SCIENTIFIC ABSTRACT OSIPOV, N.V. - OSIPOV, O.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001238410006-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

OSIPOV. N.V.
9poDtaneous pneumothorax of non-tuberculous origin. Probl.tub. 37
no.6:101-103 '59. (MIRA 13:2
(PNRJMDTHORLX ease reports)

D01,11FDANOV, 1.'nrk F'rivIovich; OSITOV, F.V., otv. ro-d.; VFXCi~FIMIK, L.I.,
, o--1 . 1 :11.111 'Il( I U , A A . 1 .1. lit, . t .-.I .
I I . I I - It 1, 1 1 ~ I . I I .
i I I . I

OSIPOV,__ILS,.4___at,arrhiy inzh.; VARNAKOVA, Ye.D., kand. fil. nrukp red.,
Btarshiy nauclm~-y sotr.; Sh'ADRItA, I.I.S., red.;
V.V., tekhn. red.
(Training of workers specializing in novirg in necondr.,rv
schoolsjOpyt podgotovki rabotnik-ov shveirWkh spotsiallnostei
v srednei shkole. Pod red. E.D.Varnakovoi. !.o_,Icva, 1,-d-vo
Akad. pedagog. nauk RSFSR, 1962. 93 p. (AURA 15:~))
1. Akaderlya pedagogicheakikh nauk IISMI, Poocow. Institut
proizvodstvennogo obucheniya. 2. Inntitut proizvodrtvonnogo
obucheniyn Akaderii pedagogichoskikh muk '-ISM(for Ossipov,
Varnakova).
(Sowing-Study and tenching)

OSIPOV. N.V. (Vlndivostok)
Trentment of Ppontpncous pneumothorFLx [with summnr7 In irencb].
Probl.tub. 36 no.?:IC5 '59 (MIRA 1::~)
(PNPJYDTTiORAX)

The 0) 111, A 'cal mahlrb of an oystam lormwo by
dk,Pb-YU-t- Wo pbosyl and avyl bbWolmat"
U-A~Iihir,~sj N. A. Twilmov (kmlov~m.-Dm %)&t,
""IV "a Chr. V % v N 10, No 141, 027N $1
P6. 4 4 44'I'lly I ,

1. 0~;IPOVI ili.v.
2. IIISSR ("YO
I.. Vermouth
7. Soviet vermoi;th -,)rodu,-*Iion. 71n. '-SSR 1~ no.1q, 1952.
9. Monthly List of Russian Accessions, Library of Congress, January -1953. Unclassified.

1 . 1"lly(RO"', V.S.;
2. USSP (~f~O)
4. Wine and Wine I-'-qking
7. 4ine Indust.ry ne ds in!ztru,7ti-rr~ ~n~ ir ~h-ricril m-~
c(-)ntrcl . - in. SSS!~ I ' nr .' ,
9. !!q ilt h List of Russian Accessions, I 'Ibrnry of Con(ireqq. .1 ~ r1 , n 7-; 19~il. [Tnrlnczt;lflr-(I.
___ _ ---l- -

1. 0")Ill(,V. N. V.
2. USSR (600)
4. Reductiono Chemiral
7. Chnmctnristics of the oxlciii'lnn-rmd~wlion proce-f~n in winp. Vin. 1,1 n,,. il-1, 1~1?.
) . Montnly LIct of RusniFmAccef;nionp.., Lil,rary of LeLymo 11),j.

03 L-()V. !4'. V.
Wine rrnd Wine 1.4king
i ork-l-r - * w 1 1 :w L o , t , ,- , , 1, , -I ~:. I .I.. " . 7 1 . SlIll " ~ . '.*,) ., ,
9. Monthl List of Russian Accessions, Library of Congress, June Uncl.
~j

1. 031POV, 11. V.
2. U33R (600)
4. Wine and 'dinp :'akin- - Ifungary
7. Wine makini, in Ihingary. Vin. S3--:R l'i, Nc. 4, 19".
9. Monthly List of Russian Accessions. Library of Congress, A:) r LI 1953. Unclassified.

_;~A 06~~
0~~ i i 'ov, :'. V. (; 'o I ~ ~ I- ~1 ". .,'I I-- 1, t ill,'. lij of ~~m ~! !' I o . .I I i I " , : .~ 1, ';'j': * , ,
Of 607-A-SV7VOt ('o!Ait ionn of' til- P'1!1A1'z1 r1_111-r'*i -. "
Mos, 19(.0 ( Mi r i o f 1: i ,: - r - ; i, ~ o,! o' (-) - & ~ r,, o ~ , ~ cl i I J ;~o_' 6,lvlc i t I C) .1 -.!.~o s
Tee raLo I o_ A c- I hu; I ol' i-'oo%l I,, ~ i. ' r.', ). ( r, L, I-I. I., )
-;, I ~' -

viwmpm, P.n. (vvvvivo,,nv): nnimv, ij.TF,.
I . ..., .. 61 4 " 4 % 4 . I ~ ~ . ., . 6 . . . %, t 1, - - ~ - ~
w I &A 4 . i4 . i i 144 . - i ~. 4 1 w & ~4 t ~ . 4 4, . .. . k 4 0 -... . , .14 t4,4
itn ti, ra i r or ins . I a v. vy" . %lollob. Nov . i ttv . bokti. z flu . I $
111-124 159. (MIRA 12:3)
(Rot*rs)

Author OSIVDVp 0.
T An Intereat1mg profeBsion
Periodical s ftdlo,3, 7, PArs 1954
Abstract About a distimgulsbed radio-technician, lKysto.11a Mikhl-'avna
Kukonkova, wbo chose the translatlon and mdulation of radio
programs for her vork md consider6d It a vory Intorenting
Su'bjnltted I .......

ji

.1. . I . .1
0, 0 a, . i, I I . . I :
--- a t m . . . . I I
II I .I
I : . , , I
I- . -..
') , ,. . .. I -

7, C.
In c ir

t r
fand toW surface energy of rational binary
Chemical Abst. -iiind 13, 4%. Ttillone LRQUaIL-
21, SW-904(10.51)
Vol. 48 No. 4 Frill. translation): Zhur. ObAchtl Kkim. 21, 817 13
Feb. 25, 1954 1951); cf. C.A. 44. 1787f.-Surface-tension (e) valuci at 2
fur several cornfins. in each of 4 binarv
General and Physical Ctmiust ry system$:' 1. allyl mustaM oil-tthylaniline; 11, phenyl must-
.rd oil-iliethylamine; III, allyl mustard oil-m-toluilline,
and IV. phenyl mustard oil-aniline. In system I the earn-
rniurnts react to form allylethylphenylthiourea (V). Fach
30 herin consists of 2 branches intersecting in a rnax at 50
ciole_7p, corresponding to the cornpri. of V. The data indl-
cate V Is undissoed. in the liquid phase. Deviations of the
I%otheftn* from linearity increase with temp. The shape of
'he i~. hermn show reaction of V with the oil. but not with
'he a=le The relative temp codY., I - (I /vj)fvj - ej)/
U. - 0 pa,-%e3 through a tnin . at 50 mole %. Total surface
energies calcd from the Gibbs-lielmholtz equation are infle-
pendent of terup and exhibit a max at FYO mole %. The
other Aysterns are qualitatively similar in physicochrui prop-
'irta', The large deviations from additiva, (507, at 300'.
d 63% at 40' at the max.) of the isotherms of 11 indicate
:
n%vxn. of the dirthylphenylthiourea which is lonned
Bernard M. Zeflert

USSRI,Chemistry - Titanium Organic Jul 52
Compoundz
CN
"The Study of the Reactlcn of Ti- 1:4
tanium Tetrt_cn1orid_- With Isoa=yl Acetate," 0. A. -0
Osipov, V. Suchkov, Rostov-on-Don State U
"Zhux Obahch Khim" Vol 22, No '7, pp L132-:136
A study vas rnde oll tbc vioco3ltyp dennld~v, uiet
elec cond of the system titanium tetrach.~,oride-
isoaxW1 -acetate, at tempo of 6(fi- and 70~:-. A co=,-v--
was formejd in the system with the co=,pn, _iCI4 -
C113C00C5Hl. which vas almost "-dissocd f.= I~he liq-_dd
229--34
phase. The relative 1-jeat C01-1ffr- of the --iscosi-~-,
and elec cond was computed.
22 grr4

0�11-0V. 0. A, and KRAVTSOV, YE.
Physico-Chemical Study of the Interaction of Titanium Chloride and Ethyl Formte,
Page 216, Sbornik statey po, obahchey khimil (Collection of Fapers cn General
Chexistry), Vol I, Moscow-Leningrad, 1953, pages 762-766
Rostov on Don State U

SOV/ 137-57-11-22288
Translation from Referativnyy zhurnal, Metallurgiya, 1957, Nr 1 1, p 232 (USSR)
AUTHORS ~uv, O.A., Feudos'yvv, N.N.
TITLE Determining the Latent Heat of Deformation of Copper Relative
to Degree of Deformation (Opredeleniye skrytoy teploty de-
formatsii medi v zavisimosti ot stepeni deformatsil)
PERIODICAL, Uch. zap. (Rost. n / D un - t), Vol 20, T r. khirn~f ak., N r 6,
1954, pp 79-BZ
ABSTRACT Bibliographic entry
Card 1/1

anu %f
'IV _... "
- C;;Z'7 . wnK tiijt-
Gc*..y i.,3 W.114.
1~4, -am CA 4s su)L3, H. L. 11,I..

