SCIENTIFIC ABSTRACT NESMEYANOV, A.N. - NESMEYANOV, A.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136620020-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

NOV h, doktor te~hn. auk; IEELINIKOVA,
jA: And 9y N~~qy~y!c,
X
A--~u V...-F-19RE
.1
Zh.1'., red.
[Isotopes in the ser-vica of* minn) izotol;y sluzizt liu-
diam. Moskva, lzd-vo 111"Inarlie," 1965- 30 P. (Novoe v
zhizni, nauke, tekhnike. IV Seriia: Tek~mlka, no.5)
18:2)

MAKAROVA, Lyubov' Gennadiyevna; 4~~q~~410V Aleksandr Nikolayevich;
KOCHESHKOV, K.A., otv. red.; RODidR6VJ,'i.-N-'.. red.
(Methods of organometallic chemistry; mercury] Metody
elementoorganicheskoi khimii; rtut'. Moskva, Nauka, 1965.
438 P. (MIRA 18:7)
1. Chlen-korrespondent AN SSSR (for Kocheshkov).

MAY-AROVA, Lyubovi Gennadiyevna; NEa:EYr%QV A.N.
[Mercury) Rtut', Moskva, Nauka, 1965. 438 p.
(MIRA 19:1)

OKRLOErSTIR 9 Oleg Yur 'yevich; NEMEYANOV 0 A.N. . akademik, otv.
red.
fuThird" chemistrv.- metallo-orgamic ca2fWVrjCwl "Trettia"
khimlia; alementnoorganichaskie soedinaniia. Moskva,
Nawtal 1965. 198 P. (MIRA 18:3)

R E-1 0 D E- UR/006
ACC NR: .4 P6012083 5OU
fjUIHOR: Nemne Kozlov5kiy, A.. G.; Gubin. F. ~-j Pqrevalovaj E'. G~
t ORG: Moscow State University im. K. V. Lomonosov (Moskovskiy gosudarstvennyy
universiVeC ~oSdsj AN SSSR (Institut eleimntoorgan-i
I.ilcheskikh soyedineniy)
TITILF.*. Protolysi.sof mercury derivatives of ferrocenett.
1965? 580
SOURCE: AN SSSRO Izvestiya. Seri~ra khimicheakayat no. 3t
TOPIC TAGS., titrimetry, ferrocene, mercury compound, dioxane, chlorine compound
ABSTRACT.- The Rate constants were determined for the protolysis of mercur7
,derivatives of ferrocens - chloromercuroferrocene and diferrocene-mercury
using hydrochloric acid in 90% (by volume) aqueous dioxane. The quantity
of acid not entering into reaction was detamined by,potentiometric titration,
7he reaction rate in all cases is described by a second-order kinetic
.equatiom. The protolpis rate of diferrocene mercury is six times greater
than the cleavage rate of di-p-anisylsercury under tho moo conditionso
Orig.,art. has: .1 table. CJPMI
SUB CODE 07 SUBM DATEt lUan65 ORIGHEF: 002
I Card UDG: 531- 1+542-957

NESMEYANOV EMMA, L.P.; MATERIKOVA, R.B.; GETNARSKI, B.U.
Stability of some ferricintax gralts, Izv, AN-SM. Ser, khta. rzo.4s
731-733 t65. (MM 180)
10 Institut elementoorganicheskikh soyedineniy AN SSSR.

KURSANOV, D.N.; SRTKINA, V.N.; KISLYAKOVA, N.V.; KOLOBOVA,
Mee; AllISIMOV, K.N.
Isotopic exchange of hydrogen atoms in cyclopentadienyl rhenium tricarbonyl.
Izv. AN SSSR. Ser. khim. no.4t762 165. (KM ISO)
1. Institut elementoorganicheskikh soyedirieniy AN SSSR.

NESMEYANOV. A.M.* PEREVALOVA, E.G.; YURIYEVAO L.P.; GUBIN, S.P.
Rodax potentials and absorption spectra in ult'raviolet and visible
regions in some.homoannular disubstituted ferrocene derivatives.
Izv, AN SSSR. Ser. khim. no.5009-911 165. (MIRA 18s5)
1. Institut elementoorgenicheskikh soyedineniy AN SSSR.

NESWYANOV A.H.; CHAPOVSKIY, Yu.A.; MAKAROVA, L.G.
Arylation o IMS:
f 7r -C F' 'pe(CO)2114 bf onlim salts. Izv. AN SSSR. Ser. khim.
no.711310-1311 165: (19-11FA 18:7)
1. Institut alemantdorganicheskikh soyedindniy AN SSSR.

L 16984-66 EWT(m)/EWP(J)/T- -WW/JW/JVM/RM
-ACC-NR: AP6002101 SOURCE CODEt UR/0062/65/000/011/2061/2063
AUTHORSt Heameyanov, As N*1 Saz nova, Vo A.j Drozd, 7.,Nj Rodionovap No A#j
Zudkova, 04.-V~'
ORGt Moscow State U
_Qqs2~ (Moskovakiy gosudarstvennyy
univers e
TITLE: Properties of 0( -forrocenylearbonic ions
SOURCE: AN SSSR Izvestiya. Seriya khimicheskaya,'no. ll,-1965, 2061-2063
TOFIC TAGSt -ferrocene,, organic synthetic process, nuclear magnetic resonance
''ABSTRACT: Reaction of tetravhenrlbor Iate ikbf phe4l-(I) and_cunhfiayu-.617-90~~-
carbonates (II) with dimethylanilinel(M) was investigatedf,
and II and some of the-n7-9r-3-p-eF-ffe-5Vere described by the authors in a previous
work (Dokle AN SM, 160., No. 2. 1965). The reaction described here takes place
at 5-20C within a few minutes and proceeds according to the equation
Card 1/2 -,UDCt 91#5h7.11 3+546.72

L 3537 66 E,,P, (m) /ZjP(-j
"~` -IV60-7
A
CC Me 2680 SOURCE CODE: UR/0062/65/000/012/2218/2220
i ~~
AUTHOR: Kursanov. D. N.; Setkina, V. N.; Nefedoy . M. N.; 11!~sme-yanov, A., N. ~r .
ORG: Institute of Orzanometallic Compo ds,. AN SSSR (Insti-tut elemntoorganicheskikh!
soyedineniy AN SSSR)
TITIE: Isotopic exchanarellf hydrogen in aljiylfer oognesl
SOURCE: AN SS---- Seriya khimicheskaya, no. 12, 1965, 2218-2220
TOPIC TAGS: isotopep hydrogen, ferrocene, electron donor, acetic acid, benzenet
chemical kinetics
ABSTRACT: The reaction of the isotopic' exchange of hydrogen in acid modia
was used a's a modal for investigating the laws of elotrophilic substitution
.in aromatic systems. Forrocono readily ontors into this reaction and tho
acetyl groups introduced into the forrocene molecules markedlzy reduce the
exchange rate of the hydrogen atoms on tho nucleus. By investigating the
.affect of electron-donor substitutes In forrocano'on its reactivity, the
authors determined the-rate constants of the isotopic exchange of hydrogon of
methyl-, otbql,. and 1,11Wdiethy1forroconos in a mixture of doutoroacotio and
trifluoroacatic acids. It was shown that the introduction of alkyl groups
enhances the reactivity of the farrocene nucleus to a much smaller degree
than that of the benzene nucleus. In alky1ferroconos all the hydrogen atoms
,of the forrocone nualous participate in the exchange, and the kinotios of
'isotopic exchange is not affected by the differences in the reactivity of
the various positions. Orig. art. has: 4 tables. 1JPRS: 36,4551
SUB CODE: 07 SUBM DATE: 2lApr65 / ORIG REF: 003 / OrH REF: 001
UDC:

18-66 DIT(M F&)(j) 1W
NR4 AP6o26891 SOURCE CODE: UR/0062/65/0001/01-2/2120/2124
AUTHOR: Nesmeyanoy A. N.; Perevalova, E. G.; Nikitina, T. V.; Kuzmtsova, N. 1.
im. Lomo
ORG: Moscow State University_ nosov (14oskov3kiy gosudarstvennyy 11-nivi-rz-,*
TITIE: Behavior of m- and p- ferrocenylhydrazobenzenes lunder condition5 of benzidine
rearrangement
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 12, 1965, 2120-2124
TOPIC TAGS: benzidine, benzene, substituent, ferrocene, molecular structure,
chemical reaction
ABSTRACT: This is a continuation of a previous investigation. The effeat
of ferraconyl as a substituent on the benzidino rearrangement of hydrazo.
bonzono was studied. It was established that forroconyl as a substituent
on the benzene ring complioatos benzidino rearrangemont: m- and p-
forrooonyllWdrazobonzenos under the conditions of benzidina rearrangement
genera13,y got disproportionatdd rather than rearranged, i,e. the end-pro&ot
is ferrooony2azine and azoforrooene.' Compounds of the banzidine type do not
form. Those findings indicate that +,he introduction of the forroconyl
substituont - whether in the Wa or in the mota position - into the
h,ydrazabonzene molmde impedes benzidine, roarrwgomont to such an extent
that disproportionation becomes the maln trend of the reaction. 'CJPRS: ~6t4551
SUB CODE: 07 / SUBM DATE: 29Jul63 / CRIG REF: 003 / OTH REF : 005

L 353-24-66 Ew(m)/Ew(j) Rm
ACC NRt Ap6026892 SOURCE CODE:
AUTHOR: Ne A. N.-. Perevalova, E. G.: Nikitina, T. V.;.Kuznetsova, N. I. A
ORG: Moscow-State Universi&Z-im. M. V. Lomonosov (Moskovskiy gosudarstvennyy
universitet)
TITIE: Effect of hydrochloric acid on the azo derivatives of ferrocenel
SOURCE: AN SSSR. Izvestiyao Seriya khimicheakaya, no. 12, 1965, 2124-2128
'TOPIC TAGS: hydrochloric acid, ferrocene, organic azo compound, chemical synthesis,
nitrobenzene, chemical decomposition, condensation reaction, chemical reduction, amin
ABSTRACT: A study was made of the effect of cono. HC1 on benzeneazoforrocanol
and m- and p-forracwWlarobenzones - azo, derivativas of retrocene qnthesizod
V condwisation of-,nitrobehzeno with ferrocenylAmine and m- and p-ferrocenylp-
.anilines. It Is shown that conc. W1 causes bonzenoazoferrocone to decompose
and form Fe-free substances; products of benzidine-type rearrangement have
!not been detected, Done, HC1 transforms a- and p-ferrocanylazobenzenes into
ferrocenylaniUne, anl1ine and substances Isomeric to forroceny2bydrazabonzwoo
Xn this case the ferroomqlawbenzenes are protonatod and decompose# to form
FGC12- wUch them re&ces the aeocod moleaulo of the protonated
fffr6*wW1wwbmswe to a bp1razo compound. The hydftzo compound is, either
fwUer 'redwed to adnos or gets dlqmportianated and re=angedo
(JFRS: 36,4551
SUB CODE: SM DATE: 29Jul63 ORIG RW: 006 / OTH W: 003

