SCIENTIFIC ABSTRACT PANCHENKOV, G. M. - PANCHENKOV, G. M.

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SCIENTIFIC ABSTRACT
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KOLESNIKOV, I.M.; FAMHENKOV) G.M. Formation of meta-substituted benzenes in the alkylp-tion of aromatic hydrocarbons with umiaturated hydrocarbons. Neftekhimia 2 no-1:48-53 Ja-F 162. OURA 15; 5) 1. Makovskiy ordena Trudovogo Krasnogo Znameni Institut neftekhimichookoy i.gazovoy lm,omyshlennosti im. akad. I.M. Gubkina. (Bonzeno derivativoo) (AlIqlation) - PANCPHENKOV, G. M.; KOLESNIKOV, 1. M. Kinetic methods for calculating! the delr7drogenation processes of hydrocarbons. Neftekhimia 2 n0'.4:~ 6 Jl-Ag 162. (MIRA 15:10) 1. Moskovskiy institut neftekhimichaskoy i gazovoy promysh- lennosti imgni I. M. Gubkina. (E~rdrocarbons) (Debydrogenation) FEY IANOVP F.A.;,PANCHENKOV, G.M.; KOIESNIKOV, T.M. Kinetic equations of heptane reactions under the conditions of catalytic reforming. Neftekhiulia 2 no-5:716-722 S-0 162. (MIRA 16:1) 1. Moskovskiy institut, neftekhimichaskoy i gazovoy promyshlannosti imani I.M.Gubkina. (Heptane) (Cracking process) 5/195/62/003/003/002/002 E075/E436 AUTHORS: -XanL1wn1co Tolmachev, A.M. TITLE: On the question of the interaction of oxygen with the* complex organic cobalt compounds PERIODICAL: Kinetika i kataliz, v.3, no-3, 1962, 378-384 TEXT: The authors invvstigated the kinetics of the interaction of 0 with bis-(N,NI-disalicylalethylenediamine)-~t-aquadicobalt (COX) and bis-(N,N-I-di-(3-,nitrosalicylal)-ethylenediamine)-ii-aqu'adicobalt (3-NO2-COX)- It was found that both compounds absorb 0 with the evolution of heat, the maximum amount of the absorbed oxygen being 1 molecule of 0 for 2 atoms of Co. At low temperatures the reaction is ~&lmost irreversible, but beginning -it 30*C for COX and-40"C for 3-NO2-COX, the strength of attachment of 0 to the complexes rapidly decreases and the reaction becomeA reversible. The following scheme is proposed for the reactions: 02 02 Diffusion Of 02,towards the surface -gas-in gasIon the of the sol-id.phase bulk surface CArd 1/3 S/195/62/003/003/002/002 On the question of the interaction ... E075/E436 02 02ads Adsorption Of 02 on the surface gas on the surface 0 Diffusion of the adsorbed 02 molecules Ozads 2 in the bulk of into the solid phase the so2ld phase (+2CoX) IV 02 f. -) COX202 Chemical reaction of the 02 in the inside solid with the complex molecules . IVa the solid (+2CoX3) V C02X202 2COX C02XN202 - Satuxation of the complex M010GUIGN, tar Whi4h roaction IV is not admissible. The rates for the processes I and II are higher than that for process III. The latter is the rate determining process for the Card 2/3 5/-i95/62/003/003/002/002 On the question of the interaction ... B075/E436 reaction below the critical temperatures. Above the critical. temperatures both processes III and IV are equally slow and the kinetic S-shaped curves characterize the subsequent reactions. Process V occurs rapidly and i3 not considered in the kinetic studies. There are 4 figures;and 2 tables-. ASSOCIATIM Ifoskovski*y gosudarstvennyy universitet im. 11A.V.Lomonosova, Khimicheskiy fakulltet (Moscow State University imeni M.V.Lomonosov Chemistry Division) SUBMITTED: may 11, 1961 Card.3/3 Id-35o ~S/193/62/003/006/003/011 E075/E436 0" h A M AUTHORS; Panchenkov, G.M.j Tolmaclevj, ;-TITLE: Kinetics'of isotopic exchaAge between gaseous oxygAn--~ and oxygen absorbed by the!organic complex compounds of cobalt -864 !.PERIODICAL: Kinetika i kataliz, v-3, n~.6 , 1962, 861 TEXT: The isotopic,exchange reaction, 16 180 16 16 16 18 0 02X2 0 0 gas + co*2x-2 - 0-.. soii:a -rO2- gas + C solid sbijs-(N,,N]L-disalicylaleth~lenediamine)-ii-aquodicobalt where X is was studied. f or. the time. . 'The complex saturated with.oxygen at a given 't TV tKe and about 380. in Hg was.evacuated and emp sa:turated with 0 0. Samples of the gas were withdrawn periodically and analysed by mass speotroinetry. The rate of isotopic exchange was measured by~ C Co COO Co where C 'and C 0 molar fractions of the "isotopic 0 at times t Card. 1/3 z AY S/195/62/003/oo6/003/011 Kinetics of isotopic ... E075/E436 .i and t 0, -he molar fraction of the respectively and Coo t 0 mole6ules at equilibrium at which the isotopic composition is the ..same in the solid and gaseous phases.. ' -In.most cases the equili- brium was not reached with the exception of COX at 400C. This mad6 the.6alculation*of Coc) difficult~except for the reaction at 400d. The isotopic.exchange was postulated to proceed in two steps'., 2 16. 18 16, .16 1'6 18 X 0 0 Ogas + C02X'2 02,aolid---> 02 Vs + Co2 2 -0solid + C02X2' 6 0~ jL6. 0 e16018 7-*'Co2X2 .02 + C'2 2, 0 the: first reac tion is fast determined the'rate of diffusion Of isotopic 02 into the crystals of the' complexes. The diffusion+', into the.narrowest pores of the crystals was stopped'howover by 0 molepules, coMbined with the complexes. , At this stage the .