SCIENTIFIC ABSTRACT MOROZ, L. M. - MOROZ, L. S.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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The first prize of 10,000 roubles(imni Do K. Chernov) was awarded to the following teams Professor So Z. Bokshteyn, Engineer To I. Gudkova, Doctor of Technical Sciences Professor A* As Zhukhovitskly, Doctor of Technical Sciences Profesvor So To Kishkin and Engineer L. M. Moroz for the paper "Investigation of the diffusion and'the distribution of components in a real meta:1 by means of radioactive tracers"* The work described IA this paper represents experimental and the&r-ectical-w--ork of fundamental importance on diffusion in alloys as a func- tion of the structure of the metal and the stress field caused by external action. A brief summary is given of this paper and it is stated-,that it is not only of major theoretical importance but also of practical interest, particularly from the point of view of the problem of high temperature strength. Results of the 1958 Competition for Obtaining imeni D. K. Chernov and Imeni N. A. Mnkevich Prizes, Metallovedeniye i termicheskaya obrabotka metallov, 1959, No. 6, pp 62-64 85379 g. AUTHORS: S/032/60/0e,-6/C 10/007/035 7:0.0 1 6/'BO-4 TITLE: Bokshteyn, S. Z., Gubareva, M. A., Kishkin, S. T., and moroz, L. Ni. Study of the Process of Iron R llization by the Method of Radioactive Isotopes Iq PERIODICAL: Zavodskaya labor-atoriya, 1~)60, Vol. 26, No. 10, pi~. '1'!-i1'4 TEXT: The authors studied the behavior of atoms at the grain boundaries during the recrys tall izat ion of" iron (content in 0.021 C, 0-014 ?, 0.011 s, o.67 Si, 0.07 Al. 0.08 Kn, m6 Ni, o.o~~3 cu). Sam~;les of this iron were covered with Fe59. In annealing, Fe59 spread due to diffusion at the boundaries between the metal grains. This permitted an observati,~n of the local displacement of atoms lying at the boundary during deformation and recrystallization annealing. Iron rods were annealed at 12500C for 8 h, and then cut into samples ('0 xl0v,20 mm). The riveted layer (70-80g) was removed by elentropolishing in perchloric anti j.-Jacial acetic acids. An Fe59 layer 1.0 p thick was electrolytically to Card 1/3 85379 Study of the ?rocess of Iron /O32/60/fO'-' Recrystallization by the I'llethod of 30 16 / L_ Radioactive Isotopes the polished surface. Subsequently, the samples were deformel by compression by 10-16~o (Fig. 4'; an-3 by 45-70" (Fi,. 2). Fi6s. 1 -,, j"'inw the /0 autoradiogram (a) on the left., anJ the microstructure kb) c'n the ri,:-..rit on microphotographs. During exposure the gamples were prote-te-A ~1 f4-17D 1 p thick (1% of Zapon varnisn in the solvent PAJ) (RDV)). a'c produ-e the autoradiograms, the samples were exposed for several days on ~,hotorraphi--- plates or films HWV,~A (NIKFI), type MP(MB). The autoradio,--rams were compared with the microstructure pictures which had been taken by a microscope of the type HOM-8 (MIY---8). Next, the recrystallization annealing was carried out (Figs. 1; 5-8). A Table on P. 1115 rives the hardness and the methods of treatment for scme samples. Or: the basis of their methods, the authors succeeded in observin-r the behavior of brain boundaries during plastic defcrmaticn and subsequent recrystallization. It was proved that iron recrystallization at relatively low (11,.%') and high (50-70%) degrees of deformation causes no essential change in the PCsition of atoms laying at the boundary of deform,,d grains. With a considerable structural change of the metal after -i double recrystallizatic,n. as well as Card 2/3 85379 Study of the ?rocess ---f Iran S/O 32/60/026j"J- 7/ Recrystallization by tLe Method of B-016/B054 Radioactive Isotopes after polymorphous a , y transformation, the atoms at the boundaries Cf the initial bodies are not displaced. 'In contr-,st with recry-s tall izat ion. plastic deformation i4j accompanied by a cinsiderable displacement of a,:-I,s, The results prove that the displacement of grain boundaries during recryntallization and the -jub:jequent growth of grains iii connected -Nith 11 specific mechanism which differs from the ordinary diffusion mechanism. There are 8 figures, 1 table, ard 1~ references: 4 Soviet, 1 US, 1 Dutch, 1 French, and 4 German. Card 3/3 S/129/61/000/001/002/013 Elll/E135 AUTHORS: Bokshteyn, S.Z.v Doctor of Technical Sciencesq?rofessor; Gubareva, M.A., Engineer; Kontorovich, I.Ye., Doctor of Technical Sciences; a Technical Sciences pq_For-oz,,_kM. I Candidate of TITLE: Peculiarities of the Diffusion of Carbon in 7ron PERIODICAL: Metallovedeniye i termicheskaya obrabotka metallov, 1961, No. 1, pp. 10-14 (+ 1 plate) TEXT; Work by two of the authors (Refs 1-4) and by others (e.g. Refs 2, 3) has shown that diffusion is often non-uniform. This effect could be associated with difference in the activation energy of diffusion (Refs 8-10). In this present work the authors studied diffusion of carbon in technical purity iron (0.0375' C) and iron alloys with 0-03Z C and 0.11+, 0.61+ or 2-93..~' Si. some alloys also contained a third component: 4-.56 or 3 Nis 0.36 or 1.61% Alt 0.88 1 3.77 or 14-13% Cr, 0.21 or 3% Mo, 1.19 or 4.97-'-' W, 0.1 or 2.29% Ti. This enabled the influence of carbide-forming and non- forming elements to be compared. Pr smatic s0ecimens 2U mm high and with a 10 mm base were used. Cl~ was depo'sited on the surface Card 1/5 S/129/61/ooo/001/002/013 Elll/E13 5 Peculiarities of the Diffusion of Carbon in Iron from barium carbonate or from special specimens containing this isotope. The first technique was used for studies in the gamma, t second In the alpha states. Auto-radiographs were obtained on he type MAK~V (NTKFI) plates, contact prints being examined micro- photometrically with a type MO-4 M-4) instrument. The diffusion coefficient was calculated by the method of Bokshteyn et al (Ref.11). Microstructural analysis was also carried out. Autoradiographs and microstructures for iron at 950 OC are shown in FIg.la and b. Autoradiographs at 550 'C for alpha iron (unalloyed and with o.64% Sit top and bottom, respectively) are shown in Fig.2a and b. Fig.5 shows plots of darkening, against depth of diffusion of carbon in the grains (top curve) and alnn7 boundiriei (bottom curve In each of the two diagrams), for ferrite k550 0--). The influence of Concentration of the differont ailoYing ele-onts on depth of diffusion (mm) in irnn at 95,~ cC i- ~;hnwn In Flg.6. Card 2/ 5 S/129/6]L/000/001/002/013 H111/H135 Peculiarities of the Diffusion of Carbon in Iron M. ~Al Jep 0 71 If$ 4 8 17 is ox-1044M Cr O.J. it 7 L Ali -9 0 so 170 ISO zwxlw'cm Fig. Fig. 6 Card .3/5 S/129/61/000/001/002/013 xll:L/El3 5 Peculiarities of the Diffusion of Carbon in Iron Fig-7 shows.relative darkening with respect to distance into ferrite grdin for carbide forming (left-hand graph) and non-forming (right- hand graph) alloying elements. The left and right ends of the plots re late to the grain boundaries; the remaining spaceg corresponding to 0.30 mm, relates to the body of the grain. A- Saw A.- I'l ru 0 0 % 1,17% w % 9,J Fe Fe Card 1+15 #.w O.Ze A. X tiff Fig.7 Vo. 9.19 0.19 S/129/61/000/001/002/013 E111/9135 Peculiarities of the Diffusion of Carbon in Iron The work shows that carbon diffusion in both alpha- and gamma-iron occurs unevenly, the grain boundaries and adjacent alpha solid- solution regions becoming enriched with carbon. The diffusion coefficient for grain boundaries is 3-1+ orders higher than for inside grains. Alloying modifies both rate of diffusion and distribution of carbon within the grain; depending on the effect of the element on the gamma region. Alloying reduces the carbon-concentration drop between the boundary and the body of the ferrite grain. There are 7 figures and 11 references: 7 Soviet and 1+ non-Soviet. Gard 5/5 BOKSHTEYN, S.Z. (Moskva); KISHKIN, S.T. (Moskva); LOZINSKIY, M.G. (Moskva); SOKOLKOV, Ye.N. (Moskva); Prinimnli tichastlye: PODVCYSFAfA, O.N.; ZILOVA, T.Y..; SOROKINA, K.P.; POLYk,, E.V.; MURCIZ, L.N.; BULYGIN, I.F.; LASffAO, N.F.; POKUESTOVA, Ir.N.; 5GADEF--YETA, I.A.; YAGLOV, R.V.; VOLODINA, T.A.; KORABL-VA, G.N.; ANTIFOVA, fe.l. Thermomechanical treatment of chromium-nickel-manganese austenitic steel. Izv. AN SSSR. Otd. tekh. nauk. Met. i topl. no.2:15-21 Mr-Ap 162. (MIRA 15:4) (Chromium-nickel steel--linrdening) '00 -55 AUTHOP3 Boksht eyn 3 Z , Doc tor of 1'echnical ~~c i etic e- Professor Ki shkin . 6,T,, , Corr rs pondi riv Membor )I iio Academv of Sciences and '-Ioroz L (:,111didate C'I Technical Sciences i IT 1. E Influence of* carbon on the movr~mont L)l -zratn boundaries in the re crystallization of iron PERIODICAL Metallo vedenlye 1 termicheskaya obiabolka metal1k), no, 3 196 2, 8 - 13 T i,XT LfAcke and Detert (Ref'.. I - Acta Metalturg v.. 5 no 11 195 7 ) and Beck (Ref. 2 - Metal Interfaces C I ev e I and A~i,%l 19 5 2 consider that there is a sharp drop in the speed of recry9talli - zation when the concentration of an impurity reaches some critical value iabout 0.0100 below the solubility. Impuritie5 forming a second phase also retard the growth of' recrystallization centres,, Using their radioact ive- isotopes technique (i?f~t. 6- "Zavodskaya laboratoriya. no. 10, 1960) the present author5 and N1 . ..A, Gubareva have studied the influence of carbon on the behaviour of grain boundaries in the recrystallization nt Card I-A VI Int'lu-nce of carbon on t1Ll/F)-)5 t ec tin ic a I - gr iid c- i rLn - C a r b o n i% a -3 c 11 os c- n a S a n e I t-m --rj t pr a(, t i c a I I y 1 nzn o I ub I e i n a I pha - i r on I [ 1~, KJIC,1~11 I o I v, I a n L t I c r c a 5 e i n r h e Ac t i va i i on en orgy o t r oc 1 1, ~ I it I1 11,11 I'M C', i r on a nd , i I p r e ~3 e n t i n (I u it I] t I ( I es ev ('11 --i I I gil I v 1 11 #-xC r-S ('t solubii1tv to PrOVent c of I t-.c t Lve recryst all izat j tm 1) ZA I i I (. k I lariv at ~1;0 - 7 () u OC ~ :m(,c impnz: were' sat ur cAt e J ~~ L t n' c iir h on from donors at -1 0() OC t o r 2 tiou r -i The helia-lour o I ( arbon atom~i at iron-gra in boundari es was f o1 lovied di rec t I y d i i r 1 11 deformat ion and subsequent recrystal I izing anneal ing g Recrystall ization wag StUdl ed on qpf-c imens 10 15 and 7)u del ormed t iie f ir st beinQ i n I ac t c I oF v t o t hf, r i ti va I u r Autoradiograms obtained belor t- and a ft t-r d t-f oi am t i on III' f. , ();,I par ed From t h i s and t lie m ic ro-3 t ru( t Ul-e ~ he hPhaV L 011t 0 1 t h f- c ~i rhon %,as eva I uat ed - I'lle sizes of all gr,iiri- Inc 1 ot--, ~! ' rr deformation. heating to 550 OC lailed to rocr%-t.il lization but grourth of alpha-phase grains occiiired I h(111 tended to move toward5 grain boundaries even then t h i mf-i ill going int o it region of hi ~,hor ( orhou conc ent I ~t ion -1 !