SCIENTIFIC ABSTRACT ORLOV, N.F. - ORLOV, N.M.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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New Methodsfor the Synthesis of Organosiloxanes SOV/2o-125-4-35/74 and leads to higher yields. A further advantage of this mothod is that it is possible to use also arylsilanes. This is im- possible in the case of H 2s04 because of the disarylating effect of this acid (Ref 15 It is easy to control the course of the reactions (1) and (4~-according to the amount of hydro- gen separated. Its rate can be easily controlled by the amount of the catalyst and the temperature of the medium. The mention- ed reactions take place with solvents (benzene, toluene, petro- leum ether etc) and without solvents (Ref 16). There are 1 table and 16 references, 3 of which are Soviet. ASSOCIATION: Institut khimil silikatov Akademii nauk SSSE (Institute of Silicate Chemistry of the Academy of Sciences, USSR) PRESENTED: December 7, 1958, by A. N. Neemeyanov, Academician SUBMITTED: November 4, 1958 Card 3/3 ., 11. F.J. Cand Ghem Sci - (d1ss) "Synthesis of triorga,!osi1L,):~,-der!v OFJOV --------------- 11 of elements of the III, IV and V .~G from trLorgaziusllanDls aria bexpr-.1k 1.,i- siloxanes," Lenix-Wraa, 1960., 18 pp (Lenirvrad State Univ im A. A. /-i1,ua.,,.)v) (KL, 36-60s 113) Stekl~b-oyv -atol-aniye; trady Tretly,4~ --cy-no,. 1'-2'0 nO7`abrVz 1959 lylt- State; Trn-nctl- of' t:.e T~ilrli All-UniM COO- fem- 01 the vltre~ stn", Neld 1, 1959) Mw'~' Izd- AJN SILSA, 1960. 5~4 p. Prmte ally inverted. 5,200 copies printt,4. (Series: Its: TruAy) Age-1-: I..tit.t khteli iI0.t- A"i-lt ... k V--ra-" lthimicheskoye ob*%ch*PtYO Imeni D.I. Y-J,ltr- and 0cxudx,~twv-y7 order 2,00144 optleheskly lftgtlt~t tm-nt 5.1. V-J!ovs. Mt.ri.1 Board: 4.7. V.r. M.A. R..b-don,, O.K. liot~lmkl., V.V.Varela, A.C. Ylavow, K.S. Y-tmp'y~, A.A. Leb,d-, M.A. Mftt-;-, V.S. K' lebso-, R.L. Hjull-, Y..A. P.-y-K-hit., Chairman, N.A. T.r,,r-. Y.K. Plorl..k.y., A.K. Tkhkind; Ed. of Pbll.bl,.S Ro~.: I.Y. 5-:,ov; Tech. 9d.: V.T. F-h-r. PJRPWX ! This book I. s.tadea far re.,&,r~lhvr. S. the and t,eh.olo,7 of CI-.. CO`MtAr,E: Th. book c-W.s the report. -d dl-~.I- .1 the TiAd All-U.1- C-fere-e on the Vltmc~~ State, beld 1,a E-i-,md on llo-be, 1(-19, 19-4. They deal Lth the ~thodA end result. of gtkd~-lng the str~etum Of Alft-, th. r-l-ti- b-t- the t,.,ct.- -d propeftl- of g1 ...... V" ..t-~ of te t..d -d Kl- structure, and the vrypt,llocnemlst-y of glass. rt~ &A .0-1= of vAtrificatim, optical prol-Lita " rlzas struct-,, ani the .1-tr1ral pro,-ti- of gles... s.re Is. discussed. A .-bar of the - ports d-1 v-1" the dv;~dcn" of glass properties On ewpopition, the tIntlug of g1"... and ff-t., and t-h.1-1, and en-i.&l rrp- ties of glax- Other 1,spem treat rlaWs ov=1cmd-tors a,.4 zc4n borcollicet, gLan-s. The Comference vas altenl~d by mom than W dvLogates from Soviet and East German scientific orb-liatians. Anmg the ;articlp-ta in the di-lonu -- N.V. Is. V. K-hl"kly, Y..A. r-t-, V.31. To. I.. Oatlib, O.P. C.P. k1kh.rl-, S.M. Pttro~, A.-I. I..-. D'I. L-Sh. A.V. Shatilm, X.T. Ploahchlankly, A.Ya. K-tsov, K.V. Deg-tymrwew. O.V. by-asom.keys. A.A. We-, N.M. Sko-yak-, ?.I.. BOY-'.. E.K. Y.11.r, T-A. T.P. P.&4-,, R.S. Z.G. Pt-, -d O.S. Molchaa- Th- final "--I- of the C-f-ce vvs addressed by Pror-.- I.I. Kita7go-iskly. I-ored Bel..%J.t -6 Enginver. Doctor or Tec.1-1-1 Sct.mt- The r.li-.-.c in~tlt~t*s we" cited fl, lont,lbut- to the of alasa "d t"hnol~U Gccu:Ltr-t-,n.,y aptivne.my Inntitut (State Optlc&l jostjt~-_)' lnstlt~t k."stil AN SSSF (Instit'a, of stlicft~ r1lichesbAY inltlt~jt AN SS514 (Physics Innti"te AS M~"), Swtit"t J04 P-SSR lnztlt~t, AS =,R), Z-tlt~t flzlki AS 1*011t. K16-k 0~ltltute of Phyfitts, Acadery of Stie-, Plelorurtkaya SSA, KInst). tAborst-Y Of FhyAl-l Chmiatry or Silicat- of tit lazt.ltut abshchey I mrorgani. Che-kvy kh1all AN PSSH, MAwk (Ics,Vlt"t' of -d J.-gailc ch-l.ty. Ac"'Ay of sciences Nl-kay. SSR' min't), Instit4% ..y.di-ty AS of Nish M.1-1.r ccmp~!'O' ),!, USSR), G-'JaPst'_ a" lostitut stekla (State institute for Glass), C-ls-~t-yy lnmtlt~l tok- IOVOIOkna (State Institute for GI-s Fibers), G-d~t-yy iustitut *t*tWmt.jLh- ftich-k.fio tetl. (St-t~ la.tlt~te r., Electrical Glee.), Slbi-kly fl-Ilt- tochnicheekiy InstlLut, Tonsk (Slbrls~ ftyalectee!~ni-l lustltv-. 71cask).1-Ingred- (L-Ing-d St.t. X--t-t- tn'tjt~t (Mos- J-tjt~t' of Ct-~-j 1..tjt~t I.. Len-ta (1-1."rad 7-tl..t t.."I LO-O"t), Fwl--kly polltlkJ~nle esky l-t1tut Plagk P.Ly,-_j~ I.stit~t-, Kln.k), pllt-kl-lC'-kly Ins'.1tit voljt-n.l~ U'A S-dl~k!y rolyt-!'~' T~ Cree-e"'" wa, P-sored ty tf,- lnstitlt~ Of SlIt.- C'-!-ry A:; 11,S), (4,t]W ~ A.S. 1~tjjb~, ~~ V-/.-j~ k-11-1--, .b.hlf-t- t,. D.1. K-A,I~ye- C!--: S-11ty 1-t D.T. t- -d- 1-1- optl'-kly t-tit'-. 1.-i "O'1- or 1-,:n" %.-I S.I. Is 1-t-Dn t~ C, nt r." 1- cr -11-t~- t- --- - t. p,bllt- : .- 01 -), 'l-, . T~'~ C-r- t Y-A. cf r--j,-, -0 ft.l~ f r--l-l or t- C-It-t. T)" "Alt-1.11 bm"d ~"kj :.~. D.P. D,-ro-, ~.A. P.T. F-1 vitre" state (C-t.) sov/5035 T-I. C'-;-.1-1, or ri-t~ or Gi-- ccmposstlon 340 Dl.~.ion %3 Color of GI&G-es ~d Eff-t of Vs,rain, V.V. Color of Glwa and Ffr-t of hr-al~ti~ 345 Orl" N F 11-1- of AI=i-t- -1 Crpt~lll.ity of Netl-" in TIntltZ U-Jer the Actl- of a-- IUV- 346 Dan1lov, V.P., and P.V. Drrbftv~~ V-sation In the S;K-*~- of Glan... of sipl~ cozp~ostl.- U'.11. tM. A~tlon or C-. 1"1. 351 llreLh-Llkt~, S.M. 0, the of C-trelal 01-1e to t"'. of Psmdi~tlvt Re,!4RtIms 355 Karaptya~, G.O. Srr-t of 01- Dtm~t- on th- S~ictral a'! Ch=!c-a Prv,-tico a. Ccri= lonn 360 Ce,rd 15/22 Vltm~ State (C=t.) sw/V35 A~', K.P., V.V. 8.D. 0-h--m, ani-, V.A. st-t~ mr,t% fyo~'-ti" of Irou-c-'t'j~~tug Gl"I~a y2aso,m, R.I., 7-1. GlAnt, And A.A. rf~ll. Ab-r-I.. 51-t- of tl~. 2. CO Iom - the Coor,11-tion rn.21.t.r ..' D.~, .-i S-11e& (1 1"... w T~6in, V.V. , wid f .1. Veyzberg. Color of Glasses in C-ctlm VItb st-.t- 372 Disc-loo PLvch-l-l -11 6- T-1-i-I Pr-n-tle, of Urtenev, O.M. sxr-t~ an! mect-scai rro;-tl~ ot Gl- ~t G2"t rlb- 3aO Eml-kAy., Y-1. T2-tJ. P,-tl.. of 01- 1. to 3ar Card 16/22 TIt'- state (coot.) &WbO3~ Aelan-, K.S. K"tari-i rr-ml- of 01- 391 R.tO171-01-31-, V.A., -1 V.V. T, -7- 0. of OL---. and M..haalml Y36 Retgrr, rh. r~rt-l,.Jnr tt.e D-.-Ity -l Virc-tty in Tl~ fcr 1-.1 J- ai- .6 111 T-fr:-ti- P-g. For-r-, I.Y. of U;, t.. the C-,i~ Boe%y -1 c, t r1i, I - W5 Y-l-,-, T-V. rt,Of of cn~i &.. F--" V.A. Ft--- of Gi- 1 1-. t- yr%t- o~ s $'.~ ~ 1. 412 DI .-.1 - IsI5 Card 17/n gNs/am b4 All-MAIM domforeaso as as wit"was Stale mume"I "able I boommum. t9". Mr S. or 45-" crou) A20194091 110 Svc su-Saida dosteremoo on "a Ttfi"~" stale VGA held In towlawal as as emes of 19". It was organissa Ry the Inailtut atou millbalow AS SOON (Awtituto of she cbffidgtry of 1111",S.a As no). vowe"Wome" thimlobaskers obobehoutwo lao.1 0. 1. OmMeloym (All-Walem Chowleal doslaty Sweet 9. 1. 