SCIENTIFIC ABSTRACT NEFEDOV, O. M. - NEFEDOV, V. B.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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86W
Production of Aryl Halides From Aromatic 3/020/60/1'3/0,~4,058iO40XX
Hydroxy CompDunds B016/BO54
as of the ArX produced, on the basis of thE authors' data and pubilcations
There are 1 table and 8 referencesi ; SOVILEt, I US, 5 German, rind 1 Indian.
ASSOCIATIONi Institut organicheskoy khimii im. N. D. Zelinaxogo Akademil
nauk SSSR (Institute of Orgaric ftemistry imeni
N. D. Zelinakiy of the Acaden.y of' Sciences, USSR)
SUBMITTED: April 25, 1960
Card 4/4
PETROV, A.D.1 MEMOV, O.M.; IXVKGV, Ya.L.; SHMUK, T.Yu.
Alkylation of benzene with 2-cy-clohaxylcyclohexanol in the
premnce Of AlC13- Neftekhimla 1 no-3062-3619 *.r-J* 161.
(MTRA 16:11)
1. Institut organicheakay khimli U SSSR imeni Zelinskago.
PETROV, A.D.; NFIWOV, O.M.; KOLESNIKOV, S.P.
Synthesis and pyrolysis of 1-subittituted 7, 7-dich.Loronorcaranes.
7Amr.VKHO 6 no.4t471-1+72 061. (MIRA 14:7)
1. Inutitut organicheakoy khimii imeai N.D.Zeliwkogo AN SSSR.
(Norcaransi)
27497
S/062/61,/OOO/0C9/G1 3/014
B1 17/B1 01
AUTHORS: Nefedov, 0. M., Manakov, M. N., and Petrov, A. D.
TITLE: lieu method of preparinf; cyclic organo-silicon compounds
PERIODICAL: Akademiya nauk SSSR. 'Zzvestiya. G%deleniye kh,-T'1,-ne8K1Kt,
nauk, no. 9, 1961 , 171 It
TEXT: The present letter to the editors reports the following: It was
found that the reaction of dimethyl-dichloro silane with lithium in
tetrahjdrcfuran (THF) at 100-70uC in the presence of styrene (2 mole to
1 mole (CH )2S'C'2) gives diphenyl-dimethyl silicacyclopentane (probably
a mixture of isomers) in 30-505/t yield.; b.p. 1270-1290C (0.2 mm Hg) and
1560-1370C (0.2 mm fig), n-'O 1.5722-1-5759, d20 1.0077-1-0135, found MR
D 4
86.99-87.20, calculated MR 86.69, found mol.wt. (cryoscopically in
benzene) 262; 257; calculated mol.wt. 266. Found: C 81.02, 80.jC,
H a.6o, 8.32, Si 10-40, 10-431/6- CiEl 322 Si calculated, C 81-11~, H Es 32,
Si 10.53%. Together with this compound, a considerable amount of a
Card 1/4
27497
S/06 (o/OOC/cCq/~'3/C'4'
New method of preparing BI 17YBI 01
resinous silicon-containing polymer of probable structure
CH
1 3 1 1
Si C_ C
I
C If3 -In
is formed. It is easily soluble in watert acetone, and other solvents
This reaction which was discovered by the authorH proceeds in a similar
manner with styrene derivatives vinyl naphthalenits, divinyl benzene and
methyl methacrylate. Under the same conditions, but in absence of
unsaturated compounds, the main reantion product is the high-molecuiar
polydimeth:ll silylene [>Si(CH 3)2]no obtained in 65-"5% yield. m.~
3400-3450C (under decomposition). It exhibits a mu(.h higher res,.stance t~,
thermal oxidation than a similar polymer obtained from (CH \ SiCl, and
sodium in benzene (2000C, 15-20 atm) (Ref. 1. see oelow, It is assumed
that the reactions described involve dimethyl silylane, a silicon analog
of the carbene compounds, as an intermediate;
Li LiCl
(CH ) Sici ___ ) (CH ) SiLiC.1l (CH
3 2 2 TIff 3 2 3)2S'~
Card 2/4
27L97
S/062/61/000/009/013/014
New method of preparing ... B110101
In the absence of alkenes the latter is polymerized to 1>Si(CH 3 2-1 n. In
the presence of alkenes , dimethy. s:.lylone probably adds to the double
bond with formation of unstable ail-.con analogs of cyclopropane of the
corresponding diradicals. These th,3n form derivatives of silicacyclopentane
and polymers by reaction with excess alkene:
C/ C: fa or C CH \~C-C/
11 +: Si (CI 1,), -I \si/ \SI/
C C/ \C 4,
CHS
C---c \ /01
I- Si +
C C/ \(:H:
~bstracterlq note: Complete trana-.ation.-!
There is I : )n-Soviet reference. '"'hin reforence tc English-language
publicuti,j.is reads as follows: C. A. Burkhard, J. Am. Chein. Soc. 11 )6
(1949); pat. USA 2554976, 2j. V. 1)51; Chem. At)etr. A.~, 880 (1951 -
Card 3/4
Z7 497
S/06 61 /,~G C/OC)9/01 ~' / ~- 14
New method of preparinC ... 311 7~31 Gl
ASSOCIATION: Institut organichetikoy khimii im. N. D. Zelinskogo Ayalemii
nauk SSSR (Institu';e of Organic Chemistry imeni N. D.
ZelinBkiy of the Auademy of Sciences USSR)
SUBMITTED: June 27, 19o1
Card 4/4
nEFEDOV, O.M.; IVASHENKO, A.A.; MANAKOV, M.N.; SEIRYAYES, V.I.;
PRETW A.D.
New metbod of preparing carbones. Izv. All SSSR Otd.khim.nauk
no.2:367 P 162. (YLIRA 15:2)
L Institut organicheskoy khimii im. N.D.Zelinakogo AN SSO.
(Carbenes)
me
5/06 62/000/007/006/013
B1 17YB 180
AUTHORSt Nefedov, 0. M., Manskov, M. N., and Petrov, A. D.
TITLEs Synthesis of substituted 1,1-dialkyl silica oyclopentanes
from dialkyl dichlorosilanes and styrenes
PERIODICAL: Akademiya nauk S55B. Izvestiya. Otdeleniye khimioheskikh
nauk, no- 7, 1962, 1226 - 1237
TEXTj The reaction of dialkyl tlichlorosilane ard aryl ethylene with
alkali metals (lithium, sodium) in an inert solvent is here described, an
a new method of synthesizing aryl-aubstituted 1,1-dialkyl silica cyclo-
pentanes (30-75%). The reaction set in immediately with considerable
heat evolution when a mixture of aryl ethylene and dimethyl dichlorosilane
was slowly added to lithium in tetrahydrofuran. The reaction with sodium
was less vigorous. Diethyl ether or benzene iwitead of tetrahydrofuran
decelerated the reaction, but hardly affected the yield (55 - 50) of the
end products. In addition to silica oyclopentanes, polymers with silicon
atoms in the principal chain slio formed during the above reaction (yield
uP to 704). (Their composition and structure will be studied in detail.)
