SCIENTIFIC ABSTRACT PAJAK, J. - PAJEVIC, R.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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In that it thw% not cflm-t quatit 4*0 00, AS.-StA -(T&Ltfjfl(.KAL LiT(RAT01 CLAISIPIC&TWO t i tire ds - 0 11 Ail 0;1 ZV It, too 4 V I A I a Old 0 M - I a 04 it Is a 7 ' W1 13, fl, tr It OF X IN it IPI S( Iffirt 1" f v4 Lost I 61 0 0 0 0 0 0 0 0 a 0 w0 0 0 0 0 ds di * 0 0 0 0 0 0 00900 S 0 as *1 a * 0 0 0 0 0 as * e 0 0 0 0 Oooooto it too 100 400 )Do log to 100 00 Do 00 Ls of 00 00 of of 00 .00 00 100 000000000000*0000000*000 0 00 a 11,90# WAR., rim a strm hypcoulfift Jake. It 6 transt4med Into 11 on rwolonced 00 Imiling in HO. red, does not welt, Inad. in H.O. OtAlinginNaOll(riv"qttinoticsultonic mid. COL.O.VaS. from the soln. of I in 119SO4 with jfNOj (1:4) below 30. yellow 00 nredim. No-mit,red,vol-inHoO. Reduction Insik. poins. with N&TISO, givms green 00 m4n. wisich, an tivabnent with-%. kads to amimdinaphtha"Woncvpginorwadfanic mid, CnHt#G#Ns%. Vftnisb black W. It stains cotton greenish black from an "ic both. Dinkrudinsphthsaidomeqtdnome, CmHAN(NQ,)v, obtained by slow 'ntrp, te. tinn of I intoconed. HAO, + HNOs e- 85*: brlght.~ . M. 373' (deempn.1 "n.yellow-brown. Cotton is stained cray-bimck W.- - 11,S0. 00 after vshistion) by the gErn hypo. sulfite take. accompanied by reduction of the dhdtro to a diamino cnn1W. Diamino. 00 Jinvp tham u1none. black powder. Its F1p%Oj win. i3 Inown, W. 00 00 00 00 so 09 00 of 00 00 00 00 00 to 0 0 0 0 to 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o to a to 0 0 to 0 0 0 0 0 0 0 9 0 0 0 0 * 0 0 0 0 0 0 0 0 - 0 0 0 0 0 9 0 0 0 4 0 0 -- FAJAX.. Tan# mgr.j inze 1~I Air and regrigerating compressors at the 30th International FOURn Nkir. Przegl mech 20 noJB:560-564 S 161o 1-- 1. Centralne Muro Aparf4*AWnicznej,, 1rakow. BERNAS.. Stefan; PAJAK, Janusz Network amalyoer determining automatically the power distribution and voltage level. Przegl elektrotec.hn 40 no. 2:96-98 F 164. 1. Politechnika, Warszawa. pt.j-k%K,s JkN L. 1~7d. 1.7,jarszamai panstipmrwe Wydawn. Roinicze i Lesenj 1954 zarys cylowu byd1a, fv. st ed-7 456p. Coutline 01, cattle breeding* Not in DLC DA So: F-onthly List of East Eurorej)-n Acceseions LC, vol. 6, 110. 10, Oct.obcr 1957. Uncl. Ir ?Ar UTAK$ K. Management of packing, p. b. (ROLNIK SPOLDZIEWA, Idarszawa, Vol. 8, no. 1, Jan. 1955.) SO: Monthly List of East European Accessions, (EEAL), LC, Vol. b, No. 6, Jun. 19.55, Uncl. PAJAK, Kieczyslaw, inz. Universal layout of city distribution networks. Energet7ka Pol 19 no.1:9-13 Ja 165. 1. Power Plants of the Southern District, Katowice. - PAJAK, Teodor Sinusoidal tables. mechanik 34 no.1:49-51 162. 1. Fabryka Wyrobow Preeyzyjn-yeh im.Ger.K.Svierczewskiego, Warszawa. -~-PiJU) 2, Acla Omni -A dielec, c6nst. of polyciyk.- Ba an a S J ta ates was- lobtairred ~as a function or d.c. biasing field for quasiftatic ,b, 'stjites'abDve and below the Curie point. Particularly the effect:of preliminary polarization of Ba titanatm on tftnc~ vatiation behavior of dielce. const. below the Curie pointo-, dependl on direction of applied field, was'observed Sylvia Nowinsk PIq P3~, A. PAjM, Z. "Thermal pseudohysteresia of the dielectric constant of ferroelectric titanates" p. 256 (acJ& physiolorica 1DO10niC J, Vol- 11, No- 3/4, 1951/52, Warszawa) East European Vol. 3, No. 3 4 SO: Mont List of AWM( Accessions/ Library of Congress, March 195Y, Uncl- V4,1 ~Thermal pseudohysteresis of th dielectric can~tant of Qglp'frl S. A. Piekara non J~ ic 6 l '~ 1 10, inir-Irawl 21 IRMEsk Poland). Ada K, t xyj- 4 ;_ const- of BaTiOi and vf 8 BaTjO2, 21.4% SrTiOj disks, fired 2 hrs. at 1300', was measured with 2 kc./scc. and 5 kc./sec. in a field of 20 v./ cm. during consmutive beating cycles of 1-5 brs, duration. The dielec. const. was always higher during cooling than during heating, with a diffprence of up to 107o. This thermal hysteresis was appearing whether or not the cycles enclose the Curie ttmp.