-Secofitt slow reaction'begins. The second itage is accelerated at 40 to 650C due.to weakening of bonds b6tween 0 and the-complexes. The effective coefficient of-autodiffus'iork of'O in C02X202 -Card 2/3 'S/195/62/603/006/003/0]Ll Xinetics of isotopic ... E075/9436 c. particles at 400C was calculated to ba'about 2.3 x 10--l' n2/sec using R. Barrer's equation (Diffuziya V tverdykh. lekakh (Diffusion in solids)'Izd-vo inostr. lit., M., 1948, 43)- There are 3 figures and I table. ASSOCIATION: Moskovskiy gosudaestvenny-~ univer'sitat im. M.V.Lomonosova (Mosco,~r State University imeni ~M.V#Lomonosovn) SUBMITTED: may li, 1961 C-ard. 3/3 PANG44MVP G.M&;. KOZLOV, L.L.; YAKOVLLI',, V.I.; KATSOBASHVILIJ, V.Ya.; VASILSYEV, L.A&; RYABUKRINj, Y-LtS. Polymerization of amylenes under the action of high-energy electrons. by. vys. ucheb. zav.; neftl i gaz 5 n0.1:57-58 262, (MIRA 16:11) 1. Hookovskiy institut neftekbdnicheskoy i gazovoy prozWohlennosti imeni akademila I.Me Gubkinz. PANCHENKOV. G.M.; KOLESNIKOV, I.M. Catalytic activity of a mixed platimm-palladim catalyst. Izv. vys.ucheb.zav.; neft' i gaz 5 no.8:75-77 162. (MIRA 17:3) 1. Mookovakiy in3titut noftekhimicheakoy i gazovoy promyclilennosti im. akademika I.M.Gubkina. KOLESNIKOV., I.M,,; FANGHENKO _G.M. -.1- --V, ~ ~... Kinetic equation of parallel biviolocular reactiono taking place in the gas phase of flow in the pro-sence of solid catalysts. Izv. vys. ucheb. zav.; neft' i gaz 5 no.10:61-6b 162. (MIRA 17:8) 1. Moskovoldy institut neftelildmicheakoy i gazovoy promynh- lennosti imeni akademika Gubkina. PANCHENKOV, G.Mi; YERCHENKOVP V.V. Temperature dependence of thes coordinalooh numbers and diffusion coefficients of liquids, UkA fiz. 'zhur. 7 no.8:801-896 S 162. (KRA 16:1) 1. Moskovskiy gosudarstvennyy universitet. (Liquids) (Molecules) (Ditfusion) s/065/62/000/009/001/002 E075/E436 AUTHORS; Kolesnikov, I.M,, Panchenkov, G.M., Orlova, A.A. TITLE: The kinetics of thealkylation reaction of toluene with propylene using alumino-silicate catalyst PERIODICAL: Khimiya i takhnologiya topliv i.masollno.9, 1962, 1-8. TEXT: As the reaction was considered to be suitable for I the preparation of chemically pure eymenes, its kinetics were 3.nvestigated in a flow system at atmospheric pressure. Thermo- dynamic calculations have shown that at the molar ratio.of toluene to propylene of 3:1, the alkylation should be carried out at a temperature not greater than 2600C. The composition of the catalyst was: W A1203 14.01; SiO2 - 84..66;' NaO - 0.36; Fe203 - 0-13; Zn and MgO traces. It was regenerated by air at 5500C. The rate of feed of toluene into the reactor was from 0.4 to 1.8 x 10-2 mole per 1 cc catalyst/hour. It was'shown that for all the reaction temperatures investigated (180, 200, 220, 240 and 260*C) the yields of products decreased with the increasing rate of'toluene feed into the reactor. The conversion of propylene exceeded that of toluene, as a result its conversion into Card 1/2 SMOXHINOI.A.; AGEYEV, Ye.F.; PANCHENKOV, G.M.; SNIILNOV, B.I. Separarion of oxygen isotopes by the themodiffusion method. Zhur. fiz. khim. 36 -nool:124-129 Ta 162. (NM 16:8) 1. Moskovskiy gosudarstvennyy universitet im. Lomonosova. (Oxygen-Isotopes) (Diffusion) 33695 S/076/62/036/002/007/009 B152/~110 AUTHORS: Makarov, A. V., Koretskaya, T. V., and Panchenkov, 0. 1.1. TITLE: Zone melting separation of boron isotopes PERIODICAL: Zhurnal fizicheskoy Ichirnii, v. 36, no. 2, 1962, 391 - 393 TEXT: In this study, the suitability of zone melting for the separation of boron isotopes has been tested. Boron anhydride B 203 was used for the purpose. The boron anhydride was filled into a stainless steel tube in such quantity that in the molten state about half the tube was full. During the experiment the tube moved at a certain velocity through a furnace heated to 700 - 8000C. In order to obtain a melting zone as narrow as possible, two water-cooled glass coolers were placed on either side of the furnace. After the experiment the sample taken from the tube was analyzed in the form of Na2B 407 in a mass spectrometer. Six experiments were made altogether, using different rates (1.5 - 0.15 cm/hr), tubes of'different dimensions (I = 45 50 cm), and a varying number of passages through the melting zone (1 25). The masS-SDectrometric Card 1 /2 PANCMNKOT,, G.M.; MKHMKOV, V.V.. Temperature dependence of the coordination number and diffusion coefficiAnt in liquids. Mir. fiz. khim. 36 no.4:869-872 Ap 162. OIIRA 15:6) 1. Moskovskiy gosudarstvennyy universitat imeni Lomonosova. (Diffusion) (Coordination number) PANCHENKOV, G.M.; KUVSHINNIKOV, I.M. Apparatus for ireasuring sorption from a gas stream. arir.fiz.- khim. 36 no.5tlIO4-1107 MY '62. (MIRA 15:8) 1. Moskovskiy gosudarstrennyy universitet imeni Lomonosova. (Adsorption) PANCHEDIKOVP G.M.; YAKOVIEV, V.I.; KOZLOV, L.L.; ZHOROV, Yu.M.; KUZOVKIN, ." . ........ I - T Activation of an aluminosilicate catalyst by protons and gamma rays of Co6O. Zhur.fiz.khim. 36 no-5:1113 Fq 162. (MIRA 15:8) 1. Moskovskiy institut neftekhimicheskoy i gazovoy promyshlennosti. (AluminosiUeates) (Catalysis) (Radiation) GCRSHKOV, V.I.;-PANCHENKOV, G.M.; IVANOVA, T.V. Kinetics of alka3-i metal ion exchanRe on the milfonate-d KU-2 cation exchanger in water and in 60% methyl alcohol. Zhur.fiz. khim. -- 36 no.8:1690-1694 Ag 162. OaRA 15: 8) 1. Moskovskiy gosudarstvenW universitat imeni M.V.Lomonosova, kafedra fizicheskoy khimii. Neta-l ions) (Ion exchange resins) SHABAHOV.. A.A.; GCRSHKOV, V.I.; PANCHENKOV, G.M. Electrochromatographic sep&ration on a cation exchanger. Part 2.