Card 1/2
3/062/62/000/007/006/013
Synthesis of substituted... B117/B180
These polymers were the main products obtained by the reaction of di-
ahlorosilenes and conjugate dienee (e.g., piperilene) with alkali metula
(Li, Na). As a possible mechar.ism of the formation of silica cyolo-
pentanes, the reaction of dichlorosilane with dilithium derivatives of
styrolene and their dimere (reaction A) is suggested, or possibly that of
dichlorosilane with the I'dimerizing" adduct of lithium to styrene (reac-
-ion B) are suggested or the oarbenoid meohnnism. Synth*siied aryl-
substituted silioa eydopentanes might possibly be used as monomers for the
synthesis of chemically and heat resistant polymers but this has not yet
been confirmed by experiment. rhere are 1 figure and 1 table.
ASSOCIATIONs Inatitut organicheakoy khimii Im. N. D. Zelinskogo Akademii
nauk SSBR (institute of Organic Chemistry imeni
N. D. Zelindkiy of the Academy of Sciences USSR)
SUBMITTEDs January 26, 1962
Card 2/2
q-,.WFljm, %.:~j . , '.. .
. I
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MMOVS O.M.; MLNAXOW,, M.N.; IVASHENYOp A..A.
Addition of diablorocarbons to sons I-subotituted 1-cyclohexerina.
Izv.AM SSSR.Otd.khim.nauk no.7tL!42-1248 JI 162. (IMilL 15z7)
I
1. Institut orgiudcheskoy khimii Lm. N.D.Zolinskogo All SSSR.
(Carrbenes) (Cyclohexons)
N9FSMv O.K.; SHIRLLYEV, V.I.; PETROV, A.D.
Phewfl carb)ns from phanylUthium and methylene chloride.
Zkur.ob.khiia. 32 no.2:662-663 F 162. (MLU 15:2)
1. Institut organicheskoy IdJzii imeni N.D. Zelinskogo
All SSSR.
(Carbow) '(Lithium) (Moth's
)J,542
S/02 62/147/006/025/034
B144YB101
AUTHORS: pgfeday, 0. hl., Manakov, M. N., Petrovo A. D.,
Corresponding Member AS USSR
TITLE: OrFanolithjum synthesis of germanium hydrocarbon compounds
from dimethyl dichloro germane. Some reactions with
,~'CH 02 C,e aj a possible intermediate product
PERIODICAL: Akadem.ya nauk 5S3R. Doklady, v. 147, no. 6, 1962,
1576-1M
TEXT: "CH 3 )2 GeCl2i4nich behaves like (C11 02 Sicl2 combines with Li
dissolved in tetrahyirofuran (I) at 20 - 450C to form a cyclic hexamer,
1 0
i(CH ) Ge-' easily soluble in organic solventel m.p. 211 - 21.3 C;
3 2 , ,69
yield up to 8W.. At --Or-C, ICII ) Ge,
k 3 2 1, !n , a strongly hydropnobic compound
similar to polydime1hyl germylene and insoluble in organic solvents was
also obtained; m.p. 200 240OC; yield 49%. Reaction scheme:
2nLi -nLiCl
n(CH ) GeCl > n(CH Gq(Li)Cl n(CH ) Go: ,~(CH ) Go'
3 2 2 - 3 2 3 2 L 5 2 in'
Card 1/5 nLiCl
S1020162114 71 /006/D2 3/0 54
Organolithium synthesis of B144/B101
(CH GeCl styrene, and Li 'molar ratio 1 : 2 : 4) in I yields the
2 2 P k
following producto ihen stirred violently at-,OOC-. (1) X,X'-diphenyl-1,1-
dimethyl germanacycloperitanel yield 40.5,A, b.p. 140 - 1410CIO.2 mm Hg;
n20 1-59201 d 20 1 . 11)86 (2) A polymer with the genexal structure
D
c if
Ge-(-C-C-) w-,icri iq easily soluble in other, 1, and benzene ; after
N 1 1 k n
3
twofoll reprecipitation with methanol a white powder in obtained
m.p. 74 - 890C; mclecular weight 2'1,90, 2960. Substitution of vinyl
toluene for styreno yields 45% X,V-ditolyl-1,1-dimethyl germanacyclo-
pentane under othe::-wise equal condJtionnj b.p. 150 - 151 0C/0.18 Mm lig;
n20 1.582',; d20 1.1346. The melting point of the :linear polymer obtained
D 4
by reprecipitation was oetween 58 and 700C, and its molecular weight was
1260, 1220. The course of the reaction as given shoos that the products
Card 2/ 3
3102 62/147/006/023/034
Organolithium Byntheois of B144YB101
obtained from Li and styrene with (CH 02 GeCl 21 ~nd also the intermediate
product (CIT5 )2 Ge: react immediately with C 6 H5CH-CH 2' The s.ructure of the
resulting compounds and their similarity with the corresponding silicon
oompounJe were confirmed by the 1H apectra. There is I figure.
ASSOCIATION: Institut organicheakoy khimii im. N.D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni v
N.D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: Septem'oer 26, 1962
Card 5/3
MEMOV9 O.M.t NAKWII-q AND PETfVVg A.D.
----------
Inmugatift of the reaction of ortanobalides of silicon
and proanim with IlUdva and its compo nds.
Report to be sutvdtt*d for the Second Dresden 3yuposium on Organic
and non-silicate silicon chemistry, from 26-30 YArth 63,p Kaxt Germw
Imt1tute for organic chemistry of the Acadepry of Science of the USSR, Mn9cow.
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NEFEDOV, O.M.; KOLFZNIKOV, 6.P.
Ethera*eB of *.richlorogermane. lzv. Ali SSSR. Ser. )rhim. no.Uz
2068 N 163, (MIRA 17zl)
1. Inatitut organicheakoy khimll Imeni N.D. Zelinakogo AN SSSR.
S/38 63/014/033/015/020
B102%1s6
AUTTIORSt Sevastlyanov, Yu. G., Bulan3v, L. A., Kaj,lan, Ye.
Nefedov,_O. 111., 3mirnov-Averin, A. P.