9nd.l.y-) U41 Govedatetwomm" optlaboOkly I"OLtut Level S. 1. Tavil.,& (OUto 4911sal Imottlisto Intel S. X. Towflov). Nor* them 100 reports as the streetare at glass, Is-estigtion awthods of the Slaves" auto, the woob"Lan or VIATifloattou and pIqSIoa.b..icft2 sea soobaleal ipm "low of glaameet we" Wlve"4. Me C-af-- 1. eyesed by Asudeatelas 4, A. Lobodev. ,At as Yth settled, 6 report@ 460t ~ith_ciam.;. - -I- "84801"9* 9 with 1110 491WIMS Of alemes. and the of r- !I!!Ies "4 4 reports with Isew,al properties of.glas'... V.-tL-Targa Ww I W. v 1. -C lorinll of GI-... 1. 04"JOS VISA fbejz morwv;-!-- a. geroll. -AboarptIon spostr" OT-114--ev. lam WIMMIlem of sai4m "A A2-Imme 1. ato ... 0. T. F. I ead 1. 1. Vortmab weported *a the kage of %be or WSW*-Itiom VMW The Lvnv--* at I- 4. 0. awspotyam reported on Ch* iaflu-oo of St. t-.t=o at S1. "a 00 APS~tml sof Oboadval PPOPCo'11-0 -T the C-r-1--- Jr, F, 01~,L_ Reported on the "Is of the adal2tor.. and the %a Is $be velarIAS of to."m Clear Iky c.- 312umma doA 16 L. $has or reporlos " the ftliFe Verare formallea In wall* (to- claeo, reva reported as f tj _j._L4_ t \J __j j is of at ;F5 tary wo,1408 In . *I.*. Of qlllb~l- I. F. P-nz-. fte ZW Caere of the wIt"ou. yh&e. In the y-oztI.TP %-he lc,;:: r ~.I. C634 4/9 . . ; OdF sms I RO Cows$ Maker' . V. A. P"an., r-prt*J an the p~hj.l- of She tefifti"W i -i -tJ- 1i'-_817h :;all" dealt alth physical 4b.aloW7 and ..ahaml.ma pr.p-ita. glave. 9. 8. 0. a. baxtso.v =4 3. X. vub- ~ reported 0. U. fwl-,* wMe somprebosel" reports. A. A lp p ~ i- _ W otracturel parameters whiib the prop-tI.. of %be ' glass. 1. A. Nalabyllakays, 1. W. T--1 rap-t~d Ff-Mr.-o" C1 ...... . -y-1. M-Wl.ro VG&v_. ";A4176 team" report*4 an Pecallexille. of the of . l 0 210684 reported .. the -bj.tS, n i j VA, Roar Re"47 of covet So #=d Their 1.14 1. the rr~... a the 71mome Me. S. _PL 5_71%.kya reported *A d f Tu p".160 o derea4for" Of the PROP.T11406 of alkali poeltloa* S. N. shobeglov. reported ons at the Do- posdowe at %are-4p-Mal Proporfl.. of Phowphto Cie.... ca the empoelliese. A. j._XOkh1x4 "port.4 so the mbj..13 'Th. P-IWI. Myortas mnA the Optical C.-ftato of Close-. ff. 5. A.1-.- repart#4 out olosbani.al Properties of Class 3,lbo,o-. A. 3. re"xlm"- made a xvp~rt on the sw.h-Loal prapai~_M_.-of ln.rpml. guests to the mansalous Im1-1 and So their stsuct-o. Tt. L. C, led a. Ch. .1a.21. proTearti.2 at glaowe# mW ca card 7/a f the "ap..Ltlo. of the Cl ..... . a their ,Mo%o,. A_T _&krwW" reported " the 'L .. birZ of SIa2.2Ikv j-alts %, A"wou. Solution. of A.146 -d the dh2t s N%%, f She 0.1a.. Is the straetw. of at... xa,aalw. a. M. : a ropors.4 ft kb aw v foina olija.t. S. 1. Dbr.- reported on phr.leo- 1,= shogista rpwjjwm of Sljj~ mille.f. V. A. Dubra-kty mad 1. reported a. the ourfeme IIIe fti~ai-Tb- --I- of~v 41.. Clear in $be ocidl., .-Iral and beat- -21... Th. fal- . or-" r"ort.4 at the float I. F- at., I- .. loot" She Ufl.~.. of the alkali.. earth ..14.. .4 the ab-I-I t.t1l,ty of CL .... 1. . buald L. To. *a 1i%1Lf1-eAL- -4 properties of bores. eja..7 pool" W.C.1 and Ra.tgor pak. .. mu..t. f- t--%-= 0---y. 1- 1. V. U. A. 1-0.rod.,, 1. 1. tlt"grad.l~ty. Aod .1 -4 1-1.1 1- -P-k- at $be fl-I aa-li-l- ; ; Oard 9/9 (3 Is--2220 ann S/062 '6()/0C0/009/-_1.' B023YM64 AUTHORS: .,Qr.~LoZ., F., Dolgov, B. N., and Voronkov, M. G. TITLE: Tris(triorganosilyl)borate PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikL nauk, 1960, No. 9, pp. 1607-1609 TEM In their development of new methods of synthesizing silicon elemental- organic compounds, the authors aimed at completing the previous methods -f producing triorganosilyl esters of boric acid - tris(triorganosilyl)borate by new methods. Three new methods were developed. They distinguish them- selves from the older ones by high yields (80-95%). The first two arg based on the reactions of triorganosilancles with boric anhydride cr borl~ acidt 3R 3SiOE B(OH) 3 (R 3sio)3B + 3H 20 (11) 6R3SiOR B20 3 2(R3sio)3B -t 3H20 (2) The third method of synthesis is based )n lh(. interaction letweer. tr,'' organosilanes and boric acid in the presence of colloidal ni-kpl: Card 1/2 8nt2 Tris(trioreanosilyl)lorate B023/B064 5E SiH 4 B(OR) ~(R'Sio) B t 3H /7,)- 3 3 3 2 The reactions (1) and (2) are based on ar. ~irinterrupt-'-d distilling off of water from the mixture of triorgancsilanoles w-,th br.r--,- acid or with boric anhydride, containing an inert solvent (benzen,~) Tria(triorganosilyl)borate was produced according to scheme (3) by heating mixtures of triorganosilane and boric acid in the presence cf colloidal nickel, forming in the interaction of nickel chloride with triorganosilane. 6 tris(triorganosilyl)bcrates were obtained by the three methods of synthesis. 4 of the compounds have hitherto been unknown. There are 1 table and 21 references; a Soviet, 6 US, 3 British, 1 Germar, and 3 Japanese. ASSOCIATION: Institut khimii silikatov Akademii nauk SSSR (Inq'i*uTp -f Silicate Chemistry of th~ Academy of Sclen-es USSR' SUBMITTEI)i May 4, 1950, Card 2/2 AUTHORSs TITLEs PERIODICAL: B2296 S/079/60/030/007/01 0/020 BOOI/B063 Orloy, N. F., Voronkov, M. G. Tris(triorganosilyl)phosphates Zhurnal obahchey khimii, 1960, Vol. 30, No. 7, pp. 2223-2229 TEM The present paper describes new syntheses of trie(triorgamosilyl) phosphates on the basis of triorganosilanols,ihexaorganodisiloxanes, or triorganosilanes. It was found that these 'posphates are formed with a yield of 50% by a reaction of phosphoric anhydride with triorganosilanols according to the following scheme: 12R3SiOH + F40 1 V--:> 4 (R3Sio)3PO + 6H20 (1). A side reaction, 6R 3SiOSiR3 + P4016->4(R 3 Sio)3PO (2), is to be assumed because of the comparatively high tendency of triorganosilanols to inter- molecular condensation with water separation, which is accompanied by the formation of hexaalkyldisiloxanes, with P 4 010 acting as a catalyst (Ref. 16). The mechanism of this reaction is illustrated by Scheme (3)- Card 1/3 ~21)1 C 0 Tris(triorganosilyl)phosphates S/079/60 007/010/020 B001/B063 Another synthesis of tris(.triorganosilyl)phosphates (yield of 90%), worked out by the authors, is based on a reaction of triorganosilanols with orthophosphoric acids 3R 3Sioll + R3PO 4~~ '(R3SiO) 3PO + 3H20 (4) in which the water must be distilled off (Ref. 22). A mechanism of this reaction is euggented in Scheme (5). An attempt to synthesize tria(triethylsilyl.) phosphate according to Scheme (7) was unsuccessful, whereas ortho- phosphoric acid could be reacted with hexaalkyl disiloxanes according to Scheme (8). The mechanism of this reaction is shown in Scheme (9). A new interesting synthesis of tris(trialkylsilyl)pho7hates with colloidal nickel acting as a catalyst is shown in reaction (10 in which a side reaction occurs, so that a yield of only 60% is obtained. All tria(tri-- organosilyl)phosphates obtained are only stable in dry air, whereas moist air splits the SiOP bond. The synthesized products are tabulated. A mechanism of the catal-ytic action of colloidal nickel is also suggested. There are 1 table and 26referencess 13 Soviet, 7 US, I Italian, 3 German, and 2 British. Card 2/3 82296 Tris(triorganosilyl)phosphates S/079/60/030/007/010/020 