SCIENTIFIC ABSTRACT PAVLOVA, I. V. - PAVLOVA, L. A.
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CIA-RDP86-00513R001239630005-2
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RIF
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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JSSR / Farm Animals, General Problems Q-1
Abs Jour : Ref Zhur-Biologiya, No 2, 195F. 7116
kithor :V.I. Pati,ishev, A.V. Polukhina, N.I. Yalovaya,
R.N. Oleneva, I.V. Paylb a$. T.I. Bat iyeva,
1). fbpovich, YZ.-Paryshkin
Inst :Webt Ural University
Title The Physiological Basis of Increased Productivity
of Farm Animals
Orig Pub: Uch. zap. Orallskogo un-ta, 1957, vyp. 15, 3-30
Abstract: Experiments made on calves which were raised on
rations with a low, average, and high content
of proteins, revealed a better digestion of pro-
teins, nitrogen-free extracts nad carotin, in
animals which had received m~,re proteins in their
rations. It was also revealed that the stimula-
tion of secretion of gastro intestinal j1iices
Card 1/3
USSR / Farm Animals, General Problens Q-1
Abs jour: Ref Shur-Biologiya, No 2, 1958. 7U6
Abstract: and a higher metabolism rate are not only due to
unconditioned reflexes prodiieed by a specific
effect of food, but occur as a resiilt of condi-
tioned reflexes induced by the condition.- :mdor
whi,.h the food had been consumed. In an experi-
mental study of horses the effect of training on
the utilization of enerry derived from food, on
blood composition, acid content of urine, reaction
of erythrocyte sedimentation, coagulation of
blood, pulse rate, metabolism etc. was revealed.
The trerendous importance of training was deter-
mined as a factor which affected metabolism, and
prodiced the complex reflexes which affected the
essential functions of an organism. Pronounced
f,-mctional changes were observed as well in
large horned cattle when kept on pasturage
Card 2/3
USSR / Farm Aninals, General Proolens
Abs JO ir: Ref Zhur-Biologiya, No 2, 195F. 7116
Abstract: grounds. Under these conditinns the passal,.e of
food throigh their gastro intestJ~nal tract was
accelerated to almost dolible the ~is:)al time. A
paradox was observed: A marked low rate of meta-
bolism and a decrease of blood circulation when
physical strain was imposed on cows (sich as the
placing of a sand bag weighIng 10-20 percent of
the body weiCht on the sho,ilders of a caw stand-
ing in a stall). Prod,ctive, shoice cows showed
a higher oxygen content in their blood.
Card 3/3
PAVLOVA, 1. V,
Problem of oxidation netabolien In the Inilmouaz7 tissue In acperimemtal
silicosis [with summary In Fmglishl. Vop.med.Wm. 4 no-5:359-261
S-0 158 (MIRA Ut1l)
1. Riokhimicheskays. laborstoriya inetituta, gigiyeny truds I profmabole-
vaniy ANN SSSR, Moskva,
(BILICOSISIO expere
eff. of succinic acid on pulm. oxygen.
con.!,tmption (Rus))
(SUCC3AT1-;, eff'
on lung o~;;en consumption In exper. silicosis (Rue))
13TAVW# A.A*. prof., otv. red.; DYIZHKOV, P.P., prof., red.; moLMANoy,
KJP.. prof., red.; IVANOV. T.L. prof., red.; HDROZOV, A.L.. Prof.,
red. ;- -YAVL0YA-,--1-L, kAnd. mad. nauk, red.: 1HUIDRINA, Ye.T.,
doktor mod. rieuk, red.; FRWROVA, V.I., red.: BILICHIKOVA. Yu.S..
tekhn. red.
(Transactions of the Symposium on the Problem of Pneunoconiosis;
etiology and pathogenesis] Trudy SIMP02iWM po problems pnevmo-
koniozov. 1957; atiologiis i patogensiz. Red. kollegils; A.A.
Letavat t dr. Moskva. Goo. izd-vo mad. lit-ry, 1959. 275 P.
(MIRA 14:5)
1. Simpozium po problems pnovmokoniozov, 1957. 2. Daystvitellnyy
chlen ANN SSSR (for Letavet). 3. Institut gigiyony truda i prof-
2abolevaniy AMN SSSR, Moskva (for Letavet. Dvizhkov, Ivanov.
Pavlave. Fedorova)
(WNGS-DUST DISEASES)
FAVLOVA, I-V., kand.med.nauk
Carbokydrate-phosphorus metabolism In the lung tissue of rats
in experimental silicoets. Bor'ba a oil. 4:125-127 '59.
WRA 12:11)
1. Inatitnt gigiyeny truds I profzabolovaniy AMU SSSR.
(LUNGS-DUST DISFASES)
(URBOHYDR&TH METABOLISM)
(FHOSPHORUS METABOLISM)
IETAVEE-T, A.A., prof.,otv.red.; MLOKANOV,K.P., prof., red.; DVIZHKOV,P.P.,
prof.,red.; KhTKHRINA,Ye.V., doktor med. nauk, red.; IVPMV,V.1.,
prof.,red.; VDROZOV, A.L., prof., red.; kand.med.
nauk., red.
[Clinical aspects of pneumoconiosis]KIinika pnevmokoniozov; trudy.
Moskva,, In-t gigieny truda i profzabolevanii AMN SSSR, 1960. 181 p.
(Nip 16:21v,
1. Sinpozium po problems pnevmokoniozov, Moscow, 1957. . Deys
tellnyy chlen kkademii meditsinskikh nauk SSSR (for Letavet).
3. Institut gigiyenj* t~ixoa!i profzabolevaniy Akademii meditsin-
skikh nauk SSSR (for Molokanov).
(LUNGS--DVST DISEASES)
PAVLOVA, 1. V., Cand Biol 5ci - (diss) "Concerning Jeveral Peculiarities of the
Metabolism of Fhophorus and Calcium in the Young of Cattle." Sverdlovsk, 19DO,
15 PP, (Ministry of Higher and Secordar7 3pecialist Education i~~FSR; Ural State
Univ im A. M. GorIkiy) 150 copies, no price given (KL, 21-60, ~21)
UZHANSKIYJ Ya.G.; PAVLCVA 1.9-- Prinimali uchastiyet MORDOVSKIY, G.G.;
KIPRIANOVA, N.I., studentka (Sverdlovsk)
Signs of autoagresoion in the mechanism of blood reg-noration.
Pat.fiziol.i ekap.terap. 4 no-4:52,57 JI-Ag 160. (MIRA 14:5)
1. Iz kafedry patofiziologii (zav. - prof. Ya.G.Uzhanakiy)
Sverdlovskogo meditsinskogo inatituta.
(frr'MORRHAGE) (ERYTHROCYTES) (ANTIGENS AND ANTIBODIES)
___ PAVLOVA.I.I.-S...-
Cand Med Sci - (diss) "Clinical features of schizophrAnis compli-
cated by chronic alcoholism." Moscow, 1961. 15 PP; (Minstry of
Public Health RSFSRj Gorlkiy Medical Inst imeni S. M. Kirov);
250 copies; price not given; (KL, 5-61 sup, 204)
PAVLOVA, I.V. --
Effect of chronic alcoholism on the course of gehizophrenia (tm!
forms with an uninterrupted, fluctuating course of the disease).
Trudy Gos.nauch.-issl.inst.psikh. 27:69-75 161. (MIRA 15:10)
I., Moskovskaya psikhonevrologicheskaya bollnitoa imeni Garmishkinfl.
Glavnyy vrach - V.N.Rybalka. Nauchnyy rukovoditell - prof. S.G.
Zhislin.
(SCHIZOPHRENIA) (ALCOHOLISM)
PAVIDVAV I.V,
Hatabolim of certain amino acids and adenosine triphosphate
deamination in the pilmonary tivaue, Vop, mod, khim. 7 no. 1:21-
25 J44 161, (MIRA 14:4)
1. Biochemiml Laboratory of the Inatitute for Industrial
Hygiene and Occupational Diseases, Academy of Medical Sciences
of the U.S.S.R., Moscow.
(LUNGS) (AMINO ACIDS) (ADENOSINE TRIPHOSPHATES)
FAVLOVA, I.V.
Oxi#ative metabolism of carbohydrates in pulmonapy tis:;ues. Vop.
mod. khim. 0 no.2:186-192 Mr-Ap '62. (MIRA 15:4)
1. Institute of Industrial Hygiene and Occupational Diseases, Academy
of Medical Sciences of tho U.S.S.R., Moscow.
