SCIENTIFIC ABSTRACT OBOLENTSEV, R.D. - OBOLENTSEV, R.D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001237710015-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

On the Chromatographic Liberation of Aromatic Hydrocarbons 2o-114-4-34/63
From Their Mixture With Organosulphur Compounds
11 ASSOCIATIONt Department of Chemistry of the Bashkir Branch of the AS USSR
(Otdel khiihii Bashkirskogo filial& Akadsmii nauk SSSR)
PRESENTEDt December 25, 1956 by B. A. Kazanskiy, Member, Acadegy of
Sciences, USSR
SUBMITTEDs December 25, 1956
Card 4/4

UM 74WE I 1300K EXPWITATION SOV/1319
Afradmiya, vAak SM. RasWdrskiy filial
Khimiya servporp"Owsk1lo soyedinenly, soderzhashchikhays v neftyoLkh I
neftaprodukta*,; materialy ;I nauchnoy sessii (Chemistry of Oulfur-
Orgaide CowMaunds Contained in Petroleun Products; Papers of the 2nd'
Scientific Session) v. 1. Ufa, Izd. Bashkirskogo, filials, AN SSSR, 1958.
228 p. 1,,5W copies printed.
Ed.: Sudarkina, X.I.,- Editorial Board: Ayva-tov, B.B., Mashk-in , AN.,
Obolentsev,, 26D. (Reap. Ed.), Rozhdestvenikiy, V.P., and Bhanin, L,L.;
Tech. Xd.: YOJ&Iwv, R. Mi.
PURPOM TMv 4m* is intended for petrolem specialists of scientific research
establlobwea, educational institutions, and petroleum refining plants.
COVEPAGN; Me aWleation is the first of a multivolume publication on the results
of scientific research work carried out in the Soviet Union on the chemistry and
techno1X4W of sulfur- iad nitrogen-organic ccopounds during the period 1954-1955;
and accox" to a coordinated research project outlined In 1956 by the sponcering
Card 1/15
1

Chadstr7 of SqUEwo-Orgstdc compounds (cont.)
sancy (PA",r Branch of the Acadeaw of Sciences USM).
ports VabIlsheA herein, abridged versions of questions,
am given wherever the editors dej!m it expedient.
TABTZ OF CONTIMM;
Fran the Witors
SOV/1319
Along with the 22 re-
answers and discussions
3
Opening Address by the flead of the Chemistry Departne~xt of the Bashkir
Branch 9f the Ac4dd" of Sciences, USSR, Professor R*D* Obojentsev 5
The autAor states that three-quarters of the pet-r-oTe-un drilli4j in the
USM Is concentrated in eastern ("vnek&vkazskiy1' - outside the Cauangs)oil
fields; that theme deposits am sulfurous; and that research on the
exploitation of these deposits Is insufficient.
Gbolentsov, R*D* 84fur-Organic Compounds of Petroleun Origin
Ms artlojA points gut the need for a new process of directly distilling
sqlfurous p*tr*1*q%,vh1ch process, it is stated, may be based on the
thwwastabAlIty of sulftir-organic canpounds.
Gbolentsey R,D* w4 D.V. Ayvuov, Cyclic SuLfides in the Kerosene Distillate
of Petralew Frm t4s Carboniferous Deposits of Ttqmazy Ollfields 19
Card 2A5

Chemistry of SuLfUY60rganic Compounds (Cant.) SOV/1319
Sulfur-orgmic compounds were separated frain kerosene fractions of petroleum
and pbysical constants (including molecular formulas, refractive Indices, etc.)
were determined corresponding to amo-, bi- and tricyclic sulf1de~. ftyerizental
data on the fractional dIstillation of these compounds (which vaporized at
209-2100 C) compared with, kmw data identified tban as 3-but71th1qj;hanes
[tetrehydro 3-butylthlophems). A.D. Biktasheva and U.S. Lyubopytove. carried out
the spectrographic analyses.
Ivanova, N.M., Ch. Kh. Hirkhaydarova. and Ya. I. Hellkenbaun (IshiAbs"kiy
nefte"re -- hcbdy zavod--l-hi aor Oil Refining Plant)
Insta,11ation for Chromatographic Belaration. of Sulfur-Containing CcnWunds
?ran Petroleum Distillates 29
Illustrations, schematic diagrams of apparatus and a table of data are
given for the chromatographic analysis of the sumW content of
Ishl 4W petroleum after Wrolysis.
GorakV%,, N.G. (Novo-Uflmkiy.n~Sto"rorebatywaytwiicbiy za6vod -- Nov Oil Reflaing
Plmt-'at We) On the ProblAm of onstructing Larger Chramatographlo Inst"timm
for Separating Concentrates of SuMw-Orgenic C=VowAs fton Fetrolaw Products 38
Card 3/15

Chemistry of SulfrAr-Organic Compounds (Centj SOV/1319
Ton tons of petrolem material v1th a sulfur content of 0.15 percent was
processed by the chrmatogrephle mthod with a separation yield of TO percent
concentration of sulfur-organle compounds amounting to 80 liters after 9 months
(approximately) of continuous operation.
Skripaik, Ye. 1. (Kujbyshevskly Industriallayy institut -- Mqbyshev Industrial
Institute). Thermal Stability of Sulfur-Organic Compounds of Sulfur-bearing
Patrols= Pros Mobyshe"kays, Oblast 1 43
According to the author, Mqbysh*vnkW oblast' ranks third In extracting
and reMil patrols= In the Soviet Vulon during the Sixth Five Year Plan.
Separation of sulfur-orgenic campowAs from theldWftly sulfurous patro-
leas of this region (3-4.5 percent; tar - up to 22 percent; and In
asphalt-tar - up to 100 percent 8) was accomplished by ~pvo methods: 1) decompo-
sition of complex sulf~w-orpnlc compounds 2) reaction 6f elementary sulfur
with bydrocartow - Mw f1ret process *took place at 3500 C Gold 601vi ImmadEms
sulfur-compound formation at 400* C and higher. The second process took place
at 180 - 2200 C with a high yield of sulfw compounds. Tabular results of these
processes axe giren.
Agolentsev. R.D. and B.V. Ayvazov.Therzal StablUty of SuLfUr-Orgenic Compounds
Contalmed in ARrolem Fromt the Tuj=azy 011field 51
Card 4/15

Chemistry of Sulfur-Organic Ccmpounds (Cant.) SOV/1319
Two types of patroleun (from ea--boniferous and Devonian deposits) vere
heated (150 - 300* C) and gr*yEd, tables and equations are given for the
separation of petrolem t~cmpoaadz with respect to heating time and tempera-
ture,
Zakharochkin.. L.D.,and S.T. Meshcheryakov,( Gosodarstvennyy naachnoissledovatel'skiy
i proyektnyy institut neftyanogo tmashinoBtroyenlya,--State Scientific Research and
Planning Institute for Petroleun Machinery Building). On the Problem of Evaluating
the Corrosive Properties of Salfctroua Petrolem, 65
oil,from various horlzonB (Devonian, Carboniferous, Upper Permian, etc.)
of Ukal-Volga deposits vas tested for free sulfur content, yield of HPS
on distillation, and speed of corrosion of steel (the latter two factors
vere determined at temperatures up to 350" 0. The jr4rpose of the investi-
gation was to establish critee-a for selecting, storing, transporting and
refining sulfurolzs petrolein trcm different fields. N.V. Tokareva,
O.V. Kallntna and G.G.Zhakovn, assiatedin the experimental work.
Chertkov, Ya. Bj and V.N. Zrelov, Nauchno--Issledovatel I skiy institut gor7uche-
gMgL7ochnykh materialov--Scientific Research Institute for Fuel and Lubricating
MaterM). Activity of Sulf'ur-Orgaaic Compounds in Relationship to the Ketal
Card 5 15

Chemistry Of Sulfur-Organic Compounds (cont.) SOV/1319
of tie Fan! System of Gsa-T=761ne Engines 69
V*xiouti fuels from the ligroin-kerosene fractions of petroleum, pro-
Auar= of both direct distillation and thermal cracking, with an aver-
age content of sulfkr (0.12 - 0.94 percent), mercaptan (0-004 - m6o
percent and elexentM sulfur (0.001 - 0#010 percent), were Investigated
for corrosive, resin- and residue-formIng properties in relationship to
copperP bronze, cadmium, zinc and chromium-steel alloys with various
surface finishes (altrided, casehardened, etc.). Illustrations of
laboratory apparatus, graiphs of the corrosive effects of elementax7
sulfur and aliphatic and- aromatic mercaptans., and tables showing the
content of these substances In bjels are given.
Tayte, S.Z. (Institut organichesko-v kh'-Ji AN SSSR--Instutute of Organic
Chemistry, AS USSR). Synthesis of Compowids of the Aliphatic Series on the
Basis of Thlophene and Its H(mtologs 80
The author states that ta2 from Povolzh 'lye (Volga region) shales and
sulfurous petroleum may serve as inexhaustible sources of thiophene
and its honologs. Reaction diagrams are given for the synthesis of ali-
yhatic compounds from this material, which yielded C4-hydrocarbons,
higher alcohols, glycolB, acids, ov7-acids, and other amino
acids, amino dicarbaxylic ac'-dB, tertiary amines, amino alcohols, simple
esters, etc.
card 6/15

Chemistry of Sulphur-Orgsaic Compounds (Coat.) SOV/1319
Obolentsev, R.D., S.V. Ketupskaya, L.K. Gladkova, V.G. BWdiarov, =d
A.V. Kash-kfn-a. Synthesis of Several Sulfur-Organic Compounds of the Type
Contained in Petroleum 87
Thirty different sulfur-organic compounds were synthesized to facilitate
the investigation of the negative effects of those compounds In the ex-
traction and refining of petroleum and to work out rational means for
petroleum desulfurivation. Synthesis reaction diagrams and physical
constants or the synthesized canpounds are given.
ObQ1entsev, R.D., S.V. Netupskaya, N.M. Pozdayev, and Ye. V. Vafina, De-
temining the Degree of Purity of Synthetically Prepared Sultur-Organic
Compounds 95
This investigation is based on the cryoscopic method. From an initial.
&H
approximation, 112 Nbers: H2 -mOlar Mount Of
7-
FL 0
-1-Irture with respect to a decrease in freezing point; C~T = To _ TV
K'j T - freezing point of a'pure substance, K; T, - freezing point
0
Card 7 15

Chemistry of Sulfur-Organic Compounds
0
of the ample substance, k; 3 fu
(Coat.)
SOV/1319
- beat of fusion of a pu" 3Ub-
stance at T., Cal/mol; R- go& ccnstant,~cal/aol degree [%'], grvpha and
tables of freezing point, purity, and cryoscopic constants are. given.
Schematic drawings of laboratory set-ups are included.
-,Qglentsev, R.Djand N.S. Lyubopytovs. Absorption Spectra of Several
Sulfides-d-n-d-Woulfides in the Ultraviolet Range
This invest1gation was. carried out because available data on this sub-
ject were obtained und r varying conditions, the practical application
of such data being extremely difficult.
Baybeyevs, S.T., V.P. Muzychenko, and N.G. Orlova, (Vaesoyuznyy nauchno-
isi dovatellakiy institut neftyanoy prow7ahlennosti-All, Union Scientific
Research Institute for the Petroleun Industry). An Accelerated Method
of Deteminin the General Sulfur Content of Petroleum and Petroleum
Products 1
This method is described by the following procedure: petroleum
material Is heated In a pipe to 900-950 OC in a current of air which
transforms the sulfur content into sulphuric omides which am absorbed
105
115
card 8/15

Chemistry of Sulfur-Organic Compounds (Coat.) SOV/1319
by a 1 percent solution of hydrogen peroxide. The sulfuric acid formed
is titrated with a 0.029 solution of sodim hydroxide in the presence of a
-1 d indicator (aothyl red-methylene blue). Resultant data Is tabulated
and campezed with dats. obtained by other methods.
Obolentsev,, R.D.,and A.A. Patovskaya, A Differential Polarographic Kethod
iRn-1vg-E1wezttea7 Sulfur and Disulfides in Several HYdrocarbon
Solutions
In contrast to the usual polarographic method (where curves of the
dependency of the current "I". passing through the solution, on the
applied electromative'.force "E" are derived), this method in-
vestigates the dependency of the speed of current change
-I on the applied e.. m. f . 11E. 11 A differential polarogrem of nitrate salts
of lead and thallium showed two distinct maxima which corresponded to the
presence of two cations in the solution.
Moguchaya, Z.N. The Determination of Sulfurous Mercaptans in Fuels 130
Card 9/15