BOOI/BO63 ASSOCIATIORt Institut khinii silikatov Akademii nauk SSSR (Institute of Silicate Chemistry of the Academy of Science.s_M) SUBMITTED: July 11, 1959 x Card 3/3 1c/W/61/0JO/0006/026/081 D205/D302 AUTHORS: Orlov, N. F., Dolgov, B. N. and Voronkov, ~'. G. TITLE: Synthesis of triorganosyloxy-derivativeB of boron, tita- nium, phosphorous and vanadium, from triorgano-ailanols and hexaalkyl disiloxanes. Reaction of hexaalkyl disi- loxanes with aluminum and titanium halides SOURCE: Khimiya i prakticheskoye primeneniye kremneorganiches- kikh soyedineniy; trudy konferentsii, no. 6, Doklady, diskussii resheniye. II Vses. Konfer. po khimii i Drakt. prim. kremneorg. soyed., Len., 1958. Leningrad, Iza-vo AN SSSR, 1961, 123-126 TEXT: The field of elemental-silico-organic compounds is of prac- tical interest because of the possibility of synthesis of compounds which are similar to inorganic compounds in their thermal stability while being soluble in organic solvents. The syntheses proposed give better yields than those previously described in literature. As to the application of the synthesized compounds, the silico- Card 1/2 OR Lo V A/, )C PHASE I BOOK EXPLOITATION SOV/60'~4 Konferentsiya po khimii i primeneniyu fosfororganicheskikh soyedineniy. 2d. Kazan', 1959, Khimiya i primeneniye fosfororganicheskikh soyedineniy; trudy (Chemistry and Use of Organophosphorus Compounds; Conference Transactions) Moscow, Izd-vo AN SSSR, 1962. 630 p. Errata slip inserted. 2800 copies printed, Sponsoring Agency, Akademiya nauk SSSR. Kazanskiy filial. Resp. Ed. : A. Ye. Arbuzov, Academician; Ed. of Publishing House: L. S. Povarov; Tech. Ed.: S. G. Tikhomirova. PURPOSE: This collection of conference transactions is intended for chemists, process engineers, physiologists, pharmacists, physicians, veterinarians, and agricultural scientists. COVERAGE: The transactions include the full texts of most of the scientifi( papers presented at the Second Conference on the Chemistry and T'se of Card 1/14 -%rd 21,, th" -,Ili 0 'R - I17dustr, esP-arch I ON a] U nstitut S of0 of P pganopho jastlcS sphoitis Chemistry and the Use of Organophosphorus (Cont.) SOV/60-'~4 The preparation and uses of organophosphorus compounds are discussed, and prospects for obtaining new high-molecular organo- phosphorus compounds are outlined. Gefter recommends 1) the preparation of new organophosphorus polymers based on oxides of unsaturated tertiary phosphines, 2) the utilization of thermal sta- bility and good mechanical properties of known organophosphorus compounds as a basis for creating new heterochain phosphorus-con- taining compounds, and 3) application of the laest methods currently used in the chemistry of high-molecular compounds to organophosphorus polymers. Or.1D _v . N. F. , and M. G. Voronkov [Institut khimii silikatov (Institute RF-Silicate Chemistry, Leningrad)). New Methods of Synthesis of Tri- organosilyl Esters of Orthophosphoric and Alkylphosphonic Acids 2)2 New methods have been developed for the synthesis of tris-(triorgano- silyl)-phosphates (R3SiO),PO, bis-(triorganosilyl)methylphosphonates Cli3(R-,S'0)2PO, and organophosphorussilicon polymers based on H,PO#, and CH,PO(OH)2' One method is based on the interaction of Card 3 /14 s/o5i/62/012/002/016/020 E202/E192 AUTHORS. Byurganovskaya, G.V., and Orlov- N_F_ TITLE: Formation of colour centres in quartz and sodium silicate glasses under the action of gamma radiation PERlUDICAL: Optika i spektroskopiya, v.12t no.2, 1962, 278-284 TIEXT: The relations between the absorption bands of' quartz glasses and sodium silicate glasses, and the amount of gamma ir- radiation, were studied together with the effect of traces of' cerium, antimony, avsenic, manganese, iz-on and lead on the properties of these bands. A large number of industrial and experimental glasses were used in the studies of colour centres. The glasses were melted preferably in an oxy-fuel burner. The irradiation was started at ambient temperature. co6o, at 9 3E lo3 roentgen/hour was used as a gamma source. The spectral absorption of the glasses was measured on a C(~-4 (SF-4) spectrophotometer and expressed as optical density. Quartz glasses showed three characteristic spectral absorption curves. The first, exhibited by glasses melted in reducing conditions or containing large admixtures of elements of Group I and 111. had three groups of Card 1/2 Formation of colour centres in S/051/62/012/002/Gi6/o2o E202/EI92 strong bands with centroids at 540, 300 and 200-210 ni-p. The second, represented by optical quality quartz glasses, had a weak absorption band with a maximum in the visible spectrum, discernible only after a large dose of irradiation (l x lc,7 1 x 108 roentgen). The third, characteristic of high purity quartz glasses, had only one shortwave UV absorption band with a max-Laium at 200-210 m~k. The formation of colour centres for all quartz glasses was the sa me I.e. quiring doses within the ranges of (4-8) x 104 and (2-4~ 6re x 10 roentgen. The silica glasses studied were based on Na2O'4S'02 and Na20.3S'02,* with the additives of oxides of the above listed elements within 0.1-0.25o w/w. The rate of formation and quantity of colour centres in these glasses were found to be influenced by the additives. All colour centre5 due to irradiation were of one type only. The anomalies in the relations be'tween the optical absorption and the irradiating dose in &lassos Containing F0203 were not fully explained, but were thought to be due to the traces of contaminants or due to the conditions of melting. There are 8 figures. SUBMITTEDt January 21, 1961 Card 2/2 S/079/62/032/002/008/01 I D204/D303 AUTHORS; Orlov, N.F. and Voronkov, M.G. TITLE- Sil-ico-orgar-ic esters of methyl phosphinic acid (MI'Al PERIODICAL: Zhurnal oLshchey kliimil, v.32, no. 2, 1962., 608-612 TEXT i This is a description of the methods of ~iynlhef-.m.4 of th- h..thez*c vpknown his (triorganos-'ylf methyl phosph-.rates, based or, interaction of CH3 P(O)(OH)2 with- (1) Triorganosilanols CH P(O'l 0S i Et'k Was pmru~-ed in 68% yield from Et SiOH 2 moles) and MPA fl. mole), by heating for 2 hr%, removing continaously the water formed. (2) Triorganosylanes CH IP(O) 0:3 1 Et2Me CH P(0) COSIEt CH P(o) /'05)NIe(n--Pr) CR PfO) 12s 3 - 3 2 3 - 2 -121 3 /..0SiNIe(Ph)2 -]2and CH3P(0)1 OSiM(Ph)9_3 . were synthesized frurn the corresponding trisubstituted silanes and NIPA in the molar ratio of 2 4 1, in 0presence of colloidal Ni, in 70-90% yields~ by heating for -.7 hr at 130 C. (3) Tr2organoalkoxysi lanes- CH 3 P"O)FOS:Et 31 , and CH 31'(0) Card 1/1 S/079/62/032,/002/008./oll Silico-organic esters of D204/D303 f-OS-,(Ph),-j were ob*a-.ned f-.om Et 3SiMe and (Ph) .1 S~~OEI lak-n . n t.!.o molar ratio of silane MPA equal te 2.4A and 2 ir 60 aid 70% yields. The reaction of MPA and tetraethy1 d.,si1cxaue (1 1 ratio' was catalyzed by colloidal N, and yielded Et Et CH 3 0 - S - 0 P - 0 El wh-~Ist anothtr pol.vvw- .1 It was ob*aiined from ar, equ. ino I e-i O-P-0 0 C117 ) D Ia.,, mixture of MPA and j--melhyl diethoxysilave.... A' I the phn-4ph jittles the exception of crys*a1l2ntL CH P~O) OSi(Ph)7j %vere -.olorlt-s-4, h-jtt- L boAlng !