SCIENTIFIC ABSTRACT OKHATAIMAKAYA, M.V. - OKHLOPKOV, V.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001237910005-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

29729
S/169/61/ODO/CO8/'b5O/O53
34M Onl) A006/A101
AUNORS O.khaWm"AyA,,,_j4.Y., 11natrusin, lu.B., Bokit-yanakly, I.I., shohap-
etnov, R.Y.
Regularltl_eB in the excitation of shcrt-perlod o3aillations in mid-
dle latitudes
PEMODICAL: Referativn7y zhurnal. Geofizika, no. 8, 1961, 42, abstract 80280 (V
Bb. "Xorotkoperiod. kolebanlya elektr.=agnitn. yolya, Zemli, no.
Mozcvw, AN SSSR, 1961, 17 - 22, Engliab summary)
TMI The study of short-parlod oBz1llat1cn3 of tolluric currents during
the IGY was carried out at stations of the Inztitut fiziki Zerill AN 3SBR (In-
stitute of Physics of the Earth, AS USSR) (Borok, Alma-Ata, Petropavlovsk-Kam-
ohatskiy, and Alushta). 7heae Inventigatiors made It posz1bla to detect a
number of common regularlties of short-pez-11od oacillatirns in riddl.9 lazitudea.
There are two basically different type3 of short-pericd esa-I'Matlonj namely'
6.W
stable oBaillatlons, pc, with T " (15 ! 40) 39c wid train-t "pe cacillations. pt,
-with T e,_00 7 90) sec. 7he maximum namber of pc~ cases occurs at local mIdday,
and pt at 100a1 midnight, Independen-t, of tho Icngitude of the station. M19
Card 1/ 2

2W29
3/169/61/000/008/050/053
Regularities in tht exoitaticn ... AOD6/AlO!
diurnal run of po ia asymmetrio ar?- hms a bro3i r.&x1,nwm around milday. 7he In-
crease of pa amplitudes occurs 1.5 timsB more quickI7 Lhan their damping. A
somewhat increased po number was observed in s-wmmar as compart-i to the winter.
Thediurnal pt run has a sharp maximum around locAl midnight. Seasonal variabili-
ty was not observed for pt. Arpplitudes of short-"rl~d oacill2itiOnS in middle
latitudes are low, being fractions of a unity and a few my/lm for pa, and several
mv/km for pt. There are indications of a tendenoj for increased short-period oB-
cilla-tion amplitudes at seaside station.3. Previous cvncepts on -the dependence
of pe and pt on universal time were explained as follows. a comparison was made
of the diurnal run of short-period oBclllat-ions on ztations located close in the
longitudej a comparison was made of unclear maxima obtained from a small number
of cases. This did not permllu the detection of tht longitudinal effect of maxi-
mum shift even for substantially remote atations; moreover, there are oBcilla-
tions, in both mcdes, correlated w1th universal time, which occur seldom but are
very intensive.
[AbBtracter's noire: Complete translation]
Card 2/2

-1
L 00309-66 E'dL'(l)/.rPA(s)-2/FPF(n)-2/T-2/ETC W IJP(c) lerd
'ACCESSION NX: AP5016659 UR/0382/65/000/002/0111/0122
539.4+621.689
.AUTHORt VasIlOyev. S. V.-, 0khemenko, H. M.t Smirnova, L. G. 11 Ir
~ I C1111 ff ~r
TITIX: Experimental Investigation of the magnetic fields of an induction pump
SOURCE* Magnitnaya gidrodinamika, no. -2~ 19,65, 111--122VI'
p, magnetic field, magnetic induction
TOPIC TAGS, electrqTa~~tLt;__pj~m
ABSTRACT:, The-spatial distribution of components of the magnetic induction, V in
the gap between two-layer winding inductors of flat-type linear Induction pump is
studied. The test device operated at 00 KVA at current reading of 120 AMP. (operat-
ing without a load). The effects of loading on components of 0 zire indicated.
,Both thermocouples on various metallic plates inserted in the gap and magnetic
probe coils were used to obtain the data. Also given are data on measurement of
Integral distribution of components of B, demagnetization coef f iclent , and secondar-I
lwakaje_.7 Various-fringe --effect a -have -been-m6daured. --In- addlt ion, it is shown that
-the above agrees- with calculations wbich were carried out-assuml-irig the plane-paral--'
I
Ilel geometry for the magnetic field, Or1g4 arto hast 5 formulasp 9 figures, 1
Itable.
CoM 1/2

AIAMIDYAN, AM.I.y dotsent; GMAUAN, L,S.y kand. blol. nauk; t-LUIUMAii, '!,.Kh.,
mlaclBhly nauchnyl sotradnik; MOZWYAN, O.Ye.; OMIKYAN, V.M.,,
starBhiy laborant , - -
EffBet of decortication and X-rays on the phagicytic activity of
laucocylues In rabbits. Vop. radiobiol. ILAN Arm. SSRi 3/4247-52
#63. (1-URA 1'/:b)

f-f,~T~9-67 -EWT
ACC NRj
AP6029970
SOURCE CODE: uR/0413/66100010151016210162
INVENTOR: Okhil'kov, G. T.; ~ergeyev, B. B.; Belonozhko, G.C.
ORG., none
TTTLE: Ignition composition for bridgeless alectroigniters. Class 78,0184677
SOURCE: Izobret prom obraz tov zn, Po. 15, 1966, 162
TOPIC TAGS: primer, explosive, detonator, Ignition
j-mition composition for
ABSTRACT: An Author Certificate has been issued for an i
electric igniters vitbout bridge circuits. To sqcure saft operation of the electric
igniters In the presence of eddy currents and increase thit stability of the electric
resistance, the com
vosition contains components in the fol.lowing concentrations:
potassium cblorate,1149-31%; lead rhodanide) 34.7-36.7%; crystallize graphite,
15-131; and high viscosity colloxyline, D.2-0.4%. fw' A. VV79 IPVI
SUB CODE: 19,91VIIISUBN DATE: .18jan65/

rjh)ii!IA,V.A.
On 20 06tober at 1500., Y.A. Oknina wJ21 sub.-lit her diwertition
for the of Candidate of ChL-raical Sciences on the theme "Photocalorimetric
M
Me hodB of Chemic:,I JoalysiB of Natural Phosphates and J~6mn Containing Oreg"
Vachernyaya MoBkav, 10 Oct 1950., No. 240 (V141)

ORFMI, F.1.1 OEHINA, To.Z.
Dormancy In plants As & procems of tell prote-plasim division. ?rncly
inst.fisiol.rAst. 6 ne.1:85-102 348. Owu 9:9)
1.1notitut f i2lologii rastemI7 ilmeni X.A.TiM177JLZ9TA AN SSSR.
ippotoplasio) jDarmandy (plants)) -

SFMNOVj V.A.; OXHIMEMO, A.I. _
Caloulation of solid prealpitationa. Trudy Xaz,,WIGHI no.16-87-92
161. (praoivitation (YAteorclogy)) (ZU .15:5)