- Rates of motion of the 20neS. Zhur.fiz.khim. 36 no.,8:1695-1697 Ag 162. (MIRA 15:8) 1. Moskovskiy-gosudarstvannyy universitet imeni Lomonosova kafedra fizicheskiy khimii. - =, ~ (Chromatographic analysis.) (Electrophoresis) (Ion exchange) 42185 S/07 62/036/01i/015/021 BIOIYB180 ATITHORS: Panohenl,ov G Mot and Zhorovp Yu. M. TITLE: Xinotics of chemical reactions between gaseous and liquid .reactants with volume changes in.a stationary system PLRIODICAL: Zhurnal fizicheskoy-khimii, V. 36,-no. 11, 1962, 2520-2524 TEM Unlike classical kinetioa, the ohange'in volume muct be taken into account. For this purpose, the volume of the reacting system is represented as a function of the degree of conversion, and the following is obtained for the rate of reaction: WAiliq noAlliq AVO - PXA,li,)l (dxA iliq/d-r), where A is the liquid reactant, n its initial concentration, x the 1 liq degree of convorsion, i the reaction time, Vo the initial volume, and P - (no- 'A 1* 11 - stoichiometric coefficient; 1 iq Card 1/2 GORSHKOV, V.I.; NJZNETSOV, I.A.;,PANCHENKOV, G.M. Continuous countercurrent ion-exchar-ge method of separation. Dokl. AN SSSR 143 no.3:643-645 MW 162. (MIRA 15:3) 1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova. Predstavleno akademikom TI.Spitsynym. iIon exchange) GORSHKOV, V.I.; KUZNETSOV, I.A.; Ma~ntbanancce of parallel transport conditions in a moving'bed of-ioa.exchanger.'Zhur. f.,Lz. khim. 36 no.3,.63.1-613 Mr 162, (MIM 17.-8) 1. Moskovsk_ly gosudarstvennyy universitat imeni Lomonosova. SEMIOKHIN, I.A.; PANCHENROVY G.M.; KOROVKIN., V.K. Oxygen isotope separation in the electrosynthesis of ozone. Par-,.-. 2. Zhur. fiz. khim. 36 no.11:2561-2563 U162. (MIRA l715) 1, MoskoNskiy goaudarstvennyy universitet imeni Lomonosova: PANCIIENFOV, G-JI.- ZBOROVY YU.M. p Kinetics of chemical reactions between gaseous and liquId reactants proceeding in a stationary system with change in volume. Zhur. fiz. khim. 36 no.,11-.2520-2524 N162. (MIRA 17:5) 1. Moskovskiy gosudarstvennyy universitet Imeni Lomonosova. GOLUBEV, V.S.; PANCHENKOV, G.M* sorption kinetice and ion exchange In the outer diffunion region in Ahe presence of liquid phase flow. &ur-fiz.khim. 36 no.10: 2271-2274 0 1620 (MIRA 17:4) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. SHABANOV, A.A.; GORSHKOV, V.I.; PANCliENNOVO G.M. Electric conductivity of the sulfonat-9--cation exchanger SDV-3 in water-alcohol and water-acetone solutions. Zhur.fiz.khim. 36 no.10:2148-2152 0 162. (MIRA 17:4) 1. Moskovskiy gosUdarstvennyy univer'sitet imeni Lomonosova, 4. PA 'NO PIE! 11 1fO1*Tj (11 H * KWISHIRUI.1m) I.M.; SAVHKOVA, N.M.; DEITISOVA, L.N. --, -- -:A ~ I) Sr,rj,t.*,.on of water on aluminosilica gals at elevated temperatures. Zhur. fiz. khim. 36 no-3:641-643 mr 162. (MIRA 17:8) 1. lioskovs~iy gosudaraWonnyy UnA.V01'.1311,0t imcni Lomonosova. PANCHENKOV, G.M.; ZHOROV, Yu.M. Determinating the kinc;tjc viijues of simple- rind compl-Cy reactions in eirculat'ng reactors. Trudy MINKHiGP no.i~/.:141-147 163. 041RA IS: 5) G M FANCHEN'YO"f Mdiation-the~ no.44:210-2!j PANCIIENKOV, G.M.; BARANOV, Ma. Kinetics of the therrml cracking of indIvIdual and oil fractions. Trudy MIKHAP no.44:214-219 163. (MMA 1-8: 5) PANCHENKOV V.A. Adsorption of the var;ora of indivi6ual- hydromrbor.3 b7 molecular sieves. Trudy MlNKlliGP rio.44-.220-226 163. (MIRA IS: 5) TOLMACHEV, A.M.; FEDDROV, V.A.; PANChTNKOV, G.M. Synthetic zeolites as ion exchanger!i. Part 3. Zhur. fiz. ki-xim. 37 no.11:2548-2550 N163. -* (MIRA 17:2) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. KGLESNIKOV, I.M.; PANCIIENKOV, G.M.; MOROZOV, Ye.A.; ANISIMOVA, N.N. Kinetics of the alkylation of beenzene with ethylene us!.ng an aluminosilica:' catalyst in the gas phase with the addition of gaseous hydrogi chloride. Izv.-vys.-ucheb.zav.; neft' i gaz 6 no.11:85-90 163. (MIRA 17!9*) 1. Moskovskiy Institut neftekhimicheakoy i gazovoy promyshlennosti Im.akademika T-.M.Gubkina. GORSHKOV, V.I.; KUZNETSOV, I.A.; PANCHENKOV, G.M.; KUSTOVA, L.V. Gontinno,is coiintercu~rent Lion exchange irie'thod for neprtrsti6n of lithium and sodium. Zhur. neorg. khim. 8 no.142:2790.-,~794 D 163. Feasibility of countercurrent ion exchange separation of rubidium and cesium. Ibid.z2795-2799 (MIRA 17:9) 1. Moskovskly gosudarstvennyy univer.91tet imani Lomonosova, kafedra fizicheskoy khimii. GORSHKOV, VJ.; PANCIFNKOV~ G 1-1 SAWNY(TA, N,P.; SAIF ST1YANOITA. 3.U. . ~. .; .0 ContInuous countercurrent Jrri m3thc/l for tz- .. 