-.qij:ds, readi!y hydr,-:yzed by water, The po!)m,!ri~ %v-!re pa'- yellow o--Is. ExperimerO~jl dela-Is are g,vs~n and phys-cal V, Card 2/3 3392 3 S/079/62/032/002/008/011 Silico-organic esters of D204/D303 the products are tabulated. There Eire I table and 17 zeferences 1i Soviel-bloc and 6 non-Soviet-bloc. Me 4 most recert referen(es to thE English-language publications read as follows R.O. Saut-r, J.Am.Chem-So., 66, 1-1707, (1944)i W.H. Keeber and H.W. Post, J-Org.Ch., 21, 509, Car-ad-an Pat. 496,623 '1953); Ch.A., 47, 4128, (1953). 16SOCIATION Ins t i tut kh~mx 1 si I ikatov Akade m,; nalik SS.,3R 'I DSt I I U I (1 (11 Silicate Chemistry of the Academy of Sciences, USSR) SUBMITM) March 2., 1961 Card 3/3 S/079/62/032/002/009/011 D204/D3O3 AUTHORS: Orlov, N.F., Bogatkin, R.A., Sergeyeva, Z.1., and Veronkov, TITLE; Interaction of triorganosilanes with carboxylic acids in the presence of colloidal nickel PERIODICAL: Zhurnal obahchey khimii, v. 32, no. 2, 1962, 650-651 TEXT. A short note on the reactions of triethyl silane with carboxylic acid, using colloidal Ni as a catalyst. Monocarboxylic acids reacted giving the corresponding triorganosilyl eathers, in .50-85% yield. Eaters of general formula Et 3SiOCO(Cif2 )11 OCOSiEt3were mynthesized in 60-80% yields from simple dicarboxylic, acids. Colloidal Ni promoted hydrogena- tion an well as dehydrocondenzation, as was shown by the reactions of Et SiR with halogenated and uneaturated acids. Monechloracetic acid yAld*d either Et 3SiOCOCH 2C1 or (Et SiOCOCH 3 + Et 3SiCI), depending on the, molar ratio of the reagents. Unsaturated acids yield hydrogenated Card 1/2 ORLOVP N.F.1 BMTKIN, R.A.; SERMYEVA, Z.I.; VORONKOV, M.G. 1=-~ Interaction of bydromWoUsneis with oatmrated acids in the presence of conoidal nickele Zhur.ob,khime 32 no,8:2%2-2566 Ag 162a (Snane) (Acids, Organic) (MIRA 15:9) ORLQIf, P.F.; BOGATKIN, R.A.; SERGEYEVA, Z.I.; VORONKOV, M.G. Nickel catalyst in the reactions of organosilane hydrides vith organic acids. Zhur.ob.khim. 33 no.6tl934-1938 Je 163. (MIRA 16:7) 1. Loeningradskif gosudarstvennyj mniversitet i Institut khimii silikatov AN SSSR. (Silane) (Acids, Organic) (Nickel catalysts) j 2 PZ-4 )/IEPR WW */R z I_ ~6~00iiA622 -So 0 -ral-i Orlov er le llov6i ng ~po q os oxanes o TITLE Jiepe ~A X L - *~' no- ten i At& liqbre r- i - TO yme YB. 9X , 'Aixthor-Cett f -cAte,-~ This: AWT - i i rq uces:oA prove parative me 0 PY -dibigandsil6kanes 'and- W. n ng pqlysiloxAnes--uti i inig Af droxypo ic _ 6 * , ~ ~ ~ _ d, )_ A' u mi--an' '~tiipfienyliil -d~hln L bxydilsopropox, - r6alkoxy ~a. umin d~ start ng* maierialsli-._ -'--This- n,,a -:prodtid ~..-with~ ijii~ Xiiifll' j _V OCIATTOR-'- none g~ -S co in DE. V~, -a 0OV. j-, AM PMS:~ Nb 1 _ 1, 2 _Cd Ap 0146 SICY2 oft 0, .th6d~fbi'--bbtAinink-tiiorimosi-IM- x4 j ja spbiiii o~' i(l. go of imtwmho . ....................... . aly,- ~ ; - _-. ~ . - - ~:, - !,~~ -- -- -. Z ~- .~ I - -. -_- - - - ~, - - - . , -- -, - -- , ~ . - --- - , , . 1 3- - I - 'W-F 5-M-D. N, 5ZI.- 15MIMM, -1 )l: a&" 3 FAVEWPO ~`ACC`Nlk :.-,.--A?60023 t3 RCV:-COb UR/0286/651000/02i[0618/001 SOU Ile Of ~'777777~ One! son Miio,~,i2:j~ 76385 k. o 23 1965, 18 t IM& t -Oho-oph Iftiltils-li":972610 t~.~ 462481 ior' Cairtl 'bia I a, p .0 f eau - sovid iste acI4~ I a -Tbe "'.a.cotopnoo h d 104"1 lio, i, Iii i luit'.J14 1tv opb too oftam6soototy-ox. Amas.,V p 0, 0 Aso] L L-4_ u., A4.,I. VC 347 ox Thd-- alcoihbl, forn4d -Molaw 'a, thph-, solated. L-V nv,~ r,))cyme'~!~v 7 ~)r s I-. a c Inoy K ORLOV, N.F.; MIU~SHKEVICE, V.' .; Al;,I,fl.()N,:'V, Ye ~~. Syn ~ ~, e S 4 F, cf anc' *.:.e:- . . m L~Prmal deromriosit'lon. ZnLr.cb.'...h;.r,,. 35 ` T '65 - ( x " 1~, ~ I (-: 1, '/ 1. Len! nh7ra(,sk-1Y ir.s'14 t,--L teKF~'. - 'noy i lec''~ ov ; r omys r . I '.!: fmeri' -').M.Kir,;va. S;it-rj~~.ed 3'~, lQt~50 L 32200-66 LrNT(m)/T/M(J) TJP(C) WW/RM ACC NR, AP60073-19 SWRCB OWES UR/OD79/66/036/002/030/0350 AUTHORS ' orlov,, N. F.1 Vovenkov, M. 0. OM: lanin-m-ad-Institate.of Textiles and Light Industry In* S. M. Klrov(t6ninpg~dskl institut tekstillnoy i 2egkoy pronWahlonnosti)l Institute of 6Fg_a_n_fc__357n the sias JAN LatSSR(Institut organiChOskogo sinteza AN IAtSM_T_ TIMES: Tris(triorgany1silyl) antimonites SOURCES Zhurna:L obshchey khimiip ve 36j, no* 2)j, 1966v 347-35D TOPIC TAGS: antimony comnound. organic synthetia process,, silicon compound &BSTRACT I A study by N. F. Orlov and M. G. Voronkov contains data on two new methods for the synthesis of tris(trialkylsilyl) antimonites. The first method (A), which is simple and economical, consists of reacting a trialkylsilanol with antimony trioxide on heating: 6R SiOH + Sb203 =* 2Sb(OSiR3) + 3H20' 3 The water formed is removed by azeotropic distillation with an inert solvent, e. g. , benzene, toluene, etc. The yield reaches 7016 of the theo- retical. Previously, the author.s used a similar method.to g~pare tri- Card Q6,28 7+5L6,a63 L 32200-66 ACC NR: AP6007229 silanol derivatives of some other trivalent elements or groups: boron, ~ iiosphorus, or vanadyl. The method is similar to that used in the preparation of trialkyl anti- monites, Sb(OR)3, by reacting Sb203 with alcohols. The higher reactivity ,-f trialkylsilanols, as compared with alcohols, can be explained by their higher acidity caused by the p, - d, interactions between silicon and oxygen atcm. The second meth6d (B) suggested is the silanolysis of trialkyl anti- monites: 3R3 SiOH + (RIO) 3Sb - (R 3SiO)3 Sb + 3R'OH. On heating of the mixture the alcohol formed is stripped off. It is advisable to add the silanols ip small quantities, e. g. , dropwise, especially in benzene solution, in order to prevent silanol condensation, thereby increasing the yield of the desired product. The presence of sodium in catalytic amounts accelerates the reaction; however, the reaction proceeds readily even without any catalyst. Tris(trialkylsilyl) antimonites are either colorless liquids or crystals with a weak silanol odor. They are stable on storage in dry air, but L 32200-66 ACC NR. Ap6007119 V hydrolyze in humid air. H y of tris(trialkylsilyl) antimonites increases with increasing length of the organic radical, and is higher than that of the trialkyl antimonites. The properties of the five compounds synthesized (four of them for the first time) are aiven in Table 1. Table 1. Tris(trialkylsilyl) antimonites I ?YV- r yield b; *C (p 2u MRI) Found 9 Wq~lati . Compound t 11 111M Hg" d, I n[)20 Found 1 C&Icu- 1sted Sk 1 11 , Fo mul a 46 W 8 01.0 N* 0) 1 1449 1.4374 W1 ".13 3'.15. 21-52, Ir,",OSbSi, 31-27 21.64 ".71 .21-29 B 00.0 f32 (G) t-1318 1.45M 102.59 102.66 29.25, 29-33 - C"If'O'Sm, 21L22 - A A 61.5 63.0 v0 (5 51 170 M 1 102 i W41 1.45M 1.4675 116.23 129.69 116.19 129.72 2573. 2SAA 23.53. 23." 