TIT:2: An activation method for juantitative determination of
organically bound sulfur im.Durities in polyphenyls
PERIODICALs Atomnaya energiya, v. 14, no. 5, 1963, 324 - 326
TEXT: A great disadvantage of usir.(7 pol.iphenyls as coolants and
moderators in power reactors is their co.-itent of sulfur imp.-urities (due
to the Droduction conditions). S 32 chan;7es over into P32 in fast-neutron
induced (n,p) reactions, while P 52 emits betas of 1.7 ~Iev and renders the
coolant regeneration difficult; moreover, sulfur reacts with the tube
material to form metal salfides 7hich ca-ise corrosion. In order to
determine the S32 content an activation taethod based on the S32 (n,p)P 32
reaction was developed. The P32 activitj is determined on comparison
with a roference standarl (pure Na,Q10 ), the irradiation (total 101 a n,cm)
4
Card 1/2
3/08 63/014/003/015/020
An activation method for ... B102YB186
taking 26 - 28 hrsj between irradiation and analysis a period of 7 - 10
days was used for complete decay of Na24. The indu?ed activity was
m9asured with an end-window countor iith a 78 mg/cm aluminum filter. I
content of - 0.1 ~'t S ir a batch of 10 - 20 mg was found to correspond to
-j3OOO pulses/min, Consequently, when the irradiation time can be raised
3 to 5 times, quantities of 0.001 - 0.0005 7-Ij S can even be determined.
The sensitivity can be further increased by concentrating the sample.
There is 1 table.
SUBYITTED: March 1C, 1962
Card 2/2
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KEFEDOV, O.M.; NOVITSKAYA, N.11.; ITTROV, A.D.
Production of cyclopropane- hydrocarbonq by the red,ic*i)n of
dihalocarbene Pidducts to )Iefins. Dokl. AN SSSR IV n,~. 1:
629-632 3 163. 'MIRA !~:I;)
1. Institut organicheskoy khindl Im. N.D.belinskopo AN SSSR.
2. Chlen.-korrespondent AN SSSR (for Petrov).
NEFEDOV, 0. M.; ?OLESNIKV, S. 1'.
Formation and telomerlzation of germanium carhencidD. lzv AN
SSSR Ser Kbim no. 4:773-774 Ap '~,4. (M:u 1": 5"
1. Institut nrganlcheskoy khimii Im. N.'~. Zellnskogo AN 3SSR.
I
WL.:~J
5092112i -0/0066/w.060100,0/0067/0074
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m i IK V *DJ(Deceq4ed):
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17-1,1
for
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fynUtesiv rag VToporties of
ihe era). Moscow, YoNauka, 1964, 67-74
N
licoorrgu'l j*
auldiM, orpnomeWlic co*vq x"mnd, oaribenoid, si
eorspowd 10 '1
p 0 derivati eg,- blorovilane
t Oya. v a
N
-.AB ACT:~- ew4k timple Wlhodls described, ation of carberkes,
Ait prepaX
&"i r on of I#hjqb~~ith dl-, and pol
IWO -acti xw-gmewi a their aryl(alkyl)
dM."Uveig - A: unt of tetrshydroWan; at a temperatuxv of -40 td +40C.- So- In -0 oF th 0--
OU NNW, OTI r thus contUtioiWwo7s utilized for thi) preptration of monomer, =4
Dro4hictif I~A now general. me devsIoIxd for the preparation of aryl - -
pler rd hu: been
Attitaki am th 76-8011, -vbIch oonsista of reacti ng
dichl 9111wee lot metals in tbo'presence of aryl-ethylenee or conjugated dienes I n-
71'
A V'
ji
.COST QqAwo--s1l1c
enwdbig on polymers with oilloon atoms In the malm
obaW': the let a up to 60-90%.- I;uch. polymeTs, but baving a crose-linked structure,
weraltilso thii male 'products in the renciion of alkali metals vfth trichlorosilanes and SICI
or .11 1-dieneo. T.he indic" reaction can also be apli
to shMIii,i~jww4 do* at -~lomevtis in groups -V, Orig. art. has i I tablo &*A
A -F
77-
Oovfl-004
ri
i 7~
ACCE=Cff NE: APW3T24l 6/0062/64/000/005/08W/0844
AUTHOR: Nefedoy,_A"I, Manakov, M. N.
TITLE: Reeatioa of d1alkyl(aryl)d1:hlorosi1wes with alkall metals in the presence
of conjugated diezve.
SOURCE: AN SSSR. Izv. Serlya kbirdaheakVa, no- 5, 1964, SW-844
TOPIC TAGS: dialky1dichlorooilane, diaryldichlorosilane, reaction, conjugated
diene,, divinyl substituted silicacyclopentana, unsaturated silicon containing
polymr, silicacyclopentena, produclion
ABSTRACT: Continuing their earlier works (Izv. AN SSSR OtA. khim. a. 1961, 17171
:~1962,, 1228) the authors investigated the reaction of dialkyl(ax7l)dichlorosilane
and conjugated dietoes with alkali mitals in tetrahydrofuran. A mixtuxv of 0.2 M
dicb1orosilane (dinethyl-,, diatkWl- or dilpheny1dichloro-silane)o o.4 N them
(divinyl, ir-oPremo PlPerYlma) and 4.5 gm Li or 12 gm fla was reacted for 0.5-1
hour at about 30C in 50-200 al absoluto tetrahydrofuren under dry nitrogen. The
produat was filtered and the fUtzraloe vwuum fractImated (0.2-0.5 am Kg). Threa
types of produats# vWse r*lALt:Lw yJAIA depen" an tAw initial reagmU and
,Card 1/4
ACCESSICU NRj AP4037241
reaction conditions# 03ee Table) were formed: 1--divinyl substituted silicacyclo-
pentaaes,, ljD-50% yield; H-unsaturetted silicon hydrocarbon polymera with 9L atcmo
in the -gin chain,, molecular weight of 1000 or more; and III-ailicacyclopmtenesp
0-10% Y163A. -
RCII- CIIR R'r
R"AR"
CHR
&AeoL R Ii.CHs;R4 011,CHI; R"- CHI, Citle, Cells_-
R,
11CII (M) G JR1 CJICII,Nl 4- R; SICI,
A 1, Ate. a. R
Carg-AN
ACCESSICK NR: A114037241
Initial Reagents Reaction Products
SilicscYclO- SilicaCY01OPentene Polymer
pentene (III) (I) (n)
Dichloro- Diene metal
vilana Yield Yield Yield Mole
gm % gm. gm. Weight
1 Cl13) OiCI~2 Divinyl Lithim Tracen 3-4-7 9-14 22-23
2 CH3
~
i 213 C12 looprens Lithim, Traceo 10.0 26 22.5 950,1060
CH
3
4 (c
5 ic
SiC%
2 Piperylene
:Csoprene Lithim
Lithim, 0
Trace '0
- Traces
21.6 -
49.5 32
16.5
920,810
5 (C 5 JIC12
~
2
[ Zooprene addium 2.7 9 6.9 15-5 23
i
6 (C6H5 2Si%
2 Vipex7lene Lithim 2.1 7 6.2 14 31 1770,1480
-17- (C iC12 Zoopm Lithium Trace - 8.0 l2.5 36
I Orig. arto hast
3 fonaLUa,, 2 tables.
