SCIENTIFIC ABSTRACT NOGINA, N. A. - NOGRADI, T.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001137310015-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KMYEV, 0.7,; KOGINA, N.A.
Classification and identification of soils In Central and Eastern
Siberia. Krat.soob. BKNII no.3s65-72 162, (KMA 16:5)
(Siberia-Soils-4ldsalficatiqn)

ALESSAMtA, I.V.; DIM, V.M.; MMMVAp V.S.; -ROGINA, M.Al;
FMIMUNAt G.A.; PAZORENNAp II.A.; TSERLUG, V.V.; ~EMXMv E.I*
Second Congress of Soil Science Delegates, Pochvovede~is
no.1:93-102 Ja 163. (MMA l6$2)
(Soil reaearch-Congreases)

EOGINA, Nina l7v'-:,.'A, Yi7-,.I;., d~-kt-jv ovllkhoz. rjauk,
otv. red.
fs,oils of I-rkrisixilkal im i ro~. tivy Zabitikfi. 'JR. Moskvaj
Izd.-vo "Nauka," 191-1, 3,11-1 1). (I-IIHA 17.10)

HARM'S, A.7o; GRMT, X.Te.; ROGINA, O.P.; SALGANNIK. G.N. (deceased);
SKMMV. G.I.; STIPANOt.-M.-U.-, IMA-KOVA. T.N., red.; TAMLUICH.
Ts.L. red.; GABIRIAND. R.1., takhn.red. ,
[Lecture couran for pregnant women] Kura leictaii Me beremanykh
zhenshchin. Pod red. L.G.Stapanova. Izd.3- Kosicva. Kedgic.
1959. 231 P. (MIRA 12:8)
1. gauchno-lealedovatellskiy institut akmaherstva i ginakologil
Kinisterstva zdravookhranonlya RSFM (for all except Khanova.
Yankelevich. Gaberland). 2. Direktor gauchno-issladovatellskago
Instituta akasherstya i ginskologii Kinisterstva zdravookhrans-
niya RSISR (for Stapanov).
(FMATAL CARE)

RMOVITS, Rosalip Maumovna, kand.med.nauk; BTU% Madechda, Romanowna;
.. ROOINA, 01*ga.Pavlovna, lmad.med.nauk; MARINA, N.M.. kand.med.
-iiii&, 'red@; KAIMANOTA, Ye.G., red.; ZATVAH. B.A.. tekhn.red.
[Kother's diary) Dnevalk materl. Hod.-sost.O.k.""aglaa. Bad.
U.N.Akeartua, I X.G.Xarnanova. Koskvs, In-t sanitarnogo prosT.
K-vs zdravookhranentia SSSR. 1960. 178 p. (MIRA 13:7)
(CEEILDM-CARF, AND HTGURS)

-a w a we-wow* 0 0,0#0 0 0.0 0 0
:04 a j 1 4 , I: I A I a It a as w a Is U
A I r-
004 B.A., I- IA a dr.
000 -6.
009
000
SIG. Inceractim ad Acetl$"w And McCVUCY CifitatUO Ob-
;00.! Absence of FAIM& fin Ituftian.) IC KIL FMI(OW41 "I"I
HKIleffs of Me Academy of Sriatefrs
o. fy.%&
of 'r'tiax of chrofiral scieaers' no. 1, 1947.
00.1 P, 105-106,
0: The Interaction of acetylene anti mercury chb,rM,
in the 414carv of a 1.,Ivt.nt. at 100'(".. rpsullpi if)
0
formation of cis-betachtarvinylatercurte chfori.le
00 in cood y1eK The (ran# compound is famed only
00 in a very small quantity.
calm
WIP 'Ut
4113
(A 6 A# F 1
woe W4116 flux MI
.00
K0*
coo
40
0
4*0
as*
goo
roo
9 0 As a a 4 4 3 6 If

AcV4m d braWas an dtlarocubQ"(". R.
A. N. Ntsca4yursaw (Icul.
(h chtm.. Ifoscuorl. /emit. A444, mesa S.S.S,R.,
;
M KhIM -VIS41ir NO, &II-S.-IfCAVIIS 10 11. StOiCCI
with 132 c, Or IN bro. tm 4 stftm both q~cve 204 C. Itt. I
ciftcli'llf. AV. yi,W. WAS%. FAMUMIly. P"Nccl
'(t" 9 ~ give 136 C. IT- 32-3% eV
A192.4." J247.). fictf*hccl elve 43,70 MccIfEte-
t~ffjlr%je, 1~,. A] ~, , 1'. 1A# 1 .500. d:* 1~7?02; j~%- -
flu( WC I 94VV 44W; ClItIVII IMPI 1.2.3-
m4p., h. QI-3% av LNrM,
3:1 1.76-N..'ad 1", lfk:, 0" lot? dor 23W..
G. It. K(4014p-d

a it m Its U
It. C- L..x
of.

so 4

00 1

4 Usalum Tetrachgoe4o Whit Akefials
dm tw4cwr of Ammomis 404 ryrwsw. (in
Rtmian.) 0. V. Ntitew, R. Kh. Fretiffina. ad A N
tieviflo .41-adeffia Nouk SSSR (MA-fto
fit fhq- Aratlemy of 4kictmvt 44 41w USSR). !"to.-tv 1,11
p U17-1iU,
RemAkm of TrCl. with rthyl, go-butyl. 4110, AlMl
444(ilie (n 411V PCtwg'tKV (A %3f. AVAI Ilif
woh cjufm to Itw pn-.wimv.,f .~rjaigm.
itordicAfni. %viii-ral arw eximpwiml- *rev tAItAm;vl
AVAI thrOf fill% %k-Al ACIAl ACCUICAl
so
00 1
'40
cow
91104D
go 0
7A8 0
-00
480
!40
i_ 4, V-# I V 1A
-Q b u 44 If VC C1 M KIM 411 4 ICA
foe & : * o 0 0 0 0 40 0 00000 0000 0 0 0 0 0 0
60 o o 0 00*00 10 0 40 0 0 0 a & 0 0 0 0 * 0 0 --* 0

