SCIENTIFIC ABSTRACT NEFEDOV, O. M. - NEFEDOV, V. B.

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SCIENTIFIC ABSTRACT
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86W Production of Aryl Halides From Aromatic 3/020/60/1'3/0,~4,058iO40XX Hydroxy CompDunds B016/BO54 as of the ArX produced, on the basis of thE authors' data and pubilcations There are 1 table and 8 referencesi ; SOVILEt, I US, 5 German, rind 1 Indian. ASSOCIATIONi Institut organicheskoy khimii im. N. D. Zelinaxogo Akademil nauk SSSR (Institute of Orgaric ftemistry imeni N. D. Zelinakiy of the Acaden.y of' Sciences, USSR) SUBMITTED: April 25, 1960 Card 4/4 PETROV, A.D.1 MEMOV, O.M.; IXVKGV, Ya.L.; SHMUK, T.Yu. Alkylation of benzene with 2-cy-clohaxylcyclohexanol in the premnce Of AlC13- Neftekhimla 1 no-3062-3619 *.r-J* 161. (MTRA 16:11) 1. Institut organicheakay khimli U SSSR imeni Zelinskago. PETROV, A.D.; NFIWOV, O.M.; KOLESNIKOV, S.P. Synthesis and pyrolysis of 1-subittituted 7, 7-dich.Loronorcaranes. 7Amr.VKHO 6 no.4t471-1+72 061. (MIRA 14:7) 1. Inutitut organicheakoy khimii imeai N.D.Zeliwkogo AN SSSR. (Norcaransi) 27497 S/062/61,/OOO/0C9/G1 3/014 B1 17/B1 01 AUTHORS: Nefedov, 0. M., Manakov, M. N., and Petrov, A. D. TITLE: lieu method of preparinf; cyclic organo-silicon compounds PERIODICAL: Akademiya nauk SSSR. 'Zzvestiya. G%deleniye kh,-T'1,-ne8K1Kt, nauk, no. 9, 1961 , 171 It TEXT: The present letter to the editors reports the following: It was found that the reaction of dimethyl-dichloro silane with lithium in tetrahjdrcfuran (THF) at 100-70uC in the presence of styrene (2 mole to 1 mole (CH )2S'C'2) gives diphenyl-dimethyl silicacyclopentane (probably a mixture of isomers) in 30-505/t yield.; b.p. 1270-1290C (0.2 mm Hg) and 1560-1370C (0.2 mm fig), n-'O 1.5722-1-5759, d20 1.0077-1-0135, found MR D 4 86.99-87.20, calculated MR 86.69, found mol.wt. (cryoscopically in benzene) 262; 257; calculated mol.wt. 266. Found: C 81.02, 80.jC, H a.6o, 8.32, Si 10-40, 10-431/6- CiEl 322 Si calculated, C 81-11~, H Es 32, Si 10.53%. Together with this compound, a considerable amount of a Card 1/4 27497 S/06 (o/OOC/cCq/~'3/C'4' New method of preparing BI 17YBI 01 resinous silicon-containing polymer of probable structure CH 1 3 1 1 Si C_ C I C If3 -In is formed. It is easily soluble in watert acetone, and other solvents This reaction which was discovered by the authorH proceeds in a similar manner with styrene derivatives vinyl naphthalenits, divinyl benzene and methyl methacrylate. Under the same conditions, but in absence of unsaturated compounds, the main reantion product is the high-molecuiar polydimeth:ll silylene [>Si(CH 3)2]no obtained in 65-"5% yield. m.~ 3400-3450C (under decomposition). It exhibits a mu(.h higher res,.stance t~, thermal oxidation than a similar polymer obtained from (CH \ SiCl, and sodium in benzene (2000C, 15-20 atm) (Ref. 1. see oelow, It is assumed that the reactions described involve dimethyl silylane, a silicon analog of the carbene compounds, as an intermediate; Li LiCl (CH ) Sici ___ ) (CH ) SiLiC.1l (CH 3 2 2 TIff 3 2 3)2S'~ Card 2/4 27L97 S/062/61/000/009/013/014 New method of preparing ... B110101 In the absence of alkenes the latter is polymerized to 1>Si(CH 3 2-1 n. In the presence of alkenes , dimethy. s:.lylone probably adds to the double bond with formation of unstable ail-.con analogs of cyclopropane of the corresponding diradicals. These th,3n form derivatives of silicacyclopentane and polymers by reaction with excess alkene: C/ C: fa or C CH \~C-C/ 11 +: Si (CI 1,), -I \si/ \SI/ C C/ \C 4, CHS C---c \ /01 I- Si + C C/ \(:H: ~bstracterlq note: Complete trana-.ation.-! There is I : )n-Soviet reference. '"'hin reforence tc English-language publicuti,j.is reads as follows: C. A. Burkhard, J. Am. Chein. Soc. 11 )6 (1949); pat. USA 2554976, 2j. V. 1)51; Chem. At)etr. A.~, 880 (1951 - Card 3/4 Z7 497 S/06 61 /,~G C/OC)9/01 ~' / ~- 14 New method of preparinC ... 311 7~31 Gl ASSOCIATION: Institut organichetikoy khimii im. N. D. Zelinskogo Ayalemii nauk SSSR (Institu';e of Organic Chemistry imeni N. D. ZelinBkiy of the Auademy of Sciences USSR) SUBMITTED: June 27, 19o1 Card 4/4 nEFEDOV, O.M.; IVASHENKO, A.A.; MANAKOV, M.N.; SEIRYAYES, V.I.; PRETW A.D. New metbod of preparing carbones. Izv. All SSSR Otd.khim.nauk no.2:367 P 162. (YLIRA 15:2) L Institut organicheskoy khimii im. N.D.Zelinakogo AN SSO. (Carbenes) me 5/06 62/000/007/006/013 B1 17YB 180 AUTHORSt Nefedov, 0. M., Manskov, M. N., and Petrov, A. D. TITLEs Synthesis of substituted 1,1-dialkyl silica oyclopentanes from dialkyl dichlorosilanes and styrenes PERIODICAL: Akademiya nauk S55B. Izvestiya. Otdeleniye khimioheskikh nauk, no- 7, 1962, 1226 - 1237 TEXTj The reaction of dialkyl tlichlorosilane ard aryl ethylene with alkali metals (lithium, sodium) in an inert solvent is here described, an a new method of synthesizing aryl-aubstituted 1,1-dialkyl silica cyclo- pentanes (30-75%). The reaction set in immediately with considerable heat evolution when a mixture of aryl ethylene and dimethyl dichlorosilane was slowly added to lithium in tetrahydrofuran. The reaction with sodium was less