SCIENTIFIC ABSTRACT PAPIROV, I. I. - PAPKO, S. I.

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SCIENTIFIC ABSTRACT
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-2LU ACC NRs AP6028715 SOURCE CODE; AUTHOR: Papirov, I. I.; Smyr-nov, Yu. M.,' Tykhyns'k~-y, Ii. P.; Firikel', ORG: Physicotechnical Inatitute, N Khnrk-iv AN UR= .-_ _A_ _Y~Syl . - TITLE: Solubility of cerium in beryllium qI SOURCE: Ukrayins'kyy fizychnyy zhurnal, v. 11, no. 8, 1966, 922-923 TOPIC TAGS: a .44 - - V 1. " 'Al .0 6f ul 1 imy", , _4 id ;,_1:i soz V 43 1,4 7'Y AR-rreee_ P49,eq;nerEe , 0,0e)e4&;(,Pfn ~&d_ov 3 CeRIUM (10A.)7_490A)AIUC 'q-' 0 Y ABSTRACT: An attempt has been made to determine the solubility of cerium in berylliLan by measuring the/fattice parameters of a beryllium alloy containing 0.35% cerium over -te at Icam, Fig. 1. Solubility of cerium in beryllium versus temperature 4w :j a&p Ewdu L(q~d i 71-1 Oil -"b FALATNIK? Lev Swnoylovich; LAjjI(OV-, Igor' junaliovich;,LPNMI,ll'bj G.G,, prof., retsenzent; ChEUOV, A-A., lcan6. fiz,-mat, y naux. rets-enzent; MIALITSEV, M V, , prof., retsenzent; I CHISTYAKOV, Yu.D., dots., kand. tekhn. nauk; nauchn.red. [Oriented crystallizationl Orieritirovannaia kristallizatsiia. Moskva, Metallurglia, 1064. 40'7 p. (MIRA 17.12) IVAIOV, Vik-uor Yevgenlyevich; PAHROV, Igor' Isaakovich; TUMNAPf, Gennadiiy Fllippovicb; L?,10NrYY,), Vasiiiy si ma%. 1 c h (Pure and ultrapure metals; preparation by the method of distillation in vacuum] Chibtye i sverkhchlotye metal2y; poluchenie metodom distilliatali v vaJniume. Moskva, Me- tallurgida, lq65. 263 p. (VIEA IC-.12", 1 /EVP(t) IJP(c) JDIJW L 25563--6E W(n) ACC Nib AMSW474X Mwcgrapb BY-1 Mo Pap ~i VMor b lr~ ~~w ~1 7:7 sugm- ware wbale production by the netbod. of dintinatio in a vacuum "A:- everkhobistyye netaUy- poludbenlye ustodom- d1wt1:U7&t9k11 v va~) -1965 26 3 p.: Miwi~ biblio. 3j.1W copies TAGS t ,Vaculkiv distillattaip Ilikal vapor depoo-Ition, process ''TURME An COVEMM; 7he book presents the theoretical prinalplea of the separation of.: -.9yaPoratidn, calculations -.oUd1fferwt.bInzz*:a"Uie systems, and a q"AtQ%1WJ!VUM shorttool f Abe notbod of obtain me netale ion In vi6luum - ~: The a t Up- 16, distm betals and the teebnology A., i ion, are dibicrited.-l'. TW: reirults of cry tests'an purification of -*at, am- 4i" -4i lm C011. me istinat oq0, 'a parawters -'of 06, ajoarstus, the opmt Alti~qzu 46i- iiii. processes,, and.also en my cial i:nst%Uxt1=w- for -vacuum distilUtions --dorteld A'An-dWEA41 IBM fare li'.depitned. jor- -.413mrize, sirtallurgifts ryo,- , additlon~.. It em be, now: pWalcs and aa-: bb :4ii' in *60iiis I MIA at senior stliifti: wa, hi,61natitatiam of Iftralwo VFV ice 5 :V2 IM 669.035.4 Y Plant ijia-as,~ls. Guitivaue-d Planta. Nn. AUTHOP Vq., Mardam, 0.,*) Eial-.atu ;a. , , 1~rvasaaui .4'~,h~ottr 3f Cn:ibuttlng tlie NiLdaw Df 'rrape Plants vitc, L.-,c r-'j of ti-v Prepar~tic:r-3 ~3 a-rid T5 in the 6~,immar of nFarl, -uB. I ntiix,t- inst. a,~run. Iasi. kiol;rosti, iABSTIRACT 'ITno res'-dts of tfroe-year -Wats have ihowa ttat the affect of tne pr-app-ratioao T3 (tiuodine) aad T~ Is -a-1 P-ort d~uz-itlrn. tiey are easily washed off by r-ain-i ~ar~a urr, x-lor rne of t-ij Sun nti -. 'Ehey &r it fur '-Lhe =,Arol of ml (~ew. 1, 1 -mr., -,j.,.3 carr' ed o~A at the ichoru &L' Ai-,.e PAPISEVILI, V.I., inzhener. Improving a 127 a. rotary klln. ?Se=nt 21 no.1:8-9 Ja '55. (KllnB, Rotary) (MIRA 8:4) EARGIB, V.A., akademik; KARA OV, V.A.; ZUBOB, V.P.; PAPISDI.-I.M. Fol7merization of acetone. DokI. AN SSSR 134 n0-5:1098-1099 0 160. (XIM 13: 10) 1. Moskovskiy gosudarstvennvy universitet im. H.Memonosova. (Acetone) (Polymerization) 84828 22D I 0-~ S102 YB 60/-.34/0C)5/()-4//023 Bo16 054 ATJTHO-ISi Kargin, B. A I Academician, Kabanov, V. A , Zubov, V P~ and Papisov, I. M. TITLE-. kclymerizationqof Acetene PERIODICAL, Doklady Akadamii nauk SSSR, 1960, Vol, 154. No 5, pp, 1098-1099 TEXT; On the basis of an approximate estimation of the theTmal effect -f the polymerization of carbonyl compounds. for instance of acetaldehyde C~r acetone, the authors find that this polymerization is impossible in the homogeneous liquid phase, The picture is, however, considerably changed if the transition from a monomeric liquid to a system of arranged monomer molecules is effected in the initial state, i.e. if the entropy of the initial system is mu,:h reduced.. One method of molecular arrangemen- iF freezing, Here, the entropy of the system is reduced during crystallizatic., by the quantity of the melting entropy This reduction in entropy gives rise to a reduction of the negative polymeriza4ion entro-d wM:h. at sufficiently lcw temperatures, may even change Its sign In this case a Card 1/3 84828 Polymerizaticn of Acetone S/02 60/134/005/01,4/02~) B011 6YB054 p3lymeriziition accompanied by a negative thermal effect would be possible Guided by such considerations, the authors attempted the polymerization cf acetone on the double bond C==O by their method (Refs 5-7) The experi- ments were carried out in an apparatus and by methods of Refs 5,6, The initialor used was metallic magnesium whose V,IpOrS Were slowly condensed 'in vacuo together with vapors of carefully dried acetone on a surface coolled with liquid nitrogen. The ratio aceton-3 4. magnesium was about 200 ~ 1. A vitrified molesular layer of an acetone-magnesium mixture was precipitated as a 3ondensate on the cooled wall, With growing *hickness cf this layer, the temperature of the surface of this vitreous layer finally reaches a value at whi~!h a spontaneous process of coordinate77egrouping of monomer molecuI96 is setting In in the ab3ence of_17_niti~tion centers. this process would lead to a crystallization of the monomeric glass An instantaneous polymerization sets in however. due to the mobility of particles originatirg _n the phase transition I'disorder - ordero The same phenomenon is observed in a gradual temperature increase