ON damoda Mill v. 'x0vuA. k'
Mins. and A. N. Newwrasm, Inv.r. M4_
"Vit"AO 'CV.S. K., tAW4. Kiksom. Vdak 1"0, =7 Al. - 1*44:1.
,1-06 " ficid qR0)jj fit ird. fixtorct trieb kill$ tialt- lit'l
t, *4mits4ted (mmc,ft4(v(y fly itwi4to 4 alk IVACCUll.
.-Am aWn, of U C. TKU. to 60 C. RUM, go C, pytt-fittv,
Aft.1 31111 tug. 'Velle with im et-Actc. t0410""I for j ft. At
ild~--711* And filtrallIm. 1(aw 67", 1" 14;'."
.'*$,it'; tAU^itJV UK VVIOAUM-11CI M14.44MIC ill OW t4tilAqe
"'It"'ll with Itte "CIC4141 rntvl ductile dt'444.
I W4 4.), 9 1. (IyIkfi(SC-1(CI, A11111 WS till. C.114 i;Aftlf 2
1416, lit '046 A 091V 77i'~ (11.01)4 (14MINTI &W% nat
WACI W A'Alle , twith kv reastille, 443". a
I jj'j, I,$ ~1111 S 1404 111, 1446AM fly P.4"4fV 44 Mf, I..
A.a of pici ams 1"Atil's '~ lit. At '40" $At. AI,$
014. 4 b414 111114. 1-4 4W J . A 111P p 11014 4. 0-
Attwd "Uh I M C. hut If 101; V441 40 C.1 (. 4cf-Ard a 41(s 441
91 1`14011. (11HOWd 6V NUIASACKW ; lVA401(i ((I V411. *till
erfl.141M all 111C 961401111(filIg .4jent IrAWO' A 111', ~Nbl.
skm M(iln. of VA S.'rict. 1.6 V44 a Clot. 4:10:11,4111 04.10
-disigg. hAktIored hydwy X 11. twi. Knit& 0.5 C., ami I.-.4it'd
I lit. At -it NV Coirr.141 j, I's. (p. 141 ~.". -
M42`~ rwu Is uIpwiscrIf whm C.M. to u-.cd 40 A 'Iduent.
th; PO`(XIUCt b#.# 15"'. ROW AIUQ. 01 24 c. TiCl. to
15o g. W011 with ke awfing. fill(owril fly (try \116 (WI.
C-Ain VA C.), Own twalitiC 41) cittin. at 741'. fdtrAtkxt tvis
C'mcls. i0i S.'rao, 414114. "ith V41(s in YVA. ft~k(UAI
AM# MIl"t"11 111ft-01-1. CAVC 7"" APP411, N I
AiMil. ve id 41 Of. XI a IM. . mA S.,
Vill till. 4:,Il, Witte ftdutc. t,v.tlrv N.M. 1.W W Iss-
"ith 1A.Stitta. fittlitti4ill, AlM 4(t44"
AVA., fiat.% 2,11 . 4;. It. k.-JACM4

FRUDLINA9 R. Kh.; NOGIWA. Q.V.; KFMMUMOV, A.U.
Bromine
Effect of bromine on alkylchloracarbortates. Uch. Zap. Mosk. un., No. 132, 1950.
9. Monthl List of Russian Accessions, Library of Congress, October 195-!P, Uncl.

NOGINAO 0. V.
USSR/Chemistry - Organic Titanium Compounts Sep/Ok-.t 51
"Action of Chlorine and Bromine on Alkylorthotitanates," A. 14. Nesmeyanov, R. Kh. Freydlina,
0. V. Noginal Inst, of Org %em, Acad Scl USSR
"Iz Ak Nauk SSSR, Otdol KhIm flauk" No 5, pp 518~-523
Fourd that action of C12 and Br2 On h;t, n-Pr, and Bu orthotitanates gives good
yield of compda of type (RO)2 TiHa'2. ROH and that orthoalkyltitanates cause ester
condensation of aldehydes according to Tishchenko. Synthesized following previously
unknown compdst (RO)2TiBr2'H0H (R = Et, Pr, Bu, resp); (RO) 2TiC12'RCH (R = Pr, Bu, resp);
(pro) TiCl by interaction of pyridine chloroaydrate with Pr orthotitanate; and (RO)4Ti
(R = hEt, Bz, MeCEt, EtOEt, resp by re-esterification.
PA 195T7

11cr-ml, 0. V.
WGIVA, 0. V. -- "Develop-4nt of Methods for the Synthesis arr4 Study -)f the
Characteri5tics of Organic Compounds Containing Titanliv." S'ub 20 ~~r
522 Inst of Organic Chemistry, Acad Sci USSR. (Dissertation for the
Degree of Candidate In Chemical Sceinces.)
SO: Vechernaya Moskva Jamuwy-December 1952

NOGINA. O.V.; PIMYTRUMA, R.Kh.; nWRYe.UGV. A.N.
Synthasis of trialkoxytitanlum chlorides. Bull. Acad. Sci. U.S.S.R., Div.
Chan. Scl. 152, 81-5 (RagI. translatioal.
(CA 47 n0.19:9911 153)

Imi-lat 0. V.
Chemical Abet
Val. 48 No* 9
ft 10t 1954
Orpnio Chodatry
A"kah-ow. rA.
CA,
49, 56Tc. ff. L. if.

~40&-w(A.41 0.4.
him
1tw&wAkd" sad skehals. -.L H Kh.
4 WOO=.