vigorous. Diethyl ether or benzene iwitead of tetrahydrofuran decelerated the reaction, but hardly affected the yield (55 - 50) of the end products. In addition to silica oyclopentanes, polymers with silicon atoms in the principal chain slio formed during the above reaction (yield uP to 704). (Their composition and structure will be studied in detail.) Card 1/2 3/062/62/000/007/006/013 Synthesis of substituted... B117/B180 These polymers were the main products obtained by the reaction of di- ahlorosilenes and conjugate dienee (e.g., piperilene) with alkali metula (Li, Na). As a possible mechar.ism of the formation of silica cyolo- pentanes, the reaction of dichlorosilane with dilithium derivatives of styrolene and their dimere (reaction A) is suggested, or possibly that of dichlorosilane with the I'dimerizing" adduct of lithium to styrene (reac- -ion B) are suggested or the oarbenoid meohnnism. Synth*siied aryl- substituted silioa eydopentanes might possibly be used as monomers for the synthesis of chemically and heat resistant polymers but this has not yet been confirmed by experiment. rhere are 1 figure and 1 table. ASSOCIATIONs Inatitut organicheakoy khimii Im. N. D. Zelinskogo Akademii nauk SSBR (institute of Organic Chemistry imeni N. D. Zelindkiy of the Academy of Sciences USSR) SUBMITTEDs January 26, 1962 Card 2/2 q-,.WFljm, %.:~j . , '.. . . I A rf.,~&r~~.ns43 ' - m - ' 'J ' c - r:,, ~ a linrl M-! '!,., )-l- ---- " 'kpir. ,r,,. o(f.,r- I "I 1." 1107 1 - ~. I ~MJ~ 9;1.) 1. 1,11 a.! *.,I '~ 07',"1r, : - '1' S K JY A r, I Tr-' I'. M.- , N i; . , " ~ . F' F Kng-) A N ., "71"1!( . MMOVS O.M.; MLNAXOW,, M.N.; IVASHENYOp A..A. Addition of diablorocarbons to sons I-subotituted 1-cyclohexerina. Izv.AM SSSR.Otd.khim.nauk no.7tL!42-1248 JI 162. (IMilL 15z7) I 1. Institut orgiudcheskoy khimii Lm. N.D.Zolinskogo All SSSR. (Carrbenes) (Cyclohexons) N9FSMv O.K.; SHIRLLYEV, V.I.; PETROV, A.D. Phewfl carb)ns from phanylUthium and methylene chloride. Zkur.ob.khiia. 32 no.2:662-663 F 162. (MLU 15:2) 1. Institut organicheskoy IdJzii imeni N.D. Zelinskogo All SSSR. (Carbow) '(Lithium) (Moth's )J,542 S/02 62/147/006/025/034 B144YB101 AUTHORS: pgfeday, 0. hl., Manakov, M. N., Petrovo A. D., Corresponding Member AS USSR TITLE: OrFanolithjum synthesis of germanium hydrocarbon compounds from dimethyl dichloro germane. Some reactions with ,~'CH 02 C,e aj a possible intermediate product PERIODICAL: Akadem.ya nauk 5S3R. Doklady, v. 147, no. 6, 1962, 1576-1M TEXT: "CH 3 )2 GeCl2i4nich behaves like (C11 02 Sicl2 combines with Li dissolved in tetrahyirofuran (I) at 20 - 450C to form a cyclic hexamer, 1 0 i(CH ) Ge-' easily soluble in organic solventel m.p. 211 - 21.3 C; 3 2 , ,69 yield up to 8W.. At --Or-C, ICII ) Ge, k 3 2 1, !n , a strongly hydropnobic compound similar to polydime1hyl germylene and insoluble in organic solvents was also obtained; m.p. 200 240OC; yield 49%. Reaction scheme: 2nLi -nLiCl n(CH ) GeCl > n(CH Gq(Li)Cl n(CH ) Go: ,~(CH ) Go' 3 2 2 - 3 2 3 2 L 5 2 in' Card 1/5 nLiCl S1020162114 71 /006/D2 3/0 54 Organolithium synthesis of B144/B101 (CH GeCl styrene, and Li 'molar ratio 1 : 2 : 4) in I yields the 2 2 P k following producto ihen stirred violently at-,OOC-. (1) X,X'-diphenyl-1,1- dimethyl germanacycloperitanel yield 40.5,A, b.p. 140 - 1410CIO.2 mm Hg; n20 1-59201 d 20 1 . 11)86 (2) A polymer with the genexal structure D c if Ge-(-C-C-) w-,icri iq easily soluble in other, 1, and benzene ; after N 1 1 k n 3 twofoll reprecipitation with methanol a white powder in obtained m.p. 74 - 890C; mclecular weight 2'1,90, 2960. Substitution of vinyl toluene for styreno yields 45% X,V-ditolyl-1,1-dimethyl germanacyclo- pentane under othe::-wise equal condJtionnj b.p. 150 - 151 0C/0.18 Mm lig; n20 1.582',; d20 1.1346. The melting point of the :linear polymer obtained D 4 by reprecipitation was oetween 58 and 700C, and its molecular weight was 1260, 1220. The course of the reaction as given shoos that the products Card 2/ 3 3102 62/147/006/023/034 Organolithium Byntheois of B144YB101 obtained from Li and styrene with (CH 02 GeCl 21 ~nd also the intermediate product (CIT5 )2 Ge: react immediately with C 6 H5CH-CH 2' The s.ructure of the resulting compounds and their similarity with the corresponding silicon oompounJe were confirmed by the 1H apectra. There is I figure. ASSOCIATION: Institut organicheakoy khimii im. N.D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni v N.D. Zelinskiy of the Academy of Sciences USSR) SUBMITTED: Septem'oer 26, 1962 Card 5/3 MEMOV9 O.M.t NAKWII-q AND PETfVVg A.D. ---------- Inmugatift of the reaction of ortanobalides of silicon and proanim with IlUdva and its compo nds. Report to be sutvdtt*d for the Second Dresden 3yuposium on Organic and non-silicate silicon chemistry, from 26-30 YArth 63,p Kaxt Germw Imt1tute for organic chemistry of the Acadepry of Science of the USSR, Mn9cow. ir 17i ~i Vt X NP at "rivauvow. ps zoole 46 wit i 4r-,t,':~,`,l; %o _-6 16 Ones: Was as lili~ '.a -'r4kdl4tlilN stabilit 4!!M* I" yo vj a A, -oil dmc -K, H C~ w4 to %r*,, USA -86# dkC50 C an eycl*,h*xma*l Wltft -10 son* .1 J wa,i 3/401/0000tj ~.