SCIENTIFIC ABSTRACT ORDELT, Z. - ORDYAN, M.B.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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8/08 11621000101 6/0~x2,/C4 31
B1 68/B1 a 6
AUTKRS: Ordelt, Qld~ich, Holomek, Josef
TITLE: 1. mcthoo --rI :n'~Iding under pressure
PERIODICAL: Referativ%yy zhurnal. Khimiya, no. 16, 1962, 542, abntract
16P211 ~Czt~chosl. patent 94306, March 15, 1960)
TEXT- Th~ --hod :s -d:,;t1r.Cuiehed by the fact that, in order to MFrove
the homogenization of the melted polymer and to raise the output of the
molding maclfune, the finished melted polymer is fed dixectly from the
polymerizinC unit or from a separate melter into the cylinder of the
machine. iAbstracter's note: Complete trani3lation.]
Card 1/1
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OP DEW I Z .
" Polyesters. (To be cortd.)," p. 182.
(Chericky Pri=,Ysi, tol-3, Nc-5, MSay 1953, Praha.)
SO: Monthly List of Fast Europear V01.2, No.9 _ __12p mber 1,;53, Uncl.
- ~~ Accessions,/Library of Congress, tembe_
OPJ)FLT.9 Z.
Problems regarding controversial views within the scope of research tasks
P. 380
Vol - 5, no. 6, Aug. 1955
ZA SOCIALTSTICNOU VFDU A TFCTINTKU
Praha
SOt Monthly List of East European Accessions, (EFAL), LC, Vol. 5, no. 2
February 1956
cR -L1
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Vel f IC C,
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PrahL Cz choslovakia
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Z /009/E 110001012 /00
E112/F953
AUTHORS: OrdeLt,-ZdLn9-k and Ciga'nek, Prantisek
TITLE: Contribution to the polycondensation mechanism o"
1,2-cyclohexanediol with phthalic anhydride
PhE I OD I CA L: ""hem i c k- 11 Dr5mysl, no.1,1, 1961, 669-671
Y
TEXT: The react'on of cyclohexanediol with maleic
anhydride was described in a previous paper \"Ref.l: Ordelt Z.,
Chem.pram.10, 35, 663, 1960), where it was shown that, during
condensation, the diol was catalytically dehydrated. In additan.E,
the reaction mechanism was obscured by possible reactions with --h(-
double bond of the maleic or fumaric acids. it was felt by the
authors that the use of phthalic anhydride would produce less
ambiguous results. it is now shown that the polycondensation witn
phthalic anhydride proceeds, because of steric hindrances, at onl~,-
r,z-;If the rate of that of maleic anhydride. During the reactior,..
Jehydration of the 1,2-cyclohexanediol takes place, the rate of
which at temneratures above 200oC, considerably exceeds the de-
hydration of the maleic resin. Best reaction condittions are
and a 15 to 20% molar excess of the diol. A portion of the
"ard 1/3
Ir
fontribution to thr- noly...
(IehydratiDn ~Iroducts remains in the resin, their concentratIo-
'n-reasing with rise of te.,riperature. TT1Urea.-,e of teiaperaLUT'~,
~,ouses increase in the molel-ular weiFht or the resin. It wa~~
(-;-,tAlishe-i that th~-- rpFin rontainf~d -,omf- polywor~(-. Materia.
w t hout ( arbory-, :',;n -,~ wnich wa,,.-. to b(~ a poly.~~;
1 . 2;-cyclohexajiene . Tn- resin produc-d froin phthalic anh-vdr-.
arA i,2-cyclohexanediol at 2000C is a brittle, transparent,
!3lightiy yellowish substance. Condensations at higher tempera-.-
i.r,s produ('e a brownish material. In principle, no basic d-f'.,', -erL-.
were detected betweon maleic and phtna-1 ic anhydride, w;ltn
t,x- eption of rat- of' r-i~tion and a-idit~ons on to the double
bori -.s of male arhy-J r, ie. ~xpt-r~m-~!itall details follow the
L
ard "15
Contribution to the poly ... Z/009/01/0')0/012/005/0c~'
E112/E'j'~,3
previous paper. There are 3 figures, 2 tables and 4 referenr-:-,
2 Soviet-bloc and 2 non-O'-'oviet-bloc. The FnF,Jish-lan5uage
references read as follow-3: Pef.3: US pat. 2 LA5 ?58 '18.7.
Ref.4: Fohle D.W., Nle!,.1-~-.hacker C. V. a Cook H., Oil a. Soap,
115 (1945).
ASSOCIATTON: Vjizkumn~ UT~Aav s~YrAet',-.,,.fcn pry:-,-,yY-ic a lake,
Pardubice
(Research Institute for S.-?-nthetic Pesi.ns and ?ain*,.,1--.
Pardubice)
SUBMITTED: February 11), 1%1
Ll
Card 3/3
OMLIT, Z. [Ordelt, Z.1
Structure of unsattxated polyesters and the mechanism of reactions
taking place during their preparation. Vyskokom.sood. 4 no.7:3-110-1117
J1 162. (MIRA 15:7)
1. Nauchno-issledovatellskiy institut sinteticheskikh smol i
lakov, Pardubitse, Chakhoslovakiya.
(Esters)
(Unsaturated compounds)
5/1)1/62/00 0/007/004 /011
13120144
Zdenek, Gudechek, Zdenek (Pardubice, C~SSR)
-Ordellt,
I?
TITLE: Insatiirbtel polyesters based on cyclotioxanediol-1,2
,:~ 7' 1 1 - 7, 1962, 20-23
. -.11 C, D I ~ ~, ~ ,lrl~~jz~t i c,.c --,:,'Lye rra2sy, no
TEXT : The most iz, )ort,.nt 'actor in the pol.,condenoation of cyclohexunc-
diol-I 2 (CHD-1 2) Yith -,a'eic anhydride (MA) is the temperature, since
this increases '.'he rate of polyesterification as well as the jenyJration
rate of the diol. The optir.-jum temperature lies between 1)0 and 2100C.
At that temperatore, t'ne polyesterification proceeds rather quickly and
the total loss in JH CroupG is about 10~"o of the initial Off groups. The
reaction time requirei is 6-8 hr. The reaction products were distilled
tith water vapor; besides traces of cycloliexadiene-113 (CH-1,5), the
distillate contained cyclohexanone and cyclopentyl formaldehyde. The
total loss in 0.11 Croups in the initial CHD-1,2 is 25-30%0 the loaS in
weight only amountinC, to 2-4%. The resulting C11-1,3 reacts immediate-ly
with the maleic or fumaric acid component to give a 3,6-endoethylene-
1,2,3,6-tetrahydrophthalic acid compound which ia the most important
Card 1/3
5/11~11'62/0-)0/007/004/01 I
i7ns~.Lur a' ed )'-ye .; te r~; i.ase I on . . . B124/BI44
b r 1 e ',-j -,:.e ",'- -h content of cyclic com,-,ouriis owint, to
c-.,is(.- '.e::.per~ture chan,,*eB. 71her, the eLllylene I'l-col Is
~,:D- I in the usual polyenter for J-jasa-re inforced
10 0 necnanif- .)roperties, particularly harlneas an] hent
re.jistance ~,re -mucIh re luce I . This can be avoided by usinf., an aliphatic
licarboxylic acid in~3*1e~,,' of -,art of PA. There are 2 figures and 3 tables.