(LUNGS) (CARBOHYDRqN METABOLISM)
. 1~
ZHURAVLEVA, M.V.; PAVLOVA, I.V.; SVII M-INIKOV, s.G. (?J06ma)
Results of active outpatient service for alcoholics in the
collective of an industrial plant. Trudy Goa. nauch.-issl.
inst. psikh. 38002-3305 t63 (MIRA 16111)
PJSHKINA, Wataliya Niko-layevna; FAVLOVA. I.V. red.; IYUDKOVSKAYA,
- . P
N.I., tekhn,red,
[Biochemical methods of research; manual for p sicians-
IWgienists and occupational disease specialistsl Biokhi-
micheskie metody issledovaniia; rukovodstvo dlia vrachei-
gigienistov i profpatalogov. Moskva, Medgiz, 1963. 393 p#
(MIRA 17:1)
jkYWVA,_ I.Vlf FEDOPOVA, V.I.
I
Some aspeots of nitrogen and oxidative metabolism in the litnge
of experirpntal animals with silicosis. Vop. meds kbda. 9 r10.42
356-362 Ti-Ag'63 OURA 17 aj
1. Biochimicheaka3ra 'Laboratorlye i patologoanatomicheaka-pi
laboratoriya Inatituta gigiyeny truda 1' professionalOnykh za-
bolevaniy AMR SSSR, Moskva.
SHMAKOV? V.N.; PAVLOVA, I.S.
Significance of the method of isolated contrastinr of thc.
and induced hypotonia in the diat-nosis of duodenitls. 7eFz.
rad. 39 no.5.33-37 S-0 164. (XIRA !F:~,
1. I-ya kafedra fukulltetskoy torapli (zav. - A.Yti.
z,~
i kafedra rentgenologii i meditsinskoy radiologil (zav. I.,. K~.n-
Donetskogo meditsinskogo instituta.
FAVLOVA, I.V.; TSUISULIKOVSKAYA, M.Ya,
Experience in the us* of frenolon for the treatment of
schizophrenia. Zhur. nevr. i palkh. 64 no.ltl25-1)0 164.
(MIRA 17:5)
1. Inatitut pbikhlatrii AMN SSSR, Moskva.
LETAVET, A.A.,, prof.,, red.; ANTONIYEV, A.A.,, dotB., red.; DROG1CHINA,
E.A., prof., red.; KONCHALOVSKMA, N.M., prof., red.;
.~~AVIDVA, I.V.,, doktor med. nauk, red.; POPOVA, T.B., kand.
med. nauk, red.; RABB, A.S., doktor mod. nauk, red.; RABEN,
A.S.0 doktor mod. nauk, red.1 RASHEVSKAYA. A.M., prof., red.;
SHATALOV, N.N., kand. mod. nauk, red.
(occupational diseases in the chemical Industry] Professior,all-
nye zabDlevanila v khindcheskol prorWahlonnosti. Moskva,
Meditsinap 1965. 322 p. (MIRA 18:12)
1. Deystvitellnyy ch2ei AMN SSSP (for Letavet).
L 05819-67 EWT(1)/EWTW DD
ACC
"R- AP6032137 /-IV) SOURCE: CODE : UR/0391/66/000/009/0041/0044
AUTHOR: Veretinskaya._A. G. (Moscow); Tolgskaya, M. S. (Moscow); Pavlova,
1. V. (Moscow)
ORG: Institute of Labor Hygiene and Occupational Diseases, AMN SSSR (Institut
gigiyefiy tru a i profzabolevaniy A MN SSSR)
'A-
TITLE: Effects of ]UHF radiatio on the nucleic acidkontent in the lungs of rats with
experimental silicosis
SOURCE: Gigiyena truda i professionallnyye zabolevaniya, no. 9, 1966, 41-44
TOPIC TAGS: UHF, medical experiment, nucleic acid, silicosis/UVCh-1 radiation
device 10
ABSTRACT: Biochemical and histochemical changes occurring in the lungs during
UHF fie*ld radiation were investigated. A UVCh-4 device operating continuously at
40 Me was used. The effects of the UHF field on the development of silicosis and
on the nuclei-acid content in lungs of rats examined were studied, and calculated in
milligram- percentages of phosphorus per dry weight of the lung. The appearance of
new celI formations during silicosis was determined experimentally. UHF radiation 7
-003. 662-092. 9-OR5. R46-07:616. 24-008. 939. 633. 2-074
L 05819-67.
ACC NR- AP6032137
was found to retard development of silicosis. Experiments showed that the macro-
phagic functions of histocytes increased, their fibroblastic functions decreased after
UHF radiation, and as a result, the collagen synthesis was retarded, Quartz
discharge from the organism is considered to increase under the effect of UHF
radiation, which shows the favoragle effect of the latter on the course of the silicosis
process. Orig. art. has: 5 figures.
SUB CODE: 06, 07/ SU13M DATE: 02Dec65/ ORIG REF: 003/
Card 2 / 2
..CC NR, AP6032135
AUTHOR: Karamzina,
( /V)
N.
SOURCE CODE: UR/0391/66/000/009/0032/0036
M. (Moscow); Pavlova, 1. V. (moscow)
~ORG; rnatitute of Industrial Hygiene and Occupational Diseases,
;.AMN SSSR (Institut gigiyeny truda i profzabolevaniy AMN SSSR)
TITLE: Oxidation processes in lungs of rate after poisoning with vari-
l
aus beryllium compounds
SOURCE: Gigiyena truda i professional'nyye zabolevaniya. no. 9, 19bbe
32-3i
TOPIC TAGS: animal physiology, respiratory system, enzyme, poison
e f f e c. t , r a t , berylii -am c ompound, aluminum compound
ABSTRACT: The comparative effect of poisoning with various beryllium
.compounds on pulmonary oxidation processes in white rats was studied.
A single dose of beryllium oxide or a mixture of equal parts metallic
beryllium and aluminum introduced intratracheally caused a sharp in-
crease in the weight of lungs of experimental animals and inhibited the
oxidation of alpha-ketoglutaric and malic acids by pulmonary tissue
enzymes. After poisoning with beryllium-aluminum alloys, pulmonary oxi--~I
dation processes were much less affected, apparently because of the
UDC: 616.24-003.669.725-092.9-07:616.24-
Card 1/2 -008. 92-2.1
C NR:AP6032135
acitered physical and chemical properties of the beryllium Alloy. Orig.
r
art. has: 3 tables. (w.A. 501
1SUB CODE& 06/ SUBM DATE: 12Dec64/ ORIG REFs 004/ OTH REF: 001
Card 2 / 2
WINGRID-No A.Y.1 PAVLOVAv I.V.
btermuot of amdato Cowl"" of nlablum am unulum
with boxamdnooobalt chloride, Lhim,nmrg*Mlft. 10
no,2M.-M V 965.
(mm 198 1)
PATRUSV, V-.I.,- HATUYE'VA, M.j BOGOMDLDV, N.A.; GAMSHKINAJ, S.M.;
NAUTWIV, -K.P.; PAVL6V,A, I.V.; PARYSHKIN, Yu.A.; POLMIRA, A.V.;
Siuli-ru?'VA, K-.U-.;--5UT1J-1OVA, 11.14.
Experiments in physiological evaluation of food ratiops. Uch.zap.
UrGU no.310-16 159. (MIRA 14:5)
(Cattle-Feeding and feeds) (Proteins)
giOlhx 'Y',-,'V A, Ye.V. ; W " -I" Vs I I V.
( fiv
ndbook on lEiboratory work in I)hy2lcq; vection:
j
Electricity] i~ukovodstvo k lar)oratornym rabotam po
fizike; razdel: Elektrichestvu. Sost. E.V.Arsenlyeva,
I.V.Pavlova. I,enlngrad, 1962. F2 p. (XIhA 17:7)
1. Leningrad. Institut tochnoy uckhaniki i optiki. Kitfodrn
fiziki.
PAVLOVA I.V. (NDskva)
.9
Fifth International Biochemic&l Congress. Gig.truda i prof.
zab. 6 no.5:55-56 1-~,162. (nill 16:8)
(1310CHEMISTRY-CMUS.SSES)
PA V W, *7 A , Y A .
P~,IIIPVA. K.A.- "Some D--obl&,PLq of tht-, tran!5fomntion of arom3tic hvrlrreart-~~ns
with orelimin-ir, hvdrof-cmit.ior,". -os,7ow, fci ~-
. ' - i . I-
P.f f iliqtr?. In!Tt of Choqilstz-~, Lahnritorv of U,-Inlrl and C?,wt-dy~,ir.
(DiFsertitions fcr t he T)npree of --Indid-if c of Chemical Scio-tic-es I .
M Knizhniva letwAr. I %o 45 , I.; I jr, 1, . "one crw .