S. K. . ji~r-iuAl, J,
-ar chFrni~al P-- cozmi., rays anI origin of
:j!~AT.- ltvsrprAtivnyy -.r.-ar-nal. A~~r~,,nomlya I Geodez',ya, no- 12,
itp!r&c~ ("!r, ~.cnrercntnll Vo ko:,mlch
1959. v. Y, AN 191 - 195)
Ine aut.nor:i rot~~ !hat. the rclative ~fntent of htavy mict,!
--ry hl;~n In prlmnry radln*lm, wker-or. th'? rmlon cont~r.' 1~ Y-1
in Ic r3tta -NI ec'-'T!e' r:qz,
! In CaTly sln~,!! of 3,j-,,-rn:7v5 #Ixplo 11 Icn3, The t-rT~ratijr- of
,;:t 1: pxpin: Icn altzint. iprrc xjm3tnly d"'K, d~nsj -.y o1' enveZov-
Vnd~-r th-.~Ot Dyntheals of heavy n'.C101 is polsiv-
rrr irit
,,n. pro-!w!~,i of n~,A*rcm capt.Urp- Sln~r the most Im t
i,)urcr I.,; r,*nn. :T-~ Craction will vanish, AMI 1~~ rele",ve
%il: cf (Y. -particles rp.3y proceed aa a res,il~ o! thxl
'-N :;rle, In IhIs prc~ce5i the role of beta-decay will be LniiWnficm,t.
Car-i I f2

4t
7;- f.: A0011AL01
1 ce"."'t ~,f will tv lncvev,-~d. hrt.lr~f rr,~,vo!i
L Z 1'i

H
0 KvP ft ti, IV

ON U E KINCTIM OF "Ill P ISOTHERM A I
7RAN-1rQfl1d&TZLnX,.LWE T04ESMILZILMA 13, yt,--
---.~U-L)umv DA'l Vu. ~ OKI 'An, Sept. 1054. V.P. Tmaillated
b'y Dr. J. D. qy6ll WtWp Al.~4t Ak~~ Nt.~j_k ~Jt. 101.
Sj'3-8(1q5G)'
A qmantuja mm&Wo-*l study h" bma made on the
martcasfta trAnafformatlan near iibaolute tero 1:~ order to
dattrmha the nature of the factors Woollno LM trans-
formAllrin proprilvi, RmIts ahmr that the rdtQ G(
marlerwim trmi4formatl(m doe.-i -vtt ilepml on tho tompariv
Wro fit tomporatures olozo to abooltite rpro, 'Mus the
vibrntioazi ensra of tho Ptoms fit the chief factor which
dolorminus L" rato of the

Gar on -'el ',e
IN10.
varl'I'le

ZAKMKII;2 I.I.) 04HOLDBYSTIJII, 0.711.; MUM;], X..A.
.
Exchang
a reactions of aIIqls between organomagnesium compounds
and halides, Izv. AN SSSR Ser. khim,. no*7:1347-1349 JI I&..
(141 RA 17: 3)
1* Inatitut elementoorganicheskikh soyedinenly All SSSR.

Pc--~IPT-4 RM
NR: AP40435150 S/0020/64/157/004/093Z./0937
AUTHORS: Al ke drQv
91 - ----'-A , I u, ; OK.',-il c-,vy* _rt in_, _Ory
TITLE; Moesbauer efre~, 4'n un!iymmetri cal C ~'T
ing electron 4-jonor substltuentB
organotin compou;id, tetrhvP,,.1int t,-%n
spectrum, elecf.rc)n donor group, tripheny-Itirilith'Lum, hexaat~-'-
tAnn&ne, hexaphenyidl5tanrane, quadrupole splitting, iSCIN71"il-
doublet line
ABSTRACT: The resonanc6 absorption spoctra -,)f unsymmetrica.1,
tin C unris containing electron donor (with reapect tc~ th;
MPID
atom) substituents, and of certal.n other tetraValent till 0,-,f
,verp atudled. Pleasuremeots were mada at liquid nitrogeTi te
SR-L19 (as SnO ) was used as the r-ray source; the f-quantur'
key was regisiered on a roa-~rnance counter. The spectra of
0,.'3-QnLi (triphanyltin-lithium), R Sn-SnR, (hexaethyl- and
icdN 1/3 .3

L. 16719-1, 5
ACCESSIM) NR: AP40~3550
ne ) and R3 SnR ' type ccmpounds were ail singlets wit.11 ;ii-o
distanna
i at 1.45, 1. 0, cor esponding to line widths of 1 5-1
4 r I
Reprdleas of tne electron dz)nor sab&L.LLuent bonded direc'.1-;
Sn# the quadrupole hpiittingAwas 0, Lne symmetry of the
of the-four 3n bandu w&.4, not nfliceably disturbed, and trio Jti i.
of the s-electrons near trie Sn -9 nuclatis was incressed on.",
While A - -0 1. n dono r c o r. t a i n _i n g- mol e ca I e s R SnD t~.e -;:j
n
pole splitting in acceptor (A) type molecillf-'3 ftnsrk-n V a 1,!. 0'1
to 1+.a mm/sec, depending on A. In batn ~f these types c, f -.3n
pounds the iaomeric 5hift varied within - 5C?% of 6 - 1 .)(1 for
symetrical R Sn, indicating tbe iiomeric shift cauCed by oJl'-
acceptor groups was compensated to a .7reat degree by the elle i-
donor substitutent-9, in inorganic tin compounds, Cvarieed fr-~~)
T.1-w-COMPOUMda of.t'46 ryp-- tC"'~J' the res
h a quaAnzwupj.4e
absorption spectra r d .3 dou~)3 t 9tructure, the
indreased witt increase in, number of 5ubatitutent radica-i i
smaller In polymer3 in comparison to the respective monowevs.
valites for & and J for (C P10) Sn(OCO(Cli C1 contain: rij-,
bond, were identical with tfmeie for th-j cor;4s~o'nding ansa!-~-
Cumpound; 6 again depended litt.'-a on the exchaiige of al~y-~~ z3

ACCESSION Nfil 14A Y' 4,,') 4155 0
-2lectron acceptor groups an(l u1nio-,i norie r~n in-creasing the number -)f
The resonanci absorpt~0,~l f0-r (~-H`03Sn('05, (CH3)3SnCllL
had only singlet 1'nes and waa the samt,
1 1- 1
(CH3)4Sn, indir-ating e"h,'rige Of (--'H3 by C6H5 or a conjugated bon
gradient In the Aectric f.e)d
:not change the elecu~or, dens!lty or cause a p
inucleus. "The authors t~iank T Krasnov L V L,a%.-n for supplyinz s-
pies nf the organotin an(j M Ye Dvatkin and G K. Senlir.
lvaluable remarks in di-scuusiz-ig the work 11 Orig art. lhaa~ I table
ASSOCIA11ON: Institut neftfkhin)khefik.-3jTo sirAeza Akadernii nauk
(Institute of Petrocheniical Svnltheais Academy of Sciences SSSR); !nw!
~elamentctorganicheskikb soyedineniv Ak~,demfi nauk SSSR ~lnstit-lte of
.jnj&e4ljc Co .5 " en f moskavsi~ u
nIX.2L ) 8 1
'j, go gr
univemiteta Im M V L-orntmofiova ~ Moscow State University)
Submitted: 24Api-64 Eric! 0 0
Sub Code ~ GC, GP N, r 1-1, f.- f "S (,~ v") C, Other- 010i1

L
ACCEO'SION NR f~ 2! AV' 0CM.! 0 12! '22 (1.