'2h e En..- I i s h - 1 -~ n,:u,..- e r e f e r e n c e i a :V. F. Jenkins et al., J. Oil a. Colo'Ir
Chem. Assoc. 44, 42 \'1)51).
Card
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103 -:~Z FWTr.)/,9jP(e)__ - WH
A-CC- NFUj AP60315c" ()v SOURCE CODE: UR/0226/66/ooo/oo8/o1oi/0105
AMNOR: Samson~v, G. V.; Vitr-yanyuk, V. K.; Ordenko, V. B.
ORG- Kiev Polytechnical Institute (Kievskiy p litekhnicheskiy institut)
TITLE: Prepari;`,)n of hiehly porous materials from refractory compoundn,
SOURCE: Poros~ -aya metallurgiya, no. 8, 196~, 101-105
TOP! C TAGZ: p(:--us materii.-1, rerractoty inetal, refractory metal compound, refractory
metal carbido, 'ract 01- tieta.1. boride, refractory metal Gilicide, oxide re,11-iction,
n) 7r^
ABSTRACT: T)h equthors inve:;tigated the possibility of obtaining high-pc,~rosi'~y
proaucts from r-rbides, sil.cides and borides of refractory metalu t,y re-ductlc% of
oxides with sir taneous sirtering of the obtained active particles of cormpeunis,
during which tY~ volatile prDducts of reduction, such as CO, 1'202 and Sio, escale.
Conditions wer( --tabliscied -or the preparation of high-porosity articles (up to
70-72% porosit.- from.chrom..um carbide b_~ reduction of chromium oxide with carbcn.
7
black and simultaneousu';-Intering. Origiiart. has: 2 figures and 2 tables.
SUD CODE: 11, 13/ SUBM DATE: 06Apr66/ oRiG nEF: Oll/ 0111 REF: 001
Card
14- 57-6-124 17
Translation from: Refera tivn zhurnal, Geograflya, 1957, Nr 6,
p 99 (TJBSRTY
AUTHOR: Ordeval, A. P_.j Kubota, Dzh., Smit, Kh. N.
TITLE: Principal Boll Types and Their Relation to Climate
(Glavnyye tipy poahv t ikh ev-yaz' a klimstom)
PERIODICAL: V ab: Merzlotny-ye yavlenlys v gruntakh, Moscow, Izd-vo
In. lit., 1955, pp 9-20
ABSTRACT: Climatic change from north to south produces change in
the solls* Low temperature and alight precipitation
cause the formation of tundra soils. Climatic influ-
once is basically of a physical nature. Both physical
and chemical factors contribute to the formation of
podzol soils. Chernozem is developed in the semiarid
and aem1humid temperate climates. In deserts, cli-
matio influence exhibits itself mainly in the physical
destruction of original materials. Latosols (former-
Card 1/2 1y known as laterites, red laterites, or red clays,
ORDIKHOVSFIT, A.V.
Treatment of azWotrophic lateral sclerosis by means of endoluziliar
Injection of vitamin B12. Vrach.delo no.1011013-1015 0 '59.
(MIRA 13:2)
(SCUROSIS)
(OTANDCOBAI"IIM
30NDART-*-.-P.; ORDIKOVI M. L. and LOPATA, A. A.
4 -
ry~pw /
v
"Ealadka Tokarnykh Avtomatov '. 1!cluavtomatov, " (Mechar-Asms anl '. ' .' _. ,
and Semi-autom tic Lathes), 2;:, , ., Kie-., ar-d Mosccw, 1'~ - -
it ". .
- J ,
~ !z ) , : ~ 1 -
Jb ta in ii ; )f irlanos, iric cu, t,,Ires of )Y M4-.-' - I ' 1 .1. - 57.
Mikro:)' ~)Io iva- v 11 - '-, P. '1 3. 1 -)[~ n .
ORDIV. A. G.
[The air fleet of the land of Soviets] Vosdushnyi flot Strany So-
vetov. Moskva . Pravda, 1948. 34 P. (NIU 7:11)
(Aeronautics)
-r! `Pvlovich
m. 1 r hno. 4' 1~ f 4 j
"Jtlc tr.
Irv, :)ilc-T r~
ec
r:, r. v. 71!
nrochJt-innni v "(!Fkv(-.
-ri (,I' t~--
CIV
r
0'!L)jj~, A. ( Col o ne 1)
1;5:"-11
"Dr- 9 1 ~, no- r o -' *. rip :': - r 1~ A '.' -., 7, - -, 4 - - - '~ W 0 r 1 -' , ~?7--- '~*,
Ciir-evt Dtglest o-- ~~ ~')o-vi-t ?re,~s, '1-1. 2, '.o. l.'. k -- . ( I - IIM ' 4 r r'. - -)
)S,
ORDIN, A. G.
Authw.' Ord'-.ns A.G.
Titlo! lir Force of tho 12,SR
63 pp - s lutat a
Data 1950
subjeett Aeronautics - Rw aU
Availablel Uborw7 of Conlya5s., Mll NR.*, TL526-00M
Sawm: Lib. of Cong. Sub,'. eat., 19P51
I r ; ; , - .
. . I
. .-v ...
ORDIN, A.G.. generpl-mavor aviateli
Vhat was learned from one emergency situatlem. Yest.Vozd.Yl. 41
no.2:3P,40 F '59- (MM~ 12:4)
Might training)
0801010a (AgriCIAItWO) - P3Mt Ikr/AW 52
Dioeam*$
"Ante4mism of ftil rumi or the penicilulm
FWAU fo~ Pbytojathopmic Ucteria," A. P.
Ordia, Wscow Sta, All-Union Inot of Plant Pro-
tection
ONikrobiol" Vol XXI, No 2, pp 192-199
26.3$ of all species of the Penicillium famIll
Gad 3-50 of species of the Asperigillus faully
comterect Bact. aroidae Tovs., Bact. caroto-
(Jones) Burgv., and Bact. vesicatorim
Doidg. All isolated active strains suppress botbL
Bact. aroiseae and Bact.cartovorum (vhich ~t
OM/Siology (Agriculture) - Plant VAr/Aar 52
Diseases (Coutd)
'be regorded as closely related strains of the
sme species), but only 47.7% of them counteract
Sact. Yesicatorium. The antibiotics evolved'b7
penicLUse exert a strong suppressing action an
tbase 3 bacterial species, all of them gram mg,
Indicating that the Gram reaction is not an &U
criterion of the resistance of bacteria to pad-
cL13m antibiotics.