1?Go 17:44' 19.0t, 16.01 CjjHaO2SbSIs C,,%,OSIkSI, 2&72 U51 MSO IfL34 B 90.5 IP3 (30) mp 2140 (benzene) 1,1038 1 Mi 1129M t29.72 - .Lis 6.09. :1.14 #..1%, S~J* Cj,II,,OSbSk, C"11,0'sm, 23.61 IL34 &H d The refraction increment for the Sb-O bond,, absenjtjn the literajure according' 590.05 Orig, art, heal I tablee to the authors$ was computed to be equal to 5o2 �SBt V*2# noog 020 OTH MW 1 002 SJB CODEt 07 / SUB14 DAM 05Jan65 / ORIG WI - - ----------- INMTOR-, Orlaw, W. F...* Kaufman. 1. L. ORG: none TITLI: Preparative method or organic o acidiclass 12, No. 1621464announced bi SMCZ Cons M/0413M/00/011/0019/0019 Iftett of SOURCR: Inabratenlya, pranyshlemyye obrastsy, tovavnyye makl, no. 11, 1966, 19 TOPIC TAGS% organoellicon ester, acetylpboophatic acid ABSTRACT: An Author Certificate has been Issued for a preparative method of o organosilicon eaters of acetylphosphonic acid. The method Involves heating of alkyl(aryl)dlcblorophosphites with triorgaDoacetoxyellases. . [so] SUB CODK: OT / SUBM DATE: 03Apr65/ ATD PRESS:5,025- UDC: 547.419.51419.1.07 L 31797-66 ENT(m)/EWP(j) RM -ACC-NR,-,Vi6021683 SOURC13 CODEt UR/0079166/036/00370--W63~~i AUZMR: Orlov, N. F.; M.Ioshkevich. V. P. 50 ORG: Loninzad Institute of the Textile and Light Industry ime S* Ile Kirov (Leningradalifty Institut tokstillnoy i legkoy prorvahlonnogti) TITILLs Synthesis and certain proportion of organozilioon esters of hydroxymothylphos phinic acid SOURCL-.: Zhurnal obshchoy Iddmii, v. 36, no- 3. 1966, 518-521 TOPIC TAGS: chemical synthesis, phosphinic acid, ester, organosilicon compound. silano, %LydroVl group, chor-dcal bonding, heterogeneous catalysis, acetic anhydride, chemical reaction, reaction mochanism ABSTIUCT: A method for producing bis(triorganosilyl)hydro3Wnethylphosphinates not previously described in the literature was developed. The reaction of Ariorganoalkoxysilanes with hydroxymethylphosphinic acid in a 21l ratio is conducted under mild conditions, distilling off the alcohol under vacuum while heating the reaction mixture to a temperature not higher thin 50-600. The formation of such products is direct evidence that the hydroxyl bonded to the phosphorus through the carbon atom in the hydroxymothylphosphinic acid molecule is less reactive than the acid hydroiWls toward alkoxysilanes. The reacti6n of biB(tri&Ltylailyl)hydrox3mothylphosphinates with trialkylai-lane Card L 31797-66 ACC NRt AP6021688 hydrides in the presence of a colloidal nickel, cat4yat end With acetic anhydride in the presence of catalytic mounts of sulfuria wid results in the formation Of *store of trialkylsilazyn9thylphosphWoor acetoxymethyl- ph4~sphbdO.&#ds, respsctiT44. ' Orig. art. hast I tahle. -rjpR-s7 SUB COM 07 / SUIR-I DATZ-t 0211ar65 / ORIG REFt 006 /. 0TH IWFt 005 Card 2/2 ','JH SOURCE CODE: AUTHOR; Orlov, K. r. - OM: none TITLE: Radioluminescence in nc>norganic glasses -C6606-6il- LA~j 0 -23j-/ C6j-6-C~6jo-G~jj 917 SOURCE: Optiko-mekhanicheskaya promyshlennost', no. 7, 1965, 6-11 TOPIC TAGS: optic glass, radioluminescence, phosphorescence, impurity center, nuclear~ radiation, Cerenkov radiation, Cerenkov effect, radiation dosimetry, cerium ABSTRACT: General questions concerning luminescence in nonorganic glasses excited by nuclear and other types of radiation are discussed. Radioluminescence of glass in high! energy fields is considered in the following terms: a) luminescence of active centers! and particular "a of structural formations initially present in the glass; b) lmi-I nescence of impurity centers and certain types of trap centers, generated by the inter4 action of radiation with the material; c) luminescence due to radicals created in the process of irradiation; d) Cerenkov effect. Type a) luminescence is observed in lead and cerium glasses. Since only trivalegocerium is capable of luminescence, the bright-:- ness of luminescence in o s mally containing tetravalent cerium, is low. ktic glasse Due to high concentration of learl-n flint glasses the extinction is very pronounced, reducing the specific intensity of luminescence. Other activators, a. g., titanium and Card 1/2 UDC: 666.11.01 : 535.37 L 40967-66 ACC NRt M6023365 antimony, present in glass as impurities, do not exhibit measurable amounts of Imines- cence. Absorption zones present in quartz glass are an example of structural forma- .tions capable of luminescence. Type b) luminescence is due to impurity elements not initially contained in the glass, but generated due to the interaction of nuclear par,; ticles with the material. The magnitude of this effect is determined by the proper- ties of radiation and the initial concentration of appropriate elements. This ef- fect is utilized in radiation dosimetry. Type 0 luminescence results from radicals created due to the ionizing effects of radiation and the breakup of the molecular bonds. Type d) luminescence due to the Cerenkov effect is more pronounced in heavy flint glass, than In crown glass. This effect is not temperature dependent. The con-! tribution of type b) luminescence is negligible, compared to the other three types. I The effects of tomperature, phosphorescence, effects of glass darkening (due to irra- diation), and glass structure on radioluminescence are also discussed. The spectral output.curves for luminescence of various types of glass are given. Orig. art. has: 4 figures, I table. (141 SUB COM: 20,11/ SLMN DATE: 27Kay65/ ORIG REF: 002 / ATD PRESS: ./P c.,d 2/2 MA, L 40809-66 E'~1T(m)/T/-Pv1P(j IJP(C) VW/RM ACC NR1 AP6025590 'SOURCE CODEs AUTHORS: 1 ORG: none TITLEt Preparative method for gilicon-containing hydrognothaylphosphona 12V No. 18~'Q(77\1; - . SOURCit lzobroteniya, pronyshlenMye obrastsy,, tovarW's zn'aki,' no. 13, 14 TOPIC TAGS: Vda - me = hWphosphonic. ad &T ABS This Author Certificate presents a method for reparing silicon. containing (hydroxymthyl)phosphonates. (Hydro3wnetbarilphosphonic acid vith-organo(alkozy)silanes at 40-MOC. ,.-SM COEEt 07/ SUBM DAM 28DecW ATD PIMSS:,5-0 /F Class ,-20 reacted 1043 L 05182 6Z EWT (M) 1 E-WP RM ACX NR% AFIVUU14Z SOURCE CODE: UR/0079/66/036/005/0920/092., GUbV. t. Fe VMDIKk. L. N.p leniam# IInstitute of the TijrtIje'qA LIght Industry U,.R*. Kjr0V (LOrAlngradskiy inatitut to-kstillnoy I leg*oy Prow7ehl-ennosti) J, "Bia(triorgmUlsilyl)phosphites'- Moscow, Zhurnal Obahchey Khimiij, Vol 36, No 5p 1966, PP 920-923 Abitract: Two nev methods were developed for synthesizing bis(triorganylsilyi). phosphiteep based on the reaction of phosphorous acid with hexaalkyldisiloxanee and triorgmylacetOXY811nnes. 5-Bia(triorgwWlsilyl)-phosphites vare synthe- ,sized; among them ble(dimethylethylsilyl) phosphite and bie(dimethyllphanylsilyl);', phosphite were prepared for the first time. The bis(triorganylellyl)phosphites cqlo~less liquIAB with a weak silanol odor,, stable In dry air and readily hydrolyzed by vater to form the original phosphorous acid 9M trIorganylsilao nols'. The Uttwx wm - umlly.dehydrated to f or& heimornmWe9moms Orig. art. has:' 2 formulas and I table. 1JPRS1 .37,0273- 70;1C TAGSI'falloxane, organic phosphorus compound SUB CODES, 07 SUBM DATE% 2lApr65 ORIG REFs 007 / OTH REFS 001 1 Card ymb. UWt 546,287 f ;t7 6911 L 046'~0-4" ~--rp 11 ) /F~-,rr! r N, - - . 