L 35316-66_ zwr~-MILFIZVALW-RM
AXC NR: AM26698 SOURCE CODE: UR/0062/65/000/012/2196/2198 1
AUTHOR: Reshetova, M. D.; Yarysheva, L. M.; Perevalova, E. G.; Nesmeyanoy, A. N.
ORG: MQ2coW State University im. Lomonosov (Moskovskiy gosudarstvenn3rf universitet)
TITIE: Synt hesis of certain substituted ferrocenylcarbinolsi
SOURCE: AN SSSR. Izve3tiya.. Seriya khimicheskaya, no. 12, 1965, 2196-2198
TOPIC TAGS: chemical synthesis, ferrocene, hydrolysis, methylation
ABSTRACT: . T1 ds is a continuation of a previous investigation (PEREVALOVAY-1
!which deals with the synthesis of hatoroannular chloro-, bromo- and cyano-
!(alpha-oxyotby1) ferrocenes and (alpha-ox;ypropyl) ferroceno by reducing the
;corresponding acy1ferrocenes with LiAlk.. The compounds thus obtained were;.
J.11-chloracat,y1forrocene. 1.11-chloro(iilpha-o)wethyl)forrocone, 1,11-
.bromo(alpha-o.Votbyl)forrocone, 1,11-eyano(alpha-oigetb;71)forrocone, and
1,11-carbomethoV(alpha-oxyotbyl)ferroceno. 1,11-cyano(alpha-oxyethyl)
:ferrooene was converted to 1,11-carbomethoxy(a3.phaoxyotbyl)ferracene by
.alka2ine bqdro,27sis and-subsequent methylation with diazomethane.
Ejkt~:' 36,4551
SUB CODE: 07 / SUBM DATE: 05Apr65 / ORIG REF: 002 / OTH REF: 002
1
C"d 1/1 UDC: 542-91+~47-1

--4* 5/00b/Ot9i!/PP)'
C
0
ACC N "RA P sotm DR.- UR/020 /00
114Y i
1VMOR- Nes=ano-y-, ZaTtsev,-X. A.'; AnisiLwy. K. Y. ; Lerner, M. 0.: Kolobova.
N. Ye-. Pbretskaya,
ORG: Institute of Heterorganic CoMpounds AN SSSR (Inptitut elementoorganicheskikh (Z
~soyedineniy M SSBR)
TITLE: Antiknock ef fectiveness itofcertain 4~rgp~omanganese,~co=ounds.
SOURCE: Neftekhimiya, V. 5,, no. 6, 1965, 892-896
TOPIC TAGS: antiknock compound, orgmomanganese compound, fuel additive
ABSTRACT:'--T~e. antiknock effectiveness of manganese carbanyl. (MC) and of cyclopenta-
anese7(CTM) derivatives was compared with that of CTM and
dienyltricarbonylmang
tetraethyllead (TEL)i The effectiveness of the individual organomanganese compounds
in different concentrations was studied in various fuels by the standard motor method
for determining the octane number. It was shown that for.a given metal content in the
fuel: 1) the antiknock effectiveness of MIC in comparis on with that of CTM and TEL
is as, follows: a) In automotive gFolines/&-66 and A-72, lower; b) in a mixture of
isooctane (60%) and heptZe r MO, nioia-Fl-y~-th6 same; c) in the aviation gasoline//,
B-951130,~ lowerL;- 2) The antiknock effectiveness of MC-CTM mixt7t =ein B-951130 gaso-
line is equal to that of -CTV.. 3), The antiknock effectiveness of 2[2-(alkoxy)-5-
he xen-3-ynyllcyclopentadienyltricarbonylmnnganeses depends on the alkoxy group and
r(Card 112 UDC: 5h7.5lh.72'171.1:665-521.23

NESMEYANOV. A.N.; 1-9-KAROVA, L.G.; POLOVYANMK, I.V.
...
Production of organomercury compounds by the decomposition of
double salts of aryl diazonium, chloric4land nercuric chloride
in water. Zhur. ob. khim. 35 no-4:681-683 Ap '65.
(MIRA 18:5)

NESVEYAKOV, A.14., akademik; BELIKOV, V.M., kand. khim. naut
Problem of food synthesis. Priroda 554 no.9:13-23 3 t65.
(Kr-RA 18:9)

NESI,EYA?40V.o MI., akademik; MATERIKOVA, R.B.; KMIETKOVA, N.S.; TS1,111GOKEN, L.A.
Salts of 1,11-d'~al'-,ylcobalt'Lcin'-u.,,i. Lrjkl. Ali 3-'-'3SR 16~, no.1:1.17-138
Ja 165. (~IIIIRA 18:2)
1. Institut elementoorgan.4cheakikh soyedineniy AN SSSR.

KOCHETKOVA,
NE")
AN SSSR
,~Ilrl,,A 18:2)
160 no.4:837-~140 F )6~.
I., S,
a 4 kh 3 d-
1 . iris A I 07e, 'n"rl' y
, t; tut e lercent iieis,

1 ACU I C li:t: 12-~007562 S/0020/6S/1SO/C:~/1r)75/LQ' 87
22

K. I
0 Port va, S. L!; qrandbarg -adn' S.
Yu. A. 11

TTTLU-. Nticl-ir Mimetic renonance spectra of L.M,,,.jderivatIveU

1W SSGR. Dohlady, V. 160, no.' 5, 1965, 1075-1678

70PIC TAGS: nuclear rognatic renonanco, famocane, proton moonance, 1(-m tt A;"W
connt;!11t, cyclic cmpound, cyclopentadLanyl mt4l

1;73STPA~Ti The authora m-nound the chemical shifts of proton signal-" in high-
re,,.olutlon nucloar maFnetic reaonanco spectra of mono- and hetercainular disub-
raltitted forrocmL,3, usinr 10-15% solutions In CC14 dnd cn nliclear mg-
notIc rr!vOn,--,hc3 Dpatra)-Aer. In tha protca macnanco cp-jetra of -11 rcnc)aub*tL-
t c.
tutcd fer-roccnint a oi rglot in produced by the fIv* equivalmit pv* --m of the us-
substiltutod fi-m-mmbetnd ring, aid two triplato ara produced by V,.n M and (a)
protonr of tlia sub3tituted iing with a apin-epin Intera~:tlr..a cu~ist,::A 1 f~7

Card 1/3

L 4618q-~~____
AC=51 Cri 1TRt APS007562
x
It was found that the chemical shifts of protma, of the unsubstituted ring are
chiefly detemined by the Induction effect of the subatituenta. The observed
values of the shifts 6b and do indicate a considerable effect of the conj~ugatlon 0
the substituent on the chemIcal shifts of protons of the substituted ring. Cor-
Gn constanti
z:nlationa am presented between the values of 8 6 and the conjugati,
of the sub3tituents, between the chemical shifto A the Induction constants of the
substituants, and between the chemical shifts of protona of the cubatttuted vin 4'.
and the H,=.ott cenctanto a of thts aubutituents. The renults of the study ue~fft -1i
pozaible to draw a clGro enl3lo-j b-A-!r-~,-n the mannitu&3.and character of th* Is,.
fluence of tho oubatitu,!nta Ca tho (a), (b), r-'nd (a) hydrc~--n of the
dz,oa
c,~nyl nuclouis ~-nd cormj,-:-adtn:,ly on 0,3-ritn# jTad p:w~l ".j- "M
Ul",
Or 1g. c -1: 3 f 2 rnd
-Z rJ
C

L 46186-65
ACCESSION MR$' iPSOO7562
ASSOCYATIONt Inatitut khlnLL prirvdaykh sajvdLmafy AkadexLf unk MR (ZmdtvW"l
of ChemLatry of tlatilral empounds, Acadazy of safamms SUR)t I=tLtut 0
arganicheckM co-jaEM-e-nly--UadamU nauk SSSR-Alutftute Of
pmnds, Acadcoy of Sciences GSSR)

DVORYANTSEVA, G.G.; SHEYNKER, Yu.Y.; NESMEYANOV, A.N., akademik; NOGINA, O.V.;
LAZAREVA, N.A.;
Infrared spectra of soma cyclopentadienyl compounds of titanium.
Doll. AN SSSR 161 no.3.-603-606 Mr 165.
- (141RA 18:4)
1. Tnstitut alementoorganicheskikh soyedineniy AN SSSR i Institut
khimii prirodnykh soyedinaniy AN SSSR.

NESMEYANOV, A.N., akademik; ANISIMOV, KA; VALUYETA, Z.P.
Reactions of chlorc-7.e*lhyleyclicr>p-ntaO-ienyinarganesetricarbrnyI with
some nucleophilic reagents. Dokl. All SSSR 162 no.l.-112-115 * 165.
(MIRA 18:5)
1. Tnititut elementoorganicheskikh soyedineniy Aff SS'S.R.

NESMMIOV) A.N. akadomik; DUBOV7.S-KlYl V.A.; NOGINA, O.V.; 130CHKAREV, V.1"J.
---- -- -'. -- _- -- -.t-
I$Ass arectra of =nonyciopentadier-yl derivatives of
Dokl., AN SSSR 165 no.1:125-126 11 165.
(MIRA 18:10)
1, Institut elementoorganicheskikh soyedineniy AN SSSR i Institut
kh,imii pr1rodnykh soyedineniy AN SSSSR,

XMYANOWt A.Ng, akadema; BORLSOV, A.Te.; NOVIKOVA,, N.V.
(WaRstric lamors of prswdm itusayl ampowds. Vckl. All 808ft
165 soo2t333-336 9 165,, (VaPA lain)
Is ImUtut ol~mnto=gsnichsskikh soyedimnly AN SSSR,

;I; g4 A,
la a 0
of
Re 1~ - 11
(6e k.
Ard SS-SR 165

314-66- ___PRLm)/EWP(j) RX
NR, APa2-M89 SOURCE CODE:
AUTHOR: NesmeLanov, A. N.; Villchevskaya, V. D.; Kochetkova, M. S.
ORG: Inst-MM-bYGrLyanometallic Compounds, ~S-S~R-TInstitut elementoorganichlikh
soyedineniyl a SSSRI -carboxybenzoylferrocene
TITLE: Reactions or o j
SOURCE; AN SSSR. Doklady v 165 no. 4, 1965 835-837
TOPIC TAGS: ferrocene, pAen;l, pAosphoric aciA, cation, chemical reaction, molecular
structure# IR spectrum, phosphorus chloride, IR analysis
ABSTRACT: A study was"ma& ot'the reactions between o-carboxybonzoylforrocone
.and nuoleophilic reagents such as thiophonol and pherG-l in the presence of
phosphoric acid. This results in the formation of S- and 0-substituted and
3-forroconyl phthalides. An attempt to accomplish these reactions in the
absence of M04 was fruitless. Evidently, the first stage of the reaction
is the forma lo of an alpha-ferrocanylmotlWl cation, with subsequent attack
of the cationoid center by the nucleophilio agent. This reaction is a now
example of the alpha-forrocanylmothyl cation reaction. The structure of 3-
forroconyl-3-thiophanylphthal:ido has been confirmed by the findings of ultimate
analysis as well an IR spectral data. The IR spectrum of this substance contains
frequencies in the regions of 1000, 1107, and 1783 ed-1. Thus, the presence
of a lactone ring may be considered proved. This was first concluded thooratically
&u-ing a study of the reaction between o-carboxybenzoy1forrocene and phosphorus
trichloride# which yielded a substance resevibling Boyde's acid chloride and
believed to contain a free aVlopentadianYl nucleus and a lactone ring.
&PM: 36 4517
SUB COEE: 20/ SUBM DATE: 07jun65/ ORIG REF: 004/ OTH REF: 001
. . A. j J?/ MM . 4.1.97 - I V% - (W

I E. -;
NMLi;'Ufl~'V A , ?,RlT,,K.AYAl .'L.; F7,DiNlp
- I ~) I i
o
Sy-nIA, -rJr; and f
Dokle MI SCSR 164 no*511058-1061 0 165. (,'~!?,A 18: I.rj)
1. Institut eleix-ntooi,ganicheskikh soyerlinenly .411 SSM.