of the wall used for the condensation. This leads to the formation of the acetone polymer, an elastic white substance which is !,oluble in its own. monomer Polyacotone is -rery unstablo at room temperature. and decomposes --ntc. Card 2/ 3 V"V~v Polymerization of Acetone S/020/60/134/005//C)'4/0211, B016/BO54 acetone, e.g. when ground between the fingers. The most stable pclymer samples "exist" without oxygen and moisture for a maximum of 10-12 h, Howeyer. traces of vinyl acetate increased the stability of the pclymer to a certain extent. Qualitative considerations on the formation mechanism of a polymer chain in an arranged system of monomer molecules have recently been made by N. N. Semenov (Ref- 8). It appears that stabiliza- tion of polyacetone could be achieved by blocking the active enis of growing polymer chains. This indicates that substances not polymerizing under the usual conditions, might polymerize 4~f a preliminary regular arrangement of molecules of a monomer were achieved eg,, by a solidifi- cation crystallization, as in -,he case descr2bed above There are 8 references; 5 Soviet and 3 French ASSOCIATIM Moskovskly gosudarstvennyy univarsite t 4M. M V Lomonosova (Mos-cow State University Imeni 19 V Lomonosov) SUBMITTEI)i July 23, 1960 Card 3/3 KARGIN, V.A., akademik; KABANOV, V.A.; ZUBDV, V.P.; PAPISOV, I-M-; KUROCHKINA, G.I. Polycondensation of acetone and other carbinyl-containing compounds. D01,1. AN SSSR 140 no.1:122-124 S-0 161. (MIRA 14:9) (Carbonyl compounds) (Condensation products (Chemistry)) KAMIN, B.A.; KABW" V, V.A.; ZUBOVj, V.P.; FAFISOV._ I.M- Initiation of low temperature polymerization in oystems obtained by the ntolecular beam method. Vyisokom,sovd, 3 no.3W6-43,4 Mr 161. (MW 4:6) 1. Mookovskiy gosudarstvannyy universitet, imeni M.V.Lmonoscrva. (Polymerization) (Molecular beams) "o1 tol all )o OIA14,\ fla by. r 0 c a,(,6 ,6 Ob et OL, -'- I e,(,e 014 'a 0 (3, 1j" I 'E~,- O'f~e *1 go 0.0 . ec% r -r0 S,~o 3 6.e - r Of~ e Ii e T e t5 0~ 1,69 eG alffio\.If e )Ole 'te a,' e -a~)a ov"? ONX T 6 r qt'.~ 460r~e; ja .c e - ( ['Ge T-fle 13 PT OT" e tylers) -COV69 T.~O, re vro al al~6 0 ce, Ot Or merS dP- 9o%% 15ecl 2 O'Do qoy~o os'~ oJ 2, S dlelA gr e of "1 70 a -ogf~ e t al t'll e 'bl~Cl Z' -~ eS 5 0 ,c e Ga as -be's s,01 e eT 5' r 5 T 5 at ty, Oet Oy 0 C,65 a 0 I~c CO ~96 0 -fs 'o ?,-C Ot;,T~6 e f~ 5 'Pave 0 e -~ 0 9 ~9) te e'~ 't ~ 0 ec'~~ 9 1 ' C~ 0 V'e-f e Oo s5es 6egrp roce . ~~9, r %1(~ e oler-k1lo. ( 0111'r 27878 Polycondensation of acetone B!03/B',O-, position of the monomer molecules may lead -o very high. often explosive polymerization rates of solid monomers, even at very low temperaturf-.s S, M. Skuratov's data (A. V. Volokhina, G. 1. Kudryavtsfv, S. M Skuratov, A. K. Bonetskaya, Internat. Symposium on Ma-,romolecular Chemistry, Sect-ion 2, M~ 765. 1,960 p 465) indicate tnat this order must have an effect also upon polycondensation The authors achieved the polycendensa- tion by heating the reactant mixtures ~n sealed glass ampuls or in n autoclave with exclusion of atmospheric oxygen to tempEratures from 70 to 2500C. This reaction can be represented ir. a general form by the e~ustlon- R - R I H20 1 n C ~0- CHM ----A G- In this reaction, acc-aidenyae DrD(,u(-,--s poly- n Ud3 acetylene, acetone produces polymethyl ace-,ylene. ace,~cph-ncne 2roauces polyphenyl acetylene, and so on. The polymers obtained are dark-brown or black powders with increased heat res.,stan,-e characterist2c of high- molecular, polyconjugate systems They dl3play sem1conductor properties and characteristic epr spectra. The solubility of polymers in organin- solv,,nts such as acptone or benzf-ne. d--~pends Dn the degree of polycon- C a r,~ --/4 27878 /020 rl/140/L-01 S A Polycondensation of acetone. B103/B101 densation; they are soluble at low degrees but unsoluble at high degrees. The degree of polycondensation and the yield of solid polymers rise with increasing amount of catalyst, temperature, and reaction time. The struc- ture of polyvinylenes is confirmed by infrared spectra. The spectrum of polymethyl acetylene (obtained from acetone in the presence of ZnCl 2) has many features in common with that of polyacetonitrile which. according tD its structure, is related with polymeLnyl acetylene, A wide, intensive band at 1 93 cm -1 corresponds to the absorption by the system of conjugate C-C bonds. Thf~ bands at 1352 and 1380 cm- 1 may be ascribed to symmetric deformation vibrations of CH 3 groups. The band at 960 cm- 1 corresponds to nonplanar C-H vibrations in the principal chain. An extensive poly- condensation of carbonyl-containing monomers can be obtained by previous o:7dering of monomer molecules in complexes with metal halides unsaturated with respect to coordination which simultaneously play the part of de- h2rdrating catalysts. Thus, various heat-resistant polyvinylenes of a considerable molecular weight can be produced. There are 1 figure, 1 table, and 11 Soviet references. Card 5/4 /cc ~,/c 7 ALITHORS; Sses TITLE. R :_na6e r , -.Mr 3 7 PERIODIC-IL ; s5sh lcw teml-erP- state at TEXT~ Th%: jr r f (me' ~-~ni tri poln, - r is ~ ls uss~i i C, ~I y ntc L platf: tunes b i_- ,i. vacuo o , a nd -; c3c~.Ied witl~ 1 q h -h lWaG q f x as rem,)v w T h was :r s u r',~ I w; t Y; y c i t". an 3 n n r 3 . h F.; 1 1 t! :~' : Ik -rau, f nor- 4 r Th~2 eff(-(,t s, f tj ,ard 30701, S10"OV61111411002IC', 6/0.-' Role of phase trans-"i-ns BICI/x'147 1600C ascribed tc the crystal-Ij-zat --f Ltr~nomer glass on reachir- Tamman temperature . The effect ') bse-~va*hle -1350C, and the reason -i:,y polymerization sta-~ts on~;e at 1600 and --~n~,e at -1350C, are still unexplained. At -1350C a secondary, additional orientation of the reaulting ml-~roir5Fst lline substar,~e take place. The two transiticrz-: are irrevers-4bie. In m~-thylu~ethacryla~c- ;~rd ;M-g condensed onto a glass sphere whiih was c-,oled to -75~-"C (apparatua ciescribed in Vysokomolek. soyed., 1, 265 (19rj9)), the polymeriiattrii in pola-rized light could be observed due t,-:t birefrini~er-e J t)-.t: -ci,ystals. At this temippra- 4ure, the mole-,ules could already m,-gratf- anr- add to the forming r.:'5'B tall JL zat.1 on nuclei.. Spherollteo ziurf. ln.