NNIL 0 V A',.-),-. N,
pa ibid.
autillirg'-Lo "op.1rL'Alle O"Llct Of tvll, mtalysf'~:
010 N~S kpotiltil chi aluinimmi
Nin-`6 wl, VIC Is
o
r
iuflml, a,pit Ow li),drquation of ben.
'flip csl)t5. at carriell pla b) nut"clairs withmirrers
COP Wf)' I
~.t tz:mpp. 4~Q, V0, awl , ' :i: 3', thq~ I whia'llkli
to stliik., 11w rfv~ivavllz, Th", itiAr"Itfoll ill C;~01 cil't,
1.,; .1 firs. Tkt. cat-alv5t ja v:-z"i lit IL-e forill, of tAlvta. TIM
ac -Iut!t~ by Ohmma-
lite P-arig by Iratialial d;3tn.
c
ldclitirwd pr(Aucts are CYCIL.-
hwume, wetli-
atul unchAriged 'r,=Ycnc.
Analyting the rcmilts obtalticd tit -00", the hydb-ogelinfirm
actlv;ty of Ot diftermt cati%)~sts ii Wf3--Ni,-,AJ&Lh >
> > W.% cm Vaillic Ov~ >
~V); thei LuRqVivition "Ic-tivit I, IV > It In > V >
(fir clttivg~ jj,'jjv-jjy V > IV >'Ill > H > The s,im& re.
Winn. of nctWjtjQ.% eiiisf.t R,r 1, 11, and Ill A60 and W.
9!ts am &13o
"C!"
'twil, of benzc1le ;;[j tile pm5v" of L Is 4?.)
l%
PA o
)
,
,
Tbo cars -utlve rpazAkna. duling the deauu:fivg hyft.'
er
%-nadon of bem"t. 71 N,
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~(110vuWlils- AVdillbs1z that tilt! hydritmaf1w., i-jtjl-
11
Emit expcrivmltall~- the duibolf; tieu rumilk.
t(platiolls arrec fairly wtit IN,101 tht ti-
Malty foand; vit-Iff, Cil r!;. 11: Is wwtdeled: 11myril
mm TT
I
Mat i1ttraig-Aht: detfructive!
tb- fnnrer
a 1 6
be~,-S prrCeAcd by tb* I'mthylCYTIO.
imc. 81cf~rtmm
lie c
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5
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Use Th"l.'jj'.'t"
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4,f IX,
bc C-Ital 1114Z
YS1
,
KhaCHITS, I.V..; PAVIDVA, K.A. ; SAIUYL4)V. S. 11.
Iffect of the recrystallization of the VS2 patulyst on its h7dro-
ganating and laomeriztiW, activities. Truay Vost.-Sib.fil.0
SSSR no.18:81-86 159. (14IRA 12--10)
(Tung,sten uulfide)
MECHITS, I.V.; FAVIXAI,Ao.&,--
Composition of products of toluene
in the presence of high temperature
fil.AN SSSR no.38:15-18 161.
(Toluene) (Hydrogenation)
destructive hydrogenation
catalysts. Trudy Vost.-Sib.
(KEM 15 -.4)
(CatalysU)
PAVLOVA, KA.; MUCHITS,, I.V.
Composition of products of o- and m-xylene destructive hydrogenation
in the presence of tungsten sulfide. Truo Vost.-Sib.fil.AN SSSR
no.38:19-24 161. (MIRk 15:4)
(Xylene) (Hydrogenation) (Tungsten sulfides)
33602
s/678/6 i / ooo, 0 38,'00 1, 0-0
A057/ A 126
AUTHORS: Kalechits, IN., Pavlova, K.A.,. aliberdu, L.M., "kvorlsc~a,
G.G., Bogdanova, T. , Sidorov, R-I , Trotsenku, Z.P.
TITLE: On the chenjism of transformations of bi-cycilc hydrocarbons
under conditions of destructive hydrogenation
PERIODICAL: Akademiya nauk SSSR. Vostochno Sibirskiy filial. Trudy. Serlya
khimicheskaya, no. 38, Moscow, 1961. Prevrashchenlya aromatichelc-
kikh uglevodorodov v protsesse destruktivnoy gidrogenizatsll.,
31 - 57
TEXT: Laboratory experiments on destructive hydrogenation of naphtha-
lene, tetralin, and decalin were carried out under semi-industrial conditions
in presence of industrial catalysts. The composition of the products obtained
was classified, 17 single hydrocarbons were separated, and il more determined
by spectrum analysis. It is shown that transformations of bl-cycli,~ hydro-
carbons occur in the presence of tungsten catalysts and In vapor-phase pro-
cesses preferably by consecutive hydrogenation isomerIzation, and final split-
ting. The transformations observed are explained by the carbenium-ionic the-
Card (0
33602
S/678/61/000/038/'00),/Oog
On the chemism of ....... A057/A126
cry, and schemes for transformations of bi-cyclio hydrocarbons in vapor- and
liquid-phase processes presented. In the present paper a discussion Is pre-
sented of the problem oftransformations of polycyclic hydrocarbons with a re-
view of appropriate literature data. Among the problems to be solved is the
question, whether a direct splitting of the ring is possible in hydrocarbons
of the tetralin, tetrahydroanthracene, eto. type, or whether isomerization
occurs before and which bonds and by what reasons are most easily split. This
and related problems were investigated before. Experiments were carried out
too, with a powdered Fe-semicoke catalyst at 4700c, 450 atm, 3 h and 10% catalyst.
The products obtained were separated by fractional distillation, and the re-
mainder chromatographically treated over siiica gel [types MCM (MSM), or KCM(KSM)].
After separating methane-naphthenic and aromatic fraotions, narrow cuts we-e
prepared by fractional distillation. M
The cuts were specified by n20 and d4
D
values, and some also by Raman spectra [taken on anWII-51 (ISP-51) spectro-
graph]. The amount of cyclohexane and homologues, and of bicyclic hydrocarbons
containing hexamethylene rings were determined by D.D. Zelinskiyls method of
dehydrogenation catalysis. The content of paraffinic and monocyclic naphthenic
hydrocarbons was determined by means of specific refraction RD and molecular
Card 2/3
00
AUTHORS:
TITLEi
33604
s/678/6 1 /000/038/003/00(~
A057/'AI26
Pavlova, K.A., Kalechits, IN.
Destructive hydrogenation of met.hyl naph.!.halenes In '.he
presence Of a WS2 Catalyst
PERIODICAL: Akademiya nauk -SSSR. Vostochno-Sibirskly fillal. 'r-ujy.
Seriya khimicheskaya, no. 38, Mos-~Ow- 1961. Prevras~lhenlya
aromat4lcheskikh uglevodorodov v protsesse dest.ruklAvrioy
gidrogenizatsii., 61 - 67
TEXT- In the present experiments naphthalene,c, --, and 6-methyinaph-
thalene were hydrogenated in the presen-.e of a WS2 ca,alyst ( '~0% by we4,ght of
the hydrocarbon), in a I I autoclave (with stirrer), at 140 atm Initlal hydro-
gen pressure, 4200C and 3 h contact time. The aromatic and naphthenic frac-
tion of the product was separated first chromatographically and then by fra--
tional distillation into narrow cuts. The composition was determined by the
refraction indices, and by dehydrogenation by Zellnskly's method. In the --al-
culations the absence of monocyclic naphthenes was assumed. Four paral 1,?! ru-~5
Card IA
33604
S/678/61/000/038/003/009
Destructive hydrogenation ....... A057/A126
were carried out with each hydrocarbon and only a low --;onten-. of h1gh
carbons observed in the products. Prevalent In the methane-naphtenic, fra-,tior)
are isomerized hydrocarbons of the series of bloyclo-0,M)-octane, and bi-
cyclo-(0,3,4)-nonane. By an exhaustive dehydrogenation of the aromati: fra:?-
tion of the methyl naphthalene hydrogenation product the presen, authors de-
termined that hydrogen addition occurs quicker in the non-substituted ring.
Hence the same regularities were observed as with other -catalysts. 111hus the
obtained results demonstrate that the introduction o#' a methyl subsiAtute a--,.el-
erates hydrogenation, isomerization, and splitting processes renpen'Ovely, and
regularities observed in monocyclic hydrocarbons are valiable also for bi-~ycllc
hydrocarbons. The content of aromatic hydrocarbons was in the hydrogenation
product of naphthalene 50.5%, of,.Q(-methyl naphthalene 48.2%. and of /1-methyl
naphthalene 34.9%. Comparing experimental data a small accelerating effect of
the methyl substitute if in Ot -position 15 shown, but an Intensive effect if
in A -position. The authors explain this effect by the carbenium ionic the-
cry. It can be seen that by an Introduction of methyl In o(-positlon, In
spite of adding a tertiary atom, the number of easily to realize possibill'.1es
of bond splitting does not change. Introduction of methyl group in /5-positlorl
adds two easily to realize variants of bond splitting, in spite of *he stronger
Card 2/3
S/081/62/000/017/'072/102
B156/B166
AWHORSt Kalechits, I. V., PaXjQyA. X. A.,.Kaliberdo, L. M.,
Skvortsova, G. G.,' Bogd9novaq T. A., Sidor6v, R. I., Trotsen-
ko, Z. P.
