvovskoy telogra-fno-telefcnnoy stantsii (for Pavlychev%

avly VC
i Minetirs of fo-rnutlofi d imc cb1oride
lluvlyuchenko and G. A. Laze-ko (Y. 1. D~nb Wh
7--Ll-jT-Smrrl7n-jv.. "minsk). Zhu
r. F4!* 1. 30,
cf. prect-jing absLr.-Fhe nie of cr-nbination (K~'
of NIT, (r) xaA -.vitb cm-st. ZnClj m-as ob!t-rved ivith a.
llmoomCtyiL W)11,3t IrMp~'. CJD.-10. 41), W, and W. Fxpll.
d-laaml U)tYpsults ufralm. are given3n.9paphs. The
rmalon proceeds in the Idniztic regirn in -he hemp. iiiterval
.0-40'. R)i22.7 e)jnrs a~ great at 0' as at-10. Tbtde-~
crease in . im
'Y is dve to tituraw ln il P- e~ 1=tol ad pilon, f
1. The rmct"on - is pf Q~ii 2nd: orde.; 2 6r. I CL
real
!'V-lnllaneou~ly wilb the solki phase. At rQ 5.1d SO the
rearOor has a d' IS A ti~

-r-USSR cmistry - Aysical cbwAi5trY
Card 3/1 Pub, i47~ 15/26
,j -Authbra I Paviyucb6nkq, H. 14,', and Lazerko,, G. A*
The kinetics of formation of Odr.12 ammoniates
Peiri ca Zhur.- fiz.. 28/1, 102-1089 Jan 3.954~ ...
:'-.4batiact A case Very rare for,chemicA reactionsinamely a reduction in the rate
~of reaction due t.o~increase In tempetature, was established during the
reaction..of formation of WC12.ammoniates. It was.found that the
reaction of formation of CdCI2. ammoniates occurs in the kinetic, diffusion-
kinetic and diffusion zones depending upon the temperature. The conversion-
from the kinetic zone into the zone of diffusion during temperature rises
was found to be connected with the formation of a solid reaction product
iddch hinders the difAmion of ammonia tow~ard the non-reacted sui~face.
.-The constant of the rate of reaction changes in ratio to the amonia pres-
~sure in the first degree* Eighteen references : 11-USM; 4-USP and
34elman _(1923-3.950~). . Graphs; dfa-Ang.
Institution The Ni' enin s
-I.-L -w~eloru s. State University, Mnsk
March 16
Sulmitted 1953

.07 Ike
USSR/tk6zdstry - Physioal,chemist27
3-A Pa.1b: 3.47 16/~6
Authors
FaA~Ucbenko., H. H., and Lazerko, G. A*
Title The kinetics of formation of
ZnC12 ammoniates.
ze Mime g/.1,409-4-15i: Jan 1954.
Abstiact 3 it, ims established experimentally that the reaction leading to the
formation of ZnC1 ammoidates occurs at 0 - 400 C in the kinetic zone.
's c'
-'The Th onstant of t e rate of reaction at a teniperature increase frA= 0 to
410P C. decrease's by 22.7 tim.es. The formation of the amnoniate takee
place during simultaneous reaction of t adsorbed-Ml molecules with
we
the 'molecule of the salt.. The redurtion in the rate of reaction during
temperature increaseo was found,to be the result of redtiction in Am
adsorption. The roaction at 60 - 80P C takes place in the diffusion zone
which~explains the absence of a mw-d= on the rate-time cunes. The
diffusion nature. of the reaction is apparently due to the formation of
mixed:cz7stals. Thirteers refererces 4-USSR; 1-USA and 8-German (1905-
1951)~ Table; graphs.
Institution The V.I. Lenin-F~relorws. State University,.Minsk
:Submitted s Xarcb 16.,.- .1953,

Card 1/1 kdb,~ V3.7- 20/22
Authors pav3,7-,Ic 116 r.1, oH. 111
Titlc Kine"U.-Les of lictcrot,.eneous mactions onckirr-.tn;~ vith the ravt iciri"J mi of

es
solid bodi

~ 20 11' '54
.S: Z) ~8/llp 20/+2-w. /;,o ovembcr Y,
Abstract The 0 rivation: of: an- voitantion -for the case of linc~ar c_--zboasion o.11'
Lr u
a: ve ct -3 in tims in accorclance. ,-yith t1-7 -,~ono-
ai m'i mitors, brij.;laat nj.
c C. 11:11 it 0:~.' JrDr~
molcc-ulc~r. r ction lavi~ -i's d6r;crib6d. The appUm'
aT4%t,.cuv' "o thv, F&actio
rp Of O:qL;eri miclatiol o.f silxx, riz ji-,
.
AoW' sco tzdning-waater of ~ cy7rtalli i-'a 'J-oil ia U
load WL ~c 1.
A,,;lbliolmd th .t iiy ivzwtlon ori~~' ii,,.Unf, fv(wi
c
one diroction. only., Cm rcrt~r n