-J W-94436 -03909 FIN, !*Pbthn]L one A00117,21. pr- 6 A*'Jif ti ijejLd. tmw sq. 40 erjlljj~ N - -- ~Iv A dit JLOO:to 2000 Ju in c ILCIL Sy, st"Y:Lor" N4 uss-4 the C&t&]LytL lio"") 4. "Us~` O'.44emLy'. Ake** 4-o 941mrim. P. ed, hy&ec4m,rb"s: ere b elk** P_AX:V SIM. 4~n _;4, ry~ OUX"ald Rp g~ A, NI Av grm k ;k :~7 4 il . I A13 Fv A WE JI: n i as ~~110488*4114 over- "ACW"i it 4bomt, 6Wf 4L&FA Pont a AlA With M"j a jai.* 4~1 S U.,M) Z 77 NEFEDOV, O.M.; KOLFZNIKOV, 6.P. Ethera*eB of *.richlorogermane. lzv. Ali SSSR. Ser. )rhim. no.Uz 2068 N 163, (MIRA 17zl) 1. Inatitut organicheakoy khimll Imeni N.D. Zelinakogo AN SSSR. S/38 63/014/033/015/020 B102%1s6 AUTTIORSt Sevastlyanov, Yu. G., Bulan3v, L. A., Kaj,lan, Ye. Nefedov,_O. 111., 3mirnov-Averin, A. P. TIT:2: An activation method for juantitative determination of organically bound sulfur im.Durities in polyphenyls PERIODICALs Atomnaya energiya, v. 14, no. 5, 1963, 324 - 326 TEXT: A great disadvantage of usir.(7 pol.iphenyls as coolants and moderators in power reactors is their co.-itent of sulfur imp.-urities (due to the Droduction conditions). S 32 chan;7es over into P32 in fast-neutron induced (n,p) reactions, while P 52 emits betas of 1.7 ~Iev and renders the coolant regeneration difficult; moreover, sulfur reacts with the tube material to form metal salfides 7hich ca-ise corrosion. In order to determine the S32 content an activation taethod based on the S32 (n,p)P 32 reaction was developed. The P32 activitj is determined on comparison with a roference standarl (pure Na,Q10 ), the irradiation (total 101 a n,cm) 4 Card 1/2 3/08 63/014/003/015/020 An activation method for ... B102YB186 taking 26 - 28 hrsj between irradiation and analysis a period of 7 - 10 days was used for complete decay of Na24. The indu?ed activity was m9asured with an end-window countor iith a 78 mg/cm aluminum filter. I content of - 0.1 ~'t S ir a batch of 10 - 20 mg was found to correspond to -j3OOO pulses/min, Consequently, when the irradiation time can be raised 3 to 5 times, quantities of 0.001 - 0.0005 7-Ij S can even be determined. The sensitivity can be further increased by concentrating the sample. There is 1 table. SUBYITTED: March 1C, 1962 Card 2/2 ft~' PRIOW AWY /VFOO~; 3 -1; 4 - . . . - . Y. '/05 'ij*0/63AV 55M58 vtO6 P. tap Ila rd YJL~-.& A&IL4 'W J 58 3~ 5554 t ran isdiatlins therma lCo"s. Cal utis. lie larometic Ndwarbonsp naphthaUl'ot or$wylv alkylaWlIphanyls allwlsted terphonylas diphienyl --km aiisii' i. Wuve~ rienUon-nWIAtion Irdlueed I-and phonyl-sub On with, rath ylene bridges -bee PbWowbiphitwi U~iera) fisi~ n stud The sample's were d4ga 't ii 'i st . pyrolysiOat'4WC indicated that: ssed'bsfqrehM4 *.ppovent 'oxidation. udy of I the stltAllty of bip A bMIL,~ ard terphenyls was two to f Me Ordexs above that of Alpha -,the -allgrl- 7L, _4 '09-mm 14. 74 the, Wm6W at, ININ 1111111:114, -the mow stmue to- ~ Iowa pyrolysis or the Im"t stable 1004 Btu d rho -thilk ZWWAUSI d1tap"'p, We lit 11940.450 alid 4%C _'Vore lmljm'-Idsd~ 4W actIvatIm -mrg vvis fand'to be vIth mtbyUns brl4ps at 4100 of PC -their tbm stAllIty.vu thive urftrm below Wk Jxr%m*4uu or Via, _--gregas SA 4 as. cm, a") at 66: WAI vas fctmd to be SIR 13,1 jt&bU at ja_ _tt in it= 60 to of MR Qmm- Alois 101SOMW: It a& famd that the MWV Ic a to Gb=XW.mW Wt surf I* deec""ItIon of b1phowl" that tti~ iupuqxw th*rmi or an st4lUty Amin by bytbe them-Oft-Me, aw agmts for. ~uw-.IW .2gM 0 OrIge art* bas: tow a J, KEFEDOV, O.M.; NOVITSKAYA, N.11.; ITTROV, A.D. Production of cyclopropane- hydrocarbonq by the red,ic*i)n of dihalocarbene Pidducts to )Iefins. Dokl. AN SSSR IV n,~. 1: 629-632 3 163. 'MIRA !~:I;) 1. Institut organicheskoy khindl Im. N.D.belinskopo AN SSSR. 2. Chlen.-korrespondent AN SSSR (for Petrov). NEFEDOV, 0. M.; ?OLESNIKV, S. 1'. Formation and telomerlzation of germanium carhencidD. lzv AN SSSR Ser Kbim no. 4:773-774 Ap '~,4. (M:u 1": 5" 1. Institut nrganlcheskoy khimii Im. N.'~. Zellnskogo AN 3SSR. I WL.:~J 5092112i -0/0066/w.060100,0/0067/0074 ,k m i IK V *DJ(Deceq4ed): ~5 17-1,1 for IM v4i~ Wwches4p -Sintex t -Pll~ 1~ fynUtesiv rag VToporties of ihe era). Moscow, YoNauka, 1964, 67-74 N licoorrgu'l j* auldiM, orpnomeWlic co*vq x"mnd, oaribenoid, si eorspowd 10 '1 p 0 derivati eg,- blorovilane t Oya. v a N -.AB ACT:~- ew4k timple Wlhodls described, ation of carberkes, Ait prepaX &"i r on of I#hjqb~~ith dl-, and pol IWO -acti xw-gmewi a their aryl(alkyl) dM."Uveig - A: unt of tetrshydroWan; at a temperatuxv of -40 td +40C.- So- In -0 oF th 0-- OU NNW, OTI r thus contUtioiWwo7s utilized for thi) preptration of monomer, =4 Dro4hictif I~A now general. me devsIoIxd for the preparation of aryl - - pler rd hu: been Attitaki am th 76-8011, -vbIch oonsista of reacti ng dichl 9111wee lot metals in tbo'presence of aryl-ethylenee or conjugated dienes I n- 71' A V' ji .COST QqAwo--s1l1c enwdbig on polymers with oilloon atoms In the malm obaW': the let a up to 60-90%.