TITLLi The chemical affinity of bicyclic hydrocarbon transformations
under conditions of destructive hydrogenation
PERIODICAL: Referativnyy zhurnal. Khimiya., no. 17, 1962t 471, abstract
17?d144 (Tr. Vost.-Sib. fil. Sib. otd. AN SSSR, no. 38, 1961,
31 - 57)
Ti~XTs rxperiments on the destrictive hydrogenation 9f naphthalene,
tetralin, and decalin in a rotating half-liter autoclave are described.
The,conaitions were almost the same as those in industrial processeq, and
industrial catalysts were used. Group composition, and in a number of
cases individual features of hydrogenation products, %ere establisned. It
i% proved that, in the presence of tungsten catalysts, bicyclic hydro-
4'rbons are mostly transformed by successive hydrogenation reactions,
fo-Ilowed by isomerization and finally by splitting. It is most likely that
I
Card 1/2
S/08 1/62/000/0171107 21 1102
The chemical affinity of ... ;156/3186
the rin6s split along the links with the other rings. When an Fe-cataly6t
is present process conditions in the liquid phase are dominated by the
transformations that characterize the theriijal process without a catal~,-,t,
which are mostly due to the splitting of the link with the benzf,,re rine,
but which Laostly occur without intermediate isomerization of the hyGro-
genated ring. Methods of transforming bicyclic hydrocarbons under vapor
and liquid phase process co-nditions are proposed. [Abstracter's notes
Complete translation.1
Card 212
VARAKSIN, Vladimir Ivanovich; PAVLOVA, K.A., red.
(Advantages of uniting heating boilers in one organiza-
tion] Chto daet ob"edinenie otopitelInykh kotellnykh v
odnoi orgar.izatsii. Moskva, Stroiizdat, 1965. 37 p.
(MIRA 180)
PAVLOVA. K.A.1 PANTELEYEVA, B.D.; DERYAGIRA. E.N.; KALECHITS. 1.V.
Effect of nonotoichloo-4tric aulfur cn the activity of ffulfide
eatalystis. Kin.i kato6 no.3:493-498 Yq-Je, 165.
(MIRA 18:10)
1. Institut nefte- i uglekhimicheakogo sinteza, Angarsk.
PAVLOTA, 1. 1 -4.1
Crimping and pleating of fabrics. Prom.koop. no.11:21-24 N '55.
(KM 9-5)
(Dressmak-ing)
IPAVLOVA, K.
New developments in the organization of socialist competition.
Avt. transp. 42 no.7:6-8 JI '64. (141RA 17:11)
1. Predsedatell Moskovskogo oblastnogo komiteta professionallnogo
soyuza rabotnikov svyazi, rabochikh avtotransport-a i shosseynykh
dorog.
KOLODEY, Anton Pavlovich, inzh.; P~Vj~~V.A Klara Artea!y~jyna,
Leoniiy
inzh.; BOGUSLAVSKIY,
Davydovich, kand. tekhn.
nauki BERNSHTEYN, Yevgeniy Iosifovich, inzh.;
KISLINSKIY, Yan Vladimirovich, inzh.; KIRFICHNIKOV,
Aleksandr Aleksandrovich, kand. tekhn. nauk; IVANOV,
Valentin Pavlovich, inzh.; KUTUKOV, Vladimir Nikolayevich,
arkh.; DRIENTIYEV, Anatoliy Ivanovich, kand. tekhn. nauk
[Handbook on maintenance of apartment houses] Rukovodstvo
po, tekhnicheskoi ekspluatataii zhilykh zdanii. Moskva,
Stroiizdat. Pt.2. 1965. 291 p. (MIRA 18:7)
PAVLOVAP K.I.
.--ow"MAMMUM
Rffect of corn monoculturOB on the dynamics of sme insect pests.
Vop. ekol. 7tl25-126 162. (MIRA 16t5)
1. Vessoyuznyy institut zashchity rasteniy Leningrad,,
(Vasillevka District-Corn (MiZe~-Diseases,4d posts)
(Vasillevka District-Insects, Injurious and beneficial)
MIDVAI K.K.- SUBDCHI V-V-
Evaluation of beee flow on evampy drainage areas* Trudy GGI
no.122t!20-130 165o (MIRA 18t9)
VSk,-VC,ILZHSKIY, V.,, ; 1,0NA'A , 'K.K.
Chfaracteris'.1ca of t'le formatic-ri of a, bsurface int-3
f
in the Pur region Trudy GGII tw~lll~,:,'71-179 I .
( M I-RA 17, : I " ,
-
t'd
t
l
gang- 11
nate% soft
ity
wolls of tbe
Aw
'
Uzjje K L T vi
X., A,,- Sul IN
kc.JQ%!~h-jT, T.
41),r
o
)vcrY of hiA~jr~eu ate.
sugvved. The Ist - stugz of evilm.. cmjjjtjjji~A to
1
to 254" crystel
C,5v;
-N c ~Co, d --,ttg
Ai Gi iWil ilwa a 7V crYbtl;, Na_,Wt
Ow. &~llt_ With Natco'-J150 +
twqA evarml. ac W
A7,
!he c
ail c 1C.,
l
"f
r
f! ATJ9 dl
jc
_ ~
_ 3t~
'tail
wiiu~ 110. At"25-7,
$4n. wai c~
vrYAj.' a part olxici)il and thd ie~zr at 2S tjie'~! _4
7, 77 M 71
7
SOKOLOVSKIT, A.A.; KUZMITSOVA, T.I.; 4VWVA, K.L.
060WASOMaw-
Obtaining high-quality poterh from wa:te soda-potash solutions
from production of alumina. 1him.nauke I prom. 2 no.4:531-534
157. (MIRA 10:11)
1. Gosudarstvennyy nauchno-iseledovatel'skiy institut khtmicheakoy
promyshlennosti.
(Potash) (Alumina)
ZFP,HDUIIN.9 Boris Semanovich., kandi.tekhn.riaak, ispolnyayushchiy ob-
yazannosti dotsenta; PAVL71A, Korneliya Ukolayev-na, stu-
dentka-diplomnitsa -------
Magnetic field in the air gap of an inductor machine with a
comb-type toothed zone. Izv. vyq. uchob. zav.; elektromakh.
6 no.8:9(Y7-916 163. (MMA 16:9)
1. 14uskovs"aya ordena Lenina aviatsionnyy institut.
j
PAVIDTA. K.N. (Zagorsk, HoskavskayA oblast')
Vehrnd closed doors. tdorovIe 4 no.1:11 Mr 058. (MIRA 11:3)
(APARTHNNT HOUSES--HYGMIC ASPECTS)
TITOV, N.P.; BOGWMVA, Z.S.; KRUGLIKOV, M.N.; OZOLIN, L.T.; PAVIOTA. K.S. ;
SWIFD. R.B.
Research carried on by the Institute of No-chamical Mineral
Ptocessing on iron ore dressing. Obog. rud 2 no.5:42-50
' 57. (VJRA 11:11)
(Notallurgical research) (Iron ores) (ore dressing)
SOV/ 137-58-7-14015
Translation from: Referativnyy zhurnal. Metallurgiya, 1958, Nr 7, p4 (USSR)
AUTHOR
TI T LE: Beneficiation of the Iron Ores of Kostomuksha in the Mezhozero
Deposit of Karelia (Obogashcheniye zheleznykh rud Kostornuk-
shskogo Mezhozerskago mestorozhdeniy Karelii)
PERIODICAL: I Tr. ] Vses. n. - i. i proyektn. in-ta mekhan. obrabotki polez -
nykh iskopayemykh, 1957, Nr 102, pp 142-151
ABSTRACT: Mineralogical analyses of 8 samples show that the ores of the
Kostomuksha deposit constitute magnetite and hematite-magnet-
ite varieties with a high quartz and silicate content, and that
there is an intimate concretion of the ma n Ht a d hematite with
0 jor.e - i e n
gangue minerals. Fe content is 39.4-3 The investigations
show that these ores are susceptible to successful beneficiation
by magnetic separation with comminution in 2 or 3) stages, the
initial size being 6-0-mm, the final being 0. 1-0 mrn (93-95 070
-0. 074 mm), and the irAermediate 0. 5-0 mm. To dress the
hematite - magnetite ore, a procedure employing combined mag-
netic and gravitational concentration is recommended. This
Card 1/2 yields a concentrate with 61-620/a Fe, with a recovery of -90~o
I
SOV/1 37-58 -7-14015
Beneficiation of the Iron Ores of Kostomuksha (cont.
f
of the Fe. To obtain a concentrate with b2-,b3o/o Fe it is necessary to eliminate
the second magnetic separation step in the first stage of beneficiation, the con-
centrate being obtained only after fine grinding of the-entire middlings. Min-
eralogical analysis of the ores of the Mezhozero deposit shows that ores to be
magnetites with medium to fine dissemination of the magnetite and the gangue
minerals. Fe content is 36. 8-35. 60/o, silicon 42. 1-43. 507o. Recommended
for these ores is a procedure for magnetic separation on separators having a
weak magnetic field, an initial size of 3. 0 or 0. 5-0 mm, and a concentrate of
61-62076 Fe, with recovery of 88% of the Fe.