1~ -eparatlcn. cr~ rubidium and ceiiilm oil tfig rrjtjc)T., exchariper KU-1. Zhur, neorg. khim. 8 no.12:28C)0-28D5 1) !0, (~MHA 17,q) 1. Mosl,ovskiy gosudarstvennyy universitet, imeni Lomonosova, kafedra fizicheskoy kbirriii. YERE,%IIN,, Ye.N.j prof.; KISELEV A.v., prof., I PANCIOfWV prod.; FOLTOFjjy, N.I., prof.; V.M.,Iprof. - TOPCHYEVA' 0 ~m ~, pro4 f .; SKURA-1011, 5 P,.,Prof.; Prof.; FILIPPOV P v., Prof.; FIGUROVS:'KIY: M.A., I Yu.v., prof.; SIIAKIIPAjjONOV prof. II&Ov Ivanovich Gerasimov; (, ur. fiz. kbim. -17 no.12:2803-2804 D Onl6his sixtieth birtbday. zh RA 17:1) 1. Kafedra fizielieskoy khlmii Moskovskogo gosudarstvennogo universiteta. GERASIMOVI Yakov Ivanovich, prof.; DREVING) Vladimir Petrovich; YEREMIN, Yevgeydy Hikolayevich; UaIM, Andrey Vladimirevich; LEBEDEV, Vladimir petrovich; ~ANGHENKOV, Qeorgiy,Mitrofanovich; SHLYGIN, Aleksandr Ivanovich; NIKOLISKlY, B.P., prof., retsenzent; SHUSHUNOV, V.A., prof., retsenzent; LURIYE, G.Ye., red.; SHPAK, Ye.G., tekhn. red. (Course in phyeical chemistry] Kurs fizicheskoi khimii. [By] IA.I.Gerasimov i dr. Moskva, Goskhimizdat, 1963. Vol.l. 624 p. (MIRA 17:1) 1. Chlen-korrespondent Ali SSSR (for Gerasimov, Nikollskiy). 2. Kafe6ra phizichEskoy khimii Leningradskogo gosudarstvennogo universiteta- (for Nikollskiyj Shushunov). ---PANCHWO'I-- GedrglSr7YILtrof anovich- 'I Kinetics of chemical proccesses in oil refining and petrochemistry in flow-type reactors " report to be submitted for the 6th World Petroleum Congress, Frankfurt am Main, V. Germany, 19-26 jun 63. PANC-%MV,, 0-14-i SEMIOXHINp I.A.; KDROVKIN, V.K. *Zur Frage des ?%chaniams der Verteilung der Isotope des Sauerstoffs bei der Elektro- anthese von 02pr? Third Working Conference on Stable Isotopes, 28 October to 2 November 1963, Leipzig. PKICHMOV0 G,, HV; - Timofeyev, Ye.P.; TSIVAKIMN, V. D.; PECHALIN, L. I.; OTrennung der Isotope des Titans durch Gogenstromieatillation von Titantstrachlorid" Third Working Conference on Stable Isotopes, 28 October to 2 November 1963, Leip71g. - -PANCHENMV~ G.M.;. ANDREYOV Yu.P.- IMRDVKIN, V.K.; SEMIOMN, I.A. - .9 A OUntersuchung der Kinetik und des Mechaniamw der Isotopenvertailung bei der Dissoziation Von Koblandioxyd in alektriacben Entladungere Third Working Conference on Stable Isotopes, 28 October to 2 November 1963, Leipzig. -pAVcHEMV, G.M.; UREMIN, V..S.,- NIKITIN, O.T.; GRYAZNDVA, S.V. xTrennung der Isotope des Wasserstoffs an Kobalt-MolekularsiebeO Tbird Working Conference on Stable lBotopes,, 28 October to 2 November 1963p Leipzig. -pAX-CHMTKOV, G. U.; KOLCHIN, A. X.; wMassenspektrometrische Isotoperanalyse ac Bortrifluorid" RMasisenspektrometrische Inotopenanalyee am einigen Blementen der Seltenen Br4en' Third Working Conference on Stable Isotopes, 28 October to 2 November 1963, Leipzig. PANCNENKOV, 0. U.,, GOLUBICV, V. S.; "Xine Methode zar Berechnung der Dynamik der Sorption und Chromatographie" Third Working Conference on Stable IsotopeB 28 Oct to 2 November 1963, Leipzig. PANCHERM7,4G.M.j GORSHKOV, V.I.; KuMTSOV., I.A. "Bing kontinuierliche Gagenstrfn-lonenaustauscbmthodii ur Trennung von Ionenmit annnhej-d ubaminetimminden Eigemachaftey? Ibird Working Conference on Stable Isotopes,, 28 October to 2 November 1963,, Leipzig. ~N z- PANCHENWIVI 06-M,; GOMM L.N,; NIKITINp OOT# 4,9 IlMassenspektrometrische Isotopenanlyse am Titan* Third Working Conference on Stable Isotopss 28 October to 2 November 1963, Leipzig. PANCHMOV, G. M.; KUMETSOVA, Ye. M.; GRYAZNOVA, S. V.; "Zur Frage der Isotopentrennung durch -4bctraktionn Berechnung des elementaren Isotopentrennfaktors bei Iotopenaustwastauschreaktionei:i und b der Deatillation. Third Working Conference on 3table Isotopes, 28 October to 2 November 1963, LeipAg. 5/189/63/000/00 1/00 1/0 D204/D307 UTHORS: Panchenkov G nd Makarov, A. V. LM._-a TITLE: Preparation of boron trifluoride PERIODICAL: Moscow. Universitet. Vestnik.. Seriya II Khimiya, no. 1, 3 -6 TEXT: The present work was motivated by the-ditficulty in producing -,large quantities of pure BF Considerable quantities of BF Con- '3 3 SiF may be obtained by gradually adding oleum to inti-' 4 mately mixed KH4B and B ..The initial 20 - 30% of B are evol- F4 203 F3 ved in the cold; further evolution requires heating. Pyrex glass is u d The BF, passed through a water-cooled reflax condensert 2 se ';.1-2~.;-trapp cooled with solid 00 acetone, and is purified by freezing 2 -'-'~-,with liquid N,*'The.apps~ratus may yield -200,1 of BF per day. Lea- a rquantitieB of BP of higher purity (~0.1% SiF 3 4) may be obtained' lie- -a 1/2 Gar paration of boron B/lBY63/000/001/001/008 D204 D307 continuously by the decomposition of C6H5 N2 BF4(into 005F, N 2and BF in pyrex Apparatus, under reduced pressure, wAh gentle heat- 3 ing. The 0 H wae'removed by passing through cold traps (acetone/so-' 6 5 lid 00 aiid BF was collected in a trap cooled with liq~xid N 2) 3 2 ~.-The gas mayp if neceasaryt be further purifiedt e.g. by rectifioa- tion or thermal diffusion. There are 2 figuresq, SSOOIATIONv-, Kafedra fizicheakoy khimii (Physical Chemistry De- partment) SUBMITTBDI February 8t -.1961.- I '~rOard 2/2 B/189/63/000/001/002i D204/D307 .,-.AUTHORS& Panchenkov, G. M. Makarov, A.. V. and Rozynov, B. V. 'TITLEs Kinetics of the absorption of BF during the formation 3 of tho anisole complex -PERIODICAL; Moscow. Universitet. Vestnik. Beriya II. Khimiya,no,o I,.' ri~~r,-'--_ - 1963t 7-9 -.mBXT,. -The absorption of pure BF (obtained by the decompositi on of 3 -phenyl diazonium borofluoride)'in the anisole. BF complex unsatu- 3 -.J.,-rated w.r.t. BF3 was etudiedo in view of the interest of this pro- _.'