Chemistry of Sulfur-Organic Compounds (Cont.)
SOV/1319
It is noted that a high content of sulfurous mercaptans in fuels
causes the corrosion of fuel equipment. A method invented by
B.G. Adma was used to determine the content of sulfurous mercaptans
in mixtures of kerosene and synthetic mercaptans, and stralght-run fuels.
This method Is based on the capacity of mercaptans to form copper mercap-
tides by reacting with an amonim solution of copper sulfate.
Results are tabulated.
Sullmovs A.D., M.V. Lobeyev, I.N. Kozhina, A.Ye.Alltsbuler, A.B. Gutman,
and V M. Satyugov, Hydrogen Purification of Distilled Fractions pf Paotern
Petrolew Without the Iqttoduction of Hydrogen From Without
A process of "autcmatic hydrogen purification" (avtogidroochiatka)
is describe4 which consists In the use of hydrogen separated during
the dehydrogenation of naphthene hydrocarbons, as proposed by
F.W.B. Porter (Refs 1, 2). Desulfurization of kerosene distillates with
initial sulfur content up to 0.8 percent was 90-95 percent after boil-
ing at temperatures ranging frcm 140 to 3000C for 1000 hours; whereas,
desulfurization of gas oil fractions of- 1 percent sulfur content was
60-80 percent after 200 hours at 200-350ac-
Balandins, A.A., V.V. Patrikeyev, S.J. Mitrofanov, and K. I. Orlova, Refinement
and Desulfurization of Petroleun With the Simultaneous Em1chment of Ore With-
out Introducing Hydrogen frm Without,
135
153
Card 10/15

Chemistry or Sulfur-Organic Compounds (Coat.) SOV/1319
A coarse concentrate of finely stomped ore is brought into contact vith
sulfurous gasoline vapors at 450-5500 C. Mineral ms containing campounds
of metals show caiaijtic properties. With the rupture of C-C or C-S and
C-H bondso these minerals (depending upon their proverties) are reduced
frar. sulfides and are covered with coke films. These changes may be exploit-
ed for flotation or other methods of enriching ore. Catalytic cracking
takes place iinultaneously. (Data are tabulated and other facets of the
process ar,.* discussed).
Stankevich, B.'Ye. (Bashkirskiy nauchno-issledovatiellskiy institut neftyanoy
prc6yshlennosti -- translated in title). Efforts of the Bashkir Scientific
Research Institute for the Petroleun Industry to Reduce Expenditures for
Caustic Reagents 162
Methoda are proposed for circumventing the expensive and extremely difficult
regenerailon of spent caustics: a) blowing through a spent caustic at
^,1000C with a mixture of wiLter vapor and compressed air b) electrolytic
regeneration -- (in expertmintal stages)jand c) Wbstitution of trisodium
phosphate (TSP) for :austic soda. Laboratory tests with an experimental
set-up producing 50 liters per hour showed that distillates pirified with
TSP passed the a Wer plate'tests.
Card 11,15 1

chemistry or Sulfur-Orpaic Ccupounds (Coat.) SOV11319
Malyavinskly, L.Vj and I A. Cbernov. Influence of the Copper Content In
Fuel on the Performance of Motors
AutoudbLle gasolines and diesel fuels obtained f ram sulfurous petroleum
of high sulfur content were found to hinder motor performance. Data are
plotted-
Horozova, 0. Ye., G. V. Vinogradov, and H.D. Bezborcdlko. (Institut nefti
AN SSSH -- Petroldtin Institute, AS USSR) Investigatioi of the Influence of
SulAftw-Organic Ccopounds on the Anti-Wear Properties of Motor Oils
Benzyl disulfide, benzyl sulfide, di-n-hexyl sulfide, elemental sul-
fur, and other sulfur-orgaaic compounds were employed as additivea to
determine whether anti-wear properties of lubricants were enhanced.
At high sliding speeds wi&h sub-critical loads, wear increased but.for
oil with an additive, the degree of wear was less than for pure oil.
Graphs are plotted with respect to the influence of temperature #Aad slid-
ing speed on anti-wear properties and the critical load value for seizing.
_Obolentsev., R.D. (Otdel khJnJi BashJdrskqgo filiala AN SSR -- Department
of Chemistr7, Bashkir Brand&, AS USM). Cruxes of the Study of Sulfur--
Organic Conpounds of Petroleum and Petrolem Products
This article is a statistical-chronological survey of developments in
the study of sulfur-orgenic ccmpouncU.
1.66
182
187
Card 12/15

Chemistry of Sulfur-Orgaalc Ccmpounds (Cont.) SOV/1319
Speeches 201
Nekrasov, A.S., Candidate of Technical Sciences, Senior Scientific Worker,
.Institute nefi AN SSSR (Institute of Petroleum, AS USSR) 201
Skripnik, Ye. I.,,Pocent, Kuybyshevskiy industriallnyy institut
(Kiqbyshev Industrial Institute) 202
Eygenson, A.S., Director, Bashkirskiy nauchno-issledo-vatellskiy
institut neftyanoy promyshlennosti (Bashkir Scientific Research 203
InsAtute for the Petrolewn Industry)
Nikiforov, V.I., Shop,Foreman, Engineer, Ishimbayskiy neftepererabatyvayu-
shchiy zavod (Ishimbay Petroleum Refining Plant) 205
Zre.lov., V.N., Fellow., Hauchno-issledovatellskiy institut gorytxche-
smazochnykh materialov (Scientific Research Iastitate for Fwl and
Lubricating Materials) 206
Obolentsev R.D., Doctor of Chemical Sciences, Feed of the Department
Bashkirskiy filial AN SSSR (Bashki., Branch, AS USSR) 208
Mashkina, A.V., Aspirant Otdela khimli Bashkirskego filiala, AN SSSR
(Depextuient of Chemistry, Bashkir Branch, AE USSR) 212
Vollf,M.B., Candidate of Chemical Sciences, Head of Laboratory,
Bashkirskly nauchno-isaledovatellakly institut neftyanoy pro-
myshlennostl(]~ash]dr S zieatific Research Institute for the
Petroleum Inh~stry) 214
Card 15h5

Chemistrj of Sulfur-Organic Compounds (Cont.) SOV/1319
Ptyasuyanskaya, A.G., Junior Scientific Worker, VeoojuzW nauchno-
isaledovatellskiy institut neftyanoy promyshlennosti (All-union
Scientific Research Institute for the Petroleum Industry 216
Patrikeyev, V.V., Senior Scientific Worker, Candidate of Chemical
Sciences, Institut organicheskoy khimii AN SSSR (Institute of
Organic Chemistry AS USSR 217
Moguchw1a, Z.N., Junior Scientific Worker, Vsesoyuznyy nauchno-
issledovatellskiy Institut neftyanoy promyshlennosti (All-Union
Scientific Research Institute for the Petroleun Industry) 218
Sorkin, Ya.G., Candidate of Technical Sciences, Assistant Director
of Scientific Research,, Bashkirskiy nauchno-isaledovatellskiy
institut neftyanoy promyshlennosti (Bashkir Scientific Research
Institute for the Petroleun Industry 218
Ratovskaya, A.A., Junior Scientific Worker, Otdel kbimii Bashkirsl~ogo
filiala. AN SSSR (Department of Chemistry, Bashkir Branch AS USSR) 220
Ayvazov., B.V., Candid e of Chemical Sciences, Senior Scientific
Worker, utdel khImli Bashkirskogo filials, AN SSSR (Department of
Chemistry Bashkir Branch AS USSR) 221
Nel 'kenbam, Ya. I. , Ragineer, Ishimbayakiy nef tepererabatyvayushchiy
zavod (Ishimbay Oil Refining Plant) 223
Golldehteyn EL.,-Candidateof Chemical Sciences, Senior Scientific
Worker, Vsesoyuznyy nauchno-iseledovatellskiy institut neftyanoy
pramyshiennosti, (AU-Vnicm Scientific Research Institute for the
PetroleLm Industry) 225
lax(i !4/15

Chemistry of Sulfur-Organic Cmpounds (coat.) SOV/131.9
Baybayeva, S.T. Candidate of Chemical Sciences, Scientific WorkerP
Vsesoyuznyy nauchno-isaledovatellski-y institut aertyanoy pro-
myshlennosti (All-Union Scientific Research for the Petroleum Industry) 226
Sukhankin, Ye.I., Candidate of Techalc&l Sciences, Head of Laboratory,
UfimOkiy nauchno-issledovatellakly tastitut neftyanoy praqrshlenno-
Oti (Sclentific Research Institute for the Petrole= Industry at. Uft)
AVAILABM Library of congreBB
Card 15/15 JM/'gMp
4-25-59

PHASE I BOOK EXPLOITATION 647
Akademiya nauk SSSR. Institut nefti
Sostav i svoystva vymikomolekalyarnoy chasti nefti; abornik rabot po, isuchenlvu
sostava L avoystv neftey i nefteproduktov (Composition and Properties of the
High Molecular Weight Fraction of Petroleum; Collection of Papers on the
Composition and Properties of Crudes and Petroleum Products) Moscow, Izd-vo
AJ;,6SSR, 19%. 370 P. 3,500 copies printed.
Reap. Ed.: Sergiyenko, S.R., Brafessor; - Ed- af-TubliaLhing House:. Nekraapv,. A.P.;
Tech. Ed.: Pavlovskiy, A.A.; Editorial Board: Thpchiyev, A.V., Academician,
Kazanskiy,, B.A., Academician, Fedorov, V.S., Candidate of Technical Sciences,
Khaakov, X.M., Professor, Sergiyenko, S.R., Professor, Plate, A.F., Professor,
Nikolaye", V.G., Candidate of Technical Sciencee.
PURPOSE: This collection of articles introduces new material in the field of high
molecular weight components of petroleum. It is intended for scientific and
engineering personnel.
Card 1/22

Composition and-Properties of the High Molecular (Cont.) 647
CDVERAGE: This book is the second collection of articles published by.the
AU-Union Conference on the Composition and Properties of Petroleum Products,
held in January 1956 in Moscow. This volume contains papers on the composition
and properties of high molecular weight compounds and sulfur compounds in petro-
leun. Several of the original papers were revised by the authors, other papers
were changed )py the editing comittee. The articles add to the knowledge of
the chemical nature and properties of the least studied fraction, that is the
high molecular veight fraction of petroleum. Many new experimental data are
given on the composition and properties of the high molecular weight fractions
of Soviet crudes (lubricating oils, paraffins, resins and asphaltenes, sulfur
compounds). Research methods are discussed.' Present and future trends in
research are explored.
TABIZ OF CONTENTS:
Preface
Introduction
Card 2/22

Composition and Properties of the High Molecular (Cont.) 647
PART I. SCM BASIC PROBLEKS OF MODEPJi PMOIM
CHOMTRr
Sergi7enko, S.R. The State and Prospects for Future Development of Research
in the Field of High NoleciLlar Weight Compounds of Petroleum 9
The author gives a review of developments in the field of analysis of the
high molecular weight fraction of petroleum in the Soviet Union and
abroad. A separate chapter is devoted to the study of Soviet petro-
leum in respect to its bitumen-asphaltene components. The indications for
further research are described. A chart is given to show the process of
analysis to which the bitumen-asphaltene fractions of various Soviet crudes
were subjected during the last Me years. There are 36 references of which
23 are Soviet,, 12 English, and 1 German.
.Mialdiltsev, PLO. Problems in the Study of Sulfur Compounds of Petroloun and
Petroleun Products 25
This article is a brief review of domestic and foreign research in
the field of sulfur compounds of petroleum. Some data are given on
Card 3/22

Composition and Properties of the High Ko).ecular (Cont.) 647
sulfur compounds found in Soviet crudes. Attention is paid to the recovery
of sulfur compounds from high boiling point fractions. There are 7 tables,
and 14 references of which 11 are Soviet and 3 English.
Gallpern, G.D. Physicochemical Properties and Composition of Petroleum
Products 36
The author gives a general review of the field of petroleum
chemistry. Foreign and Soviet developments are discussed including
methods for the determination of the composition and properties of
hydrocarbons in multicomponent hydrocarbon liquids. There are 36
references of which 15 are Soviet, 15 English, 2 German, 3 Dutch-,
and 1 French.
PART II. STUDY OF THE HYMOCARBON COMPONENTS OF OUS
TIIich4kdv'9 Okfixi~eviehj N.A.,--Gryoscapic
Method for Quantitative Determination of Aromatic Hydrocarbons in
Petroleum Oils in Cyclohexane Solution 47
Card 4/22

Composition and Properties of the High Molecular (Cont.) 647
This article describes the improved cryoscopic method of Tilicheyev and
mentions its application for the first time to control of the clearness
of separation of aromatic hydrocarbons from alkanes and cyclanes in the
chromatographic separation of lubricating oils into aromatic and saturated
components with silica gel. It was determined that various aromatic
fractions separated from petroleum oils by chromatography (under conditions
chosen by the author) contained 2 to 22 mol. percent of nonsulfonating
admixtures. There are 4 tables and 3 Soviet references.
Zherdeva, LeG., Sidlyarovok,_F.G. The Structure and Properties of Aromatic
Compounds Contained in the High Bolling Petroleum Fractions 54
Thi article considers the structure and properties of aromatic com-
pounds from two types of eastern petroleum: Taymazy petroleum
(paraffinic, sulfur containing)arid Emba petroleum (low paraffin, low
sulfur content). It vas determined that high molecular veight aromatic
compounds separated from sulfur-containing petroleum consist of a
mixture of polycyclic (3 - 7 cycles in an average molecule), mostly con-
densed aromatic hydrocarbons,, and sulfur compounds similar '..n their pro-
perties to aromatic hydrocarbons. The calculation of the structural
Card 5/22