1. Iron ores--Analysis 2. Iron ores--Test results
A. S h.
Card 2/?
PAVLOVA, ?,.V., K.B.
Kinc-~Ic-lg ef v:iaction of aJild'at-lon by pc;tlassium
-~Illcrzltc. ill HE.(' of rhonium. Zhur. nearg. khim. 10
'y 16~'. (MIA 18f6)
no.5-1027-103" ~f
_401
ACCESSIOW IM4 ~.:'AP5012967 UR/007816510101005/1027/1032
-128.2
_642,,943.541.126.546.15~
'
-
AUTHOR*.-.* av
lova
P V..- Yat~imirskiyj K B.
of -the oxidation..of iodide by potassium chlorate in the presence
of rhefilm,
16URCE:*~' ZhUrnal nibi~janlcheskqy khimii, v. 10, no, 5, 1965, 1027-1032
TOPIC.TAGS: rhanium oxidation catalyst, chlorate ion, iodide ion, catalytic oxi-
dat on:
~BSTRACT.-The:Ainetil- cs---qnd-mwch-&ftjs-_oT A I(Aidd-ioif -~y -the-
-pre f z4!hium compounds.vas investigated. The reaction
3- Hj+ 3H 0
tudie&iwas CIO 61 + 6.H Cl 2
catalyzea-by divalent-rhenium.
!a6tiqn,-ra e-was a
a-funat on of
t -Wdidd i the-concentrations of the reacting
nt studied, 0.16 N HC1
vas found to be differe in-the- Avo solAitions.-
and The s6ntitfvit~ of the catalytic reaction depends on the state
-in r
of divalent rhenium sulfuric and hydrochloric acid, it is less when stable com
exes o
I f WHY are formed as in the HC1 medium, because the fraction of the cata-
p
PAVIOVA, L.
About good people. Okh. truda i sota. stra". no.6:91.-93 Je '59.
(MI3A 12:10)
(Industrial hygiene)
PAVLCYVA, L. (Lyudinovo, Kaluzhskoy obl.)
Man lives among people. Sov. profsoiuzy 19 no.7:6b..7 Ap 163.
(Hii,A 16;1+)
(Lyudinovo-Machinery industry workers) (Socialist competition)
(Labor discipline)
PAVLOVA, L. (Sokol, Vologodekoy pbl,)
The vorkim is studying. Sov. pro.'soiuzy 19 no.13:24-25 J1
163. (MIRA 16:9)
(Sokol (Vologda Province)--Evening and continuation schools)
- PAVLOVA, L.
How to measure this wealth. Sov. profsoiuzy 17 no.19:4')-44 0
161. (!~:~ 2 L: -- )
(Amateur art activities)
PAVWVA., L. Wintsy)
In the YJA ntsy com unity centers. Sov. profsolluz.v IS no.-I :32-
33 Ja 162. 15:2)
Mintsy-Zommmity centere)
YAVIDVA, L.._ (Bryansk - Hoakm)
A worker and stage-,director. Save profsoiuzy IS no.13:35 JI 162.
(MIRA 15:6)
(Bryansic-Amateur theatricals)
PAVWVA, L.
~Orna ~On ~nuse of a consunerBl good's funde FinqSSSR 20 no-3:
63-66 Mr '59- (Russia--f4anufactures) (MIRA 12~-7)
A 8 -L
AT P W.
X. A. TWulmv" an", A, Nvk 111avlovNIO. Ind
Immwim!). Min, A14:723,"N't
fog MAI(lo 15). ^00
Thr blood susar W." dirld. alter 13-14 hft. of hunset.
(two Itif 0. COW Susaf MA MI)CC. ""or 011T gircts its
0 ir hy1wrtmilve vatirats wAf tht blood %ugw %&- 641"""1
Inf3hrs. Ftent the WHAI vulut d ?O-W ins. ~v tbe l4imad
'Utal ten wilbin 41.5 br. to 141) ,,. r;, tbrn (IrE441"I
Wwly am 2 bra. to lkw Initial Imel, anti thttv to a mildly
hyPoll)wmic 1"d In boallby rub)mt-. In hygvtttnQvv
,*--- (va"s tirpt" gal arterkwIrroalih) Kant *I, itl
juat Wnts- alpmoil diefinior dcLIviallim. Intet. #worms). l'betp 0
1A)*Wd a m**SZ68~04 Imsomm1mv.)
hyinifflYmMil. A31hw2b no LkOn it it 1knOlhip 61%,vil
the lack c4 xvSw rcrablion anti rfin" %yinpimn, tivuld
Ixt "IslAishtd. Tbi% Iwk 01 ftSWalkm 0, timnrcWt sith age
moo
mob
age
use
~Oi
0 00 ft Its 11 ft 111 0 a 9 14 a III It of
0 0 0 0 0 0 0 0 0 0 0 a 0 * 0 0 0 0 0 & 0 0
fo fo fo *1 00 0 00 00 000 0 40 0 & 0 0 L 10 0 0 9
0 0 -*Ole 0
F-*.kTW-V'A, L. A.$
Azwn,thanes I. Hydmlyst.9 of B. A. V. S. 3~
3nd L. A. Pr2vlova (Leningrad Technnl. In~',. : J. Gei:. Chem. 17,,,
. I
(in R~assian)/
For desc,-. - t " -n of process see 'J' bl', - -,f B. -A. F
--AVLOV4,,L. A.
Mr., Lab. Org. Chem. Leningrad Tech. Inst., Im. Lensovet, -cl949-.
"Research on the Conversion of Pinacols with Substituted
Acetylene Radicals: V. Synthesis and Conversion of
Diphenyl-Methyl-Phenylacetylenyl-Ethylene Glycol," Zhur.
Obshch. Khim. 19, No. 5, 1949;
Synthesis and Conversion of Methyl-Diplienyl-Pheriylacetylenyl-Eth3rlene-(.Ilycol
(Sy=etrical) (2,3,5-Truphenyl-Pentyne-4 diol-2,3)," ibid.
Trantlotmationts of r4risrols with substituted scrtOrnk
Isilkslis. VII Synthesis and transtollumbons of methyl-
diplitayliwi-butylpthrityi pelltyleas glytel - 1;' D.
,iml 1. A. il,in-et Icchn,4
Ix"inirr-li. rAui,-ML ki AL. 1 1. c- Cf.-,
20. SLI MMINI); & C.A. 44, Ail-In 4 m4thirl-
1,rill-All Olmn bellill mi'l MCMICII In Hit, 1'. $,,1 It's%' -
C%IlllF,%lHl%nK'2lt-%V-l flu"Uttilliv .-Indi'lltmnig I LvV,
x.tvcb9`; Af,Pkc((Ph)ctmm'hl* CCAle m. 41-5` tJter
1:411,11111 1W.3'. ItollnulAttlettly"d with
I t"rt. :0), , 111M 1. 3 hrvi. C.Sve 1 SJV ,
d,mrlkyl-#-hrpdYm#-:--e, ni. 79 Sl* Iff."n lwtr ribeiv
In. Rml UP; -%I& mollaM b'10
.1, ethich mrimml AS fli.Ithrf b(Illivr After crystin. i9 the
Almove ketone; if 2511' , llSA), t% used I(* the isoriveraLaticin.
the yield of the koone drops to W"; . Thm cmd, kvto tk,
,~mld not 1. da,t~l ithoul decompti. ihv- of 11,0 and
I-A.ly Ah,t king-, . its o%W.,n,-n with KNI110, CAVe
A,Ph, I-nril. 140H. tt..vs A IlCiNII. -trul
OhIl. Ck%m~-ul dehyArAtion 4 thi, jk- .,ei Amotn-
ph,hecl by he.iting it tii 1.76' with an cqu.il vol of Ar,O 1 5
hr.., which ywided bit'
~xr. th., 1.'A1 9* 1 lrmua,t~naffr. f1l.
rhe mucturc %..% ,nfitmcd Ivy mulmim with KNIto t. to
t..nrll. .-.1 %l,.CctWt%jl C. %I K
PAVLC VA, 1- A.