O-S
USSR/Chemistry - Ana),y3is
Pub.* 151 - 9/36
Authors 3 Lysenko, Yu. A., and Osipov, 0. A.
----------
Title 3 Pbysico-chemical investigation of the reaction between titanium tetrachloride
and etbyl acetate
PariedIC&I 3 Zhur. ob. khim. 24/1, 53-55, Jan 1954
Tiie viseosity, density and electrical conductivity of a TiC1 - COt system
wers'measured at 97 and 1020 temperatures. The viscosity, d~nsiV a elec-
trical conductivity isotherms of t)v binary system, are shown in graphs. The
composition of Vie wlecular -compound p formed by this bi=7 systemp is de-
scribed. Numerous exper33wntal data show that the density of the Investigat-
ed system is not of such importance as viscosity which makes it possible to
establish the existing chemism between the components and to determine the
composition of the obtained compound. Four USSR references (1940-1953).
Graphs*
Institution : The V. M. Molotov State University, Rostovpon
Submitted t June 21,, 1953

Osj-poy.-GA-
Mwchwdstry
Out 3/1 3 P&- 151 - 10/42
Autbm I Foodonyev, N. N.;vggj=L 0. A.; and Morozova, G. K.
MIS 3 Heat of blending dioxane with water
3 Zhur, ob. khim. 24/9,, 1540-1542., Sep 1954
Abstract I The surface tension,, densityp vapor pressure, index of refrastion and
solidification point of the dioxam-water system were investigated.
The heats of blending dioxane with water were measured in a ealorimeter
with isothermal shell. The isothermal curve, representing the blending
heats for the dioxane-water system., was found to have, positive as well.
ative sections which Is explained by the formation of a molecular
as neg
bydrate type compound between the water and the dioxans and decomposi-
tion of the water. Four references.- 2-USSR; l-USk and 1-German (1907-
1949). Table; graph.
Institution, t State University,, flostov/Don
Submitted : May 17,. 1954

Card 1/1
.:Aithors I Lyasnko, Yu. A., 091pov, 0. A., and Foodosylevp N. No
Title I Blending Temperatures for Systems Formed by a Titanium Tetrachloride
with Ethylacetats and n-Butylacetate.
~rivdical I Zhur. Fis. Xhim. Vol. 28, Ed. 4, 7OD-702, Apr 1954
Abstract Formulas and calculation of the blending temperatures for TICI -
CH,;00002H5 aril TiCl - CH CODC ~Hq systems. According to the a&hor
of this articla the4heat iffect in the TIC14 - CH
%OD*5 system 'a
'i CH ODC system 8.93 kcal/
signif cantly higher than in the SnCl4 C
mole as compared to 5.67 kcal/mole). Six r2ferences; graphs.
Institution Rostov State University.
Submitted June 26, 1953

AJI~l
rA IA"r a LficnlA systems. surtalce
MitiAcadat jmd the voltuns propertw C4 maluum Of
bin" systoral. B. jg,_T4--11'tmum J-J QLA_-_NPQ_�
--,% ~Tlwofnv gnlV . Qv~ AAj4Oj Oarr'~ ~.
W); Cf. L;.A .45. Of She 2
vamNn-nts of a bmiLry %ymcm may, In W swfscv Is)-cr,
In * thus, the Wy. ix the Sur-'
be 'difycitut ham Ow . balk,
I.Av 1-yer way Ix )Dr*wjArtt muo &I temp. T 41 whO tbo
*Nl)ty in bulk Is unlimitrd; 2wmt, de-inhing In a tw-
abd
t
'~nwrwy to Starol4mts,
fAte hymnayworat any temp. L
a al. (C-4. 47, 9M), surfstv dt-v~kxh.% wvd imirt havv any
ciltri on 3he Vol. Prop" 10
wrax. .11. P-Sbt=- (all- Aultim)
sit Sh ~111 4
w V The surfam tonsia" Op cd OJNK *Dd I
domaws nmd)t bpeAft w)ws 7 lists, titIll a al
'Ph is
011 In O~N -.09 indrj*3hkm W T I bet7men
WaudW).
thew wi:ns, Tbt Itinp. cmfi. of tht dkitt. toam. a cA
I-OWPh maWs., ivai dttfl. between 10* W 40'; It above
no anonWy. AUo tbt wAalims with 7
of , au4 d.
PhNfircnlohc~c mixts, and d a. of a mkitykyw.
Ntrom whi. vvrrt zxr=3j. AU0 h C40,4
(us
17, 31AIPmxztze~ U=slat;00). Mttnss~

I't ltbas4lllra) study (d ohs rtartion of t1lonlurn to IT..
___
xvVf1Off all,
eitters of su",)batlle ad&. V.
YO S VS 11 u um ittlAthitilide with prApyl igtlatr itild blityl awsle-V
.
r
I l
j~. Alnivy
-V, Vil'A "
TIP
1.5
Viwr
bjuhr him
J1D-;Z(3bS5j; R.
"

.
.
.
) -nic triwi. htst of mixijijr It 10 inl to dt-
j,)4
~
relov AT prulttrly ~JwmrAar rrf)j'011)0j1) Oil 7101 -Ind
- -1 ccli-f -1
NMI A fMJ) -Mun wn t 1) 1 A c,
Th* p ty-Corlipm cutvet kft Olown lor d"
h
Mid. the systeina of TiCli with PrOAt ft;ld wit
Alta
the fameir at 70' liud NJ% 1114! Uttff At 70' An' W
O
'
1
i"
Ity and
v
. The niaotima Fhown by tho curvtj 0
go
-
r
v
3how that
nd
d the
e
s of
l
h
t
d
l
.
i:
<
o
s
A
an
ope t
o
i
vur
i
igo
Ji-bile mn:10. Jorntatirin takn platv Mill rVilmaky pro.
~kxtlonx nt tho c9mikinva.1a lit Will owe, In ofida.,
TiCl, 2ROM pro jilmi fritioM flut Am
-

l
lc
R I
T
.1 v., it's tif
A trim".
it",
T
t
e5
t to Ittoy dlxw-x4, sit 60 Aton in Ots.
R 11)11 alit.lat
Chiris, fu~i.S.T) 2S,.1.13-7,(!11,MX I

uw""uon).--see C-4.49,~Il
oil

OSIFOV, O.A.; PANINA. V..A.; U2)UXIT, L.E.
Dielectric constitrt of )iziary liq,iid aystems containing asnorlIcilf..,.,
comonents. Zhur.ob.khim. 25 no.4:062-666 Ap "5. (?.ILRA ~i: -, )
1. Roatovskiy-na-.)onu Go9iidarstvennyy -iniveroltet.
(Systoms (G~iemlstry)--Hlectric properties)

':)t
t
USSR/Physical Chenistry - Thernolynamics. Thornschemistry, B-8
EquiliLrium. MysicochmIcal Aiialysis. Ftwo TransItioi,G
Abs Jour i Irieferat 7hur - Khiidya.. No 2, 19572 3757
Author : Osipov -0 A , Seric-mov A.D.
TItlo : ;;i~ccular-~Weipht of Sumu Complex Compouirls of Titai-.1111;
TetrachloriAo.
Orig Pub : Zh. obshchey khirdi, 1956, 25, No 11, 2059-2c62
Abstract : Conpositioii-properties dIngraLm plottel on the tanin of'
results of determiiiatioii uf viscosity, conductarce, Iu-
sibility uni deiisity of the system TiCl4-C3 H7COXJ'I~(I)'
TiCI 4-C3it 00C5111, (11) iiid TIC14-CN2MCOCIC2115
iii,licate the formatiaii of theri.nlly stable compowids of
the 1:1 type (RZhMin, 101~, 11279). Cryosccpic determi-
iiatims of the MlecW.ur waiF;a,, of the complux,!s ware
carried out iii beiizene vith equirwlecular -proportioix of
Card 1/3 - 105 -

zd Akk~-IVWT- A oj'.~-)v. J.
J z
-77
-7

spilla* w.) th -=I 0 1 If, dd
1"Y' bud f I

au
peraltability o! ULN h-qu uo-
IiLt and CJI&NP. sysicim were inveitipted iii a
r

And CA. 48, 133911)1 C(ijupjrjean %vith tile
rAylki, tc~-ulls IndicAtet an abautin4 I utht. (it chum. intrr-
utiim betwecit the components, comIxined with tile thmnal
brculalown of ja--ioM, mnlq~ durieg mixing. It 1% it"iturd
tile 2 syslvul-4by way Of 1141mILA11-'r-,
mern the Nift EroUll pUd tile: N Of the hV1vfGcVd1C
auiinrs. Tfiv b.ps. af Ott 2 sy5trin.4 nt :trm. Incrsurc 'Arcre
dctd. Tba IV.-Imrs 1huty that coullml., Phrvaj in Ific-
trin are slovily thermilly dlssucd; in tile rywerr. mu atr(YUM
t,=p.. und are compIttely decumsmi. m the b.ps., and lhc
b.p. curves are charactuistic Only fur tl,e tj
mmal (ft""Pti.
of the-cmirAtz moli. into their compinvots dtisitw 111cir
m-ptual suln, sternbutg

2

C:S Pn 1("~,

1~- Intmelation Among surface t"ozi,_bIndIu1_Mr6-1
and Ionic rad;i. Q. A. 0,4p,)v (Statt Univ.. Rmtvr-on-
-
-
AT3T-
V
N
= S
102
317j
D
d
R
2(JpN3)
-
g
.
.
.
O
O
&
j
,
y
Ftq the rutlta otalk.,411 h3)id". anl
Oib zroap of the pidkxUr *y_~iem, Obert 13 A hnew itlj11o)1.i
-4 amou
of wdinary
the swlarr imskin amd The tn"y
l
'
binding B. the rarity of 2bt cry3tal lattk* V, axd the honk.
or "ralrut, ekment mdg r. At temps. rrv the alsth.
w factors Are newly idmtirAl lot the liqukl and the i
pew I thez
Crpt., 312tft (YS- L FrMW, KiXImiAtykayo ezwya