CRDTVt
Tenicil'in
Production of sIngle-spore T-.-nicillin cultures with a dry needle. M, ikrot)ioloVija
21 no. 4, 1952.
Monthl List of Russian Accessi~~ns, Library of Congress, November "9V/
ORDIN, A. P., Cand Biol Sci -- (diss) "Mycoflora of the
rhizosphere of plnnt.s and soils of iW stony steppe."
Mos, 1957. PO pp (Inst of Microbiology, Acad Sci USSR),
120 copies (KL, 1-58, 117)
- 36 -
ORDIN. A.P.
Affect of TOget8tion an the composition of soil microflore. Itv.
AN SSSR. Ser.biol. no.4:495-502 J149 '57. (KLRA 10: 8)
1. Inmtitut mikrobiologii Akademti nauk SiSR
(IIAKINNATA STIM-SOIL MICRO-CRGANISMS)
ORDIN, A.P. ___
Device for-surface grain sterilization. Mikrobiolo iia 31
no.1:158-159 Ja-F 162. %RA 15:3)
(STERIMATION-EQUI RENT AND SUPPLIES)
ACCESSION NR: AP4000450 S/0032/63/029/011/1341/1343
AUTHORS: Cherkez, M. B.; Ordin, V. P.
TITLE: Study of corrosion processes in passivating metals by application of anodic
polarization
SOURCE: Zavodskaya laboratoriya, v. 29, no. 1.1, 1963, 1341-1343
TOPIC TAGS: passivating metal, metal corrosion, passivating metal corrosion,
corrosion study, potentiostatic method, corrosion study potentiostatic method,
anodic polarization, anodic polarization current, E1602 steel corrosion, E1602
steel passivation, passivation potential, E1602 steel passivation potential,
transpassivation potential, E1602 steel transpassivation potential, E1602 steel,
anode current polarization, metal passivation, critical passivation current
density, passivation current density
ABSTRACT: A potentiostatic apparatus was used to study corrosion processes) to
determine the limits of a stable passive state, and to establish the relative
variation in the metal corrosion rate during its transition from an active state
into a stable passive and transpassivation state. The experimental results are
C,,d iA
ACCESSION NRz AP4000450
presented graphically in Figures 1 and 2 on the Enclosures. They represent the
polarization curves (voltage current density) which reflect the variation in the
corrosion process intensity during a gradual metal paBsivation induced by anodic
currents. The density of the anodic polarization current corresponded to the
metal affinity toward passivation. It is shown that polarization curves may be
used for the determination of corrosion velocity, Limits of a stable Waive state,
relative variation of metal corrosion velocity in active and passive states, and
the absolute value of the corrosion rata in the passivation state. Orig. art. hast
4 figures.
ASSOCIATIONt now
SUEMITTED.- 00
SUB COM MM
Card 2/4
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ACCESSION NR: AP40DO450 ENCLOSURE:. 01
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time, min.
time# min.
Fig. 1. Variation of anodic polarization current with timo at
constant electrode potential: steel 1OKP (a) and alloy EI602 (b)
Card 3/4
AccEssim NR AP40oO450
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40-
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ENCLOSURE t 02
Fig. 2. Polarization curves; steel 10KP alectrode'(A) and BI 602
electrode (B)
card 4A
L 01996-67 EWT(1) SCTD DD
ACC NRi AM6023679 Monograph
Ordina, G. P.
T-M
Technology learns from nature; bionics. Recommended review of literature (Tekhnika
uchitsya u prirody; bionika. Rekomendatellriyy obzor literatury) Comp. by G. P.
Ordina, Moscow, Izd-vo "Kniga", 65. 0021 p. (At head of title: Gosudarstvennaya
biblioteka. SSSR imeni V. I. Lenina) Series notet Novoye v nauke i tekhnike, vyp.
12
TOPIC TAGS: bionics, cybernetics, biocybernetics
FMOSE AND COVERAGE: This pamphlet presents a list of articles and books on bionice
and related sciences. Bionics is explained as the study oi processes in living nature
to obtain knowledge applicable to technology and its automation. Nature's processes
are valued because of their dependability, compactness, and efficiency. Prokhorov,
A., "Bionica'V- The Science Born Before Our Eyes," Kommuniet, 1965, No. 4, PP. 46--557-
~-Meyngauz, A., "The Eaigineer and Nature. Bionics. Yihat Is It?" Novyy Mir, 1963, No.
9, pp. 194--210. _Saparina, Ye., V., "What the Jellyfish Are Concealing." Conclusion
by A. 1. Berg. Moscow, "Molodaya gvardiya," 1966. 144 pp. illua. Aotashenkov, P. T.,
'What Is Bion ce." Moscow, Voyenizdat, 1963. 87 PP. illus. (Nauch.-popul. b-ka).
Kr2y=er, L. P., "Bionics." bloscow-Leningrad, Gosenergoizdat, 1962, 72 pp. illus.
Parin, V. V., "Living and Technical Systems," Priroda, 1964, No. 5, pp. 20--25.
Linkovski-y. G. B. and Sa2au, S. I., "Bionics, Its Methods and Results," Priroda,
1964, No. 3, pp. 52--58. Alltov,-G. S., "Paleontology and Bionics," Priroda, '1964,
Card 1.12 -UDC;-016.6.
L o1996-67
ACC NR, A346023679
No. 11, pp. 111-112. Manteyfell, B. P. et al, "The Orientation and Navigation of
Animals. The Most Important Trends in Bionic Research," Priroda, 1965,,NLo. 2, pp.
26--32. Mironov, I., "Not a Templev but a Workshop," Znaniye -- sila, 1964, No. 7,
PP. 14-16. Parin, V. V., "Bionics," Zdorovlye, 1964, No. 1, pp. 9-10. Napalkov,
.A. V. and Chichvarina, h. A., "The Brain and Cybernetics. (Cybernetic keys to
secrets of the brain)," "Znaniye," 1963. 46 pp. illus. Prokhoroy, A. 1.'Tionics."
Foreword by V. V. Parin. Moscow, "Znaniye," 1963. 56 pp. Teplov, L. 'Essays on
Cybernetics. " Moscow, "Moak. rabochiy," 1963, 415 PP. illu8-.-7ffa-p=ar na, Ye. k`yber-
netice Within Us.' Moscow, "Holodaya gvardiya," 1962. 303 pp. illus.
SUB CODEt 06/ SUBM DATEt 1qjul65/ ORIG REF: 015
2/2
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4:,
P. ~o hl -)f Russian Accessions, Library of Congross,
EL__l L i. s tr
ORDINA, N. A.