- I;uch. polymeTs, but baving a crose-linked structure, weraltilso thii male 'products in the renciion of alkali metals vfth trichlorosilanes and SICI or .11 1-dieneo. T.he indic" reaction can also be apli to shMIii,i~jww4 do* at -~lomevtis in groups -V, Orig. art. has i I tablo &*A A -F 77- Oovfl-004 ri i 7~ ACCE=Cff NE: APW3T24l 6/0062/64/000/005/08W/0844 AUTHOR: Nefedoy,_A"I, Manakov, M. N. TITLE: Reeatioa of d1alkyl(aryl)d1:hlorosi1wes with alkall metals in the presence of conjugated diezve. SOURCE: AN SSSR. Izv. Serlya kbirdaheakVa, no- 5, 1964, SW-844 TOPIC TAGS: dialky1dichlorooilane, diaryldichlorosilane, reaction, conjugated diene,, divinyl substituted silicacyclopentana, unsaturated silicon containing polymr, silicacyclopentena, produclion ABSTRACT: Continuing their earlier works (Izv. AN SSSR OtA. khim. a. 1961, 17171 :~1962,, 1228) the authors investigated the reaction of dialkyl(ax7l)dichlorosilane and conjugated dietoes with alkali mitals in tetrahydrofuran. A mixtuxv of 0.2 M dicb1orosilane (dinethyl-,, diatkWl- or dilpheny1dichloro-silane)o o.4 N them (divinyl, ir-oPremo PlPerYlma) and 4.5 gm Li or 12 gm fla was reacted for 0.5-1 hour at about 30C in 50-200 al absoluto tetrahydrofuren under dry nitrogen. The produat was filtered and the fUtzraloe vwuum fractImated (0.2-0.5 am Kg). Threa types of produats# vWse r*lALt:Lw yJAIA depen" an tAw initial reagmU and ,Card 1/4 ACCESSICU NRj AP4037241 reaction conditions# 03ee Table) were formed: 1--divinyl substituted silicacyclo- pentaaes,, ljD-50% yield; H-unsaturetted silicon hydrocarbon polymera with 9L atcmo in the -gin chain,, molecular weight of 1000 or more; and III-ailicacyclopmtenesp 0-10% Y163A. - RCII- CIIR R'r R"AR" CHR &AeoL R Ii.CHs;R4 011,CHI; R"- CHI, Citle, Cells_- R, 11CII (M) G JR1 CJICII,Nl 4- R; SICI, A 1, Ate. a. R Carg-AN ACCESSICK NR: A114037241 Initial Reagents Reaction Products SilicscYclO- SilicaCY01OPentene Polymer pentene (III) (I) (n) Dichloro- Diene metal vilana Yield Yield Yield Mole gm % gm. gm. Weight 1 Cl13) OiCI~2 Divinyl Lithim Tracen 3-4-7 9-14 22-23 2 CH3 ~ i 213 C12 looprens Lithim, Traceo 10.0 26 22.5 950,1060 CH 3 4 (c 5 ic SiC% 2 Piperylene :Csoprene Lithim Lithim, 0 Trace '0 - Traces 21.6 - 49.5 32 16.5 920,810 5 (C 5 JIC12 ~ 2 [ Zooprene addium 2.7 9 6.9 15-5 23 i 6 (C6H5 2Si% 2 Vipex7lene Lithim 2.1 7 6.2 14 31 1770,1480 -17- (C iC12 Zoopm Lithium Trace - 8.0 l2.5 36 I Orig. arto hast 3 fonaLUa,, 2 tables. Card 3/4 :ACCESSICN NR: Ap4o37241 ASSOC=(Zf: Institut orgmichealcoy khIml I im. N. D. Zelinak Akadomll riatile 0 SSSR (Institute of Organic Chmialryp AcadeaW of Sciences MST SMUT=): 26oct62 ENCL: 00 SUB CODE: OC NO EW SGVt 004 004 Card '14 40 'ADM Ova i :1A pro"ruto-o ra 0 32 19% ;W-:*-2U& f, it~% ZI wtj ;Core mai lfoi*Awo co "41 Wiii '4ii6iiii- 04 of, N. Irl ~Mf V. ra- o c j4~~6-- vi" setabi nh~i ompo%wls, *me ri4dilrveduoad to Vw aorr"pandia; amines iihuo r Id thrO4#1 Ah* *A) -4 titti" yie or-, U d ii; Spoo Tide.- rodlwit* y- It tolated to itto stru *Ulti ik 15foorau, Uld -car ua'~ C*tvm car *Uw* fulpos"ari, Gafto ou" 1-~- is al"Offl.01-mt M a r r Er I- i:sw Milo 4.i A 'F-." 77-1 Of" -:6h) -12 "Rli Az r~.;t~; 71! ii 441 1 4 OT 51 A 41:5*114 j~ "J t 'i4 S' NVEDOV, O.M.;I.WIAXOV, M.P. -- ?o-rmation of reactions of ailylenes, silicon analogs of carbanes. Zhur. ob. khim. 34 noo7t2465-2467 J1 164 (MIRA 17:8) 1. Irstitut orgaricheskoy kh-imii imeni N.D.Zelinskagc AN SSSR. ACCESSrON Nr,-., AP4012091 S/0020/64/154/002/0395/0397 AUTHORS: Nefedov, O.M.; Nanakov, M.N.; Petrov, A.D. (Corresponding mosber), - -, ,, TITLEt Mechanism or formation of aryl-substitut*d allacyclopentanos front organodichloroallanes, styrenes and lithium. Now method for obtaining substituted disilacyclohexanes. SOURCEt AN SSSR. Doklady*, v. 154, no. 2,, 1964, 395-397 TOPI.-. TAOS: aryl substituted t;11acyclopertane, substituted disilacyclobexane, biradical intermediate, bilonic Intermediate, 1, 4--disilaoyclohexane, reaction mechanism ABSTRACT: 'Olmethyldiohlorosilane and styrene (1:1) were reacted in tetrahydrorwran diluted with n-heptane (1:1) to form a d1mer--X,X' -diphonyl-1,4*4-tetramethyl-1,4-disilacycloho3ano#,.Ln 30% ield. The biradical C6H5CHCH23r% (r) or the bilon C6HSCHCH231R2 (115 are both possible intermediates. Siallar disilacyclob*xanes are obtained from styrene and other org-madichlorallanes, and from dImthy1dich- Card 1/12 ACCESSION NR: AP4012091 lorosilane 4nd alpha-mothyl-styrene or atilbene. X,,Xl-bletrimethyl- 3ilyl-1,1,4,4..tetramethyl-1.4-disilacyclohexans was obtained in 26% y1eld from diisethy1diahlorosilane, vinyltrimethylailane and lithium. IR spectra and chemical degradetion helped determine that 1,,2- disilacyclotie.canes were not formed. It is shown that intermediate bir-adicals and bilons similar to I and 11 are formed by either of the following routes: 21.f -LJCI effe-c"C."o R*SiCll:-- Ra& (U) C1 - RSl-.- CIHICII SOCHI 1~1 C, If CH (U) CHO R-SIC1. 1 A-4 11. -2LI-Cl "(IR spectra were) taken by L.A. Leytes on the UR-10 spectrometer In IS a solid solution of XBr . Orig. art. has: 1 figure and 4 equations. ASSOCIATION: Institute orgmdcheakoy khimil im.- N.D. Zolinakogo Akademil naia: SSSR (Institute of Organic Cheadatv7I, A*adeW of Sciences 83310 SUBMITTED: 'd!53GPt63 DATE AOQ:- 147sb64 ZRCL: 00 SUB CODE& C11 NO REP SOV: 004 OTMI 000 Ca.