Y~SOItbSO. (Rt 110V); NaF-XV-RbF-CsF
On'); NxNOXNORbNO~-.;
C3NOI (5W'); Nal-KI-Rbl-Cs! (MO')- N&CEN&Dr-'
'
,
l
CI
bC
R
A
l-
-KDt-Xl
Br-
RbF-R
Na
b
l;
; K

bowrizr, we valid also for the striti "I~X (X - F, C1, Dr.
1) lat 20'); CHIC.1fix (X - C), Dr. 1) OW); CaUx (at!
20 ); CJIYX (al 2D'). Ile laws discussed are analogous to,,.
the lyDtznpk, suits AN&* > X * > Rb " > Cs+ > fm the salt-.
invent tffects of thm )Guy in a ,wlns.; the CWTO in
0
aerks fDr the anlow)s 33%- > > Cl_ > Br~l >
>
1%

itudies ol.thr-nmaiall fit fit"11
tllm,~r;Tfc With of ;07)
('6tor fill 77 tu
or Ut ",pvemv. wx*t fit m, tawchJuride est(--.n- a luonobaslc
av,l~ Vu A. I IV
-. "ll,
-KW,m M' ITI
forml,
twj; icl L)N
~Avv, [Aw t 0-h 14, 1
a nTiv. iii Iliv lik'i~-z,ilr m.p. iit%v~ Dt cach
111A. *; I 1c1, Tho i nq dl%~
-"I~d fl~mr 4;;ij;~i-.-;M`, VUjr~:- -'rii- Ai~
'1,;i'A-). Ti C 1
IiAl 0 e -I PJ ~,7,
710t.PrOl, 78,0' TiC1, it )A r
Tic,4.11-cldf,(:0013u 721.0-, TiM.CIC11,C0001,
ty
Ti,,:1..Ftc(xMt 1110.:21" Ticl..PICOOLt Itk3.0',
C- IL 11 14XLU

;4

waaddvalent ti and
Mat
__
_
T

N_
T9
k
x
19 Or .4 104di--7 ra the
l
'
of
,
1295
g
-: T! 14. VHTf
,1
npds. wem dtlt
d
C1111
TiClg-C#lijCOOC4He (4.4W, TlC1,-C,1lCOO-
CoHn (4-37D.), Sn"-2CsHyC('OCt1h .52D.), SnCl,-2Cr
HICOOC4111 (8,44D.), and SnCOCIRICOOC&III) (OMD
)
-The high dipole moment shows that complex formation 2
"
tUmseltowitli esters Increases ibe;wlarily. Acomparlson
of p ]or *
dlfftren"( * ester Wow and for the wroplex shows thAt their
(or both 1:1 and 1, 2 ratios) mnains almost const.
and that t he chaln len;1h has little effect. For the M com-
*
plext-, the differ"ce u 2.5-2.61).
and fiv So 4D. It is
concluded, on tht basis of the narx-mr6nent of the dijxile
moment$. that tht cmnplrxej 44 SnCls with :1 ester MOS.
have a c6 strurture.

USSR/ Physical Chemistry nerraodynanies. Thernocherdstry. B-8
Equilibrium. Fhysicochemical Analysia. Phase Transitions.
Abe Jour Referat Zhur - Khiriiya, No 3, 1957, 7192
Author Osipov' 0*A' and Shelomov, I.K.
Title DMectri; Constant and Average ripoic Moment cf Binary
Liquid Systems
Orig Pub Zh. fit. kbimii, 1956, Vol 30, No 3, W-615 (English
summary)
Abstract The dialectric constants of the following binary systems
have been investigated over a wide range of concentra-
tions: quinamine-uninine, pyridine-unitaine, acetic acid-
dioxane, anirAine-diethyl ether, chloroform-diethyl ether,
animine-dioxana, o-to'uidine-dioxane. An attempt is made
to formulate a theoretical basic for the impirical for-
mula of Ya.K. Syrk;.n (Doizi. Ail SSSR, 1942, Vol 35, 45)
and the possibility of its application to binary liquid
systems in which chemical reaction occure between the
Card 1/2 - 1-15 -

4 DIArt 7
.............. ----- -
=AL th Oxgue, I cc. ca
2%.,far ZzCh are; O.W47011 2 W 10420-0.
2 1.0400; O.OMWIt. 2N9 I bik, 6 0001f
28, 1.6~77; 0.0015421,2.2S1, Lai; Fau
2
At, 2.2-39. 1-03631 0.001709, 2.232 10341, 00014IMi'
*
~_J? 10353, 0 DOMM, 2 224 It FAI -
*
0 0~100 2.230i
'
'
' *

0.&~AH, 2.21B.
347 io;
1.0344;
1.0
ZrBr. F.OD274.
;
2.290. 1.0434 -, 0.00YTOM, 2.275, LOM 0 00183 U 2.WOJ~
The dtfarrmitional 1xiliduti(M molsir "0
at Bfinite dila. (in cc.), juid dipe4e moimnt (D, am,
for ZrC14, 44-33, -75, 6,94; TiC4 40,90, 291, 3.48, a
ZrDrA, 62-al, W 4.69. The indiettiou from then dat
tba the halides forui compl"e2 vwfth the sal"at was ccon ,
firmed by the vynth-As o! *he followitit new compO.~

103*; TiCl.
-2CHA, yellow. cryst., ru. 182% and ZrBr4-1-
CiM101, Irk. 190*. Ilse stability of these t" ef , 11"
~;
h
1l
b
f
l
h
&
e
formed
a
i
y tetra
ts
rota t
t element& of Gr
v 11
P
crutses with fucrease lit the covalent nullu of the ceotrC
Atixu. 15 r0trences. A. P.XMIIAQ~~

tro a, s,i ca, ~,cmistry - Mo~ecu-ie, Chv-,z,-,cal Bond. 13-4
Abs Jour Referat Zhur - Khimiya, No 1, 058, 164
Author O.A. Osipov, G.S. Samofal,-va, Ye.I. Glushko.
Inst
Title D-IPOLe Moments of C,,mj)1cx Compounds of T~~n TuLrachiorlde
with Some OrL;anic Acids.
Orig Pub Zh. obshch. khLmti, 195'1', 2'(, No 6, 1428-1433-
Abstract The dipole moments and/" (in D) in benzene of the moiecu-
lar compounds of SnC14-2CH3COOH - 6.38; SnCl4.2CH2C'Coo"
- 3.44; SnC'4.2CCl 3COOH - 2.09; CsnC14-2CH 3 COOI~'-CH3 COOH
- 7.23; CSnC14'2CH.2ClCOO~7.CH2ClCOOH - 3.67; SnC1),.3CCi3-
COOH - 1.89; SnCij,-2C 6H5COOH - 5.73 and 5nClOC05coo~7
.C6H5COOH - 6.16 were mea!,ured. It was assumed that
Card 1/2

AUTHORS: On ipov , 0 e ~e I and ~ le tc- ri i K pf Uji
T
ITL-: Dipole -oments -,f ttie (-~mpl(,x --,rrp--urAn )I -irc,)i- i r it,
Lsturs 2f "'Ionobdric cids ill (Dipil.-~yp
ny'RI. 5oyedineniy t,t~traknlorida t-qjrkDniya F,
osnovnykh kislut !.11).
Zt,-lrnal )bsI,.cIiey ~I.Amll, L?'-:7, ,'7, *r 11,
,diSTr.jiZT: T!,e interaction of" the t,-~ract,lr)r~ 1,-- 1' I-in
ri,3u-g ~)rL;anic cD-,,,-)ou-As .i*-z-,'t-n -Ir-A -)YyLr':~ tr~ the
forriation nf complex M-11~~I~ 11t:9 wit ." I itt, --,c~, a
hi(;h polarity ol the cc)mf,lt;x
alone :)e explainud t y J~Lr!7 Itj IDf)-j-' r~, A, "s I.e
occ urre-ice ?f a s trrr.,~4 --ir i j A 'r-b j, r -L T., is
Paper the a it~,,,)rs jete.-
udnat:.,Dn -) f d ipn r.4. x Drium
cttLorid~p ~tt.yi, wid i,-; )prnpyl~for wati,-, ~-S - t , ,I ty I-
anJ !.,-- nz y I-ac- t - v.* i L t.r t t.j L i i r is
Shawn *,hat mp Dund
esters -,f aci is lu, t.:.(: f
,ard 1/2 of Ii-, I were

D I po le -I o r: i e r. f- ~,j c ft t, e x r
i r i (is
C;ort,)ound L-9ters n1' I ~r,
t"'k, alf 1, 1 L
~1~van lr(A : I?, Cl.
110 iF,I,i,lt
( :L,) I J,u 1 1"- w. t: C ~Mplt--X,
whereas U~t2 !r(7rk--Ls(, it. ~,t- ~~artial -f t.ht au i-t es i 1, ie 7,1.arp=
ly reducer, t . i r~ -r th ir, f 1~ th ~A t t,t:l :i i I -i t~y , "! , (: lex
-)f the tYi)C -rl~l[, ii i7 t-t.u i~iti-n ut it- 'ilvrit jri
r 7
.he quantity
C, 1: It-i t"'w~ is
s tri. c r t, .
Thert, ~u,t: 1, "T'.1 I I I
:. C- % el-., " r
N Lm~ Lihrary ~ f r,,r
Complex compound~,-Dipolv :aomonLr, 2. ZlrcDnium ole
moments 3. Organic cornpounds-Dipole moments
Card

------- - ---- -- --
OSIPOV, O.A. SHRIA)MOV, I.K. (Rost ov-na-Donu)
The relntion between the diDO1~ moment and surfPce tension
[with summary In English). Zhur.fiz.~him.ll no.9:1756-1761
AP Is?. (MIRA 10:12)
(Dipole momente) (Surfnce tension)

OSTPOV, O.A.-. LYSENKO. Tu.A.
Electrolysis of tatravslent titanium compounds of various
monoprotic acid meters. Zhur. neorg. khim. 3 no.7:1605-1607
ii 858. (MIRA 11:9)
(Raters) (Platinum oreanic compounds) (Electrolysis)

AUTHORS: Lyeenko, Yu. A., Osipov, 0. A. SOV/79-28-7-2/64
TITLE: The Investigation of the Conversion of Titanium Chloride With
the Eeters of Monobasic Acids (Iseledovanlye vzaimodeystviya
chetyrekhkhloristogo titan& so slozhnymi efirami odnoosnovnykh
kielot) XII. On the Decomposition of TiCl 4* E Compounds(xii- 0
raslozhenti soyedinenly TiCl 4' E)
PERIODICAL: Zhurnal obehohey khimii, 1958, Vol. 28, Nr 7,
Pp. 1724 - 1727 (USSR)
ABSTRACT: Earlier (Refs 1-6) the author found t;.at the titanium chloride
dissolved in the eaters of monobasic tcids forms compounds
of the composition TiCl
' E and TiCl
* 2E(where E denotes the
4
4
eater molecule), with the products TiCl 4" E in the liquid phase
being stable within a wide temperature interval. Although the
data obtained by the authors point to a very stable reaction
of most of the esters to TiCl
(Refs 1-6) the data presented
4
in papers (Refs 8-15) on the deoomposition of the ethers and
eaters in the presence of aluminium halides ( and other metal
Card 1/3 halides) permit to assume that similar reactions must take place