""M, ako VY(
I-AC-S41 yields ROTiCts as the We product. The rescents

(D AvAtid; d4--a-4 thoroughly dry and the react1cm muikt be protected agaftut
4 atm. mal-ture. To 142.5 c. TIC14 and AM ml. pecr. ether
(b."') was gradually added 30 j. PrOH In 200 mi - petr.
ether. the mUt. was rdluxed 3 hn., concd.. and chilled,
yfecifing a t. which itas scipd. and distd. giving after 2
distrus, 96.6% PrOF70ii, bio O-S', his IM-2-, in. 6"'.
Similarly 142 C. TIC14 and 23 g. E(Oll In pecr. ether Cave.
h
i
f
rom a coacn. of t
e
on
after I hre. mffux. decantat
sola.. and chfUlac, Z7,5% FjOria., M"*. Mid
CCI
f
2
OH I
223
l
d
4
h
o-Bu
.
ter
n
m
2
# gave a
26 C.) an
924*
d ti
l
00
i
H
O riC
b
A
I
2
so-
%. reaux an
a
ng. near
y 1
h.
.
,
%
81-3*
ka-AmOH (44
) and 142
TICI
In
ett
m
5 C
.
.
.
.
.
,
p
mi.
ether give after 5 firs. us 9S.5% iso-AwcOVai, bit
*
'
110-11
. m. "
; C4HnOH and VC14 similarly LAve
after 3 hrs. reltux nearly IM9,' CArOrXlt. be 120-2-. in.
TICI
17 F38
4 142
5
I
.
ts
C.) a.
,
F.
MOUIC itearly IM a MOCIrs-
o
~
slow(y at I" at 5 mm'.
IS"'
bli
d
t
m
I
d th
d
It
W
I
ft
e su
uc
.
wu
n
.
.
au
me
pro
,
n pe
;
ether, C". CsHC. at Stio. 0. M. Kowaaaff
O
V
-4z-41w;1---..-. RM

MU)themistry - Titanium C*n*&mdz Zan/reb 52
"A New Method for Synthesizing Trialkoxytit-nn-lum
Chlorides," 0. V. Nogina, R. Kh. Freydlina, A. N.
Ntameysnov; Inst of Org Chem, Acad Sci USSR
-11 Ak Nauk, Otdel Khim Nauk" No 1, PP 74-77
T-h* nev synthesis is based on the re-etherification
of thietboxy ti~,anium chloride, and proceeda as
follows:
(C050)3T'Cl 3 Ron 4 (RO)3 TICI + 3 C 2H5OH.
208!06
UM/thimistry - Titanium Compounds JanlFeb q2
(Contd)
A w=ber of heretofore ualmown compda was synthesized
by tbis method, Vhich in quick and gives an almost
qftnt yield.
20&1,6

0A.
Ift; lef 88mi
(D ex4t" (j,,v%c4C&t app. provided with drying tutj,-s (cw exclusims of moisture 102
C. dry altyl &k. and 256 mi. dry Cjl* is treated with ke
coo(int with 60 c. T*LCI4 aver 3G- 40 min., alter which the
mixt. satd. with NIf. (rxot ten than 23 c. run (a wt.) and
fiftered. The filtrate yiekto 4t-6%(CII#:CffCIfO).V. th
t4l-2*. whkh is very hycroscopic and rexxWy hydrolyzed.

dw,w. aA- 1 It Ora
F-w awl F
IV=)* cf. G.A.44.315G.-To-M-C.
F 1'1~
4w C.
dry MW M ad.' drl~
Cife is
&CMcd with k4 ~Owrlg. ff.
T I= Mist.
N then he4ted a ka at P-70, Coom W(Tb OW atid
futered. The Oltnt;; itetas as~ mouria. ba 174-6".
All mcksturs amt be extuded on hoO14 tW pWuet

.in'l A- 13- Brh-,s JJl-
11'r- -V 0"'.
Sedhtenif. Sbarmik 2, d. C.A 44. Sk-,Ii -
To C49) nit. atm. MOll k graditalh- addt-d % ith c-litig ;,t,.1
mirving t42 g. TiCl., aftvr %hich the mim i~ '%0. with 'ttv
ml, With Ice mAing 1111fil 5t g. pin k it-mIltil. The
14 rapidly fillert4l coned. in raturv, roilter(41, and fliAd.
yielding 67-74(lel~ (1-:10)'1't, h? 1311 IV. 1t.2311 V. All ycra-
(IonsintIO

'~k'/ ~'.) (!- I /I ~ //
11 f () I i
NESHEYANOT, A.H., akaaamilt.; mam, O.T.
~
Roaction of dialkov/-titanium-oxIdes with tetra-alkov
y-silanes.
Dal-ft, AN SSSR 117 no,2';'49-?51 9 '57. (min 1113 )
Oltanium organic compoundis) (SlIane)

RESIMUMOV. A.N,.; XOGIRL. O.V.; MY=,KA, R.Kh.
Preparation of hersalk7loildItitaaoxanes (Rob" - 0 -- TI(ORb-
Izv.*N SM.M.Wm.nauk zto.3:373-375 Kr 156. (KLRA 9:8)
1. Institut elementoorgaalchaskM soyedluenLy Akademil nauk SSM.
(Titanium organic compounds)

5 (4)
AUTHORS- Nesmeyanovy A. Top SOV/62-59-8-32/42
Dubovitskiy, V. A.
TITLEs Effect of the Time Factor on the Degree of Association of
Titanium Alkox7l Derivatives in a Benzene Solution
PERIODICALs Izvestiya Akademii nauk S33R. Otdeleniye kbimicheskikh nauk,
1959, Nr 8, pp 1496-1498 (USSR)
ABSTRAM This brief surve discusses the property dealt with in numerous
papers (Refs '1-3~ of the alkoxyl derivatives of titanium to
associate in aqueous benzene soluticna. It has been shown that
the methods used for the determination of the molecular weight
(kryoscopy and ebullioscopy) yielded a higher molecular weight
than corresponded to the monomer. The authors of the present
paper now succeeded in showing that the degree of association of
C1
Cl
'~Tio'
TiOsROH,
the substances: (R0) Ti, ClTi(OR) (-RO) TiO,
11
1
4 3
2 ROI-
RO
C12TiO-2ROH changes gradually. It diminishes and, after some
hours, equals 1. The decomposition rate of the associates,
Card 1/2 howeverg ia not high, while the activation energy of the