"The Intercalary Meristem and Its Role in the Ontogenesis of
Wheat." Cand Biol Sci, Inst of BotarW imeni V. L. Komorov, Acad
Sci USSR (Apr-Jun 54). (Vest Ak Nauk, Nov 54)
Survey of Scientific and Technical Dissertations Defended at USSR
Higher Educations Institutions (11)
SOt Sum. No-521, 2 Jun 55
USSR/Plant Dtsca~es - Diseases of Cultivated Plants. o-3
Abs Jour Ref 7hur - Biol., No 7, !j')", 30234
Author Ordina, N.A.
In-Qt Central Scientiftc Rcseu--ch Ins*,'tute of Bast Fiber.
Title The Structural and Ilicrochumical Changes In Flux ",telms
aiLd Fibers in the Presunce )V Fungous Infections.
Orig Fab Nauchno-issled. tr. T7,cr.,r. i-i in-t prom-st': luL.
vol,)kon, 1957, 10, 58-7-'.
Abstract Description is given th(. changes In flax stem und
beaten fiber produced a--. a rc--,;;ult of ~nfectton wit].
Pa.-iarlum lini Boll. and P(ly~jjjr)ra lini Peth.
Card 1/i
1. ORDINA.,O. M.
U33M (6CO)
4. Lungs - Diseases
7. Clinical and anatomical study on modifications in the diaphragm in pulmonary
and cardiac insufficiency. Arkliiv pat. 14, No. 6, 1952.
9. Monthly List of Russian Accessions, Library of Congress, may 1953. Unclassified.
ZIVERT. K.W., prof.; ORDINA. O.M., dots.
Rnre compliention of enrdlospnom twith summnry in English]. KhirurriiA
34 no.l:loq-ll4 JA (MIRA 11:3)
1. Iz knfedry gospitril'noy Lhirurgii (znv.-deyi3tvitel'nyy nh1en
AMY SSSR A.G-Savinvkh) I knfedry patologichenkny anAtomii (Znv.-
prof. I.V.Tor0Dt80V)
(CARDIOSPASM, surgery,
POStOD. aSODhAgenl ulpar nerf. into oulm. vein (RuB)
(PEPTIC ULCXR, nerforntion,
esophageal into nulm. vein nfter cnrdlospnsm Purg. (Rue)
(VEINS. PULMONARY, perf.
by enophngenl ulcer nfter cArdiospeam aurg. (Rua)
.qRM RA, 0,-Mdots.
Some morphological data substantiating the renal origin of so-called
tkypernophromas. Urologiia 24 no.421-26 Ja-F 159. (KMk 12:1)
1. 12 kafedry patologichtskey anstomil (zav. - prof. Ij. Toroptsev)
TomBkogo meditsinskogo instituts.
(KIDN31S, neoplasms
hypernephroma. hiBtogenesis (Rual)
ORDINA, O.M., Itand.med.nauk
Clinical morphological characteristics of sympatho goniona. Pediatriia
37 no.11:50-56 N '59. (KM 13-3)
1. 1z kafedry patologichookoy anatomli (zaveduyushchly - prof. I.V.
Toroptsev) Tomskogo meditsInskogo Instituta.
(NWROBLASTOMA pathology)
ORDINAp O.H.v dotsent; MOSKVIN, V.I.j, doteent
I------
Cancer of the intestines in children, Pediatriia 38 no.12.--6~
160. (MnM 102)
1. Iz kafedry patologicheskoy anatamii (zav. - prof. I.V. Toroptsev)
i kafedry detskoy khinwgii (zav. - prof. I.S. Tengerarskiy)-Tomsko-
go meditsinakogo instituta.
(CECUM--CAVCER)
VIZOVSKAYA, G.L.;- ORDIVA, 0.1-1. Obmek)
Pheochramocytoma with a malignant form of hypertenoion. Probl.
endok.i gorm. 7 no.3012-1U 161, (MIRA 14:9)
1. Im kafedry propedevticheskoy terapii (zav~m;,Prof. B,M.
Shershavskiy) i kafedry patologicheskoy anat (zav. - prof.
I.V. Toraptsev) Tmskogo meditainakogo instituta.
(ADRENAL GLANDS-TUMORS) (HYMMISION)
L 46145-66 EWT(m)/E%~ P" )/T - IJP(c VAVRM
- D6_6_A__r_~4 _sOUR
FACC NR, 736 , CE CODE: UR/0183/66/00 00/001~7/~043
AUTHOR: Serkov. A. T,; Budnitskiy, G. A.; Chivilikhina, M. P ; Veretennikova, T. P.a
Shishkina, N. P. i Kondrashova, I. A. ; Muravleva . L.-Y. ; Ordina'-L-I.
ORG: VNIIV
TITLE: Improving the quality of viscose cord
SOURCE: Khimicheakiye volokna, no. 3, 1966, 42-43
TOPIC TAGS: cellulose, synthetic material, cellulose plastic, synthetic fiber
ABSTRACT: The details of a modified procedure for manufacturing high tensile streE "t
viscose cords are described. In essence, the procedure consists of accelerated pro-
cesses of coagulation, filtration, and cord forming. It also requires the use of highl
purity reagents: sulfuric acid (GOST 2194-59), and ethylene oxide- and aliphatic
amine derivatives as modifiers. The modified procedure does not require any new ma-
chines, only a minor adjustment of the cord spinning procedure. It is claimed that
the modified procedure is capable of yielding viscose cords with tensile strength by
50-60% greater than that manufactured elsewhere in the world. Orig. art. hast 2
figures. 0
SUB CODE i IW/ SUBM DATE: 2BFeb66/ ORIG REFt 004
UM 677,453
.41-6card 1/1
Tr a i..5 I ation from Rcfer a zh1irn a i Mct a!! urgiya, i ~-, Nr p IUSSR)
AUTHOR~ Ordina, Z, G
TITLE Diffusion Siliconizing of Iron and Steel (Diffuzionnoyt. :,O\ a -
nive zi-xicza 1 stali)
PERIODICAL Tr Luningr tekhnol iii-ta pishch prom-sti, 1'6~, Vtj.