The Investigation of the Conversion of Titanium SOV/79-- -1-2/64
Chloride With the Eaters of Monobasio Acids. XII. On the Decomposition of
Ticl 4* E Compounds
with some eater compounds of titanium chloride. Proceeding
from the experimental results concerning the decomposition
of the aluminium esters (Refs 12 - 14) it may be assumed that
the decomposition of titanium chloride with esters taken place
in ouch a case where the enter reaoting with it consists of a
radical of a strong acid and an alcohol radical of minor
electronegative characterl this in especially the case with
isopropyl formiate, benzyl formiate and others; with compounds
of titanium chloride and the corresponding esters of trichloro-
acetic acidwhere the tendency to decompose must be greater.
According to the conceptions on the polarization It would have
to be expected that of the compounds TiCl 4* 2E, TiCl 4' E and
2TiC1 4' E the two latter display the greatest tendency to de-
compe e. Thus, the results of the conversion experiments of
titatilum chloride wi-th the above mentioned esters are mentioned
and the authors determined that trie data of Demarcay (Ref 7)
(Demarse) on the compounds 2TiCl E in liquid phase 'id not
Card 2/3 stand up to their checking. It wis found that TiCl 4 with the

,The Investigation of the Conversion of Titanium SOV/79-28-7-2/64
Chloride With the Esters of Uonobasic Acids. XII. On the Decomposition cf
TiCl 4* E Compounds
eaters of trichloroacetic acid and benzoic acid yields compounds
of the composition 1:1. The presence of the compounds 2TiCl 4"E
in solid phase was proved as well as the instability of the
binding of the second molecule of titanium chloride with the
ester TiCl 4* E. There are 2 tables and 22 references, 16 of
which are Soviet.
ASSOCIATIO14: Kubanakiy aellskokhozyaystvennyy inctitut (Kuban'Agricultural
Institute)
SUBMITTED: June 17, 1957
1. Titanium chlorides--Decomposition 2. Monobasi- acij
--Chemical reactions
Card 3/3

5(4), 5( 3)
AUTHORSt
Par. i r~a, MI. A-
0oi SC'J"7,~
TITLE: Thf, Di e -c t ri c Po larl zatl ~,r, of 3y nt~m 5 Comj.-,~1-11 f Two Li
~' Dio lek *, ri cl~,Pskaya po Iyari za t slyn s4 otf-m, 130!lt
dvukh pclyarnykh zh' dkoste,
PERIODICAL: Zhurnal f i ziche9koy khimi Vol "2, Nr 10, p~ 22e--~- Z ?'I
(USSR)
A,B S T Rk CT In a previous paper (Ref Fir, ~.,quati Dr, ~A,' was given t~~at brings
intc relation the diel~2tri' --onstant of the jurf, Folar
with the dipolar moment . By q mod' fi cation B) t!~4 S eq-~',* -n
mav be used for the determin ation cf the diFcl~ir m=-n' --f a
polar substance in the pclar solvent. The Fresent yay.,~r g4ves
experimer.tql prove of the aF plicability of the 'B', f~r
binary systems congistIne of polar comFonents. T),ie -f
determination as W011 as the purification --f thc,
sutstances to 1~e 4nvestiCate d has alrealy been leqcr~'~',-! 'R~f-,
2-41'. Diethyl ether and methyl berzcatp were ~.sod as t~,e scvents
in which the dipolar moments of nitrc-benzen- and
keton~? were determined. Th~ ill-:7:ar moment of i!-
Card 1,"' other 19 AD an .1 in m~ t hy : !~,p n~k tC , C 4 D,

SCV,", 2- 10-
The Diel-tri- Pr~'arl--nt-n )f Syftoms C-mj -sel -)f Two
ar. d t ha t o 'I tfe mr-I ~,y Ik, e * r~, r, n e ~ h e r 1 .9 2 , 7
and in mothyl benzoate 2,76.0,02 D. The dipolar moments ~,f
. -7 ~' +
quinoli ne and pyridine in dim- hyl ani 11 ne and of ch:or:~-
benzene .' n bromo-1, enzene w Pr- a: so determi ne I . The ' S:
giv?n 4r. tatles t1nat th, Pl',;atior. '~B) -a.-; he. f-r
such determinations. '.t msiy, h~-,vpver, not be -isel f--r th.-, 1-
termination of the diFciar moment cf dissc-lved substances
react with% the solvent. s -.,.,as rr~,ved -.,.-ith the systp"'s
f.-rr- - diethyl e+her, anil' ,, ~ - q ncline, acetic ac4d,
-in-.-in~- - dithy: -yr~d4ne,
q'.;J,no.i-ie, Ein1:4r.- - dioxan-?, dI:'xane, -hl-r-f--rrn-
-ac-Ptone, and Ch:crcf-r7, - i'-xqrc,, as the --' ".;
~.-iarizriticn -ind cf +he m=-rts w-re obtained fr,n~
additive val-it~ (araunl 10-300). In this %ay the eq,.;a.,,)n ~(B\
can, however, give an explanation in physica: - chpm.-al
analyses of liquid E~ystems- Using data of the paper by 1. A.
Sheka and K. F. Karlysh4-ia Ref 18J and "ne iii-lar
moment accr~rdJnE tc Deby,~. Dettiy) 'Rf-,.!r t-~ f-~,~
with n1cotine and chi croh,,-. -is 'X a:nFeS 'hn-'
a
Card wit~~ t~l

scri,
Th,~ D, ,I p -I r f 7-1;~
6rences, 'c
ASSOCIATICN: G 0 su -I:- R, 3.
S':BYI-77-'D.

I T
v

S 7) R
T79 R

STRA CT

-o n
f

tit tI n r,
c mor, c, r

t e

";i r

V, ;),)-1~2-
r 0 C- 7:. c'
iOll 'I C P 91C Ol I-r 'A 11 (2 0 0
~-! r
c nt;i f i or, ~
nl~ ..e I e -r e,2 o f t i I:, c t
3 , -. e a r, L3 a r. e 11 ' ; I ~ ~' r ~ i - ~ 111. fo rc i c t-- r r
t, ~j t
e e 53 t rer..,t 9 o, , t, - o ; r! , ,
r r,, u n n,: P, 4i-, r n;,
otren-tli E. For E,. 1' e r e w e r
r1 r, 12 r F, a e F o
orl nn
t r en (,- t 0 f t n I
ra i is of the icn -.:I - r c- v f, r!, t it
V (I An r e o i t-) 0 11 a I S f r e f f t v 7.
U"e ra
n ri I c c, r i e n r1
t e jCa"ppt C - E3
"r';j oner,- -)f' c r . s-- t n f e
c i or~ re c we 71 t. t ip e e r : rn, it;i
~n r, 10, lir 171~ i - 11 '~~ r o 3 t? t

On the Froblem of the Ilydrntion of Tono in Aqueous Solutions
ASSOCIATION: RoBtavBkly-na-Dom gosudarBtvenyy universitet (Rostov-na-Donu
State University)
FRESENMED: ftY 17P.1958, by A. N. Fnm'w'n,, Academician
SUBUTTED: December 13, 1957
Card 3/3

5(4) SOV,
AUTHORS: Osipov, 0. A., ;helomov, 1. K.
TITLE: The Determination of the ln.!tability Constant of Complex
Compounds by I'leans of the Polarization Mothod (Opreleleniye
konstanty nestoykoati kompleksnykh soyedine0y ml)todom
polyarizatail)
PERIODICAL: Nauchnyye loklady vyashey shkoly. Khimiya i khimicheskaya
tekhnolog,iya, 1959, Nr 2, pp 253--255 (TISSR)
ABSTRACT: The quantitative relationshil, botween the degr-e of diaooci~rl-
tion of complex, of electrically noncondijetive compounds
and their orientation polarization is invoctigntod. The
oqu,-itiong for the orientation polarization are (lorivod and
found for the instability constant
k - a,
XB(2 - a
(X concentration of the component F. The ~ larization
equations and the value of the instability constant werfs tef
ad on binary systems yielding complex e~nmp.,)tinls by hydrogen
Card 1/2 bonds. Table 1 shown the valijes for chloroform diethyl ethc

SOV,'i'~6-71?-2-9 4'~
The Determination of the Instability Constant oll Complex --or-,ounis ,y ~,,eans
of the Folarization Method
table 2 for chloroform - methyl acetate. The calculated in-
stability constant amourts to 4.20 # 0.2 for th.) firot
systeii, to 3.92 + J.12 for the second. Thorn aro ' tn~,Ivs
and 7 references, 5 of which are Soviet.
FWMrF1 D BY: Kafodra fizicheakoy i kolloidnoy khimii Roatovokol-o-na-Donu
gosudarstvennogo univoraiteta
(Chair of Physical wid Colloid Cheniatry. Nootov-na-Donu
State University)
SUBMITTED: October 23, 1958
Card 212

s'.
,4
AUTHORS: Kletenik, Yu. B , Ozipov, U. A
TITLEt Physico-chemical ftamination of leveral C,,mpiex Compounda of
Zirconium Halides `$'Ith Enters of the T.!onc'Ousic ~:Lrboxyllc Acids
PERIODICALt Izvestiya vysshikh uchebny?.h zavedeniy. T',iii;iiyu I khiTiCheskva
tekhnolot-,iya, 1959, Vol 2, TIr 5, Pp 679-684 (T;-R)
ABSTRACT: The authors cnntiniie their previ ),i:1 itudiec (Iieft', 6) on the
subject mentioned in the title. in the present paper, additional
laws governllni~, the chanre ~ii polarity, st:Lbility and the formation
temperature of the zirc-)rlum chl ori~e-bromide- iodide series are
studied. The aiethodo Lre donc!ibed in refercnce!3 ~-8. Tabl(~
shows the measurement re,,3ults of the dielectric --onstatt (k
and of the density (d) of benzono ciolutions of' the complex
ZrCI 4' CH C00C 2H 5 and the calculated values of its polarizatIon
(P). The poiarizati,)n )f the compl,~xoo ZrIfal. 'CH .100~-111,
4 1 11
that these complexes do not dis:i,,ciato In iritn their
components in a marked mann-~r. The -mpll ix--~- ZrHal cli-1106-1 J.,
dissociate accordiiie, t(:, the -,clierfie 4, 'Z-,, t ZrIlal 4' 1-;' S +
Card 1/3 + Est. The tendency for incre~',fien in the or6oi