Instittition
.11,a V. I.
Ph-eloraos-State Univbrsity, 1 JL nk
somatt!A A M11'12.,' 19 54

6901 R~ gri ii~ ff";1%

t4lkv
Ace
fe-
Y.A
ON
z!2
7~j
72
Ur

2 Ili
-a
j-
p "Toil hichl tjj~ jictj~ ilitrWlilg spre, q,
Nctor
out h. ull direcdon.. N i, i i,: i Q ~ - '. !u'--s - 1 1)w F ~'.
of 6- 7 by using re~ulfw ty-! lit, I khtch
j.,.4ave not" IK-en r"uliuriz,-ii. t
m

'tit
ji
ra of a 1 0 il_alr
beferiuluailon of the spedfic autfit 1-0-
W3, it. M. paylyu-IMUko and
-p-
Set.
11PI. 1955, o
Cryfit. uIlErLAUld, Cryst. Fmand. amorphous gmild, and
finely dispersed abietic acid (the lut-natned being ob-
Wntd by thermal dewrnpn~ of NHg abletate) were otudIM.
Surface am was Ineastirm by U%& adsorptiou of methylene
blue and converslon to surface arta by assuming I tng. of,
dyt equal to I sq. in, of surface. The opt6fic surfac-a
'Arrag th
obtained -(sq. ut./g. for the various raciplet of
abletle'acid were, mp.; 0 31, U.45,'4,9, and Thi
!j
COTTe, nding 6urface eireas for BR, Ca. anti INIn vibletam
RIO 3- d 5, By relating Mnx. oxidatfoll reff 11)
Z Pre. N , 0, Ra
sp"ific turfaze, arm thp effccts of tile sustituelit mupt on
reactlon rate can be e.;tabllplied. Attempts to measure our-
face area of Mg abletate yieldui anvamlously filgh Yalu."
Mat were found to be uncorrelated Asith surface nrea, but
were related to a tendvicy of the Mg corapd. to hydrolyre
pndcr,ost tmaditiorm

- - - -- - - - - - - - -

44^- tin d arldzu'un utagL=wl
i 10
l
-
At""
Ser. K~itw. i913-,
No.

~4, 17&-' ~,!; cf. pm,:i-ding mac-0 ng
of N.4 find 1;
F, %W~fatcs 1,P, 7'X mm." vvtrc lolimml by Ob-
etviqg therearud qu,~,it~ of 0 qs a ~f time ;,I Oe alAl
tc!tnj,.. jr:tervul With Ne, cthi~Mtt, lhc tatre r!aL-.,, i
I iii upt7,1-r - 2) a nd '! ~c

t nt, m rtt t ciriltr At P10 ;,nd !20,
Ibc IL~lx. rf~ ilir "
t~.rc- Lt amtl algwi At ~!Igll ',hif
n ruf -z t,
zl~-n, kw"I'v-1 C~;ntpl~ "r, :4ze Up !b-z Oulk ulmax,
axir"Ithn. Thcrt~:;ftnr a cf lmc;ic and 4Y;%j-
O)n far~Lors &t. !ie rate. at-ittat-, ri.-A u~,Wize at f

&mps. 3p C. 11. Fuchf.
t

if
ME

Mg.

AV,

W~diR___rE_1AA_H _41i'sid 11 Nr
at Ids
ja

g
i
A- 9,
g

~ I -_- -_ r
g
h
23, 914-18UPM); C A. J9, 0WV.-.
Products of oxidation of roim vIth 03 at 6D-Ml it d
Air At roorn temp. wm exAmd.; abletic "
and the
f ,
tyst. part of ibe rosin wervotuAIM. The widation 1"o
tts contain peroxide grouplngn, but the content of vct~
U
exides drops by a factor of 10 vhtn ilia rtaction ternp. Is
-
- The oxidation of rosin Acids
ed to 00* f
l
oom te
o

LN
re
s
r
m r
mp.
4:, reduces the confent of double bonds by W7(
id
d
I
l
f
i
4b
d
f

roperox
ation
ie
orm
at
on
ts,
of oxi
s apparen L
y i
y
:
whose decowpoe %
Jeld3 a inanDoxide, ales.. -and carbinly)
-
-4 At 60, has
Pompds. ThE solid fraction of rosin oxidized
i some 2D-B% active 0 (baud on added 0), Nhile In abielic
acid this v4l6e is but Oxidation reduces lbe abwip-
of abielle acid at 2410 A. and of rosin 2t 211M A.