pp Z90- W7
ABSTRACT Pack and gas siliconizing IS) of sDecimens of Fv of t;-.v VIT _LCC
and specimens of steels of the types 110, 40, U7. and U a,
conducted under laboratory conditions at temperat-res of 9~7)~;,
1000, 1050, 1 1100, 1 150, and 12000C, the exposure timus
to i, f, , 1), 1-1 . 18. aiid 2-1 hou I- s A mixture coniposcd of
FuSi, 15% fire (-Iav (with partit le sizes ranging from 0 :, to
and ~Lvo NH4Cl was chosen for the pack S pro(,css Bcst resi.;ts
clurijig gas S xvcru achic%ed with FeSi particles of " (!--' ~ di.(i .' __)_
~ 0 1711-n III size, 'Alth a ( onsulliptioll of C) of -, htcrs i,.,-
rI1ICI_0St:_UCtUr(, and mic roharcincss of the layer st~idt,C
It
was established that the Si content in the diffusion a\,tlr
C a r d i determined from the microhardriess of the latter Tnc dt,pt:, o:
D;I f!i , Ion Si I I( on I i I rig o I I rm, a rid St
the sili( or~.ized layer in carbon steel dimmisf es rapidiv at fir~,t, ds I-,(- C k W., t
tration in the steel is increased, its ratc of de( rease be( or-ning
smaller- WhOll CXj)OSed to a L W-I-L)SI\t' gdb('0115 111CClIUM In Hit' ( L):I'-St' 01 1
test at tempei-atui-es up to 800', the sili( unized layer- on spe(.miens ()I V, F
and grade 10 steel exhibited good ( orrosion i-t-sistance The samv silii
steel .-.as fOLind to bt- chei-nically stable in, 1 O'n solutions of H SO4 and 14"~O
lwk tempe!-at-.jres as well as at the boiling tvii-ipe.-atkire
0
C a rd 2
AUTHOF.: S--,;
TITLE: The Dete rm i nat i on of t ne Si I , con Content aS a VU!,
yer Thi,:kn,'~-qs tby tnc- of
the La
niye so1erzhaniya ~remniya po t7lu!Ane
tverdosti)
PER D L Zivid-,,~A.va Lar,uratoriya, Vol. 124, Nr 6,
ABST",'..-T Since t,. met,.--,J of ~i-,-,D-tarlness .s t,-,p iu.-t,.-. t
si.-,i,lest :net~,-A for det~rmi,.i~q.7 lnes~, Jt
be el to clarifyi- -u F, s t i c r.
j I I A - I - C e i:.
t:-.e n ~ r 1 n e f;.-: of ~7 u re la,,- c-
Coni Ds : t i :)n or 'o 1:. t o r-!
chani,es in t,,.e mi cro-har-Iness of' ~, 1-r-si :,;r,
a si:lcor, -ontert of 1,06 - IFJ,5-' f e i s t 1
P M T -3 ap~ ratus by M.:.'..Khrushc,.ov
Be rk o vi ch wa s -; s e-1 . T: e expe r re,.,~ s w
hs: !nes increases w4
s i e:. t o f t e s * r o n . t
Card 1, 2 t.,.:,.t t~.e ri~:-Iu'~ '~s o*L1,-.-4:.;~ I variei wit-. I.-.e sd-e t
The Detr-r~nination of t,.,i ~~,nte,.t as a
Function of tte L,,iyer -.:ness of ~,_Cr
I z-,orler to confirm t~.iz3 r e I t i e n t
ir, ~-,rl,.ec;s t_e _'onte:-I of t e ~e
-1j j_; :Ite
analyses were carried --)ut V I T - i r. m.' -Ir.
st eel s un,! er v~irio-,s -on j'. S it W-1."I .", D'~~;,.
conter.t Df -1: e I e t e r m, r, e ul i n;t pr
by t,.e 7-~ of
m e a s u r e ~ f o r a n i n - c o n u y wn o s u t-:.
is kn -)wn . T* ' ero ~-,r- tf;t :e, ,-e:
which are Soviet.
ASSJC'_~.713T; Tekhnol j,-, ? -.eskiv I nst t ;t pi sh.,!,evoy
(Te _-'nnij'I 3,~ : I.,-. t ~~ -ute of Fl- J In-~ : -t
Card 2/2
69388
s/i29/6o/ooo/o6/ol2/022
C115o E073/E535
AUTHOR: Ordina, Z. G., Candidate of Technical Sciences
TITLE: D-i-f-f-u-s T_o_nt ~ _o~i I i c o n ~in Chromium Steell~
PERIODICAL: Metallovedeniye i termicheskaya obrabotka metallov,
ig6o, Nr 6, pp 46-47 (USSR)
ABSTRACT: It is known that the combined influence of cXomium and
silicon on the corrosion resistance of steel , s stronger
than that of each element separately (Refs I and 2).
Therefore, the author considered it of interest to
investigate the anti-corrosive effect of a surface layer
enriched simultaneously with these two elements.
Experiments have shown that Si enriched 12.4% Cr steel
has a high resistance to gas corrosion up to IOOOOC and
Si enriched low carbon steel has a good resistance to
gas corrosion only up to 8000C, the corrosion resistance
being smaller by a factor of 4 than that of chromium steel-
Little has been published on this subject (I German and
1 French patent are quoted). For the purpose of
elucidating the influence of chromium on the diffusion
Card 1/3 of silicon into steel, the authors investigated a number
& P~_
69368
S/129/6o/ooo/o6/012/022
E073/E535
Diffusion of Silicon in Chromium Steel
of steeA namely, steel 20 (.13 to 0.17% C), 20Kh (15; Cr),
Kh6 (6.3% Cr) and Kh13 (12.4% Cr). The silicon
enrichment was produced from solid powdery mixtures at
temperatures of 1050 to 12000C for durations of 3,6,9
and 12 hours and also by means of gas cyaniding by the
passage of chlorine through ferrosilicon with firebrick
at 9500C for durations of 1,2,4 and 6 hours. The
influence of the chromium content on the depth of the
silicon enriched layer is shown by the plot, Fig 2.
It was found that in the case of saturation of chromium
steel with silicon a bright silicized layer forms on the
surface which does not etch and consists of a uniform
solid solution of a columnar structure containing
simultaneously chromium and silicon. The chromium in
the steel reduces the depth of the layer but brings
about the formation of a dense and uniform layer. Such
a surface layer ensures a higher resistance to corrosion
Card 2/3 than a layer containing only silicon. LAI
b9388
S/129/60/000/06/012/022
E073/E535
Diffusion of Silicon in Chromium Steel
There are 2 figures and 2 Soviet references.
ASSOCIATION: Leningradskiy tekhnologicheskiy institut pishchevoy
promyshlennoBti (Leningrad Technical Institute for the
Food Industry)
Card 3/3
ORDINTSOV, V. S.
"On Bllood-suckinE Midees of the kayaz 'ma tdver Basin."
Tenth Conference on Parasitological Problemu and Diseas(,s with Natural
aeservoirs, 22-29 October 1959, Vol. II, Publishing HouLie of Academy of
Sciences, USSR, Moscow-Leningrad, 1959.
(Moscow)
ORDLOVSKIY, M.B.
New Famennian polyzoan species from the Chatkal-flaryn zone of the
Tien Shan. Paleont. zhur. no.2%64-71 161. (MIRA 14:6)
1. KirgizskWe geologicheskoye upravleniye.
(Tien Shan--Polyzoa, Fossil)
BRYZGALOV, V. A., ORDNSKIY, V. V.,- V. 3.