Composition and Properties of the High Molecular (Cont.) 647
group composition from physicochemical constants without hydrogenation
shows considerable disagreement with the composition determined on the
basis of hydrogenationY and therefore cannot be used for fractions of
polycyclic high molecular weight aromatic compounds. There are 10 tablesY
1 figure, and 15 references of which 7 are Soviet, and 8 English.
Kaum5rah,._VWY&, Stepa6yALp, T.S., bfusayev, M.R. Determl tion of the Hydro-
carbon Composition of Oil Fractions 69
In order to explain the relation between quality of oils and hydro-
carbon composition the authors studied a number of oils from the Baku
region. They came to the conclusion that the adsorption method of
analysis is the most objective one and should be recommended for the
determination of hydrocarbons in oils. It is sufficient to examine the
fraction with viscosity E 7 (table 15) in order to obtain the
characteristicsof the entiore~range of oils of the studied crude.
There are 15 tables, and 3 Soviet references.
Card 6/pp

Composition and Properties of the High Kolecular (cont.) 64T
Krol',B.B.,-Zherdava, L.G., Ostroumova, Ys.A. Determination of the Chemical
Composition of Oils by Ke~n~ of Adsorptive Separation 81
This paper gives a description of the adsorptive separation method
as used in the oil chemistry laboratory of the VNII NP to determine
the chemical composition of crudes and oils. It is designed for the
determination of group composition of oils, oil distillates, residues
and extracts. Application of this method to the analysis of crudes
gives an estimate of the yieldand quality of oils produced. There
are 6 tables, 1 figure, and 15 references of which 8 are Soviet, and
7 English.
Artemly6va; O.Ag,"'Nitrofanov, M.G., Martyneako, A.G. Investigation of the
Dynamics of Changes in the Chemical Composition of Crudes and Intermediate
Products in the Production of Aviation Oil VS-20 90
This paper is a study of the effect of production processes on the
quality of group composition in KS-20. MS-20 is described as the
final product obtained from a blend of concentrates from Karachukhur-
Surakhan petroleum and Groznyy cylinder stock. After refining by
selective solvents, deparaffination, and contact refining with clay
Card 7/22

Composition and Properties of the High Molecular (Cont.) 647
powder the NS-20 shows the following group composition (percent by
weighti: naphthene-paraffin hydrocarbons 70-3: naphthene-aromatic
hydrocarbons 27.1; propane soluble tars 0.7; and tarry substances
not soluble in propane 1.9. There are 20 tables and 2 English
references.
Kaverina, N.I., lasikov, B.V*,*Fedyant9ev&, k.k. Idsorption Method for
DetermIning the Fractional Composition of High-Polymeric Lubricating
Oil Additives
The authors show that chromatographic adsorption can be used as a
method for separating polyisobutyl-i-ne and vinypol, with active
carbon or silica gel as adsorbent. The method can be of considerable
interest in estimating the quality of high-polymer viscous additives
in oils. It can also be used in obtaining polymer fractions with
equal aolecular weights. There are 5 tables, 1 figure, and 3 refer-
ences of which 2 are German and 1 English.
log
Card 8/22

Composition and Properties of the High Molecular (Cant.) 647
PART III. EFFECT OF COMPOSITION ON TEE PERFORKMCE OF IMMICATING OILS
Kuliyev, A.M*, Kullyev, R.Sh., Aliyev, M.I. Effect of the.Hydr-ocarbon Composition
on the Physicochemical Properties and Performance of Lubricating Oils 119
A study was made of the narrow oil fractions and a rcial oils obtained
from various Balm crudes. It was shown that the physicochemical properties
and the performance properties of oils are modified by the hydrocarbons
composition and structure. The naphthene-paraffin hydrocarbons obtained
from various crudes are similar in quality and have very good temperature-
viscosity properties but show low oxidation stability. Aromatic hydro-
carbons differ in their properties and have a greater effect on the quality
of lubricating oils than naphthene-paraffin hydrocarbons. Aromtics and
tars inhibit the action of depressants and additives. The article contains
16 tables there are no references.
Kreyn, S.E., Borovaya, M.S. Effect of the Chemical Composition of Fetrolsua
Lubricating Oils on Their Properties 138
This paper is a study of petroleum oils obtained from various Baku
exudes. Components were separated by adsorption. The distillates
Card 9/22

Composition and Properties of the High Molecular (cont.) 647
were refined by sulfuric acid and solvent processes. The effect of
the composition and the hydrocarbon structures on the quality of
lubricating oils was determined for several types of oils. The
role of quantity and structure of aromatics, naphthene-aromatics,
hydrocarbons, resins and sulfur compounds was studied In motor oils
as a factor modifying the character of naphthenic-paraffinic hydro-
carbons. The type of the crude and the purpose of the lubricating
oil determine the refining processes and their extent. There are 23
tables and 9 references of which 5 are Soviet and 4 English.
Minogradov, G.Ve, Kreyn, S.E. Chemical Composition and Wear-Resistance
Properties of Petroleum Oils 167
Various types of M? oils (naphthene-paraffin fractions) were studied
on friction-test machines in order to establish their wear-resistance
properties in relation to their chemical composition. Their wear-
resistance properties depend on the amount of aromatic fractions (AF)
which are sulfur bearing, in relation to the NPF of variable viscosity
and oxidation stability. The chemical composition of oils and indi-
vidual fractions determines their characteristic behavior in relation
to metals. These characteristics vary throughout the entire range
of products from distillates through oils to W fractions. The
article gives 14 figures and 1 table. There are no references.
Card 10122

Composition and Properties of the High Molecular (Cont.) 647
V1Wgr*do'0, G.V., Semechkin, L.YpL., Pavlovs~aya, N.T. -,hanges in the Compo-
sition of Motor Oils During Service 185
In order to study the effect of working conditions on lubricating oils,
two oils were chosen: MS-14 (GOST 1013-49) obtained from Emba crudes,-
and motor oil SU (GOST 1707-51) obtained from Balakhany crudes. These
oils were tested on several engines. Characteristics of initial and
spent samples are given. The teats on piston engines showed that a
period of 60 hours of service does not lead to a change of the chemical
group-composition of oils. Longer periods (100 hours) are needed to
cause noticeable changes. There are two tables and 4 references of which
3 are Soviet and 1 English.
Zelenskly, V.D..r, Vinogradov, G.V. Effeat-of the Composition on Wear-
Resistance Properties of Petro.Leum. Products. 189
The authors studied the vear-resistance properties of lubricantp and
the effectiveness of additives as seizing inhibitors. The lubricants
were tested on a friction-test machine. In order to establish which
light fractions begin to show wear-resistance properties, several pe-
'Card 1l/ 22

Composition and Properties of the High Kolecular (Cont.) 647
troleum products were tested (e.g. kerosene fractions). The perform-
ance of lube oils was examined at high surface friction and with various
additives (sulfur, phosphorus, chlorine). Oils used were: transformer
oils, SU, AK-15. A close study of the NPF (naphthene-paraffin fraction)
was maile,and their characteristics were deterudzed as modifying the pro-
perties of the oils. The NPF from various crudes are different and their
sensitivity to additives vary (especially towards orgEtnophosphoric wear-
resistance additives). There are 2 tables, 2 figures, and 2 Soviet
references.
Favlovskaya, N.T., Vinogradov, G.V., Bezborodlko, M.D. Idear-Resiatance Pro-
perties and Oxidizability of the Naphthene-Paraffin Fractions of Viscous
and Lov-Viscosity Petroleum Oils 198
Since friction tests show the importance of oil composition, in particu-
lar of the NPF, a through study was made of this fraction. The NPF of
transformer oil and of MS-20 were used in these tests. Results show that
it is possible to achieve an exact differentiation of the various naphthene-
paraffin fractions obtained from petroleum oils with different viscosity
indexes. It was shown that the NPF of low-viscosity oils have a lover
oxidation stability. There are5figures and 3 Soviet references.
Card 12/ 22

Composition and Properties of the High Molecular (Cont.) 647
PART IV. THE CHEMICAL NATURE OF SOLID PETROLEW HTDROCARBONS
Chernoshukov, N.I., Kazakova, L.P. Methods for the Separation of Solid
Hydrocarbons From Petroleum Oil Fractions ana Their Characteristics 203
The article describes a new method for the extraction and separation
of various groups of solid hydrocarbons from petroleum oil fractions.
A Romashkino, crude concentrate was used for the extraction of solid
puraffinic, raphthenic, aromatic, and naphthenic-aromatic hydrocarbons.
The paraffins constituted only a minor part. Solid aromatics, mainly
those *_,bich do not form urea complexes, contain a considerable amount
of solid sulfur compounds. There are 7 figuresY 2 tables) and I Soviet
reference.
Topchiyov, A.V., Rozenberg, L.M., Terentlyeva, Ye.M., Nechitaylo, N.A.
Separation of Petroleum Paraffins into Normal and Isomer Hydrocarbons 208
The temperature ranges for the decomposition of complexes of indi-
vidual normal paraffins C16 to C32 were determined by means of the
differential-thermal analysis. They can be used for the identifi-
cation of normal paraffins. It was shown that urea is not a selective
Card 13/ 22

Composition and Properties of the High Kolecular (Cont.) 647
reagent for normal paraffins. Only slight branched paraffins easily
form urea complexes. Most of the Isoparaffins which were separated
from the rsrozwjy paraffin as urea complexes have slightly branched
structures. Hydrocarbons which do not react with urea resemble the
cycloparaffins. There are 6 figures, 2 tables, and 39 references of
which 8 are Soviet, 24 English and 7 German.
Vosuesenakaya, Ye.V., Zhordeva, L.G. Study of Solid Hydrocarbons From
Sulfur-Containing Eastern Crudes 218
It was determined that highly refined solid hydrocarbons obtained
from a deasphalted Tuymazy crude concentrate (b.p. > 350*) belong
to the methane series and are mainly normal paraffins (C23 to C'9,6)'
Solid hydrocarbons with m.p. > 650 contain about 35 percent i9omeric
methane hydrocarbons. There are 12 figures, 6 tables, and 19 refer-
ences of which 9 are Soviet and 10 English.
Card 14/ 22

Composition and Properties of the High Molecular (Cont.) 647
GoIldborg, D.O. Solid Petroleum Hydrocarbons, Their Composition and Methods
of Separation 226
The article is a general review of research done in the field of
solid petroleum hydrocarbons separated from Soviet crudes. The
author mentions the fact that there is no adequate method for the
analytical oxidation of high molecular weight hydrocarbons with
long pararfin chains. It -was shown that normal paraffins and ceresins
are very susceptible to depressants e.g. dialky1naphthaline, not like
solid naphthenes which are very stable in solutions vith petroleum
products, and are not affected by most depressants. This specificity
of action of additives can serve for the identification of solid hydro-
carbons. The article gives 2 tables and 1 figure. There are no refer-
ences.
Melikadze, L.D. Crystalline Components of High Molecular Weight
Petroleum Fractions 236
This is a study of the crystalline substances obtained from several
types of Soviet crudes. Two main groupo were neparated: lumineocant.
Card 15/22

Composition and Properties of the High Molecular (Cont.) 647
products which were determined to be hydrocarbons (high paraffin content-
and low resin content) and nonluminescent reddish-blue products (nitro-
gen containing compounds). Evidently, the high molecular weight compounds
contain aromatic rings and other structures of low thermal stability,
which fact can be regarded as confirmation of the low-temperature forma-
tion of petroleum. There are 2 tables and 19 references of which 14 are
Soviet and 5 English.
PART V. RESINOUS-ASPHALTIC SUBSTANCES. CMMSITION, PROPERTIES,
AND RESEARCH METHODS.
Sergiyenko, S.R., Davydov, B.E. Physical Properties of Petroleum
Resinous Substances 245
Resinous substances from the Romashkino crude and from the Gyurgyany
crude were taken for this study. The increase of the amount of acid
and neutral saponifiable substances is directly proportional to the
increase of the amount of hetero-atoms they contain (0,S,N). All
resinous substances are characterized by considerable surface activity.
They can be separated into fractions of increasing surface activity
Card 16122

Composition and Properties of the High Molecular (cont.) 647
with the aid of a series of solvents with increasing dielectric constants.
The differentiation of resinous fractions can be improved by the inclusion
of cyclohexane as a solvent. The molecular, surface, and polarization
characteristics are used for the differentiation of fractions YhIch show
similar results in chemical analysis. There are 2 tables, 9 figures, and
7 references of which 5 are Soviet, and 2 English.
Benlkovskiy, V.G. Certain flew Methods for the Separation of Resinous
Substances 20
The author proposes the following types of methods for the separation
of resinous substances: methods of collodial chemistry and electro-
chemistx7 (electrophoresis, electrodialyais, high-voltage electrolysis,
thermodiffusion), and the method of molecular compounds (reaction of
organic compounds with salts of various elements). There are 2 figures,
1 table, and 14 references of which 5 are Soviet, 8 German, and I English.
Velizartyeva, N.I., Zherdeva, L.G. Physicochemical Stud;r of Asphaltic-
Resinous Substances From Eastern Crudes 266
Card 17/22