CS AJA~ 0. M. 12),
~~WER/ Chemistry Physical efiezdstry
1/2 Pub J47 - 5/26
PavIyuchenko, M. H.
I 2"c a a ~ni i
0 n Mice an nechanism of heterogeneous chemical reactions
taking place with.the partigipation of solid bodies.
fiz -47~ Jani 1955
Zhur khim. 29/1p 39
-Abstract".: lbtperlmental data airs presented regarding:the kinetics of hetero-
geneous chemical reactions occurring with the participation of solid
bodies and it is.shoi4n that the solid reiction product (mixed or
ground,-or applied on the surface of.crystals) does not increase the
rate of.reaction except for the reaction leading to the decomposition
of wcplosives.
.1n8titution Acad. of So. Byelorues'. SSR, The V. 1. Lenin State University, Minsk
Subindited Marchi'll, 1954

FAVLYUCHKNXO, M.N.
e
Kinetics of the decomposition of explosive substances. Zhur.fiz.
khim. 29 no.69996-10DO Je 155. (KW 9: 1)
l.Bolorueekly gosudsrstvennyy universitst iment V.I.L*nIna.Hinsk.
(Nxplosions)

PAVLVCHMO. N.M.; LUMO. G.A.
Influence of temperature on the kinetics of formation of anaines
of sulfates and chlorides. Zhur.fis.khim. 29 no.6:1064-1072 Je
155. (KIRA 9:1)
I.Belorusakiy gonudaretvennyy universitat, Minsk.
(Ammin"s)

L,iC
4
V
~
IW
Y

'
d 1
N
V
e1
OR
I
W
an
1,
.
a
nshl
b
9t Run
n (
'UnIv., Mins1r). 2hur, As. Xkim 29~
'
73-W 9
At klnetk
cs wem studiod at IM-kP.
71e decompn. Tate increases with the temp. to a max. and
tbendrepstoO.. The mcdon starts InImparate amtem and.
r
then spre
&pId)y slovig the surlace~ whIarb Is cootal In
t
t
,
Ain
the sOid rtactIon predact. , A Wold In-
!
crease in the gemetric sudam of the XlICOj lm pmetically
no vffect on the reaction rutt; ubkb U explAlved by the
Jup Inm surlace of the crouds. The activation
of the demmpr-. of X)]C% vra Jound rqual to 15,50D rid..
and equals within The expil. emw. the hent effect of The
XIICO~Jecompn.reaclion. XCO,. whether applied to the'.
XIICO~ Irrim Wn, cr smund with the X11M and IWP
quelled with it, dom not inemase the dcrompa. Velocity.
W. M. Stembtra.-

sov/81-59-16-56832
Transia-;Ion from: Referativnyy zhurmal. Khimlya, 1959, Nr 16, p lig (ussR)
AUTHORS: Akulovich, V.M., Pavlyuchenko. M.M.
TITLE: The Spectral Determination of Potassium in Mineral Salts
PERIODICAL: Sb. dokl. 1-y Nauchno-tekhn. konferentsii po spektr. analizu. Minsk,
AN BSSR, 1956, pp 40-46
ABSTRACT: In the hollow of a Cu-plate moving during exposure with a rate of 1.4 mm/sec
1 g of the sample containing up to 50% KC1 is placed. As upper electrode
a carbon rod sharpened to a truncated cone is used. The spectra are ex-
cited in the discharge of a low-voltage spark at a capacitance of 20,44 fa-
rad, a current intensity of 4 a and an operating gap of 2 mm. The stand-
ards and the samples are diluted in the ratio of 1 : 2 by means of NH4C1
containing 1% of CdC12, The analysis is carried out, with allowance for
the background, by the line K 3446.7-Cd 3466.2 A; at concentrations of
KC1 < 5% the lines K 4047.2-Cd 3610.5 A are employed. The error of ana-
lYsis is '~ 7%. Similarly the analysis of the soluble part of K-fertili-
zers is carried out. For this purpose strips of filter paper are soaked
in a solution containing together up to 5% KC1 and NaCl and are fastened
Card 1/2 on a cylindrical horizontal moving Cu-electrode. The analysis is carried