Card 3/4
:ACCESSICN NR: Ap4o37241
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Of"
-:6h)
-12
"Rli
Az r~.;t~;
71!
ii
441 1
4
OT
51 A
41:5*114 j~
"J t 'i4 S'
NVEDOV, O.M.;I.WIAXOV, M.P.
-- ?o-rmation of reactions of ailylenes, silicon analogs of
carbanes. Zhur. ob. khim. 34 noo7t2465-2467 J1 164
(MIRA 17:8)
1. Irstitut orgaricheskoy kh-imii imeni N.D.Zelinskagc AN
SSSR.
ACCESSrON Nr,-., AP4012091 S/0020/64/154/002/0395/0397
AUTHORS: Nefedov, O.M.; Nanakov, M.N.; Petrov, A.D. (Corresponding
mosber), - -, ,,
TITLEt Mechanism or formation of aryl-substitut*d allacyclopentanos
front organodichloroallanes, styrenes and lithium. Now
method for obtaining substituted disilacyclohexanes.
SOURCEt AN SSSR. Doklady*, v. 154, no. 2,, 1964, 395-397
TOPI.-. TAOS: aryl substituted t;11acyclopertane, substituted
disilacyclobexane, biradical intermediate, bilonic Intermediate,
1, 4--disilaoyclohexane, reaction mechanism
ABSTRACT: 'Olmethyldiohlorosilane and styrene (1:1) were reacted in
tetrahydrorwran diluted with n-heptane (1:1) to form a d1mer--X,X'
-diphonyl-1,4*4-tetramethyl-1,4-disilacycloho3ano#,.Ln 30% ield. The
biradical C6H5CHCH23r% (r) or the bilon C6HSCHCH231R2 (115 are both
possible intermediates. Siallar disilacyclob*xanes are obtained
from styrene and other org-madichlorallanes, and from dImthy1dich-
Card 1/12
ACCESSION NR: AP4012091
lorosilane 4nd alpha-mothyl-styrene or atilbene. X,,Xl-bletrimethyl-
3ilyl-1,1,4,4..tetramethyl-1.4-disilacyclohexans was obtained in 26%
y1eld from diisethy1diahlorosilane, vinyltrimethylailane and lithium.
IR spectra and chemical degradetion helped determine that 1,,2-
disilacyclotie.canes were not formed. It is shown that intermediate
bir-adicals and bilons similar to I and 11 are formed by either of
the following routes: 21.f -LJCI effe-c"C."o
R*SiCll:-- Ra& (U) C1 - RSl-.-
CIHICII SOCHI 1~1 C, If CH (U) CHO R-SIC1. 1 A-4 11.
-2LI-Cl
"(IR spectra were) taken by L.A. Leytes on the UR-10 spectrometer In
IS
a solid solution of XBr . Orig. art. has: 1 figure and 4 equations.
ASSOCIATION: Institute orgmdcheakoy khimil im.- N.D. Zolinakogo
Akademil naia: SSSR (Institute of Organic Cheadatv7I, A*adeW of
Sciences 83310
SUBMITTED: 'd!53GPt63 DATE AOQ:- 147sb64 ZRCL: 00
SUB CODE& C11 NO REP SOV: 004 OTMI 000
Ca.-d 2/9
ACCZSSIQN M A7401"76
81=0164104/006/13491&392'
AUTHMt Matedoww 09 Not Kslesmikwq so 1P.1 ftsebstavowl, Ao $,I Fetrowo A. Do
member)
0
TITLZ: Properties of 1,1-dLcbtoro- and 1.1-dimethylgotmems cyclopeattass-3
SGURCIZ: AN SSSR, Daklady*, v. 154, no. 6, L964, 1369-1392
TOPIC V,Cgt Lcommal dkblocogermenecyclopenteno, Lcomme, I dL%ethyLse-c=su*cyc1o-
penteas 3. trLchloce genwasp lcominal dtch loro- I -gerwaacyc lopentaw-3 . lcommel
dinethyL I sormenecyclopentess 39 sermselum compoundo gormantum,
ABSTMC,T: During the reaction of an excess of dLv1myl witb HGeC13 at a tempOrstwe'
Lnterwit of -80 to SOCO bLghec molecular germanium oegsuic compounds are formed
togetlwtr with the compounds CH3CH*CUCNZCeCL3 (1) sad lgi-dicb1ora-bgermene
cyclopointens-3 (It)* A dimirLc was sqwcat*4 (yield n) vbLck corresponded move
closely to the structure 2(-C%C =KfAC12-)I(1W sod also separated were
liquid and solid polymers (welOt lstLou 103C)', made, up mostly of the weamer
u&LtL CM-A..01 " Oftal Yield 13-3016 molowlar veftbt 2' 152"Gh Ow
Cate Xwed 1.1-41motawl-1-8 systopentems-3 (10 go- 4160
Cwd 113
ACCZSSICNI NR: A74019976
studLed* ThLe unsaturated heterocycle dehydrates more eaeLly and more fully then
the substLtuted cyLa-snd Senesse cyclopenta--s. Thies. at 450C over
A1203jCr2O3.K20(S4:l4t2) or at 350-400C vw*t 10% Ft/C, the conversion of (IV) is
60% w th K2 content to the gaseous deby4rognotLon products from 96-967. whereas
the 1. 1-dLeenthylgermane cyctopentane does not change Is these conditLons.