11 ~'. "I", F6M ACC Nk~__AWOOOZ37 SOURCE CODE: UPd0079/66/036/004/0699/0704 a;. /j AUTHOR: Orloy *.J.11leshkevich V. P. ORG: LenfRM TRBZSUW~-~~~aw Lii4 Industry in. S. M. Kirov (Laningr skiy Instl.tut tekstUrn-oy- i :Leikoy F-om-y-aMennostl) -TrTLE:-Reaotion-- of Hydjroxym6ftlphoi~hinlo Acidvith Trialkyl- aoetox;rsilaneso Synthesis of Eaters of AostoxYmethylphosphinic Aold Mosoows Zhurnal Obehchey Rhimil, vol 36, No 4. 1966. pp 699-704 'Abstract: Two new methods of producing esters of ftcetoxFmejhZjm_~_ Phowhinio &c1d1were developed. based on the reaction of hydrom zYmethylpEo-9-phifto sold with trialkylacetoxysilanes %ind acetic Anhydride, an well as that of eaters or trialikoxyallyloxymethylm ,phosphinic solds with acetic anhydride In the presence of catalytic amounts of sulfuric acid. The reactivity of various silicon-oontairAng derivatives of hydroxymethyl~hosphlnlc acid with aoetlo anhydride was studied, and a scheme of the mechanism of their Interaction was proposed, Under the same conditionst the SI-O-C group is quantitatively oleaved, the 81-0-P group Is oleaTed -by on)z_Z5j3$&._XhXlq. the C-O-P group remains Inert Orig. art. has: 2 formulas and I table. [JPRS: 37,17?1 TAGS: anic synthetic silane -'stqrificationv- hosp I Ic acid or -process QV5 11W9%RM14Q'x OQ4 SWO CODEs 07 / SUBM WkTts &H RUt 7 L 06502-67 jrP(j)/WT m) 7 ___p AR NR, AF1 0 75 -SOURCE-CODE i--M/0079/66/036/OC)6/1075/10781 MILESHKWICH, V. VAYRRG V. M., Leningrad Institute of the OFJOV N. F _- j Te_xT11e___-a Inoy an -4&t Industry im. S. M -Kirov (LeRngradskiy institut tekstil :1 legkoy promyshlennosti) "Synthesis of Owanosilicon Esters of AlDha- and Beta-Chloroalkyi(aryl). phosphinic Acids. Interaction of Bia(trialkyloilyl)chloromethyl- --plo-sphinaies with godium Triethylsilanolate" Moscow, Zhurnal Cbshchey Khimii, Vol 36, No 6, 1966, pp 1075-1078 IAbstract: A method was developed for producing new bis(trialkylBilyl) esters of chloromethyl-, beta-chloroethyl-, and alpha-chlorobenzylphorphinic acids. They were synthesized by the reaction of d-ichlorides of the corresponding chloroalkylphosphinic acids with trialkylacetoxysilanes under conditions of continuous distillation of the acetylehloride formed. In the reaction of sodium triethylsilanolate with bii3(trialkylsilyl)chloromethylphoi3phinates, hexaalkyldisiloxaDes and sodium salts of triallWIsilyl eaters of chloromethyl- phosphinic acid were formed. The reaction mechanism deduced indicates a sub- stantial sensitivity of the P-0-Si group to the action of nucleophilic agents. Orig. art. has: 1 formLa and- 1 t6le._ 1JFRS: 37,0231 TOPIC TAGS: organosilicon compound, ester, organic synthetic process, phosphinic acids SUB CODE: 07 / SUBM DATE: 06Feb65 / CRIG REr: 003 / OTH REF: 004 1r, X-E, 547-419 L MI84-2 --f ACC NRt AP7000740 ~rd"IZCZ CODE: UR/0079/66/036/005/0892/0895 0=V6 NO-F-O.A KUMMMICH, V. P., Leningrad Institute of the Textile and Mght_lndustE~ imerd G. M. Kirov (Loningradskiy institut tekstillnoy i logkoy promyshlennosti) % with Trialkylst~We Interaction of lkydroxyzwthylphoophinic Acid Hydrides" Moncovo Zhurnal Obahchey Khimil, Vol 36, No 5, 1966, pp 892-895 'Abstract: In ak previous communication the authors reported o~ the synthoeia of 'A ;.6is(triar ghnosil _Y1) triorganosil~2~thylphos ElAmatealby the reaction of hy&o- xymthylp hos phinic acid with triorganosilane ikeelin the presence of a ' I t was -catal"t. In a further otudy of the side reactions , i . -found that the reaction of hydroxyvethylphosphinic', acid with trialkyloilaw hydrides.results in the formation not only of tiio(trialkyll3ilyl)trialkyloiloxy- -netbylphosphInates, but also 0-tri&lkvlailyl-O-Lbia(trialkylsilyl)phosphone- metilylltrialkyloiloxymthvliDhosubinates. -Rj3ew class of compoLinds. A reaction fjpRS: 37,023 TOPIC TAGS: silane, phosphinic acidg or.-anic synthetic process SM CODE: 07 sm DATE: 2&jan65 ORIG REM 009 OTH REF: 001 N& 54 Cord 1/1. vmb UDC*_ 7 547 Z412MQE TOPIC TAGS: Phosphorous acid, silane SUB CODE: 07 SUBM DATE: 20Dec65 ORIG REF: 003 + ir'A MUM ACC NFItAFW35666 Aj SOURCE CODE; li-R/0413/6~/000/C)19/0032/OC)32 'INVENTOR: Orlov, N. F.; Viktorov, 0. F. ORG: none TITLE: Preparation of dialk,rl-l-(3-chloro-2-hydroxphropyl) hydroxmethyl! i phosphinates. Class 12, No. 186474 (announced by Leningrad Institute of Ithe Textile and LiGht Industry " S. 14. Kirov (Leningradoicly lnotitu-~ tokfitillnoy I legkoy promyishlennoBtl)) SOURCE: Izobreteniya, promyBhlennyye obraztsy, tovarnyye zn-ki, no. 7-91 ~1966, 32 TOPIC TAGS: e%ZDaphosphorus compound, phoophinic acid)ester ABSTRACT: In the proposed method, dialkyl-l- (3-chlo ro-2-hyd roxy p ropy 1) hydroxymethyl phosphinates are obtainod by the reaction of HC1 with dialkylglycidylhydroxymethyl phosphinatas. SUB CODE: 07/ SULM DATE: 23Nov65 Card [PS IWA-50; CBE NO- 14 ACC NRi AP7002970 (A SOURCE CODE: UR/0413/66/000/024/0050/0050 INVENTOR: Orlov,'N. F.; Vol'f, L. A.; Androsova, M. V.; Kirilenko, Yu. K. ;ORG: none TITLE; Preparative method for poly(vinyl alcohol)-based fireproof fibers, films or fabrics. Class 29, No. 189515 SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 24, 1966, 50 .TOPIC TAGS: polyvinyl alcohol, fire resistant material, polymer ,ABSTRACT: An Author Certificate has been issued for a method of preparing poly(vinyl alcohol)-based fireproof fibers, films or fabrics. The method involves treatment of dehydrated fibers, films or fabrics with dialkyl hydrogen phosphites. SUB CODE: ll/ SUBM DATE: 12Jul65/ ATD PRESS: 5112 Card 1/1 UDC: 677.494.744-72:66.093.6 ORWF, N.G. - ~. 2h~ SM-25/100-tYPO walking excavator. DWI. tokh.-alm a. inform. nD.2207-39 059. (MIM 13: 4) (Nxc&v&tiug WChIuW7) CRLCNO N.G., 4,!2zh, Sew development in the technology of mnafacturing welded rr~ils. Zhol.dor.trwwp. 44 no.745-48 JI 162. (MIM 15:8) (Railroads-Raila) GIAZHAN . M.G.; ORLOV, N.G. I kandidut meditainskikh nauk, glawnyi vrach. Study of stable straina of staplkylococci; author's abstract. Zhur.mikro- biol.epid.i immun. no.2:53-54 F '53. (MI-RA 6:5) 1. Bollnitea Imeni Bauman&. (Staphylococcus) ORLOV, N.G.. kandidat moditainakikh nsuk Work organization of district general practitioners In a consolidated city hospital. Sov.tdr#-v. 15 no-501-37 B-0 '56. (KLRA 10:1) 1. Glaynyy vrach Oblyedinennoy bollnitay imani N.I.Baumans v Moskva. (HOSPITAL ADMINIS"rRATION in Russia, work organiz. of GP's in consolidated city hospital) ORMTI-N. Go -- - How functions the United BaumallrHoepital in Moscow. Cesk. sdruvot. 5 to.1:1-6 Jan 57, to laudIdat lskarsk;ych ved, reditel Baunanovy nesocales v No*vs, (RDSPITW United Baumans Romp.. Moscow (Cs)) 0 - I - Information service In mmicipal hospitals and polyclinics. Nod. sestre 16 n0-5:7-10 * 157. (KIRA 10:7) 1. Is GorodLakey bollnitay Iment Baummus, Moskva. (HOSPITALS--NAEAMOMYT AD RNGUIATION) U"V H.G., bmnd.med.nauk (Moskva) Organizing epidemic control work in a polyclinic servicing a specific area. Zdravkoojeder. 2 no.2:19-21 Y 158. (MIRA 11:3) (COMMUNICABIA DISIUSBB) ORLOV. N. G. - - Two-stage treatment of patients in hospitals* Zdrav&'RosOFed9r* 2 no.7ta-12 J1158 (Mn-U 1117) 1. GlevW wMeh belenitsy in. Bacumana. Moskva. (HOSPrTALS) -ORLOV p-NXt.