SOV/8 .1 -~6 -16-5681 c-~
Translation from- Referativnyy zhurnal, Khimiya, 1959, Nr 16, P l15 OssR)
AUTHORS- Akulovich, V.M., Filonov, B.O., Pavlyuchenko, M.M.
TTITLE - Some Ebssibiliiies of the Met-hod of Additions in the 3pectrai Analvsis
Mineral Salts
PERIODICAL.- Sb. dokl . 1-y Naucnno-teknn. konferentsli po spektr. -3-na-Ilzu Mins-F.,
AN BSSR, 1956, pp 47-52
ABSTRACT., A method of extrapolat!~--)n for finding the concentrations of an element on
the base of tne known dependence R = AC6 at any values of b is de5cr4bed
If the sample is divided into fractions and in 2 of them ad,-iitions a
a.nd c % are made, then Rx = A-3 ; RX+a = A(x.+a)b and R x 4,c =Ak4c)O.
verting int-c iogarithris and excluding b, the-following equatijn is ob-allne~"
lg (Rx/R--.,,) lg(x4.a)/(x+c) = lg(Rx4a/Rx.+,) The latter ~quatior s4mple
solution under the coriiition: 1 gR / fix +a 4.a/Rx4c., from whi-h
that R~+a - -R j~nen (x+aMx-K) nx4.a) and --he
mula has the form. x 2a), For analysis a graph '.s p--.'
coordinates R versus con~-~!n~-atlon of additions; the geome~rl~ me--ti. 1~5
Card 112 calculated between tne rela,ive intensities for the sample vrithoUT ad~j-,~-~nS

f cAltium AMR& by 'i)L~jin-
Lics of ox3datian o
At. and V~ M. A1,11h)VICh. Yrihi likad.
795puk vvarns. Y.S.R. -)rr. Pit-, I exh. Nurnk 1056, NO. 1,
smimiary),-Kbirfics (4 oxidallon of Ca
abletute (1) with Otat 70-110" Is deserlin-41, Ale. :,oln. W
able-fic acid trealed with ak- KOII gave It nblOate, wlikh
on treat inent with Ca(AcO)p L-ave a j)pt. of I MAth i.~ imsol.
in 140 and ate. and comahis 3 mol. 11,01moll. Fif 1. Oxlda~
tion of I at 80 and DO* and 7-10 rum. IIg itart!; with a max.
rate that dccrcanc; with the time. At (30* die reaction rate
Is very vinall within the Ist 2-3 bts., and then incrtmes
and temains coint. wit'll flive. S(opping (it the rmethin
for 10-18 hra. and varying the pr6surt within 150-720 Win.
Ila vere without- effcct oil the mittloll mm, liolveytt,
fine pulverization of I bict eased, OL rate and decrewied the
time required for the oxittition of one hnff of the I sample
Arate of I at Go* at a
J0.3 1g.) 6.0 fold. Oil heating the h3

I at fKW" 00, ICO, and li
at 90' arid-above, the reaction rate is the within
9-tes,
the first few hrs. and dtpwds m the rate d diftw. of the
cling particles; at 70-W* !he reaction pirmeeds with
d d
d
n tht
t
i
h
i
me an
s o
ra
il
ction rate w
epen
t
t
incrmsing rea
rptWn of 0. The oxidation reaction
of the chem. abso.
,e at the adscirbml 0, and its rate i3
proct6lis at the exmm
Independent of the'O limsure. The oxidation reduzzes the
peroxides are not formed.
content of double bon6 but
analyze 'h' IL W.-
d -Mficauv.
are

/C A) v 4-
Category. USSR
Alis J(jilr Zh- Kh, No 5,
Autho r Pavlyuchellko, Pvl,
Inst ALaden-ly of Sclences elorussiin SSR
Tit!e On the Mc(hanism C)f fletrrogt-neous Reactions
0 r 1 gPub I z-. AN IIISSR , Sec tiOn "ll PhY s 1( cAl ind Tec hnic al S(. Iv n( v S,
1956 No I , I -A -, - I :~-)
Absi raL t A (liscussion Set- RZIiKhirri~ 1956, 67870.
C'I r -28-
B-9
MOW

W -J,
9W

It 0
1
0
5 71

'
.
c saw tan cag
j
Wn
an. 1 4
Al.~OPO.iqkiNul mimmary -F

-hatk1jr-tititalm-M min
With a raVJ4 d=mw tw. canler; *-Y-3010
maller i-n the prcsev~e ~if - tho W1164ka atcel thmi h, the
r V-nc of the noutimted captral, tht gmttst (IMMAW
Mig for the SAMP16 Sul9dized 'at higher ttmp.- contg.
hl~Ager ton~n--. of 5 In the staiace layer; Ahe Ont. of the
4dsorbed S LuxzmAd vvltb at time of h%titat the #Catesl
the r~onsalfidixed samples, and the rife bf the
lucmased durIng me ist 80~-W (~~tivl) and
et
41 samplts) of the v4diation fol-
Iowbd by a dtl=lae; -. Tew-bic-cff test fnilkattll that Me -
stability (hmkm) of thoppecinkus In a-- L, :*nd 2G- 30
ftes at the result of marthe sof4l* +
alotintioll proccasinp, ."WED-L I
7

