SCIENTIFIC ABSTRACT PADALKA, P.G. - PADANYI, A.

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CIA-RDP86-00513R001238720010-7
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December 31, 1967
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SCIENTIFIC ABSTRACT
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SIDOROV, N.T9.0 kandidat tekhnicheskikh nauk; TOTSKIT, G.P., inshener; KADU&,jA&% inzhener. Open-hparth pig iron with reduced manganese content. Hatallurg no.12:6-7 D '56, (KLRA 10:1) 1. Ukrainski7 nauchno-iseledovatellskiy institut metallov (for Si- dorov). 2, Tenakiyovskiy metallurgichaskiy zavod (for Totskiy and Padalka). (Tonakiyevo--Blast furnaces) (Cast iron.) AUTHMS Shiclyarevskiy, I.N. and,j~, ~alka, ~111.G.~ TITLE Measurement of the Optical Constants of Copper, Gold and Nickel in the Infrared Region of the Speetrum (Imeraniye opticheskikh poxt6~iiaykh medi, zolots i nikelya v infrakrasnoy oblasti. spektra) PMODI CAL s Optika, i Spektroskopiya, 1959, Vol 6, Nr 1, pp 78-84 (USSR) ABSTRACTs The optical constants of copper, gold and nickel were measured in the region of 1-12 p by moans of the method deraribed by ShIclyarstysidy ot al~~ (Refs 4. 5). Messuremonts were made on a number of pairs of samples and in each cast reproduu1bl* values of the refractive index It and the absorption index were obtained, The results of measurements are given in Tables 13. The seven columns of each table give the wavelength X. the angle of incidence of 'the light 1, the number of reflections m. the phase Shift,&, the azimuth V, the refractive index IL and the absorption index jil. The optical constants were calculated fras the usual formula* (9qs 6 and 6) which give IL and jil in terms of T, V and& Thick layers of copper vere prepared by vacuum deposition on glass plates. Measurements of the optical constants of copper were made within five days. Control measurements carried out on freshlyt Card 1/3 prepared samples yielded the same optical constants as the measurements SOV/51-6-1-13/30 Measurement of the Optical Gonstants of Gopper, Gold and Nickel in the Infrared Region of the Spectrum carried out after five days. The affect of a layer of copper oxide was neglected;'according to Hodgson (Ref 6) such a layer should not affect the optical constants by more than a few per cent. The results obtained for copper are given in Table 1 and the derived optical constants are shown in Fig 1, where the open circles represent the authors' results " the black dote represent those of FOrstorling and Frooderichaz (Ref 7). Layers of gold 1.5-2 ji thick were deposited on glass plates by vacuum deposition. No differences waris found between optical constants derived from measurements made seven days after evaporation and optical constants derived from measurements carried out one month after preparation of the samples. 'rho results are given in Table 2 and the derived optical constants are shomn in Fig 2. Again open circles denote the present authors, results and the black dots those of F'O'raterling and Froaderichsz (Roi 7). Thin layers of nickel were deposited by vacuum deposition on glass plates. The results obts,"ed are given in Table 3 and the derived optical constAnts-in Fig 3t i0hers open circles denote the present authors' values,and triangles show the optical constants obtained by Ingersoll (Ref 8) at 2~p. Card 2/3 SOV/51 -6-1 Measurement of the Optical Ccnrtants cf Copper, Gold anj Nickel In the Infrared Region of the S pe.-~trxu Using the classical Drude thecry of free electrons in metals the authors calcalated densities of free electr!=, relaxation times and d.i. condoztlvitiql~ :)f' ccrpor.. ".1d, ni~~16-.el and silver. *111ey are given in Tablo ti tx-4.0ther with raZults taken from Hodgson1s and Beattia and Conn's -work (Ref-9 6, 10). Frciu the I-mown values of 11 ani -g.1 it is possible to calculate the value of the absorption coeffiniont A given ~.-y R whero R is the roflo(,tion cooffteitat oC ilia motal. Dependence of the abiorptlon ctooffiniont A on vevelength is given for copper, silver, go.Ld ard air.-Lel In F:io, 7. The ordinato axis I applies to copper, gold ani silv6r and tho ax"s I-r applias tv nickol. Acimowlodgments aro made to Professor K.D. 3intllnikov for his advizo. There are 7 figures, 4 tablaa and 12 referen-les, 5 of whieh are Soviet, 3 English 2 German I Dutch and 1 tram lation. SUBHITTSD-. 11ar,.-h 2-i, 111,~ Card 3/z; SOV/51-4-6-1,3/21 AUTBORS: SWyarevsiciy, 1.'N,, Staranov, N.G. and Padalka, V.G- _ T.T,.nl Measurement of Optical Constants of Silver in the Infrared Spectral Region klzmeraniye optichesIdAh postoyannykh serebra v Infrakrasnoy oblasti spektra) FMODIUL: Optika I Spektrookopiya, 1958, Vol IV, Nr 6, pp 792-795 kUSSR) ABSTRACT: Optical constants of metals are of great interest in the electron theory of metals if they are measured in the frequency region which satisfies the inequality given by Eq. I on p. 792s V02 4U402 o" where V. is the frequency of electron collisions with the crystal lattice and 4 is the freqaency corresponding to the upper limit of the internal photoeffect. This frequency region lies usually in the infrared part of the spectrum. The present paper reports measurements of optical constants