SCIENTIFIC ABSTRACT NALBANDYAN, A.B. - NALBANDYAN, A.B.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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NAMANDYAN, A.B.
Keaour='~t of the quantum yield in the oxidation of aqthans,
senBitized by iftercury. Dokl. AN Arm. SSR S) no-3'.101-103 1480
(Kr2A 9:10)
1..Dwtl~ut khimicheskoy fisiki Akademii nauk SSSR, Khimichakiy
inisiiut Akademii'nauk ArVauskoy SSR, Kosic7FL-Yerevan. Predatavleno
I.I. Semenovym.
(Kethane) (Oxidation)
NAiZANDYAN, A. B.
PA 56/49T22
WWChemistrl - Photochemical Reactions Dec 48
Chemistry - Oxidation
"Mechanism of the Photochemical Oxifttim of Vathane
A. B. Nalbandyan) IAb of Kinetics of Photoohem ;
Reactions, Inst of Chem Phys, Aca4 Bot U36R, Moscowt
lov, pp
"Zhur Fiz Ehim7 Vol MIP No 12
Discusses (1) experiments under fixed conditions,
(2) quantumoutput of the reaction, and (3) researc'h
onIntermadinte -?roducts of the reaction under dynamic
conditions. Submitted 22 Apr 48.
56/49T22
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WALBANDYAN-r-A,B, -~ Editor-)- - -- --- -- -- -1
A conpendium of work on kinetics of oxidation chain reactionst including oxidation of oxygen,
mechanism of low temperature oxidation of carbon oxides etc; published by the Adademy of
Sciencesq USSR* i goreniia vodoroda The machinery for tho oxidation and combustion of bydre-
gen 14ookva, Izd-vo Akademii nauk SSM, 1949. l?8 p. (52-28543)
QD 181. HlN2
TJAWAND)~Ul, A.B. & V- V. VOEVOI)SK-Il
RT-1158 (The process of acidation and combiistion of hydrogen) 11reface, Qhapters I a:e II
(pp.) 3-41) of:
IMIMITZI-I CKISLENIIA I GOUMTA VODORODA L"oscoirr-Leninerad', 1949-
1,UUM1DYA11J, -A. -B. ---- --- --- -- -- , - --
"Mechanism of Photochemical Oxidation of Ethane Sensitized by Mercury," Vest. Ak.
Nauk, No. 6, June, 1949. Discusses new methods of microelementarj analysis developed
in the Laboratory of Quantitative Microanalysis, Institute of Organic Chemistry, Acad.
of Sci.
It 11 Is 11 if Isda 1, a 0
Is I Is I
Is A it J- -1 1- A -2 it cc MIL
A
I ,
of the products. A. It. Nalbarec.111211. DOIJI -I It is'l[blis evident I hit Co if fill C(;t., re
Ila Inverilkation I try pn.ltwi a
of detorillin. Ott tile 116111,11111, blamed AhlPhelli.
:0 k4y Allied. Xljok N.-S-S. R. 66- 413 VIIAIII Itature, .4 tile le.ictiml k I,v tile I"
P0`;- 4h- %Atll- will' 119 "14" a' cirair .4 file ifilit. 44 Ahlorhydr, %ah it., ls~mv . ofm-, 41
I lie III
And 941100ftl 14? 4 1111-0118 lilt 14131 of ;011), all.) - it XJ we,. I." ~Um Am. 9 1. 111, amt.. 4.1 JI.Ir
00 W noll. it. air A lillivil ... 14.1 jKo doV, %el,wity v. At lite - hydes at 2S. 190. wid 1:10 were 0.118. 3.21S. aml XW IV..
I lowest v - o.t)l the products were N.1 cc. *lite- -
09 - The yiclds W Coe k resp. At coust. tillte CIF illuillifution, the yield tit mahle.
hydell. W cc. CO. cold ILIW cc. Co. OlIdi-Arl-ruring Ilydrs Is prollisivillenal III 113P MI'Llre 1,44 Ott file Inkmity.
d of CO Isill vv1Y fi-t with 111cm1i'llf r-
altog"lwf at About r - it. CO fit 13 cc-Allito consequently. tcirvakiallon tit the r1mim ovi-m, thf-Aigh te,
he yield rtsitibincilloo col the chjle cirrier. ice tile v..I, Ittroarner .4
60 a6laldithydrs lost hicir"atva fes"'ItIchAt with v At very Im "P ,is- Pt"'Zill" WAS daItMted; their 'Line. 41CCICAW4 %CFY
00 -3 1hens &lit, Imssing thnough it mAx.p dmfOrAws ctRitintiallY acj,
with furthcr incereAsini %d`jwIl to I vol. ~; of (he Cilia IY linearly with luarazingr; thuj,at.,jj(j*. (or (WI cc.