*or lie above or below it. TheCurletcmp. for BaTiOs during heating was 127* and during cooling 125* 0 (corresponding values for BaTiOrStTIO, 50* and 64'). Stopling of the cooling process enused a spontaneous dro Of r i t the lelec.const. A previous cooling does not pr(Auce ler- mal hysteresis and shifting of a certain preestablished value, as realized by a cycle for Ba Sr titanate betwcen 45 and 20*. t There exists only a high-temp. memory, no low-temp h H b B S L: . ac s et ert memory. Thermal inaependenco of pci-mittivity of ferrop-lectric hecteror-eneou-, syst~irris. In Enclish. p.83 B',JUi;";!N-, Varsovie 7ol. 4, no. 2, 1956 SO. East E-iro7.~tean Accessions List 11o1. 5, ho. 9 Senitember 1956 f) r\-)'7-,- "Synthesis of ferroelectrics of the BaTJL03 tyPe-" Postepy Fizyki, '.IarSU;4, Vol 5, No IC, 19154, 1). 212 SO: Eastern European Accessi:ins List, Vol 3, !~o 10, Oct 1954, Lib. of Conxgress AUTHOR: Fajak, Z SOURCE: postepy fizvki~ 15, no. ToPIC TAGS, semicondlActor, dielectric, rjagnetic material, quantum electrottiCS sideT-cd te. be of pl-ITWTY i,'2 L ~557L-6~ ACCESSION NR: AP4047631 fizyki FAN (Ph c J-L-c i n-, it ut e , PILN,- f %- Y- wItIh many unTv-er-_Qity deDartments. The cog--rittee -F tkn PAN i- the main cootdinator of irvest ~gat ions t~'. i~i AS9nrT-AT'ION- Zenpol flz-,?ki ciala stalego KcnItetu flzyki PAN (Solid Rtat- PhvSicS NQ REF SOV: 000 rITHER: 00~) Card 2/2 If'A t I M, I W11-11-1 POLAND PAJAK,, Z.; STANKOWSKI, J. PAN Institute of Physics, Dept, of Nonconductors (Instytut Fizyki PAN, Zaklad Dielektrykow), Poznan (for both?) Crakows Zostepy fizykis No 3. May-June 1965* PP 313-324 "Ageing process In ferroelectrie substances." M &W-lf p-i"'Rp 9 az -RI.OIN iMs f r' PAJAK,, Zdxlslaw -- Dielectric investigation of Perovskite type ferroolectrics. Ft. 1. Farroeleatric systems with small teml*ratvre coefficient of permittivity. Pt. 2. 'Aging process in ferroelectrites. Acts, physica Pol 18 no.5: 473-520 159. 1. Polish Academy of Sciences,, Institute of Physics,, Dielectric Woratoryp Poznan. -2 X. ~ 9 ~?') 4~_ 67146 -24 N~7_7__r % AUTHOR: .XAJ p4iJaLigs .1art POL/45-18-5-6/11 TITLE; Dielectric Investigation of Perovskite Type Ferroelectrics'~ Part I: Ferroelectric Systems With Small Temperature Coefficient of Permittivity PERIODICAL: Acts, Physica Polonica, 1959, Vol 18p Nr 5, PP 473-506 (Poland) "K In the introduction the author gives a short survey on facts characterizing ferroelectrics. They can be classified into two groups, the first containing crystals with various so-called hydrogen bonds, the second comprising crystals with oxygen octahedra; a third group seems to be represepted by the recently examined dicalciwn-strontium propip4ate tlli~cf 16), Ferroelectricity results from spontmicous polarization, i.e. from dipole interaction which is due to off-centered protons in the H-bond or to off-centered metal ions in the oxygen ocatahedra, respectively. A satisfactory theory of ferro- electricity does not exist as yet. In his investigations the author used samples of BaTio 3 and BaTiO 3-SrTiO3 solid solutions of different composition as viell as BaTiO 3-11g3no3 Card 1/5 solid solutions. Impurities were detected by applying 67146 Dielectric Investigation of Perovskite Type Porro-- POL7115-16-5-6/11 electrios. Part I: Ferroelectric Systems With Small Temperature Coefficient of Permittivity spectrography. The influence of the sample support on the properties of the samples is considerable. Reaction rate depends on grain size, thus, before sintering, the reagents were milled in order to develop the largest active surface. Low porosity and consequently high degree of homogeneity were 2 attained by applying pressures of up to 3500 kg1cm . Technical difficulties, however, concerning