-iiad. The characteristic Maltese sross r=li clearly t-e I.,; %tiiE. sy8tem, slow polymerzator. took place. It began at the edges of tl,,- and in fissures. Shifting of the crystal polymer (ould be observed with the of birefringence whi.-h vaniahad L-)3prvr-,zation. CC)ntral,j t, 11. 1~ Semenov's hypothesis (Xhimija i tt-jkLn(!,)-,;!Ya rolimerov, T1(- 7-8, 196 (1960)) thrit raT.-,,..d tukr-j 111acE preferably Jr, Ideal crystals, experimental data show,~d tha4 thii3 offect or-curs in defect. crystals while ideal -ystals p,llymeril~~io Lattice defe~.ts are Card A KARGIN, V.k., akademik; EAMOV, V.A.; PAPISOV, I.H.; ZUEOV, V.P. Role of phase transitions in the polynerizati:)n of monomers in the solid state. Dokl. AN SS6R 141 no.2:389-392 N 161. (MIRA 14:11) 1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomon3sova. (Polymerization) 69991 S/190/61/003/OCJ3/007/C'4 B101/B204 AUTHORS: Kargin, V. A., Kabanov, V. A- Zubov, V. P., Papisov,I-M. TITLE: Initiation of low-temperature polymerization in systems that have been obtained by the molecular beam method PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 3, 1961, 426-434 TEXT: In earlier papers, (Ref. 1: Vyeokomolek. soyed. 1, 265, 1959; Ref. 2: Vysokomolek, soyed., 1 1422, 1960; Ref. 3: VyBokomolek. spyedineniya, 1, 1859, 1959; Ref. 6: Vysokomolek. soyed. 2 303, 1960, Ref. 4: V. A. iabanov, Thesis, MOSCOW, 1960) the present authors showed that a few monomers when condensed together with metals, inorganic salts, or oxides may enter polymerization upon a cold' surface at the melting temperature or even below it. When the usual methods are used, these substances (metals, salts, oxides) are absolutely inert. It was the &im of the present investigation to disclose the initiation in these systems. A) The systems monomer + metal: Rapid, explosive polymeriza- tion was attained by simultaneous condensation of vaporized magnesium and Card 1/5 89991 Initiation of low-temperature S/19 61/003/003/007/014 BlOIYB204 acrylonitrile, methaorylonitrile, methacrylate, isopropylacrylate, methyl methacrylate, acryloamidq, methacryloamide, butylester of ethylene sul- fonic acid, dibutylester of vinylphosphinic acid, formaldehyde. acetalde- hyde, and acetone upon a surface cooled with liquid nitrogen. The authorB employed the arrangement shown in Fig. 1 in order to explain this mechan- ism. This apparatus may reduce the overlapping of both molecular beams in the gaseous phase in the case of simultaneous condensation of the monomer (1) and magnesium (2) upon the cooled surface (3). It was found that in this case a polymer does not form. Thus, polymerization takes p2ace only when the vapors interact. Prom epr spectra it was found that fTee magnesium-organic radicals form when magnesium and acrylonitrile vapor are condensed simultaneously. The analyses showed that the poly- acrylonitrile formed under these circumstances contained Mg which could be extracted by hydrolysis with diluted HC1. In this case, the molecular weight (130,000 and 1!0,000) dropped to about half of its former value, Prom this; the authors concluded the following course of the reaction: ME-CH 11>~ CHO + (n - m)CH 2- CHCN (-CH 2- CH-) n-Mg-(-CH 2-?H-)m,l CN Card 2/5 695,91 -nitiation of low-temperature_ 5/19 61/005/003/007/0114 B101%204 Further experiments showed that also atomic hydrogen initiates the poly- merization of acrylonitrile, methyl methacryi4te, and styrene- 'Chen Mg was heated on a tungsten spiral up to 2500"C it reacted also with less active monomers, as vinyl acetate. In the same way Zn, Cd, and Hg could be activated. The authors assume that., similar to the results obtained by Steacie (Ref. 9: see end of abstract) and Laidler (Ref. 10: see end of abstract), initiation is due to the excitation of the metal atoms: CH 2. CHR-Me* 0 MeH * &H-CHR. Lead or tin vapors do not initiate the pollymerizatlon of acryllonitrile, but even hinders it when Mg is present, due to an addition of the free radicals. B) The systeMB mino "er .4,,. a~t ,~n awnomez :~,OA'W Joint condensation of molre- ~u 'bea*ms- of 6tyrene, a-methyl -AfYi9nd,"6-r isoprene with water-free BeCl 2' ZnC'2, TiCl 39 and of the first two compounds with MoO leads to a rapid polymerization near the melting point of the intqns2y colored molecular mixture, The forma- tion of n complexes with double bonds is characteristic of the mentioned oxganic compounds. They only initiate the polymerization of monomers which contain a dense electron cloud at the double bond. The authors assume a cationic mechanism, according to A. R. Gantmakher and S. S, Me-dvedev (Ref. I: Vysokomolek. soyed. 1, 1331, 1959). Perfect cristals CE.rd 3/5 ami Initiation of low-temperature... S/19 61/003/003/007/014 B101Y1,204 of these catalysts were not very activeg wbereas polymerization could be brought about' at room temperature through vacuum-vapo-rized crystal films containing enough surface defects. NaCl and KCI do not initiate the polymerization of monomers with electropositive subBtituentB. How- ever, with negatively substituted monomers, as acrylonitrileg.polymeriza- tion oc6urred below the melting point of ackyloni-trile in the case of joint condensation, when the salt was.heated by means of a tungsten spiral. This process is explained by a partial dissociation. Small regions with non-stoichiometric metal atoms in the lattice aro~ forming, and thus P centers which initiate polymerization by giving their electron to the monomer and forming an anionic radical* As the ionization potential of the F center (2.2 v for KCI) iBJOWbr than that of a free-atom (4,3 v for a K atom), these P centers are intense initiators. The phase of the catalysts and initiators of the investigated systems depends on the ratio of the aggregation rate of the molecularly dispersed catalyst to the rate of polymerization. Thus, a continuous transition from homogeneous to heterogeneous catalysis may be attained. In all the cades investigated the processes were found to be highly specific due to the nature of the monomer and of the catalyst or initiator. There are Card 4/5 KUMIN, V.A., KAEANOV, V.YA., PAPISOV, I.M. Effect of phase transitions on the polymerization of monomers below their molting point* Rkiport submitted for the International blymposium of Macromolecular Chemistry, Patris, 1-6 July 63 PAPISOV, 1!