pailmd at P - 42 cc . The ratio of IICJI0 to AM Call$ P45", At v - 0, IM$, still 210 m.ejidii.. the oti.,q
I'll, nf,
MnAin, appeals. mactst. liltelselidelitly of R; thill. f4mr Is. lit licrolfil" Jointed Waim. r"ll.. 4m, :1. 1, And 2,11 x
00 111". the 130. -A' aldch~,de
000 2,j cc, paurd tile glotle. tit IICIIO and Act[. field. liothor-1-
graphically. writ. at If 7-354"d lr*ll - ,(%,fly ex).111troll.11 V, M. I x It 14, 1. ;111.1 1 N
60 D` 2 and ).all. I.lrj ^11d U.I..J. JI.L1,1 &list IV. It J11116-All'. I00. With hirma%I118 1'. tile ?.III., A I.Iolldvi I"
ItAt of the 2 tracti-1114, Call. + 115VII.) - 2 ellm t hYdric, llivma~- At very higil r, I v.. *.rry %hitf, I. 1),,f
Sit oxidrs should lk-Onle tile ottly ittivnimimir linklilt-tS. 10)
anti Cilia + Ilselp - Calls + 11 + IIX(i. the rachl'i'm of Uldcliv.1m Thir feadjon Al'itcul, Its Ill.,.
the drift is the rstirr "'M In t"nis .1 the titue III MAY r
la the firradill"I scene, tile Octal. of C,11. rt"Isatilvi I. eved over org. r4dival%. loirming liensihicri Merritt with Ila
Coen On I a straight line; tile mint. Of Allichyd" tins. anti then Stable liennitles *file C,I I.; lite tit4ble lictimi,jr,
""' I I " r4cird lit lilt,) 41.1rhydr. "Itit'll, m wnfler hma
ductrit Macilleg aticactly *1111 thit III file Call$ I A
Jkleit r 0 10.35 -2 Kv., but then it levrls "a to a value ,Cry CO slid COO.
nearly C*n$t.. while tht hielf-11011111 Of CO + COO. StAftilit
from jem at r - 2 sec.. riws vefv neArIv linri,lv with r.
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USSR/Chemistry - Photochemistz-Z 21 Jul 49
Oxidation
"Mechanism of Mercury-Sensitized Oxidatio-a of Propane.," N. V. Fok., B. B. Beres.Lavskiy.,
A, B. Nalbandyan, V. Ya. Shtern, Inst of Chem Phys, Acad Sci USSR, 3 PP
"Dok Ak Nauk SSSR" Vol LXVII., No 3
Formerly, high temperature necessary for Dhotochmeical oxidation of methane and ethane
prevented any sub$tantial yield of peroxides and aldehydes. Here, yield of these products
was studied as a function of time of exposure in photochemical oxidation of propane in
temperature interval 20 - 3000 C at a pressure of 50 mm of Hg. Results show peroxides are
a primary intermediate product (with respect to temperaturo),q while aldehydes are a
secondary intermediate product. Submitted by Acad N. N. Semenov 16 May 49
Pa. i5oT13
'k. B.
USSR/Chemistry - Fuels Aug 52
Rea6fion Kinetics
"Inve stigation of the Com position of Pexoxides Formed
in the Oxidation of Propane at Room Temperature With
PhotQchemically Sensitized Mercury," N. V. Fok and
A. B. Halbandyan
"Dwssse vol 85, No 5, PP 1093-1095
On-the basis of chem and polarographic analysis a~d
through the reaction of the peroxide vith various
substances., it vas established that the peroxide
formed during the oxidation of propane vith photo-
chemically sensitized Hg at room temp is isopropyl
hydrogen peroxide. Submitted by Acad 11. N. Semenov
23 may 52. 239T27
US5R/Chemistry - Fuels
Combustion Aug 52
ITeriodic Combustion Flashes in Mixtures of Car-
bon Monoxide and Oxygen," N. S. Yenikolopyan and
C\I A. B. Nalbandyan
"DAN SSSR" Vol 85, No 6, Pp 1309-1312
A quant description of the combustion observed
in a m-Ixt of CO and Q2 when a small amount of H
iq added by diffusion is worked out on the basis
of the reaction mechaaism and the coasts of ele-
mentary reactions caled from previous work.
When the pressure of the H on the membrane is
decreased and its Tate of entry to the mixt is
decreased, the time between explosions is in-
creased. By means of eqs derived from the mech-
iinism of the reaction, the article explains why
the combustion is only a flash and not a com-
plete burning of the entire mixt. Presented by
Acad N. N*. Semenov 14 Jun 52
All)
USSR/Chemistry - Fuels' Peroxides 21 sep 52
tI.The Mechanism of the Reaction of the Oxidation of
Propane With Photochemica;lly Sensitized Mercury at
Room Temperature," N. V. Pok and A. B. Nalbandyan
DAN sssR, voi 86, 110 3, pp 589-592
Propane is oxidized at room temp vith photochemi-
cally sensitized Hg to form propyl hydrogen per-
oxide. The reaction proceeds vith a preliminary
exitation of the propane mol. Presented by Acad,
N. N. Semenov 5 Jun 52
247T17
Nkeltar Sti.
FF
7..