TTT L E S,/ h
ir- a medium s;c
SOURCE*. AN
TOPTC TAGS 0 'An v 0in

iodide
.A.Bs,r TP A',--'.
was

alkyb~
i
tion of
21

of the ;Ileull.
A I kvii rf- 71
and :1 a d t
table
ASSOCLAIT
it,
001
SUB CODF
co, d 2 , 2

L 15694-6'~ FPA, TV" !r /E p "'i, P /'F 4
i -SD---3TA F ri
AtCESSION NR; AP4045840 Rzo,w/'2-~-
AUTHOR: ZaktuL~ILL, 1 la~ t A,
0khloby4ni-in, 0. Y
TITLE: Srlt I It! b ', S~l ~A C t,! F t!fg L(F! r t c 0 m po "m cls. D
and its de ri*/;jt i v(.,. e
1, ~k N no
SOURCE, AN'
TOPIC T A C, S) L r f- f -de r - v ~i i v i~.-
acetylenic cnrnp,-mrin i! ~,i a. i
7 =--, F7-- --77 1 - -,~ - . - I -
-W89TiV'k-,7T-` ln-te--nv-firv- -,-*f lip- 'tb rt- with accitv~c- r-ornpounas in me preserc.,!
Y.--) t- T f I Q
of
cl;-,ss
(C2H02F~ an-d Irl Pll'fll 1-r- dF7
ing to I an (I

Al~('E.7,-STC)t' Nil
A vi-eld of up
Or I.: -io i n ~Iprpl~ !hc
'Ienic corn t J, veci, 4,32) (1962) on Ine i
isoproWmylacef. Pnp wizh F. V"j:lfq obfqjnPri
derivative.9 cinna T':
mmeral acids ;mld ~,n, -)d a
ane . Orig a r ~i -
in5ritut etffmvntuurganicne"iktj uutdinumy Akademn riauit z-,z:iz:,rt
cif thi. Aendomm, e)f
SUBMITTE'D, '26~~
-SUB CODE. k
Cord "i 2

SVT (m)/FFF~. OIAM A ~.O Rc-4 R
fACCE56ION NRI AP4044709
4UTHORs Zakharkin, L, I.; Bregad2e, V, 1,; Okhlobytintin, C. Nu.
ITITLEt Syntheels of derivatives of bsrenol'~
.'SOURCIj Ali 93SR, levestlya. Seriva khimit-beekaya, no~ 9, '.064, 5
1540
JOPIC TAGSt barene, organoboron compuund, organosilican
o r g an o t i n c o m T, o u n d , o ~ a ri ri, h -7 fi It (y r u ti c o m p c it a d
i
iABSTRACTi A s tudy h i? uh h I an, e rv a t L ve a__o f _ b-a
Z A h d rk ii, , L V 1; -, a t .3 e vYA . C h a pc vv
Yu. VkhIcb76tJn, Izv, AN SSSP. Ser. XhIn., 1963, 2)38)
and 0.
Ivith orgauo-sillcan,,~ I-, zift , v--tue rcury . and -phcaphorug chlo rl da I
ferm a ~cmpasunds Ii vhich the element atom it; at :sc~i-
;'to the barene ring. The re-actIon of phenylbarenyl) lithium
utiozi for-aed C-phenyl-C
t rise thy1chlorosi I ane hi Sol
(trLuethjIviIvI)baren6 (eap 104-106C) in a 61% yieldr
.t12

L10442,-~
CC985TON YR3 KP4044709
fill Lt.%
I reacted WICh triphenyltin Chlolide to form tripheriv
(!ap 186- C) in ala 84% yield and with me th-
(ph*nylbaranyl) tin 18~
mercury bromide in a benzene auspension to form methyl "phenyl.-
19 - 16 0 C',I in A 621 yield.
baronyl) mercury (mp 1, 1 also renctini
dibexylphoe phipous ch I a r i de to f o rm (I L lie xy I ( pheny lbarenyl ) ph ) qh
(imp 9-10C) in a 5',X yield. Orig. art. haa! 6 formula@.
ASSOCIATIONj lastitvt iplenvientoorgani-heakikh aclyeditmnly AN q;S
J(Inftitute of Orgenoelamental Compoundej-" 55SE2
ISUBMITTZDt 16Jan64 ATD PRiSfit 3110 KN CL r (I
jSU6 CODKI I C , 'G C NC REV SOVi 004 OTHER-
Cmd

AIMS.ANDROV,, A. Yu.; CKHIDBY-STBl,O. lu.r FCLAK. L.S,; SHPUTEO,V.S.
Mossbauer effect in imaym. etri-cal organotin compounds witto
electrcn-donor subBtituepts. Dokl. AN SSSR 157 no.4:934-937
Ag 164 (MIRA 17:8)
1. Institut neftekhlmichoskogo sintaza AN SMR! Institut
elementoorganicbeskikh soyedineni.y All SSSR i M~Stitut yadelmoy
fi2iki Mcskovskogo gosudarstvennogo universiteta. Predstarlero
akadamikom V.I. XabaoYmikom.

-'OKV4L-08YS,rw' 0 - YV-
M-SR/Cheriiistry - Synthesis
'A Pub, 22 - 32/56
Authors , Skvarchenkc, V. R.; LeviTia, R. YA.; and Okhlobiatin, 0. Yu.
Title , Synthesis of nydrocarbon3. New method of synthesizing
I
there (oc~.anehtrene,1, and their
Periodical j Dok. M 35SR 99/5, 789-792, Dec 11, 1954
Abstract t The reaction of splitting tetrahydropthalic anhydrides under the effect F-10r,
1 4 ,
vi-as used In the drivation of tricyclic condensed hydrooarl),-Mt-, e-Y m, hy
drophenanthere (actanethrone), 4,5-cyclopentanoindan and Lheir
Ttw basic, diens JhVAroc,--- Dona fvund r'Q ba
dicyclopentenyl, the first of which conbined with maleic anhytirLde y1elaed 1
2,3,4,5,6,7,8-octahydrophenanthrene. Gther hydrocarbons derive~j from 1,1t-
licyclopentf~iVJL riixeki witn r.-aloic, clLraconic and
-Gennan i 1~
Institution The M. V. Lomonosov State University, Moscow
Presented by: Academician A. N. Hesmeyauov, july 16, 1954

;LJ&
Ov

7_11j
MTHORS: Zakha*rkin, L. I.; and Okhlobystin, 0. Tu. 20-2-20/50
TITLS: The Utilization of Aluminum Trialkyls in the Synthesis of
Ilemen-tal Organic Compounds (IspolIzo7aniye alyuminiytrlalkilov
dlya sinteza elementoorganicbeskM soyedineniy).
PERIODICAL: Doklady AD SSSR, 1957, Vol. 116, Nr 2, pp. 236-238 (USSR)
A13STRACT: An connectinn with the fact that organoaluminum compounds
were easil-y accessible in recent times the problem naturally
rises of their utilization in the synthesis of other
element-organic compounds. In patent publications production-
methods were described of organo2inc, organocadmium and
organonexcury compounds of the type R.MeX, as well as of trial-
kylborines from haloid compounds of the same elements and
from a mixture of alkylaluminum-halides which forms on the
action of appropriate haloidalkyls on aluminum:
3 RX + 2 Al :~ RAIX2+R2AIX. Is far as this reaction
only takes placB with the lower alkyls (B not higher than
C3H7 ), this method can not be considered Ceneral enough. In
Card 1/4 the present paper the authors studied the interaction of