Rq~ i/L Ak

M. PavjymhcT Akulovkh. N-

1956, No. 5, of Ms abl efate at 80, 40,

uitb Incrtadits rate thakma6es a IMM.' -
and 0" proceeds
and then deemr-sca. The reaction starts In ftpmtt actin
(ft~.ftyrraatlan of emteru follows the Ist-order law).
wh it prolrLgates is one direction. The: oxidation

/L
follows X imbere X - me" Ot, A - Const., 1 - tim
"
d 90
an
ti - order (n - 2 Mom max-19 reached). At 70
the oxiclailoo Is follow by evolution of heat, and the wnpk
arts
uartz to I
kt
~kvwder is addcd
10
l
If
h
q
ca
.
,
a qLm~
p
q
_
*
0

f4ollaws the Barne
oxidatian at 70
And 90
;ut WjK aLk-t-atej
ith
Th
i
h
E
e reut
on rate c
"jes w
w as at lower tcmps..
the ulwart root (if 0 pressare, - Oxidation of Mg abittate
proLeeds by adsarbijig 02; the adsorption lzwrmses with
ILW~rease to temp. and decreases with decream in 0 prtsmre.
Ariaxlaa S. Omne

PAUYUCHERO. M.H.; AKULOVICH, VJI.
Oxidation kinetics of barium abietate by oxygen. Sbor.nauch.rab.
Inst.khim.AG BSSR no.5:165-173 156. (MLU 10:5)
(Barium abietates)
(Oxidation)

YERHOUNKO, I.N.; PAYLYUCHMO, M.M.
Oxid2tion of cellulose. Uch.zap. BGU no.29:36-59 '56.
(MIRA 11:11)
(Cellulose) (Oxidation)

PAYIYUCHMO, M.M.; 11WOLMOO I.N.
_,~_
Spectrum analy6le of products formed during alkaline destruction
of oxidized celluloae. Uch.zop. B(RJ no.29:60-71 156.
(Cellulose--Spectra) (MIRA 11:11)

FAVLTUGHEbTO. N.M.; KAFUTSKIT, P.R.
... Kinetics of formation of cadmium ammonium iodide. Uch.zap. BGU
no.29:87-94 156. (MIRA 11:11)
(Cadmium ammonium Iodides) (Chemical reaction, Rate of)

FATTJU 0-t,.:K.V.'o,- VAITSMYN, Ye.N.
" v
Decc=osition kinetics of sodium bicarbonate. Uch.zs-p. BGU
no.29:95-101 156. (MIRI 11:11)
(Sodium carbonates) (Chemical reaction. Rate of)

PAVLYUCHZNKO, M.M.; ZHUEROVITSKAYA, R.L.
Absorption spectra of cobalt perchlorste in aqueous and nonaqnsoug
solutions. Uch.zap. BGIJ no.29:102-113 156. (MIRA 11:11)
(Cobalt parchlorate--Spectre)

Igatiotj of 6a proftcls and mcchankm of
alifogen - dioxidr., - M.
11aviyuchmko and 1. N. Frinolctiko~ * ltdr4- A kae. Ur
20, No. fJ, 54f3-5I(JUt).-L1It;1v1o1et-
light ab-:mption of ultrocellulose is inticasett after oxidatirln
with NIO, Bunds njjpt~ar at MG-70, 330, 341,5, 3615,
livnv:ne, CC14, et,~_ show a 5ttong band tit 340 tnp, judl
a dillwilvillon to NA lit thc-;~C. "Obeciall. T111, 11
u~-Wwd cellOwLe am-s not ciurelptoid tc, any voiuW. of
and 0, Wt. It tcs~ejobluq Oat of nttrow-. ac3d and nittoo
compds. stich ;is i~aaiuylnkfite and It is different Imin tb4t
of inorv. n1trilvs, 1rom thtn'- tests the S"eture 11-0-
N~A:) is pw~tttbtrd for n1trous acid. The t4nds at 210-20
mu and at 11~4) rij, !lc atuil,uted to carboxyl amt i;wborivl
9mull" tht: writ. (A which, its Well ct~ that [if tsitrit,3, (lecrew-rS
-lug temp,
with jimms-