~ 'k, r e1. r %-sral I izat ion was a lmost Comp] el t- t 1) 0 L ~ I I holl I f-Mil 1 11 1 H V .1! ~-ard 2A Int-1 ueric e of carbon on El 1 ]/E7,55 the g-,-airi boundaries produced after heatint,,, ot -)')u0C- Althoii,zh recrystailization was pract icall,, in~iojiton(-oil,, -,)Mplotelv new fine-grained structure was product,d 0"I t I r1 Q t )U C produced growth of recrystallized griins in~! mnvmnen! not always. complete , of carbon to the new gri-st n hoiiivior i t-- decrystallLZation anneiling at 700 C for If5 111111 ot lmon, after 131. deformation gave little change L11 micro~t I 'L~- tilt (, carbon moved from the boundaries of deformed graiti!~ tk) those of the neti;- recryEtallized grains. The -int'luence of' the alpha- gamma transformation on the behaviour of carbon jtom-s loc,ttfd a t ex r, o r i rii eri i bourtdari es was studied in another series of For this purpose specimens vc-re heated at 950 0(. fo'r I hour Completely new grains were produced, the carbon both migrating to them and forming large accumulations of carbides. It 1~; e-ident that the behaviour Of LM[)U1-1ty atoms located at bOUndilries and forming i.nterstitial sOlUtLO11S Is vorv different from that of boundarv atoms of' the base element. as shown previou:ily (Pef,. 6), boundary acoms in iron recr,,-StallizatLon k~ard -VI - I r, I I 'A v I I c (- ~, I carbon on . ~ . . I., I I I / F,-; -~ 5 ( c r 1, o i ,, m (, r ph 1 c t ra n!~, f o r ma tion) i emain in 1, III\- III, 9 a rii e p C) ~ 1 t 1 0 ri ,carbon atoins fol lot. new I %-- I orm(~d v r 1 1 n b o u n (l a r -i e s . f 11 t- r - i r- c () I i ~! 11 r es a ri d I t , i ii I r. . ,-arci ;[/-'I .x 9/129/62/000/009/001/006 E071/E492 AUTHOPS Bokshteyn, S.Z., Doctor of Technical S.ciences,Professor, Bronfin, Engineer, Kishkin, S.T., Doctor of Technical Sciences, Professor, Moroz, L.M., Candidate of Technical Sciences TITLE: Grain boundaries on recrystallization PERIODIC\:,: Metallovedeniye i.termicheskaya obrabotka metallov, no.9, 1962, 6-8 TEXT: This is a continuation of earlier work ("Zavodskaya laboratoriya", no.10, 1960). The behaviour of W, Ni, Sn and C admixtures present at the grain boundaries dur 'ing recr-ystallization of iron (().021'. C, 0.01,4~~' P, 0.011-6 s, o,670, Si, 0.07',, AI, U.08% Mn, o.0600' Ni, 0.033*,, Cu) was studied by autoradiogranhic investigation and microstructural analysis. The admixture S, forming with iron substitutional solid solutions in the case of W, Ni, Sn and interstitial solid solutions in the case of C, were in 'troduced by diffusion saturation at 600 to 7000C. The recrystallization was carried out after preliminary deformations of 10 to 15 and 50 to 70%. The Ni, W and Sn were completely Card 1/3 S/I 29/62/000/009/001 /006 Grain boundaries ... E071/r,492 soluble in iron at all recrystal-lization temperatures investigated and remained in their original lattice positions, despite substantial changes in the structure of the metal. The behaviour of carbon a toms wits SUbstantia I ly clif feren t : above 7500C carbon passed from the boundaries of deformed grains; to the boundaries of new recrystallized grains. However, in the .L initial stages of recrystallization (after 30 to 45 min at 650 to 750 aC) carbon atoms remain at the boundaries of t!i, grains and boundaries of the new grains remain free from carbo:1. The possibility of "heredity", i.e. preservation of the inLLi.ll 5tructuraL and concentration non-uniformities in recrysta'117f-O metal was demonstra ted on a molybdenum alloy (0. 54% Zr, 0. `0 0.0008", Ti and 0.011'~ C). A thin layer of tungsten 185 electrodeposited on the surface of a flat specimen of the alloy, submitted to a preliminary annealing at 17000C. 111c. activated specimen was then annealed in vacuo at 17500C for' 100 hours. Autoradiographs of an oblique section showed the presence of an accelerated diffusion not only along the botinc!aries of the newly formed grains but also a preferential penetraLi~-i oL' Card 2/3 S/129/62/000/009/001/006 Grain bo6ndaries ... E071/E492 the W185 along those sections where old grain boundaries. wore passing be."ore recrystallization. The velocity of diffusion along the old boundaries was lower than along the new boundaries, nevertheless it was noticeably faster than.volume diffusion. The results confirmed that within the grains the process of grain boundary mi-gration does not pro-duce as high concentration of , and at the end of the defects as is produced at the"beginning boun&%x-y migration. There are 6 figures. Card 3/3 BOKSATEYN, S.Z.; KISHKIN, S.T.j HIKISHGV, A.S.1 POLYAK, E.11.1 SOLOVIYEVA, G.G.; Prinimali uchastiyes ARWAKOV, V.M.1 BULANOV, A.V.; VERTYUKOVA, L,G.1 KORABLEVAj 14IRSKIY, L.M.; PODVOY3KAYA, O.N.; SAZONOOVA, 7,N.; SOLONINA, O.P.j TITARENKO, I.I.; RINK, L.P.; KDZLOVA, M.N.; YERMOLOVA, M.I.; ~C.ROZ L~~M. Aging of plastically deformed alloys, Metalloved. i term. obr. met. no.5340-" MY 163. (MIRA 16-5) (Heat-resistant alloys-Hardening) (Deformations (Mechanics)) ACCESSION NR: AT4013954 S/L659/63/010/000/0214/0218 AUTHOR: Bokshteyn, S. Z Kishldn, S. T. ; Moroz, L. M. 77TLE: Condition of grain boundaries during recrystallization SOURCE: AN SSSR. Institut metallurgii. Issledovaniya po zharoprochny*m splavam, v. 10, 1963, 214-218 TOPIC TAGS: metal fatigue, steel grain, recrystallization, grain boundary ABSTRACT- The present investigation dealt wit1i two problems: First, whether or not the atoms of the initial grain boundary serve as the boundary of the newly-crystallized grains and second, whether or not the initial grains leave traces of their inadequate structure, I. e. whether their inadequacies are completely eliminated during recrystallization. Radioactive isotopes were used for the Investigation of the grain boundaries during recrystaUization of molybdenum, nickel, iron and Iron containing various impurities. The results showed that the atom a of the base metal grain boundary do not take part in creating the grain boundaries of the recrystallized metal and that the boundaries of the recrystallized grains inherit some of the structural features of the initial grain. Orig. art- has: 3 figures. ASSOCIATION: Institat metallurgil AN SSSR (Institute of Metallurgy AN SSSR) Caw ACCESSION N11: AT4040411 S/0000/G4/000/000/0074/0094 AUIT11011: Bokshtcyn, S. Z. ; Kishkin, S. T. ; Moroz, L. N1. TITLE- investigation of the conditions of the grain boundaries during recrystallization of iron and its alloys SOURCE: Protsessy* diffuzii, struktura i svoysl-va mettallov (Diffusion processes, structure and properties of metals); sbornik statey. Moscow, Izd-vo Mashinostroyeniye, 1964, 74-94 TOPIC TAGS: iron, iron alloy, steel, tungsten steel, carbon steel, steel structure, grain boundary, recrys tall ization, iron microstructure, carbon diffusion, tungsten diffusion, tin diffusion, nickel diffusion ABSTRACT: There are still unclear aspects of the mechanism of recrystallization, such as the nature of the reconstruction of grain boundaries, the formation of ne%v grains and their Subsequent growth, the influence of impurities, and the role of diffusion. The present authors investigated recrys tall ization of iron in specimens previously subjected to a plastic deformation of 10-16 and 45-70%, involving a variety of heat treatments (anneal- ing at 720--800C, recrystallization at 700-1370C, additional heating at 700-950C). Data on microhardness before and after these processes are tabulated. Furthermore, recry- Lrd 1 /4 ACCESSION NR: AT4040411 stallization was investigated on specimens of iron in which impurities were located at the iron grain boundaries, formed a part of the solid solution by replacement or formed a part of the solid solution by penetration; here again, various degrees of plastic deforma- tion and various heat treatments were applied. The impurities tested were carbon, tin, tungsten and nickel. Finally, radioactive isotopes were used as tracers to observe local displacements of atoms by radio autographs, as well as by photomicrographs and X-ray radiographs. In order to study the behavior of base-metal atoms, the isotope Fc59 was used; for the behavior of atoms of a.- alloying elements, a corresponding isotope of the alloying element was employed. Test specimens 10 x 10 x 20 mm were cut from iron bars previously annealed (1250 C for 9 hrs. ) in order to obtain a homogeneous structure and a coarser grain for the convenience of radiographic investigation. After cutting, the work- hardened surface layer (70-80 microns) was removed by electrolytic polishing. The radio- active tracer was deposited on the polished surface electrolytically. Diffusion annealing was carried out in a vacuum furnace at residual pressures of 10-3 - 10-4 rrun Hg. The temperature of diffusion annealing was 720C, at wMch the influence of grain boundaries on the diffusional flux has been found to be particularly pronourced. Deformation of speci- mens was carried out in a 200-ton Arnsler press. An analysis of the experimental results showed that atoms of soluble impurities (nickel, tungsten, tin), like the atoms of the base- 2/4 ACC1'SSl`ON NR: AT40,10,111 sliov:ed that atoms of soluble impurities (nickel, tungsten. tin), like the atoms of the base- meLal, practically remain at their initial locations despite significant changes in the micro- s~ructurc of the metal. Prolonged annealing at recrystallization temperature (78 hrs. at 700C for iron with nickel; 30 hrs. for iron with tin; 28 hrs. at 750 C for iron with tungsten), heatim, at temperatures above the A3-point, or high-temperature annealing (30 min. at 1200 C for iron with tungsten) did not cause atomic migration of impurities from the initial locations toward the boundaries of the recrystallized grains, regardless of tile deuce of prior deformation. During recrystallization, atoms of impurities which %%ere located at the grain boundaries and formed part of the solid solution by penetration showed a substantially different behavior than atoms of base-mctal at the boundaries or atoms of impurities form- ing part of the solid solution by replacement. Carbon atoms, unlike atoms of iron, tungsten, nickel, and tin, follow behind the boundaries of newly forming grains, so that at certain stages