"I, Study of Trunssfornations of Pimcones with Substituted Acetylenic R-Ladic"Is.
vIll. Synthesis and Transforzations of Trimeth 1plierylacetylery! Ethv--Ene
Glyccl (2,3-Diireth3,l-5-flhenylpcntYnc,-4-diol-~~lt3~." by E. D. Venus-Dan3lcva,
V. I. Serkova, and L. ,. ?avlova (p. 221C)
'00: Journal-of General Chenistry (Zhurml Cbshchei Khimii), 1951, Vol,,me 21,
r1o. 12
T-
Alaur-qc-' '0' lh~. attm-turt, a thh~ Etr L-W Oil
-p -it~va, ""d -A.
a tF RIM 1-finrgra
pr(Aw.-Is nal lomwil
art ~CuWii wrw 5
To salts with acili, rd (,,Aomd Cvmp1LmLq wio~
lurid, -pt R.Fv.Clj~ wi I
wme me cit. of the t~ d
aft, Aovll Ift 1) -
Thr
x
thtir basiri
dr
o
i
a
h tmill
o
:
q~
v gr
up
y
y
p
' yanthOl 't
r-6~
hroam;%As
Kw
tcd to
and
l
'-
'
,
HgC1j indurm stmiluz Ermisf(omaLIO-.11. P-111 !"V,
a, th, wtr -:~ I-.,fY,11t Ari'l :f.
of L11C LSC).-nerie tf-.ijjSf'-TnL'ttii)jLE- of ;LC(:tYjCjjjC glycot-, Ivariiij
to --cctyleido ketoixa, by dchydration n, tv
-r n~ %ith p,msibk- furthrr d-
d1hydmfumm by evOi2sfio.
hydianoll t~. sll~"'Lauioj f'lravs if H i_ vvatinbk it, 1"
posltkm, If &hydratinn N impossable, d byarottayl wis
may be famwd (2 mi-Letural formulai arr giveli-
The, e &*ifts, ~*n hydnAyms Pnd; cltavag;~ of the free bail ,
111:1V Inti In ttilyh-mv -oxk~ aft's. Similar sramJ,,,?m,,-
obsurved, lvitil 2- alM 4 oiAj:;li-.1llLxi brutupm-nol,
12 rulertaievs. J. Vvbm
VJURIS-DANILOVA, R.D. - PAVLOVA L.A.; 74-BRITSY, A.
Iffect of the structure ofQ(-glycole of acetylene series on their
conversion. Veet.Len.un. 11 no.16:117-125 '56. (MM 9:11)
(Glycols)
ORLOVA, A.N.; PAVLOVA, L.A.; VEWJS-DANILOVA, E.D.
Hydroxydihydrofuranfi. Part 13: GondenstAtion of
1-hydroxy-phthalan and 5.5-dimethyl-2,4-diphenyl-2-hydroxy-2,1)-dihyd-
rofuran with malonic acid. Zhur. ob. khim. 34 no.10:3265-3270 0 164.
(MIRA -117:.,!)
1. Laningradskly gosudarstvennyy pedugogicheBkiy institut im. Gersten&
i Leningradskiy tekhnologicheskiy institut i-meni bensoveta.
PAVU)VA , L.A.
Condensation cf tertiary acetyienic a-icohcj~,F,
Containing lat rydrogen atoms. Zhur. ob. k-him. 3/.
3270-3274 C, 164. ( M I RA i 'I - ]. ll 'I
1. Leningracskiy teklinologicheskiy institut imeni Lensoveta.
/) '~- )_ " Y /) / I /) 450
AUTHORS: Favcrskaya, T. A. and Pavlova, L.- A.
TI TLE: Study of Conversions of Beta-Glycols of the Acetylene Series.
Part 1. Synthesis and Conversion of 2,4-dimethyl-6-pheny1hexine-
5-diol-2,4 (Izucheniye prevrashcheniy Beta-glikoley atsetilenovogo
ryada. I. Sintez i prevrashcheniya 2,4-dimetil-6-fenilgeksin-5-
diola-2,4)
PMODICAL: Zhurnal CYbshchey Khimii, 1957, Vol. 27, No. 1, Pp. 52-57 (U.S.S.R.)
ABSTRACT: The study of beta-glycols of the acetylene series began with the
most accessible 2,4-dimethyl-6-phenylhexine-5-fiol-2,4 synthesized
according to the lotsich method from diacetone alcohol and
phenylacetylene. The glycol was subjected to effects of sulfuric
0
acid of various concentrations and heated for 1-2 hrs to 70-100
When diluted sulfuric acid was used, a greater part of the glycol
was recovered without any changes and the react&on pm dicta in-
cluded only small amounts of acetone and isopropenylphenylacetylene.
The acetone was determined by the 2,4-dinitrophenyl hydrazone.
Isopropenylphenylacetylene was first obtained by Skosarevskiy (4)
ftring dehydration of dimethypheriylacetylenyl-carbinol. The forma-
tion of this hydrocarbon is also mentioned by A. I. Zakharova and
Card 1/3 Z. I. Sergeyeva (5) during the derivation of chlorohydrin of
Study of Corriersions of Beta-Glycols of the
Acetylene Series. Part 1
450
dimell~hyl-phenylacetylenyl-carbinol. The constants of the hydro-
carbon obtained by the authors of this report were in conformity
with literature constants.
The curve clearly shows the absorption intensity maximum character-
istic for the acetylene bond (4.48,W and for the isopropenyl group
(valent frequency 3.25,A.,,, deformation frequency 11)A); the curve is
similar to the absorpt3.on curve in the infrared zone far phenylace-
tylene and vinylacetylene. It was found that an increase in acid
concentration, tenperature and heating time is followed by an in-
crease in the amount of acetone and isopropenylphenylac.gtylene in
the reaction products. In experiments with a 4% alcohol solution
of sulfuric acid, the authors also obtained a higb boiling fraction
which gave qualitative reactions with hydroxyl, ethoigl. double bond,
revealed no carbonyl groups and its composition and molecular weight
were close to glycol.
One graph. There are 1.1 references, of which 9 are Slavic.
Card 2/3
P/) vl- C Vtl"l ~' I // I
VINES-DAITILOVA. E.D.; IPAVIOVA, L.A.;,, FABRITSY, A.
Study of oxvdihydrofurans. Part 6: Reaction of 505-dimethvl-2,4-diphenyl
-2-ox.vdihydrofurna-2.5 &-nd 2,4-dinitrophenylhvdra2ine. Zhur. ob. khim.
27 no.9:2423-2429 S '57. (MIRA 11:3)
1.Leninp?adskiy tokhnologicheskiy institut imeni Lensoveta.
(Fwan) (Hydrazine)
AUTHORS- Pavlova, L. A., Fabratsy A.
- =, ov~a E D.
TITLE: Investigation of the Reactions of Pir-acols With Sub
stituted Acetylene Radicals (Issledovaniy~, prevrashcheniy
pinakonov s zameshchennymi atsetilenovymi radikalami).
XV. The Action of' Sulfate of Mercury on the Asymmetric
Dimethylphenyl-Phenyl-Acetylenyl.- and the Asymmetric
Methyl-Diphenyl.,Phenylacetylenyl-Ethy'4.ene-,Glyrols
(XV. Deystviye sernokisloy rtuti nn nesimm.dimeti).- fenil
-fenil_-ateetilenil- i nesimm.metil-difenil-fenl-latsetileniI
-etiler
-gl4koli)
PERIODICALs Zhurnal Obshchey K;amii 1958. Vol. 26. Nr 3,
pp, 651-657 (USSR)
ABSTRACT: Using mercury salts the authors have not succeeded until
now in obtaining hydration products of acetylene-double-
L,ertiary a-glycols It was observed that the asymmetric.,
methyl-diphenyl-phenylacetyleiiyl-ethylene glycol (formula
I b) in aqueous as well as in acetone solution converts
Card 1/4 to the earlier described C 46H3602(ref 3) in the presence
Investigation of the Reactions of Pinacols
With Substituted Acetylene Radicals.