Composition and Properties of the High Molecular (Cont.) 647
Propane treatment yields products with a high hydrogen content and high
molecular weight. Phenol treatment gives products of lover molecular
weight, high density, and high S, N and 0 content. Resins from Tuymzy
and Emba crudes are composed of polycylic compounds containing S, N, and
0, with average molecules of 4 - 6 cycleu. The average molecule contains
not only aromatic cycles, but also considerable amounts of naphthenic
(sometimes up to 50%) and paraffinic (40 - 50%) cycles, basically short.
There are 7 tables, 3 figures, and 13 references of which 12 are Soviet
and I German.
Bogdanov, N.F. Plan of a Standard Method for the Study of Mazut 280
The proposed method is not in its definitive form. Changes and additions
are expected after the completion of work on problems which still remain
unsolved, both in apparatus and methodology. The proposed method consists
of two stages. The first stage which is identical for all mazuts determines
hydrocarbon composition and physicochemical properties. The second stage
is concerned with the separation of technical products for particular
applications. These products are characterized by technical, physical,
and chemical properties which should fulfill some requirements, therefore
this stage is not uniform for all mazuts but is dictated by specific
needs. There are 2 tables, 1 figure, and 4 references of which 2 are
Soviet and 2 English.
Card 18/ 22

Composition and Properties of the High Molecular (Cont.) 647
Bogdanov, N.F., Martynenko, A.G., Artemlyeva, O.A. _Wthods for Study of
the Composition of Heavy Petroleum Products by Fractionation with Liquid
Propane and an Adsorbent 291
The high-boiling residual petroleum products are investigated by means of
the fractionation method developed by the GrozNII. This method is based
on the separating properties of liquid propane and of liquid propane plus
an adsorbent. The use of liquid propane permits finer separation than
achieved by other methods. The molecular weight of the cuts increases
with fractionation, and their chemical composition shows increase of
aromatization. Composite fractionation with an 6Asorbent, gives narrower
cuts differing in chemical composition. The advantage of these methods
is the maintenance of the chjmical composition of all components through-
out the process. There are 13 tables, 2 figures, and 2 references of which
1 is Soviet, and 1 English.
Sereda, Ya.I. A Method for Anaiysis of the Chemical Composition of Organic
Components in Acid Asphalts 3o8
The Laboratory for Petroleum Refining at the Geological Institute of
Mineral Resources, Lvov Branch of UkrSSR, developed a new method for
analysis of the chemical group composition of acid asphalts obtained
from the refining of oil and wax. This method serves for the deter-
mination of the composition of all types of acid asphalts, and can be
Card 19/22

Composition and Properties of the High Molecular (Cont.) 647
conveniently used in plant laboratories. It introduces new elements into
asphalt analysis: more complete quantitative an lysis of organic components.,
especially of paraffinic acid asphalts (for the first time), determination
of carboxylic acids (naphthenic and asphaltous), determination of "oxonium7
compounds of resins and asphaltenes as independent from the various groups
of asphaltene-sulfonic acids, and the discovery of the hitherto unknovu
new group of asphaltene-oulfonic acids which are not soluble in acetone.
There are 3 tables and 8 references of which 4 are Soviet, 1 German, and
3 English.
PART VI. PETROLEUM SULFUR COM&v)UNDS AND METHODS FOR THEIR INVEWIGATION
Obolentsev, R.D... Ayvozov, V.B., Ratovskaya, A.A. Physicochemical Method for
Group Analysis of Sulfur Compounds in Petroleum Distillates 323
The article discusses existing methods and describes a new method
developed for the study of sulfur compounds in 1-igroin-kerosene-solar
petroleum fractions. The method is based on the direct determination
of elementary sulfur, and sulfur in mercaptans, sulfides and disulfides,
by amperometric, potentiometric, and polarographic analyses. The kerosene
fraction from Tuymazy crudes was used in the analysis. There are 4 figures,
7 tables,, and 15 references of which 8 are Soviet, and 7 English.
Card 20/22

Composition and Properties of the High Molecular (Cont.) 647
Luklyanitsa, V.G., Gallpern.. G.D. Methods for Study of Group Composition of
Sulfur Compounds in Petroleum Products
The article reviews the existing methods for the determination of sulfur
compounds in petroleum products., and enumerates foreign as well as Soviet
methods for the analysis of separates classes (free sulfur, hydrogen
sulfide,, mercaptans, dimilfides, sulfides; thiopkenes.~ and for group
analysis. There are 3 tables., 1 figure, and 73 references of which 17 ar
Soviet, 45 English, 5 German, 2 Czech, and 4 French.
Gusinskaya, S.L. The Nature of Sulfur Compounds in Crudes From Soithern
Uzbekistan
It was determined that Southern Uzbekistan crudes have a high su'.fur
content (3 - 6 percent) and high content of nitrogen compounds (ip to
1 percent). Thiophane homologues were detected (methyl-=Wl-heptyl) in
these crudes. Uch-l(zyl crudes include also thiazoles (methylthiaole).
Gasoline and kerosene from these crudes show 2 - 4 percent sulfur There
are 5 tables and 21 references of which are 15 Soviet, 3 English and
3 German.
Card P1/22

Composition and Properties of the High Moleculor (Cont.) 647
Chudakovaj I.K., Valynakly, N.P. Determination of Sulfur Content in Hetvy
Petroleum Products by Double Combustion 352
This Is a new method proposed for the double combustion for the dete:--
mination of sulfur in all types of petroleum pro(bicts,, with the exce, tion
of gasoline and low-sulfur kerosene, and in individual organic compcn nds
containing C p R 1 0 j N j, and B. This method is more exact than the bol b
and VT1 methods. There are 6 tables, 5 figures., and 5 references of which
are 4 Soviet and 1 English.
G
Gurevich, I.L. On the Problem of Petroleum Desulfurization 364
The author describes the continuous desulfurization of cruder. by meaza of
the MI adsorption method. Variation of the adsorbent - crue-, ratio controls
the sulfur content of the various fractions. The article gives 3 ficares.
There are no references.
AVAILABLE: Library of Congress
TM/hcr
12-8-58
Card 22/22

OBOLMMEV, F.D.
"The urgency to intensify researches on the sulphurous petroleum (deposits
of Bashkiriya"
."m yawsuW at the calm at Wo P"wId1m of the Counall fcw Co-
4941"IM -at ftifttaft Owk at tM Adedud" at Sat a at VUSM SW611M
" ~ (as DenlopmA of beewdws an Nimbi NWLerAw Caqpm&)
2L J~Aw 190. (Test. Ak go* WMg, 190,p No. 9v pp. IM-10)
Chairman of the Bashkiriya Branch of the AS USSR

SIMINOT. N.C. alcadamik; ARBUZOV. A.Ts., aka4ami1c: KILWATITIV, ru.G.-.
KARGIM, V.A.. akademlic; TITOT, N.G.. doictor khln.nauk; OBOTJMTM.
R.D.. doktor khtm.nauk: IMSHIMMKIT, A.A.; SISAKYAH,
Difteuselon of the reWrt. Vast. AN SSSR 28 no.8:19-2.6 Ag 158.
(mm 1119)
1. Chlon-korrespondent AN SSSR (for l4amsdallyaw, Inshanstskiy.
Steakyan).
(Ohmmistry, Organic--Synthests)

AUTHORS: Obolentsev, R. D., Mashkina, A. V. 2o-119-6-38/56
TITLEs The Hydrogenolysis Kinetics of Dibenzothiophene and
Octahydrodibenzothiophene Over an Aluminum-Cobalt-
Volybdenum, Catalyst
(Kinetika gidrogenoliza, dibenzotiofena i oktagidrodibenzo-
tiofena nad alyumokoball tomolibdenovym katalizatorom)
PERIODICALs Doklady Akademii nauk SSSR, 1958, Vol. 119, Nr 6,
PP. 1187-1190 (USjR)
ABSTRACT: The moat important modern catalytic working processes of
sulfurous mineral oils are based on the hydrogenolysis
reactions of organo-sulfuric compounds. They are insuffi-
ciently investigated, especially the kinetics mentioned
in the title, in spite of the widely spread application
of the mentioned catalyst in the mineral oil processing
industry. This gap is partly to be closed by the present
paper. As the so-called "rest sulfur" mineral-oil products
is highly represented by compounds of the thiophene series
the authors selected the substances initially mentioned
Card 1/4. in the title (the second one is called 1, 2, 3, 4, 5, 6,

The Hydrogenolyeis Kinetics of Dibenzothiophene and 2o-119-6-3e/56
Octahydrodi5enzothiophene Over an Aluminum-Cobalt-
-Molybdenum Catalyst
7, B-octahydro-benzothiophene). Their synthesis is already
described. (Refs. 1, 2)- As 0,5~-(according to sulfur)-
solutions in technical cetane in a flowing-through plant
(Ref. 3) with some modifications they were subjected to
hydrogenolysis. For the purpose of describing the experi-
mental results (Table 1) the authors tried to employ the
kinetic equation by Frost for monoaolecalar reactions
(Ref- 5)- Other equations of this type (Refs. 6-9) are
mentioned. According to the methodology by S. A. Kazeyev
(Ref. 8) the authors found equations which represent the
dependence of depth and velocity of both substances men-
tioned in the title on the duration of contact (Table 2).
The correctness of the equations is confirmed by the
satisfactory agreement of the experimentally determined
and computed depths of the hydrogenolysis (Table 1).
Because the clearing up of the dependence of the depth
of hydro-desulfonation on the partial hydrogen pressure
Card 2A is important for industry, the authors deduced equations

The Hydrogenolysis Kinetics of Dibenzothiophene and 20-119-6-38/56
Octahydrodibenzothiophene Over an Aluminum-Cobalt-
-Molybdenum Catalyst
of the total dependence of depth and of the velocity of
hydrogenolyeia of both mentioned substances on the duration
of contact and on the mehtioned pressure. Because the
parameter "b" is practically independent of this pressure,
the authors could obtain, after corresponding substitutions
the desired equations (8) - (11), which satisfy the experimen-
tal results (Table 1). The results of analysis referring
to the absorption spectra with'.n the ultra-,Jolet range
showed that the total sulfur contained within the liquid
catalyst is represented by the not reacted dibenzothio-
phene and octohydro-dibenzothiophene. Only biphenyl forms
the decomposition product of dibenzothi-aphene, its quan-
tity within the limits of the experipental error agreeing
with the quantity of the reacted dibenzothiophene. The
hydrogenolysis of ihe latter procea'As in one stage wbere
biphenyl and hydrogen sulfide form. There are 1 figure,
Card 3/4 2 tablesand 10 references, 8 of which are Soviet.

The Hydrogenolysis Kinetics of Dibenzothiophene and 20-119-6-36/56
Octahydrodibenzothiophene Over an Aluminum-Cobalt-
-Molybdenum Catalyst
ASSOCIATION: Bashkirskiy filial Akademii nauk SSSR
(Bashkir Branch AS USSR)
PRESENTED: December 11, 1957, by A. V. Topchiyev, Member, Academy of
Sciences, USSR
SUBMITTED: December 11, 1957
Card 4/4

Al 7 j)
FFM-E 1 BOOK MWIDITATION SOV/2(YT5
Akademiya neuk SSSR. Bashkirskiy filial, Ufa
Khimiya seraorgaaicheskikh soyedinenly, soderzhashchikhsya v neftyakh i
nefteproduktakh; rmaterialy III nauchnoy sesaiij (Chemistry of sulphur
Organic Compounds Contsined I.n Petroleum and Petroleum Products; [?apers of the
Third Scientifid'Session]) Moscow, Izd-vo An. SSSR, 1959. 376 p.
2,000 copies printed. Errata slin inserted.
Editorial Board: R. D. Obolentsev (Resp. Ed.) Doctor of Chemical Scien(;as:
G.D. Gallpern, Doctor of Chemical Sciences,' Ya. B. Chertkov, Doctor of Technical
Sciences; V.V. Panov, Candidate of Tech--O-cel Sciences; and V.P. Rozhdestvenskiy,
Candidate of Chemical Sciences; Ed. of Publishing House: !.I. Brunov;
Tech. Ed.: T.P. Polenova4
PURPOSE: This book is intende(I for chemists, chen-ical engineers,and technicians
specializing in the chemistx-j of petivlemd.
Card 1/10

Chemistry of Sulphur Organic Compounds (Cant.) SOV/2075
COVERAGE: The book is a collection of papers presented at the Third Scientific
Session on the Chemistry of Organic Sullf%w- and Nitrogen Compounds Contained
in Petroleum and Petroleum Products. The scientific session vas held in Ufe..*
June 3-8, 1957. The book consists of six sections: 1) Synt thesis, charac-
terization, and analysis of organic sul-fur compounds; 2) Separation and
composition of organic sulfur compounds contained in petroleum and petroleum
products; 3) Transformation of organic sulfur compounds by thermall catalysis;
4) corrosive properties of and tar fomation In sulfur-containing petroleum
and petroleum products; 5) Uses of organic sulfur compounds and hydrogen
sulfide; 6) Physiological properties of organic sulfur compounds. No personali-
ties am mentioned. There are 315 referenceslof which 179 are Soviet,
118 English, 5 French, 12 Ge=an )and 1 Czech.
TABIE OF CONTEIMS
From the Mtorial Btaff 3
Introduction 5
Card 2A0