Effect of the Time Factor on the Degree of Association SOV/62-59-8-32/42
of Titanium Alkoxyl Derivatives in a Benzene Solution
dissociation of the associates is considerable. Figures 1 and 2
show the change in molecular weight of some of the relevant
substances in the course of time. The table contains the
molecular weights of the substances under investigation. Some
substances had been synthesized by the authors for the purposes
of this paper and had actually been obtained for the first time,
It was seen from the curves that initial monomers are formed by
dissociation. Thus it is possible to use kryoseopy for the
determination of the molecular weights of the compounds under
investigation. The authors will report an the newly oyathesized
substances in future papers. There are 3 figures,1 table, and
5 references, 1 of which is Soviet.
ASSOCIATION: Institut elemcnto=,;anichesk1?h soyedineniy Akadeaii nauk SSSR
(Institute of Elemental-orge"ic Compounds of the Academy of
Sciences, USSR)
SUBMITTED: February 18, 1959
Card 2/2

6617 q
SOV/2o-128-5-2Q/67
AUTHORSs Nesmeyanov, A. N., Academician, Nogina, 0. V., Dubovitakiy, V. A.
TITLZ: Activation Energy of the Disaggreeation Process of Associated
Titanium Alkoxyl Derivatives
PERIODICALs Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 5,
pp 964 - 965 (USSR)
ABSTItACT: The association degree of these derivatives decreases compara-
tively slowly in diluted benzene solutions. Within several
hours'all associates disappear (Ref 1). The association of
these derivatives is explained by intermolecular coordination
bonds between the oxygen atoms of ond molecule and the titanium
atoms of the adjacent molecules.(Refs 2-5). The dependence
of this phenomenon on temperature was investigated and the
activation energy of disaggregation determined in this paper.
The method of cryoscopy was used for this purpose. Figure I
shows the kinetic curves of the disaggregation process of the
associates of tetra-n-propoxy titanium at various temperatures.
The values of activation energy were computed from the dependeL-
cies of the initial velocities on temperature Uig 2). Th~-i
Card 1/3 are 7-7 kcal/mol for tetra-n-propoxy titanium, 8.0 kcal/mo I
tl~

66174
Activation Energy of the Disagaregation Process of S07/2o_12A--5-2i/67
Associated Titanium Alkoxyl Derivatives
for associated tetraethoxy titanium, and 6.1 kcal/mol for
di-n-propoxy titanium oxide. Limit concentration at which the
association degree of titanium alkoxyl derivatives decreases
to 1 depends little on the structure of the titanium compound
(Fig 3). The structure of the alkyl, however, hau a distinct
effect on this phenomenon. Spatial obstacles influence the
association degree of the titanium derivatives mentioned.
Association does nqt take place Ett all if there is a rami-
fied carbon chain of tetraalkoxy titanium at the carbon ntom
adjacent to titanium (tetraisopropoxy titanium, tetratertiary
butoxy titanium,. references 2,6) in the case of concentrations
of benzene solutions up to 2.0 mol%, If the ramification of
the alkyl chain in tetraalkoxy titanium occurs on the
carbon atom, the tetraalkoxy titaniums are associatt
in
benzene solutions. Also.in this case the association degree
decreases gradually and reaches I after several hours. There
C3rd 2/3 are 3 figures, and 6 references, 1 of which is Soviet. LV

66174
Activation Energy of the Disaggregation Process of '507/2o-12,,-5-20/67
Associated Titanium Alkoxyl Derivatives
ASSOCIATIONt Institut elementoorganicheskikh soyedineniy A~ndemii nauk
SSGR (Institute of Eloinontnl-or~,-anic Compounds of the Acadrz:-4
of Sciences, USSR) tj~
SJMUTTED: July 9, 1959
Card 3/3

/vo
82101
S/06 60/000/07/04/007
B0159054
AUTUORS: Nesmeyanov. A. N.-, Nogina, 0. V., Berlin, A. M.9
Kudryavtsev, Yu. P. .
TITLE: Chemical Transformations of Dialkory Titanium Oxides
PERIODICAL: Izvestiya Akademii nauk S35R. Otdeleniye khimicheakikh nauk,
19609 No. 7, PP. 1206-1214
TEXT: The authors describe the chemical properties of dialkoz7 titanium
oxides. They continued the investigation of deposition to theM w 0 boad,
studied the stherifloation reactions, and found the substitution of alkoxy7A
by halogens as well as a substitution reaction of the oxygen bound to ti-
tanium with two chlorine atoms. They obtained the first compounds of a
hitherto unknown series of titanium-containing organic compounds, i.e.,
athory-9 a-propoxy-, and n-butory titanium oxide chlorides. By the action
of chlorine on di-n-propory- and dilsobutoxy titanium oxides, they produced
the compounds Cl 2TiO*2n-C3N7OH and Cl2TIO-2i-C 4H9OH. On the reaction of
dialkyl dichloro silanea with dialkoxy titanium oxideav the following ex-
change of oxygen with two chlorine atoms takes place: A
Card 1/2