MILLIONSHCHIKOV, M.D., akademik; ARUTYUNOV, K.B.; IESNEYANOV. A2N.,, akademik;
TALIROZE, V.L., doktor khim.nauk; PAVLENKO, V.A.; KOTELINIKOV, V.A.,
akademik; PETROV, B.N., akadend-k; NOVIKOV, I.I.; WDELISHTAM, S.L.,
doktor fiz.-matem.nauk; VAYNSHTEYII, B.K.; SWILOVSKIY, akademik
Problems in the manufacture of scientific instruments. Vest.AN SSSR
35 no.60-20 Je 165. (MIRA 18:8)
1. Glavnyy konstruktor Spetsiallnogo konstruktorskogo byuro
an-aliticheekogo priborostroyeniya (for Pavlanko). 2. Chleny-
korrespondenty SSSR (for Novikov, Vaynshtayn). 3. AN Kirgizakoy
SSR (for Shumilovskly).

NESMEYANOV, A.N., akademik; KURSAMOV, D.N.; IFFEDOVA, M.N.; SETKINA,
V-.Tt *,t~-?EREVALOVA, E.G.
Substitution of a proton for a halcgen in ferrocene halides. Dokl.
AN SSSR 161 no.6:1349-1351 AP 165. (MITRA 18-,5)
1. Inetitut elementoorgRnicheskogr sinb* kN SSSR. 2. Chlen-ior-
respondent AN SSSR (for K-irsanov).

NEW,YAIIOV k,N.; AHISIMOV, K.R.; KOLOBOVA, N.*fe.,, ARILONOVA, A.B.
00
ftaction of ungarsese --hloroFentacarbonyl -with trich2orrgermave. I'zv,
AN SSSR. $or. khim. no.7-130 t65.
1. Institut elamentoorganichaskikh soyedineniy AN SSSR.

TV
L 27
UCESSION NR: APS023717 kUR/0025/65/000/008/0014/002.1
;AUrHORt He yanov, A.( AcademLcL4, Belikovs V.( Candidate chemical sciences
of
1TITLE-z synth new problem in chemistry
ISOURCE: Nauka L zhL=I# no. 8$ 19656 14-21
ITOPM TAM ntitpLtiont -.food techoologys cheiAcal industry
AABmAcr: ,.The- probaems of synthetic food . production are consLdez-ed with regard to f
the human', reslu~e~ ments of water, protein, 'carbohy~drates, fats, salts, and vitamins.'
rt is polnted.6ut.that synthetia methionine andyeast protein concentrates are being
produced and.used commercially for food production. The consistency and taste of
!
fartificial food Its discussed. It is concluded that although little has been done InI
ithe area of.synthetic food production, there is a great future for this industry.
Orig. art. has: 6 tables,
;ASSOCrATrON: none
'SUBMITTEDs~ 00 CODE1 L5j,*.GC,
EXCLA. 00 SUB
REFSOVt 000 OTHMU 000
v'q

NESHEYANIOV, A.N.; RYBINSKAYA, M.I.; RYBIN, L.V.
.Reaction of aryl- f~-nitrovinyl ketones witb aniline. Izv. All
SSSR. Ser. khIm. no.8tl382-1388 165. (KM 18:9)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

NESMEWOV, N.; MAGOHMM, G.K.; KOLOBOVA, _N.Ye.; ANISIYDV, K.N.
Condensation of acetylcyclopentadien.-flwnganese tricarbonyl
into 2-butenon-4yl-2.4-bisayelopentadienylmanganese tricarbonyl.
Izv. AN SSSR. Ser. khim. no.8-.1496-1497 065. (KMA 18:9)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

AP50252" souRn. com: UR/0026/65/000/W9/0013/0023
AUTHORS.- 11.1esmeyanov, A.' ?T. (Academician); Belikov, V. M.(Candidate of chemical adencei)
ORG Institute of Elemento-organic Do s Alf SSSR 1'roscov Unstitut. -All
Oom und
GlemontoorganleReek soyedineR5~ A11
TITLE Problems of foodstuff synthesis
S07JRCE: ~Priroda, no, 9, 19651 13-23
TOPIC TAGS- food technology, organie synthetic process, protein, amino acid,
carbohydrate, vitamin
ABSTRACT: Fo22owing a brief review of the progress in synthetic organic chemistry
during the last century and of its effect upon human activities (synthetic dyostuff,
modicinals, synthetic rubber, fibers, leather) the authors bring up the,question of
the synthesis.of foodstuffs. The discussion,develops along the lines of require-
ments., present natur supply, and possible synthetic production of five components
of 'human foodst Vtein,carbohydrates, fats, vitamins, and mineral salts.
Of these,-the Indt two are alroady producod synthetically, The Wthesia of proteins,
-the componont.most deficient in the diet of the world population, can be roducod
to the preparation of eight nonieverchangeable amino acids. This can be accomplished
~by a total chemical synthesis, microbiological synthesis, or aIcombination of the
two. Methane or olefins may serve as starting materials for the first of these
Ca~d 1/2 UDC: 54.114: 641-59 1,

L i3gil-66
ACC NR:
AP5025244
-k-etoacid is. espe
methods. Reductive amination of cs, cially attractive, as the Ins'
step in this process may be accomplished by microorganisms producing the desired
.L-isomer of the amino acid. One of the newest methods introduced by French scien-
tists involves growing yeast on petroleun fractions, The protein thus produced may
be used in human foodstuff. Pats and carbohydrates can be obtained so cheaply from
agricultural products that there are no known.competitive synthetic processes.
Solutions to the problems of taste, palatability, and consistency of synthetic food-
.stuffs are offered. Advantages of the synthetic production of foodstuff are de-
scribed, They inolude abundance of nourishment, independence from the forces of
nature,. andrelease of 34% of human labor now employed in agriculture for other
activities. Orig. art. has: I+ tables and 2 figures.
SUB CODE: 06, 07/, SUBM DATE: none/ SOV REF: OOl/ OTH REF: 002
Lssrd 2/2

NESW-YAN-- . A. .; PEREVALOVA, E,G.; LEONTIYEVA, L.I.; USTYNYUK, Yu.A.
ForracenYlmethYlthiOl and Meth7I(fe"menyl=tbyl) sulfide.
Izv. AN SSSR. Ser. khim. no.9tl696-1697 165. (mm 1819)
1. Moskovskiy gosudarstvennyy universitet.

.J.,; SAZONOVA, V.A ; ROMANENKOp V.I.; ZOWHIKOVA, G.P.
IU.A 0
Photolysis of 1,11-ferracenedicarbox-fl-4c acid. Izv. AN SSSR.
Ser. khlm. no.9rl694-1695 165. 180)
1, Moskovskiy goisudarstvannyy univorsitat.

NESMEYANOV~ A.ff.~ DROZI), V.N.; SAZONOVA, V.A.
listylation of M-aiylazinoferrocenes. lzv, AN SWR. Sar. khim. no.7s.
1205-1208 165. (MIRA ISO)
1. Moskovskiy gosiidarstve.nrxyy universitet im. MN.Lomonosova.

KTJF.SANUI, D.N~; SUKINA, V.X,~ NEFEDOVA, M.N.; -NEVE-YANOV" A.,N.
Hydrogen isotope exchange in a1kr1fsrrcc-3aeP. iz--.AJi S-S~'?,Ser,khlm
no,1222218-2220 165. (MIRA 18zj2)
1. Tnstitut alementoorganicheakilkh soyedineniy All SSSR. Submittad
April 21, 1965.

UMPTOV.4, M.D,; TARYSPEVA, L~M.,- PPMAL-OVA, E,G~.s A.H.
--"- I-- ~ - 1.
Syntheais of ame subs t I '.1ifed
SSSJR.S"r.khlm. no.IL;~10/6,4)108 165,
041R~A lp-~22)
I* Moskovaki7 gcsudarstvenn7y unllversitdt ~M. Lomcncsova.
Submitted Arril 5, 1965.

NESMYANOV, A.N.; FEREVALOVA, E~G~,- NIKITINA, T.V.; HIZUETS0,17A. N.I.
Behavior or and cl.;nditicnrt
of benzidin,~ rearrangement. Tzv.AN SS,:MI.Ser,khim. no.12w2l2c-
2124 165.
Atution of hydrochloric acid on azo derlvaUvAs of fe-rclc,~ne,
Izv.AN SSSR.Ser.khir.. nr.!,~.-23.24-2128 165.
(MIR-A 18.22)
1. Moskovskly gosud&rbtvfnnyy universite', im. lxmonosova.
Submitted July 29, 1.9630

Yu .
ITESI,TYAl'TOV, A.N.; FER-ENALOVA, F.G.; LE-ONVYEVA', L.7.; US';-j,',Ij J.. Yu.A.
Synthesis cf 1,2-di-substituted fe.rro~~nt~c. TZV. *j' --
U- r- S - ER `3 e I .
no.10:1882-1884 16~ (PERA 18:10)
.? 0
1. Moskovskiy gosudarstv-3nrly-I uni,,rersltet.

IYESMEYANOV, A.N., akademik; VILIGHEVSKAYA, V.D.; KOCHETKOVAv N.S.
Reactions of o-carboxybenzoyherrocene. Dokl. 'IN SSSR 165
no.4:835-837 D 165. (MRA 18:12)
1. Institut elemntcorganiche3kikh soyedineniy AN SSSR.