The Utilization of Aluminum Trialkyls in the Symthesis of 20-2- 20/50
Element Organic Compounds
boron-, antimony-, arsenic-, phosphorus-, tin- and
mercury-halides with triethylaluminum and tri-isobutyl-
aluminum. In all cases investigated an exchange reaction
takes place under formation of an aluminum halide and of
alkyl derivatives of the elements taken. On addition of
trifluorboro-ethydrate to tri-isobutyl-aluminum,
triisobutylboron forms at 60-650C. The same forms on
blowing gaseous trifluorboron through a triethyleluminum
solution In decahydronaphthalone. The interaction of tri-
isobutyl-aluminum-othyrate with a suspension of trifluor-
antimony in ether takes place just as easily. The inter-
action of tri-isobutyl-aluminum with arsenic trichloride
in ether does not lead to trialkylarsine; chief products
are, however: inobutyl-trichloroaraine and di-isobutyl-
chloroarsize. The interaction of tri-isobutyl-aluminum with
phosphorus trichloride is more complicated. The formation
of a complex of the reaction products with chloroaluminum
takes place as the result of an energetic reaction (in-
Card 2/4 dependently of the type of solvent). Yrom the reaction mass

The Utili23tion of Aluminum Trialkyls in the Synthesis of 20-2-20/50
Elemental Organic Compounds
isobutyldichlorophosphine can be distilled off in a
Tacuum. On further heating of the rest a radical
decomposition takes place unier formation of volatile
products and elementary phosphorus. The interaction
of equimolecular amounts of tri-isobutyl or tri-ethyl-
aluminum with mercuric bromide or sublimate in ether or in
hexane chiefly leads to symmetric dialkyl derivatives of
mercury: a) Diiso-butyl-zercury and b) bromo-isobutyl-
mercury. Diethyl-mercury was obtained from sublimate and
triethylaluminum In hexane. Stannic tetrachloride yields
tetxa-i3obutyl-tin on the action of tTi-isobutyl-aluninum
in heptane at 40-480C (after decomposition by a VaOH-aolution)~
Besides, tri-isobutyl-tin-oxide can be isolated by distil-
lation of the rest over sodium, apparently by dehydration
of the corresponding hydroxide,, Thus (iso-C4H ) and (iso-
C4H9)3 SnCl for; in the case of Interaction o? tri-isobutyl-
aluminum and stannio tetrachloride.
There are 14 references, 1 of which is Slavic.
Card 3/4

The Utilization of Aluminum Trdalkyls in the Synthesis of 20-2-20/50
Elemental Orgatic Compounds
ISSOCI.&TION: IMBtitute for Element Dreamic Compounds AN I)SSR
(Institut elementoorranicheskik)i soyedineniy Akademii nauk
SSSR)
PRESENTED: By A. N. Nesmeyanov, Academician, May 8, 1957
SUMITTED: May 7, 1957
AYAILABIE: Library of Congress
Card 4/4

ALTNORS: 41akharrkiri, L. I., Gavrilinko, V. V., Okh1ohyGtin,O.Yu. 62-1-18/29
TITLE: The Action of Tr-letbyl ldw~dnm, and D-iisobutyl Liuminum. Hydride on
Metal Chlorides of Grow VI in the Frosence of Carbon Eonoxide
01' tllu ardTuii;stt:n Carbunyls
U,
(Dey.stviyo trietila-juiiiniya i (iiizobutiluljui:iiniy,,,,idi-ida na
khloridy metallov VI Crappy v prisutotvii okici uj;l~jrodn.sirltez
karbonilov khroiza, molibdena i vollfraLla)
PERIODICALs Izveatiya Ali SbSR~Otdoioniye Khimicheukikh Fauk, 1958
Nr 1 , pp loo - 1o2 (jsoli)
ABSTIUCT: The action of triethylalurainum and diisobutylaluminumhydride on
the above mentioned chlorides was for the first tine inveatigat-
ed by Jab and Cassal (reference 1). Both found, tli--.t carbonyles
of chromiu-m, nolybdenum, and tungsten are formed in the reaction.
Later this method was inve-Btigated by means of LangnesiuL-orGanic
compounds, i.e. in dfferent varianto. The authors rihow in this
paper that for the obtainin,", of Cr(CO)6, T'Ok'CO)6 and "006
triethylaluminum and diisobutylaluminunchloride can beized with
Succenn., i.e. in carrying out the reaction of the chlorides of
L
the m'talo of the 6th group with triethylalumin=a in etheric
solution. In the reiction under the same conditionJ with diiso-
Card 1/2 butylaluminumhydride Cr(CO)6 aPd 110(CO)6 wi~r4D obtained (with a

Tho Action of Triothyl AInninLm an I Diisobutyl ;%lu;n1num Rydride on 6," - 1- 1012)
Yetal Chlorides of Group 71 In -the Presence of Carl.~on 2onoxide. Syntiic.An
of t1v Chromiu::;, - n~olybderium-, and, Tangsten Carbonyls
yield of 73 - 75~u) The 3ynthenis of the triethylaluminum and
triiBobutylaluminuia (of w!iich diisobutylaluninuiahydride was
produced) woo carried out by the authors correspondir'.;-, to the
reaction of Ziegler, Gellert, Zosel (reference 5) frou, alurainum,
hydrogen, and the corresponding olefin. There are 1-1 references.
ASSOCIATIONi Institute of Elemental-Orfanic Compounds, AS USSR (Ir-.-,b'Ltut
elementoor6anicheskikh c3oyedineniy Akademii nnuk SOS-R).
Sb'B;.-:ITT.ED: July 12, 1957
AVAILABLE: Library of Congress
1. Triethylaluminum-Syntbesis 2. TrUsobutylaluninwn-Synthesis
3. Chronim carbonyl-Synthesis 4. Mol7bdenum carbor*'I-Synthesis
5. Tungsten carbonvl-Synthesis 6, Diisobutylalumininihydride-
Production 7. Notal chlorideB-Chenical reactions
S. Trielbylaluminum-Chmi-cal. reactions 9. Diisobutylaluminumhydride-
Chemical reactions 10. Carbon monoxide-Applications
Card 2/2

Sov/63 - 3.- 6 -

AUTHORS: !~arkevich, TVA irents--_ I Candida-yezi of Chemical SC-1 en-
cez, Okhlob7otin, O.Y-a-
TITLE- Conference on Iletal-Organic Syntheoo3 (Soveshchaniye ~o
loorganicheskin sintezam)
PERIODICAL: Khimicheskuya nauka 1 1~roL;yshlenno3t'. 1015C., Vol III, 111'r 6,
p C-21 (USSR"
In june 1956 a scienti-fic-technical conference took -place ~n
nloscow dealing with metal-organic syntheses of aicoholi, :_-0TX-
merz, acid3, etc The conference vaj atterded by 50
ists from 10" different organizations. The followir,,-,
presented, O.Yu. Okhloby.,-.tin,, L.I. Zakharkin, Institute of
E! enent -Organic Comyounds. "'11he Use of 1.1uminum-Or.,-:,nic Co.-'~-
pounds for the Synthesis of Other Ele-merst-Organic Comuounds";
V.V. Gavrilenko, L.I. Za)(hrirliin, Institute of
Compounds, 11~yntheois of C~irbonic Aci(13 and Alkylhal
on the Biui3 of Aluminumtrialkyls"; I.M. rl'.horlina, L.1,
Za'Yr'-_-r3,in, Tn3tltute of Elcment-Organic Con;pounds, "Proluction
of Aldehydes -From 37.14tryls and Dcuble-Deco=.rcsed A_-id(,,S by D-4-
i3obut-~" 1-~' lur.-.4' Pr~duvtion"; V.Y. ~isituin, St~,.te
3 12 CommittQe for nf he USSR Council of