3 3
Physi co- chemical Examination of Several 7omp]ox 7
Compounds of Zirconium Halides 'With afters of the Monol~ar:ic CarbixTlic Acids
chloride - bromide - iodide. TlLbloo 2 and 3 list the
measurement results of the dielectric permeability and tile
density of the benzene so!utior, of several complexes of
zirconium - bromide and zircorilin Jodi,ie as well as th-~
polarization values computed Ici ,hese complexes. A maryed
change in the polar propeTtie~-, f the
cannot be determiried in '.he ti-finl3itlif, i :-on z ~:-~,cnllu. r~.,e
to -bromide and -iodide. .7he pf)iarity of' the i )., e
is lower than that of the chloride co;~iplcxes of' zirr.Oniui,-.
In the transition froin zxrcoziium-chlorid,~ to
bromide and zirconium-iodide. the influeiLce ~,f the tdcohol
radical of the eater rises which increasoo, tho pulaxity
of the complexes. The complexes ZrHal 4 21111,~COOC2Hhave a
cis confiRguration. The ail(liti-)ri temperature of "he 2nd ethy.
acetate molecule to the zirco.aium halide is mu,,,.i lower than
the addition temperature of the lat molecuie. The transition
from zirconium-chlorido to zi.-:-cDniun-bronide has little Offect
on the reaction temperature w: th ethyl acetate. There are
Card 2/3 3 tables and 8 referencen, 7 r~[ which axe -)oviet.

5(2) SOV/78-4-7-6/44
AUTHORS: Osipov, 0. A., Kletenik, Yu. 11.
TITLE: The Dipole Moments of Halides of Zirconium, Titanium, Tin, and
Aluminum in Dioxane (Dipollny3,e momenty galogenidov tsirkonlya,
titana, olova I alyuminiya v d1oksane)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 7,
pp 1494-1497 (USSR)
ABSTRACT: in an earlier paper (Ref 1) the authors proved that In the
elements of the fourth group a direct dependence exists on the
ratio of the covalent radii of the oomplex-forming atom and of
chlorine for the polarity of the tetrachlorides in dioxane,
With a growing value of this ratio polarity increases. In the
present paper the dipole moments of A13r,, AlJ.., SnCl 4' SnJ 4$
Zri4 and TiBr 4 in dioxane are measured. The values for the di-
electric permeability and for the density of the aforementioned
compounds (at 200) are given in tables I and 2. Table 3 con-
tains the data concerning the dipole moments in dioxane of the
halides of Hg, Al, Ti, Zr, Sn and As as measured by the authors
Card 1/2 or available in publications. The following was found: For

BOV/78-4-7-6/44
The Dipole Moments of Halides of Zirconium, Titanium, Tin, and Lluminum in
Dioxane
SUBMITTED:
AlBr3 3.30D, AIJ.3 4.98D, SnCl 4 5.10D, SnBr 4 -4.13D,
Snj4 1-55D, ZrJ4 5.36D, TiBr 4 5-05D* The polarity of
alusinum halides increases in dioxane in the series Cl - Br - J;
that of tin halides decreases in the same direction. The
dipole moment of ZrCl 4 Is higher than that of bromide and
iodide. TiBr4 has a higher dijole moment than TIC1 4 . On the
basis of published data and own measurements the following rule
is assumed: The polarity of the halides of elements of the 2.
and 3. group of the periodto system increases in the series
Cl - Dr - J, that of the halides of the elements of the main
subgroups of the 4. and 5. group decreases. The titanium sub-
group occupies an intermediate positions There are 3 tables ftnd
16 references, 11 of which are Soviet.
April 26, 1958
Card 2/2

R~; K 3
,'I av t s ~~-w ye Ye
T!TLE C o o ra i r~ t, i ~, r~ ,inis -im Tel ra,:h- i, r i I e
0 f MonjbLs -~c. I s XV K, r a a s c,:, r,~- y es y e,--
'~4: rK a s o r am r. K:.
I EA,L C, D., CAL Z t, r a 1
Ao j-, ~t C 3 T. 0;,w
r w e 3
il- 1'1 ~3 V. i, J
t t
t t. t- ty rC t inter-sif 1 a t
rt
ha:i t c - A r.,i ~ t r, I:! t o 1, wh, ': ~l I [I chal a r i it a
e emer. t A,- r I i,,j t ii lww', r. Re f 2 t ski jw H
s c I n Et s
Card

.11 0
rd i I Q
With --Esters C f 14 0 B.
ASSOCIATIONi
Card 2,'3
t r
W
I'm
ti-
f
;<
art r- C ar We 1 17".
Of the -!cm-, lex a e c re astl 3
es were determined according ne C
r,jentioned ,~OmPIOf he, ency of' the com~,ex~`s
OCOPIC method T ,,uge for tho tend e trIF'e
towards ELSE3ociati3r, wEL9 exI ai ned T h
an d r HCGOC F C H CH wer,~
HCON Ii C H 6 3
ZrCI 61 6,
4' 2 5' ere arl s a1, d r
h
separated and analyzed
4 of which are Soviet
Ro-ttovskly gosudarstv"nnyy ;niversitet '.9Oq*,Qv state

E, T R..', C T
h
0 x f 0 r 7n,~, o n bo t

jn j, -h-I'Dride
n
c ~ad ~ c en i nvc,!,,, , .-%, , 1 1, .,. r.. -.1 '.-
fel ffer svnt~(,fijz(,j

2:711
- 11 an,~ I~n,-!
f 1
an, ;chn -ibe 1 i nve - t I -.I t, cc--,. j.,:, c t~(, typo
3n:'l 2 o f jo j - t r 1 r 11,~ II c I
n%tinn of vi~,,-or,,jt f t n t

the -,ro !i-ic,:! -)f t'vO C(,-', I--
-;n
SnCI 4C H OH ( 21 e f 4
2 7V La u b e! 1 7 ~! Ve I' -i n
Card 1/3 shc-.ml by the aid of infrare d al sol-,.t Ion sji,c t1,,, Jr-

A po I c :,Ici -(,n*. qof t he Coml I e x Co::, ound o o' Starinlc
-.:-L1 or ide i t h Sor:~e .'~ I i i,ha t i c A I c ohol s .XVTI
wi t h C H, 011 1 nad s t o c Dmpound 3nCl 2C,11 011 (Ref
2 11 '1 1 5
R. A. Ford -in 11. ~3. %'ar.9chall confirmed the (,--ii,lex
SnCl, . 2C11,011 ~y the aid of ultraviolet ~inl izifr-ire4 s-pectr,-i
(Ref 6). Recently, Yii. 1:. Vol'nov invent i~-ate,l by tho
copic mothod the reaction of 3n "' 14 with al i ~ ~,a t i c -i I c o.-iol
and a3cert .i no I t lie pre sen cc of molecular com;oound~- of th.
type Sn -'I 'I ,2RO11 (Ref 7) - In the present piper the
specifv the rf-~;'ts of their determinati on o~ thx, 11 :,ol-
which were oltaire 'lie rk,-
moment.9 in oun~,Is,
action o, staruiic ch-Loride :71th -ieth3,1- , n.luty, lc
n d 7
i a oamy I al ro I ~~ I , f rom t ho c om p,) s i t . or. in -'l R JR --.nd
-f
)R r, thf, baq4 17 o' tile ~1;01- rnoment vilu-!l
all mentioned coM.: 1.,x com;,oiinA:i q cis-structilre Can be -,s-
cribed to tli-m It was showri th-it their dipole -io-nents dr) not
dej.end on the ',en -1;t of the alc,)hol i-ndica" . "'he dipolo. moments
of the fullowin, complex compounds were drtermin-d
Card 2, 5

Di - Io of t~,u Com p I ex :,)m I, o it nd nStannic
Chloride I th -.ome A Ii i?,a t i c ',I co~io I!,.. XV I I
1
13 nCl OC2H~~ 011C ri, SnCI C 11 OffC 11r) - T"
4 4
nC1 0 c11 113 012 and 2
I Q STIC I Oc 11
'ihe transition fro,7 3n"I 2ROH into SnCl
4 0 T IM J2
accompaniod by a Aecrease in polariV There -.r(.
1C tables and 1(-', refort-nce~l, 4 of which are j(, v it, t ,
ASSOC!,,T:-7': 1~~;stov~,-iy-na-DonU L- -,),-ud;~rqtv-nnyy univ-rnit ~~t v-, -i-D nu
State ',,Iniversily)
OIUR,'4T ~'T J ~nuar
y
Card 3/3

5 (4)
AUTHORS: Osipov, C. A., Kletenik, Yu. B. SOV/79-2')-4-71/17-
TITLE: Physico-chemical InvestiCation of the Reaction of Zirconium
Chloride With Eaters of the Monobasic Acids. 111. (Fiziko-
-khimicheskoye isaledovaniye vzaimodeyetviya khlorida tairkoniya
so slozhnymi efirami odnoosnovnykh kislot.III)
PERIODICAL: Zhurnal obshchey khimii, lnr9, Vol 29, Nr 4, P1 1377 - 1362
(USSR),
ABSTRACT. Publications do not point out the existence of compounds which
contain more than two eater molecules for one molecule MeCl.,
e. g. h!ecl 4* 3 E (eater molecules) (Refs It was the
authors' task to investi.Cate the reaction of the complexes of
the composition ZrCl 4' 2 E with a third eater molecule in ben-
zene. For this investigation more precise data on the molar
state of the complexes ZrCI 4* E and ZrCl 4* 2 E in benzene were
necessary. The complicatel character of the dopendenco of the
polari-,ation of the complext~;; ZrCl 4* 2 E on the concentration
Card 112 which was detected (Ref 9) and interpreted earlier by the