-d 2/9 ACCZSSIQN M A7401"76 81=0164104/006/13491&392' AUTHMt Matedoww 09 Not Kslesmikwq so 1P.1 ftsebstavowl, Ao $,I Fetrowo A. Do member) 0 TITLZ: Properties of 1,1-dLcbtoro- and 1.1-dimethylgotmems cyclopeattass-3 SGURCIZ: AN SSSR, Daklady*, v. 154, no. 6, L964, 1369-1392 TOPIC V,Cgt Lcommal dkblocogermenecyclopenteno, Lcomme, I dL%ethyLse-c=su*cyc1o- penteas 3. trLchloce genwasp lcominal dtch loro- I -gerwaacyc lopentaw-3 . lcommel dinethyL I sormenecyclopentess 39 sermselum compoundo gormantum, ABSTMC,T: During the reaction of an excess of dLv1myl witb HGeC13 at a tempOrstwe' Lnterwit of -80 to SOCO bLghec molecular germanium oegsuic compounds are formed togetlwtr with the compounds CH3CH*CUCNZCeCL3 (1) sad lgi-dicb1ora-bgermene cyclopointens-3 (It)* A dimirLc was sqwcat*4 (yield n) vbLck corresponded move closely to the structure 2(-C%C =KfAC12-)I(1W sod also separated were liquid and solid polymers (welOt lstLou 103C)', made, up mostly of the weamer u&LtL CM-A..01 " Oftal Yield 13-3016 molowlar veftbt 2' 152"Gh Ow Cate Xwed 1.1-41motawl-1-8 systopentems-3 (10 go- 4160 Cwd 113 ACCZSSICNI NR: A74019976 studLed* ThLe unsaturated heterocycle dehydrates more eaeLly and more fully then the substLtuted cyLa-snd Senesse cyclopenta--s. Thies. at 450C over A1203jCr2O3.K20(S4:l4t2) or at 350-400C vw*t 10% Ft/C, the conversion of (IV) is 60% w th K2 content to the gaseous deby4rognotLon products from 96-967. whereas the 1. 1-dLeenthylgermane cyctopentane does not change Is these conditLons. 11owever, 1,1-dLmethylgermne cyclopentadLens-2.4 La pure fors was not separated from the dehydrogensto because of Its extrone toodemy to condense. The structure of d1wre and polywre developLog from (11) and (IV) at dLrectly frow divLnyt "d HGGC'3, ILke compounds of the gawavoL forsi Z(-CH2C1L-C"CN2G~Jt2-)T (R xx CL or CH3, X and T s R and C1 or C83) La sboets by a stgaLficant sLoLlaritv of proton spiectra to a spectra of corresponding monomer beterocycles (11) and (Me The proveisce of three ba~Lc types of protons La these COWOMWE which COMSPOW to the wasomer mLt OF$X.CVCv2C*(CRj)2 (-C 9*43-9~91 dW11CAto So47-8o49 and 8*30-11#36; 4*72-4*73 mode) La Lodketed, OCU, art, best 2 ILS~o ASSOCTATIMs Ustitut segaisLeleaskey, AWL La. ff. Do 9411641W0 Akfildwil seeik SSSR (UstAtsto of Oqp"e Chandatrye, A644OW 09 89140960 INV CM, 213 ACCUSION US sualar 1 145063 =a COD38 Ce Dan AcQI not" in moms 006 =ICLs 00 Glum on Card 313 4 OV , C,.M . ; I , A. t. Roact Ion of d I-, tr l-, &rri - * r, -!,., r- , *.l~.i,.,--,.i - ~ ". "'L ~ , li thl um. A now tachniq-je , " . ~--,tirufirje) pr.d " I, : ~r.. . I- ;,. , . AN 53SR 256 no. 4:884-V7 ".j , f, I ., ~ - t, 1. Ins"Atut organlchfisko.r ' ~ -., ':. i ~ ,I ~ i.,_, t - ~ A 1, -'~ ~ ! . PredsUivleno akademikom 1%, NEFEDOV, O.M.; NOVITSKAYA, U.N.; I'I:TR()'I, A.D. ldp~-eflql-( ) Production of met.*.yltrWy,l-lf--ne,; by thp cf all~-(j benzenes with chlorocarhone and 5)?.1. Alt' SS..R 158 nn.21 4.11-414 S '64. (MIFtA 17:10) 1. Inatitu. orimnlohm-skoy Khimii iri. N.D.Zellntikofzu AN -'. Chlan- korrespondfirit AN SO'SR (for Potrov). NEFEDOV, I Z,.,. ~repamtive mr-*.~od fcr -btaln~nF ' AN 53SR Ser. kh'.71. n, ., :31745-3'~+ 1 ~ I . ( ~, :11'A " g: --, ; 1. 1 nsLi tut organ! Yt.1 m' I Im. III. ~ . Ze 1 Inskoizo AN MiR. NEFFIDCVP O.M.; !AUTM, R.N~ Comparative atwiy of varlous mattiods of prepara,-icr, of bone. Ivv. AN SASH, Ser. khim. n,-).3253&-541 165. 'KAA i8:5) 1. Instltut orgt.nichoskoy khtmil :-m. N.D.7elln.9kogo V4 ~S,31 . AM NRi AM012082 SCURGE CODE: UR/0062/65/000/003/0579/0580:~ AUTHOR: Neredov, 0. M.; Kolcanikov, So P.; Movitakayap He No rizanic Chujat= imA 14. D,-Zal J naki X- AN MM (Institut organicheakoy khimli AN SSSR) TITLE: Addition of trichlorogermane,to cyclopropane derivatives SOURCE: AN SSSR. Izvestiya. Serlya khimicheskayal no- 3, 19650 579-580 TOPIC TAM cyclic groupp arawtic hydrocarbon, germanium compound, chlorine compound,, organogermani comp)und ABSTRACT: C~rSlopr~k~nslnd itti derivatives exhibit well-kAown unsaturation, which is evident,, for example, in their capacity to add on such reagents as halogens, acid3p salts of mercuric oxide. Accordin4y, the reaction of cyal'>propano deriV&tiTS3 With HI*C'3 (I), which is known to add readily to ,olefins and other un"turated ewpounds, has becan of considerable intere,st. It iras found that (I) actually Inry readily adds an to aryl- and sliql- substituted cycllop~~nee to forak the corresponding organotrichlorogermanos,, for example: R-JQW-"+HGeC1 ---4PCY1.;r.* (R)CHCH CH-Thuso the reaction of - ~&10 n8P 0.1 X phenylcycio~~s wiza 0.'D5 A (I) (Z:1 0 25 alnutes) laide to I-phanyl-14trichlorojerwl) ro ane at a yield of 12.6 V%m* 65%)s boiling ~Voint 1,25-1260 _(a M)s nBP'1..M?1j Ef found 35.0,.Galcia M%e (JPRSj SUB CODE: 07 SUBK DATE: %Jin65 ORIG REFS 002 W,FFI)OV, C.M. ; 'Jlr 1 ' ~ :~~ , - N'. 'I . ; ",Yt 'I, '- - ' 'I .. -,, 1 * 1 Vi ty , , -~, -, ~: 9 1! -) " , ~ - ~ .! , , , ~ . I I - .. - s , -. v- t I ,nF, . :,ok : . AS .,. ~ ;I ~ 11 t , 7: () . ~ -, -08 #- 'I , il, A'. f t 4 . I I : , I . Instir.-it iko Lm. I [,.~>Itnsk ,, -N ~ '~ I 3ti~mi t te-l k, - ' - 11 , 1 0; .11 . F---' (IV C). Y'. t N: K.; Y. Ins t,1 .r rqr r., .