.:.-,:blem in.the separation of various isotopes of B. Pyrex apparatus was used throughout. The complex waB maintained at 2000 and the ---,init:Lal pressure (p was measured. Additional BF was then passed 0 3 in, o give a pressure P, and this pressure was measured as a ..function'of.time-tq i.e. (t). The experiment was regarded as fi-~,~ p nished when. p(t)'remained practically conBtant with time& It was- Card 1/2 ",.A.V4La116Vj U92AS16 WLU VILUZ *IUU Wl~ -1 kll- mation PEMIODICAL: Vestnik Moskovskogo universiteta, Seriya II, Khimiya, no. 2, 1963, The construction of a two-stage cascade apparatus with six pe.oked TEM Colum-ris for the separation of boron isotopes by chemical exchange is deacribed. The n:-actionating is carried out between gaseous BF3 and the liquid R-13 oomplex with anisole. The apparatus might be used also for other B'F3 complexes oi- for separation of isotopes cf other elements. It contains princiPallY 3 reservoirB for the BP .3 - C&l15c'CH complex, one flask for pumping over the complex, an electromagnetic regu~2or of the flow velocity, six packed columnz (length about 2.5 m,. diameter 15 and 9 m, total length of package 15.8 nij two distillation columas, one electromagneti.c flow-separator, two desorbers, six evaporatA)rs, C ard 1/2 ___--___X_~~~ ?Igav_nw, -for'borcin isotope .... A057/A126 -cascade .0aratus coolers, manometer, etc. The BF3 gas wa:; prepared from NH4BF4, B203 and H~,SQ4 and passed through anisole to the saturation point with BF The BF3 complex ic thell passed bW meana of The aloctromagnotio do8er to th 0 first column of the Carmado, -then ovaporated In 'the first evaporator (200 C); the evaporated 131? 3 and anisole are condensed and thus the newly foruped complex is passed to the top of the second packed column. ThIs was repeated until the complex passed the fifth packed column, from where it entered the electromagnetic separator, whero the thermal decompesition of the complex to BF3 and anisole was effected on the desorber. By changing the duration of electric pulses and the pulse intervals, the separation degree of the complex flows was regulated. The final decomposi- tion of the complex was attained in the second (150*C) desorber. P-.3riodic sam- pling is carried out during the operationof the apparatus for isotope analysis. -----There As 71 -figure. Kafedra,fizicheakoy kh1mii (Department of Physical Chemictry) .-SUBVIMTEDs April 6, 19 62 Cara ?/2 S/152/63/000/002/003/003 B126/B166. AUTUORSi Panohenkov, G. 14.t Ilikiti na, E& V. TITLE: Exchangeability of alumosilioatga prepare.d by varivuo methods PERIODICALt Izvestiya, vy9ehikh uchobnykh zavedeniy., Neft, A. -g" I A09., 21 1963, 70 74 TEXT: Three methods were.-ueed.to pre pare samples -of an.alumo6ilioat6 catalyst: blending of sulfate.of aluminum sofutions, and: liquid glaee wil'1i pubsequent coagulation to alumosilicate.' gel; a at.uration of humid gel with solutions of aluminum -nitra-te of various 'OoAcentraiivns-,with-- aub-: sequent decomposition of aluminum salt during drying ,an-a' he-atink; and- blending of separately precipitated'silica g6la'and aluminum hydroxido. It was shown that the exchange of aluminwr-and hyroszen ions. in alumo--* silicates obtained by joint precipitation is.subject to the law.of mass, and their maximum qUiLntity exchangeable' against the ion of sodium 'from a sodium chloride solution was calculated on this basis% Rowevert- -this IaW is not applicable to samples obtained by ~saturation of .9ilioa- gal or by blending separately precipitated gels. In these catalyst& 1he quantity' of exchangeable ions of aluminum is much smaller, Ho*ev'e'r'# rAn - i hil dr*a as e Card 1/2 ACCESSION NRs AP3=04 5/0189i63/000/003/0029/0032 'AUTHORS: Semiokhin,, Is. A.; Panchenkov, G. M.; Korovkin, V. K. ,TITLE.- Utilization of ozone electrosynthesis in the concentration of the rare oxygen isotope 0-18 SOURCE: Moscow. Universitet* Vestnik. Seriya 2, Khimiya, no. 3, 1963, 29-32 TOFIC,TAGS; electrosynthesis, ozone electrosynWesis) 0-18 isotope, ov-gen isotope, oxygen isotope concentration, ozonizer, ozone concentration, molecular ozonb redistribution, molecular oxyGen redistribution, isotope redistribution, 92Wgen isotope redistribution velocity ABSoTRAM A short report was delivered at the All-Union UnivurniLios Conforonco on Ozonoj WU) May 1960o The purpose of this atudy wao to dotormino the rolation between the separation coefficieet, arxl the velocity of oxygon inotope separation (with respect to the time interval during which oxygen remained in the electrical discharge zone, to length of the reactor, to pressure, to temperature, and.to the procedure of ozone accumulation and sampling). Haximum ozone concontrat.-Ion was 9-10 vol % (at 2OG and 760 mm Hg), The isotope composition analysis was conducted with the 14S-3 maas-appotrometers T.119:specific energy factor u/v (ratio of Card 1/2 L r-4 W./VW FW ACCESSION NR: A23oc)4692 AUTHORS-._ V.; ?aNcnelikov, Xakarov, A. of its comolex coa:)Gunds -46-rBS ..