-(tfoskva) Experience in expert temporary disability evaluation in the polyclinic. Say. zdrav. 19 no. 408-42 160. (KH.A 13:10) 1. Iz bollnitey imeni Baumana. (DISABILITY EVALUATION) ORLOV, n. G. Dai.ly dispensary. Zdrav. RoB. Feder. 5 no-50-5 My ,61. (MM 144: 5) l.Glavnyy vraoh bollnitsy imeni N.E.Baumam . Moskva. (MOSGOWS--IIOSPITAIS-OUPATIENT SERVICES) ORLOV $ N.G. (Moskva) Kliminating lines in registering at the polyclinic. Sov. z~irav. 2~- no.9:30-31+.161. (HI~LA 1l+:12) 1. Glavny-I vrach bollnitsy imeni Bawaana. (MEDICAL CARE) CIUVO N.G. (Moskva) Reorganization of the vork. of a polyclinic under rjwr conditions. Sav. zdrav. 20 no.12:52-56 161. WIPU~ 15:6) 1. Gl-nvnyy vrach Bollnitsy imeni P.E. Bamana. (HOSPITAIS-AD14INISTRATION) ORLOV N.G. ----- A day clinic for poptle ulcer patients. Bov.sdraw, 21 no-8slO-13 062o (KMA 15:11) 1. Glavnyy vrach bollnitay imeni N.E.Bmumana,, Mcookwa. (PEPrIC ULCER) (HOSPITALS-OUTPATIEW SERVICES) URTIYEV, Viktor Petrovich; LURIYE, Vitolld Samarlyevich; ISAYEV, kl1bert Semewvich;-ORIDVI Nikolay Illicb;, TSYPLUKHIN, Petr Gavrilovich; SOKOLOV, A.N., red.; SHILLING, V.A., red.izd-va; EELOGUROVA, I.A., tekhn. red. -- (Vacuum are furnace]Dugo~aia vakuumnaia pech'. Leningrad, 1962. 25 P. (Leningradskii dom nauchno-tokhnicheskoi propagandy. ob- men peredovym opytom. Seriia: Liteinoe proizvodstvo, no.5) (MIRA 16:2) (Electric furnaces) (Vacu" metallurgy) 86-11-26/31 AUTHOR: Orlov, N. I., Col TITLE: The Practice Bomb Should be Modified (Prakticheakuy-u bombu aleduyet modernizirovat') PERIODICAL: Vestnik Vozdushnogo Flota, 1957, Nr 11, p. 84 (USSR) ABSTRACT: The author states that the practice bomb used at the present time for training navigators is inadequate, because with the aid of those optical devices and radar with which the bombing grounds are equipped, it is not always possible to obtain the precise fixes of the impacts of practice bombs. The author stiggests that the present practice bomb be mDdified or a now bomb designed. The author gives some details concerning ~he design of such a bomb. AVAIIABLE: Library of Congress Card 1/1 25025 S/05 61/031/007/006/021 B108YB209 AUTHORS: Golant, V. Ye., IOrlov, V. I., Pakhomov, L. P. TITLE: Production of a high-density plasma by a hot-cathode dis- charge in a magnetic field PERIODICAL: Zhurnal tokhnicheskoy fiziki, v. 31, no. 7, 1961, 797-801 TEXT: The authors present the results of an investigation of a hat-cathod discharge in a magnetic field. In such a discharge with a -urrent density,- of over 3 a/cm 2 in w-, inhomogeneous magnetic field (H/H c > 3 1 5;H-m4gnetic; field strength in the region under examination, H. - magnetic field str-e%th near the cathode) a plasma concentration of over 1014 cm-3 may be attained theoretically. It was the aim of the present investigation to determitie the concentration of charged particles in such a plasaia. The emitting atea 2, ~mperature over on the loop- or ring-shaped cathode was 1.5 cm its te 20000C, The distance between the tungsten anode and cathode was 25 cm. The measurements were made in both a homogeneous and an inhomogeneous maE.- Card 1/~ ORLOV, N. 1. Magnetic ore deposits and snow cover. Prirods 52 no.l,.IU 163. (MM 1611) 1. Institut geografil AN SM, Moskva. (Kursk Magnetic Anomly-Snow) Orlov, R.I. (Hoskva) ancrwatomo. Priroda 52 no.2tl27-la 163e (KMA 16t2) (Mizzarda) ORLOV N-1.1 glavnyy veterinwnVy vrach Bugullminskogo rayon&, Tatarskoy ummmmm. V.P. Prophylactic effoct of hemosporikin. Voterinarlia 30 no-11:58 N '5). MRA 6-.11) 1. Glavmyy fel'daher teentrallnogo soovetuchaetka. Dugullminskogo rayona. (for larmysheehkin). GROYSMAt', B.A., ORLOV;._J.,l. Acttpamy--o8i n --,f T~,e :-,bLrjTAT-y gland. 7Aravookhrant-nie 1. nr;.3 -, 5-7 My-je'6,1 . OATRA 1. 1z khiru-,gicheskogc, (zav.MJ~Voynova)rayonnov bol nitzy g,Orgeye~v-a (glavryy wra~;n M.A.Bagmanyam), (ACTIMMMOSIS) (MAISIARY CdMDS) -9 goo 0 9 4 a * 0 * 0 0 6 * 0 f 0 a 0 0 * a # 0 00 I I 0, a al a u 14 1$ Is I? a Is SO a a it a of 4 63 al it X i - A~ b--L- A 0 A , , too 4 1- go a iY_ 0 I. Ism"-r! "M sw wmemb A- N. & C - . W O in", KskAWW-41worlpi -lidAk"Ski k l N .00 got . . aw . Tumba pOm. &p. JWS. No. 5. W PP--Tht &WMOOV ttst "W ,itamnim A is not OP. Us fluAnt - OW vWu as M Prr"mhwy tocnic. The HaRNI-1 isnOt ft'Wtivt goal. ICU is vulq4v, mm. The 9b" simsd AsC6 coMb kw ckWmtric Imt,. m presuibed in the Mormscoptilk. We convenitnt eww"tim al fi2b.fiver one. amd way br nrrd rox fi . r App an when a laviboW finloull cl is not oli.. F. Smith see a di- Zoo 00 coo 00 goo 00 800 q0 0 so 0 ILA BETALL &5 USIGIC&L LIT90AINS9 CLASSWICST101, 00 8. 4 Ito* %*maps .4 goo., 410.1 . 9.1043 .10 0.1 cat -i-SAIllm 4~._Asl 0 60 0 a 0 1 W Is 9 A a 0. .1 OT Air-we -ell a -2 d" i0 & 0 0 v a 0 0 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 4119 0 0000 0 o 00 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0 0 0 a 0 0 0 0 0 0 0 a 0 0 0 0 0 0 10 11 it m is to it a to A A a a 0 J. 10 10 IS &I owl) mono M _A%X Witt I.P ..v _--]u 00 -A Ott .,.r, jkp 060101 Abe in 18~6,,P_ W-11111% aad ift 04 ;MV- m m -00 , W auk=". V. P. zeta" OW N. i i 00 a, ts wen Piummlys 4. No. 5. 40-55(103). -Analywo we a food 11, beg Shme . I wom dimmovertmil. Sol h to i s - t the SW"M of the ail. j. wdke ed. Za -- 00 toll. gwr Its- of prodw, tOOD noom vwiod Imm 400 to mumbrallommemopec"y rich in zinc. 2pscin of rumalavomme km ruietions in zu content troll- of phat naterial. 50 to MID me. per ka - of drY wt - F. If. itsibmann 400 coo we a zoo 00 4r ~* 0 0 ' I bu a w Ai a n V II I I a ad a 1 0 j At a 4 I d,13 " o w a 00 IT It 0 00 0 ill 00000 00 0 0 0 00004 0 If It So, of as I.AL I!- u T -i- - -0 ll, see ti plift1tall,1111 AMP 0#0410#01011 M"p V~ ~ I - - (0, 41W rr) In he* OW prac~d mumbraiiiiiiiiii. X I OrlDv I A Srib- rwv. .4.11)1-23119W- If, its, 11 weiri cat nvuhhormornit agnsairr"I attar vitasssin it. -.t,w hAt (14 WISVIF ~ YVAII (W .11 (1-t- I %-'ITI 1%, %,t,t XMItal" CIN 4114-1 ZIS, A 1141`11-111 f 1-filln tao-mveraw Zia i4nd flar vil.tatim - -of#, fit fit Ifilff'rivne sipevit, isroldiffmvit turt- n! Off, -its, mu.hr-i, Ito, vitamin "woorm, III ittrint sim,hravotaxi, ~Sf .I,. ~f file -00 -00 0 00 00 0.0 *0 11111.111,14#111 foorts. 1"Ist-T 111"If fit,- All, It CAMIC01% off wiliIIIIIII I'll 'IS to ifftlh Coo too !~TALILrfif!CAL LI &AAILQ# CLASWK00011 a, as -1 111141s. siv,sikl- so"" a Its a 0 'T 0T! -0411461* goiIIII 6 0 0 * see a 411190 20 114 Sao., 00"Smy e& lab Vne .0 * 0 0 0 0 0 0 6 0 0 0 0 0 o1 professor Problems in the hygiene of nutrition at the Thirteenth Congress of Hygienists, Spidemiologists, Microbiologists and Specialists in Infectious Diseases [with summary in Inglish). Gig. i san. 22 no.3:7-12 Mr 157. (MLRA 10:6) (IMITION) CHLOV, N. I., Doe. Med. Sci. Dissertation; "Fungi,, Mushroom Poisonings and Their Prophylaxis." Central Inst. for Advanced Training of Physicians." 6 May h7. SO: Vechernyaya Moskva, May 1947 (Project #17836) olu 0v, 1". 1. 