11owever, 1,1-dLmethylgermne cyclopentadLens-2.4 La pure fors was not separated
from the dehydrogensto because of Its extrone toodemy to condense. The
structure of d1wre and polywre developLog from (11) and (IV) at dLrectly frow
divLnyt "d HGGC'3, ILke compounds of the gawavoL forsi Z(-CH2C1L-C"CN2G~Jt2-)T
(R xx CL or CH3, X and T s R and C1 or C83) La sboets by a stgaLficant sLoLlaritv of
proton spiectra to a spectra of corresponding monomer beterocycles (11) and (Me
The proveisce of three ba~Lc types of protons La these COWOMWE which COMSPOW
to the wasomer mLt OF$X.CVCv2C*(CRj)2 (-C 9*43-9~91 dW11CAto So47-8o49
and 8*30-11#36; 4*72-4*73 mode) La Lodketed, OCU, art, best 2 ILS~o
ASSOCTATIMs Ustitut segaisLeleaskey, AWL La. ff. Do 9411641W0 Akfildwil seeik
SSSR (UstAtsto of Oqp"e Chandatrye, A644OW 09 89140960 INV
CM, 213
ACCUSION US
sualar 1 145063
=a COD38 Ce
Dan AcQI not"
in moms 006
=ICLs 00
Glum on
Card 313
4
OV , C,.M . ; I , A. t.
Roact Ion of d I-, tr l-, &rri - * r, -!,., r- , *.l~.i,.,--,.i - ~ ". "'L ~ ,
li thl um. A now tachniq-je , " . ~--,tirufirje) pr.d " I, : ~r.. . I- ;,. , .
AN 53SR 256 no. 4:884-V7 ".j , f, I ., ~ - t,
1. Ins"Atut organlchfisko.r ' ~ -., ':. i ~ ,I ~ i.,_, t - ~ A 1, -'~ ~ ! .
PredsUivleno akademikom 1%,
NEFEDOV, O.M.; NOVITSKAYA, U.N.; I'I:TR()'I, A.D. ldp~-eflql-( )
Production of met.*.yltrWy,l-lf--ne,; by thp cf all~-(j
benzenes with chlorocarhone and 5)?.1. Alt' SS..R 158 nn.21
4.11-414 S '64. (MIFtA 17:10)
1. Inatitu. orimnlohm-skoy Khimii iri. N.D.Zellntikofzu AN -'. Chlan-
korrespondfirit AN SO'SR (for Potrov).
NEFEDOV,
I Z,.,.
~repamtive mr-*.~od fcr -btaln~nF '
AN 53SR Ser. kh'.71. n, ., :31745-3'~+ 1 ~ I .
( ~, :11'A " g: --, ;
1. 1 nsLi tut organ! Yt.1 m' I Im. III. ~ . Ze 1 Inskoizo AN MiR.
NEFFIDCVP O.M.; !AUTM, R.N~
Comparative atwiy of varlous mattiods of prepara,-icr, of
bone. Ivv. AN SASH, Ser. khim. n,-).3253&-541 165. 'KAA i8:5)
1. Instltut orgt.nichoskoy khtmil :-m. N.D.7elln.9kogo V4 ~S,31 .
AM NRi AM012082 SCURGE CODE: UR/0062/65/000/003/0579/0580:~
AUTHOR: Neredov, 0. M.; Kolcanikov, So P.; Movitakayap He No
rizanic Chujat= imA 14. D,-Zal J naki X- AN MM (Institut
organicheakoy khimli AN SSSR)
TITLE: Addition of trichlorogermane,to cyclopropane derivatives
SOURCE: AN SSSR. Izvestiya. Serlya khimicheskayal no- 3, 19650 579-580
TOPIC TAM cyclic groupp arawtic hydrocarbon, germanium compound, chlorine
compound,, organogermani comp)und
ABSTRACT: C~rSlopr~k~nslnd itti derivatives exhibit well-kAown unsaturation,
which is evident,, for example, in their capacity to add on such reagents as
halogens, acid3p salts of mercuric oxide. Accordin4y, the reaction of
cyal'>propano deriV&tiTS3 With HI*C'3 (I), which is known to add readily to
,olefins and other un"turated ewpounds, has becan of considerable intere,st.
It iras found that (I) actually Inry readily adds an to aryl- and sliql-
substituted cycllop~~nee to forak the corresponding organotrichlorogermanos,,
for example: R-JQW-"+HGeC1 ---4PCY1.;r.* (R)CHCH CH-Thuso the reaction of
- ~&10 n8P
0.1 X phenylcycio~~s wiza 0.'D5 A (I) (Z:1 0 25 alnutes) laide to
I-phanyl-14trichlorojerwl) ro ane at a yield of 12.6 V%m* 65%)s boiling
~Voint 1,25-1260 _(a M)s nBP'1..M?1j Ef found 35.0,.Galcia M%e (JPRSj
SUB CODE: 07 SUBK DATE: %Jin65 ORIG REFS 002
W,FFI)OV, C.M. ; 'Jlr 1 ' ~ :~~ , - N'. 'I . ; ",Yt 'I, '- - '
'I .. -,, 1 * 1 Vi ty , , -~, -, ~: 9 1! -) " , ~ - ~ .! , , , ~ . I I - .. -
s , -.
v- t I ,nF, . :,ok : . AS .,. ~ ;I ~ 11 t , 7: () . ~ -, -08 #- 'I , il, A'. f t 4 . I I : ,
I . Instir.-it iko Lm. I [,.~>Itnsk ,, -N ~ '~ I
3ti~mi t te-l k, - ' - 11 , 1 0; .11 .
F---' (IV C). Y'. t N: K.; Y.
Ins t,1 .r rqr r., .-k K ,T 1 T "r r.-.K
ii~ kh'. mi I I, r ~ r -Any kt.
_nFUX!j. -SKAYA, U.N.
, _Rttjy,.IVASHFNK0, A.A.; WV1T
r.. Cc%
Preparation of cyclo-1,3-heptadlenes from n--.
Izv. All SSSF. Ser. khIn. no.9rI716 165. ~.~GRA '-Pig)
1. Institut orgunicheskcy khImII im. N.D. Zelinskog-) Mi ~533R.
XWT(.E)/SPF( )/Ew(j)l 'T
Acc a$'. =MCI 0=8 wdf/owAn0ow/bw
0.
AUIMMv
TnZ&s* NsUM hr obtalalm. m orawdo Claw 39a lb. 173951
pooth =Whwt no. 169 1050 05
2WM 2MMe *swum# POUIMS ONOMMOt
Mrftal this AmMor CortItUate proments a m~UM fw obtaWmg gormwdm Grp*-
ic P61pliffe * rems"m amWLm with voisetwated allpW&le sawowands In
Wpolm Urovial WIT"o filmoresse Mo warl"y at startft *=VsvNds# at*"=#
ad 64~ we used as oow#swdoo The
ilm savud'-sit at a-30C.
m aml, 07/ 21ANA
Card IA 6160"ISWAIP I
0. oV
"III L!
NOVITSKAYA, N.N.1 ISAYEV, I.S.; NEFEDOV 0.14.