of the process a lag -may occur due to a difference between the diffusion velocity of carbon and the recrystallization velocity. It is characteristic that carbon atoms always migrate toward the grain boundaries, and not in the direction of the maximum concentration gradient of the impurity. The authors suggest, in conclusion, that the activation energy of tile migration process be determined and compared with the activation energy of the dif- fusion process of carbon in iron. Orig. art. has; 25 photomicrographs and 3 tables. ASSOMATION: None Lrd 3/4 L - - ACCESSION NR: AT4040413 S/0000/64/000/000/OQ99/0109 AUTHOR: Bokshteyn, S. Z; Kishkin, S. T.; Moroz. L-M.; Chaply*gina. V. S. TITLE: Structure imperfections of metal following recrystallization SOURCE: Protsessy* diffuzii, struktura I svoystva metallov (Diffusion processes, structure and properties of metals); abornik statcy. Moscow, lzd-vo Mashinostroyeniye, '1964, 99-109 TOPIC TAGS: metal structure, metal diffusion, diffusion permeability, metal re- crystallization, iron, tia, tungsten, carbon diffusion ABSTRACT: Many of the properties and processes occurring in metals depend upon the degree of structural perfection. However, it is not clear how and under what circum- stances structural defects arise or disappear. In some cases, it has been possible to act,ieve a displacement of interstitial impurities into the inner regions of grains by re- crystallization, thus increasing the plasticity of the alloys. However, such a beneficial Influence of recrystallization has been observed only in individual cases. Therefore, the assumption can be made that in regions where grain boundaries have been located before recrystallization, preservation of the specific state Is possible, I.e., there is a possibility C. 1/3 ACCESSION NR: AT4040413 of "heredity". In the present'paper, the authors investigated the heredity of metal struc- ture during recrystallization and grain growth, using autoradiographic and microscopic techniques. The degree of structural perfection was evaluated by diffusion permeability of C14, a higher permeability corresponding to a more defective structure. Using. specimens of pure iron and of iron containing diffusionally introduced interstitial additions, such as tin and tungsten, the authors studied the stability and degree of defectiveness of the original grain boundaries during recrystallization in relation to the degree of metal purity and the recrystallization conditions. Iron was annealed at 1250C for 9 hrs. , electropolished and etched with 4% picric acid in ethanol to reveal the structure. Tin and tungsten were added in a microfurnace at 700C. Recrystallization was then carried out either at 650C for 45 min., at 700C for 30 min. or at 750C for I hr., followed by heating at 600C for I hr. in the presence -)f radioactive carbon. Measurements of hardness and C14 distribution demonstrated that diffusion is affected by recrystaffization temperature and that the residual effects of previous cold working can remain after application of the common types of recrystaWzation. The diffusional mobility of atoms was found to in- crease during the process of recrystallization. Failure of alloys at high temperatures generally proceeds along the grain boundaries, but sometimes it occurs transgranularly. It is possible that, in the latter case, the alloy falls along the boundaries of original 2/3 ACCESSION NR: AT4040413 grains which were metal lographic ally undetectable. The question of the influence of various impurities on the defectiveness of the original grain boundaries thus gains con- siderable significance. It is very possible that inheritance of defectiveness is linked to a considerable degree to the presence of impurities; therefore, the question arises of the possibility of displacing the impurities from the boundaries to the inner region by re- crystallization. The results of the present investigation permit the authors to assume that the detrimental influence of Impurities can be reduced by applying suitable recrystallization conditions. Orig. art. has.: 7 figures and I table. ASSOCIATION: none SUB.W=LTED: 09Dec63 DATE ACQ: 28May64 ENCL: 00 SUB CODE: MIM NO REF SOV: 002 OTHEFL- 000 ACCESSION NR: AT4040422 S/0000/64/000/000/0183/0187 AUTHOR: Bokshteyn, S. Z.; Kishkin, S. T.; Moroz, L. M. TITLE: Effect of thermomechanical treatment on diffusion mobility SOURCE: Protgessy* diffuzii. struktura i avoystva metallov (Diffusion processeS, structure and properties of metals); abornik statey. Moscow, Iza-vo Mashinostroyeniye, 1964, 183-187 TOPIC TAGS: thermomachanical treatment, diffusion mobility, diffusion coefficient, fine structure, diffusion mobility determina- ~ion, thermomechanical treatment effect ABSTRACT: The diffusion mobility of iron in austenitic steel E1481 and E1437B alloy were investigated after conventional heat treatment and after thermomechanical treatment (THT). The parameters of the latter treatment were: 1080C - temperature of deformation; 28Z reduction; and 13.5 m/min - deformation rate. The diffusion mobility was determined by the method of tagged atoms in combination with microstructure analysis. The specimens were electrolytically coated Lc--,d -_i 1- 3 ACCESSION NR: AT4040422 with a thin film of radioactive Fe59 and annealed in a vacuum furnace at 800C for 150 hr. After annealing, the diffusion coef- ficients were calculated for grain volume and grain boundaries. Table I (see enclosure) presents the results obtained. Thus, TMT changes not only the conditions of the grain boundaries but of the grain bodies as well. The increase of diffusion mobility is pre- served even after annealing at higher temperatures (temperature of recrystallization). The increase of diffusion mobility produced by TMT limits the applicability of this method for heat-resistant alloys. TMT could be beneficial, however, for alloy working at relatively low temperature. Ori;j. art. has: 4 figures and 2 tables. ASSOCIATION: none SUBMITTED: 09Dec63 ATD PRESS: 3072 ENCL: 01 SUB CODEz MM NO REF SOVz 001 OTHER: 00 Card 2 /3 ACCESSION NR: AT4040422 ENCLOSURE: 01 Table 1. Iron diffusion coefficients D-10 cm /sec on grain boundaries Dgr and in grain bodies Db of alloys E1437B and E1481 at 800C Conventional heat treatment TMT Alloy Dgr Db Dgr Db E1481 E1437B .62 0.87 4 .6 3 .5 2.8 1.7 - 11 Average diffusion -coefficient E1481 E14-37BJ 1.4 1.0 3.0 1.3 Card 3/3 1, 071~2-67 EWT (m)/EWP-(t- --upta) ACC NRi AP6027751 WN1 SOURCE CODE: UR/037O/66/ooo/oo4/Ql39/rji42 AUTHOR: Boksbteyn, S. Z. (Moscow); Kishkin, S. T. (Moscow); Moroz, L. M. ~Moscow); Chaplygina, V. ORG: None 0 /_3 TITLE: Characteristics of carbon diffusion in niobium SOURCE: AN SSSR. Izvestiya. Metally, no. 4, 1966, 139-142 TOPIC TAGS:- carbon, niobium, metal diffusion ABSTRACT: The naLure of carbon diffusion in niobium is studied as a function of struc-: 'ture and surface state. The specimens were melted in a vacuum arc furnace, forged and heat treated at 20001C for 10 hours to produce a uniform structure and relieve inter- -nal stresses. Carbon diffusion was studied by autoradiography combined with micro- structural analysis. The niobium specimens were diffusion saturated with radioactive carbon at 9000C for 2 hours. Three types of carbon diffusion measurement in the sur- face layer were compared: 1. directly after stabilizing annealing in a vacuum at 20001C for 10 hours; 2. after stabilizing annealing and mechanical destruction of the surface layer by polishing the specimens on glass with abrasive powders of v3xying 'granularity and by preparation of a microsection; 3. in the oxidized surface of a mi" 1crosection. It was found that considerable diffusion of carbon tales place along the Card 1/2 UDC: 548-526 L 07182-67 ACC NR: AP6027751 0 'grain boundaries of the niobium regardless of the state of the surface layer. The .surface state has a considerable effect on volumetric diffusion. Annealed specimens ishow practically no volumetric diffusion while specimens with a polished surface show I considerable mobility of carbon atoms within the niobium grains. This diffusion is !considerably stronger along the subgrain boundaries than in the remainder of the grain I .volume. Analysis of the experimental results shows that carbon diffusion in niobium :consists of three elementary processes: 1. diffusion of carbon in the crystal lattice of niobium; 2. reactive diffusion with the formation of a carbide phase; 3. diffusion of carbon in niobium carbides. The carbide phase is formed chiefly in defect sections lof the structure: along the boundaries of grains and subgrains and also in the less perfect sections of the grain volume where diffusion is most irtense. Orig. art. has: l table. ! /1 0 SUB CODE: Yk~ 7/SUBM DATE: OqMar65/ ORIG REF: 006/ OTH REF: 005 I_qcrd 2/2 ACCE&SION NR: AT4040404 S/0000/64/000/000/0015/0024 AUTHOR: Gubareva, M.A.; Moroz, L. M. TITLE: A study of self diffusion and diffusion in nickel alloys t)O~MCE: Protsessy* diffuz1f, struktura i svoystva metallov (Diffuc-ion prolesses, structure and properties of inetals); sbornik statey. '114osc,)w, Izd-vo Nlashinos,royen.yt-~, 1964, 15-24 TOPIC TAGS: nickt,!, nickel alloy, Kli'.IONSOT", alloy, ZhS3 alloy, nickel selt diffusion, bounda-ry rliffuF~inn, bulk diffu:,ior, iuLuradiogr%j,:ji,-, diffusion arialysis, self diffusion co- efficien't, diffw;ion activation onergy, tin, tin diffusion ABS"1"1U%CT: 'rhe authorii presen" a (101'a;led of diagram's f 'hr- Nsii,ii in nickell and offer some cluilitauve eva1LJ,'tL1(j1-iS of 'Lho diffusif)il of Lin and self-diffusion of nickel in nickel and nickel-bas(~d alloys, 7ney dcraonstrate tho huterogeneity of the self- diffusion process and the significance of grain I)otindaries, temperarure and compogiiion or structural' factors for the procosses of self-and ncwro-diffusion. Prismatic samples of technically puro Ni, Ni plus 0. 01% B, Ni plus 0. Wio %V and of alloy lQi2ON80T3 were annealed at high temperatures (I hr. at 1100C, 12 hrs. at 1100C, 9 lars. at 1200C and 2 hrs. at 1200C, CRrd 1/2 ACCFSSION Nil: AT40,1640,; respoctively; all cooled in the furnac(~ I.o ')00C, Lhon in free air), thon poli~,hcd CleCLI-olytically 63 and (~Icctroplated with Ni (Coat thickness u1) to Plated sampies were horriogi~niz(,.