~ M..; PISARENKO, 7'. A.; PANASENKO, A.A.; KABANOV, V.A.; r,f,Rr,IN, V. A... akademik Nature of the initiator and the phase state of acetaldehyde ar influencing the chemical struct,.re of macromolecules formed during acetaldehyde F.,clynorization. Dokl. AN SS:~R 156 no. 3:661!-672 164. (MIRA 17:5) 1. Mookovokly gosodarstvennyy universitet im. M.V.Lomonosova. 'd .RIF, i , iI ~ I ...... I I I ` ,l I I I ~L 1,11'.. ~ I I i ~? mmli~, .- 11 ,u m-, imm ml r "" 1, ~'N )AAWA(CY. RPL WXj W/ -NA 6611RCE 60DE: ~Vpl ps?~~WOWWA779/1786 to) All 1. Hoj.Kebanova Vi ~Aoj W Ini ~-Ve k rw "AUTHOR Maier' quoso Mo a 60w 211.X Lom AS In K OMskovskly All gosu , aratvenny-T universit,et). TITIEft.. Conditions for the onset of rapid Pol erization'%elow the a -L 1z monomer melting points* Rapid polymerizatl�Maesr~Wl explosion SOURCE-.;-.Vysokonolekulyarnyye soyedinenlyas, v,, 7,, no& 10, 196.5,9 _177911706 -TOPIC TAGS: pol7morization, polymerization kinetics, meth7lmetbacry- --:late organic nitrile compound .:ABSTRACT: -The,investigation of polymerizing frozen ers in thin TWU lay-er a-. In, continued In this studywitb scr*lonit lje~ JiietbZlmet]2acry___ r-46 1. ateVend serylonitrile-prORlohitrile-.nixturese~, Tbe~dependence of the eurrez p! -sly ~oc iciB of , ex 0 W. polymerl ge iion In systams produced by simul- ;.aneous freezing of monomer and-Initiator (magmealum) vapor upon the thickness of 'the condeniaii. 146r, I~Itlatoxv.concentration and surface temper -a as nod, It was shown that the rate of explo- ture change. w exud give polyAeri Zation -below tbe:melting point:of the monon~rs teJdng KABANGVP V. A.; PA-PISOV). LOMB , A.N~J~ KARGIN~ V.A. Rc,le of 51auile ir: apid polyzerizat'-On 'be:,w the melting polr-.~, of Vyimkom.rioed. 7 no.1041787- 1791 0 9651. (M-T~A as.-]I) 1. Moskovskly goeudaiat7annyy un'-varsiteL Lmeni FAF13CV, T.K., inzh.; MALOVA, I.D., inzh.; SINFLINIKOV, V.A., inzY. ?-'Od4f-,r!at',cn cf e~e mashing method fn c~rom,-,xr. processes. Vod.i san.tekh. no.12:33 D 165. 1q:l) 8L639 8/076/60/034/010/022/022 B015/BO64 A11THORSt Gurman, V. S., Yakovenko, Ye. I., Papisova, V. I. TITLE: Influence of the Phase Transitions It in the Matrix Upon the Annihilation of the Radicals Formed in the Photolysis of a Frozen 25% H2 02 Solution in-later PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 10, p. 2372 TEXT: In the course of investigations of kinetic laws of the concentra- tion and recombination of radicals, forming in water in a photolysis by ultraviolet light of a 25% frozen H 202 solution, by the method of the electron paramagnetic resonance the authors observed that the processes of the phase transformations in the matrix influence the recombination of the radicals. Allen and Stoyn (Ref. 1) have already assumed the possibility of such an influence. The spectrum of the electron paramagnetic resonance of the radicals, in samples irradiated at - 1960C, changes somewhat at a temperature increase to - 1300C, and in the range of from - 125 OC to .. 1200 C the radicals vanish completely. When the irradiation temperature of the samples is over - 115 0C, the radicals form again and remain stable Card 1/2 84639 Influence of the Phase Transitions in the S/076/60/034/010/022/022 Matrix Upon the Annihilation of the Radicals B015/BO64 Formed in the Photolysis of a Frozen 25% H202 Solution inWater until - 530C are reached to be then rapidly annihilated again, The thermo- grams of the non-irradiated samples show that at - 1160C an exothermic phase transition begins, and at - 530C an endothermic transition, According to Chormley (Ref. 2), the transition from the amorphous to the 0 crystalline ice takes place at _ 120 C. N_ Ye. Mironov and A. G. Bergman (Ref. 3) observed the formation of a eutectic in the system H202 - H20 at - 52.50C. Thus, it was shown that under the conditions of the present experiments, the phase transitions in the matrix cause a rapid annihila- tion of the frozen radicals, ['Abstracter-s note: This is a slimmarized translation] There are 1 figure and 3 references; 1 Soviet and 2 British. ASSOCIATION; Moskovskiy gosudarstvennyy universitet im- M. V Lomonosova (Moscow State University im.eni M' V, LomonosovL SUBMITTED: April 20, 1960 Card 212 PAPISOVA, V.I.; SHLYAPINTOKH, V.Ya.; VASILIYEV, R.F. Cheidluminescence and kinetics of chemical reactions. Usp. khi-m. 34 no.8.-1416-1"7 Ag 165. (MIRA 18:8) 1. Moskovskiy gosudarstvennyy universitet imeni M.V. Lomonosova i Institut khimicheskoy fiziki All MR. DID, 217027 -.,r -UR1007 7 t5 i7. 5- 1.', 3 p4 g~_ 'A' G ;*41., ..Shlyap irv Childl, sconce-An e caa, c 7 T Tol dig Mm PSFI!PPW~ I~Dem A P-'~'~~-~z`.-.,5*~~,.;',, r-*"~~~--'~~~,--,~~,~~--.",*::""7"-~-~----.,~ in cance d deviftd& kiUtltbili4~ botifit6': um as an t on" tu 't t Dn.- s es 'n,wb cV~tbiimil eseence was' ves a icsji-~ d.-- -,.Mac- !ms`A6s6~-ma6hiAnl:vm re Oly',4et -6a, or j3i iraiililh6, reac.-~ t b' a., by, metbodi' of cheMcal ki --o lumineseence i :F an y,means T cula- As ~qtpnt a. escapee as a t attent vii t6-. x o --of ~4uantlta -dl;vlae& Into Ae is tive stuoy: of.'3va tivn -:Fldiq6; (2), reactions - of mitrogen, 'px- pen ce reictioils; (4) cti=6 deal,w tb gas-pbase ogo64-67 EWT(m)/EWP(j) WWIJWIRM AP602 ACC NR, 3961 SOdAdE C6ffl *6264X6 "00 N 163 03 AUTHORS Sorgeyov, G. _11.] Pqpisoy&A- V, I, Pla;!