of silver in the 1-12 ts. region using the methods described earlier kRefs 1, 2). In the first of these methods (Ref 1) the phase difference A = d, - Cr. between the p- and a- components is made equal to -1800 by mulplasreflection of light by two identical samples. The apparatus used is shown in Fig 1. Here S is the exit card 1/4 alit of a monochromator =-2; Z1, Z2" Z. and Z4 are aluminized Measurement of Optical Constants of Silver in the Infrared Spectral Region mirrors; P and A are a polarizer and an analyser, respectively, made of piles of six selenium plates which are placed at an angle of the order of 700 to the light-beam; M, and 1[Z are the samples of the studied metal; B is a receiver. A parallel beam of monochromatic light passes through a polarizer, which is positioned at an angle of 4:50 to the plans of incidence. and falls at an angle f on to samples M, and M?. The angle of incidence is chosen to make mA = -1800, vhere m is the number of reflections from metal samples. Under these conditions the light reflected from metal samples may be extinguished by the analyser, Position of the analyser gives the value y' , which is related to the azimuth of restored polarizatioa V by the relationship tan V = - Knowing the angle of Incidence 4P, the phase difference & and the azimuth If the optical constantn can be easily calculated. The second method of "rotating analyser" (Ref 2) is tased on a conversloa of eXptically polarized into circularly polarized light. The apparatus is the same as in Fig 1. By a suitable choice of the angle of incidenr~e for a given -wavelength, the condition mh = -900 is satisfied and the amplitudes of the p- and a-eomponents are made equal by a suitable Card 2/4 rotation of the polarizer. Then the light reflected frcm metal surfacea SOV/51-4;-6-1-3/24: Measurement of Optical Constants of Silver in taie Infrared Spectral Region is circularly polarized. The modulated component which has passed through the rotating Analyser disappears and the recording instrument shows only a constant signal. The azimuth of the restored polaritation is obtained as in the first method, 1xxt y now represents the angle between the chief direction of the polariser and the plane of incidence of light. From measured values of r#, a and Y the optical constants p (refractive index) and J&)[ (absorption coefficient) are obtained. The optical constants of silver layera produced by evaporation in vacaum vere measured by both these methods . The rosults are shown in the table on p. 795 whose columns give respectively the wavelength (in Ja), the angles of incidence (#, the number of reflection m, the phase differences -h, the azimuth V, the refractive indices ~L and the absorption coefficients j&)L- Fig 2 compares the values of the refractive index and the absorption coefficient (carves 1 and 2 respectively) obtained by the present authors (shown by open circles) with those of Forsterling and Freaderickgz kRef 7, shown by black dots) and those of Motulevich and Shubin (Ref 6 shown by half-black dots). All these values are shown an a function of vavelength and they agree Card -3/4 -well-with each other, except for values of the refractive index in SOV/51-4-6-13/24 measurement of Optical Constants of Silver in the Infrared Spectral Region the 3.5-6 ~L region reported in Rof 6. in the spectral region where the inequality given by Eq. 1 on p. 792 is satisfied the conduction electron donsityR is independent of the wavelength If 3 ia '02 - .,,2 f(,~,2) which should be a constant It follows that Lykj r, straight line. Such a straight line is shown in Fig 3. In the region 5-12 Ik the slope of this line given the conduction electron d&tsity as 7.4 x 1022CM-3. The experimental points in Fig 3 in the region 1-6 p also lie on a straight line whose slope gives the conduction electron density as 5.2 x 102'2cm-5, which is the same as the nvmbez~ of atoms of silver in 1 cm3- 'rho authors thanic K.D. Sinellnikov fv~-, his interest and advice. There are 5 figures, 1 table and 8 referen:*i, 4 of which are Soviet, 2 English, 1 German and 1 American. ASSOCIATION: Kharlkovskiy gosudaretvennyy universitat im. A.m. Gorlkogo (Kh&Nov State'University imeni A.M. Gor'kiy) SUBUITTED.- November 15, 1957 Card 4/4 24(4), 24(3) S(PI/51-6-6-9/34 1UTHORS Shklyarevskiy, 1.11. and Padalka, V.G. TITLE The Anomalous Skin-Effect and the Optical Constants of Copper, Silver, Gold and Nickel in the Infrared Region (Anomallnyy skin-affekt i opticheskiye postoyannyye medi, serebra, zolota I nikelya v infrakrasnoy oblasti SDektra) PERIODICIU- Optika I sveLctroskopiya, 1959, Val 6, Nr 6, pp 778-770 tUSSR) ABSTRACT: Recently the authors measured the optical constants of copper, silver, gold and nickel at infrared wavelengths and interpreted their results in toms of the clasGical froo-olectron theory of Drude kRefs 1, 2). From these optical constants the authors had deduced, Inter alia, the d.c. else-crical conductivities of these metals. These conductivities -were found to be considerably smaller than the values obtained directly on massive samplas . The reason for this discrepancy lies in the use of dispersion formulae of Drude which are valid only for the normal akin-effect, when the inequality f