AgricuLture - Experimentation
Mat scientists are working on in 1952. Sad i og. No. 6, 1952.
9. Monthly List of Russian Accessions, Library of Congress, -1953, Unclassified.
ORDODY, Janos, okleveles" 'peszmernok
. I
Designing or copying Szabrvany kozl 16 no. 8:143-146 Ag '64.
t~
1. Hungarian Eburea-- of,Standards, Budapest.
ORDODYI J.
OFMM' J.
Nvolvent, geometric wepression of the length of trawmission belts.
P. 439
Vol. 7. No. Us Nov. 1955 Budapest, Hungary GEP
SO: 16fithly Mit-of East European Accessiona, (EM), LC, Vol. 5
No. 3, March, 1956
Q.-,~DODY ~ jftl~os
113 thO 1111 -~:~ . I :- -,I- il' Sz~ibvan.v koZ-' llr~
0 loi.
ORDODY, Janos, okleveles gepeszmernok
Rol* of the Renard numberis in Vis standardization of printing
plate drawings. Szabvany kozl 16 no.llsl95-196 N '64.
1. Hungarian Bureau of Standards, Budapest.
ORIJC - 0, 1 .
ORLOG, I. ~'ualitative ch;,racteristics of induEtria.1 sands in t:.e diEtrict of -Llatcn. P-3L8 1
Vol. 11, No. 6, June 1956.
HANYAS?ATI LAPOK
TECTOLOGY
Budapest, HunLary
So: Last Euror,ean Accession, Vol. 4, No. 2, .0'e-,. 11-57
0.7MG, Istvg-n
Reg-tulation G., trvir,3istor amplifiers; transistr'r technol 3U.
FLrdiotechn---*Ica 12- no.8:238-239 162.
ORDOG, Istvan
Esperanto radiobroadcasting. Radiotechnika 14 no.10:376 C 'b4-
;I ryr 1".) 1
C'D L; o s ~i
w I'el -I
r-1
20
O1QOGHP F.; SZENDE, K.
Temperature bacteriophageB isolated from Rhizobium meliloti.
Acta microb. hung. 8 no.lt65-71 161.
1. Institute of Genetics, Hungarian Academy of Sciences, Budapest.
(BACTERIOPIIAGE) (RHIZOBIUM immunol.)
HLHG1JiY/',1uj.LAn and 1-hystology (No"L
ia T-14
S,kin.
fibs Jour M-f Mur 1V 1-1, iqc8, 51426
Author Czaku, Jczsef; Ordc(~~h, Katalir
Inst
Title The Influence Df EDvirmental Ter.4jerature uT,,,r, ti.c: Zk~*r,
and Huir Temperature Qf Larf~e Hcrned Cattle (nulticoi-rol
Hwi6arian Dreed).
Orig Pub ',llaTtcnycsztes, 1956, 5, N~:; 4, 311-316.
Abstract Nc a'..stract.
Card 1/1
- 147 -
nF4, r, s 1 n
XA
':ungary
9n.
OqDO!A I M.
'Toncaral 'vtic" oxida'.iori of P. 32~ xA -J~ -
AFA7-YJA !:Iiijar-~ F.,= ary Val. :', n,3. 3/1, lr~~"
.;Ont,E; '.-,Ail LC lo 1 . " , . I , J u IV 0
HUNGi,.RY/Physical Chemistry. Kinetics. Cor:bustion. Explosions.
Topochenistry. Catalysis.
1.be Jour: Ref Zhur-Khir.., No 13, 1958, 4263o.
Author Szabo Zoltan, lrdoL~h Maria
Inst
Title Kinetics of Dissociation of A=Lonia at the Surfuce
of Quartz.
nrie, Pub: Magyar tud. akad. Ken. tud. oazt. kozl., 1956, 7,
No 3-4, 313-324.
Abstract: i. study of the kinetics of f-ecomposition cf NF at
the surface of quartz, at 740 and 64c) 'and initital
Nif ,, -pressure Pe 5C-2DO mm Hg- It was ascertained
that the resulting N, does not affect decomposition
of Nli;, while H~, which is strongly adsorbed at the
quartz surface decelerates this reaction. The fri-
Card 1/2
22
HMIGARY / Physical Chemistry. Kinetics. Coiabustion. b-9
Explosions. Topochemistry. Catalysis.
Abs Jour: Ref Zhur-Khimiya, No 7, 1959, 22566.
Author :Szabo, Z. G.
Ins t :Not given.
Title :On the Kinetics of the Decomposition of Ammonia
on Quartz Surface.
Orig Pub: Acta phys. et chem. Szeged, 1957, 3, No 1-4,
69-77.
Abstract: The decomposition of NH3 in a quartz vessel was
studied in a static system at 640 and 7400 and
under initial pressures Of NH3 of 50 to 200 mm
of mercury column. N2 has no noticeable effect
on the rate v of the reaction, but H2 decreases
it very much. v may be expressed by the equa-
tion v = kpNH 3Op,,/(bNH3pN-H3 ~ bH2pH2)' where po
Card 1/2
19
.V The .0
an
hia-M,
ov
V,
S Zd 6ow, Vp i Y 1.
werstalytie oxidation of N141
Im InftWpied in a quuu reaction vessel, and the course
of the upt-was Mowed by amlymb, In mbft. cmtg.
excess NH& -On rate of reaction wax,okwer tbau in those
!;wig. dWy P'm=U imt. d NE4 mad been 01 the
w" aw". 24d ordw, ~ ~Tbft dicomps, a w1h Mal=
wan w" Smium to be tbe Arst sup of the O"tke 0 F -
because the actIvation emgy of any other-ekmentary it-
aeflon between NIL &W 0 aols. was considered so Post
AGSi that in the pme3m* of the ..*a much a homogeneous ele-
9`0"; mentary room could slot take p1m. S. Soudmjam~
ORDOGH, M.; SCHNEER, A.; AUWSY, GY.
Analysis of uranium, thorlum, and zirconium. p. 295.
Budapest. Kozponti Fisikai Kutato Inteset. A MAGYAR TUDOW709 kKEDEMIk KOZPONTI
FIZIKAI MATO IN7VaTENZK KOZIEMNYEI, Budonest, Hungary, Val. 6, No. 4, Jul/Aug. 1958
Mwthly list of Ee:--t European Accessions (SM) IZ, Vol. 8, No. '/, JalY 1959
UNCL
Analysis Of vwimull thPTim, (Ind Timonium. GYU14-
-Almimy. jlh_tfa._.Ord_qzIi, and Anna Schneer. Uply9L
of Umulum can be extracted Into a tributyl phosphate-ben-
n-ne solution, from a weak nitric QcW solution half saturaW
withNH,NO,. It can be Mixtracted with &0.2 M(NH.)..