*Mk - K, : ChPAJOD-AhA Y ORGS Moscow State University (11oskovskiy gosudarstyennyy universitet) TITIES Reactions of !!~trog~n oxides?with unsaturated daqmMa at lov temperatures SOURCES Neftekh1miya, v. 6, no. 2, 1966f, 302-308 TOPIC TAGS1 nitrogen oxidep olefin ABSTRA~71 A thermographic method was used to study the reactions of_PZQj~ N , and N20 with tthyjp~j9V'jp1ropy1enej, 1-butenet isobutylene, 1-hexons, cyclohexone, acetylone,j~ methylacetylenev allenev benzene, 10-butadiene, 1,3-cyclopontadienev &nTI,3-CYclo- hexadiene at subzero t2M~ ~ratuijps -7 N2C4 reacted at a high rate with 1-butene, 1-hox- enep and cyclohexene at about -40, -32, and -660 respectivelX, and with pr~Wlene~and isobutylene at -35 and -740. The reactions of 1*3-butadion6land 193-cyplop -eii:Facaene with NZQ~ were even more vigorous. Ethyleneq acetife-io-s-6iclohexadiene and c~i; Cain othor compounds did not react with ?kO4 at low temperatures. NO and 1420 did not react with any of the unsaturated compounds at low temperatures. Infrared spectroscopic analysis of the reaction products, performed after heating the reacted mixture of Acy- clia- blefins and N2% to room temperatures, showed that chiefly nitrates and nitro compounds were formed. The reaction of N204 with blefins is explained in terms of, Card 112 ON 546.1 L 09064-67 ACC NRo AP602396i 00]!Plsx fOrmation.' Orig.'art. hast 3 figures wid 2 tables. SUB COM 07/ SUBM DATRI 26AU965/ ORIG WO 013/ OTH IUWI 009 CoH 212 not PAPI-SZALAY, G. Temperature gradient of free atmosphere in the lower 500 meters under various macrosynoptic conditions. P. 105. IDOJARAS. (MeteoroloFiai Intezet es Magyar Meteorologiai Tarasag) Budapest, Hungary. Vol. 63, No. 2, Mar./Apr- 1959 Monthly List of East European Accessions, (IMAI) W, Vol. 9, no. I Jan. 1960 Uncl. 355~~ Vo--rosl o lec-011".1' led. To-'a, C( SO: L 1 iw- i ialn 6`1a a--, , .'c PAPI'iASHV-.LI, Y. 1h. 35552- Rak 1-~Etki I Bererennost'. Trudy Sev.-Oset. Gos. Med. In-ta, Tili. 4, 1949, c. 55-58. Letopis' L"hu2-ral'nykh Statey, Vol. 48, Iloskv-, 194~1, ASATIANI. G.K., prof., doktor med.nauk;,- PAPITASHVILI, M.Ye., red. [Treatment of gynecological patients at Takholtubol Lachenie ginekologIcheakikh bol'Wkh v TSkbaltubo. Thilisi, Gruszedg12, 1957. 68 p. ()GRk 12:1) (TSKBALTUBO--?GNBRKL WATERS) (WOMN-DISEASES) - KORIDZE, Shalva Melitonovich; '~!UXS I DZHINCIWWZE, Margarita Zakbarlyovna [Technique of some gynecological operations] (Tekbnika ne- kotorykh ginekologicheakikh operataii. Tbilisi, Sabahota. Sakartvelo] 1964. 181 p, [In Georgian] (MIRA 18t7) ?AFIU, V.; Kizyk, A. The litholopy of rpef calcareous sediments in baile herculane. ~. 121 SWDII CI CEKETAiiI DI; GLOI-CCIF. Bucrprti, Rup.ania, Vol. 3, no. 112, 191)F MorAhly list of East Furojean Accessions (EE~I) LC, Vol./no. 2, Feb. 19W Unc-'. 7/0 V SURNAME, Given Names Cotmtry: Ruman i a Academic Degrees: -not given- Afffliation: -no t given- Sow-ce: Bucharest,, Comunicarile Academlel Republioil Populare, Romine I VO 1 xi I No 12 9 lq6T 9 pp 1515-15-27. DaW "l-lagnetometric Data Conoerning the Genesis of Therzwmineral Waters at Bails-Heroulane." Authors: E&ETY - V - Co r in RO?4ANESCU-, _D_. IONF-SCU . Pi. PAPIU, V.~.; A.; 3 Jtidl.Affl~lp V. Lit~ogenetic iiqicrtLn,2e of tht, --a-rLx-.aaLbd rOC,-S 2-r. e. a- i -3i&-rz i~uJca 'massif- :)--ri s-3~1 .1- s-i 49 ; t'.2. 53-6? 1-- --1 r"-2" 16.~ ; 1. Dec.--,ber , !-~d. FAFIU, V. Corvir; fWlANESCU, D.; IONESCV, Fl. Magnetometric data on the origin of thernomineral waters of Baile-Herculane. Comunicarile AR 12 no.12:1515-1520 D 161. 1. Comunicare prezentata de Sabta Stefanescu, membru corespondent al Academiei R.P.R. FAPIUJV- V., Corvin;.POPESCU., A.; SET~I':'IYCVICI, V.; DUTU, 14arcela Geologic and petrographic research in the dolomite Hunedoara Massif. Dari seama sed 1+7:323-3" 159/60 (publ. 162.]. BANCILA I I.; PAPIU, V. Corvin On the Cretaccaus sediment lithology in the Cirrm-Valea Tiganilor (Bicaz 3~egi n) Anticline. Pta. 1-2. Dari seatra sod 45 13-35, 1151-129 '57/58 (publ. 1,52]. RANCIIA, I.; PAPIU, V. Corv:Ln On the Lower Cretaceous, silicolites in the marginal bdein of the Eactern Carpathlana. Dari neama vad 46:25-53 '5f,,/5')' [publ, 162-1. DRAGOS.# V.; PAPIU 11 Victor Coryin (Bucurest") "Geologic and metallogene'lic study of the medium part of the Arize Massiff by Flena A(Jriana Perseil. Peviewed bv V. Dragos, Victor Corvin J'apJu. I-latura GeoFraf~e 16 nt 1:96 Ja-F 164. PLFIVANOV, Radoy Prevention of hemolytic disease of newborn. Soy.med. 19 no.2:49- 52 7155. (mm 8:5) 1. Is Instituta biologii (dir. akademik Nstodir PaPav) SOfiYBkOF meditsinskay skademit imeni Vulko Chervenkov. (JRYTHROBILSTOSIS. FXTAL. Prevention and control) ZIKARWp M.R., inzh.,-, GLWOV, IW., Jumho; PIPIMp R.F.9 agronom Testing SNU-48 mounted narrow-rev grain drillp. Trakt. i sell- khozmash.' 31 no.1:28 Ja 161. (HIPA 1101) 1. Zakaftankaya Gosudarstvamaya msmhinoivpyULtellnaya stant-slya. (Drill (Agricultural machinery)) AHDROHNIKOV. K.S~ -. BALAKOV. V-V-; BUZHIESKIY. A.N.; BURAGO, A.N.; VINTHAN, L.A.; VISHMXVSKIT. A.A.; VOLOSOV, D.S.; GrASSOVSKIT, L.F., professor; GARSHUN, A.A., professor; YEL'YASHUICH, K.A.; YNVSTRGPITNV, K.S.; GURRICH, M.N., professor; KOLTADIE, A.I.; KORUKIN. B.M.; KURITS- KIY. A.L.;-FAPIYA-UTA,-,L.,A~,; PROKOFIYXV, V.K., professor; MSIM, Ye.K.; RAZUNOV, K.A., RITTNI, H.R.. SAVOSTITANOVA. N.V., professor; SBVCHANKO, A.N., SANBOV, B.I.; STOZHAROV, A.I.; FAYXWN, G.P., professor; FROFILOV. P.P.; TBARIVSKIT, U.N., professor; CHSKMATAY'BV, D.P.; YIMIN. Ye.F.; KAVRAYSKIY. V.V.. professor; VAVILOV, S.I.. akademik. redaktor LOPtieg in military science] Optika v voennom dole; abornik Btatel. Pod red. S.I.Vavilova I K.Y.Savostlianovol. Izd- 3-e. zanovo parer. i dop. Koskva. Vol-2- 1948. 387 P- (KLRA 9:9) 1. Akademiya nauk SSSR. 2. Sostavitalt - sotrudniki Gosudarstven- nogo Opticheskogo instituta (for all except Vavilov and Xavra"kiy) 3. Voyenno-morskaya akademiya (for Kavrayskiy) (optics) IPAPIYJITTS. K.A. Method of crossed spectral prisms used for ra-Did evaluation of the aberration of optical aratems. Opt.