Chemistry of Sulphur Organic Compounds (Cont.) EOV/2075
PART I. SYMMIS, CHAR)WT&RIZATIO14, AND ANAL78TS OF
ORGMC SULFUR COMPOMM
Obolentsev R.D., V.G. Bukharov. Synthesis of at -substituted ThJuphanes 9
-Obalantsey, ~,D., N.M. Pozdeyev, L.L. Shan-in. Deriving Standard
PreparaTi-ons of Organic Sulfur Compounds 20
Obolentsev,_B,.]L, N.S. Lyubopytova. Determination of Sulfides in
Petroleum Products With the Aid of Absorption Spectra in the
Ultraviolet 30
Gallpern, G.D., I.K. Chudakova, M.V. Yegorushkina. Develcqnent of
the Double Combustion Method Suitable for *'.-,qe Det&rmination of
Sulfur and Halogens in Organic Compounds, PetrolL-=, and
Petroleum Products 57
ObolentsjY,__R.D.,, L.L. Shanin, V.A. Naydeno-,. Radiametric Method
for Dete-r-minatIon of the Total Sulfur Content in Petroleum Products 44
Card 3/10

Chemistry of Sulphur Organic Compounctg (Cont.) SOV/2075
Obolentsev, R.D.., A.A. Ratovskaya. Method of Group Determination of
Org-anTc-90:~ar Compounds P,,oposed by BashFAH CBashkir Branch,
Academy of Sciences, USSR 1 49
Pozdeyev, N.M. A Laboratory Oscillographic Polarograph 58
Bezinger, N.N., G.D. Gallpern, T.I. Savostlyanova. Determination
of the Total and Basic NitrOgeL in Petroleum nnd Petroleun Products 67
PART II. SEPARAT110? AND COMPOSIMON OF ORGANIC SULFUR
COWOUNDS COWAIM IN PETRtOI=1 AND
F019-012UM FRUJUC15'."S
Numanov, 1.U., V.P. Chayko, A.I. Skobelina, G.L. Tolmacheva.
Organic Sulfur Compounds Contained in the Vide Fractions of
Kzyl-Tumshuk and Khaudag Petroleum 77
Gusinskaya, S.L. Study of the Nature of Organic Sulfur Compounds
of Southern Uzbekistan Petroleum 81
Card 4/ 10

Chemistry of Sulphur Organic Compounds (Cont.) SOV/2075
Sergiyanko, S.R., I.A. Nozhkina, Ye. V. Rozdrina. Catalytic
Hydrogenation as a Method for Tnventigating the Chemical
Nature of High-KoleL,_lar Gondensed Aromntic Sulfurous
Petroleum Camp mds 85
O.b,o,,:,.1entse_v B.P., B.V. Ayvazov. Distribution of the Total Sulfur by
r t-
rUn Fuel Fractions Obtained from Sulfur-aft"I,
Petroleum 101
Obolentsev R.D., B.V. Ayvazov. Separattion of Mixtures of Hydrocarbons
--':~~~~Sulfur Compound by the ChromatheraoEpaphy Method in
Vapor Phase 110
Sanin, P.I., Ye. A. D'yachkova, N.I. Kjimissarova. Separation of
Sulfur Compounds and Aromatic Hyd-rocar-bons by t1he Adsorption
Chromatography Method 125
Skrynnikova, Z.V., A. Ya. Kantor. TestIng an Experimental Chromato-
graphic Insta-Ilation for the Production of a Concentrate of
Organic Sulfur Compounds 139
Card 5/ 10

Chemistry uf Sulphur Organic Compounds (Cont.) SOV/2075
Nikolayeva, V.G., Ye. V. Zvereva, M.A. Timracheva. Oxidation of Aromatic
Hydrocarbon Fractions for the Removal of Sulfur CompoundA 142
Klimenok, B.V., K.G. Yullyakshina. The Problem of the Effect of Organic
Sulfur Compounds on the Rete of Deparaffination of the Disael Fraction
With Carbemdde 150
PABT Ill. THMMATALITIC TRANSFOI-MA0 IONS OF ORGANIC SULFUR COMPOUNDS
Yerofeyev, B.V., S.F. Ne=ova. Theniodjnmaics of Some Reactions of
Sulfvr-Oontaining Compounds 157
K-araulova, Ye. N., D. Sh. Meylanova, G.D. Gallpern. Transformations
of Allyl Aryl Sulfides and Allyl Aryl Sulfones 164
Tits-Skvortsova, I.N., T.A. Danilova. Synthesis and Transformations
of Sulfur Derivatives of Tetralin in the Presence of an
Aluminosilicate Catalyst 174
Card 6/10

Chemistry of Sulphur :)rganic Compounds (Cont.) SOV/2075
Obolentsev, R.D., L.N. Gabdallina. Kinetics of Transformation of
MXrM in the Presence of an Aluminosilicate Bead Catalyst 183
V.I. Dronov. Kinetics of Transformation of cis--2,5
li-n.-propylthlopane in the Presence of an Aluminosilicate
Bead Catalyst 200
Obolentsev, R.D,. D.M. Torikov. Kine"l-za of Hydrogenolysis of
---------4r--ft-tylthLopene in the Presence of a Platinum Catalyst 219
Obolentsev, R.D., A.V. Mashkina. Kinetics of Hydrogenolysis of
--ftneffmotff-op-hene in the Presence of an Alumimum-Cobalt-Mblybdenuan
Catalyst 228
Skripnik, Ye.I., V.G. Dyrin. Catalytic Refining of Straight-run
Gasolines by Removing Organic Sulfur Compounds 259
Card 7/ 10

Chemistry of Sulphur Organic Compounds (Cont.) SOV/2075
PART IV. CORROSIVE ACTIVM AW1 TAR FORMATION OF
SULFUR-CONTAINING POTTROIMM AND PETROIMM PRODUCTS
Zakharochkin, L.D., S.M. Vollfson. Cor-rosive Properties of Sulfur-
containing Petroleum 269
Bespolov, I.Ye., O.V. Pletneva, Ye.V. KolotuaWdma, G.P. Belyayeva,
M.S. Malyaheva. Corrosive Effect of rmls Derived from Sulfur-
containing Petroleum 276
Chertkov, Ya.B., V,N. Zrelov, V.M. Shchagin. Organic Sulfur Compounds in
Fuels as Inhibitors in the Corrosion of Copper and Its Alloys 284
Puchkov,, N.G.,, .V.. Gavryukhin:. Methods of ControLling the Wear of
Engines Dne to Corrosion Caused by Use of Diesel Fuels With a High
Sulfur Coutent 293
Card 8/ lo

Chemistry of Sulphur Organic Compounds (Cont.) BOV/2075
ftblnshten, I*A., B,V. Losikov, Ye. P. SobOlev, M.G. Zaychik.
Effect of Orgente Sulfur Compounds on the lAw-temperature
Properties an& Oxidizability of Kerosene-Gas Oil. Fractions 304
Mikheyev, V.S. Some Properties and Experience With the Use of
Heat-reelstant Iron-Chromium Alloy No. 2 in a Higi-temperature
Pyw*tia' Process 316
PAR? V. USES OF ORGANIC SULFUR COMPOUNDS
Shostakovskiy, M.P., Ye.,,'N. Prilezhayeva, Y.I. Uvarova, V.M. KaravVeva.
Synthesis and Transformations of Sulft-~7&ntaining Vinyl Compounds 337'
Nik-iforov, V.I., L.K. Yezova.. Industrial Extraction and Uses of Organic
Sulfur Compounds Contained in the Diesel Distillates of Ishimbay
#etroism 351
Ame3in, A.G. Manufacture of Sulfuric Acid From Hydrogen Sulfide
Recovired From Fuel Gases 356
Card. 9/10

GHIBRIKOTA. Ye.V.; ROWDESTUNSLAYA. A.A.; OBOLENTSM.,.R.D.. prof.,
dcktor khim.nauk, glavnyv red.; OLLI, A.I.. doktor geol.-
miner.nauk, otv.red.; CHZPIKOVA. I.M., red.izd-va; ASTAF'T37A.
G.A., takhn.red.
[Katerials on the paleontology and stratigraphy of Devonian
and older deposits of Bashkiria] Naterisly po paleontologii
i stratigrafti. devonskikh i bolas drevnikh otlozhanii Bashkirii.
Koskva, Izd-vo Aknd.nouk SSSR, 1959. 246 p. (HIRA 13:1)
(Bashkiria--Paleontology, Stratigraphic)

030LENTSEV, R. D,, GAI,')*,,R'l, G. D.1 AIVA7011, ii. -1.)
KARALLOVA, F. N., 1';K*fVTT3A, V. I., FLAT-WSKAYA, A. A., V. 1).
(S-,!.CTI0I'.T V)
11 "
,.orposition of Sulfur- and c4trogen-Orp-anic 0P!P0jjTjrj.I, -',)ntai-ie,i in
the Oil of the :eastern Areas in the Soviet Union."
i(enort si.:bri.ttpi at thE --'Lfth ',,,'orlj P~Aroleim lomgress, I( Iay -
gew Lork.
June 1.99. 1

doktor khIm. nauk, oty. red.; MMINA. A.T..
k9nd- khIm. a-auk. re&,; HOMIZA. I.A.. kand. khta. nauke
red.; ROZII-XSTw3UN--- , V.P., knad. khIm. nauk. red.; ffAD-
KOWA, L.K., red.; SIBMT, T.V., red.; SEFAFIM. I.G.. takim.
red.
[Chemistry of sulfur and nitrogen organic compounds In
jetroleux and petroleum products] KhImiIa sers- I axotoor-
A-pnicheskikh soedlnenil. sadershashchikhaie v neftlakh i
riefteproduktakh. Ufa. Tol.3. 1960. 337 p.
(KIU 143-5)
1. ALrademiya nauk SGSR. BashkIrskly filial, Ufa. Mel khi-
mil. 2. Bashkirskiy filial AN SWR, Otdal khImIA (for Gbo-
(Petrolau*--Analysis) (Sulfur organic compounds)
(Ifitrogen organic compounds)

TRASE I DCOr MWITATION Sav/14941
XPZhTU24T$kGye moVeshc4mantle po khtmil norti, Romeow, 1956.
3boMU %rudov Mexhvuzovskogo sovesbehaniya po khiwi norti
~C*IZ*~tlcn of Trbnsactlons of the Inter-"nAversity Can-
rerenze an Petroleum chemistry) [Moscow) 1%4-vo Mosk.
Unto. . 1960. 313 p. Errata olip inserted. 1,600 copies
printed.
orwlzs=g committee or the Conf*rencot Chairman: B. A.
KAxa"kly. Academician. VIcs-Chalrmani S. 1. Khromov,
Doestst; 0. ft. Panchonkov. Prof*58orl A. F. Plate, Pro-
fessor; Secretary: To. S. Balonkova, Scientific Worker.
Zd1torlal Board: Rsep. Ed. j A. F. Plate; 1. V. Gostun.
Sks", 1. R. T%t$-SXvortsovq, L. A. Crivanakaya.
?==- Th1s colls,ction of articles to Intended for the
teaching staff of universities and Schools or higher ad.
u0st-lon training specialists for the petroleum and petrol-
eux-reftnIng industries.
Cal-d 1/7
CCVVLAZ-&: The collection Includes articles dealing with the
pr"e,mt *tat* of the petroleum lndustr7, the scientific
research probleats In petroleum chemistry, the chemistry
of petraleum. the composition or petroleum and petroleum
proftets, the scientific principles of refining petroleum
.1sto motor ruels and lubricamts, and the manufacture of
synt2tetlc prod4ct3 from hydrocarbon gases and petroleum.
One article discusaeo the effect of chemical composition.
and -,qL11tjv*s on fluol combustion In jet engines. The ma-
ter-I&I was :Presented at the Inter-UnIveralty conference
an Petroleum Chemistry, held at the Romeo. State Universi-
ty Im"l M. V. Lomumo3ov November 26.28, 1956. No ;erson-
autzes or* mentioned. References accompany most 01, the
?ABIS Cr CCMTZNTSt None given
The author* and the titles of articles am as roliaws:
Introdc.ction by D. A. Kazaaskiy, Amadvedclar,
Card 2/7

Collection of Transaotions (Cont.) sov/~941
Obolent�-evR. D., Bashk1rBk1y filial AN SSSR (Bashkir
Branch of the Acadermy of Sciences USSR). Specific Prob-
lems in Refining Sulfur-Bearing Crudes 128
Akishin, P. A., N. 0. Rambidi, I. N. Tits-Skvortsova, and
Yu. K. Yurlyev, Moscow State University imenI M. V.
Lomonosov. Study of the Raman Spectra of Certain Sulfur-
Containing Compounds 146
Dorogochinekiy, A. Z., Groznenskly neftyanoy nauchno-
isaledovatellskly institut i Groznenskiy neftyanoy in-
stitut (Groznyy Petroleum Scientific Research Institute
and Groznyy Petroleum Institute). Alkylation React,ions In
the Industrial SynthesiB of Hydrocarbons and Some of Their
Derivatives 163
Oborin, V. I., M. S. Ostrikov, I. V. Rostovtseva, and
0. L. Arutyunova, rroznyy Petroleum Institute. Effect
of the Porosity of Silica-Base Catalysts on the Cracking
Oftrt-57'~-T