I-.,--..-
Study of the mechanl3m (of monocyclic hydrocarbon formation
in the pyroly-Is of 7,7--dichloronorcaranes by the tracer
technique. Zhur.VKHO 10 no-4:459-459 165.
18ill)
1. Tni3titut organ J ~! hes k,.,3r khimll
PJI SSSR I Novoslbirskiy Insiltut
Slbirskogo ctdeIenlya All SSfR.
(MIRA
inmnj N.D.ZelinBkogo
orgapioheskoy khImII
r vp O.k.
.ion of tri at the 11 irl, *.I c rMilt! Qi!
-ds. 10 no-4.4-,'J-479 ' ',5.
(Y] RA
'K~,r, rwri N.f).Zf- ',I nskogr
NET -J, rllvj O.M. - I-, A - ,
A
P-,y-m3tion of -.a rt*ness In !nt rF~a i '.on , f 1, % -. -- , ~ . y -,r n -
M-Ithanoa wit,-; "w"A' I: '~ . - '; , '1r , z .' . :' I'.' S f:F , s e r - 1. 1 ~ = ,
c.o. 12 a 2209--2-'- j,~ ', 1. '!~j ~-.' ~3~ .' )
.i . InstitiO. ~rgftr.'. Pr .;t.. - -i , N ~' , " ~- .' t, F ~. v, !~ ~ F, .
31;bmi , Led '~ p - . : '), -4t , .
1 10673-66 - E-Wr (AAAMOW-HRL MXM
__ACC NRs SOUKCZ CI?Dlg: UR.10020/65/1(A/004/0622/0025
..AUTM: a cargo G. sft' T.; mig ev, v I
god".
?Z~
Ins, itut drago
MG: tauts a# Organic Chemistry La. N. 0. ZG1LnGkLv (Imt 06skay
khimii)- ousciances, VmRi*wdampost
Ingmante Chemistry Research Acadew
(Ise ledovdt~_l 'ekkays GrIAW.00 neacpaLchmakoy khimLL Ak&4e,uiL Sauk TM)
T A t I degradatf.
rm: ~:Stcisctura 8v _40f cycltc and linswr Polymer
silit" and! diamthyl
Soung: M: UIR DAlady, v. I", no. 4, 1963t 622-625
TOPIC TA109: orsomellieft compo"do,or'"notermalum compa"d. Pyrolysis
ALVEMs, As 119 IWO ~amd me&-speetrointric study.of the soluble part of the pro-
ducts ths' reaction Of 0113)ISLCIZ with Ifthim La tetrehydeofuran
showed that ft i t mainly of Ctystals' malting'sit 228-231C and foraLus
the Cyclic V0117-98'r-1. 3)ZSLqt:_/A- SUdlarlys a 10068'spectrametric analysis can-
fknod that &b6 sommium poly;w-;. walting at 20.7-209c, also fens the cyclobexamsL4
VC43)208 C-1 Pyrolysis of dimathyleLtylene and dimathylgaWleme at moderate
tempecatureal;P to 350-4m) laws imstaly, to the rupturf of bonds to this
formation of amerfel diveric, and pakmeric bleadicals:
Cud
L 10873-66
ACC M
Ob C16 C16
where M $I or Go; k 0-4 oc mace; a-.*1(?)p4-6 sad wace. Is the absence of
..special acceptormA. tb*se biradicals. recombine chiefly with me another, fotuing tbi
cyclic POIJPwtf L(Cv -:7u. The date obtained Indicate that pyrolysis of the
~Polywrs- L(cR3)2M4C-1,, where N - Si, Go, So, or ft, - cow be us.,ed so a general ustbed
of generating ~the corresponding c&rbemtds (CE3)21M-' - The paper we asented by
vj~ a
A. ftsduskiy, - Number of M SUR, 26 Mac 65. Authors. thank M'. . Lf Inkel 0. -A. S.
chotucow. &'ad O'CAomytom, foc carrying out the spfttco4copfC-4itGOdM4tLCM*.
Oryx--art.- has: 2. ml"*-
$us cow: 07 SM DM: I Ubc65 ORIJ; AW: 004 OM RW: 007
Cgird
NEnDOVP O.M.; KOLESNIKOV, S.P.
Preparation of orgariogerm&nium oligomers and polymera hy
reactions of trichlorogermine and its etherates with inna-
turated compounds. Vysokom. so"d. 7 no.11ilA57-1862 IN '65,
(MIRA ICI: " ,
1. Institut organicheakoy Khimii imeni N.D. Zelinskogo All ",S.T.
Submitted November 27, 196,..
27337-66 Ewr( )/Fwp(j)/r ijp(,c) at.
ACC MR AP6"962
sOURcz Oms UR/C-'90/65/007/Oii/1e5T/j062
J~6
i". AMMj 1101"'wX 0- U-1 Kolesnikov, So p.
ORO: Institut* of %wic Cho Idetry in, N.- Do 7,eljnsjjU,. Ag 56.3g 3_3
crpnicYea-W iMIL AN 33aR) _(Institut
olid,mere and POIPMrs by reactine
TI=I 'ptepwation. f
turAtOd compounds
gumnium trIchlarid: and lite staerateg with Una&
SOURCEt
Ty~'Dkmo'QWPWVYQ soyed~n`niYss v- 7, no. 11, 1965s 1657-1862
TWIC ?AGO$ Or6~4ic synthetio Frooems' 9"'"ium c=POUndp JH)1Mr chemistry
Geol StIcIM of now bet"Oe'liphatic and olef'A'O OrIMAOgerm8nium Oligoners
A&MACT I preW invesUPtOd by using gerlIsnium tri
and POIYRW6 has be.
2 IWOuP ftiab readily attack unsaturated bond Chlorides as & acu-eq of
isowtF146O)t 193-diews (kaba 16mo- lefind (-O-tbyleno
0/~ L- w
0001pounds, isopreng) is Iwo n4 OL p A -unsaturated
O"r'"* *f double bonds- While BIV10 others were used t
iup OASOmer as
801"At4- MW, chlortmated
to the GGIMM 8 and Polymers formed according
4.