20636 Orlov, N.I. K pyatilesyatiletyu zaslijz', ennof-a -jeynteya na,.ki Kazek., --P y pespul-liki, doktora bin ogicheskikh naA, professnra Tselis, el.eva Arkadiya Andlrx--,.-evic-n. IzvestJya Akad. nauk Kaza~,h SSR. No. 44, Seriya parazitol., vyp. 6, 194p, s. 1-2 SO: LITOFIS ~HUFIiAl ~--TATFY - Vol . 28, ;"Ioskva, 194c, ORIOVI ~. 1. 20637 Orlov, N.I. Spetsifichno-t i nfjtogenn,~sl pros teysl-.i Irl. v svete proi-lemy vzaimo,-)tnosheniy parazita I knozyaina. Izvestiyt, Akad. nau), KaznkY. 331i, Nc). 44, Weriya parazitol., vyT,. 6, IQ48, s. 3-18.-Rezyu,e na Ka7ak~. yaz. SD: IFTOPIS Z!IUEiAL O'TAT*,Y - Vol. 118f ',Ioskvnt 1949 ORLOV, N.I. USSHMedicine - Food Poisoning Nov 52 DReviev of monograph Food Poisoning and Its Prophylaxis,8 by N.I. Orlov, Library of the Practicing Physician, Medgiz, 1952, 119 pp, 25,000 copies," (Yu. A. Koz1ov, reviewer) Gig i San, No 11, pp 60, 61 Lauds the clear and concise style of the author and the up-to-date presentation of information on food poisoning of bacterial and nonbacterial origin. Objects to the brief treatment of Salmonella organisms and of their pathogenicity in producing toxic infections. Considers that too little space is allocated to a discussion of Sonne Dysentery bacilli as Originators of toxic food infections, and does not quite agree with the author's treatment of the symtomatology and pathogenesis of toxic infections caused by Sonne bacilli. Source #264T35 ONLOT, Wilmlay Ivanovich. Idible and poisonous mushrooms; mushroon poisoning and Its prophylaxis. Moskva, Medgiz, 1953. 269 p. Pitlioteks praktichookogo vrecha (53-40396) RUZ42.M907 ORkO V, ff..T Subject Card 1/2 USSR/Medicine Pub. 37 - 10/22 ATD P - 2168 Authors Belostotskaya, Ye. M., Beryushev, K. G., Kands. of Med. Sci., Orlov, Ji I., Dr. of Med. Sci., Fcngauz, M. I., Kand. of M-e-d. '"Ci., and Cherkinskiy, S. N., Doc. of Med. Soi. Title J?rom the practical work of the Scientific Research Sani- tary Institute im. Erisman in the introduction of physio- logical methods in investigations of hygiene Periodical Gig. I san., 4, 40-43, Ap 1955 Abstract The purpose of this article is to explain the work of the Institute in the light of I. F. Favlov's theories and his analytical approach to observed phenomena. The reactions of the organism are studied in relation to the changes in its environment, climatic, atmospheric industrial conditions, etc. The article is illustrated by many examples, observations of human beings and tests performed on animals. 10 Russian references (1951-1954). AID P - 2168 Oig. i san., 4, 40-43, Ap 1955 Card 2/2 Pub. 37 - 10/22 Institution : Scientific Research Sanitary Institute im. Erisman Submitted t My 10, 1954 eigla-A&L".&KOf essor Mushroom, 7dorovIe 3 no.8:9 Ag 157. (MIRA 10: 9) (MUSMMS) ORW YAJ6J,tOWoskv&) control and ezamination of food products before the Revolution; 1891-1917.- Vop.pit. 16 no.6:70-7~ Y-D '57. (MMITION, (MIRA 11:3) manit. control in pro-revolutionary RUBBia (RUB)) ORLOV. N.I., prof. Achievements in some arose of food hygiene in the U.S.S.R. during the last 40 years. Gig. I son. 22 no.10:57-66 0 '57. (MIRA 10:12) (FOOD hygiene, in food indust. & prep., hiet. in Russia) ORWY, Nikolay Ivanovich Clkshroome] 0 gribakh. No8kvG, Instittut senitarnago proavesbcheniia, 1958. 109 p - (Mushrooms) (MIRA 11:11) CM=, I*Igs prof . ,..-~--4ood hygiene.' Gig. i man. 23 no.8t86-87 Ag '58 (MM 11:9) 04,W- (FOOD RMLING) / zlr, ORWV, N. I.. U. ~. "Modern Prot-lems of HyL-iene of Nutrition. Correspundir.E-member of the Acad Red 3ci U-";M-." report submitted at the 13th 1~11-Ll~on Congress of hygienists, EjAdemioio, ists and Infectionists, 1959. ORWV, N.I., PXO. (Moskva) Decisions of the 21st Gongress of the MW on the oroblem of nutritional hygiene. Gig. i san. 24 no.4:3-7 Ap '59. (KEIRA 12:7) (PODD, hyg. in %Issia (Ras)) ORLOV, N.I., prof. (Moskva) Fifth International Congress on Nutrition in Vashington. Gig. j- san. 26 no-4:86-91 Ap(161. (MIRA 15:5) NUTRITION-CONGFZSSES) SHILLr-R--VOlKOVk, N-N.; r,0lCflPJAp T.P.; NE-~--SKAYAI Ye.A.; TF'jllSY,AYA, F-E-DORTIA, F.A.; MIYA5111LENA, O.F. Experie~r.,!- 4-n 'tie unn~, of cyt3logiv mothodr in preventive ~xaminatlons of women. Aixsh. *,- g1n. 1.0 rio,64171-74 -r.-Ag (MIRA 1824) 1. Goao,'Jarstvormyy on~,?.loglchoakly Institut imeril Gertsena (dir. - prof. A.N.N,--,rikov).v Moskva L Rodilvnyy dom (gl.avnyy vrach I.V. I,p 11. T. -4, ~f - -, , , 0 ~~q 7"4 Z. P, h Clec4r1mg ~nj;r r-~atfcr-~ rn a -. -~w, , - J'fl XTRA 3.8:8) rio. 6171-7~ W-6. 14,50 ORIDV, N.X. 0 (Kiyov); CHMMENKO, A.Te., Wyev) -% WININNOWASK On the possibility of eliminating circular hauls on the road. Zbel. dor. tranap. 38 no.8:45-48 Ag '56. maA 9:1o) 1. Zameatitell nachallatim Yugo-Zapadnoy dorogi (for Orlov) 2. Naeballnik sektora finansovogo otdola (for Cherepanko). (Railroads-Aanagement) CRIDV. N.I., inzh.; CH9R=jMD, A.Ye., Inth. -- - I Opportunities for reducing car rerouting on the Southwestern railroad. Zhel. dor. transp. 40 no.3:36-39 Mr '58. (MIU 11:4) (Russia, Southern-Railroads--Traffic) ORLOV, N.L. "- (FIF-sults of the rough draft method of laying out *hips] Opyt eskisnogo metoda rasmetki sudovykh konstruktoli. [Leningrad) Gos.Isd-To sudoetrolt. lit-ry, 1953. 46 p. (KESA 7:6) (Shipbuilding) P0KIUSHICMIK0,, Valentin Fedorovich; KRUPHENK01, leygenly Ivanovich; ORIM., N.L., plazvVy r -, tcb&,- retgenwnt; SUMOV, A.I., W-Voi-enzent; KOZO==; V.Sp. 2=81M7 r"61 BOWAIMN) OoA*ptr"*; FRUMMv P.Se, tekhn, reds [Manu;l of a mold loft-sman] Spravoebtft rabDchego- plazovshcbika. laningrad,, Sadprongiz, 1961. 200 p. WIRA 15:3) (Shipbuilding) ZEFIROV, Igor' Vasiltyevi~-h; NIKOEOV, Sergey Nikolayevich; PANKRATOV, Vladimir Petrovich; rabochiy- razmetchik, retsenzent; RIMM, A.I.r ini~, retsenzent; SHAKHOV, A.I., inzh., nauchn. red.; LISOK, E.I., red. (Laying off in shiptruilding] Sudovaia ram~etka. Leningrad, Sudostroenie, 1965. 411 P. (MIRA 18:8) ZGIRSKIY. Ch.l.; GUTW. I.H.. inzhener, rateentent; doteent; STUDNITSYN. B.P., redaktor; IXJGINA, NA., takhOcTeMsEMaktor. [Repair of tractor parts] Vosstanovlenie detalei traktorov. Hoskra, Goa. nauchno-takhn. i2d-vo mashinostroltallnoi lit-r7, 1954. 119 p (Tractors) (KMA 8,.4; YERAKHTIN, Dmitriy Dmitriyevich,, dote., kand. tekhn. nauk; GOKHKAN, Shlema Molveyevichp kaDd. tekhn. nauk; DVINYAIIINOV, Vistor Nikoluyevich,, at. prepodavatell; ZAYTSEV, Pavel Alekseyevich, inzh.; LOPATM, Anton Vemediktovich, dote.; SLR~~~ Mikbaylovich,lwh.; STRATANOVICH, Nikolay Nikolayevich, inzh.; RMINGWOV, Nikolay Ipatlyevichs insh.; TIKHONOV, Nikolay Prokoplyevich, dotoop kand, toklm, nauk; RAYKHUN# Ullman Tanfilovich,, at. prepodavatell; BELOV, Alskeandr Yemelluovich, dots.; RESHMIKDV, N.S., dotsent, retsenzent; BAWMIN, I.N., red.; PITEMM, Ye.1f., red.isd-va; PARAMNAp W.L.p tekbn. red. (Rapdr,or lwdwrtw-md fmvvtry machinery) Remong lewzmgoto- vitelliWkb i leaokhoziaIatv9mWkh masUn. By D.D.Erakhtin i dr. Mo&va,, GooleebmiMatp 1961. 436 p. (MIRA 15:2) 1. Kafedra remonts Moskovskogo lesotekbnicheskogo instituta (for Reshet-nikov). (Forests and forestry-Equipment and supplies) (Lumbering-Machinery)