-I in a vacuum, furnance at 700, 600, 1000 or 1200C. Lffvcts of structurai factors ~)n difljsion '( . Ix rate were stud.,,ed on cast or Jorged samples ol alloy ZhS3 which were f, ,- 7 S. at I I -33C, then homogenized in argon at 80(j, S:io oi- '~50C. ILL wati lound thLL ,iolf-diilt.i~iion -,f Ni proceeded mainly along the grain boundaril.!s within the rwige of ~JIA -1200C. S,-,:! - U`iffij,ion coefficients ranged from 2.0 to 56.0- '(),2 cn,.~'Vsec f(,,r pulrt- Ni at, t-iO- and !2100C, respectively and 0. 6 to Z8, 0 for alloy n2' `)I*,S0':':i at such temperawres. activation energy was 24 800 kcal/g-atom. Coeffici ts of tLn I dius ion in ZhS3 ranged f rorn 0. 3 to 0 crn~/sec (for cast material) at en 113.0. 1 13 800 iznd 9,-i)C, respectively and from 0. 8 to 33. 0 for forged material. The ratio Qsurf/Qbull~ was 0. 75, 0. 62 and 0. 52, respectively, for ZhS3, KH20N8OT3 and pure nickel. Orig. art. has: 5 tables and 7 figures. ASSOCLATIOM. none SUBMITT7,D: 09Dec63 DATE ACQ: 28May64 ENCL: 00 SUB CODE: MM NO REF SOV: 001 OTHEM 008 Card 2/2 41, i,ate !-,~tlca-l IcRr~-, -.. -I. . I " , -* --L .- 1 -1 - , . it of -,*,.e z - t:r - ` t~.e : '-- )'-r-) '.* c , i-. t Ical .'. - : ar~ ' u - I.-, '-~:ar. Te3h. FIz., 14, .:)s. I " 1); li I , . '. 0 joe o o 0 (600990 0 00 0000*-0:00000000600000000 10000 W00*000000it is to t, I 6 v a It a a -In It a an is v is 0 4 44 a 'to a 064 I Iit ofT lo!"i , . - #I" C"fal 00 Af -00 i-00 oot oes 008 :0 .0060 netweem aw StImIct'm I me sad&" at W&V= and 00 Stru'dum 41 grft ad RUNLAAR-) ;;0o L P. AtIlres- Zhu r"4iDrVkr.Vh C=T 'd-! (journal of Tchialcal Physics), V. IS. Mar. 1948. p. 3Q3-316- coo 0041 0 0 ~00 WOOD N t It dog 00 U a I* IND f1k. a rw a 4 1 9 111 2 0a 0go 0 A ma Ill Ill of Cl it It of RO III fX4 at '00 ~'000-0 -0-0 -00 4: 0000* 0 0000000**.Is 00 0 0* 0 0 * 0 0 0 *6see 0 0 0 - ------ -00 0-0 so 09~ 0 * 000 *-* a& 0 * 0"king00 ga * 0 * 0 000000 L. C W -I". r I~onthl-,. Lif-~ 7:: Vor o i: T ITLE: eo ry o t h e 9 rx) c te r i s , i Cs "n P.,.c *.,-Orr . ',lc Anpsrntus (-.eorlyn pnroqov.,:kh kh-r-kteris*ik fotowrifirtj.-,-us.n(-- go prilorn~ I. The ~~ole of the -pticni .7ystem ~f t~ie Annprs'us in the Case of fndivilual r)! jPcts in t%e Vision Akea :-~ol' opti- cheskoy sistpmy prilqrn v sluc~pye .)Hpl'nyk~ o~"ye~t-)v v pole zrenly-') FF ,RTn'TCAL: 7. urnnl nPuchnny i rrikl-ldn fo toiyrnf ii i ~ ino-, t )i7rnf ii 195,9, Vol ~, Nr 6, pp 443- '40 The author interprpt-~ th- theory of the threshc,11 cir-r-ctrr- istics of p-. )t ;PrRphic apppr-tus nt the open sessions of the '-ommission for _'cientif ic :_hotoprnp~y qnd of the A.-) in 1 Pningr-il %;nd "oscow in recto` er an~ -'eceT-er 19r7. ';n this first PPrt ~,e is concernrA with t-.e contrast in the re-l im-ge in the cnpe of in,:ividunl pre.,( oh.;ects lo- cnted in f ields 1 ri,7hter or d-rker tl~pn the o! jeots t~~emspl ves EquPtions for a ~eterminqtiin of the relevant t!iresh,-)ld cha- racteristics are discussed. It is conclude,-' thqt, ,,p(-,n a comiparison of the resulting finpl equations, it is possible Card 1/2 The Theory of the Threrholl T. The Role of the ')ntical Objects in t~~r- Vision Area SUEMITTE71: 'rarpc'ertF: tics zf tne np-r:~ *-s. System of the AT)npritus in t"e of Tnlivi,1~1'91 to cover thresh.-)ld chpracteristics also in the cases o~ en- tirely different objects, oplic9l systems an,! photograp-ic anpAratus th;,t hA,ie scatterini~ properties. There are 1. praphs, 1 dinaram and ' references, one of is -soviet An;' 1 Pritish. ecember 1,-,, 1017 Card 212 ITJ THOR Idoroz, L.P. TI TL3 Formation of Images of Objacts , in a Field which in Brighter or Daricer than the Objecti , by an Aberrationless Optical 3yrt(xG (Izobratheniya bazabarratnionnoy optit,haskoy sistemoy otdollnykh ob)ektov, nalchodyashchikhsp -4 polla. boleye i1i. meneyo svetlam, chc%m stuni ob)olcty) llh;RIODICA.L: Optica i Spektroskopiya, llj~181 Vol 5, Nr 6. pp 692-698 (USSR) ABSTRACT: The object is a band in a field whi-h is either brighter or darker than the object itself. -rhis object is imaged by an aberrationierF. optical system with a circular &perturs. The author obtains an equation which relates together the obie-A width, its contrast with the surrounding field, thG c-ontrast between a point on tho object ax"5 and the surrounding field. the a parture of the optical system and the wavelength used. xhis equation maces it possible to find the limiting values of each of the listed quantities, when the other quant.Ltias are -Ivan, as a function of the limit of sensitivity to contrast of the recoiver used. The folloving special cases are considerod; contrast in s. real image of a black band in a bright field as a function of th,3 object (band) width, contrast in a real image of a gray band in a fi,31d Card 1/2 brighter than the band. contrast in a real image of a gray bqnd in a ,-)OV/ 19 Formation of' Dnages of Objects, in a Fiald which is Brighter or Jarcar tia-, V-.-n 0'ujoctG Tneinselves , b~ an -,oorrutionless Optical System Viaid daricur than tqe -oand . rho f orni of the equition d eriv A by + Le autnor dopo--ids -n whathar the objact is dar&er or brij;htar tho field for a piven contrast of the object N7itti tho I,ioilll - : o .[-it, cd vias usad to obtain this equation may be apolijd to 01 t", 46) f other shapes, to optical systacus wkth othur oroporti~,s k-j 1") whi ch have SCatt3ring properties. iho paper i,; anti.-(,)Ly ti,,-,orAt~:a] Thero are 4 figures . I table and 2 rofaroacas , I of' wi-den i:3 .~ovi rt and 1 :English - SUBMITTED: November 5, 1957 C-ard 2/2 23(1) SO V/77 -4 -1 /1,-,' AUT. -OR; Moroz, TITLE: The Theory of the Threshold Characteristics of a i,hoto- graphic Instrument (Teoriya orogovykh kharakteristik fotografiruyushchego pribor a~ 2. Problems Arising During the Design and Operation of Photographic Instru- ments (Zadachi, voznikayushchiye pri konstruirovanii i ekspluatatsii fotografiruyushchikh priborov) 0 PERIODIC~*LL: Zhurnal nauchnoy i prikladnoy fotografii _J kinemato.,_;rafii, 1950, Vcl 4, Nr 2, pp 81-89 (U1,3SR) A&3TRACT: At the open scientific sessions of the Komissiya po nauchnoy fotografii i kinematografii All 3,313R (Committee for Scientific Photography and Cinematography of the AS U.~SR) in Leningrad and Mloscow in the winter of 1957, the author stated that the threshold characteristics of a pho-o-raphic instrument depend on the qualities of its , Lj optical system and its image receiver. If the optical rv ,-lard 1/8 307177-41-2-11118 The Theor, of the Threshold Characteristics of a Fhotogra:~hic Instru- ment, 2. Problems Arising During the Design and Operation of L-hoto- graphic Instruments. system is non-aberrational with a circular aperture and the object is a strip of any given width, placed in a field lighter or darker than itself, then due to diffraction, the optical system will convert each emit- tilng line into a band of energy dispersion. U~ing'the grapho-analytical method of consideration f 1-/, the author produced an equation connecting the following: 1) the width of the separate object in the form of a stripi 2) the linear 8 or the angular Gc (in cases when the strip is placed in a lighter and darker field than itself); 3) its contrast K with the surrounding field; 4) the contrast KL between a point on its axis and the surrounding field in the image, formed by a non-aber- rational system with a circular aperture; 5) the apErture of this system (the numerical aperture A or the diameter Card 2/8 The TCeGr~ cAL' t-,~-ie, Thres':.ol~,' Charac-. _ristic~~ ~-_f ahic ln:~tru- iroblems Arisinc- During the Def3i n anul e n t o - ment ,-ra, hic instrumen.,.s. D of tlie entry pupil); and S) the length of 'Q*;,ie wave of the emission L, - ~k . If the object is darker than t-e field the e-,uation looks as follows: 0. T,?4 JL8 (I - 0 /7D x -~- A At 0 and if the object is-liiiter than 'Uhe field; 0. egA~-4- A~ -Ki 1-k i These equations -.ake it po.-,sible to find the nece_--.,=y, particularly the threshold values of each of the enumera- ted values when the remaining values are Jven. 1.3y con- tras~ the relaLionship light-dark is understood in all light Card 5/8 The TI'Ieory of tiae Threshold Characteristics of a ment Problems 1'~risinE ~)urin-- the Design and -:-~07'c'- ,-rapnlc :n-~rruments. cases. The author defines sor,-ie of o,6her vu'---ies more closely and demonstrates the accurac~~ of results obtained by e-luations (1) and (1-1.) and other _iven equations, and the :--r-a,)hi(, method of solution whica per- mits --reater accuracy. He shows how to calcul-:'Ue by integration (see table) the value of Kiot (imair - _,e cc)n- trast in the case of a b':.a,-.k object. in ',I~e field, when K=I) and to present in the form of a relationship between Kiot and the values "V""e -P A-n sin u - the numerical aperture, of the sys' 'em (n is the refrac,ive indlex of tllie medium in front. of the system; u is the al:erture angle from the side t.~.e "11'e"i of the objects). Ile derives equal"ions (" IJ ai,(I W) !,vhich -.,re simplifications of (L) ay.d (I"J. 1"he author then 't-irns to formula'ting an~,' Uard 4/E. SCV/77-4-2-1/18 -'he -.-eory of the Threshold Charact-eristics of a-! '- o-~oz- I roblems Arising bring: t',,,-e __esio-n an _4 -.--era-. i __L O__ ment, ln:3truments. typical problems, ari3inE d~iring the _~esi~_7n ar.al use of photo:-raphic instruments and instruments cons--'st-in:, of an optical system and an image receiver. 1"nese are as follows; 1) Finding the size of an object of a I-liven contrast with the field, formed by an optical system _L W4 th a previously given con rast on the receiver; 2) Finding the least contrast value between the ob- ject and the field at which the instrument will dis- cover its existence there; 3) Finding the necessary value of tl-~e threshold of perceivinG the contrast of the instrument's receiver so thLt tIe la ter may dis- cover the existeLce of an object of a -iven size and -4 111 t concrast t 11, ._" -e f-*Leld; 4) Finding he necessary value of the apeTture of an optical system from the side of the image area ~in pa_-Licuiar, the value of the focal diStar~ce Car 5/8 SOV/77-4-c_ -111 --1 The Theory of the Threshold Characteristics of a Photographic Instru- ment, 2. 1 roblems Arising During the Desigr- and 'U'peration of ':,hoto- C T F, r a nhi Lnstruments. of the instrument's optical system) at which a -iven ob- ject of a Given contrast with the field will be at the iimit of instrament dscriminaticni 5) Finding 'he necessary value of the numerical aperture of an optical system (or the diameter of it1c- entry pupil) w`- ere an o Ib- ject of given contrast wit'n tt.,e field will be repres- ented on the receiver with a previou-sly given contrast, -S) Finding the necessary value of 'he numerical. apert- LLre of an optical system (or t"ne diameter of its entl-ry pupil), where the instrument will still discover a given object of a ;-iven contrast with the field; 0 C, Finding +-he --reatest distance to a given object of a driven contrast wilh the fie1d where the inStf,iment will still discover its exi5tence; various other problems. The author finally draws t1ie following conclusions 1) Equa- Card 6/8 ,-)'OV/77--)4 -2-1 /JP- The -1 .