XV. The Action of Sulfate of Mercury on the Asymmetric
-Phenyl-Acetylenyl- and the Asymmetric Methyl-Diphenyl Pnenyla-s%_
Lthylene-Glycols
of small amounts of sulfuric acid. It can be as!jum,_-d from
the dehydrat-,on and thp regrouping within the mol~,,-Lillo
that in t.ie beginning a 2 ~ 9 , 5-trlpheLlyl 4-v iny ~ -dihyd ro-
furfurar-4 r. 13 formed which then converts to a dimef'.
analogous to 2.3,3.4-tetramethyl-.2-((t (~) dimethylv:nyi-
dihydrofurfuran-2,.~ (rpf. 4) The parallel ex-jeriment to
convert glycol (I b) with diluted sulfuric acid without
sulfate of mercury was not suooeasful, as waa to be O)Cpec.
ted. The a8ymmetri,, dimethyl.-phenyl-plieriylacetylonyI -ethy-
lene glycol (I a) wag subjected to the action cf sulfate
of mercury on various conditions, In aqueous and weakly
acidous sulfuric acid 5 5-dimethYl (-2,4-d~phenyl-" oxydihy-
drofurfuran-2.5 (II) resulted, in acetone i;olution a vis.
cous oil which did riot have any hydroxyl grcLip and slowly
decolored a bromo- and potassiumpermanganate solution. The
synthetized product could be obtained pure by va--uum d1stil.
lation. The same product resulted from the action of sul=
faze of mercury on glycol in acetone solution. According
Card 2/4 to it, elementary solution and its molecul&r weight this
Investigation of the Reactions of Pinacols With 79-28-1 '9/61
Substituted Acetylene Radicals.
XV. The Action of Sulfate of Mercury on the Asymmetric Di.nethylphenyl-
-Phenyl-Acetylenyl- and the Asymmetric Methyl-Diphenyl Phenylar-E-tylenyl-
Lthylene-Clycole
product could either be an isopropylidpfe derival~ive of
glycol (VII) or that of a condensation oxydihydrofurfurans
(II) with acetone-5,5-dimethyl-2 4-(Iiphenyl--2 acetonyldi-
hydrofurfuran-2,5 (VIII) The attempt to try and obtain
the bond (VIII) by condensation of dihydrofurfurann (II)
with acetone was suc--essful, The heating of the acetone
solution of the compound (II) wish sulfate of mercury lead
to a product which is identical with the one synthetized
from glycol"nderthese conditions. This expe '-iment makes it
possible to acknowledge the compound obtained from glycol
in acetone solution under the action of sulfate of mercury,
as being 5,,5-dimethyl-2,4.-diphenyl-2-acetcnyl.-di.hydrofur-
furan-2,5, The identity of the products obtained from (I a)
ai-,d (II) was illustrated by taking the absorption
spectra in ultraviolet light.
There are 2 figures and 12 references, lo cf which are
Card 3/4 Soviet,
Investigation of the Reactions of pinacols With 79-28 -3 1916 --
Substituted Acetylene Radicals.
XV. The Action of Sulfate of Mercury on the Asymmetric Dimethylphenyl-
-~henyl-Acetylenyl- and the Aaymmetric Methyl-Diphenyl--Phenyla,;e*ylenjI
Ethylene-Glycols
ASSOCIATION: Leningradskiy tekhnolo.-icheskiy institut imeni Lensoveta
(Technological Institute imeni Lensovet , Leningrad)
SUBLUTTED; January 2~ 1957
Card 414
5 (7)
AUT;lc 11 Pavlova, L. A. SCV/79-29-5-7'!,'7r)
TITLE. Investigations in the Field of the Oxy-phthalpnen
(Issletovaniyp v oblasti oksiftalanov). 3,3-Limeth-,1-1-(p-
tolyl)-1-oxy-phthalano and 7~,3-Di-.lethyl-l-(p-pnio,,,I)-l-oxy-
plithalane
1-(p-anizil)-1-oksiftalan)
PERICDICAL: Zhurnal obshchej khimii, 10,59, Vol ?9, Ir 5,
pp 1~F30-1592 ("3',R)
A33TRACT: Substituted ox:,7-phthalanca react both in cyclic form. \'I' ~~nd
in the form of o-ncyl-benzyl alcohols (TI) %'Ief2
il-, IQ-,T'3 M R
9 - C"- C -I- C"-OT1 R-- 41"). - R3
2 4
For both kinds of reaction dcta were available in piblications
(Refs 2, 4, 5, r,, 7). According to their aibTtituted
oxy-phthalp-nes resemble 2-oxy-dihydro-fur,--ns -,hic)-.
obtained and investigated for the first time by ':. D. Vqnus-
Card 1/3 Danilovq and her corrorkers (Rofs 8-10). t,13o ox~-Iih.,,,dro-furans
lnve3tig,ationo in the 7-iild of the OXy-~)hthal~~neS. tZCt' f-79-2 11
3 , 3 -Di me t Ily 1p- t o !.-.!I -o xy- ph t h,,~ I ane an(I 3 , 3-Di me t hyl - I
o-4y-rhthalane
ren.ct in ,7ays. Besidec, thoy have the irti~rer-.rr
capability of salt formation. For this renscr ir, Trpsmnt
paner the asnumed basic properties of the r;0),,4tnnce:-,
mentioned in the title rern cheriked in this irticiro. 7~,,e
preparation rni carrici out b7,, reaction of
with mt-!~neoium-(p-tolyl )-bromide and
respectively. For
the autbor obtained "'he perchlorate, ferric chloride, nd
ctr~nnic el,loride, nnd the perchlorate, ferric r-,hlrjrid.,,. and
T)icrate for the p-anisyl compound. The infro~.P-d sp,,~c~r- of
both initial compounds as well as that of 5,1. I-idmethy!-2,4-
~iphenyl-~'-oxy-dih,ydrofuran-2,5 (Pigure, takon 1) 'y T. 1.
Yakovlevn) showed no frequencies of carbonyl Croups. ?he
OXI.-PlIth-icnon primarily occur in cyclic struct,!re (P.,3 0--~Y-
dili7-iro-furanq), Pocordinirly. Publientiona of ot.hor roithnrs
(Rcifs r,, 10) ,3howel that 2-oxy-(Iihydro-furana-',5 taro to hg
regardod ivi five-membered analogs of the compoundn of the
seric3 of chromenol, flavenol and xanthydrol.
oxy-phthfilane3 should, accordingly, br! P-dded t-)
investipations iri V,e -if the Oxy-plithalanen. 3CV/79-29-5-71; /7:~
71 P-ne !ind 3,3-Di-Iethyl-I-,r--..nis--. -1-
-AIriyl-1-,'7--!r)I:-I )-1-,--y-phtn,-_l
r,xy-nhthnlrno
of connoun.ls. The experimental part givec tl~e -)f the
ini tir I co:~-\o,_,n-I -- ~,ind their RP! tl , '-he i in i ",-o- -I- rn -.,I -
'-,.vdrPzones !7nd se-nicrrbozonos n,i -rell ns 'ho nril
(!R+a. The stuA,~ritn v rl n J n
assiate! in the3e 9%Derimento. Thcr(-.~ rro 1 fi-_irc ani
17 references, _1 of which are ?oviet lclis'.
A S C I T I r 'I Lenin-rtidqkiy tPkhr,_-lopicheski1 inctitut
(Leninerrad Technolo~7ical :nsILi+,:tv i-rni Lpn- vet)
3'U.9%!ITTI7,D. DecenbGr 31, 1957
C a r d
5.3400
SIDV/71-j-
AUTHORSi Favlova, L. A., Orlova, A. N., Venu,'3-D-inllovit, D.
TITLE; Concerning the Condensation of 3,3-D1m(Ahv1-1-P1~,
Hydroxyphthalan and
dihydrofuran-2,5 With Acetic Anhydrld(,
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol 30, Nr 3, PP Y35-'(111:'
(USSR)
ABSTRACT: This is the continuation of investlgation~3 of the con-
densation of hydroxyhydrofurans and hydroxyphtlMlari:3
with acetone, phenylmethylpyrazolone, and other corT-,po~.inds
this journal,Vol 26, o 8848~1956); Ibld., V( A, , i -, 6 5 1
~; en t
R958); ibid.; Vol 29 'p 15 (1959). It, the Pre, -
study, 3,3-d:Lmethyl-l-plienyl.-l-hydroxyptithaliii (I) -.,.,a.,:
condensed with acetic anhydride on boilinf7 for 4 hr in
the presence of pyridine. The reaction gave (3,3-
dimethyl-l-phenylphthalyi-1) acetic acid (II, yield 35%;
mp, 106-1070 C, from ethyl ether + petroleum ether) and
o-isopropenyll)enzophenone (IV, yield 52.425, mp 112-430 cy
Card 1/5 from methano! dilute). The latter was l'ornied as a res,ilt
Concerning the Condensation of 3,3-Dimethyl-l- 78251
Phenyl-l-Hydroxyphthalan and 5,5-Dimethyl- SOV/179-30-3-551/;-~9
2,4-Diphenyl-2-Hydroxy-dihydrofuran-2,5 With
Acetic Anhydride
of the dehydvrtljon ol' thu ojwii hydroxyhot,O-roi-111 (11i)
of phthalan 1.
c1l,coocnC1,11.