112t-nd:, of the of Inluzo-trial Production v~
cthyl-Lnud b..- t'-e E'2Lctrel.*75i~; of Compounds of Tr-i.-
etlh~-I,Aluminur.,"; C"-rLcrov, 1".". Chowych-alova, A11-1,Trion
Scientific M~sc-arc,, Institut-e of 1,,Ynthetic Rubber,
of '1_7 ~ethyl-but~ylen-l anil 2-A:1,i1bUte1,-1 on t1-:0 Baois of Pro-
1,ylen, Ot -Butylcn a%,,1 17ith tho Applic%tion of '2r,` -
ethyl-Alumin,="; '.:.I. Farberov, S.I. Kr~-ul:ov, Kutlin,
"Selective of Propyl.-M and Its [Joe in Tecl,.iloal
I nhe,-es"; A.1% Slad:-,ov, V.A. 7Tarkev_ich, Scientific Resc,-. c
Institute of 5.,-nUetic Alcohol.- and OrZanlc Prodnots, "P.~,,)-
duction of ificher Alcohol's From Oz-,,anic Cor!T,,Qur:(1!3 of Alum-nw..".
It hao been recommended to install an
plant for the production of 3inple alk.;ls and pure suzsr_cr~cl
aluminum whicli are necded for netal-orcanic -l,,nthesis and
are not available in the necessary quzxtitics. Col,~Oluia
Ca-l 2/2 ohol-ld be arrznced at intervals of 4 011ths.

AUTHORS: 0kh!,-zjs1.in- 0. 7u., Zakha,.*k-,.-,, L. 1. 50-1/62-58-5-1j,/2-2
TITL?-: The Action of Alumini-ar. Tz-lallkyls cn PhoNphoru.- lkz~
(Deyst-riye a1yum-.!Lni'Y-1V:ria1ki!-cv na trekhkliloristyy fusf:~)
?ERIODICAL: 12,,restiya Akademii nauk SSSR, Otdeleniyo khimicheskikh ra-,;k,
1958, 3r 8~ pp- 1006-1008 (USSR)
A3STRACT: The interaction of the aluminium. trialky13 with phosphorus
trichloride has been investigated only little up to no-m.
Organo-lithium-,magnesium-and 2inc compounds alkylato phos-
phorus trichloride to the trialkyl phosphines. In the intro.-
duetion the authors discuss the investigations carried cut
'by Xhaxash as well as the work on the effect of mercury dialky!
on phosphorus trichloride (Refs 2-4). The findings of this papar
are that after the interaction had taken place between the
aluminium trialkyls and phosphorus tTichloride all three stagea
of the alkylation of PCI 3 may be o'btained:
AiR 3 + PC1 3 ->R'PCI2+ It3PCI + 'R3Al.
In the present short report the conditions for the synthesis
of alkyl dichlorophosphines is described proceeding from the
Card 1,12 phosphorus trichlaride and the corresponding aluminium trialkyls.

SOV/62-518-e-15/22
The Action of Aluminium Trialky13 on Phoszhorus Trichloride
Theie are 9 references, 2 of which are Scylet.
ASSCCIAT103: lustitut elementoorganichesk.rkh sovedineniy Akndemii nauk SSSR
r-rms~-'~ute c~ 31amental.;-Organic CompounaB AS MR)
- -' '. I
SUBMITTED: Narch 5, 1958
Card 2/2

.07HORS: Zaakharkin, I., 0'khlob~rotr., 0. 1u. 2
TITLE: Regroupint-, of Aluninun TrialkylB (.PeregrUDpirovka alyuniniy-
trialkilov)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdoleniye khimicheshikh nauk,
1950, Nr lo, pp 1278 - 1278 (USSR)
ABSTRACT: The authors found by the example of triisopropyl oluminum
and tri-sec.-butyl aluninum that secondary al~;.inum
trialkyls regroup into primary alwminum trialkyls on
heatin;3. The described method of the production of
triisopropy'L aluminum from (i-C 3H7)2Hg and 4~1 doos not
only yield triisoprolyl alumin=2 an the authors suG.-coted
(Ref 1), but tilso the mixture of triisopropyl aluminuxi
and triDroDyl aluminum which can be separated by
fractionation. The triisopropyl aluminun produced in
this way can be completely converted to t~ipropyl aluminum
in a sealed ampoule. Tri-sec.-butyl aluninum, produced
in the reaction (sec. C 4H9 )2 HE; with aluminum can be
Card 112 converted under the same conditions by reGrouping into

Regroupino of Aluninum Tri all-1:y! a
tri-n.butyl aluminum. In thij case P-hutylene and di-n.
butyl aluminum hydride could partly form. Tri-n. but.11
aluminum could be identifii-A by neans of n.butyl
mercury bromide; boiling point 1360. There is 1 referencc.
ASSOCIATION: Institut ioyedineniy Akademji nnuk, SSS-R
(Institute of Ele!"W"'tw7 Organio Compounds AS UM)
SUMUTT-ED: June 6, 1958
Card 2/2

5(3) '7
AUTHORS: Zakharkin, L. I., 9~-_h~, Yu.
TITLE: On the Reaction of Realkylation in the Aluminum and Boron
Trialkjl Series (0 rea~-tsii perealkilirovaniya v ryndu
alyunimiy- i bortrialkilov)
PERIODICAL: Izvestiya Akadenii nauk SSSR. Otdelt-niye khimich2nkikh n-u!.,
1959, 11, 1, PP 181 - 181 (USSR)
ABSTRACT: The nuthoro write in a
alkyl or triaryl boron
a reaction of realkylation
products of incomplete
aluminum are formed:
letter to the cditor: On Ac-antirC, tri-
R-B with triall,yl nluminun R1 'A I
3
occurs. Thus R' 3B, R3'11 ond
realkylation of initial trial!.-yl
R 3B+R I al --4 Ral + R 13B
al= 113 Al; R= n-C 4 R9; '-C4H9' C6H5; R'= C113 C 2H".
Mecaune of the high reaction temperature (120-18~)o) thc, le-
fin ic separated from the R Al forned in some cares to a
Card 1/3 considerable degree. Conneq~ently correspondino ~ialkyl

On tht, Reaction of Healkylption in the Aluminum and Boron '1')0V/62-5')-1-57/,-,)C,
Trialkyl Series
aluminu-m hydridev are produced. In the interaction of
triisobutyl boron with triethyl aluminum, for inst-.nce,
triethyl boron and diisobutyl aluminum hyilride were obtainel.
On gradual heating (up to 1800) of the nixture of triphenly!
boron with a double quantity of triethyl nluminur. triethyl
boron is slowly distilled in pure nitrogen current. After
the distillAion of the -mixture (C 2H5)2 AIC6H5 and
C,H Al(C H in vacuum triphenyl aluminum remains in the
IL 5 6 5)2
residue. Under equal conditionn, trimethyl boron ic
sized from (C H 'B and (CH Al rith P. yield of Tri-
6 5)3 3)3
methyl boron is slowly separated on heating the mixture of
trimethyl aluminum and tributyl boron up to the boilint;
point. The tributyl aluminum beino produced contr.,ins tip to
25~o dibutyl aluminum hydride. In the interaction Df tributvl
boron vrith triethyl aluninum triethyl boron an(I also a
nixture of t-ributyl aluninun and dibutyl altiminum hydride
is forned which contains 50,~~ of the latter.
Card 2/3

"C - 'z ~ / 7 r~
On the Reaction of Realk7lation in the Aluminum and Boron j V
Trialkyl Series
ASSOCIATION: Institut elernentoorc-anicherkikh coyedineniv AkaJcmii nauk
SSSR( Institute OfZl,-Z*_ntnl )r!-anic Compolln"s of the Aca~e-y
of ScienceE, US'R)
SUBMITTED: September 9, 1958
Card 3/3