impurities limited the pressure to about 1000 kg/cM 2 in most of the cases. The pressure was exerted by a large oil hydraulic press of up to 100 tons (put at the disposal by Professor W. Kuczyflski, A. Mickiewicz University at Poznafl). The samples were twice milledq pressed and sintered whereby, when passing through the process for the second time they were sifted through a finely ineshed sieve. To obtain the heterogeneous mixtures solid solutions, recrystallized during the second stage of preparation, viere crushed and sifted and afterwards sintered 'under pressure. Card 2/5 Two and in some cases three different solid solutions of the ----- -- vu-u -wnos6 ttro P itY temperature ~, -) it 6 Dielectric Investigation of Perovskite Type Ferro- PI)L/45-18-5-6/11 eloctrics. Part 1:, Ferroelectric Systems aith Small Tori1jerature Qoefficient of Permittivity same grain size were used to prepare a heterogeneous system. The homogeneous systems were prepared in nearly the same way. The samples were pressed mid sintered in the shape of tablets, carefully polished and coated with a silver paste (Chiefly silver oxide thoroughly milled to-ether -?.,ith -Iycerol), thus forming a ferroelectric condenser, For preparation, reagents produced by The British Drtig j I' ~j T t Poole, E~i-land (titanium dioxide) and by The Labo2atory Chemicals Factoryq Gliwice, Poland (the other compounds bein.- barium, strontium and magnesium carbonates and stannic dioxide) wexe used. Radio- gr-aphical analysis (carried out by 1.-,r. J. JarA-.o to whom. the author expresses his gratitude) showed only the desired perovskite structure in the finished reaction products. The capacity of the samples Nvas measured by the resonance method; figure 1 shows the wiring, Dielectric power factor and hysteresis were also measured (Pigs 2, 3). Three methods were used for compensating the temperature coefficient of the sample permittivity, The first consists in connecting in parallel t-ao Card 3/'5 ferroelectric capacitors whose permittivity temperature ~K 6 7 11-Z Dielectric Investigation of Perovskite Type Ferro- POL/45-18-5-6/11 electrics. Part I: Ferroelectric Systems With Small Temperature Coefficient of Permittivity coefficients have opposite sign. The second method suggests to compose a heterogeneous system of two or three simple BaTIO,'~_ _SrT'03 solid solutions. '1%7o oolid solutions with different'-. Curie temperatures but.thd same grain size are chosen and react on the grain surfaces in the process of sintering foriani-'J", M intermediate boundary layer of a-new Curie point, Thus, the result was a material consisting of three or more solid phases and, moreover, a gaseous phase ovring to the porosity, The third method consists in composing -MgSnO solid solutions. This , BeLT'03 3 method presents the best advantages yielding a permittivity temDerature coefficient smaller than 2~10 2 deg-1 and a rather high value of permittivity, The temperature dependence of the temperature coefficient of permittivity near the ferroelectric transition point is discussed, Theye are 28 figures, 2 tables, and 41 references, 9 of Which are Soviet. ASSOCIATION: Polish Academy of-Sciences, Institute of P~jsics, Dielectrin Card-4/5 L ab o r a t o r7,,-P-o _zn a-E - Y' 6,7146 Dielectric Investigation of Perovskite Type Ferro- POL/45-18-5--6/11 electrics. Part I: Ferroelectric Systems 'Uith Small Temperature Coefficient OT Permittivity ~K SUBUITTED: February 16, 1959 Card 5/5 C~9.'12 POO Ho .24 (6~- 67147 AUTHOR. -Pajak Zdzislarr POL/45-18-5-7/11 TITU: I'nvestigation of Perovskite Type Ferroelectrics Part II..