8
Chemical Transformations of Dialkoxy Titanium Slo6 6010/000/07/04/007
Oxides BO I 5PBO54
(n-C 3H70)2 TiO + C'251R2 ---& (n-C 3"70)2 T'Cl2 + 105iR 2] X' A similar reaction
takes place by the action of tetra-n-propoxy silane on the compound
Cl 2TiO*2n-C 3H7OH, namely Cl 2 TiO*2n-C 3H7OH + (C 3070)4 St --*.Cl2 Ti(OC3H7),On-
C 39709 + n-C 3 H7OH + losi(OC 35 -n) 21X . By the linkage of dimethyl di-n-
propoxy silane with di-n-propoxy titanium oxide, the following compounds
were obtained: CH CH
/ 3 1 3
(C 37')3 Ti-O-Si-CH 3 and (C 3 H70)3Ti-O-Si-O-Ti(OC 3H7)3
\1 4 1
OC 35 CH3
There are 8 references: 7 Soviet and I British.
ASSOCIATION: Institut elementoorganichaskikh soyeaineniy Akademii nauk
SSSH (Institute of Elemental-organla Compounds of the
Academy of Sciences, USS
SUBMITTED: January 23, 1959
Card 2/2

83900
S1020~601134100310131020
B016/ ~054
AUTHORSi Nesmeyanov, A. IT., Academician, Hogina, 0. V., and Berlin,
A. M.
TTTLEt Interaction of Cyclopentadienyl Sodium With Alkoxy Titanium
Chloridesi -
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 3,
Pp. 607-606
TEM The authors investigated the reactions of cyclopentadienyl sodium
with alkoxy titanium chlorides, and isolated mono-ir-cyclopentadienyl
derivatives of titanium: cyclopentadienyl-trietboxy- and tri-n-propoxy
titanium (see Diagram). They are colorless liquids distillable in vacuo
and very sensitive to air moisture. The authors indicate the established
and calculated yields and molecular weights of the two derivatives. As
opposed to the ordinary alkoxy derivatives of titanium, the Tr-cyclo- Lx
pentadienyl-trialkoxy derivatives are not associated in solutions, not
even at a concentration of 1.7 mole,'I. The molecular weight of
C5H5Ti (OC2H5)3' cryoscopically determined in benzene solution, correspoi-As
Card 1/3

83900
Interaction of Cyclopentadienyl Sodium With S/020/60/134/003/013/020
Alkoxy Titanium Chlorides B016/BO54
to that of the monomeric compound. The authors proved the structure of
lr-eyelopentadienyl-triethozy- and tri-n-propoxy titanium by conversion
into the known. (Refs. 7,S) cyclopentadianyl-titanium trichloride (see
Diagram). Further, the authors allowed ethory-titanium trichloride to
react with oyclopentadienyl sodium, and determined and calculated the
physical constants of (C 5H5)2 Ti(002H5)01. The -W -cyclopentadienyl- 0
trialkoxy derivatives of titanium are decomposed by alcohols at 70-80 C
within 1 ho while corresponding tetraelkory titanium and cyclopentadiene
are formed. The latter was isolated as cyclopentadianyl thallium. By
reactions of Ir-eyalopentadianyl-tri-n-propory titanium with acetyl
chloridel the authors obtained mixed chloride alooholates of "T -cyclo-
pentadianyl titaniums 1) cyclopentadionyl-di-n-propoxy-titanium chloride
which is disproportionated by vacuum distIllationj 2 cyclopentadionyl-n-
propozy-titanium dichloride. Both compounds are greenish-yellow, viscous
liquids decomposing under the action of air moisture, but still storhble
at lower temperatures. There are 8 references: 2 Soviet and 2 US.
Card 2/3

2JI 00
AUTHORSt
TITLE;
PERIODICALs
M46713
ezO1WS12f
S10201601134100610181031
B016/B067
Nesmeyanov, A. ., Academician, Nogina, 0. V., and
Dubovitskiy, V. A.
Slow Dissociation of the Associates of the A2koxyl and
Alkyl Derivatives of Metals in Solutions
Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 6,
pp. 1363-1366
TEXTs In earlier papers (Refs. 1,2) the authors described the slow dis-
integration of associates of the alkoxyl titaniumqderivatives in dilute
benzolic solutions. In the present investigation they observed that the
phenomenon occurs also in the solutions of organic compounds of other
metals. It was found that the degree of association in the alkoxyl
derivatives of tinj irconium.,q and aluminum cryoscopically deterain-9d
decreases with time and that within some dra it becomes equal to one.
Fig. 1 shows the curves of the variation with time in the molecular
weights of (n-C H,O) Sn in benzolic solution with a conegntration of
3 1 4
Card 1/3

e44-73
Slow Dissociation of the Associates Of the S/020/60/134/006/018/031
Alkoxyl and Alkyl Derivatives of Metals B016/B067
in Solutions
0.100 mold (curve 1) an; an analogous curve (2) f~,r (n-,C 4H90)4 Zr
centration 0.161 aol%). The production method of tetra-n-,propoxy-tin and
of tetra-a-butoxy-zirconium (Refs. 4,5) and of other products used is
described. Fig. 2 gives the analogous curves (1.2,5) for
(iso-C4 E[9)2 Aloe 2N in benzolic solution (concentration 0.099 mol%) and
for (n-C3H 70)3Al as well as for (iso-C 4990)3Al. The authors state that
at constant concentration and temperature the dimer of triethyl aluminum
in dilute benzolic solution slowly dissociates to the zonomer stage.
Fig- 3 shows a curve similar to those already obtained for (C 2H5)3 Al,
and Fig. 4 shows a curve for (n-C 4H9 0)4Ti (1) in nitrobenzolic solution
as well as (2) for (n-C 3H70)4Ti in dioxane solution. Curve (3) il-
lustrates the variation in the molecular weight of tetra-n-propoty-
titanium dissolved in cyclohexane. There are 4 figures and 23 referenceal
7 Soviet, 7 US9 2 French, 3 Germ%nq ani 4 British.
Card 2/3