--..E!scowj; niversite 16PICIsTAGB; boron fluoride, desorption, kinetics of desorption, complexes, 1-1 s 14': enot ogle, chlorex i-ABSTRACT.,;' The desorption kinetics at various temperatures of borontrifluoride I Us comolexes with anisole, phenet 7chlorex, ai-d sulfuric acid were vestigated. Experiments were conducted in apparatus designed by A. V. Makarov and G. 1-1. Panchenkov (Zhi~ih, 3L, 639, ig6o), in which the volume of evolved BF 3 -4" 115-estimated by means of a gasometer. Fifty-three kinetic curves of the evolved I'g. anging from ! as for 10 to 60--minute inteinrals were plotted, with temperatures r '134 to 116.% for the anisole from 28.9 to 146.8C for the phenetole, frora 31.6 96. C for the chlorex, and from 68.2 to 96.2C for the sulfuric acid complex. Thvresults show that the desorption of BF3 from its complexes proceeds at a !comparatively slow rate for temperatures of 50-10OC' the desorption from the i suAfuria: acid'complex being the slowest,, The findinisgs are expected to be of 1/2 t i -, .. w- ACCESSION NR; AT40087W S/2982/63/000/044/02)0/0213 AUTHOR: Panchenkov. G. M.: Yakov)ev, V. I.; Koz)ov, L. L.; Zhurav)ev, G. 1. TITLE: Radiation thermal cracking of petroleum fractions SOU9CE: Moscow. institut neftekhimicheskoy I gazovoy promy*sh)ennosti. Trudy*, no.'44, 1963. Neftekhimiya, pererabotka neftl I gaza, 210-2)3 TOPIX TAGS: cracking, petroleum product cracking, thermal cracking, radiation cracking, radiation thermal cracking, gamma irradiation, gas oil radiation crack- Ing, petroleum product irradiation, gasoline fraction Irradiation, petroleum refining, petroleum cracking, radiation cracking ABSTRACT: Gas oil from Romashkinskaya petroleum (fraction 300-345C).was irradiat- ed (100 r/sec) at temperatures of 400 and 425C. Another series of experiments em- ployed the 350-500C fraction of the same petroleum, a radiation dosage of 92 r/sec and temperatures of 375 and 390C. The designations "RTC' and IIHC" are used here to indicate heat cracking processes with and without the use of radiation, respect- Ively. The authors found that radiation accelerates the decomposition of the original gas oil by 50 to 100% (see Figs. I and 4 in the Enclosure)f The yield of gasoline fractions showed preferrable patterns for the 300-345C fraction at 425C and radiation- levels above 3500 r, as wel I as for the other fraction at 390C and Card IAV; ,ON NR: AT4008703 ACCESS ire). The content of olefins levels above 3000 r (see Figs; 2 and 3 in the Enclos, nding fractions for "C* oli e fractions Is 10we for RTC than in correspo in gas n phs. Orig. art. has: 4 gra INSTITUT NEFWjjjMIC1iESYOY I GAZOVOY PRomY*SHLENNOSTI, MOSCOW ASSOCIATION: stry and the gas industry) (institute for petroleum chemi ENCL; 04 DATE ACQ: 16Jan64 SUBMITTED: 00 OT"ERZ 002 .SUB CODE: FL No REF SOV: 006 card k . -I --- . FAIRCHMOVS G.M.; GORSHKM, V.I.; SLOVETSKIY, V.I. Comparative kinetic charaoteristico of the KU-lp SDV-3. SM-12,.and SBS cation eirbangers, Kin,i-k ft. 4 no.1:82-87 Ja-F 163. (MIM 160? lo Moskovskiy gosudarstvannyy universitet imeni M.N.Damonosova, Ichimi-choskiy fakulltet. (Ion exchange) GOLUBEVY V-S-; KIRIGINTSEV, A.N.; FAhCHEHKOV,,_G..,t~, ......... Equation for the output curve of equilibrium sorption in a con- tinuous flow of the substance adsorbed by an adsorbent. Kin. i kate 4 no-4.635-643 R-Ag 163,, (MIRA 16:1.1) 1. Institut neorganichesk* kbimii Sibirakogo otdeleniya -0 SSSR J l,bskovskiy gosudarstvennyy universitet imeni Lomonosovap khimiches- kiy fakulltet. AGEM, Ye.P.; pANCHENKOV, G.M. ---- - oxygen isotOPe BOParation 14 no .5'494-496 energ. emal diffusion mthcld- Atom. bY the th (mIRA 16:01) Yff 163. (Jaotopo, separation) KUZKgfSOV, I.A.; ~USTOVA, L.V.; GORSHKOV, V.I.; PANCHMOV, q.M._ Equilibrium of cation exchange of alkali metals on cation exchange-resins KU-1 and KU-2. Vest.Mosk.un.ger.Whiz. 18 no.2:10-1.3 *-Ap 163. (MIRA 16.5) 1. Kafedra fizicheskoy khimii Moskovskogo universiteta. (Alkali metals) (Ion exchange resins) (Chromatographic ana2,vais) PANCHMOV, G.M.; MAKAROV,,A.V.; DIYACHENKO, V.Ya.; MOISEYEV) V.D. Therual diffusion-of BF3 under pressure. Vest. Moak. un. Ser. 2: Khim. 18 no.3:33-36 W-Je 163. (MIRA 16:6) 1. Kafedra fizichesk6y khimii Moskovskogo universiteta. (Boron fluorides) (Boron isotopes) GOLUBEV., V.S.; PANGHENKOV,, G.M.. Layer by layer method of computation of the dynamics of non- equilibrium sorption and chromatography. Zhur.fiz.khim~ 37 no.2: 310-317 F 163, (MIU 16;5) 1. MDakovskiy gosudarstvennyy universitat imeni M.V.Lomononova. (Sorption) (Chromatography) S/076-163/037/002/018/016 '5' Yc~L B1447B180 Panchenkov, Go Mot Tolmachev, L. M., Fedorovp V, As AUTHORS; TITLE: Synthetic zeolites as Ion exchangers. II. Study of the ion exchange equilibrium PERIODICAL: Zhurnal fizicheskoy khimii, v. '37, no. 2, 1963,-456-459 TEXT: The equilibrium of the exchang' + + + 2+. 