~eory of the Tlareshold Characteris tics of a ment 2. Iroblems Arising During the Design and Cperation of I C) ~Sraphi - Tnstruments. tions have been derived which canec, ',~-Ie wide',-. of a separate obiject in the form of a strip (,w',,en it is placed in a field lighter or darker thin itself,'., its contrast with the surroundinC, field, the contrast between a point on its axis and the surrounding field in trie image, f,-,rmed by a non-abern-itional optical system with a cir- cul:~r apk,rture, the aper,L-,ire of this system 1-ind the lenjIth of the waves of emission 2) Phe form of the equttion differs according to whether the object is ligLter or darker than the field, at a given contrast between the object and the field. A connection between both cases has been established. 3) The equation makes it ;)ossible to find the re-uisite or threshold values of any of tU',.e enumerated values, shen tne remaining values a2e in connection with the values of tf':e t'--reshold of contrast; Card 7/8 SGV/77-4-2-_'/1;__- The Tl~eory -~f t,,.e Thresi~old Characteri sties of a ithoto'-,,raphic Inst ru- ment , p. i rob] ems AT~iS: nj_r During the Desi (.-,n and Oper,% t1ion '-)f phic 'n.;Lru-ments. perception of the insti.,ument receiver, 4) ")ome 16ypical problems of threshold characteristics, arising during the design and use of pho*.o.:~-r-aphic instruments, ~-.-,ve '11 1 ;'al "Inal -iven been formulated i.' solved. ysis It -is been , of these solutions. There are I table and 5 ~3(.~vie~ re- rerences. 1. 71, 195'7 and Dece:Lber _11, _95'17 i't.! 1 -2: _~ D Jecember l.. , 1957 ~-rd 8/8 MOROZP L.P. Theory of the threshold characteristics of the photographic mechanism. Part 4: Reproduction of details in the form of separate slits of any width and any contrast with the field by the complex function of the optical system and photographic layer. Zhur.nauch.i prikl. fot. i kin. 6 no.2;13G-138 Mr-Ap IO'l. (MIIRA 14*4) (Photographic optics) (Photographic emulsions) Howlis-L-171-1- Imaging of separate linear objects with the field surrounding them by a gramila layer. Opt. i spektr. 10 (optics) of different width and contrast combining an optical Qatem and no.2:2/+9-256 P 161. (HIEUt 14:2) 4308 S/o5i/62/013/005/014/017 E032/E3i4 AUTHORS: Kirily4k, Z.O. and Moroz, L.P. TITLE: The effect of stray light on the diffraction pattern of isolated line objects PERIODICAL- Optika i spektroskopiya, v. 13, no. 5, 1962, 734 - 739 TEXT: Stray light due to sources inside or outside an optical instrument is superimposed on the image produced by the latter and may have an appreciable effect on the threshold characteristics of the instrument. The formulae derived in this paper may be used to take into account the effect of the background, whatever its origin, on the contrast of the diffraction imagesof line objects (wires or slits) and their immediate neighbourhood for different object widths, wavelengths, aperture of the systems, Contra.,;t between the object and its immediate neighbourhood and contrast between this neighbourhood and the general illumination field. Using the approximate energy-distribution in the diffraction pattern of a luminous line, derived in earlier papers (L.P. Moroz, Zh.nauchn. i priki. fotogr. i kinematogr., 5, 81,1959; Card 1/2 S/051/62/o.13/005/014/017 The efCect of .... E032/E3i4 Opt, i spektr. , 10, 249, 1961 explicit expressions are obtained for the threshold widths of darl, objects for different contrasts. These expressions have been verified experimentally by the micro- photometry of diffraction patterns due to wires 0.02 - o.1 mm in diameter with differently illuminated backgrounds. The results obtained are summarized in a numerical table which indicates good agreement between experimental results and the theoretical formulae. These formulae may therefore be used in practice to determine any of the quantities list'ed above when all the others are given. There are 2 figures and I table. 3 UBM ITr ED: October 4, 1961 Card 2/2 MORCYA, L.P.; AYUKWOV, A.Kh. Possibility of detamining the effective deptih of the yield of secondary electrons in the ion-eleatron emission from dielectrics. Tzw. AN SSSR. Ser.fiv. 26 no.11&1322-1327 N 162. (MIRA 15:12) (Secondary electron emission) (Dielectrics) -J; 4v v ...... Xh;` lox tta (in", t ti ~1~ v Vane, tC.at a y-, i~, up .1963" -vror. re. tudL#4~~'- --~-h6gativ e ra idiia- bile: no trow:'Oompo Ilants w tilthd ave .4:~ tll~fga, ~Cbmnj id mb4,L*%kftdTLt n rom 4GV"~'f bad, 4 -.dt~ --Tit "un, or:a z or. I.S AM.,~.The char 'd gilt oh~',df, th~ -OP( Iiidlik"10ith nat of -a: thick- all~ iu-~' t-0 7 7 Id 3 0 02 0 to Me 10 &V th- ou,4mlssloti P-hiddd",'qu2'te!"d ff even V, i C-Itheid 3-`~wjt a Ats& a0 and,.in- Ls- a _0 emrgy.---:an acrea 2.n ma's n4 d d zMar us- t b it," Ut Th the, ra io;: a p9 e a of ry~ qp. ow; no 'i 6d drd' z4~46' a -anergy- can-, -ftc TM UBIIM. MOROZ, L.P.; AYUKIMN07, A.Kh. Use of the secondary ion-electron emission method in the comparative study of the depth of penetration of various inns into d'electric films. Izv. AN SSSR. Ser. fiz. 2-8 nn.8:1395-1400 Ag 164 (MR-A 17:F) MCROZ, L.S. "Musamwit Sensory innervation of the cranial mesenteric artery Irwith summary in Inglishl. Biul.eksp.biol. i med. 43 no.3:107-110 Mr '57. (MLHA 10:7) 1. 1z kEkfadry naormallnoy anatomil (zav. - prof. G.F.Ivanov [deceased]) I Moskovskogo meditsinskogo Instituts. Predstavlona akademikom A.D. Speranskim. (ARTIRUS. HESICYBRIC, Innerv. sensory Innerv. of cranial mesenteric artery (Rua)) Vc, WS; 000600015L 00 A 1 0 J ? 1 I AA 0 LL it it $ . Tko tatio d dfiluittoci (a omitutatlito d Fe M C- '00 4 Wins, And L. 14. MOM. Stal I.N. a. 1. 1, No it, A7 4" itol 1); 4, C. . 1. IS. M471 Two kindt,d diffu4m sm '00 f~` sent: a "rmetive" and a "puie" 11311rd ot the pre -00 0: Iit t c Itirturf a chein cituthinatento k fnmcd om the %tat - f&.V if the crine"I"I Inalefial while in the tallf'r the -00 00. lifftio'big toram'Sisrati, thigh thr.Ty.l. utl%i,,d - " 9 0 00 difictiarnoti"uph- Reactive thicemen(tdmitteriaJ. . &A by the forniatkiti cof carbides when Fe t, rmeni,l *0 with C The Impimt coor is the cementation A .-F~ 1111110, 00 1'hm ptm.to 6 umore cognpiciL when a steel alloyed with larbide4fortniets elcuient. 1* crinend"I T,, su-iy Ott. -00 pfom4 steel spetintem wm 4std. in a varying degree -it fi -00 W ur Xfo; then thew tpecimem wrrr cemented in a ms%t Tbers-%ulivatilmitfoubl, -00 ementotsm we detailed and illustrated with phmiiiisri- '90 Kraphs \1 11-h -09 tie Ito; -00 + I lo 0 0 e 0 r!0 0 0 0 0 0 0 0 0 41, 0 0 0 s 000 do* 0000 00 *OGG 0 Goo*@* 0.0 as** 0 0 40 0 0 00 0 0 4 OM t oil t of, lot? 0. . "R A COq Mochaalaul (d illauglug of fratlevo Iota atif )a Itan, ivad wChel M 1. 4 And L. .11 MUtill, ) I e, k /'* , A (I !% " It A It, :0-3 WGMM, Cylts"Ific imit .11.1 1 1 /I "vI,1" 'lip 60 air I, 11100ed Ill M." W. N# 414.1 I ; 11-011 "1 ill it, '01 lit- Alict -4mg. I' 'A Ill" I Ilsill flilsh -11,v- air lurt-I I(I Ain't -1.1"f(A 1'. 'Ifelf, , tillAr"Crapill, Awl 0 ID e -,,v I1.1- . C., A....."I I I I lit( It, I., *(I,, 'tulvt 0 mi t- h, C', uml se '1111-9.11 "HI-11 It .-Ild -IIA, All MI, 0% A it) FC; aftl,f 1.1tact !.', l"'. At P-Ill U . ht,l. at UNK), Air Ow ljvvt at% itil,rim-fall" , I"Atmi. .10, I-W h, lay" . Jid -In All Mo fWl ,I" 4illI' l4w dw .4w of 'I'di'lljil IV I -m.t %I,, I've W, vIIIII'llill. If I( lit,- itil,mi,vAili, utuln] , in 1. y,.r, 0 I'll MIA' flit ~falll- If thv condition, of flic "c"14,"isiplo if-mv , dwwiwicl~. At a dirtmitc ilwwkn-. flivic I, a uddirti droiA A thc Mo (W, -utl,tril. ilrbsch It- _'Ati- If th,r dwanoll till t'llip aull, le C11:1- .,tb ojAt:r,&,mjj tlarkilic,, f2- DifTu,i,,n of Si ..F,, it, I-, ~WA min At II.W. wild ~olu. II St ot bar. at 11213". br.t -layrr voltnpd. Fr,lw 14-,, So, -cInd- Ivt,t X.S.Z" St (3, tic in pl,. If) b-, at IOXX)' I'M 3 hr, At 1401", tint Isycir Frile,, ilct-und-lailve, orntAl with _ItAI -In of It, ill -I-c % Ill. W, 11"t of Bir A S 6 - I L A IIIIALLUARCOCAL UYEAVATUIRE CLASSMoCATICh 0- I -v# ?1 01, 1: 1; A I A, I is Po U's b f All . .., J." A I '. ..... . . It, It I A 11 I_fIJ,InJE N, v N It N -4f "I , -hd -I.. It I., % I 1., 4 _4 I fkl.,t . Wir'l "alil"i %011, -III'l .-1t-1 till Ill hill, 41 Ill At lit V. I AIN. _Iltl 1 41 A, mi, - 11 All \A I lit of !I:,. 411.1 -own --ur, Ill I .... 1,-r of It,, A, I,:j" . A ..... of kill tf; In -N, 'till n gl-, I- tf,_" (h, to Alf 1-19111"1 M.W_ -,,all hr. at im;* a at -fid -11i of it,- Ff"'A' It" forccolifir T-U11%, 'AulAO&IMAIM I,v nittAlogrApily. Aml %_ t4v it 1, IllitfTed that thr lir,,t Italic Alf ~)Ijj -o Iy .*,If a. 1)), 1*14, 111 dwit; "war.,iltv. flip tat, "I -bl Ill ill, IfIlArtn"J411t, -111P1 in Ow pur,- uut,il. th, fIrri- -,,, I. InIv 41-1,tit 1h. -fifli, ill,- Ltt,-r fil"lon Jv Al"?`-- -,Ih laroir-,m, I,f: Thv '101 . ...... dal,d it lh~ "Pur". phir, j,jju,j_I --Mpf It' M n. A 2 --,;, hal A llwh~, W. NI. 11, nd I Il,n DID Os" T u 0 11T 1W 0 so I it- 111 Oflit Sit mi mi 11111typ OIDID1601 :00 00 0:00 0 0 0 410 0 0 Ole eeie so e* 0 6 e 'Do: 01,61, *so 00004 90 .0o of Zoo 0 --so tie 9 M14 .jjeChAW= Of WS DtMWOD LD thC CdfU.-3t4!;O3 of clewwal J3, 111-iyuw th . ......... 1.0-. '4 .11l.'rlnwfjtA imem Arbil, j-&r lt~ flu. "Mroting jx'wdrr Im-Lal '%ilmi.r rrr V. R-Lit., h". ri'~ I. f-M.- C (3 hm. i. tint I~P-r V:ft tf-f "oh mf .. ..... q- ....... m the ti.- 1-- v,,rY Aaf~r-,nt da~,Lo,n -1 tltn&ryl AIIIN Ol \',Sl. -1 W. pi.". in the 'f-' 1vt ... it- in Itt.-A 'd ffm V-11ttrIt, fit, 10.1 1 --I WrIA-al ot r1i. 1-P -.-,it .1, [h. "n~' thr"'),ch h' t 4., w-t lu& tfi-~ -xi,r in if,,- -t fl lljl'~Sl ;".I ''I %. 10 3- A LAL sit 7`411?ITT Ittlittll Mitt Iv rVvIft I 1 11 A : A L-1 a 0 A --- - --- - - -- -- IF M sichiectilem ad thele eff a fleets annedict, On Mi, saris. ett * 1hrrct drtn of the 4 0'. 1""" hy -V .4 -00 ctft$dctecI. I..S.m va. 'r J( SS_R.j Ia. 171-M)OWA) On ~4111111_ 111 3 cillfreent i-asijunt . . 'teswItumeatt"i ox x .4 X 4 ,, 4 'treA.-4 , -00 ste~6,14 X 14 X que-b-i is, 14)1, N'a()It A. * (.w 1-4 let.. ft.." -1 12. 