L 27692-66 EWTW/RWPQ) RM
ACC NRs AP6017.400 StURCE CODE, trR/0062/65/000/007/1205/1208
AM0Rz,;..Negm9Ymw, A. K.; Drozd, yf-N-P; Slazonava. V. A.
ORG i , tirivers In, M.
140800W State it7 V. (Maskovskir goaWarst"
universitet)
TITLEt Aoetylatior. of N-aaylaidnoferroconee
SOURCEt AN SSSR.
-Imetiyao Seriya kh1mioheskAY& no- 7o 19651 1203-UO8
TOPIC TAGSt organoiron compound, organic inine comfound,'aninet farrooene', wwtio
anhydride
AWTRAC ITs'ldhtu~g acetylation in the ring of N-ferrocenyl~hthalindhw and-I
IX-acety1ferrocenylamine) the authors found that the aZ77amino-group is an.
;electron acceptor with respect to ferrocene and directs substitution md r4.
in the free cyclopentadienyl. ring. Thus, in the acetylation, of 14--ferro-
CwW1phthalimide with acetic anhydride in the presence of HJPO,4, the mAin
reaction product was ll-(N-phthalimido)-l-acety3.ferrocene and a smaller
amount of homoannular N-phthalimidoacetylferrocene (yields of'40 and 7% of-~.'
theoretical, respectively)* Acetylation of N-acetylferrocerqlamine pr10_
'ceeds with the formation of large amounts of tarry substances; of the
!reaction products with 17,"al yield only 11-acetamino1.1facetylferrocene Vas
:isolated..:It was found that 11-amino-1-acety1ferrocene is obtained by th
,hydrolysis of.ll-(N--phthalimido)-l-acetylferrocene and 11-acetaminoacetyl7i-
~ferrocene and from the Curzius reactin 1 cetylferrocene-l-carbo 31
acid4 Orig~.TArto has:--'l foroluu.*
SUB CODEse~- SUBK DATEt lWun 3 ORIG REF: 004 OTH REFt 004
Card 3A. nnct S42-Q1+%2.9M%-22

L1_aZ,7k::& EWT(m)/EWP(J)/T 1JP(C) RM
ACC M AP6016974 SOURCE CODE: UR/oc)2o/65A65/003/0575/
'AUTHOR: Nesmeyanov,-A. N. (Academiciar.); ~Monova, V. A.; Drozd, Y.N. 77
01ROG: Ve sitat
scow State Im. M. V.-Lomonosov (Moskovskiy.gosudarst nnyy univer
~TITLE: Introduction of aromatic and heterocyclic radicals int.o ferrocene Reaction
of bromoferrocene-with grganomagnesium compounde
SOURCEt AN i*SSS Do ak, -vo-165', 3o 1965j 575-~,577
-noq
TOPIG TAGS: ferx,ocene, organomagnesium compound, brominated.organic compoundp
organic-synthetic process, Grignard reagent, nuclear magnetic resonance, chromatograpty
ABSTRAGT: Jn previous. studies the* kitborsijint6siz6d hydroxyferrocenev l)lr-r
-dihydroxyferrocenes ferrocenylamine, diferrocenylaminej, pbenylferrocenylamine,
Adipbeny1ferrocenyleminev ferrocenylazide (followed 'by conversion to diazo
.~owounds of ferrocene)) ferrocenylaryloulfones w4other ferrocene derivatives.
'through balo-derivatives of ferrocene. In this work the reaction of bromo--,
with organomagnesium compounds was investigated. Phenyl-, alpha-
:thienyl-, and alpha-naphtby1ferrocenes were produced in 75-80 yield by the
addition of an ether solution of drignard reagent to a mixture of bromoferrocenet
.,:Copper bromidep and,copper, folloved by distillation of the ether azA he*ting
;~of the reaction sixtwe under nitrogen at 130o- In tho'case of an alicyclic
,Grlgnard reagent# cyclobexyl magnesium chloride, the reduction of brosoferroceus,-
to -ferrocene became the basic reactianp, and,on4 cyclehexen was lmo4"
:I, cmd 1/2 --- UDC: .257.2+50*21U.-A

L EWT(M)AWP(i) RM
f-ACC NRt AP5-027691 �OURGE CODE: TJR/0062
,/65/000/019/1882/188
AUTHOR-.- Nes'meyano .,A. No; Pirevalovas So G.;-Ljont'yeva, L. to;
Ustynyuki- -W. -- -7- . I I -
j0RG: University.iM.-M. V. Lomonosova (Moskovskiy
igosudarstv,ennyy universitet)
TITLE: Synphesis of.lp2-disubstituted ferrocenes
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskityap nos 10, 1965,
1882-1884
TOPIC TAGS, chemical'reaetions desulfurization., chemical
reduction
ABSTR>: ,The reduction of l..2-(2t-thia-4t-ketotetramethylena)ferrocone
(1).was investiga .ted in order to find suitablemethods. for the synthesis
.1of homoannular disubstituted forrocenes. I was desulfurized with
Raney nickel to form ls2-methylethyl-.and lj*2-methylacetylferrocene,
Reduction of I with lithium aluminum hydride gave lj,,Z-(?-t-thia-k-hydr0-
xytetramethylene)ferrocone (II). Reduction of I in the presenee.of
aluminum chloride gave 1,,2-(2t-thiatetramethylene)-forrocanaI &.small
amount of II,, and methylferrocone, .and in one instancet 1,2-(21-thia-
31 J141 deh7drotetramethylene)ferrocene. Orig. art. has: 2 equations.
cw~ 1/p- 542,91+547,35+546.72

"L 36507-66 F747(m)/EVIP(j) RM
ACC NR. Ap6017876
SOURCE COD.Ec UR/0062/66/000/005/0832/0339
r
AUTHORs Poren~ova, E. G.; Grandberg, K. I.; Zharikova, N. -"LIZIp S.
ORGI
sitet);
stitut
(Yoskovskiy gosudarstvennyy univer-
s, Acadeaq of Sciencest SSSR (in-
TITTLEt Electronic influence of forrocanxilas a substituent
SOURCEs AN SSSR. Izvestiya. Seriya khimichaskaya, no. 5, 1966, 832-839
TCPIC TAGS: ferrocene, dissociation constant, aniline, benzoic &aid$, phenol, substi-
tuentq amino
ABSTRACT9 By determining values of Hammett's CC 9 the authors studied certain olec-
trordo effects of ferracenyl as a substituent. Using acid-base potentiometric titra-
tiong they determined the dissociation constants of p-9 m-1, and o-ferrocanylbenzoic
aoidsg a series of gubgtituted benzoic aoide and ferracenecarbWlio acid in 70% di-
orzane, and the dissociation constants of p-forrocerkylphenol and a series of p-substi-
tuted phonals In 50% othawl, The basicity constants of p-p a-, and a-forracenylani-
linesp a serlea of p-substituted anilinesp and forrocerylamine in 80% ethanol were
also determined. 7he data obtained were treated by the least-squares method, (0 val-
ues were calculated for the reaction series studdedg d values were found for forro-
UDCt 541 + 541.49 + 547.163s541.132

ACC NRs AF6017876
canyl as a substituent In various positions of the phox7l ringj, and the Induction c
stant or was dot-ermined. The data showed that in the series of forroconylbenzoic
acids$ tL strongest to a-forrocarylbenzoic acid; p- and m-forrocenylbenzoic acids
are comparable in strength and are respectively 1-5 and 1.6 times stronger than forr
conocarboxylia acid,, which therefore is the weakest acid. p-Forracenylphanol is a
weaker acid than phenol (by a factor of 1.3). The opposite relationship is observed
in ferracenyl derivatives of anilinet a-ferrocerqlaniline is the weakest bases 300
times weaker than ferrocerqlamine. The strongest base# ferracezWlaminep to 42 times
stronger than aniline and almost 28 times stronger than p-ferrocerqlaniline. It is
concluded that ferrocerql has a strong positive inductive effect and a weak positives
conjugation effect. OrIg. art. has$ 7 tables and 2 formulas.
SUB COEE I k I 27DOq63/ OM REF1 009/ OTH REF: 014
07.IYSUBH DATE

liMW-Y A NOV. A. N. I H SMUJ, K . 14. ; EON 5 OV A, N Yt-, A NTONOVA, A.13.
Fhenylryern.-~:rtiwni -~er 1-;,-, *,-' ~/es of mLnpane:~P- c a rhon-y-I z-;.
T
Ser.khim. rjo.1:1(~~262 16c'~.
1. InstiLut el(,mt,..ritooi-fanicho.,3ki-kh soyed-Inenly All SFM. ib-m` d

NF-I'M'~'YANGV A-11 - KOLOPOVA, If.Yc-.; AITl';iVOV, MAN!" Z111KOY V
Fnenyl-rmanium a 4
I
..';e I-. im. nc;- I6i' 'c-6.
f
-7 --A
M
Tnstll,ut elerientoorganicheski-kh zoyelinpniy
ilittee, tLY 14, 1965

NESMETA-NOV, A.!..; T,~,'-STAYA, T.P.; lFkYFVA, L.S.
Fhea,71-2-t~dcnyl bromonilon Sal tZ. S--~F.
I.-A .1 ,
no.1:166-168 1661, (%f7-)
I.. InstituL elom-entoor~anieheskikh s(Arodlreniy ANI ='l*R ~
Moskovskiy t~,,osudarstvennyy univensitet. Submitted Ma-,, 17,
1965.

L 35327-66
ACC NRs
SOURCE CDDEt
AUTH)Rt Nefedova, U.N.; Kursanoy D N (Corresponding'member AN SSSR); Setkina, V.H0;
~esmeyanovj' _VZQcian)
Perevalo _,_E.G.; A.N. c
la
ORG: none 6
TITLE: Effect of substituents on the rate of n ferrocenall
derivatives
SOURCEs AN SSSR. Doklady, v. 166, no. 2, 1966, 37h-377
TOPIC TAGS, ferrocene, electron donor, dissociation constant, substituent, reaction
rate
ABSTRACT:
The authors determined the rate constants for acid isotopic exchange
of hydrogen in six ftionosubstitated and four disubstituted ferrocenes. The
relative rate constants Kr 1 were then calculated assuming unity for
unsubstituted ferrocene. %e substituents studied Included both electro-
donor and electron-accepter types. An analysis of the resultant data shows
that the effect of the substituent on the reactian rate in an aromatic
compound my be described as a combination of induction and conjugation, The
conjugation effect is much less important in this case than it is in electro-
philia substittition in the benzene series. It was found that.the substituent,
UDCt 5h6.11.2+5h2-957+546-V-

L 35327-66
ACC NRs AP6026836
fconstants obtained from the dissociation constants for phenylacetio acids may
be used as a quantitative index of the effect which the substituent has an
the reaction rate. Curves for In k/kO for all substituents studied show a
linear correlation with those constants, Haterocyalia disubstitated deriva-
,tives lie on this same line if doubled values of substituint constants are used,
i.e., the substituent3 have an additive effect within the liats of experimntal
error. - The authors'thank 5 15",- - -
,Y-. Portn6yi and G.P. Yroira for taking the nuclear
resonance spectra. The authors further thank V.A* Fallm and M.P. Gambar-yan for
participating in the discussions of the results. Orig...arb. hass I figure and
I table ZJFR�t 36s 45Y
SUB COUES 07 SOU UTES 235eP65 alm REFS 013 OTH REFs 010