L 27337,m"
ACC IR i-AP6000"9
R' R" CI
IIR' + GOC6 IRR'G-CIIR")
e
Go
where Rt t. and R" Rp a!IWI9 alkenyl, are pale yellow viscous liquids or white
powders having so p, frOM 50--70C (in me of 10-dienes)y or 250--3500 (in case of
CAI 02N , ieo-Cj&). The average molecular weight of the polymers was from 2500
to 6000" L The presanoe of labile Go-Cl bonds in addition to unsaturated carbon-
aaAm ba"s uQm'these compounds suitable fi)r a vsxisty of chemical transform&_
-to L. Ai laff"s
tione# ~ s'"me. euUwre ezpress their gratitude ani A. S. Khaohaturov
for help Aft pWfW~di* S"otr&l Q*,Jg# arts bass 1 figuret r~" p
and 2
4!41"
CRXff'-FM?o W61, M RMs W3
AM 27ol
144f
2/9,;
L 31366-66 EWP(J)/FjYT(m) RM ----I
ACC NR, AP6021098 SOURCE CODE: UR/0062/66/000/002/0201/0211
AUTHOR: Nefedov, 0._M.. Kolesnikov, S. P.
ORG: Institute of Orianic Chemistry im. N. D. Zelinskiy, AN SSSR (Ingtitut
organiclWa-k-oy- kh1mii -W 5,-ZH )
TITLE: E~ ~~-,richlorogermaniumlas sowcos of germanium dichloride -- a
germanium analog of d.'chlorocarbene
SOURCE: AN SSSR. Izvestiya- Seriya khimicheskaya, no. 2, 1966p 201-211
TOPIC TAGS: ether, organogermanium compound, orpanotin compound, halogenated organic
compound, halide, analytic chemistry
ABSTRACT: A staly of the physical and chadcal properties of etherates of
trichlorogenuinlum wd other trihalogen1d" of gamantus and tin show that
they have a carbenold character and my serve In xW reactions as sources
of corr"poWift dibelagenides of gerwanim or tin - Inalade analogs of
dihalocarbews. the garm"us diddarld" wA dilwaddes; gakwated In this
veyo we was reasUve than the awAmwis saybeadds 0*1 a and &dM2* T"
othersto of sexpeatle" 2(Cjx5) -MCO~ Is a v4stiles elly gressilsb4sUev
UqvdLd. Insoluble In "her md orgentle esibmte. and dessupee" "we &AD-
tillation or prolonged 3torage. (JPRSJ
SUB CODE: (Y7 / SUBM DATE: O3Aug65 / ORIG REFt 020 / OTH REFs 007
el UDC 1 U3. + 5Q-2m
'L 31893-66 EWT(a)/EWP(j) MM
ACC NR: AP6012526 SOURCE CODE: UR/0062/66/000/003/0443/0452
AUTHOR: Kolesnikov, S. P._i Nefedov, 0. M.; Sheychonko, V. I.
ORG: Institute of Organic Chemistry im. N. D. Ze1j.nskiy, Academy of Science SSSR
(Institut organicheskoy khimii Akademii nauk SSSR)
TITLE: Ilorp
Reaction of trich &oLrmane with aromatic compounds and uncatalyzed addi-
tion of germanium chlorr-form at arom tic unsaturatel bonds
SOURCE: AN SSSR. Izvestiya. Seriya khlmicheakaya, no. 3, 1966, 443-452
TOPIC TAGS: organic synthesis, aromatic hydrocarbon, germanium compound. deuterated
compound
ABSTRACT: Germanium ch~loroform displays extremely high reactivity in addition to
olefins and'acetylenesjin the absence of catalysts and generally exotnermally. Two
of the authors reported previously [rav. ZN SSSR. Ser. Khim., 579, (1965)) addition
of HGeC13 to alkyl- and arylsubstituted cyclopror)anes with opening of the three-
membered ring and formation of isoalkyl or aralkyltrichlorogermanes. The article
describes addition of HGeC13 and along the aromatic unsaturated bonds which have not
been investigated prior to this time. It is shown that the reaction of germanium
Card 1/4 UDC: 543.422 + 542.91 + 661.718.66
L 31893-66
ACC NR: AP6012526
chloroform with a number of aromatic compounds proce-ads quite readily at moderate
temperatures and without .--atalysts, contrary to the experience with hydrides of
cther elements of group 1VB. The addition occurs not only at the olefinic and
acetylene bonds, but also at the aromatic double bonds. Addition of HGeC13 to naph-
thalene was -accomplished by single heating of equimolar mixture of reagents to 100-
1300C for 10-25 min. The reaction proceeded by the following scheme:
+ 211 GeCis GeCJ, CH3MC81
Gecl, CHOM
M
:n addition t b*s(t ' ethylgermyl)tetralines methylated reaction products of HGeC13
IT
with naphth W4,econrtaining high boiling germanium hydrocarbons. Reaction of alkyl-
Ll- n
naphthalenes wit germanium chloroform proceeds ever tasier than with naphthalene
t
and results in formation of isomeric bis(trichloTogemyl)alkyltetrahydmnaphtha-
.Lenes. In contrast to pnlynuclear aromatic hydrocarbons, benzene and alkylbenzenes
do not add HGeC13 (even after prolonged boiling), M introduction of electron donor
alkoxy group into the ber.zene ring promotes addition of germanium chloroform to the
double bond of the benzene ring:
Card 2/4
L 31893-66
ACC NR: AP6012526
OR OR OR
+ 311GeCt, c1,
NO
It was also found that HGeCl-l can be added to heteroaromatic systems. It was reacted
exothermally with thiophene ~ roducing isomeric bis(trichlorogermyl) tetrahydrothio-
phenes. It was concluded that introduction of electron donor groups (CH31 CH30
C2H50) onto the ring facilitates the addition of HGeC13 at the aromatic double bond
while electron acceptor groups such as halides hinder su::h a reaction. This indi-
cates the electrophilic natur? of the addition reaction .)f germanium chloroform to
aromatic compounds. Such an exclusive nature of germanium chloroform among hydrides
of group IVB elemnts is explained mainly by the strong acidic properties of this
compound. To evaluate accurately the acid strength of HGeC13 and to determine its
reactivity as a function of the basicity of aromatic hydrocarbon, experiments were
conducted on deuterium exchange between DGeC13 arA the benzene series hydrocarbons.
Experiments show that while with toluene deuterium exchange does not take place even
during 1 hr mixing with DGeCl3 with more basic hydrocarbons (mesitylene ' sodurene)
DGeC13 acts as a strong acid c-3pable of rapid deuterium exchange. IsotogZ exchange
Card 3/4
L 31893-66
ACC NR: AP6012526
data indicate the tendency of HGeC13 to ionize. The auth~,rs thank V. A. Koptyug and
MI. I. Gorfinkel' for assisting in the experiments on deuterium exchange and for the
d-1-scussion of the results. The authors also thank M. G. Voronkova for commenting
on the reaction mechanism. Orig. art. has: 3 figures and 1 table.