2+ ,o e of NH Li Na Ca. , Pb no.' 4 ' was studied on two samples of-synthetic 4A zeolites at 20 + 2 C. Based on the equation of R. M. Barrer and J. Do Falkoner (Proc. Toy. Soo., . I'4 A236, 227, 1956),Iog K' - log (M ) + a(i - 2 was derived- M ) M th BX AZ BZ AX AZ for the 1,1-valent ion exchange and log Kit - log K + a (M 1/2M )/(lj + 1/2M..) for the 1,2 ion'exchanget th AZ BZ AZ where Kth are the thermodynamic equilibrium,constants, M the concejtratioz~ B the univalent cation, X the univalent anion, A a cation of valency 1 or 21 and Z the zeolite. The second equation holds onlyfor constants concentrations of the solution. These equations include the ratio of the. Card-1/2 S/076/63/037/002/018/018 Synthetic zeolitea as ion i. B144/B160 ion activities in bolution and show that KI is independent of the th concentration, whereas K" decreases significant-ly when the concentration- th increases. This was proved.by the values calculated for the systems Cacl + Li4A; Fb(NO + NH 4A; CaCl + Na4A. K is highly dependent ok 2 3)2 4 2 7 the degree of ex'change. It:decreases 'when small ions are replaced by big lons or univalent by bivalent'ions. The separating capacity of synthetic.'' zeolites is 150-90oA, greater than that of ion exchange resins. There are 2 figures,and 4 tables. ASSOCIiTION: Moskovskiy gosudarstvennyy univereitet im. M. V. Lomonosova (Moscow State University imeni M. V. Lomonosov) SUBMITTED: April 21, 1962 Card.2/2 L 16927-63--. Bw (q) IVAT (m) AFM/ASD it, S/076/0'3/,~32/004/019/029 AWHOR: Arshakuni, R._ G., Kolchin,_ A.- M.,- Pancli nkov~ G. M. IIELE: Hass syactroscopic analysis of germanturi isotopes -a,,/ PERIODICAL: Zhurnal fizicheskoy khirdi, V. 37, No. 4, 1963, 893-896 TEIrl,. A mass spectroscopic method of the isotopic aaalysis of germanium has been develoDed. For the arialysie the complex sali. BaGeF6 which decomposes In rizer is used. The ar-ount of subsiancc which R_'_Ed_771-._~-h~ a;,.a1YL`z - a vapo s 0.3-,D..,I, milligrams of BaGeF6, which is not a minimum quantity. The BaGeF6 iLter- acts with the material of the vaporizer with the foxmition of GBF2. The mass spectrum which is formed ixpon the ionization of the molecules of GeF2 is studied. _.____TOe_,ex,pedienq of an isotopic analysis of germanium for peaks of CeF4- Ikons is saourr --and tin analysir. a de.- A analysir, 'A's of- siample~-:bf metallic germanium is-, rforTw n made of random errors in measurement. There are 3 figures and 1 table. ASSOCIETION: Yoskovskiy gosudarstvennyy universitet ineni M. V. Lomonosova (V'c~scow State University imeni M. V. Lomonosov), Moscow SUBMTED: Fjay 2-2, 1962 Card.1/1 SjUaOyjaN, I.A.; PANCHEIMO.V, G.M.; Y~RSHOVA, N-P- 41--- Separation of carbon isotopeb by countercurrent chemir-al exchange in the gas, phase. Part,2-. Effect of -nitrogen and oxyg6n..Zhur, fiz. khin. 37 no.6:1409-14-U Je 163. (HIRA 16:7) 1. Moskovski7 gosudarstvennyy universitet imni Lomonosava. (Carbon isotopes) (Nitrogen) (Cmygen) TOLMACHEV, A.M.; 6ORSHKOV, V.I.; EgqypNYOv, G.M. Eachnnga dybivoics of ions of diffore-rit valoncieB. Zhur,fiz.k1lim. 37 no.7-. 1635-1636 Jl 163. (MIRA 17:2) 1. Ilmskovskiy gosudarstvennyj mn~;,fersitct, KU2NETSOVA, Ye.M.; MAKAROV, A.V.; PANCHENKOV. G.H.: PARBUZIN, V.S. 4,j,='tion of the once-through isotope separation coefficient fr-oim data on,ihe equilibrium operation of a column with a draw-off pan. Zhur. fiz.khim. 37 no.lOt2349-2350 0 163. (MIRA 1':2) 1. Moskovskiy gosudarstvannyy universitet imani Lomonosova, khinticheskiy fakulitet. KOLESNIKOVP I.M.; G11.1M. Calculation of the kinetic constants of processes occurring in the gas phase in a flow. Zhur. fiz. khim. 37-no.12:2698-2705 D t63. (MIRA 17:1) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. SUG01UHNO I.A.; ANDREYEV, Yu.P.; PAL~QHENKOVI, q.M. Separation of oxygen and carbon isotopes in dissociation of C02 in the silent electrical discharge, Zhur. fiz. khim. 37 no .12t 2782-2783 D 163. (MIRA 17:1) 1. MoskDvskiy gosudarstvennyy universitet imeni Lomonosova. i IUZNMOVA, Ye.14.; MRYAZNOVA, ZOT.; PAECHIMKOV., G.14. Calcalatim of the single-separatium coefficient for acne cheadoel axcbange reactions. DWI. AN SSSR 148 no*ltl44-1/+7 ;a 163, (MM 16t2) 10 Woskovskiy gosudarstvennyy universitet im. M.V. lomonosova. Predstavleno akademikom A.N. Pi-mgdmyn. (Isotope separation) PANCHENKOV, G.M.; YERCMTKOV V.V. Relation between diffusion and short-range order in a liquid. Vast. M)sk, un. Ser. 2:20-29 Ja-F 164. (MIRA 17;6) 1. Kafedra fizicheakoy khimii,, Moskovskogo universiteta. i.if AGGEIKON XRi A.P4047&t6 AUTHORSt TT'r!F! "h.? t -f' ACCESSION MR: A.P4047646 no energy In the presence of 002. At a fix-ad pr64vuli-e, tbe combust-Isn "ItaFs dacreaaad with inarease in Ho ALW A conc-antration, t;ut L-d t i &I pr"sure of the g" nd-xtUrO WELS '150 00 H&i. CtangO J,,11 out impuritv) from 300 to 750 M- Hg !Ad 1whw-ge in r--;7r-z ~i c, 'L :1 13 0 -c rm p U L 'Z, ,ra-!,v 01 U- PJ-1-f V.. EM equildbrims. caus ---lXG-Aa SO.Arm-417 fte to A~:Aedliuo it lbe2paratwe in the of --10HI3* Of OW.5 QiaFlrg~' d"rMnur, excit-e-tion n? 4--h--3 0,; arr-A ~!C- ACCFSnG.q MI AP047646 diBsoaiLtica. In an aloatrina rU-sch-aroe thin ujugilr.