RM
ACC NRI AP6021104 SOURCE CODE: UR/OO62/66/ooo/oo2/O384/q3e
AUTHOR: Gubih, S- P.; SheRilov, I. P.; Mesmey=2 111
Zj A. N. 0
ORG: Institute Of Organoelemental CqMpounds, AN SSSR (Institut elementoorganichaskiR
soyedineniy) "I
TITLE: Acetylation of forrocene!!by the complex 2CH sub 3 COM.EF sub 3
SOURCEt AN SSSR. Izvestiya. Serlya khimicheakaya,, no. 2, 1966, 384
TOPIC TAGS: ferrocene, acetylene compoundo reaction rate, activation energy,
spectrophotometric analysis, catalysis, chemical reaction kinetics
ABSTRACT: T~e authors determined rates of acetylation of ferrocene by the complex
- U.n in glacial acetic acid under pseudo-first order conditions. The
'ti arr
e
ac ested by pouring the sample (1 ml) into 20 ml of absolute ethanol.
The ferrocene and acetylferrocene concentrations in the solution were determined
spectrophotometrically at 337 millimicrons on the SF-4A unit. The apparent energy
of activation is 22.4 kcal/mole. When the catalyst concentration is increased,
the reaction rate rises. The data obtained shows that ferrocene is 200-300 times
more active than anisole in the acetylation reaction. (JPRS1
SUB CODE: .07 / SUBM 12ATE., 17Nov65 / OTH REF: 001
card 1/1 ~'t' UDC: 542-.957-+ 546-72 + 66-095-11

L
Acc-Mc-AM026817 SOURCE CODE: UR/0020/66/166/003/0607/061(
AUTHCRt Newevanoy, A. He (Academician); Vollkenau, H. A.; Bolesova, I. N.
ORG: Institute of oelemental Gcmpounds, AN SSSR (Institut elementoorganichoold
.~F~an
soyedineniy AN SSSR)
TITIZ: Interaction of 12aocenaiwith substituted aromatic compounds
SOURCE: AN SSSR. Dokla4y,, Y. 166, no. 3. 1966, 607-610
TOPIC TAGS: ferrocene, chemical reaction, molecular structure
ABSTRACT: This paper is a continuation of previous.studies on exchange of.the
ligand group in ferracene and its derivatives in the aromatic ring wd the effect
of substituents in the ferrocene nucleus on this reactione Interaction of-
ferrocene with toluene, p-xylene, diphanyl, naphthalene, fluoreneq aniline,
acetanilide,, chlorobenzene, bromobenzene, benzanitrile, acetophenone and thiophene
was studied. Eight aromatic cyclopentadianyl iron salts were produced with
substituantis in the six-membered ring, Orig. art. has: 1 tables EMS: 3694:551
SUB CODE: 07 / SUB14 DATE: 22Jul65 / ORIG REF: 002 / GTH REFt 003
Cwd 1/1 e1
D.9

6 '-EWP(J)/E,'4T(m) IJP(c) RNfi/KW
XP6021100 SOURCE CODE:,
AUTHOR: Nesmeymov, N.: Perevalova, E. G.; Reshetova, K. D.
ORG: Moscow ..A.e University im. K. V. Lomonosov (Koskovskiy gosudarstvennyy
universitet)
TITLE: Salts of N-(alpha-ferrocenylalW )pyridinjum
IU
SOME: AN SSSR* Izvestiya. Seriya khimicheqkaya, nol 2, 1966, 335-337
TOPIC TAGS: pyridine, alcohol, esterification, solubility, chemical synthesis#
organic nitrile compound, org~mic amide, ferrocene
ABSTRACT: The reaction of alcohols with p-toluenesulfachlorlde in p7ridine
is the method by vhich eaters of p-toluenesulfonic acid ore obtained. How-
eirer, In some cases p-toluenesulfonates.of pyridinium are'formed instead; for
example.,with 2.4-dinitroresorcine, or 2,4-dinitronaphthol. The authors found
that ferrocanylearbinal and substituted ferracenylaarbinols react In this
way. In the reaction of oMmethyl-, alpha-mWethyl-, oxybenzyl, and 1.10-
cyana-(alpha-ozyethy1)ferrocene with p-toluenesulfachlorlde In absolute pyrift
dine the authors obtained p-toluenesulfonatdo of the corresponding pyridiums.
.Salts of N-(alpha-forrocenylalkyl)pyridinivas are soluble In water (except.
1(ferrocwWjba'n%y1)pyrJLdi"=)q alcohol, acatonitrils, WA OW 'tAdn polar
solvents. Nitriles of forroconylacetic, f a anylproplonice and forrocanyl.
(;dqyj)acetie adds wwo *obtained. . Wriles7of tho first two acids were
byd"Iyxed to odds@, INS. adA4~ Jp- air* In contrast:
to the nitriles. Orig. art., has: 1 table. (JMJ
SUB CODE: 07 / SUBK DATE: 191(aY65 / CRIG REW: 002 / OM REF.- 002
card 1A a P, UDC: 54201 + 547-19.3 + 546-72

L-27094-66 EwT(m)/EWP(j) RM
UR-M COM. IJR70OR1637
r ACd 17399 o001007A 0911 9
-AUTR(Yat' Ne~mryanov, A* No; Anisimov. Ko 11 Kolobava. N Yet; Anto, loni A B.
O?G: Institute 0 .f Orpnoelemental G2Epoqnds` AN SSSR-(Institat olementoorganiahes
11TITIE48
AN,SSSR)
Reaction of ~manginase chloropentao"bo?W with trichlorogermanimf
SOURCE.- 'AN SS3R. Izvestiya, Sertya Mdmicheskayao no. 7, 1965, 1309
TOPIC TAGS: a compound, germanium compound, 3R spectrum, absorptioA b&M-
ABSTRACT.- BiZtnSmlic compounds of carborqls of transition metals with gidiip 1
:IV metals are obtained by reaction of the sodium salt of the metal carbonyl,
with the halogenide derivative of a group IV metal. The authors carried out
~a new reaction.of manganese chloropentacarbonyl with trichlorogermanium. for
+ HC1.'
the series of metal 'ca?�2!71s:q- C1jGeH + aDfri(CO),c --Va3Ge14n(C0)5
ra,
'The reaction was carried out iih tetrahydrofuran with gradual rise in tempe
ture from 20 to 600C during the course of one hour. The manganoOntacaxbonyl-i
'trichlo.rogermanium) obtained with a _4C% yields is a white cx7stalline compowidJ,
b. p. 168.3 - 16900s insoluble in water',, soluble in petroleum others
benzene, and other organic solvents,-sublimating in vamms and stable in air#'
The infrared spectrum of the compound contained intensive absorption bands in.[
the region characteristic of carbonyl groups bound with metal,, 2030 and 2130 "t
=71;,banda, were present in the region of,400 and 453 mrl, corresponding to I
eOrig*artehast 1:
Go-Cl.bonds in 21 _LSro p _6
mpounj!.!~!~ the GeF
05 ftA r., ""a_ A"

L 265�4
EwP0)A*T(m)/T ijp(c) Rm
ACC -NRt AP60.17364. SOURCE CODE: UR/0062/667567666376w/0359 I
AUTHOR:-~: Nesmeyan6v, A. If. Pe~revalova, E. G.; Le --Ustynyuk, Yu. A.
ORG*.~ M6-sc-o-w' S ate niversity im. M. V. Lomonosov (14oskovski3r gosudarstvennyy
U1#versfUe=
TITLE: oftdferrocenylehloromethane- hydrochloride
f -SOURCE: AN.SSSR. Izvestiya. Seriya khimicheskava, hoo 3, 1966t -558-559
TOPIC TAGS: organoiron compound, chlorinated organic campound,-.organcmagnesium compolmd,,.
organosodium, compoundq organolithium compound, chemical reaction
ABSTRACT: Triferrocerqlchlorowthane hydrochloride reacts with nucleophilie'
reagentg (organomagnesium and organosodium. compounds, lithium aluminohydridep
soditm methylate andoodium cyanide) to form the corresponding derivatives of
triferroceny1methane, [JFRS1
SUB CODE:.-07 SUBM DATE- 22.Tul65 ORIG REF 002 OTH FM 001
r4 jh" V 'UDQ: 542.91+541. +546,72--

L 26555-66 - E-f1P(J)/EV1T(m)/T JJP e., 91,
ACC NR, Ar6ol?3C SOURCE CODE: UR/0062166/000/003/0556/0558
AUTHOR:-. Nesm2=CV P6~revgL Ustynyuk,
ova, E.. G. leontlyeva, L.- YU
ORG:, Moscow State-UniversitZ im. ff. V., Lanonosov (Moskovskiy gosudarstvennyy
universitet).
TlTLE;.& Triferrocenylchloromethane hydrochloride
OURGE, AN BSSR. Izvestiya. Seriya khimiche -5513
S skayd, no..3, 3-966, 556
TOPIC TAGS: organic synthetic proce3e, perchlorie acid# perchlorate, hydrogen
chloride,-organoiron,compound
ABSTRACT: The. 'ionic t.riferrocenylme-Lhy-lperchlorate and triferrocenylchloromethane,
hydrochloride were synthesized by reaction of triferrocenylcarbinol with perehloric.
acid in benzene and anhydrous HC1 in ether, respectively.
)3 HQ104
(C5H5Fe(;5H4)30C'P4
00H
(C if For, H CCI- HM
5
,In polar solu+,iorj6ltriferrocenylchlorometharie hydrochloride decomposes toform
ferroceny1fulvenea-TaRS)
~SUB CODE1. 07 SUBW DATE: 22Ju165 ORIG FEN 003 OTH Wt 002
cmd -1 UDC I 542.21+54l.A9+546.72

NF--M-MATIOV, A.11., a~adumlk; VOLIKIIIAIJ, N.A..; P11-11PT)VAlt 1-174.
Interact~-cr. of ferrocene with cubzt.-I'll-ted aro:ia-lic
Dolcl. AN SSSR 166 no.3:0337-610 Ja 166o ( m i 1 -9 : I )J
1. linstitut elementoorclanichesk[kh soyedironly AN Subm.,ttod
.1 1 -
.r
Duly 22, 1965,

L 36986-66 Lw(j
ACC NR- AP6008509
M) 1ZK
SOURCE CODE: UR/0067- /66/000/00 1/0 L60
AUTHOR: Nesmey
=ax-A~ Anisimov, K. N.1 Kolobova, N. Ye. Antonova,
A. B. *n-1
3,51
ORG: Institute of Heteroorganic Compounds, Academy of Sciences SSSR (Institut
elementoorganicheskikh soyedineniy Akademii nauk SSSR)
TITLE: PhenYlR ermaniuml derivatives of manganese carbonyl
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 1, 1966, 160-16a
TOPIC TAGS: manganese compound, phenyt compound, germanium compound.
ch,emical synthesis, organogermaniurn compound
ABSTRACT: This investigation is devoted to the synthesis of phenylgermanium
derivates of manganese carbonyl (C6H5) 4-nGeBrn - nNaUn(Co)5-0 (C6H5)4n
Ge[.Mn(GO) A+ nNaBr, where n a I or 2. and to a study of certain of their
"Properties.4's a result of the reactions of the sodium salt of manganese carbonyl
with halogenated phenylgermaniurn derivatives, the authors synthesize the
bimetallic compounds (C6H5)3GeMn(C0)5, (C6H5)?Ge(Mn(CO)51?. and
(C6H5)? (CO)5Mn GeGej Mn(CO) I (C6H5)Z-
By substituting CO-groups inlo the bimetallic compounds for phosphines,
I/Z UDC: 542.914-547.113

L 36986-66
ACC NR, AP6008509 C~
arsines, and stibines, the authors obtain
.(C6H5)3peMn(CO)4p(C6H5)3, (C6MGeMn(CO)4As(C6Y3, and
(C61-~~Gemn(cO)496(cA)3-
When halogens act on the phenylgermanium derivates of manganese carbonyl
(C61t)?.BrGeMn(CO)5, (C,6FT5)BraGeMn(CO)5, Br3GeMn(CC)5, and C13GeMn(C(3)5
are obtained. The authors thank Yu, N, Sheynker and G. G. Dvoryantseva for
measuring the infrared spectra.
SUB CODE: 07/ SUBM DATE: 14May65/ ORIG REF-. 007./ OTH REF: 003
Qrd 2/7.