84673
Slow Dissociation of the Associates of the S10201601134100610161031
Alkoxyl and Alkyl Derivatives of Hetals B016./Bo67
in Solutions
ASSOCIATIONo Institut elementoorganichookikh soyedineniy Akademii
nauk SSSR (Institute of Elemental-organic Compounds of
the Academy of Sciences, USSR)
SUBMITTEDs July 12, 1960
Card 3/3

AUTHORSs
TITLEs
PERIODICAL:
20938
B117/B208
Nesmeyanov, A. N., Nogina, V.., and Dubovitskiy, V. A.
Synthesis of dialkozy (aryloxy) titanium oxides by eater
Interchange-of di-n-propoxy-titanium oxide
Izvestiya, Akademii nauk SSSR. Otdoleniye khimicheakikh
nauk, no. 3, 1961, 437-441
TEM The authors outlined the possibility of obtaining dialkoxy (aryloxy)
titanium oxides and bia(triothyl-siloxy)titanium oxide by ester intercharge
of the easily accessible di-n-propoxy titanium oxiie. (C2H 50)2 TiO and
(i-C5 Hil 0)2 TiO, (n-C6H 13 0)2TIC, (C6H50) 2TiO, PC2H5),SiOjjTiO, hitherto not
yet Oescribed, were prepared in this way. Diphenoxy titanium oxide was
also prepared in the form of its molecular compound with phenol. All
experiments were carried out with completely dry raw materials under
exclusion of atmospheric moisture. The ultrared spectra of these compounds
were obtained on a double-beam UR-spectrophotometer. The spectra were
taken of solutions of the substances in carbon disulfide and carbon tetra-
Card 1/3

20938
3/06 61/000/003/004/013
Synthesis of dialkoxy (aryloxy) ... B117YB208
chloride, as well as of a paste in vaselin oil. But no characteristic
frequencies were found in the range of 600-1400 cm-1that could be
assigned to the Ti-wO bond. Also titanium oxide bis-acetylacetonate was
prepared by reaction of di-n-propoxy titanium oxide with acetylacetone,
This compound was prepared by hydrolysis by A. Jamamoto, S. Kambara (see
below) who have assigned it a cyclic dimeric structure. Cryoscopic
determination of the molecular weight of titanium oxide bis-acetylacetonate
showed, contrary to this statement, that this compound has obviously the
structure R3C\C-0 O-C CH3
HC/ \TJ ole CH
~~ C- 0 / 11 ~'* '0-C/
H3Cz 0 %% CH 3,
and is a monomer in dilute solutions. The attempt of carrying out the
addition to the Ti. 0 double bond in titanium oxide bis-acetylacetonate
gave no addition product but dialkoxy titanium bis-acetylacetonate. Thus,
the reaction proceeded according to the formula
(C5H702)2 TO + Si(OR) 4 (C5H702)2 Ti (0R)2 + t)S'(QR)2'
Card 213

-~j
S/062/61/000/003/004/013
Synthesis of dialkoxy (aryloxy)... B117/B208
where R . C2H 5; n_C3H7 . The authors thank L. A. Kazitayna and G. A. Rudenko
of the Moskovakiy gosudaratvennyy universitet (Moscow state University)
for determining the IR spectra of di-n-propoxy titanium oxide samples.
H. A. Chumayevskiy is thanked for taking the IR spectra of the remaining
compounds, which was done at the laboratorya akad. I. V. Obreimova
(Laboratory of Academician I. V. Obreinov)of the authors' association.
There are 5 figures and 8 references, 5 Soviet-bloc and 3 non-Soviet-
bloc. The reference to the English-language publication reads as followst
A.. Jamamoto, S. Kambara, J. Amer. Chem. Soc. 79, 4344P 1957.
ASSOCIATION: Institut elementoorganiohookikh soyedineniy Akademii nauk
SSSR (Institute of Elemental-organic Compounds, Academy of
Sciences USSR)
SUBMITTEDt January 81 1960
Card 3/3

t)O
23569
S/062/61/000/005/004/009
BI18/B208
AUTHORSt Nesm^yano7, A,N. Nogins, 0. V., and Berlin, A. M.
TITLEt Mono-IT-cyclopentadienyl derivatives of titanium
PERIODICALi kkademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no., ~, 1961, 804 - 807
TEXTs The authors studied the reaction of sodium cyclopentadienyl with
diet, hoxy-t itanium dichlorid^
Oc2HC;
2M Ti(OC H 3CH,Na--,iC HT-.,(OC H;) (C,,H ) T." + 3Nacl.
2 2 5 2 3 5 2
cl
The soparated liquid cyclopentadienyl.-*.riethoxy.-titanium which was analyt-
ically confirmed is not associated in solution, rontrary to the common
alkoxy--,itanium derivatives, Its molecular weight, cryoscopically deter-
mined in benzene, corresponds to that of the monomer compound, even in a
concentration of 11.7 molt ~4. I-,s structurm was confirmed by conversion
with acetyl chloride to cyclopentadienyl titanium trichloride C 5H5TiCl 3'
Card 1/4

23589
5/062/61/000/005/004/009
Mono-n-cy-,lopentadienyl-, B118/B208
Its melting point J's by 200 C higher than that found by R~ D. Gorsich (see
below). The se,-ond yellow, crystalline produ.ct of the above reaction
(!orresponds to dicyc1rpentadienyl titanium ethoxy-chloride. To obtain
only cyclopentadienyl trialkoxy-titanium in the reaction of sodium cyclo-
pentadienyl with alkoxy titanium i-hlorides, tri-n-propoxy-titanium chloride
was used as titanium derivative which gave, as was expected, cyclopenta-
dienyl-tr1propr:xyztitaniu.m CC;H,Ti(OC H,), n a yield of 96 %. With acetyl
chloride the latter gives Cyciopentad-~enyl titanium trichlorldpi
~ 1 1-- , I
C H,.TI(O(,' H CH COCI H,TiCl
~ I j - . C + 'CH Cdoc H
5 11 5 7 3 3 3 3
The reaction of 0011iUM cycl.:;p-ntadienyl with ethoxy-titanium trichloride
took place according to the formula
Cl TiOC H -+ 2C,:H H )Ti---~ NaCl.
3 2 5 5 5 0C2H5
The attempt of an eater internhange of' cyclopentadienyl triethoxy-titanium
with propyl alcohol was uns-i,~cessful, as this alcohol converts this
Card 214