~.; or tha co'd 16C-10-6~ FVr- (m)/EPF(,- 1."T T t ACCESSION mR. A P40-i8 j T I LE: X,~ flFt I L', J~ 1 :-L catajytic reforming,, SOURCE' VVUZ Nef t a I 9di 40 - -1564. TOPIC TAGS: hydrogenolys'fs, t hnPliene. s0fide, ~:atalytic reforming, sulfur, heptane, butylthiophene, merzaptan, octane nufr.t~er ABSTRAC'r, The octane number and corro5iveness of fuels are influenced considerab- b, an~ -~e-r 3ct in, 'q~': 'hey cc,rtair. one OF t tie ~"thn-dc~ for re- react iot; inixture cz3uce.d tne Card /2 crease, but with increasing t mmpevat lire, under othf-lise equal dearee of corvers;on jnCrea,~&(J. T-,~ (-~j Lj a I j F)v! ~ -. - --j : -11 - I ~ I of the final U-'erivtd equation are La"llate"U. TI 3-1 rc vvi'ai-nt 6, %,-.I VUL I V71 'U'M I"W~ found to be 25.5 kcalf"mole. By the formiula 9'ven, 'the degirei-, of cc,caver-5 ion Of 2-butylthir--phene was calculated at different feeding rates and temperatures. The theoretical and cyperimental pcir-r?,ed we'', r h: C: "-M c -4 :~Ij --,Jror3~-tlorl arid hydrooen, the v n:, Orig. art. ha:~: 2 tabies and b 'ormulas. ASSOCIATION: Moskovskiy inst'4tut neftekhimichesko), i gazovoy promy*shlennosti im.akad. I . M. Gubkina (Moscow ln~~tititte of the Pet rochemicFl --4nd (_-a,; i:.riij~trv) IUBMITTED: DbAp r6L, OTHER: 000 PANGIMKOV, G.M.; VE-ITYATACTIA!'JOI, 'Yu.t,'* Kinetics of tle debardrocyc~ lzT tar of p~,niff:L-i hydlroCa3~banZS or, L OyAde catalysts. NeftekhIm-Liz 4 nc.1230-30' Ja~FIU (MI-RA 1? :6) 1. Moskovskiy histitut neftekh-i-micheskoy I g&zovoy promyshlen- nosti imeni 1.14.QLblina. PM4cHa1XDvP G.14.; ZBOROV, Yu.Y.; VIWKATACPAL~24, X.A.; GUIRWICT11, I.P. Datermining the group compositim. of hydrocarbon mixtures by liquid chrorr tography with luminescent Indicatont. Nefte'k-himiia 4 ro.1:128-.;-~32, -Ta-F'64 (MIRA 17:6) 1. Moskovskiy institut noftekhimicheskc.,r i gazovoy promysh- lermosti. imeni. I.M. Oubkina. ZHOROV) Yu.M. t PANCHENIKOV., G.14.~., Formal kinetics of chemical reaczions Jin Una 1-4quj-d ~:hase oczuring with change in volume. Izv. -;ys. ucheb. zav.; neft' i gaz 7 no.7: 49- 53 IZ4. (MM 17:9) 1. Moskovskiy instit-ut neftekhimichaskoy i gazovoy prOm7shlemo3ti in. akad. I.M. Gubkina. SEMIOMN G.M.; SALIMOVA, K.M.; AA~Mlp YU.P. Isotope exchange between carbon d4-xide and its ethanolaminS solutions. Vast. Mosk. un. Ser. 2-.Khiia. 19 no.1:35-38 Ja-F 164. (MIRA 17:6) 1. Kafedra fizicheskoy khimii Moskovskogo univeraiteta. TOMICHEV, A.M.; DINISOVA, L.V.; FT)OROY, V.A.; -G,M., Elution-partition of alkali metal iOn;3 on a syntheti.c A-type zeolite. Vest. Mosk. mi. Ser. 2 Khim.. 19 no.200-22 Mr-AP'64 t 1. Kafedra fizicheskoy khimii Moskovskogo univeraiteta. KOLESNIKOV, I.M.; ~AN.CHENKOV,,G.M. Kinetics of ethyl alcohol dehydration In the gas phase in a fl(yw. Kinetic equations. Zhur. fiz. khim. 39 no.1:96-101 Ja.164. (MIRA 17:2) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. PANCHE14K-OVP~ G.M. Kinetics of chemical reactions in a flow with complete mixing. Zhur. fiz. khim. 38 no.1:136-140 Ja164- (YIRA 17:2) 1. Moskovskiy institut neftekhimicheskoy i gazovoy promyshlennosti imeni I.M. Gubkina. G*14* --P --~ . mical, Processes in a flow it Dynamics of unsteady.phYAr-c-ch8 ~ecqtlar reaotion the case of the process ra~,e ob,3ying the biMO-L (MIRA 17-~?) 3-aw. Zhur. fiz. khim. 38 no.3-770-773 Mr 164. 1*Moskovalkiy institut'neftelchimichookcy i gazOvoY pronyi~U en- noati imeni 1.14. Gubkina- ANDREYEV, yu.p.; -rMIOKHIN, 1,A,; PANGHENKOV~ G*M,; PARAYEV, V*V- Dissociation of carbon dimide !n the silent electric discharge. Zhur. fiz, khjm. 38 no.3:791+-797 Mr 164. (MIRA 17:7) 1, Mookovskiy gosudarstvenpyy universitet imeni M.V. Lomonosova. GOLUBEV, V.S., PANCHENKOV,,.__G.M6 DeterTdnation of the diffusion mechaniBmcontrolling the rate of sorption (ion exchange). Zhur. fiz. kh-4m. 38 no.4:1010-1013 AP 164e (AURA l7t6l 1. Moskovskiy gosudaratm-ennyy univeraitet im. M,,V. Lomonosova. p.; SEMIOKHIN, I.A.;~ rj,M- AAMEM YU % i Redistribution of oxygen and carbon isotopes bo-tween carbon dioxide and the products of its dissocia-Iion in a silent 164. electric discharges Zhur. fiz. khim. 38 no,4:lo32-1035 AP (MIRA 17:6) 1 Moskov" gosudaretvennYY universitet imeni M.V. Lomonosovas /EWP (O)lEwp 'Pq-4 I 2L'" 3 6 VoIT m p:jnch-enkov, TA, A. C 2' C, X. electrical discharge SOUPCT: Zhurnal fizicheskoy W111MU, v, 38, no. 8, 2072-2076 7",n dine,,;, de merlt, rnass specrornetry, nf carborn d".-ox,cle n a P allu ui- -S a f~mction of exper~-n--e -e Cord 1/4 PM gj) gosudarstvennotgno unwersite- ;,akul!tet Moskovskc) ASSoc.-,A,flON. yhimiche-9k. u6cow S-.atte 'Um-i- ,a (CIle mist ry_p_~~a v V. MendeleyeN n., WM-M: W_. sk g ggn -1-0 M 'T4 am M V-nold! m M411 M2 V -A L 21335-65 A P 4 0 4 4 4 4 ffM.Card 4/4 :~Cc- -Ei -I- Dissociation C)f c a rban 10:1 :ZCN---,)Cr _zIc, ac',,.Orl T RA C i. i-~-tV~-~ 2m,! --- w~ Big r -ma-li'l Zfj ME L IL'.6-:1-65 ACCE3SIONN NR: AP404 1450 ~1~5-Bhpwn =q-.1--. - diQQnnintir-n Pnililibrium -is esse-ntiall-v indepencient of flhe ternp,-?ature of ozonizer, n cnanges very ;.-i-ET.Le wim strenglh of the discharge. The maximum degree of dissociation was obtained at SUBMITTED: 29Ju.163 SUB GC ENCL: ;)I N 0 REF SOV: 004 O'I*HT--R- 000 Coro -2 uM RIM A,-P4 U44-4 W -AtCkSSIDII WR17`~ ENCLOSURE 01 r,77, u Apparaius: 1--drying collumn, ?--rheorneter C-) 7 Card 313