Phydco-chemical InvestiCation of the Reaction of SOV/17~-2?-4-71 /7
Zirconium Chloride With Esters of the Monobasic Acids. ITII.
authors was in the present paper based upon cryosco~ic investi-
gations of some of these components. The tables 1-3 and figure
1 give the cryoscopic data of the benzene solutions of the corn-
plexqs ZrCl 211COOC H,'~rCl 21CH COOC H and ZrCl 2C H C~Oc)H'.
4 * 2 4 * 3 2 5 4 * 3 7 ' '
The comparison of the results confirm the aforesaid assumi,tion
concerninC the r8le of the concentration. It was found that the
complexes of this composition dissociate considerabiy into the
components in benzene solution. The series formiate-acetate-
-butyrate shows a clear tendency to dissociation. A scheme was
suggested for this dissociation. By means of tlie cryosropic
method and by the determination of the dielectric constant was
found that the zirconium chloride reacts in benzene with two
ester molecules only. The dielectric constants of the complex
computed from the data of polarization and to the cryc-
a cop ic mot hod we ro oqu a". T1,em fir o I fi,,-uro ind I q
, 7 tal)l-n,
.references, 1C of which art., Scviet.
ASSOCIATION: Rostovskiy-na-Donu Cosu,larstvennyy universi-tet (Rcstov-na-Dcnu
State University~
SUBMITTED: January 23, 1550
Card 212

3 , V/7 7
A 1.7"'j K I c, t , r, J, lk tY ui po v A
T I Phy3 i c al -Ch emi c al I nve s t i -,at i on o " the 1 n te ric t i o n C, f n-
Hal i de 9 Wi th Es to rs of I.:o nubasi (, Ac i (I s ( Fi z ik c,-khi mi
i.,;-1o,!u%,a:iiyo vzainudflystviya GaloGonidov t:iirkoniya ~-,O -r:,
nyni efirari odnooqnovn3,k1h kislc~t). '..Complox-l of
D romi ie ( I . Kom;) I ek sy b romi d,,i t s i rk -, ni~- a)
:~I,:AL: Zhurrial obL31,.chey khiinii, Vol 29, N-
p p 1A, 2 71 - 1 A ~' 9r. )
A--,,-,T~~ACT: In the preqont palier the complexes "ormed from zirc~ niun, br mide
and estora of monobagic aci(ls were inveiti,-%ted by i:;va-~!, ' t~.e
method of the dielectric constant and cryoocopy in as
well ar, by prepa:-ation in a pure condition. T!.e in,.-sti,,ation
methods and the purification of the re%gent!~ used vt!~re dec. :.,il)ed
Previoll'oly (T~OfS 3 and 5). in tabloo 1-1;~ Ue dielectric
densiti0c and moiccular polarizations of the comi.le;on
ZrBr 4- ECOCC ZrBr C11zCUUC,E and :,rlir,.C-
2 .11 C-(-)C,li, in
4- 5 It 7
"ard 1/ 3 1 nzcn- Rro surimarii~ed. The 'ipole mcmcnts of these com; lev's

Physical-Chemical Investigation of the Interaction of SOV/79-29-5-4~'75
Zirconium Halides Wit)i Esters of Monobasic Avils. 4.Complexes of
Bromi do
tile clipole moments of the esters contained in them
and the difference r i
are given in table 4. he f f,,u_
shows the cr-oacopic data for the complexes
ZrBr 4 HCOOC 2H,, ZrDr 4 C11'kCOOC2H 5 as well as for ZrBr 4' 211CC'-C2115
and ZrBr 4.2CH 3COOC 2H5 in benzene. The tables 5-9 contain data
on the dielectric polarization of complexes ZrBr 4' 211COOC2 H51.
ZrBr 4' 2CH'COOC 2 H5' Zr)r 4 Ml~COOC 5H7' ZrBr4.2CH 3COOC4119'
ZrBr 4' 2C3H 7COOC 2H 5* TtLble 10 presents data on the molecular
polarization of the ccmplex ZrBr 4' 2CH3 COOC2H5 in benzene ~olu-
tions with different excess of ethyl acetate. The polarization
was found to decrenae, in complexes of a '.?rBr 4' 2E'-compooition
(with the exception of othyl formats) in the queries zirconium
chloride-bromide and the dissociation of the linkage with the
second molecule of the ecter was found to increase. The tindency
vf the ZrBr . R-complexeo towards dimerization is less pro-
Card 2/3 nounced thaA In eimilar complexes of the zirconium (_h1uride.

Physical-Chemical Investigation of the Interaction of SO V/79-29-5- 4,"75
Zirconium Halidoe With Esters of 14onobasio Acida. 4.Comploxes of Z1rc,n1'X_-
Bromide
On the otrength of the data concerning polarization and cryo-
scopy of the ZrBr 4.2CH3COOC211 5- complex its dionooiation constant
2
in benzene wao calculated. It provad to bo about 2.10- . The
polarity was found to increase in ZrBr 'complexes vAth cthyl
acetate, propyl acetate and isobutyl agetate if the alcchol
radical increases. 7he complexes ZrBr 40 HCOCC 211 51 ZrBr 4' cii~cc'.C 2H 51
ZrBr 4'C3H7COOC 2115were separated and thoir melting poirto 1'~_
termined (1080, 1640 and 157o). l., the mixed complex
ZrBr 4# HCOOC211 5*C6H6was prepared in pure condition. It was found
that the benzene in it is bound to a considerably lower extent
than in the similar ZrCl 4' HCOOC2R5'C 6H6-00mPlex (11of 6). There
are I figure, 10 tables, and 12 references, 9 of which are Soviet.
ASSOClATIONs Tiovochorkaaakiy politekhnicheakiy inBtitut (Novooherkasak
Poly"ohnic Institute)
SUBMITTBD~ Marob IC, 1958
Card 3/3

5 (2)
AUTHORS: Csipov, C. A., Fletenik, Yu. F. cv"-
TITLE: Physicochomical InvestiFation of the liefirtion of Zirroniiiii;
Halides Sith Eqtors of Monobaitc Acids (Fizi1,(,-khi;i,i
lssledovriniye vzaimodeystviya Ealogeni,lov tqirkur,~,i 90 S1071--
nymi efiraial odnooonovnykh kislnt). V. ror-Ioxen of 7irc-niu-:.
Iodide (V. Komploksy yodida tairkoniya)
PERIODICAL: Zhurnal obahchey khimii, 195), Vcl 2), 'Ir 7
2119 - ?124
, 11
(USSR)
ABSTRACT: In th,? 7,r,?sent Paper the results cf the invostiC~iti-n tlo_
polar pronerties of zirconium iodide complexes with esters )f
monobasic carboxylic acids in benzene are mentioned. The ini-
tial benzene solutions of the comp*,exes wer,, jrod~.red by dis-
solvi-iC zirconiuri iodide in benzene which -ontained an Pquiva-
lent amo,,int of ester. The dipole moments of the cqmVlPxPS
ZrJ
CTI COOCIE ZrJ 2HCOOC 11 ZrJ ?C1T1, C00%11
ZrJ
f
,
C~y
,
2 5
4 3
2CH COC7 H Zri ? isc-CH C00C H and ZrJ ~C H (D!- 11
'
3 3 7
4 3 4 9 4 3 7
in benzene were determined. It wao found that tho increase of
the acid radical cf tl-n esters relu_-es ai,d th~_- ir'-r"ase -,f tale
Card 1/3 alcohol radical in-reases V,,
, ' ~.xt-
),)larit
of tY
ti-
inve
~
z~
s
1
y

Physicochemical InvestiCati,)n of t~.,~ I'leartion Df
Zirconium Halides With Eaters o. 2.1onobasic Acids.
V. Complexes of Zirconium Iodi(le
gated. The dissocilitinil .- ~ntitant of the oomplex :,rJ42CH 3-
COOC2R5 was approxia. itely 44-termined by meanB of the diolec-
tric constant. In the cr)rrr-1f-x+i3 of zirconium tetrahalilea wiO)
the oaters of monoblAoic a,,'ido in the series of ?~Irt-:)nium t)~Ior-
ide, bromide, and iodide an increasint; tenlon,,y f tht~ com-
plexes Zrllal4- 2E (E-ester) towards di3sociati,r, (eeparation
of the second eater molecule), on the other hand, h-%vLver, a
decreasing tendency of th- complexes Zi-11al,, *E t-w-trin rtsso-
ciation and an increasin,~- influence of tho alooh-l r ~ I i - ~t' iv- r
observed. The tendency of the ~or.,-Iexes ZrHal, t -irl,
dissociation increases -.7i th t),e increasint; acil r~_d 1
parison of the polarity 1 it,i -)f th- uvriplexes Zr:!;il
Zr11al4- 2L (7 t:11-les) to the !on,~Ilisinn tl,iat all ZrHal
2E complexes inve3tiCatel have- r-ia-stru,,t,ire. Ther.~
Card 2/3 ure, "t tables, an-' 9 Sr-,viet roforenceg.