COrsolution. A coloritnetric method was used to determine
the Uranium content, morin was uoed as a complexing agent.
TWum was quantitatively cluted In paper chroma.
Wgrapb or from 4 cellulose column by SN nitric acid-ether
'gust Volume. 7te content of twum was 4eter-
tnlow DoWnwitkally w1th to6o. Zirw1om WOO Kali
IWIvely with swundelle " In 111t.
WWA~ - ___
Cher-,dstry. .nalysis t Incr,.anic E
CheLdstry.
.'~bs J ur: T,ef Zhur-KhiL.., ,v: 24, 1958, 81322.
_u;~h,_r Curd,.,f~h, M.; Fodor, 11.1.
Inst
Title Deter,-ination ~f UraidiL.,-
OriC. PuL: EnerCia es at--)i. teclu-i., 1958, 11, Nc 1-2, 27-33.
.'.bstract: Review of the deterTAnation methods (precipita-
ti,z,, cc.,-.iplex fcrmati,,,n, extracti~,n, distilla-
tion, electrolysis, and ion exchange) and cf
detexT.Lination (gravimetrical, titrimetrical
photonetrical, and fluorouetrical) of uraniun.
The bibliography includes 18 naries. -- I. Krish-
tofori.
Card 1/1
-,-)D'CA 1
"El- 1M, r, Vol no. Julv/A_
Da ta -n "i- -rn, + rr 2~n
1*9~ o' 7.i-t, r,ir--nr !,r.,-- ;,)-s
ORDOGH, Maria; SCHNEER, Anna
Paper chromatographic analysis in connection vith the producing of
tellurium (VI) compounds. Koz fiz kozl XTA 8 no.1.39-40 160.
(EEAI 10:1)
1. Magkemiai Laboratorium II, A Magyar Tudomanyos Akademia Kozponti
Fizikai Nutato Intezete.
(Tellurium) (Chromatography) (Chlorination)
(Butyl alcohol) (Hydrochloric acid) (Tin chlorides)
1 1 C G;-A
7 ~'7
e n. c, n a:"k, EL: C, I, f C.
de tQ r~..in I ri~ ,j eruct 'v, -.c-*,;-.cas, as-n~: y-s-)ectrc;;zetr~~,
crt":
t t cr,
Card lill
CTWGH, Maria
Ultrarnicrochemical analysis. Mapy keir lap 15 no.7:325-329 J1 161
1. Kczponti Fizlkal KOnto Irtmzet.
SZABO, Elek; FLEK, Antal; OT ~"H, MRrla; UPOR, Fndre
I
4 ~
Deteimination of tne trace elemc t,d of rocks by tne
method of neutron activation. Knz,~'iz kczl MTA 12
no.5055-364 '64.
.. Central Resear-1, Institute of Physics, liungnrian Acwlemy
nf Sciences, Budapest.
~-:*-.! I
A.'' , I - -, ~ n '. ': . *
V"Ai!.; Y4,r ri~ ,
I ' n 7 ' i ! l: " 'T .
- ~ I r. ;. r --,., i~ .~- ~i :- - ~. i '~ . t 1 - - - - . -,~- -; .S, C; - - ~-f.
A ,,: -~ -.w - ., s , :. I " 1, .1 " . !; ,.
V 13MWOW/00 J10691069
A0061*10 I
-AWMA, OrOkov, I.
Wxz: 4asidual.otresses of the II and III order in eleotrolytio coatings
PERIODICAL: Referativnyy zhurnal. Metallurgiya, no.3, 1961, 61, abstract 31471
Pralftevallskogo ped. no-5, 1957 (1958), 93-102)
TEXT: The X-ray method was employed to investigate the crystallite and
eleoentary dimtorf4eps In olentrolyU. a Cu-ooatings on steel plates. , It, was
esta~llshode,t,hat~,,tA*,estornal- loycor of thp oosting vequired 14he atoria-arystalline
01quaturo -of ~~on!;iqj~"ed metal, with increasing thickness, due to higher current
izit4moity or,depealblorl time.,
Ye. L.
[Abstractor's note: Complete translation.]
Card W1
cr
OTry"'..
11 o r ma 1'-z a c : ~a .-; , :- z,-II..- -, -.- "i-', 4-I i ~ns-.-4owe -,,`--i-..
_:~ .- . k . - .
Fechn'l.czne, 19r-. l-),- P.
(Standardizat-~or, in the cheuc;31 industry. lst ed. li-3Frs., inJex, tableF)
SO: YonthLy List of .'last -Europe-m Acce:3slons (:-,"IAL) ].-:, Vol. ~,, no. ', ~un,~ I",-- , '~'ncl.
OR~' 'a.', 0 .
TF-C ~ ~ I L,-Q.'
Pp.:-iodica.D-: *.'Cl. - , n". -, Sept. llll~'
. The Euron-an --qnVrf-.sF Df Chemica-l EnrLnpf~r..r.,-.
Monthl,v List of Fast !Aro, ean AcceFs I ons if, Vol. I , '*r). ),
Febriiarv lk'nrlass.
-:f"~dMMON NR: PO/0092/65/000/07-/0003/0012
AUTHOM 094M. staniAL (Commander, Doctor)
Ddson aspects in the development of the maritime economy of the Polish
501=z: orseeed =Wd no. 7-8. 1965, 3-12
engineering, merchant marine status,
TOPIC TACO. marine
defense MAI Bum Intation
ABSTA&C76 After defloin the concept maritime economy, the author reviews the condi-
id iort thellidii the Polish naval forces existing prior to World War IL The legal
-of bandS by ft:PMeb navy and ft. reasons. compelling the
BMW
Pon&' am a now naval port at 061" M:tbe ar after World War 1, when
A 014, the 0ort at. DanzigiM" avalbble, are discussed. ~ The Yle lop and the insuffi-
Chat' bellitles for biwal forms to pro-World. War Iff Poland mm pointed out. Present-
ft~ooimdltl ons are also revierwed: -Vww large ports are available, In Gdansk, Gdynia am
Bacsiods. I)aft are given concerning do aim of the merchant and the fishing fleets, 04
do adiftry haportance of do two fleete Is IndIc*bd. Me shipbuilding Industry in
L
00527-66
.A
Camom W. AMIMI
Wairld Whr 11 Pdaiid is deawbed and contrasted widk So present-day sibation of
V **Md=. 1* Is Id qat bat In 1964 Polish shipy" bullt 47 ships d total
ty af~Mj= DRT Wd carrying capacily-:01 296.430 DWT. attaining 12th place in the i
4m, d Alps. odw 'Jam d equipmainti: iudh aw Diesel engines, In also,
V!qWMI; Val
Pic; fesse "Swat of so I 1 11 Ung kfttry- is also poinied out. Next, the
and merdwst, smaAms edwal a am reviemd. It In noted that in
-PO" a
Im of Offleers in the mmd lorme'.bed higber mtHtu-y, or civilian educa-
A two Is abaft Ow ==bars of shAmats dm dWerent deparbnente 1
16 State - -- 'i
Avmq~ sdmb I's the ymm hvm IM b IM. Maritime schools of see-
19"d an
jud do andw d peduales am given for 1963-
amda" "d a
Hie-rimmeara Imulubs, based in dm couW an o( Poland and dealing with
ANWIA720M.- Nums
00
-DUMED.