31081/621000/005105811 1, 2
315 1 //--- I C I
Ho.~ Obolentjov, it. D. )o7,dryukowi, T. '1e. ,
i,ototskaya, A Ye -
TIILL': i of -io.,.~)-subst . ~ute6 t~.i ophan~s
-UD 1 C;.,L Refer t4v;-,jly zhu-C.-t-l- KI.J::iJa, no.
a L) s 'u ra c t 5 m s e ra - a z 0 t o r--az . I r, e r. iy
v nef tyE~kh i ,i--,f tepro-uktc~khl' . v.
2o k'lisya
met ho J s pu4 forw-rd foi Lae sjrt of a-su' , :;t" tute-I
t~.ic')hz.nes, strtii,.6 froi:. a.ejLfury'-carbinol,;, -1ccordinK Lo t",,e follc...ilng
so neme ;
licHfol,T) 6-GlCii=CFO CH ~OOC H ~11~-RCH(C)H)Cil CH I-H iii (IIII->
2 2' 2 5 2 2
R C HO r C H 2VE 2C H 2 Br V a 0 H~; li2CH20H 25 V I is converted by neating
for 2-5 - 3 hrs. in abs . C 2H 5 Oll containin&- 0-3 - 0-5/0' HC1 gas (ir the
Card 1/6

2
Tne syntaesio of mono-:~u--~-'.Uted ... B1547,
case o-" mol. vit. H t~,e heatinr is car.-ied out for 0.- iir,;, 4-,,~,l HCl-l
S Tj (IT
~14.tll jields of 55 - L)Gp, in'.0 et~vl ester,;^ I a-.-) -mu I ~lt, r
0 20 IG Tla,
-are :-iven the substance, R, b. d. in C,/mmHg, r. D, d
CH C(CF ),CH,, 89-91/4, 1.4346, 0.')~93j b, jH,"H c(Oi,)2~"2'
3 3 2 11
I C
1.4-,10, G-9562; c, CH 5 2)59 113-115/2, 1.4370, 0.9440; d, CH3 2)71
-132/2, 1'.4403, 0.9517; e, .1Z CH 145 "/5, 1.4450, 0-542~'
5 ,b
2)8'
70
CH 5- ( C q2)JOV -, im. ~~. 2~,-2, The :,- obtained art: re,'Juced
a two-fold excess of -Ti"~llll 4 to L.,;e cor~'C!~"pondin", :111 :!:a,
~l - ~t 1.4545, 0.9319; b, 21, '5,
10H C(CH 112-1 1. 4 /3
3 3)2'P'2' C73CH2C 3 2 21 1/
1.4637, 0-9373; C, CH3 (CH 2)5' 159-140/3-5, 1.45-.16, 0.9249; d, CH . ~~'OH2)79-9
P. 46-46.50C, (;H (Cif" )8, - , 4 1 - 5-420C , -
CH5 (CH 2)10p-p m. P. 59-40c, 9 g, 2-C '10H7 -' M. P.
h, 4-d-J,,henjl, p. 6() 0C, cyclo-C UH11CH2, -- m- j- 5~-5-60-000,
Card 2/6

.3/081/62/000/005/038/112
~--ie sjr."-~eois of mono-substituted . . .
B15j/B-,C)l
The !I! ~~lycols art-. Iiz~.~o~ 0
ved Jr, "lacial CH,CGOF L,,' -,he 4olu-.ion
.s.-,,.uratQ,j viit~, dry HBr ~,t C Lnd fr,,-~ctionatud, iihen t.,.e 17
ob t, in ed
21
""I c HP 1.5627j;
-5-4, 2~
0, d , CH, (CH, 1 )'7 15V -4~,j 1 .2 )70; C H
I ~jo-, 6"15, 1 - 4b,j3 201
1.4865, CH 5 2~lv
0 0
2-C 110H 7 54-56 C, h, 4'-diphenyl, -, n. j. 54-6~ Cl -f
2-1135/1-5, 1 .5202, 1.4"110. On 'builin- the
cyclo-1. 6H 11 CH 2p 15
dibi,cmides 1V for 3 ars v,,it,,, a ')G,o water-alcohol soluLiol, of ~lu 23 there
are formied, with yield.3 of 80-190,4, tne V 'V--k): va, CH ~(CH 3J2 CH 21
31
202-203/760, 1.4812, 0.9155; b, CE,1H CkCH 107-108/17, 1-48062,
1 2 3)2C"2'
0.9272; c, CH 3(CH 2)51 240-241/760, 1.4823, 0.9095, d, CH 3 (CH 2)7'
275.5 - 276/760, 1.4793, 0.8992; e, CH 3 (Gil 2)6' 292-295/760, 1.4792, 0.8940;
I'Erd 3/6

5/081/62/000/005/'03,3/112
The synthesis of mono-sl~b3titut~d ... B15!/B',Oi
CH (r-ii ' 326.5 - 327/76u, 1.'7ab, g, 2-C i m. z,. 74-75
3 2)"0' f 10 79
-9 n, 4'-di~,henyl, m. 5(1~-"Oo 1-1 -1 -; I, cyclo-CH
6
86-87/2, 1.5135, 0.9611; G6 1 5- G H21 109-110/2, 1.5710, 1-0)'77. '.71 t -, t tL c
-ethod Iriven ori,--,imL- phunji-
it was not possible to obt,.~in V ksince tho -
furfurylcarb,-nol on boiling wita an alcohol solut~-on of HCI resinifies and
the corresponding dibromide was obtained in anotY-er way. (R. I'aul, compt.
rend., 1936, 202, 1444). The glycols IIIU- II:h were obt'~,inell by the
reductions of the correojonding ~-(2-na~)ht.ioyl) z.nd -O-biphenyloyi)-
,pro~)ionic acids, synthi--oized by the condensation of the corl-esponding
hydrocarbons wi-.h tale succinic an.~ljdride usinr tl~.e Fr'edel-Crafts reaction.
'I p-anes were obt-,,in-d me-, '10d
by another
H.-C COCH OH(COOC H Hj, 'VII~
D 2 2 2 5 2 (VI' "i 2 2
-RCF(COOC H )CH MOC H
2 5 2 2 5 2 2 '~-ICH20H
~'iCH( CH2 Br)CH 2-.1 H2Br ( x -'2--"i2b'CH2 (X-T). T'lie Na derl4vaGives o. V'~
are condensed ir, the u:;ual way with halo.-en alkyls and yields of 8C)-50,')
of VII are obtained. These are japonified, decarboxylated and esterified
Card 4/6

s/oal/62/000/005/038/1112
The synthesij of mono-subotituted ... B151/B101
VIII (VIIIa-d) are obtained in a yield of 70-Mfg- V:I.Ia, (CH./. C
110-')012, 1.4260, 0.9710; b, CH CH -CII(Cli )CH 101--w~/2,
5 '2 5 21
CH.(Ci: 96-97/1-~, I-jjio, 0.9625; d, CHI (CH, 150-151/1, 1.43c,5,
2 41 3 7
19 4 5 V III io reduced vi i t.,. Lit% I H 2 5 mol L!G ) and IX~i-d ) are
dijtilled off: IXaj (CH 3 C'ic H2 1,B-120/1.5, 1 -4~25, 0-91596;
CH
CKCH,CH(CH )CH 120-~50/2.j, 1.45'0, 0.9269; c, CH
5 21 4'
-.e
1-45cbO, 0.9299; d, CH 3( C H2 7) 161-16212, 1-45~0, 0.9157. Fr o : i '. '-
obtLtiried by the method dei3cribed above the X (Xa-d) ar~-, obtaine,4 -. Xal
( C 1745'; 2 'HC H2 , 7 5- 7 6/11 - 5, 1 . 4"-'(3 5, 1 - 4 7 5 1 ; b, C 115C:I2CH'~CE5)CH 21 10)-1051 2-5,
1-497~, 1.4205; C, CH 3(CH 2)4? 114-116/,z, 1.4975, 1.4144; d, CH 3(CH 2)V
126-129/1, 1.4910, 1.5078. TIne X are converted, in the usual way into
X! 'Xia-d); Xia ICH C H C' H1260-2U!, 1.4850, 0.921' -F(CH
3)2 2' b, CH 5CHi 3'1-21
221.5-222, 1-4824, 0.9108; c, CH 3 (CII 2'4' 229-5-250, 1.4542, 'V-~!164;
d, CH (CH 282-5-283, 1.4808, 0.9057. The yields in XI were 84-93;,
Card 35/10 2)71

3/Q81/62/G00/,-,05/'G5,3/i',2
The synthe3is of mono-substituted ... B151/3101
based on X and 30-40;,. based on VI., .'~bstracterls note; Complete
- L
tranelaLion.~
,_r~ ~ 0

OWIERrSU R 0 - MMUMV, V.G.; WJ~ASIMOV, H.M.
Sulf*xides and sulfones of sow monosubstituted thiophanes. KhJA.
aemwi asotarg.soad. sad.v nof t.i nefteprod, 3:35-41 , lWo (ICU 146)
lo Haohk#skiy fiUal AN S=,, Otdol khJmJJ.
(Bulfoxides) (Sulfans) (Thipheno)

GMXMWT.-, R.D.i. BUKHAROV, Y.G.; GFMSIKOV, H.H.
Reduction of thiouhaw sulfmes and its hcowlogs by swam of
alumimn I.-yidrides. Xhimosem-i as4torgesoed.sod-v zeft-i
nefteprod. 'k.43-49 160. (MIRA 1.4:6)
1. Bag skiy filial AN SSSR, Mel W-14.
(Sulfons) (kluminma lithium hydride) (Reduction, Chemical)

IMUNTSEVo RD,; BUKHMVj, V.G.; FAYZULLIKAj, H.K.
Complex compounds of sow -cyclic and aliphatic milfides vith
mercury chloride. Khim.sera-i azotorgsoed,sod.v neft.i nefteprod.
301-05 160, (MIRA 14:6)
la. Bashkirskiy filial AN SMp Otdal WWI.
(Sulfur organic compounds) (Maidwy chloride)

OBOLENTSM R.D.; BUKHMV., T.G.; PAYZUT4LINA,, N.K.
lodowtbylates of sms cyclic and aliphatic m1fides. "'.sers-i
azatorg.sood. so4v neft.1 nefteprod. 3t67--U . 1600 NM 14:6)
1. Beghkirskiy filial AN SSSR,, Otdal 'rhimil
(Sulfide) (Iodomethylatio4i

3 11 C
S/081 ~1/000/022/001/076
2-0 1220 B102 B108
AUTHORS: Zimina, K,, I., Obolentsev, R.-D-7, Polyakova, A, A,.
Khmellnitskiy, R. A,
TITLE- Mass spectra of some homologs of thlophane
PERIODICALi Referativnyy zhurnal. Khimiya, ao, 22, 1961. 12-13,
abstract 22B72 (Sb, "Khimiya sera-i azotorgan, soyedineniy,
soderzhashchikhaya v neftyakh i nefteproduktakh", Ufa, v, 3,
1960, 81-92
TEXT. The mass spectra of a-alkyl thiophanes with rddicals of normal
structure from C 1 to C6 were studied by means of an MC-1 (14S-1) mass
spectrometer, Total ionization caused by 70-ev electrons was studied as
dependent on the molecular weight of the substance investigated: It is
shown that the total quantity of molecules and fragmentary ions increases
linearly with increasing molecular weight. The total ionization value
measured for thiophenes makes it possible to carry out an analysis of the
structural groups of heterocyclic compounds, The ionization potentials
of thiophanes were determined approximately. They were found to decrease
Card 1/2

S/081 61/000/022/001/076
Mass spectra of some homologs B102 BIOB
(from 9.5 ev for C1 to 8 ev for C6) with increasing length of the chain of
the alkyl radical,. The mass spectra of the alkyl thiophanes were all
characterized by the presence of an intense peak at the mass 87 which
r
permits identifying these compounds LAbstracter's noted Complete
translation.]
Card 212

MUMSR, R. .; LIUBOMM,, M.S.; MAK07A, Ye~A.
Abaorption spectra in the ultraviolet of some cyclic sulfides,,
thiantbrOns., and 2-ethYlthioPhons. Dim-sera.1 azotorg*soedosod.v
neftA nefteprod. 3:93-104 960. 11 (mim 14:6)
1. BashIrl skiy filial AN SSSR, Otdel 1chimil.
(Sulfide-Spectra) (Thianthrene-Spectra) (Thiophene-Spectra)

OBOLENTOT. RO.; KGTOV Yu.I.; CIMWV, Ye.H.
2
Tibratiaml speotra of sulfides. Khim.sera-i azotarg,soedeod.v naft.
nefteprodo 3*.105-114 160a, (K1RA 14:6)
1, Bashki skiy filial AN MUSH, Otdol WWI.
(Sulfide-Speotra)

~ ; RATOVSKAYA, A.A.; TINFUN, V.D.
OBqLWS&TL_R.D
Sulfide 'sulftw In s=e crude oUs of Bashkirla. Kh1Amr*,L asotor
soed.sod,v neft.i nefteprod. 3&1&7-172 .160 It (.Mk 14:61*
v
1, Baohkq skiy filial AN SSSR, Otdol WWI.
(Baabkiriar.-Patroleum--Apillysis) (Sulfur-Amlysis)
(Sulfide)