E:WP(J)/MT(m) RK
ACC NR, AP6008SIO SOURCE CUDE: UR/006Z/66/000/001/0163/0164.
t1 ;~
AUTHOR: Nesmemov, A. N.; Kolobova, N. Ye.; Anisimov, K. N.; 40~
Kbandozhko, V. N.
ORG: Institute of Heteroorganic Compounds. Academx of SciencesoSSSR (Institut
elementoorganichaskikh soyedineniy Akademii nauk SSSR)
TITLE: Phenylizermaniurn phenyls atives of rhenium carbonyl
jand tannidderiv
I
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 1. 1966. 163-164
TOPIC TAGS: phenyl compound, germanium compound, tin compound, rhenium
compound, organotin compound, chemical synthesis, organogermanium compound
ABSTRACT: In this work the authors accomplish the synthesis of compounds with
a Ge-Re bond and investigate certain properties of these compounds. Compounds
of the type R4-nG e [Re(Cu)~ ln~ are produced by the reactions of the appropriate
organogermanium, halides with tLe sodium salt of rhertium pentacarbonyt
R4-nGeXn + nRaRe(CO~ -* R4-,Ge( Re(CO)5 In + nNaX, where
R4 C6 1-15; X - Br, C 1; n w 1, Z. From this reaction the authors obtained
P GeRe(CO)5 and Ph7Ge[Re(CO~IZ with yields of 87 and 60%, respectively,
in the form of colorless crystals stable in air. Both compounds are readily
dissolved in polar solvents and in hydrocarbons with heating. By using halides
UDC: 542.91+547.103

L 16q87-66
ACC NR, AP6008510
(Br? or halogen acids (HCQ, the authors synthesized Br3GeRe(CQ5and
, 0
Ph2~eRe(CU)5. In the reaction of PPh3, AsPh3, SbPh
3 with Ph3GeRe(CO)5
and Ph3SnRe(CO)5. the corresponding substitutes are obtained with the general
formula Ph3M-Rii(C0)4JL, where M a Ga. Sn; L a PPH3; AsPh3; SbPh3. The
authors thank Yu, N. Sheynker and G. G. Dvoryantseva for measuring the
infrared spectra.
SUB CODE: 07 / SUBM DATE: 14May65/ ORIG REF: QOZ OTH REF: 000
-card Z /Z

L 31361-66 'EMPOVENT(s) IJP(c) RK
ACC Nts AM21101 SWFdGz caust UR/bO62/66/0W/0W/0357A03

AUTHORt A. U.; Rommenko, V. I.; &monova, V. A.
-
-
-
-
In. M. V. r~
oeo
v
TF(oskovskiy gosudarstveraW univeral
ORG: Y'Pecour state ~~drftt
- 4W
TITLE: Basicity constants of i0
ms or f ene
SOURCE: AN SSSR. Izvestiya- SeF5W-kjMa-cTWsXa&9(no. 29 1966, 357
.TOPIC tAGS: rerrocene,, amines solution acidity,, potentiometer, titrimetryp
.
",.distillation, burfer solutioqp chemical neutralization,, alkyl radical/pH - N4c

entiometer
pot
AMTRACT: Basicity constants of forroqW2adne, ethyl forrocaWlanine,
UAWIferrocanylsolne. 1.11-chloraferrocony1sain*v. dnd a2pha-p7r1dr2f*rr*okuw
:iww* dAmmined by potantionotric titration 1na0% (1v weight) ethanol In
40.025 v RM on aps - Nkc type potentiometer. with 0 2009 class olvatrods.

kilverits were prepared as followst distilled ter was -tvice redistilled
wa
w AkaUns'pet"slum paw"anaU in sqf4runt prateited with ascults.
ItMed taboal purchased absolute alookel was treated with sodium (6 grams 'R
,or sodium Pw liter or aleekel) std distilled. and the flest ad last
. ApartrAr portionvvere rejected. The Ultration method Is oan-4ntionall
'ill!nwt. of electrodes was In a blpbtb&Uto buffer (pH 4.00L)e taiparature 22
iad ANIAO N# Budolty constants of the adnes were
--A

for* I
2wee 4 .-- of fteatralizatlan PS '50, ad to), for fack.-
-
e
th
4
l
t
d
t
o
d
s were n
0
a
us
no
WWM
weammmen
e sprea
el
Compwison of basicity constants of W-411w1sted favroceno aminew with"
tbome Of ~ ax~mtic and aliphatic amines show that In the ferrocene awl"
-the 4"Oot C
if. the &1jWlP 1. the *me'&@ An the aliphatic series.
'
Oti
;art
1 t
bl
T
.
a
g.
im
e!-
si
SUBK UTE: 02 u16 REF t 004
-07 5 ORIG GTH fW: 002
sn c
PM

U
cmd Mgt 541-124.7 +
L 7433 +%6
&

L 36506-66 ENT(M)/EWP(J) R111
C NR, Ap6OjM2 (A) SOURCE COM UR/0062/66/ooo/005/0938/0940 ?
AUTHM VesmeyanovP A. N.; Villchevskayap V. D.; Kochetkovav N. S.
ORG& Institute of Oranometallic Coymounds, Academy ot Sciences* SSSR- Institut ele-
mentoorganichaskikh soyedinerdy Akademli nauk SSSR)
TITLE: Cyclization of o-carbox3rbenny1ferrocene 4
SOURCEs Ali SWR. lzvestiya. Seriya. khimidieskaya, no. 5. 1966, 938-940
TOPIC TAGS$ oyolizatlQnq iron compound, ferrocene
ABSTRACT: Cyclization of o-carboxybenzy1ferrocene in the presence of phosphorus pen-
tachloride at 60"C in a nitrogen stream produced in analog of enthrone (I) containing
one ferrocenyl ring in place of one benzene ring. For such analogs,*the authors sug-
gest that the same nomenclature be Introduced as for ordinary aromatic compounds with
the prefix %" for each benzene ring substituted by the ferrocene ring. Thus# the
compound W obtained should be termed 1lb-anthroneg
uDct
A7.25 + 66.o95.25 + 546.72

U 16`,OAw66_
TCC Nib AP6017M2
0
31
The structure of (1) was confirmed by IR and M spectra and by determining the mole-
cular weight, Bences it is shom that the cyclization of o-carboxybenzy1ferrocene
under the influence of PCI forms a cyalopentadierql ring. The Fe-anthrone obtained
readily oxidizes to Fa-ant?waquinone (or Phthaloy1ferrocene) an stirring Its benzene
solution with Mdc~s
Fe Fe
Oll
%der milder oxidising conditions, a compound is forvied whose IR spectra indicated
the structure of Fo-hydroVanthraquinone (III);
Card 2/3

1
ACC NRg Ap60IM2
1 - H
~11
I- k -)
)g
6
PC fill)
0. . -
0
SUB COM, 071 SUBH DATE& 180ot65/ MM Wt 003/ OM RUS 001

WP
im
ACC NR.. AP017884 SOURCE CODE: UR/0062/66/000/005/09,44/0944
AUTHORs Nesmoyanov, A, 14 Kijrnanoya D N , Sotkinap 11, N.; Xi!j1yakovrA#
MOTO-16,0-E~ D. 14. Anisimov, N.
ORGS Institute of Organometallic Compounds. AcaderrT of Sciences- S55R.(Inr;titut
elomentoorganicheski~h soyedinenly Akademit nauk SSSR)
TITIEt Isotopic exchange of hydrogen atoms of manf~arosa cyclo ontadionyltricarbo 1
i-n-d--rh--o-nlu--m--c-y-clo-pentadionyltricarbonyf-i-~ alkaline media
SOURCE: All SSSR. Izvestiya. Seriya khimicheskaya; ni. 5, 1966, 944
TOPIC TAGS1 hydrogen, manganese compound, rhenium compound, deuterium,
B3-10 Ts't ~Thea ehors found that manganese cyclopentadienyltricarbonyl ('NCT) end
A
T 1C
rhenium cyclopent-adionyltricarbonyl (RCT) enter into the reaction of isotopic ax--harig~
of hydrogen under the influence of alkali catalysts. For example, all th~3i hydrogan
atoms of the cyclopentadier-yl rings of MCT and RC-1 are axchanged for doutori~vi in tl--
reaction with deuteroethanol in the presence of sodium alcoholato. 711,~ kirl-Aics r~f
this reaction were studied at 1000C at molar ratios MCT or RCT:C2H
1200.5. The rate constants of hydrogen exchange under these condition's ai-e Y .10`~
see-1 and 80 x 10-6 sec-1 for VICT and RCT respectively, i.e., the relative i-fi~ctj.-,rlty
of the cyclopentadienyl rings of the rhenium derivative ia &bnoct 27 time3 f~hdt
UW1 547.1'3 + 541-127 + 539-183.2 + 661.183.123
c
-9ma-IL2 -------- ---

i6'A6-66
ACC NR: AP601M4
the cyclopentadienyl derivative of manganese. '11io op osite relationship is
in acid catalysis# and the exchange capacity of the hydrogen atoms in tho cycloperit:--
dionyl rings linked to manganese is highor than In tho rhonlum corvounds. It 1", C011-
cluded that on passing from Mn (an element of period 4) to Re (period 6) of group V111
of the periodic systemp the reactivity of cyclopentadienyl ligands In acid riodia do-
creases, whereas in alkaline media the opposite is observed.
SUB CODE: 07/ SUM DATES 12Feb661 ORIG REFS 0021 OTH REFs 001
2/

h6260." EWT(i
AM NRs
j) RM
AP6030570 SOURCE CODE: UR/0413/66/000/01610038/0038
4. AQ
N.: Vil'ch ska Gorelikova.
INVENTOL, N neV ya, V. D.: Kochetkova. N. I.;
Yu. Yu.
ORG: none
TITLE: Preparative method for (0-carboxybenzvl)f Ierrocene~ Class 12, No. 184879
SOURCE: Izobretenlya. promyshlennyya obraztsy, tovarnyye maki, no. 16, 1966, 38
TOPIC TAGS: ferrocene derivative, ferrocene dye, synthesis ) re'e'e0e'CA')A- ID 'M
01dem -a eRiP-*,77j,(1.qA-
ABSTRACT: An Author Certificate has been issued for a method for preparing (O-car-
boxybenzyi)ferrocene derivatives, such as
CH
suitable for the synthesis of ferrocene Ayes. The method involves the reaction of
(0-carboxybenzyi)fecrocene or its derivatives with PC1, In nitrogen at about 60C.(801
SUB CODR: 07/ SUBM DATE: 02Dec64/
Cam 1/11 mia 1MVs q&7-&1Q-A1179-2-n7.