ENCL. 00 BUD CODE: MS, 00
OTHE& 025
NO UF SOV.- 60
Card 2
SXMRNOV. M.P., sotrudnik; sotrudnik; LYKOSHIN, A.G..
sotrudnik; MOLOKOV, L.A., sotrudnli; KHRAMOGINA. T.S.. sotrudnik;
GOWBINKOVA. L.A.. redektor izdatsl'Btvo; GUSIVA, B.S., takhnicho-
sirly redaktor
[Papers from the hydrogeolagical engineering laboratory] Trudy
laborstorti inthenernoi gidrogeologit. Moskva, Gos.iad-vo lit-ry
po stroit. i arkbit.. 1957. 230 p. (NLRA 10:7)
1. Moscow. Vaesoyusnyy nauchno-issledoystel'skiy institut vodo-
snabsbentya. kanalizatsit. gid rote khnicheski kh soorusheniy i
insheimernay gidrogeologii. 2. Vaesoyusnyy nouchno-iseledovatellalriy
inmtitut Todgeo (for Samenov. Oradowskaya). 3. Moskovskore otdalentre
Gidroonergoproyakta (for Iqlroshin Kolokov. Khramogins)
(Hydraulic engineering) tAngineering geology)
ORWVSKM, L.A,j FRENKELI, B.I., atarnhiy naunhn.,ry cotrudnlic (10mr1kov)
,Lepeated ser(.loC,--* v-1 w-m-minatior. of pregnant womer is rc.
expedient. Vest.dam.i ven. nc.1:59L6G IQ% (~9:FtA I -- : I )
1. W-riste-Pt.irr vlrsvnnlrl-rrncnlvP "krSSR, Kiyev (for Ordovskaya).
2, -
, UK= (for henkel I I - -W f , ~A~
-sS.-:lV!Al.T REACTION)
(PREGJ~A17C7)
-,r - wt
rr
M~JUCARYANY L.P.; OTU)CYAN, M.S.
Effect of general X-ray radiation on the semia.1 system of
whita mice and vr~bbi-,s (female). Vop. radiobiol. [All Arm.
SSR] 1:127,135 160. (MIRA 15:3)
1. Iz kafedry akusherstva i ginekologii (zav. - zasluzhennyy
deyateil nauki prof. A.M. Agaronov) i kafedry patologicheakoy
amtomii (zav. - dot3ent V.T. Gabriyalyan) Yerevanskoga medit-
sinskogo instituta (dir,- doLsent, S,N. Galstyan).
(X RAYS- PHYSIOLOGICAL EFFECT)
(G-11ZRATIVE ORGANS)
PIPINOV, A.V.; ORDUYAN G.S.
:i~~
Design of optical transducers for automatic orientation of scientific
apparatus by the sun. Trudy Vych.tsentra no.2182-93 164. (MIRA IS.-8)
A J" iUAS Y T 62 - I -23"~'
T 1'. L z, 01~ Ca t --il. t ic Hj G 11C. e 1-9 a t i
,U i, i I i (.J!~261 a L; --.'i j
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AUTHORS: Fydus, Ya. T., arid ordyar.. M. r. 0- 27 '44
TITU: On the Yethylation of Cyclopentenes by Yethylene Radicals that
Form Men Carbon Monoxide is Reduced by Contact with Hydrcger
(0 metilirovanii tsikloperitena metilenovymi radikalami, obrazuy-ush-
chimisya kontaktrym vosstanovleniyem okisi ugleroda vodorodom).
FnIODICkL: Doklady AN S33R, 1957, Vol. 116, Nr 1, pp. 101-IOL(USSR).
ABSTRACT: It was earlier proved that In the reaction of the cataV,'-'c
condensation of carbon monoxide with olefines a methylation of cyclon
hexene by methylene radicals takes place which form due to a hydra-
tion of CC by contact with hydrogen. From this develop mcnomethyl-
and 1,2-dimethyl substitutes of cyclohexene. It was earlier experi-
mentally proved that in the cataly-tic synthesis of hyd-rocarbons from
CO and H2 by methylation of benzene in toluol an intermediate forma-
tion of methyene radicals takes place. In the present paper the re,
sults of the study are described which were obtained from the ins
vestigation of the behavior of another cyclo.-olefine, of cyclopentene-
toward the hydrocondensation reaction with carbon monoxide. The appa-
ratuB and the test arrangement remained the same as in earlier works.
Card 1/4 The production method and the properties of the initial cyclopentene
on the Methylation of Cyclopentenes by Methylene Radicals , 0 -L-27,U
that Form When Carbon Monoxide is Reduced by Contact with Hydrogen.
are described. before the actual problem (see above) the :,-!,,-i\inr o!*
the mentioned substance alone and in a mixture with hydrogen wa-,
st-Aied. In the latter case the hydro-genation to cyclopentane
/at -
k ?%', ^o 5o % calculatf-d on -yc Li ',(-fine) took place as the orly
reaction. Neither hydro-cracking nor hy.-L-Ienclysi,~ , f 4 1
-yrle -.rrt Cn tte -assage of cyclopentene through a ga-s rrLxture
w1th Cc and E0 the !_Jq,,i~4d c o,- *,' F- 7,-' -1e corL9 i9tf
clopertl,ene axid ~yrlopentane_eixture. The fraction 43,6 - Wi,'10 -r,,
tained small ayn(,unts of alii,hatic ~~IvTq wl ',' had formed fr-m
CO and H 2' Or. hydration of the liquid catalysate over platinized
charcoal with addition of H 2PtC1 6 reaction products which boiled
higher than cyclopentane were contained in a quantity of 4
The hydrogenisate was subjected to fractionzated distillation.
Figure 1 shows the fractionation curve. It has 3 wide plateaus which
correspond to fractions II, IV and V. The results of an optical ana-
lysis showed that fraction II consists of almost pure methyl-cyclo-
pentane with traces of cyclohexane. Fraction III contained 6o/4 of
the former and 4oO/aof the latter substance, fraction IV - loq10f
the latter and 350/,oof the former. Fraction V cortained considerable
rard 2/L amounts of ethyl-cyclohexane, elityleyclopentane and propylcyclopen-