GDOLENTSET, R.D.; AIVAZOV, B.V. ; ZITOVA, K.V.
Comparative oharacteristics of various silica gel samolea based on
their relations to sulfur organic donpounds - cdutelmd in sow fuels*
xhim morar-i azotorgesoed,saLv nbfti nefteprod. 3t211-217 160.. --
(KmL 14&6)
L Bashkirekly filial All SSSR Otdol khWi.
(UUca) (Adsorption) JSuLfur orpnic compouWa)

OBOLENTSU R.D.,- ArIAZOV,, B.T-.; GATZMA, G.V.j GISLOV, U.N.
Composition of sulfur orgwdc compounds in a otraight-run fuel
produced frm Tuyvasy and Barly oils* IhImesera-i asotorgewed,va4v
neff.i neftaprod. 3tUlw250 16o. (MBA 14:6)
1. Bashkirskly filial AN 33SR9 OWel kbix".
(SulAw orgemic compounda) Mai-Awivis)

OBOIENTSEV9 R.D.; AYVAZIDVO B.V.; TITOVA,, N.V.
Role of almontary sulfur in the formation of hydrogen sulfide
durIng the heating of curde oils. Khlm.sera-i azotor#esoedo sodv nefte
J, nefteprod, 3:253-259 $60, (MM 14:6)
1. Bashkirskiy filial AN SSSR, Otdal khimii,
(Petroleum-Tberzkal properties) (Hydrogen. w3lfidc)
(sulfur) I

GBOIARMV, R.D.; GABDULLINA, L.Ve
91mUcs of transformation of 2., 8-dimthyl-5-thianona3me and 5, 7-
dipropyl-6~=dmaw in the presence of an al=lwsilicate
mta7et, MA,sem-i amotorgesoedaadev rPfj#i zofteprodo 3t261,-270
960. (MM 14:6)
1. Bashkireldy filial AN SWR Otdol WWI,
(Sonam I (Undecam)
(Sulttw orgwde compowads)

3/081 /u'2/0G0/D05/G57/1 12
3 5 1 /31 G
~AolentLiev, Dranov, V. I.
T I T ',.-4netic~, of Of somi~ ~:,onocycllc ju'-fides
in t,.L; 'j~-esenc':~ of a r
';Ilicute
"~IODIG.,L: iufonit.jv.-qy i ~~i no. 2 o, ,ct
ya r
,~Z~15b Oijj"I- i aZ0tOI---,,11.
soderzha.;ix~ii!-.~.sja v neftyal"hn i nt~fteprodul:t%Vlill v. 5
Ufa, VluD, 271-2~4)
T Z."T k-,netics o,' the of an~ I e i
(I), 2-etnylt~.iopl-.are (:1), 2-m~Ahjl thia-cyciolexanc k : i
I )
...-U'cycio'neptane (IV), ~V)
'VI' in tne i).ce3ence of a :lobular aluminosilicate
eti., .,-'oihene
catalj2t in a flow system, at ;~rLs-ure, is StuJled. For
1 - IV the reaction is carried Out at 350 4)0 0C an~; a vo-11ZA2 VLI-Oc: .Lty
(VV) from 1 to 40 hrs- for VT at 45G-550 C and VV 0.3 - 4 hrs at a
Card I/

T.-le kinetic-i of tranL;for;;;,~tlon of
concentr,xtion of 0.4),I~ 0 on tiio suifur in a ~; -H 7,'2d i wr
wit*- V are carried our 1-- cc:tan,~, and
5)0 - ~'0000, at VV fro:r, 2.~- to j0 -",u main, sulfur-cont~!
~Iroduct of all tne catalytic tr;,nal'ormationj is H The kinetic u:,t--crs
2
arCh derived. The dependence of t,e purameters of these equations on t-.e
reciprocal of tiIe albsolu~e te;-,,Periture is found. The ;-.iean velic'ty of
transformation of the monoc~,clic sulfidez tneir 311ruct-ure -Bind
~creases %-ii,". ~ncrei-~3ina- wei--nt. '2 !-, e r --, T, - o f t r c r:., o,-. o I
',-',at of t,-.e --soweric
Fo r t e i s om u r _4 c m o r, o c y c I i c u 1 z ,,i i t a n,! 6 :,- i ,? ~. i b er '.:~O f-Lt-Z~L;
a r , ~ a -,, o s T. e , u a 1 , a i i d i i _4 , ; ~ -, u i L i o r ~. i '-~ e r e , LI rn . ~, . . , *. '., , e
cis- and trans- isomers of the rates -,r,. very cl,),;"
to.et'ner. Tne difference in th,:.: rat--,L; oi' of t~- , C, -M G r, C, C j CI C
suifides.is reflected in the coi-3positior, of tna monocyclic ~;Ulf4deS c o;, L. In e d
in trie di~;tilled iroductL; from catalytic crackinl- w-ic.. enri,~;. 4n lori mol;
-,;t. sulfides and 2-alkZ(ltiio~.hanes at the expense of' hi,h mol. wt. Oulfidej
0
and 2,5-dialkythiophanes. Tho desulfuration of Petfoleum products in .,-e
catalytic crackint; process depunds on their hydrocarbon coiz~;osi-.ion, n I : n
card 2/3

-2/~,81/62/00v-/065/0 3 7/1 12
T.-,L kind t i r, s of t r a nsf or fzia t lior. of . . .
i-~ borne out by the diffe.-ant ratco of of V On
U
e -ulvant. "~-,e LLlU.-Ii.',o:;--'liCaLu CaLidySt Ca". Used for rid of
cyclic zulfides r o,i, e J r ja J x t ur i t t i t-,z t' e t of
tr,injfocmu.L ion of whici, i~i conai,;erably lower, i; Shown .'r, *~he cE~~ie of V:.
lo,,~pl~jto tranolation.'
,,bsLracterls noLG: U
3/3

OWIS-MISMO,-R.D4--WSHKIHAl A.V.
ff,Tdrogenolysis of sulftw organic compounds under conditions of
h7droginingo Khimosera-i azotorgooed. sod.v neft,i zef te- od 3:295
329 960o 5(FMIM 14--6)
le Bashkirskiy filial AN SSSR, Otdol kbim",
(Sulftr organic compounds) (Fetroleum-Refining)

3/08 61/000/021/014/094
B102YB138
AUTHORSs Obolentsev, R. D., Torikov, D. V.
TITLEs The kinetics of the hylrogenolysis of compounds of the
thiophina and thiophans series with a platinum catalyst
PERIODICkLi Reforati"7y shurnal. Ihimiya, no. 21, 19619 52, abstract
2IS420 Sb. 09himiya ssr~.- i asotorgan. o9yadinenty, so-
isrshashchikhoya v nefty-11a i neftoproduktakV, Ufa, Y. 3t
1960, 333 - 343)
TRITs the reaction kinetics of the hydrogenolysis of thiopbsue, 2-vtbyl-
thiophemag 2-butylthiophous, 2,5.-diethylthlophone, 2,5 -dibutylthiapheno,
2-butylth-iophAno.ond at$-2,5 -dinothylthiophans were studied, in the
-presenew -art a platforming catalyst at 3409 400 and 5000C, a total prews re
of 400 ats-, - a morlar hydrojon to raw material ratio of 5 11 and a mmtect
ttz9-of-O-,;5--; 9-sta. Kinetic equations are proposed which describe, tho-
dependence of depth and rate of hydrogenolysis on contact tines and
relatiops.isre derive& for the temperature dependence of the parameters of
Card 1 2

8/08 61/000/021/014/094
The kinetic* of the bydrogenolysis of ... B102YB136
the kinetic equations. The reaction energies of hydragenolysia and-the
kinetic coefficients of the activity of the reactions are determined.
[~bstracterfs notei Complete translation.]
Card 212

CHUMMS Ya*B*; MMOV" V,N,;
Mormal stability of wilflur cooqxnmds and their effect an the
perforiozm characteristics of fuels. XhIjuasm-L asotorg.soodood-T
neftei nefteprod. 3t463PW+68 060. (MM 14:6)
11 1 isoledovatellaidy institut goryucho-smasochnfth
mater , Bashkirskiy filial AN SM.
(Sulfur organic oompdWAs--T -4 .1 pro))Srties)
(ftel-Test

TINDOUNA. 14.Z.(Ufa); KRIVOLAFOT. S.S.(Ufa)-. 080=bM59K, R.D. (Ufa);
IND STVINSKIT, T.F. (Ufa)
Reduction roasting of rich iron ores by mixtures of petroleum
gas and water vapor. Isy. AN SSSR. Otd.tekb.iumk. Met.1 topl.
no-5:19-24 S-0 160. (MIRA 13911)
(iron ores) (ore dressing)

5/)79/60/030/04/47/080
BO')I/BOO2
AUTHORS* Zisina, K. I.* Polykova, A. A., Khmelln:.takiy, R. A.,
Obolentsev,-i. D.
TITLEs Mass-spectrometric Investigation of Some Homologs, of
Thiophane I
PERIODICALs Zhurnal obahchey khimiip 19609 Vol- 30, No- 4, PP. 1264-1268
TEXTs Only a small number of reports on the nano spectra of sulfur com-
pounds had been hitherto published. Detailed investigations were only
carried out with respect to a series of thiophenes, whose spectroscopic
data were# as *xpected, similar to those of alkyl benzenes (Ref. 2). In thf,"
present paper the results of mass-spectrometric investigations of homo-
logous a-alkylthiophanoo exhibiting radicals of normal structure (C I - C6)
were described. The spectrometric investigation by means of the already
earlier (Ref. 3) modified mass spectrometer MC-I (MS-I) is described in
detail. The distribution of the mass intensities in the spectra, the
values of the relative sensitivity, and the dependence of these values on
Card 1/2

Mass-spectro2etric Investigation of Some Homologs S/07g6o/o5O/O4/47/080
of Thiophans B001 002
the molecular weight were determined. The complete ionization was computed.
It was shown that on identification of the structures, and a qualitative
analysis of a-alkylthiophans mixtures Is possible. The accuracy of the
quantitative analysis of the mixtures is relatively 10 -15%. The data given,
are partly provided by the Toesoyuzuyy nauchno-isaledovatellskiy institut
neftyanoy promyshlennosti (All-Union Soi6ntific Research Institute of
Petroleum Industry). There or* 3 figures, 2 tables, and 5 references, I of
which are Soviet.
SUBMITTEDs March 28, 1959
Card 2/2

0
0 0
AUTHORSs Obol Rjgjv-,-R, D., Dronov, 19 SDV/20-130.1-27/69
T-
TITLEa Transformation Kinetics of Some Monocyclic Stulfidao on an
Aluminoollicate Catalyst
PERIODICALs Doklady Akademii nauk SSSR, 1960, Vol 130, Nr 1, pp 98-101 ~JSSR)
ABSTRACTs The problem mentioned in the title is of importanoi, in connection
with the catalytic cracking of petroleum containing much sulfur.
With their paper, the authors wanted to i-~Iose a gap in the
respective publications. For this purpose, they used nis- and
transisomers of 2.5-dimethyi.thiophene and 2,5-di-n-propyl-
thiop4ane, 2-ethylthiophane, 2-n-hexylthiophane, 2-methyl-
thiseyoloherans, thiacyolohaptane, and 2-athylthiophone.
A continuously working laboratory apparatus was used for the
experiments which were carried out at atmospheric preasure. The
voluno velocity was between 1 and 80. The sulfides were catalyzed
in benzene and some other solvents as 0,45~ solutions (computed
with respect to sulfur). The catalyst used was an aluminoollicato
ca+el-st with the activity index 33. A sulfur balance was made
Card 1/4 for each experiment. Ito authors proved that H 23 is the most

6 79 5?
Transformation Kinetica of Some Monocyclic SOV 20-130-1-27/69
Sulfides on an Aluminoeilicate Catalyst
important sulfur-containing product of the transformations
mentioned. The quantity of mercaptane sulfur in the catalyzates
does not exceed 2.5% computed with respect to the sulfur content
in the initial raw material. The sulfur content in the coke does
not exceed 3/o of "he sulfur in the initial solution. Equations
(1) and (2) suggested in a general form by A. V. Frost (Ref e 1, 4)
and S. A. Kazeyer (Ref s 2 ~ 5) were used for the kinetic
characteristics of the abo-e traneformations. Table 1 shows the
characteristic values determined for the kinetic equations of the
above substances. Their degreee of transformation were computed
in dependence on the contact time at 350, 400 and 4500C.
Figure I shows such a dependence at 4500 as an example. It shows
that the points determined experimentally lie rather exactly on
the curves computed. In a short contact timeg differences in the
average transformation rates of the cyclic sulfides occur. This
rate increases with the molecular weight of the sulfide. From
this and other differences found, the authors conclude that this
phenomenon certainly influen--~ea the composition of the cyclic
sulfides contained in the distillation products of catalytic
cracking. These products are enriohed by low-molectular sulfides
Card 2/4 and 2-alkylthiaphanes at the expense of the centent in