L-4 -7 ~)- E,,,.,T-( m ~z-'F-',~IP-L- I- Rm
cc NR.- AP6oz4396 SOURCE CODES UR/0020/66/1691002/03-5-1/0-3-,--54-;,
AUTHORI Nesmeyanov, A. N. (Acade.--Acian); V111chevska ap V. D.; Makaravag A. L
! OFCY9 Institute of Organometal-lic Compounds, Academy of Sciencosj__SS,~.R (Institut
i elementoorganicheakikh soyedineniy Akadenii nauk SSSR)
TIT129 Phosphorylation of forrocenelderivatives -2
w
SOURCES AN SSSR. Doklady, v. 169, no. 2, 1966, 35t-354
TOPIC TAGSt forrocene, phosphorylation
ABSTRACTS The phosphorylation of forrocene derivativas was o*rrW out as foLlawst
X X
3 Fe
4. Pci, F P Fe P=:O
where X ia a substituent. The products were studied by thin-layer chromatography on,
abimina and by means of IR spectra. The following contpounds woro thus ay!0ihqstzqcr1 for
the first timel (a) tris(o-carbomethoxybenzy1farrocanylen?lplSqRhina
y-leld); (b) trio (tert'-butylferrocarqlene?phosphine oxide (~37, Y1e!A)i-Tc-T-tk9(pherq1-
ferrocenylens)phosphine oxide (14% yield). Sulfonation of trio (tart-butylferroceny*-
Card 112 UDG:

042 62-67 EWT(I)/EWT(m)/EWP(j)/r/EWP(k)/EWP(l) IJP(c) WG/RTWA01
ACC NR3 AP6030020 SOURCE CODE: UR/0020/66/169/005/1083)1M
Dyoryantseva,, G. G.; Yur'yeva, L. P.; Portnova, S. L.; Sheynker, Yu. m"
JAU'rHOR:
',Mesmey!=.Aa. (Academician)
IORG: Institute of Chemistry of Natural Ccmpounds, Academy of Sciences SSSR (Institut 1
khimii prirodnykh soyedineniy Akademii nauk SSSR); Institute of Heter*-Orzanic Com-
1pounds, Acade of Sciences SSSR (Institut elementoorganicheskikh soedenineniy Akade-
5Y_
TITLE: Proton magnetic resonance spectra of disubstituted ferrocenes
SOURCE- AN SSSR. Doklady, v. 169, no. 5, 1966, 1083-1086
TOPIC TAGS: proton resonance, farrocene. analytic chemistry, spectrum analysis
ABSTRACT: The proton magnetic resonance spectra of 25 heteroannular disubstituted
ferrocenes with various substituents in both rings were taken and the rule of additi-
vity of chemical shifts of the ring protons was established. The structure of several
hi,nzoannular isometric amids of methyl- and ethylphenyl-ferrocene carboxylic acids and
nitriles of ethyl- and phenyl ferrocene carboxylic acids was defined on the basis of
the PHR spectra. The PHR spectra were measured using 10% solutions in CC14 and CDClj
and a JNHC-60 spectrometer with an operating frequency of 60 megacycles. In all cases
excellent agreement was observed between the experimentally determined chemical shifts
UDC: 538.113t547.13+546.72
Card 1/2

L 04262-67
AOCN'R, AP6030020
I
v 1
1
for the ring protow and the chemical shifts calculated using the additivity ru2e.
Orig. art. has: 2 tables.
SUB CODE: 07/
SEEM DATE: 12Feb66/ ORIG REF; 004/ OTH REF: 003
2/2 fv

ACC NRs APMUDuMi SOURCE CODE: UR/0062/66/0001007/1252/1292
AUTHOR: Nesmeyanov, A. N.; Anisimov, K. N.; Koloboya, N. Ye.; Skripkin, V. V.
ORG: Institute of fleteroorganic Compounds Academy of Sciences USSR (Institut
Ielementoorganicheskikh soyedineniy AN SSSRI
TITIE: Bi- and polymetallic compounds with a Fe-Sn bond and their derivatives
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 7, 1966, 1292
TOPIC TAGS: organotin compound, organoiron compound
ABSTRACT: The reaction of &41., G6Y3 SnC1 3 , and (Cdl 5)2bbC'2 with
Na~Fe(CO)2C5 H5in tatrahydrofuran yielded ~i-c 5H5 Fe(00)2]j"Sn (1).
r i-C K Fe(GO) J3 %G 6H5 (11). and(pi-C3H3FO(CO)212 Sn(Ce,), (III).
V 5 5
Hydrochlorination of (II) and (111) in carbon tetra-chloride yielded the
1mo-MI X.5Fe(C0)A 1%C120 The latter was used to prepare a series.
[pi-C5 2
of compounds with various functional groups on the tin atomo These
colored compounds were characterizedo Most were obtained in high or
quantitative yields. Orig. art. has: 1 table- 1JPRS: 38#9671
SUB CODE: 07 / SUBM DATE: 05ffay66 / OTH FM:. 001
+ 546o72 + 546.81

ACC NR.- AP701242D SOURCK OUDS: UR1006Z,!66100G'.'O1L,1938iL943
AUTHOR: Nesmeyanov, A. H.; Perevalova, C. G. Tyurin, V. D.; Gubin, S. P.
ORG: Fbscow State University Im. H. V. Lamonosay (MoskmMy gasudarstvennyy
universitet)
TITLE: Metallattan ot alkyiCerrocenes
SOURCE: AN SSSR. lavestlya. Serlya khlmtcheskay;a, no. 11, 1966, 193 -194
8 3
TOPIC T=: ferrocene, lithium compound,, forracenyllithium
SUB CODS: 07
-proWiferrocene with
The Metallation of metilyl-l ethyr-p and n
ABSTRACT:
lexcess n-butyllithium at room temperature was studied. mixtures of mono- and
dimetallated, alkylferrocenes were obtained. The monometallated alkAferrOl2enes
Were found to possess a heteroannular structure- The mixture Of mono- a"d dimet-'
allated alkylferrocenes, after carboxylation,*vere converted to a mixture of
and dicarboxylic act,48- Met&1lation of alkylferrocenes proceeded With
mono
~greater di .1 that of ferrocene itself. Approximately 2-2-5 times as
iculty tha,
ff
rw va llated
much of 'the monometallated, alkylfer ene s formed as of the dimeta
jvZ.. 7de metallArAd allqrlferrocenes were also used for the synthesis
derivat
of heteroannular nitroaliqlfer=Cenes by the reaction. vith propyl nitrate-
re obtained in low
I,Ihyl-,, nitroethyl-,, apd nitr. Propy1ferroceneg we
_0
UDCt 542o91 + 547.113 + 346.72
Card
0732- 135(P

- - -

ACC. NR-- AP7012421 SOURCE CODE: UR/00621661'000!011 2017/2GL9
AUTHOR: Nesmayanov
_ff.; Satonova, V. A.; Zudkova, G. I# Isayeva, L. S.
ORG: Moscow State University In. M. V. Lamonosov (Jfoskovskly gosudarstvennyy
universitet)
TITIZ: Alpha-ferrocenylcarbanium salts
SOURCE: AN SSSR. Izvestlya. Serlya khtnicheskaya, no# 11, 1966, 2017-2019
TOPIC TAGS: hydrolysis, dimethylamins, acetic acid, Inorganic salt
SUB CODE: 07
ABSTRACT: The ifirluencie or the dImethylaraLrio' 'group, situated in the p-position
of the'benzene ring.bonded to a carbonium carbon upon the stability and reactiv-
ity of alpha-ferracenylphenylearbonium salts was investigated. 7hree salts
were synthesized from the corresponding carbinols and tetraphenylborosodium in
glacial acetic acid. Such salts uere more stable than the carbonium salts
'not containing the dimethylamino group. Hydrolysis of phenylferrocenyl- and
.diphany1ferroceny1carbonium tetmphenylborates is Instantaneous, Vaereas the
corresponding tetraphenylbomtes containing the dimethylamino group are re-
covered unchanged. Other reactions of the salts syntaesized. were studied:
.W~"Lon of dimethylanillne in the p-positlon;yea~q!~Ions vith piperidine
Card 1/2

0

ACC NR. AP7011357
SOURCE CODE: UPJ0062/66/000/010/1871/1671
AUTHOR: Chapovskiyq Yu. A.
ORG: Institute of Iletero-Organic Compounds, Academy of Sciences WSR
(Institut elanenroorganicheskikh soyedinenly AN SSSR)
TITLE: Stable iron hydride C5H5Fe/P(0C6H5)3/2H
SOURCE: AN sssR. rwostiya. Seriya khimicheskaya, no. 10, 1966,
1871,
TOPIC TAGS: kqxlrids# iron compound, UV irradiation, iodide, sodium amalgam
SUB CODE: 07
ABSTRACT: It is shown that ultraviolet irradiation of a mixture of
CSHSFe(CO)2I with triphenylphosphite results in eXchange of both carbonYl
ligands with the formation of CSHSFefp(OCOH )3121 This iodide reacts with
sodium amalgam to form the hydride CsHsFeLROC~HSi312H. DpFG: 40,35t7
Card I/ UDC: 541.44+546.72
017.3/ 't .7 $-1 9e

ACC NR: M"7012431 SOURCE CODE: UR/0062/66/006/00811467tL469.
AUTHOR: Nesmeyanav, A. N. Perevalova, E. G.; Yurlyeva, L. P.; Gosteyeva, G. N.
ORGt Institute of Hoteroorganic Compounds, AN $SSit (Institut elementoorgenicheskikh
soyedinenly A14 SSSX)
TITLE: Synthesis of nitrites of phenylfarracenecarboxylic acids
SOURCE: AN SSSR, lavestiyes Sertya khIMIChaskaya. noo S. 19660 1467-1469
TOPIC TAGS: organic nitrite compound, chemical separation, phony Iforrocenecarboalic
SUB CODE: 07
ABSTRACT: The authors de skribe - an improVei~ent on ad *earlier method for separat-
ing mixtures"of amides of isomeric phenylferrocenecarboxylic acids, prepared by
the hydrolysis of the reaction products of the cyanation of phenylferrocene.
The Individual amides of the isomeric phenylferrocenecarboxylic acids were con-,;
verted. to the corresponding nitrileso 7he nitrile of p-ferracerylbenzoic acid
was also prepared from the amide of y-ferrocenylbenzoic acid and used as a
standard in gas chromatographic analysis of the m1xture of nitriles of 1,2-,
43-, and l,,V-pheny1ferrocanec&rbqvUc acids,:obtained In the cyanati f
X27
pliquy1forrocenok., Orig. art# has: 2 formulas'and 'I tautee DPRS: 40,911 o
$42.91-542.951+621.785.666
1377.