23589
S 6.2
Mono-i'~-cyclopentadi,~,r.y'-..., B-02108
n-cyclopen'ladienyl compound to tptraprop,)xy- t4 tanium (C H 0) Ti under
5 7 4
mild conaitions, Ethyl alcohol reacts similarly forming tetraethoxy-
t1tanium (95 % yield) and ry-71op-~ntadleno (97 % yiald, in the form of
thallium cyclopentadieny!). To obtain mixed chloride alcoholates of it-
Ti(OR'Cl and C H Ti(OR Yt-cyclopenta-
cyclopentadienyl titanium, CSH 5 2 5 9 )2C"
dienyl propcxy-titanium wan allowed to react with acAtyl chloride ( 112
and 10), where 0 H TI(OC,H )PI
5 1; 7 '12 and C',HrITi(OC 3H,),Cl, respectively,
resulted. The rea(,tion prodiv~ts art green-yollow viq,~oiis liquids, not
stable to atmcspherin mo3stnre. but stable when stored a, I - 50C, There
are 11 referencesi 3 So-iet blo-~i and e non-Sovipt-bloc. Thp 4 references
to Engligh,language publications read as follows, C.L. Sloan, W. A.. Barber,
J. Amer. C~ em, Scr 81 7
'164 (19159',; M, A~ Lynch 1~ C. Brantley, Chem.
Abstr. c2~ 11126 (19~`81; A. K Fis-her. G' . Wilkinson, J, Inorgan. Nuclear
Chr-m. 149 (1:956); F. D. Goroich, J. Am-~r, Chem. Soc,. 80. 4744 (1958)-
ASSOCIATIO11i Tnatitut elementoorganicheskikh aoyedinen-,y Akademli nauk SSSR
(Institute of Els-mental-Organic Compounds of the Academy of
Sciences USSR)
Card 1./4

Mono-n-cyclopentadienyl....
SLJBMTTTEDi April 8. '960
23589
S,,'062161/0-00100510041009
B11-8/B208
x
Card 4/4

NESKEYANOVO A.R.; NOGINA, O.V.; BERLIN, A.M.; GIRSHOVICH, A.S.; SHATALOV, G.V-1
Acyl and alkoxyl derivatives of bis-(cyclopentadlevyl)titaniua "
the refraction increment of the ;C 5Ti group. Izv. AN SSSR
Otd.khim.nauk no.12:2146-2151 0 6? (MIRA 14:11)
1. Institut elementoorganicheskikh soyedinenly Akademii nauk SSSR.
(Titanium compounds)

S/062j62/000/007/012/013
B1170180
AUTHORS: Nesmeyanovp A* N., Regina, 0.- and Surikova, T. F.
TITLEs Alkylation of bio(oyclopentadionyl)titanium diohloride
(C5H02 T'Cl2
PERIODICALs Akadeaiiya nauk SSSR. Izvestlya. Otdeleniye khimicheskikh
nauk, no. 7, 1962, 1314
TEXT: The authors are the first to have achieved aromatic substitution
in cyclopentadienyl titanium derivatives by means of (C 5a5)2 T'Cl2-
Alkylation of bia(cyclopentadienyl)titaniuz dichloride took place under
the action of ethylene on a (C 5H5)2T'012 solution in*chloroform at a
pressure of 30 atm without the catalyst AM 3* Double subliaation in
vacuo yielded C 10H4(C2 H5)6 TiCl 2- Diothyl-bia(cyclopent.dienyl)titanium
dichloride 0 10 HO(C 2H 5)2 TiCl. was/obtained under the eame conditions in the
presen;e of AM Y Monoothyl-b/io(cyclopentadionvl)-titanium dichloride
Card 1/2

S/062/62/000/007/012/015
Alkylaticn of bia ... B117/B180
C H (C H )Ti 1; was obtained without AM by the action of triethyl
10 9 2 5 C 2,- 3
amine on (C5 H5)2 TiCl 2- The infrared spectra of the resulting compounds
showed bands characteristic of methyl and nethylene groups. [Abstracter's
notes Essentially complete translation.]
ASSOCIATIONs Institut elementoorganicheskikh soyedineniy Akademii nauk
SSSR (Institute of Elemental Organic Compounds of the Academy
of Sciences USSR)
SUBMITTEDs May 17, 1962
Card 2/2

S/W/'21/000/008/013/016
BIOI/B180
AUTHORS: Nesmeyanovo A. 11o, Nogina, 0. V.,.and Dubovitskiyp V. A.
TITLE: Data on the titanium - cyolopentadienyl ring bond in
C5H5Ti(OC 2H5 )3and (C 5H 5)2%,,7CCOCH 3)2
PERIODICAL; Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 6, 1962, 1461-1463
TM(T: Using the method of A. K. Fischer, G. Wilkinson (J. Inors. and
Nucl. Chem. 2. 149, (1956)) the ionic nature of the Ti bond in sandwich
compounds was checked by reaction with FeC12) or Fe (II) acetyl acetonate,
in argon atmosphere, and tetrahydrofuran solvent at*650C. Results:
no ferrocene is formed from (C 5H5)2TiCl2P (C5H5)2T'(c6H 5)2v C 5H5TiCl 3;
C5H 5Ti(oy 5 )C1 120 C5H5 Ti(OY 5)2C' or
C5H5TI
Card 1/2 LX;2H5