-mekh.prom. 25 no.6:7-12 Je '5R. (MIRA 11:10) (Aberration-Measuremnt) FED111, Leonid Andreyevich;, FArIYAWa,-K.A, ~ kand. fiziko-matem. nauki, retsenzent; KORDLBV,, N.V-p inA.9 reteenzentj1DFFEpG.Ae prod. ;TOKO 1,V.Me q red. izd-va; ORESMWA, V.I., t9khn. redo [Manual on microscopes, their accessories, and' a) Mikro- skopy, prinadlezhnosti k nim i 1upy; spravochn~Wkniga. Pod red. G.A.Ioffe. Moskva,, Goa. nauchno-tekhn. izd--7o Oborongiz, 1961. 251 p. (MIRA 14: 10) (microscope) PAPIYEVY G.G., inzh. Enlargement and opec.1-PlIzation of furniture manufacturing in Georgia. Der. prom. 12 no.r):18-lQ 8 163. NIRA 1. Upravlenlye Jernrly i bumazhnoy promyEhlennostl soveta nar-in"ro khozyaystva CiruzinsRoy SSR. FAFIYEV, G.G. Fram pr~L ~'-iN-.s In safety engineering and industri-a-I liy6,-ierw-. Der.lzor-, 11 nc.6-, A.) je 1626 (MMA 15 - Q . (Akhal-lal:o--IN;rnituT-e industry-Safety ia,,:imures) (Indu.-tri!ll hygiew) PAI IYSIV, 1-G- - ~, --.:: --: Frli ~r - e -,;, I :. f T ! -, ,- - 4 :,.- fT, , ,Oape,-t3 f-- *.,. i "1 2( 1 Armenia. Cicu. J -- a' .- ---- f V. - -~ - " PAPEE, Anna Diffuse hypertrcph7 and h7perfmction of the islands of langsrhans. Endokr. pol. 14 no.2218.1-186 163, 1. 111 X21nika Chlrurgiczna AM v Pozaaniu Kierownik., prof. dr A. Piskorz. (ISLMS OF LANGMANS) (ISLET CHU TUMOR) (DIAmcsis., DIFFEMTIAL) (HYPERTROPHY AND h'YFMFLLSIA) (HMRDISULINISM) FRIA, G.T. . ..... ....... Surgeon A.G.Zaloga, a mian of public activity. Soy. sdrav. 13 no-4: 50-55 JI-Ag 154. (MA 7:9) (ZALOGA,AMkTOLII GEORGINVICH, i87o-1954) PAPIA, G.F. -~V*lve_r~~' - -.00-1 I.X~Spiz;hnrnvi; physininn, scientigt, teacher. Pnd Tniblic figuro; 1857-1924. Ehirurgila 34 no.62136-142 Ja 158 (MIRA 11:8) 10 Iz trnwintologichoskogo otdeleniya Moskovskoy porodskoy klinicheakoy ordenn Lanina boltnitay imeni S.P. Botkinn (glRvw vrach - prof. A.E. Shnbnnov). (SPIZHAIWYI, IVAN XONSTANTINOVICH, 1857-1924) PAPEO. G. F. Gandidiasis of the internal organs in association with staphylococcal septicemia in surgical practice. Sov.med. 23 no.8:118-125 Ag '59 (MIRA 32:12) 1. Iz travmtologlebeskogo otdelenlya (nauchnyy rukavoditall - prof. D.K. Tazykov) Moskovskoy qorodskoy klinicbeekoy ordena ten1na boll- nitsy imeni S.P. Botk1na (glavnyy vrach - prof. A.N. %abanov). (MONMIASIS etiology) (STkPRYIOCOCCAL INFECTIONS complications) (SURGERY, OPERA-TIVE complications) (AIrLIBIOTICS eff., Inj.) PAPKO Case of primary plastic surgery of the forearm following almost total avulsion. Khirurgiia 35 no. 5:112-114 My 159. WIRA 13:10) 1. Iz travmatologicheskopo otdeleniya Moskovskoy gorodskoy k-linicheskoy ordena Lenina bollnitsy in. S.P. Botkina (glavnyy vrach - prof. A.N. Shabanov, rukovoditell kliniki - prof. D.K. Yazykov). (ARM-WOUMS AND INJURIES) (SURGERY, PLASTIC) PAPKO, G. F., Ca-nd Med Sci -- (diss) "A. A. Bobrov and his school." Moscow, 1960. 23 pp; (Second Moscow State Xedical Inst iL b. 1. ogov): 300 copies; price not given; list of author's wor4s on pT, (KL, 26-60, 144) :: PAWO, G.F. (Moskva) A.V. Mart7nov and his role in the development of ftestan surger7*. on the 25th anniversary of his death. Sov.zdrav. 19 no.2:70-75 160. (MIRA 13:5) 1. Iz travmatologiabeekogo otdeleniya Hoskovskoy gorodskoy ordena Lenine, klinicheskoy bolluitay Imeni S.F. Botkina (dir. - prod. D.K. Yazykav, glavuyy vrach - prof. A.W. Shabaucyv). (MARTYNDY, A I VASILINVICH, 1868-1934) -,_IPAPXOI GOP& Aleksoi Thoillevich Martyno7o VestAbire 84 no.1&136-140 Ja 160. (MU 13:10) (MARMOYp All VASIL'isvi ) PAPRO, G.F. An outstanding representative of Russian surgery, S.F. Yedcrov, 1869-1936. Sw.med. 24 no.%139-345 5 960, (MIRA 13s11) 1. Iz travmatologieheskogo Weleniya ~bskovskoy gorodskoy klini- cheskoy ordena lenima bollmitey imeni BeP& BDtkina (glavnyy vrach - profs A.B. Shabanor), (YEWROV~ SEMBI PEMVIM9 1869-1936) PIPEO, G.F.; SFMROVJL, II.I. Osteold osteora. Scvv.med. 25 rw.5:143-146 Itr 162. (Yrl~LA 2 5: P-) 1. Iz travmatologicheiskogo otdoleniya (nauchrWy rukavoditell - prof. D.K.Ya2ykov) Moskovskoy gorodskoy ordena lenina klinicheskay bolinitsy imani S.P.Botkina (glavrWy vrach - prof. A.P.Shabanov) i pervoy kafediT rentgenologii i radiologii (zav. - prof. S.A. Reynberg) TSentrallnogo instituta usovershenstvovaniya vrachey. (BOvE, S--TU1401;(S) 7", POLAW/General Problems of Pathology - Tumors. T-5 Abe Jc-ur Ref Zhur Biol-, No 3, 1958, 12832 Author, Budzynska Xozaneeks, A., Papke, A. Imst Not given. Title A Case of a Large Teratoma of the Ovary in a 6-year Old Girl. Orig Pub Pediatr. polska, 1957, 32, No 1, 74-76 Abstract No abstract. Card 1/1 PAPKE. Anna Two cases of p-ptic ulcer in the jejumm operated on by Henley's method. Polski przegl. chir. 28 no.11:1187-1193 Nov 56. 1. Z III Kliniki Chirurgicznej A.M. w Poznaniu Kierownik: doe dr. J. Borszewski. Poznan, ul. Ontroroga 13, m. 3. (PEPTIC ULCER jejunum. wirg., Henley'5 method ~Pol)) BORSZIWSKI, Jerxy; PAPKE, Anna; LFJA, ZbIgniew Assimilation of proteins and fats following Hanley's gastric resection. Polski przegl. chir. 29 no-3:197-202 Mar 57. 1. Z III Kliniki Chirurgiesnej A.M. w Posnaniu Kierownik: doc. dr. J. Borazewski. Adres autorow: Posaim, u1. Szkolza 8112 111. Klinika Chirurgiesna A.M. (GASTMTOW, Henley's operation in peptic ulcer. postop. protein & fat &bsorp. (Pol)) (FATS, metabolism, aboorp. after Henley's operation in peptic ulcer (Pol)) (PROTEINS, metabolism, same) (,j fu 6 "S,( EWSKI, Jerzy; PAPKE, Anna WO Surgical trestrient of postoperative stenosis of the common pos" oil bile duct. Polski tygod. lek. 12 no.13-463-468 25 Mar 57. 1. (Z III Kliniki Chirurgicznej A.M. W P02nFkniu; kierownik: doe. dr. Jftr2y Boraziewski). Adres: Po2nan, III Kl. Chir. A.M. (BIL'S DUCT, COMN. stenonis surg. of pDotop. stenosis (Pol)) BUDZYNSKA-MMAMMA, Alic a- P Case of a large ovarian teratona In 6 year old g1rl. Peediat. Polska 32 no.1:74-76 Jan 57. 