Transformation Kinetirs of Sjom-,~ SOVPa')~ 1 3)~ ' -27/69
Sulfides on an Aluminosilicat-~~ .-atalyst
high-molecular sulfilea ar.L-1 2,,.5---Iiedkyithi3phares Thus , it was
-A-,7st r,,an be used 'or
shown I-hat an al-imino 9i 11cat e cat ~ I
eliminating mon3~-ycllc sulfides from. their mixture with
thlophoLes,, The factors of dIffLsI:n ir-h-l"Ition compared
and 19.1j. 31hche..4r fRof 6) showed
aeoording tc., A. YFA~ k
that - dapendire ~n !:he grafn size of the oata~7at
.!s-2,,5-dimethyIthIcpEane is either transf~,-,Avc-d in the Inner
diffusion range or 1~. th-a 7ange, The authora assume
that distillates with tha lawps, =v~-,fur ~-)r.,~ent a-fe p:oduoed in
oracking in a eusp.;-asion w~~U a ,.'.y8t, r,-,gf.ITA- 22,
shows that d'-svolved in benzene
and oe--methyl. naphthalen--i., 1!3 mc,,et z,,xp14ly ransforrv--Id.
'!--, -etar- IL slow6e~ t t sf;)
-1, 1 . A - - . I . 0 Tan -z M
A higher content of tsooct7leme in tl~ i tane --i ao.- .-- ty lane
mixture rsdu,~ey +b-, iatena~ty o! ~:Is--2,5-dlaeth7l-
thiophanp (Fig 3). The degz*~- of desulfuvizzatior. can be
Card 3/4

67952
Transformation Kinetics of Some Monocyclic SOV/20-130-1-27/69
Sulfides on an Aluminosilicate Catalyst
determined from the kinetic characteristics of the sulfide
mixtures 4n petroleum products. The total intensity of
transformation of,a sulfide mixture follows the rule of
additivity (Fig 4). There are 4 figures, 1 table, and 6 Soviet
references.
ASSOCIATIONt B~shkirs)ciy filial Akademii nauk SSS'R (Bashkirl*ya Branch of the
Academy of Sciencee, USSR)
PRESENTED-. July 79 1959, by.A.V._Topchiyev, Academician
SUBMITTEDt July 6, 1959
Card 4/4

1~67 a ~ .2 0 8COCI
AUTHORS: Obolentsev, R. D., Mashkina, A. V. S/020/60/131/05/030/069
------ BO11/B117
TITLE: Kinetics of the Reactions of Hydrodesulfuration
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol 151, Nr 5, pp 1092-1095 (USSR)
TEXT: In their paper, the authors report on the results of the systematic study
of the kinetics of hydrogenolysis1for 14 sulfides and thiophenes in the presence
of an aluminum-cobalt-molybdenum catalyst (Al-Co-Mo). Experimental methods used
were described in reference 4. Figure I shows, as an example, the curves of the
dependence of the conversion degree on the time of contact for 2,4,6,8-tetramethyl-
5-thiononane. The shape of these curves is characteristic of all compounds
investigated here. Hydrogenolysis is well-defined by equations suggested in a
D b
general form by Frost (v 01n 11y- - a+pv0y) and Kazeyev (In D-M. ar ) (v 0 being
the average feeding rate of the compound used to the reaction vessel per 1 g of
the catalyst per 1 hour; y the intensity of hydrogenolysis Jn fractions of
unity; a and P parameters; -r time of contact in seconds, H ;he intensity of
hydrogenolysis in %; D the limit of M for T # oo , a and 'i perameters). The
parameters of these equations for 14 compounds investiga;ed Lre given in table 1.
From an analysis of these parameters, it follows that the ordanic compounds of
Card 113

tooc I
Kinetics of the Reactions of Hydrodesulfuration S1020160113110510301069
BO11/B117
sulfuriform as to their rate of hydrogenolysis, the following sequence with
increasing activity holds; A, B, V, G, D, Ye, Zh, Z, K, L, H, N, 0, P. The
values of the parameter a are proportional to the rate constants of the hydro-
genolysis reaction of these compounds at 375'. They are related to each other in
the following way: (A, B, V, G, D) : (Ye, Zh) : (Zi K) : (L, M, N, 0) : P =
- 1 : 2 : 3 : 4 : T. The possibility of oLtaining a selective hydrodesulfuration
of petroleum products on the Al-Co-Mo catalyst is based on this dependence. In
addition, this catalyst may be used to perform group analyses of organic compounds
of sulfur. This dependence makes it possible, moreover, to predict the type of
products formed by hydrogenolysis. The hydrogenolysis rate of organic compounds
of sulfur obeys the law of additivity (curves in Fig 2). Thereby, the prediction
of the composition of organic compounds of sulfur formed when petroleum products
are hydrodesulfurized is made possible. The authors intended to study the in-
fluence of the reaction products on the rate of hydrogenolysis. Dibenzo thio-
phene solved in cetane with diphenyl and H23 added was therefore subjected to
hydrolysis. Maximum intensity and rate of hydrogenolysis are rapidly reduced by
the addition of biphenyl to the initial solution of dibenzo thiophene, but are
practically independent of the H2S added (Fig 3). Dibenzo t~.Lor'Aene together with
its derivatives represents the major part of the so-called II.-.!sidual sulfur".
Card 2/3

800C
Kinetics of the Reactions of Hydrodesulfuration S/02Y60/131/05/030/069
B011 B117
Results obtained are of interest in the processing of petroleum. From table 2,
it is obvious that hydrodesulfuration should be performed in the dispersed layer
for the beat results. YAoreover, data obtained by the authors can contribute
to the development of new ways of obtaining hydrodesulfurizing catalysts. The
main products of hydrogenolysis are H2S and the corresponding hydrocarbon.
Monocyclic hydrocarbons are not hydrogenated practically under the conditions
given. The Al-Co-Mo catalyst can be used to identify organic compounds of sulfur
by means of their hydrolysis products (analogously to Raney nickel). There are
3 figures, 2 tables, and 4 references, 2 of which are Soviet.
ASSOCIATION: Otdel khimii Bashkirskogo filiala Akademii nauk SSSR (Department of
Chemistry of the Bashkiriya Branch of the Academy of Sciences. USSR)
PRESENTED: December 8, 1959, by A. V. Topchiyev, Academician
SUBMITTED: December 6, 1959
Card 3/3

..OBO;Aga&V+-B.D*-t-prof.t dok-tdr khim, nauk# otva redel GLADROVA9 LvK*j
red.; DRONOV9 V.I.v red.j KALANTAR9 N.G.9 kand. tekhn. nauk, red.;
KIIMZV, G.M., red.; POZDEYEVi N.M.j kand. fiz.-mt. nauk, red.;
KLEMMOVAI, K.F., vedushchiy red.; FEDOTOVA, I.G. 9 tekhn. red.
(Materials of the Sitentific Session on Chemistry of Sulfur- and
Nitrogen Organic Compounds Contained in Petroleum and,Petroleum
Products] Materialy Nauchnoy sesaii po kbimli sera- i 'azotorganicho-
eldich soedinenii, saderzhashchikhsia v v#ftiakh i nefteproduktakh. 5th,
Ufa, 1999. MO*7a,, Gos. nauchno-tekhn. W-vo neft. i gorno-toplivnoi
lit-ry. Vol.4. [Chemistry ofsulfur organic compounds contained in
petroleim and petroleum products] Khimlia seraorganicheskikh soedine-
nii, scderzhashchikbsia v neftiakh i nefteproduktakh. 1961. 278 p.
(MIRA 24:9)
1. flauchnaya sessiya po khimii sera, i azotorganicheskikh soyedinen4v
soderzhashchikhsia v neftiakh i nefteproduktakh. 5th, Ufa, 1959.
2. Bashkifskiy filial AN S=q otdal L-himii (for Obolentsev).
(Petroleum-Analysis) (Sulfur 3rganic compounds)

PSM I BOOK EnWITATION SM/5769
Obolentsey, Roma Dmitriyevichp and Anna Tsai:~Iyl-vn& Nhahkins
------------
Gidrogenoliz seraorgmicheskikh soyedinenly nefti (Hydrogenolysis of Organic
Sulfur Petroleum Compounds) Moscow,, Gostoptekbizdaty 1961. 143 P.
2,100 copies printed.
Famcutive Nd,:, 0. N. Yenisberlova; Tech. Ed.: k. S. Polosira.
PURPOW: This book is intended for scientific workers and engineers at research
institateaj, design and planning organizationss and petroleum refineries,, and
can also be used by students in advanced courses in schools of higher technical
education specializing in petroleum engineering,
COVERAM the book systemati2es and describes reactions of the hydrogenolysis of
organic sulAw compounds of the type present in petroleum crudes. Information
Is also givea an reaction thersiodynandca,, kinetics# and L the mechWam of
reactions vMch constitute the theoretical basis of the hydroreflning process.
A al-IfIcaut part of the data can serve as refervince material for desigaing,,
plannin9j, and operating hydrorerining installations at petroleum-mrining plant4
Card 1/3

ffydwgezo1ys1s of Organic Sulfur Petroleum Compounds S0715T69
No personalities am mentioned, There are 116 references: 67 Soviet,
46 English., and 3 German,
TAKE OF COMMUS:
Introduction
Ch. 1. SydragienolLysis of Organic Sulfur Compounds In the
Presence of Oxide and Sulfide Catalysts 21
Ch. Il. Tbarmadynazoic Probability of Reactions of
Sydrogenolyals of Organic Sulfur Compounds 3.-L
1. Sam thermodynamic features of organic sulfur compounds 31
2. Ergat affect 31
3, Equilibrium constants and equilibrium concentrations 37
Ch. M. Xechanism and Kinetics of the Hydrggenolysis of Organic
Sulftr Compounds - 51
Ch. IT, me "e- and rdnetics of the Hydrodesulfurization of
Fe Prod=ts U6
Card 2/ 3

S/08 62/000/005/039/112
B1 51YB101
AUTHORSs Obolentsev, R. D., Bukharov, V. G., Baisheva, A. U.
TITLE: Synthesis of cis- 2,5-dibenzylthiophane
PERIODICALi Referativnyy zhurnal. Khimiya, no. 5, 1962, 264, abstract
5Zh237- (Sb. -'Khimiya seraorgan. soyedineniy,
soderzhashchikhoya v neftyakh i nefteproduktakh. v. 4." M.,
Gostoptekhizdat, 1961, 20-23)
TEXT: A new method is developed for the synthesis of the stereoisomers
of 2,5-disubstituted thiophane (I thiophane). By bromination of adipic
acid (II) a mixture ( 90%) of almost equal amounts of the isomers of
2-5-dibromo-II is obtained, and these are separated by the et,-ql esters
(EE) into the crystalline meso- and the liquid racemic forms in a yield
of 30%. The latter F.re oyclized by the action of (NH 4)2 S in a mixture
of water and alcohol and acetone in the cold to form the isomeric EE of
thiophane-2,5-dicarboxylic acids (III) in a yield of 64-65A- on
reduction of the trans- and cis-111 the corresponding glycols are easily
Card 1/2

3/081/62/000/005/039/112
Synthesis of cis- 2,5- B151/B101
obtained (yield- 100%). These are unstable to heat. The halogenides
prepared from them (PBr 3 or SOC12 in the cold) are o~ low reactivity. For
instance LiAIR 4 reduces them only with difficulty to 2,5-dimethyl-I in a
yield of 35~6. Li-organic compounds react more energetically. With
C6H- Li, from cis-2,5-dibromo-methyl-1 firstly cis-2,5-dibenzyl-I is
obtai-ed in a yield uf 55%. Another possible method: ill + CR 311gl
(or C2H 5lIgBr)-,.2-5-bis-dialkyl-oxymethyl-I (yield 42-75%)---2.5 bis-dialkyl
chloro-methyl-I (IV) HC1 (acid) yield 75A Oid not give results, since
1V does not form an Mg-or.-anic compound and is only with difficulty
reduced with a large vxcess of LiAlH 4 even with prolonged boiling. The
substances so formed, yield 50~-, probably consist of a mixture of the
corresponding 2,5-bis-dialky3methyl-I and the products of dehydrochlorina-
tion of IV. Abstracter's notes Complete translation.
Card 2/2

S/081/62/000/006/069/117
B149/BIO6
AUTHORS: Obolentsev R D Timofeyev, V. D., Ratovskaya, A. A.,
-;-~;~~ova, ~A.&,"afikova, L. G., Gavrilova, L. D.
TITLE: Group-composition of organic sulfur compounds in petroleum
from the Bashkirskaya ASSR
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 6, 1962, 527, abstract
6M135 (5b. "Khimiya seraorgan. soyedineniy, soderzhashchikh.,I-
ya. v neftyakh i. nefteproduktakh. V- 4", M., Gostoptekhiz-
dat., 1961, 103 - 112)
TEXT: The total sulfur, sulfide and elemental sulfur content of crude
letroleum from various deDosits were determined, the former by double
combustion, the two latter by anode polarography with solid electrodes.
In addition, the distribution of organic sulfur compounds accordine to
fractions with onset of boiling at 120, 120 - 200, 200 - 250, and 250-300%
from a series of petroleums was studied. The sulfide sulfur in the
fractions was determined by the iodine complex method, the meroaptan
sulfur by the Gri-ma method. Elemental sulfur was found in only one of
Card 1/2