This phi"hernical Ovidatlad Of a at bi to
Dolkdyllamd' (b.L
'foR
tutes. N. V, Fok and
Naub S.S.S.R. 89, IN'419_56~3,-T ethotochem. oxida-
-tion of CgH. was carried at 100-300*, for equal tnixts. of
:CtHaaadClatapressureofbOmm. At 100* Acil is present
An the reaction products~ At 200', along with Isopropyl hy-
droperoxide and;Afff, formaldehyde Is present lit the reac.
tion ptoducts-Walmoat, the s.1tino extent As AtIl, As the
4 temp. Is fiatifeltitrtutd, the ratio of formaldchyde to AM
Increases. Among the oxidation products at 300* are ace-
tone and CO. The exptl. results Indicate that the active
centerstr the photachern. reaction are the peroxide radicals
owhkh pirish an the walls et the reaction vessel.
Rmftir Leath
ri-e Camittee on O'Lalim i,rizen (of vae couricii of Minietere USSR) iii t6i fleldp of
6,~Ience and inventloas annamcee that the follcuring scientIfic works, rpc-,;ulax P-cllem-
Ivif iq b-.vokn ', pxd texLbcvXz havc brrn vicn.-It"d tor cempetiticn. tor Stailn 11'rizea for
tile '1952 aml ).91:"3 M-amuv, riL). 22-1,01, 2f) ?cb -3 hP7 19S';
71ilbanfl-,~an, A. P.
VOye--v,:,,llSk4.y, V:V.
T I t.;
of t', e
anel
Lion of
5,
Tnstit;.,tc r.f"
so. w.-3cm)4. 'I J,-dy 1954
NALRMYAN,A.B., professor, rediktor; EMAMMI,N.M., professor, redaktor;
CMMI t O.Y.M., redaktor; ZZlXff0V.A.Ye.V., tekhnichaskiy redak-
tor
(Chain reaction of gaseous phase oxidation of hydrocarbons] TSepnye
reOAaii okisleniia uglevodorodov v gazovoi faze. Kookwa, 19$5. 209 p.
(MLRA 1:1)
1. Akademiya nauk SSSR. Inatitut khimicheskoy fisiki
(Hydrocarbons) (Oxidation)
J. 'V
USSR/Kinetics Combustion. Explosions. Topochemistry. Catalysis. B-9
Abs Jour : Referat Zhur - Khimiya, No 6, 1957, 18562
Author : N.V. Fok,,A.B._Nalband an.
y_
Inst : Academy of Sciences of USSR.
Title : To Mecharism of Photochemical Oxidation of Hydrocarbons.
Orig Pub : in the symposium Tsepnyye reaktsii okisleniya uglevodoro-
dov v gazovoy fatsii. M., AN SSSR) 1955) 118-139-
Abstract : Review of works published by the authors earlier
(Nalbandyan A.B., Zh. fiz. khimii, 1948, 22, 1443; Dokl.
AN sssR, i949, 66, 473; Fok N.V., Bereslavskiy B.B., Nal-
bandyan A.B., Sbtern V.Ya.,.Dokl. AN SSSR, 1949, 67, 499;
Fok N.V., Nalbandyan A.B., Dokl. AN SSSR, 1952, 85, 1093;
86, 589; RZhKhim, 1953, 2853).
Card 1/1 - 233 -
USSR/ Physical Chemistry Kinetics. Combustion. Explosives. Topochemistry. B-9
Catalysis
Abs Jour : Referat Zhur Khimiya) No 4, 1957, L1220
Author : Kleymenov N.A., Antopova I.N., Markeitich A.N., Nalbandyan A.B.
Title : Oxidation of Methane by Oxygen Atoms Formed on TRFERI -Decomposition
of Ozone
Orig Pub : Zh. fiz. khimii-, 1956, 30, No 4, 794-797
Abstra6t : Formation of peroxide on oxidation 0:0 CH4 under conditions of flow
(mixture CH4 : 02 - 1:1, rate of flow 406 cc/minute) in the presence
of 1.45% 0 becomes apparent at the emperaturb (100-116o) that
itLn of 03 begins.' On same t auth
decompos thi6'basis the ors consider that
initiatoraction is'a6aociated'not -4ith the-O3molecule but with 0
atoms vhich are decomposition products of 03-
MMILOVA, L.V.; TENIKOMPTAN, H.S.; NALBABDTAR, A.B.
Kinetic study of thm Initial phase of nitrogen oxide
catalysed oxidation of methane (with English sumary in
Insert). Zhur.fiz.khim. 30 no.4:798-810 Apr. 156. (MLRA 9:9)
1. Akadamiya nauk SSSR, Institut khtmichaskay fiziki, Moskva.
(Methane) (Oxidation)
"r
----AIITC)TIOVA, M -B --FET-lI-.S0Vr, -G. --I.
"Tracer Study of the Mechanism of the Reaction of Methane O/idation,
Problemy Kin*tles -mrj'-' C6W-yeiis. v. 9, leotapea Is. CatalvvU9, W,4~cow,
AN SS&.o 11957, W12P.
Modt ef the psp---rc ln thlo enl,!e-.ttc,?3 vtre prask-raml &I- the; Crmf V-X3
-7 !4,,~s At
7 !r ll~ f, 1950.,
tv. C4-t-O-qir~ vOlhich t