1. Z I Kliniki Chorob Dzieclecych A.R. w Poznantu Xterownik: prof. dr. mod. T. Rafinski i z IIIJIliniki Chirurgicznej A.M. w PoznmLniu Kierownik: doc. dr. mod. J. Borazewski. Adres: Poznan, ul. Magdaleny 14. (OVARIES. neoplasms teratoma in 6 year old girl (Pol)) (THWO14h, in Inf. & child ovarian. in 6 year old girl (Pol)) PO LAN D PAF1U,__An_ria,, -Clinic of Infectious Diseases (Klinika Chorob Zalcaznych), A~f [Alcademia Nledyczna, Medical Academy] in Poznan (I;irector-. Prof. Dr. A. PISKORZ) "Mechanical Jaundice in Chronic Pancreatitis.11 Warsaw-Krakow, Przeglad Lekarski. Vol 19, Ser II, No 4, 63, pp 220-222. Abstract: [Author's English summary modified] mecl-ianicai jaundice may appear in patients with chronic pancreatitis Vrithout the presence of stones in tl-ie common bile duct. Such jaundice may be caused by mechanical ?ressure of the inflamed head of the pancreas on the terminal section of the common bile duct, as well as bY stricture or cicatri- zation of the sphincter of the heptopancreatiG ampulla. Sur.-ical clearin- of the common bile and pancreatic ducts may bring about the disappearance of the symptoms of the jaundice and the pancreatitis. 17ho eight (8) references consist of two (2) Russian and six (6) Western sourcos. J 29 DEBSKA, Wanda, dr dr The need of acientific and technological progrees in pharmaciea. Farmaoja Pol 18 no.21:522-523, 526 10 N 062. P03,,',I.rD / Meadow Coltivation Abs Jour: Ref Vol 13, A u th o r: Pap-e, Inst :1,.'Dt ~~-Lven Title :The Utilization of PhytocenoloUy in the T~,T-)o- lo-ical Class-',ficat;on o-' lleadous and P3-stures LD - I J.n t"Oe Li,-ht of Recent, Research of German Au.`Ghors u Crig fi,b: P-oatepy na-.-'- roln., 1957, )!, No ~-, 147-151 A 1; s t, i~a c t :Do abstract. Card 1/1 PAPIO, G.P., SKMOVA, R. 1. Diffuse oeteoporosig In amyloidonis of the liver and kidneyme Sov;med, 22 -noeft37-42 Ag '58 KIRA Iltlo I* Is travmatologicbeekogo otdeleniya (nauchnyy rakovoaitell - prof. D.K. Yazykov) Moskovskoy gorodskoy ordena Lenin& k1hicheakoy bollnitsy imeni S.P. Botkina (glavnyy vrach - prof. A.N. Shabanov) I pervoy kafedry rentgenologil I radiologil (savo' - prof. S.A. Reynberg) TSentrallnogo inatituts usovershenstvovaniya vrachey. (AMUOIDOSIS, compl. osteoporosis diffuse, in amyloidosis of liver & kidneys (RUBb (LIVXR DISBASES. compl. osteoporosis, diffuse, in amyloidosis (RU)) (KID M S. DISEASES, compl. same (Rw)) (OSTEOPOROSIS. compl, diffuse, with amyloidosis of liver & kidneys (Rus)) PAR09 G.P. S.F. Fedorav and hia role JA the develcpcent of Swim surger7 (1869-1936). Khirargiia 36 no,29LV-235 P 160. (FEVWVq SERGEI FEMVICH; 1869-1936) (SURGERY) (MIRA l3sl2) .. PAPW? -G.F.. kanchmed.nauk Some hletorical data an the development of the Moscow Municipal Clinical Hospital Bo*I+ and the present state of its scientific work in the light of the prospective plan for the hospital's deve3,opment during 1960-1962. Nauch.trudy Chetv.Mosk.gor.klin. bol%, rio.1:7-3-1 161. (MIRA 16a2) (MORGOW-HOSPITAIS) KUKIli, Nikolay Nikolayevich, uwktor med. naukl,PPKO, Grigoriy Fedoseyevich, kand. red. nauk; SOilOKO, Ya.I'.",---r'e*d.; RAKITIN, I.T., tekhn. red. [Ways of surgery] Puti khirurgii. Moskva, Izd-vo "Znanie," 1964. 47 P. (Novoe v zhizni, nauke, tekhnike. VIII Seriia: Biologiia i meditsina, no.3) (MIRA 17:2) ROZANTSKVI E. G.;.PAFKIO, R. A. 2.2.,7,7-Tet th71-5-homopiperazinone-nitric oxide, a new stable free radical. 12,,v. AN SSSIR Otd. khim. nauk no 12:2254 D 162. (MMA 16:15 1. Institut khimicheskoy fiziki AN SSSR. (Piparazinone) (Radicale(Chamistry)) ROZAN+, E.G.; PAPXOP R.A. Beckmann rearrangement of a free radical. Izv. All SSSR. Otdox-hi3. ravA no.406je-765 10.~ 16). (MIRA 16-0) 1. Institut khimicheskoy fiziki All SSSR. (Beckmann rearrangement) (Radicals (Chemistry)) PAPKOO 0.-s~l. Cand. Chem. ~ci. Dissertation: "Oxidation of the Aqueous Lolut-'ons of AmmonJa with Ozonized Oxyge4i." Moscow :)tate Pedago,,ical lnst imeni V. 1. Lenin, 2 Jun 47. SO: Vechernyays ldoskvli, -Jun, 1947 (Project #17636) al,090000690900*00000;O 0 & 0 0 0 0 0 0 0 'W as to so 161 a It 0 It 1111 It 0 a 1 14 to ,A~ a L a. 'I " 'k A" 0 0 ar -PT W., - 0 000 so 14-10111 -4. time of amovisla III --go, to -66 sea v"V fast, which ruitairm tf~ War- I- --1 -00 Alop. h4lad Kh" I[ At""" ~jjAjr profitort.. Tilt orrhArtimat In th, or, Into an lifteet low intriol KlWJI Vain. throuXb a Schott filtro iwb as to rimurv dis. - volvi"S 1111rianhimir lommitim of N11,011 at-- .0 for lbr, Ifilififirtv"i rificess of a ovtr P01; the N'lliml go pfflilm of #hr Cas into firrm bubblirs. gfirollur" hish vithis ~f Allies ;J.-INIINO. t0l"1941 in ill, Initial %tep Is "Witell not only by Ill but '4140 ity IN. 00.5alion of NIL i'lCtrAses filwally *tilt flit It, fill Not.$" low -411'. vall.A. twits. 14 1 1"I"Savall. arrimve. ItAnt t4 0. ill the It*-. lbus, under the at.rfiv t.mIAM -00 b , ' Th. - XI 1. MAII his.. vvith ailitifill, with Ob M44, 11 or"), 1) 114414 V "It " a 2, " " 1 3-007. 24.4. 18.11. 11.-,, 2-h 41W~,mndm Tifirin,vir,wolfi, I OAM, O.W, 2.0b 1; 7,6, 3.6%. Thrm filutril fit lilt mpilirAl forinuta q - srit~ It& (h content Indicates thit 0 forriml in the de 4).Xv f, -- 4 1.1111.22. The depm of sfitfllgaji~uj of es"01111, 01 Ch "0111 is ovorr active than inA 0~ Futrifi- rald'st '"I %be of Ifir over '411 rtfirtion t.ol"lloo 1-6tirm I., mo Jum, that oudalsolt of Nit, Ifirgio. of ill, I V16 -- Nll.\'t). 1 11.0 f ON, is, &I the ottin-T Milt ""llvitt .4 OMM a "b"l. '11W hillwom, ~,JuAtlotj briffialronrils , a - I"Jo.j. Vk~ 1. 114 1- A 41114% liCt"t"ll V, 111-1 04% -4 V%hih 1--K & - 1 1010 =01 darr" of ulifiltion vitreedifts Hill', nicailli. 44 4-14o,, -.ml - 1.114M. -v, Advsovr midil *4 NII.Nt), Jfij,l $list Mhifi osi,ht-l .... t onlv hr 1),, 1011 In?" .,I, inrorikifir, 9 very sliollilly jjhu,, 13 04"j. NII.Nifi, ln,rr.