11 _~' -i'l " ~ " hunn" It, at W41 . ' I l 00 AF at 4-M'. rinved-I .the firuiell hard,w" A lit, Intel.. at 4 Cdown it, 0.(1(13 le anle / in ;. gise. t . lowl of 3WWW) he.) Pits"ref agaill.1 The CAjFt..J returns le.trizisollatum to 0- C .4 't-1. t.-J.-I -4 * ; 00 81' (0 12 t. 11 49";) sti linciu, juerva- ot 14 with I'; C at 1trainty III It A. .4 fl-vtlois M '.s. coul-I. That the 1 'Go an~ cilevil annil-Alluell trull, I I'litulirl or.1filit till" ju~ hold. derms 4. Itur lowest C -W-t 1, ."1 " v t 0 41' ObtAluril fur VAIIIIIIIII. ft. 11tilelli,le iff.Mil aral.111 2 lit. , FulureafrIl 6.1 *-' lit, At 0.". 1-41, I SICTI .41111 ic ." -00 llf Fullerelfills at 4110. 4.141, two), 117,11% re'l. . Jilt 4). 12' r C. 'utu. ever. it - a 41.3.1411. 4 115, 445u-, , r-p . it r ~j 0 - 3.1%3.7. 4 1. 4.5 nine., re,1, . (,it 41 tx,,~ C if . ,"I trullerfed anal ItiorlitAIMI. It - .5 it I lif- ITAIAHO b-in . 13.15. 3.4. 31145, 4.2 tsun.. rellp. Sititwr it was shown by (it the R-CeC 1111CIS IMWCS that tile ITIMIAIIIIIII 14 tile J x-ray investigation, that thr C "Intent ot tile 0-phase orl , effe*t 4 C coriteert on the hard--d- ,.,I sAll ..111 1. I atencidniq of a ceino. fabove 44111".dor, nil( de ful on the ,v th, do,I.-mly ,I cither wunK the h2rdnm~ i4 neu &W al I-, C of the orel. the ficilear i reIs,r (W with I;C r i. (fur to the cArbide phaw~ Tile VAnati,-ii cit JR A% a fit, lljghrr~ i~f~t,vtr .4 the -.1.1 1.- IF, I- function of "; C "insists in a c"urv III the res"tesuev 1. ~Irrl~ than the d74" liver. wher,- they a- deforenaticen c4 the m grains as an effect 4 t1w eunu I-It lear.11O. ValFiatinsil cit the hardll- .4 feel .I a cutside. Extral"4416M of the If.', C hisee, Ili Jr. C ( . . , NIVCH ( CePtIvent, in frrtilt lit dIIr rill IF, IV 1-0 A' hittlar giveii the heirdus- 4 it,, pls,tw. thr rre.W .96 the pcol~ll- .4 Ili, '. .41.1 111. 11 , t Ian... illvr,l~l I I the &-vurription .4 a .4 tile "ou'll, if it,, 4 ... All- .4 11 .. ...... 41 ... a 1, 1 01-1 -00 111 'Farbute at onctly `;L' - 0 twtior, .4 [till-- mesuill"'u", lietren 4.5 iudn. sawl I(Ou hr, . At .h 1. Irr,A,.F,tc,f 00 it the C&IIIISIC I)ILLW 111~111-JWArril At 11 mescaline only shifts the line listralld to steed t4, lower at III-, C. the hairchl- .4 .. at velp-) --1.1 be, -60 3.52 seem. 4% again%l I viA trine to o,; C . .00 J 00 &16 it& 4#TALLUVOK.i WFORATI-11 CILWOPKATOGO I, 4 4 7 4'* U 5 If .4[) is L S is lid 0 4 1 ill W it 2 11 a III It 00 the hirb,.-f-urimi 00 of 00 so 00 so GOP 00 of Os 00 00 9e: 0 040 00 Ifvp fin Arust-Wifig A, .-t At" Ow nature .f the "I-fored .1111t mu'l g;.... 1. 11, th.- ~1'4" 'll.gram 14. 1. '' .I It 'he B-';C ploone t. det.l. "ely by tit, the 14-1 -ti-I scolely by a ~Iusnjte 4 1-q-t.- .j h, ph&w I'VIdirntly, the (tioun. of thr cart,,.1,* jmf1j,I_ &ft&ln% R celtiCod value m annealing al,ivr 4jo, . .1" P"Mty ~" lottiv Ite a Jet$[ (art,w .11 t. ..... IW10,q4tilit' If jjjd%t he "Mj-Ijjj!e,I that Ill.- tf_jjjj,,% .-f -i.pirted 41 311,11 4#111' It-unted, tout .,oatflnurs ago 1067.11, of 00 66 00 00 09 00 00 odi 66 00 00 00 00 00 00 400 00 0 0 0 e 0 0 0 0 0 0 0 0 0 0 0 0 o o 0 0 0 0 0 0 0 9 0 0 0 Sit 0 0 0 0 0 q a 0 0 0 0 0 0 0 0 0 0 o 4`6 -40 0 o 00 *so sojes,00909*090040060 00000000000060;;& AA CkLI tjl~ I Loot! 140 00 A~ 00 So *0 -00 oo 00 %fair of .4ran Its Annealed Harien.14c. ;I,, i 00 L. 8 %Ifgp and Yu S. T.-riifl.axov Zhu,""? l"'46 -00 -0161 4'-;' 1.1ki (3--kIrnut ,f Ttwhnivnl Phy-w-1, fee 00 19. Mar. 1919. p. 3143-390. oo The slinve wax lnw%tijratv4 by X.ray diffrviefim, go usiv)g swimpris of carlwn Meel water f',,m goo,r. and annealed for fifferent -00 aynd at Mertnt temoeraturex. Afetlind f .-%jvri. so mental inv"fluation 1% dexcritied. fIxta nrp ,bnrt,,.f :j: 40 00 and ts~ulated 12 ref- 00 ~2 t -100 'awf7" -,2z too It ..... o' it K La n 0 es 0 sees 0 0 0 0 0 00 00 0 0 0 00 0 0 111 0 0 0 000 0000 9 0 0 0io see* 0 0,110041110 -0 --0--0 0 --a 0-0 0, PHASE I TREASURE ISLAND BIBLIOGRAPHICAL REPORT AID 35~ - I BOOK Call No.: TN672.V8 Author: MOROZ, L. S. Full Title: STRENGTHENING OF ALLOYED IRON IN THE PHASE TRANSFORKATION Transliterated Title: Uprochneniye legirovannogo zheleza pri fazovom prevrashchenil Publishing Data Originating Agency: All-Union Scientific Engineering and Technical Society of' Machine Builders. Urals Branch Publishing House: 3tate Scientific and Technical Fublishin House of Machine Building Literature ("Mashgiz Date: 1950 No. pp.: 11 No. of copies: 3,000 Text Data This is an article from the book: VSESOYUZNOYE NAUCHNOYE INZHENERNO- TEKHNICHESKOYE OBSHCHESTVO MASHINOSTROITELEY. URAL'SKOYE OTDELENM, THERMAL TREATMENT OF METALS - Symposium of Conference (Termicheskaya obrabotka metallov, materialy konferents1i) (p.225-235), see AIr 223-11 Coverage: Substantial increase of hardness of practi6ally carbonless alloyed iron at tempering Is discussed. The experimental results indicate that the hardening of,-,:~-Iron crystals oc- curs because of deformation at vr)l-ume change in the process of phase transformation of-?(Fe-)-_---(Fe.. The appearance of re- 81dual strease:a in the cryutal iattice and the breaking up 1/2 Uprochneniye legirovannogo zheleza pri. fazovom AID 3513 prevrashchenii of' the grains create the strengthening of alloyed Iron which is the substance of "phase hardening". Comparison of physico-mechanical properties obtained by the phase and mechanical hardening leads to the important con- clusion that the 3trengthening of alloyed Iron at plastic deformation and heat treatment Is subjected to the same laws of mechanics of materials. However, the mechanical state of crystal lattice at "phase hardening" has a special nature. 10 charts, 2 tables. Purpose: For scientific workers Facilities: None No. of Russian and Slavic References: 5 Russian (1941-49) Available: Library of Congress 2/2 Y,O'tczt L. -). Me tal lof-re -)hy Causcs fcr th~ ~1 'f I *us ior: o!' In tr-rferer.c, ';I nz :-, -n X-re-.- ! - ~ -ar-!,:rjf!e4 (*h,":.Cn- free alloys of iron. Zhur. tekh. riz. -,? nr,. -1, 1992 9. Nionthly L~ist r,.1 Russian Accessi~-,ns, Librrary ()f' C,,rigr-ss, A ug~-Us t - '~q -ix, 2U, I r I. MORO7. 11 0. USSR~hy;ics Alloys, Plasticity Card 1/1 Author Moroz, L. S. FD 364 Title Significance of plasticity characteristics, reflecting certain sides of the physical state of alloys Periodical Zhur. tekh. fiz. 24, 425-432, Mar 1954 Abstract Experimentally establishes expediency of considering separately uniformly-distributed and concentrated deformations of alloys under tension and discusses significance of each kind of deformation in investigation of various factors which have effect on physical con- ditions of alloys. Studies deformations of carbon steel and its characteristics, such as yfeld point, tensile strength and reducticn in area, versus chemical composition, structure and heat treatment. Fifteen references, all USSR; most 1948-1952. Graphs. Institution Submitted September 18, 1953 141GIRTZ, t L . 3 . bTSR/MRtals Hardening Card 1/1 Pub. 153 - L2/ i Author Moroz, L. S. The phenomenon of internal cold hardening during the pclymorphi- '~on- version cf ga-mma-Fe to alpha-Fe Per.ludical Zhur. tekh. fiz. 24, 705-7!4, Apr 1954 Abstract :Triestigates the influence of volumetric variations, during the pc~_'Y_ merphir conversion cf gamma-iron to alpha-iron, upon the internal structure and mpchanical propertieE of alloys. Attempts to ~,onne,t the tcughening caused by cold hardening of the alpha-iron crystals. fe'lLewing the --hanges in volume during the conversion of gamm -Fc- tc alpha-Fe, with the changes in the mosaic structure of the al,-OYF, Inotitutioa Submitted September L8, 1953 ALITGAU23S. 0.S.. kandidat fiziko-matematicheskikh nauk; BONSHTSTN, M.L.. kaad.idat tekhnichookikh nauk; BIAMPMR. H.Te., doictor tekhaicheakikh naak; BOKSHTITH, S.Z.. doktor takhnichaskikh nauk; FOLKHOVITINOVA, Ts.N.. kandidat tekhnicheakitch nauk; BOR7.DTKA. A.M., doktor tekhni- chaskikh nauk; BUNIN, K.P., doktor takhnicheskikh uauk; TINOGRAD, M.L. kandidat tekhnicheskikh nauk; VOLOVIK. B.Ye., doktor tekhniche- alcilch nauk Cdeaeaasdl; GAHOV. K.1., inzhener; GNLLIR, Tu.A.. doktor tokhnicheakikh nauk; GORAILK. S.5.. kandidat tekhnicheakikh nauk; GOLIDEOERG. A.A., kandidat tekhnicheakikh nauk; GOTLIB. L.I.. kandi- dat tekhnichaskitch nauk; GRIGOROVICH, V.K., kandidat tekhnir-heskikh nauk; GULTAYZV. B.B.. doktor tokhnicheakikh nauk; DOVGALICVSKIY. U.N. Irandidat takhnichaskilch nauk; DUDOVTS.SV, P.A., Icandidat tekhnichs- skikh nauk; KIDIN, I.N.. doktor tekhnicheakikh nauk; KIPNIS. S.Kh.l inzhener; KORITSKIY. V.G.. Icandiclat takhnicheskikh nauk; TLANDA, A.F.. dolctor takhnichaskilch nauk; LEYKIN. I.H.. k-andidat tokhnichaskikh nauk; LIVSHITS, L.S., kandidat takhnicheskikh nauk; LIVOV, N.A.. Imadidat tekhnicheakikh nauk; KALTSHEV,K.A.. Irandidat tokhnicheakikh nauk, HWMSON. G.A.. doktor tekhnichaskikh nauk; MINKXVICH, A.N., kandidat tekhnichaskikh naulc; L.S.. doktor tokhaic-heslcikh nauk; MATANSON, A.K.. Imndidat4%aT'lL-,-U'9kikh nauk; MAKHIMOV. A.M., inzhener; HAKHIMOV, D.M., kandidat tokhnichaskikh nauk; POGODIH- ALUSAM, G.I., dcktor takhnichaskikh nauk, POPOVA, N.M., kandidat talchnichaskikh nauk; POPOV, A.A.. kandidat takhnicheakikh nauk; RAKHSHTADT. A.G., kandidattokchnichaskilEh nauk; ROGELIBARG. 1.L.. kandidat takhnicheakikh nautc; (Continued on next card) ALITGAUZICN, O.N.---- (continued) Ca rd 2, SADOVZKIT, V.D.. doktor tekhnicheskikh nauk; SALTTKOV, S.A.. inzhenar; SOBOL9Y, N.D., kandidat tekhnicheskikh nauk; SOIDDIKHIN. A.G., kandidat tekhnichosicikh nauk. UKANSKIY, Ya.S., kandidat takhnicheakikh nauk; UTEVSKIY, L.M.. kandidat tekhnichaskikh nauk; FRID14AN, Y&J.. doktor tbKhnichaskikh nauk-, KHIMYSHIN. 10.F.. kandidat takhnicheskikh nauk; KBRUSHCHEV, K.K.. doktor tekhniche- skikh nauk; CHARNASHKIN, V.G.. kandidat tekhnicheek1kh nauk; SHAPIRO. M.M., inzheaer; SHKOLINIK, L.M.. kandidat takhnicheskikh nauk; SHRAYBER, D.S.. kandidat tekhaichaskikh nauk; SHCHAPOV. N.P.. doktor takhnichaskikh nauk; GUDTSOV , N.T.. akademik, redaktor; GORODIN. A.M. redaktor izdatellstva; VAYUSHTiCYN, Ye.3., tekhnicheskly redAktor [Physical metallurgy and the heat treatment of steel and iron; a reference book] Netallovedenie i termicheskaia obrabotka stali i chuguna; spravochnik. Pod red. N.T.Dudtsova. N.L.Bernahteins, A.G. Rakhahtadta. Koskva. GoB. nauchno-telchn. izd-vo lit-ry oo chernoi tsvetnol metallurgit. 1956. 