50Y
MY/62-59-6
AMOFSs Zald.,arkin, 1. 1: -32/A9
TITLE& Synthesis of Bwmtrialkyls by the "tion of Organo-netallio
Com.pmmds on ~,ue FAters of Ue Metaborio loid (Polucheniye
bortrialkilov deyatviyem netalloorganichaskikh soyedinenly na
efiry netnbornDy kialoty)
PUIODICALs Izvestiya Ikadeaii 3aauk SSSR. Otdeleniye lr*h4--4ohezkikb nmek,
:1959, Nr 6, pp 1135 - 2136 OSSR)
ABSTRACTs Me reaction mentioned in the -title has hitherto hardly been
investigated. In the present investigation the borotrizlIyls frou
alkylaetaborates (RM), (wi-+,b R27CH~, zwC JL) vi-tb aluminim
3 4-9
trialkyI3, mime dialkyls and nagnesiumbalold alkyls were
ryzthetized,
(HBO) 4- JURY -4 P +11
3 3 B? 203+ (M)3A" R's !CO5' "Y9
+ZnO + (RD) I
(BMO)3 + Znl~ -4 'j'R in) " zr-~' Y7
CHMO~ + RIXA ---) 13 4. w + x9 4-W*X, ILOX.P.
Ri '4S'
2he reactiona occurred witb higb y1eld. In the erperinental :p~
the methods for the production of borotrialkyls an daroxibed.
C&M 1/2 The yield in borotrialkyls obtained by different methods is

Synthesis of Bxo#trialkyls 1y the Aotion of Org=o-uetallic 307/62-59-6-33/36
Compounds on -the Estera of the 21ataboric Icid
:given in a table. There are I table and 2 referenowi, I of
vhioh is Soviet.
1=CUTICIS: Inatitut elementoorganicheald1b soyedlm~niy Akadeaii nauk SSSR
(Institute of XlzmerUl Orgarde Conpounds of tbe kadmjr of
3clences, U33R)
SUBaTTEDt Deoember 24, 1958
Card 2/2

8229
113/079/60/03P007/004/020
13001/33063
AUTHORSt ZakhaTkin, 1. 1,, Okb1obystinj Of Tub
TITLEs Reactions of the Alkyl Exchange in the Series of Elements
of the Third and Second G:rOUPB (Al, 13, Zn, Mg)
PERIODICALj ZbuTnal obBhchey khimil, 1960, 701- A No- 7, pp. 2134-2138
TEXT: Suffioient,y c;n7enient methods are n w available for the conversion
of organoaluminum com oundB into organoboxon compounds (Refs- 1-4), whereas
c
the reverse proce s has not yet teen possib e. The authors of the piesent
8
paper attempted to exchange the radicals between organoboron and or8ano-
aluminum compounds. The reactions uf the exchange of alkyl derivatives of
different metals (Refs. 5-8) are well-known, especially those of lithium.
This Is also the case with some alkyl derivatives of sodium and mercury
(ROfB. '7,8). Apart from the exchange reactions between 132B6 and
(Y5)3 Al$ as well as C? 5MgX (Scheme 2), which were deBcribed 'by E. Wiberg
and P, BtTibel (Bef, 9), such reactions have hitherto been unknown for
aluminum- and 'boron trialkyls. The exchange reactions of the 7-adica3s
Card 1/3

82294
Reactions of the Alkyl Exchange in the Series S/079/60/030/007/004/020
of Elements of the Third and Second Groups 10011BO63
(-Al, 13, Zn, Mg)
between aluminum- and boron trialkylB were studied by the authors 1y a re-
action of triethyl aluminum or trimethyl aluminum with boron txiallyls
and boron triary2s according to the scheme 2 Al -+ RIB ;-~P Al + 2 1. The
3 3 3
reversible reaction may take place with a complete exchange of radicals
if the more -volatile component is removed from the reaction zone. It may
be assumed that this reaction proceeds in the following stageV3
R Al + -RIB-)R RIAI + R'R3j R RIAI + R'I->RR';Al
3 3 2 2 2 3 + R21RB'
RIB + R B
3 3
The authors studied exchange reactions of triethyl- and trimethyl aluminum
with tripheny! boron, tributy2 boron, and triiBobutyl boron. The mechanimm
of radical exchange between or;ganoaluminum- and organoboron compounds could
not be clarified. It was found -that alkyl exchange also took place between
organoaluminum- and organozinc compounds as well as between oxga-noboron-
and organozinc- or organomagnesium, compounds (cf. the three LaBt-mentioned
schemes). There are 13 referenceB, 4 Soviet, 4 Gernan, 4 IJSp and
2 British.
Card 2/3

82294
Reactions of the AA'kyl Exchange in the SorieB 5/079/60/030/0071'004/020
of Elements of the Third and Second GrOUPB 3001/M63
1
kA2, B, Zn, Xg)
ASSOCIATIONj InBtitut e1ementoorganicheBkIkb avyedineniy Akadenii nauk
SSSR (Institute of Elemental-organio Compoumdr of til
Academy of Sciences 'USSR)
SUBMITTEDs JulY 8, 1959
Card 3/3

CXHLOBYSTIU, 0. Yu.
Cand. Chem Sci - (diss) "Synt'l-le-sis of eleiLento-orgaric co.:ipounds
with the aid of aluminum alkyls." Moscow, 1061. '/ pp; (Eoscot-.'
Order of Lenin and Order of Labor Red Banner State Univ imeni
F. V. Lororosov); 120 copies; price not given; (KL, 5-61 sup, 177)

S/026/61/000/004/002/002
A166/A127
KUTBORS: Zakharkin, L.I., Doctor of Chemical Sciences, and
Okhlobystin~ 0.7u.
TITLE: Aluminum-organic Compounds
PERIODICAL: pxiroda7 no. 41 19611 89-92
TEXT: The autbors describe the properties of aluminum-organic
compounds and their uses in the polymerization of olefines, 6pirit
production and the synthesis of carbonic acids. The Institut
ele,mentoorganicheskikh soyedineniy AN SSSR (Institute of Elemental-
Organic Compoundss AS USSR) has found that carbonic acids can be
produced b7 the action of dioxide on aluminum trialkyl at high pres-
sures and temperatures:
(C2H 5)3 A' + 3C02 --2-(C2H 5COO)3A"
Card 1/2

Aluminum-organic Compounds
S/o26/61/000/004/002/002
A166/A127
'The method can be used to produce higher fatty acids uued in the
manufacture of synthetic detergents and emulsifiers. The use of
aluminum trialkyl gives higher fatty acids of normal structure and
-without side branches which do not give lats toxic to the human body.
Thus the method can be used for synthesizing edible fats simply frow
crude oil. It has further been found that aluminum-organic compounds
can be used to synthesize alkyl derivatives of zinc, caumium, boron,
gallium, Bilicon, germanium, lead, tin, mercury, thiillium, phospho-
rus, arsenic, antimony and bismuth. The method has been used to
produce tetraethyl lead, valuable as an anti-detonator in motor
fuels. There is I diagram,
ASSOCIATION: Institut biokhimil im. A.N. Bakha AN SSSR (Institute
of Biochemistry imeni A.P. Bakh, AS US"-R), Moscow.
Card 2/2

ZAKHMUD, L.I.-, STANKO) V.I.; OEHLOBYSTIN O.Yu. .
Reactions of decaborane and pentaborane vith nercapta-3 and sulficies.
-Tzv.All S5SR.Otd.k1him.nauk no.1l.-2083-2C84 'N 161, (XIRA 14:11)
2. Institut organicbeskoy RhAnii A-m. N.D.Zelinskogo I Instit,it
elementoorfanicbeskikh zoyedinenly AN BSSR.
jDecaborane) (Pentaborane) (Sulfides)