Physicochemical Investigation of the Reaction of gOV/7-)-29-- 7,197
Zirconium Halides With Eaters of Monobasic Acido.
V. Complexes of Zirconium Iodide
ASSOCIATION: Novocherkasakiy politekhnicheakiy in8titut (Novocherkassk
Polytechnic Instituto)
SUEMITTED: June 10, 1958
Card 313

C
AUTE C R S Z h d Y A S 0 v
S?~ e e i r. Y e -i r,
e r, t 9 ar d S I r j c ~u re, o f S,-r,, e De r i v it s
rerinapnth~ndenGno
F ER I CD 1 ;LL Dok 1 ady Af. adem i i nauk SSSR 9 V c . 1 4
uss
ar, t re r,:~ an r - r. e i i r, W 0 a, k r
A ?S F~A," 7 Fe r i naT I-, t~, i nd erion 1 t
c !~ ara- t P r i s t i ~: k o ne o r t 9 'Refo 1
:D,-,i u~x with protonic and a; r, n 9
s sui,-CeB ts a - --is ide r!ir,: 1,uri ty c f Ur.-
1 r 5 t rit 1 : : t~- o f pe r i naph I~t i nd*,ri e ar, i be- 7 ar, tnrz,,-. E3 x T-,~ S 3 -
' y ' ~~ -,~ ~ r ', -:-, i ~,ncy c f pas 9 ; ;-.~~ c7 ve r i r. *,u t, s '.a r -.,x , d :7 e IL~
The possi tie existet-,:-- )f a -.r-it,.,-,,,,,, ~r, i,.l
racently as a comp~'Lx sal t ' Ref had beer. S'_ M F I , ii e r
ht-f t) a, tl,c)ugh the attempt at produ,ing i t ha I f
ritl ~ lat , ins (,f the b, na,,rij~ onprgios in tl,~~ j t~
sysl.o~m by the method of moi-,_~ulur orLi tn qki.-)weJ tlta' A
state w~ th a 1 2n-el~-ctron assembly is enfrget ). -a. a t~
s f, r t t, i s s y s t e r, . Tf,o s y 9 t i g a ro m a t i r ~ f as t
fir I 51-7-.t 1 '.' ',R(- f - ~ . Th~is , tin intralonic bindinC ~hara ter :)f

The Dipole Moments ard Stri;ct~.re of Some Derivatives
of Perinaphthindenone
can be assumed (according to Ref 8) fur the carbony. --.19
of the perinaphthindene series where the negative charee is
localized on the oxygen, whi)e the positive one is distributed
over the entire carbc)zi system. An extor-givo ana )f t~.e
pr-Terties of tro;-nne (11',' and perinaphthindenonp ~erT..,ts t e
redu ~t,, or, o I ~, ts s tr,i ctu re to that of perinaphth indeny' cx
(la', usirg also the analogy with trojil oxide :!:a' ''ger
gram ) . For pori naphth .1ndenone , a cons 1 dernhl e d I po 1 o mumer, t
(in the magnitude of 4D) can be expected, all the more eo as
tro~-ne has a moment between 4.17 and 4.5C D 'Ref ?,. Tc c:ar-
i fy tt~i s probl em, the authors measured the dipol e moments o'
perina:,hthindenone and some cf its derivatives. Table ' ~r,~
sents the resu: ts showing that the dipole moment In d.,nxank- is
reduced by 0~.72 D by the introduction of bromine inte t~,,~
nucl f-~s of perinaphthinaenone, and in benzanthrone by I
The introdu-tton of a benz3nal nic:eus redures .t by
On thf. ~~thqr hand, the onoment increases r,~, tt.e irt:--
d,i,'tior. i-f ar, ;xy gr3u;, into posltijn 7 of perinaphthindenQne
I = d
An -ntramulec,-ilar cycle with a hydrogen bond is f -e
r'ard 214 Thus, the negativP charge :)f the carb.-,ny! cxyger. is star-, 1 i7pi

The Dip-:e Moments and Structire cf Some Dorivatlvea S~';,'K- ' 28-4 -2
nf Perinaphthinder, )ne
ar,d the C - C gr,-~up Is ta'N~er, --it )' th" c ~nlugat. -~n -x-,, ',-. t
gri-ind skeleton of t~,e molq-,u: e iue tc, .ntracy7l - ~?X, %M.w
processes v.1a the nydrogen bond. in ~jntras' t,., tn~ at-_ve,
tr,)~-olnne has a di-,cle mument mu.,h toc :Dw %'!.- D, as
W 4 t.
I ~. the trc,-cine. 7~.e va,-,;p -,.' the dipc.',,, m,_Tent x
c 13 H 8 CS b c 9 . D) ~erm_,ts, assum~t.,Qns vis t- ,I s st-
Y'~ ~ , T.
s t -,,i - ~_i r, f a de-
n f K _n f LL, L
state 9;, i:Ti I ar to HS~' f,
p-, c il ~i r t I ,,d r.c 'r n '-i,,a I ,n,-. id ~i1 . -,i f,
n d n y i i m, a n, I t an t t a s -, n e f ad i r.
e q t. t r p a r t i c pa C: n t h e 1 o r d i n Fi t i Fq~,-ro w
~1 "S 0 [1 -'-' I t 1i b I P M. 1 1
Ai v
ASSOCIAT,C!;: R! 8 t v i y na - D -,n,-i 6") 9'.~ ~ ar 9 t v k-riny y -.n r 9 '. to t R S
t a t ~ , , . I
.9
Card

LS-7 I L'6 . ; ' , !.-. . . ; : ~ , ' ~'.% .
'.. ri! "1%: 'r . p0 ~7 - IT, - " T" -~ -, ' I , - -'.
11 . . 7
7,'A ' '~ '. '~ F. -0 : , '- ,, - m - D~ T-' I I . " -~-'. -1 C) I-I V. ,, ';:" ,
- '. ,~: I I rl' p
. A ~- - " C

HINKIN, V.I.; OS)POV, O.A.; GARNOVSKIY, A.D.; S +NOV, A.M.
Dipole mcments of i-midazole and Its derivatives. Zhur. fjz.
khlm. 36 no-31469-473 Mr 162. (MIRA 1'7:8)
1. Rostovskiy gosuaarstvonnyy universitet.

OSIPOV, O.A.; ISPLAILOV, Kh.M.; KASHIRENINOV, O.Ye.; GARNOVSKI-Y, A.D.;
ORIMA, L.V.
Study of some dialkylaminoirothylpheriols and aromatic sulfides.
Dokl. All Azerb. SSR JCf no.9:21-24 'b3. (MIRA 17:P)
1. Rostovskiy-na-Donu gosudarstvennyy univor,91tet I In.9titut
neftekhiniO,eskikh protgessov AN AzS3R. F'redstwrleno akademi-
kam AN AzSSR M.A. Dalinym.

L -17823-65 E:,PA(s)-2/EW(m)/gPF(C)/EWEWP(.J)/T Pc-4/Pr-4/Ps-4/Pt-10 RFI/
BERM WAI
ACCESSION NR: AP4047650 S/0079/64/034/010/3407/3411
AUTHOR: Garnovskiy, A. 1). Osi 0 A '- Dalgatov, D. D.; Simonov, A. "Al.
Minkin. V, E2.Vl
TITLE: Complex compoundsAof metals with certain nitrogen- containing ligands.
Comple~xes -of -the- 2--o - hyd rMan),:1'16C6zim1dazole eries--
SOURCE-- Zhurnal.obahchey Itbinnit, v.. 34, no.- 10, 19641 3407-3411
TOPIC TAGS: organometallic compound, chelate compound, benzimidazole deri-
vative, organic complex
ABSTRACT: Two newo-hydroxyanils of 1-methyl- 2-formylbenzimldazoie were
,-synthesized: 1-inethylbenzimidazoie-2-aldehyde-21-bydro)kyphenylimine and I-
methylbenzimidazole-2-aldehyde-(21-acetylamino-51-methoxy)phenylimine. The
complex-forming ability of the first compound was investigated; the complexes
of the second compound are to be subsequently described. Heating an alcobolic
solution of the compound with the acetates or nitrates of Cu, N1, Pb, Mn., Th
or U02 gave ~brightly colored thermally stable rather insoluble crystals. Based
Card 1/3

L 17823-65
ACCMION N11: AP4047650
on elementary analysis and IR spectra, the 1:1 complexes- formed with Pb and
U02 and the 2:1 complexes formed with Ni and Th were assigned the following
chelate structures-
X /"O\
NI
(51
0 Pb X - OCOCII~ No,:
I
MQ=UO;,X=QCOG11,.
IV) MNI. X
.1-methylbenzimidazole- 2 derivaLves containing no hydroxyl group or hydro5ql
group in the p-position would not complex. The heteroatom of the imidazole ring
'Card 2/3

L 17821-65
ACCESSION NR.- AP404765.0
was also shown necessary for chelate formation, since benzal-o-aminophenol
wotild not form a complexunder similar conditions. "Spectra were obtained by
A~. N. Sheynker on the UR- 10 (Zeiss) apparatus in a paste with vaseline oil.
Orig. art -as-10 form lae
U
ASSOCIATION: Rostovskiy-na-Dony gosudarstvenny*y univt;rsitet (Rosto+n-
Don State University)
SUBMTTED: 01Ju163 ENCL: 00
SUB CODE: OC NO REF SOV: 006 OTHER: 010
card 313

SHELOMVP I.K.; OSIPOV, U.A.; WHILIOAENOV, O.Yv.
Complex formatton In diluted oolutions bry the method qf molecular
polarizations. Diur.ob.khi~;i. 33 no-4:1056-1059 Ap 'k. Zhur.ob.-
khim. 33 no-4:105b-1059 AP 163. (MIRA 1615,)
.2-. Rostovskiy-na--Donu gosudart9tverinyy universitet.
(Complex compoundo.-Dipole momentAg)

WIFUVP O.A.; GAYVOhONSK1Y, V.I.
Complex for-mation of titanium tc--trachloride witAi kptones studied b7
the infrared spectroscopy method. Zhur.ob.ldtim- 33 no.4.1346.-1349
Ap 163. (,XL!,A 16.-,)
1. Rostovskiy-na-Donu gosudarstveany universitet.
~Titanium chlorides) (Ketc (Spectrum, Infrared)