12o4 p. (MLPA 9-9) 1. Chlen -korrespondent Akademil nauk USSR (for Bunin) (Steel--Heat treatment) (Iron---Heat treatme,t) (Physical metallurgy) . - ~L~.Ctt, IAKHTIN, Tu.M.. redaktor; VADDV, N.A.. redaktor JUN". - 9~0 izdatelletva'; IVUSOS, I.M., takhnichaskiv redBktor LIFIne structure and the strength of steel] Tonimia struktura i prochnoott stall. Koskva. Goa. nauchno-tokhn. izd-vo lit-ry po charnoi i tevetnot metallurgit. 1957. 158 p. WaA lo:6) (Steel-Notallography) 7 Translation from Refer~t;,-::v% z,, Nit- v USSR, AUTHORS Moroz L S Kr,sin Yi; D T F T rr LE T he St I'l-0 i, of I' I f -t 11: 1111 1 llo-0 1, 1 in, PER1OD,CAL V SI) Most c)\.k- AN SSSP 172- 193 ABSTRACT An I l)VCS' 1011 ~-k dS M (I(. of I lit (.ff(.k I (.)I 1o%,. I cnl!)" Irc t. !crIgtK of load nu I me tl()t( !!I n" nd wl,e, f~( to"s oil tlif, I T r d ~ a modulus Of Of I)CILLS1-11 s me I t ed - n ii t. e i ( - - t v ( u furna( c Ti t- duthors dis ( ov v - c d -1 S ;~- I d I ff(' t- 1!( :5 t* 11 bT 1 t %t 0 notci-mg SN. in ii-wt~!s of s t, a t t, s ri i v't , i 16! 5 wlr_ %k s (I t, i the :-alio bctAct~ii ti-e sp,c f~t dt~fo-rri~t oti wo-~ of ~rilp.~t slrolcll,:;!_~ of smooth spec meris -And I~c ~k of notched Mesnage., -1 vpe s:) i m c n s Ti which 1-.s . high SN is ~Iso scfisiflvc Io Ihe st~,tv of I!.,- e lit. notched spe( inivits ni,,x tnurii onivio (it with whi( 1, Ti i-cf,lins i tolv-,ible SN b 111 t I . - s f : g L i t i i v v I ing upon 0 -ind N ( ontent Ti,v -Wens-tv of the offccl of It oil hw i,,, determined by the size nd typ(- of' T,fI prec 1PIT11tiOrl ki:IL h dcp(-nds Card I /Z upon the ( ooling rrjlc fr oni 11 c lemprr -iliji-c of , -100"C' sf,~ ( 1, The Strength of TitaniurTj 7 bending tests of notched spec imons showe(l thtl the MagnIlLIdt' Of Tilt' b( AIIIILI~ deflec- tion and the deformation work Lip to the appearan(-t~ of thc first ( r t(k - jis wt-11 as the work of propagation of the (-ra(k thi-ougl- tI'v t.lltlr(~ se( tioll of !, t. _";wk :mt.:I it room temperatUre, art, less in Ti it-;iti Ili SKi-L--i !it (kil'inlit tc.itilig _171 with 0 0007% 11 oxhib,ts no (old-brittit-tiess what(,%erl 5LIT 'xl~on Ilic( tod !)" In-IpW"- ties, in )arti(-iI1ar by H. it be(omes c~old-briiilt- An int rt,as,, i*i 11 t on'"!~l lu 0.0 1-, decreast-s ., b v 7 ~:, "0 ai 9 6 o CT,,,, t,ti,ors d%aii~ t.- to ex,)Iain the plivsical naturo of of Ti bv TI-t, lock S,j of fo~~'O-ublv oriented hvdride incluslonb It was disco, t-ed i!'-it he st r-i:n rate 1~ j~, i.o vffe( I on the ductility of smootl-, bpet iniens of '17; vn-( ht-d \k ti, It Gard t. t, ,,, ~, -Z It. % . AUTH(YRS- Moroz, L. S. Dr. Tech. 5r.., Nemchinskiy, A. L., Cand, Tech. Sc. _Pa__aER_ov_, Dr. Tech. Sc. , Pro,". , Shurakov, S. 3. , Tech. 3c.; and Bendryahev, 0. L., Cand. Tech. Sc., Hev of the Central Factory Laboratory (Tsentrallnaya zavodskaya 1;,boratoriya) TITLE: Brittle Breakdown of Steel and Steel Parts (Khrupkiye razru- sheniya stali i stalInykh detaley) PERIODICAL: Zavodskaya Laboratoriya, 1957, Vol. 23, No, 1, pp. 123-1;5 (U.S,S~R.) ABSTRACT: The first fair of the above authors present a review of Lhe book, "Brittle Breakdown of Steel and Steel Parts" by Ya. M. Potak, which contain3 389 pages and is published by OBORONGIZ, dated 1955. These critics find that the aLthor used much material based on his own investigations, IT*y state that the book fills a need in the metallurgical in- dustry and contains little that. merits crit3cism, The author listed last above, Bendryshev, mak-s a separat( re- view and finds that the book will acquain*. wide circles of Card 1/2 TO !g V a IV. '01 ~ 41 'Ork- v45 I- P. fln q0 19 SIR D 21. 31 a A 41 a H 'N F JJA a, i9i re 4 Sol A& SAVAd a A a MOROZ, L.S I - - _,4 doktor tekhn.nauk; MIGIN, T.E,, inzh. Machaniam of the hydrogen embrittlement of steel. Fetallo- vedenie 3:51-57 159. WIRA 14:3) (Steel~liydrogen content) MOROZI L.S., doktor tekhn.nauk; KHESIN, Yu.D., inzh. Study of the mechanism of hydroger. embritt2em-ent of titanim and its alloys. Metallovedenie 3:74-87 t59. (MIF! 14:3) (Titanium-Hydrogen content) MOROZ, Lq,_�-j doktor tekhn.nauk; XIMIV, Yu.D. , Inzh. Anomalous metal grain growth in vacuum. Metal2avedenie 3:32-2- 313 '59. 14:3) (Vacuum meteilurgy) (Metal crystals--Growth) al qmcm JO W4~m uvwv ~r~ov a -i;i_7q-vz6 rm-V -1 -Mw 991 ~n - .-T3 7. in T-7-1 J. ~~.Q -0 .4 -rmQ PSI ft"..z 'I _TTW q, 'P2 PlT" -T%jjd--V ,Wtti -TTW nn!.f ; -?C-M -11-Ty "I P_ -1-1-MU J. Aunl ... u -1 .4 I~r .1 "~O r- Td ... W.Tx T_T.Q-kl J. npTr-0 '.., .,,=.Z T-,ns P_ J. Almq~s Z.TT~_Tpw J. tW ...... qN T-T-.pAl J. qWTV-V vi I.M .11 P- -1~1,1 j. '-3 P" P_ q?TR 1. ..ScUTUrm J. _jVM LKLI ..m T-T~W.N .1 vw 'A P_ ;. ~.PTP-z -a -A N -9 '-.In J. 1-ir -7 --. J.-C In %.-.TjiTq.S ..9-prd, * 71;.Mm 'S 'I r'- T-T-q-1 J- IM-4 ~. 61 I-V J- --mjw T 1- 6.1 .6 -H s M~ J. ZwTrm J.-ts 9-U-TTY J- 1--JJX --n V- R-T11-9 PM-M T -Ing J. ~.N .-.Jw T-TM.%L J. -%.m -V .P-74.- - 0.71TT~.d 'Eq ..T.Tsft u -74-T-- P- (C V_ TA,-Iwd Twluwzrzm Alatn cn mviw fv sLoTTv jo mlm~ P" -w-4-mns 'Y,m'-iT- (~ (-TT-Av-- 1-n-4- '-Ti-woq- '-n-P-t) 7~~T J- ~Twr- ..r- .~-ftn -1,~ IV ~ITW WTT4T4q 01 -X~VM WTunqM V~ r- J. -n - --,Ov -01~ j: W.u". q% (I j. M IZNUI= P--A" 1-.d . 72.-j- -AJ P-V-ft-I -1 3- -MZ--nm -M :lPDAM I-ps -woz rtm A-Irl fo~wm r-7.4--m JO ".PTVM .WAd" -1 .0 *P"""d ..Td~ 00?-C d O~c *"61 .T9-dpm -7 I(C -.0 '--T-TWN J. T-T.&W) C -9 'An.49 TF-0qq ffttrv".rT"A" 'YffP-7F I B00Y EXM ITTATION SOV/4575 Moroz, Lev Solomonovich'. Doctor of Technical Sciences, Professor; 13-c-ris Borisovich 'tTe-Mi~tVrn'Y 11yevich Polin, Leonid Vladimirovich Butalov, Saveliy I Moiseyevich Shu-11kinY and Aleksandr Petrovich Goryachev Titan I yego splavy, tom 1: Tekhnicheski chistyy titan (Titanium and Its Alloys, Vol. 1: Commercially Pure Titanium) Leningrady Sudpromgiz, 1960. 515 P. Errata slip inserted, 4,200 copies printed. Ed, (Title page): L.S. Moroz; Ed. (Inside book); Z.V. Vlasova; Tech. Ed.: N.V. Erastova. PURPOSE: This book is intended for scientific workers, plant engineers, and students in advanced courses in schools of higher technical education and tekhnikums. It may also be used as a manual for designers and industrial engineers (with the exception of mechanical engineers). COVERAGE: The book presents data on the structure, phase transformation, and physicochemical and processing properties of commercially pure titanium. CarT116- Titanium and Its Alloys (Cont.) SOV/4573 Shape-casting, vacuum metallurgy, plastic deformation, welding, and soldering and brazing processes for titanium are d-iscussed. Special attention is given to problems of constructional strength and to titanium reduction processes. L.S. Mo z wrote section 1 of Chapter 1, Chapter 2, and sections 1, 4, and 6 0T_=R7Mrr 3. B.B. Chechulin wrote sections 2-6 of Chapter 1, sections 2, and 5 of Chapter 3, and Chapters 4 and 9. I.V. Polin wrote Chapter 5; L.V. Butalov, Chapter 6; S.M. Shullkin, Chapter 7; and A.P. Goryachev, Chapter 8. The authors thank A.V. Smirnav for his advice, and I.A. Bytenskiy for assistance in editing the manuscript. References accompany each chapter. TABLE OF CONTENTS: Foreword Ch.-.,I. Physical Properties 5 Atomic and crystalline structure 5 - 0 tic 1 properties 12 Eplectaronic properties 15 \Electrical properties 16 5: !'T et~c properties 21 6. T evqZtl properties 23 Bibliograpo 33 car-T-2716- Titanium and It- Alloys (-'ont.) SOV/4573 Ch. 2.- Effect of Principal Impurities on the Structure and Phase Composition of Titanium 37 1. Regularity patterns of a general nature 37 2. Effect of 0 2~ NV cy 112 ~ Fe)and Si impurities on the structure and phase composition of titanium 42 Bibliography 56 C11. 3. Mechanical Properties 58 1. Mechanical properties of chemically pure titanium. Effect of impurities. Commercially pure titanium 56 2-Heabst7deal properties of commerciaUy pm*t~ titanium 63 -3.-SkIr-tioix-properties 80 Characteristic features of titanium constructional strength 91 4~-,Kffeet-ef-cold working on mechanical properties and structure of titanium 125 Effect of heat treatment on mechanical properties and structure of titanium 134 WbUography 144 Gar"AL 6~692 s/l8o/6o/ooo/oi/olV02? E193/El-35 ALITHORS: Moroz, L.81,--and Khesin, Yu. . (Leningrad) TITLE: ~fri~estigation of the Mechanism of Hydrogen Embrittlement of TitaniumAand its Alloys PERIODICAL: Izvestiya Akademii nauk SSSR,Otdeleniye tekhnichesklkh nauk, Metallurgiya J. toplivo, 1960,Nr 1,pp 111-1.22 (USSR) ABSTRACT: The object of the present investigation was to study the effect of hydrogen on the mechanical properties of a.-Ti and titanium alloys of the 0 and a+3 type (the constitution diagram of the Ti-H system is reproduced in Fig 1; wt-%, top scale, at-%, bottom scale)., The experimental materials comprised: technical purity Ti (U.T.S. 2 55 kg/mme_ at room temperature); a two-phase, Ti-base alloy containing 2% Mn, 1.3% Fe, 0.8% Ci, 1.42% Mo and 1.2% V; a two-phase, Ti-ba3e alloy containing 5% Al~ 3% Mo and 3% V; and a 0-alloy, containing 15% Mo~ After hot working, all these alloys were finely-crystalline with the average grain size of 0.04 to 0.07 mm, after a vacuum treatment (15 h at 7000C) Card their hydrogen content was less than 0,003%. Two methods i /16 were used to introduce hydrogen into the test pieces that were to be employed in the subsequent tests: the f"'02 S/180/60/000/01/016/027 K193/EJ35 Investigation of the Mechanism of Hydrogen Embrittlemerit,-.,' Titanium and its Alloys electrolytic and high-temperature diffusion method, The electrolytic treatment was carried out in a 0.1 N H2SOL~ solution, containing 20 mg As203/litre, at a ourrent density of 0.2 amp/cm2, After 2 h treatment, the concentration of hydrogen in the specimen varied from about 0.2 wt-% in the surface layer to 0.1% at a distance of 0.1 mm from the surface, and 0.01% at a distance of 0.2 mm from the SUTface. The high-temperature diffusion treatment was carried out at 700 OC, hydrogen being obtained by decomposition of titanium hydride; after the diffusion treatment the test piece was heated and, to avoid the effects of ageing, the mechanical tests were conducted within 24 h. To determine the effect of heat treatment on the constitution of the alloy, the effect of the quenching temperature on the structure of the a.+0 alloys was investigated with the aid of X-ray diffraction Card technique. The results are reproduced in Table 1 2/ 16 showing: quenching temperature, OC; proportion ~%) of the p-phase in alloy Nr 1 and Nr 2 (for composition see 66 6 9 2 s/18o/6o/ooo/o!