30168
s/o62/61/000/012/000/012
7 (-) C) Bl!7/Bl47
AUTHORS: Zakharkin, L. I., Okhlobystin, 0. Yu., and Strunin, B. 11.
TITLE: Synthesis of organic beryllium compounds
PERIODICAL: Akademiya nauk SSSR. I7vestiya. Otdeleniye khimickle:3kikh
nauk, no. 12, 1961, 2254
TEXT: In the present "Letter to the Editor", the authors report on studies
of the noncatalytic interaction of metals of the 2nd group with halogen
alkyls. Powdery beryllium was found to react with halogen alkyls oven in
total absence of ether or any other catalyst. With sufficient duration
of the process, alkyl beryllium halides are obtained in satisfactory yield:
Be + RHal 1300C -> RBeHal
12 - 60 hr
R - C2H5v Hal - I; R - C 4E90 Hal - Br, 1; R - C5H ill CaHl7v Hal = 1.
Similar to alkyl magnesium halides, alkyl beryllium haliden are insoluble,
and separate as a precipitate during the reaction. Analysis shows that
Card 1/3

303M
S/062/61/000/012/009/012
Synthesis of organic beryllium... B117/B147
the yield 0g. butyl beryllium iodide reaches 65-70% of the theoretical
amount (17 C
,0 9 12 hr. without solvent). During reaction of the obtained
alkyl beryllium halides with cyclohexanol the correspordirgl-alkyl cyclo-
hexanols are formed in a good yield:
/ OR
:~K R
H = C H boiling point 61 0C (10 mm Hg), n 25 1.4623; d250.9226; R = C 1199
2 5$ 0 25 D 25 4 4
boiling point 90 - 91 C (10 mm. Hg); n D 1'4635; d 4 0.9141; R = C 5Ells
boiling point 970C (5 mm Hg); n 20 1.4667; d 20 0.9162; R - C H boiling
D 8 17'
point 130 - 131 0C (10 mm Hg); n25 1.4610; d~5 0.8633. Abstracter's notet
D 4 1
Essentially complete translation .I There is I non-Soviet reference. TLe
reference to the English-1 anguage publication reads as follows; H. Gilman.
W. Schulze, J. Amer. Chem. Soc. 49, 2904 (1927).
Card 2/3

3010
S/062/61/000/012/009/01-
Synthesis of orgAnic beryllium... B110147
ASSOCIATION: Institut elenentoorganicheskik)i soyedineniy Akademii nauk
SSSR (Instituteof Elemental Organic Compounds or the Academy
o-117' Sciences USSR)
SUBMITTED: October 26, 1961
Card 3/3

30169
S/062/61/000/012/010/C)12
B117/B147
AUTBORS: Zakharkin, L. 1., Okhlobystin,___P_,__Tu,_, and Strunin, B. N.
TITLE: Organic magnesium synthesis of elemental organic compoinds in
ether-free medium
PERIODIUL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
- 2255
nauk, no. 12, 1961, 2254
TEXT: In the present "Letter to the Editor", the authors report or, studies
of noncatelytic organic magnesium synthesis. It was found that mafnesium
easily reacts exothermically with halogen alkyls either without a -olvent
or in various paraffins, and that for the synthesis no specific solvents of
the isopropyl benzene type are required. Organic magnesium synthevis in the
absence of ether was used for the production of various elemental organic
compounds by one- and two-step synthesis of (aryl) derivatives of a number
of elements: EXn + n!U) gX ERn + nMjSX 2
EXn + nNg + nHX ERn + nNpX2
Card 112

30169
11
Organic magnesium synthesis of... B117/B147
R - C 1Y n-C,119; V E = H9, B, Al, !3n, Ge,
2 '_C51111; n_^61113; n_C017; C6H5;
Si, Sb, P, As; X = Cl, Br, I. The yields of elemental organic compounds
amount to 70-90%. P. Shorygin is mentioned. [Abstracter's note: Essentially
complete tranalation -1 There are 4referencess 2 Soviet and 2 non-Soviet,
The two references t . English-language publications read as follows: M, S-
Xharaoh, 0. Reinmuth, Grignard reactions of nonmetallic substances, I;,, Y,
1954; D. Bruce-Smith, G. Cox, J. Chem, Soc. 1961,
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR
(Institute of Elemental Organic Compounds of the Academy of
Sciences USSR)
SUBMITTED: October 31, 1961
Card 212

ol ~o
S /07 0/61 /031 /01 J/ 011 --'0 15
~22811'11365
.AVTJIOJIS L.. 1-
TIMY-I S.Tntbesi3 of somp zoetalloorg"it compounds by meaw4 of
the alumimo trialkyla
ITRIODICAM3 Zhurnal obBhebey kbjmij,, w,, 31,, no,, H, 1961 3662-36,65
TELT 3 Thiz stu~ay o1 -the reaction of triethyl and
vitb -the chlorideB of 2nt 13, Ga. 6e. and Sn is a continuation of
pre-vious research by L, J~ Z"barkin and 0, 'Yu., Okblobyatin (Rof , 1,
DokI. AN SSSR~ 1169 236, 19-57; 2b. obshch,, kbimii,, 30., 2134., 1904)) oil tl-~-
ust vf alumbio trialkyla Ir. the syntbesim of metalliorgan3c compolln"If-
Anhydrous 2aCI2 'ran reacted with Mt3&1 by btating tht% inixtu r,~ f,) - 3
hTo at 10,0*9 the dietbylzinz then being separate:] from 4b.- F! XI! by
1 2 It
-vacuum distillation,. The reaction As rf-Rersible since the niAborg
1), prepared a mixturs of *tbyl- and diettly3aluminum cblorid,* from W.C.1
and Et n. Trimethylgallium Tars syntbasiz.'5d from Mik M anI Gac".
3
Card 1/3

S~yntbesia of 3ome-.
sj/070/8-t /031.1011./0). oo
D,228/D363
by heating the mixture for 2 br,, at Se amd distill Amg,,,lff th-? 4~j
In the onag of tatrziatb7lgermanium, the originai mat-erials.-E* .3 A:i, iv.1 I
041 -mere boated for 8 br, at 120 - '030 aftPr whi,.)) Vni~ tanloill.,)-i -v~
diluted vitb ,ttbor and docomposed by NaOll; TAP. tbro d i ~s t I -I to, If t
from the washed and dried ether It-yer similn:- I
in the pro parvition of t P trfii SO bU IXI jl~ VIIIIIIIiiin frrm ro~ Coil') V~. ft
Vie rvrithc~;is of isobutylboren dichlor.,de invo!-~,s the interactiozi il~
BCI 3 ,and isti-DU3Al at 20 for approximately 1~5 br,,, fokJowid Vy thk.
gradual beating of the solution to room- t,~mp~- wNur t aiid lt~ .4ohqeqiiI-.f~-
distillation; etbylboron dieblaride -as .3ynthe6p~,z;-j f .,cj, 11031 r, :1
Z 4, 3Al at a temperature -of aboul, ...5 Thi 811010cs prepar-)
stannous oxide by 3tirring a solution o! coobydrous SnO~I wqi ).P,) Plj~ A~.
?, - I4!i0II PvAd tbi~ V~~
for 2 h, ai. 110 - 115 This wat Jarorjps~J by