S/06 62/000/006/013/016
Data on the titanium B101 YB180
(synthesized for the first time, report printing). (2 ferrocene io
formed from C 5 H5Ti(OC2H 5)3 and (C5H 5)2Ti(OCOCH 3)2' (3~ the ionic nature
of the bond in C 5H5 Ti(OC2H 03 and (C5H 02Ti(OCOCH 3)2 was further
demonstrated by the ease with which these compounds hydrolyze in the pre-
sence of water at 60-600C. (4) The compound C 5 115Ti(OC2H 5)2Cl was
synthesized for the first time by reaction between CH 3COCI and
C H Ti(OC H I bop* 113-1140C/0-5 mm Hgo n 20 1-5812, d20 1.2253. There
5 5 2 5)3 D 4
are 2 tables.
ASSOCIATION: Institut elemenioorganicheakikh soyedineniy Akademii nauk
SSSR (Institute of Elemental organic Compounds of the
Agadomy at RGLORGOR UPOR)
SUBMITTED: February 17, IIQ62
Card 2/2

NESMVAROVY A. V.; NOGINA. 0. V-J DUBOVITSKIY, V. A.
Alkylation of b4s4cyclopentadianyl) titanium dichloride by
means of acetyl chloride. Izv. AN SSSR Otd. kbim. nauk no.12:
2254-2255 0 162. (HIRA 16:1)
1. Institut alementoorganichaskikh soyedinsniy, AN SSSR.
(Titanium compounds) (Acetyl chloride)

-:77-71-71-1 -T-7-E i
iACCIOSIC" NRI AP30OM24
TAWHOR: Neameyvj~"p An No; 0 ~-V
TI nZ Cyaloyentaaerql ethw7 titanium big-W=nuinolinate)
SOURM AN SSM* Izvestlya, Otdolwdye khimichaskikh nauk no. 32 19630 831-05
-i-TOPIC TAGS: -cyclopentadierql ethoxy titanium bia-(&-*xyTAw11mxte), d1propy1w-
titanium bie~48-oxyquinolinateOp bia-(S-oxyquinolinate) titaniun'cocidej octaetho~q-.
trititanium =Bra
IMSTRACT: CVlopentadierql ethwq titanium bin-(S-,
CfICO;Pr (VII), Inactive at U11CAM; I (Cool
OWWO. 2.4-AcO(OX)CHXITsBr (4 0 and 2 11,
KOAe in 20 mi. AcOU rtfluxed 2Z hrx., Us; mi2t. dild.,v!th
140, and rrcrystd. Kave 2.5 r. I,4-Ar(O,M)C.HC9tOAc
Vill), in. 75-0* (frorn lUOU). - Hydrolyfis of 3.2 r. Vill
its 40 nil. 301,,; &!c. 11C, by Wling 4 hrs., On RtOll dktil..
the "Sidue extd. with "I.. And the CJls removed ItI4 2 g,
2+100tNX41riC11,011 (IX',, yellow oil: P-nilrolcmst;am,
tn. 2W-5. (from EtOH). CattilytIc reductirn of 1.8 x.
IX in 60 mi. StOH with Pd-C (the rubstinct absorbed 925
nil. 11 in .10 inin.), the mixt. filtered, titt flitriste coned. in
TT
acid
14D-M') vrith MilliffrO irzv~ 111, M. 220~56
~dccompn,) (from EMT). Sirulwly vrert prepd. V. enjor.
Icts n"Ales, m, above 350" (from Jiro); VM. m. 177-8*
(fror" UtOU); Vill, calorle-m m. IDG-7'. Er 5-
riftro,-24utancurbattylate (XXT) (2.5 X.) in DW mi. abi.
MR tt"ttd at 0* with CM ITjjNsll4JIjO. left 2 days at
0" the SON. trrAted with C, t e tOll Omd. in tuate, and
the rWdue rcaystA. from FtOll xuve hninire VI which Was
purified by sublinshin out tincli-togrd XXI;tttd recr~-.tg. ttie
rcsiflut twice from EtOlf, yielding 9.0 g' VI, tn. 102-4",

'L~JhN. treateo wltjl o-10 j," jjxj,,
2.4-11012.4-11~ Rt
0,N)CH,(!Olj~jW
2 1 .26
Hydrotedatfou of 6 g. x in 2W MI. RtOAc ovw 10%
Pd-C gave the IT'N comod. W), COWICSS aredles, m. 200--
I (from AcO .H). Hydr4yils of X1 witb aq. Mon pve
(0 v
~-Cr11de`1v-iThkl1-'-wd.' fri;t~'WIAN WRIT as. moal icf6r.*
le-,4, dewmv). 212-3'. 1 (3 g.) and 2,0 g, plithalic an-
hydr;dc (XII) in 100 mi. HtOAc let stand 24 bm. at r0ofn
(crap., the material filtered, and wzLifted with EtOAP i
Afforded JVot acid, decompd. ISP,00* vvith Ps evolution,
becoming solid, and then m. 215-20*. 1 Ht e3ter (3.6 It.)
and 3 11. XII in W mi. EtOAc let ittnd overnight, the
__cryxt. product filtered, and washed with MOAc pvt 4.7
r. Wa,-m. 17Q-83*-(deqompn.). . IV& If J') licatel I hr.
-at 2W* and remstd. yielded V. m. 102-3 (f"a AcOll).
Dentalation of 14a - I In sq. NatCO3 Inve 20 It, V1, In.
-=--l (fmrn R(OAcl ~ p-II0~CCH-.CTIC.IT,NTi,.IICI (6
v.) and W mt PtOH treated 4 hm- with dry HCJ while waa-
Ing an the water bath, the soln, cooled, the c*-3t. material
filteted. arid *Whed with a MCC prolf ga 3 g. VU. TIC),
10FILtm TIM
m. 2101 (decompn.).