113V
0 I(C \0/\ (1611,
(C113M" ~-C,61(, C113C C-Cell,
Card ~/5
Concerning the Condensation of 3,3-Dimethyl-l- '78251
Phenyl-l-Hydroxyphthalan and 5,5-Dimethyl- S011179-30-3-151610
2,4-Diphenyl-2-Hydroxy-dihydrofuran-2,5 With
Acetic Anhydride
The condensation of 5,5-dimethyl-2,2~-dtp)ieri,yl-2-oxydi-
hydrofuran-2,5 with acetic anhydride gave (5,5-dimetfiyl
2,4-diphen 1-2,5-dihydrofuryl-2) acetic acid (VIL, mn
137-1380 C~, and not acid (V) as suggested previously
by the authors (this journal,Vol 23, p 681 (1953).
C0011
M
0
M)
Card 3/5
Concerning the Condensation of 3,3-Dimethyl- 78251
-1-Phenyl-l-Hydroxyphthalan and 5,5-Dim- SOV/"(I)-.*51----3-5/69
ethyl-2,4-Diphenyl-2-Hydroxy-dihydrofuran-2,5
With Acetic Anhydride
I Is - C ---- C I I clell,-G-cil
Oil call,
(('113)2(: (YCll, (C,113)2~
0/ \Cll,(,Ooll
\0
(VII)
((',0011)2 +
I
0111 8 (NIIII)
CO, C4115cooll + Cll,corooll
C
a
oil (X) Oil
(2)
c, 11,
I
CIII&COOll + 110OC-C-012cooll
Oil
I (I X)
I
C'GllbCOCOOll + (CoOfl)2
Card 4/5
Concerniii,, tire Cuit(it q,
Phenyl-1- I Iydro:-:.vn I it! i,-. I:, n ;~,r: i
2.,4-Diplieiiyl-2-flydi-.-;,~y-,.iiiiycil-~)i, 'Al
Acetic Anhydride
The struct.~ire )f' VI ,(,jifInv2d ,ts
oxidation with pktai3z~Lii;n
product of th~.- oxidrition, the hydroxylf-,t' 0-a,,,ld W,
could not, IC --1,3 it oxIdI:,(2d rapidly I.-.
dIrecI-.Ioii;; formliq,: (1) diberi;~oyIni,,-th,irif, (VIII,
39~%) arid oxallo :irld C--phenylin,ill- ~jr,j(j
(IX, yi,~ld 1O.Y1%) -i!icl 1),-,n:~olo u(~Ld. Ther-, ar-
r2-ferences, 2 U.S. , 3 U.K., 1~ Fi-ench, I Dutch, G,rrr.'ir
1 C~,cch-)nlovak, Y 'J'o v 1, ~ t, .Tht- U.S. and U.K.
are, J. B. Nledrl, W. F. J. Am. Ch(-,in. S~,)'
J. Chem.
719 (1937); J. E - IS) I-) c3Yi ~1~-i,
E. B. Barnet. t, J. 1-1 . C o:-' 1. 0. NIxon, J. Chum.
5011 (1927); E. ff. huritr~?so, 11. C. Walter, J. Am. Chc~n~'.
Soc., 70, 3702 (1948).
ASSOCIATION: Lensoviet Leningrad Tt~chnolo~Tlcal Institut,(-
skiy telchnologicheskly Institut imeni Lensoveta)
SUBMITTEDs December 30, 1958 Card 5/5
PAVLANA, L.A.; VENUS-DANILOVAS E.D.
Hydroxydihydrfuranig. Part. 7: Condensation of 5,5dizwthyl-2,4-di-
phenyl-2-hydroxy-2,5-dihydrefuran with diethyl malonate. Zbur.
ob. khim. 31 no.4:13.50-n54 Ap 161* (14IFA 14: 4)
1. Leningradskiy tekhnologicheskly institut imeml Lensoveta.
(Furan) (11alonic acid)
I ~
SAVTCH, I.G., ffl.LFN7'Yi-,VA, T.1-1., ., ,
Study of hydroger 'r,-:ndiro in ny-4- XY,h,:,)-,alanF?B brv
spectrcsccopy. -t. 3' n n. 3 ~ 41 5-,L19 Pr ' ,I I
( VU -~ . 0 ; 4 '1
1. I-.eningr-,d4xjy tcyJ.nolog.,,~)-sy-y Institi-,t Imeni l,ens(,VeUi,
~D-'i~ - f. --N A. G, V. ; A, V A, ,
.1. m .
qtr.; --t ara -. I -,~ " , " . -a, . -!. - r ~-, 2 : - .- . 11 : . ',:-
1l,)-54:103- .;?~ " .
111.11-1-10VA, I...k.i
)ivr,l r oxv j ;; o- n,-' r- '. -, -j e s ,Part 3.,:.7 /-,, 1 - : --, I s a rrj p r:) p e r t A t- 3 -- f
14 ~ 5 - d Iv e t 'j- I - 2 q).h e ny I - I - p - t c, ) y I i -?~, v (I rox y I sr) I n d o 11 n e, 'nur.
orz, khf-m. I no, P,, l4q~- 1499 ~g 165. (wo !P,11)
1 . i ~nin~radslr."7 I ':?I c"' - XiY Ins t' Lul. imen I 7-p- ~ - - ' I
. . I
400,V---SOURCE-
AUTHORt Kuslain, Ke I*; Favlovas L. As
ORG: Kazan Chemical Technology Institute Los So He Kirov (Knasnskiy
khiulko-tokhnologicheekly Institut)
TITLE% Acetylenic derivatives of arsenic
SOURCE: Zhurnal obahchey khinti, v. 36, no. 6, 1966, 1476-1480
&1UR4%kL,
TOPIC TAGS# bledialkylarainoacetylene, - ---A so., -, acetylene
4AtxA- 0
ABSTRAM The five previously unreported bia(dialkylarsino)acetylenes
were obtained by the reaction
BrM61C~-CMgBr + 211,AsJ ---w
Composition and constants of the new coupounds are given In the table,
Origo arts hass I tables [W.A. 501
car~L_ 1/ 2 UDCi 547*312+661.718.2
ACC NRs AP6028904
yield JAP#jA At
an) (in 1) , ca Is,
W"w
W-160 16) us
43' m
115,63 LOW)
I.IISI 91
Ito:45
!
11.10 42.2$
37.v
134-136 I
3D.
01" 110 DD
* 11 .3 30.90 SIX
1"-1" 17 t.6103
6343
1 :(4m
MW 129
W,
13 N 32.4D
39
U sa."
ISM
. .
&Vegas
SUB COVII 07/ SUBM DATRI 03Jul65/, ORIG Mrs 001/ OTH REFs 002
Card
wi~
1101-67 TU!, __ -
ACC W7,-AI,7003665 SOURCE CODE1 UR/0079/66/oat)/003/1.1,7,~/1",k~,,.,
AUZIOR: Xuzlmin, K. I.; P~Llowj L. A.
ORG: I~azan' Chemicotechnological Institute im. S. I.I. larov (1~azartakly
kk) iml ko-teldinologi cheak iy- ins ti tut
TITLE: Acetylenic darivatives of arsenic
SOURCE: Zhurnal obsachey lchimii,v. 36, no. 8, 1966, 1478-1450
TOPIC TAGS: Grignard reagent, organic arsealc compound
ABSTRACT: Five new bis(dialivylarsine) acet:y1cne3, not descrlhc~d in
literature, %;are synthesized by the maction of a Grig-nard reagent pr0;)ar'c!c;
from ethyl bromide and magnesium with acetylene, followed by trcatmcn', With
dialkyliodoarsine. Tho atomic refraction of arsenic in bis(dial,-ylarsine)
acetylenes vas found to be 12.43 on the avera&e. ~g?I~S: 36,97g
SUB CODE: 07 SUZIM DATEt OUu165 / ORIG RE?: 001 / 07H 00'
,-Card UDG., 5-47,312 + 61.7_1~.2
NELENTIYEVA, T.G.;.PAVLOVA, L.A.
Acid-base con-7ersions of hydroxyphthalans. Zhur. -,*-. ki.im. I
no.10%1739-.742 0 165. (miltA lp:]-(-))
1. Leningradskly tekhnolog'rheskiv Institut impnf L,-nc,Sov-ih.