LYSENhJ,- YU.A. ; Will't-1, J.A., IJ~AVT-,~-)V, Ye.Ye.
2
On the existence of titanium etherates. Zhur.noorg.khim. no-3:663-667
Mr 163. (MlhA 16-4)
1. Luganskly sel'skokhozyaystvennyy Institut, kafedra obahchey khilnit.
(Titanium compoundg) (Eaters)

k-U!~Q~5 EWT(m)/1UP(j TIEwPWAMb)
Pe--4- IJP(C)/SSD Ila )/ AF,"D(t) 'Rx
4aassiok RR: iP4044808 3/0078/64/009/009/2126/2128
--ami pnv- A--k-- v
G M F6I
..Z5
N
kA A Wk&
hic 0 -io-acidestera--
arb xyl
~SOUROE.'-Zhurnal neorganthheekoy khimil' V.. 9 -2128
no..9 .1964, 2126
'TOPIO-TAGSt-lanthanum diethyloxalate
A _complex, lanthanum diethylmalon-
--;a plext lauthanum dieth lsuoolnate oomplex, noodymium diethyl-
loxalate complex, neodymium Nothy1malonate oomplex, lanthanum diethyl
~sucoinate complex, synthesis, IR spectrumt lanthanum chloride ccn-
:~talning complex, neodymium chloride containing complex
ABSTRACT: Molecular compounds of lanthanum and'neodymium ohloride13
:with diethyloXalate, malonate and succinate were synthesized by shak-
~ing thesinb-droun chlorides ulth excess eaters in sealed ampoules,
washing-~he produot in benzene and drying in a desiccator. The
-';Ianthauum complexes were white aud the neodymium were lilac-colored
rystalline materials soluble In alcohol but Insoluble In other org;,n-.
~ic solvents. Complexes of the general formulae 2MeO1 eater and
eater were formed with the oxalate and malonate?'the 2:1
19013'
2

~13 -65
50
~--~-,-,,JLOOBSSION-NR.,-AP4044808
:,quooinate complex was probably not formed. IR spectra of the 4,om-
-.-..--,-Pou,uds were-exmine-&-in- the- -100-!',LBOQ-- am"J- range. In the 2:1 oom-
KIF.07--
-sroupe--We
9-t, or-band-
IFty-Noi-va t to
'diethylmalonate was synthesized and the following Probable formula
was pxoposed; H
C
F/\
V
1,ASSOC'IATION: None
SUBXITTED: 12Jun63 HOOL: 00
BUB- -OODE tIC, OC N -REF SOV.- .003 OTHER: 005
M
2/2
Card

FU,'C V,~ K . Y , t, A Y.
~Onrlex
Part 1: 0m; exi, s 18
'os tovqk : ,--nu- AII FS '-V(~T,rV'V T, v P -o o

............ . . .1 1 . .1

OSIFOV, Osip Aleksandrovich; NINKIN, Vladimir 1saakovich; ISUPOVA,
-.I -F-w-
Pandbook on dipole moments] Spravochnik po dipolInym mo-
mentam. Izd. 2., perer. i dop. Moskva, Vysshain shkola,
1965. 262 p . (MIRA 18:7)

F, r 1,4
"JU

KUFHATIOV, 7.P.; OSIPOV, O.A.; FOVALENKO, K.N.
lnnf-r-comTlax compounds of copper w!th KOtnnna.
hur. neorg. khi-m. 10 no.2.,50-~4r, F ,6 . (11,1-.,~A IP-11,
1. Submitted Jiln(. J." 1964.

L 27827-66 EWT(z),4WP(t)/1T1 IJP(c) JD
Acc NAt AR6Migh SOURCE COM, UR/0D58/65/ODD/011/D026/D026
AVMOR: Osipov,, 0. A.; Semenova, 1. H.; Kostan. V. A.; Hinkin, M. I.; Sokolovo V.
-.1
TITLI: Infrared spectra of &ZIligh iqALM, titanium, and_%IL' chlori-les with some
organic ligandi 7
BOOM Befs zh. Mike, Abe. 1ID203 0413
REP SOURCE: Tr. Koxis. po spektr6sk22ii. AWBSSR t. 3s vyp. i, ig6h, 76-83
t
,TOPIC TAOS, spectrum analysis. chloride, IR spect~rum, gallium, indium, titeniun, tin
AMRACT: An infrared spectrum analysis was uBed for the study of the characteris-
tics of Interaction between gallium and Indium chlorides with acetone, methvlhexyl
ketone, cyclobeyanone, acetophenone* benzophenone, and some.other oxygen-containing
empomdso (Translation of abstracts) IKPI
StM COD11 07/ SUBM DATE: none
P

., (,I I," I " .,.:, "V
FACC NRs AP6020371 (A) SOURCE CODSo uR/007f3/66/011/003/0536/0539
AUTHOM ROW"s, M- 0.1 Osirvo O.-A4 Iflayeva-9- L. -3
ORGI roy* t~
TITIEs Coordination compounds of rare earth chloride* with eaters of diga jig
acids rbm
SOMMI Zhurnal risorganichigskoy khiraiiq v. 11, no. 3, 1966, 536-539
TOPIC TAOSS prasoodynium cmpmndo BAnArium cov"undt gadolinium compound,
clYsPrOsium compotmd, lanthanum compoundo noodymium oompoundo dicarboxylic acid,
electron donor
ABSTRACTs Continuing their study of the electron-acceptor propnrtAos of rar earth,,)
halides, the authors ir estigated the interaction of-praseq4ym~umi?aamAriumi~gado-
linium, and dysproalum'4hlor~ es with diet 1 oxalate, malonate, and succinato, "n
Mh 1
nd noc um orides with diethyl adipate, madeate,
the interaction of lantk I !Y-Mi .
and phthalate. The structure of the complexes thus obtained (which could not ')e
Isolated in the pure form) was studied by comparing the IR spectra of the pure
11gande and complexes'l It was found that the formation of complexes of the camposi-
tion 211 causes the disappearance of the band corresponding to the stretching vibra-
tions of the free carbonyl group and to the appearance of a strong band in the longer-
wave region which can be assigned to the vibrations of the diester carbonyl grcrups
12 umt --,,46.6511311541.49

DALGATOV, D.D.; TERTOV, B.A.; GATVORONSKIY, V.M.; OSIPOV, O.A.
Structure of 2-formylbenzizaldazole. Zliur. VFHO 8 na.5:582-
583 163. (MIRA 17-1)
1. Rostovskiy gosudaretvenliyy universitet.

OS I Mv, O.A.; ~',Ay'.' ~ ON ;Y: Y, A.A.
Donor ' ;.r.o.,iphcrj'l iril P!i-r )xygen Ln
ZhLrr.nctorg.'r.:-lT- 0, - . I : ? I ~ .'I , I S 't, ~ . (m:IiA

ACCtZSION N111 AP4014693
L ~
3/020/63/019/009/00"/0024
At7j~jo7,s: Osipov, 0. A.; Ismailov, "..I. Atq] reninov, 0. Ye.; Garnovsk,~,, A. D.;
Orlova, L. V.
TILTLE- Investigation of some and aromatic sulfides
(Presented by 1-1. A. Dalin, acadcnici.-.ii D.' t!io Azcrl)aydzlian (All SSR)
X~ AzerbS3R. Doklady,.,, v. no. 9, 1963, 21-2L
T'J?I'. "'LAgS: antioxidant, diaLcyla-i' suLlide, intrimolocular bond,
1"A:-r1CtiC suscopt-Jbility,
4nte.-molecular bond, hydrojorl bon(i, --r, -
infrared spec'.ra
The dipole moments and and the infnired spectra
c~ derivativcs of aD-
ylphenyl-
s,zlfidns (kAPS) were studied. -~'ncst -:-,'nnc-cL7 wcre of interest as
an' . i oxid ants for lubricatj-n~; oils, a phenolic
Ot 1 C 110 nV(~S i
in ortho position in respect t,, -a2kylrin nom lyl roup. T i t -
Cat--on ccnt~,rcd on whether there occ, --od i.n co,-,pounds the formation of
either intramolecular or intormolecu-'..,r bonds, as
Card 0

ACCESSION NRI Ap~oiL693
O-H
CH, N (R) 2
(VI)
OH R CH2N(R)2)
\-CH N-H-O-e"
(Vil)
To this end, dielectric corrductivity measx-oments were conducted in benzeno
solutions ar-A the dipole moments canlculat-~-d, using P. A. Osi-.o,,' 9
(ZhOlCh. 1561 t. 26). The cdstenco of intramolocular hydroC~,r, bond-- 7--:t- Of
the D10021 was confirmed, blit was proved a'~,oent in the JU-Lk?S compounds. g art
has: 2 formulas and 3 tables.
ASSOCIATION: Rostavskiy-na-Donu gosudar3tvennr4y universitet (Rostov-on-the
Don Stato University); institut neLftokhii-uchcskikh protsessov (Institute of
Fatroleum Procoases)
Card 213

KOGAN, V.A.; OSIPOV, O.A.; MINKIN, V.I.; GORELOV, M.I.
Dipole moments and strurture of inner-complex compounds al"
copper with aromatic Schiff bases. Dokl. AN SSSR 153 no.):
594-596 N '63. (MIRA 17:1)
1. Rostovskiy-na-Donu gosudarstvennyy universitet. Prod-
stavleno akademikom V.I. Spitsynym.

KOGAN, V.A.; OSIPOV, O.A.; GARNOVSKIY, A.D.
Compounds of thorium tatranitrates with sallcylalanllne.
Zhur. neorg. kh1m. 9 no.2t494 F'64. (MIRA 1712)
1. Rostovokly-na-Donu gosudarstvennyy tiniversitet.

ACCISSION NR: AF4019493 3/0078/64/OD9/003/0734/0737
AUTHORt 0sipav, 0. A.; Kashirenicov, 0. To.; Leshebankot A. V.
TITLEi Electric conductivity of niobium ozychloride in organic solvents
SOURCZ: Zhurnal neorg. khiuii, v. 9. no. 3. 1964, 734-737
TOPIC TAGS: niobium oxychloride. electric conductivity, niobium liquid extraction,
niobium separation. specific conductance, solvent dielectric constant. methanol
complex, dioxance complex. dipole moment. donor acceptor reactions. molar
polarization
ABSTRACT: In order to develop more effective procedures for separating niobium
from other metals by liquid extraction, more data is required on the effect of
the chemical nature and the polarity of the solvent on the behavior of niobium
compounds. Measurements were therefore made of the electric conductance of
niobium oxychloride in a series of organic solvents (1,4-dLom&rA# methanol, prepan-
ol, butanol, bept&Dol, pyridins and nitrobenzene) In relation to ccocentration a"
temperature. In the alcoholic solutions. the specific conductance of HbOC13
decreases with Increase in the weight of the alcohol radical* The specific
Card 1/3