SUB CODE: 07/ SUBM DATE: 03!;ep65/ ORIG REF: 010/ OTH REr: oo4
Card 4/4
L 31887-66, EWT(E)/SWP(J)/r IMC) RM
ACC NR; AP6012537 SOURCE CODE: UR/0052166/000/003/0584/0584
AUTHOR: Kolesnikov, S. P.; Shiryayev, V. _I.,_i Nefedov'0 14. q"
ORG: Institute of Organic Chem:Lstry__im. 14. D. Zelinskogo, Academy of Sciences SSSR
(Institut organicheskoy khimii Akademii nauk SSSR)
TITLE: Germanium dichloride cormlex compQund I
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 3, 1966, 584
TOPIC TAGS: germanium compound, complex compound, chemical decomposition
ABSTRACT: During the study of the reaction of HGeC13 with diethers it was discov-
ered (that contrary to the report of a previous communication (Angew. chem. , 76,
496, (1964)] 1,4-dioxane does not produce trichlorogermane ether with HGeC!,, but
that they react upon the liberation of 11Cl. According to data obtained from elemen-
tal analysis, IR, NMR and molecular weight, they produce a crystalline complex com-
pound of ger-nanium dichloride C4[1.0,-GeCl,. Foi-tion of C411602'GeC12 from HGeC13
and dioxane is a direct proof of ~h~ abillity of HGeC13 to dissociate easily upon the
formation of GeC12. The complex is stable in air and upon aqueous hydrolysis
Card 1/2
UDC: 661.718.1
L 31887-66
ACC NR: AP6012537
produces Ge(01021 is insoluble in hydrocarbons, and reacts with ethanol and acetone.
Upon heating, it decomposes at 140-2100C. With unsaturated compounds, the complex
produces gernanium organic monomers and polymers.I
SUB CODE: 07/ SUBM DATE: Moc65/ ORIG ITF: 004/ OTH REF, 002
Card 2/2
1 . r 1-1*~ .,D;, I) p .
2. T13H (6, -))
1, . ""Iectric btors
7. bavici for making the Aarting of a 3hort-circuited elect -ic motor
Khol. tekh. 29 no. 4, 1952.
9. Vonthl-,i L.3t of Aus:jian- Acce.-,L'Ons, Library of Congress, ,arch .95 1. Unrla3311ied.
NEFE DOV, P. G.
"Ways of' Reducir4 Labof --aiftwm I rw I rw ari(I C I,, rin I %; A, ~7rir. I I %. f~'
The Kirov District of LeningriLd Strives for Techw:.ogleal Progress; k7ollection
of Articles, Laningrad, Budpromg1z, 1957. 171pp.
Ibis collection of artleles describes the progressIve experience of the
industrial plants of the Kirov district of the clt.*f of LentrVad in the
fields of shipbuilding, machine bulldIN7, Instrumeat-nakIrW, casting,
hydrolytic and other Industries. New manufacturIng methods are cliscussed
IVLNGVP V.M.; OV., -
Experlmntal Jimatigation of the combustion of particles of natural and
exalvified liquid fuels. Trudy IGI 19135-45 162. (MMA 16s4)
(Liqtdd fuels) (Combustion)
t 116
GANA, N.Z.; DRABKIN, G.M.; KRISTOL, D.I., LAPINAGOV, P.I.; NEFEDUI, i'.K.,
SELUYANCII, M.P. ----
I
I Standard sections of universal multistory industrial buildingg.
!& Prom. stroi. 40 (i.e. 411, no.507-40 Ky '63. 'MIRA iW)
(Industrial buildings-Design and constructi n,
AO
GLUSKIN, E.Ya.; FOLYAKOV, N.V.; I'HOYNih, V.F.; USHAKOV, N.S.;
NEFEDOVI F.K.v inzh., red.
(OverFill mechanization and nutomatlon of Intraplant
transportation in instrumen-. plantii) Komplek.;naia me-
khanizatsila i avtorratlzatniia vnutrizavodskogo trans-
porta N priborostruenii. 2., izd., ispr. i dop. Mao-
skva, I-lashinostroenle, 1964. ~8~ P. (MIRA 17:i1)
SAMPYLOVICHO G.G., prof.; dELYAYFV, N.I., in2h.,- KUDRITAn, 5.M.,
dots.j GLAGOLEV, A.V.P inzh.1 inzh.;
GALKINA, Ye.A., fit. nauchn. gotr.,- PLINK, L.I., Irzh.i
DOlla(GY, I.P., prof., retsenzot.tj SAVELIYEV, V.V., kand.
tekhr- nauk, dots., retsenzent~ ALYSHFV, I.F kand. tekhri.
nauk, dots., rretsenzent; LOBALMV, A.N., prof:' doktor tekhn.
nauk, retsenzent; DOROKHOV, i3.A., inzh., red.
(Use of aerial photographic iurveying in forest engineerin,~I~
Primenenie aer-ofotoollemki v lesoinzheneimom dele. Mcinkva,
Leariala promyshlenriost' ,1965. 354 1,. Wli~A IF-.10)
1. Kafedra Bukhoputnogo transports lose 1,-motekhnichaskoy
akademil Im. S.Y.Klrova (for Alyshav). 2. Zamestitell giavncgo
inzhenera riosudarstverxogo instituta po proyektirovaniyu les-
nogo tranaporta (Afor Dorokhov).
IU,,Kv;DOvj kand. VkJin. naae.; .. ., it izh. ; II'C, it. ;t I " , 't. A., ill 7.yj . .
LOPUTHOV, A.Ye., irizi, A
Present-day methrl of' :ji_IvjrW, t:;o prulit., of the ,listrlLu%i~,r, r~-,
mass,ts of G,,j.,-tfj. 7 r -, r~:j , . ,; t.n, i . 11 ne . 4: 41-43 A i I
I k
~, D,-4 1,!: '. "
bi
Al Z.,
( Fc, J~ -
ffffmm, P. Ya., Candidate Tech Set (dies) .- "Producing cupola-furnace coke-
briquette fuel based on anthracite". Sverdlovsk, 1959. 18 Vp (Kin Higher
Muc USM, Ural Polytech Inst in S. N. Kirov, Chair of Chem Tvcb of ruel),
150 COPIes (KL, ND 24, 1959, 139)
WF7MAN, II.V.; NFFT.-,OV, P. ill.
Brijuet.ted cr)ke f,iel for c~jprla furnaces. K.4-3 i krim. no. -,,:
31-34 '-'~4 - K-PA 1-:4
1. flrqllskiy poIiL--.khnIcheskIy Institut (for roftman .
2. Vogto