/016/027 Z193/E135 Investigation of the Mechanism of Hydrogen Embrittlement of Titanium and its Alloys the heading of the table). The effect of hydrogen on the mechanical properties of the technical purity titanium, annealed at 650 OC7 is illustrated by data given In Table 2 under the following headings~, H2 content, wt-%; as (yield point, kg/mm2) ; 'qf (reduction of area, %); ak (impact strength, kg/mm2). It will be seen that whereas neither the yield point nor ductility (as indicated by Nf) of the specimens were affected by increasing hydrogen concentration, the impact strength, determined on notched bars.. failed catastrophically, This effect is a direct consequence of the nature of the Ti-H constitution diagram (Fig 1), Solubility of H In mw-Ti varies from 0.18 at 300 OC to O~002 wt.-% at 100 OC; after slow cooling from temperatures above 300 OC, hydrogen is present in titanium in the form of fully preoipitated titanium h7dride platelets (see the photomicrograph, Fig 2); when titanium, containing less than 0.18 wt-% H2, is heated to 300 Ocy Card hydrIdes dissociate completely and a solid solution of H 3/ 16 In Ti is formed. On quenching from this or a higher temperature, a super--saturat9d, precipitation-harderiable, Dob~2 S/180/60/000/ol/ol-,/027 E193/E135 Investigation of the Mechanism of Hydrogen &brittlemeriz; Titanium and its Alloys solid solution will be obtained, Thus, a titanium specimen with OX3% H, quenched from 500 OC, had an impact strength of 7 kgm/cm2i after ageing at 200 OC its Impact strength decreased to 1 kgm/cm2. Similar results could be obtained by prolonged room temperature ageing; this is illustrated by data, given in Table 3, which shows values of ak of the H-bearing Ti specimen after quenching from 500 OC, and after 1, 10 and 100 days' ageing at room temperature. Electron-microscope study of the ageing process confirmed the hypothesis tftat, in this case, embrittlement during ageing is associated with the precipitation and coalescence of titanium hydrides; this is illustrated clearly by the photomicrographs (X 2_350) reproduced in Fig 3 (a - the m1crostructure of an H-bearing, Ti specimen in the quenched conditlong b - the same microsection after 7 days' ageing at room Card temperature) which show the increased proportion of the V16 hydrides as well as the grain-boundary broadening In the aged material. Regarding the mechanism of the embrittling 11K 68692 S/180/60/000/01/016/02,7 E193/E135 Investigation of the Mechanism of Hydrogen Embrittiement of Titanium and its Alloys effect of hydrides, the authors base their con3iderations on the experimental data reproduced in Tables 4 and 5. The effect of the rate of deformation on ductility of annealed, H-bearing, a-Ti is illustrated in Table 4, which showss H2 content, wt-%; elongation (6, %) and reduction of area (N4f %) for specimens tested ~t the rates of strain of: M 2 mm/win, and ~II) 2,10 mm/min. The effect of the test temperature on the ductility of the same material is illustrated in Table ~, showing: H2 content, wt-%, 6, and 4f determined at +20 20 and -60 OC; (the specimen with 0.03% H tested at --40-0c failed in a brittle manner), It can be inferTed from data given in Tables 2, 4 and 5 that brittleness due to hydrogen is not revealed by standard tensile testsq conducted on cylindrical specimens, and only becomes evident in the presence of a notch, at high rates of strain, or at low temperatures. These J'acts can be interpreted In one way Card only; titanium hydrides, while possessing some ductility, 5/~16 have low resistance to rupture, if the normal. tensile stress in titanium is lower than tkie rupture ,trength of s/18o/Wooo/oi/016/027 E193/E135 Investigation of the Mechanism of Hydrogen Emby1ttleme,il, Titanium and its A.1loys the hydrides, the effect of hydrogen will not become apparent; if the normal stress is raised above that critical value (by introduction of a notch, increasing the strain rate, or lowering the temperature), cracks are formed in the hydrides which reduce the 3trength of the metal to a level depending an the propoylion of hydride platelets present and on their size, since these factors determine the number and dimensions of the cracks, This is illustrated by data reproduced in Fig 4, where the true tensile strength (SK, kg/mm2) of H-bearing titanium at --196 OC Is plotted against the quantity and dimensions of the precipitated hydrides, points a,6 and 0 relating to: (a) specimen quenched from 500 OC (low hydride concentration); (6) specimen quenched and aged for 2 h at 100 OC (medium (,-oncent-ration of hydrides of small size); 63) specimen annealed at 1+00 OC (high Card concentration of coarse hydride particles), The 6A6 propagation of crar;ks in hydrogen-embrittled titanium is assisted by the internal tensile stresses. prasent at the 66692 s/18o/Wooo/o L/ o 16/02 7 E193/E135 Investigation of the Me(,hanism of Hydrogen Embrittlement of Titanium and its Alloys edges of the hydride platelets owing to their higher (in comparison with Ti) specific volume. Oxygen, nitrogen, and carbon additions increase the sensitivity of titaniiun to hydrogen embrittlement, since they promote propagation of cracks; tne effect of aluminium. is beneficial since this metal increases solubility of hydrogen in titanium. The effect of hydrogen on the mechanical properties of a 0-type, 15% Mo-Ti alloy was studied next, The results are reproduced in Table 6, showing-, condition of the alloy (degassed; hydrogen- im regnated by electrolytic. treatment - 3 h at 0.2 amp/ cm~)i U.T.S. (cr]3, kg/mm2); yield point (aS~ kg/mm"); 6. %; 1,~ 9 %. It will be seen that none of the investigated properties were affec..ted by the presence of hydrogen. The results of experiments on specAmens with higher content of hydrogen (introduced by high- temperature diffusion), quenched from 7550 OC ', are given Card in Fig 5, where -~-r of specimens tested at the rates of ~1/ 16 strain of 2 and 2-00 mm/min (crcsses and circles.. respectively) Is pLotted against the hy(irogen c.,ntent '~ _- c '7~ - S/180/60/000/0 1 /0-7 ,b/02 E193/E135 Investigation of the Mechanism of Hydrogen Embrittlemei.,~ Titanium and its Alloys It will be seen that as long as hydrogen is in the solution, it does not affect the ductility of the 0--phase; precipitation of hydrides in the 0-pha3G causes the metal to fail in a brittle manner, this effect being attributed to notch-sensitivity of the p-phase. The hydrogen embrittlement of the cL+O alloys is next discussed, Two alloys of this type, containing 20 and 50% of the ~-phase, were investigated. Their mechanical properties OS, 6, and w), are given in Table 7, the figures in the fIrst and second sub-columns for each property relating to the hydrogen-free specimens and to specimens subjected to 24 h electrolytic hydrogenization treatment. It will be seen that, whereas the yield point was not affected by the presence of hydrogen, the ductility of the alloy (6, W ) decreased sharply. It was observed, also5 that fracture of the Card hydrogen-bearing specimens started at the surface, the 8/16 first cracks appearing already in the elastic deformation range (see Fig 6), The effect of the 68692 S/180/60/000/01/016/027 E193/E135 Investigation of the Mechanics of Hydrogen Embrittlement of Titanium and its Uloys variation of the content of hydrogen, introdu^,ed by high-temperature diffusion, is Jllustrated by data given in Table 8 under the following headings; H2 oontent, wt--%; W., % of the alloy containing -DO and 501 of the P 0-phase, specimen of the alloy,. containing 20% of the p-phase and 0,1% H2, failed in the brittle manner). These TeSU1tS showed that the embrittling effect of hydrogen was more pronounced in the alloy with a lower content of' the 0-phase. The effect of the deformation rate is Illustrated In Figs ~ and 8. In Fig ?a, ,.4f is plotted against the rate of strain (V, mm/min) fOT an alloy containing 20% of the 0-phase, curves 1 and 2 relating to specimens before and after the electrolytic hydrogenization treatment, respectively; the corre3poxn- ding curves for the alloy containing 50% of the ,3-pnase are plotted in Fig -b, Tn Fig 8a, I& is plotted aga-1 st L Ln Cai-d V for the alloy containing 50% of the ~--phase, curves 1, ? and relating to spe(Jmens with 0,025), 0,0SO and 0,119 9/1.6 of hydTcgen (Int T' -D d U C ed by tigh A.empisrai,~ire ~11,LfAisl0r, S/180/60/000/01/016/027 E193/X135 Investigation of the Mechanics of Hydrogen Embrittlement of Titanium and its Alloys treatment) respectively; the corresponding curves (I and 3) for the alloy containing 20% of the ~-phase are plotted In Fig 8b. In this case, too, the proportion of the O-phase determined the behaviour of the alloys. The ductility of specimens containing hydrogen, introduced electrolytically, increased with increasing V, approaching the ductility of hydrogen- free material at V = 200 mm/min, this restoration of ductility with increasing V being less pronounced in the alloy with 50% of the 0-phase. In the case of specimens containing hydrogen introduced by the high- temperature diffusion treatment, the restoration of ductility with increasing V was slow in specimens containing 50% of the 0-phase, and did not occur at all in specimens containing 20% of the O-phase and 0.1% H2, The effect of the constitution on the sensitivity of the Card cL+P alloys to hydrogen embrittlement was revealed also 10/16 by the results of impact strength tests, conducted on notched, cylindrical specimens 8 mm diameter (depth of 68o9a s/18o/6o/ooo/01/016/027 9193/E135 Investigation of the Mechanics of Hydrogen Embrittlement of Titaniim and its Alloys the notch 1 mm, root radius 0.55 mm). The results of these tests are given in Table 9, showing: H2 content, wt-%; ak, kgm/c~n2, of specimens containing 20 and 50% of the O-phase, However, it is pointed out that tensile test at slow rates of strain is a more sensitive method of revealing the hydrogen embrittlement of titaniwa alloys of the a+p type. The difference in the behaviour of material containing hydrogen, introduced by different techniques, is attributed to the fact that hydrogen introduced electrolytically (i.e. at room temperature) can dissolve in the O-phase only. This was checked by X-ray diffraction analysis, carried out on a complex, Mn-bearing alloy, whose alloying elements, however, did not affect the solubility of hydrogen, The results are given in Table 10 under the following headingst constitution of the allu (relative Card proportion of the a,- and 5-phase ; lattice parameters 1.1/ 16 of the a- and 0--phases in the degassed alloy; lattice parameters of the cL-- and 0-phases in the alloy with