-k K ,T 1 T "r r.-.K ii~ kh'. mi I I, r ~ r -Any kt. _nFUX!j. -SKAYA, U.N. , _Rttjy,.IVASHFNK0, A.A.; WV1T r.. Cc% Preparation of cyclo-1,3-heptadlenes from n--. Izv. All SSSF. Ser. khIn. no.9rI716 165. ~.~GRA '-Pig) 1. Institut orgunicheskcy khImII im. N.D. Zelinskog-) Mi ~533R. XWT(.E)/SPF( )/Ew(j)l 'T Acc a$'. =MCI 0=8 wdf/owAn0ow/bw 0. AUIMMv TnZ&s* NsUM hr obtalalm. m orawdo Claw 39a lb. 173951 pooth =Whwt no. 169 1050 05 2WM 2MMe *swum# POUIMS ONOMMOt Mrftal this AmMor CortItUate proments a m~UM fw obtaWmg gormwdm Grp*- ic P61pliffe * rems"m amWLm with voisetwated allpW&le sawowands In Wpolm Urovial WIT"o filmoresse Mo warl"y at startft *=VsvNds# at*"=# ad 64~ we used as oow#swdoo The ilm savud'-sit at a-30C. m aml, 07/ 21ANA Card IA 6160"ISWAIP I 0. oV "III L! NOVITSKAYA, N.N.1 ISAYEV, I.S.; NEFEDOV 0.14. I-.,--..- Study of the mechanl3m (of monocyclic hydrocarbon formation in the pyroly-Is of 7,7--dichloronorcaranes by the tracer technique. Zhur.VKHO 10 no-4:459-459 165. 18ill) 1. Tni3titut organ J ~! hes k,.,3r khimll PJI SSSR I Novoslbirskiy Insiltut Slbirskogo ctdeIenlya All SSfR. (MIRA inmnj N.D.ZelinBkogo orgapioheskoy khImII r vp O.k. .ion of tri at the 11 irl, *.I c rMilt! Qi! -ds. 10 no-4.4-,'J-479 ' ',5. (Y] RA 'K~,r, rwri N.f).Zf- ',I nskogr NET -J, rllvj O.M. - I-, A - , A P-,y-m3tion of -.a rt*ness In !nt rF~a i '.on , f 1, % -. -- , ~ . y -,r n - M-Ithanoa wit,-; "w"A' I: '~ . - '; , '1r , z .' . :' I'.' S f:F , s e r - 1. 1 ~ = , c.o. 12 a 2209--2-'- j,~ ', 1. '!~j ~-.' ~3~ .' ) .i . InstitiO. ~rgftr.'. Pr .;t.. - -i , N ~' , " ~- .' t, F ~. v, !~ ~ F, . 31;bmi , Led '~ p - . : '), -4t , . 1 10673-66 - E-Wr (AAAMOW-HRL MXM __ACC NRs SOUKCZ CI?Dlg: UR.10020/65/1(A/004/0622/0025 ..AUTM: a cargo G. sft' T.; mig ev, v I god". ?Z~ Ins, itut drago MG: tauts a# Organic Chemistry La. N. 0. ZG1LnGkLv (Imt 06skay khimii)- ousciances, VmRi*wdampost Ingmante Chemistry Research Acadew (Ise ledovdt~_l 'ekkays GrIAW.00 neacpaLchmakoy khimLL Ak&4e,uiL Sauk TM) T A t I degradatf. rm: ~:Stcisctura 8v _40f cycltc and linswr Polymer silit" and! diamthyl Soung: M: UIR DAlady, v. I", no. 4, 1963t 622-625 TOPIC TA109: orsomellieft compo"do,or'"notermalum compa"d. Pyrolysis ALVEMs, As 119 IWO ~amd me&-speetrointric study.of the soluble part of the pro- ducts ths' reaction Of 0113)ISLCIZ with Ifthim La tetrehydeofuran showed that ft i t mainly of Ctystals' malting'sit 228-231C and foraLus the Cyclic V0117-98'r-1. 3)ZSLqt:_/A- SUdlarlys a 10068'spectrametric analysis can- fknod that &b6 sommium poly;w-;. walting at 20.7-209c, also fens the cyclobexamsL4 VC43)208 C-1 Pyrolysis of dimathyleLtylene and dimathylgaWleme at moderate tempecatureal;P to 350-4m) laws imstaly, to the rupturf of bonds to this formation of amerfel diveric, and pakmeric bleadicals: Cud L 10873-66 ACC M Ob C16 C16 where M $I or Go; k 0-4 oc mace; a-.*1(?)p4-6 sad wace. Is the absence of ..special acceptormA. tb*se biradicals. recombine chiefly with me another, fotuing tbi cyclic POIJPwtf L(Cv -:7u. The date obtained Indicate that pyrolysis of the ~Polywrs- L(cR3)2M4C-1,, where N - Si, Go, So, or ft, - cow be us.,ed so a general ustbed of generating ~the corresponding c&rbemtds (CE3)21M-' - The paper we asented by vj~ a A. ftsduskiy, - Number of M SUR, 26 Mac 65. Authors. thank M'. . Lf Inkel 0. -A. S. chotucow. &'ad O'CAomytom, foc carrying out the spfttco4copfC-4itGOdM4tLCM*. Oryx--art.- has: 2. ml"*- $us cow: 07 SM DM: I Ubc65 ORIJ; AW: 004 OM RW: 007 Cgird NEnDOVP O.M.; KOLESNIKOV, S.P. Preparation of orgariogerm&nium oligomers and polymera hy reactions of trichlorogermine and its etherates with inna- turated compounds. Vysokom. so"d. 7 no.11ilA57-1862 IN '65, (MIRA ICI: " , 1. Institut organicheakoy Khimii imeni N.D. Zelinskogo All ",S.T. Submitted November 27, 196,.. 27337-66 Ewr( )/Fwp(j)/r ijp(,c) at. ACC MR AP6"962 sOURcz Oms UR/C-'90/65/007/Oii/1e5T/j062 J~6 i". AMMj 1101"'wX 0- U-1 Kolesnikov, So p. ORO: Institut* of %wic Cho Idetry in, N.- Do 7,eljnsjjU,. Ag 56.3g 3_3 crpnicYea-W iMIL AN 33aR) _(Institut olid,mere and POIPMrs by reactine TI=I 'ptepwation. f turAtOd compounds gumnium trIchlarid: and lite staerateg with Una& SOURCEt Ty~'Dkmo'QWPWVYQ soyed~n`niYss v- 7, no. 11, 1965s 1657-1862 TWIC ?AGO$ Or6~4ic synthetio Frooems' 9"'"ium c=POUndp JH)1Mr chemistry Geol StIcIM of now bet"Oe'liphatic and olef'A'O OrIMAOgerm8nium Oligoners A&MACT I preW invesUPtOd by using gerlIsnium tri and POIYRW6 has be. 2 IWOuP ftiab readily attack unsaturated bond Chlorides as & acu-eq of isowtF146O)t 193-diews (kaba 16mo- lefind (-O-tbyleno 0/~ L- w 0001pounds, isopreng) is Iwo n4 OL p A -unsaturated O"r'"* *f double bonds- While BIV10 others were used t iup OASOmer as 801"At4- MW, chlortmated to the GGIMM 8 and Polymers formed according 4. L 27337,m" ACC IR i-AP6000"9 R' R" CI IIR' + GOC6 IRR'G-CIIR") e Go where Rt t. and R" Rp a!IWI9 alkenyl, are pale yellow viscous liquids or white powders having so p, frOM 50--70C (in me of 10-dienes)y or 250--3500 (in case of CAI 02N , ieo-Cj&). The average molecular weight of the polymers was from 