- Ageing Process in Ferroelectrics PERIODICAL: Acts, Physica, Polonica, 1959~ Vol 189 1Tr 5, PP 507-520 (Poland) ABSTRACT: The author of this paper found that permittivity and power factor of BaTiO 3-MgSnG 3 solid solutions undergo ageing, too. In order to observe the alterati6ns over a greater temperature range, measurements of permittivity as a function of temperature were carried out for young samples and for samples aged at room temperature (Pig 1). For aged samples, the Curie point is shifted towards higher temperatures. All these effects are not typical properties of the material but depend on the sampie's history, Spontaneous polarization, coercive force and hysteresis losues vaniBh aa a rovult of againg, As L)econdary offecto (theoretically explained by Mason, 1955), the drop or vanishing of spontaneous polarization involves a decreaDe in permittivity, power factor and mechanical coupling factor. The author suggests a domain mechanism of ageing, leading to the Card 1/2 formation of domain-antiferroelectrics, He also investi&ated WAKSI Zdzislaw Study on molecular interactionS by MagDetic nuclear resonance,- Theqr complemes. AcU physice, Pol, 21 no.2:131-244 F 162. P/045/62/021/002/003/007 B102/B101 ATITHOR: Fajjk, Zdzislaw TITLE: Study of molecular interactions by nuclear magnetic resonance. The n complexes PERIODICAL: Acts. Physics, Polonica, v. 21, no. 2, 1962, 131 - 144 TEXT: The nuclear magnetic resonance method was used for determining the hydrogen bond type and the n complexation in aromatic compounds as benzene and naphthalene with different acceptors (halogen derivatives of methane and ethane). Induction technique (6 koe, 25 MC) and a TrUb-Tgubner spectroscope (2.10- 8 resolution) were used. Molecular complexation is due to chemical bond or Van der Waals binding; hydrogen bonds, investigated here, are somewhat between these two types. They are stronger than the latter, but weaker than the former (e.g. 109 kcal/mole for O-H, 6 kcal/mole for O..H in C 2H5OH). The binding parameters depend on the acidity or basicity of the agent. The n-complex bond forms when the molecular n-electrons act as proton acceptors, e.g. between benzene and a cation. Card 1/3 P/'045/62/021/002/003/007 Study of molecular interactions ... B102/B101 The interaction between the acceptor protons and the n-electrons of an -aromatic compound in n-complexes is thus considered as a particular case of hydrogen bond. The effect of a n-donor on different acceptors was studied by proton magnetic resonance. As has been shown already (Pajek, C. R. Paris, 249, 1211, 1959), when chloroforme interacts with benzene, the proton band is shifted toward stronger fields. The same was found to hold for bromoforme and iodoform. The chemical 'shift 6 was measured for various mixtures. Though the n-effect for the acceptorproton causes a positive variation (M(n) >0) of the shift, it is assumed to be a case of complexation. The experimental results Speak in favor of this. The existence of a n-effect was proven for benzene with the homolog series CH2X2 and CH31. A correlation exists between the n-effect and the chemical shift of the acceptor proton. 66(n) decreases with the shift of the acceptor band toward the stronger fields. Also the correlation between acidity and acceptor structure exists. For naohthalene and heterocyclic compounds the existence of n-complexes was proven. In the latter case, the free doublet of the heteroatoms forms an "aromatic sextet" with the four n-electrons of the double bond. Professor R. Freymann and Professor A. Piekara are thanked for help and advice. There are 7 figures, Card 2/3 )111~11AKIX (I M filaw t Physics of solids on the twentieth anniversary of tne Polish Peoples Republic. Postepy fizyki 15 no.4:375-383 164.- 1. Working Collective of Physics of Solids, Polish Academy of Sciences, and Institute of Fhyt3ics, Foliqh Academy of' Sciences, Pqznan. TT NANICKI, Z;PAJAKOVA, R. Biological tests In diagnosis of hemophilia. Prs*gl. log., Krakow no.1:10-11 1952. (CLWL 2W) 1. Of the Second Clinic of Internal Disease* (Head-Prof. Tadenes ~empka.'M. D.) of Krakow Medical AcadoW. /