ACC NR~ AP70113'56 SOURCE COE)F.% UK/0062/66/000/0101187011871
AUTHOR,. Nesmayanovv A. N.; Chapovskly, Yu. A.; Ustynyuk, Yu. A.
ORG; Institute of Hetero-Organic Compounds, Academy of Sciences USSR
(Institut elementoorganicheskikh soyedinaniy AN SSSR)
TITLZ: Splitting of the Fo-C bond In the exchange reaction of the carbonyl
limazid of C )37d6H5 for triphenylphosphits
0 05FOOO)NOCA
SOURCE: AN SSSR. Izvestlya. Serlya khtmichaskaya, no. 10, 1966,
1670-1871
TOPIC TAGS: exchange reaction, carbon compound, nuclear magnetic resonance, mass
spectroscopy. M spectroscopy
SU3 CODE:
ABSTRACT: The authors used nuclear magnetic resonance, infrar-ed and mass
spectroscopy for studying the product of interaction between
C5H5Fe(C0)1F(0CGH5)3]C6H5 and triphenylphosphite under ultraviolet radia-
tion. Me results show a single cyclopentadienyl and two triphenylphosphite
ligands per iron atom with no carbonyl ligands. This, together with the
diamagnetiGM of the resultant compound indicate the dimer structure
(C5H5Fe[?(OCGH5)312)2. However, data of x-ray analysis are needed for a
final conelusion. A CJPRS: ' 40',35D,
Card UDC: 541.57+542.957+547.2+547.241
I - . --- 9. 9131 /7-5 7

ACC NR: 41?7013158 SOURCE CODE: UR/0062/66.iGOO,'012 2209:2211
AUT14OR: Nesmayanov, A. N.*,' Ferovalova, S. G.; Tsiskarifto, T. T.
ORG: Moscow State University Im. H. V. Lowonosov (Moskovskly gosudarstvennyy
universitet)
TITLE: Ditferocanoyl and L,2-differacenylethylene
SOURCS: AN SSSR. Izvestlya. Seriya khimichaskaya, no. 12, 1966, 2209-2211
TOPIC TAGS: ethane, ferrocene, oxidation reduction reaction
SUB CODE: 07
ABSTRACT: *The oxidation Of 1,2-dif&rro~enylethane with mariga--ese dioxide war.
found to result in a mixture of diferrocenoyl, and trans-l,,2-dife,-racenyle,'hylene..
The ratio of the diketone and unsaturated compound in the oxidation products
depended upon the reaction conditions. 1,2-diferracenylethylene predominated
at room temperature.. whereas diferrocenoyl predominated when the mixture was
heated. The oxidation of 1,2-diferracenylethane with KiO is recommended as
a simple wathod for synthesizing diferrOcenoyl and 1,2-0errocenylethylene.
-Diferrocenoyl is not oxidized by Mn02- It forms derivatives with hydroxyla-
.mine and 2,4-dinitropheny1hydrazine and reacts with organomagnesium, compounds
such as n-propyl magnesium. bromide with only one carbonyl group. Oaly in the
reduction of diferrocenoyl with lt-uhium alumimua hydride do both carbonyl
cord V 2 UDCe..- 547ol*3:546.72
07373 01372-
----------

ACC NRt AP7013153
groups react, to yield 1,2-diferrocenylethanediol-1,20. Diferracenoyl does not
undergo a benzil-type rearmnSement. The 1,2-diferrocenylethylene produced
in the oxidation of 1,2-diferrocenylethane vas found to be the transisomer.
Oxidatioa of this compound under the conditions of. oxidatioa of 1,2-diferro-
,nylethari
ce yie4led dife cenoyl and ferrocene 41doyde!. Oria. art. has: 5
formulas. ryn
ORS: 40,42T2
0

ACC NRt AP7013160
SOURCE COM UR/0062i66/00o 012!2239!2240
AUTHOR: Shilovtseva, L. S%; Ferevalova, E.; Nefedav, V. A.; Nesmeyanov. A. N.
GRG: Moscow State Untversit~ in. M. V. lamnosov (J~bskovskly gosudarstvennyy
univorsitet)
TITLE: Aminamethylation of ethylferrocene
SOURCE: AN SSSR. Izvestiya. Seriya khimlcheskaya, no. 12, 1966, 2239-2240
70PIC TAGS: methYlation, ferragene
SUB CODE: 07
- Mie diii4thylamin
AB~TRACT:., a of ethyl~errocene - ir~'-dbndudted with
7;,N,N W-tetramethylAiamin thane. 1,2-,1,3-, and l,1'-(NA-djrethyjamjno=-
,ethyl;ethylferracenes (total yield aWrOximmtelY 70% of the theoretical) and 1
11-di NN-dimethylaminowthyl)-2--thylferrocene and lSl'-d:L(X,N-dIwthylaminom-
ethyl)-3-ethy1ferrocene (total yiel(I about 7%) were isolated from the reaction
products. The products were characterized,, and their atructures studied accord.,
ing to their absorption capacity and infrared spectra. Me yield of the homa-
annular isomers was aPPr0xiMtC1Y fOur times as great*as that of the hetero-
annular isomers. The ratio of 1,3-is *omers to 1,p2-isomers was'approximately
3:1. both-for the monQ-and for. the diamines. ~f.values for the isomers obtained
Cacd ILI2 UDC: 542.958.3 + 547.1#13 + 546.72
0?33 0374

ACC NR: AP7013160
are cited ior chrocatography an alumina lo
pregnated with formaoldo.
Orig. art. hast I table. LJ'PRS: 40,422-1

ACC NRs AP7013161 SOURC& CODE: UR.10062166,'000.012?2246'2246
AUTHOR; Nesneyanov, A. N.; Anislwv, K. N.; Kolobova, N. Ye.; Denisov, F. S.
ORG: histitute of fleterorganic Compounds, AN SSSR (Institut clementoorgunicheskikh
soyedineniy AN SSSR)
TITLE: Synthesis of pi-Cyclopentadienyldicarbonylirontrichlorogermane and
pi-Cyclopentadianyldicarbonyltrondichloregercane
SOURCE: AN SSSR. Izvestiya. Serlya khtmicheskaya, no. 12, 1966, 2246
TOPIC TAM: gerritantun c,ow-pound, chlorinated organic compound, organic
chenical synthesis'
sUa CoDe-.: 07
ABSTRACT: Pi-C~'o-16pentadienyldi'carbonylirontrichlOrOgerulanc (I) was synthesizied
,V.ithe reaction of pi-CYClOPentadienYld-icarbonyliran chloride vith HGeCl 3*
was also produced in a Mix-
lCompound (I), an air-stable crystalline substancei rane (II) in low yield
.ture with pi-CyclopentadienYldicarbOnY)LirOndichlOroge
.by the action of trichlorogermane upoa dimer pi-cycloi3entadienylirondicai~ooiiyl,
Me compound (1j) was also produced in 85% yield by the reaction of a complex
of dio=ne.and germanium dichloride on dimer pi-eyelopentadie~nylirond:LcarbOnYl-
card 1/2 UDC: 542. 91 + 547 113

- - - - - - - - - - - - - - - - - -
ACC NR-- AP7013161
COmPound (10 is an orange crystalline substance, stable in air. Both (1)
and (11) were characterized, and their'Infrared and nuclear magnetic resonance
'7
spectra were taken. Orig. arts has: I formulae n: 40,422
Lip

NESMEYANOV, A.IN., Doe Chem Sci -- (diss) wMeasi ring t4
steam pressure of solids and their binary alloys
C% 05
by the method of radioactive indicatAwe.tl Mas 1958,
27 pp. (Mos Order of Lenin and order of Labor Red
Banner State Univ im V.V. Lomonosov. Chem Faculty.
Chair of:lnorganic Chemistry. Laboratory of Radio-
chemistry) 130 copies. Bibliography at end of text
(22 titles). (KL, 39-56) 107)
- 9 -

NE-smEoilott AM,
PHASE X TREASURE ISLAND BIBLIOGRAPHICAL REPORT AID 681 - X
(Supersedes AID 681 - 1)
BOOK Call No.: AF645591
g-SMANOV, LAPITSKIYO A. V.s and RUDENNO.N. P.
Authors: Ng~ ~,j ft
Full Title-!- N OF JOISOTOPES
Transliterated Title: Polucheniye radIoaktjvnykh izotopov
PUBLISHING DATA
Originating Agency: None
Publishing House: State Scientific and Technical Publishing House
of Chemical Literature
Date: 1954 NO,PP,: 193 No. of copies: 100000
Editorl4l Staff: None
PURPOSE AND EVALUATION: This book Is designed for research workers
interested In nuclear chemistry and physics and In the application
of the method of tagged atoms. The material Is organized clearly
and oonalsely and Is brought up to date. The text Is amply
illustrated with formulas, diagrams* and tables. Of great value
is the extensive bibliography (2089 references). This volume may
be favorably compare4 with books on the produotion of isotopes
published In the U.S.
TEXT DATA
Coverage: Mendeleyev's perlodia system and the diffieulties
.arising in the olassifloation, of elements with the atomic
1/3

Polucheniie radioaktivn7kh izotopov AID 681 - X
numbers 93-99 are discussed In the introduction. The book con-
sists of two parts. Part 1. based on monographs and papers
published during 1932-1952, gives a brief survey of the
theoretical principles which served as a basis for the develop-
ment of methods of production and isolation of radioelements.
The sources of natural and artificial radloelements are 14dicated.
Chapter V is devoted to the description of simple methods of
production of Isotopes which may be used as tagged atoms. The
yields are compiled in a table. Part 11 consists of a table of
Isotopes.where data on the production and properties of isotopes
are coinpiled from papers published in Soviet and non-Soviet
periodkoalsover the period of 1934-1954. An explicit and clear
explarfAtion precedes the tablee Chapter V11 consists of decay
schemes for.radioisotopes, including a general scheme explaining
all symbols. The highlights of the book are the clarity and
simplicity of the theoretical presentations and the table of
Isotopes encompassini the latest data,, so that this volume may
serve as a guide for'research warkers active In this specialized
fidlde
2/3
0'10~~on~of'Any _Ra-
II1.'irod`uc'ts" lement 188
Of Numbers Multiplied by 64 189
We Products Of Numbers Multiplied by 16 191
Vo Series of Radioactive Transformations 192
No. of References: 2089 (80 Russian: 1935-1953)
Facilities: Some Russian scientists are mentioned
3/3