S/079/61/031/011/011/01 5
Synthesis of some-, 3)228/D30'5
then ir*,.~Ied and dried; it muy be Ivrified bI.T reprecipitntion from an
HCl aolutiun -with NU 3~ There are 11 referencear 2 Soviet-bloc and 9
mon-Ewy-let-bloc. The references to the -1 most recent English--Innguag4
publicatioms read as followam C. 1, Kraus. B. A, Flood, J. An. Chem.
Soc., 54, 1635 (1032); Y; 13. Brindly, W. Geirrard, M. F. Lappert, J.
Chow. Sot., 1958, 824; P, A, McCusher. 6, F, Hennion. Z', A~ Ashby, J.'
Am. Chem. Soc,,., 79; 5182 (1957),, J. D. Bone-ycutt. J. M. Riddle J~ Am
Chem. Sot... 82, 3051 (IsGo).
SUBMITUID: November 18. IOGU
Card 3/3

ZAKIHAAKINI, L.110 doktor khim.nauki OXHILBYSTIN, D.yu,.
Alumimm organic oompoundo. -vriroda 50 no.,4:89-92 Ap $61.
OW 3-4:4)
I* Inatitut alementoorganicbeekikb isoyedi-neni7 AN SSSR,, MDkva,
(Alumimm organic oompounda)

3/062j62/000/011/007/021
3101/3144
AUTHOR53 Zakharkin, L. I., Okhlobystin, 0. Yu., and.Strunim, 1. N.
TITLB3 Use of organomagnaBium compounds for synthesizing organic
derivatives of the elements of groups 11-7 in non-ethereal
medium
2BRIDDICAL3 Akademiya nauk SSSR, '11-vastiya. Otdoleniye khimicheskikh
nauk, no. 11, 1962, 2002 - 2008 -
TZXT3 It is shown that ar-ganni-magneBium compounds are easily synthesized
from 3ag and alkyl halides in yields of 80-92~, even without the uBual
Grignara catalysts (etherv amines, etc.). Halides of the elements of
groups 11-V are easily alkylazed with the resulting organomagnesiun com-
pounds. The reaction was performed in N 2 by addition of alkyl or aryl
halides RX (R - C 2H5 to C9H191 C6H5' P_C23COY X ' C" :Br' 1) to nagnes"M
-chips and, as a rule, by utilizing the developed beat for the reaction with
the gradually added halide (or oxyhalide) or Hg, 3, 11, Si, Ge, Sn, P, As,
3b. The further treatment is carried out as in the usual organomagne31UM
synthesis. In some cases alkyl and element halides were made to react
Card 1/3

S/062/62/000/011/007/021
Use of organonagnaBium cozpounds... Z101/3144
simultaneously vith Mg. By choosing the appropriate solvents (heptane,
iBooctane, decalin, dodecane), work can be done at high concentrations and
optimum temperature. The folloving syn~hesez were mades tetraethyl tin;
triethyl tin fluoride was precipitated with XF froz the triethyl %in
halideB formed as by-products; tri-n-butyl boron, Yield 85%; tetra-n-butyl
silane, yield 79%; nethyl-(n-butyl)-phenyl silane from Mg vith n-butyl
chloride in heptane, and addition of (CH 3*63 5 )SiCI2' Yield 859~, b.p.
1250C/4 ma lig, n20 1.4930, d20 0.8749; tetra-z-1butyl tin, yield 90%; di-n-
.D 4
butyl tin oxide (additIon of SnCl4 at -1000, yield 65-A tri-n-butyl
20 20
,germanium chloride, yield 60,1,'v', b.p. 1040C/I = Eg; n,) 1.4638, d4 1.0252;
butyl dichloro phosphine 'addition of P01 a% -7000, Yield 45%, tri-n-
% 3
'butyl phosphine, yield 66%; tributyl phosphine oxide, Yield 84.4%; tri-n-
butyl srBine, yield 80-7%; tri-m-butyl stibine, yield 73%. triisoanyl
aluminum, Yield 87%, b.p. 1520C/I~mm Hg; triisoamyl tin fluoride (reLction
vitb SnCl 4' pret'p"a"On with a ), yield.82%; hexyl dicbloro pho2phine
(adaition of ni 3 at -700C), yield 46%; trihexyl phoaphins, yield 63%;
Car,a 2/3

3/062/62/000/011/007/021
Una of organonagnapium compounda... 3100144
n-octyl mercury iodidct, yield 65%, m.p. 96OC; trioctyl phospins oxides
(a) from zagnsium and with simultaneous addition of n-octyl iodide and
POCI3 in i-cctanef yield 85~;; (b) from iodineactiyated Mg and n-oc%yl
iodide in i-octane, and with addition of POCI 3 after cooling to 100C,
yield 67~; zri-n-nonyl phosphine oxide, yield 92.4%, a-P. 35-360C, b.p.
235-240OC/4 m= HS; triphenyl aluminum, yield 75-3%; tetraphenyl tin, yield
74343 triphenyl phosphine, yield 72-3~; triphenyl phospine oxides yield
92.2~; nothyl-di-p-tolyl phosphine.-oxide, yield 80%; triphenyl arsine,
Yield 75-7%- The =oB* important English-language reference is: 1). Bryce-
Sxith, G. F. Cox, J. Lem- Soc-, 1958, 1050. .
ASSOCIATION3 InBtitu% elezentoorganichookil;h so"yedinaniy Akademii zauk SSSR
(Instl%ute of Elemental Orgamic Compounds of the Icademy*of
Sciences USSR)
ZUBMITTED3 Xarob 22, 1962
Card 3/3

ZEMARUN3 l.l.; 0' SMILYI'STIN D,lu,; - STRUI IN;, D.N.
Synthebis of organometal2ic compmnds -A, a organomagneslum, co--l'ox-do
in an other-free medium. Dok:L. AN SSSR. -14A no.6:-1299-3.302 Je
162. (11 DU -15: 6)
1. Institut element,;organicbeskikb spyedineniy Akademii rgiuk
SSR. PredstaylenD akad. A.H.Ilesme~nmovyz.
(Organometallic compounds) (ivagneBium organic compowds)

ZAKHEMN, L.I*,, 0191LOBr>TIH, 0.7u,; STRUNIN, B.N,,
lb:,eparation,ofalIql mainselum baUdes from primary
alkyl halides and magnesiim in a hydrocarbon zAl=,
Dokl. AN SSSR 147 no.1:108-220 B 762, 04IRA -15:21)
1. InstitUt elementoorganichealcilch soyedineni), AN SSSP.
Predstav2eno akaaemikom I.L. Knunyantsen.
(MagneDium organic compounas)
(Alkyl halides) (Hydroe&Tbons)

S106216.5100010011022102c)
B101/B186
AUTHORS: Zakharkin, ~L. I., and._Q blobystin. 0. Yu.
TITLE: synthesis of organozinc conpounds in 3olvating (solventis)
PERIODICAL: Akademiya naiak SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 1, 1963, 19~
TEXT: Rhen studying the effect of solvents on the reaction of metals with
nl'Ayl halides it was fqund that the reaction of In with alkyl halides be-
came greatly accelerated by the presence of solvating media such as dimethyl
ether of ethylene or diethylene glycol, dimethyl formamide, dimethy]. sulf-
oxide, etc. In such solvents the alkyl iodides RI (R - CH C 1i n-C H
30 2 51 3 70
i-C 3H71 n-C 4 H9) reacted spontaneously and e*xothermi~ally with commtrcial
zinc dust to form the corresponding, alkyl zinc iodides in high yields. As
regards their accelerating effect the oolvents cgnq In the orders iao-
octnnsa