2500 to 6000" L The presanoe of labile Go-Cl bonds in addition to unsaturated carbon- aaAm ba"s uQm'these compounds suitable fi)r a vsxisty of chemical transform&_ -to L. Ai laff"s tione# ~ s'"me. euUwre ezpress their gratitude ani A. S. Khaohaturov for help Aft pWfW~di* S"otr&l Q*,Jg# arts bass 1 figuret r~" p and 2 4!41" CRXff'-FM?o W61, M RMs W3 AM 27ol 144f 2/9,; L 31366-66 EWP(J)/FjYT(m) RM ----I ACC NR, AP6021098 SOURCE CODE: UR/0062/66/000/002/0201/0211 AUTHOR: Nefedov, 0._M.. Kolesnikov, S. P. ORG: Institute of Orianic Chemistry im. N. D. Zelinskiy, AN SSSR (Ingtitut organiclWa-k-oy- kh1mii -W 5,-ZH ) TITLE: E~ ~~-,richlorogermaniumlas sowcos of germanium dichloride -- a germanium analog of d.'chlorocarbene SOURCE: AN SSSR. Izvestiya- Seriya khimicheskaya, no. 2, 1966p 201-211 TOPIC TAGS: ether, organogermanium compound, orpanotin compound, halogenated organic compound, halide, analytic chemistry ABSTRACT: A staly of the physical and chadcal properties of etherates of trichlorogenuinlum wd other trihalogen1d" of gamantus and tin show that they have a carbenold character and my serve In xW reactions as sources of corr"poWift dibelagenides of gerwanim or tin - Inalade analogs of dihalocarbews. the garm"us diddarld" wA dilwaddes; gakwated In this veyo we was reasUve than the awAmwis saybeadds 0*1 a and &dM2* T" othersto of sexpeatle" 2(Cjx5) -MCO~ Is a v4stiles elly gressilsb4sUev UqvdLd. Insoluble In "her md orgentle esibmte. and dessupee" "we &AD- tillation or prolonged 3torage. (JPRSJ SUB CODE: (Y7 / SUBM DATE: O3Aug65 / ORIG REFt 020 / OTH REFs 007 el UDC 1 U3. + 5Q-2m 'L 31893-66 EWT(a)/EWP(j) MM ACC NR: AP6012526 SOURCE CODE: UR/0062/66/000/003/0443/0452 AUTHOR: Kolesnikov, S. P._i Nefedov, 0. M.; Sheychonko, V. I. ORG: Institute of Organic Chemistry im. N. D. Ze1j.nskiy, Academy of Science SSSR (Institut organicheskoy khimii Akademii nauk SSSR) TITLE: Ilorp Reaction of trich &oLrmane with aromatic compounds and uncatalyzed addi- tion of germanium chlorr-form at arom tic unsaturatel bonds SOURCE: AN SSSR. Izvestiya. Seriya khlmicheakaya, no. 3, 1966, 443-452 TOPIC TAGS: organic synthesis, aromatic hydrocarbon, germanium compound. deuterated compound ABSTRACT: Germanium ch~loroform displays extremely high reactivity in addition to olefins and'acetylenesjin the absence of catalysts and generally exotnermally. Two of the authors reported previously [rav. ZN SSSR. Ser. Khim., 579, (1965)) addition of HGeC13 to alkyl- and arylsubstituted cyclopror)anes with opening of the three- membered ring and formation of isoalkyl or aralkyltrichlorogermanes. The article describes addition of HGeC13 and along the aromatic unsaturated bonds which have not been investigated prior to this time. It is shown that the reaction of germanium Card 1/4 UDC: 543.422 + 542.91 + 661.718.66 L 31893-66 ACC NR: AP6012526 chloroform with a number of aromatic compounds proce-ads quite readily at moderate temperatures and without .--atalysts, contrary to the experience with hydrides of cther elements of group 1VB. The addition occurs not only at the olefinic and acetylene bonds, but also at the aromatic double bonds. Addition of HGeC13 to naph- thalene was -accomplished by single heating of equimolar mixture of reagents to 100- 1300C for 10-25 min. The reaction proceeded by the following scheme: + 211 GeCis GeCJ, CH3MC81 Gecl, CHOM M :n addition t b*s(t ' ethylgermyl)tetralines methylated reaction products of HGeC13 IT with naphth W4,econrtaining high boiling germanium hydrocarbons. Reaction of alkyl- Ll- n naphthalenes wit germanium chloroform proceeds ever tasier than with naphthalene t and results in formation of isomeric bis(trichloTogemyl)alkyltetrahydmnaphtha- .Lenes. In contrast to pnlynuclear aromatic hydrocarbons, benzene and alkylbenzenes do not add HGeC13 (even after prolonged boiling), M introduction of electron donor alkoxy group into the ber.zene ring promotes addition of germanium chloroform to the double bond of the benzene ring: Card 2/4 L 31893-66 ACC NR: AP6012526 OR OR OR + 311GeCt, c1, NO It was also found that HGeCl-l can be added to heteroaromatic systems. It was reacted exothermally with thiophene ~ roducing isomeric bis(trichlorogermyl) tetrahydrothio- phenes. It was concluded that introduction of electron donor groups (CH31 CH30 C2H50) onto the ring facilitates the addition of HGeC13 at the aromatic double bond while electron acceptor groups such as halides hinder su::h a reaction. This indi- cates the electrophilic natur? of the addition reaction .)f germanium chloroform to aromatic compounds. Such an exclusive nature of germanium chloroform among hydrides of group IVB elemnts is explained mainly by the strong acidic properties of this compound. To evaluate accurately the acid strength of HGeC13 and to determine its reactivity as a function of the basicity of aromatic hydrocarbon, experiments were conducted on deuterium exchange between DGeC13 arA the benzene series hydrocarbons. Experiments show that while with toluene deuterium exchange does not take place even during 1 hr mixing with DGeCl3 with more basic hydrocarbons (mesitylene ' sodurene) DGeC13 acts as a strong acid c-3pable of rapid deuterium exchange. IsotogZ exchange Card 3/4 L 31893-66 ACC NR: AP6012526 data indicate the tendency of HGeC13 to ionize. The auth~,rs thank V. A. Koptyug and MI. I. Gorfinkel' for assisting in the experiments on deuterium exchange and for the d-1-scussion of the results. The authors also thank M. G. Voronkova for commenting on the reaction mechanism. Orig. art. has: 3 figures and 1 table. SUB CODE: 07/ SUBM DATE: 03!;ep65/ ORIG REF: 010/ OTH REr: oo4 Card 4/4 L 31887-66, EWT(E)/SWP(J)/r IMC) RM ACC NR; AP6012537 SOURCE CODE: UR/0052166/000/003/0584/0584 AUTHOR: Kolesnikov, S. P.; Shiryayev, V. _I.,_i Nefedov'0 14. q" ORG: Institute of Organic Chem:Lstry__im. 14. D. Zelinskogo, Academy of Sciences SSSR (Institut organicheskoy khimii Akademii nauk SSSR) TITLE: Germanium dichloride cormlex compQund I SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 3, 1966, 584 TOPIC TAGS: germanium compound, complex compound, chemical decomposition ABSTRACT: During the study of the reaction of HGeC13 with diethers it was discov- ered (that contrary to the report of a previous communication (Angew. chem. , 76, 496, (1964)] 1,4-dioxane does not produce trichlorogermane ether with HGeC!,, but that they react upon the liberation of 11Cl. According to data obtained from elemen- tal analysis, IR, NMR and molecular weight, they produce a crystalline complex com- pound of ger-nanium dichloride C4[1.0,-GeCl,. Foi-tion of C411602'GeC12 from HGeC13 and dioxane is a direct proof of ~h~ abillity of HGeC13 to dissociate easily upon the formation of GeC12. The complex is stable in air and upon aqueous hydrolysis Card 1/2 UDC: 661.718.1 L 31887-66 ACC NR: AP6012537 produces Ge(01021 is insoluble in hydrocarbons, and reacts with ethanol and acetone. Upon heating, it decomposes at 140-2100C. With unsaturated compounds, the complex produces gernanium organic monomers and polymers.I SUB CODE: 07/ SUBM DATE: Moc65/ ORIG ITF: 004/ OTH REF, 002 Card 2/2 1 . r 1-1*~ .,D;, I) p . 2. T13H (6, -)) 1, . ""Iectric btors 7. bavici for making the Aarting of a 3hort-circuited elect -ic motor Khol. tekh. 29 no. 4, 1952. 9. Vonthl-,i L.3t of Aus:jian- Acce.-,L'Ons, Library of Congress, ,arch .95 1. Unrla3311ied. NEFE DOV, P. G. "Ways of' Reducir4 Labof --aiftwm I rw I rw ari(I C I,, rin I %; A, ~7rir. I I %. f~' The Kirov District of LeningriLd Strives for Techw:.ogleal Progress; k7ollection of Articles, Laningrad, Budpromg1z, 1957. 171pp. Ibis collection of artleles describes the progressIve experience of the industrial plants of the Kirov district of the clt.*f of LentrVad in the fields of shipbuilding, machine bulldIN7, Instrumeat-nakIrW, casting, hydrolytic and other Industries. New manufacturIng methods are cliscussed IVLNGVP V.M.; OV., - Experlmntal Jimatigation of the combustion of particles of natural and exalvified liquid fuels. Trudy IGI 19135-45 162. (MMA 16s4) (Liqtdd fuels) (Combustion) t 116 GANA, N.Z.; DRABKIN, G.M.; KRISTOL, D.I., LAPINAGOV, P.I.; NEFEDUI, i'.K., SELUYANCII, M.P. ---- I I Standard sections of universal multistory industrial buildingg. !& Prom. stroi. 40 (i.e. 411, no.507-40 Ky '63. 'MIRA iW) (Industrial buildings-Design and constructi n, AO GLUSKIN, E.Ya.; FOLYAKOV, N.V.; I'HOYNih, V.F.; USHAKOV, N.S.; NEFEDOVI F.K.v inzh., red. (OverFill mechanization and nutomatlon of Intraplant transportation in instrumen-. plantii) Komplek.;naia me- khanizatsila i avtorratlzatniia vnutrizavodskogo trans- porta N priborostruenii. 2., izd., ispr. i dop. Mao- skva, I-lashinostroenle, 1964. ~8~ P. (MIRA 17:i1) SAMPYLOVICHO G.G., prof.; dELYAYFV, N.I., in2h.,- KUDRITAn, 5.M., dots.j GLAGOLEV, A.V.P inzh.1 inzh.; GALKINA, Ye.A., fit. nauchn. gotr.,- PLINK, L.I., Irzh.i DOlla(GY, I.P., prof., retsenzot.tj SAVELIYEV, V.V., kand. tekhr- nauk, dots., retsenzent~ ALYSHFV, I.F kand. tekhri. nauk, dots., rretsenzent; LOBALMV, A.N., prof:' doktor tekhn. nauk, retsenzent; DOROKHOV, i3.A., inzh., red. (Use of aerial photographic iurveying in forest engineerin,~I~ Primenenie aer-ofotoollemki v lesoinzheneimom dele. Mcinkva, Leariala promyshlenriost' ,1965. 354 1,. Wli~A IF-.10) 1. Kafedra Bukhoputnogo transports lose 1,-motekhnichaskoy akademil Im. S.Y.Klrova (for Alyshav). 2. Zamestitell giavncgo inzhenera riosudarstverxogo instituta po proyektirovaniyu les- nogo tranaporta (Afor Dorokhov). IU,,Kv;DOvj kand. VkJin. naae.; .. ., it izh. ; II'C, it. ;t I " , 't. A., ill 7.yj . . LOPUTHOV, A.Ye., irizi, A Present-day methrl of' :ji_IvjrW, t:;o prulit., of the ,listrlLu%i~,r, r~-, mass,ts of G,,j.,-tfj. 7 r -, r~:j , . ,; t.n, i . 11 ne . 4: 41-43 A i I I k ~, D,-4 1,!: '. " bi Al Z., ( Fc, J~ - ffffmm, P. Ya., Candidate Tech Set (dies) .- "Producing cupola-furnace coke- briquette fuel based on anthracite". Sverdlovsk, 1959. 18 Vp (Kin Higher Muc USM, Ural Polytech Inst in S. N. Kirov, Chair of Chem Tvcb of ruel), 150 COPIes (KL, ND 24, 1959, 139) WF7MAN, II.V.; NFFT.-,OV, P. ill. Brijuet.ted cr)ke f,iel for c~jprla furnaces. K.4-3 i krim. no. -,,: 31-34 '-'~4 - K-PA 1-:4 1. flrqllskiy poIiL--.khnIcheskIy Institut (for roftman . 2. Vogto