- 'Ifni :1 tit lurtil" anits of NII,Nth 7 (N' it the l'a"Oo" halt twirti 111411411~1 IV jfi~ IJW 4 11-11 til.A ill 21 1`~I. f. sit &,- -.1 low Ila. has Imt 1111tr effet-4 on a t J.".. as "mW Slukirl the Mitosis, havv no mot, 11-t I.. IV rivither #hr MW #- Fb.uli- to live 0-- 4 lobildlim illar rate Ill B" '"'I "I I- (I 1-/hf- le"i'll"41 ill by tht N11.N4 4 form"t. it is ItoballAr t,- -tv flit nitid. 9 frum 17.2 to M1%; ahme 4-5 I./hr.. 9 bectlaws prarti- tion of Nil, In soon. by 0, very far. Tow of It oh rally coni. I'd irmlependrut of the rate of flow. Like. tallied are consitlerably blShrr than thow relufirt"I in I"- wlw it rrmjin% martirvRor roust. At the corm. rate of Vj,,As literallife. X Tom 41. IT., of TV. 00 rovilent -W!- I - I "'. v tiW.. only verv see I urto I r "it I a r tract m, art, mirvouir. prav t MY --to hoo, od, non. -tit. Kin,lic.11Y. 111k. frart"lit 0,,- C, ,, C to 1w 111 the ;.'flit or-kv. with tl~ -II, -fifisst, It OAM at Z%* min.). which is con3listrot with a 9 binstil. ralr4ric alto) Nil. 4 (1~ N110M tN 4 to. *"$ftv :00 WOOD -4 If1d&O 4040 041, coo all --41,I oaf a.. 4%. too u 91 AV so ASI; 1, or 4, 1, 41 If 0 or a a It of 1 14 0 0 0 `0 0 0 0 4111 0 0 0 0 0 0 0 * 0 e 0 o go 0 0 0 0 0 0 0 : : 0 0 0 0 0 o M.1t mell~ last, mail-4. Appfied Chats.) Z3, fl-2D(IRM).-Rdatirc rato of Sim d N)h is 6Q. =b. by Ob (:= 00 SWAM at 4 1'IV,. w0" drK by the pmr of N113 oddind to N1101 ImA in W saim, Art 4.5 bra. 0%Mation ION)II&M Is k6 Im W04 tb* thu4tu, mvp of the, whou midatiom p . At 25, at coot. amust C at CONN as Catairm. 0.35 as ;Z1V Co. va&tbm of the ishial Nil) rea"I 0. siml a**, film O'D to 6% twAb in a COHtMh,,&iJW1A**J= 1141111 VA III dliht 0 it t4h At eftO r or - im-mw firm Ila to im"; OM & bmaft Imm 0.4 sim of % in dle oaWfloa pram. At cowl 4, 9 Cfftwa from 76 to IX7~ with C iw"asim ftom 0.12 to OAS%. rm Cattily* evect, d CUSO, 6 attramated to- n F4~viullm al the NIL mcb, doomb farmlim d the jCu(Xl4)oj** compkai i=. NIM has still a exallytic effect. but his thin CUSUA, 72w r"llom d a with a at toam. C. SW with C at cvmt'a b" the sam fam 03 with COEN. Mw &UPts d the *Fe) lion at coal. a we aMm.tbammiabotbeam. With Cal", iniindmed as C*SGs sW apostsocauly oxifflud by air in the alk. mb., and Itsviog. afin Mustim firom the CqA ppi.. at swal. c - OAW% In mob., the catalytic efwt fil inus- mWisle brielve IZI of CO' wO tb.1 d Ni". Tb, sihope 41 the *(a) nvve of twill, ( Is The mme, Tbr caulytic WFKA moal" UKUNSW *b", with 4 krpl toad., e Is varkd bm 0.01 to OM%. No estalytict d earvi Imfoam will, $11maso.12)610%,fujo (C - 0.870); 8(N"jjD.t2WQ#.7JW it" IL oftht aegammull wkd. irApeadmi of & bttwm 0.32 and 0.90-1 014bt Catatylk ~ TM suo abomw with RAVO., i-&-_ arrAral to e betarm 0.1 am 0.9".. N. Them to -aillu, the flow method. L. Nik) and S. i. P.4*6 y (Stulin , -s7 s 7 c 1, tx. tfa~ 29, 3- 1 app igned to va an promedhig in iquid Rtmarn in dllTc=t observe the reaction proecedhig in sections of th,,tt stream, The app. is clitimed ermits I-j th t f this l l t l t d 4 ar e( e s o u . p y a y o up an identhicatian of intunnediate proclucts and of the initial sviges, of bornogencous catalysis, possibly,also the kinetics of oforg; dyes, such us IFKIiLator,3,AumlaescenFe b C ter erg eltm n c; - lum II WAIMM .COVA~ fj AUTHOR:- Papko, S. I. TITLE: On the Interaction Between Ammonia and Ozone Solved in Carbon Tetrachloride (0 vzaimodeystvii ammiaka i ozona, rastvorennyk'r v chetyrekhkhloristGm uglerode) PERIODICAL: Nauchnyye doklady vysshey shkol,,-, Khiriya i khimicheska,,-a .1 1 1 tekhnologiya, '958, Nr 1, pp. 36 49 (T~SSRI ABSTRACT: The oxidation of ammonia is much less investigated than t.-'e oxidation in te gas phase. From the point of view of practical exploitation 4t is much more advantai:eous to rxi'!---e ammonia in anhydrous solvents. Ozone and ammonia are assj-..--d to be soluble in them, t-e solvent has to be inert with res--ect to the two gases; furthermore it must be cheap and not short in supply. Carbon tetrachloride corresponas to all these conditions. Ozone is better soluble in the latter than in water, ammonia is less. F,.Fure 1 shows a scheme of the Tlant used for the oxidation. Before the beginning of tne experi-ent the carbon tetrachloride saturated with a=Dnia was com;:.'et--.7 -!ear. With progres~ling flowing through of ozonized oxyger. Card 1/3 the liquid became bl,irred, and white ~-mall grains of the r, 1~ 7 On i. h e 1 n t e ra c t i ) ri b e t w rj r. I a0 z j r; F, 3 c) I v f! d156 1),; - in Carbon Tetrachk)ride oxid at ior, prod uc- s be-an t c form or-, t e wa I's of t~:e vessel (6). The experiments were carried out at 14 and The isolated solid oxidntion, products were recrystallizei. The qualitative analysis showed the presence of ~he following ions: NH-' , NO"', Cl". OC-L-'. N0- --,CN-- and CO " ions were 4 31 2 3 lacking. The re-sults of' a q'-I-,Lntitative analysis of individual fractions are 3hown in table 1. They agree with the soiubl'!J~'J-- c~~f NH NO arA NH ~1- The jr-,il fraction contains mainly NH C, 4 1 4"' 4 L. The fra,~,tions II and .1II are practically of the same --om;~osit-JD- and contain mainly NH 4 NO 3* Average date. on the composition of these roducts (Table !) show that they represent a mixture of 5B% NH 4NO 3 and 36~ NH 4c1. 6,-~o are formed by organic admixtures. The temperature cna-,.,~7e d~,es not influence consi--era~--'y the ratio of tnL' i~roduc'S. The way of t,.e th-r3ugh of ammo:~--a and ozona .-s, however, very i-portant (Table ',). There are Card 213 1 fig-ure. '; tables, and 4 re.ferences; 1 of whi-ich is Soviet. On the Interaction Between A.-imonia and Ozone Solved SOV/156 - -8- ! - in Carbon Tetrachloride ASSOCIATION: Kafedra khimii M-)skovskogo instituta, inzhenerov transporta im. I. V. Str!, ina (chair of Chemistry of the Moscow Institute of RR Engineers imeni IN. Stalin) SUBMITTED: October 5, 1957 Card 3/3 PAPKC, S.I. Kinetics of the reaction between ammonia and o,7-one, disevlved in carbon tetrachloride. Zhur. fiz. khim. 34 n0-2:387-394 F '60. (MIRA 14- 7) 1. 2-y Moskovskiy gosudarstvennyy meditsinskiy institut im. N.I.Pirogova. (Ammonia) (ozone)